NC0000396_Renewal Application_20100611

Progress Energy
NPDES permit renewal request
Asheville Steam Electric Plant
Permit Number: NC0000396
Buncombe County
June 11, 2010

&*,, Pro ress 9 Energy
Hand Delivered
File Point: 12520 -13-01
Tom Belnick, Supervisor
Complex NPDES Permitting Unit
North Carolina Division of Water Quality
1617 Mail Service Center
Raleigh, NC 27699 -1617
June 11, 2010
Subject: Carolina Power & Light Company dba Progress Energy Carolinas, Inc.
Asheville Steam Electric Plant
NPDES Permit No. NC0000396
Buncombe County
Renewal Application
Dear Mr. Belnick:
The current NPDES permit for the Asheville Steam Electric Plant expires on December 31, 2010.
Progress Energy hereby requests that the NPDES permit for the facility be reissued. Enclosed are EPA
Application Form 1 — General Information, EPA Application Form 2C — Wastewater Discharge
Information and EPA Application Form 2F — Stormwater Discharges Associated with Industrial Activity,
all in triplicate.
As we have previously discussed with DWQ staff, in order to facilitate enhancements to the existing dam
of our 1964 ash pond, Progress Energy proposes to relocate outfall 001 to a point approximately 3000 feet
downstream of its current location. This relocation will be necessary to allow for additional stabilization
work to be undertaken on the existing 1964 ash pond dam. The proposed relocation is to a point where
access under Interstate 26 already exists. Coordinates for the proposed discharge point are North
35.47367 and West - 82.504. Enclosed with this renewal application is information pertaining to the 7Q10
and IQ 10 flows provided to us by staff of the USGS for this location.
With reissuance of the NPDES permit, Progress Energy requests the following language regarding usage
of biocides and the completion of the Biocide Form 101 be added to the permit:
The permittee shall not use any biocides except those approved in conjunction with the permit
application. The permittee shall notify the Director in writing not later than ninety (90) days prior to
instituting use of any additional biocide used in cooling systems which may be toxic to aquatic life
other than those previously reported to the Division of Water Quality. Such notification shall include
completion of Biocide/Chemical Treatment Worksheet —Form 101. Division of Water Quality
approval is not necessary for the introduction of new biocides into outfalls that are tested for whole
effluent toxicity. Completion of the Biocide Worksheet is thus, not necessary for those outfalls with
toxicity testing requirement.
In addition, Progress Energy also requests the following reductions in monitoring requirements based on
analysis of sampling results during the term of the current permit:
Progress Energy Carolinas, Inc.
Asheville Steam Plant
200 CPU Drive
1 Arden, NC 28704

Outfall 005
Remove sampling requirements for Beryllium, Cadmium, Chromium, Copper, Lead, Manganese, Nickel,
Silver, Thallium, Zinc and Fluoride
Outfall 001
Remove monitoring requirements for Beryllium, Cadmium, Chromium, Coopper,,Lead, Manganese,
Silver, Thallium, Zinc, Fluoride, Total Nitrogen and To a1 pho_�
Reduce required monitoring for Mercury to twice per month -ou
Condition A.(7) of the,current NPDES permit for the Asheville Steam Electric Plant requires that
Progress Energy request a continuation of its 316(a) variance beyond the term of the present,permit
Enclosed is an EPA guidance letter dated August 11, 1988 outlining the general procedure to be followed
in requesting the continuance of a316(a) variance The following, is Progress Energy's response to the
pertinentYfactors contained in the EPA general procedure for the reissuance of the 316(a) variance.
1 The permittee must request the variance be continued
Response Progress Energy hereby requests continuation of the 316(a) variance reflected in
its present NPDES permitfor the Asheville Steam Electric Plant
2. Plant operating conditions and load factors are unchanged and are expected to remain so for the
term of the reissued permit
Response The plant operating conditions and load factors are unchanged and are expected
to remain so for the term of the reissued permit
3 There are no changes to the permittee's knowledge to the plant discharges or other discharges in
the plant area which could interact with thermal discharges
Response During periods of drought, as makeup water is pumped from the French Broad
River to Lake Julian to sustain, operating cooling water levels, Progress Energy
staff suspect there may be some influence m Lake Julian from our upstream
discharge point in the French Broad River This permit application includes a
proposal to relocate the discharge point from the facility's ash pond (outfall 001)
to facilitate enhancements to the facility's 1964 ash pond dam. This outfall
relocation should also eliminate any potential influence in Lake Julian from our
discharge in the French Broad River
4. There are no changes to the permittee's knowledge to the biotic community of the receiving water
body which could impact the previous 316(a) determinations
Response- As demonstrated by Progress Energy's environmental monitoring, since issuance
of the current NPDES permit there have been no changes to the biotic
community of Lake Julian which would impact the previous 316(a)
determinations

If you have•any questions regarding the enclosed information, please contact Shannon Langley at (919)
54'6 -2439
I cent, under penalty of law, that this document and all attachments were prepared under my direction
or supervision in accordance with a system designed to assure that qual f ed personnel properly gather
and evaluate the information submitted Based on my inquiry of the person or persons who manage the
system, or those persons directly responsible for gathering the information, the information submitted is,
to the best of my knowledge and belief, true, accurate, and complete I am aware that there pare
significant penalties for submitting false information, including the, possibility of fines and imprisonment
for knowing violations
Sincerely,
- M, ���
Garry A Whisnant
Asheville P1ant,Manager
Enclosures
CC. Laurie Moorhead (Asheville Plant)
Crystal Diedrich (Asheville Plant)
Shannon Langley (PEB 4)

*
August 11, 1988
R17: 4M-FP
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY
REGION IV
343 COURTLANO XTR99T
7 ATLANTA, GCOROIX 30349
Mr. Clyde Baldwin
'Division of'Water
KY* Natural Resources
Prvtectlon Cabinet
port Boone Plaza
i8 'Aeilly Road
Frankfort, KY 40601
& Environmental
RE: 346 GL a for Permit Reissuance
Dear
t�lr. n:
,o,
Questions have arisen as to what pures and activities are necessary in
reissuing a permit for a facility which has thermal limitations based on a
previous variance granted under Section 316(x) of the Clean meter Act. The
following, is provided as 'a, follow�up to information provided at the February
1988, EPA/State meeting in Aestin, Florida.
J
A thermal variance granted under 5316(a) terminates on, expiration of the NPDES
permit of which it is a, part (Attachment A). Procedures for a reissuance are
virtually unchanged from an initial determination. The amount of data necessary
to support the variance at the time of reissuance will probably be minimal.
Bkxmver, if conditions have changed materially, a significant quantity of informa-
tion may be needed.
NEE: Tb the extent that permittees are unaware of these, regUirements, they
should be notified, of they expeditiously so that they can be prepared.
The general procedure is as follows:
I. The permittee must request that the variance be continued, preferably at the
time of permit application. At that time, he should provide a basis for that
continuance. The basis couldbe as simple ash (•a) plant operating conditions
-and load factors are unchanged and are expected to remain so for the term of
the reissued permit, (,b) there are no changes (to his knowledge) to plant
discharges or other discharges in the plant site area which could interact
with the thermal discharges, and (c) there are no. changes (-to his knowledge)
to -the biotic community of the receiving water body which would impact the
previous 316 determinations.
2. If the permitting authority agrees with the, basis, appropriate permit oondi-
t -ions would be developed; otherwise, additional data would be requested as
needed. Request for additional data must be made within 60 days of receipt of
the application ,(Answier to Question 7, Attachment A) . Additional studies can
be made a permit requirement if needed '(Answer to Question 7.1.

Page 2
August 11, 1988
0
3. The Fact Sheet/Utionale should contain a summ' ary of 316 variance activities
from the - previous permits (dates, deteLminations, limitations, etc.) and
indication of the proposed basis for continuing the 316 variance. an
language is included in, Attachment B. Sale
4. The Public notice ;requirements are contained in S124.75(a),
is also ,included in Attachment B. ale language
Should you have have questions or need assistance,
-404/347 -3012. feel free to contact me at
Sincerely yours,
j U�
charles ,s. Kaplan, P.E.
National Expert Steam Electric/Water
Enclosures
1„ - ,
cc: Mr. R. Bruce Scott
Identical letters sent to all states in Region IV

PI—P nrint nr tvnA in the ii—hnirlpri areas nniv
Form Approved OMB No 2040-0086
FORM'
US ENVIRONMENTAL PROTECTION AGENCY
IJEPA I D NUMBER
GENERAL,INFORMkTION
EPA
S TIA C
Consolidated f5ermiis Program
F
GENERAL
(Read the "General Init-rucurins before starting)
2
LABEL,ITEMS
q. % GENERAL INSTRUCTIONS
i if if a preprinted label has been providea, affix it in the
a, �R
space R iview the information carefully if any ofoii
rough it and enter the correct data in'the
is incorrect, cross through
F. appropriate fill-in,area below Also, if any of the,preptinted data
is absent (the area to the left of the label space lists the
PI FA­ "A information that should appear), please proAde it in the proper
PLEAbE2PI1A
fill-in area(s) below If th6,label is Complete and correct, you
need not co m pletedierns I'll(, V, and'VI (ex'Oept.1/1-81 which
UWE, must be completed regardless) Complete all items if no label
'U1W has been provaed Refer to the instructions for detailed item
N
UMbLKE
TYNAME
(III `FACIU,
_�g 'Or�, U" descriptions and for the legal authorizations underwhich this
Y,ILOCA
data is collected,
11 POLLUTANT CHARACTERISTICS
INSTRUCTIONS Complete A through J'to determine whether you needto submit any permit application forms to the EPA If you answer "yes" to any questions, you must
submit,this form,and the supplemental form listed in the parenthesis foil-owing the question Mark W in the box in the third column If the supplemental form is attached If
you answer "go" to each question, you need,not submit any',,of these forms You may, answer 'no"'if your activity is excluded from permit requirements, see Section C of the
instructions See also, Section D ofthe instructions for definitions of bold-faced terms
Mark *X*
Mark'X
SPECIFIC QUESTIONS
YES
NO
FORM
ATTACHED
SPECIFIC QUESTIONS
YES NO FORM
ATTACHED
A Is this facility a publicly owneid,treatment works which
results in a discharge,to wateis•of the U S 9 (FORM 2A)
X
B Does or will this facility (either existing or proposed),
include 'a concentrated animal feeding operation or
X
aquatic animal production facility which results in P
Is
17
Is
—
19
20
21
discharge to waters of the U S.? (FORM 213) -
C Is this a facility which currently results in `discharges to
X
X
D Is this a proposed facility (other than those.descnbed in,A
*result
X
waters of the U S other than,thos&descnbed in A or B
or B,above) which ittill in a,discharge to.watersW
above. (FORM iC)
X2
23
24
the U S 9 (FORM 2D)
_25
t 2e
21
E Does or will this (facility treat, store, or of
F Do you or will you inject at this facility lirdustrial or
-
-dispose
hazardous wastes?'(FORM 3)
X
municipal effluent below the lowermost stratum
X
containing, within one quarter mile of the well bore,
28
N
30
underground sources of drinking water? (FORM 4)
131
M
33
G rpo you or will you,qect,at,this facility any produced water
H Do, you or will you inject at,this facility fluids for special
or other fluids- which are 'brought' to the surface in-
processes,such as mining of sulfur byithelFrasch process,
connection with conventional oil or natural gas•production,
X
solution mining of minerals, in situ combustion of fossil
inject fluids used for enhanced recovery of,oil or natural
fuel, or recovery of geothermal energy? (FORM 4)
gas, or inject fluids for storage of liquid hydrocarbons?
(FORM 4)
—34
35•
37
n
39
1 Is this facility a proposed stationary source which is one
J Is this facility a proposed stationary source which is
of the 28,industrial categories listed'in the instructions and
X,
NOT one of the 28 industrW Categories fisted in the
X
Which will potentially emit 100 tons per year of any air
instructions and which will potentially erri tons per
:pollutant regulated'6nder the Clean Air Act and may affect,
year of any air pollutant regulated under the Clean Air Act
10'
41
42
43
or be located in an,attainment area? (FORM!5)
and may affect or be located in an attainment area'?
(FORM 5)
III NAME'OF FACILITY
TI SKIP' I Asheville -Steam Electric Plant
IV FACILITY'CONTAC
A, NAMEA TITLE (last,firsi: &title) B PHONE (area code& no) W 'I
2 Jc
Whisnant, Garry A. Pl ant lManager 8�8 6 7L5 A -1
16 41 46 48 1,49 51 1 52
V FACILTY'MAILIN6,ADDRESS
A STREET OR P 0 BOX 10"
c I live I I I I I I I I I I I I I
61
2 0 CP&L,Dr
J3
AeR
16
B CITY OWTOWN
C STATE D ZIP COD
c
Arden
C 2J7J4
4
40,
41 42 47 51
VI FACILITY LOCATION
A STREET, ROUTE NO OR,OTHER SPECIFlb IDENTIFIER 3 QU
c I I I I I I I I J
6 A& -rive SO CE! ,SO
2 01
" M p,
5 R`- ,
45
B COUNTY NAME
Buncombe . . .
A
P. 'V�
70
C -CITY OR TOWN
D STATE
E ZIP CODE
F COUNTY CODE (i(known)
V-�
Lfl,Ardiln'
1401
J2' 7134
17 51
53 S4
EPA Form 3510-1 (8-90) CONTINUE ON REVERSE

CONTINUED FROM THE FRONT
VII SIC CODES (4-digit, to orderof non
A FIRST B SECOND
e
'4911
(spec) Electric Power Services 7
(speck)
7
15 116
19
15
116 18
C THIRD D FOURTH
e
(specify) 7
(sPeC�)
7
5
18 1g
15
18 18
VIII `OPERATOR INFORMATION
A NAME B Is the name fisted to Item
t VIII -A also the owner?
s Carolina Power & Light Company d /b /a. Progress Energy Carolinas, Inc 0YESONO
15, 16 - - - 55 BB
C STATUS OF OPERATOR (Enter the appropriate letter into the answer box j "Other, "specify)
D PHONE (area code & no)
F = FEDERAL
M= PUBLIC (other than federal ar state)
P
(specify)
`
A
8 2�8 687 5 2 01
S= STATE
P = pP,RIVATE 0 = `OTHER (spec)
_
56,
15
16 18 jig z1 11 M
E `STREET OR P O BOX -
� "` �� r" `s� �:' ,_. , � � �•�y,st`' "�t� t a fit; v4'"vs
i� �x. �r.•, ^3.,: -.. 's�'��.}, >•.tl": �u� "�SE ^`"d'. ks, y k "` k
x '�
. Y^Y' Cpl
, x
_
AID' C & Drive
'
iMd
66
AiX Sf
F CITY OR TOWN
IG STATE
I H ZIP CODE
IX INDIAN LAND
-
Is the facility located on,lndian lands?
JB
A rden
NC
28704
❑ YES © NO
5z
1s
1B a
+1 iz
a s1
X EXISTING ENVIRONMENTAL PERMITS
D PSD (Air Em+ss+ons romPra osedSources <`Syu�3tt,;f
C T I.. "'E_f "4'$'Fr`"'}`i3° r` ]; "'{s•° eehlieS ;:u -1
u .' =
s P
A NPDES D+schar es toSuraceWate "r
C
s
T
N
I
NC0 0 0 0 3 9 6
, a, s
B 'UIC Under round Fn ectron o Fluids
-E OTHER` s ect
C
I i
I I
t
T
(SpeClity) WNCRAPCA Air Permit
='
-
a - 30
15
•18
1J 1B
- 30
C' RCRA' Hazardous Waltes
— E OTHER :sec+ '
C
T
I
-
s ec+ State non discharge permit for ash
(P JJ)
9
R
-
g WQ0000020 reuse
15
1 10
17
18 _ _ ,30
15 1 16 1 17 118 _ 30
XI MAP ,
Attach to this application a topographic map of the area extending to attleast one'mde beyond property boundaries The'map must show�the outhne,of the facility, the
location of each of its existing and proposed intake and discharge structures, each of its haiardoud waste treatment, storage, or disposal facilities, and each well where,it
-injects fluids underground' Include all springs, rivers, and -other surface water bodies in-We map area See mstructions'for precise requirements- - -
XII NATURE,OF BUSINESS provide a bnefdescn tion)
Electric utility - This facility is an ,electric generating facility consisting of two ecoal sfired units with a
total net capacity of 376 Megawatts and two Internal Combustion turbines with a total net capacity of 324
Megawatts
XIII CERTIFICATION (see instructions)
I certify under penalty of la'w that 1 have personally,examined and am famthar with the information submitted inithis application and all attachments and that, based on my
inquiry of those persons immediately responsible for obtatntng,the information contained to the application, I believe that the information ts'true, accurate, and complete I
;am aware that there are significant penalties for submtthng,falde tnformahon, including the possibility of fine and imprisonment
A NAME' &OFFICIAL TITLE (type or print)
B SIGNATURE
C',DATE,SIGNED
Garry A. Whisnant
Manager - Asheville Steam Plant
o / �
(
04
COMMENTS FOR OFFICIAL OSE ONLY ;
���;s5ag{ BEY
C. iAFi � xj e ' id t
✓
55
R''1 °c -43"1x�G46'4 F�ME, �.k3R'i'x'u]i"t
EPA Form 3510 -1 (8.90)

EPA I D NUMBER (copyfrom Item 1 ofform 1) Form Approved
OMB No 2040 -0086
Please print or tune in the unshaded areas oniv N Approval expires 3 -31 -98
FORM
2C
NPDES
U S, ENVIRONMENTAL PROTECTION AGENCY
mod" EPA EXISTING MANUFACTURING " COMMERCIAL, MINING AND S LVICUL'TURE OPERATIONS
Consolidated Permits Program
I OUTFALL LOCATION
For each outfali, list the latitude and longitude of,ds location to the nearest 15,seconds and the name of the receiving water
A OUTFALL NUMBER
(list)
B LATITUDE
C LONGITUDE
D RECEIVINGWATER'(name)
1'DEG
2,MIN
3 SEC,
1 DEG
2 MIN
3,SEC
001
35
28
03
82
32
56
'French Broad River
002
35
28
10
82
32
20
Lake Julian
II FLOWS, SOURCES OF POLLUTION, AND TREATMENT TECHNOLOGIES
A Attach a line drawing showing the water flow through the facility Indicate sources of intake water, operations contributing wastewater to the effluent, and treatment units
labeled to correspond to +the more detailed descriptions in Item B Construct a water balance on the line drawing,by showing average flows between intakes, operations,
treatment units, and outfalls If a water balance cannot be determined (e g ;for certam'mmmg,activities); provide a pictorial description of themature and amount of any
sources of water and any collection or treatment measures
B For each outfall, provide a description of (1) All operations contnbuting wastewater to the effluent, incl6ding process wastewater, sanitary wastewater, cooling water,
and storm water °runoff, (2) The average flow contributed by each operation, and (3) The treatment received by the wastewater Continue on additional sheets ff
necessary
1 OUT-
2 'OPERATION(S) CONTRIBUTING FLOW
3 'TREATMENT
FALL
NO (list)
a OPERATION (list)
b AVERAGE FLOW
(include units)
a DESCRIPTION
b LIST CODES FROM
TABLE 2C -1
_
001
'Ash sluiceu water -
'See attachmenC 2 for flows
Sedimentation„ Neutralization
- -
1 =U -
2 -K
Coal Pile runoff
See at wchmenc 2 for fhowe
Sedimentation, Neutralization
-
1 -U
2 -K
_
FGD wastewater
See attachment '2'for flows
Flocculation, coagulation, wetland treatment
1 -G
" -
Low volume wastewater
See attachment 2 for flows
Sedimentation, Neutralization
1 -U
2 -K
- --
WaPei treatment wastes
-
Boler blowdown
-
Plant drains - - - -
- - - - -
-- - - - -
-,
_ 'Ash hopper seal water
Air,preheater cleaning wastes
_
Chemical metal cleaning wastes
Evaporation of neutralization and precipitation
1 -F
2 -K
Plant stormwater
,See,attachment 2 for flows
Sedimentation, Neutralization
1 -U
2 -K,
-
Comustion urk- 2-wastewateis
- - b - T
-
See - attachment 2 for flows
Sedimentation, Neutralization
1 -U -
2 -K
002
Once through cooling water
See attachment 2 for flows
'Evaporation
1 -F'
Circulating water Co heat exchangers
See attachment 2 for flows
Evaporation
1 -F
OFFICIAL USE ONLY (ejfuentguidebnevsub- categorrer)
EPA, Form, 3510 -2C (8 -90) PAGE 1iof4 CONTINUE ON REVERSE

Cn NTINIJFn FROM THE FRONT
C Except for storm runoff, leaks„ or spills,, are any ofthe discharges described in Items III' A or B intermittent or season a19
© YES (complete the following table) ❑ NO (go to Section 111)
3 FREQUENCY
4' FLOW
'a DAYS'PER
B TOTALVOLUME
2 OPERATION(s)
WEEK
b MONTHS
a FLOWRATE,(mmg.)
(specitywnhumus)'
1 LONG TERM
2 MAXIMUM
1 LONGTERM
2 MAXIMUM
1 OUTFALL
CONTRIBUTING FLOW
(specify
PER YEAR
C DURATION
NUMBER (hst)
(hsi)
avemge)
(specifyavemge)
AVERAGE
DAILY
AVERAGE
DAILY
fin day')
001 Water treatment, wastes /Filter
Rarely
0,003
0.006
backwash
- 2 /year
0 003 pear
0 005
Combustion Turbines
unit
Chemical metal cleaning waste
0 -90 „000
gallons
produced
every 5 -8
years
Plans are
to evap
instead of
discharge
,Air preheater cleaning
2 /yr /unit
0 01
0 01
Revers Osmosis reject stream (if
installed for process water makeup)
as needed`
0 015'
0075
ill ,PRODUCTION
A Does an- effluent guideline limitation promulgated by EPA under Section
304 of the
Clean Water
Act apply to your
facility?
W] YES `(complete fhem'111 -8)
❑
NO'(go to Section
IV)
B Are the limitations In the applicable, effluent guideline expressed inderms of production (orothermeasure of operation)?
❑ YES (complete Item 111-0 W1 NO (go to Section 1V)
C If you answered "yes” to Item III -B, list the quantity which, represents an,actual measurement of your level of production, expressed In the terms and units used In the
applicable effluent guideline, and 'indicate, the affected outfalls
_1- AVERAGE DAILY PRODUCTION
2,AFFECTED OUTFALLS
(listoutfoll numberv)
a QUANTITY PER DAY
b UNITS OF MEASURE
c OPERATION, PRODUCT, MATERIAL, ETC
rspecify)
IV IMPROVEMENTS
A Are you now required
by any Federal, State or local
authonty to meet any implementation" schedule for the construction,
upgrading or operations of wastewater
treatment equipment or
practices or any other environmental
programs which may affect the discharges described In this application?
This includes, but is not limited to,
permit,00ndnions, administrative
or enforcement orders,
enforcement compliance schedule letters, stipulations, court;orders, and
grant orloan conditions
❑ YES (complete
thefollowing table)
® NO (go,to7iem'1V -B)
1 IDENTIFICATION OF CONDITION,
2 AFFECTED OUTFALLS
3 BRIEF DESCRIPTION OF PROJECT
4 FINAL COMPLIANCE DATE
AGREEMENT, ETC
a NO
b SOURCE OF DISCHARGE
a ,REQUIRED
6 PROJECTED
B OPTIONAL You may attach additional sheets describing any additional water pollution control programs (or other environmental projects which may affect your
discharges) you now have underway or which you plan Indicate whether each program Is now underway or planned, and indicate your actual or planned schedules for
construction
® MARK "X" IF DESCRIPTION OF ADDITIONAL, CONTROL PROGRAMS IS+ATTACHED
EPA Form 3510 -2C (8 -90) PAGE12 of 4 CONTINUE ON PAGE 3

- CONTINLIED'EROM PdGE,2 EPA I D NUMBER (copyjrom Item ! oJForm /)
EPA Form 3510 -2C (8 -90) PAGE 3 of 4 CONTINUE ON REVERSE
V INTAKE AND EFFLUENT CHARACTERISTICS
A, B, 8 C See instructions before, proceeding — Complete one set of tables for each outfall — Annotate the outfall number in the space provided
NOTE Tables VyA, V- B,,and V -Care Included on separate sheets numbered V -1 through V -9
D Use the space below to Ilst,any of the pollutants listed In'Table�2c -3 of the Iinstructions, whlch� you know'or have'reasom,to believe Is,dlscliarged or may be discharged
from any outfall For every pollutant you list, briefly describe the reasons you believe It to be present and report'any analytical data In your possession
1 POLLUTANT
2 SOURCE
1 POLLUTANT
2 SOURCE
Asbestos
Used in insulation, trace
amodnts may be washed down
drains in plant areas during
maintenance activities
Strontium
Trace elements occasionally,
Uranium
present in coal
Vanadium
Zirconium
VI POTENTIAL DISCHARGES NOf COVERED_BY'ANALYSIS
Is any 'pollutant, listed, in Item V -C a substance or a component of a substance which you currently use or manufacture as an Intermediate or final product or byproduct?
YES'(hrr all such pollutamts'helow ) ❑ NO (go to item V! -B)
The following substances may be present in coal
Antimony
Arsenic
'Beryllium
Cadmium
Chromium
Copper
Lead
`Mercury
Nickel
Selenium
;Silver
Thallium
Zinc
See attachement 4 for Potential Discharges Not covered by Analysis
EPA Form 3510 -2C (8 -90) PAGE 3 of 4 CONTINUE ON REVERSE

rr1NTINl 11zn FRr1M THr FRONT
VII BIOLOGICAL TOXICITY TESTING'DATA
Do you have any knowledge or reason to believe that any biological test for acute or chronic toxicity has been made on any of your discharges or on a receiving water In
relation to your discharge within the last 3 years
W`YES,(ident fy lhe,tevt(y) and describe their purposes below) ❑ NO (go to Section VIM
Outfal'1 001 From 2006 through 2009, 12 chronic toxicity tests were performed on the ash pond discharge as
required by the current NPDES permit. All of the -tests were recorded as "pass" and exhibited no
toxicity at required testing concentrations
VIII CONTRACT ANALYSIS;INFORMATION
Were any of the analyses reported In Item V performed'by a contract laboratory or consulting firm?
® YES,(hrt the name, address, and telephone number of, and pollutants analyzed by - ❑ NO'(go to Section /X)
each suchdaboratory orfirm below)
C TELEPHONE
D POLL'UTANTS,ANALYZED
A NAME
B ADDRESS
(area code & no
(list)
Pace Analytical Labs
2225 Riverside Drive
(828) 254 -7176
Metals, TOC, BOD,
Asheville, NC ',28804
Nutrients, TSS, COD,
Flouride, Oil and Grease,
cyanide, phenols, volatiles
Environmental Testing Solutions
PO Box 7565
(82&)1 S50 -9364
Aquatic Toxicity
Asheville, NC 28802
Applied Speciation and
18804 Northcreek Parkway
(425) 483 -3300
Selenium_ Speciation
Consulting,
Bothell, WA 98011
IX CERTIFICATION
1 certify under penalty of, law that,this document and all attachments were, prepared `under my direction or supervision in, accordance with a systemi4esigned,to 'assure that
qualified personnel properly gather and evaluate the information submitted' Based, on my inquiry of the person or persons who manage the system or those persons
directly responsible for gathenng the information, the mformahomsubmitted is, to'the best of my knowledge and belief, true, accurate, and complete ham,6vare that there
are significant penalties for submitting false information, including the possibility of fine and imprisonment for knowmgmolations
A ,NAME & OFFICIAL TITLE (type or print)
B rPHONE NO (area code & no)
Garry A Whlsnant, Plant Manager
(828) 687 -5201
C SIGNATURE
,D DATE SIGNED
�& 0
/o ( O
EPA Form 3510 -2C (8 -90) PAGE 4 of 4

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EPA ID Number (copy from Item 1 of Form 1) Form Approved OMB No ,2040 -0086
P!anaa rint ,-, t. n,,,fho,—had.el. —­1v NC0000396 I Approval expires 5-31-92
FORM
2F
NPDES
U S Environmental�Protection Agency
�1 Washington, DC,20460
For Application for Permit to Discharge Storm Water
Discharges, Associated with Industrial Activity
Paperwork Reduction Act Notice
Public reporting burden for this application is estimated to,average 28 6 hours per application „including time for reviewing instructions, searching existing data sources,
gathering and maintaining the data needed, and completing and reviewing the collection of information Send comments regarding the burden estimate, any other aspect
of this collection of information, or suggestions for improving this form, including suggestions which may increase or reduce this burden to Chief, Information Policy
Branch, PM -223, U S Environmental Protection,Agency, 1200 Pennsylvania Avenue, NW, Washington, DC 20460, or Director, Office of Information and Regulatory
Affairs, Office of Management and Budget, Washington, DC 20503
I. Outfall Location
For each outfall, list the latitude and longitude of ds location to'the,nearest '15 seconds and the name, of the, receiving water
A Outfall Number
(list)
B Latitude
C Longitude
D Receiving Water
(name)
SW -1
35
28
01
82'
32
13
Lake Jul -fan
'SW -2
35'
27
51
82
32
05
Lake Julian
SW -3
35,
27
55
182
32
06
Lake Julian
SW -4
35,
28
39
82
32
46
Lake Julian
SW -5
35
28
29
82
32
51
Unnamed tributary to Powell Creek
ISW -6
35
28
23
X82
32
45
Lake Julian
II. Improvements
A Are you,now required by any Federal, State, orlocal authority to'meet any implementation schedule for the construction, upgrading or operation of wastewater
treatment4gwpment,or practices or any,other environmental programs which may'affect the, discharges described in this application? This includes, butts not limited
to, permit conditions, administrative or enforcement orders, enforcementcompliance schedule letters, stipulations, court orders, and granb or, loan conditions
1 Identification of Conditions,
Agreements,,Etc
2 :Affected Ouffalls
3 Brief Descriptiowof Project
4 Final,
Compliance Date
number
source of discharge
a req
b prof
N/A
I
f
B You may attach additional sheets describing any additional water pollution (or other environmental projects which may affect your discharges) you now have under
way,or which you, plan Indicate whether each program is now underway or planned, and indicate your`actual or planned schedules for construction
III Site Drainage Map
Attach,a,site map showing topography (or indicating0e oubine'of,drainage areas served by the outfalls(s) covered in the application if a,topographic map is unavailable)
depicting the facility including each of,ds intake ,and,di`scharge structures, the'drainage area of each storm water outfall, paved areas and buddings, with in, the drainage
area of each i storm water outfall, each'knovinpast or present %areas used for outdoor, storage of disposal of sign ificant'matenals, each existing (siructurat control' measure
,to reduce, pollutants in,storm water runoff, materials loading and access "areas, areas where pesticides, herbicides, sod condrtioners?and'fertilizers ., are applied, each of
its hazardous waste treatment, storage or disposal units (including each area not required to, haveia RCRA permit which isrused for accumulating hazardous waste
under 40 CFR 262 34), each well where Fluids from,the.facility are infected underground, springs, and other surface water bodies which recerved,storm water discharges
from the facility
EPA Form'3510 -2F (.1 -92) Page 1 of 3 Continue on Page 2

Continued from the Front
IV. Narrative Description of Pollutant,Sources
A For each outfall provide an estimate of the area (include units) of imperious surfaces (including paved areas and building roofs) drained to the outfall and an estimate of the,total surface area
drainetl by the outfall
Outfall
Area of Impervious Surface
Total Area Drained
Outfall
Area of Impervious Surface
Total Area Drained
Numtier
(provide units)
(provide units)
Number
(provide uni
(provide units)
SW -1
0 34 acres
3 69 ares
SW -4
0 o9 acres
5 5 acres
SW -2
0 13 acres
0 38 acres
SW -5
0 09,acres
4 0 acres
SW -3
0,84 acres
9 X06 acres
SWr_6
0 18 acres
7, 6 acres
B Provide a; narrative description of significant materials that are currently or In the past three +years have been treated, stored or disposed in a manner to, allow exposure
to storm water, method of treatment, storage, or disposal, past and" present, materials management practices employed'to minimize contact'by °these materials with
storm water runoff,, materials loading and access areas, and,the location, manner, and'frequency'm which pesticides, he�biades, sod,conddloners,,and'fertihzers are
applied
See attachment 6
For each outfall, provide, the location and a description of existing, structural and nonstructural control measures to reduce pollutants in storm water runoff, and a
description of 'the treatment;thelstorm'water receives, Including the schedule,and� type of maintenance for +control and treatment measures and the ultimate disposal
ofany solid or fluid wastes other than,by discharge
Outfall
LIsTCodes from
Number
_ _ Treatment
Table 2F -1
See attachment 7 -
V. Nonsto=ater Discharges
A I certify under penalty of law hat the outfall(s) covered by this apphcatlon have,been tested or evaluated for the presence of nonstormwater discharges, and that all ,
nonstormwater�jdischarged from these oudall(s),are Identified In either an accompanying,Form 2C or From,2E appllcation,for the outfall
Name °and Official Title (type or print)
Signature
Date Signed
Laurie Moorhead, Env Specialist
B Provide a description of the method used, the date of any testing, and the onsite drainage points that were directly observed during a test
On an annual basis, the Asheville Plant Environmental Specialist conducts a visual inspection of all stormwater outfalls during
an extended period of dry weather This visual inspection serves to ensure that there are no unpermitted discharges from the
permitted stormwater outfalls Certification statements are signed, dated and kept onsite behind Tab 5 Annual Certification
Page of the SWPPP
Dates for previous certifications include April 16, 2010, April 23, 2009
VI. Significant Leaks orSpills
Provide existing Information regarding the history of significant leaks or sp(lis of toxic or hazardous pollutants at -the facility,In the lastrthree years, including; the
approximate date and location'of the spill or Leak, and the,type,and amount ofmatenal released
There have been no leaks of spills of toxic or hazardous pollutants on the old or new access roads in the past three years
EPA Form'3510 -2F (1 -92) Page 2 of 3 Continue on Page 3

EPA ID Number (copy from Item 1 of Form 1)
Continued from Paaer2 Nc00003§6
V
EPA Form 3510 -2F (1 =92) Page 3 of 3
VII. Discharge Information
A, B. C,.& D See instructions before proceeding Complete one set of-,tables for each outfall Annotate th&outfall number in the space provided'
Table VII -A, VII -B, VII -C are included on separate sheets numbers VII -1 and VII -2
E Potential discharges not covered by analysis — is any toxic pollutant listed in table 2F -2, 2F -3, or 2F-4, a substance or a component,of a substance which you
currently use or manufacture as an intermediate or final product or byproduct?
❑✓ Yes (list all such pollutants below) ❑ No (go to Section 1X
The following elements could be present in coal and /or" oil
Antimony
Arsenio
Beryllium
Cadmiun
Chromium
Lead
Mercury
Nickel
Selenium
Silver
Thallium
Zinc
VIII Biological Toxicity Testing Data
Do you have any' knowledge or reason to believe that any biological,test for acute or chronic toxicity has been made on any of your discharges or on a receiving water in
relation to your discharge within the lastiTyears?
❑Yes, (list all ^such pollutants�below) ❑✓ No (go to SectiondX)
IX Contract Analysis Information
Were any of the analyses reported in Item VII performed by a contract laboratory or consulting firm ?'
© Yes (list the °name, address, and telephone number, of, and pollutants
❑ (go to Section X)
analyzed by, each such laboratory or firm below)
A Name
B Address
C Area Code & Phone No
D Pollutants Analyzed
Pace Analytical Services, Inc
2225 Riverside Drive
(828)254 -7176
All
Asheville, NC 28804
X. Certification
I certify underpenalty of law that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure
that qualified personnel properly gather and evaluate thetmformation submitted Based on my inquiry of the person or persons who manage the,system or those persons
duectly'responsible for gathering the information, the information submitted is, to the best of, my knowledge and belief, true, accurate, and complete I am aware that
there are significant.penalhes for submdtmg,false information, including the possibility of fine and imprisonment for,knowmg,violahons
,A Name•& Official Title (Type Or Print)
B Area Code,andiPhonefNo
Garry A Whlsnant, Plant Manager
(8281) 687 -5201
C Signature
D Date,Signed
61101(,D
V
EPA Form 3510 -2F (1 =92) Page 3 of 3

EPA ID Number (copy from Item 1 of Form 1) Form Approved OMB No 2040 -0086
00000396 I Approval expires 5 -31 -92
VII. Discharge information (Continued from page 3 of Form 2F)
Part A — You must provide the results of at least one analysis for every^pollutant inithis table Complete one table for each outfall See instructions' for additional details
Pollutant
and
CAS`Number
(if available)
Maximum Values
(include 'units)
Average Values
(include units)
Number
of
Storm
Events
Sampled
Sources of Pollutants
Grab Sample
Taken During
First 20
Minutes
Flow - Weighted
Composite
Grab Sample
Taken During
First 20
Minutes
Flow- Weighted
Composite
Oland Grease
<5 0 mg /l
N/A
J
1
Below detection level
Biological Oxygen
Demand (BOD5)
4 6 mg /l
2 0 mg /l
ri
Decaying vegetation
Chemical Oxygen
Demand (COD)
432 mg /l
64 0 mg /l
1
Decaying vegetation
Total Suspended
Solids (TSS)_
426 mg /l
.92 7 mg /1
.1
Erosion, Settled dust and debris
Total Nitrogen
4 9 mg /l
2 1 mg /l
1
Fertilizer
Total Phosphorus
0,79 mg /,l
'0 18 mg /l
1
Fertilizer
pH
Minimum 6 7
Maximum 5 7
Minimum
Maximum
11
Part B — List each pollutant that is limited in an effluent guideline which the facility is subject to or any pollutant listed in the facility's NPDES permit for its process
wastewater °(d the facility is operating under an existing NPDES permit) Complete one table fog each outfall See the instructions for additional details and
requirements
Pollutant
and
CAS Number
(d available)
Maximum Values
(include units) _
Average Values
(include units)
Number
of
Storm
Events
Sampled
Sources of Pollutants
Grab Sample
Taken During
First 20
Minutes
Flow- Weighted
Composite
Grab Sample
Taken During
First 20
Minutes
Flow- Weighted
Composite
Total Copper
68, 5 ug /l
11 8 ug /Q
1
Total Iron
38300 ug /l
7230 ug /1
1
~
Total Arsenic
46 4 ug /l
13 6 ug /l
1
Total Selenium
<10 ug /l
<10 ug /1-
1
Total Silver
<5 0 ug /l
<5 0 ug /l
1
Total Thallium
,<10 ug /l
<10 ug /l
1
TKN
4, 5 mg /l
1 9 mg /l
1
Nitrate- Nitrite
0 40 mg /l
0 15 mg /l -
1
Total Mercury
0 33 ug /l
<0 2 ug /l
1
Total Beryllium
3 4 ug /l
<0 1 ug /l
1
Total Cadmium
<1 0 ug /1
<1 0 ug /l
1
Total Chlorides
i69 4 mg /l
31 3 mg /1'
1
Total Chromium
43 4 ug /l
718 ug /l
1
Total Flouride
<0 1,0 mg /l
<0 10 m4/1
1
Total Lead
45 8 ug /l
7 3 ug /l
1
Tot Managanese
1010 ug /l
125 ug /l
1
Total Nickel
,32 2 ug /l
5 2 ug /l
1_
Total Zinc
325 ug /l
54 1 ug /l
1
TRCt
250 ug /1•
1
• Possibly analytical inteference
from naturally occurring manganese
and /or turbidity in the sample
Result from TRC,grab sample at end
sampled outfall_,SW
-3 only due
to; representative
outfall sta
tus
of SW sampling,event waa 20 -ug /1
No known source -
EPA Form 3510 -2F (1-92) Page VII -1 Continue on Reverse

Rnnfinuart frnm the Frnnt
Part C = List each pollutant shown in Table 2F -2, 2F -3, and 2F -4 that you know or have reason`to believe is present See the instructions for additional details and'
requirements Complete one table for each odtfall
Pollutant
and
CAS Number
(ifavadable)
Maximum Values
(include units)
Average Values
(include units)
Number
of
Storm
Events
Sampled
Sourcesof,Pollutants
Grab Sample
Taken During
First 20
Minutes
Flow- Weighted
Composite
Grab Sample
Taken During
First 20
Minutes
Flow-Weighted
Composite
P_a_rt,D — Provide data'for, the Fstorm,event(s) which resultedon the maximum values for the flow weighted composite - sample
1
Date,of
Storm
Event
2
Duration
of Storm. Event
(in minutes)
3
Total rainfall
during storm event
(in inches)
,4-
Number of.hours between
beginning ofistorm measured
and end of previous
measurable rain event
5
Maximum flow rate during
rain event
(gallons/mmute,or
specify units)
6
Total flow from
rain event
(gallons or specify units)
31/11/2010
210 minutes
0 39 on 3/11/2010 (during
sampling)
Precipitation over the next
four days totaled 1 81
inches
168 hours
20 6 GPM
9,548 gallons from
outfall SW -3 during
sampling event
7 Provide a descnptiomof, the, method'of flow, measurement or estimate
A container with a known volume and a stopwatch was used to measure flow from,SW,outfall pipe
`EPA Form 3510 -2F (1 -92) Page VII -2

Carolina Power & Light Company d /b /a Progress Energy Carolinas, Inc.
Asheville Steam Electric Plant
National Pollutant Discharge Elimination System Permit Number NC0000396
Attachment 1
Form 1— Item XI - Map

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Attachment 1 — Form 1 — Item XI — Map
Carolina Power & Light Company
Asheville Steam Electric Plant
Buncombe County
Page 1 of 2 June 2010

VW
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Attachment 1 — Form 1 — Item XI — Map
Carolina Power & Light Company
Asheville Steam Electric Plant
Buncombe County
Page 2 of 2 June 2010

Carolina Power & Light Company d /b /a Progress Energy Carolinas, Inc.
Asheville Steam Electric Plant
National Pollutant Discharge Elimination System Permit Number NC0000396
Attachment 2
Form 2C Item II —A
I- m- drawing for Flows, Sources of Pollution and Treatment Technologies

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Carolina Power & Light Company d /b /a Progress Energy Carolinas, 'Inc.
Asheville .Steam Electric Plant — NPDES Permit Number NC0000396
Attachment 2
Form 2C - Item II -A Flow, Sources of Pollution, and Treatment Technologies
Stream
Name
Average Flow
Comments
A
Ash Pond Discharge
3 52 MGD
Outfall 001
B
Intake to Once- through Cooling & Circulating
Water to Heat Exchangers
255 1 MGD
C
Plant Potable and Sanitary Uses
0.002 MGD
From POTW
D
Makeup to Lake from River
2 68 MGD
2009 Average
E
Low Volume Wastes
• Ash Hopper Seals
• Sandbed Filter Backwash
• Boiler Blowdown
• Truck Wash
• Water purification process waste streams
0 05 MGD
2600'Gal /event
0 006 MGD
Variable
variable
Rare Usage
Startup - Estimated
F
Circulating Water from Heat Exchangers
19 3 MGD
,Estimated
G
Ash Sluice Water
3 03 MGD
Estimated
H
Dam Seepage
0 09 MGD
Calculated
I
City Water Supply to Boiler Makeup
0 MGD
Rare Usage
J
Coal Pile Runoff
0 01 MGD
Based on Average Annual
Rainfall-of 47" and 50 % Runoff
K
Storm Water
0 07 MGD
Estimated
L
Chemical Metal Cleaning Wastes
0 - 90,000 Gallons
(0 gallons anticipated)
Normal Practice is Evaporation
M
Water From Combustion Turbine Facility
Operation (Blade wash activities)
0 - 0 02 MGD
Intermittent
N
From Lake to Intake
256 59 MGD
Estimated
O
Intake to Service Water
0 05 MGD
Estimated
Q
Fire,Protection Water
0 010,MGD
Estimated
R
Air'Preheater Cleaning
10,000 gallon-s'/event
Estimated
S
Discharge to Lake Julian
255 1 MGD
T'
Emergency Fire Protection Water
0
Used for firefighting
Outfall 002 - Calculated
U
Diesel Fire Pump to Lake,Julian
0 -128 MG /week
Estimate - pump testing
V
Flue Gas Desulfunzation Blowdown
0 086 MGD
Calculated
X
Intake to FGD system
01 08 MGD
Y
Chloride Dilution Water
0 35 MGD
z
Constructed Wetland Discharge
0 376 MGD
Outfall 005
AA
Makeup water supply
22 Million gallons/ year
Calculated
Attachment 2 - form 2C - Item IIAFlows, Sources of
Pollution, and Treatment Technologies
Carolina Power & Light Company d /b /a /Progress Energy Carolinas, Inc
Asheville Steam Electric Plant
Buncombe County June 2010 Page 2of 2

Carolina Power & Light Company d /b /a Progress Energy Carolinas, Inc.
Asheville Steam Electric Plant
National Pollutant Discharge Elimination System Permit, Number NC0000396
Attachment 3
Form 2C — Item II -13
Description of Flows, Sources of Pollution and Treatment Technologies

Carolina Power & Light Company d /b /a Progress Energy Carolinas, Inc.
Asheville Steam Electric Plant
National Pollutant Discharge Elimination System Permit Number NC0000396
Attachment 3
Form 2C - Item II -B Flow; Sources of Pollution, and Treatment Technologies
The Asheville Steam Electric Plant is located in Arden, North Carolina south of Asheville, North
Carolina The Asheville Steam Electric Plant is a coal - fired, steam cycle electric generating
plant with two generating units Two Internal Combustion (IC) Turbines are also located on the
plant site The plant has a 320 -acre cooling lake (Lake Julian) on the east side of the French
Broad River in Buncombe County, North Carolina
Chemical constituents contained in'the discharges from this plant will', in part be representative
of °the naturally occurring chemical,quality of the intake, water and will also_ have, chemical
constituents of such quality and quantity associated with similar discharges for fossil generating
facilities of this size, type and in this geographical location Either all or part of the elements
listed on the, Periodic Table, either singularly or in any combination, may from time to time be
contained in the discharge
J
Outfall 001-- bischarge from Ash Pond to French Broad River
The-Plant's ash ,pond (hereinafter;_referred to as -the 1982 ash pond), is- located east,of•the
French Broad River; south of the, plant and discharges into the French Broad River The ash
pond receives.ash sluice water, various low volume wastes, coal pile runoff, limestone pile
runoff, gypsum pile runoff, air pre- heater cleaning water, fire protection system drainage,
chemical metal cleaning wastes (potentially), storm water and other waters from the
Combustion Turbine Facility on the Plant's site Wastewater from the plant's truck wash and,
weigh stations also are directed to the plant's 1982-Ash Pond ,Accumulated water within the
boundaries of the old ash pond (hereinafter referred to as the 1964 ash pond) may also from
time to time be transferred to the 1982 pond The plantwill. also be considering installation of a
reverse osmosis system to treat water for plant process uses ,Reject water from this plant
process system will be sent,to the ash pond The pond provides treatment by sedimentation
and neutralization to the above - referenced individual waste streams Water leaves the 1982
ash pond via a standpipe with skimmer and flows by pipe and lined ditch to a secondary basin,
where it is discharged by overflow to a ditch that coveys it to the French Broad River Toe
`'1 ^-�

Carolina Power &- Light Company
Asheville Steam Electric Plant
National Pollutant Discharge Elimination System Permit Number NC0000396
drains from both the 1982 pond and the 1964 pond drain to the French Broad River Detailed
descriptions of the individual Waste streams are below
Ash Sluice Water
Fly ash and bottom ash from both units are hydraulically conveyed by an ash sluice pipeline to
the ash pond As needed, alum is added to the ash sluice influent to aid settling A Selective
Catalytic Reduction system (SCR) is operated on both Unit 1 and Unit 2 for NOx emissions
control Urea is injected to reduce NOx emissions A byproduct of this process is an "ammonia
slip" which will be carried to the 1982 ash pond via ash sluice water As necessary, a system to
mitigate SO3 emissions may also infect additional ammonia into't'he combustion, process This
mitigation system has not been needed to date but, may become necessary as fuel sources
change. Various boiler sediments and ash accumulations collected during maintenance
activities may also be transported to the 1982 ash pond The ash pond discharge flows into
the secondary settling pond where it combines with the FGD treated wastewater prior'to
discharging to the French Broad River. Progress Energy plans to relocate this secondary
settling pond and discharge point during the term of this permit to facilitate modifications
designed to enhance the 1964 ash pond dam's safety factor
Coal Pile Runoff
Storm water runoff from the coal pile is collected in drainage ditches that surround the coal pile
The drainage ditches are routed to the 1982 ash pond for1reatment During maintenance
activities, sludges removed from catch basins, sumps,, etc may be, transported -to either the
1982 ash pond or°the 1964 ash pond for disposal_
Limestone and Gypsum Piles Runoff
Storm water runoff from the limestone and gypsum piles is collected in drainage ditches which
are routed to the 1982 ash pond for treatment During maintenance activities, sludges removed
from catch basins, sumps, etc. may be transported to the 1964 ash pond and /or the 1982 ash
pond for disposal
Storm Water
Storm water runoff from the plant area, parking lots, combustion turbine area, oil storage and
handling facility and the plant's substations is routed to the ash ponds for treatment During
2

Carolina Power,& Light Company
Asheville Steam Electric Plant
National Pollutant Discharge Elimination System Permit Number NC0000396
maintenance activities, sludges removed from catch basins, sumps, etc may be transported to
the 1964 ash pond and /or the 1.982 ash pond for disposal
Low Volume Wastes
Boiler water make up is withdrawn from Lake Julian and purified'utilhzing vendor supplied
equipment Boiler water is treated with ammonia, hydrazine, and sodium hydroxide Boiler
blowdown and drainage is sent to the ash pond and may contain small quantities of the
chemicals. A new Reverse Osmosis system or alum coagulation /filtration service will be used
in conjunction with the vendor supplied equipment -to provide water for various plant processes
The reject stream from the Reverse osmosis unit will be sent to the 1982 ash pond Some
molybdate waste'from the closed cooling water system is created through valve leakage and
t
maintenance activities -and is discharged to the 1982 ash pond A furnace ash hopper seal is
maintained by using plant service water A standard operation water level is ,maintained' in' a
seal trough for the ash hopper seal Overflow from this trough is discharged to the. 1982 ash -
pond. A sodium hydroxide solution is fed into this flow stream as necessary for ash pond pH
adjustment Sulfuric acid is fed to the ash sluice water as necessary for 1982 ash pond pH
adjustment Coal dust suppression is achieved by spraying a propnetary chemical on coal at
different stages ,of coal use Small amounts of excess dust suppression chemical have the
potential to, be discharged to the, 1,982 ash pond via plant drains or coal pile runoff Small
amounts of urea waste from bulk urea unloading operations are discharged to,the 19,82 ash
pond All plant area floor drains are routed to the 1982 ash pond and include equipment
drainage and wash down along with rainfall runoff During maintenance activities sludges
removed from catch basins, sumps, etc may be transported to the 1982 ash pond and /or the
1964 ash pond for disposal
In many cases,, added chemicals are consumed or chemically altered during the plant
processes Only trace amounts might'be recoverable in water entering the 1982 ash pond
Detectable levels of these chemicals would not be expected to occur in ash pond discharges
Flue Gas Desulfunzation Blowdown (Low Volume Waste)
The Flue Gas Desulfunzation (FGD) system directs flue gas into an absorber where a limestone
(calcium carbonate) slurry is sprayed Sulfur dioxide in the flue gas reacts with the limestone to
produce calcium sulfate (gypsum) This system reclaims any unreacted limestone slurry to be
3

Carolina Power & Light Company
Asheville Steam Electric Plant
National Pollutant Discharge Elimination System Permit Number NG0000396
reused in the absorber A small blowdown stream is used to maintain the chloride
concentration in the reaction tank The blowdown stream is passed through a clarifier to
remove solids and the chloride concentration in the waste,stream is diluted using water from
Lake Julian Chemicals are used to adjust pH and to aid solids removal in the clarifier A
constructed wetland is used to remove metals, mercury and selenium specifically, and the,
treated wastewater is discharged into the secondary settling pond
Air Preheater Cleaning (Low Volume Waste)
The air preheater will be water`washed once per year or more frequently as needed The
wastewater from this activity will be discharged to the 1982 ash pond
Chemical Metal Cleaning Wastes
The boilers are chemically cleaned every five -to -eight years using Tetraammonia ethylene
diamine tetraaccetic acid (EDTA)'solution This cleaning solution and its rinses are stored on
site for disposal by evaporation in an operating unit's furnace Typical cleanings would result in
awaste of approximately 80,000 gallons Should evaporation not be used, the wastewater can
be treated by neutralization and precipitation prior to being conveyed to the 1964 ash pond, or
to the 1982 ash pond, or other means- of disposal `Cleaning of other heat exchanger surfaces
may produce 5,000- 10,000 gallons of wastewater every three -to -five years.
Other Wastes
Operation of the combustion turbine (CT) generation facility may produce turbine blade wash
water, inlet filter cooling water, various' condensate waters, and water,from equipment ,and tank
drains' These wastewaters will be collected in the storm water collection system of the CT site
and routed to the 1982 ash pond During maintenance activities, sludges removed from catch
basins, sumps, etc may be transported to the 1964 ash pond and /or the 1982 ash pond for
disposal
Plant Potable and Sanitary'System
The supply of water for plant potable and sanitary use is obtained from the Asheville /Buncombe
Water Authority system and waste from this system is discharged to the Metropolitan Sewage
District System
4

Carolina Power & Light Company
Asheville Steam Electric Plant
National Pollutant Discharge Elimination System Permit Number NC0000396
Herbicide and Pesticide Usage in the Treatment System,Ponds
Herbicides may be used as needed to control nuisance aquatic vegetation These herbicides
are applied by'licensed applicators, or persons under the, immediate supervision of a, licensed
applicator, in accordance with the manufacturer's instructions Pesticides may be used as
needed to perform biological assessments These Pesticides are applied by licensed
applicators, or persons under the immediate supervision of a licensed applicator, in accordance
with the manufacturer's instructions
230 KV Substation Storm Water
Storm water runoff from the substation located adjacent to the plant is conveyed to the 1964
ash pond This water may be transferred to the 1982 ash pond as needed to maintain
appropriate water levels in the 1,964 ash pond
Outfall 002 - Discharge to,Lake Julian
Once - Through Cooling Water
This flow provides condenser cooling water for the generating units 1 and 2 Maximum
condenser flows for units 1 and 2• are 150 MGD and 156 MGD, respectively
Once - through cooling water{is used to supply non - contact cooling water for the component
closed cooling water system The component closed cooling water system flows combine with
unit 1 and 2 condenser flows prior to discharge to Lake Julian Maximum component closed
cooling water system flows for unit 1 and 2 are 9 1 MGD and 10 2 MGD, respectively
Discharge flow to Lake Julian is calculated at the intake to units 1 and 2 condensers and to the
circulating water to'the heat exchanger, The discharge, of water from the heat exchangers is
routed to an ash sump The majority of thiswater,is further routed to the discharge of units 1
and 2 condensers Less than one percent of the flow to the ash sump is used to supply ash
sluice water, preheater cleaning water, and fire protection water
Control of biological fouling on heat- exchanger,surfaces is accomplished by addition of sodium
hypochlorite as required, which is usually less that 2 hours per day per unit, with a net total
residual chlorine,of less,than 0 2 ppm discharged during that period Cooling is accomplished
by evaporation from the surface of Lake Julian and mixing and convection with lake waters
Make up for Lake Julian is from the French Broad River, natural runoff and creek flows Water
5

Carolina Power & Light Company
Asheville Steam Electric Plant
National Pollutant Discharge Elimination System Permit Number NC0000396
is pumped from the French, Broad River during dry periods to supplement the flow Although
discharge from Lake Julian to the river is extremely rare, any occurrence would be during
periods of heavy rainfall.
Herbicide and Pesticide Usage in the'T'reatment System Ponds
Herbicides may be used as needed to control nuisance aquatic vegetation These herbicides
are applied by licensed applicators, or persons under the immediate supervision of a licensed
applicator, in accordance with the manufacturer's instructions Pesticides may be used as
needed to perform ,biological assessments- These Pesticides are applied by licensed
applicators, ,or persons under the'immediate supervision of a licensed applicator, in accordance
with the manufacturer's instructions
N

Carolina Power & Light Company d /b /a Progress Energy Carolinas, Inc.
Asheville Steam Electric Plant
National Pollutant Discharge Elimination System Permit Number NC0000396
Attachment 4
Form 2C — Item'VI
Potential Discharges Not Covered by Analysis

Carolina Power & Light Company d %b /a Progress Energy Carolinas, Inc.
Asheville Steam Electric Plant
National Pollutant Discharge Elimination System Permit Number NC0000396
Attachment 4
Form 2C -'Item VI - Potential Discharges Not Covered By Analysis
Chemical
Estimated Quantity
Frequency
Purpose
Used er ear
Hydrazine (35 %)
1840 lb /yr
Continuous
Oxygen scavenger in
_
boiler
Ammonium hydroxide.
2730 1-b./yr.
Continuous
pH control of boiler
water _
Sodium hydroxide
141,139 lb /yr
Continuous
pH control of ash pond
25
Sodium hydroxide
30 gallons
As required
pH control of boiler
50%
_ _
water
Sodium hypochlorite
91,072 lb /yr
As required
Control of biological
(1a5 %)
fouling on, heat
exchangers
Sodium molybdate
100 pounds
As required
Corrosion control in
closed cooling water
system
Tetraammonia EDTA
35,000 pounds
Every 5 to 8 years
Boiler cleaning
(38,%
Urea (50 %)
7365 tons /yr
Continuous during
NOx control
high ozone months
Sulfuric acid (93 %)
Variable
As needed
pH control of ash pond
BetzDearborn Dustreat
11,400 pounds -
As,required
Coal dust suppression -
DC9136
estimated
proprietary chemical
Fyrewash (detergent)
200 gallons
As needed
Combustion turbine
blade washing
Detergents /cleaning
Variable
As needed
Housekeeping
agents
_
Limestone ,(Calcium
21,944 tons /yr
Continuous
Flue Gas
carbonate
Desulfurization
Polymer (high weight,
3255 lb /yr
Continuous
Solids removal — FGD
anionic, emulsion-type)
wastewater
Coagulant (Ferric
.3060 lb /yr
Continuous
Solids removal — FGD
chloride — 41 % )
wastewater
Sodium Hydroxide
17600 lb./yr.
Continuous
pH ,adjustment — FGD
25%
wastewater
Hydrochlonc.Acid
400 gallons -
Continuous
pH adjustment- FGD
30%
estimated
wastewater
Magnesium Hydroxide
Variable
Continuous
Applied to coal for slag
control
Aluminum Sulfate 25 %-
variable
_
As required
Water treatment
50% , ,Alum
processes, TSS control

Carolina Power & Light Company
Asheville Steam Electric Plant
National Pollutant Discharge Elimination System Permit Number, NC0000396
Sumachlor 50
As needed
Coagulant for water
treatment filter
'MIT7602 (Organic
As needed
R �O Anti - scalant
Polymer)
_ _
50% Caustic
Variable for R O pH
As needed for pH
R O pH adjustment
adjustment
adjustment
and
1'000 gallons for
Periodic Typically 4 /yr
R O cleaning per
for R O cleaning
R O cleaning
event
Hydroclonc Acid
1000 gallons /event
Periodic Typically 4 /yr
R O membrane
cleaning
Citric adid
1000 gallons /event
Periodic-Typically 4 /yr
R O membrane
cleaning
Trilon B (EDTA)
1000 gallons /event
Periodic Typically 4 /yr
R -O cleaning
ROClean P911
1000 gallons /event
Periodic Typically 4 /yr
R O cleaning
Bisulfite (sodium
As needed
R O layup
bisulfate
600 gallo ns /event
Alkyl alcohol
Variable
As needed
Freeze conditioning
agent
Propylene Glycol
Variable
As needed
Freeze conditioning
agent
Calcium Chloride
Variable
As needed
Freeze conditioning
agent
Diethylene glycol
Variable
As needed
Freeze conditioning
,agent
Glycerin
variable
As needed
Freeze conditioning
agent
Fertilizer
Variable
As needed-
Wetland treatment cell -
lant mana ement
Pelletized Lime
Variable
As needed
Wetland treatment cell
plant management
Rev April 2010

Mar, 16. 2010 1: 48PM
,USGS
science 1(ar a c�iang /n� wror►d
No, 2668 N. 1
❑ Not applicable '% S keW-�
VIi4
Fax to. &0)
Date: /�'�o -r44 Il ;2"0 /0
Subject: /
Comments:
AA
.. s
A Oukk note firom:
J. Curtis Weever, P.E.
Hydrologist (Civil Rng)
[e-mail]
http: / /nc.water.usge.gov/
U.S. Department of the Interior
U.S. Geological Survey
391 8u nset ° Ridge ° Road
Raleigh, NC 27607
(919) 571 -4043
(919) 5714041 FAX

Mar. 16. 2010 1: 48PM No. 2668
N. 2
Request No: l/ Site No: Stromflow Conditions: LOGIN
n
GINSIATED
'A
REQUEST ?OR WATER°SMLY STATIS=CS
Station No. -Type Station 20 Data Index ,
Station Name , YM4,4;•+ 13f60
Location A4 IVC /y6 wtA - o-r Sk,,lw.,J - - --
Lat. 3S °.Z` ", Long 2 ® 3V 2 V", Basis. Xre-v e l�ro l� %vim
S ky 1-*4
Qaad No. E, Coaaty Ne JePso,^ a 91 State _ District V?
HQC G2 G d I d C p• . N�CD d y- U," U., D =aivage Aran
.
Average Discharge.
&atimated, using, . �? cfsm. w+ i."7 4!_G� cis. (�)
Ki namom Di.schaxp.,
"
Min. day ? Q -year rscu:rreaca interval of sir;. cfs•
Dirt. -& day s -year recamnce' intarval- q5I �f sm. t3lets.
" VR z
Min. 'I dap � -yank recu =Ce interva].� �. y��fS � (A�
l�
�i a.�? dsy "�• °year' recurrence' interval, �fsm. '�3 legs. (A)
,PceMd /7rCM-j liver av Ale-leAc` ai T
s�� a�
Sfr
River at D.A. sq mi.. Type_..-
Creek near
Rive K mi• Type
Creek• sear
loiter
Transmitted by comp. to S"90-- Computed by - C W date, �.' 10 • D y
...,». Checked Jr- W dazte� 4,
1�1C D � Q Ravi.emed by .� date Z- 2r✓� -G�i
.
Remarb�s a ; . • ., ,
0.3 OA
� 0-7:
�7-7 (. V -04)
(a) Estimate is basal oat records ected at or (near the site.
(b) Estimate is based entirely an runoff observed at nearby streams.
(a) Estimata based an pmeadnres ,Sivea j*' OPen-FL14 Repoi't 90 -399 '1'LovF7ow
Charaeteri atics of Streams in 'North Carolina's'
(d) Estimte based on procedureo given ira Open -File Report. 90 -399 and in =Mjuetion vith
records collected at or sea the site.
n
r
'A

Ma r, 1,6. 2,010 1: 49,PM No. 2668 N, 3
United States Department of the Interior .
ID U.S., GEOLOGICALSURVEY
391GSunset Ridge Road
Raleigh, North Carolina 27607
February 23, 2004
Ms. Susan A. Wilson, Environmgntal Engineer
N.C. Division of Water Quality, NFDES Unit
1617 Mail Service Center
Raleigh, North Carolina 27699 -1617
Dear Ms. Wilson:
In response to your request for low -flow data, the U.S. Geological Survey (USGS) does not
have site - specific, low -flow discharge data for French Broad River at NC'280 near Skyland,
NC (station id 03447840, drainage area 660 m12): The low -flow characteristics that are pro-
vided on the attached sheet have been computed by correlating the runoff characteristics of a
nearby continuous - record gaging station upstream of the request site., Please note that the.flow,
estimates do not- specifically account.for the presence of any diversions. or regulation, present
or future, which may occur upstream of the request site. Because afsimilar request for the
1Q10 low -flow discharge was received about.the3 same time from Progress Energy, this, low»
flow statistic is included on the attached sheet.
Low -flow characteristics were analyzed using streamflow records from a continuous - record
gaging station on the'French Broad River near Fletcher, operated since July 2001 and located
upstream at Secondary'Road 1419 (station id 03447840, drainage area 640 m12). Because of
the short period of record at the Pletcher gage, low -flow analyses at this gage were completed
by correlation analyses using two' other gaging stations having Wong periods, oftecord (station
id's 03443000 and 03451500). 'Shen, using the difference in drainage areas between the
request site,and,the K, etcher gage, low -flow characteristics at the- request location were deter-
mined using the low -flow yields' (expressed,as flow per square mile drainage, area) at the
Pletcher gage. The estimated 7Q10 discharge is 306 W/s and is lower than the estimate pro-
vided to `you in an e-mail dated January 14, 2004.
Analyses of `low -flow characteristics at all three gaging stations indicates 'a decreasing, trend
in low -flow yields between the gages -at Blantyre and Asheville. Between these two locations,
thexiver is affected by some diversions occurring4n tributaries along with regulation by small
upstream reservoirs and a power plant located about 8 miles upstream of,Blantym The anal-
yses indicate that most of the decrease in low -flow yields occurs between the Blantyre and
Fletcher gages.
The table shown on the accompanying page summarizes the low-flow characteristics at the
gaging stations used in the analyses. As previously discussed in January, the French,Broad
River downstream from3lantyft is affected by some'regulation and diversions. The low -flow
discharge values are baked on stream,flow records available through September 2003, and the
associated low-flow yields for each value is listed to provide insight in the changing low -flow
yields between the gages,
(919) 571 -M - FAX [phone]

Ma r, 16. 2010 1; 4'9 PM No. 2 6U N. 4
Ms. Susan A. Wilson
Page 2
February 10, 2004
These data are preliinivary and' subject to revision pending approval for publication by the
Director of the U.S. Geological Survey, and are made available, through our cooperative ,pro-
gram' of water�resources investigations with `the forth Carolina Department of Environment
and Natural Resources.
if you have any questions regarding this information, please, contact, us at (919) 571 -4000.
Sincerely,
. Curtis Weaver
Hydrologist
Enclosure
r:
Lovwflaw charactsrlstics
�
(Bela)
swon name
m
�
®°
r
a
ki,
,
03443400 Fnrach Broad River at Bla Vts
(Secondary Road 1503, Henderson County)
Z96
3.3
197
(0.666)
375
(1:267)
232
(0.851)
316
(1.068)
43447687` French Broad River aear Fletcher
(Secondary Road,1419, Buncombe Coanty)
640
2:7 '
297
(0.463)
613
(0.957)
397
(0.620)
515
(0 .'804)
M4415001'rewh Broad River at AsiwyU1e
(Secondary'Road 1348, Buncombe County)
945
12
425
(0.450)
833
(0.882)
563
(0.5M
720
(0.762)
These data are preliinivary and' subject to revision pending approval for publication by the
Director of the U.S. Geological Survey, and are made available, through our cooperative ,pro-
gram' of water�resources investigations with `the forth Carolina Department of Environment
and Natural Resources.
if you have any questions regarding this information, please, contact, us at (919) 571 -4000.
Sincerely,
. Curtis Weaver
Hydrologist
Enclosure

Mar, 16. 2010 1:49NM No. 2666 N. 5
REQUEST'NO -,,- 91623 SITE °NO :,_ �01 DATE:. 02/10/2004_
SOURCE: DPNR fDWO) ACTION: Now
STATION NUMBER: 09447,84_ STATION TYPE: Un agId (20)
STATION NAME: _ Frepch Broad giverat NC 280 near Wland. NC
LOCA'T'ION: At NC' ,Lon ,-Sh 'd e " 2 miles w - _ 'S- lan
LATITUDE: 35028'53" LONGrME: 810
QUANDRANGLE:NAME AND °NUMBER: Sialand ELM
COUNTY CODE: „ Henderson _10891 STATE CODE: NC r371—DISTRICT CODE: _ _ NC
33711
wmROLOGIC UNIT CODE: 06010105 _ ENR BASIN CODE: - -03-02
DRAINAGE AREA: 66L®12
Flow statistics as follows:
AVERAGE FLOW: Estimated using
2.70,
ft3/S/mi2
1,780
fe/$
We note
f A
ANNUAL 7Q10:M[Egl l%IUM FLOW:
0,4634
ft3 /s/mi"
306
/$
see note
r A�
ANNUAL 30Q2 MINIMUM FLOW:
0.9570
fp/shnIa
631
ft%
seemote
U
WINTER 7Q10 MITTIMUM FLOW:
0,6198
W /slmZ
409
WIS
see note
f
ANNUAL 7Q2 MINIMUM FLOW:
0.8041
fe/shop
531
fe /$
see note
U
,OT HER FLOWN,(specifY): �10I0_
0,4258
ft3 /.s/mi2
282
�!s
see note
�
NOTES:
[A] Estimate is based on records collected at or near the' request site.
[B] Estimate is based entirely on runoff characterWcs observed at nearby;streams. r
[C] Estimate,based on procedures given in USGS Water Supply Paper ?403 "Low -flow Characteristles
of Streams in North Carollbi'o (Giese and Mason, 1993).
[1D] Estimate based on procedux" given in USGS Water Supply Paper 2403 and in conjunction with
streamflow records collected at or near the request site.
,[E] See remarks.
These data are,considered provisional and subject to revision,pending approval by the Director, USGS.
REMARKS:
• Low -flow estimates based on low -flow characteristios upstream gaging station 03447687 (French Broad
River near Fletcher),during 7uly'2001 through September 2003, 1Q10 flow requested by Progress Energy-
,,,Requested by Ms. Susan Wilson, N.C. Division of Water Quality ll Ms. Louise,England, Progress Energy
ENTERED BY:_ TCW FEE CAGED: $ 150 —

Ma r. 16. 2010 1: OPM No, 2668 P. 6
United 'States Department of the Interior
U.S; GEOLoGICAL SURVEY
396 Sunset Ridge.Roid
Raleigh, North Carolina 27607
February 23, 2004
Ms, Louise,England, Senior Environmental Specialist
Progress Energy - IMC
3932 New Hill - Hoileman`Road
New Hill, North Carolina 27562
Dear Ms. England:
In,response to your,request for low -flow data, the U.S. Geological Survey (USGS) does not have site - specific,
low -flow diicharge'data,for French Broad River at NC 280 near Slcylaud,,NC (station id 03447840, drainage
area 660 mi ), The low -flow characteristics,that M- Provided,on the attached sheet,have been computed by
correlating the runoff characteristics of a nearby continuous- record gaging�station,upstream'of the request'sits..
Please note that the flow estimates do not specifically account for thepresence of any diversions or regulation,
present or future, which may occur upstream of the request site. Because your request was received about the
same time,as a similar request -from the N.C. Division of Water Quality (DWQ), the low- flow'statistics esti-
mated for the DWQ are included on the attached sheet.
Low -flow characteristics were analyzed using streamflow records from a continuous- record gaging station on
the French Broad River near Fletcher,, operated since July 2001 and located upstra= at Secondary Road 1419
(station id 03447840,,drainage area 640 M12)• Because °of the short period of record at the Fletcher gage,,low-
flow,anal'yses at,this gage were completed by correlationanalysesusing -two ofher gaging stations having long
periods of,record (station4d's 03443000 and 03451500). Then, using the difference in drainage areas between
the request site and the Fletcher gage, low -flow characteristics at the request location were determined using
the low -flow yields (expressed as flow per square mule drainage area) at the Fletcher gage, The estimated
1Q10 discharge is 282 fP/s-and is lower than the,estimated 7Q10 discharge. of306 f13 /s.
Analyses of low- flowcharacteristics at all three gaging stations indicates,% decreasing trend inlow -flow yields
between the gages at Blantyre and Asheville. Between these two locations, the river is affected by some diver-
aions occurring in tributaries along with,regulation by small upstream reservoirs and a power plant located
about 8'miles upstream of Blantyre. The analyses,indicate that most of the decrease in low -flow yields occurs
between the Blantyre and Fletcher gages.
A charge for accessing and processing information has boon assessed to`partially offset these•costs. Your
requested data and an invoice covering,processing costs for these data are enclosed. Please forward the orig-
inal bill with your check to the U.S. Geological Survey, 12201 Sunrise Valley Drive, MS 271-, Reston, Virginia
20192.
These data are preliminary and subject to revision pending approval for publication by the Director of the U•S-
Geological Survey,,and are made available through our cooperative,program of water - resources investigations
with the North Carolina,Department of Environmentland Natural Resources.
If you have any questions regarding this information, please contact us at (919) 571 -4000•
Enclosures
Sincere%ly %, ,
h Curtis Weaver
drologist
(919),571.4000• FAX [phone]

Ma r. l b. 1U I U I :M-FM No. 1668 N.
�ii1�"'S"AItY OF LAM OW ESTIMAM IN RESPONSE TD RE UEST
REQUEST NO: , 1� SITE NO: 01 _ DATE: - 2/10/200
SOURCE..- - DEN . W'O) _ACTION: Now -
STA'nON NUMBER: 0344784 STATION TYPE: Ungaged (20)
STATION NAME: French Broad River at NC 280 near Skyland. NC
LOCATION: -, At NC 8�g,Sh alb a brid je_). and 2 miles west of SIDL14nd-
L-A7TI`UDE--' 35019'53" LONGITUYDE: Or 3128" _
QUANDRANGLE NAME AND NUMBER: Sky d M-8 -Mj
COUNTY CODE: 'Henderson T0891 ,STA'T'E CODE: NC f37) DISTRICT CODE: NC
( 7„ 1
HYDROLOGIC UNIT CODE: _ 06010105
ENR BASIN CODE: 04 -0302 _
DRAINAGE AREA: 660 —mil
Flow statistics 'as follows:
AVERAGE FLOWN Estimated using
2.70
fp/s,/omiz 1,780
ft31s
see note
--A
ANNUAL 7Q10 MINIMUM FLOW:
0.4634
ft3 /s/mi2 306
Vis
seezote
Lam,
ANNUAL 30Q2 MINIMUM FLOW:
0.9570
fe/shni2 631
ft 3/9
see note
LAJ
WINTER 7Q10 MINIMUM.FLOW:
0.6198
f0/s/m12 409
0/$
see note
I A
ANNUAL 7Q2 MINIMUM FLOW:
0.8041
ft/ 2' 531
1ft3 /s
see,note
F A
OTHER FLOW (specify): ^101
0,4258
ft%/W2 `282
fe /s
see note
r A
Q • :+
[A) Estimate is based,on records collected „at or`near the request site.
[B] Estimate is based entirely on runoff characteristics observed at nearby streams.
[C) Estimate based on procedures given in USGS Water,Supply Paper 2403 "Low -flow Characteristics
of,Streams,in North Carolina” (Giese and.Masons 190.
[D]'Estlmate based on procedures given in USGS Water Supply Paper 2403 and in,conjunctiou with
streamflow records collected at or near the request site.
[E] See remarks.
These data are considered provisional and subject to revision pending approval by, tilt Director, USGS.
REMARKS;
Low -flow estimates based on low -flow characteristics upstream gaging station 03447687 (Freach Broad
River near Fletcher) during July 2001 through september 2003. 1Q10 flow requested by Progress Energy.
Requested by Ms. Susan Wilson, KC. Division of Water, Quality # Ms. Louise England, Progress Energy
ENTERED BY: I'LW FEE CHARGED: $ 150

Carolina Power & Light Company d /b /a Progress Energy,Carolinas, Inc.
Asheville Steam Electric Plant
National Pollutant Discharge Elimination System Permit Number NC0000396
Attachment 9
Proposed conceptual relocation route of outfall 001

Proposed relocation of outfal 001
In order to facilitate enhancements to the 1964 ash ,pond -dam,, it will be necessary to relocate'the
existing settling basin and discharge outfall 001. The Asheville Steam Electric Plant is located in close
proximity to the French Broad River but has limited access to the river,because of Interstate 26. In order
to relocate, outfall 001, it will be necessary to go north approximately 3000 feet to a point where existing
access under the Interstate is located. This proposed discharge location is on property owned by
Progress Energy The entire span of property between the existing outfall and the proposed outfall is
also owned by Progress Energy.
In addition to the current °flows from the 1982 ash pond, a "new" flow will be added to the relocated
outfall. This flow will consists of stormwater and ground water, seepage that currently'flows into the
1964 ash pond. H tsi cas flow has been allowed to evaporate and /or infiltrate. The
enhancements to the 1964 pond require that this water level be managed and maintained below a
certain elevation. 'Therefore, it may °be necessary to periodically pump water from the 1964 ash pond to
the combined, relocated settling basin and outfall 001 A sample of the water from the 1964 ash pond
was taken as part of the preparation of this application Results from that sampling analysis are
attached.

a)
P
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13)
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(3)
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13)
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(3)
(A
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i

(� IaceAnalytkal
wwwpacelabxcwn
April 23, 2010
Ms Crystal Diedrich
Progress Energy
200 CP &L Drive
Arden, NC 28704
RE Project DUCK POND 04/12
Pace Project No 9267173
Dear Ms Diedrich
Pace Analytical Services, Inc
2225 Riverside'Dr
Asheville, NC 28804
(828)254 -7176
Pace Analytical Services, Inc
9800'KinceyAve Suite 100
Huntersville, NC 28078
Enclosed are the analytical results for'sample(s) received by the laboratory on April 12, 2010 The
results relate only to the samples included in this report Results reported herein conform to the
most current NELAC standards, where applicable, unless otherwise, narrated in the body of the
report
Inorganic Wet Chemistry and Metals analyses were performed at our Pace Asheville laboratory and
Organic testing was performed at�our Pace Huntersville laboratory unless otherwise footnoted All
Microbiological analyses were performed at the laboratory where the samples were received
If you have any questions concerning this report, please feel free to contact me
Sincerely;
C: X 0. 7
Lorn Patton
torn' patton@pacelabs com
Project Manager
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc
(704)875 =9092
Page 1 of 14

aceAnaljftal
wwwpaoefab&com
Project DUCK POND 04/12
,Pace Project No 9267173
Asheville Certification IDs
2225 Riverside Dr Asheville, NC 28804
Connecticut Certification # PH -0106
Virginia Certification # 00072
Tennessee Certification # 2980
South Carolina Certification # 99030001
South.Carohna Bioassay Certification #,99030002
Pennsylvania Certification #,68-03578
North,Carolina Wastewater Certification# 40
Pace Analytical Services, Inc
2225 Riverside Dr
Asheville, NC 28804
(828)254 -7176
CERTIFICATIONS
North Carolina Drinking Water Certification # 37712
North Carolina Bioassay Certification # 9
New Jersey Certification # NC011
Massachusetts Certification # M -NC030
LOWSIana/LELAP Certification # 03095
Florida /NELAP Certification # E87648
West Virginia Certification# 356
REPORT OF LABORATORY ANALYSIS
This,report shall not be reproduced, except in full,
without the written consent of'Pace Analytical Services, Inc
//1C1CGpy�
Pace Analytical Services, Inc
9800 Kincey Ave Suite 100
Huntersville, NC 28078
(704)875 -9092
Page 2 of 14

aceAnalytical
wwwpaoelaftcarn
Project DUCK POND 04/12
Pace Project No 9267173
Pace Analytical Services, Inc
2225 Riverside Dr
Asheville, NC 28804
(828)254 -7176
SAMPLE ANALYTE COUNT
Pace Analytical Services, Inc,
9800 Kincey Ave Suite 100
Huntersvtlle, NV28078
(704)875 -9092
REPORT OF LABORATORY ANALYSIS
This report shall not beireproduced, except in full,
without the written consent of Pace Analytical Services, Inc
Page 3,of 14
Analytes
Lab ID Sample ID Method
Analysts
Reported
Laboratory
9267173001 DUCK POND EPA 200 7
JMW
11
PASI -A
EPA 245 1
SHB
1
PASI7A
SM 5210B
JDA
1
PAST -A
40CFWPART 503
SAJ
1
PAST -A
EPA 351 2
EWS
1
PASI -A
EPA 353 2
JDA
1
PASI -A
EPA 365 1
JDA
1
PAST -A
SW 5220D
LEP
1
PASI -A
REPORT OF LABORATORY ANALYSIS
This report shall not beireproduced, except in full,
without the written consent of Pace Analytical Services, Inc
Page 3,of 14

aceAnalytical
wwwpeoelabstwm
Project DUCK POND,04 /12
Pace Project No' 9267173
Pace Analytical Services, Inc
2225 Riverside Dr
Asheville, NC 28804
(828)254 -7176
ANALYTICAL RESULTS
Pace Analytical Services, Inc
9800 KinceyAve , Suite 100
Huntersville, NC 28078
(704)875 -9092
Sample- DUCKPOND
Lab,ID: 9267173001 Collected
04/121100906
Received 04/12/101240 Matrix Water
Parameters
Results Units Report Limit
DF
Prepa"red
Analyzed
CAS No
Qual
200.7 MET ICP
Analytical Method, EPA 200 7 Preparation Method EPA 200 7
Antimony
ND ug /L
100
2
04/15/10 17 00
04/19/10 12 28
7440 -36 -0
D3
Arsenic
ND ug /L
100
2
04/15/10 17 00
04/19%1612 28
7440 -38`2
D3
Beryllium
ND ,ug /L
20
2
04/15/10 17 00
04119/10 12 28
7440 -41 -7
D3
Cadmium,
ND ug /L
20
2
04/15/10 177 00
04/19/10 12 28
7440 =43 -9
D3
Chromium
ND ug /L
100
2
04/15/101 - 7 00
04/19/10 12 28
7440 -47 -3
D3
Lead
ND ug /L
100
2
04/15/10 1,, 00
04/19/10 12 28
7439 -92 -1
D3
Nickel
29.6 ug /L
100
2
04/15/10 17 00
04/19/10 12 28
7440 -02 -0
D3
Selenium
21.4 ug /L
200
2
04/15/10 17 00
04/19/10 12 28
7782 -49 -2
D3
Silver
ND ug /L
100
2
04/15/10 17 00
04/19/10 12 28
7440 -22 -4
D3
Thallium
ND ug /L
200
2
04/15/10 17 00
04/19/10 12 28
7440 -28 -0
D3
Zinc
37.6 ug /L
20,0
2
04/15/10 17 00
04/19/10 12 -28
7440 -66 -6
D3
245.1 Mercury
Analytical Method EPA2451 Preparation Method EPA 245 1
Mercury
ND ug /L
020
1
04/16/10 10 55,
04/16/10 18 01
7439 -97 -6
5210B,BOD, 5 day
Analytical Method SM 5210B
BOD, 5 day
ND mg /L
2'0
1
04/13/1017 30
04/18/,10 14 50
B2
Total Nitrogen Calculation
Analytical Method 40CFR PART 503
Nitrogen
0 73 mg /L
060
1
04/21/10'15 25
7727 -37 -9
351.2 Total Kjeldahl Nitrogen
Analytical Method EPA 351 2
Nitrogen, Kjeldahl, Total
0.66 mg /L
050
1
04/22/10 13 30
7727 -37 -9
353 2 Nitrogen, NO2 /NO3 pros.
Analytical Method EPA-353 2
Nitrogen,, NO2, plus NO3'
ND mg /L
010
1
04/19/10 11 28
365.1 Phosphorus, Total
Analytical Method EPA 365 1
Phosphorus
ND mg /L
010
1
04/18/1011 33
7723 -14 -0
5220D COD
Analytical Method SM 5220D
Chemical Oxygen Demand
ND mg /L
25`0
1
04/14/10 16 46
Date 04/23/2010 03 48 PM
REPORT OF LABORATORY ANALYSIS
This report shalrnot be reproduced,, except in full,
without the written consent of Pace Analytical Services, Inc
,a,,„ •ccuyo
�L ,_
Page 4 of 14

® Pace Analytical Services, Inc
aceAnalXical 2225 Riverside Dr
w,N,pa��� Asheville, NC 28804
(828)254 -7176
QUALITY CONTROL DATA
Project DUCK POND,04 /12
429216
Units
Spike
Conc
LCS
Result
Pace Project No 9267173
% Rec
Limits Qualifiers
Antimony
ug /L
500
QC Batch MPRP /6150
95
Analysis Method
EPA'2007
'QC Batch Method EPA 200 7
500
Analysis Description
200 T MET
Associated Lab Samples 9267173001
Beryllium
ug /L
500
METHOD BLANK 429215
99
Matrix Water
Cadmium
ug /L
Associated Lab Samples 9267173001
479
96
85 -115
Chromium
ug /L
Blank Reporting
483
Parameter
Units
Result Limit
ug /L
Analyzed Qualifiers
,Antimony
ug /L
ND
50
04/16/10 17 25'
Arsenic
ug /L
ND
50
04/16/1017 25
Beryllium
ug /L
ND
1 0
04/16/10 17 25
Cadmium
ug /L
ND
1 0
04/16/10 17 25
Chromium
ug /L
ND
56
04116/10 17 25
Lead
ug /L
ND
5 0
04/16/10 17 25
Nickel
ug /L
ND
5 0
04/16/10 17 25
Selenium
ug /L
ND
100
04/16/10 17 25
Silver
ug /L
ND
50
04/16/10 17 25
Thallium
ug /L
ND
100
04/16/1017 25
Zinc
ug /L
ND
100
'04/16/10 1,7 25
Pace Analytical Services, Inc
9800'Kincey Ave Suite 100
Hunterswile „NC 28078
(704)875 -9092
LABORATORY CONTROL SAMPLE”
Parameter
429216
Units
Spike
Conc
LCS
Result
LCS
% Rec
% Rec
Limits Qualifiers
Antimony
ug /L
500
474
95
85 -115
Arsenic
ug /L
500
480
96
85 -115
Beryllium
ug /L
500
496
99
85 -115
Cadmium
ug /L
500
479
96
85 -115
Chromium
ug /L
500
483
97
85 -115
Lead
ug /L
'500
486
97
85 -115
Nickel
ug /L
500
482
96
85 -115
Selenium
ug /L_
500
480
96
85 -115
Silver
ug /L
250
224
90
85 -115
Thallium
ug /L
500
468
94
85 -115
Zinc
ug /L
500
490
98
85 -115
MATRIX SPIKE & MATRIX SPIKE,DUPLICATE
429217
429218,
MS
MSD
9267053001
Spike
Spike
MS
MSD
MS
MSD
% Rec
Parameter
Units
Result
Conc
Conc
Result
Result
% Rec
%' Rec
Limits
RPD Qual
Antimony
ug /L
ND
500
500
491
488,
97
97
70 -130
1
Arsenic
ug /L
00080
500
500
510
507
100
100
70 -130
1
mg /L
Beryllium
ug /L
ND
500
500
503
499
101
100
70 -130
1
Cadmium
ug /L
00013
500
500
476
474
95
95
70 -130
0
mg /L
Chromium
ug /L
0 034
500
500
519
514
97
96
70 -130
1
mg /L
Lead
ug /L
0 034'
500
500
511
506
95
94
70 -130
1
mg /L
Date 04/23/2010 03 48 PM
REPORT OF
LABORATORY ANALYSIS
Page 5 of'14
This report shall not,be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc
AO

®
Pace Analytical Services, Inc
Ma�ytical
2225 Riverside Dr
wwwpacab68com
Asheville, NC 28804
(828)254 -7176
c.
QUALITY CONTROL DATA
Pace Analytical Services, Inc
9800 Kincey Ave Suite 100
'H u nterswlle,,N C`28078
(704)875 -9092
Project DUCK POND 04/12
Pace Project No 9267173
MATRIX SPIKE &'MATRIX 'SPIKE DUPLICATE
429217
429218
MS MSD
9267053001
Spike Spike
MS
MSD
MS
MSD
% Rec
Parameter
Units
Result
Conc Conc
Result
Result
% Rec
% Rec
Limits
RPD Qual
Nickel
ug /L
053,
500 500
1010
987
95
91
70 -130
2
mg /L
Selenium
ug /L
ND
500 500
489
480
98
96
70 -130
2
Silver
ug /L
ND
250 250
225
224
90
89
70 -130
0
Thallium
ug %L
ND
500 500
429
429
86
86
70 -130
0
Zinc
ug /L
43
500 500
4790
4810
93
98
70 -130
0
mg%L
SAMPLE DUPLICATE 429219
9266960001
Dup
Parameter
Units
Result
Result
RPD
Qualifiers
Antimony
ug /L
875
900
3
Arsenic
ug /L
258
280
9
Beryllium
ug /L
264
285
8
Cadmium
ug /L
187
204
9
Chromium
ug /L
1310
1400
7
Lead
ug /L
3460
3500
1
Nickel
ug /L
1260
1380
9
Selenium
ug /L
193
195'
1
Silver
ug /L
171
195
13
Thallium
ug /L
ND
28 6J
Zinc
ug /L
126000
138000,
9
Date 04/23/2010 03 48'PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc
Page�6 of 14

I eAnalyfical
wwwpawlaftcom
Project DUCK POND 04/12
Pace Project No 9267173
QC Batch MERP 12765
QC Batch Method EPA 245 1
Associated Lab Samples 9267173001
METHOD BLANK 428949
Associatedlab Samples 9267173001
Parameter Units
ug /L
Mercury
Pace Analytical, Services;lnc Pace Analyticaf Services, Inc
2225 Riverside,Dr 9800 KinceyAve Surte 100
Asheville, NC 28804 Huntersville, NC 28078
(828)254 -7176 (704)875 -9092
QUALITY CONTROL DATA
Analysis,Method EPA 2451
Ana lysis'Descnption 245 1 Mercury,
Matrix Water
Blank Reporting
Result Limit Analyzed Qualifiers
ND 0 20 04/16/10 21 21
LABORATORY CONTROL,SAMPLE 428950
Spike
LCS
LCS
% Rec
Parameter Units
Conc
Result
% Rec
Limits Qualifiers
Mercury ug /L
25
25
100
85 -115
MATRIX SPIKE & MATRIX -SPIKE DUPLICATE- 428951
428952
MS
MSD
9267110001
Spike
Spike MS
MSD
MS MSD % Rec
Parameter Units Result
Conc
Conc Result
Result
% Rec % Rec Limits RPD Qual
Mercury ug /L ND
25
25 ND
25
-2 97 70 -130 MO
SAMPLE DUPLICATE 428953
Parameter
Mercury
Date 04/23/2010 03 48 PM
9267173001 Dup
Units Result Result
ug /L ND ND
RPD Qualifiers
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in',full,
without the,written consent of Pace Analytical Services, Inc
gnrrYY��«o,o.
Page 7 of 14

aceAnalytical
.pacelabs.com
Project DUCK POND 04112
Pace Project No 9267173
QC Batch WET /12044
QC Batch Method SM 5210B
Associated Lab Samples 9267173001
METHOD BLANK 428123
Associated Lab Samples 9267173001
Parameter Units
BOD, 5 day mg /L
LABORATORY CONTROL SAMPLE 428124
Parameter Units
BOD, 5 day mg /L
SAMPLE DUPLICATE 428137
Parameter Units
BOD, 5 day mg /L
Date ;04/23/2010 03 48 PM
Pace Analytical Services, Inc Pace Analytical Services, Inc
2225, Riverside' Dr 9800 KmceyAve Suite 100
Asheville, NC 28804 Hunterswlle, NC 28078
(828)254 -7176 (704)875 -9092
QUALITY CONTROL DATA
Analysis Method SM 5210B
Analysis Description 521-013WD „5,day
Matrix Water
Blank Reporting
Result Limit Analyzed Qualifiers
ND 2 0 04/18/10 14 50
Spike LCS L'CS % Rec
Conc Result % Rec Limits Qualifiers
198 174 88 84 -115
9267206001 Dup
Result Result
1370 1370
RPD Qualifiers
0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc
Page 8 of 14

aceAnalytical
wwwpacelabs corn
Project' DUCK POND 04/12
Pace Project No 9267173
QC Batch WETA17196
QC Batch Method EPA 351 2
Associated Lab Samples 9267173001
METHOD BLANK 431150
Associated Lab Samples 9267173001
Parameter
Units
Nitrogen, Kjeldahl, Total
mg /L
LABORATORY CONTROL SAMPLE
431151
Parameter
Units
Nitrogen, Kjeldahl, Total
mg /L
MATRIkSPIKE'�SAMPLE
431152
Parameter
Units
Nitrogen, Kjeldahl', Total
mg /L
SAMPLE DUPLICATE 431153
Parameter
Units
Nitrogen, Kjeldahl, Total
mg /L
Date 04/23/2010 03 48 PM
Pace Analytical Services, Inc
2225'Riverside Dr
Asheville, NC 28804
(828)254 -7176
QUALITY CONTROL DATA
Analysis Method EPA 351 2
Analysis Description 351 2 TKN
Matrix Water
Blank Reporting
Result Limit Analyzed Qualifiers
ND 0 50 04/22/10 13 27
Pace Analytical Services, Inc
9800 IGncey Ave Suite 100
Huntersville, NC 28078
(704)875 -9092
Spike LCS LCS % Rec
Conc Result % Rec Limits Qualifiers
5 52 105 90 -110
9266978001 Spike
Result Conc
60 5
9267173001 Dup
Result Result
066 1 6
MS MS
Result % Rec
97 74
RPD Qualifiers
'82 R1
,REPORT OF LABORATORY ANALYSIS
This report'shall not'be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc
% Rec
Limits Qualifiers
90 -110 Mo
Page 9'of 14

® Pace Analytical Services, Inc Pace Analytical Services, Inc
aceMalXical 2225 Riverside Dr 9800 Kincey Ave Suite 100
wwwpacelabacam Asheville, NC 28804 Huntersville, NC 28078
QUALITY CONTROL DATA
(828)254 -7176 (704)875 -9092
Protect DUCK POND 04/12
Pace Project No 9267173
QC Batch WETA17183
Analysis Method EPA 353 2
QC Batch Method EPA 353 2
Analysis Description 353 2 Nitrate + Nitnte; preserved
Associated Lab Samples 9267173001
METHOD BLANK 430324
Matrix Water
Associated Lab Samples 9267173001
Blank Reporting
Parameter
Units
Result Limit
Analyzed
Qualifiers
Nitrogen, NO2 plus NO3
mg /L
ND 0 10
04/18110 10 32
LABORATORY CONTROL SAMPLE
430325
Spike LCS
LCS
% Rec
Parameter
Units
Conc Result
% Rec
Limits Qualifiers
Nitrogen, NO2 plus NO3
mg /L
5 5'1
102
90 -110
MATRIX SPIKE SAMPLE
430326
9266802001 Spike
MS
MS
% Rec
Parameter
Units
Result Conc
Result
% Rec
Limits
Qualifiers
Nitrogen, NO2 plus NO3
mg /L
041 5
52
96
75 -125
MATRIX'SPIKE SAMPLE
430328
9267367005 Spike
MS
MS
% Rec
Parameter
Units
Result Conc
Result
% Rec
Limits
Qualifiers
Nitrogen, NO2 plus NO3
mg /L
76 5
11 7
81
75 -125
SAMPLE DUPLICATE 430327
9266805001 Dup
Parameter
Units
Result Result
RPD
Qualifiers
Nitrogen, NO2 plus NO3
mg /L
046 046
2
SAMPLE DUPLICATE 430329
9267367007 Dup
Parameter
Units
Result Result
RPD
Qualifiers
Nitrogen, NO2 plus'NO3
mg /L
ND ND
Date 04/23/2010 03 48;PM
REPORT OF LABORATORY ANALYSIS
Page 10 of 14
This report shall -not be reproduced, except in full,
without the written consentof Pace Analytical Services, Inc
/1±Y 11y {J� 1 ACCo# o,

(�IaceAnalytical
wwwpscebabs:cem
Project DUCK POND 04/12
Pace Project, No 9267173
QC Batch WETA[7175
QC Batch Method EPA 365 1
Associated Lab Samples- 9267173001
METHOD BLANK 429864
Associated Lab Samples 9267173001
Parameter
Units
Phosphorus
mg /L
LABORATORY CONTROL SAMPLE
429865
Parameter
Units
Phosphorus
mg /L
MATRIX SPIKE SAMPLE
429866
Parameter
Units
Phosphorus
mg /L
MATRIX SPIKE SAMPLE
429868
Parameter
Units
Phosphorus
mg /L
SAMPLE DUPLICATE 429867
Parameter
Phosphorus
SAMPLE DUPLICATE 429869
Parameter
Phosphorus
Date 04/23/2010 03 4&PM`
Pace Analytical Services, Inc
2225 Riverside Dr
Asheville, NC 28804
(828)254 -7176
QUALITY CONTROL DATA
Analysis Method EPA 365 1
Analysis Description 365 1 Phosphorus, Total
Matrix , Water
Blank Reporting
Result Limit Analyzed Qualifiers
ND 010 04/18/10 11 26
Pace Analytical, Services, Inc
9800 KinceyAve Suite 100
Huntersvdle, NC 28078
(704)875 -9092
Spike LCS LCS % Rec
Conc Result % Rec Limits Qualifiers
1 10 101 90 -110
9267367015 Spike MS MS % Rec
Result Conc Result % Rec Limits Qualifiers
436 1 449 123 90 -110 MO
9266715001 Spike, 'MS MS % Rec
Result Conc Result %,Rec Limits Qualifiers
3 2' 1 51 194 90 -110 M&
9266947001 Dup
Units Result Result
mg /L 34 34
9267067001 Dup
Units Result Result
mg /L 70 71
RPD Qualifiers
0
RPD Qualifiers
2
REPORT OF LABORATORY ANALYSIS
This report'shall not be reproduced, except in full,
without the,wntten consent,of Pace Analytical Services, Inc
Page'11 of 14

® Pace Analytical Services, Inc Pace Analytical Services, Inc
a malytical 2225 Riverside Dr 9800 Kmcey Ave Suite 100
a*,pacelaftcom Asheville, NC 28804 Hunterswlle, NC 28078
[phone] [phone]
QUALITY CONTROL DATA
Project DUCK POND 04/12
Pace ProjedNo 9267173
QC Batch WETAU144 Analysis Method SM 5220D
QC Batch Method SM 5220D Analysis Description Z220D,COD
Associated Lab Samples 9267173001
METHOD BLANK 428014 Matrix 'Water
Associated Lab Samples 92.67173001
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Chemical Oxygen Demand mg /L ND 25'0 0464/10 16 46
LABORATORY CONTROL SAMPLE,
428015
Spike LCS
LCS
% Rec
Parameter
Units
Conc Result
% Rec
Limits
Qualifiers
Chemical Oxygen,Demand
mg /L-
750
716
95
90 -110
MATRIX,SPIKE °SAMPLE
428016
9266663008
Spike
MS
MS
% Rec
Parameter
Units
Result
Conc
Result
% Rec
Limits Qualifiers
Chemical Oxygen Demand
mg/L
700
750
804
98
75 -125
MATRIX SPIKE SAMPLE
428022
9266996001
Spike
MS
MS
% Rec
Parameter
Units
Result
Conc
Result
% Rec
Limits Qualifiers
Chemical Oxygen Demand
'mg /L
179
750
890
95
75 -125
SAMPLE DUPLICATE 428021
9266750007 pup
Parameter Units Result Result RPD Qualifiers
Chemical ,Oxygen Demand mg /L 600 596 1
SAMPLE DUPLICATE 428023
9266758005 Dup
Parameter Units Result Result RPD Qualifiers
Chemical Oxygen Demand mg /L 2630 2580 2
Date 04/23/2010'03 48 PM
REPORT OF LABORATORY ANALYSIS
This 'report shall not be reproduced, except'in, full,
without the written consent of Pace Analytical Services, Inc
o coo,,o
�E \\
i�Ja
Page 12 of 14

aceAnalytkal
WW O6818bs cam
QUALIFIERS
Project DUCK'POND 04/12
Pace Project�No 9267173
T EFINITIONS
Pace Analytic#Se_rvices;,lnc
2225' R iverside,Dr
Asheville, NC 28804
(828)254 -7176
Pace Analytical,Services, Inc,
9800 KinceyAve Suite 100
Huntersville, NC 28078
,(704)875 -9092
DF - DilutioniFactor, if reported, represents,the factor applied to,the reported data due to,changes in sample preparation,, dilution of
the sample aliquot, or moisture content
,ND ­Not Detected at'or above ad) usted'reporting'ilmrt
J­ Estimated, concentration above theaad)usted method detection limit and'below the adtusted,reportingHllmrt�
MDL- Adjusted; Method Detection Limit
S -Surrogate
1, 2- Diphenylhydrazine(8270,listed analyte)Aecomposes toAzobenzene
Conslstent,withlEPA gwdehries;,unrounded'data aredisplayed'and have been used to,calculai6% recovery+and 'RFD values
LCS(D) - Laboratory'Control,Samplei(C uplicate)
MS(D) a MatnxlSpikel(Dupllcate)
PUP - =Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable
Pace Analytical�is NELAP accredited >'Contact,yqur Pace,PMlor the currentlist;of accredited analytes
U - Indicates'theicompound'was analyzed for „but not,detected
LABORATORIES
PASI -A Pace,Analytical Services -Asheville
ANALYTEfQUALIFIERS
,B2' Oxygen usage is less than 2 O'for all'dilutions,set The reported valueris,an estimated less than value and, is; calculated
for the dilution using the;mostamount of sample
D3 Sample was dil tedtdue,to the`presence of high level&of non- tar`get=analgtes%or,oi er`mateix`interference
MO Matrix spike recovery and /or matrix,spikerduplmate recovery was ,ioutside,laboratory,control limits
�R1 RFD ^value wasloutside,control'hmits
Date 04/23/20,1,003 48 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be'reproduced, except in full,
without the written consent of PaceAnalytical Services „Inc
AO
� a
Page f3lof 14

® Pace Analytical Services, Inc
aceAnalytical 2225 Riverside Dr
wwwpacelabscam Asheville, NC'28804
(828)254 -7176
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project DUCK POND 04/12
Pace,Project No 9267173
Pace-Analytical Services,,lnc_
9800 KinceyAve , Suite 100
Huntersvdle,'NC 28078
(704)875 -9092
Date 04/23/2010 03 48 PM
REPORT OF' LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the wnttemconsent of Pace Analytical Services; tnc
/1 1 ry CCpq�
uL�r z
Page 14 of 14
Analytical
Lab ID
Sample ID
QC Batch Method
OC Batch
Analytical Method
Batch
9267173001
DUCK POND
EPA 200 7
MPRP /6150
EPA 200 7
ICP/5675
9267173001
DUCK POND
EPA 2451
MERP /2765
EPA 2451
MERC /2731
9267173001
DUCK POND
SM 52106
WET/12044
SM 5210B
WET/12085
92671.73001
DUCK POND
40CFR PART 503
WET/12127
9267173001
DUCK POND
EPA 351 2
WETAf7196
9267173001
DUCK POND
EPA 353 2
WETA17183
9267173001
DUCK POND
EPA 365 1
WETA/7175
9267173001
DUCK POND
SM 5220D
WETA/7144
Date 04/23/2010 03 48 PM
REPORT OF' LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the wnttemconsent of Pace Analytical Services; tnc
/1 1 ry CCpq�
uL�r z
Page 14 of 14