Loading...
HomeMy WebLinkAboutNC0026573_Fact Sheet_20220728Fact Sheet NPDES Permit No. NC0026573 Permit Writer / Email Contact Diana Yitbarek / diana.yitbarek@ncdenr.gov Date: 7/28/2022 Division/Unit: NC DEQ Division of Water Resources / NPDES Municipal Permitting Unit Fact Sheet Template: Version 01/09/2017 Permitting Action: ❑X Renewal ❑ Renewal with Expansion ❑ New Discharge ❑ Modification (Fact Sheet should be tailored to mod request) 1. Basic Facility Information Table 1. Facility Information Facility Information Applicant/Facility Name: City of Morganton/Catawba River Pollution Control Facility Applicant Address: PO Box 3448, Morganton NC 28680-3448 Facility Address: 1000 Vine Arden Road, Morganton NC 28655 Permitted Discharge Flow: 8.0, 10.5, and 13.0 million gallons per day (MGD) Facility Type/Waste: Major Municipal/ 62 % Domestic and 38% industrial* Facility Class: Biological Class/Grade IV Treatment Units: Influent pump station/wet well, bar screening and grit removal structures, two primary clarifiers, sludge holding tank, three peak flow storage basins/equalization basins, three diffused aeration basins, three secondary clarifiers, chlorine contact chamber, dechlorination, aerobic digestors, dewatering centrifuge, and composting site Pretreatment Program (Y/N) Y County: Burke Region Asheville Regional Office (ARO) *Percentages based on the facility's current operating design flow tier, 8.0 MGD and current industrial permitted flow, 3.1 MGD Permitting Action: The City of Morganton (City) applied for NPDES permit renewal for the Catawba River Pollution Control Facility in September 2019. The Facility has a design capacity of 8.0 MGD and is currently authorized to discharge 8.0 MGD (up to 10.5 MGD and 13.0 MGD upon request) into the Catawba River. The Facility serves 18,468 residents in the City of Morganton and the Town of Glen Alpine. This Facility received authorization to construct in 2017 to improve the Facility and currently has no plans to expand. The Facility receives pretreated industrial wastewater from three significant industrial users (SIUs), Case Chicken Farm, UNIX Packaging, and Seiren (textile) in their pretreatment program. The City has a long-term monitoring plan (LTMP) and the current industrial permitted flow to discharge by the SIUs is 3.64 MGD. Page 1 of 18 Facility Background: In 1997, the Facility was granted an expansion to 10.5 MGD based on growth and capacity issues; however, based on information provided in 2022, the facility is not yet ready to operate up to 10.5 MGD. By 2002, the Division had authorized an effluent limitation and monitoring page with a higher flow tier of 13.0 MGD. Improvements to the treatment system were completed in June 2014 due to a Special Order by Consent (SOC) to address compliance issues at the Facility. In 2017, the City also completed Improvement Projects to repurpose existing aeration and equalization basins, among other improvements. At present, this fact sheet assessment is based on a wastewater plant flow of 8.0 MGD, and the Facility has confirmed capacity to treat up to 8.0 MGD. The Facility utilizes composting on site as the method of disposal of its municipal sewage biosolids under Division permit WQ0002127. The compost is sampled and sold to the public. 2. Receiving Waterbody Information: Table 2. Receiving Waterbodv Information62 Outfalls/Receiving Stream(s): Outfall 001/Catawba River (35°46'42.8"N 81°39'33.5"W) Stream Segment: 11-(34.5) Stream Classification: WS-IV and Critical Area (CA) Drainage Area (mi2): 705* Summer 7Q10 (cfs) 118* Winter 7Q10 (cfs): 118 30Q2 (cfs): Unknown Average Flow (cfs): 1060* Instream Waste Concentration (IWC) (% effluent): 9.5 % at 8.0 MGD (7Q10S) 12.0 % at 10.5 MGD (7Q10S) 14.5 % at 13.0 MGD (7Q10S) 303(d) listed/parameter: No Subject to TMDL/parameter: Yes/Mercury Statewide TMDL implemented in 2012. Basin/Sub-basin/HUC: Catawba/03-08-31/03050101 USGS Topo Quad/State Grid: D12SW/ Morganton -North * Stream flow values taken from previous fact sheet, 2002 - 2015 per Division's Guidelines The receiving stream is the Catawba River, stream segment 11-(34.5) located between Lake James and Lake Rhodhiss The stream is classified WS-IV CA. The class denotes use as a water supply, primary recreation, and critical area waterbody. Because of its location downstream of Lake James Dam, the 7Q10 flow at this site has been estimated over the years, by using the 25 cubic feet per second (cfs) instantaneous flow of the dam plus tributary flow from several rivers which drain into the Catawba River upstream of the Morganton discharge point. Historical estimates had the 7Q10 flow at 126 cfs at the WWTP. However, in 1994, the Division of Water Resources requested an updated 7Q10 due to the request for expansion and used 118 cfs for 10.5 MGD and 13.0 MGD. For consistency with the use of the current 7Q10, this renewal uses a summer 7Q10 of 118 cfs for 8.0 MGD, 10.5 MGD, and 13.0 MGD. Page 2 of 18 3. Effluent Data Summary Effluent data for Outfall 001 is summarized below from January 2016 through July 2021. Table 3. Effluent Data Summary with permit limits Outfall 001 Parameter Units Average Max Min Permit Limit Flow MGD 5.4 28.7 1.1 MA* 8.0MGD BOD5 mg/1 14.7 632 1.8 MA 30.0 mg/I WA* 45.0 mg/I Total Suspended Solids (TSS) mg/1 17.64 755 2.5 MA 30.0 mg/I WA 45.0 mg/I NH3N mg/1 20 - MA 16.0 mg/I WA 35.0 mg/I Fecal Coliform #/100 ml 5.8 (Geomean) 352000 1 MA 200/100m1 WA 400/100m1 pH SU 6.8 7.6 5.8 6.0<pH<9.0 Dissolved Oxygen (DO) mg/1 8.2 10.9 5.9 DA*> 5.0 mg/I Total Residual Chlorine (TRC) µgn 20.7 57 20 DM* 28.00 pg/I Temperature °C 20.4 28 9.6 Conductivity umhos/cm 439.9 4523 127 Total Phosphorus (TP) mg/1 3.4 12 0.4 Total Nitrogen (TN) mg/1 14.05 28.2 7.9 Total Copper µg/1 20.8 281 1 *MA -Monthly Average, WA -Weekly Average, DM -Daily Maximum, DA=Daily Average. Table 4. Effluent Data Summary from expanded effluent pollutant scan Outfall 001 Parameter Units Average Max Aluminum µg/1 299.6 1010.0 Antimony µg/1 17.0 26.0 Chromium µg/1 1.1 2.5 Cyanide µg/1 5.1 6.0 Dimethyl phthalate µg/1 5.2 5.4 Methyl Bromide µg/1 3.5 5.5 Mercury ng/1 2.2 14.6 Molybdenum µg/1 1.2 2.9 Nickel µg/1 1.6 9.0 Selenium µg/1 8.7 11.0 Silver µg/1 1.3 6.0 Total Hardness (as CaCO3) m n g 36.2 51.5 Zinc µg/1 49.7 157.0 Page 3 of 18 Sample results for arsenic, beryllium, cadmium, chlorinated phenolic compounds, lead, and thallium were less than the method detection limit. The compounds in the above table were analyzed in the reasonable potential analysis (RPA), with the exception of aluminum, and discussed below in the RPA section of this fact sheet. 4. Instream Data Summary Instream monitoring may be required in certain situations, for example, 1) to verify model predictions when model results for instream DO are within 1 mg/1 of instream standard at full permitted flow; 2) to verify model predictions for outfall diffuser; 3) to provide data for future total maximum daily load (TMDL); 4) based on other instream concerns. Instream monitoring may be conducted by the Permittee, and there are also Monitoring Coalitions established in several basins that conduct instream sampling for the Permittee (in which case instream monitoring is waived in the permit as long as coalition membership is maintained). Instream data summary and instream monitoring proposed for this permit action: The current permit requires instream [upstream (U) and downstream (D)] monitoring for conductivity, dissolved oxygen, and temperature. In this permit renewal, U monitoring for total hardness will be required. The U sampling point is located at — 250 ft of the outfall. The D sampling point is located — 2.3 miles from the outfall on Huffman Bridge Road. No road closer to the outfall is intersecting the stream. The graphs below summarize instream and effluent (Eff) data from the analyzed period, June 2016 - July 2021. Figure 1. Average, maximum, and minimum instream and effluent data summary 700.0 600.0 500.0 400.0 300.0 200.0 100.0 0.0 Conductivity, umhos/cm DO, mg/I IN I Upstream il Effluent Downstream ■ Average ■ Max ■ Min 20.0 15.0 10.0 5.0 0.0 Upstream Effluent ■ Average ■ Max ■ Min Downstream 35.0 30.0 25.0 20.0 — 15.0 10.0 5.0 0.0 Temperature, °C Upstream Effluent •Average ■ Max ■ Min Downstream T-tests were run to analyze relationships between instream sample results. A statistically significant difference is determined when the t-test p-value result is < 0.05. Conductivity: As a major Facility with industrial sources, instream monitoring for conductivity is required per 15A NCAC 2B .0508. The variances in downstream and upstream conductivity were up to 129 Page 4 of 18 umhos/cm, on 8/9/2017. The t-test concluded that there is statistically significant difference between upstream and downstream conductivity. DO: The minimum downstream DO detected was 3.7 mg/1, and the maximum DO differential between the upstream and downstream samples was 8.9 mg/1. The t-test concluded that there is a statistically significant difference between upstream and downstream DO. The review of instream data in the Catawba River showed that the DO standard of 5 mg/1 [Per 15A NCAC 02B .0211 (6)] was being met upstream, but it is failing to be met downstream of the WWTP. Temperature: The maximum upstream, effluent, and downstream temperatures were 27 (9/2019), 28 (7/2020), and 32 (7/2019) degrees Celsius. The review of instream data in the Catawba River showed that the T standard of 29 degrees Celsius was not met on a few certain occasions, nor the 2.8 degrees Celsius temperature increase (For our purposes, natural water temperature is defined by the upstream temperature.) The ttest concluded that there is statistically significant difference between the upstream and downstream temperatures. Hardness: Instream hardness sampling upstream of the discharge will be added to the permit at a monitoring frequency of quarterly. The NC 2007-2014 Water Quality Standard (WQS) Triennial Review was approved by the NC Environmental Management Committee (EMC) on November 13, 2014. The US EPA subsequently approved the WQS revisions on April 6, 2016, with some exceptions. The NC Division of Water Resources NPDES Permitting Unit is required to implement the new dissolved metal standards in all permits public noticed after April 6, 2016. The new standards for most metals include acute standards. Further, the freshwater standards for several metals are expressed as the dissolved form of the metals, and seven metals have hardness -dependent equations. As a result, the NPDES Permitting Unit will need site - specific effluent hardness data and instream hardness data, upstream of the discharge for each facility monitoring these metals in order to calculate permit limitations. Is this facility a member of a Monitoring Coalition with waived instream monitoring (Y/N): NO Name of Monitoring Coalition: NA 5. Compliance Summary Below find summaries of compliance data from January 2016 to May 2021. Compliance record with permit effluent limits (past 5 years): The Facility received a total of 31 notices of violation (NOVs) for exceeding limits for BOD5, TSS, fecal coliform, conductivity, DO, and pH. The Facility also received 47 enforcement cases for exceeding limits for TSS, BOD5, fecal coliform, flow, TRC, and pH. The ARO, Linda Wiggs, is working with the Facility to monitor the Facility's compliance performance. The report on limit violations that proceeded to NOV and Enforcement Case were as follows: Table 5. Facility's Compliance Summary of Events from January 2016 to May 2021 Parameter/Event Daily Min. Not Reached MA Exceeded WA Exceeded Weekly Geometric Mean Exceeded BOD5 Fecal pH TSS 23 Page 5 of 18 Summary of the compliance record with aquatic toxicity test limits and any second species test results (past 5 years): The Facility passed eighteen of eighteen quarterly chronic toxicity tests at 9% effluent. Failed to comply with all four 2nd species, but with the expedited compliance schedule from the aquatic toxicity branch, the Facility was able to complete their four -second species test on 2/2021, 3/2021, 4/2021, 5/2021. All four tests passed. Summary of the results from the most recent compliance inspection: The last Facility inspection conducted in August 2020 reported that no compliance issues were noted. The Pretreatment team and the regional office noted that Case Farms (IUP# 1098) had 16.6% of sampling violations for Oil & Grease in the 2nd six months of 2020; Seiren North America (IUP# 4002) had 16.6% of sampling violations for Zinc in the 1st six months of 2020. 6. Water Quality -Based Effluent Limitations (WQBELs) Dilution and Mixing Zones In accordance with 15A NCAC 2B.0206, the following stream flows are used for dilution considerations for development of WQBELs: 1Q10 streamflow (acute Aquatic Life); 7Q10 streamflow (chronic Aquatic Life; non -carcinogen HH); 30Q2 streamflow (aesthetics); annual average flow (carcinogen, HH). If applicable, describe any other dilution factors considered (e.g., based on CORMIX model results): NA. If applicable, describe any mixing zones established in accordance with 15A NCAC 2B. 0204(b): NA Stream flow values were extracted from the previous fact sheets, 2002-2015. Oxygen -Consuming Waste Limitations Limitations for oxygen -consuming waste (e.g., BOD) are generally based on water quality modeling to ensure protection of the instream dissolved oxygen (DO) water quality standard. Secondary TBEL limits (e.g., BOD= 30 mg/1 for Municipals) may be appropriate if deemed more stringent based on dilution and model results. (If permit limits are more stringent than TBELs, describe how limits were developed) The current permit limits for BOD are water quality limited and are based on the 1994 water quality model results. Ammonia and Total Residual Chlorine (TRC) Limitations Limitations for ammonia are based on the protection of aquatic life utilizing an ammonia chronic criterion of 1.0 mg/1 (summer) and 1.8 mg/1 (winter). Acute ammonia limits are derived from chronic criteria, utilizing a multiplication factor of 3 for Municipals and a multiplication factor of 5 for Non -Municipals. Limitations for Total Residual Chlorine (TRC) are based on the NC water quality standard for protection of aquatic life (17 ug/1) and capped at 28 ug/1 (acute impacts). Due to analytical issues, all TRC values reported below 50 ug/1 are considered compliant with their permit limit. Page 6 of 18 Proposed changes to ammonia and/or TRC limits for this permit renewal: Ammonia The current permit sets year-round limits for ammonia (MA 16.0 mg/1 and WA 35.0 mg/1) for the 8.0 MGD flow tier based on the 1994 water quality model. For the 10.5 MGD and 13.0 MGD flow tiers, the permit sets summer and winter limits according to the waste load allocation (WLA) calculations. Self -monitoring data generally indicates ammonia concentrations of less than 5 mg/L, which indicates that the facility is achieving ammonia removal through nitrification. As seen in the graph below, there are peaks in the ammonia concentration at the end of 2018 and the beginning of 2019. As explained by the Permittee, during this period, the plant had completed construction on the two new diffused bubbler aeration basins and was placed online; therefore, the Facility experienced higher ammonia levels during this changeover time with the nitrification process in its infant stages. Figure 2. Ammonia effluent data summary Ammonia, mg/I 25 20 15 10 5 0 01/2016 08/2016 03/2017 09/2017 04/2018 10/2018 05/2019 12/2019 06/2020 01/2021 07/2021 The permit only had a monthly average limit of 16 mg/1 until it was renewed in 2006, when a weekly average limit of 35 mg/1 was implemented. The permit was renewed in 2011 with the same limits. The current ammonia policy is to calculate an allowable ammonia limit based on aquatic toxicity using a target of 1 mg/1 instream ammonia to protect aquatic life. If this calculated limit is more stringent than the limit calculated by the water quality model, the more stringent limit is applied to the permit. Ammonia limit calculated for protection of ammonia toxicity in the stream results in 8.4 mg/1, which is less than the existing monthly average limit of 16 mg/l. Therefore, year-round limits are adjusted in this permit cycle for the 8.0 MGD flow tier as follows, MA 8.4 mg/1 and WA 25.3 mg/1. For the 10.5 MGD and 13.0 MGD flow tiers, the ammonia limits were evaluated via the WLA and will be the same as the previous permit cycle. TRC The Facility uses chlorination as its primary disinfection. The current permit limits TRC at 28 ug/L as a daily maximum. Through this permit cycle, the Facility reported TRC values below 30 ug/L, with the exception of summer 2020, when several reported TRC values exceeded the 30 ug/L but remained below Page 7 of 18 50 ug/L. The TRC limit has been reviewed in the attached WLA and has been found to be protective. No changes are proposed for TRC. Reasonable Potential Analysis (RPA) for Toxicants The need for toxicant limits is based upon a demonstration of reasonable potential to exceed water quality standards, a statistical evaluation that is conducted during every permit renewal utilizing the most recent effluent data for each outfall. The RPA is conducted in accordance with 40 CFR 122.44 (d) (i). The NC RPA procedure utilizes the following: 1) 95% Confidence Level/95% Probability; 2) assumption of zero background; 3) use of Y2 detection limit for "less than" values; and 4) stream flows used for dilution consideration based on 15A NCAC 2B.0206. Effective April 6, 2016, NC began implementation of dissolved metals criteria in the RPA process in accordance with guidance titled NPDES Implementation of Instream Dissolved Metals Standards, dated June 10, 2016. The RPAs were conducted for permitted flows of 8.0MGD, 10.5 MGD, and 13.0 MGD with a 7Q10S of 118 cubic feet per second (cfs), specific effluent hardness values, and default upstream hardness values. During the public notice period, the Permittee corrected eDMR values; the RPA was updated accordingly. Additionally, the RPA was corrected to replace the outstanding resource water (ORW) stream classification in the original draft with the correct classification as WS-IV and CA. This correction updates the calculated water quality standard (WQS) values and the RPA results. The answers below are based on the updated RPA. Pollutants of concern included toxicants with positive detections and defined water quality standards/EPA criteria and BPJ. Based on these analyses, the following permitting actions are proposed for this permit: RPAs were conducted on effluent toxicant data collected in the Permittee's January 2016 through July 2021 DMRs, and three effluent pollutant scans (2016, 2017, and 2018). Pollutants of concern included toxicants with positive detections and associated water quality standards/criteria. The data set was limited for antimony, beryllium, dimethyl phthalate, methyl bromide, and total phenolic compounds. Based on this analysis, the following permitting actions are proposed for this permit: • Effluent Limit with Monitoring. The following parameters will receive a water quality -based effluent limit (WQBEL) since they demonstrated a reasonable potential to exceed applicable water quality standards/criteria: For 8.0 MGD — Copper For 10.5 MGD — Copper For 13.0 MGD — Copper To provide an opportunity for the City to develop a plan to assess sources of copper in order to come in compliance with the limits in Section A. (1.) a 3-year schedule of compliance has been added to the permit for 8.0 MGD. See Special Condition A. (9.) • Monitoring Only. The following parameters will receive a monitor -only requirement since they did not demonstrate reasonable potential to exceed applicable water quality standards/criteria, but the maximum predicted concentration was >50% of the allowable concentration: For 8.0 MGD — Silver. Method with the lowest PQL must be used. (See note below) For 10.5 MGD — Silver. Method with the lowest PQL must be used. For 13.0 MGD — Silver. Method with the lowest PQL must be used. The City of Morganton reported Total Silver at less than detection, with detection levels < 1.0 µg/L and < 2.5 µg/L in the Effluent Pollutant Scans (or their DMR results). The City's allowable discharge concentrations are 0.63 µg/L for Total Silver. DWR's laboratory identifies the target Practical Quantification Limits (PQLs) for Total Silver as 1.0 µg/L. Page 8 of 18 15A NCAC 2B .0505 (e) (4) requires that all test procedures must produce detection and reporting levels that are below the permit discharge requirements and all data generated must be reported to the approved detection level or lower reporting level of the procedure. If no approved methods are capable of achieving a detection level below the permit discharge requirement (or allowable discharge concentration) the Method with the lowest detection level must be used. The City should use sufficiently sensitive test methods for all pollutants, including when performing Effluent Pollutant Scans. • POTW Effluent Pollutant Scan Review: Three effluent pollutant scans were evaluated for additional pollutants of concern. o The following parameter(s) will receive a water quality -based effluent limit (WQBEL) with monitoring, since as part of a limited data set, two samples exceeded the allowable discharge concentration: NA o The following parameter(s) will receive a monitor -only requirement, since as part of a limited data set, one sample exceeded the allowable discharge concentration: For 8.0 MGD — Antimony. For 10.5 MGD — Antimony. For 13.0 MGD — Antimony. • No Limit or Monitoring: The following parameters will not receive a limit or monitoring, since they did not demonstrate reasonable potential to exceed applicable water quality standards/criteria and the maximum predicted concentration was <50% of the allowable concentration: For 8.0 MGD: Arsenic, Cyanide, Lead, Molybdenum, Nickel, Selenium, Zinc, Total Phenolic Compounds, Dimethyl phthalate, Methyl bromide. For 10.5 MGD: Arsenic, Cyanide, Lead, Molybdenum, Nickel, Selenium, Zinc, Total Phenolic Compounds, Dimethyl phthalate, Methyl bromide. For 13.0 MGD: Arsenic, Cyanide, Lead, Molybdenum, Nickel, Selenium, Zinc, Total Phenolic Compounds, Dimethyl phthalate, Methyl bromide. 15A NCAC 2B .0505 (e) (4) requires that all test procedures must produce detection and reporting levels that are below the permit discharge requirements and all data generated must be reported to the approved detection level or lower reporting level of the procedure. If no approved methods are capable of achieving a detection level below the permit discharge requirement (or allowable discharge concentration), the Method with the lowest detection level must be used. The City should use sufficiently sensitive test methods for all pollutants, including when performing Effluent Pollutant Scans. • Additional Notes: o Aluminum: In order to assess the impact of this compound in the stream, a monitoring requirement for aluminum will be added on a quarterly basis. The 2018 Recommended Aquatic Life Ambient Water Quality Criteria for Aluminum in Freshwaters depend on a site's water chemistry parameters (pH, hardness, and dissolved organic carbon (DOC)); therefore, this permit cycle the Division proposes quarterly monitoring for DOC, in order to calculate the water quality standard (WQS) and conduct the RPA for aluminum in the next permit cycle. For 8.0 MGD: Aluminum and DOC For 10.5 MGD: Aluminum and DOC Page 9 of 18 For 13.0 MGD: Aluminum and DOC RPA results as well as a copy of the Dissolved Metals Implementation Fact Sheet for freshwater are included in the attachments of this Fact Sheet. Toxicity Testing Limitations Permit limits and monitoring requirements for Whole Effluent Toxicity (WET) have been established in accordance with Division guidance (per WET Memo, 8/2/1999). Per WET guidance, all NPDES permits issued to Major facilities or any facility discharging "complex" wastewater (contains anything other than domestic waste) will contain appropriate WET limits and monitoring requirements, with several exceptions. The State has received prior EPA approval to use an Alternative WET Test Procedure in NPDES permits, using single concentration screening tests, with multiple dilution follow-up upon a test failure. Describe proposed toxicity test requirement: This is a Major Publicly Owned Treatment Work (POTW), and a quarterly chronic WET limit will continue to apply at Outfall 001 at 9.5 % effluent concentration using Ceriodaphnia dubia for 8.0 MGD; 12.0 % for 10.5 MGD, and 14.5 % for 13.0 MGD. Mercury Statewide Total Maximum Daily Load (TMDL) Evaluation There is a statewide TMDL for mercury approved by EPA in 2012. The TMDL target was to comply with EPA's mercury fish tissue criteria (0.3 mg/kg) for human health protection. The TMDL established a wasteload allocation for point sources of 37 kg/year (81 lb/year) and is applicable to municipals and industrial facilities with known mercury discharges. Given the small contribution of mercury from point sources (-2% of total load), the TMDL emphasizes mercury minimization plans (MMPs) for point source control. Municipal facilities > 2 MGD and discharging quantifiable levels of mercury (>1 ng/1) will receive an MMP requirement. Industrials are evaluated on a case -by -case basis, depending if mercury is a pollutant of concern. Effluent limits may also be added if annual average effluent concentrations exceed the WQBEL value (based on the NC WQS of 12 ng/1) and/or if any individual value exceeds a TBEL value of 47 ng/1 Find summaries of compliance mercury data from May 2017 to October 2020 in Table 6. (Methods 1631E and 200.7) Table 6. Mercury Effluent Data Summary — 8.0MGD 2017 2018 2019 2020 # of Samples 3 4 8 10 Mercury Annual Average (ng/1) 66.7 50.0 13.6 2.84 Mercury Annual Max (ng/1) 100.0 50.0 50.0 14.6 TBEL, ng/L 47 WQBEL, ng/L for 8.0 MGD 126.2 WQBEL, ng/L for 10.5 MGD 99.0 WQBEL, ng/L for 13.0 MGD 82.3 Page 10 of 18 Describe proposed permit actions based on mercury evaluation Since the facility is >2 MGD and reported quantifiable levels of mercury (> 1 ng/1), a mercury minimization plan (MMP) was added to this permit in the last permit cycle and will continue in this permit cycle. Mercury evaluation results were available and used Method 1631E in 2019 and 2020. Previous sampling events used Method 200.7. No annual average mercury concentration exceeded the WQBEL. Individual mercury samples exceeded the TBEL when Method 200.7 was used; however, according to August 23, 2007, US EPA Memorandum, only the most sensitive methods such as Methods 1631E and 245.7 are appropriate in most instances for use in deciding whether to set a permit limitation for mercury and for sampling and analysis of mercury pursuant to the monitoring requirements within a permit. Therefore, the sampling results obtained in 2017 and 2018, which used Method 200.7, are not considered to set a permit limitation for this facility. The facility must continue to use only Method 1631E. Other TMDL/Nutrient Management Strategy Considerations If applicable, describe any other TMDLs/Nutrient Management Strategies and their implementation within this permit: During the 2010 permit renewal, effluent and instream monitoring for total nitrogen (TN) and total phosphorous (TP) were included in the permit due to the impairment of Lake Rhodhiss (2010 NC 303(d) List). In 2016, the instream monitoring for TN and TP was eliminated due to the Lake Rhodhiss being taken off the 303(d) list. Lake Rhodhiss was listed in the 303d list for high pH and excessive algal production beginning in 2006 and removed from it in 2014. Plans for the nutrient TMDL were dropped, as it was no longer impaired. Due to lower pH and algal growth in the lake, the Division decided to change nutrient monitoring frequencies from weekly to monthly and eliminate instream monitoring requirements for four facilities (Marion, Morganton, Lenoir, and Valdese) discharging to Lake Rhodhiss. The permit reflects a monthly nutrient (TP and TN) monitoring for 8.0 MGD and 10.5 MGD and weekly monitoring for 13.0 MGD, as well as annual nutrient (TN and TP loads) monitoring for the 13.0 MGD flow tier. TN and TP annual load monitoring requirements are added to the 10.5 MGD in this permit cycle. See Special Condition A. (2.) See in the Figure 3, the total phosphorus loading and the total nitrogen loading trends in the last permit cycle. Figure 3. Total Nitrogen and Total Phosphorus Annual Loading Summary from 1994 to 2021 400,000 0 'a "' -- 300,000 Z 200,000 100,000 3 0 80,000 • 60,000 o o_ d 40,000 '0 • 20,000 o c Q `o � z a > 2 0 12 10 8 6 4 0 NC0026573-001 - Catawba River Pollution Control Facility Out -fall Name: Effluent to the Catawba River -- Outliers Removed: i iumullmrlllllll iiilliiuiihhll'i i i 1 [1 11 11 11 11 II II II II oiORoio,h �Ob oi01 oio'm oio'O 000 00� OOti OO"� 001%OOh OOro 001 OO�OOA 010011 O1v01� O1PO1y 0.�� 0�10.�0 01A O,t00 Page 11 of 18 25 20 15 10 5 6 5 4 3 2 6-5 6-0 5-5 5-0 4-5 4-0 3-5 30 • Annual Mean N Loading ▪ Annual Median N Loading • Mean Nitrogen (mg/L) • Annual Mean P Loading ▪ Annual Median P Loading Mean Phosphorus (mg/L) N Months no Flow Data N Months no Nitrogen Data N Months no Phosphorus Data —Median Flow (MGD) —Mean Flow (MGD) Other WQBEL Considerations If applicable, describe any other parameters of concern evaluated for WQBELs: NA. The Facility submitted a chemical addendum with no additional pollutants to report. A PFAS monitoring Special Condition is added to the permit based on the absence of data for this group of pollutants, significant industrial users (SIUs) discharges, and the receiving water stream classification, W S-Iv. If applicable, describe any special actions (HQW or ORW) this receiving stream and classification shall comply with in order to protect the designated waterbody: NA. If applicable, describe any compliance schedules proposed for this permit renewal in accordance with 15A NCAC 2H.0107(c)(2)(B), 40CFR 122.47, and EPA May 2007 Memo: A 3-year schedule of compliance for copper was added to the permit. If applicable, describe any water quality standards variances proposed in accordance with NCGS 143- 215.3(e) and 15A NCAC 2B. 0226 for this permit renewal: NA 7. Technology -Based Effluent Limitations (TBELs) Municipals (if not applicable, delete and skip to Industrials) Are concentration limits in the permit at least as stringent as secondary treatment requirements (30 mg/l BOD5/TSS for Monthly Average, and 45 mg/l for BOD5/TSS for Weekly Average). YES If NO, provide a justification for alternative limitations (e.g., waste stabilization pond). NA Are 85% removal requirements for BOD5/TSS included in the permit? YES If NO, provide a justification (e.g., waste stabilization pond). NA 8. Antidegradation Review (New/Expanding Discharge) The objective of an antidegradation review is to ensure that a new or increased pollutant loading will not degrade water quality. Permitting actions for new or expanding discharges require an antidegradation review in accordance with 15A NCAC 2B.0201. Each applicant for a new/expanding NPDES permit must document an effort to consider non -discharge alternatives per 15A NCAC 2H.0105(c)(2). In all cases, existing instream water uses and the level of water quality necessary to protect the existing use is maintained and protected. If applicable, describe the results of the antidegradation review, including the Engineering Alternatives Analysis (EAA) and any water quality modeling results: NA 9. Antibacksliding Review Sections 402(o)(2) and 303(d)(4) of the CWA and federal regulations at 40 CFR 122.44(1) prohibit backsliding of effluent limitations in NPDES permits. These provisions require effluent limitations in a reissued permit to be as stringent as those in the previous permit, with some exceptions where limitations may be relaxed (e.g., based on new information, increases in production may warrant less stringent TBEL limits, or WQBELs may be less stringent based on updated RPA or dilution). Are any effluent limitations less stringent than previous permit (YES/NO): NO If YES, confirm that antibacksliding provisions are not violated: NA Page 12 of 18 10. Monitoring Requirements Monitoring frequencies for NPDES permitting are established in accordance with the following regulations and guidance: 1) State Regulation for Surface Water Monitoring, 15A NCAC 2B.0500; 2) NPDES Guidance, Monitoring Frequency for Toxic Substances (7/15/2010 Memo); 3) NPDES Guidance, Reduced Monitoring Frequencies for Facilities with Superior Compliance (10/22/2012 Memo); 4) Best Professional Judgement (BPJ). Per US EPA (Interim Guidance, 1996), monitoring requirements are not considered effluent limitations under Section 402(o) of the Clean Water Act, and therefore anti - backsliding prohibitions would not be triggered by reductions in monitoring frequencies. For instream monitoring, refer to Section 4. The Division will maintain the effluent monitoring frequency requirements as the previous permit in compliance with the monitoring frequencies set for Facilities Class IV described on 15A NCAC 2B .0500. 11. Electronic Reporting Requirements The US EPA NPDES Electronic Reporting Rule was finalized on December 21, 2015. Effective December 21, 2016, NPDES regulated facilities are required to submit Discharge Monitoring Reports (DMRs) electronically. While NPDES regulated facilities would initially be required to submit additional NPDES reports electronically effective December 21, 2020, EPA extended this deadline from December 21, 2020, to December 21, 2025. The current compliance date, effective January 4, 2021, was extended as a final regulation change published in the November 2, 2020, Federal Register. This permit contains the requirements for electronic reporting, consistent with Federal requirements. 12.Summary of Proposed Permitting Actions Table 7. Current Permit Conditions and Proposed Changes for 8.0 MGD, 10.5 MGD, and 13.0 MGD Parameter Current Permit Proposed Change Basis for Condition/Change Flow 8.0 / 10.5 / 13.0 MGD No changes 15A NCAC 2B .0505 Total Monthly Flow (TMF) None Added TMF requirement for 13.0 MGD -Monitor and report continuously For calculation of T.N. and T.P. Loads BOD5 For 8.0 MGD MA 30.0 mg/1 WA 45.0 mg/1 For 10.5 MGD MA 18.5 mg/1 WA 27.8 mg/1 For 13.0 MGD MA 15.0 mg/1 WA 22.5 mg/1 No changes TBEL. Secondary treatment standards/40 CFR 133 / 15A NCAC 2B .0406. TSS MA 30 mg/1 WA 45 mg/1 For 8.0 / 10.5 / 13.0 MGD (All Flows) No changes TBEL. Secondary treatment standards/40 CFR 133 / 15A NCAC 2B .0406. NH3-N For 8.0 MGD MA 16.0 mg/1 WA 35.0 mg/1 For 8.0 MGD MA 8.4 mg/1 WA 25.3 mg/1 WQBEL based on WLA calculations for 8.0, 10.5, and 13.0 MGD Page 13 of 18 For 10.5 MGD (S) MA 6.6 mg/1 WA 19.8 mg/1 (W)MA 13.3mg/1 WA 35.0 mg/1. For 13.0 MGD (S) MA 5.6 mg/1 WA 16.8 mg/1 (W) MA 11.0 mg/1 WA 33.0 mg/1. No changes for 10.5 MGD and 13.0 MGD 15A NCAC 2B .0500 — Surface Water Monitoring: Reporting Fecal coliform (Geometric Mean) MA 200 /100m1 WA 400 /100m1 for All flows No changes WQBEL. State WQ standard, 15A NCAC 2B .0200. pH 6 — 9 SU. for All Flows No changes WQBEL. State WQ standard, 15A NCAC 2B .0200 DO Not less than 5 mg/1 for effluent and instream for All Flows** at Variable Monitoring Frequency*** No changes WQBEL. State WQ standard, 15A NCAC 2B .0200, 15A NCAC 2B.0500 TRC DM 28.0 µg/1 for All Flows No changes WQBEL. Maximum daily limit to protect acute toxicity Temperature Monitor and report daily for effluent and instream for All Flows at Variable Monitoring Frequency*** No changes 15A NCAC 2B.0200 and 15A NCAC 2B.0500 Conductivity For All Flow: Monitor and report daily for effluent and instream at Variable Monitoring Frequency*** No changes The facility has industrial dischargers and pretreatment program 15A NCAC 2B.0500 Hardness None Added Quarterly monitoring upstream and in effluent for All Flows Hardness -dependent dissolved metals water quality standards approved in 2016; facility with pretreatment program Antimony None Added Quarterly monitoring in effluent for All Flows Based on the Reasonable Potential Analysis, reasonable potential (RP) exists. Limited dataset. Predicted Max > Allowable Concentration (Cw). Add quarterly monitoring. The Method with lowest PQL must be used Total Copper Quarterly monitoring for 8.0 MGD, 10.5 MGD, and 13.0 MGD Updated to monthly monitoring for All Flows monitoring and Based on the Reasonable Potential Analysis, RP exists. Add monthly monitoring and limit Page 14 of 18 added limits as follows: For 8.0 MGD DM 96.1 ug/1 MA 85.9 ug/1 For 10.5 MGD DM 76.8 ug/1 MA 68.0 ug/1 For 13.0 MGD DM 64.9 ug/1 MA 57.0 ug/1 A 3-year compliance schedule for copper was added to the permit to provide an opportunity for the City to develop a plan to assess sources of copper to come in compliance with the limit in Section A. (1) Total Silver None Added monthly effluent monitoring in for All Flows Based on the Reasonable Potential Analysis: Predicted Max > Allowable Cw, 4 values > allowable Cw. Add monthly monitoring. Method with lowest PQL must be used Total Phosphorus (TP) For 8.0 and 10.5 MGD - Monitor and report monthly For 13.0 MGD - Monitor and report weekly No changes 15A NCAC 2B .0500 — Surface Water Monitoring and Reporting. TP Load For 13.0 MGD - Monitor and report annually (as lb/yr) Annual TP mass limit of 33,200 lb/yr For 13.0 MGD continue monitoring and reporting requirement. annual TP load limit remains the same For 10.0 MGD added annual TP monitoring and reporting requirement. Mass load limits were calculated in 2009 based on the Point Source Action Plan, using the 2007-2009 average discharge flows and nutrient concentrations. Total Nitrogen (TN) For 8.0 and 10.5 MGD - Monitor and report monthly For 13.0 MGD - Monitor and report weekly No changes 15A NCAC 2B .0500 — Surface Water Monitoring and Reporting. TN Load For 13.0 MGD - Monitor and report annually (as lb/yr) For 13.0 MGD continue monitoring and reporting requirement. Mass load limits were calculated in 2009, using the 2007-2010 average discharge flows, nutrient concentrations. Page 15 of 18 Annual TN mass limit of 146,659 lb/yr annual TN load limit remains the same For 10.0 MGD added annual TN monitoring and reporting requirement. Total Kjeldahl Nitrogen (TKN) Weekly monitoring for 13.0 MGD No changes TN monitoring Nitrite and Nitrate ( NO2 + NO3) Weekly monitoring for 13.0 MGD No changes TN monitoring PFAS None Added PFAS quarterly monitoring requirement with delayed implementation Facility discharges to WS-IV waters and has an active Pretreatment Program Toxicity Test Chronic limit, 9.0% for 8.0MGD, 12.0 % for 10.5 MGD 15.0 % for 13.0 MGD Updated Chronic limit for 8.0 MGD and 13.0 MGD, 9.5% for 8.0 MGD, 12.0 % for 10.5 MGD 14.5 % for 13.0 MGD WQBEL. No toxics in toxic amounts. 15A NCAC 2B.0200 and 15A NCAC 2B.0500 Updated according to RPA results and Aquatic Toxicity Branch input. Effluent Pollutant Scan Three times per permit cycle for All flows Next three scans must be performed in each of the following years: 2024, 2025, and 2026 40 CFR parts 423 and 122 Mercury Minimization Plan (MMP) MMP for All Flows No changes Consistent with EPA approved 2012 Statewide Mercury TMDL Implementation. Electronic Reporting Electronic reporting special condition for All Flows Added language for new electronic reporting deadline December 21, 2025 In accordance with EPA Electronic Reporting Rule 2015 and Rule - Phase 2 Extension * MA - Monthly Average, WA — Weekly Average, DM — Daily Max. **All Flows = 8.0, 10.5, and 13.0 MGD *** Variable monitoring frequency is defined as follows: samples collected three times per week during June 1 through September 30 and once per week October 1 through May 31. 13. Public Notice Schedule Permit to Public Notice: October 28, 2021 (First) and June 16, 2022 (Second) Per 15A NCAC 2H .0109 & .0111, The Division will receive comments for a period of 30 days following the publication date of the public notice. Any request for a public hearing shall be submitted to the Director within the 30 days comment period indicating the interest of the party filing such request and the reasons why a hearing is warranted. Page 16 of 18 14. NPDES Division Contact If you have any questions regarding any of the above information or on the attached permit, please contact Diana Yitbarek at (919) 707-9130 or via email at diana.yitbarek@@ncdenr.gov. 15. Fact Sheet Addendum Were there any changes made since the Draft Permit was public noticed (Yes/No): Yes. The Division received comments from the Southern Environmental Law Center (SELC) and the Catawba Riverkeeper Foundation on July 22, 2022, by Alyson Merlin (See full comments and responses in fact sheet attachments). Below is the list of permit changes after the draft permit was public noticed on June 14, 2022: • The PFAS monitoring requirement was revised from 2/year to quarterly. • Upon review of the most recent silver monitoring data, all the values were less than detect after September 2019; however, to collect additional representative data, DEQ is increasing monitoring frequency from quarterly to monthly Below is the list of permit changes after the draft permit was public noticed on October 26, 2021: • The permit expiration date was modified to February 26, 2027. Accordingly, the specified years for the Effluent Pollutant Scans have been adjusted (2024, 2025, 2026). See Special Condition A. (6.). • The authorization language in the Supplement to Permit Cover Sheet and Special Condition A. (1.) and A. (2.) was updated to modify the requirements before the Facility is authorized to transition from the 8.0 MGD flow tier into the 10.5 MGD flow tier. This change was made to require an upgrade of the Facility to meet the final limits for the 10.5 MGD effluent limitation page. • Based on our review of the nutrient information, the proposed nutrients limits (Total Nitrogen (TN) and Total Phosphorous (TP)) have been removed from the 10.5 MGD flow tier limitation page; as well as monitoring requirements for Total Kjeldahl Nitrogen and Nitrite and Nitrate. TN and TP annual load monitoring requirements for 10.5 MGD are added. [See Special Condition A. (2.).] The limits for the 13.0 MGD flow tier page have been maintained at your request with the same limits that was originally public noticed. The 13.0 MGD flow tier may not be used for an extended period of time from your information, it is not appropriate to change the existing 13.0 MGD limits. When the original NPDES permit was issued a review of the 13.0 MGD flow tier was conducted and approved, so this flow tier will be maintained. • The monitoring frequency for copper was corrected from quarterly to monthly. See Special Condition A. (1.), A. (2.), and A. (3.) • The weekly average limit for BODS for the 10.5 MGD flow tier was corrected from 45.0 to 27.8 mg/1. Page 17 of 18 • The reasonable potential analysis (RPA) was corrected to replace the outstanding resource water (ORW) stream classification in the original draft with the correct classification as WS-IV and CA. This correction updates the calculated water quality standard (WQS) values and the RPA results: o The limit for copper was updated for all flow tiers. See Special Condition A. (1.), A. (2.), and A. (3.). Special Condition A. (9.) was updated to include a notation for the Permittee with the option to request the removal of the Copper Schedule of Compliance. o The monitoring requirement for zinc for 10.5 and 13.0 MGD was removed. See Special Condition A. (2.), and A. (3.). o The monitoring requirement for selenium for 13.0 MGD was removed. See Special Condition A. (3.). • Special Condition A. (6.) was also updated to include language about the additional toxicity sampling. Samples must represent seasonal variation. 16. Fact Sheet Attachments: 1. RPA Sheets Summary for 8.0, 10.5, and 13.0 MGD. Each sheet contains: input information tab, data analyzed tab, results summary tab, and dissolve to total metals calculation tab. 2. BOD and TSS Removal Rate calculations 3. NH3/TRC/Fecal Waste Load Allocation (WLA) Spreadsheet for 8.0, 10.5, and 13.0 MGD 4. Mercury TMDL Calculations for 8.0, 10.5, and 13.0 MGD 5. Toxicity Summary/WET testing 6. Pretreatment (PT) Summary and Pollutants of Concern (POC) Review Form 7. Renewal Application Addendums Signed Effluent Pollutant Scans Addendum Form 2A Mercury Minimization Plan (MMP) summary Chemical Addendum 8. NPDES Implementation of Instream Dissolved Metals Standards — Freshwater Standards 9. Compliance Inspection Report (August 2020) 10. Correspondence 11. 2018 Aluminum Criteria Fact Sheet 12. Public Comments and Responses 13. Public Water Supply Memo 14. Nutrient Load Limit Calculations 15. Affidavits (October 2021 and June 2022) Page 18 of 18 tal Translators /95% Confidence U 95% Probabilit Freshwate MAXIMUM DATA POINTS = 58 REQUIRED DATA ENTRY Table 2. Parameters of Concern Table 1. Project Information U O U E CHECK IF HQW OR ORW WQS J O) 7 J O) 7 J O) 7 J O) 7 J 3) E J O) 7 J O) 7 J O) 7 J O) 1 J O) 1 J O 7 J O 7 J O 7 J O 7 J_ a) C J O) 3 J O) 1 J O) 1 J O) 7 J O) 7 J O) 7 J O) 1 J O) 1 J O) 1 J O) 1 O Ln O o cm N/A LO (.0 co W M (Ni 942.9357 CO Q Z 10.9774 N N 79.8603 349.7004 Q Z M LO O N CO O 131.1482 Li_iM 2 >> Li_ >> Li_ > > Q Q Li_Li_Li_ >> Li_ Li_Li_ >> Li_ Li_> > Li_> > >> Li_ Li_Li_> > > > > > > > in 0.6088 0 N— 300 W co CO 00 N N— Q Z 8.1675 in 1,800 3.0835 (r) 38.5728 25.0000 in CO O O 131.3069 co Lb o 0 0 z z z z z z z z z z z z z z z z z z z z z z z Aquactic Life Human Health Water Supply Aquatic Life Aquatic Life Water Supply Water Supply Aquatic Life Aquatic Life Aquatic Life Aquatic Life Aquatic Life Aquatic Life Aquatic Life Aquatic Life Aquatic Life Water Supply Aquatic Life Water Supply Aquatic Life Aquatic Life Aquatic Life Water Supply Water Supply Water Supply Water Supply U a) N Q Arsenic E 2 l) Cadmium Chlorides Chlorinated Phenolic Compounds Total Phenolic Compounds EN E O t 0 Chromium VI Chromium, Total Copper Cyanide U j — Lead Mercury Molybdenum Nickel Nickel E C a) N U) > = C N Aluminum c-c E U C Q a) Q t N E 0 Methyl Bromide N M W CD N. CO W 0 N M V 0 O N CO W 0 N M et lfl O O O O O O O O N N N N N N f6 f6 f6 f6 f6 f6 f6 f6 f6 f6 f6 f6 f6 f6 f6 f6 f6 f6 f6 f6 f6 f6 f6 f6 f6 a a a a a a a a a a a a a a a a a a a a a a a a a Catawba River Pollution Control Facility NC0026573 0 O 0 O co Rhodhiss Lake (Catawba River) 0 O 0 0 Facility Name WWTPIWTP Class NPDES Permit Flow, Qw (MGD) Receiving Stream HUC Number Stream Class Apply WS Hardness WQC Eirri O 0 0 W O O O O O co O N 0) V! w in c,) u w 3 u w .... O • O N u O 36.23 mg/L (Avg) J rn E 0 N J rn E co Cd Effluent Hardness Combined Hardness Acute 2 `O a) `— aa ( U Q) U J C as (V N 0 N O co U O 0 .O i O_ 0 O a) o 2 Z a) L 0 co co 0 0 J U U > L a) E a) L Q L a) E O E a) T C O E c as k p co 2§ \§ RECOMMENDED ACTION No RP, Predicted Max < 50% of Allowable Cw- No Monitoring required, other than pollutant scan (PS) Limited Dataset (n<8 samples). Predicted Max< 50% of Allowable Cw. No detects (Max PQL 20 pg/L). Predicted Max< 50% of Allowable Cw. No detects (Max PQL 2.5 pg/L) Limited Dataset (n<8 samples). Predicted Max < 50% of Allowable Cw- No Monitoring required, other than PS See Chromium, Total See Chromium, Total a: No monitoring required other than PS if all Total Chromium samples are < 5 pg/L or Pred. max for Total Cr is < allowable Cw for Cr VI. RP exists. Predicted Max> Allowable Cw, 1 values > allowable Cw-Add monthly monitoring and limit No RP, Predicted Max < 50% of Allowable Cw- No Monitoring required other than PS No RP, Predicted Max < 50% of Allowable Cw All values reported non -detect - No Monitoring required other than PS No RP, Predicted Max < 50% of Allowable Cw - No Monitoring required other than PS No RP, Predicted Max < 50% of Allowable Cw - No Monitoring required other than PS REASONABLE POTENTIAL RESULTS ri # Det. Max Pred Cw Allowable Cw Acute (FW): 2,978.0 Cbronic(FVT) 1,577.4 Max MDL=10 Chronic(Ilti): 864.8 -- Max MDL=10 Acute: 569.33 Chronic: 68.35 Max MDL=20 Acute: 29.643 Chronic: 6.403 Max MDL =2.5 Acute: NO WQS Chronic: 300.0 Max MDL=10 l .: & .: _ ;_ . \ \ !! Acute: 140.1 Chronic: 115.7 , ® ) ; 3{ ) ] ; I § o; 3 , ;: ± , ; \\, \ .! , , . I § .§ ! — ; ! , , \) \ .! } , 2 Acute: 699.486 Chronic:---- 32.427 -- MaxMDL=10 Acute: NO WQS Chronic: 1,682.E No value> Allowable Cw _II & i; 4 3 . ;@ !; ' (' ( \ \j\A ) !) V g , 4,o 2 J ( \ 2 30.00 C.V. (default) NO DETECTS ) ( \ 2 31.0 C.V. (default) NO DETECTS § / . ° , ` ( ( \ 2 ® 3 0 Note: n <9 Limited data set 1 0 Note: n<9 Limited data set ^ ) ) ) ) : \ \ { { ) { \ \ o NC STANDARDS OR EPA CRITERIA ) i) f) ) 150 FW(7010s) 340 10 HH/WS(Qavg) ` \ { ® , \ { ) ) » F.,` 121.8368 FW(7Q10s) 942.9357 11 FW(7Q10s) 16 8.1675 FW(7Q10s) 10.9774 Pi) \ { } / , \ ; - 38.5728 FW(7Q10s) 349.7004 25.0000 WS(7Q10s) E 0 o 2 2 2 2 2 2 2 2 2 2 2 2 PARAMETER Arsenic Arsenic E et tFn _7. Chromium III Chromium VI Chromium, Total Copper ! Molybdenum \ \ No RP, Predicted Max < 50% of Allowable Cw - No Monitoring required other than PS Predicted Max > Allowable Cw, 4 values > allowable Cw - Add quarterly monitoring. Method with lowest PQL must be used No RP, Predicted Max < 50% of Allowable Cw - No Monitoring required other than PS RP exists. Predicted Max> 50% Allowable Cw - Add monthly monitoring Limited dataset. Predicted Max> Allowable Cw- Add quarterly monitoring. Method with lowest PQL must be used No RP, Predicted Max < 50% of Allowable Cw - No Monitoring required other than PS No RP, Predicted Max < 50% of Allowable Cw - No Monitoring required other than PS 1 1 i i.o 3 a A z 1 1 B i a .. i ,O ^ .. 00 3 a .o A z Acute: NO WQS Chronic: 3996.129 No value> Allowable Cw Acute: NO WQS Chronic: 58.89032 No value> Allowable Cw Acute: NO WQS Chronic: 21032.25806 No value> Allowable Cw Acute: NO WQS Chronic: 1051.61290 No value> Allowable Cw 0.6 78.00000 C.V. (dciault) 16.29000 C.V. (default) 16.47000 C.V. (default) 3 2 Note: n<9 Limited data set 3 1 Note: n<9 Limited data set 3 1 Note: n<9 Limited data set t a i . t FW(7Q10s) 56 gl a w o 131.3069 FW(7Q10s) 131.1482 380 WS(7Q10s) a 3 , 0 a 3 N 0 a 3 o U Z U Z U Z U Z z U Z 2 Z N N N E E Q E Q E 0 Methyl Bromide REASONABLE POTENTIAL ANALYSIS H1 Effluent Hardness Use "PASTE SPECIAL. Values" then "COPY" . Maximum data points = 58 Date Data BDL=1/2DL Results 1 7/14/2016 34.10 34.1 Std Dev. 14.3197 2 10/26/2017 51.50 51.5 Mean 36.2333 3 4/19/2018 23.10 23.1 C.V. (default) 0.6000 4 n 3 5 10th Per value 25.30 mg/L 6 Average Value 36.23 mg/L 7 Max. Value 51.50 mg/L 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 H2 Upstream Hardness Use "PASTE SPECIAL. Values" then "COPY" . Maximum data points = 58 Date Data BDL=1/2DL Results 1 25.00 25 Std Dev. N/A 2 Mean 25.0000 3 C.V. 0.0000 4 n 1 5 10th Per value 25.00 mg/L 6 Average Value 25.00 mg/L 7 Max. Value 25.00 mg/L 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 -4- 26573 RPA 8.0.xlsm, data 7/28/2022 REASONABLE POTENTIAL ANALYSIS Par01 & Par02 Arsenic Date Data BDL=1/2DL Results 1 5/18/2017 < 10 5 Std Dev. 2 7/11/2017 < 10 5 Mean 3 10/5/2017 < 10 5 C.V. 4 1/25/2018 < 1 0.5 n 5 4/19/2018 < 10 5 6 7/19/2018 < 10 5 MultFactor= 7 10/9/2018 < 10 5 Max. Value 8 1/29/2019 < 10 5 Max. Pred Cw 9 4/11/2019 < 10 5 10 7/15/2019 < 10 5 11 9/24/2019 < 10 5 12 10/15/2019 < 10 5 13 11/13/2019 < 10 5 14 12/10/2019 < 10 5 15 1/9/2020 < 10 5 16 2/21/2020 < 10 5 17 3/17/2020 < 10 5 18 4/21/2020 < 10 5 19 5/19/2020 < 10 5 20 6/15/2020 < 10 5 21 7/7/2020 < 10 5 22 8/12/2020 < 10 5 23 10/14/2020 < 10 5 24 1/12/2021 < 1 0.5 25 4/20/2021 < 2.5 1.25 26 7/20/2021 < 1 0.5 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 Use "PASTE SPECIAL. Values" then "COPY" . Maximum data points = 58 Par03 Beryllium 1.5921 4.3365 0.3671 26 1.16 5.0 ug/L 5.8 ug/L Date Data BDL=1/2DL Results Use "PASTE SPECIAL. Values" then "COPY" . Maximum data points = 58 1 7/14/2016 < 20 10 Std Dev. 5.4848 2 10/26/2017 < 20 10 Mean 6.8333 3 4/21/2018 < 1 0.5 C.V. (default) 0.6000 4 n 3 5 6 Mult Factor = 3.00 7 Max. Value 10.00 ug/L 8 Max. Pred Cw 30.00 ug/L 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 -5- 26573 RPA 8.0.xlsm, data 7/28/2022 REASONABLE POTENTIAL ANALYSIS Par04 Cadmium Date Data BDL=1/2DL Results 1 1/12/2016 < 0.2 0.1 Std Dev. 2 4/7/2016 < 0.2 0.1 Mean 3 5/18/2017 < 0.2 0.1 C.V. 4 7/11/2017 < 0.2 0.1 n 5 10/5/2017 < 0.2 0.1 6 1/25/2018 < 0.2 0.1 MultFactor= 7 4/19/2018 < 0.2 0.1 Max. Value 8 7/19/2018 < 0.2 0.1 Max. Pred Cw 9 10/9/2018 < 0.2 0.1 10 1/29/2019 < 0.2 0.1 11 4/11/2019 < 0.2 0.1 12 7/15/2019 < 0.2 0.1 13 9/24/2019 < 0.2 0.1 14 10/15/2019 < 0.2 0.1 15 11/13/2019 < 0.2 0.1 16 12/10/2019 < 0.2 0.1 17 1/9/2020 < 0.2 0.1 18 2/21/2020 < 0.2 0.1 19 3/17/2020 < 0.2 0.1 20 4/21/2020 < 0.2 0.1 21 5/19/2020 < 0.2 0.1 22 6/15/2020 < 0.2 0.1 23 7/7/2020 < 0.2 0.1 24 8/12/2020 < 0.2 0.1 25 10/14/2020 < 0.2 0.1 26 1/12/2021 < 1 0.5 27 4/20/2021 < 2.5 1.25 28 7/20/2021 < 1 0.5 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 Use "PASTE SPECIAL. Values" then "COPY" . Maximum data points = 58 Par07 Total Phenolic Compounds 0.2362 0.1696 1.3925 28 1.47 1.250 ug/L 1.838 ug/L Date Data 7/14/2016 < 10/26/2017 < 4/21/2018 < BDL=1/2DL Results 1 0.5 Std Dev. 10 5 Mean 10 5 C.V. (default) n Mult Factor = Max. Value Max. Pred Cw Use "PASTE SPECIAL. Values" then "COPY" . Maximum data points = 58 2.5981 3.5000 0.6000 3 6.20 5.0 ug/L 31.0 ug/L -6- 26573 RPA 8.0.xlsm, data 7/28/2022 REASONABLE POTENTIAL ANALYSIS Par10 Chromium, Total Date Data BDL=1/2DL Results 7/14/2016 1 1 Std Dev. 5/18/2017 < 1 0.5 Mean 7/11/2017 < 1 0.5 C.V. 10/5/2017 2 2 n 1/25/2018 < 1 0.5 4/19/2018 < 1 0.5 MultFactor= 7/19/2018 < 1 0.5 Max. Value 10/9/2018 < 1 0.5 Max. Pred Cw 1/29/2019 < 1 0.5 4/11/2019 < 1 0.5 7/15/2019 < 1 0.5 10/15/2019 < 1 0.5 11/13/2019 < 1 0.5 12/10/2019 < 1 0.5 1/9/2020 < 1 0.5 2/21/2020 < 1 0.5 3/17/2020 < 1 0.5 4/21/2020 < 1 0.5 5/19/2020 < 1 0.5 6/15/2020 < 1 0.5 7/7/2020 < 1 0.5 8/12/2020 1 1 10/14/2020 < 1 0.5 1/12/2021 1.37 1.37 4/20/2021 2.5 2.5 7/20/2021 < 1 0.5 Use "PASTE SPECIAL. Values" then "COPY" . Maximum data points = 58 Pall Copper 0.5059 0.7065 0.7160 26 1.30 2.5 pg/L 3.3 pg/L Date Data BDL=1/2DL Results 1 1/12/2016 12 12 Std Dev. 2 4/7/2016 14 14 Mean 3 6/2/2016 16 16 C.V. 4 7/14/2016 12 12 n 5 10/6/2016 26 26 6 1/12/2017 < 1 0.5 MultFactor = 7 4/11/2017 13 13 Max. Value 8 5/18/2017 < 1 0.5 Max. Pred Cw 9 7/11/2017 26 26 10 10/5/2017 281 281 11 10/26/2017 10 10 12 1/25/2018 < 1 0.5 13 4/19/2018 < 1 0.5 14 7/19/2018 < 1 0.5 15 10/9/2018 68 68 16 1/29/2019 8 8 17 4/11/2019 6 6 18 7/15/2019 47 47 19 9/24/2019 2 2 20 10/15/2019 10 10 21 11/13/2019 10 10 22 12/10/2019 6 6 23 1/9/2020 33 33 24 2/21/2020 < 1 0.5 25 3/17/2020 7 7 26 4/21/2020 14 14 27 5/19/2020 9 9 28 6/15/2020 4 4 29 7/7/2020 7 7 30 8/12/2020 6 6 31 9/21/2020 34 34 32 10/14/2020 3 3 33 1/12/2021 5.89 5.89 34 4/20/2021 18.1 18.1 35 7/20/2021 5.92 5.92 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 Use "PASTE SPECIAL. Values" then "COPY" . Maximum data points = 58 47.5550 20.4831 2.3217 35 1.41 281.00 ug/L 396.21 ug/L -7- 26573 RPA 8.0.xlsm, data 7/28/2022 REASONABLE POTENTIAL ANALYSIS Par12 Cyanide Date Data BDL=1/2DL Results 1 5/18/2017 < 5 5 Std Dev. 2 7/11/2017 5 5 Mean 3 10/5/2017 5 5 C.V. 4 1/25/2018 < 5 5 n 5 1/12/2016 < 5 5 6 2/11/2016 < 5 5 Mult Factor = 7 3/3/2016 5 5 Max. Value 8 4/7/2016 < 5 5 Max. Pred Cw 9 5/18/2017 < 5 5 10 7/11/2017 5 5 11 10/5/2017 < 5 5 12 1/25/2018 5 5 13 4/19/2018 5 5 14 7/19/2018 < 5 5 15 10/9/2018 5 5 16 1/29/2019 < 6 5 17 4/11/2019 < 5 5 18 7/15/2019 < 5 5 19 9/23/2019 < 5 5 20 10/15/2019 < 5 5 21 11/13/2019 5 5 22 1/9/2020 < 5 5 23 2/20/2020 < 5 5 24 3/17/2020 < 5 5 25 4/21/2020 5 5 26 5/18/2020 5 5 27 6/15/2020 5 5 28 7/6/2020 5 5 29 8/12/2020 5 5 30 10/14/2020 5 5 31 1/11/2021 5 5 32 4/19/2021 6 5 33 7/20/2021 < 5 5 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 Use "PASTE SPECIAL. Values" then "COPY" . Maximum data points = 58 Par14 Lead 0.0000 5.00 0.0000 33 1.00 5.0 ug/L 5.0 ug/L Date BDL=1/2DL Results 1 1/12/2016 < 10 5 Std Dev. 2 4/7/2016 < 10 5 Mean 3 5/18/2017 < 10 5 C.V. 4 7/11/2017 < 10 5 n 5 10/5/2017 < 10 5 6 1/25/2018 < 10 5 Mult Factor = 7 4/19/2018 < 10 5 Max. Value 8 7/19/2018 < 10 5 Max. Pred Cw 9 10/9/2018 < 10 5 10 1/29/2019 < 10 5 11 4/11/2019 < 10 5 12 7/15/2019 < 10 5 13 9/24/2019 < 10 5 14 10/15/2019 < 10 5 15 11/13/2019 < 10 5 16 12/10/2019 < 10 5 17 1/9/2020 < 10 5 18 2/21/2020 < 10 5 19 3/17/2020 < 10 5 20 4/21/2020 < 10 5 21 5/19/2020 < 10 5 22 6/15/2020 < 10 5 23 7/7/2020 < 10 5 24 8/12/2020 < 10 5 25 10/14/2020 < 10 5 26 1/12/2021 < 1 0.5 27 4/20/2021 < 2.5 1.25 28 7/20/2021 < 1 0.5 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 Use "PASTE SPECIAL. Values" then "COPY" . Maximum data points = 58 1.3438 4.5446 0.2957 28 1.11 5.000 ug/L 5.550 ug/L -8- 26573 RPA 8.0.xlsm, data 7/28/2022 REASONABLE POTENTIAL ANALYSIS Par16 Molybdenum Date Data BDL=1/2DL Results 1 5/18/2017 < 1 0.5 Std Dev. 2 7/11/2017 < 1 0.5 Mean 3 10/5/2017 < 1 0.5 C.V. 4 1/25/2018 < 1 0.5 n 5 4/19/2018 < 1 0.5 6 7/19/2018 < 1 0.5 MultFactor= 7 10/9/2018 < 1 0.5 Max. Value 8 1/29/2019 < 1 0.5 Max. Pred Cw 9 4/11/2019 < 1 0.5 10 7/15/2019 < 1 0.5 11 9/24/2019 < 1 0.5 12 10/15/2019 < 1 0.5 13 11/13/2019 < 1 0.5 14 12/10/2019 < 1 0.5 15 1/9/2020 < 1 0.5 16 2/21/2020 < 1 0.5 17 3/17/2020 < 1 0.5 18 4/21/2020 < 1 0.5 19 5/19/2020 < 1 0.5 20 6/15/2020 < 1 0.5 21 7/7/2020 < 1 0.5 22 8/12/2020 < 1 0.5 23 10/14/2020 < 1 0.5 24 1/12/2021 1.58 1.58 25 4/20/2021 2.91 2.91 26 7/20/2021 2.45 2.45 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 Use "PASTE SPECIAL. Values" then "COPY" . Maximum data points = 58 Par17 & Par18 Nickel Date Data BDL=1/2DL Results 0.6209 1 5/18/2017 < 1 0.5 Std Dev. 0.7092 2 7/11/2017 < 1 0.5 Mean 0.8755 3 10/5/2017 < 2 1 C.V. 26 4 1/25/2018 < 1 0.5 n 5 4/19/2018 < 1 0.5 1.36 6 7/19/2018 < 1 0.5 MultFactor= 2.9 ug/L 7 10/9/2018 < 1 0.5 Max. Value 4.0 ug/L 8 1/29/2019 < 1 0.5 Max. Pred Cw 9 4/11/2019 < 1 0.5 10 7/15/2019 < 1 0.5 11 9/24/2019 < 1 0.5 12 10/15/2019 9 9 13 11/13/2019 < 1 0.5 14 12/10/2019 < 1 0.5 15 1/9/2020 < 1 0.5 16 2/21/2020 < 1 0.5 17 3/17/2020 < 1 0.5 18 4/21/2020 < 1 0.5 19 5/19/2020 < 1 0.5 20 6/15/2020 < 1 0.5 21 7/7/2020 < 1 0.5 22 8/12/2020 < 1 0.5 23 10/14/2020 < 1 0.5 24 1/12/2021 5.89 5.89 25 4/20/2021 2.5 2.5 26 7/20/2021 1.98 1.98 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 Use"PASTE SPECIAL -Values" then "COPY". Maximum data points = 58 1.9541 1.1873 1.6458 26 1.60 9.0 pg/L 14.4 pg/L -9- 26573 RPA 8.0.xlsm, data 7/28/2022 REASONABLE POTENTIAL ANALYSIS Par19 Selenium Date Data BDL=1/2DL Results 1 5/18/2017 < 10 5 Std Dev. 2 7/11/2017 11 11 Mean 3 10/5/2017 < 10 5 C.V. 4 1/25/2018 < 10 5 n 5 4/19/2018 < 10 5 6 7/19/2018 < 10 5 Mult Factor = 7 10/9/2018 < 10 5 Max. Value 8 1/29/2019 < 10 5 Max. Pred Cw 9 4/11/2019 < 10 5 10 7/15/2019 < 10 5 11 9/24/2019 < 10 5 12 10/15/2019 < 10 5 13 11/13/2019 < 10 5 14 12/10/2019 < 10 5 15 1/9/2020 < 10 5 16 2/21/2020 < 10 5 17 3/17/2020 < 10 5 18 4/21/2020 < 10 5 19 5/19/2020 < 10 5 20 6/15/2020 < 10 5 21 7/7/2020 < 10 5 22 8/12/2020 < 10 5 23 10/14/2020 < 10 5 24 1/12/2021 1 1 25 4/20/2021 2.5 2.5 26 7/20/2021 1 1 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 Use"PASTE SPECIAL -Values then "COPY" . Maximum data points = 58 Par20 Silver 1.7143 4.8269 0.3552 26 1.15 11.0 ug/L 12.7 ug/L Date Data BDL=1/2DL Results 1 5/18/2017 < 1 0.5 Std Dev. 2 7/11/2017 < 1 0.5 Mean 3 10/5/2017 < 1 0.5 C.V. 4 11/14/2017 1 1 n 5 1/25/2018 < 1 0.5 6 4/19/2018 < 1 0.5 Mult Factor = 7 5/2/2018 1 1 Max. Value 8 7/19/2018 < 1 0.5 Max. Pred Cw 9 10/9/2018 < 1 0.5 10 1/29/2019 < 1 0.5 11 4/11/2019 < 1 0.5 12 7/15/2019 < 1 0.5 13 9/24/2019 6 6 14 10/15/2019 < 1 0.5 15 11/13/2019 < 1 0.5 16 12/10/2019 < 1 0.5 17 1/9/2020 < 1 0.5 18 2/21/2020 < 1 0.5 19 3/17/2020 < 1 0.5 20 4/21/2020 < 1 0.5 21 5/19/2020 < 1 0.5 22 6/15/2020 < 1 0.5 23 7/7/2020 < 1 0.5 24 8/12/2020 < 1 0.5 25 10/14/2020 < 1 0.5 26 1/12/2021 < 1 0.5 27 4/20/2021 < 2.5 1.25 28 7/20/2021 < 1 0.5 29 10/11/2021 < 1 0.5 30 1/10/2022 < 0.5 0.25 31 4/13/2022 < 0.5 0.25 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 Use "PASTE SPECIAL - Values" then "COPY" . Maximum data points = 58 0.9995 0.7177 1.3925 31 1.39 6.000 ug/L 8.340 ug/L -10- 26573 RPA 8.0.xlsm, data 7/28/2022 REASONABLE POTENTIAL ANALYSIS Par21 Zinc Date Data BDL=1/2DL Results 1 5/18/2017 156 156 Std Dev. 2 7/11/2017 149 149 Mean 3 10/5/2017 12 12 C.V. 4 1/25/2018 26 26 n 5 4/19/2018 < 1 0.5 6 7/19/2018 < 1 0.5 MultFactor= 7 10/9/2018 9 9 Max. Value 8 1/29/2019 14 14 Max. Pred Cw 9 4/11/2019 25 25 10 7/15/2019 13 13 11 9/24/2019 42 42 12 10/15/2019 17 17 13 11/13/2019 54 54 14 12/10/2019 10 10 15 1/9/2020 157 157 16 2/21/2020 77 77 17 3/17/2020 89 89 18 4/21/2020 38 38 19 5/19/2020 21 21 20 6/15/2020 24 24 21 7/7/2020 54 54 22 8/12/2020 16 16 23 10/14/2020 38 38 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 Use "PASTE SPECIAL. Values" then "COPY" . Maximum data points = 58 Par22 Aluminum 48.5547 45.3043 1.0717 23 1.52 157.0 ug/L 238.6 ug/L Date Data 1 7/11/2017 1010 2 1/25/2018 39 3 7/19/2018 119 4 1/29/2019 85 5 7/15/2019 423 6 9/24/2019 181 7 1/9/2020 604 8 7/7/2020 221 9 1/12/2021 160 10 7/20/2021 154 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 BDL=1/2DL Results 1010 Std Dev. 39 Mean 119 C.V. 85 n 423 181 MultFactor = 604 Max. Value 221 Max. Pred Cw 160 154 Use "PASTE SPECIAL - Values" then "COPY" . Maximum data points = 58 301.8588 299.6000 1.0075 10 2.31 1010.000000 pg/L 2333.100000 pg/L -11- 26573 RPA 8.0.xlsm, data 7/28/2022 REASONABLE POTENTIAL ANALYSIS Par23 Antimony Use "PASTE SPECIAL -Values" then "COPY" . Maximum data points = 58 Date Data BDL=1/2DL Results 1 7/14/2016 15 15 Std Dev. 10.5040 2 10/26/2017 26 26 Mean 15.3333 3 4/19/2018 < 10 5 C.V. (default) 0.6000 4 n 3 5 6 Mult Factor = 3.00 7 Max. Value 26.000000 Ng/L 8 Max. Pred Cw 78.000000 Ng/L 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 -12- 26573 RPA 8.0.xlsm, data 7/28/2022 REASONABLE POTENTIAL ANALYSIS Par24 Dimethylphthalate Date Data BDL=1/2DL Results 1 7/14/2016 5.43 5.43 Std Dev. 2 10/26/2017 < 10.3 5.15 Mean 3 4/19/2018 < 10 5 C.V. (default) 4 n 5 6 Mult Factor = 7 Max. Value 8 Max. Pred Cw 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 Use "PASTE SPECIAL - Values" then "COPY" . Maximum data points - 58 Par25 Methyl Bromide 0.2183 5.1933 0.6000 3 3.00 5.430000 pg/L 16.290000 pg/L Date Data BDL=1/2DL Results 1 7/14/2016 < 5 2.5 Std Dev. 2 10/26/2017 5.49 5.49 Mean 3 4/19/2018 < 5 2.5 C.V. (default) 4 n 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 Use "PASTE SPECIAL. Values" then "COPY" . Maximum data points = 58 1.7263 3.4967 0.6000 3 Mult Factor = 3.00 Max. Value 5.490000 pg/L Max. Pred Cw 16.470000 pg/L -13- 26573 RPA 8.0.xlsm, data 7/28/2022 Date: 7/28/2022 Dissolved to Total Metal Calculator I Facility Outfall 001 In accordance with Federal Regulations, permit limitations must be written as Total Metals per 40 CFR 122.45(c) IM d � M w 2 Q E 6 COMMENTS (identify parameters to PERCS Branch to maintain in facility's LTMP/STMP): PARAMETER M 00 CD 03 O) CO 03 CO CO Z N CO O 03 9 E E m U N 0, N E 0 I 0 U E E L U co E E t U E E t U CO M CO N L a 0. U a L TD U 00 E N Z .d. a w W W N O CO M Dissolved to Total Metal Calculator data direct! Do NOT enter an This calculator has been inserted into the RPA to calculate Total O CD O E m M tal Translators /95% Confidence U 95% Probabilit Freshwate MAXIMUM DATA POINTS = 58 REQUIRED DATA ENTRY Table 2. Parameters of Concern Table 1. Project Information E CHECK IF HQW OR ORW WQS J O) 7 J 0) 7 J O) 7 J O) 7 J ) E J O) 7 J O) 7 J O) 7 J O) 1 J O) 1 J O 7 J O 7 J O 7 J O 7 J_ a) C J O) 3 J O) 1 J O) 1 J O) 7 J O) 7 J O) 7 J O) 1 J O) 1 J O) 1 J O) 1 O N— LO O pN CO N/A LO CO a0 V (Ni 952.9963 O Q Z 11.1123 N N 81.0331 353.5552 Q Z O LO co O CO O 132.5961 L�L O i 2 >> L>L >> L>L > > Q Q L�L L�L L�L >> L>L L�L L�L >> L>L L�L > > L�L > > >> L>L L�L L�L > > > > > > > > 0 in CO O V CO O La -0 300 122.9586 Q Z 8.2460 Ln 1,800 3.1226 38.9397 25.0000 O CO O O 132.5579 o o z z z z z z z z z z z z z z z z z z z z z z z Aquactic Life Human Health Water Supply Aquatic Life Aquatic Life Water Supply Water Supply Aquatic Life Aquatic Life Aquatic Life Aquatic Life Aquatic Life Aquatic Life Aquatic Life Aquatic Life Aquatic Life Water Supply Aquatic Life Water Supply Aquatic Life Aquatic Life Aquatic Life Water Supply Water Supply Water Supply Water Supply U a) N Q Arsenic E 2 l) Cadmium Chlorides Chlorinated Phenolic Compounds Total Phenolic Compounds E - E 0 0 Chromium VI Chromium, Total Copper Cyanide N U j — Lead Mercury Molybdenum Nickel Nickel E C a) N U) > = O C N Aluminum c-c UE C Q a) a) Q _Ct N E 0 Methyl Bromide N M W CD N. CO W 0 N CO Cr LC) O N- CO W O N CO Tr 0 O O O O O O O O N N N N N N f6 f6 f6 f6 f6 f6 f6 f6 f6 f6 f6 f6 f6 f6 f6 f6 f6 f6 f6 f6 f6 f6 f6 f6 f6 0- Catawba River Pollution Control Facility NC0026573 0 0 LC) 0 Rhodhiss Lake (Catawba River) 0 O 0 0 Facility Name WWTPIWTP Class NPDES Permit Flow, Qw (MGD) Receiving Stream HUC Number Stream Class Apply WS Hardness WQC Eirri O 0 0 W O 0 O O 0 co 0 N 0) V! 4 N w 13 u w .... O • O N u O 36.23 mg/L (Avg) J 0) E N J rn E co Cfl N J rn E co Cfl N Effluent Hardness Combined Hardness Acute a) L 0 co R 0 0 J U U > L a) E a) L Q L a) E O E a) T C O E c as Outfall 001 Qw = 10.5 MGD 11 §m w / 2 — \ O 0 Q a Ct \�k in V) § E 0 Et } 2 a a. % xi . ) ro a E ce I n ca / \Qjj#0 ƒ 1HHHH \ E=44442 72 oaaaaa> $$>&\./ 7 /}3\q(.& U =\ c G 47, } 2 _ \ Effluent Hard: 0 value > 100 mg/L Effluent Hard Avg = 36.23 mg/L o NC0026573 RECOMMENDED ACTION No - RP, Predicted Max < 50% of Allowable Cw - No Monitoring required, other than pollutant scan (PS) Limited Dataset (n<8 samples). Predicted Max> 50% of Allowable Cw. No detects (Max PQL 20 pg/L). Pr- edicted Max< 50% of Allowable Cw. No detects (Max PQL 2.5 pg/L) L- imited Dataset (n<8 samples). Predicted Max < 50% of Allowable Cw - No Monitoring required, other than PS S- ee Chromium, Total S- ee Chromium, Total a: No monitoring required other than PS if all Total Chromium samples are < 5 pg/L or Pred. max for Total Cr is < allowable Cw for Cr VI. R- P exists. Predicted Max > Allowable Cw, 1 values > allowable Cw - Add monthly monitoring and limit REASONABLE POTENTIAL RESULTS it Det. Max Pred Cw Allowable Cw Acute (FW): 2,349.9 Chronic (FW) 1,237.E MaxMDL = 10 Chronic (IIII) 661.3 Max MDL = 10 i i © i7 4 i® i i i; '' i_ i° e „ ) Acute: 23.657 Chronic: 5.06E Max MDL=2.5 Acute: NO WQS Chronic: 300.0 Max MDL = 10 Acute: 6,586.7 Chronic: 1,014.5 Acute: 110.6 Chronic: 90.8 — — towable Cw Max reported value = 2.5 Acute: 76.80 Chronic: 68.03— 1 value(s) > Allowable Cw 5.8 NO DETECTS 30.00 C.V. (default) NO DETECTS 1.838 NO DETECTS 31.0 C.V. (default) NO DETECTS M 4 5 M ° z 7 J v \ _ 3 0 Note: n <9 Limited data set _ 1 0 Note: n <9 Limited data set _ ° To \ ° m m_ \ \ \ ƒ \ \ \ \ \ ,d NC STANDARDS OR EPA CRITERIA Chronic Applied Acute Standard 150 FW(7Q10s) 340 10 IIII/WS(Qavg) 6.5 FW(7Q10s) 65 0.6140 FW(7Q10s) 3.4228 cq 122.9586 FW(7Q10s) 952.9963 11 FW(7Q10s) 16 8.2460 FW(7Q10s) 11.1123 § 0 0 z z z z z z z PARAMETER Arsenic Arsenic Beryllium Cadmium Total Phenolic Compounds Chromium III Chromium VI Chromium, Total Copper N L 8 N C1 G a) y Gl c.> _ C O_ co • o u• 113 R 0 L a rn a ca co LL >, 3 LL O 0 U 0 0 a d U NC0026573 N- o RP, Predicted Max < 50% of Allowable Cw - No Monitoring required other than PS No RP, Predicted Max < 50 % of Allowable Cw. All values reported non -detect - No Monitoring required other than PS No RP, Predicted Max < 50% of Allowable Cw - No Monitoring required other than PS - --------------------------- N- o RP, Predicted Max < 50% of Allowable Cw - No Monitoring required other than PS No RP, Predicted Max < 50% of Allowable Cw - No Monitoring required other than PS Pr- edicted Max > Allowable Cw, 28 values > allowable Cw - Add monthly monitoring. Method with lowest PQL must be used No RP, Predicted Max < 50% of Allowable Cw - No Monitoring required other than PS RP exists. Predicted Max > 50% Allowable Cw - Add monthly monitoring L- imited dataset. Predicted Max > Allowable Cw- Add quarterly monitoring. Method with lowest PQL must be used N- o RP, Predicted Max < 50% of Allowable Cw - No Monitoring required other than PS N- o RP, Predicted Max < 50% of Allowable Cw - No Monitoring required other than PS Acute: 152.1 Chronic: 41.3 No value > Allowable Cw Acute: 560.062 Chronic: 25.762 -- Max MDL = 10 Acute: NO WQS - Chronic: 1,320.1 No value > Allowable Cw Acute (FW): 2,443.6 Chronic (FW): 321.3 No value > Allowable Cw _ Chronic (WS) 206.3 No value > Allowable Cw Acute: 387.0 Chronic: 41.3 No value > Allowable Cw Acute: 2.283 Chronic: 0.495 28 value(s) > Allowable Cw Acute: 916.4 - Chronic: 1,093.7 No value > Allowable Cw Acute: NO WQS Chronic: 3135.146 No value > Allowable Cw Acute: NO WQS Chronic: 46.20215 No value > Allowable Cw Acute: NO WQS Chronic: 16500.76805 No value > Allowable Cw Acute: NO WQS - Chronic: 825.03840 No value > Allowable Cw 5.550 NO DETECTS O s. O N od ,.D N O O O O M M M N 78.00000 C.V. (default) 16.29000 C.V. (default) 16.47000 C.V. (default) -_. O 00 M ,o ,o N 7 ,o M co N N M O O -� 3 2 Note: n<9 Limited data set 3 1 Note: n<9 Limited data set 3 1 Note: n<9 Limited data set aN aN a a aN aN a a O 5 FW(7Q10s) 22 3.1226 FW(7Q10s) 81.0331 0 a O ,a 38.9397 FW(7Q10s) 353.5552 25.0000 WS(7Q10s) 5 FW(7Q10s) 56 0.06 FW(7Q10s) 0.3303 132.5579 FW(7Q10s) 132.5961 0 a O 000 M 0 a `p 0 a 00 O N 0 a O 0 z 0 z 0 z 0 0 z z 0 z 0 z 0 z 0 z 0 z 0 z 0 z a a m U a a J Molybdenum a a u u Z Z £ 3 a N co N N Aluminum c £ .% Dimethylphthalate Methyl Bromide Date: 7/28/2022 Dissolved to Total Metal Calculator I Facility Outfall 001 In accordance with Federal Regulations, permit limitations must be written as Total Metals per 40 CFR 122.45(c) IM d � M w2Q E f0 = m E I0 a= $ N N Jo 3 7 N Z � O m N M COMMENTS (identify parameters to PERCS Branch to maintain in facility's LTMP/STMP): PARAMETER CD CD 06 Z O CD CD O 03 co 9 E E m U N 0, N co E 0 I a U rn E E L U O E E t U E E t U L a O U uo Lo L TD U 00 E N Z .d. a w W W O CO M O CD O CD O E m Dissolved to Total Metal Calculator data direct! Do NOT enter an This calculator has been inserted into the RPA to calculate Total tal Translators /95% Confidence U 95% Probabilit Freshwate MAXIMUM DATA POINTS = 58 REQUIRED DATA ENTRY Table 2. Parameters of Concern Table 1. Project Information E CHECK IF HQW OR ORW WQS J O) 7 J o) 7 J O) 7 J O) 7 J i) E J O) 7 J O) 7 J O) 7 J O) 1 J O) 1 J O 7 J O 7 J O 7 J O 7 J_ a) C J O) 3 J O) 1 J O) 1 J O) 7 J O) 7 J O) 7 J O) 1 J O) 1 J O) 1 J O) 1 O Ln O O M N/A in O 3.4587 962.3658 coO Q Z O CO N N N 82.1292 357.1464 Q Z CO Ln N r M CO O 133.9450 L3 L i 2 > LL > LL > Q Q � LL � LL � LL > LL � LL � LL > LL � LL > � LL > > LL � LL L�L > > > > O O 0.6189 in N—O 300 124.0154 z 8.3199 in 1,800 3.1595 39.2855 25.0000 in CO O Oco 133.7367 Lb o o 0 z z z z z z z z z z z z z z z z z z z z z z z Aquactic Life Human Health Water Supply Aquatic Life Aquatic Life Water Supply Water Supply Aquatic Life Aquatic Life Aquatic Life Aquatic Life Aquatic Life Aquatic Life Aquatic Life Aquatic Life Aquatic Life Water Supply Aquatic Life Water Supply Aquatic Life Aquatic Life Aquatic Life Water Supply Water Supply Water Supply Water Supply U a) N Q Arsenic E 2 l) Cadmium Chlorides Chlorinated Phenolic Compounds Total Phenolic Compounds EN _ E O t 0 Chromium VI Chromium, Total Copper Cyanide U o — Lead Mercury Molybdenum Nickel Nickel E o a) N U) > = o N Aluminum c-c U E C Q a) a) !Z t N E 0 Methyl Bromide N M W CD N. CO W 0 N M V 0 O N CO W 0 N M et 0 O O O O O O O O N N N N N N f6 f6 f6 f6 f6 f6 f6 f6 f6 f6 f6 f6 f6 f6 f6 f6 f6 f6 f6 f6 f6 f6 f6 f6 f6 a a a a a a a a a a a a a a a a a a a a a a a a a Catawba River Pollution Control Facility NC0026573 0 O 0 O Rhodhiss Lake (Catawba River) 0 O 0 0 Facility Name WWTPIWTP Class NPDES Permit Flow, Qw (MGD) Receiving Stream HUC Number Stream Class Apply WS Hardness WQC Eirri O 0 0 W O O O O O co O N 0) V! w in c,) u w 3 u w .... O • O N u O 36.23 mg/L (Avg) Effluent Hardness Combined Hardness Acute 2 `O a) 7 • aa ( U Q) U 0 as (V N 0 N O co U O 0 .O I` i Q 0 O r • o o 2 z a) L 0 co R 0 0 J U U > L a) E a) (6 L o_ L a) E O E a) T 0 O E c as 0 u_ 0 0 U 0 tr. 0 a G) : ■ 2 U Freshwater RPA NCOO26573 q k) ■ Effluent Hard: 0 value > 100 mg/L Effluent Hard Avg = 36.23 mg/L RECOMMENDED ACTION No RP, Predicted Max < 50% of Allowable Cw - No Monitoring required, other than pollutant scan (PS) L- imited Dataset (n<8 samples). Predicted Max> 50% of Allowable Cw. No detects (Max PQL 20 pg/L). Pr- edicted Max< 50% of Allowable Cw. No detects (Max PQL 2.5 pg/L) L- imited Dataset (n<8 samples). Predicted Max < 50% of Allowable Cw - No Monitoring required, other than PS See Chromium, Total See Chromium, Total a: No monitoring required other than PS if all Total Chromium samples are < 5 pg/L or Pred. max for Total Cr is < allowable Cw for Cr VI. R- P exists. Predicted Max > Allowable Cw, 2 values > allowable Cw - Add monthly monitoring and limit REASONABLE POTENTIAL RESULTS 11 # Det. Max Pred Cw Allowable Cw Acute (FW): 1,963.4 Chronic (FW): 1,028.4 MaxMDL= 10____ _ ___ Chronic (HH): 536.1 Max MDL = 10 Acute: 375.35 Chronic: 44.56 Max MDL = 20 Acute: 19.973 Chronic: 4.243 Max MDL=2.5 Acute: NO WQS Chronic: 300.0 Max MDL = 10 Acute: 5,557.4 Chronic: 850.3 Acute: 92.4 Chronic 75.4 towable Cw Max reported value = 2.5 Acute: 64.90 Chronic: 57.04 2 value(s) > Allowable Cw 5.8 NO DETECTS 30.00 C.V. (default) NO DETECTS 1.838 NO DETECTS 31.0 C.V. (default) NO DETECTS M z 5 M z I % v F. \ 3 0 Note: n < 9 Limited data set 1 0 Note: n < 9 Limited data set Tot Cr valu 26 6 cq &4n \ 0 0 0 0 \ \ \ 0 ,d NC STANDARDS OR EPA CRITERIA Chronic Applied Acute Standard 150 FW(7Q10s) 340 10 HH/WS(Qavg) o CZ / W 0.6189 FW(7Q10s) 3.4587 0 rn 124.0154 FW(7Q10s) 962.3658 11 FW(7Q10s) 16 8.3199 FW(7Q10s) 11.2380 w u u 0 z 0 z 0 z 0 z 0 z 0 z 0 z PARAMETER Arsenic Arsenic E ! Cadmium Total Phenolic Compounds Chromium III Chromium VI Chromium, Total Copper CN {Ci ( CNI L 0 U) LL r Tts C� G a) .N G1 _ C O co Lf) v y R 0 L 0 a L >, 3 (./ LL O L 0 U 0 O 0- CD Ids> N U NCOO26573 N- o RP, Predicted Max < 50% of Allowable Cw No Monitoring required other than PS No RP Predicted Max < 50 % of Allowable Cw. All values reported non -detect - No Monitoring required other than PS No RP, Predicted Max < 50% of Allowable Cw - No Monitoring required other than PS N- o RP, Predicted Max < 50% of Allowable Cw No Monitoring required other than PS No RP, Predicted Max < 50% of Allowable Cw - No Monitoring required other than PS Pr- edicted Max > Allowable Cw, 28 values > allowable Cw - Add quarterly monitoring. Method with lowest PQL must be used No RP, Predicted Max < 50% of Allowable Cw - No [ Monitoring required other than PS RP exists. Predicted Max > 50% Allowable Cw - Add quarterly monitoring Limited dataset. Predicted Max > Allowable Cw- Add quarterly monitoring. Method with lowest PQL must be used N- o RP, Predicted Max < 50% of Allowable Cw - No Monitoring required other than PS N- o RP, Predicted Max < 50% of Allowable Cw - No Monitoring required other than PS Acute: 127.0 Chronic: 34.3 No value > Allowable Cw Acute: 474.271 Chronic 21.662 Max MDL = 10 Acute: NO WQS Chronic 1,097.0 No value > Allowable Cw Acute (FW): 2,062.4 Chronic (FW): 269.3 No value > Allowable Cw Chronic (WS): 171.4 No value > Allowable Cw Acute: 323.4 Chronic: 34.3 No value > Allowable Cw Acute: 1.947 Chronic: 0.411 28 value(s) > Allowable Cw Acute: 773.5 Chronic: 916.9 No value > Allowable Cw Acute: NO WQS Chronic 2605.310 No value > Allowable Cw Acute: NO WQS Chronic 38.39404 No value > Allowable Cw Acute: NO WQS Chronic: 13712.15881 No value > Allowable Cw Acute: NO WQS Chronic 685.60794 No value > Allowable Cw 5.550 NO DETECTS O 7 l O N 00 D od N O O O O M M M N 78.00000 C.V. (default) 16.29000 C.V. (default) 16.47000 C.V. (default) ,o. O 00 N co ,.O N 7 ,O N 7 V N M 00 N N N O — 3 2 Note: n < 9 Limited data set 3 1 Note: n < 9 Limited data set 3 1 Note: n < 9 Limited data set a r, IN) cn c� c�r,r, a a a -a-0oi, a a a ---a) a a ---a) c� 5 FW(7Q10s) 22 3.1595 FW(7Q10s) 82.1292 160 WS(7Q10s) 39.2855 FW(7Q10s) 357.1464 25.0000 WS(7Q10s) CZ O a s 0.06 FW(7Q10s) 0.3372 133.7367 FW(7Q10s) 133.9450 380 WS(7Q10s) 5.6 WS(7Q10s) 2000 WS(7Q10s) 100 WS(7Q10s) 0 z 0 Z 0 Z 0 0 Z Z 0 Z 0 Z 0 Z 0 Z 0 Z 0 Z 0 Z Cyanide a v J Molybdenum W W u Z Z Selenium y >_ y U N E = = T o s _ a Dimethylphthalate Methyl Bromide Date: 7/28/2022 Dissolved to Total Metal Calculator 0 IL 0 0 U 0 OM a0- ] N K 0 U � Z m � w w Fa J N U 0- a LL Z In accordance with Federal Regulations, permit limitations must be written as Total Metals per 40 CFR 122.45(c) IM d � M w2Q E f0 I� N m E 0 N M COMMENTS (identify parameters to PERCS Branch to maintain in facility's LTMP/STMP): 41, O U CD O CV 03 co N"i N co 0 N co Z M co co co CO CO CNI V. Z N O W N O CO CO PARAMETER 9 E E m U E E L U E E t U E E t U L 9 a 0 U 9 TD E N Z .d. a w CD CD CD E m Dissolved to Total Metal Calculator data direct! Do NOT enter an This calculator has been inserted into the RPA to calculate Total City of Morganton/Catawba River Pollution Control Facility NC0026573 N O oo c I N oo N N to N O to oo r1 m r\ Ol oo d- m% -1 N 00 Ol LC) n n N CO CO CO to Ol 00 0 to to N to Ol o0 N lfl Ln c-I m O N m 1: 00 00 h: lfl 00 00 lfl Ln c-1 Ol oo oo 0o Ol 0o Ol Ol Ol Ol Ol Ol Ol Ol Ol Ol Ol Ol Ol Ol Ol Ol Ol Ol co November-18 December-18 01 Ol %. 1Cn Cn c-I I c-I Cn, Ol Ol ci > E f6 U i 7co c i co LL a) N October-19 November-19 December-19 January-20 February-20 0 N O O O O O O N S N N N N co c co Q- = aA aE) Q N N October-20 November-20 December-20 January-21 February-21 L -1 s U fa 2 N N to lfl O to 00 d- 00 N N N to O oo Ol 1, m c I Ln c I Ol 1, to to n N N ci O Ol O m m O 1, 00 0o Ol L -1 N Ol 1� Ol 0 % -1 Ol N % -1 O N d- m Lr) CO Lr) 00 lfl n 00 lfl n 00 m n 4 Li, 00 to n Ln lfl lfl lfl n n N to Ln 00 lfl n Ln Ol Ol Ol 01 01 01 01 01 00 01 Ol N 01 01 01 01 01 01 01 01 01 to 01 00 00 al Ol Ol 00 00 to lfl `1 to to to r1 N ID co.,. 00 c = E a a) October-16 November-16 December-16 January-17 February-17 N n L-1 r, N N CO .� co o E co Q- 7 an a) 2 Q 2 a Q a) V) October-17 November-17 December-17 January-18 February-18 00 oo CO00 00 00 00 c-I 00 c-I s l - -0 a) cococ Eon a) o 2 Qco 2 Q a a, o V) Overall TSS removal rate N O E a) c O E 0 m V 0 cc cc t C 0 2 0 O N (11 d' 0 00 00 r1 N m oo r1 m to c 1 m to m. 1 m rn Lo LO r1 0o Ol LD �) m if) m N o ci O o L -1 c-I 1� lfl 00 o N c-I O . . . . . . . . . . . . . . . . . . . . . . . . 4 4 to o m to to r1 00 0o rn rn o0 00 0o m o0 00 00 00 0o a o0 r o rn o0 00 0o rn oo rn rn rn rn rn rn rn rn rn rn rn rn rn rn rn rn rn rn rn November-18 December-18 Ol 01 Ol c�-I Ol Ol Ol ci 1 N f6 > 7 i i co C 0 E 7 coo Q , -,a —, °_ < a) rn V) October-19 November-19 December-19 January-20 February-20 0 N 0 0 0 0 0 0 N N N N ID 5 c'o c —'' E co Q- = ago a) Q Q a a) October-20 November-20 December-20 January-21 February-21 L -1 N t U fa 2 L -1 N Q lfl N Ol N 0 d' 00 Ol c -1 L -1 1, O d- 0o N c-I <0 Ol O 00 00 o0 o0 o0 o0 o0 oo a o0 Ol Ol Ol Ol Ol Ol Ol Ol oo Ol Q a) October-16 November-16 December-16 January-17 February-17 CO CO CO CO N L.f) N L.f) O Ol to m lfl 0 Cr %-1 %-1 N Ol c-I Ol m m 1� o Ln oo 0o 0o r1 00 m to 0 Ln Ln N 00 00 00 1: lfl n Ol Ln L.f) Ol Ol Ol Ol Ol Ol Ol Ol Ol N Ol 0o Ol Ol Ol Ol Ol Ol N00 c0 00 N N 00 I� ci c-I Op 00 0 a) '� E co U '� > E co Q f 6 °° No a) Q `° °A Q a) p o Li Q a) October-18 Overall CBOD removal rate NH3/TRC WLA Calculations Facility: City of Morganton/Catawba River Pollution Control Facility PermitNo. NC0026573 Prepared By: Diana Yitbarek Enter Design Flow (MGD): 8 Enter s7Q10 (cfs): 118 Enter w7Q10 (cfs): 118 Total Residual Chlorine (TRC) Daily Maximum Limit (ug/I) s7Q10 (CFS) DESIGN FLOW (MGD) DESIGN FLOW (CFS) STREAM STD (UG/L) Upstream Bkgd (ug/I) IWC (%) Allowable Conc. (ug/l) Less stringent than current permit limit. Maintain limit at 28 ug/I to protect for acute toxicity. Fecal Coliform Monthly Average Limit: (If DF >331; Monitor) (If DF<331; Limit) Dilution Factor (DF) Maintain 200/100 ml MA limit Ammonia (Summer) Monthly Average Limit (mg NH3-N/I) 118 s7Q10 (CFS) 8 DESIGN FLOW (MGD) 12.4 DESIGN FLOW (CFS) 17.0 STREAM STD (MG/L) 0 Upstream Bkgd (mg/I) 9.51 IWC (%) 179 Allowable Conc. (mg/I) Current year-round MA limit 16.0 mg/I based on the 1994 water quality model. 2021 Update: MA summer limit, 8.4 mg/I WA summer conc., mg/I Ammonia (Winter) Monthly Average Limit (mg NH3-N/I) w7Q10 (CFS) 200/100m1 DESIGN FLOW (MGD) DESIGN FLOW (CFS) STREAM STD (MG/L) 10.52 Upstream Bkgd (mg/I) IWC (%) Allowable Conc. (mg/I) 2021 Update: MA winter limit, 16.8 mg/I Total Residual Chlorine 1. Cap Daily Max limit at 28 ug/1 to protect for acute toxicity WA summer conc., mg/I Ammonia (as NH3-N) 1. If Allowable Conc > 35 mg/I, Monitor Only 2. Monthly Avg limit x 3 = Weekly Avg limit (Municipals) 3. Monthly Avg limit x 5 = Daily Max limit (Non-Munis) If the allowable ammonia concentration is > 35 mg/L, no limit shall be imposed 118 8 12.4 1.0 0.22 9.51 8.4 118 8 12.4 1.8 0.22 9.51 16.8 Fecal Coliform 1. Monthly Avg limit x 2 = 400/100 ml = Weekly Avg limit (Municipals) = Daily Max limit (Non -Muni) NH3/TRC WLA Calculations Facility: City of Morganton/Catawba River Pollution Control Facility PermitNo. NC0026573 Prepared By: Diana Yitbarek Enter Design Flow (MGD): Enter s7Q10 (cfs): Enter w7Q10 (cfs): 10.5 118 118 Total Residual Chlorine (TRC) Daily Maximum Limit (ug/I) s7Q10 (CFS) DESIGN FLOW (MGD) DESIGN FLOW (CFS) STREAM STD (UG/L) Upstream Bkgd (ug/I) IWC (%) Allowable Conc. (ug/I) Less stringent than current permit limit. Maintain limit at 28 ug/I to protect for acute toxicity. Fecal Coliform Monthly Average Limit: (If DF >331; Monitor) (If DF<331; Limit) Dilution Factor (DF) Maintain 200/100 ml MA limit 118 10.5 16.275 17.0 0 12.12 140 Ammonia (Summer) Monthly Average Limit (mg NH3-N/I) s7Q10 (CFS) DESIGN FLOW (MGD) DESIGN FLOW (CFS) STREAM STD (MG/L) Upstream Bkgd (mg/I) IWC (%) Allowable Conc. (mg/I) Maintain Ammonia (Winter) Monthly Average Limit (mg NH3-N/I) w7Q10 (CFS) 200/100m1 DESIGN FLOW (MGD) DESIGN FLOW (CFS) STREAM STD (MG/L) 8.25 Upstream Bkgd (mg/I) IWC (%) Allowable Conc. (mg/I) Maintain Total Residual Chlorine 1. Cap Daily Max limit at 28 ug/1 to protect for acute toxicity Ammonia (as NH3-N) 1. If Allowable Conc > 35 mg/I, Monitor Only 2. Monthly Avg limit x 3 = Weekly Avg limit (Municipals) 3. Monthly Avg limit x 5 = Daily Max limit (Non-Munis) If the allowable ammonia concentration is > 35 mg/L, no limit shall be imposed 118 10.5 16.275 1.0 0.22 12.12 6.66 118 10.5 16.275 1.8 0.22 12.12 13.3 Fecal Coliform 1. Monthly Avg limit x 2 = 400/100 ml = Weekly Avg limit (Municipals) = Daily Max limit (Non -Muni) NH3/TRC WLA Calculations Facility: City of Morganton/Catawba River Pollution Control Facility PermitNo. NC0026573 Prepared By: Diana Yitbarek Enter Design Flow (MGD): 13 Enter s7Q10 (cfs): 118 Enter w7Q10 (cfs): 118 Total Residual Chlorine (TRC) Daily Maximum Limit (ug/I) s7Q10 (CFS) DESIGN FLOW (MGD) DESIGN FLOW (CFS) STREAM STD (UG/L) Upstream Bkgd (ug/I) IWC (%) Allowable Conc. (ug/l) Less stringent than current permit limit. Maintain limit at 28 ug/I to protect for acute toxicity. Fecal Coliform Monthly Average Limit: (If DF >331; Monitor) (If DF<331; Limit) Dilution Factor (DF) Maintain 200/100 ml MA limit 118 13 20.15 17.0 0 14.59 117 Ammonia (Summer) Monthly Average Limit (mg NH3-N/I) s7Q10 (CFS) DESIGN FLOW (MGD) DESIGN FLOW (CFS) STREAM STD (MG/L) Upstream Bkgd (mg/I) IWC (%) Allowable Conc. (mg/I) Ammonia (Winter) Monthly Average Limit (mg NH3-N/I) w7Q10 (CFS) 200/100m1 DESIGN FLOW (MGD) DESIGN FLOW (CFS) STREAM STD (MG/L) 6.86 Upstream Bkgd (mg/I) IWC (%) Allowable Conc. (mg/I) Total Residual Chlorine 1. Cap Daily Max limit at 28 ug/1 to protect for acute toxicity Ammonia (as NH3-N) 1. If Allowable Conc > 35 mg/I, Monitor Only 2. Monthly Avg limit x 3 = Weekly Avg limit (Municipals) 3. Monthly Avg limit x 5 = Daily Max limit (Non-Munis) If the allowable ammonia concentration is > 35 mg/L, no limit shall be imposed 118 13 20.15 1.0 0.22 14.59 5.6 118 13 20.15 1.8 0.22 14.59 11 Fecal Coliform 1. Monthly Avg limit x 2 = 400/100 ml = Weekly Avg limit (Municipals) = Daily Max limit (Non -Muni) m J J 0 \ \ N 0A 0.0 C C MERCURY WQBEL/TBEL EVALUATION No Limit Required MMP Required 0 i 0 U I J W CO O O O O O O -1 Cf Permitted Flow = ng/L - Annual Average for 2019 ng/L - Annual Average for 2020 ng/L - Annual Average for 2021 ▪ % -1 Ol ▪ N Ol Ol 00 l0 00 l0 N N N % -1 l0 Ol O I� LC) m % -1 m Cr) N O O % -1 c-I m 711 ▪ c-I Ol c-I N Ol Ol 00 00 i--1 l0 N N I� ci l0 % -1 N N 01 O m m N O O c-I c-I m c-I c-I c-I c-I c-I N c-I c-I c-I T -1 Ol Ol Ol Ol 01 01 0 0 0 0 0 0 0 0 0 0 r1 r1 •-1 c-I c-I c-I c-I c-I c-I N N N N N N N N N N N N N O O O O O O O O O O O O O O O O O O O N N N N N N N N N N N N N N N N N N \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ Lfl ▪ Ol IN ci N Ol c-I Ol m LC) m lr -1 00 m N Ol c 1 %-1 N c-I c-I c-I c-I N c-I \ N c-I N N N N c-I N N N co Ol O ▪ c-I N N • m • 1. • l0 • N • co al O c-I c-I c-I c 1 m N N 0 0 U Z U (0 LL 0 0 U 0 a=. 0 d 4) (0 (0 (6 U C O (0 d0 O 2 O U U • • ct Acji ct ct V--I N N O N m ri 0 N 0 N O % -I 00 N 0 Cr) c-I O N N cr.) N N N # of Samples J 0.0 J W CO H J 0.0 J W CO m N N 0 0 U Z U f0 LL 0 0 U 0 a=. 0 d 4) c0 f6 U C O f0 d0 O 2 O U U • • ct Acji ct ct V--I N N O N m ri 0 N 0 N O % -I 00 N 0 Ol c-I O N N m n # of Samples J 0.0 J W CO H J 0.0 J W CO m N N 0 0 U Z U f0 LL 0 0 U 0 a=. 0 d 4) c0 f6 U C O f0 d0 O 2 O U U • • ct Acji ct ct V--I N N O N m ri 0 N 0 N O % -I 00 N 0 Cr) c-I O N N cr.) N m N 00 # of Samples J 0.0 J W CO H J 0.0 J W CO Whole Effluent Toxicity Testing and Self Monitoring Summary V O V 0 Jan Apr Jul Oct Basin: CTB31 PF: 13 IWC: 8.96 NC0026573/001 Morganton -Catawba R. PCF NonComp: Single chr lim: 9% @ 8MGD; Oa a a Q a1/41 a a LL a n ca m o 0 0 0 0 0 Jan Apr Jul Oct m Mecklenburg CO. C O V 0 Z Cerio24PF Lim: 90% Oa a a z z LL CO m o 0 0 0 s o V O V 0 v Jan Apr Jul Oct co d V ro CO NC0022209/001 Motiva Enterprises LLC-Greensboro Acu Fthd 24 PF Lim: O z LL n a m o 0 0 0 0 0 V O VI 0 v MarJun Sep Dec NC0022217/001 Motiva Enterprises LLC-Wake O O 0 r-1 24hr LC50 ac monit e 0 O N a-1 N a -1 61 U N -17 LL O z n a m o 0 0 0 0 V O VI 0 v Jan Apr Jul Oct cn m ro m O 2 O U1 OC NC0022187/001 Motiva Enterprises -Paw Creek 0 O N n Cerio 24 PF Lim @ 90 Begin: 9/1/2015 Oa a z LL Page 76 of 120 Legend: P= Fathead minnow (Pimphales promelas), H=No Flow (facility is active), s = Split test between Certified Labs A B I C ID E F I G I H 1 d I K I L IM N I 0 I P 1 2 NPDES/PT POC Review Form 1. Facility's General Information vn 20..04 3 Date of(draft)R Review 10/20/2021 (1st) 4/6/2022 (2nd) c_ POC review due to: e Contact Information 4 Date of(final)Review 7/21/2022 Municipal NPDES renewal ❑+ Regional Ofiice(RO) I0O NPDES PermtWaer(pw) Diana Yilbarek New Industries ❑ RO PT Staff I stephanie.williamskoncdenr.Wv I RONPDESStaff I stephaniewilliamskoncdenr.00v 5 6 Permillee-Facility Name City a Morganton - Catawba River Pollution Cantrot Facility WWTPexpansim ❑ Facility PT Staff, email I)arnevGmoraantonnr cm, ] NPDES Permit Number NC00265]3 Stream rectssladjustment 0 f. Receiving Stream 8 NPDES Permit Effective Date 5/1/2016 0.11 relocation/adjustment ❑ Ouffalll 9 NPDES Perrot Renewal Application Date 9/3/2019 7Q10 update ❑' Receiving Stream: Catawba river QA, cfs 1060 10 NPDES Permit Public Notice Bate 10/28/2021 Other, .plain below 0 Stream Class WSN' CA 7Q10 (5), cfs 116 11 eDMR data evaluated from: 1/12016 1 to 7/30/2021 OO11me"ts on POC review trigger Outll tat SS 46428 N 00000 Long. 81.30335"W 12 a_ WWTP Capacity Summary 7010 was updated from 126 cub c feet Per Outfall II 13 Current Permitted Flow, mgd 8.0 Im,Oesgnetl Flow, 80 second (cfs) to 118 cfs for the 8.0 MOO flaw tier in 10/2021 0010,0ng Stream: NA QA, cfs NA 14 Permiged SIU Flow, mgd 36 tl_ IU Summary Stream Class NA 7Q10, cfs: NA 15 b_ PT Dots_ Summary # IUs Oda!! tat. NA 00n11 Sons. NA 16 IWSapproval date 10/24/2017 #SMs 3 Isthere a PWSdownstream of the FacilTy'souffa115! I ❑' YES ❑ NO 17 USTMP approval date: 3/1212005 #GUs 0 Comments: 18 #NSOUs 0 PwsNc0tt20t0 is bratedaboul5]miksfroa, ourcall. 19Types HWA approval date 3/21/2014 # IUs w/Local Permits or Other 0 20 r. 2. Industrial Useri Information. E 21 a# Industrial User (IU)Name IUAciivty IUGonventional Pollutants IUNm Conventional P011utansBToxic Pollutant IUP Effective Date zz w Case Farms chicken BOB, T., pH, oil grease CCM,amnona v3n20r6 23 1-Seun NUM AmerKa Tex.BM, COD, chrorrium, copper, nickel,phenol, selenium(monitor), zinc, PEAS 3/312017 24 UNIX Packaging LLC Beverage BM -MS, pH COD 6/1.021 31 32 Comment The division recommendsasse sing ammonia load from Case Farmland PEAS from Steven 3. Comments from NPDES pw 33 Facility Summary, background information, and NPDES regulatory action: Comments from NPDES pw to PT staff (Central, R0, Facility)_ 34 The Control City of Morganton applied for NPDES permit Facility in September 2019. The Facility renewal for the Catawba River Pollution had a design capacity of 10.5 MOO (there Poo that are recommended to be added/modified in USTMP TN, TP, Phenols, Alumni., Antimony, PEAS 35 ae ongoing 8r0 MG0 conversations about this capacity) (up to 10.5 MOO and 13.0 MOO upon and is currently authorized to discharge request) into the Catawba River. ORC'scommentson IU/POC: Provided recent data from Case Farms 36 Additionalpollutantsconcerns added to t/STMP due to POIWs concerns: None 37 NPOES pv's comments on IU/POG None 38 4. Status of Pretreatment Program (check all that apply) 39 Status of Pretreatment Program (check all that apply) 40 41 42 43 44 45 46 la 0 la ❑' ❑ la. 1) facility has no SIU's, does have Division 2) facility has no SIU's, does not have 3) facility has Sills and OWQ approved 3a)Full Program with LTMP 3b) Modified Program with STMP 4) additional canditians regarding Pretreatment 5) facility's sludge is being land applied approved Pretreatment Program that is INACTIVE Division approved Pretreatment Program Pretreatment Program attached or listed below or composted 47 48 la. ❑ 6) facility's sludge is incinerated (add Beryllium 7) facility's sludge is taken to a landfill, and Mercurysam piing according to § 50343) Ryes which landfill_ 49 ■ 8) other 50 51 52 Sludge Disposal Plan: The City of Morganton util¢es composting as it' s method of disposal of municipal sewage dosolids. If solids do not meet requirements to be sold to the pudic the material is re- instated into the mixing process and put back on a bed to cure again. If more material is on site than the Facility can handle, the excess material will be disposed of in the landfill. 53 Sludge Permit No: W00002127 54 55 PW: Find LJSTMP document, HWA spreadsheet, DMR, previousand new NPDES permit for next section. 56 0 OO Parameter of Concern (POC) Check List New NPDES POC Previous NPDES POC Required by EPA PT(1) POC due to Sludge (2) POC due to SIU (3) POTW POC (4) % Removal Rate USTMP Effluent Freq NPDES Effluent Freq PQLs review Comment 5] a PQL from L/STMP, ug/I Required PQL per NPDES permit Recomm. POL, ugll 58 0 Flow 0 0 0 ❑ 59 0 BOD L:I 0 0 ❑ 2000.0 60 0 TSS 0 0 0 ❑ 2000.0 61 0 NH3 0 0 0 ❑ Joao 62 0 Arsenic 0 ❑ ❑ ❑ ❑ 10.0 2.0 Recomm. Updating POL to 2.0 ug/L 63 ❑ Barium 0 ❑ 0 ❑ ❑ fi4 0 Beryllium(5) 0 ❑ 0 0 ❑ 65 ❑+ Cadmium(1) 0 0 '❑ 0 0 ❑ 2.0 os Recom . updating POLto63 ug/L 66 0 Chromium (1) ❑ ❑ 3 0 ❑ ❑ 5.0 100 67 ❑' Copper(1) 0 ❑' ❑' 0 0 ❑ 2,0 2.0 68 0 Cyanide 0 ❑ 0 0 0 10.0 69 ❑+ Lead(1) 0 0 0 0 0 0 10.0 2.0 Recomm. Updating POL to 2.0 ug/L 70 0 Mercury(5) ❑ ❑ ❑+ ❑ ❑ 0.001 0.001 71 0 Molybdenum ❑ 0 0 0 0 100.0 100 Recomm Updating PDLto10.0 ug/L 72 ❑v Nickel(1) ❑ ❑ 0 0 0 ❑ 10.0 5.0 Recomm. Updating PQL to 5.0 ug/L 73 ❑' Selenium ❑ ❑ 0 0 ❑ 10.0 74 ❑' Silver 0 0 0 ❑ ❑ 5.0 1.0 Must update POLto 1.0 ug/L 75 L7 Zinc(1) ❑ ❑ 0 ❑+ 0 ❑ _0/ 12.0 76 0 Sludge Flow to Dispose 0 0 ❑ 77 0 % Solids to Disposal ❑+ ❑ ❑ 48 L7 Oil a Grease 0 ❑ 49 0 TN ❑+ ❑+ ❑ ❑ Recomm. Adding g to LIMP 80 ❑' TP L7 0 ❑ 0 Recomm. Adding g to LIMP 81 ❑+ Total Phenols ❑ ❑ 0 0 Recomm. Adding a to LIMP 82 ❑' Aluminum 0 ❑ ❑ ❑ Recomm. Adding 0 to LIMP 83 ❑' PFAS 0 0 0 0 Recomm. Adding 0 to LIMP 84 ❑' Antimony 0 ❑ 0 0 Recomm. Adding g to LTMP 85 9 0 0 0 0 86 ❑ 0 ❑ 0 0 87 ❑ 0 ❑ 0 0 ea 8 90 91 92 93 94 95 97 98 Footnotes: (1)Ahvays in the LTM%STMP due to EPA -PT requi emnt (2) Only in LTMP/STMP R listed in sludge permit (3) Only in LTMP/STMP while SIU stilldisehargest° POTW (4)Only in LTMPSTMP when pollutant is stillof concern to POTW (5) In LTM%STMP, if sewage sludge is incinerated Please use bluefont forthe info updated by pw Please use red font for POC that are recommended to be added to the USTMP sampling plan .1131ue shaded cell(D58:Ha]): Parameters usually included under that POC list 99 IIIIIIIII - 6. Pretreatment updates in response to NPDES permit renewal 100 NPOES Permit Effective Date 9/1420221180 days after effective (date): I 2/28/2023I Permit write, please add list of required/recommended PT updates in NPDES permit cover letter_ Page 1 26573 POC Review Form xlsm Pretreatment Program Info Database for Program Name Morganton WWTP Name City of Morganton Program Approval Date Pretreatment Status Region County NPDES Number NPDES Effective Date NPDES Expire Date POTW is Primary WWTP Design Flow mgd WWTP SIU's WWTP CIU's 0 3 date Inactive 07/01/1983 Full ARO Burke NC0026573 05/01/2016 02/29/2020 TRUE 10.5000 Program SIUs Program ClUs printed on: 10/6/2021 Stream Information 7Q10 Flow cfs / mgd 1Q10 Flow cfs / mgd Stream Classification IWC % at 7Q10 12.11 118 96.21 WS-IV / 76.23 / 62.18 Basin Number CTB31 Receiving Stream Name CATAWBA RIVER Last PAR Rec 02/19/2021 Current Fiscal 05/08/2019 Year PCI Done Last Audit on 05/13/2015 13/0 Design mgd is SIU permitted 13 I 0 34.70 PAR Due Date 03/01 /2022 Audit Year Next19/20 Permitted SIU flow (mgd) [Pt_SIU) 11411 mercury 1631 required yes HWA LTMP � IWS SUO ERP �1 Date Next Due 06/01/2022 Date Received by DWR 12/29/2020 08/11/2005 06/05/2017 03/06/2013 12/16/2019 Date Approved 08/12/2005 10/24/2017 03/28/2013 02/05/2020 Adopt Date Required Date Adopted 03/04/2013 Info in this Box from Pt Contacts PT_Pro g.Prime Formal Name Phonel ext Fax Date Date Date Attended Attended Attended HWA Wksp IUP Wksp PAR Wksp Mr. Timothy Arney (Prim 11828-438-5376 I 1(828) 433-8593 II 1/30/2019 15/22/2019 11/29/2019 tarney@ci.morganton.nc.us Pretreatment Coordinator PO Box 3448 28680-3448 J JPretreatment Related NOVs from DWQ 2/28/1997 NOD; 2/13/97 PCI; SUO corrections, flow data for an DWR Central Office Contact DWR Regional Contact Keyes McGee Linda Wiggs EPA Identification Number Pollutant (Required) NPDES Number NC0026573 Method Number CAS number (if Applicable) Facility Name Catawba River Pollution Control Facility Outfall Number 1 Reason Pollutant Believed Present in Discharge There are No additional pollutants to be reported. Estimated Concentration (If Known) g/e -AIA- i 1 --, 1 Eli Self - Superintendent & ORC Date Blue Ridge Labs POBox 2940 Lenoir, NC 28645 828-728-0149 blueridgelabslenoir@gmail.com Client : Attention: Date Received: Report Date: Sample Date: BILL #: City of Morganton P. O. Box 3448 Morganton, NC 28655 Ms. C. Benton 14-Jut-16 16-Aug-16 14-Jul-16 BRL-2016-0543 Lab Sample ID: LSID-2016-01994 Client Sample ID: E0714M t-s Parameter Ag As Cd Cr Cu Ni Pb Sb Se Total Phosphorus Zn Hardness Hg Result MQL Analysis Analysis Unit Method Time Date Analyst Reported By: $ 0.001 * 0.01 * 0.0002 0.001 0.001 0.012 0.001 0.001 0.001 0.01 0.015 0.01 % 0.01 0.873 0.02 0.056 0.001 34.1 0.03 * 0.0001 A1!!f S. ' l s h' nsan, D.R. Wessinger mg/1 200.7 1994 13:08 7/21/2015 KCJ mg/1 200.7 1994 13:08 7/21/2016 KCJ mg/1 200.7 1994 13:08 7/21/2016 KCJ mg/l 200.7 1994 13:08 712112016 KCJ mg/1 200.7 1994 13:08 712112016 KCJ mg/200.7 1994 13:08 7/21/2016 KCJ mgll 200.7 1994 13:08 7/21/2016 KCJ mg/1 200.7 1994 13:08 7/21/2416 KCJ mg/1 200.7 1994 13:08 7/21/2015 KCJ mg/1 200.7 1994 13:08 7/21/2016 KCJ mg/1 200.7 1994 13:08 7/21/2016 KCJ mg/1 234013 1997 13:08 7/21/2016 KCJ mg/1 245.1 1994 13:05 8/3/2016 KCJ * Concentrations are below Minimum Quantification Limit except where noted. NC Laboratory Certificate No. 275 • Page 2 of 15 Blue Ridge Labs PO Box 2940 Lenoir, NC 28645 828-728-0149 blueridgelabslenoir@gmail.com Client : Attention: Date Received: Report Date: Sample Date: BRL #: Lab Sample ID: Client Sample ID: Parameter City of Morganton P. O. Box 3448 Morganton, NC 28655 Ms. C. Benton 14-Jul-16 16-Aug-16 14-Jul-16 BRL-2016-0543 LSID-2016-01995 E0714TN Analysis Analysis Result MQL Unit Method Time Date Nitrate + Nitrite Nitrogen (N2+ Total Kjeldahl Nitrogen (TKN) Reported By: 3.88 0.08 mg/I 4500-NO3-E 15:40 7/28/2016 10.2 0.5 mg/1 4500-Norg B 11:15 7/28/2016 S. Jfhnson, D.R. Wessinger * Concentrations are below Minimum Quantification Limit except where noted. NC Laboratory Certificate No. 275 Page 3 of 15 Analyst KCJ KCJ Blue Ridge Labs PO Box 2940 Lenoir, NC 28645 828-728-0149 blueridgelabslenoir@gmail.com Client : City of Morganton P. O. Box 3448 Morganton, NC 28655 Attention: Ms. C. Benton Date Received: 14-Jul-16 Report Date: 16-Aug-16 Sample Date: 14-Jul-16 BRL #: BRL-2016-0543 Lab Sample ID: LSID-2016-01996 Client Sample ID: E0714NH3 Analysis Analysis Parameter Result MQL Unit Method Time Date Analyst Ammonia Nitrogen 3.36 0.5 mg/1 SM4500 199 15:47 7/21/2016 KCJ Reported By: S. J. nson, D.R. Wessinger * Concentrations are below Minimum Quantification Limit except where noted. NC Laboratory Certificate No. 275 Page 4 of 15 Blue Ridge Labs PO Box 2940 Lenoir, NC 28645 828-728-0149 blueridgelabslenoir@gmail.com Client : City of Morganton P. O. Box 3448 Morganton, NC 28655 Attention: Ms. C. Benton Date Received: 14-Jul-16 Report Date: 16-Aug-16 Sample Date: 14-Jul-16 BRL #: BRL-2016-0543 Lab Sample ID: LSID-2016-01997 Client Sample ID: E0714TDS Parameter TDS Analysis Analysis Result MQL Unit Method Time Date Analyst 307 1 mg/1 2540C 1997 11:20 7/21/2016 KCJ Reported By: S. nson, D.R. Wessinger * Concentrations are below Minimum Quantification Limit except where noted. NC Laboratory Certificate No. 275 Page 5 of 15 Blue Ridge Labs PO Box 2940 Lenoir, NC 28645 828-728-0149 blueridgelabslenoir@gmail.com Client : City of Morganton P. O. Box 3448 Morganton, NC 28655 Attention: Ms. C. Benton Date Received: 1 4-Jul- 16 Report Date: 16-Aug-16 Sample Date: 14-JuI-16 BRL #: BRL-2016-0543 Lab Sample ID: LSID-2016-01998 Client Sample ID: E0714TL Analysis Analysis Parameter Result MQL Unit Method Time Date Analyst Be 0.02 mg/1 EPA 200.7 12:22 7/26/2016 Summit TI 0.02 mg/I EPA 200.7 12:22 7/26/2016 Summit Reported By: S. nson, D.R. Wessinger * Concentrations are below Minimum Quantification Limit except where noted. NC Laboratory Certificate No. 275 Page 6 of 15 Blue Ridge Labs PO Box 2940 Lenoir, NC 28645 828-728-0149 blueridgelabslenoir@gmail.com Client : Attention: City of Morganton P. O. Box 3448 Morganton, NC 28655 Ms. C. Benton Date Received: 14-Jul-16 Report Date: 16-Aug-16 Sample Date: 14-Jul-16 BRL #: BRL-2016-0543 Lab Sample ID: LSID-2016-01999 Client Sample ID: E0714CN Analysis Analysis Parameter Result MQL Unit Method Time 7/21/2016te Analyst Rcj Cyanide 0.005 0.005 mg/1 4500-CN-E 1 16:42 Reported By: Johnson, D.R. Wessinger * Concentrations are below Minimum Quantification Limit except where noted. NC Laboratory Certificate No. 275 Page 7 of 15 Blue Ridge Labs PO Box 2940 Lenoir, NC 28645 828-728-0149 blueridgelabslenoir@gmail.com Client : Attention: Date Received: Report Date: Sample Date: BRL #: Lab Sample ID: Client Sample ID: City of Morganton P. O. Box 3448 Morganton, NC 28655 Ms. C. Benton 14-Jul-16 16-Aug-16 14-Jul-16 BRL-2016-0543 LSID-2016-02000 E0714624 Internal QC data on attached vendor report. Parameter 1,1,1-Trichloroethane 1,1,2,2-Tetrachloroethane 1,1,2-Trichloroethane 1,1-Dichloroethane 1,1-Dichloroethene 1,2-Dichloroethane 1,2-Dichloropropane 1,3-Dichloropropylene 2-Chloroethylvinyl Ether Acrolein Acrylonitrile Benzene Bromoform Carbon Tertachloride Chlorobenzene Ch Iorodibromomethane Chloroethane Chloroform Analysis Analysis Result MQL Unit Method Time Date Analyst Reported By: 0.005 mg/I EPA 624 21:04 7/21/2016 Summit 0.005 mg/I EPA 624 21:04 7/21/2016 Summit 0.005 mg/I EPA 624 21:04 7/21/2016 Summit 0.005 mg/I EPA 624 21:04 7/21/2016 Summit 0.005 mg/1 EPA 624 21:04 7/21/2016 Summit 0.005 mg/I EPA 624 21:04 7/21/2016 Summit 0.005 mg/1 EPA 624 21:04 7/21/2016 Summit 0.005 mg/1 EPA 624 21:04 7/21/2016 Summit 0.01 mg/I EPA 624 21:04 7/21/2016 Summit 0.05 mg/I EPA 624 21:04 7/21/2016 Summit 0.05 mg/I EPA 624 21:04 7/21/2016 Summit 0.005 mg/I EPA 624 21:04 7/21/2016 Summit , 0.005 mg/1 EPA 624 21:04 7/21/2016 Summit 0.005 mg/1 EPA 624 21:04 7/21/2016 Summit 0.00.5 mg/1 EPA 624 21:04 7/21/2016 Summit 0.005 mg/1 EPA 624 21:04 7/21/2016 Summit 0.005 mg/1 EPA 624 21:04 7/21/2016 Summit 0.005 mgJ1 EPA 624 21:04 7/21/2016 Summit S. J.( f1son, D.R. Wessinger * Concentrations are below Minimum Quantification Limit except where noted. NC Laboratory Certificate No. 275 Page 8 of 15 Blue Ridge Labs PO Box 2940 Lenoir, NC 28645 828-728-0149 blueridgelabslenoir@gmail.com Client : Attention: Date Received: Report Date: Sample Date: BRL #: Lab Sample ID: Client Sample ID: Parameter City of Morganton P. O. Box 3448 Morganton, NC 28655 Ms. C. Benton 14-Jul-16 16-Aug-16 14-Jul-16 BRL-2016-0543 LS1D-2016-02000 E0714624 Dichlorobromomethane Ethybenzene Methyl Bromide Methyl Chloride Methylene Chloride Tetrachloroethene Toluene Trans-1,2-dichloroethene Trichloroethene Vinyl Chloride Reported By: Result MQL Unit Analysis Analysis Method Time Date Analyst 0.005 mg/I EPA 624 21:04 7/21/2016 Summit 0.005 mg/1 EPA 624 21:04 7/21/2016 Summit 0.005 mg/1 EPA 624 21:04 7/21/2016 Summit 0.005 mg/1 EPA 624 21:04 7/21/2016 Summit 0.005 mg/I EPA 624 21:04 7/21/2016 Summit 0.005 mg/1 EPA 624 21:04 7/21/2016 Summit 0.005 mg/1 EPA 624 21:04 7/21/2016 Summit 0.005 mg/1 EPA 624 21:04 7/21/2016 Summit 0.005 mg/1 EPA 624 21:04 7/21/2016 Summit 0.005 mg/1 EPA 624 21:04 7/21/2016 Summit S. hnson, D.R. Wessinger * Concentrations are below Minimum Quantification Limit except where noted. NC Laboratory Certificate No. 275 Page 9 of 15 ° Labs ��l��������������������� PO Box 2940 Lenoir, NC 28645 828-728-0149 Attention: Date Received: Report Date: Sample Date: Lab Sample 00; Client Sample ID: City of Morganton 9.O.Box J44G Morganton, NC 28655 Ms. C.Benton l4-Jul'l6 |6-Aug-|6 |4-Jul-l0 BRL-2016'0543 LSlD'2018-02001 E0714625 Parameter |2 n 1,2'Dich|ombcnzone 1,2'Diphenyl-hydruzinc 1,3'Didb|nmhznzeoo 1,4'DicNnrnbcnzcnc 2.4,6'Tcicblorup6ono| 2.4'Dioblorophcoo| 2.4'Dimedhy|yhono| 2.4'Dinitrnpheno| 2.4'Dindroto|ucnc 2,6'Diuk,otolucoo 2'ChlornoaphdhaJznc 2'C6kunybeoo| 2'rJitrophcno| 3.3''Dich|onvhcnzidinc 3`46cnzoOuommbone 4.6'Dinh,o'o'crcon| Reported By: Internal UCdata onattached vendor report. Analysis Analysis 0ud Method Time Date Analyst mg/1 EPA 625 I04 7/23/2016 Summit mg/1 EPA 625 3:04 7/23/2010 Summit mg/1 EPA625 9:04 7/23/2016 Summit mg/1 EPA 625 3:04 7/23/2016 Summit mQ/| EPA625 3:04 7/23/2016 Summit mg/1 EPA625 3:04 7/23/2016 Summit mg/1 BPA625 3:04 7/23/2016 Summit mg/1 BBA625 3:04 7/23/2016 Summit mg/1 EP&d25 3:04 7/23/2016 Summit mg/1 E9&625 3:04 7/23/2016 Summit m@/| BfA625 3:04 7/23/2016 Summit m8/1 ElA625 3:04 7/23/2016 Summit mg/1 EPA625 3:04 7/23/2016 Summit mA/) EPA 625 3:04 7/23/2016 Summit mg/1 GPA625 3:04 7/23/2016 Summit mg/1 B9&625 3:04 7/23/2016 Summit m@/| EPA625 3:04 7/23/2016 Summit mg/1 EPA 625 3:04 7/23/2016 Summit °Concentrations are below Minimum QoundficubooLimit except where noted. NC Lubunurury Certificate No. 275 Page 10o[ 15 Blue Ridge Labs PO Box 2940 Lenoir, NC 28645 828-728-0149 blueridgelabslenoir@gmail.com Client : Attention: Date Received: Report Date: Sample Date: BRL #: Lab Sample ID: Client Sample ID: City of Morganton P. O. Box 3448 Morganton, NC 28655 Ms. C. Benton 14-Jul-16 16-Aug-16 14-Jul-16 BRL-2016-0543 LSID-2016-02001 E0714625 Analysis Analysis Parameter Result MQL Unit Method Time Date Analyst 4-chlorophenyl phenyl ether 0.001 mg/I EPA 625 3:04 7/23/2016 Summit 4-Nitrophenol Acenaphthene Acenaphthylene Anthracene Benzidine Benzo[a]anthracene Benzo[a]pyrene Benzo[g,h,i]perylene Benzo[k]fluoranthene bis (2-Chloroethoxy) methane bis (2-Chloroethyl) ether bis (2-Chloroisopropyl) ether bis (2-Ethylhexyl) phthalate Butylbenzylphthalate Chrysene Di-n-butylphthalate Di-n-octylphthalate Reported By: 0.001 mg/1 EPA 625 3:04 7/23/2016 Summit 0.001 mg/l EPA 625 3:04 7/23/2016 Summit 0.001 mg/I EPA 625 3:04 7/23/2016 Summit 0.001 mg/1 EPA 625 3:04 7/23/2016 Summit 0.001 mg/I EPA 625 3:04 7/23/2016 Summit 0.001 mg/I EPA 625 3:04 7/23/2016 Summit 0.001 mg/I EPA 625 3:04 7/23/2016 Summit 0.001 mg/I EPA 625 3:04 7/23/2016 Summit 0.001 mg/I EPA 625 3:04 7/23/2016 Summit 0.001 ring/1 EPA 625 3:04 7/23/2016 Summit 0.001 mg/l EPA 625 3:04 7/23/2016 Summit 0.001 mg/I EPA 625 3:04 7/23/2016 Summit 0.001 mg/l EPA 625 3:04 7/23/2016 Summit 0.001 mg/1 EPA 625 3:04 7/23/2016 Summit 0.001 mg/1 EPA 625 3:04 7/23/2016 Summit 0.001 mg/l EPA 625 3:04 7/23/2016 Summit 0.001 mg/I EPA 625 3:04 7/23/2016 Summit S. hnson, D.R. Wessinger * Concentrations are below Minimum Quantification Limit except where noted. NC Laboratory Certificate No. 275 Page 11 of 15 RidgeBlue Labs PO Box2940 Lenoir, NC 28645 828-728-0149 b|uehdgeiQbS|eDnir@�rnmQi|.COrn Attention: Date Received: City of Morganton P.O.Box 3440 MorgantOD, NC 28655 Ms. C.Bcntoo |4' ul-lh |6-Aug'|6 )4-Jul-|O B}QL'2016-0543 l.S[C-2016'02001 E0714625 Parameter Result MQL Dibeoz[a,h]unthruccuc Diethy|phda|mc Dbmeth |phthalatu F|unruothcno F|uorcnc Hrxucb|orohcnzeoc 8oxuch|ornhuzudieno Hcxucb)nrncydupeotadion Rcxach|nrnndhanc lndeno[|.2.]'cd]py,cno |xnphornnu N'Y4i\ruyv'di'n'propylam ine N'Nitrouodimuthylam ine N'Nitrnmodiphcny|amino Naphthalene Nitrobenzene p'Ch|opo'm'coon| Pentachlorophenol Reported By: Analysis Analysis Unit Method Time Date Analyst * O.00| mg/l EPA &5 3:04 7/23/2010 Summit * 0.001 mg/l EPA635 3:04 7/23/2816 Summit 0.00543 0.081 mg8 EPA625 3:04 7/23/2010 Summit * 0.001 m&/| EPA025 3:04 7/23/2016 Summit * 0.001 mQ/| EpA625 3:04 7/23/2016 Summit * 0.001 mg/| EpA625 3:04 7/23/2016 Summit * 0�00\ mg/| EPA 625 3:04 7/23/2016 Summit * 0.001 mg/| BPA625 3:04 7/23/2016 Summit * 0.001 m8/| EpA625 3:04 7/23/2016 Summit * 0.001 m8/| EyA62S 3:04 7/23/2016 Summit * 0.001 mg/| EPA 625 3:04 7/23/2016 Summit * 0.001 m&/| EPA 625 3:04 7/23/2016 Summit * 0.001 m8/| EPA 625 3:04 7/23/2016 Summit * 0.001 mQ/| EPA625 3:04 7/23/2010 Summit * 0.001 mg/| EPA625 3:04 7/23/2016 Summit * 0.001 mg/| EPA625 3:04 7/23/2016 Summit * O.00| mg/| EPA 625 3:04 7/23/2016 Summit * 0.005 mg/| EPA 625 3:04 7/23/2016 Summit S. J ;ri ouoo,D.R. Wessinger °Concentrations are below Minimum Quantification Limit except where noted. NC Laboratory CerbficateNo. %75 Page 12o[ 15 Blue Ridge Labs PO Box 2940 Lenoir, NC 28645 828-728-0149 blueridgelabslenoir@gmail.com Client : Attention: Date Received: Report Date: Sample Date: BRL #: Lab Sample ID: Client Sample ID: Parameter Phenanthrene Phenol Pyrene City of Morganton P. O. Box 3448 Morganton, NC 28655 Ms. C. Benton 14-Jul-16 16-Aug-16 14-Jul-16 BRL-2016-0543 LSID-2016-02001 E0714625 Reported By: Result MQL Analysis Analysis Unit Method Time Date Analyst 0.001 mg/1 EPA 625 3:04 7/23/2016 Summit 0.001 mg/1 EPA 625 3:04 7/23/2016 Summit 0.001 mg/1 EPA 625 3:04 7/23/2016 Summit S. ohnson, D.R. Wessinger * Concentrations are below Minimum Quantification Limit except where noted. NC Laboratory Certificate No. 275 Page 13 of 15 Blue Ridge Labs PO Box 2940 Lenoir, NC 28645 828-728-0149 blueridgelabslenoir@gmail.com Client : City of Morganton P. O. Box 3448 Morganton, NC 28655 Attention: Ms. C. Benton Date Received: 14-Jul-16 Report Date: 16-Aug-16 Sample Date: 14-Jul-16 BRL #: BRL-2016-0543 Lab Sample ID: LSID-2016-02002 Client Sample ID: E0714PL Parameter Phenols Result MQL Unit Method Time 0.012 0.01 Reported By: 420.1 1978 Analysis Analysis Date Analyst 17:14 7/28/2016 KCJ S. J. JWnson, D.R. Wessinger * Concentrations are below Minimum Quantification Limit except where noted. NC Laboratory Certificate No. 275 Page 14 of 15 Blue Ridge Labs PO Box 2940 Lenoir, NC 28645 828-728-0149 blueridgelabslenoir@gmail.com Client : Attention: Date Received: Report Date: Sample Date: BRL #: Lab Sample ID: Client Sample ID: City of Morganton P. O. Box 3448 Morganton, NC 28655 Ms. C. Benton 14-Ju1-16 16-Aug-16 14-Jul-16 BRL-2016-0543 LSID-2016-02003 E07140G Parameter Result MQL Unit Analysis Analysis Method Time Date Analyst Fats, Oil & Grease 3.1 Reported By: mg/1 5520B 2001 15:29 7/27/2016 S. Johnson, D.R. Wessinger * Concentrations are below Minimum Quantification Limit except where noted. NC Laboratory Certificate No. 275 Page 15 of 15 KCJ Blue Ridge Labs PO Box 2940 Lenoir, NC 28645 828-728-0149 blueridgelabslenoir@gmail.com Client Attention: Date Received: Report Date: Sample Date: BRL 14: Lab Sample ID: Client Sample ID: City of Morganton P. D. Box 3448 Morganton, NC 28655 Ms. C. Benton 26-Oct-17 16-Nov- I 7 26-Oct-17 BRL-2017-0889 LSID-2017-03441 E1026624 Paraineter Rest] It 1,1,l-Trichloroethane 1,1,2,2-Tetrach loroeth asp e 1,1,2-Trichloroethane 1,1-Dichloroethane 1,1-Dich1oroethene I ,2-Dichloraethane 1.2-Dichloropropane 1,3-Dichloropropylene 2•Chloroethylvinyl Ether Acrolein Acrvlonitrile Benzene Bromoform Carbon Tertachloride Chlorobenzene Ch lorodibromomethane Chloroethane Chloroform Reported Fly: £eu &(1___ MQL Unit Method 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.01 0.05 0.05 0,005 0.005 0.005 0.005 0.005 0.005 0.005 me EPA 624 mgil EPA 624 mgil mgil mg/1 mg/1 mg/1 mg/1 mg,I mg/1 mg/1 m gel mgil mg/1 mg/l mg/1 mgf1 mgll EPA 624 EPA 624 EPA 624 EPA 624 EPA 624 EPA 624 EPA 624 EPA 624 EPA 624 EPA 624 EPA 624 EPA 624 EPA 624 EPA 624 EPA 624 EPA 624 Analysis Tim e 23:45 23:45 23:45 23:45 23:45 23:45 23:45 23:45 23:45 23:45 23:45 23:45 23:45 23:45 23:45 23:45 23:45 23:45 Analysts Date Analyst 11/1/2017 11/1/2017 1 1/1/2017 11/1/2017 11/1/2017 3l'1/2017 11/1/2017 11/1/2017 11/1/2017 11/1/2017 11/112017 11/1/2017 11/1/2017 11/1/2017 111112017 11/1/2017 11/1/2017 11/1/2017 S A, ohnson, D.R. Wessinger * Concentrations are below Minimum Quantification Limit except where noted. NC Laboratory Certificate No. 275 Page 1 of 14 Summit Summit Summit Summit Summit Summit Summit Summit Summit Summit Summit Summit Summit Summit Summit Summit Summit Summ it Blue Ridge Labs PO Box 2940 Lenoir, NC 28645 828-728-0149 blueridgelabslenoir@gmail.com Client : Attention: Date Received: Report Date: Sample Date: BRL #: Lab Sample ID: Client Sample ID: Parameter City of Morganton P. O. Box 3448 Morganton, NC 28655 Ms. C. Benton 26-Oct-17 16-Nov-17 26-Oct-17 BRL-2017-0889 LSID-2017-03441 E1026624 Dichlorobromomethane Ethybenzene Methyl Bromide Methyl Chloride Methylene Chloride Tetrachloroethene Toluene Trans-1,2-dichloroethene Trichloroethene Vinyl Chloride Reported By: Analysis Analysis Result MQL Unit Method Time Date Analyst * 0.005 mg/1 EPA 624 23:45 11/1/2017 Summit * 0.005 mg/1 EPA 624 23:45 11/1/2017 Summit 0.00549 0.005 mg/I EPA 624 23:45 11/1/2017 Summit * 0.005 mg/1 EPA 624 23:45 11/1/2017 Summit * 0.005 mg/l EPA 624 23:45 11/1/2017 Summit * 0.005 mg/1 EPA 624 23:45 11/1/2017 Summit * 0,005 mg/1 EPA 624 23:45 1 1/1/201 7 Summit * 0.005 mg/1 EPA 624 23:45 11/1/2017 Summit * 0.005 mg'1 EPA 624 23:45 1 1/1.201 7 Summit * 0.005 mg/1 EPA 624 23:45 11/1/2017 Summit S. eohnson, D.R. Wessinger * Concentrations are below Minimum Quantification Limit except where noted. NC Laboratory Certificate No. 275 Page 2 of 14 Blue Ridge Labs PO Box 2940 Lenoir, NC 28645 828-728-0149 blueridgelabslenoir@gmail.com Client : Attention: Date Received: Report Date: Sample Date: BRL #: Lab Sample ID: Client Sample ID: Parameter Cyanide City of Morganton P. O. Box 3448 Morganton, NC 28655 Ms. C. Benton 26-Oct- l 7 16-Nov-17 26-Oct-17 BRL-2017-0889 LSID-2017-03442 E1026CN Reported By: Analysis Analysis Result MQL Unit Method Time Date Analyst * 0.005 mgll 4500-CN-E 1 17:08 10/27/2017 KCJ nson, D.R. Wessinger * Concentrations are below Minimum Quantification Limit except where noted. NC Laboratory Certificate No. 275 Page 3 of 14 Blue Ridge Labs PO Box 2940 Lenoir, NC 28645 828-728-0149 Client : Attention: Date Received: Report Date: Sample Date: BRL #: Lab Sample ID: Client Sample ID: Parameter N2+N3 TKN City of Morganton P. O. Box 3448 Morganton, NC 28655 Ms. C. Benton 26-Oct- ] 7 16-Nov-17 26-Oct-17 BRL-2017-0889 LSID-2017-03443 E 1026N Result MQL 3.70 0.08 7.28 0.5 Reported By: bEueridgelabslenoir@gmail.com Unit Method me/1 SM194500-N 13:19 mg/1 SM 19 4500-N 13:03 Analysis Analysis Time Date Analyst 10/27/2017 10/30/2017 S. L,1F6hnson, D.R. Wessinger x Concentrations are below Minimum Quantification Limit except where noted. NC Laboratory Certificate No. 275 Page 4 of 14 KCJ KCJ Blue Ridge Labs PO Box 2940 Lenoir, NC 28645 828-728-0149 blueridgeiabslenoir@gmail.com Client : Attention: Date Received: Report Date: Sample Date: BRL #: Lab Sample ID: Client Sample ID: Parameter Ammonia Nitrogen City of Morganton P. O. Box 3448 Morganton, NC 28655 Ms. C. Benton 26-Oct-17 16-Nov-17 26-Oct-17 BRL-2017-0889 LSID-2017-03444 E1026NH3 Reported By: Analysis Analysis Result MQL Unit Method Time Date Analyst 1.26 0.5 mg/1 SM4500 199 9:35 10/3012017 KCJ t���� S. J. 4, son, D.R. Wessinger c Concentrations are below Minimum Quantification Limit except where noted. NC Laboratory Certificate No. 275 Page 5 of 14 Blue Ridge Labs PO Box 2940 Lenoir, NC 28645 828-728-0149 blueridgelabslenoir@gmail.com Client : Attention: Date Received: Report Date: Sample Date: BRL #: Lab Sample ID: Client Sample ID: City of Morganton P. O. Box 3448 Morganton, NC 28655 Ms. C. Benton 26-Oct-17 16-Nov-17 26-Oct-17 BRL-2017-0889 LSID-2017-03445 E1026H Parameter Hardness Reported By: Result MQL 51.5 0.03 Unit Method Analysis Analysis Time Date Analyst mg/1 2340B 1997 14:24 1 1/ 14/2017 KCJ S. J /nson, D.R. Wessinger 4 * Concentrations are below Minimum Quantification Limit except where noted. NC Laboratory Certificate No. 275 Page 6 of 14 Blue Ridge Labs PO Box 2940 Lenoir, NC 28645 828-728-0149 Client : Attention: Date Received: Report Date: Sample Date: BRL #: Lab Sample ID: Client Sample ID: Parameter City of Morganton P. O. Box 3448 Morganton, NC 28655 Ms. C. Benton 26-Oct-17 16-Nov-17 26-Oct-17 BRL-2017-0889 LSID-2017-03446 E1026625 1,2,4-Trichlorobenzene 1,2-Dichlorobenzene 1,2-Diphenyl-hydrazine 1,3-Dichlorobenzene 1,4-Dichlorobenzene 2,4.6-Trichlorophenol 2,4-Dichlorophenol 2,4-Dimethvlphenol 2,4-Dinitrophenol 2.4-Dinitrotoluene 2,6-Dinitrotoluene 2-Chloronaphthalene 2-Chlorophenol 2-Nitrophenol 3.3'-Dichlorobenzidine 3,4 benzofluoranthene 4, 6- D i n itro-o-creso l 4-Bromopheny I-p heny tether Reported By: Result MQL * 0.0103 * 0.0103 * 0.41 * 0.0103 * 0.0103 * 0.0103 * 0.0103 * 0.0103 * 0.0513 * 0.0103 * 0.0103 * 0.0103 * 0.0103 * 0.0103 * 0.0103 * 0.0103 * 0.0103 * 0.0103 S. blueridgelabslenoir@gmail.com U nit mg/1 mg/1 mg/I mg/1 mg/1 mg/1 mg/1 mg/ l mg/1 mg/1 mg/1 mg/1 mg/I mg/I mg/l mg/1 mg/l mg/1 Method EPA 625 EPA 625 EPA 625 EPA 625 EPA 625 EPA 625 EPA 625 EPA 625 EPA 625 EPA 625 EPA 625 EPA 625 EPA 625 EPA 625 EPA 625 EPA 625 EPA 625 EPA 625 hnson, D.R. Wessinger Analysis Analysis Time Date Analyst 22:50 1 1 /612017 Summit 22:50 11/6/2017 Summit 22:50 11/6/2017 Summit 22:50 11/6/2017 Summit 22:50 11/6/2017 Summit 22:50 11/6/2017 Summit 22:50 11/6/2017 Summit 22:50 11/6/2017 Summit 22:50 11i612017 Summit 22:50 11/6/2017 Summit 22:50 11/6/2017 Summit 22:50 11/6/2017 Summit 22:50 11i6/2017 Summit 22:50 11/6/2017 Summit 22:50 11/6/2017 Summit 22:50 11/6/2017 Summit 22:50 11/6/2017 Summit 22:50 11/6/2017 Summit * Concentrations are below Minimum Quantification Limit except where noted. NC Laboratory Certificate No. 275 Page 7 of 14 Blue Ridge Labs PO Box 2940 Lenoir, NC 28645 828-728-0149 blueridgelabslenoir@gmail.com Client : Attention: Date Received: Report Date: Sample Date: BRL : Lab Sample ID: Client Sample ID: Parameter City of Morganton P. O. Box 3448 Morganton, NC 28655 Ms. C. Benton 26-Oct-17 16-Nov-17 26-Oct-17 BRL-2017-0889 LS 1D-2017-03446 E1026625 4-chlorophenyl phenyl ether 4-Nitrophenol Acenaphthene Accnaphthylene Anthracene Benzidine Benzo[a]anthracene Benzo[a]pyrene Benzo[g,h,i]perylene Benzo[k]fluoranthene his (2-Chloroethoxy) methane his (2-Chloroethyl) ether bis (2-Chloroisopropyl) ether bis (2-Ethylhexyl) phthalate Butylbenzylphthalate Chrysene Di-n-butylphthalate Di-n-octylphthalate Reported By: Result MQL * 0.0103 * 0.0103 * 0.0103 * 0.0103 * 0.0103 * 0.0103 * 0.0103 * 0.0103 * 0.0103 * 0.0103 • 0.0103 * 0,0103 * 0.0103 • 0.0103 * 0.0103 * 0,0103 * 0.0103 * 0.0103 Unit mg/1 mg/1 mg."l mg/I mg/1 mgI mg/1 mg/1 mg/1 mg/1 mg/1 mg/1 mg/1 m«;1 mg/l mg/l rng/l mg/I Method EPA 625 EPA 625 EPA 625 EPA 625 EPA 625 EPA 625 EPA 625 EPA 625 EPA 625 EPA 625 EPA 625 EPA 625 EPA 625 EPA 625 EPA 625 EPA 625 EPA 625 EPA 625 Analysis Time Analysis Date Analyst 22:50 11/6/2017 Summit 22:50 11/6/2017 Summit 22:50 11/6/2017 Summit 22:50 11/6/2017 Summit 22:50 11/6/2017 Summit 22:50 11/6/2017 Summit 22:50 11/6/2017 Summit 22:50 11/6/2017 Summit 22:50 11/6/2017 Summit 22:50 11/6,2017 Summit 22:50 11/6/2017 Summit 22:50 11/6/2017 Summit 22:50 11/6/2017 Summit 22:50 11/6/2017 Summit 22:50 11/6/2017 Summit 22:50 11/6/2017 Summit 22:50 1l/6/2017 Summit 22:50 11i6!2017 Summit S. J 7' son, D.R. Wessinger * Concentrations are below Minimum Quantification Limit except where noted. NC Laboratory Certificate No. 275 Page 8 of 14 Blue Ridge Labs PO Box 2940 Lenoir, NC 28645 828-728-0149 Client : Attention: Date Received: Report Date: Sample Date: BRL #: Lab Sample ID: Client Sample ID: Cite of Morganton P. O. Box 3448 Morganton, NC 28655 Ms. C. Benton 26-Oct-17 16-Nov-17 26-Oct-17 BRL-2017-0889 LS1D-2017-03446 E1026625 Parameter Result MQL Di benz[a,h]anthracene Dibenzofuran Diethvlphthalate Dimethylphthalate Fluoranthene Fluorene Hexachlorobenzene Hexachlorobutadiene Hexachlorocyclopentadine Hexachloroethane lndeno[ 1,2,3-cd]pyrene Isophorone m&p Cresol N -N itroso-di-n-propylam i ne N-Nitrosodimethylamine N-N itrosod i pheny [amine Naphthalene Nitrobenzene Reported By: * 0.0103 * 0.041 * 0.0103 * 0.0103 * 0.0103 * 0.0103 * 0.0103 * 0.0103 * 0.0103 • 0.0103 * 0.0103 * 0.0103 * 0.041 * 0.0103 * 0.0103 * 0.0103 * 0.0103 * 0.0103 blueridgelabslenoir@gmail.com Unit mg/ 1 mg/1 mg/1 mg1 mg/1 mg/1 my/1 mgI m g.1 mg11 rng/1 mg'I mg] mg/1 mg/1 mg/1 mg1 mg/I Method EPA 625 EPA 625 EPA 625 EPA 625 EPA 625 EPA 625 EPA 625 EPA 625 EPA 625 EPA 625 EPA 625 EPA 625 EPA 625 EPA 625 EPA 625 EPA 625 EPA 625 EPA 625 S. J.Irftson, D.R. Wessinger * Concentrations are below Minimum Quantification Limit except where noted. NC Laboratory Certificate No, 275 Page 9 of 14 Analysis Analysis Time Date Analyst 22:50 11/6/2017 22:50 11/6/2017 22:50 11/6/2017 22:50 11/6/2017 22:50 I1/6/2017 22:50 11/6/2017 22:50 11/6/2017 23:50 11 /6.;2017 22:50 11/6/2017 22;50 11/6/2017 22:50 11/6/2017 22:50 1.1162017 22:50 11 /6/2017 22:50 11/6/2017 22:50 11/6'2017 22:50 11/6/2017 22:50 11/6/2017 22:50 11/6/2017 Summit Summit Summit Summit Summit Summit Summit Summit Summit Summit Summit Summit Summit Summit Summit Summit Summit Summit Blue Ridge Labs PO Box 2940 Lenoir, NC 28645 828-728-0149 blueridgela bslenoir@gmail.com Client : Attention: Date Received: Report Date: Sample Date: BRL #: Lab Sample ID: Client Sample ID: City of Morganton P. 0. Box 3448 Morganton, NC 28655 Ms. C. Benton 26-Oct-17 16-Nov-17 26-Oct-17 BRL-2017-0889 LSID-2017-03446 E1026625 Analysis Analysis Parameter Result MQL Unit Method Time Date Analyst p-Chloro-m-cresol * 0.0103 mg/1 EPA 625 22:50 1 1/6/2017 Summit Pentachlorophenol * 0.0513 mg/1 EPA 625 22:50 11/6/2017 Summit Phenanthrene * 0.0103 mg/] EPA 625 22:50 11/6/2017 Summit Phenol * 0.0103 mg/1 EPA 625 22:50 11/6/2017 Summit Pyrene * 0.0103 mg/1 EPA 625 22:50 11/6/2017 Summit Reported By: S. J. J- son, D.R. Wessinger * Concentrations are below Minimum Quantification Limit except where noted. NC Laboratory Certificate No. 275 Page 10 of 14 Blue Ridge .Labs PO Box 2940 Lenoir, NC 28645 828-728-0149 blueridgefabslenoir@gmail.com Client : Attention: Date Received: Report Date: Sample Date: BRL #: Lab Sample ID: Client Sample ID: Parameter Ag As Cd Cr Cu Ni Pb Sb Se Total Phosphorus Zn Hg Be '11 City of Morganton P. O. Box 3448 Morganton, NC 28655 Ms. C. Benton 26-Oct-17 16-Nov-17 26-Oct-17 BRL-2017-0889 LSID-2017-03447 E1026M Result MQL * 0.001 * 0.01 * 0.0002 * 0.001 0.010 0.001 0.001 0.001 * 0.01 0.026 0.01 0.01 3.39 0.02 0.037 0.001 * 0.0001 * 0.02 * 0.02 Reported By: Unit Method mg/1 200.7 1994 mg/1 200.7 1994 mg;1 200.7 1994 mg/1 200.7 1994 mg/1 200.7 1994 mg/1 200.7 1994 mg/1 200.7 1994 mg/1 200,7 1994 mg/1 200.7 1994 mg/1 200.7 1994 mg/1 200.7 1994 mg/1 245.1 1994 mg/1 EPA 200.7 mg/1 EPA 200.7 Analysis Analysis Time Date Analyst 14:24 11/14/2017 14:24 1 1/14/2017 € 4:24 11114/2017 14:24 11 /1412017 € 4:24 11/14/2017 14:24 11/14/2017 14:24 11/14/2017 14:24 11/14/2017 14:24 11/14/2017 14:24 11/14/2017 14:24 11/14/2017 14:20 11/8/2017 15:05 11/3/2017 15:05 1 1/3/2017 S. J..J on, D.R. Wessinger * Concentrations are below Minimum Quantification Limit except where noted. NC Laboratory Certificate No. 275 Page 11 of 14 KCJ KCJ KCJ KCJ KCJ KCJ KCJ KC.1 KCJ KCJ KCJ KCJ Summit Summit Blue Ridge Labs PO Box 2940 Lenoir, NC 28645 828-728-0149 blueridgelabslenoir@gmaii.com Client : Attention: Date Received: Report Date: Sample Date: BRL #: Lab Sample ID: Client Sample ID: Parameter TDS City of Morganton P. O. Box 3448 Morganton, NC 28655 Ms. C. Benton 26-Oct-17 16-Nov-17 26-Oct-17 BRL-2017-0889 LSID-2017-03448 E1026TDS Reported By: Result MQL 278 1 Analysis Unit Method Time mg/1 2540C 1997 11:22 S. JIfnson, D.R. Wessinger Analysis Date Analyst 10/27/2017 KCT * Concentrations are below Minimum Quantification Limit except where noted. NC Laboratory Certificate No. 275 Page 12 of 14 Blue Ridge Labs PO Box 2940 Lenoir, NC 28645 828-728-0149 blueridgelabslenoir@gmail.com Client : Attention: Date Received: Report Date: Sample Date: BRL #: Lab Sample ID: Client Sample ID: Pa ramete r Fats. Oil & Grease City or Morganton P. O. Box 3448 Morganton, NC 28655 Ms. C. Benton 26-Oct-17 16-Nov-17 26-Oct-17 BRL-2017-0889 LSID-2017-03449 E 1 0260G Result MQL Reported By: Unit Method Analysis Time Analysis Date Analyst mg/1 5520B 2001 11:28 10/31 i2017 KCJ S..l4linson, D.R. Wessinger * Concentrations are below Minimum Quantification Limit except where noted. NC Laboratory Certificate No. 275 Page 13 of 14 Blue Ridge Labs PO Box 2940 Lenoir, NC 28645 828-728-0149 blueridgela bslenoir@gmail.com Client : Attention: Date Received: Report Date: Sample Date: BRL #: Lab Sample ID: Client Sample ID: Parameter Phenols City of Morganton P. O. Box 3448 Morganton, NC 28655 Ms. C. Benton 26-Oct-17 16-Nov- 17 26-Oct-17 BRL-2017-0889 LSID-2017-03450 E1026PL Reported By: Result MQL Analysis Analysis Unit Method Time Date Analyst * 0.01 mg 1 420.1 1978 16:15 11/14/2017 KCJ S. J. "son, D.R. Wessinger * Concentrations are below Minimum Quantification Limit except where noted. NC Laboratory Certificate No. 275 Page 14 of 14 Blue Ridge Labs PO .Box 2940 Lenoir, NC 28645 828-728-0149 blueridgelabslenoir@gmaii.com Client : Attention: Date Received: Report Date: Sample Date: BRL #: Lab Sample ID: Client Sample ID: Parameter Ag As Cd Cr Cu Mo Ni Pb Se Total Phosphorus Zn Hardness He City of Morganton P. O. Box 3448 Morganton, NC 28655 Ms. C. Benton 19-Apr- i 8 02-May-18 19-Apr-18 BRL-2018-0222 LSID-2018-01056 E0419M Result 0.532 * 23.1 * Reported By: 1-04-zn 1 MQL Unit Method 0.001 mg/1 200.7 1994 0.01 mgll 200.7 1994 0.0002 mgjl 200.7 1994 6.001 mg/1 200.7 1994 0.001 mg/1 200.7 1994 0.001 mg/1 200.7 1994 D.001 mgll 200.7 1994 0.01 met 200,7 1994 0.01 mgti 200.7 1994 0.02 mg/1 200.7 1994 0.001 mgil 200.7 1994 0.03 mg;1 2340E 1997 0.0001 mg/1 245.1 1994 S. J. i nson, U.R. Wessinger Analysis Analysis Time Date 12:49 12:49 12:49 12:49 12:49 12:49 12:49 12:49 12:49 12:49 12:49 12:49 15:16 5/2/2018 5/2/2018 5/2/2018 5/2/2018 5/2/2018 5/2/2018 5/2/2018 5/2/2018 5/2/2018 5/2/2018 5, 2/2018 5/2/2018 4/25/2018 * Concentrations are below Minimum Quantification Limit except where noted. NC Laboratory Certificate No. 275 Page 1 of 15 Analyst KCJ KCJ KCJ KCJ KCJ KCJ KCJ KCJ KCJ KCJ KCJ KCJ KCJ Blue Ridge Labs PO Box 2940 Lenoir, NC 28645 828-728-0149 blueridgelabslenoir@gmail.com Client : Attention: Date Received: Report Date: Sample Date: BRL #: Lab Sample ID: Client Sample ID: Parameter Be TI City of Morganton P. O. Box 3448 Morganton, NC 28655 Ms. C. Benton 19-Apr-18 02-May-18 19-Apr-18 BRL-2018-0222 LS1D-2018-01057 E0419BE Reported By: Result MQL * 0.001 * 0.02 Unit Method mg/1 EPA 200.7 mg/1 EPA 200.7 S. J , nson, D.R. Wessinger Analysis Analyst Time Date 15:11 4/27/2018 19:23 4/27/2018 1 * Concentrations are below Minimum Quantification Limit except where noted_ NC Laboratory Certificate No. 275 Page 2 of 15 Analyst Summit Summit Blue Ridge Labs P4 Box 2940 Lenoir, NC 28645 828-728-0149 blueridgelabslenoir@gmail.com Client : Attention: Date Received: Report Date: Sample Date: BRL #: Lab Sample ID: Client Sample ID: Parameter Ammonia Nitrogen City of Morganton P. O. Box 3448 Morganton, NC 28655 Ms. C. Benton 19-Apr-18 02-May-18 19-Apr-18 BRL-2018-0222 LSID-2018-01058 E0419NH3 Reported By: Result MQL 0.56 0.5 S. J Unit Method mg/1 SM4500 199 nson, D.R. Wessinger Analysis Analysi Time Date 10:01 4/26'2018 * Concentrations are below Minimum Quantification Limit except where noted. NC Laboratory Certificate No. 275 Page 3 of 15 Analyst KCJ Blue Ridge Labs PO Box 2940 Lenoir, NC 28645 828-728-0149 blueridgelabslenoir@grnail.corn Client : Attention: Date Received: Report Date: Sample Date: BRL #: Lab Sample ID: Client Sample ID: Parameter N2+N3 TKN City of Morganton P. O. Box 3448 Morganton, NC 28655 Ms. C. Benton 19-Apr-18 02-May-18 19-Apr-18 BRL-2018-0222 LSID-2018-01059 E0419TKN Result 2.67 6.34 Reported By: Analysis MQL Unit Method Time 0.08 mg/1 SM 19 4500-N 14:12 0.5 mg/1 SM 19 4500-N 9:42 J •mot,-y S. J. ohnson, D.R. Wessinger * Concentrations are below Minimum Quantification Limit except where noted. NC Laboratory Certificate No. 275 Page 4 of 15 Analysis Date Analyst 4/27/2018 KCJ 4/27i2018 i KCJ Blue Ridge Labs PO Box 2940 Lenoir, NC 28645 828-728-0149 blueridgelabslenoir@gmail.com Client : Attention: Date Received: Report Date: Sample Date: BRL #: Lab Sample ID: Client Sample ID: Parameter TDS City of Morganton P. O. Box 3448 Morganton, NC 28655 Ms. C. Benton 19-Apr-18 02-May-18 19-Apr-18 BRL-2018-0222 LSID-2018-01060 E04I9TDS Reported By: Result MQL 247 Unit Analysis Method Time Analysis Date j Analyst mg/1 2540C 1997 11:14 4/26/2018 S. Johnson, D.R. Wessinger * Concentrations are below Minimum Quantification Limit except where noted. NC Laboratory Certificate No. 275 Page 5 of 15 KCJ Blue Ridge Labs PO Box 2940 Lenoir, NC 28645 828-728-0149 blueridgelabslenoir@gmail.com Client : Attention: City of Morganton P. O. Box 3448 Morganton, NC 28655 Ms. C. Benton Date Received: 19-Apr-18 Report Date: 02-May-18 Sample Date: 19-Apr-18 BRL #: BRL-2018-0222 Lab Sample ID: LS1D-2018-01061 Client Sample ID: E0419625 Parameter 1,2,4- Tri c h lorobenzene 1,2-Dichlorobenzene 1,2-Diphenyl-hydrazine 1,3-Dichlorobenzene 1,4-Dichlorobenzene 2,4,6-Trich lorophenol 2,4-Dichlorophenol 2,4-Dimethylphenol 2,4-Dinitrophenol 2,4-Dinitrotoluene 2,6-Dinitrotoluene 2-Chloronaphthalene 2-Chlorophenol 2-Nitropheno] 3,3'-Dich lorobenzidine 3,4 benzofluoranthene 4,6-Dinitro-o-cresol 4-Bromophenyl-pheny tether Reported By: Result MQL * 0.01 * 0.01 * 0.04 * 0.01 * 0.01 * 0.01 * 0.01 * 0.01 * 0.05 * 0.01 * 0.01 0.01 * 0.01 * 0.01 * 0.01 * 0.01 * 0.01 * 0.01 Unit mg/1 mg/1 mg/I mg/I mg/1 mg/1 mg/1 mg/1 mg/1 mg/1 mg/1 mg/1 mg/1 mg'l mg/1 mg/1 mg/1 mg/1 Method EPA 625 EPA 625 EPA 625 EPA 625 EPA 625 EPA 625 EPA 625 EPA 625 EPA 625 EPA 625 EPA 625 EPA 625 EPA 625 EPA 625 EPA 625 EPA 625 EPA 625 EPA 625 S. J. , sT son, D.R. Wessinger Analysis Analysi Time Date Analyst 18:03 4/25/2018 Summit 18:03 4/25/2018 Summit 18:03 4/25/2018 Summit 18:03 4/25/2018 Summit 18:03 4/25/2018 Summit 18:03 4/25/2018 Summit 18:03 4/25/2018 Summit 18:03 4/25/2018 Summit 18:03 4/25/2018 Summit 18:03 4/25/2018 Summit 18:03 4/25/2018 Summit 18:03 4/25/2018 Summit 18:03 425;2018 Summit 18:03 4/25/2018 Summit 18:03 4/25/2018 Summit 18:03 4/25/2018 Summit 18:03 4/25/2018 Summit 18:03 4/25/2018 Summit * Concentrations are below Minimum Quantification Limit except where noted. NC Laboratory Certificate No. 275 Page 6 of 15 Blue Ridge Labs PO Box 2940 Lenoir, NC 28645 828-728-0149 blueridgelabslenoir@gmail.com Client : Attention: Date Received: Report Date: Sample Date: BRL #: Lab Sample ID: Client Sample ID: Parameter City of Morganton P. O. Box 3448 Morganton, NC 28655 Ms. C. Benton 19-Apr-18 02-May-18 19-Apr-18 BRL-2018-0222 LSID-2018-01061 E0419625 4-chlorophenyl phenyl ether 4-Nitrophenol Acenaphthene Acenaphthylene Anthracene Benzidine Benzo[a]anthracene Benzo[a]pyrene Benzo[g,h,i]perylene Benzo [k] flu oranthe ne bis (2-Chloroethoxy) methane bis (2-Chloroethyl) ether bis (2-Chloroisopropyl) ether bis (2-E.thylhexyl) phthalate Butylbenzylphthalate Chrysene Di-n-butylphthalate Di-n-octylphthalate Reported By: Result MQL * 0.01 * 0.01 * 0.01 * 0.0I • 0.01 * 0.01 * 0.01 * 0.01 * 0.01 * 0.01 0.01 * 0.01 0.01 0.01 * 0.01 0.01 * 0.01 0.01 Un it mg/I mg/1 mg/I mg/1 mg/I mg/1 mg/1 mg/I mg/1 mg/1 mg/1 mg/1 mg/I mg/ 1 mg/1 mg/1 mg/1 mg/1 Method EPA 625 EPA 625 EPA 625 EPA 625 EPA 625 EPA 625 EPA 625 EPA 625 EPA 625 EPA 625 EPA 625 EPA 625 EPA 625 EPA 625 EPA 625 EPA 625 EPA 625 EPA 625 Analysis Analysi Time Date 18:03 18:03 18:03 18:03 18:03 18:03 18:03 18:03 18:03 18:03 18:03 18:03 18:03 18:03 18:03 18:03 18:03 18:03 4'25i2018 4/25/2018 4/25/2018 4/25/2018 4/25/2018 4./25/2018 4/25/2018 4125i2018 4/25/2018 4/25/2018 4/25/2018 4/25/2018 4/25/2018 4/25/2018 4/25/2018 4/25/2018 4/25/2018 4125/2018 S. Jnson, D.R. Wessinger * Concentrations are below Minimum Quantification Limit except where noted. NC Laboratory Certificate No. 275 Page7of 15 Analyst Summit Summit Summit Summit Summit Summit Summit Summit Summit Summit Summit Summit Summit Summit Summit Summit Summit Summit Blue Ridge Labs PO Box 2940 Lenoir, NC 28645 828-728-0149 blueridgelabslenoir@gmail.com Client : Attention: Date Received: Report Date: Sample Date: BRL #: Lab Sample ID: Client Sample ID: City of Morganton P. O. Box 3448 Morganton, NC 28655 Ms. C. Benton 19-Apr-18 02-May-18 19-Apr-18 BRL-2018-0222 LSID-2018-01061 E0419625 Parameter Result Dibenz[a,h]anthracene Diethylphthalate Di methy 1phthalate Fluoranthene Fluorene Hexachlorobenzene Hexachlorobutadiene Hexachlorocyclopentadine Hexachloroethane Indeno[1,2,3-cd]pyrene Isophorone N-N itroso-di-n-propylamine N-N itrosod i m ethy lam in e N-N itrosod ipheny lam ine Naphthalene Nitrobenzene p-Chloro-m-cresol Pentachlorophenol Reported By: MQL * 0.01 * 0.01 * 0.01 * 0.01 * 0.01 * 0.01 * 0.01 * 0.01 * 0.01 * 0.01 * 0.01 * 0.01 0.01 * 0.01 * 0.01 * 0.01 • 0.01 * 0.05 S. J Unit Method mg/I mg/1 mg/1 mg/1 mg/1 mg/1 mg/1 mg/1 mg/1 mg/1 mg/1 mg/1 mg/1 mg/I mg/1 mg/I mg/1 mg/1 EPA 625 EPA 625 EPA 625 EPA 625 EPA 625 EPA 625 EPA 625 EPA 625 EPA 625 EPA 625 EPA 625 EPA 625 EPA 625 EPA 625 EPA 625 EPA 625 EPA 625 EPA 625 son, D.R. Wessinger Analysis Analysi Time Date Analyst 18.03 4/25/2018 Summit 18:03 4/25/2018 Summit 18:03 4/25/2018 Summit 18:03 4/25/2018 Summit 18:03 4/25/2018 Summit 18:03 4/25/2018 Summit 18:03 4/25/2018 Summit 18:03 4/25/2018 Summit 18:03 4/25/2018 Summit 18:03 4/25/2018 Summit 18:03 4/25/2018 Summit 18:03 4/25/2018 Summit 18:03 4/25/2018 Summit 18:03 4/25/2018 Summit 18:03 4/25/2018 Summit 18:03 4/25/2018 Summit 18:03 4/25/2018 Summit 18:03 4/25/2018 Summit * Concentrations are below Minimum Quantification Limit except where noted. NC Laboratory Certificate No. 275 Page 8 of 15 Blue Ridge Labs PO Box 2940 Lenoir, NC 28645 828-728-0149 blueridgela bslenoir@gmail.com Client : Attention: Date Received: Report Date: Sample Date: BRL #: Lab Sample ID: Client Sample ID: Parameter Phenanthrene Phenol Pyrene City of Morganton P. O. Box 3448 Morganton, NC 28655 Ms. C. Benton 19-Apr-18 02-May-18 19-Apr-18 BRL-2018-0222 LSID-2018-01061 E0419625 Reported By: Result MQL * 0.01 * 0.01 * 0.01 Analysis Analysi Unit Method Time Date Analyst mg/1 EPA 625 18:03 4/25/2018 Summit mg/1 EPA 625 18:03 4/25/2018 Summit nib/] EPA 625 18:03 4/25/2018 Summit S. '! h' nson, D.R. Wessinger * Concentrations are below Minimum Quantification Limit except where noted. NC Laboratory Certificate No. 275 Page 9 of 15 Blue Ridge Labs PO Box 2940 Lenoir, NC 28645 828-728-0149 blueridgelabsienoir@gmail.com Client : Attention: Date Received: Report Date: Sample Date: BRL #: Lab Sample ID: Client Sample ID: Parameter Cyanide City of Morganton P. O. Box 3448 Morganton, NC 28655 Ms. C. Benton 19-Apr-18 02-May-18 19-Apr-18 BRL-2018-0222 LSID-2018-01062 E0419CN Reported By: Result MQL 0.005 Unit Method rn '1 4500-CN-E 1 S. ' . Johnson, D.R. Wessinger * Concentrations are below Minimum Quantification Limit except where noted. NC Laboratory Certificate No. 275 Page 10 of 15 Analysis Analysi Time Date 17:02 4/24/2018 Analyst KCJ Blue Ridge Labs PO Box 2940 Lenoir, PVC 28645 828-728-0149 blueridgelabslenoir@gmail.com Client : Attention: Date Received: Report Date: Sample Date: BRL #: Lab Sample ID: Client Sample ID: Parameter City of Morganton P. O. Box 3448 Morganton, NC 28655 Ms. C. Benton 19-Apr-18 02-May-18 19-Apr-18 BRL-2018-0222 LSID-2018-01063 E04190G Fats. Oil & Grease Reported By: Analysis Result MQL Unit Method Time 1.4 1 mgrl 5520B 2001 10:33 yam". S.: +ohnson, D.R. Wessinger Analysi Date 4/26/2018 * Concentrations are below Minimum Quantification Limit except where noted. NC Laboratory Certificate No. 275 Page 11 of 15 Analyst KCJ Blue Ridge Labs PO Box 2940 Lenoir, NC 28645 828-728-0149 blueridgelabslenoir@gnnail.com Client : Attention: Date Received: Report Date: Sample Date: BRL #: Lab Sample ID: Client Sample ID: Parameter Phenols City of Morganton P. O. Box 3448 Morganton, NC 28655 Ms. C. Benton 19-Apr-18 02-May-18 19-Apr-18 BRL-2018-0222 LS1D-2018-01064 E0419PL Result MQL * 0.01 Reported By: Unit Analysis Method Time Analysi� Date Analyst mg,/1 Pheno1420.] 16:14 4/26/2018 S. Johnson, D.R. Wessinger * Concentrations are below Minimum Quantification Limit except where noted. NC Laboratory Certificate No. 275 Page 12 of 15 KCJ Blue Ridge Labs PO Box 2940 Lenoir, NC 28645 828-728-0149 blueridgelabslenoir@gmail.com Client : Attention: Date Received: Report Date: Sample Date: BRL #: Lab Sample ID: Client Sample ID: Parameter City of Morganton P. O. Box 3448 Morganton, NC 28655 Ms. C. Benton 19-Apr-18 02-May-18 19-Apr-18 BRL-2018-0222 LSID-2018-01065 E0419624 1,1,1-Trichloroethane 1,1,2,2-Tetrachloroethane 1,1,2-Trichloroethane 1,1-Dich]oroethane 1,1-Dichloroethene 1,2-Dichloroethane 1,2-Dichloropropane 1,3-Dich]oropropylene 2-Chloroethylvinyl Ether Acrolein Acrylonitrile Benzene Bromoform Carbon Tertachloride Chlorobenzene Chlorod ibromom ethane Chloroethane Chloroform Reported By: Result MQL 5 5 5 5 5 5 5 5 10 50 50 5 5 5 5 5 5 5 Unit ug/1 ug/l ug/l ug/l ug/l ug/l ug/l ug/1 ugl1 uWl ug/l ugl l ug/l ug/1 ug/l ug/l ug/1 ugll Method EPA 624 EPA 624 EPA 624 EPA 624 EPA 624 EPA 624 EPA 624 EPA 624 EPA 624 EPA 624 EPA 624 EPA 624 EPA 624 EPA 624 EPA 624 EPA 624 EPA 624 EPA 624 S. J,121 nson, D.R. Wessinger Analysis Analysi� Time Date Analyst 17:48 4/20/2018 Summit 17:48 4/20/2018 Summit 17:48 4/20/2018 Summit 17:48 4/20/2018 Summit 17:48 4/20/2018 Summit 17:48 4/20/2018 Summit 17:48 4/20/2018 Summit 17:48 4/20/2018 Summit 17:48 4/20/2018 Summit 17:48 4/20/2018 Summit 17:48 4/20/2018 Summit 17:48 4/20/2018 Summit 17:48 4/20/2018 Summit 17:48 4/20/2018 Summit 17:48 4/20/2018 Summit 17:48 4/20/2018 Summit 17:48 4/20/2018 Summit 17:48 4/20/2018 Summit Concentrations are below Minimum Quantification Limit except where noted. NC Laboratory Certificate No. 275 Page 13 of 15 Blue Ridge Labs PO Box 2940 Lenoir, NC 28645 828-728-0149 blueridgelabslenoir@gmail.com Client : Attention: Date Received: Report Date: Sample Date: BRL #: Lab Sample ID: Client Sample ID: Parameter City of Morganton P. O. Box 3448 Morganton, NC 28655 Ms. C. Benton 19-Apr-18 02-May-18 19-Apr-18 BRL-2018-0222 LS1D-2018-01065 E0419624 Result Dichlorobromomethane Ethybenzene Methyl Bromide Methyl Chloride Methylene Chloride Tetrachloroethene Toluene Trans-1,2-dichloroethene Trichloroethene Vinyl Chloride Reported By: MQL * 5 * 5 * 5 * 5 * 5 * 5 * 5 * 5 * 5 * 5 Analysis Analysi• Unit Method Time Date Analyst ug/1 EPA 624 17:48 4/20/2018 Summit ug/1 EPA 624 17:48 4/20/2018 Summit ug/1 EPA 624 17:48 4/20/2018 Summit ug'1 EPA 624 17:48 4/20/2018 Summit ug/1 EPA 624 17:48 4/20/2018 Summit ugil EPA 624 17:48 4/20/2018 Summit ug/1 EPA 624 17:48 4/20/2018 Summit ugil EPA 624 17:48 4/20/2018 Summit ug/1 EPA 624 17:48 4/20/2018 Summit ug/1 EPA 624 17:48 4/20/2018 Summit S. J. nson, D.R. Wessinger Concentrations are below Minimum Quantification Limit except where noted. NC Laboratory Certificate No. 275 Page 14 of 15 Attachment A —Request for Missing Information 40 CFR 122.21(f](2) 1.1 Email address of facility contact eseif@Ci.morganton.nc.us 40 CFR 122.21(0(3) 1.2 NAICS Code(s) Description (optional) 221320 Sewage treatment plants or facilities 40 CFR 122.21(0(4) 1,3 Email address of operator eself@ci.morganton.nc.us Ci.morganton.nc.us 40 CFR 122.21(0(9) 1.4 Does your facility use cooling water? ❑ Yes 'No 4 SKIP to Item 1.6 Identify the source of cooling water. (Note that facilities that use a cooling water intake structure as described at 40 CFR 125, Subparts I and J may have additional application requirements at 40 CFR 122.21(r). Consult with your NPDES permitting authority to determine what specific information needs to be submitted and when.) 1.5 40 CFR 122.21(0(10) 1.6 Do you intend to request or renew one or more of the variances authorized at 40 CFR 122.21(m)? (Check all that apply. Consult with your NPDES permitting authority to determine what information needs to be submitted and when.) O Fundamentally different factors (CWA Water quality related effluent limitations (CWA Section Section 301(n)) 302(b)(2)) O Non -conventional pollutants (CWA ❑ Thermal discharges (CWA Section 316(a)) Section 301(c) and (g)) ❑ Not applicable 40 CFR 122.22(a) and (d) 1.7 Certification Statement I certify under penalty of law that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fine and imprisonment for knowing violations. Name (print or type first and last name) Eli Self Official title Superintendent & ORC Signature tia Date signed Attachment A —Request for Missing Information Table 2. EPA Application Form 2A Missing Information 40 CFR 122.21(j)(1) 1.1 Email address of facility contact eself@ci.morgenton.nc.us 1.2 Applicant email address eseIf@cj.morganton,nc.us 1.3 Email address of the organization transporting the discharge for treatment prior to discharge NA 1.4 Email address of the organization receiving the discharge for treatment prior to discharge NA 1.5 Do you intend to request or renew one or more of the variances authorized at 40 CFR 122,21(n)? (Check all that apply. Consult with your NPDES permitting authority to determine what information needs to be submitted and when,) ❑ Discharges into marine waters (CWA Section "Water quality related effluent limitation (CWA 301(h)) Section 302(b)(2)) ❑ Not applicable 1.6 Email address of contractor responsible for operational or maintenance aspects of the treatment works Al A 40 CFR 122.21(jj(6) 1.7 _ Indicate the number of SIUs and NSCIUs that discharge to the PDTW Number of SIUs Number of ClUs 2 SIU & 1 NSCIU 40 CFR 122.22(a) and (d) 1,8 Certification Statement I certify under penalty of law that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fine and imprisonment for knowing violations. Name (print or type first and last name) Eli Self Official title Superintendent & ORC Signature Date signed f NC Department of Environment and Natural Resources Model Mercury Minimization Plan Background The North Carolina Department of Environment and Natural Resources, Division of Water Resources (DENR), has issued a statewide total maximum daily load (TMDL) for mercury. The TMDL responds to a statewide fish consumption advisory for mercury. The TMDL calls for a 67% reduction in mercury levels from the year 2002 baseline mercury loading. The ultimate goal of the TMDL is to ensure safe - levels of mercury in fish throughout North Carolina for human consumption. As explained in the TMDL, 98 percent of mercury in North Carolina waters comes from atmospheric sources — the vast majority of which are located outside of the State. Under the Clean Water Act, atmospheric deposition of mercury into surface waters is regarded as a nonpoint source. Minor amounts of mercury are discharged directly into surface waters by industrial and municipal point sources as a group. Specifically, the TMDL determined that point sources contribute less than two (2) percent of the annual mercury loadings to State waters. The TMDL allocates two percent of the statewide allowable loadings collectively to the point source sector. This does not mean that an individual discharger may not have significant levels of mercury in its discharge in terms of local water quality considerations. While we expect such instances to be rare based upon the Department's review of statewide mercury data, dischargers with higher mercury loadings will be expected to implement more aggressive mercury controls. Notably, unlike any other source, local governments actually reduce mercury loadings in the environment by first filtering mercury out in the treatment of public drinking water (particularly where the source of raw drinking water is surface water) and then a second time when wastewater is treated. In order to implement the two percent point source sector wasteload allocation, the Department has developed a point source permitting strategy which is located at http://portal.ncdenr.org/web/wq/ps/mtu/tmdl/tmdls/mercury . The Environmental Management Commission has approved both the TMDL and the Permitting Strategy. The permitting strategy calls for certain point sources to develop and implement mercury minimization plans (MMPs). For POTWs, an MMP will be required if the facility has (1) a permitted design capacity of more than two million gallons per day and (2) mercury at quantifiable levels in their effluent. MMPs feature best management practices and have been implemented successfully in numerous states around the country. The attached document is [Utility name]'s MMP. Typically, MMPs focus on pretreatment controls — a local government's interaction with non -domestic users of its sewer system as well as outreach to the public at large regarding the proper use and disposal of household products containing mercury. The MMP approach is intended as a reasonable, low-cost approach toward making some progress toward managing the two percent loading statewide from point sources. Mercury treatment and even testing is very expensive and does not make sense to reduce a small part of the already insignificant two percent overall point source annual loading to State waters. Catawba River Pollution Control Facility for the City of Morganton MODEL MUNICIPAL MERCURY MINIMIZATION PLAN [1/12/2021] SECTION I - PURPOSE The purpose of this Mercury Minimization Plan ("MMP") is to describe best management practices through which City of Morganton will seek to reduce the amount of mercury discharged into its system and, ultimately, to the environment. The MMP compiles mercury reduction -related efforts to -date and potential future action items. It is designed to be a working document to help guide City of Morganton in its efforts to control mercury loadings discharged into its Publicly -Owned Treatment Works (POTW) by users of the sewer system. Such a reduction in loadings to the sewer system should translate to a reduction in the amount of mercury which is discharged from the treatment plant. The management practices summarized below may also help control some of the mercury reaching our storm sewer system as well. SECTION II — FACILITY DESCRIPTION The City of Morganton operates a publicly owned treatment works (POTW), including a collection system and wastewater treatment plant (WWTP), that serves the city of Morganton, Drexel and Glen Alpine areas of North Carolina. The WWTP Facility removes trash and debris from waste stream with bar screens, grit is removed with a cyclone separator. BOD (Biochemical Oxygen Demand) and TSS (Total Suspended Solids) are removed with the biological process created through mixing oxygen into an aeration basin to allow microorganisms to further break down waste. Wastewater is then disinfected with Chlorine. After disinfection, the Chlorine is removed with Sodium Bi-Sulfate before entering the Catawba River. Sludge accumulated is dewatered using centrifuges and composted. Finished residuals are classified as Class A Biosolids and is distributed to the general public. As with most municipal treatment plants, the City of Morganton's WWTP is not designed to remove mercury and it is exceedingly expensive to do so to very low levels. Incidental mercury removal occurs through typical municipal treatment with trace levels of mercury (and other metals) ending up in solids removed from the raw wastewater. Mercury is not used in the treatment processes at the WWTP. Mercury may be introduced into the sewer system through a variety of sources, such as from industrial users, laboratories, and other businesses. Residual deposits of mercury are also possible in the sewer system from historic practices. Finally, trace amounts from household products and atmospheric deposition (both wet and dry) contribute to sewer system mercury loadings. While there is typically some mercury contributed to public sewer systems statewide, it is usually in minute quantities and comprises a tiny portion of the already insignificant statewide loading for all point sources - just two percent of the annual mercury loadings to all State waters. SECTION HI — PROGRAM PLAN A. EVALUATION OF POTENTIAL NON -DOMESTIC SOURCES CONTRIBUTING MERCURY TO THE POTW Within 24 months from the NPDES required 180-day period for development of an MMP, the City of Morganton will evaluate available information to assess the potential for non -domestic users of the sewer system to contribute mercury to the system. The information to be reviewed may include: (1) POTW influent and effluent mercury data and trends; (2) industrial user permits and associated mercury monitoring data; (3) Toxics Release Inventory (TRI); (4) state hazardous site registry and the National Priority List relating to mercury contamination; and (5) historical records of industrial sites which may have contributed mercury loadings to the sewer system. The City of Morganton will also survey and evaluate the following common sources of mercury in its service area: (1) dentist offices; (2) hospitals; (3) laboratories; (4) auto recyclers; and (5) other potential sources of mercury based on existing information. The City of Morganton will request that industrial users review mercury concentrations in high -volume process chemicals and demonstrate that the mercury concentrations are below industry average. The City of Morganton will request that alternative sources for chemicals be explored if the mercury levels are determined to be significantly higher than would normally be expected. The evaluation of potential non -domestic sources of mercury to the sewer system will be updated every five years, as warranted by prior sampling results and any additional new potentially significant sources to the system. B. ADDITIONAL CONTROL MEASURES This MMP identifies reasonable and cost-effective control measures to minimize mercury being discharged into the POTW. Below is a listing of initial BMPs for this POTW. Pollution Prevention Substances used at the WWTP will be evaluated to determine if they contain mercury or mercury -based compounds. Any such chemicals will be evaluated for substitution with non -mercury -containing substances. Housekeeping, Spill Control and Collection, and Education The City of Morganton will develop procedures to minimize the possibility of any spill or release at the WWTP involving mercury containing substances. The City of Morganton will add mercury identification and proper disposal to ongoing and future operator training procedures. Public Outreach The City of Morganton will make available educational information regarding sources of household mercury and appropriate use/disposal practices. This information may be posted on the City of Morganton's website. The availability of this information will be highlighted in the coming months of 2021 to outreach the City of Morganton's customers. The City of Morganton will also facilitate public awareness regarding community collection points for mercury -containing products from residents/customers for proper disposal. Periodic reminders of such collection programs will be provided as part of the City of Morganton's ongoing public outreach. Laboratory Practice The City of Morganton operates a laboratory for purposes of complying with state and federal monitoring and sampling requirements. The laboratory is a potential source of small quantities of mercury - containing compounds. Laboratory employees will be trained in the proper handling and disposal of these materials. The laboratories have also replaced mercury thermometers with non -mercury thermometers, whenever practical. C. TRACKING AND MONITORING In order to assess the implementation of the control measures, the City of Morganton proposes to undertake the following evaluations beginning after the first full year that this MMP is implemented: 1. Survey annually at least ten percent (10%) of any non -domestic users identified as possible significant sources of mercury to the POTW; 2. Track the implementation of the programs outlined above; 3. Monitor influent mercury at least annually. Require significant non -domestic sources of mercury to monitor periodically, as warranted; and 4. Measure effluent mercury as required by the NPDES permit. These efforts will allow the City of Morganton to establish a baseline of influent and effluent mercury levels to assist in identifying any trends in mercury contributions from domestic and non -domestic users of the sewer system. This baseline will be tracked annually. SECTION IV — IMPLEMENTATION OF CONTROL MEASURES The POTW sampled for Low Level Mercury in its effluent each month beginning in September 2019 to November 2020 to gather a baseline and for the needs of our Headworks Analysis and Long Term Monitoring program. POTW has continued to sample for Low Level Mercury quarterly. The City of Morganton in 2020 began sending surveys to dental offices in an effort to identify and monitor mercury use at their practices. The City of Morganton has also began in 2021 sending out surveys to its Significant Industry Users (SUI's) in an attempt to identify and reduce the potential mercury discharge from their facilities. We are in the process of gathering information to send to Hospitals after SUI's. The City of Morganton will implement the control measures summarized in Section III over the permit term and will update this MMP as warranted. SECTION V - REPORTING A summary of the MMP activities will be submitted as part of the NPDES permit renewal process. Permit No. NC0026573 NPDES Implementation of Instream Dissolved Metals Standards - Freshwater Standards The NC 2007-2015 Water Quality Standard (WQS) Triennial Review was approved by the NC Environmental Management Commission (EMC) on November 13, 2014. The US EPA subsequently approved the WQS revisions on April 6, 2016, with some exceptions. Therefore, metal limits in draft permits out to public notice after April 6, 2016 must be calculated to protect the new standards - as approved. Table 1. NC Dissolved Metals Water Quality Standards/Aquatic Life Protection Parameter Acute FW, µg/1 (Dissolved) Chronic FW, µg/1 (Dissolved) Acute SW, µg/1 (Dissolved) Chronic SW, µg/1 (Dissolved) Arsenic 340 150 69 36 Beryllium 65 6.5 --- --- Cadmium Calculation Calculation 40 8.8 Chromium III Calculation Calculation --- --- Chromium VI 16 11 1100 50 Copper Calculation Calculation 4.8 3.1 Lead Calculation Calculation 210 8.1 Nickel Calculation Calculation 74 8.2 Silver Calculation 0.06 1.9 0.1 Zinc Calculation Calculation 90 81 Table 1 Notes: 1. FW= Freshwater, SW= Saltwater 2. Calculation = Hardness dependent standard 3. Only the aquatic life standards listed above are expressed in dissolved form. Aquatic life standards for Mercury and selenium are still expressed as Total Recoverable Metals due to bioaccumulative concerns (as are all human health standards for all metals). It is still necessary to evaluate total recoverable aquatic life and human health standards listed in 15A NCAC 2B.0200 (e.g., arsenic at 10 µg/1 for human health protection; cyanide at 5 µg/L and fluoride at 1.8 mg/L for aquatic life protection). Table 2. Dissolved Freshwater Standards for Hardness -Dependent Metals The Water Effects Ratio (WER) is equal to one unless determined otherwise under 15A NCAC 02B .0211 Subparagraph (11)(d) Metal NC Dissolved Standard, µg/I Cadmium, Acute WER*{1.1366724ln hardness](0.041838)} - e^{0.9151 [ln hardness]-3.1485} Cadmium, Acute Trout waters WER*{1.1366724ln hardness](0.041838)} - e^{0.9151[ln hardness]-3.6236} Cadmium, Chronic WER*{1.1016724ln hardness](0.041838)} - e^{0.7998[ln hardness]-4.4451} Chromium III, Acute WER*0.316 - e^{0.8190[ln hardness]+3.7256} Chromium III, Chronic WER*0.860 • e^{0.8190[ln hardness]+0.6848} Copper, Acute WER*0.960 • e^{0.9422[ln hardness]-1.700} Copper, Chronic WER*0.960 • e^{0.8545[ln hardness]-1.702} Lead, Acute WER*{1.462034ln hardness](0.145712)} • e^{1.273[ln hardness]-1.460} Lead, Chronic WER*{1.462034ln hardness](0.145712)} • e^{1.273[ln hardness]-4.705} Nickel, Acute WER*0.998 • e^{0.8460[ln hardness]+2.255} Nickel, Chronic WER*0.997 • e^{0.8460[ln hardness]+0.0584} Page 1 of 4 Permit No. NC0026573 Silver, Acute WER*0.85 • e^{1.72[ln hardness]-6.59} Silver, Chronic Not applicable Zinc, Acute WER*0.978 • e^{0.8473[ln hardness]+0.884} Zinc, Chronic WER*0.986 • e^{0.8473[In hardness]+0.884} General Information on the Reasonable Potential Analysis (RPA) The RPA process itself did not change as the result of the new metals standards. However, application of the dissolved and hardness -dependent standards requires additional consideration in order to establish the numeric standard for each metal of concern of each individual discharge. The hardness -based standards require some knowledge of the effluent and instream (upstream) hardness and so must be calculated case -by -case for each discharge. Metals limits must be expressed as `total recoverable' metals in accordance with 40 CFR 122.45(c). The discharge -specific standards must be converted to the equivalent total values for use in the RPA calculations. We will generally rely on default translator values developed for each metal (more on that below), but it is also possible to consider case -specific translators developed in accordance with established methodology. RPA Permitting Guidance/WQBELs for Hardness -Dependent Metals - Freshwater The RPA is designed to predict the maximum likely effluent concentrations for each metal of concern, based on recent effluent data, and calculate the allowable effluent concentrations, based on applicable standards and the critical low -flow values for the receiving stream. If the maximum predicted value is greater than the maximum allowed value (chronic or acute), the discharge has reasonable potential to exceed the standard, which warrants a permit limit in most cases. If monitoring for a particular pollutant indicates that the pollutant is not present (i.e. consistently below detection level), then the Division may remove the monitoring requirement in the reissued permit. 1. To perform a RPA on the Freshwater hardness -dependent metals the Permit Writer compiles the following information: • Critical low flow of the receiving stream, 7Q10 (the spreadsheet automatically calculates the 1Q10 using the formula 1Q10 = 0.843 (s7Q10, cfs) 0.993 • Effluent hardness and upstream hardness, site -specific data is preferred • Permitted flow • Receiving stream classification 2. In order to establish the numeric standard for each hardness -dependent metal of concern and for each individual discharge, the Permit Writer must first determine what effluent and instream (upstream) hardness values to use in the equations. The permit writer reviews DMR's, Effluent Pollutant Scans, and Toxicity Test results for any hardness data and contacts the Permittee to see if any additional data is available for instream hardness values, upstream of the discharge. If no hardness data is available, the permit writer may choose to do an initial evaluation using a default hardness of 25 mg/L (CaCO3 or (Ca + Mg)). Minimum and maximum limits on the hardness value used for water quality calculations are 25 mg/L and 400 mg/L, respectively. If the use of a default hardness value results in a hardness -dependent metal showing reasonable potential, the permit writer contacts the Permittee and requests 5 site -specific effluent and upstream hardness samples over a period of one week. The RPA is rerun using the new data. Page 2 of 4 Permit No. NC0026573 The overall hardness value used in the water quality calculations is calculated as follows: Combined Hardness (chronic) = (Permitted Flow, cfs *Avg. Effluent Hardness, mg/L) + (s7Q10, cfs *Avg. Upstream Hardness, mg/ (Permitted Flow, cfs + s7Q10, cfs) The Combined Hardness for acute is the same but the calculation uses the 1Q10 flow. 3. The permit writer converts the numeric standard for each metal of concern to a total recoverable metal, using the EPA Default Partition Coefficients (DPCs) or site -specific translators, if any have been developed using federally approved methodology. EPA default partition coefficients or the "Fraction Dissolved" converts the value for dissolved metal at laboratory conditions to total recoverable metal at in -stream ambient conditions. This factor is calculated using the linear partition coefficients found in The Metals Translator: Guidance for Calculating a Total Recoverable Permit Limit from a Dissolved Criterion (EPA 823-B-96-007, June 1996) and the equation: Cdiss = 1 Ctotal 1 + { LKPoI �SS(1+a)I [1 0-61 J Where: ss = in -stream suspended solids concentration [mg/1], minimum of 10 mg/L used, and Kpo and a = constants that express the equilibrium relationship between dissolved and adsorbed forms of metals. A list of constants used for each hardness -dependent metal can also be found in the RPA program under a sheet labeled DPCs. 4. The numeric standard for each metal of concern is divided by the default partition coefficient (or site -specific translator) to obtain a Total Recoverable Metal at ambient conditions. In some cases, where an EPA default partition coefficient translator does not exist (ie. silver), the dissolved numeric standard for each metal of concern is divided by the EPA conversion factor to obtain a Total Recoverable Metal at ambient conditions. This method presumes that the metal is dissolved to the same extent as it was during EPA's criteria development for metals. For more information on conversion factors see the June, 1996 EPA Translator Guidance Document. 5. The RPA spreadsheet uses a mass balance equation to determine the total allowable concentration (permit limits) for each pollutant using the following equation: Ca = (s7Q10 + Qw) (Cwqs) — (s7Q10) (Cb) Qw Where: Ca = allowable effluent concentration (µg/L or mg/L) Cwqs = NC Water Quality Standard or federal criteria (µg/L or mg/L) Cb = background concentration: assume zero for all toxicants except NH3* (µg/L or mg/L) Qw = permitted effluent flow (cfs, match s7Q10) s7Q10 = summer low flow used to protect aquatic life from chronic toxicity and human health through the consumption of water, fish, and shellfish from noncarcinogens (cfs) * Discussions are on -going with EPA on how best to address background concentrations Flows other than s7Q10 may be incorporated as applicable: 1Q10 = used in the equation to protect aquatic life from acute toxicity Page 3 of 4 Permit No. NC0026573 QA = used in the equation to protect human health through the consumption of water, fish, and shellfish from carcinogens 30Q2 = used in the equation to protect aesthetic quality 6. The permit writer enters the most recent 2-3 years of effluent data for each pollutant of concern. Data entered must have been taken within four and one-half years prior to the date of the permit application (40 CFR 122.21). The RPA spreadsheet estimates the 95th percentile upper concentration of each pollutant. The Predicted Max concentrations are compared to the Total allowable concentrations to determine if a permit limit is necessary. If the predicted max exceeds the acute or chronic Total allowable concentrations, the discharge is considered to show reasonable potential to violate the water quality standard, and a permit limit (Total allowable concentration) is included in the permit in accordance with the U.S. EPA Technical Support Document for Water Quality -Based Toxics Control published in 1991. 7. When appropriate, permit writers develop facility specific compliance schedules in accordance with the EPA Headquarters Memo dated May 10, 2007 from James Hanlon to Alexis Strauss on 40 CFR 122.47 Compliance Schedule Requirements. 8. The Total Chromium NC WQS was removed and replaced with trivalent chromium and hexavalent chromium Water Quality Standards. As a cost savings measure, total chromium data results may be used as a conservative surrogate in cases where there are no analytical results based on chromium III or VI. In these cases, the projected maximum concentration (95th %) for total chromium will be compared against water quality standards for chromium III and chromium VI. 9. Effluent hardness sampling and instream hardness sampling, upstream of the discharge, are inserted into all permits with facilities monitoring for hardness -dependent metals to ensure the accuracy of the permit limits and to build a more robust hardness dataset. 10. Hardness and flow values used in the Reasonable Potential Analysis for this permit included: Parameter Value Comments (Data Source) Average Effluent Hardness (mg/L) [Total as, CaCO3 or (Ca+Mg)] 36.23 Data provided in DMRs Average Upstream Hardness (mg/L) [Total as, CaCO3 or (Ca+Mg)] 25.0 Default value 7Q10 summer (cfs) 118.0 NPDES Files 1Q10 (cfs) 118.0 Calculated in RPA Permitted Flow (MGD) 8.0 NPDES permit application Date: 9/22/2021 Permit Writer: Diana Yitbarek Page 4 of 4 United States Environmental Protection Agency E PA Washington, D.C. 20460 Water Compliance Inspection Report Form Approved. OMB No. 2040-0057 Approval expires 8-31-98 Section A: National Data System Coding (i.e., PCS) Transaction Code NPDES yr/mo/day Inspection 1 ICI J 2 IS I 3 I NC0026573 111 121 20/08/13 117 Type 18 [ I I I I I Inspector Fac Type 19 G I 201 211111 I I I I I I II I I I I I I I I I I I I I I I I I I II I I I I I 166 Inspection Work Days Facility Self -Monitoring Evaluation Rating B1 QA Reserved 671I 7° I I 711I 72 I N I 73I I 174 L� 1 751 I I I I I I 180 Section B: Facility Data Name and Location of Facility Inspected (For Industrial Users discharging to POTW, also include POTW name and NPDES permit Number) Catawba River Pollution Control Facility 1000 Vine Arden Rd Morganton NC 28680 Entry Time/Date 10:30AM 20/08/13 Permit Effective Date 16/05/01 Exit Time/Date 12:30PM 20/08/13 Permit Expiration Date 20/02/29 Name(s) of Onsite Representative(s)/Titles(s)/Phone and Fax Number(s) /// Other Facility Data Name, Address of Responsible Official/Title/Phone and Fax Number Contacted Eli Self,PO Box 3448 Morganton NC 286559850/Superintendent ORC/828-438-5375/ Yes Section C: Areas Evaluated During Inspection (Check only those areas evaluated) Permit Operations & Maintenar Records/Reports Facility Site Review Effluent/Receiving Wate Section D: Summary of Finding/Comments (Attach additional sheets of narrative and checklists as necessary) (See attachment summary) Name(s) and Signature(s) of Inspector(s) Agency/Office/Phone and Fax Numbers Date Linda S Wiggs DWR/ARO WQ/828-296-4500 Ext.4653/ Signature of Management Q A Reviewer Agency/Office/Phone and Fax Numbers Date EPA Form 3560-3 (Rev 9-94) Previous editions are obsolete. Page# 1 31 NPDES yr/mo/day NC0026573 111 121 20/08/13 117 Inspection Type 18ILI 1 Section D: Summary of Finding/Comments (Attach additional sheets of narrative and checklists as necessary) Linda Wiggs met with Eli Self (ORC) and Tim Arney (Pretreatment Coordinator). Records were reviewed remotely. No compliance issues were noted. The staff do an exceptional job operating this facility. Page# 2 Permit: NC0026573 Inspection Date: 08/13/2020 Owner - Facility: Catawba River Pollution Control Facility Inspection Type: Compliance Evaluation Operations & Maintenance Is the plant generally clean with acceptable housekeeping? Does the facility analyze process control parameters, for ex: MLSS, MCRT, Settleable Solids, pH, DO, Sludge Judge, and other that are applicable? Comment: sludge judge, settleability, pH, DO, MLSS, MCRT, microscopic analysis. Permit (If the present permit expires in 6 months or less). Has the permittee submitted a new application? Is the facility as described in the permit? # Are there any special conditions for the permit? Is access to the plant site restricted to the general public? Is the inspector granted access to all areas for inspection? Comment: Record Keeping Are records kept and maintained as required by the permit? Is all required information readily available, complete and current? Are all records maintained for 3 years (lab. reg. required 5 years)? Are analytical results consistent with data reported on DMRs? Is the chain -of -custody complete? Dates, times and location of sampling Name of individual performing the sampling Results of analysis and calibration Dates of analysis Name of person performing analyses Transported COCs Are DMRs complete: do they include all permit parameters? Has the facility submitted its annual compliance report to users and DWQ? (If the facility is = or > 5 MGD permitted flow) Do they operate 24/7 with a certified operator on each shift? Is the ORC visitation log available and current? Is the ORC certified at grade equal to or higher than the facility classification? Is the backup operator certified at one grade less or greater than the facility classification? Yes No NA NE • ❑ ❑ ❑ • ❑ ❑ ❑ Yes No NA NE ❑ ❑ • ❑ • ❑ ❑ ❑ • ❑ • ❑ • ❑ ❑ ❑ • ❑ ❑ ❑ Yes No NA NE • ❑ ❑ ❑ • ❑ ❑ ❑ • ❑ ❑ ❑ • ❑ ❑ ❑ ❑ ❑ ❑ • 0 0 0 0 0 0 • ❑ ❑ ❑ • ❑ ❑ ❑ • ❑ ❑ ❑ • ❑ ❑ ❑ • ❑ ❑ ❑ • ❑ ❑ ❑ Page# 3 Permit: NC0026573 Inspection Date: 08/13/2020 Owner - Facility: Catawba River Pollution Control Facility Inspection Type: Compliance Evaluation Record Keeping Is a copy of the current NPDES permit available on site? Facility has copy of previous year's Annual Report on file for review? Comment: Effluent Pipe Is right of way to the outfall properly maintained? Are the receiving water free of foam other than trace amounts and other debris? If effluent (diffuser pipes are required) are they operating properly? Comment: Bar Screens Type of bar screen a.Manual b.Mechanical Are the bars adequately screening debris? Is the screen free of excessive debris? Is disposal of screening in compliance? Is the unit in good condition? Comment: Grit Removal Type of grit removal a.Manual b.Mechanical Is the grit free of excessive organic matter? Is the grit free of excessive odor? # Is disposal of grit in compliance? Comment: Primary Clarifier Is the clarifier free of black and odorous wastewater? Is the site free of excessive buildup of solids in center well of circular clarifier? Are weirs level? Yes No NA NE • ❑ ❑ ❑ • ❑ ❑ ❑ Yes No NA NE • ❑ ❑ ❑ • ❑ ❑ ❑ • ❑ • ❑ Yes No NA NE • • ❑ ❑ ❑ • ❑ ❑ ❑ • ❑ ❑ ❑ • ❑ ❑ ❑ Yes No NA NE • • ❑ ❑ ❑ • ❑ ❑ ❑ • ❑ ❑ ❑ Yes No NA NE • ❑ ❑ ❑ • ❑ ❑ ❑ • ❑ ❑ ❑ Page# 4 Permit: NC0026573 Inspection Date: 08/13/2020 Owner - Facility: Catawba River Pollution Control Facility Inspection Type: Compliance Evaluation Primary Clarifier Is the site free of weir blockage? Is the site free of evidence of short-circuiting? Is scum removal adequate? Is the site free of excessive floating sludge? Is the drive unit operational? Is the sludge blanket level acceptable? Is the sludge blanket level acceptable? (Approximately'/4 of the sidewall depth) Comment. Blanket checked multiple times daily. Aeration Basins Mode of operation Type of aeration system Is the basin free of dead spots? Are surface aerators and mixers operational? Are the diffusers operational? Is the foam the proper color for the treatment process? Does the foam cover less than 25% of the basin's surface? Is the DO level acceptable? Is the DO level acceptable?(1.0 to 3.0 mg/I) Comment: Continuous DO read system. Secondary Clarifier Is the clarifier free of black and odorous wastewater? Is the site free of excessive buildup of solids in center well of circular clarifier? Are weirs level? Is the site free of weir blockage? Is the site free of evidence of short-circuiting? Is scum removal adequate? Is the site free of excessive floating sludge? Is the drive unit operational? Is the return rate acceptable (low turbulence)? Is the overflow clear of excessive solids/pin floc? Is the sludge blanket level acceptable? (Approximately'/4 of the sidewall depth) Yes No NA NE • ❑ ❑ ❑ • ❑ ❑ ❑ • ❑ ❑ ❑ • ❑ ❑ ❑ • ❑ ❑ ❑ • ❑ ❑ ❑ • ❑ ❑ ❑ Yes No NA NE Diffused • ❑ ❑ ❑ ❑ ❑ • ❑ • ❑ ❑ ❑ • ❑ ❑ ❑ • ❑ ❑ ❑ • ❑ ❑ ❑ • ❑ ❑ ❑ Yes No NA NE • ❑ ❑ ❑ • ❑ ❑ ❑ • ❑ ❑ ❑ • ❑ ❑ ❑ • ❑ ❑ ❑ • ❑ ❑ ❑ • ❑ ❑ ❑ • ❑ ❑ ❑ • ❑ ❑ ❑ • ❑ ❑ ❑ • ❑ ❑ ❑ Page# 5 Permit: NC0026573 Inspection Date: 08/13/2020 Owner - Facility: Catawba River Pollution Control Facility Inspection Type: Compliance Evaluation Secondary Clarifier Yes No NA NE Comment: Blanket checked multiple times daily. Page# 6 [External] RE: Morgaton_Catawba RPCF_26573_pre- 2nd Public Notice Self, Eli <ESelf@morgantonnc.gov> Tue 5/24/2022 07:59 To: Yitbarek, Diana <diana.yitbarek@ncdenr.gov> Cc: Boris, Brad <BBoris@morgantonnc.gov>;Robert Vinay <Robert.Vinay@freese.com>;Mcgee, Keyes <keyes.mcgee@ncdenr.gov>;Montebello, Michael J <Michael.Montebello@ncdenr.gov>;Arney, Tim <TArney@morgantonnc.gov> 1 attachments (18 KB) Morganton WWTP NPDES Permit; CAUTION: External email. Do not click links or open attachments unless you verify. Send all suspicious email as an attachment to Report Spam. Diana, After discussing the posed question on the cover section with our engineers, we have come to a conclusion. The answer to your question is yes we would, to confidently meet the proposed 10.5 MGD permit requirements. Attached is a statement from Engineer Robert Vinay which reads: Eli, In their latest draft NPDES permit cover letter (dated May 31, 2022), the NCDEQ Permitting Unit asks the question of the City to "Please clarify, with the revised limits, whether the Facility needs an Authorization to Construct/upgrade before moving to the 10.5 MGD flow tier". We are assuming they are asking you if the existing plant can reliably treat a monthly average of 10.5 MGD, and if Freese and Nichols, as your consultant will provide an engineering certification stating such. Design of the Process Conversion Project in 2017 was based on influent flow characteristics from 7 years ago and performance of existing plant components at that time. Based on recent discussion with the plant's operation staff, and now that several years of performance data is available with the upgraded plant in operation, we believe that a re-evaluation of plant capacity would be prudent prior to offering a current engineering opinion regarding the plant's design capacity. Thanks, Eli Self Superintendent Wastewater Treatment Plant Morganton, NC 828-438-5375 From: Yitbarek, Diana <diana.yitbarek@ncdenr.gov> Sent: Friday, May 6, 2022 1:21 PM To: Self, Eli <ESelf@morgantonnc.gov> Cc: Boris, Brad <BBoris@morgantonnc.gov>; Robert Vinay <Robert.Vinay@freese.com>; Mcgee, Keyes <keyes.mcgee@ncdenr.gov>; Montebello, Michael J <Michael.Montebello@ncdenr.gov>; Arney, Tim <TArney@morgantonnc.gov> Subject: Morgaton_Catawba RPCF_26573_pre- 2nd Public Notice © THIS EMAIL ORIGINATED FROM OUTSIDE THE CITY CAUTION: Don't be quick to click! We're counting on you! This email is from an external sender! Don't click on links or open attachments from unknown sources. If you know this is spam delete the message. If you believe this message is a phish attack or you are unsure what to do, contact IRMS @ mis@ci.morganton.nc.us. Good afternoon, Eli - Hope this message finds you well. Please find attached the courtesy draft NPDES permit package. Please address the question you will find in the Cover Letter's comment section, and let me know if you have any comments or questions by May 24th. Thank you, Diana Yitbarek (she/her) Engineer T: 919-707-9130 NPDES Municipal Permitting Unit NC Department of Environmental Quality/ Division of Water Resources Email correspondence to and from this address is subject to the North Carolina Public Records Law and may be disclosed to third parties. From: Self, Eli <ESelf@morgantonnc.gov> Sent: Wednesday, March 30, 2022 08:50 To: Yitbarek, Diana <diana.yitbarek_@ ncdenr.gov>; Montebello, Michael J <Michael.Montebello_@ ncdenr.gov> Cc: Boris, Brad <BBoris@morgantonnc.gov>; Robert Vinay <Robert.Vinayyfreese.com>; Mcgee, Keyes <keyes.mcgeePncdenr.gov>; Kenneth Bruce <Kenneth.Bruce@freese.com>; Nick Landes <Nick.Landes@freese.com>; Wiggs, Linda <linda.wiggL@ncdenr.gov>; Arney, Tim <TArney_ morgantonnc.gov>; Annas,Rex <RAnnas_. morgantonnc.gov> Subject: RE: [External] RE: Morgaton_Catawba RPCF_26573_pre-issuance CAUTION: External email. Do not click links or open attachments unless you verify. Send all suspicious email as an attachment to Report Spam. Permit writing, After much discussion, we request to keeping the 13.0 MGD flow tier for the upcoming permit. If you have any further questions, please let us know. Thanks, Eli Self Superintendent Wastewater Treatment Plant Morganton, NC 828-438-5375 From: Self, Eli [mailto:ESelfj morgantonnc.gov] Sent: Tuesday, March 8, 2022 12:13 PM To: Yitbarek, Diana <diana.yitbarek@ncdenr.gov>; Boris, Brad <BBoris@morgantonnc.gov>; Robert Vinay [External] RE: Morganton CRPCF_NC0026573 Permit Questions A 0 01 0 ro 0 N N W N V o w O J h To:Yitbarek, Diana <diana.yitbarek©ncdenr.gov> Cc: Annas,Rex <RAnnas@morgantonnc.gov>;Arney, Tim <TArney@morgantonnc.gov>;Wiggs, Linda <linda.wiggs@ncdenr.gov>;Boris, Brad <BBoris@morgantonnc.gov> CAUTION: External email. Do not click links or open attachments unless you verify. Send all suspicious email as an attachment to Report Spam. c 0 L O 3 m as w E 0) o. c bb C "O N 0) C 0) "O 2 0. N w ) E Anyway, so now we will go back and revise the eDMRs again. I also forgot to update the antimony from 4/11/2018, so the new list of eDMR's corrections and the corresponding paperwork (attached PDF) are as follows: u u a m a 1 .. o0 00 n Q1 00 I\ N .--I 01 01 In O 01 O O n u e-I N M I!) l0 W We are sorry for the confusion and the incorrect data, I hope we have cleared all the missing/wrong parameters for the permit renewal. A 0 00 0 0 c 0 E V `o A 0 m N 13 00 .110 0 c ra c 00 00 ri C 0 C 0 0 E 001 E Q O E v H A > > c E i oo ¢ 0, Q `c ri W "O O N ..-I V 00 In C U N .-I @) O O NO E CZ1 M `0 U aOa E 0 "O O Z f0 C C�pp ]• C `0 m V ccO l!J N ' -0 f1U11• W T., 0) goC c u . F- e c d Ec ¢ a LL 10n) H u I' I0" 0 We have double checked all of our copper results referencing the data sheet draft. The only result that was incorrect was 10/5/2017 — correct result was 0.010 mg/I. Attached is the lab sheet. I will now begin to update all of the eDMR's incorrect results with the correct results. These will be as follows: 01 01 to O V a N u N ri N M n l0 Look forward to hearing back from you, CAUTION: External email. Do not click links or open attachments unless you verify. Send all suspicious email as an attachment to Report Spam. See attachment for signed copy of the chemical addendum. Let me know if you need anything else. ) \ ) Good afternoon, Eli - Thank you. We have an additional request for this submittal: Since we want to maintain the format and also know who reports the form and when. Could you please pdf the Chemical Addendum form and add a signature block with a date next to your note? Thank you and please let me know if you have any questions. Division of Water Resources $@ƒ "Please check with the appropriate staff before visiting our offices, as we may be able to handle your requests by phone or email. CAUTION: External email. Do not click links or open attachments unless you verify. Send all suspicious email as an attachment to Report Spam. Morganton CRPCF_NC0026573 (pre -public notice) Yitbarek, Diana <diana.yitbarek@ncdenr.gov> Thu 10/21/2021 13:50 To: Wiggs, Linda <linda.wiggs@ncdenr.gov> Cc: Mcgee, Keyes <keyes.mcgee@ncdenr.gov> Linda - apologies I forgot to include you in the email below. From: Yitbarek, Diana <diana.yitbarek@ncdenr.gov> Sent: Thursday, October 21, 2021 13:28 To: Self, Eli <ESelf@morgantonnc.gov> Cc: Mcgee, Keyes <keyes.mcgee@ncdenr.gov> Subject: Morganton CRPCF_NC0026573 (pre -public notice) Good afternoon, Eli We are close to sending the permit package for public notice and wanted to update you on a few items: 1. Aluminum - We are interested in assessing the discharge of the effluent based on EPA's 2018 aquatic life criteria - https://www.epa.gov/wqc/2018- final-aquatic-life-criteria-aluminum-freshwater; however, we need additional information; therefore, a. The Division will require Aluminum (Al) monitoring in a quarterly basis. b. To calculate a specific instream target value (ITV) for Al, specific dissolved organic carbon (DOC), hardness, and pH data are needed. We will add a DOC monitoring requirement on a quarterly basis, as well. The ITV will be assessed in the next permit cycle. 2. Long Term Monitoring Plan (LTMP) update required. a. The LTMP currently lists Al as an SIU limited pollutant. Since that is not the case anymore, please update the LTMP document to list the Al monitoring as an NPDES required pollutant. i. The attachments to the fact sheet will convey that information in the pollutants of concern (POC) review form. Please address any further comments to the LTMP, and when ready, please submit the updated LTMP to Keyes McGee (cc'd here) Thanks for all your assistance in this process, and please let me know if you have any questions or if you'd like to have a virtual meeting with us. Best, -Diana Diana Yitbarek (she/her) Engineer II T: 919-707-9130 i n .yitbarek(aa ncdenr.gov NPDES Municipal Permitting Unit NC Department of Environmental Quality/ Division of Water Resources Mailing: 1617 Mail Service Center, Raleigh, NC 27699-1617 Physical: 512 North Salisbury Street Raleigh NC 27604 "Please check with the appropriate staff before visiting our offices, as we may be able to handle your requests by phone or email. We can also be available via Microsoft Teams or other web -based calling services if requested. Thanks for your patience and stay safe. Email correspondence to and from this address is subject to the North Carolina Public Records Law and may be disclosed to third parties. From: Self, Eli <ESelf@morgantonnc.gov> Sent: Wednesday, September 22, 2021 14:36 To: Yitbarek, Diana <diana.yitbarek@ncdenr.gov> Cc: Annas,Rex <RAnnas@morgantonnc.gov> Subject: [External] RE: Catawba - Morganton RPCF (NC0026573) - NPDES Permit Renewal CAUTION: External email. Do not click links or open attachments unless you verify. Send all suspicious email as an attachment to I sport Spam. Diana, Our lab supervisor Rex has checked and all the aluminum results reported are correct. Eli Self Superintendent Wastewater Treatment Plant Morganton, NC 828-438-5375 From: Yitbarek, Diana <diana.yitbarek@ncdenr.gov> Sent: Wednesday, September 22, 2021 7:16 AM To: Self, Eli <ESelf@morgantonnc.gov> Subject: Catawba - Morganton RPCF (NC0026573) - NPDES Permit Renewal LL THIS EMAIL ORIGINATED FROM OUTSIDE THE CITY CAUTION: Don't be quick to click! We're counting on you! This email is from an external sender! Don't click on links or open attachments from unknown sources. If you know this is spam delete the message. If you believe this message is a phish attack or you are unsure what to do, contact IRMS @ mis@ci.morganton.nc.us. Thank you, Eli. I have updated the reasonable potential analysis (RPA) to include the 2018 sample for antimony. Regarding Aluminum, I'd like you to confirm that the following data reported in the DMR corresponds to what you have on your file. Date Data, ugll 7/11/2017 1010 1/25/2018 39 7/19/2018 119 1/29/2019 85 7/15/2019 423 9/24/2019 181 1/9/2020 604 7f7/2020 221 1/12/2021 160 7/20/2021 154 Thank you, -Diana Diana Yitbarek (she/her) Engineer II T: 919-707-9130 diana.yitbarelc@ncdenr guy NPDES Municipal Permitting Unit NC Department of Environmental Quality/ Division of Water Resources Mailing: 1617 Mail Service Center, Raleigh, NC 27699-1617 Physical: 512 North Salisbury Street, Raleigh, NC 27604 *Please check with the appropriate staff before visiting our offices, as we may be able to handle your requests by phone or email. We can also be available via Microsoft Teams or other web -based calling services if requested. Thanks for your patience and stay safe. Email correspondence to and from this address is subject to the North Carolina Public Records Law and may be disclosed to third parties. From: Self, Eli <ESelf@morgantonnc.gov> Sent: Thursday, September 16, 2021 07:48 To: Yitbarek, Diana <diana.yitbarek@ncdenr.gov> Cc: Annas,Rex <RAnnas@morgantonnc.gov> Subject: [External] RE: Catawba - Morganton RPCF (NC0026573) CAUTION: External email. Do not click links or open attachments unless you verify. Send all suspicious email as an attachment to Report Spam. Diana, We were able to track down the antimony test from 2018, it was missed by the Blue Ridge Labs in 2018 and we had to have them add parameter afterward that year. Attached is the results. Sb = <.0.01 mg/I Eli Self Superintendent Wastewater Treatment Plant Morganton, NC 828-438-5375 From: Yitbarek, Diana <diana.yitbarek@ncdenr.gov> Sent: Wednesday, September 15, 2021 3:09 PM To: Self, Eli <ESelf@morgantonnc.gov> Cc: Annas,Rex <RAnnas@morgantonnc.gov> Subject: Catawba - Morganton RPCF (NC0026573) ® THIS EMAIL ORIGINATED FROM OUTSIDE THE CITY LL CAUTION: Don't be quick to click! We're counting on you! This email is from an external sender! Don't click on links or open attachments from unknown sources. If you know this is spam delete the message. If you believe this message is a phish attack or you are unsure what to do, contact IRMS @ mis@ci.morganton.nc.us. Eli - Thank you so much for addressing my questions. Please sample and test for antimony. -Diana Diana Yitbarek (she/her) Engineer II T: 919-707-9130 d is na.yitbarekCal ncdenr.goy NPDES Municipal Permitting Unit NC Department of Environmental Quality/ Division of Water Resources Mailing: 1617 Mail Service Center, Raleigh, NC 27699-1617 Physical: 512 North Salisbury Street Raleigh NC 27604 "Please check with the appropriate staff before visiting our offices, as we may be able to handle your requests by phone or email. We can also be available via Microsoft Teams or other web -based calling services if requested. Thanks for your patience and stay safe. Email correspondence to and from this address is subject to the North Carolina Public Records Law and may be disclosed to third parties. From: Self, Eli <ESelf@morgantonnc.gov> Sent: Tuesday, September 14, 2021 11:25 To: Yitbarek, Diana <diana.yitbarek@a ncdncgov> Cc: Annas,Rex <RAnnas@morgantonnc.gov> Subject: [External] RE: Catawba - Morganton RPCF (NC0026573) CAUTION: External email. Do not click links or open attachments unless you verify. Send all suspicious email as an attachment to Report Spam. Hey Diana, I will do my best to clarify for each. We try to keep everything as mg/I for simplicity. Copper on 4/11/17 —the correct lab result is 0.013 mg/I - Lead on 4/19/18 — The correct lab result was <0.01 mg/I - Lead on 1/12/21 & 7/20/21— Both were correct at <0.001 mg/I & <0.001 mg/I Selenium on 7/19/18—the correct lab result is <0.01 mg/I - Temperature on 5/15/17 was a typo — correct result was 16.9 C Conductivity on 7/10/19 was a typo — correct result was 452 Antimony on PPA 2018 — after investigating, the test was not conducted for 2018 but was for 2017 from the chain of custodies. Dimethylphthalate on PPA 2017 — results of <0.0103 mg/I (see attachment) Dimethylphthalate on PPA 2018— results of <0.01 mg/I (see attachment) Aluminum analytical method is EPA 200.8 — see attachment for info. Let me know if you need any else. I assume we will need to get another antimony test conducted. Eli Self Superintendent Wastewater Treatment Plant Morganton, NC 828-438-5375 From: Yitbarek, Diana <diana.yitbarek@ncdenr.gov> Sent: Tuesday, September 14, 2021 8:14 AM To: Self, Eli <ESelf(&morgantonnc.gov> Subject: Catawba - Morganton RPCF (NC0026573) ® THIS EMAIL ORIGINATED FROM OUTSIDE THE CITY CAUTION: Don't be quick to click! We're counting on you! This email is from an external sender! Don't click on links or open attachments from unknown sources. If you know this is spam delete the message. If you believe this message is a phish attack or you are unsure what to do, contact IRMS @ mis@ci.morganton.nc.us. Good morning, Eli - I hope you are well. I just restarted working on the NPDES permit renewal for the Catawba River Pollution Control Facility. I have a few requests below. • Please clarify and update the following entry values in the eDMR as needed. o Copper, 4/11/2017 was 0.013 ug/I. Did the City want to report 13 ug/I? o Lead, 4/19/2018 was 10 mg/I. Did the City want to report to 10 ug/I? For the lead reported on 1/12/2021 and 7/20/2021, did the City mean to report <10 ug/I/0.01 mg/I? o Selenium, 7/19/2018, did the City mean to report <10 ug/I/0.01 mg/I? o Upstream temperature, 5/15/2017. There may be a typo. o Effluent conductivity, 7/10/2019. There may be a typo, or please confirm/explain. • Please provide laboratory reports for the following compounds: o Antimony - there was no 2018 result for this pollutant in the provided priority pollutant analysis (PPA). Please follow up with your lab. (Application, Part D. lists 3 sampling results) o Dimethyl phthalate - there was no 2017 and 2018 result for this pollutant in the provided PPA. Please follow up with your lab. (Application, Part D. lists 3 sampling results) • Please clarify what analytical method was used to test for aluminum and its ML/MDL. Thank you and please let me know if you have any questions, -Diana Diana Yitbarek (she/her) Engineer II T: 919-707-9130 d is na.yitbarek@ncdencgov NPDES Municipal Permitting Unit NC Department of Environmental Quality/ Division of Water Resources Mailing: 1617 Mail Service Center, Raleigh, NC 27699-1617 Physical: 512 North Salisbury Street Raleigh NC 27604 Q "Please check with the appropriate staff before visiting our offices, as we may be able to handle your requests by phone or email. We can also be available via Microsoft Teams or other web -based calling services if requested. Thanks for your patience and stay safe. Email correspondence to and from this address is subject to the North Carolina Public Records Law and may be disclosed to third parties. From: Yitbarek, Diana < i n .yitbarekCla ncdenr.go> Sent: Thursday, June 10, 2021 10:43 To: Self, Eli <ESelfl&morgantonnc.gov> Subject: Re: 2nd species needed - Fw: [External] RE: NC0026573, Morganton Good morning, Eli Thank you for the notification on completing the fourth and final second species test. All four tests passed! I will add the permit renewal to my queue and let you know once I restart working on it. Happy Thursday! -Diana Diana Yitbarek (she/her) Engineer II T: 919-707-9130 diana.yitbarek@ncdenr.gov NPDES Municipal Permitting Unit NC Department of Environmental Quality/ Division of Water Resources Mailing: 1617 Mail Service Center, Raleigh, NC 27699-1617 Physical: 512 North Salisbury Street Raleigh NC 27604 E Q� "Please check with the appropriate staff before visiting our offices, as we may be able to handle your requests by phone or email. We can also be available via Microsoft Teams or other web -based calling services if requested. Thanks for your patience and stay safe. Email correspondence to and from this address is subject to the North Carolina Public Records Law and may be disclosed to third parties. From: Self, Eli <ESelfl&morgantonnc.gov> Sent: Thursday, June 10, 202109:03 To: Yitbarek, Diana <diana.yitbarek@ncdenr.gov> Cc: Annas,Rex <RAnnas@a morgantonnc.gov> Subject: RE: 2nd species needed - Fw: [External] RE: NC0026573, Morganton CAUTION: External email. Do not click links or open attachments unless you verify. Send all suspicious email as an attachment to Report Spam. Good morning Diana, We have submitted our 4 second species tests to the appropriate branches. I want to confirm that we are caught up and can continue with our permit renewal. Please let me know if you need anything. Eli Self Superintendent Wastewater Treatment Plant Morganton, NC 828-438-5375 From: Yitbarek, Diana <diana.yitbarek(alncdenr.gov> Sent: Wednesday, January 20, 20218:57 AM To: Self, Eli <eself ci.morganton.nc.us> Subject: 2nd species needed - Fw: [External] RE: NC0026573, Morganton THIS EMAIL ORIGINATED FROM OUTSIDE THE CITY CAUTION: Don't be quick to click! We're counting on you! This email is from an external sender! Don't click on links or open attachments from unknown sources. If you know this is spam delete the message. If you believe this message is a phish attack or you are unsure what to do, contact IRMS @ mis@ci.morganton.nc.us. Good morning, Eli We can put the permit on hold for now. Please go ahead and schedule four (4) 2nd species tests and let me know once you have the results. Please let me know if you have any questions. Best, -Diana Diana Yitbarek Engineer II T: +1-919-707-9130 diana.yitbarek@ncdenr.gov NPDES Municipal Permitting Unit NC Department of Environmental Quality/ Division of Water Resources Mailing: 1617 Mail Service Center, Raleigh, NC 27699-1617 Physical: 512 N. Salisbury Street Rm. 925T Raleigh, NC 27604-1170 ;trfittps://attachments.office.net/owa/diana.yitbarek%4Oncdenr.goviservice.svc/s/GetAttachmentThumbnail? id=AAMkADNmOTIxZjdhLTEyMWYtN DEzMS1iOGNiLTkxNmZhYWJmZThI MABGAAAAAAChNtXPy901QhuVQ14DYFU BBwBXZLmYUZH014ikbNYDUx2JAAAAAAEPAABXZLmYUZHO14ikbNYDUx2JAAC9Fej6AAABEgAQADsU Dks G2-0bDg3pbgZetRwgZeh5s22CYcGDG8P5L4ZPj15-ij-OQFT_KupTpPDrNdTw140_ekyFyLAB9I1B4f3x0Vge0WZBVBo3P0Kmpnn5Xn MAAavVP_Qh6tHY2-EGzHmvcTvmOS9TjyOzfC19YZxh2cf5xV1gmM_K4TjW7Lkg3e3wxSUsDM "Please check with the appropriate staff before visiting our offices, as we may be able to handle your requests by phone or email. We can also be available via Microsoft Teams if requested. Thanks for your patience and stay safe. Email correspondence to and from this address is subject to the North Carolina Public Records Law and may be disclosed to third parties. From: Self, Eli <eself(Eci.morganton.nc.us> Sent: Wednesday, January 20, 2021 08:13 To: Yitbarek, Diana <diana.yitbarek@ncdenr.gov> Subject: RE: [External] RE: NC0026573, Morganton CAUTION: External email. Do not click links or open attachments unless you verify. Send all suspicious email as an attachment to Report Spam. Diana, We looked through everything we have in the lab from previous ORC and Lab supervisor then we called our outside lab to determine if a second species test was completed. Unfortunately we have no information showing the second species test was completed. The outside lab does have a spot open in February, would you like for us to go ahead and schedule it so you can at least have one test result for 2nd species? It would be fat head minnow. Eli Self Superintendent Wastewater Treatment Plant Morganton, NC 828-438-5375 From: Yitbarek, Diana [mailto:diana.yitbarek@ncdencgov Sent: Thursday, January 14, 2021 11:44 AM To: Self, Eli Subject: Re: [External] RE: NC0026573, Morganton ® THIS EMAIL ORIGINATED FROM OUTSIDE THE CITY CAUTION: Don't be quick to click! We're counting on you! This email is from an external sender! Don't click on links or open attachments from unknown sources. If you know this is spam delete the message. If you believe this message is a phish attack or you are unsure what to do, contact IRMS @ misGaci.morganton.nc.us. Eli, Thank you for your message and all the information you have provided so far. You are correct. The language about that test is on page 9. Best, -Diana Diana Yitbarek Engineer II T: +1-919-707-9130 diana.yitbarek@ncdenr.gov NPDES Municipal Permitting Unit NC Department of Environmental Quality/ Division of Water Resources Mailing: 1617 Mail Service Center, Raleigh, NC 27699-1617 Physical: 512 N. Salisbury Street Rm. 925T Raleigh, NC 27604-1170 j1ttps://attach ments.office. n et/owa/di a na.yitha rek%4oncd enr.gov/service.svc/s/G etAtta ch mentThu mb nai I? id=AAMIcADNmOTIxZjdhLTEyMWYtNDEzMS1iOGNILTkxNmZhYWJmZThIMABGAAAAAAChNtXPy901QhuVQADYFUBBwMamYUZHcgaikbNYDUx2JAAAAAAEPAABXZLmYUZHq MMAYDUx2JAAC9Fej6AAABEgAQAIM3Myf G2-0bDg3pbcgetRwilZeh5s22CYcGM8P5L4ZPj15-ij-OQFT_KupTpPDrNdTw140_ekyFyLAB9I1B4f3x0VgeOWZBVBo3POKmpnn5Xn MAAavVP_Qb6tHY2-EGzHmvcTvm059TjyOzfC19YZxb2cf5xV1gmM_K4TjW7Lkg3e3wx5UsDM "Please check with the appropriate staff before visiting our offices, as we may be able to handle your requests by phone or email. We can also be availabk via Microsoft Teams if requested. Thanks foryourpatience and stay safe. Email correspondence to and from this address is subject to the North Carolina Public Records Law and may be disclosed to third parties. From: Self, Eli <eselfC7a ci.morganton.nc.us> Sent: Thursday, January 14, 2021 11:19 To: Yitbarek, Diana <diana.yitbarek@ncdenr.gov> Subject: [External] RE: NC0026573, Morganton CAUTION: External email. Do not click links or open attachments unless you verify. Send all suspicious email as an attachment to Report Spam. Diana, I am currently looking into the second species request. My Lab Supervisor is out today so I will have to wait to see if we have any results. I am unaware that we needed the 2nd species test but looking over our permit, it does mention on page 9 of an "Additional Toxicity Testing Requirements". The language in this section of the permit is confusing but I believe this is what you were asking about. Eli Self Superintendent Wastewater Treatment Plant Morganton, NC 828-438-5375 From: Yitbarek, Diana [mailto:diana.yitbarek@ncdencgov Sent: Thursday, January 14, 2021 9:18 AM To: Self, Eli Subject: NC0026573, Morganton LL THIS EMAIL ORIGINATED FROM OUTSIDE THE CITY LL CAUTION: Don't be quick to click! We're counting on you! This email is from an external sender! Don't click on links or open attachments from unknown sources. If you know this is spam delete the message. If you believe this message is a phish attack or you are unsure what to do, contact IRMS @ mis@ci.morganton.nc.us. Dear Eli, It was good to talk to you yesterday. Per our conversation about no plans for expansion for this facility, I will remove the 13.0 MGD flow tier page from the permit. I need your support with the following: 1. I noted that the toxicity testing data results were recorded under section E.4. of the application, however, I can't tell whether a four 2nd/alternate/multiple species test was performed. Could you please double check with your lab results? and send me a scan of the 2nd species test. Here is additional information on the testing. 2. Please confirm if the City still has 2 SIUs and 3 NSCIUs Thanks, -Diana From: Yitbarek, Diana <diana.yitbarek(alncdenr.gov> Sent: Tuesday, January 12, 2021 13:02 To: Self, Eli <eself ci.morganton.nc.us> Subject: NC0026573, Morganton When: Wednesday, January 13, 2021 9:00 AM-9:30 AM. Where: Tomorrow at 9 am works for me. Look forward to talking to you then. I will call you on the phone and I am adding a link to MS Teams in case we need to share screens. From: Self, Eli <eself ci.morganton.nc.us> Sent: Tuesday, January 12, 2021 5:45:57 PM To: Yitbarek, Diana <diana.yitbarek@ncdenr.gov> Subject: Re: [External] RE: Request - NC0026573, Catawba River Pollution Control Facility, City of Morganton, Burke County, ARO CAUTION: External email. Do not click links or open attachments unless you verify. Send all suspicious email as an attachment to Report Spam. Unable to do 1 today. Can we try again at 9am tomorrow? Eli Self Superintendent Wastewater Treatment Plant Morganton, NC 828-438-5375 From: Yitbarek, Diana <diana.yitbarek@ncdenr.gov> Sent: Tuesday, January 12, 2021, 11:04 AM To: Self, Eli Subject: Re: [External] RE: Request - NC0026573, Catawba River Pollution Control Facility, City of Morganton, Burke County, ARO LL THIS EMAIL ORIGINATED FROM OUTSIDE THE CITY LL CAUTION: Don't be quick to click! We're counting on you! This email is from an external sender! Don't click on links or open attachments from unknown sources. If you know this is spam delete the message. If you believe this message is a phish attack or you are unsure what to do, contact IRMS @ mis@ci.morganton.nc.us. Thanks for your message, Eli. I will give you a call at 1 pm. Let me know if that time works or if you prefer another time. For now, I will attach the current form 2A with the instructions, and here is the link to the 40 CFR 122.21(m) and (n). We will go through it on our call. Best, -Diana Diana Yitbarek Engineer II T: +1-919-707-9130 i n .yitbarekCla ncdenr.guv NPDES Municipal Permitting Unit NC Department of Environmental Quality/ Division of Water Resources Mailing: 1617 Mail Service Center, Raleigh, NC 27699-1617 Physical: 512 N. Salisbury Street Rm. 925T Raleigh, NC 27604-1170 G`Jfittps://attach ments.office. n et/owa/di a na.yitba rek%40ncd encgov/service.svc/s/G etAtta ch mentThu mb nai I? id=AAMkADNmOTIxZjdhLTEyMWYtN DEzM51iOGNiLTkxNmZhYWJmZThI MABGAAAAAACbNtXPy901QbxVQ14DYFU BBwBXZLmYUZHgQ4ikbNYDUx2JAAAAAAEPAABXZLmYUZHgQ4ikbNYDUx2JAAC9Fej6AAABEgAQAIM3Myf G2-OhDg3phgZetRwgZeh5s22CYcGfxi8P5L4ZPj15-ij-OQFT_KupTpPDrNdTw140_ekyFyLAB911B4f3xOVgeOWZBVBo3POKmpnn5Xn MAAavVP_Qh6tHY2-EGzHmvcTvmOS9TjyOzfC19YZxh2cf5xV1gmM_K4TjW7Lkg3e3wxSUsDM °Please check with the appropriate staff before visiting our offices, as we may be able to handle your requests by phone or email. We can also be available via Microsoft Teams if requested. Thanks for your patience and stay safe. Email correspondence to and from this address is subject to the North Carolina Public Records Law and may be disclosed to third parties. From: Self, Eli <eself(alci.morganton.nc.us> Sent: Tuesday, January 12, 2021 10:35 To: Yitbarek, Diana <diana.yitbarek@ncdenr.gov> Cc: Montebello, Michael J<Michael.Montebello@ncdenr.gov>• Wiggs, Linda <linda.wiggs@ncdenr.gov> Subject: [External] RE: Request - NC0026573, Catawba River Pollution Control Facility, City of Morganton, Burke County, ARO CAUTION: External email. Do not click links or open attachments unless you verify. Send all suspicious email as an attachment to Report Spam. Diana, On EPA Form 2A, what would you want me to check for section 1.6 on page 2, and section 1.5 on page 3? When you are available, please give me a call as I have other questions. Thanks, Eli Self Superintendent Wastewater Treatment Plant Morganton, NC 828-438-5375 From: Self, Eli Sent: Tuesday, January 12, 2021 8:18 AM To: Yitbarek, Diana' Cc: Montebello, Michael J; Wiggs, Linda Subject: RE: Request - NC0026573, Catawba River Pollution Control Facility, City of Morganton, Burke County, ARO Diana, I have received the email and I will work on gathering the information needed. Thanks, Eli Self Superintendent Wastewater Treatment Plant Morganton, NC 828-438-5375 ;city-seal-500px From: Yitbarek, Diana[mailto:diana.yitbarekCancdenr.gp_v] Sent: Tuesday, January 12, 2021 8:15 AM To: Self, Eli Cc: Montebello, Michael J; Wiggs, Linda Subject: Request - NC0026573, Catawba River Pollution Control Facility, City of Morganton, Burke County, ARO ® THIS EMAIL ORIGINATED FROM OUTSIDE THE CITY CAUTION: Don't be quick to click! We're counting on you! This email is from an external sender! Don't click on links or open attachments from unknown sources. If you know this is spam delete the message. If you believe this message is a phish attack or you are unsure what to do, contact IRMS @ mis@ci.morganton.nc.us. Dear Eli Self, I hope this message finds you well. As Linda mentioned previously, I am the assigned permit writer for the subject Facility. I recently started reviewing the NPDES permit application for renewal submitted by the City on September 3, 2019, and have a couple of requests: 1. Please submit the signed Annual Monitoring and Pollutant Scan for 2016 - 2019. Scanned copies with your signature would suffice. 2. Please provide coordinates for upstream and downstream location points. 3. Please submit the mercury minimization plan (MMP). 4. Since the EPA form 2A has been updated, please complete this form. I'll attach it as an addendum to your application. Thanks for your continued cooperation with the NPDES program and your work protecting public health and the environment. Please confirm the reception of this email and let me know if you have any questions. Best, -Diana Diana Yitbarek Engineer II T: +1-919-707-9130 diana.yitbarek@ncdenr.gov NPDES Municipal Permitting Unit NC D@pattment of Environmental Quality/ Division of Water Resources Mailing: 1617 Mail Service Center, Raleigh, NC 27699-1617 Physical: 512 N. Salisbury Street Rm. 925T Raleigh, NC 27604-1170 'Mips://attachments.office.nesJowa/dianayitbarek%40ncdem.gov/service.svc/s/GetAttachmentThumbnail? id=AAMkADNmOTbaj dhLTEyM W YtNDEzM S 1 iOGNiLlkocNmZhY W JmZTh1MABGAAAAAACbNtXPy901 Qbx V QI4DYFUBBwBXZLmYUZHgQ4ikbNYDUx2JAAAAAAEPAABXZLmYUZHgQ4ikbNYDUx2J. G2-ObDg3pbgZetRwgZeh5s22CYcGOCi8P5L4ZPj 15-ij-OQFT_KupTpPDINdTw140_ekyFyLAB9I1B4f3xOVgeOWZBVBo3POKmpnn5XnMAAavVP_Qb6tHY2-EGzHmvaymOS9TjyOz1C19YZxb2cf5xV 1gmM_K4Tj5 *Please check with the appropriate staff before visiting our offices, as we may be able to handle your requests by phone or email. We can also be available via Microsoft Teams if requested. Thanks for your patience and stay safe. Email correspondence to and from this address is subject to the North Carolina Public Records Law and may be disclosed to third parties. Microsoft Teams meeting Join on your computer or mobile app Click here to join the meeting Learn More I M in94ptions Microsoft Teams meeting Join on your computer or mobile app Click here to join the meeting Join with a video conferencing device ncgov@m.webex.com Video Conference ID: 114 429 195 6 Alternate VTC instructions Learn More I Meeting options Microsoft Teams meeting Join on your computer or mobile app Click here to join the meeting Join with a video conferencing device ncgov@m.webex.com Video Conference ID: 115 249 393 0 Alternate VTC instructions Learn More I Meeting opticsn :EPA Environmental Protection United States Agency Office of Water EPA 822-F-18-003 December 2018 Fact Sheet: Final 2018 Aquatic Life Ambient Water Quality Criteria for Aluminum in Freshwaters Summary The EPA has published final updated aquatic life ambient water quality criteria recommendations for aluminum in freshwater under Section 304(a)(1) of the Clean Water Act to reflect the latest scientific knowledge. There are not enough data to support the development of estuarine/marine aluminum criteria at this time. Aluminum can inhibit an aquatic organism's ability to regulate salt concentrations and clog fish gills, potentially resulting in death or affecting growth and reproduction. States and authorized tribes can adopt these criteria into their water quality standards or can adopt other aluminum criteria that is scientifically defensible based on local or site -specific conditions. These final criteria are not a regulation, nor do they impose a legally -binding requirement. These criteria provide information for states to develop science -based standards that reflect site -specific factors and are protective against the effects of aluminum on aquatic life. Background The EPA first published criteria for aluminum in 1988. The updated aluminum criteria better reflect the latest science. Studies have shown that three water chemistry parameters — pH, total hardness, and dissolved organic carbon (DOC) —can affect the toxicity of aluminum by affecting the bioavailability of aluminum in the water to aquatic species. Unlike the fixed acute and chronic values found in the 1988 criteria recommendation, these final 2018 recommended criteria provide users the flexibility to develop site -specific criteria based on local water chemistry. The EPA released a draft of this criteria in 2017 for public comment and has reviewed the comments and updated the document. What is Aluminum and How Does It Enter the Water? Aluminum is found in most soils and rocks. It is the third most abundant element and the most common metal in the earth's crust. Aluminum can enter the water via natural processes, like weathering of rocks. Aluminum is also released to water by mining, industrial processes using aluminum, and in waste water and drinking water treated with alum, an aluminum compound. How Does Aluminum Affect Aquatic Life? Aluminum is considered a non -essential metal because fish and other aquatic life do not need it to function. Elevated levels of aluminum can affect some species' ability to regulate ions, like salts, and inhibit respiratory functions, like breathing. Aluminum can accumulate on the surface of a fish's gill, leading to respiratory dysfunction, and possibly death. Aquatic plants are generally less sensitive to aluminum than fish and other aquatic life. What is a Water Chemistry Parameter and Why is it Important? Bioavailability is the measure of whether a substance in the environment is available to affect living organisms, like fish. The bioavailability of aluminum is dependent on the chemistry of the water. The more bioavailable the aluminum is, the more likely it is to cause a toxic effect. The water chemistry parameters that have the greatest impact on aluminum's bioavailability are pH, total hardness, and DOC. pH: a low pH generally makes it easier for aluminum to be dissolved, and therefore more bioavailable. At higher pH, aluminum speciation changes make it more bioavailable. Hardness: generally, higher hardness values mean there are more ions present. These ions compete with aluminum and make aluminum less bioavailable. DOC: higher dissolved organic carbon reduces bioavailability. Aluminum is bound to DOC, making the aluminum less bioavailable to aquatic organisms. What are the Recommended Criteria for Aluminum in Freshwater for the Protection of Aquatic Life? The recommended aquatic life criteria for aluminum in freshwater depend on a site's water chemistry parameters. Unlike the fixed values found in the 1988 criteria document, these criteria use Multiple Linear Regression (MLR) models to normalize the toxicity data and provide a range of acceptable values. The criteria are calculated based on a site's pH, total hardness, and DOC. See Table 1 for a comparison of 2018 and 1988 criteria values. For freshwater criteria, users can enter their site's water quality parameters into the Aluminum Criteria Calculator V.2.0.xlsm or use the lookup tables in the criteria document's appendix. The resulting acute criterion indicates that freshwater organisms would be protected if the one -hour average concentration is not exceeded more than once every three years on average. The chronic criterion indicates that freshwater organisms would be protected if the four -day average concentration is not exceeded more than once every three years on average. Where can I find more information? For more information and to view the aluminum criteria document and the criteria calculator, please visit EPA's website at www.epa.gov/wgc/aquatic- life-criteria-aluminum or email Diana Eignor at eignor.diana@epa.gov. Table 1: Comparison of the EPA's 2018 and 1988 National Recommended Aquatic Life Criteria for Aluminum Version Freshwater Acute' (1 hour, total recoverable aluminum) Freshwater Chronic' (4-day, total recoverable aluminum) 2018 Criteria (vary as a function of a site's pH, total hardness, and DOC) 1- 4,800 µg/Lb 0.63 - 3,200 µg/Lb 1988 Criteria (pH 6.5-9.0, across all total hardness and DOC ranges) 750 µg/L 87 µg/L 'Values are recommended not to be exceeded more than once every three years on average. b Values will be different under differing water chemistry conditions. Dear Permit Renewal Team, We at the City of Morganton intend in this letter to appeal the decision to remove 8.0 MGD permit as well as address potential changes of the permit. Included in this document are the following: 1. Rainfall and I&I challenges 2. Investments into wastewater system 3. Literature from engineer design studies 4. Nutrient removal (N&P) for 10.5 MGD permit 5. Literature from flow rate study in 2017 6. Removal of 13.0 MGD permit 7. PFAS Monitoring requirements 1. Rainfall and I&I Challenges As spoke about in the meeting on 2/9/2022, we believe the challenges Morganton NC had during the year 2018 and 2019 were not indicative of normal operations and thus feel unwarranted to be moved to the 10.5 MGD permit. We have compiled data points from flow, rain totals and averages over the past several years to show these challenges. Below are graphs of the flow and total rain fall for the area of Morganton NC over the last 5/6 years. 7 6 5 2 4 3 0 L. 2 1 0 Wm I 1 2016 2017 Rain vs Flow 2018 2019 Rain (inches) —•—Flow (MGD) 2020 • 2021 90 80 70 60 50 40 30 20 10 0 Rain Inches E 0 NC0026573 Average Flow by Month Compared to Average Flow by Year 12.00 10.00 8.00 6.00 4.00 2.00 0.00 Ln Ln Lf1 Lo LD LD N N N CO CO CO 01 rn al 0 0 0 .-i .-i .-i .-i .-i .-i .-i .-i .-i .-i .-i .-i .-i .-i .-i N N N N N N 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 N N N N N N N N N N N N N N N N N N N N N ci LA O1 —1 Lr 6c1 LA O1 c1 LA O1 c1 Lr 6c1 Lr 6c1 Lr 60 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 —Flow (mgd) Average Flow Referencing the graphs above, one challenge Morganton had was much higher than normal rainfall for the calendar year of 2018, 2019 and 2020. As mentioned in the meeting, several other cities also had challenges with the rainfall during this period of years. Morganton struggled with I&I issues. In December 2019, a major 30" sewer line was repaired. There is a significant difference shown after the line was repaired, when looking at top graph, 2020 shows higher amounts of rainfall with lower annual flow than in 2019. 2. Investments into wastewater system Morganton continues to invest in its collection system. Capital projects are ongoing to repair sewer lines and rehabilitate manhole. Currently there are engineered designs completed and near ready for bidding to construct a new lift station to replace a major existing station. This is our largest and most extensive lift station, pumping an estimated average of 1.5-2.0 MGD to the plant. This is estimated to cost around $5 million. Also currently is an engineer design and planning phase for another lift station overhaul that will cost a significant amount of money to complete in the coming year. The WWTP has gone through three major construction projects during and since the previous permit cycle. Over $20 million has been invested into the plant since 2010. The primary focus of the investments has been to repair or replace failing infrastructure with some planning to address future regulatory requirements and potential future expansion. 3. Literature from Engineer design study from 2015 Below are some excerpts from a "Secondary Process Conversion Feasibility Memorandum" provided by engineering firm Freese and Nichols from year 2015. This study was used to design and construct our current operating facility. Construction was completed in July 2019. What was constructed is briefly mention from study proposal as the option #3: "3. Construct two rectangular aeration basins with dimensions identical to the current EQ basin and install blowers and fine -pore diffusers to provide aeration in both new basins. Retain the Interim Aeration Basin and leave its surface aerators in place, allowing it to serve two purposes: an EQ basin for storage of peak flows (with aeration/mixing), or a backup aeration basin to allow maintenance of either aeration basin. It would still be advisable to convert Reaction Basin 3 for peak flow storage in case the plant would receive peak flows while one of the aeration basins was out of service for maintenance." Next, using this design above, calculations were conducted and designed to accommodate the 2016 flow average of 4.5 MGD, 8.0 MGD, and 10.5 MGD. Conclusions are following the chart below in the design used for the authorization to construct from 2017. Morganton WWTP Aeration Basin Sizing Parameter Units Current Conditions Permitted Conditions Min Weekend Average Month Ann Avg Dsgn Q Peaking Factor Peak Month Peaking Factor Peak Day Flow Rate MGD 2.3 4.5 8 10.5 Influent BCD mg/L 414 374 350 Primary BOD removal % 43.2 43.2 37.1 Primary effluent BOD mg/L 235 212 220 Primary effluent BOD lb/day 4,511 7,973 14,688 1.4 20,564 2.0 29,377 Influent NH3-IN mg/L 22 22 22 Primary NH3-N removal % 13.6 13.6 13.6 Primary effluent NH3-N mg/L 19 19 19 Primary effluent NH3-N lb/day 365 713 1,268 1.4 1,775 2.0 2,535 Number ABs in service --- 2 2 3 3 3 BOD Organic Loading Ib/1000 ft3-d 12.4 21.9 26.9 37.6 54 Oxygen required (AOR) Ib/hr 234 427 778 1,089 1,556 lb/day 5,627 10,242 18,671 26,139 37,341 lb/day/basin 1,876 3,414 6,224 8,713 12,447 "The following spreadsheet was developed to calculate process organic loadings (lbs BOD per thousand cubic feet per day) as a function of influent flow rate, primary effluent concentrations, and the number of aeration basins in service. The goal of the design is to provide enough aeration volume to keep the permitted peak month BOD organic loading rate below, or just slightly above, 35 lbs BOD / 1000 cu ft - day, a conservative design criterion for single -stage nitrification. The peak month and peak day organic loadings are calculated using a typical organic loading peaking factor of 1.4 and 2.0 respectively. The results indicate that to meet the permitted condition of 10.5 MGD the plant will require three aeration basins. The existing EQ basin will be converted to an aeration basin. The two proposed basins will match the existing EQ basin size: 225 ft long by 45 ft wide, with 18 ft SWD, and a volume of 1.363 MG. The design has incorporated flexibility to add a fourth aeration basin all of which can be zoned into anaerobic and anoxic zones to provide biological nutrient removal if required in the future." 4. Nutrient Removal (nitrogen and phosphorous) Below is information concerning total effluent nitrogen and total phosphorous for the calendar years of 2019-2020-2021. These years were selected because of the new secondary process that was constructed and completed in 2019 and how plant is currently operated. Data was collected from eDMR and totals calculated. 2019 N mg/I P mg/I Month MG N Ibs P Ibs Jan 11.2 3.84 278.41 26006 8916 Feb 11.1 2.72 282.99 26198 6420 Mar 10.5 0.376 217.49 19046 682 Apr 12.29 1.87 230.06 23581 3588 May 11.76 4.63 171.35 16806 6617 June 11.2 6.1 239.03 22327 12160 July 11.2 2.3 147.8 13806 2835 Aug 11.11 2.68 137.73 12762 3078 Sep 12.7 0.544 145.69 15431 661 Oct 11.32 9.97 155.33 14665 12916 Nov 12.07 1.91 164.78 16587 2625 Dec 12.37 4.38 183.12 18892 6689 Total 226,105 67,187 10.5 MGD permit limit 146,659 33,200 2020 N mg/I P mg/I Month MG N Ibs P Ibs Jan 11.94 4.24 214.43 21353 7583 Feb 14.21 1.23 157.26 25412 2200 Mar 13.21 2.19 139.38 17326 2872 Apr 11.92 10.4 172.22 13856 12089 May 13.24 3.75 149.41 19017 5386 June 12.51 3.45 124.58 15588 4299 July 13.27 2.97 178.71 13787 3086 Aug 13.79 2.15 177.97 20553 3204 Sep 13.74 3.15 186.48 20394 4675 Oct 13.83 2.09 205.65 21509 3250 Nov 12.04 2.45 179.04 20650 4202 Dec 13.49 3.85 166.00 20143 5749 Total 229,589 58,596 10.5 MGD permit limit 146,659 33,200 2021 N mg/I P mg/I Month MG N Ibs P Ibs Jan 12.76 1.36 184.45 19629 2092 Feb 11.88 1.89 175.34 18275 2907 Mar 11.26 3.9 194.45 16466 5703 Apr 12.48 3.55 150.87 20239 5757 May 11.72 4.87 142.35 14747 6128 June 10.95 3.2 133.13 13000 3799 July 13.85 4.33 138.08 15378 4808 Aug 12.77 2.97 151.76 14706 3420 Sep 11.1 2.48 132.48 14049 3139 Oct 12.3 3.19 160.67 13590 3525 Nov 11.44 3.21 135.03 15329 4301 Dec 12.05 2.74 136.38 13570 3086 Total 188,978 48,665 10.5 MGD permit limit 146,659 33,200 As shown, the total nutrients vs. the 10.5 MGD purposed permit limits would not be met. Further construction of a dedicated system to remove nutrients would have to be implemented. Below is an excerpt from the same engineering study referenced above: "At some point in the future, the state regulatory agencies probably will impose nutrient limits on the City's treatment plant. Implementation of BNR processes for total nitrogen and phosphorus typically requires conversion of one-fourth to one-third of the secondary treatment volume to anaerobic and anoxic zones. At that point, four (4) dedicated aeration basins with internal nutrient removal infrastructure will be needed to provide the 8.1 MGD permitted plant capacity." 5. Flow Rate Study Morganton underwent a "Water and Wastewater Master Plan and Rate Study" in 2017 by engineering firm Freese and Nichols. This study helped show that the city is not anticipating the need for the 10.5 MGD permit flow in the upcoming years from population growth or projected industry needs. Table ES.1 Projected Population Year Service Area Population Water Wastewater 2015 31,965 20,089 2020 32,886 20,833 2025 33,834 21,605 2035 35,812 23,235 Table 6.1 Table ES.2 Projected Wastewater Flows Year Projected Wastewater Service Area Population Average Annual Dry Weather Flow (MGD] 2016 2D,089 5.5 2020 20,833 5.8 2025 21,605 6.0 2035 23,235 6.5 Historical Wastewater Flows Average Per Capita Annual Year Population WW1) Flow Flow Rainfall (MGD} (gpcd) (inches) 2011 2012 2013 2014 2015 20,557 20,455 20,333 20,211 20, D89 4.6 4.7 222 229 36.3 44.0 5.8 283 4.7 230 4.6 231 75.9 47.3 61.3 Average Maximum An evaluation summary was taken from the rate study below: "Wastewater Treatment Plant Capacity Evaluation: ...illustrates the historical average annual daily flow (AADF) from 2011 through 2015, projected average annual daily flows for each planning year and the permitted AADF and 80% of the permitted AADF under Part 1 and Part 11 of the NPDES permit. By the year 2035, the average annual flow to the treatment plant is expected to reach 6.5 MGD. This will trigger a move to Part II of the current NPDES permit and more stringent discharge limits. The City will need to begin planning for a treatment plant expansion when the AADF reaches 80% of the Part II permitted flow, 8.4 MGD. Based on the projected population and 2035 AADF of 6.5 MGD, the City will not need to begin planning additional treatment capacity until after 2035." Conclusion of engineering, further study will be required to determine the feasibility of the proposed 10.5 MGD permit for the plant for the future if required. The greatest challenges would be the N&P removal, the removal of additional sludge generated and settling capabilities of secondary system to comply with stricter parameters such as BOD. 6. Removal of 13.0 MGD permit We also appeal the decision of keeping the 13.0 MGD permit. Referencing the comments mentioned by the Southern Environmental Law Center, the City agrees with said comments; "....has no plans to expand. Expansion would require an "Authorization to Construct" from DEQ. We are aware of no reason why DEQ would provide limits for a flow level that cannot currently be accommodated at this facility. If expansion to 13 MGD flow becomes necessary, the proper course is to modify the permit active at that time. DEQ should not attempt to preauthorize the expansion for purposes of Section 402 of the Clean Water Act in this permit." 7. PFAS Monitoring requirements In regards with the decision over email to potentially require monitoring for PFAS for industries and plant effluent, we are not informed with the procedures or requirements needed to meet this proposal. We request more information associated to these requirements or the monitoring be postponed to future permit requirements as more solutions are developed for the removal of PFAS in wastewater streams. Sincerely, Eli Self — Wastewater Superintendent Brad Boris — Water Resources Director SOUTHERN ENV RONMENTAL CENTER Via Electronic Mail and U.S. Mail NCDEQ/DWR NPDES Permitting Branch c/o Diana Yitbarek 1617 Mail Service Center Raleigh, North Carolina 27699-1617 diana.yitbarek@ncdenr.gov 48 Patton Avenue, Suite 304 Telephone 828-258-2023 Asheville, NC 28801 Facsimile 828-258-2024 November 29, 2021 Re: Draft NPDES Permit NC0026573 Dear Ms. Yitbarek: Please accept these comments on behalf of the Catawba Riverkeeper Foundation and the Southern Environmental Law Center concerning the renewal of NPDES Permit NC0026573 for the Catawba River Pollution Control Facility in Morganton, NC. The Catawba Riverkeeper Foundation's primary mission is to protect the 8,900 miles of waterways in the Catawba—Wateree River Basin. The Foundation fulfills its mission through monitoring, conservation advocacy, and public education and engagement. The Foundation's members routinely use rivers and streams within the watershed for recreation; some members rely on the river as a drinking water source, others for educational and business purposes. The Southern Environmental Law Center works to protect the basic right to clean air, clean water, and a livable climate; to preserve the South's natural treasures and rich biodiversity; and to provide a healthy environment for all. The Catawba River Pollution Control Facility processes domestic sewage from Morganton and Glen Alpine, as well as industrial effluent from three Significant Industrial Users.' Effluent is discharged from the facility into the Catawba River just above Lake Rhodhiss. The wastewater treatments plants for Lenoir and Valdese also discharge into, or directly upstream of, Lake Rhodhiss. Several municipalities get their drinking water from the lake.2 The lake has a history of nutrient loading problems.3 The Catawba River Pollution Control Facility ("the facility") has violated the terms of its existing NPDES permit multiple times in the last several years.4 ' Fact Sheet, Draft NPDES Permit No. NC0026573 (Oct. 26, 2021) at 1-2 (hereafter "Fact Sheet"). 2 See Western Piedmont Council of Govemments, Western Piedmont Source Water Protection Plan (2014) at 1, available at https://files.nc.gov/ncdeq/Water%20Resources/files/swap/SWPP%20Westem%20Piedmont.pdf. 3 See Burke County, 2011 Community Health Assessment at 16, available at https://www.burkenc.org/ArchiveCenterNiewFile/Item/233. 4 See Environmental Protection Agency, ECHO Detailed Facility Report, available at https://echo.epa.gov/detailed- facility-report?fid=110027948498. Charlottesville Chapel Hill Atlanta Asheville Birmingham Charleston Nashville Richmond Washington, DC Rather than address the facility's continued violations or ameliorate concerns about water quality in Lake Rhodhiss, the draft permit fails to protect the Catawba River in violation of both the Clean Water Act and North Carolina state law. The draft permit must be withdrawn, substantially revised, and reissued for public comment. Specifically, DEQ must make the following changes in particular: • The permit must evaluate and include technology -based effluent limitations for constituents discharged from the facility, including copper, antimony, zinc, aluminum, NH3-N, fecal coliform, pH, dissolved oxygen, total residual chlorine, arsenic, cyanide, lead, molybdenum, nickel, selenium, total phenolic compounds, dimethyl phthalate, phosphorous, nitrogen, and methyl bromide. The omission of these effluent limitations is especially egregious for copper, antimony, zinc, and selenium, which DEQ acknowledges may threaten water quality standards. • It is unclear if the Reasonable Potential Analysis contemplates discharges from Unix Packaging LLC, a Significant Industrial User whose contribution to the facility was not yet active during permit application. If those discharges were not considered, the Reasonable Potential Analysis must be revised. • The permit must include water -quality -based effluent limitations for constituents that have a reasonable potential to affect water quality standards —namely, copper, antimony, zinc, and selenium. • The facility must disclose if per- and polyfluoroalkyl substances are present in its discharge and, if so, DEQ must include appropriate limits in the NDPES permit. • To comply with anti -backsliding provisions of the Clean Water Act, DEQ must enforce the more stringent effluent limitations applicable under the 10.5 MGD flow regime. • Finally, the permit should rescind DEQ's attempt to pre -approve effluent limitations for the facility under a 13 MGD flow regime since that rate has not been requested by the facility, is not anticipated, and would require additional approvals from DEQ. To the extent these changes require modification to the facility's treatment process or pipe network, we encourage Morganton to seek funding newly made available in the North Carolina state budget and federal Infrastructure Investment and Jobs Act. I. DEQ must impose technology -based effluent limits A. The Clean Water Act requires DEQ to evaluate technologies available to treat pollutants Congress passed the Clean Water Act in 1972 "to restore and maintain the chemical, physical, and biological integrity of the Nation's waters." 33 U.S.C. § 1251(a). To that end, Congress established an "interim goal of [achieving] water quality which provides for the protection and propagation of fish, shellfish, and wildlife and provides for recreation ... by July 1, 1983" and a longer -term "goal that the discharge of pollutants into the navigable waters be eliminated by 1985." Id. § 1251(a)(1-2) (emphasis added). To meet those goals, Congress 2 prohibited the discharge of pollutants5 from point sources6 without a permit. See id. § 1311(a). The Clean Water Act's National Pollutant Discharge Elimination System ("NPDES") permitting program is structured around progressive improvements in pollution control over time to meet Congress's "national goal" of eliminating discharges of pollutants. See id. § 1251(a)(1).7 NPDES permits control pollution through two primary mechanisms: first, by setting limits based on the technology available to treat pollutants ("technology -based effluent limits") and second, by setting any additional limits necessary to protect water quality ("water quality - based effluent limits"). 33 U.S.C. §§ 1311(b), 1314(b); 40 C.F.R. § 122.44(a)(1), (d). Every NPDES permit "shall" contain technology -based effluent limits ("TBELs"), which set the minimum level of control required in every NPDES permit. 40 C.F.R. § 125.3(a). DEQ may issue an NPDES permit only if the permit assures compliance with all technology -based and water quality -based effluent limits. 33 U.S.C. § 1342(a)(1)(A); 40 C.F.R. § 122.43(a). Stated differently, to comply with the Clean Water Act, a permit writer first imposes TBELs and subsequently evaluates the need to impose additional water -quality based effluent limits ("WQBELs") if the TBEL is insufficient to ensure compliance with water quality standards. TBELs "are developed independently of the potential impact of a discharge on the receiving water, which is addressed through water quality standards and water quality based effluent limitations." EPA, NPDES Permit Writers' Manual at 5-1.8 A discharger must implement technology -based standards, even if doing so goes beyond the level necessary to meet water quality standards. Id.; see 15A N.C. Admin. Code 2B.0404(a) ("if the discharge is subject to both technology based and water quality based effluent limitations for a parameter, the more stringent limit shall apply"). Permit writers run afoul of the Clean Water Act by focusing exclusively on WQBELs, in part, because this would foreclose the Congressional goal of eliminating discharges of pollutants to navigable waters —discharges would be maintained, or even increased, so long as they did not violate water quality standards. For publicly -owned treatment works ("POTW"), like the Catawba River Pollution Control Facility, compliance with TBELs is achieved, in part, by meeting secondary treatment requirements. See 33 U.S.C. § 1311(b); 40 C.F.R. § 125.3(a)(1). Secondary treatment requirements limit discharges of pollutants commonly associated with POTWs: oxygen consuming waste (BOD5), suspended solids, and pH. See 40 C.F.R. § 133.102. Permit writers must clearly present the data used to determine whether secondary treatment standards apply to a 5 "The term `pollutant' means dredged spoil, solid waste, incinerator residue, sewage, garbage, sewage sludge, munitions, chemical wastes, biological materials, radioactive materials, heat, wrecked or discarded equipment, rock, sand, cellar dirt and industrial, municipal, and agricultural waste discharged into water." 33 U.S.C.§ 1362(6). 6 "The term `point source' means any discemible, confined and discrete conveyance, including but not limited to any pipe, ditch, channel, tunnel, conduit, well, discrete fissure, container, rolling stock, concentrated animal feeding operation, or vessel or other floating craft, from which pollutants are or may be discharged." 33 U.S.C. § 1362(14). North Carolina administers the NPDES program within its borders under delegated authority from EPA. See NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM MEMORANDUM OFAGREEMENT BETWEEN THE STATE OF NORTH CAROLINA AND THE UNITED STATES ENVIRONMENTAL PROTECTIONAGENCY REGION 4 (2007) available at https://www.epa.gov/sites/default/files/2013- 09/documents/nc-moa-npde s.pdf. 8 Available at https://www.epa.gov/sites/production/files/2015-09/documents/pwm 2010.pdf. 3 permitted facility, and thoroughly describe how these standards are applied in the fact sheet. See NPDES Permit Writers' Manual at 5.1.3.6. But compliance with secondary treatment standards is not a substitute for application of TBELs to other contaminants discharged through the POTW. If other contaminants are discharged, the permit writer must evaluate and apply TBELs to them as well. North Carolina law similarly requires TBELs for other contaminants discharged from POTWs. Secondary treatment requirements apply to "all municipal wastewater treatment discharges and all discharges consisting primarily of domestic sewage" but "limits applicable to industrial categories ... shall be applicable to any municipality if influent waste discharges from industries in any single category account for 10 or more percent of its average daily wastewater flow or the industrial discharges significantly impact the municipal system or its effluent discharge." 15A N.C. Admin. Code 2B.0406(a). The Catawba River Pollution Control Facility passes this threshold. The average daily flow from the facility is 6.4 MGD;9 2 MGD influent flow is allocated to Case Farms (chicken processing) and 1.5 MGD is allocated to Seiren industries (textiles).10 Thus, both federal and state law require additional TBELs, as well as the secondary treatment standards applicable to POTWs, at the Catawba River Pollution Control Facility. See 15A N.C. Admin. Code 2B.0406(b) (incorporating TBEL requirements from the Clean Water Act). Technology -based limits are derived from one of two sources: (1) national effluent limitation guidelines ("ELGs") issued by EPA for various industries, 33 U.S.C. § 1314(b), or (2) case -by -case determinations using the "best professional judgment" ("BPJ") of permit writers, when EPA has not issued an ELG for an industry. See 33 U.S.C. § 1342(a)(1)(B); 40 C.F.R. § 125.3(c)(2). North Carolina rules likewise direct staff to calculate TBELs using "available information" in the absence of a promulgated ELG. 15A N.C. Admin. Code 02B .0406(b)(3). Here, where EPA has not issued effluent limitation guidelines for the relevant industries, TBELs derive from the "best professional judgment" of the permit writer. To be sure, the city of Morganton is not left alone to meet these requirements for industrial dischargers using its wastewater treatment plant. The city is required to regulate its industrial dischargers so that they do not cause the treatment plant to violate its own Clean Water Act obligations. See 40 C.F.R. § 403.8(f)(1). This is how the Clean Water Act "assures the public that [industrial] dischargers cannot contravene the [Clean Water Act's] objectives of eliminating or at least minimizing discharges of toxic and other pollutants simply by discharging indirectly through [wastewater treatment plants] rather than directly to receiving waters." 11 The pretreatment program is intended to place the burden of treating polluted discharges on the entity that creates the pollution, rather than on the taxpayers who support municipally -owned treatment plants. But the first step in this process is for DEQ to apply TBELs in this NPDES permit; 9 See Catawba River Pollution Control Facility, NPDES No. NC0026573 Renewal Application (Sept. 3, 2019) at Section A.9 (hereafter "Renewal Application"). 1° See City of Morganton, Annual Pretreatment Report for 2020 (Feb. 17, 2021), Allocation Table. 11 General Pretreatment Regulations for Existing and New Sources, 52 Fed. Reg. 1586, 1590 (Jan. 14, 1987) (codified at 40 C.F.R. § 403). 4 Morganton can then require upstream industrial dischargers to reduce pollutant inflow to ensure compliance with NPDES limits. B. DWR failed to include TBELS for many constituents in the draft permit Despite this obligation, DEQ left TBELs out of the draft NDPES permit for the facility, except for those related to secondary treatment requirements (BOD5 and Total Suspended Solids).12 The draft fact sheet indicates that DEQ established WQBELs for NH3-N, fecal coliform, pH, dissolved oxygen, and total residual chlorine, but provides no indication that it considered technology -based limits.13 The fact sheet states that the permit includes no standards for "arsenic, cyanide, lead, molybdenum, nickel, selenium, zinc, total phenolic compounds, dimethyl phthalate, [and] methyl bromide" specifically because "they did not demonstrate reasonable potential to exceed applicable water quality standards."14 This may justify lack of WQBELs but it cannot justify failure to evaluate TBELs. The fact sheet notes several other constituents discharged through the POTW with no indication that DWR evaluated TBELs to limit their discharge, including antimony, copper, silver, phosphorous, aluminum, and nitrogen.15 This approach does not comply with the Clean Water Act. As explained above, DWR must evaluate whether there are technologies available to limit the discharges of these contaminants and, if so, apply TBELs as appropriate. DWR may not skip directly to WQBELs without evaluating TBELs (as it appears to have done with NH3-N, fecal coliform, pH, dissolved oxygen, total residual chlorine, arsenic, cyanide, lead, molybdenum, nickel, selenium, zinc, total phenolic compounds, dimethyl phthalate, phosphorous, nitrogen, and methyl bromide); fail to evaluate the need for TBELs, or impose WQBELs, for constituents that appear to risk violations of water quality standards, such as copper and antimony; or fail to evaluate TBELs for constituents with no water quality standard, such as aluminum. The failure to include TBELs for copper, antimony, zinc, and selenium is particularly problematic because, according to the cover letter accompanying the draft permit, discharges of these constituents risk violating water quality standards.16 Fortunately, technologies are available to limit the discharge of many of these pollutants. For example, the use of a sand -chemically carbonized rubber wood sawdust column system has 12 Fact Sheet at 14. 13 Fact Sheet at 14-15. 14 Fact Sheet at 9. 15 Fact Sheet at 14-16. 16 See DEQ, Draft Permit No. NC0026573 Cover Letter (Oct. 26, 2021) at 1-2. The Fact Sheet and Cover Letter appear to take inconsistent positions on whether discharges of these constituents risk water quality standard violations. Compare Cover Letter at 2 (noting "RPA predicting a maximum effluent zinc concentration that is greater than the allowable discharge concentration based on state water quality standards") with Fact Sheet at 8 (stating that zinc "did not demonstrate reasonable potential to exceed applicable water quality standards"). See also Fact Sheet at 15 (stating that for zinc "RP [Reasonable Potential] exists"). 5 been shown to reduce copper discharges in municipal wastewater," and several different technologies have been used to reduce selenium discharges in nonmunicipal wastewater.'$ DEQ must evaluate the potential for these and other technologies to minimize the discharge of pollutants from the facility. The Clean Water Act requires that DEQ evaluate and issue TBELs as appropriate for the discharged constituents not already covered by secondary treatment standards for this facility. Since there is no applicable ELG, DEQ must use its best professional judgement to determine how available technology can effectively limit discharges of numerous constituents including copper, antimony, aluminum, NH3-N, fecal coliform, pH, dissolved oxygen, total residual chlorine, arsenic, cyanide, lead, molybdenum, nickel, selenium, zinc, total phenolic compounds, dimethyl phthalate, phosphorous, nitrogen, and methyl bromide. By omitting this analysis and neglecting to set appropriate effluent limits, the draft permit violates the Clean Water Act. The agency cannot bring this permit into compliance without evaluating technologies available to limit discharges of these pollutants. IL DEQ must apply WQBELs to pollutants with a reasonable potential to violate water quality standards Even when TBELs are applied, the Clean Water Act prohibits DEQ from issuing a NPDES permit that allows a violation of water quality standards. 33 U.S.C. § 1342(a)(1)(A); 40 C.F.R. § 122.43(a). Accordingly, WQBELs "shall be established for discharges that are found . . . to have a reasonable potential to cause or contribute to exceedance of applicable water quality standards." 15A N.C. Admin. Code 2B.0404. The WQBEL must be sufficient to "ensure that a discharge does not cause or contribute to a contravention of state surface water quality standards." Id. 2B.0403(15). To fulfill this requirement, DEQ conducted a reasonable potential analysis ("RPA") evaluating the potential for specific constituents to violate water quality standards. This RPA is flawed and incomplete. As an initial matter, it is unclear if the RPA accounted for pollutants discharged by Unix Packaging LLC. Unix Packaging appears to have sought permission to discharge to the POTW as a Significant Industrial User after Morganton submitted its NPDES renewal application.19 As a result, there is no information about Unix Packaging available in the renewal application, including no disclosure of pollutants associated with Unix Packaging's industrial processes. If 17 See Swarup Biswas, Treatment of Copper Contaminated Municipal Wastewater by Using UASB Reactor and Sand -Chemically Carbonized Rubber Wood Sawdust Column, BIOMED RESEARCH INTERNATIONAL (Jan. 20, 2016) available at https://www.hindawi.com/joumals/bmri/2016/5762781/. 18 See Lea Chua Tan, et al., Selenium: environmental significance, pollution, and biological treatment technologies, BIOTECHNOLOGY ADVANCES (September -October 2016) available at https://www. sciencedirect.com/science/article/abs/pii/S0734975016300623. 19 Documents available on DEQ's Laserfiche system indicate that Unix Packaging requested an Industrial User Pretreatment Permit in early 2021; the NPDES renewal application was submitted to DEQ on Sept. 3, 2019. 6 the RPA does not account for industrial wastewater from Unix Packaging, DEQ must re -run its RPA to assess the need for additional WQBELs. More to the point, the cover letter to the draft permit concludes that "based on the reasonable potential analysis," discharges of copper, antimony, zinc, and selenium may exceed state water quality standards at various permitted flow levels.20 The accompanying fact sheet likewise states that "[b]ased on the Reasonable Potential Analysis, RP exists" for those same constituents except selenium, which is not discussed.21 Nevertheless, the draft permit includes no limits on discharges of antimony, zinc, and selenium; only a requirement to monitor discharges. Monitoring alone will not "ensure that a discharge does not cause or contribute to a contravention of state surface water quality standards." 15A N.C. Admin. Code 2B.0403(15). DEQ must revise the draft permit to add WQBELs for those constituents with a reasonable potential to violate state water quality standards. For copper, DEQ has proposed a new limit, but it gives the permittee one year from permit issuance to develop a strategy for arresting copper discharges and three years from permit issuance to comply with the limit. We are sympathetic to the need for the permittee to identify the sources of the copper in its wastewater and make appropriate changes, but this time table is too long. To be clear, if discharges of copper from the facility are currently causing or contributing to water quality standard exceedances, then the facility is in violation of its existing permit and the Clean Water Act. There is no need to delay the process of identifying the source of the copper in the facility's wastewater until a new NPDES permit issues —that process should start now. The Clean Water Act requires compliance schedules, such as the one proposed for copper, to achieve water quality standards "as soon as possible." 40 C.F.R. § 122.47(a), see also 40 C.F.R. § 123.25 (requiring permitting authorities to administer delegated state programs in conformance with this and other specified regulatory provisions). EPA's guidance to permit writers elucidates the minimum criteria applicable to schedules of compliance for state water quality standards. See NPDES Writers' Manual at 9.1.3. Echoing the regulatory requirements, EPA directs permit writers to "[j]ustify and demonstrate that compliance with the final WQBEL is required as soon as possible." See id. Furthermore, EPA guidance to regulators provides eleven principles to assess whether a compliance schedule is consistent with the CWA and its implementing regulations.22 This guidance reinforces the responsibility of state regulators to ensure that the schedule is justified and requires compliance "as soon as possible." The proposed copper compliance schedule does not meet these requirements. DEQ has not explained why three years is necessary to identify sources of copper discharges and bring them into compliance with water quality standards. The permit also appears to impose no limitation on copper discharges in the intervening three-year period. This will allow unlimited copper discharges for the next three years, despite the fact that these discharges risk violating water quality standards now. DEQ should require the permittee to begin the process of 20 Cover Letter at 1-2. 21 Fact Sheet at 15-16. 22 See Memorandum from James Hanlon to Alexis Strauss, "Compliance Schedules for Water Quality -Based Effluent Limitations in NPDES Permit" (May 10, 2007) available at https://www3.epa.gov/npdes/pubs/memo complianceschedules may07.pdf. 7 identifying the sources of copper discharges now and to come into compliance within one year. At the very least, DEQ should establish interim limits to progressively reduce copper discharges as quickly as possible. III. DEQ must require disclosure of any PFAS discharges and include appropriate limits in the draft and final permit The Clean Water Act's strategy of applying TBELs and WQBELs to reduce or eliminate discharges of pollutants into navigable waters only works if permittees and permit writers know what contaminants are discharged from a facility. Accordingly, a core requirement of the Clean Water Act is that permittees assess and disclose the pollutants in their effluent. The Renewal Application for the facility's NPDES permit is silent on whether per- and polyfluoroalkyl substances ("PFAS") are discharged. DEQ must require the facility to disclose whether PFAS are being discharged and, if so, apply appropriate limits. The human health and environmental problems associated with PFAS exposure are now widely known. EPA recently recognized PFAS as "an urgent public health and environmental issue facing communities across the United States."23 EPA has called on "[e]very level of government —federal, Tribal, state, and local—[ ] to exercise increased and sustained leadership to accelerate progress to clean up PFAS contamination [and] prevent new contamination," specifically calling on states to "[1]everage NPDES permitting to reduce PFAS discharges to waterways."24 Increasingly aware of the health problems associated with PFAS exposure, several states have acted to reduce PFAS in drinking water. Just this month, Pennsylvania's environmental agency proposed drinking water standards for two PFAS compounds of 14 and 18 parts per trillion, respectively.25 DEQ has acknowledged that disclosure of toxic pollutants, including PFAS, is required by the Clean Water Act and state law. In its enforcement action against The Chemours Company, LLC, for the company's discharge of GenX and other PFAS into the Cape Fear River, the agency stated: Part of the permit applicant's burden in this regard is to disclose all relevant information, such as the presence of known constituents in a discharge that pose a potential risk to human health. The permit applicant is required to disclose "all known toxic components that can be reasonably expected to be in the discharge, 23 EPA, PFA Strategic Roadmap: EPA's Commitments to Action 2021-2024 at 1, available at https://www.epa.gov/system/files/documents/2021-10/pfas-roadmap_final-508.pdf . 24 Id. 25 Frank Kummer, Pennsylvania DEP proposes strict limits for `forever chemicals' in drinking water, T PHILADELPHIA INQUIRER (Nov. 16, 2021), available at https://www.inquirer.com/science/climate/pennsylvania-dep- pfo s-pfo a-standards-20211116.html. 8 including but not limited to those contained in a priority pollutant analysis." 15A N.C.A.C. 2H .0105(j) (emphasis added).26 The agency further acknowledged that the company had violated its NPDES permit and state water quality laws by "failing to fully disclose all known toxic components reasonably expected to be in [the company's] discharge."27 DEQ's position in the Chemours enforcement case was correct. The Clean Water Act generally prohibits discharges to streams and rivers. See 33 U.S.C. § 1311(a). The NPDES permitting program is a limited exception to that prohibition, see Nat'l Ass'n of Home Builders v. Def. of Wildlife, 551 U.S. 644, 650 (2007), and discharges under the program cannot be approved unless they are disclosed, see In re Ketchikan Pulp Co., 7 E.A.D. 605 (EPA) (1998); Piney Run Pres. Ass 'n v. Cty. Comm'rs of Carroll Cty., Maryland, 268 F.3d. 255 (4th Cir. 2001); Southern Appalachian Mountain Stewards v. A & G Coal Corp., 758 F.3d 560 (4th Cir. 2014). EPA has also stressed the need for disclosure of pollutants during the permitting process: [D]ischargers have a duty to be aware of any significant pollutant levels in their discharge. [...] Most important, [the disclosure requirements] provide the information which the permit writers need to determine what pollutants are likely to be discharged in significant amounts and to set appropriate permit limits. [...] [P]ermit writers need to know what pollutants are present in an effluent to determine approval permit limits in the absence of applicable effluent guidelines.28 Moreover, municipalities that own and operate wastewater treatment plants are required to "fully and effectively exercise[] and implement[]" their authority to "[i]dentify the character and volume of pollutants contributed to the [publicly owned treatment works]" by Industrial Users. 40 C.F.R. § 403.8(f)(2)(ii). Based on information included in the NPDES permit renewal application, there is the potential that PFAS are discharged through the Catawba River Pollution Control Facility. The textile industry has been recognized as a common source of PFAS.29 Seiren North America is a textile facility which discharges through the POTW.30 Seiren uses "polyester yarn, dye stuffs, surfactants, and finishing agents" to produce fabrics for automobiles.31 It is known that "[f]inishing agents based on [PFAS] are widely used in textiles in order to achieve water, oil and 26 Amended Complaint, N C Dept. of Environmental Quality v. Chemours, 17 CVS 580, 6-7 (N.C. Super. 2018) (hereinafter "N.C. DEQ Amended Complaint") (citing 33 U.S.C. § 1342(k), Piney Run Pres. Ass 'n v. Cty. Comm'rs of Carroll Cty., MD, 268 F.3d 255, 265 (4th Cir. 2001)). 27 Id. at 33. 28 Consolidated Permit Application Forms for EPA Programs, 45 Fed. Reg. 33,526-31 (May 19, 1980). 29 See EPA, Multi -Industry Per- and Polyfluoroalkyl Substances (PFAS) Study — 2021 Preliminary Report at 8-1 — 8-4, available at https://www.epa.gov/system/files/documents/2021-09/multi-industry-pfas-study jreliminary-2021- report 508 2021.09.08.pdf. 3° No information is provided in the application regarding Unix Packaging LLC so it is unclear if its processes also potentially involved PFAS. 31 Renewal Application at 20. 9 dirt repellency of the material."32 PFAS have also been recognized as effective surfactants.33 Because PFAS are used in a broad array of industries, it is also possible that PFAS are used and discharged by other facilities using the POTW as well, including non -significant industrial facilities that are not listed in the POTW's permit application. Given the potential for PFAS discharges by Seiren North America and other facilities through the POTW, Morganton must assess and disclose whether PFAS are in fact being discharged. As explained above, if a permit holder is discharging a pollutant that it did not disclose in its NPDES permit application, it is in violation of the permit and the Clean Water Act. Piney Run, 268 F.3d. at 268. DEQ, in turn, may not issue a permit that does not ensure compliance with the Clean Water Act. If PFAS are present in the effluent, DEQ must include appropriate limits in the NDPES permit, starting with TBELs. Effective technologies, such as granular activated carbon, are available to limit PFAS discharges. Recently, DEQ included TBELS for PFAS in its NPDES permit for Chemours, noting that it was exercising its "professional judgement and experience in establishing Technology Based Effluent Limits for [PFAS]" at the facility.34 DEQ must do the same here. If TBELs are insufficient to protect water quality, then DEQ must develop PFAS WQBELS to ensure water quality standards are met. 33 U.S.C. § 1342(a)(1)(A); 40 C.F.R. § 122.43(a). This includes compliance with North Carolina's toxic substances standard, which requires that "the concentration of toxic substances, either alone or in combination with other wastes, in surface waters shall not render waters injurious to aquatic life or wildlife, recreational activities, public health, or impair the waters for any designated uses." 15A N.C. Admin. Code 2B.0208(a). DEQ has recognized that PFAS "meet the definition of `toxic substance' under North Carolina law.35 Finally, DEQ must also reasonably ensure compliance with North Carolina's prohibition against allowing "[o]ils, deleterious substances, colored, or other wastes" in waters classified as Class C waters —which include the section of the Catawba River that would receive Morganton's discharge36—"to render the waters injurious to public health, secondary recreation, or to aquatic life and wildlife, or adversely affect the palatability of fish, aesthetic quality, or impair the waters for any designated uses." Id. 02B .0211(12). 32 See Danish Ministry of the Environment, Alternatives to perfluoroalkyl and polyfluoro-alkyl substances (PFAS) in textiles (2015) at 7, available at https://www.enviro.wiki/images/f/f4/DEPA2015.pdf. 33 See supra note 29. 34 See NCDEQ, Responses to the Comments, Chemours Permit NC0089915 (Sept. 11, 2020), at 1, available at https://deq.nc.gov/media/17001 /download. 35 N.C. DEQ Amended Complaint at 32 (stating that "the process wastewater from [Chemours'] Fluoromonomers/Nafion® Membrane Manufacturing Area contains and has contained substances or combinations of substances which meet the definition of "toxic substance" set forth in 15A N.C.A.C. 2B .0202," referring to GenX and other PFAS). 36 Morganton's treatment plant discharges to Water Supply IV waters, which are also protected as Class C waters. Draft Permit at 2; 15A N.C. Admin Code 02B .0218. 10 As explained above, once appropriate limits are included in the NPDES permit, Morganton can put the burden of cleaning up toxic PFAS pollution on the industries that create it by regulating upstream users to limit their PFAS discharges. IV. The draft permit violates the Clean Water Act's anti -backsliding provision As recognized in the draft permit fact sheet, the Clean Water Act requires that "when a permit is renewed or reissued, interim effluent limitations, standards or conditions must be at least as stringent as the final effluent limitations, standards, or conditions in the previous permit." Fact sheet at 13 (citing 40 C.F.R. § 122.44(1)); see 33 U.S.C. 1342(o) (statutory anti -backsliding provision); 15A N.C. Admin. Code 02B .0408(25) (incorporating § 122.44 by reference). The draft permit violates this condition on two fronts. First, the active permit includes a weekly average BOD5 limit of 27.8 mg/L under the 10.5 MGD flow regime.37 The draft permit replaces this with a weekly average limit of 45 mg/L under the same flow regime.38 DEQ must reinstate the 27.8 mg/L limit or explain why the increase to 45 mg/L meets one of the limited exceptions to the anti -backsliding provision. Second, both the current and draft permit explain that the facility is authorized to discharge 8 MGD as a monthly average until "this facility reaches an annual average daily flow equal to or greater than 6 4 MGD."39 Once that happens, the facility is authorized to discharge up to 10.5 MGD under different, more stringent effluent limits.40 The NPDES permit application indicates that "last year" annual average daily flow was 6.494 MGD and "this year" annual average daily flow was 7.43 MGD.41 As a result, the facility is now subject to the more stringent limits under the 10.5 MGD flow regime. Nevertheless, the draft permit appears to reset the clock on this requirement, allowing the facility to apply the less stringent limits under the 8 MGD flow regime for at least a year or until it "reaches an annual average daily flow equal to or greater than 6.4 MGD"—even though that has already happened. This is backsliding, which is explicitly foreclosed by the Clean Water Act. DEQ cannot revert to the less stringent standard each time this NPDES permit is renewed. Once the more stringent 10.5 MGD limits kick in —as they have here —they must be carried forward to the next permit renewal. V. DEQ should remove the effluent limits under the 13 MGD flow regime The draft NPDES permit also purports to provide effluent limits in the event that the facility is expanded to accommodate 13 MGD in flow.42 These effluent limits should be removed. The facility is only designed to accommodate up to 10.5 MGD in flow and "has no 37 Final NPDES Permit No. NC0026573 (March 28, 20176) at 4. 38 Draft Permit at 5. 39 Final NPDES Permit No. NC0026573 (March 28, 20176) at 4; Draft Permit at 5. 49 Final NPDES Permit No. NC0026573 (March 28, 20176) at 4; Draft Permit at 5. 41 Renewal Application at 3. 42 Draft Permit at 7. 11 plans to expand."43 Expansion would require an "Authorization to Construct" from DEQ.44 We are aware of no reason why DEQ would provide limits for a flow level that cannot currently be accommodated at this facility. If expansion to 13 MGD flow becomes necessary, the proper course is to modify the permit active at that time. DEQ should not attempt to preauthorize the expansion for purposes of Section 402 of the Clean Water Act in this permit. VI. Conclusion We appreciate the opportunity to comment on this draft permit. As explained above, the draft permit must be revised to ensure compliance with state and federal law. Revisions must include application of TBELs for multiple constituents and application of WQBELs for pollutants with a reasonable potential to impact water quality standards. Additionally, disclosure of toxic pollutants such as PFAS should be mandated, and any applicable effluent limitations must be issued. Finally, the permit must comply with the Clean Water Act's anti -backsliding provisions by enforcing the more stringent effluent limitations already applicable to the facility under a 10.5 MGD flow rate, and DEQ must not attempt to circumvent a proper Clean Water Act Section 402 analysis by pre -approving effluent limitations at a flow rate not yet possible or anticipated by the facility. Please contact Patrick Hunter at (828) 258-2023 or phunter@selcnc.org if you have any questions regarding our concerns. 43 Fact Sheet at 1 44 Draft Perinit at 2. 12 Sincerely, Patrick Hunter Managing Attorney Alyson Merlin Associate Attorney SOUTHERN ENV RONMENTAL CENTER Via Electronic Mail and US. Mail NCDEQ/DWR NPDES Permitting Branch c/o Diana Yitbarek 1617 Mail Service Center Raleigh, North Carolina 27699-1617 diana.yitbarek@ncdenr.gov 48 Patton Avenue, Suite 304 Telephone 828-258-2023 Asheville, NC 28801 Facsimile 828-258-2024 July 22, 2022 Re: 2'd Draft NPDES Permit NC0026573 Dear Ms. Yitbarek: Please accept these comments on behalf of the Catawba Riverkeeper Foundation and the Southern Environmental Law Center concerning the 2nd Draft National Pollutant Discharge Elimination System ("NPDES") Permit NC0026573 for the Catawba River Pollution Control Facility in Morganton, NC. Our previously filed comments on the 1st Draft Permit for the facility are also attached. North Carolina Department of Environmental Quality ("DEQ") must implement more stringent requirements for several constituents of concern to public health which were only addressed through monitoring provisions. First, the Clean Water Act ("CWA") requires that per- and polyfluoroalkyl substances ("PFAS") discharges, like all constituent discharges, be made only with proper disclosure to DEQ and with appropriate effluent limitations. It appears that the permittee has not disclosed any discharges of PFAS to DEQ. Disclosure' must be made in the permit application_ Discharges not disclosed in a permit application are not covered by an NPDES permit, and therefore violate the CWA.2 The purpose of disclosure is two -fold: to make DEQ aware of the full scope of discharge from the applicant's facility, and to allow the public to be fully informed during the public comment period. This is because "permit writers need to know what pollutants are present in an effluent to determine appropriate permit limits.i3 Additionally, public notice must be given about permitting decisions, 1 The Fourth Circuit has defined "disclosure" to require more than a "general description of the plant's operation" or a "general[] aware[ness]" by the agency that a pollutant discharge is possible. S. Appalachian Mtn. Stewards V. A&G Coal Corp., 758 F.3d 560, 568 (4th Cir. 2014). In other words, descriptions of an industrial process known by an agency to be associated with or produce particular pollutant(s), like PFAS, does not satisfy the requirement that an applicant disclose the pollutant(s) in its NPDES permit application. See id. 2 Piney Run Preservation Ass'n v. Civ Comm'rs, 268 F.3d 255, 268 (4th Cir. 2001) ("To the extent that a permit holder discharges a pollutant that it did not disclose, it violates the NPDES permit and the CWA.") 3 Consolidated Permit Application Forms for EPA Programs, 45 Fed. Reg. 33516, 33526 (May 19, 1980). Charlottesville Chapel Hill Atlanta Asheville Birmingham Charleston Nashville Richmond Washington, DC including "a summary of each applicant's activities or operations that result in the discharge described in the NPDES application." 15A NCAC 02H .0109(a)(3)(C). Such a summary would be ineffective if all discharges were not included in the permit application. In the new draft permit, DEQ has ordered twice annual monitoring for PFAS "[b]ased on the categories of significant industrial users" which discharge through the Catawba River Pollution Control Facility. Monitoring is not a substitute for required disclosure. Moreover, because the Catawba River Pollution Control Facility handles discharges from industries suspected to discharge PFAS, DEQ should make clear in final permitting documents that any undisclosed pollutants, including PFAS, are not permitted and therefore violate the CWA.4 The Tennessee Department of Environment and Conservation has made clear that undisclosed discharges of PFAS are unpermitted for at least one permit for a facility that manufactures coated paper products: The facility's application did not report any forms of PFAS as chemicals that there was the potential to discharge. The permittee has no permit shield for the discharge of PFAS compounds because no such chemicals were disclosed in the permit application or otherwise...5 DEQ should do the same here. Once PFAS discharges are properly disclosed, DEQ must include technology -based effluent limitations ("TBELs") for PFAS in the permit. The CWA requires TBELs be assessed first, to be followed by water -quality based effluent limitations ("WQBELS") where necessary to ensure compliance with water quality standards. 33 U.S.C. §§ 1311(b), 1314(b); 40 C.F.R. § 122.44(a)(1), (d).6 North Carolina law similarly requires TBELs. See 15A N.C. Admin. Code 2B.0406(b) (incorporating TBEL requirements from the Clean Water Act). Publicly Owned Treatment Works ("POTW") permit limits must take into account whether the POTWs treat industrial discharges: "Limits applicable to industrial categories ... shall be applicable to any municipality if influent waste discharges from industries in any single category account for 10 or more percent of its average daily wastewater flow or the industrial discharges significantly impact the municipal system or its effluent discharge." 15A N.C. Admin. Code 2B.0406(a). The Catawba River Pollution Control Facility passes this threshold. The average daily flow from the facility is 6.4 MGD'; 2 MGD influent flow is allocated to Case Farms (chicken processing) and 1.5 MGD is allocated to Seiren North America (textiles), representing 31.3% and 23.4% of daily 4 See In re Ketchikan Pulp Co., 7 E.A.D. 605 (EPA) (1998); Piney Run Pres. Ass 'n v. CO;. Comm'rs of Carroll Cty., Maryland, 268 F.3d. 255 (4th Cir. 2001); Southern Appalachian Mountain Stewards v. A & G Coal Corp., 758 F.3d 560 (4th Cir. 2014). 5 TDEC, NPDES Permit NO. TN0002330 (2020), Holliston Holdings, LLC, Addendum to Rationale, https://perma.cc/4RKY-PKFG (emphasis added). 6 Assessing TBELs for constituents of concern is necessary even where analytical methods for pollution detection are not yet perfected. "Nonetheless, even at levels where the accuracy of the data may be somewhat uncertain, analytical information is useful to the permitting authority as a screening technique to identify the presence of a pollutant and supply an estimate of its concentration." 49 Fed Reg. 37908, 38002 (Sept. 26, 1984). Thus, DEQ is not absolved of its obligation to regulate PFAS if more effective technology is being developed. See Catawba River Pollution Control Facility, NPDES No. NC0026573 Renewal Application (Sept. 3, 2019) at Section A.9. 2 flow, respectively.89 As the draft permit notes,10 these SIUs represent industry categories likely to discharge PFAS. As a textile facility representing over 20% of daily flow, Seiren North America's discharge of PFAS is especially probable," and DEQ's failure to assess TBELs associated with this effluent is concerning. Finally, the new draft permit represents that the Reasonable Potential Analysis ("RPA") found both silver and antimony have a likelihood of exceeding the maximum effluent concentration allowable by state water quality standards. However, DEQ assigned only quarterly monitoring requirements for these constituents. As detailed extensively in our original comments and reiterated above, DEQ has an obligation under the CWA to issue both TBELs and WQBELs for constituents covered by an NPDES permit which have the potential to cause or contribute to water quality violations. The failure to set these limitations is even more egregious where, by DEQ's own analysis, these constituents pose a threat to public health and environmental welfare according to state water quality standards. We hope to see this error corrected in the final permit for the Catawba River Pollution Control Facility. Thank you for considering these comments. Please contact me if you have any questions about the information contained in this letter. Sincerely, Alyson Merlin Associate Attorney amerlin@selcnc.org 8 See City of Morganton, Annual Pretreatment Report for 2020 (Feb. 17, 2021), Allocation Table. 9 An unknown amount of the Catawba River Pollution Control Facility's daily flow is allocated to Unix Packaging, LLC (beverage packaging). If this SIU represents 10% or more of the Catawba River Pollution Control Facility's daily flow, the above arguments apply to this facility as well. 10 Draft Permit at 2 ("Based on the categories of significant industrial users (SIUs) discharges, there is a need to assess PFAS compounds."); Draft Fact Sheet at 12 ("A PFAS monitoring Special Condition is added based on the significant industrial users (SIUs) discharges."). " See Multi -Industry Per- and Polyfluoroalkyl Substances (PFAS) Study — 2021 Preliminary Report, ENVIRONMENTAL PROTECTION AGENCY, EPA-82 1 -R-2 1-004 (Sept. 2021). 3 The Division received comments for the City of Morganton/Catawba River Pollution Control Facility draft NPDES permit NC0026573 (See full comments in fact sheet attachments) and provides the following responses: Comments from the Southern Environmental Law Center (SELC) and the Catawba Riverkeeper Foundation on July 22, 2022, by Alyson Merlin I. Comments suggesting stringent requirements for silver and antimony, constituents of concern to public health which were only addressed thorough monitoring provisions Response: NC DEQ DWR applies WQBELs to pollutants with a reasonable potential (RP) to violate water quality standards, for which there is a representative data set (e.g., typically 8 to 12 samples). Additional representative data needs to be collected by the Permittee at the correct PQL. For comments and calculation results for each pollutant, please see the reasonable potential analysis (RPA) results attached to the Fact Sheet. NC DEQ evaluates up to the last 4.5 years of data to be used in the RPA per 40 CFR 122. • Since there is not a representative data set for antimony, DEQ will maintain quarterly monitoring for antimony. • Upon review of the most recent silver monitoring data, all the values were less than detect after September 2019; however, to collect additional representative data, DEQ is increasing monitoring frequency to monthly with the requirement to use the most sensitive PQL. A review of the silver data will be made in the permit renewal. II. Comment on PFAS Discharges a. DEQ must require disclosure of any PFAS discharges and include appropriate limits in the draft and final permit Response: The Facility has reported that has not conducted any sampling for PFAS. Upon consideration that the Facility discharges to WS-IV waters, has an active Pretreatment Program, and the categories of significant industrial users (Sills) discharges prompt a need to assess PFAS compounds, the Division has revised the PFAS monitoring requirement for this NPDES permit from 2/year to quarterly. Since, to this date, no published final 40 CFR 136 wastewater sampling Method is available for PFAS compounds, the PFAS requirement was added as a Special Condition which will take effect six months after the Method is published in the final form in the Federal Register. The Division received comments for the City of Morganton/Catawba River Pollution Control Facility draft NPDES permit NC0026573 (See full comments in fact sheet attachments) and provides the following responses: Comments from the Southern Environmental Law Center (SELC) on November 29, 2021, by Patrick Hunter and Alyson Merlin I. Comments on technology -based effluent limitations (TBELs) and water -quality based effluent limits (WQBELs) a. The Clean Water Act requires DEQ to evaluate technologies available to treat pollutants b. DWR failed to include TBELS for many constituents in the draft permit a. DEQ must apply WQBELs to pollutants with a reasonable potential to violate water quality standards Response: EPA establishes TBELs for POTWs that set minimum technology -based limits. This permit includes limits that comply with minimum secondary technology -based limits for BOD5, TSS, pH, and percent pollutant removal for BOD and TSS. In addition, water quality limits have also been applied as described in the Factsheet. 15A N.C. Admin. Code 2B.0406(a) applies to categorical industries with pretreatment standards. For NC DEQ DWR, categorical industries are industries with pretreatment standards. Seiren industries (textiles) do not have pretreatment standards per current regulations. Case Farms (chicken processing) and Unix Packaging are being currently regulated by the POTW under current Pretreatment requirements. NC DEQ DWR applies WQBELs to pollutants with a reasonable potential (RP) to violate water quality standards, for which there is a representative data set (e.g., typically 8 to 12 samples). Additional representative data needs to be collected by the Permittee at the correct PQL. For comments and calculation results for each pollutant, please see the reasonable potential analysis (RPA) results attached to the Fact Sheet. NC DEQ evaluates up to the last 4.5 years of data to be used in the RPA per 40 CFR 122. Lastly, DEQ has decided to maintain the Copper Compliance Schedule in the NPDES permit. The Facility has identified the potential industrial sources for copper in October 2017. Within one (1) year of the permit effective date, the Permittee shall submit to DEQ a Corrective Action Plan (CAP) for Division approval (which could include a pretreatment local limit assessment), summarizing the strategy or actions to be taken to achieve compliance with the copper limitations listed in Section A. (1.). This plan will include specific dates for the completion or implementation of each action. The Permittee may request the final limit be placed in effect and remove the Compliance Schedule. III. Comment on PFAS Discharges a. DEQ must require disclosure of any PFAS discharges and include appropriate limits in the draft and final permit Response: Upon consideration and review of the industrial activity in the City and the status of upcoming PFAS 40 CFR 136 Methods and regulations, the Division has added a PFAS-related requirement to this NPDES permit. Since, to this date, no approved 40 CFR 136 sampling Method exists for PFAS compounds in the wastewater matrix, the PFAS requirement was added as a Special Condition which will take effect six months after the Method is published in the final form in the Federal Register. IV. Comment on anti -backsliding a. The draft permit violates the Clean Water Act's anti -backsliding provision Response: Based on the information provided by the POTW, the existing wastewater Facility cannot currently meet all the limits at 10.5 MGD. The permit will require an Authorization to Construct (ATC) and engineering certification before moving to the 10.5 MGD flow tier. Therefore, the 8.0 MGD effluent limitation page will remain in place with the ATC condition. V. Comment on expanded flow tier, 13.0 MGD b. DEQ should remove the effluent limits under the 13 MGD flow regime Response: DEQ is maintaining the authorized 13.0 MGD flow tier limitation page at the request of the Permittee. Comments from the City of Morganton WWTP's team on November 29, 2021, by Eli Self and Brad Boris I. Rainfall and I&I challenges II. Investments into wastewater system III. Literature from engineer design studies IV. Nutrient removal (N&P) for 10.5 MGD permit V. Literature from flow rate study in 2017 VI. Removal of 13.0 MGD permit VII. PFAS Monitoring requirements Response: The Division has revised the status for nutrients in the Lake Rhodhiss area and based on the available information has decided to remove the proposed nutrients limits for the 10.5 MGD flow tier. The Division acknowledges that the Facility is not ready to transition to the 10.5 MGD flow tier; therefore, permit authorization requirements have been updated to facilitate the transition to the higher flow tier. Per Facility's email received on March 30, 2022, the 13.0 MGD flow tier will be maintained in the permit. Due to the timeframe projected before these limits become effective, the nutrient limitations in the existing permit have been maintained. If you wish to remove this limits page, this can be addressed sometime in the future. ROY COOPER Governor ELIZABETH S. BISER Secretary S. DANIEL SMITH Director MEMORANDUM To: NORTH CAROLINA Environmental Quality October 26, 2021 Kimberly Barnett and Nicole Hairston NC DEQ / DWR / Public Water Supply Asheville Regional Office From: Diana Yitbarek NC DEQ / DWR / Municipal Permitting Unit Subject: Review of Draft NPDES Permit NC0026573 Catawba River Pollution Control Facility Outfall 001/ Catawba River Burke County Please indicate below your agency's position or viewpoint on the draft permit and return this form by November 26 , 2021. If you have any questions on the draft permit, please contact me at 919-707-9130 or via e-mail [diana.yitbarek@ncdenr.gov]. RESPONSE: (Check one) §§§§§§§§§§§§§§§§§§§§§§§§§§§§§§§§ Concur with the issuance of this permit provided the facility is operated and maintained properly, the stated effluent limits are met prior to discharge, and the discharge does not contravene the designated water quality standards. Concurs with issuance of the above permit, provided the following conditions are met: Opposes the issuance of the above permit, based on reasons stated below, or attached: Signature: ��tet- Date: 1 1 /01 /2021 D_E NORTH CAROLINA Department of Environmental tluali� North Carolina Department of Environmental Quality I Division of Water Resources 512 North Salisbury Street 11617 Mail Service Center I Raleigh, North Carolina 27699-1617 919.707.9000 3 LLO rrl 12007-2009 average a 0 O a a M a CO O co CO co N C m O Z CO O O) r a O O O 12007-2009 average 2007-2009 (Morganton 0 co W co 6 CO 0 co(71 r W cn co O O CO CO a O NC0026573 City of Morganton O O O O.- N M V O O O O O O.- N M V OO 0000000000 0000000000 N N N N N N N N N N N N N N N N N N N N NC0041696 Town of Valdese Morganton News Herald Advertising Affidavit PO Box 968 Hickory, NC 28603 NC DENRIDWQ ATTN: WREN THEDFORD 1617 MAIL SERVICE CENTER RALEIGH, NC 27699-1617 Account Number 3142720 Date October 28, 2021 Date Category Description Ad Number Ad Size 10/28/2021 Legal Notices Public Notice North Carolina Environmental Management Comi 0000750084 Publisher of Morganton News Herald Burke County Before the undersigned, a Notary Public duly commissioned, qualified. and authorized by law to administer oaths, personally appeared the Publisher's Representative who by being duly sworn deposes and says: that he/she is authorized to make this affidavit and sworn statement: that the notice or other legal advertisement_ a copy of which is attached hereto, t+'as published in the News Herald on the following dates: 1012812021 2x31 L and that the said newspaper in which such notice, paper document, or legal advertisement was published. was at the time of each and every such publication, a newspaper meeting all the requirements and qualifications of Section 1-597 of the General Statutes of North Carolina. Billing Representative Newspaper reference: 0000750084 Sworn to and subscribed before me, this 28th day of October, 2021. Notaii Public State of Virginia County of Hanover My commission expires: Kimberly Kay Harris NOTARY PUBLIC Commonwealth of Virginia Reg. No. 356753 Commission Exp. Jan. 31, 2025 THIS IS NOT A BILL. PLEASE PAY FROM INVOICE. THANK YOU Public Notice North Carolina Environmental Management Commission/NPDES Unit 1617 Mail Service Center Raleigh, NC 27699.1617 Notice of Intent to Issue a NPDES Wastewater Permit NC0026573 Cata- wba River Pollution Control Facility The North Carolina Environmental Management Commission proposes to issue a NPDES wastewater dis- charge permit to the person(s) listed below. Written comments regarding the proposed permit will be accepted until 30 days after the publish date of this notice. The Director of the NC Division of Water Resources (DWR) may hold a public hearing should there be a significant degree of public in- terest. Please mail comments and/or information requests to DWR at the above address. Interested persons may visit the DWR at 512 N. Salisbury Street, Raleigh. NC 27604 to review information on file. Additional infor- mation on NPDES permits and this notice may be found on our website: ht tp://deq.ncgov/about/divisions/water-resources/water-resources- permits/wastewater-branch/npdes-wastewater/public-notices, or by call- ing (919) 707-3601. The City of Morganton (P.O. Box 3448 Morganton, NC 28655) has requested renewal of the NPDES Permit NC0026573 for its Wastewater Treatment Plant in Burke County. This permitted facility dis- charges treated domestic and industrial wastewater to the Catawba River in the Catawba River Basin. Ammonia, biochemical oxygen demand, dis- solved oxygen, fecal coliform, pH, total copper, total residual chlorine, to- tal nitrogen, total phosphorous, and total suspended solids are water quali- ty limited parameters in both permits. These discharges may affect fu- ture allocations in these segments of the Catawba River. Publish: October 28, 2021. Morganton News Herald Advertising Affidavit PO Box 968 Hickory, NC 28603 NC DENR/DWQ ATTN: WREN THEDFORD 1617 MAIL SERVICE CENTER RALEIGH, NC 27699-1617 Account Number 3142720 Date June 16, 2022 Date Category Description Ad Number Ad Size 06/16/2022 Legal Notices Public Notice North Carolina Environmental Management Comi 0000788673 2 x 31 L Publisher of Morganton News Herald Burke County Before the undersigned, a Notary Public duly commissioned, qualified, and authorized by law to administer oaths, personally appeared the Publisher's Representative who by being duly sworn deposes and says: that he/she is authorized to make this affidavit and sworn statement; that the notice or other legal advertisement, a copy of which is attached hereto, was published in the News Herald on the following dates: 06/16/2022 and that the said newspaper in which such notice, paper document, or legal advertisement was published, was at the time of each and every such publication, a newspaper meeting all the requirements and qualifications of Section 1-597 of the General Statutes of North Catolina. Billing Representative Newspaper reference: 0000788673 Sworn to and subscribed before me, this 16th day of June, 2022. 2I Notary Public State of Virginia County of Hanover My commission expires: rco220 Kimberly Kay Harris NOTARY PUBLIC Commonwealth of Virginia Reg. No. 356753 Commission Exp. Jan. 31, 2025 THIS IS NOT A BILL. PLEASE PAY FROM INVOICE. THANK YOU Public Notice North Carolina Environmental Management Commission/NPDES Unit 1617 Mail Service Center Raleigh, NC 27699•1617 Notice of Intent to Issue a NPDES Wastewater Permit NC0026573 City of Morganton The North Carolina Environmental Management Commission proposes to issue a NPDES wastewater discharge permit to the person(s) listed below. Written comments regarding the proposed permit will be ac- cepted until 30 days after the publish date of this notice. The Director of the NC Division of Water Resources (DWR) may hold a public hearing should there be a significant degree of public interest. Please mail com- ments and/or information requests to DWR at the above address. Interest- ed persons may visit the DWR at 512 N. Salisbury Street, Raleigh, NC 27604 to review information on file. Additional information on NPDES per- mits and this notice may be found on our website: http://deq.nc.gov/abou t/divisions/water-resources/water-resources-permits/wastewater- branch/nodes-wastewater/public-notices or by calling (919) 707-3601. The City of Morganton (P.O. Box 3448 Morganton, NC 28655) has request- ed renewal of the NPDES Permit NC0026573 for its Wastewater Treat- ment Plant in Burke County. This permitted facility discharges treated do- mestic and industrial wastewater to the Catawba River in the Catawba River Basin. Ammonia, biochemical oxygen demand, dissolved oxygen, fe- cal coliform, pH, total copper, total residual chlorine, and total suspended solids are water quality limited parameters. This discharge may affect fu- ture allocations in this segment of the Catawba River. Publish: lune 16, 2022.