WQ0002052_Monitoring - 04-2022_20220516 (2)

GW-59A COMPLIANCE REPORT FORM Permit# OCK50O ,OSa—
(Submit one each monitoring period with GW-59 forms.)
1 Enter date monitoring results were due.( 5-31-Z.) Will this monitoring report(GW-59 and GW-59A) YES 10
be submitted after the established due date?
2 Was any required information missing on the GW-59 report forms? YES NO
IF the answer to question 1 or 2 is"YES", list in the space provided below the well identification number(s)and
explain the problems encountered in obtaining the required information.
3 Are any of the monitor wells in need of repair or maintenance(damaged casing,unlocked or missing cap,missing YES
identification plate,area overgrown,etc.)?If the answer is "Yes",contact the Regionalfce for guidance.
4 Are any monitored constituents equal to or above the establishes standards YES Q
If the answer to question 4 is "NO", skip to section 8. t t 0 3{�va
If the answer to question 4 is"YES"list the affected wells individu?wRh'coris ti nt(s)and concentration(s)
exceeding standards in the space provided below: �,�-• ea a
.
Ct a
LL 5}a
5 For the constituents identified in question 4 above,have standard been exceeded previously for the YES NO
same constituent(s)in the same well(s)in the last two years?
If the answer to question 5 is "NO", skip to section 8.
If the answer to question 5 is "YES';list in the space provided below, each well with constituent(s)exceeding
standards, concentration(s)reported, and sample collection date for each occurrence(for the last two years).
N
N
O
N
Are the monitoring wells listed in section 5 located at or beyond the review boundary? DES NO
If the answer is"YES",a groundwater quality problem maybe occurring. CONTACT THE REGIONAL
OFFICE IMMEDIATELY FOR GUIDANCE.If the answer is "NO';monitoring wells may be improperly
located;contact the Regional Office.
7 Is the permittee implementing previously approved actions required by the Division involving this YES NO
groundwater quality problem?
If the answer to question 7 is "YES", describe those actions in the space provided below.
If the answer to question 7 is"NO';contact the Regional Office within 90 days;an evaluation may be
required to determine the impact the waste disposal system is having at the review and compliance
boundaries surrounding this facility. Failure to do so may subject the permittee to a Notice of Violation,
fines,and/or penalties.
8 The person completing this portion(GW-59A)of the monitoring report should sign below and submit this
form with GW-59 forms for required wells to the address provided at the top of the current GW-59 form.
I hereby acknowledge that the above information was evaluated and the information submitted in this
report(Complia ci
Report GW-59A)is true a complete to the best of my knowledge.
C�G S"�/.2/a k
Signature f Permittee(or Autho ized Agent) Date
GW-59A 12/8/2003

WITER4117TCH LABS inc.
POST OFFICE BOX 1056 • #5 PINEWOOD PLAZA DR.
GRANITE FALLS,NORTH CAROLINA 28630
[phone]
SAMPLE: Milliken-Golden Valley WeII#6 COLLECTION DATE: 4/12/2022
PERMIT#: COLLECTION TIME: 11:00
ADDRESS: Milliken &Co. RECEIVED DATE: 4/12/2022
Rt. 2, Highway 226 RECEIVED TIME: 15:10
Bostic, NC 28018
REPORTED: 5/10/2022
ANALYSIS
ANALYSIS RESULTS UNITS DATE ANALYST
NO3 as N 0.69 mg/L 4/20/22 jdg
VOC's pace
NH3 <1.0 mg/L 4/14/22 jrg
LOG ID: 2204-161 REPORTED BY: NC CERTIFIEDLAB#50
falOaft
Tony Gragg,Lab Supervisor

Pace Analytical Services,LLC
0 1377 South?ark Drive
aceAnalytical Kerne svElle,NC 27284
www.pacelabs.cam
[phone]
ANALYTICAL RESULTS
Project: MILLIKEN MONITOR WELL
Pace Project No.: 92599485
Sample: MILLIKEN MONITOR WELL Lab ID: 92599485001 Collected: 04/12/22 11:00 Received: 04/14/22 10:00 Matrix: Water
#6
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
8260D MSV Analytical Method:EPA 8260D
Pace Analytical Services-Charlotte
Acetone ND ug/L 25.0 1 04/15/22 20:38 67-64-1
Benzene ND ugiL 5.0 1 04/15/22 20:38 71-43-2
Bromobenzene ND ug/L 5.0 1 04/15/22 20:38 108-86-1 •
•
Bromochforomethane ND ug/L 5.0 1 04/15/22 20:38 74-97-5
Bromodichloromethane ND ug/L 5.0 1 04/15/22 20:38 75-27-4
Bromoform
ND ugiL 5.0 1 04/15/22 20:38 75-25-2
Bromomethane ND ug/L 10.0 1 04/15/22 20:38 74-83-9
2-Butanone(MEK) ND ug/L 10.0 1 04/15/22 20:38 78-93-3
tert-Butyl Alcohol ND ug/L 100 1 04/15/22 20:38 75-65-0
n-Butylbenzene ND ugiL 5.0 1 04/15/22 20:38 104-51-8
sec-Butylbenzene ND ug/L 5.0 1 04/15/22 20:38 135-98-8
tert-Butylbenzene ND ug/L 5.0 1 04/15/22 20:38 98-06-6
Carbon tetrachloride ND ug/L 5.0 1 04.+15122 20:38 56-23-5
Chlorobenzene ND ug/L 5.0 1 04/15/22 20:38 108-90-7
Chloroethane ND ug/L 10.0 1 04/15/22 20:38 75-00-3
Chloroform ND ug/L 5.0 1 04/15/22 20:38 67-66-3
Chlorometfiane ND ug/L 5.0 1 04/15/22 20:38 74-87-3
2-Chiorotoluene ND ugiL 5.0 1 04/15/22 20:38 95-49-8
4-Chlorotoluene ND ug/L 5.0 1 04/15/22 20:38 106-43-4
1,2-Dibromo-3-chloropropane ND ug/L 5.0 1 04/15/22 20:38 96-12-8
Dibromochloromethane ND ug/L 5.0 1 04/15/22 20:38 124-48-1
1,2-Dlbromoothane(EDB) ND ugiL 5.0 1 04/15/2220:38 106-93-4
Dibromomethane ND ug/L 5.0 1 04/15/22 20:38 74-95-3
1,2-Dichlorobenzene ND ug/L 5.0 1 04/15J22 20:38 95-50-1
1,3-Dichlorobenzene ND ug/L 5.0 1 04/15/22 20:38 541-73-1
1,4-Dichlorobenzene ND ug/L 5.0 1 04/15/22 20:38 106-46-7
Dichlorodifluoromethane ND ugiL 5.0 1 04)15/22 20:38 75-71-8
1,1-Dichloroethane ND ug/L 5.0 1 04/15/22 20:38 75-34-3
1,2-Dichloroethane ND ugiL 5.0 1 04/15/22 20:38 107-06-2
1,2-Dichloroethene(Total) ND ugiL 5.0 1 04/15/22 20:38 540-59-0
1,1-Dichloroethene ND ug/L 5.0 1 04/15/22 20:38 75-35-4
cis-1,2-Dichloroethene ND ug/L 5.0 1 04/15/22 20:38 156-59-2
trans-1,2-Dichloroethene ND ug/L 5.0 1 04/15/22 20:38 156-60-5
1,2-Dichloropropane ND ugiL 5.0 1 04/15/22 20:38 78-87-5 •
1,3-Dichioropropane ND ug/L 5.0 1 04/15/22 20:38 142-28-9
2,2-Dichloropropane ND ug/L 5.0 1 04/15/22 20:38 594-20-7
1,1-Dichloropropene ND ug/L 5.0 1 04/15/22 20:38 563-58-6
cis-1,3-Dichloropropene ND ug/L 5.0 1 04/15/22 20:38 10061-01-5
trans-1,3-Dichloropropene ND ug/L 5.0 1 04/15/22 20:38 10061-02-6
Diisopropyl ether ND ug/L 5.0 1 04/15/22 20:38 108-20-3
Ethylbenzene ND ugiL 5.0 1 04/15/22 20:38 100-41-4
liexachloro-1,3-butadiene ND ug/L 5.0 1 04/15/22 20:38 87-68-3
2-Hexanone ND ugiL 10.0 1 04/15/22 20:38 591-78-6
Isopropylbenzene(Cumene) ND ugiL 5.0 1 04/15/22 20:38 98-82-8 •
p-Isopropyltoluene ND ug/L 5.0 1 04/15/22 20:38 99-87-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in ful,
Date:04/19/2022 02:10 PM without the written consent of Pace Analytical Services,LLC. Page 4 of 19

•
Pace Analytical Services,LLC
w 1377 South Park Drive
ace Analyt caJ
Kernersvllio,NC 27284
www.pacelabs.com
[phone]
ANALYTICAL RESULTS
Project: MILLIKEN MONITOR WELL
Pace Project No.: 92599485
Sample: MILLIKEN MONITOR WELL Lab ID: 92599485001 Collected: 04/12/22 11:00 Received: 04/14/22 10:00 Matrix: Water
#6
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
8260D MSV Analytical Method:EPA 8260D
Pace Analytical Services-Charlotte
Methylene Chloride ND ug/L 5.0 1 04/15/22 20:38 75-09-2
4-Methy1-2-pentanone(MIBK) ND ug/L 10.0 1 04/15/22 20:38 108-10-1
Methyl-tert-butyl ether ND ug/L 5.0 1 04/15/22 20:38 1634-04-4 v1
Naphthalene ND ug/L 5.0 1 04/15/22 20:38 91-20-3
n-Propylbenzene ND ug/L 5.0 1 04/15/22 20:38 103-65-1
Styrene ND ug/L 5.0 1 04/15/22 20:38 100-42-5
1,1,1,2-Tetrachloroethane ND ug/L 5.0 1 04/15122 20:38 630-20-6
1,1,2,2-Tetrachloroethane ND ug/L 5.0 1 04/15/22 20:38 79-34-5
Tetrachloroethane ND ug/L 5.0 1 04/15/22 20:38 127-18-4
Toluene ND ug/L 5.0 1 04/15/22 20:38 108-88-3
1,2,3-Trichlorobenzene ND ug/L 5.0 1 04/15/22 20:38 87-61-6
1,2,4-Trichlorobenzene ND ug/L 5.0 1 04/15/22 20:38 120-82-1
1,1,1-Trichloroethane ND ug/L 5.0 1 04/15/22 20:38 71-55-6
1,1,2-Trichloroethane ND ug/L 5.0 1 04/15/22 20:38 79-00-5
Trichloroethene ND ug/L 5.0 1 04/15/22 20:38 79-01-6
Trichlorofluoromethane ND ug/L 10.0 1 04/15/22 20:38 75-69-4
1,2,3-Trichloropropane ND ug/L 5.0 1 04/15/22 20:38 96-18-4 •
1,2,4-Trimethylbenzene ND ug/L 5.0 1 04/15/22 20:38 95-63-6
1,3,5-Trimothylbenzene ND ug/L 5.0 1 04/15/22 20:38 108-67-8 i
Vinyl acetate ND ug/L 10.0 1 04/15/22 20:38 108-05-4 1
Vinyl chloride ND ug/L 5.0 1 04/15/22 20:38 75-01-4
m&p-Xylene ND ug/L 10.0 1 04/15/22 20:38 179601-23-1 1
1
o-Xylene ND ug/L 5.0 1 04/15/22 20:38 95-47-6
Surrogates
4-Bromofluorobenzene(S) 102 % 70-130 1 04/15/22 20:38 460-00-4
1,2-Dlchloroethane-d4(S) 99 % 70-130 1 04/15/22 20:38 17060-07-0 1
Toluene-d8(S) 109 % 70-130 1 04/15/22 20:38 2037-26-5
{
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except In full,
Date:04/19/2022 02:10 PM without the written consent of Pace Analytical Services,LLC. Page 5 of 19
I

NMTERiTECH LABS inc.
POST OFFICE BOX 1056 • #5 PINEWOOD PLAZA DR.
GRANITE FALLS. NORTH CAROLINA 28630
[phone]
SAMPLE: Milliken-Golden Valley Well#7 COLLECTION DATE: 4/12/2022
PERMIT#: COLLECTION TIME: 11:35
ADDRESS: Milliken & Co. RECEIVED DATE: 4/12/2022
Rt. 2, Highway 226 RECEIVED TIME: 15:10
Bostic, NC 28018
REPORTED: 5/10/2022
ANALYSIS
ANALYSIS RESULTS UNITS DATE ANALYST
NO3 as N 0.39 mg/L 4/20/22 jdg
VOC's pace
NH3 <1,0 mg/L 4/14/22 jrg
LOG ID: 2204-162 REPORTED BY: NC CERTIFIED LAB# 50
Tony Gragg,Lab Supervisor

•
Pace Analytical Services,LLC
aceAnalyticalPark
Kemersvulle,NC 2772184
www.pacelabs.cero [phone]
i
i
ANALYTICAL RESULTS
Project: MILLIKEN MONITOR WELL
Pace Project No,: 92599485
Sample: MILLIKEN MONITOR WELL Lab ID: 925994-85002 Collected: 04/12/22 11:35 Received: 04/14/22 10:00 Matrix:Water
#7
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qua!
8260D MSV Analytical Method:EPA 8260D
Pace Analytical Services-Charlotte
Acetone ND ug/L 25.0 1 04/15/22 20:56 67-64-1
Benzene ND ug/L 5.0 1 04/15/22 20:56 71-43-2
Bromobenzene ND ug/L 5.0 1 04/15/22 20:56 108-86-1
Bromochloromethane ND ugiL 5.0 1 04/15/22 20:56 74-97-5
Bromodichloromethane ND ug/L 5.0 1 04/15/22 20:56 75-27-4
Bromoform ND ug/L 5.0 1 04/15/22 20:56 75-25-2
Bromomethane ND ug/L 10.0 1 04/15/22 20:56 74-83-9
2-Butanone(MEK) ND ug/L 10.0 1 04/15/22 20:56 78-93-3
tert-Butyl Alcohol ND ug/L 100 1 04/15/22 20:56 75-65-0
n-Butylbenzene ND ug/L 5.0 1 04/15/22 20:56 104-51-8 ,
sec-Butylbenzene ND ug/L 5.0 1 04/15/22 20:56 135-98-8
tert-Butylbenzene ND ug/L 5.0 1 04/15/22 20:56 98-06-6 l
Carbon tetrachloride ND ugiL 5.0 1 04/15/22 20:56 56-23-5
Chlorobenzene ND ug/L 5.0 1 04/15/22 20:56 108-90-7
Chloroethane ND ug/L 10.0 1 04/15/22 20:56 75-00-3
Chloroform ND ugiL 5.0 1 04/15/22 20:56 67-66-3
Chloromethane ND ug/L 5.0 1 04/15/22 20:56 74-87-3 •
2-Chlorotoluene ND ug/L 5.0 1 04/15122 20:56 95-49-8
4-Chlorotoluene ND ug/L 5.0 1 04/15/22 20:56 106-43-4
1,2-Dibromo-3-chloropropane ND ug/L 5.0 1 04/15/2220:56 96-12-8
Dibromochloromethano ND ug/L 5.0 1 04/15/22 20:56 124-48-1
1,2-Dibromoethane(EDB) ND ug/L 5.0 1 04/15/22 20:56 106-93-4
Dibromomethane ND ug/L 5.0 1 04/15/22 20:56 74-95-3
1,2-Dlchiorobenzene ND ug/L 5.0 1 04/15/22 20:56 95-50-1
1,3-Dlchlorobenzene ND ug/L 5.0 1 04/15/22 20:56 541-73-1
1,4-Dicl'dorobenzene ND ugiL 5.0 1 04/15/22 20:56 106-46-7
Dichlorodifluoromethane ND ug/L 5.0 1 04/15/22 20:56 75-71-8
1,1-Dichloroethane ND ug/L 5.0 1 04/15/22 20:56 75-34-3
1,2-Dichloroethane ND ug/L 5.0 1 04/15/22 20:56 107-06-2
1,2-Dichloroethene(Total) ND ug/L 5.0 1 04/15/22 20:56 540-59-0
1,1-Dichloroethene ND ug/L 5.0 1 04/15/22 20:56 75-35-4
cis-1,2-Dichloroethene ND ug/L 5.0 1 04/15/22 20:56 156-59-2
trans-1,2-Dichloroethene ND ug/L 5.0 1 04/15/22 20:56 156.60-5
1,2-Dichloropropane ND ug/L 5.0 1 04/15/22 20:56 78-87-5
1,3-Dichloropropane ND ug/L 5.0 1 04/15/22 20:56 142-28-9
2,2-Dichloropropane ND ug/L 5.0 1 04/15/22 20:56 594-20-7 '
1,1-Dichloropropene ND ug/L 5.0 1 04/15/22 20:56 563-58-6 •
cis-1,3-Dichloropropono ND ug/L 5.0 1 04/15/22 20:56 10061-01-5
trans-1,3-Dichloropropene ND ug/L 5.0 1 04/15/22 20:56 10061-02-6
Diisopropyl ether ND ug/L 5.0 1 04/15/22 20:56 108-20-3
Ethylbenzene ND ug/L 5.0 1 04/15/22 20:56 100-41-4
Hexachloro-1,3-butadiene ND ug/L 5.0 1 04/15/22 20:56 87-68-3
2-Hexanone ND ugiL 10.0 1 04/15/22 20:56 591-78-6
Isopropylbenzene(Cumene) ND ug/L 5.0 1 04/15/22 20:56 98-82-8
p-lsopropyltoluene ND ugiL 5.0 1 04/15/22 20:56 99-87-6
REPORT OF LABORATORY ANALYSIS
This report snail not be reproduced,except in ful,
Date:04/19/2022 02:10 PM without the written consent of°ace Analytical Services,LLC. Page 6 of 19

Pace Analytical Services,LLC
1377 South Park Drive
__ aceAnalytical
KemersvlYe,NC 27294
www.pacoIabs.com [phone]
ANALYTICAL RESULTS
Project: MILLIKEN MONITOR WELL
Pace Project No.: 92599485
Sample: MILLIKEN MONITOR WELL Lab ID: 92599485002 Collected: 04/12/22 11:35 Received: 04/14/22 10:00 Matrix: Water
#7
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
8260D MSV Analytical Method:EPA 8260D
Pace Analytical Services-Charlotte
Methylene Chloride ND ug/L 5.0 1 04/15/22 20:56 75-09-2
4-Methyl-2-pentanone(MIBK) ND ug/L 10.0 1 04/15/22 20:56 108-10-1
Methyl-tert-butyl ether ND ug/L 5.0 1 04/15/22 20:56 1634-04-4 v1
Naphthalene ND ug/L 5.0 1 04/15/22 20:56 91-20-3
n-Propylbenzene ND ug/L 5.0 1 04/15/22 20:56 103-65-1
Styrene ND ug/L 5.0 1 04/15/22 20:56 100-42-5
1,1,1,2-Tetrachloroethane ND ug/L 5.0 1 04/15/22 20:56 630-20-6
1,1,2,2-Tetrachloroethane ND ug/L 5.0 1 04/15/22 20:56 79-34-5
Tetrachloroethene ND ug/L 5.0 1 04/15/22 20:56 127-18-4
Toluene ND ug/L 5.0 1 04/15/22 20:56 108-88-3
1,2,3-Trichlorobenzene ND ug/L 5.0 1 04/15/22 20:56 87-61-6
1,2,4-Trichlorobenzene ND ug/L 5.0 1 04/15/22 20:56 120-82-1
1,1,1-Trichloroethane ND ug/L 5.0 1 04/15/22 20:56 71-55-6
1,1,2-Trlchloroethane ND ug/L 5.0 1 04/15/22 20:56 79-00-5
Trichloroethene ND ug/L 5.0 1 04/15/22 20:56 79-01-6
Trichlorofluoromethane ND ug/L 10.0 1 04/15/22 20:56 75-69-4
1,2,3-Trichloropropane ND ug/L 5.0 1 04/15/22 20:56 96-18-4
1,2,4-Trimethylbenzene ND ug/L 5.0 1 04/15/22 20:56 95-63-6 •
1,3,5-Trimethylbenzene ND ug/L 5.0 1 04/15/22 20:56 108-67-8
Vinyl acetate ND ug/L 10.0 1 04/15/22 20:56 108-05-4 '
Vinyl chloride ND ug/L 5.0 1 04/15/22 20:56 75-01-4
m&p-Xylene ND ug/L 10.0 1 04/15/22 20:56 179601-23-1
o-Xylene ND ug/L 5.0 1 04/15/22 20:56 95-47-6
Surrogates
4-Bromofluorobenzene(S) 101 % 70-130 1 04/15/22 20:56 460-00-4
1,2-Dichloroethane-d4(S) 96 % 70-130 1 04/15/22 20:56 17060-07-0
Toluene-d8(S) 109 % 70-130 1 04/15/22 20:56 2037-26-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except In full,
Date:04/19/2022.02:10 PM without the written corset of Pace Analytical Services,LLC. Page 7 of 19

INIRTERiTECH
POST OFFICE BOX 1056 • #5 PINEWOOD PLAZA DR.
GRANITE FALLS,NORTH CAROLINA 28630
[phone]
SAMPLE: Milliken-Golden Valley Well#8 COLLECTION DATE: 4/12/2022
PERMIT#: COLLECTION TIME: 12:10
ADDRESS: Milliken & Co. RECEIVED DATE: 4/12/2022
Rt. 2, Highway 226 RECEIVED TIME: 15:10
Bostic, NC 28018
REPORTED: 5/10/2022
ANALYSIS
ANALYSIS RESULTS UNITS DATE ANALYST
NO3 as N 0.44 mg/L 4/20/22 jdg
VOC's pace
NH3 <1.0 mg/L 4/14/22 jrg
LOG ID: 2204-163 REPORTED BY: NC CERTIFIED LAB 4 50
6
Tony Gragg, Lab Supervisor

Pace Analytical Services,LLC
aceAnalytical 1377 South Park Drive
7
Kemersville,NC 27284
www.pacelabs.com
[phone]
1
I
ANALYTICAL RESULTS
Project: MILLIKEN MONITOR WELL
Pace Project No.: 92599485
Sample: MILLIKEN MONITOR WELL Lab ID: 92599485003 Collected: 04/12/22 12:10 Received: 04/14/22 10:00 Matrix: Water
#8
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
8260D MSV Analytical Method:EPA 8260D
Pace Analytical Services-Charlotte
Acetone ND ugiL 25.0 1 04/15/22 21:14 67-64-1
Benzene ND ug/L 5.0 1 04/15/22 21:14 71-43-2
Bromobenzene ND ug/L 5.0 1 04/15/22 21:14 108-86-1
Bromochloromethane ND ug/L 5.0 1 04;15/22 21:14 74-97-5
Bromodichloromethane ND ug/L 5.0 1 04/15/22 21:14 75-27-4
Bromoform ND ug/L 5.0 1 04/15/22 21:14 75-25-2
Bromomethane ND ug/L 10.0 1 04/15/22 21:14 74-83-9
2-Butanone(MEK) ND ug/L 10.0 1 04/15./22 21:14 78-93-3
tart-Butyl Alcohol ND ug/L 100 1 04/15/22 21:14 75-65-0
n-Butylbenzene ND ug/L 5.0 1 04/15/22 21:14 104-51-8
sec-Butylbenzene ND ug/L 5.0 1 04/15/22 21:14 135-98-8
tert-Butylbenzene ND ug/L 5.0 1 04/15/22 21:14 98-06-6
Carbon tetrachloride ND ug/L 5.0 1 04/15/22 21:14 56-23-5
Chlorobenzene ND ug/L 5.0 1 04/15/22 21:14 108-90-7
Chloroethane ND ugiL 10.0 1 04/15/22 21:14 75-00-3
Chloroform ND ug/L 5.0 1 04/15/22 21:14 67-66-3
Chloromethane ND ug/L 5.0 1 04/15/22 21:14 74-87-3
2-Chlorotoluone ND ug/L 5.0 1 04/15/22 21:14 95-49-8
4-Chlorotoluene ND ug/L 5.0 1 04/15/22 21:14 106-43-4
1,2-Dibromo-3-chloropropane ND ug/L 5.0 1 04/15/22 21:14 96-12-8
Dibromochloromethane ND ug/L 5.0 1 04/15/22 21:14 124-48-1
1,2-Dibromoethane(EDB) ND ug/L 5.0 1 04/15/22 21:14 106-93-4
Dibromomethane ND ug/L 5.0 1 04/15/22 21:14 74-95-3 '
1,2-Dichlorobenzene ND ugiL 5.0 1 04/15/22 21:14 95-50-1
1,3-Dichlorobenzene ND ug/L 5.0 1 04/15/22 21:14 541-73-1
1,4-Dichlorobenzeno ND ug/L 5.0 1 04/15/22 21:14 106-46-7 I
Dichlorodifluoromethano ND ug/L 5.0 1 04/15/22 21.14 75-71-8
1,1-Dichloroothane ND ug/L 5.0 1 04/15/22 21:14 75-34-3 •
1,2-Dichloroethene ND ug/L 5.0 1 04/15/22 21:14 107-06-2
1,2-Dichloroethene(Total) ND ug/L 5.0 1 04/15/22 21:14 540-59-0
1,1-Dichloroethene ND ugiL 5.0 1 04/15/22 21:14 75-35-4
cis-1,2-Dichloroethene ND ug/L 5.0 1 64/15/22 21:14 156-59-2
trans-1,2-Dichloroethene ND ug/L 5.0 1 04/15/22 21:14 156-60-5
1,2-Dichloropropane ND ug/L 5.0 1 04/15/22 21:14 78-87-5
1,3-Dichloropropane ND ug/L 5.0 1 04/15/22 21:14 142-28-9
2,2-Dichloropropane ND ug/L 5.0 1 04/15/22 21:14 594-20-7
1,1-Dichloropropene ND ug/L 5.0 1 04/15/22 21:14 563-58-6
cis-1,3-Dichloropropene ND ug/L 5.0 1 04115/22 21:14 10061-01-5
trans-1,3-Dichloropropene ND ug/L 5.0 1 04/15/22 21:14 10061-02-6
Diisopropyl ether ND ug/L 5.0 1 04/15/22 21:14 108-20-3
Ethylbenzene ND ug/L 5,0 1 04/15/22 21:14 100-41-4
Hexachloro-1,3-butadiene ND ug/L 5.0 1 04/15/22 21:14 87-68-3
2-Hexanone ND ug/L 10.0 1 04/15/22 21:14 591-78-6
Isopropyl benzene(Cumene) ND ugiL 5.0 1 04/15/22 21:14 98-82-8
p-Isopropyltoluene ND ug!L 5.0 1 04/15/22 21:14 99-87-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:04/19/2022 02:10 PM without the written consent of Pace Analytical Services,LLC Page 8 of 19

,, Pace Analytical Services,LLC
'aceAnalytical 1377 South Park Drive
Kernersville,NC 27284
www.pacolebs.cam [phone]
I
I
ANALYTICAL RESULTS
Project: MILLIKEN MONITOR WELL
Pace Project No.: 92599485
Sample: MILLIKEN MONITOR WELL Lab ID: 92599485003 Collected: 04/12/22 12:10 Received: 04/14/22 10:00 Matrix: Water
#8
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
8260D MSV Analytical Method:EPA 8260D
Pace Analytical Services-Charlotte
Methylene Chloride ND ug/L 5.0 1 04/15/22 21:14 75-09-2
4-Methyl-2-pentanone(MIBK) ND ug/L 10.0 1 04/15/2221:14 108-10-1
Methyl-tert-butyl ether ND ug/L 5.0 1 04/15/22 21:14 1634-04-4 v1
Naphthalene ND ug/L 5.0 1 04/15/22 21:14 91-20-3
n-Propylbenzene ND ug/L 5.0 1 04115/22 21:14 103-65-1
Styrene ND ug/L 5.0 1 04/15/22 21:14 100-42-5
1,1,1,2-Tetrachloroethane ND ug/L 5.0 1 04/15/22 21:14 630-20-6
1,1,2,2-Tetrachloroethane ND ug/L 5.0 1 04/15/22 21:14 79-34-5
Tetrachloroethene ND ug/L 5.0 1 04/15/22 21:14 127-18-4
Toluene ND ug/L 5.0 1 04/15/22 21:14 108-88-3
1,2,3-Tdchlorobenzene ND ug/L 5,0 1 04/15/22 21:14 87-61-6
1,2,4-Trichlorobenzene ND ug/L 5.0 1 04/15/22 21:14 120-82-1
1,1,1-Trichloroethane ND ugIL 5.0 1 04/15/22 21:14 71-55-6
1,1,2-Trichloroethene ND ugIL 5.0 1 04/15/22 21:14 79-00-5
Trichloroethene ND ug/L 5.0 1 04/15/22 21:14 79-01-6
Trichlorotluoromethane ND ug/L 10.0 1 04/15/22 21:14 75-69-4
1,2,3-Trichloropropane ND ug/L 5.0 1 04/15/22 21:14 96-18-4
1,2,4-Trimethylbenzene ND ug/L 5.0 1 04/15/22 21:14 95-63-6
1,3,5-Tnmethylbenzene ND ug/L 5.0 1 04/15/22 21:14 108-67-8
Vinyl acetate ND ug/L 10.0 1 04/15/22 21:14 108-05-4
Vinyl chloride ND ug/L 5.0 1 04/15/22 21:14 75-01-4. ,
m&p-Xylene ND ug/L 10.0 1 04/15/22 21:14 179601-23-1 ,
o-Xyfene ND ug/L 5.0 1 04/15/22 21:14 95-47-6
Surrogates
4-Bromofluorobenzene(S) 102 % 70-130 1 04/15/22 21:14 460-00-4
1,2-Dichloroothane-d4(S) 97 % 70-130 1 04/15/22 21:14 17060-07-0
Toluene-d8(S) 107 % 70-130 1 04/15/22 21:14 2037-26-5
i
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except In full,
Date:04/19/2022 02:10 PM without the written consent of Pace Analytical Services,LLC. Page 9 of 19

Method SM 20 Ed 450041-2011
pH WORKSHEET
Analysis Collection
Date Time Sample ID Date Time Results SU's Analyst
Buffer 4.00 ***** ***** ecLIAZ
06, y 2_. Buffer 10.00
06. y. Buffer 7.00 QC
7.
***** Slope Efficiency *****
*****
***** *****
*****
az 101
7/0 5 /111/h/e..e....nit4/41 6 4:-/2-2 7- /1 ci?)
a1/41-6 kto4 7 /(33.- 62•(*
/2-- 11 4101- g $i 12/ ?. 3
/
BUFFERS:
4.00 LOT# 8111363 EXP NOV 2023
7.00 LOT# 8110554 EXP NOV 2023
10.00 LOT# 8109645 EXP OCT 2023
*NON REPORTABLE
FOR NPDES
COMPLIANCE_MONITORING_ DUPLICATE/S 0.1-SU'S- - — -—

SUBMIT FORM ON YELLOW PAPER ONLY
GROUNDWATER QUALITY MONITORING: Mail original DEPARTMENT OF ENVIRONMENTAL QUALITY-DIV.OF WATER RESOURCES
INFORMATION PROCESSING UNIT
COMPLIANCE REPORT FORM and 1 COpy t0: 1617 MAIL SERVICE CENTER,RALEIGH,NC 27699-1617 -
FACILITY INFORMATION Please Print Clearly or Type PERMIT Number: Expiration Date: 7/31/2028
Facility Name: Milliken and Company-Golden Valley Plant Non-Discharge WQ0002052 UIC
Permit Name(if different): NPDES Other
Facility Address: 2080 NC Hwy.226 TYPE OF PERMITTED OPERATION BEING MONITORED
Bostic (Street) NC 28018 Count
y Rutherford ❑ Lagoon CI Remediation: Infiltration Gallery
(City) (State) (Zip) ❑■ Spray Field ❑Remediation:
Contact Person: Greg Marana Telephone#: [phone] ❑ Rotary Distributor ❑ Land Application of Sludge
Well Location/Site Name:Monitor Well#6(Upgradient) No.of wells to be sampled: 3 ❑ Water Source Heat Pump ❑Other:
(from Permit)
SAMPLING INFORMATION If WELL
WELL ID NUMBER(from Permit): N76Y6 Date sample collected: 4/12/2022 FIELD ANALYSES: WAS
Well Depth: 40 ft. Well Diameter: 2 in. pH 00400: 7.8 units Temp.0o010: °C DRY at
Depth to Water Level 82546:39.2 ft. below measuring point Screened Interval: 29.5 ft. to 40 ft. Spec.Cond.00094: µMhos time of
sampling,
Measuring Point is 2 ft.above land surface Relative M.P. Elevation: 1174.8 ft. Odor 00085: check
Volume of water pumped/bailed before sampling: 0.4 gallons Appearance here:
Samples for metals were collected unfiltered: ❑YES ❑■ NO and field acidified: ❑YES Ill NO
LABORATORY INFORMATION
Date sample analyzed:4/15/2022 Laboratory Name: Water Tech and Pace Analytical Certification No. 50 and 12
PARAMETERS NOTE:Values should reflect dissolved and colloidal concentrations.
COD 00335 mg/L Nitrite(NO2)as N oasis mg/L Pb-Lead o1os1 ug/L
Coliform: MF Fecal 31616 /100mL Nitrate(NO3)as N 00620 .69 mg/L Zn-Zinc o1092 mg/L
Coliform: MF Total 31504 /100mL Phosphorus:Total as P oo665 mg/L
(Note: Use MPN method for highly turbid samples) Orthophosphate 70507 mg/L Other(Specify Compounds and Concentration Units):
Dissolved Solids:Total 70300 mg/L Al-Aluminum o11os mg/L
pH(Lab)00403 units Ba-Barium 01007 ug/L
TOC 00680 mg/L Ca-Calcium 00916 mg/L
Chloride 00940 mg/L Cd-Cadmium 01027 ug/L
Arsenic o1002 ug/L Chromium:Total 01034 ug/L
Grease and Oils 00552 mg/L Cu-Copper 01042 mg/L ORGANICS:(by GC,GC/MS,HPLC)
Phenol 32730 ug/L Fe-Iron o1o4s ug/L (Specify test and method#.ATTACH LAB REPORT.)
Sulfate o0945 mg/L Hg-Mercury 71900 ug/L Lab Report Attached? ❑■ Yes(1) ❑ No(0)
Specific Conductance 0009s µMhos K-Potassium 00937 mg/L VOC 7873 ,method# 8260D
Total Ammonia oo610 <1.0 mg/L Mg-Magnesium 00927 mg/L , method#
(Ammonia Nitrogen;NH3as N;Ammonia Nitrogen,Total) Mn-Manganese a1o55 ug/L , method#
TKN as N oo62s mg/L Ni-Nickel 01067 ug/L , method#
For Remediation Systems Only(Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal%
I certify that,to the best of my knowledge and belief,the information submitted in this report is true.accurate,and complete.and that the laboratory analytical data was produced using approved methods of analysis by a
DWR-certified laboratory. I am aware that there are significant penalties for submitting false information.including the possibility of fines and imprisonment fnr knowing violations.
J.R.Williams,Plant Leader �� iflr�/a'
Permittee(or Authorized Agent)Name and Title-Please print or type Signature of Permitt:-(o Authorized Agent) (Da e)
GW-59 Rev.06-07-2018

SUBMIT FORM ON YELLOW PAPER ONLY
Mail original 7 m,_ .,.`TMENT OF ENVIRONMENTAL QUALITY-DIV.OF WATER RESOURCES
GROUNDWATER QUALITY MONITORING: and 1 copy to: INFORMATION PROCESSING UNIT -
COMPLIANCE REPORT FORM 1617 MAIL SERVICE CENTER,RALEIGH,NC 27699-1617
FACILITY INFORMATION Please Print Clearly or Type PERMIT Number: Expiration Date: 7/31/2028
Facility Name: Milliken and Company-Golden Valley Plant Non-Discharge W00002052 UIC
Permit Name(if different): NPDES Other
Facility Address: 2080 NC Hwy.226 TYPE OF PERMITTED OPERATION BEING MONITORED
Bostic °'' NC 28018 County
Rutherford ❑ Lagoon El Remediation: Infiltration Gallery
Slate) °' ❑■ Spray Field ❑ Remediation:
Contact Person: Greg Marana Telephone#: [phone] ❑ Rotary Distributor ❑ Land Application of Sludge
Well Location/Site Name:Monitor Well#7(Downgradient) No.of wells to be sampled: 3 ❑ Water Source Heat Pump ❑Other:
(from Permit)
SAMPLING INFORMATION If WELL
WELL ID NUMBER(from Permit): N76Y7 Date sample collected: 4/12/2022 FIELD ANALYSES: WAS
Well Depth: 30 ft. Well Diameter: 2 in. pH 00400: 6.6 units Temp. 00olo: °C DRY at
Depth to Water Level 82546:6.1 ft. below measuring point Screened Interval: 19 ft. to 29 ft. Spec.Cond. 00094: tiMhos time of
sampling,
Measuring Point is 2 ft. above land surface Relative M.P. Elevation: 1106.2 ft. Odor 00085: check
Volume of water pumped/bailed before sampling: 11.7 gallons Appearance here:
Samples for metals were collected unfiltered: ❑YES ❑■ NO and field acidified: ❑YES ❑■ NO
LABORATORY INFORMATION
Date sample analyzed:4/15/2022 Laboratory Name: Water Tech and Pace Analytical Certification No. 50 and 12
PARAMETERS NOTE:Values should reflect dissolved and colloidal concentrations.
COD 00335 mg/L Nitrite(NO2)as N 00615 mg/L Pb-Lead 01051 ug/L
Coliform: MF Fecal 31616 /100mL Nitrate(NO3)as N 00620 .39 mg/L Zn-Zinc 01092 mg/L
Coliform: MF Total 31504 /100mL Phosphorus:Total as P 0066s mg/L
(Note Use MPN method for highly turbid samples) Orthophosphate 70507 mg/L Other(Specify Compounds and Concentration Units):
Dissolved Solids:Total 70300 mg/L Al-Aluminum o11os mg/L
pH (Lab)00403 units Ba-Barium 01007 ug/L
TOC 00680 mg/L Ca-Calcium 00916 mg/L
Chloride 00940 mg/L Cd-Cadmium 01027 ug/L
Arsenic 01002 ug/L Chromium: Total 01034 ug/L
Grease and Oils 00552 mg/L Cu-Copper 01042 mg/L ORGANICS: (by GC, GC/MS, HPLC)
Phenol 32730 ug/L Fe-Iron o1045 ug/L (Specify test and method#.ATTACH LAB REPORT.)
Sulfate 00945 mg/L Hg-Mercury 71900 ug/L Lab Report Attached? ❑� Yes(1) ❑ No(0)
Specific Conductance 00095 tiMhos K-Potassium 00937 mg/L VOC 7873 , method# 8260D
Total Ammonia 00610 <1.0 mg/L Mg-Magnesium 00927 mg/L , method#
(Ammonia Nitrogen,NH5as N,Ammonia Nitrogen,Total) Mn-Manganese 01055 ug/L , method#
TKN as N 00625 mg/L Ni-Nickel 01067 ug/L , method#
For Remediation Systems Only(Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal%
I certify that,to the best of my knowledge and belief,the information submitted in this report is true.accurate.and complete.and that the laboratory analytical data was produced using approved methods of analysis by a
DWR-certified laboratory. I am aware that there are significant penalties for submitting false information,including the possibility of fines and imprisonment for knowing violations.
J.R.Williams,Plant Leader i G s //&/�a—
Permittee(or Authorized Agent)Name and Title-Please print or type Signature of P mittee(or Authorized Agent) (Date)
GW-59 Rev.06-07-2018

SUBMIT FORM ON YELLOW PAPER ONLY
GROUNDWATER QUALITY MONITORING: Mail original r t -. ., , ,,,; �'y � t A
COMPLIANCE REPORT FORM and 1 copy to A , � : ; �.
FACILITY INFORMATION Please Print Clearly or Type PERMIT Number: Expiration Date: 7/31/2028
Facility Name: Milliken and Company-Golden Valley Plant Non-Discharge WQ0002052 UIC
Permit Name(if different): NPDES Other
Facility Address: 2080 NC Hwy.226 TYPE OF PERMITTED OPERATION BEING MONITORED
Bostic (Street) NC 28018 Count
y Rutherford CI Lagoon ❑ Remediation: Infiltration Gallery
(City) (State) (Zip)
❑■ Spray Field ❑Remediation:
Contact Person: Greg Marana Telephone#: [phone] ❑ Rotary Distributor ❑ Land Application of Sludge
Well Location/Site Name:Monitor Well#8(Downgradient) No.of wells to be sampled: 3 ❑ Water Source Heat Pump ❑Other:
(from Permit)
SAMPLING INFORMATION If WELL
WELL ID NUMBER(from Permit): N76Y8 Date sample collected: 4/12/2022 FIELD ANALYSES: WAS
Well Depth: 30 ft. Well Diameter: 2 in. pH 00400: 8.3 units Temp.0o010: °C DRY at
Depth to Water Level 82546:10.1 ft.below measuring point Screened Interval: 19.5 ft. to 30 ft. Spec.Cond.00094: µMhos time of
sampling,
Measuring Point is 2 ft.above land surface Relative M.P. Elevation: 1073.5 ft. Odor 00085: check
Volume of water pumped/bailed before sampling: 11.7 gallons Appearance here:n
Samples for metals were collected unfiltered: ❑YES ❑■ NO and field acidified: ❑YES ■❑NO
LABORATORY INFORMATION
Date sample analyzed:4/15/2022 Laboratory Name: Water Tech and Pace Analytical Certification No. 50 and 12
PARAMETERS NOTE:Values should reflect dissolved and colloidal concentrations.
COD 00335 mg/L Nitrite(NO2)as N 00615 mg/L Pb-Lead o1051 ug/L
Coliform: MF Fecal 31616 /100mL Nitrate(NO3)as N oo620 .44 mg/L Zn-Zinc 01092 mg/L
Coliform:MF Total 31504 /100mL Phosphorus:Total as P o0665 mg/L
(Note Use MPN method for highly turbid samples) - Orthophosphate 70507 mg/L Other(Specify Compounds and Concentration Units):
dissolved Solids:Total 70300 mg/L Al-Aluminum o1105 mg/L
pH(Lab)00403 units Ba-Barium o1007 ug/L
TOC 00680 mg/L Ca-Calcium 00916 mg/L
Chloride 00940 mg/L Cd-Cadmium 01027 ug/L
Arsenic olooz ug/L Chromium:Total 01034 ug/L
Grease and Oils 00552 mg/L Cu-Copper 01042 mg/L ORGANICS:(by GC, GC/MS, HPLC)
Phenol 32730 ug/L Fe-Iron o1045 ug/L (Specify test and method#.ATTACH LAB REPORT.)
Sulfate 00945 mg/L Hg-Mercury 71900 ug/L Lab Report Attached? ❑■ Yes(1) ❑ No(0)
Specific Conductance o0095 µMhos K-Potassium 00937 mg/L VOC 7873 , method# 8260D
Total Ammonia oos10 <1.0 mg/L Mg-Magnesium 00927 mg/L , method#
(Ammonia Nitrogen;NH3 asN,Ammonia Nitrogen,Total) Mn-Manganese o1055 ug/L ,method#
TKN as N 00625 mg/L Ni-Nickel 01067 ug/L , method#
For Remediation Systems Only(Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal%
I certify that,to the best of my knowledge and belief.the information submitted in this report is true.accurate and complete.and that the laboratory analytical data was produced using approved methods of analysis by a
DWR-certified laboratory. I am aware that there are significant penalties for submitting false information.including the possibility of fines and imprisonment for know:tg violations.
J.R.Williams,Plant Leader , _______ /, Z/,x1)._
Permittee(or Authorized Agent)Name and Title-Please print or type Signature Permitte r (or Authorized Agent) (Date)
GW-59 Rev.06-07-2018