WQ0004797_Monitoring - 05-2022_20220623

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DWR - NonDischarge Monitoring Report Submittal
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NORTH CAROLINA
Enrlranmenlel QHaffly
Monitoring Report Submittal
..............................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................
Permit Number#* WQ0004797
Name of Facility:* Clement Pappas NC LLC
Month:* May Year:* 2022
Report Information
Type* Upload Document*
GW-59 May 2022 Ground Water 7.86MB
Sampling Signed-Permit No.
WQ0004797_.pdf
PDF Only
Please upload one PDF containing all applicable monitoring reports
(i.e., NDMR, NDAR-1,NDAR-2,NDMLR,GW-59).
Confirmation Email Address:* [e-mail]
Name of Submitter:* Dale I Wolfe
Signature:
a4 V 4
Date of submittal: 6/23/2022
This will be filled in automatically
Initial Review

Reviewer: Gerald,Wanda
Is the project number correct?* WQ0004797
Is the monitoring report accepted?* Yes No
Regional Office* Asheville
Reviewer: _anonymous
Review Date: 7/12/2022

Anchor QEA of North Carolina,PLLC + A
CHOR
231 Haywood Street
Asheville,North Carolina 28801
828.281.3350
June 21, 2022
Blake Kehoe
Director, Engineering
Lassonde Pappas & Company, Inc.
125 Industrial Park Road
Hendersonville, North Carolina 28792
Re: Spring 2022 Water Quality Sampling Event
Non-Discharge Permit No. WQ0004797
Clement Pappas NC, LLC
Dear Mr. Kehoe,
Anchor QEA of North Carolina, PLLC, is pleased to present the results of the Spring 2022 water quality
monitoring event at the Clement Pappas NC, LLC (Clement Pappas) facility(the Site), located at
485 Brookside Camp Road in Hendersonville, North Carolina.As recommended by the North Carolina
Department of Environmental Quality(DEQ),Anchor QEA performed disinfection of monitoring wells
MW-5, MW-6, MW-7R, and MW-8 and redevelopment of MW-7R prior to the water quality monitoring
event.The company that operates the facility rebranded to Lassonde Pappas&Company in 2016.
However,for permitting purposes,the Hendersonville facility retains the Clement Pappas NC LLC name
that is designated on the property deed. Clement Pappas is currently permitted under a Wastewater
Irrigation System Permit by the North Carolina Department of Environmental Quality(DEQ)
Environmental Management Commission for the operation of a 99,900-gallon-per-day wastewater
treatment and irrigation facility.
Groundwater Well Chlorination and Development
The DEQ recommended disinfection of MW-5, MW-6, MW-7R, and MW-8 to address intermittent
detections of fecal coliform bacteria in the Compliance Inspection Report for the Clement Pappas
Wastewater Treatment Facility,dated January 27, 2022. Additionally, the DEQ recommended
redevelopment of MW-7R to address plant roots penetrating the well screen and buildup of organic
debris at the bottom of the casing, which may have been impacting water quality immediately
around the well screen and sand pack. As reported in the Fall Groundwater Sampling Event and Well
Integrity Evaluation, dated December 17, 2022, Anchor QEA identified root growth and organic
debris in MW-7R during the well integrity evaluation performed in October 2021.
Anchor QEA mobilized to the Site to perform chlorination of MW-5, MW-6, MW-7R, and MW-8 on
April 20, 2022, in accordance with DEQ disinfection guidelines. Based on well volume and sand pack
calculations, chlorine (68% sodium hypochlorite) mixed with deionized water was poured down each
\\Athena\Asheville\Projects\Clement Pappas\Reports\2022\May\20220621_Spring2022_Groundwater Sampling Event Clement Pappas NC,LLC.docx

June 21,2022
Page 2
monitoring well, making sure to allow contact with the PVC well casing. A submersible pump was
then lowered into the well within the screen interval and used to recirculate the chlorinated mixture
within the well and formation. At least three well volumes were recirculated in each well.
Anchor QEA returned to the site two days later on April 22, 2022, to purge chlorinated water and
flush all five wells. A submersible pump was lowered into each well, within the screened interval, and
used to pump at least three well volumes out of the well. Purge water from each well was disposed
of on land in the vicinity of the well, in accordance with DEQ approval. The submersible pump was
decontaminated between each monitoring well during chlorination and purging activities.
On April 22, 2022, Anchor QEA began redevelopment of MW-7R with a Waterra Hydrolift pump and
surge block. Anchor QEA attempted to purge organic debris with a trash pump; however, the pump
did not function. Anchor QEA returned on May 6, 2022, to purge organic debris with a diaphragm
pump and complete redevelopment with a Waterra pump and surge block. Monitoring well
chlorination and redevelopment logs are included in Attachment 1.
Groundwater Quality
Anchor QEA performed the groundwater sampling event at the Site on March 10, 2022.A Site location
map is included in Figure 1.The groundwater sampling event was performed in accordance with DEQ
wastewater irrigation system permit No. WQ0004797 issued September 3, 2015, and renewed
May 15, 2020(referred to as "the permit" in this letter; effective September 1, 2020, and expiring
July 31,2026).Anchor QEA used low-flow methods to purge and collect groundwater samples from six
monitoring wells: MW-4, MW-5, MW-6, MW-7R, MW-8, and MW-9. Monitoring well MW-9 was installed
April 14, 2015,to replace the previously damaged monitoring well MW-2R.The locations of the
monitoring wells are shown in Figure 2.Anchor QEA submitted the groundwater samples to Pace
Analytical Services, Inc.,a North Carolina-certified laboratory,for analysis of the parameters specified in
the permit, as follows:
• Total organic carbon • Total nitrate
• Chloride • Phosphorous
• Fecal coliform • Total dissolved solids
• Total ammonia
Groundwater Elevation
Table 1 summarizes current and historical groundwater elevations from November 2018 to May 2022.
Except for monitoring well MW-9,all monitoring well concrete pads and top-of-well casing (TOC)
elevations were surveyed by Wes Cole Land Surveying, PA,on November 21, 2012. Monitoring well
MW-9 was surveyed by Wes Cole Land Surveying, PA, on May 29, 2015.The surveyed TOC elevations are
shown in Table 1.

June 21,2022
Page 3
Groundwater Analytical Results
Table 2 summarizes the current and historical groundwater analytical results from November 2018 to
May 2022. During the current sampling event,the parameters analyzed were below or within the
groundwater standards provided in the permit,' except for nitrate and pH,which are described as follows:
• The pH of the samples collected from MW-4 (5. 8 standard units [SU]), MW-5 (5.6 SU),
MW-6 (5.4 SU), MW-7R (5.1 SU), and MW-9 (5.4 SU) were below the groundwater standard
range of 6.5 to 8.5 SU. The sample collected from the background monitoring well, MW-5, has
a pH (5.6) that is similar to the other groundwater monitoring wells.
• The nitrate concentration exceeded the permit groundwater standard of 10 milligrams per
liter (mg/L) in the sample collected from one monitoring well, MW-7R (31.0 mg/L).
The 2L standard for total coliform is 1 colony-forming unit per 100 milliliters (1 CFU/100 mL). There is
no specific permit limit or 2L standard for fecal coliform; however, total coliform includes fecal
coliform. Fecal coliform was not detected at or above laboratory detection limits in any groundwater
samples.
Surface Water Quality
Beginning in May 2017, Clement Pappas voluntarily collected surface water samples from Mud Creek,
analyzing for the same constituents as those sampled in groundwater. The renewed permit issued in
May 2020 and effective September 2020 requires semiannual sampling of the surface water
locations. Sampling point SW-1 is located upstream of the Site, and sampling point SW-2 is located
downstream of the Site. Sampling locations are shown in Figure 2.
Surface Water Analytical Results
Table 3 summarizes the historical and current surface water analytical results. For the May 2022
sampling event, no parameters were detected at concentrations above the associated Title 15A
NCAC Subchapter 2B surface water standards (2B standards).
Since collection of surface water samples for all permit constituents began in May 2017, nitrate
concentrations have been similar in SW-1 (upstream) and SW-2 (downstream). The Spring 2022
sampling showed a similar relationship: upstream sample SW-1 had a nitrate concentration of
0.88 mg/L, while downstream sample SW-2 had a concentration of 0.87 mg/L. The results for total
organic carbon, chloride,total dissolved solids (TDS), ammonia, and total phosphorus were also
similar for upstream and downstream samples, indicating the unlikelihood that the Site is impacting
Mud Creek.
1 Most of the groundwater standards are represented by the 2L standards,with the exception of nitrate and total organic carbon,
which are set in the Wastewater Irrigation System Permit Number WQ0004797.

June 21,2022
Page 4
Discussion and Recommendations
Based on analytical results, monitoring well disinfection appeared to address previous fecal coliform
issues. Fecal coliform was below laboratory detection limits in all groundwater samples collected
during the Spring 2022 sampling event.
Anchor QEA performed redevelopment of MW-7 to remove organic debris, which have accumulated
due to root penetration of the well screen and impacted water quality; however, the concentration of
nitrate in the sample collected from MW-7R during the Spring 2022 sampling event remained above
the permit standard. The root mass on the outside of the casing and within the sand pack may be
continuing to leach nitrogen as organic matter decays.
Nitrate concentrations were below the permit standard in samples collected from all other
monitoring wells. The results for all analyzed constituents in surface water, including nitrate, were
below applicable standards and similar for upstream and downstream samples. Per a discussion
regarding the results with DEQ Hydrogeologist, Brett Laverty, Anchor QEA will continue to monitor
nitrate concentrations to determine if further action is needed.
In accordance with the spray irrigation permit WQ0004797, Clement Pappas is required to submit the
following to the DEQ by June 30, 2022 (on or before the last working day of the month following the
sampling month):
• Laboratory analytical reports and chain-of-custody forms (Attachment 2)
• Well sampling logs and the equipment documentation and instrument calibration data sheet
(Attachment 3)
• DEQ GW-59A—Compliance Report Form (Attachment4)
• DEQ GW-59—Groundwater Quality Monitoring: Compliance Report Form, for each
monitoring well (Attachment 5)
Anchor QEA proposes to complete the next scheduled groundwater and surface water sampling
event in November 2022.

June 21,2022
Page 5
If you have any questions or would like additional information, please do not hesitate to contact me
at [phone] [e-mail].
Sincerely,
1a V. Ci)
~°t
Jennifer Verde, PE James Robert Howell, PG
Managing Engineer Principal Scientist
Attachments
Table 1 Current and Historical Groundwater Elevation Measurements
Table 2 Current and Historical Groundwater Analytical Results
Table 3 Current and Historical Surface Water Analytical Results
Figure 1 Site Location Map
Figure 2 Site Map
Attachment 1 Monitoring Well Chlorination and Redevelopment Logs
Attachment 2 Laboratory Analytical Reports and Chain-of-Custody Forms
Attachment 3 Well Sampling Logs and Instrument Calibration Data Sheet
Attachment 4 DEQ GW-59A—Compliance Report Form
Attachment 5 DEQ GW-59—Groundwater Quality Monitoring: Compliance Report Forms

Ta • I _ s

Table 1
Current and Historical Groundwater Elevation Measurements
Top-of-Casing
Screened Depth to Top-of-Casing Height Above Groundwater
Well Interval Date Groundwater Elevation Ground Surface Elevation
Identification (ft bgs) Measured (ft) (ft AMSL) (ft) (ft AMSL)
05/02/2018 8.44 2055.33
11/02/2018 8.00 2055.77
05/21/2019 8.49 2055.28
11/14/2019 8.82 2054.95
MW-4 5.0-15.0 05/06/2020 7.98 2063.77 2.43 2055.79
11/06/2020 8.02 2055.75
05/11/2021 8.52 2055.25
10/28/2021 9.15 2054.62
05/10/2022 9.14 2054.63
05/02/2018 8.47 2077.93
11/02/2018 8.23 2078.17
05/21/2019 8.57 2077.83
11/14/2019 8.90 2077.50
MW-5 9.0-19.0 05/06/2020 8.28 2085.60 3.00 2078.12
11/06/2020 8.90 2077.50
05/11/2021 8.77 2077.63
10/28/2021 9.44 2076.96
05/10/2022 9.15 2076.45
05/02/2018 5.36 2056.54
11/02/2018 5.03 2056.87
05/21/2019 5.53 2056.37
11/14/2019 5.59 2056.31
MW-6 5.0-10.0 05/06/2020 5.41 2061.17 3.00 2056.49
11/06/2020 5.33 2056.57
05/11/2021 5.68 2056.22
10/28/2021 5.94 2055.96
05/10/2022 5.91 2055.26
05/02/2018 10.99 2051.87
11/02/2018 10.33 2052.53
05/21/2019 10.88 2051.98
11/14/2019 11.33 2051.53
MW-7R 5.0-15.0 05/06/2020 10.11 2062.86 3.00 2052.75
11/06/2020 10.05 2052.81
05/11/2021 10.85 2052.01
10/27/2021 11.74 2051.12
05/10/2022 11.66 2051.20
05/02/2018 9.39 2051.41
11/02/2018 8.85 2051.95
05/21/2019 9.38 2051.42
11/14/2019 9.75 2051.05
MW-8 3.0-13.0 05/06/2020 8.54 2060.80 3.00 2052.26
11/06/2020 8.37 2052.43
05/11/2021 9.24 2051.56
10/27/2021 10.06 2050.74
05/10/2022 10.02 2050.78
Spring 2022 Groundwater Sampling Event Page 1 of 2
Clement Pappas,Hendersonville,North Carolina June 2022

Table 1
Current and Historical Groundwater Elevation Measurements
Top-of-Casing
Screened Depth to Top-of-Casing Height Above Groundwater
Well Interval Date Groundwater Elevation Ground Surface Elevation
Identification (ft bgs) Measured (ft) (ft AMSL) (ft) (ft AMSL)
05/02/2018 5.07 2055.16
11/02/2018 4.55 2055.68
05/21/2019 4.89 2055.34
11/14/2019 5.15 2055.08
MW-9 6.0-16.0 05/06/2020 4.30 2060.23 1.44 2055.93
11/06/2020 4.10 2056.13
05/11/2021 4.75 2055.48
10/27/2021 5.57 2054.66
05/10/2022 5.70 2054.53
Notes:
Top-of-casing elevations:MW-5 through MW-8 top-of-casing elevations are based on a survey by Hill and Associates Surveyors,
dated January 10,2002,through May 2012.MW-2R and MW-4 top-of-casing elevations are based on differential level
measurements made by Altamont Environmental,Inc.,on June 26,2006,through May 2012.The top-of-casing elevations for the
monitoring wells were resurveyed on November 21,2012,by Wes Cole Land Surveying.The top-of-casing elevations for MW-9
were surveyed on May 29,2015,by Wes Cole Land Surveying.
Monitoring is performed in accordance with Permit No.WQ0004797 issued to Clement Pappas on May 15,2020 and effective on
September 1,2020.
AMSL:above mean sea level
bgs:below ground surface
ft:feet
Spring 2022 Groundwater Sampling Event Page 2 of 2
Clement Pappas,Hendersonville,North Carolina June 2022

Table 2
Current and Historical Groundwater Analytical Results
d N
2 471 c a
o '°
'c E a D. o r r v o
al a m
m _o` o`
p` c v a 'c e a r o N E .- 2 tsi 2
..:,2 .°o o` 'm y 'm v E s s c s 5. 9
x .a c LL o Z'o E o a = « 2 E
o. 1- U U Z i VI ¢ I- I- I- i7 'v 'v
(CFUs
Sample Name Sample Date (SU) (mg/L) (mg/L) per 100 mL) (mg/L) (mg/L) (mg/L) (mg/L) (Hg/L) (Pg/L) (Pg/L) (Pg/L) (Pg/L) (Pg/L)
2L Groundwater Standards 6.5-8.5 10 250 1 NL 500 1.5 NL 0.7 3 70 100 0.03 7
Groundwater Standards Provided in Permit No.W00004797 6.5-8.5 10 250 NL 10 500 1.5 NL 0.7 3 70 100 0.03 7
05/02/2018 5.86 3.0 10.0 <1.0 2.1 167 <0.020 0.11 NR
11/02/2018 5.47 3.6 9.0 <10.0 0.48 137 <0.10 0.070 <0.50 I <0.50 I <0.50 I <0.50 I <1.0 I <0.50
05/21/2019 5.81 3.0 11.3 <1.0 3.3 170 <0.050 0.044 J NR
11/14/2019 5.82 3.7 11 <1.0 0.42 190 <0.10 <0.050 <0.50 I <0.50 I <0.50 I <0.50 I <1.0 I <0.50
MW-4 05/06/2020 5.70 2.3 7.6 <1.0 3.7 172 <0.10 <0.050 NR
11/06/2020 5.30 2.8 6.9 <1.0 0.73 148 <0.10 <0.050 <0.50 I <0.50 I <0.50 I <0.50 I <1.0 I <0.50
05/11/2021 5.8 2.8 6.9 <1.0 1.4 169 0.14 <0.050 NR
10/28/2021 5.7 3.1 6.7 <1.0 0.084 161 <0.10 <0.050 <0.50 I <0.50 I <0.50 I <0.50 I <1.0 I <0.50
05/10/2022 5.8 2.9 6.8 <1.0 0.46 136 <0.10 0.063 NR
05/02/2018 5.69 5.7 16.1 2.0 0.0 90 <0.10 0.097 NR
11/02/2018 5.53 5.1 23.9 <10.0 <0.020 86 <0.10 0.085 39.1 I 6.0 I 6.7 I <0.50 I <1.0 I <0.50
05/21/2019 5.68 9.4 26.8 7.0 0.1 91 <0.050 0.120 NR
11/14/2019 5.59 6.0 20.1 7.0 0.055 202 <0.10 0.081 22.4 I 4.4 I 5.0 I <0.50 I <1.0 I <0.50
MW-5 05/06/2020 5.90 6.9 7.3 8.0 <0.040 116 <0.10 0.083 NR
11/06/2020 5.65 4.6 6.9 8.0 <0.040 61.0 <0.10 0.060 0.80 I 1.0 I <0.50 I <0.50 I <1.0 I <0.50
05/11/2021 5.5 5.5 11.8 <2.0 <0.040 110 <0.10 0.090 NR
10/28/2021 5.7 6.6 17.3 5.0 <0.040 76.0 <0.10 0.054 30.7 I 11.6 I 12.6 I <0.50 I <1.0 I <0.50
05/10/2022 5.6 2.7 49.0 <1.0 0.10 158 <0.10 <0.050 NR
05/02/2018 5.28 2.3 9.4 1.0 0.1 81 <0.10 0.097 NR
11/02/2018 5.02 2.5 10.1 69.0 0.6 88 <0.10 0.057 <0.50 I <0.50 I <0.50 I <0.50 I <1.0 I <0.50
05/21/2019 5.46 3.3 11.3 23.0 0.4 78 <0.050 0.068 NR
11/14/2019 5.30 2.9 9.3 44.0 0.56 342 <0.10 0.052 <0.50 I <0.50 I <0.50 I <0.50 I <1.0 I <0.50
MW-6 05/06/2020 5.38 2.0 9.7 3.0 1.1 96.0 <0.10 <0.050 NR
11/06/2020 5.23 2.6 12.5 3.0 3.2 139 <0.10 <0.050 <0.50 I <0.50 I <0.50 I <0.50 I <1.0 I <0.50
05/11/2021 5.5 2.2 10.9 5.0 1.4 99.0 <0.10 <0.050 NR
10/28/2021 5.4 2.3 8.7 <1.0 <0.040 85.0 <0.10 <0.050 <0.50 I <0.50 I <0.50 I <0.50 I <1.0 I <0.50
05/10/2022 5.4 1.5 13.6 <1.0 <0.040 96.0 <0.10 <0.050 NR
Spring 2022 Groundwater Sampling Event Page 1 of 4
Clement Pappas,Hendersonville,North Carolina June 2022

Table 2
Current and Historical Groundwater Analytical Results
d N
2 = c a
o
'c Ein D. o r r r v o
ol a m
m _2 2
p` c v a C e a r o ry P N Q ti
'm .°o o` 'm y 'm v E '0, s s c .-ta 5. 9
i e . c LL e Z. E e a = « 2 °
a 1- U U Z i VI ¢ I- I- I- i7 'v 'v
(CFUs
Sample Name Sample Date (SU) (mg/L) (mg/L) per 100 mL) (mg/L) (mg/L) (mg/L) (mg/L) (Hg/L) (Pg/L) (Pg/L) (Pg/L) (Pg/L) (Pg/L)
05/15/2002 --- 20.0 6.5 <1.1 5.2 <40 <0.10 NA NR NR NR NR NR NR
11/05/2002 --- 16.0 3.3 <1.1 1.3 68 1.4 NA <0.50 <0.50 <0.50 <0.50 <0.50 <0.50
05/13/2003 --- 9.7 3.6 2.2 1.8 44 0.72 NA NR NR NR NR NR NR
11/04/2003 --- 19.0 6.1 <1.1 0.7 <2.0 <0.10 NA <0.50 <0.50 <0.50 <0.50 <0.50 <0.50
05/05/2004 --- 3 7 <1.1 1.3 52 <0.10 NA NR NR NR NR NR NR
11/09/2004 --- 2.2 5.1 5.1 1.9 62 <0.10 NA <0.50 <0.50 <0.50 <0.50 <0.50 <0.50
05/17/2005 --- 3.2 6.1 <1.1 1.2 40 <0.10 NA NR NR NR NR NR NR
11/03/2005 --- 7.7 6.1 <1.1 1.0 58 0.1 NA <0.50 <0.50 <0.50 <0.50 <0.50 <0.50
05/24/2006 --- 8.4 5.5 <1.1 1.5 48 <0.10 NA NR NR NR NR NR NR
11/09/2006 --- 1.9 7.0 <1.1 1.1 38 <0.10 NA <0.50 <0.50 <0.50 <0.50 <1.0 <0.50
MW-7 05/18/2007 --- 3.6 8.6 <1.0 2.2 70 <0.10 NA <0.50 <0.50 <0.50 <0.50 <0.50 <0.50
11/13/2007 --- 4.2 6.8 <1.1 1.7 42 <0.10 NA <0.50 <0.50 <0.50 <0.50 <1.0 <0.50
05/27/2008 --- 7.6 11.5 <1.1 2.2 88 <0.10 NA NR NR NR NR NR NR
11/18/2008 --- 7.5 7.7 <1.1 1.7 30 <0.10 NA 0.79 <0.50 <0.50 <0.50 <0.5 <0.50
05/28/2009 --- 23.4 9.8 <4.0 2.3 336 <0.10 NA NR NR NR NR NR NR
11/05/2009 --- 5.3 10.7 2.0 2.3 70 <0.10 NA <0.50 <0.50 <0.50 <0.50 <1.0 <0.50
05/13/2010 --- 4.6 11.0 <2.0 2.5 71 <0.10 NA NR NR NR NR NR NR
11/08/2010 --- 15.4 8.9 <2.0 2.3 60 <0.10 NA <0.50 <0.50 <0.50 <0.50 <1.0 <0.50
05/17/2011 --- 6.0 11.6 <2.0 5.3 103 <0.10 NA NR NR NR NR NR NR
11/15/2011 --- 2.2 9.9 <2.0 3.5 89 <0.10 NA <0.50 <0.50 <0.50 <0.50 <1.0 <0.50
05/17/2012 --- 4.4 10.9 <2.0 3.8 67 <0.10 NA NR NR NR NR NR NR
Spring 2022 Groundwater Sampling Event Page 2 of 4
Clement Pappas,Hendersonville,North Carolina June 2022

Table 2
Current and Historical Groundwater Analytical Results
d N
2 = r =
a
c E
oo. c '°
I
vr r
to m o _ o
a e a r o P N
p ° v a C v E ry 2
co t
y. s .- *I' 9
x ' o o 'mLL y ' Zo ' E o s '2 a 'vo. 1- U U Z i n ¢ I- 7
13
(CFUs
Sample Name Sample Date (SU) (mg/L) (mg/L) per 100 mL) (mg/L) (mg/L) (mg/L) (mg/L) (Hg/L) (Pg/L) (Pg/L) (Pg/L) (Pg/L) (Pg/L)
11/07/2012 --- 11.6 13.1 <100 4.0 108 <0.10 NA <0.50 <0.50 <0.50 <0.50 <1.0 <0.50
05/16/2013 --- 12.8 17.1 <1.0 10.5 252 <0.10 NA NR NR NR NR NR NR
11/20/2013 --- 9.4 14.0 <1.0 5.5 <250 <0.10 NA <0.50 <0.50 <0.50 <0.50 <1.0 <0.50
05/22/2014 --- 8.9 13.1 <10,000 5.7 93 <0.10 NA NR NR NR NR NR NR
11/18/2014 --- 19.1 16.0 <20.0 7.1 93 <0.10 NA <0.50 <0.50 <0.50 <0.50 <1.0 <0.50
05/13/2015 --- 8.5 17.0 <2.0 9.3 125 <0.10 NA NR NR NR NR NR NR
11/04/2015 --- 9.9 18.0 <2.0 8.3 129 <0.10 0.350 <0.50 <0.50 <0.50 <0.50 <1.0 <0.50
05/04/2016 --- 13.5 27.7 <10.0 11.2 130 <0.10 0.780 NR NR NR NR NR NR
06/09/2016-Pace --- NA NA NA 10.9 NA NA NA NR NR NR NR NR NR
06/09/2016-Prism --- NA NA NA 10.0 NA NA NA NR NR NR NR NR NR
MW-7R 11/09/2016 --- 13.0 22.7 <20.0 12.5 147 <0.10 1.000 <0.50 <0.50 <0.50 <0.50 <1.0 <0.50
05/02/2017 --- 6.7 17.9 <4.0 8.9 169 <0.10 0.430 NR NR NR NR NR NR
11/08/2017 --- 3.9 17.9 19.0 36.8 376 <0.10 0.140 <0.50 <0.50 <0.50 <0.50 <1.0 <0.50
05/02/2018 5.41 3.2 22.6 <2.0 15.5 207 <0.10 0.320 NR
11/02/2018 5.48 5.3 20.2 <10.0 15.7 243 <0.10 0.170 <0.50 I <0.50 I <0.50 I <0.50 I <1.0 I <0.50
05/21/2019 5.58 3.0 29.0 <2.0 20.2 234 <0.050 0.130 NR
11/14/2019 6.42 3.0 22.7 <2.0 17.1 73 <0.10 0.084 <0.50 I <0.50 I <0.50 I <0.50 I <1.0 I <0.50
05/06/2020 5.20 1.2 20.9 <1.0 21.5 219 <0.10 <0.050 NR
11/06/2020 5.54 1.7 17.8 <1.0 13.0 205 <0.10 <0.050 <0.50 I <0.50 I <0.50 I <0.50 I <1.0 I <0.50
05/11/2021 5.2 1.7 34.2 <1.0 40.4 296 <0.10 0.051 NR
10/27/2021 5.3 1.1 24.9 <1.0 26.0 222 <0.10 <0.050 <0.50 I <0.50 I <0.50 I <0.50 I <1.0 I <0.50
05/10/2022 5.1 <1.0 30.8 <1.0 31.0 279 <0.10 <0.050 NR
05/02/2018 6.74 10.8 12.9 <2.0 14.4 548 <0.10 0.190 NR
11/02/2018 6.52 9.5 8.0 19.0 6.8 351 <0.10 0.250 <0.50 I <0.50 I <0.50 I <0.50 I <1.0 I <0.50
05/21/2019 6.89 7.9 7.3 <10.0 6.2 249 <0.050 0.290 NR
11/14/2019 6.71 7.7 7.2 2.0 1.2 51 <0.10 0.100 <0.50 I <0.50 I <0.50 I <0.50 I <1.0 I <0.50
MW-8 05/06/2020 6.41 2.7 2.8 <1.0 3.6 139 <0.10 <0.050 NR
11/06/2020 6.34 2.8 2.3 14.0 2.4 127 <0.10 <0.050 <0.50 I <0.50 I <0.50 I <0.50 I <1.0 I <0.50
05/11/2021 6.6 3.8 2.0 <1.0 1.7 114 <0.10 <0.050 NR
10/27/2021 6.6 4.7 3.5 1.0 0.86 189 <0.10 <0.050 <0.50 I <0.50 I <0.50 I <0.50 I <1.0 I <0.50
05/10/2022 6.7 4.5 7.4 <1.0 3.2 240 <0.10 <0.050 NR
Spring 2022 Groundwater Sampling Event Page 3 of 4
Clement Pappas,Hendersonville,North Carolina June 2022

Table 2
Current and Historical Groundwater Analytical Results
m m
2 =
a
c
'in c a la oD111
r r 2 2m ,u
a a r 2p ° v y Cv e '0 riry P 2
cs t C5.
x 'e o co 'mLL 'e ' EE e a s s' .E
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(CF Us
Sample Name Sample Date (SU) (mg/L) (mg/L) per 100 mL) (mg/L) (mg/L) (mg/L) (mg/L) (Hg/L) (Pg/L) (Pg/L) (Pg/L) (Pg/L) (Pg/L)
05/02/2018 5.52 4.6 4.9 <2.0 0.58 69 <0.10 0.370 NR
11/02/2018 5.11 8.4 5.8 <10.0 0.57 88 <0.10 0.470 <0.50 I <0.50 I <0.50 I <0.50 I <1.0 I <0.50
05/21/2019 5.64 7.2 4.6 <10.0 0.20 80 <0.050 0.230 NR
11/14/2019 5.57 6.1 5.4 <1.0 0.89 56 <0.10 0.076 <0.50 I <0.50 I <0.50 I <0.50 I <1.0 I <0.50
MW-9 05/06/2020 5.52 5.9 1.8 <1.0 <0.040 68.0 <0.10 0.099 NR
11/06/2020 4.93 4.5 1.4 16.0 0.043 88.0 <0.10 0.095 <0.50 I <0.50 I <0.50 I <0.50 I <1.0 I <0.50
05/11/2021 5.4 3.6 9.8 <2.0 1.9 <25.0 <0.10 0.089 NR
10/27/2021 5.4 3.8 3.2 1.0 0.35 48.0 <0.10 <0.050 <0.50 I <0.50 I <0.50 I <0.50 I <1.0 I <0.50
05/10/2022 5.4 3.6 6.3 <1.0 1.5 67.0 <0.10 0.086 NR
Notes:
2L standards are set in North Carolina Administrative Code,Title 15A Subchapter 2L-Groundwater Classifications and Standards,Department of Environmental Quality(Amended April 1,2013).Total organic carbon and nitrate standards are set in Wastewater
Irrigation System Permit Number WQ0004797.There is no defined 2L standard for fecal coliform;therefore,the standard listed is for"total coliform."
Bolded values indicate a concentration equal to or above the respective groundwater standard or outside the groundwater standard range.
Shaded cells are from the May 2022 sampling event
pH is analyzed by Anchor QEA of North Carolina,PLLC;NC lab certification number 5445.
Monitoring is performed in accordance with Permit No.WQ0004797 issued to Clement Pappas on May15,2020 and effective on September 1,2020.
<indicates that the constituent concentration was not detected above the method detection limit
pg/L:micrograms per liter
CFU:colitorm-forming unit
J:The concentration is above the adjusted method detection limit and below the adjusted reporting limit and is therefore considered an estimate.
mg/L:milligrams per liter
mL:milliliter
NL:No 2L standard exists.
NR:not reported
SU:standard unit
Spring 2022 Groundwater Sampling Event Page 4 of 4
Clement Pappas,Hendersonville,North Carolina June 2022

Table 3
Current and Historical Surface Water Analytical Results
2
-a m
.2 c ;a ate, _> v, o a
= o FP m s V - A '� o s
a , O U U ii laZ H G in i < I- a ,n
Sample Name Sample Date (SU) (mg/L) (mg/L) (CFUs per 100 mL) (mg/L) (mg/L) (mg/L) (mg/L)
2B Standard 6.0-9.0 NL 230 200 NL NL NL NL
5/2/2018 6.88 1.5 4.8 53.0 0.74 54.0 <0.10 0.044 J
11/2/2018 6.28 2.9 5.1 780 0.72 54.0 <0.10 0.077
5/21/2019 7.02 1.6 5.0 98.0 0.75 42.0 <0.050 0.067
SW-1 11/14/2019 6.76 1.9 5.3 118 0.83 57.0 <0.10 0.1
5/6/2020 7.20 1.6 4.6 290 0.76 49.0 <0.10 0.092
(Upstream) 11/6/2020 5.83 1.6 4.4 145 0.71 56.0 <0.10 <0.050
5/11/2021 6.8 1.3 5.3 191 0.80 48.0 <0.10 0.068
10/27/2021 7 1.8 5.2 145 0.72 52.0 <0.10 0.061
5/10/2022 7.1 1.4 5.1 81.0 0.88 51.0 0.12 0.15
5/2/2018 6.98 1.4 4.4 118.0 0.72 51.0 0.052 J 0.045 J
11/2/2018 7.08 2.9 4.6 940.0 0.75 53.0 0.099 J 0.076
5/21/2019 6.99 1.6 4.9 200.0 0.76 47.0 <0.050 0.068
SW-2 11/14/2019 7.01 1.9 5.4 127 0.82 83.0 <0.10 0.089
5/6/2020 6.67 1.7 4.2 420 0.72 53.0 <0.10 <0.050
(Downstream) 11/6/2020 6.19 1.6 4.4 97.0 0.70 59.0 <0.10 <0.050
5/11/2021 6.9 1.4 5.0 146 0.74 47.0 <0.10 0.061
10/27/2021 6.9 1.9 5.2 145 0.71 55.0 <0.10 0.063
5/10/2022 6.9 1.4 4.9 118 0.87 50.0 <0.10 0.16
Notes:
2B standard:surface water standard per North Carolina Administrative Code,Title 15A:Department of Environmental Quality,Subchapter 2B-Surface Water
and Wetland Standards(last amended in November 2019),or the standard obtained from the U.S.Environmental Protection Agency Nationally Recommended
Water Quality Criteria for Aauatic Life and Human Health.
Bolded values indicate a concentration equal to or above the respective 2B standard or a value outside the 2B standard range.
< indicates that the constituent concentration was not detected above the laboratory reporting limit
Monitoring is performed in accordance with Permit No.WQ0004797 issued to Clement Pappas on May 15,2020 and effective on September 1,2020.
CFU:coliform-forming unit
J:The concentration is above the adjusted method detection limit and below the adjusted reporting limit and is therefore considered an estimate.
mg/L:milligrams per liter
mL:milliliters
NL No NC 2B standard exists
SU:standard unit
Spring 2022 Groundwater Sampling Event Page 1 of 1
Clement Pappas, Hendersonville, North Carolina June 2022

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LEGEND: SOURCE(S):
Basemap: USGS Topographic Maps,Fruitland and Hendersonville 0 2,000
Site Location Quadrangles, 1997.
0 11
Parcel:Henderson County GIS 2016 Feet
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\ . ANCHOR Figure 1
()EA`.w, Site Location Map
Spring 2022 Groundwater Monitoring Report
Lassonde Pappas and Company,Inc.

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Daily Log
Anchor QEA of North Carolina,PLLC
.,„ . °� m.^ „... �. 231 Haywood Street
t. .,1m Asheville,NC 28801
Phone [phone]
PROJECT NAME: Lassonde Pappas Well Chlorination&Redevelopment DATE: V W 117
SITE ADDRESS: 485 Brookside Camp Road,Hendersonville,NC 28792 PERSONNEL: l y t SS(CV,
WEATHER: WIND FROM: � NE E SE S SW W NW ("A-106 ;T MEDI
'� HEAVY
"SuNN CLOUDY RAIN TEMPERATURE: r� 'x °c
Kirtie appropriate units]
TIME COMMENTS
.1 ) t 1 '1) A
u„P
ir ti,f1 t..Y . 'V\ ra. )r' p ...... ...
0 b 15 tr ow21 '1 C6'tt
tic Sneltct- ii,\
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( ,
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c), .. . ? 1° ,xw �.
Signature: �"�, ��1 h ,� � ' ,��' �
U

Daily Log
Anchor QEA of North Carolina,PLLC
P m 231 Haywood Street
i R
.. Asheville,NC 28801 1
Phone [phone]
Lassonde Pappas Well Chlorination&Redevelopment
,PROJECT NAME: DATE• ��.�� � �U� r �°,c�. (COCCO�'�tUIU..Qd
SITE ADDRESS: 485 Brookside CampRoad,Hendersonville,NC 28792 PERSONNEL: &i ,,i,°I
►� r�S
WEATHER: WIND FROM: N J. , ' E SE S 1 SW RW..1 NW LIGHT �` MEDIU'�' SO
SUNNY CLOUDY RAIN ? TEMPERAT(i `° 4;(F . °C
[" F appropriate units]
111 TIME COMMENTS
io 0 .k) o., Do °, W -- ,.: . . ' , - "' �, o t.m ,v i , 0 ... b +(.
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Signature: l ..,k, "'?LL( � '' , i

Daily Log
Anchor QEA of North Carolina,PLLC
"' .. "' R I
231 Haywood Street
:: .. ',:'
u Asheville,NC 28801
Phone [phone] 1
PROJECT NAME: Lassonde Pappas Well Chlorination&Redevelopment DATE: 6. ,::2 S I'),64)
Camp PERSONNEL: : '`v 8( ,�,�
[ L. _1 I
SITE ADDRESS: 485 Brookside Road,Hendersonville,NC 28792
WEATHER: WIND FROM N„��.,•,��� : � E SE S SW 1N�NW LIGH� " � MEDIUM" HEAVY
� UNNy) CLOUDY L. RAIN I ? EMPERATURE:f ' ) 5 i . °c
_^"" [Circle appropriate units]
TIME COMMENTS
r 1►6 ° '1C3i((ZCd C
'100 ov ft, vAei Pay -CPS-_ v ag, wave-4 tr.:, INV,,,► - 4 Y b I c,/,k)
T ,"fir( („, . t, �� yl �, t", ,,jf . t f � :� cc.. v i . `' LI5sec= " /s
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Signature: " I Y ,:)r ,11'1

Daily Log
o� m v � �
Anchor QEA f North Carolina, 1„I^C" III
���� et
'Co ermn,n.,qlfi Asllevillea NC 2'8 01.
Phone 828.281,3:a0
PROJECT NAME: Lassonde Pappas Well Chlorination&Redevelopment DATE:E 1-1 cA,5 1? t"d
SITE ADDRESS: 485 Brookside Camp Road,Hendersonville,NC 28792 PERSONNEL: 11:.1 r 11 . "e
WEATHER: WIND FROM:IrdellTaltillIMINEMIEZIEZillESSIMNIMAIIIMINTaw0111 HEAVY
Inditall CLOUDY I RAIN 7 i PERATURE: Vii �•
. [t.mr.e appropriate units]
COMMENTS
i(
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tail
p ,L ,.
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Signature: , w,, ,., w �1 + + " � 1

,
- — -
Daily Log
O
Anchor QEA of North Carolina,PLLC
ANCI 'I OR
231 Haywood Street
(,)11'A „,...„,,, Asheville,NC 28801
Phone [phone]
./
PROJECT NAME:Lassonde Pappas Well Redevelopment DATE: (i'i 4 2
SITE ADDRESS: 485 Brookside Camp Road,Hendersonville,NC 28792
PERSONNEL:
WEATHER: WIND FROM: N NE E 1 SE S,1, W i WLNW - LIGHT Lr MEDIU. HEAVY. 1
SUNNY CLOUDY ('IIIAII4 ( ? TEMPERATURE:L(6)(r:a IL
a ppropri).ateunits] C 1
TIME COMMENTS
, ,,
(i I L i " i
t t ci 0, tt4(it,It t 't itil.',It tt lit,,,, II, I I it t "1,t), I-t, i
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1
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1
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Signature:

'Nft AI1(,,:114 )R. Anchor QEA of North Carolina,PLLC
I'A 4.-46-‘-' 231 Haywood Street
,i- tA f etle-Al 1
‘,2 1,,,,,C. Asheville,North Carolina 28801
Edipment Documentation and Instrument Calibration Data Sheet(
Project Name: Lassonde Pappas ' Analyst Conducting Calibration: ,,',T ex„,i
mber. C21482-01.01 Task 7 Date of Calibration: WA11:
Project Nu
, ,
Project Location:, Hendersonville,NC_ Date of Field Measurements: 6
„„ ......
Facility ID or Permit#(if applicable): Permit No.WQ0004797
, —
EQUIPMENT DOCUMENTATION
Rental sample analysis equipment or meters used to take measurements:
Equipment Type Brand Serial Number Date of Use Rental Company._
.............--,-
77 —
,
Select Turbidimeter: Hach 21000(sin 151006045207) 19 Q. - C.( * 1 ° rev PC e d 1 V eCcLO ---ri
A j
HF Scientific MicroTPW(s/n 200601045)
7---"" Instrument Readings
Instrument Readings
(Hach 21000) _ (HF Scientific MicroTP1N)
Cal Std Information I 10 NTU , 20 NTU I 100 NTU 800 NTU 1,000 NTU 10.0 NTU VA&NTU
Lot#:, ,: 77,V i ,.r;,,,,7): '," I 2,C''142, '';i'''?' (,./
..j
Expiration Date: A i ,. '.7, '‘) ,, '4'., ,", I.----4,
--"n"""''''''''
Cal(NTU): Cal(NTUI:en Cal(NT ): ,..,n Cal(NTU):
Cal,„(NTU4 .t _,,,,,e Cal(NTU); ,,
t .-1 . • 7—— !:.
---,
Time:01.3(1—Time:,,,,_i_5 4,,I, Time: Time: ,,, Time:
.,' 4 .
[-) I -.- f,t 1 ,t 1 1 '1 '''',,AL:'t
Calibration'Pre-Analysis Result(NTU: rdi)5 .f*6,d: .
. , 01 31-1- *Pee-Analysis Re, (NTU)1 '''-"rimer!'
• t
Verification:Check(10 NTU): Check(7,4149.7),)4,
...6..... 1.°
*Pos-t-Analysis Result(NTU): 1Time: ,,**0.0-At , si; Ftsoft otfr,u), f„ i fkime:,
.. ,,,c...10,0410iNito: ..,, , 4,,4 -.1.-,4,
Check CIO NTU): ,
— , —
_
YSI Professional Plus Multiparameter Meter(s/n newistm
, t ,
.„... 4 , ,, , .7, s 7 Coistd miorrition' 7 I
Instrument Readings 1 greei
Lot# 1,,,77, „„ Exp.Date
s ,,0.execi„,t
Dissolved Oxygen Initial(%): Cal(%): mmHg: „.Jv,, ,, ,
Temperature CC): Time:
(%saturation)
DO(Site#2, Initial(%): Cal(%): mmHg: Temperature(°C): Time: ,.„... 1
if applicable)* a i
_ _ .........nnmmt=.
,
QC**Check:DO Time: Result(%): Time: Result(%): Time: ,RdSult(%):
..........— .7.7....
pH 7 S.U. Initial: pHmV: Cal(S.U.): pHmV: I
report to O./S.U. Time;,.
pH 4 S.U. Initial: pHmV: Cal(S.U.): pHmV: „..,' Time:
report to 0.7 S.U.
— , —
pH 10 S.U. Initial: pHmV: Cal(S.U.): „„4,44mV: Time: ,
report to 0.1 S.U. —. .....___
QC**pH 7 S.U. Time: I Result(S.U.): Timer'
.., Result(S.U.): Time: Result(S.U.):
.„„.,
report to 0.1 S.U.
Spec.Cond. Initial: Cal(pmhosicK: Time:
1,000 umhos/cm,.., I
— —.
%Recovery= ,77'''''''
.........--07—.... -7,777- ............4......„ ' ........ '
QC**Spec.Cond. Result(p m hos/cm): Time: Result(pmhos/cm): Time: Result(pm hos/cm):
1,000 pmhos/4017
, .....7 Initial: Cat: lheumperstiort
PP 200 mV
nalyst Signature: 1:kc ,' Ilk ), I 1 I,
71 I t ,
Analyst Name: „7,, ( '„ , 7,- ,,:7„7, ,,7 i ii Date: I,,,X-41777"
Notes: ii"i 9 '9 Cie i iiise ei.)is
Revision Ri 12/20/20,MAK
1 Onatrenents that be calibrated in accordance elan tile rnenoitat rarer%operation creutual.
2.Specific Cronductivity should be tallbratee accariting tri values If eprmprotadve&rested:kr range
la ID ei:et CAfilichatior is as follows i Siwal tic Condieteity,pli 7,.pal 4„1 10,INS,.ORP,QC citaelcs.
4'When pal-Forming DS)analyses at multiple sampin saws De.project Mel lily I octane*,dm DCa probe rnust be cat:mated al:co&sample It'prior Ica analysis,
5,OE Aar aplable Ranges:ph i a i Oil SAL aria Specific CondurlivIty 10%of the trap value Of BIC MaiiIIIIS Ale out ot raiar the Evendale%needs to bp i adelthr abet
DS check must be:perforned prier lac sampling and Mowing cAmplation sampling,at as minimum.QC droves must Irv?!performed with cat bream standeid from a separate Pt 8 as:Die iniatal 012.
7%Recovery s wake Obtained,itiniesium 7 True Value,binchosicma.8 100
8..INC;.Flea Laboratory Certificate Number 5445
9.borkinental ion errors ara to he crossed out with a single tries so die ariginal text is still legit:Qs frollantina by tie staff members initials and Mae
18 LIHf,55,othesubse noted,ail DO calibrations and Merasurementi are per feigned et Cli opt.Salinity.
1.1.'I pehoferri P 11 aSicril
Abbreviations: Method Reference:
itinhectErni milatorohns por cerI6 meter lb he naphakinnatic erect ly ianda temperature:SM 2550 B-2010
clettnes DolciiI 01214.oxidation recii,Ktion IPoteniial Eportric conductivity:EPA Merhoil 120.A Reit"1984
100i eisselbed oxygen sin,serial number DO,SIVI 4500 0 Gi 2011
lingallt HI ligrarns per liter Sea crandare tints WM SIM 4500r i Iiii B-20 I 1
ried.lie ivolt Spec.Comic Speen,Koulauctelliw Avolairtiv BM 2129 la 2011
Page 1 of 1

','C ''l 1/11, Anchor QEA of North Carolina,PLLC
• a - ' 231 Haywood Street
Asheville,North Carolina 28801
Equipment Documentation and InstrMnent Calibration Data Sheet
Project Name: Lassonde Pappas Sp4mtrie27170-M6"fiTonng Analyst Conducting Calibration: ikk CNC 111:ki Ami,—
Project Number C21482-01.01 Task 7 Date of Calibration:
Project Location: Hendersonville,WC--- Date of Field Measurements:
Facility ID or Permit#(if applicable): Permit No.WQ0004797
, .„.......
EQUIPMENT DOCUMENTATION
Rental sample analysis equipment or meters used to take measurements:
Equipment Type , Brand Serial Number Date of Use .,,. Rental Company e
Select Turbidimeter: )(.. . Hach 21000(s/n 151006045207)
HF Scientific MicroTPW(s/n 200601045)
Instrument Readings Instrument Readings
(Hach 2100Q) (HF Scientific MicroTPW) ..,"
Cal Std InfomutIon 10 NTU 1 20 NTU , 100 NM 800 NTU 1,000 NTU 10.0 NTU 0.02
......____—.
Lot it: ,:'''1i,..?1 ,1 r! i'l , '52.1 ' i,,,L i,44 L,4c4'4. lit 7i ...
a ration Date' I
Cal(NT Cal 1 1I!,..
Cal(WT ./ Cal(NTU): Cal(NTU): ItrialtNTU):
, c
i
Time: , . R i., Timi.. . . Time: 1 C, ,,, Time:':141 i k p I Time:
L 442 4,4), 44,4" Time:
Calibration*Pre-Analysis Result(NTL..): , Time: ,), ' tPre-Analysis RettillANTU): Time:
Verification:.Check(10 MU): q ' '1)". 1 1 4": t) 'Check(10 NTU..,,
..Post-Analysis Result(NTU): 'Time: .Post-Ane)yils Result(NTU): Time:
Othoislel(10 NTU):
...s
YSI Professional Plus Muitiparameter Meter(tin 160101 ODD) 4
Cal Std infonnatiosve 1
Instrument Readings I Dato,'
Lot# 'i Exp.
Date
4rrened
Dissolved Oxygen Initial(%): Cal(%): mmHg: .
Temperature CC): Time:
(%saturation)
DO(Site 1/2, Initial(%): Cal(%): mmHg: Temperature('C): Time:
t , if applIketrolle)"
,Time: Reitullt CRS Timer l Result.(%): "time: rah' ''Rase 11)(%)::
ilSC%Check DO
ad,
pH 7 SAL initial: peltrif: Cal(SO4: tal,mte:
dr
ll
report ha a 1 S Lk
OD 4 S,U., Initial: pillwV: Cal(Sit.): pinhole me: E Ti
'
report to 0(%U.. I I
pH 10 S.U. Initial: pillimen Call(DU.idtm p1 rtiV: Time:
report w a 1 s.u
-----,-4;;-- ,
QC° I)?p NC Tithe: I Res tat(S.U„):: pi'lime Resellt(DUD Time Result Ill,,U.):
an'
terror.re 0.1 DU. .
Spec,Cond. l White Cal(utottortiern ins): Ion:, .
1„000 triminittrow, l l
. l 1
%Disavaveirwr
ClCci Spec.Canal 'Pine),',dt Result(vm husicand Time: ReSIU It Dim hosium): Time 'Result(nathowthnin
ut
1,000 polio:tapir(
1 II I I
%Reseal%te 1. ,
et initial: Call:: Temperature CC): Time:
ORD,,Lra,_mV
Analyst Signature \
Analyst Namet \, ( iit,, EriDiainf 1 VII 1 Date:
. —
litotes,
Rat'at O l 2/20/20,Mill
'L llost Ailments shab be n%leated d encontaida with the nn amens:tures operation Marta.
ii.Specific Conductivity should be erdibrated according to gaVUet reptesentatthe of historic vAnge,
3.Order of Calibration lib as faltar,Specilk Conductivity,pH 7,pH 4,pH it,DO,oai:QC:checks,
4,*Mon performing DO amlybes at ryttAtbple rant pit sites PA pro :t/Maty locations),the.DO probe burst,lAr calibrated at each'art pa site prior to analyes.
8 QC Acceptable Ranges:pH if DI 511.and Specific ConduArbolitylrthb tibia tale bathe.If QC readings are orb of range,the instrument needs to be reogbrated.
9,*"CC check riot be pargorrned prior to sampVing and folllowthig orprpOthr on of saunglirg,at,ingnimUM.CC checks most be performed gthh bebbrabon standard from a sepothke Ilat ate'the VOW 6.10
7.%Pecopery 9 Nall.Obtained,gmhosibm 9 True Value,prtgmbkng b 100
R.NC Debil laboratoug Certificate lb rroher 5445
9.Documentabon errors are tabs crossed eat with a Onoia ID.so.the origihnal text iisstdOlegibbb let tom.by the staff rnemberp inbials and date
la Unless otherwise naked,Al DO agilbrations and densurettionts are performed at 0 ppt Salinity.
111.1 prnhohom 9 1 1.6/thr,
Akthregrandonsr Method Ebefermbeb
11,1,Am/cm mithrothhos per centimeter NID:Inephelametric turbidity units Temberatunth SM bASO 02010
'Cr&pees....us ORA bAdation lreducti.potential Specilk conductivity:EPA Method 120.1,Reth 1982
1E70 dissobred oxygen sin:aerirg number IDO:CM 4800 0 G.2011
ur bit ImAigrarns per ken 01 standard units pH,SM 4500-W 8-2011
hththafilllicolt Spec.Cond.:Specthic ConductbAty TurAtdity:CM 2130 0...2011
Page 1 of 1

ttac - nt2
La • oratory nalytical - sorts an .
ain-of- usto • y For s

Pace Analytical Services,LLC
aceAnal tical 2225 Riverside Dr.
Jq/'� Asheville,NC 28804
www.pacallabs.caim [phone]
May 16, 2022
Jennifer Verde
Anchor QEA
231 Haywood Street
Asheville, NC 28801
RE: Project: Lassonde Pappas WQ 5/10
Pace Project No.: 92603755
Dear Jennifer Verde:
Enclosed are the analytical results for sample(s)received by the laboratory on May 10,2022. The results relate only to the
samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual,where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace Analytical Services-Asheville
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Lorri Patton
[e-mail]
1(828)254-7176
Project Manager
Enclosures
REPORT OF LABORATORY ANALYSIS
�° This report shall not be reproduced,except in full,
without the written consent of Pace Analytical Services,LLC. Page 1 of 27

Pace Analytical Services,LLC
aceAnal tical 2225 Riverside Dr.
Jq/' Asheville,NC 28804
www.pacallabs.caim [phone]
CERTIFICATIONS
Project: Lassonde Pappas WQ 5/10
Pace Project No.: 92603755
Pace Analytical Services Asheville
2225 Riverside Drive,Asheville, NC 28804 South Carolina Laboratory ID:99030
Florida/NELAP Certification#: E87648 South Carolina Certification#: 99030001
North Carolina Drinking Water Certification#: 37712 Virginia/VELAP Certification#:460222
North Carolina Wastewater Certification#:40
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
without the written consent of Pace Analytical Services,LLC. Page 2 of 27

Pace Analytical Services,LLC
aceAnalytical 2225 Riverside Dr.
Jq/� Asheville,NC 28804
www.pacallabs.caim [phone]
SAMPLE ANALYTE COUNT
Project: Lassonde Pappas WQ 5/10
Pace Project No.: 92603755
Analytes
Lab ID Sample ID Method Analysts Reported Laboratory
92603755001 MW-4-20220510 SM 2540C-2015 MAB2 1 PASI-A
SM 9222D-2015 YEG 1 PASI-A
EPA 350.1 Rev 2.0 1993 NDS 1 PASI-A
EPA 353.2 Rev 2.0 1993 MFO 1 PASI-A
EPA 365.1 Rev 2.0 1993 SMT 1 PASI-A
SM 4500-CI-E-2011 MDW 1 PASI-A
SM 5310B-2014 MJP 1 PASI-A
92603755002 MW-5-20220510 SM 2540C-2015 MAB2 1 PASI-A
SM 9222D-2015 YEG 1 PASI-A
EPA 350.1 Rev 2.0 1993 NDS 1 PASI-A
EPA 353.2 Rev 2.0 1993 MFO 1 PASI-A
EPA 365.1 Rev 2.0 1993 SMT 1 PASI-A
SM 4500-CI-E-2011 MDW 1 PASI-A
SM 5310B-2014 MJP 1 PASI-A
92603755003 MW-6-20220510 SM 2540C-2015 MAB2 1 PASI-A
SM 9222D-2015 YEG 1 PASI-A
EPA 350.1 Rev 2.0 1993 NDS 1 PASI-A
EPA 353.2 Rev 2.0 1993 MFO 1 PASI-A
EPA 365.1 Rev 2.0 1993 SMT 1 PASI-A
SM 4500-CI-E-2011 MDW 1 PASI-A
SM 5310B-2014 MJP 1 PASI-A
92603755004 MW-7R-20220510 SM 2540C-2015 MAB2 1 PASI-A
SM 9222D-2015 YEG 1 PASI-A
EPA 350.1 Rev 2.0 1993 NDS 1 PASI-A
EPA 353.2 Rev 2.0 1993 MFO 1 PASI-A
EPA 365.1 Rev 2.0 1993 SMT 1 PASI-A
SM 4500-CI-E-2011 MDW 1 PASI-A
SM 5310B-2014 MJP 1 PASI-A
92603755005 MW-8-20220510 SM 2540C-2015 MAB2 1 PASI-A
SM 9222D-2015 YEG 1 PASI-A
EPA 350.1 Rev 2.0 1993 NDS 1 PASI-A
EPA 353.2 Rev 2.0 1993 MFO 1 PASI-A
EPA 365.1 Rev 2.0 1993 SMT 1 PASI-A
SM 4500-CI-E-2011 MDW 1 PASI-A
SM 5310B-2014 MJP 1 PASI-A
92603755006 MW-9-20220510 SM 2540C-2015 MAB2 1 PASI-A
SM 9222D-2015 YEG 1 PASI-A
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
without the written consent of Pace Analytical Services,LLC. Page 3 of 27

Pace Analytical Services,LLC
aceAnalytical 2225 Riverside Dr.
Jq/'� Asheville,NC 28804
www.pacallabs.caim [phone]
SAMPLE ANALYTE COUNT
Project: Lassonde Pappas WQ 5/10
Pace Project No.: 92603755
Analytes
Lab ID Sample ID Method Analysts Reported Laboratory
EPA 350.1 Rev 2.0 1993 NDS 1 PASI-A
EPA 353.2 Rev 2.0 1993 MFO 1 PASI-A
EPA 365.1 Rev 2.0 1993 SMT 1 PASI-A
SM 4500-CI-E-2011 MDW 1 PASI-A
SM 5310B-2014 MJP 1 PASI-A
92603755007 SW-1-20220510 SM 2540C-2015 MAB2 1 PASI-A
SM 9222D-2015 YEG 1 PASI-A
EPA 350.1 Rev 2.0 1993 NDS 1 PASI-A
EPA 353.2 Rev 2.0 1993 MFO 1 PASI-A
EPA 365.1 Rev 2.0 1993 SMT 1 PASI-A
SM 4500-CI-E-2011 MDW 1 PASI-A
SM 5310B-2014 MJP 1 PASI-A
92603755008 SW-2-20220510 SM 2540C-2015 MAB2 1 PASI-A
SM 9222D-2015 YEG 1 PASI-A
EPA 350.1 Rev 2.0 1993 NDS 1 PASI-A
EPA 353.2 Rev 2.0 1993 MFO 1 PASI-A
EPA 365.1 Rev 2.0 1993 SMT 1 PASI-A
SM 4500-CI-E-2011 MDW 1 PASI-A
SM 5310B-2014 MJP 1 PASI-A
PASI-A= Pace Analytical Services-Asheville
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
without the written consent of Pace Analytical Services,LLC. Page 4 of 27

Pace Analytical Services,LLC
aceAnal tical 2225 Riverside Dr.
Jq/'� Asheville,NC 28804
www.pacallabs.com [phone]
ANALYTICAL RESULTS
Project: Lassonde Pappas WQ 5/10
Pace Project No.: 92603755
Sample: MW-4-20220510 Lab ID: 92603755001 Collected: 05/10/22 12:49 Received: 05/10/22 14:56 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
2540C Total Dissolved Solids Analytical Method: SM 2540C-2015
Pace Analytical Services-Asheville
Total Dissolved Solids 136 mg/L 25.0 1 05/13/22 09:26
MBIO 9222D Fecal Coliform AVL Analytical Method: SM 9222D-2015 Preparation Method:SM 9222D-2015
Pace Analytical Services-Asheville
Fecal Coliforms ND CFU/100 mL 1.0 1 05/10/22 16:10 05/11/22 14:22
350.1 Ammonia Analytical Method: EPA 350.1 Rev 2.0 1993
Pace Analytical Services-Asheville
Nitrogen,Ammonia ND mg/L 0.10 1 05/12/22 11:45 7664-41-7
353.2 Nitrogen,NO2/NO3 unpres Analytical Method: EPA 353.2 Rev 2.0 1993
Pace Analytical Services-Asheville
Nitrogen, Nitrate 0.46 mg/L 0.040 1 05/11/22 03:09 14797-55-8
365.1 Phosphorus,Total Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation Method: EPA 365.1 Rev 2.0 1993
Pace Analytical Services-Asheville
Phosphorus 0.063 mg/L 0.050 1 05/12/22 17:53 05/12/22 21:12 7723-14-0
4500 Chloride Analytical Method: SM 4500-CI-E-2011
Pace Analytical Services-Asheville
Chloride 6.8 mg/L 1.0 1 05/12/22 14:33 16887-00-6
5310E TOC Analytical Method: SM 5310B-2014
Pace Analytical Services-Asheville
Total Organic Carbon 2.9 mg/L 1.0 1 05/13/22 13:03 7440-44-0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date: 05/16/2022 02:14 PM without the written consent of Pace Analytical Services,LLC. Page 5 of 27

Pace Analytical Services,LLC
aceAnal tical 2225 Riverside Dr.
Jq/'� Asheville,NC 28804
www.pacallabs.com [phone]
ANALYTICAL RESULTS
Project: Lassonde Pappas WQ 5/10
Pace Project No.: 92603755
Sample: MW-5-20220510 Lab ID: 92603755002 Collected: 05/10/22 13:35 Received: 05/10/22 14:56 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
2540C Total Dissolved Solids Analytical Method: SM 2540C-2015
Pace Analytical Services-Asheville
Total Dissolved Solids 158 mg/L 25.0 1 05/13/22 09:26
MBIO 9222D Fecal Coliform AVL Analytical Method: SM 9222D-2015 Preparation Method:SM 9222D-2015
Pace Analytical Services-Asheville
Fecal Coliforms ND CFU/100 mL 1.0 1 05/10/22 16:10 05/11/22 14:22
350.1 Ammonia Analytical Method: EPA 350.1 Rev 2.0 1993
Pace Analytical Services-Asheville
Nitrogen,Ammonia ND mg/L 0.10 1 05/12/22 11:48 7664-41-7
353.2 Nitrogen,NO2/NO3 unpres Analytical Method: EPA 353.2 Rev 2.0 1993
Pace Analytical Services-Asheville
Nitrogen, Nitrate 0.10 mg/L 0.040 1 05/11/22 03:12 14797-55-8
365.1 Phosphorus,Total Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation Method: EPA 365.1 Rev 2.0 1993
Pace Analytical Services-Asheville
Phosphorus ND mg/L 0.050 1 05/12/22 17:53 05/12/22 21:13 7723-14-0
4500 Chloride Analytical Method: SM 4500-CI-E-2011
Pace Analytical Services-Asheville
Chloride 49.0 mg/L 2.0 2 05/12/22 14:58 16887-00-6
5310E TOC Analytical Method: SM 5310B-2014
Pace Analytical Services-Asheville
Total Organic Carbon 2.7 mg/L 1.0 1 05/13/22 13:57 7440-44-0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date: 05/16/2022 02:14 PM without the written consent of Pace Analytical Services,LLC. Page 6 of 27

Pace Analytical Services,LLC
aceAnal tical 2225 Riverside Dr.
Jq/'� Asheville,NC 28804
www.pacallabs.caim [phone]
ANALYTICAL RESULTS
Project: Lassonde Pappas WQ 5/10
Pace Project No.: 92603755
Sample: MW-6-20220510 Lab ID: 92603755003 Collected: 05/10/22 11:40 Received: 05/10/22 14:56 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
2540C Total Dissolved Solids Analytical Method: SM 2540C-2015
Pace Analytical Services-Asheville
Total Dissolved Solids 96.0 mg/L 25.0 1 05/13/22 09:26
MBIO 9222D Fecal Coliform AVL Analytical Method: SM 9222D-2015 Preparation Method:SM 9222D-2015
Pace Analytical Services-Asheville
Fecal Coliforms ND CFU/100 mL 1.0 1 05/10/22 16:10 05/11/22 14:22
350.1 Ammonia Analytical Method: EPA 350.1 Rev 2.0 1993
Pace Analytical Services-Asheville
Nitrogen,Ammonia ND mg/L 0.10 1 05/12/22 11:49 7664-41-7
353.2 Nitrogen,NO2/NO3 unpres Analytical Method: EPA 353.2 Rev 2.0 1993
Pace Analytical Services-Asheville
Nitrogen, Nitrate ND mg/L 0.040 1 05/11/22 03:07 14797-55-8
365.1 Phosphorus,Total Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation Method: EPA 365.1 Rev 2.0 1993
Pace Analytical Services-Asheville
Phosphorus ND mg/L 0.050 1 05/12/22 17:53 05/12/22 21:22 7723-14-0
4500 Chloride Analytical Method: SM 4500-CI-E-2011
Pace Analytical Services-Asheville
Chloride 13.6 mg/L 1.0 1 05/12/22 14:35 16887-00-6
5310E TOC Analytical Method: SM 5310B-2014
Pace Analytical Services-Asheville
Total Organic Carbon 1.5 mg/L 1.0 1 05/13/22 14:19 7440-44-0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date: 05/16/2022 02:14 PM without the written consent of Pace Analytical Services,LLC. Page 7 of 27

Pace Analytical Services,LLC
aceAnal tical 2225 Riverside Dr.
Jq/'� Asheville,NC 28804
www.pacallabs.com [phone]
ANALYTICAL RESULTS
Project: Lassonde Pappas WQ 5/10
Pace Project No.: 92603755
Sample: MW-7R-20220510 Lab ID: 92603755004 Collected: 05/10/22 09:34 Received: 05/10/22 14:56 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
2540C Total Dissolved Solids Analytical Method: SM 2540C-2015
Pace Analytical Services-Asheville
Total Dissolved Solids 279 mg/L 25.0 1 05/13/22 09:26
MBIO 9222D Fecal Coliform AVL Analytical Method: SM 9222D-2015 Preparation Method:SM 9222D-2015
Pace Analytical Services-Asheville
Fecal Coliforms ND CFU/100 mL 1.0 1 05/10/22 15:44 05/11/22 14:22
350.1 Ammonia Analytical Method: EPA 350.1 Rev 2.0 1993
Pace Analytical Services-Asheville
Nitrogen,Ammonia ND mg/L 0.10 1 05/12/22 11:50 7664-41-7
353.2 Nitrogen,NO2/NO3 unpres Analytical Method: EPA 353.2 Rev 2.0 1993
Pace Analytical Services-Asheville
Nitrogen, Nitrate 31.0 mg/L 0.40 10 05/11/22 03:20 14797-55-8
365.1 Phosphorus,Total Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation Method: EPA 365.1 Rev 2.0 1993
Pace Analytical Services-Asheville
Phosphorus ND mg/L 0.050 1 05/12/22 17:53 05/12/22 21:25 7723-14-0
4500 Chloride Analytical Method: SM 4500-CI-E-2011
Pace Analytical Services-Asheville
Chloride 30.8 mg/L 1.0 1 05/12/22 14:36 16887-00-6
5310E TOC Analytical Method: SM 5310B-2014
Pace Analytical Services-Asheville
Total Organic Carbon ND mg/L 1.0 1 05/13/22 14:37 7440-44-0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date: 05/16/2022 02:14 PM without the written consent of Pace Analytical Services,LLC. Page 8 of 27

Pace Analytical Services,LLC
aceAnal tical 2225 Riverside Dr.
Jq/'� Asheville,NC 28804
www.pacallabs.com [phone]
ANALYTICAL RESULTS
Project: Lassonde Pappas WQ 5/10
Pace Project No.: 92603755
Sample: MW-8-20220510 Lab ID: 92603755005 Collected: 05/10/22 08:09 Received: 05/10/22 14:56 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
2540C Total Dissolved Solids Analytical Method: SM 2540C-2015
Pace Analytical Services-Asheville
Total Dissolved Solids 240 mg/L 25.0 1 05/13/22 09:26
MBIO 9222D Fecal Coliform AVL Analytical Method: SM 9222D-2015 Preparation Method:SM 9222D-2015
Pace Analytical Services-Asheville
Fecal Coliforms ND CFU/100 mL 1.0 1 05/10/22 15:44 05/11/22 14:22
350.1 Ammonia Analytical Method: EPA 350.1 Rev 2.0 1993
Pace Analytical Services-Asheville
Nitrogen,Ammonia ND mg/L 0.10 1 05/12/22 11:52 7664-41-7
353.2 Nitrogen,NO2/NO3 unpres Analytical Method: EPA 353.2 Rev 2.0 1993
Pace Analytical Services-Asheville
Nitrogen, Nitrate 3.2 mg/L 0.040 1 05/11/22 02:56 14797-55-8
365.1 Phosphorus,Total Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation Method: EPA 365.1 Rev 2.0 1993
Pace Analytical Services-Asheville
Phosphorus ND mg/L 0.050 1 05/12/22 17:53 05/12/22 21:28 7723-14-0
4500 Chloride Analytical Method: SM 4500-CI-E-2011
Pace Analytical Services-Asheville
Chloride 7.4 mg/L 1.0 1 05/12/22 14:36 16887-00-6
5310E TOC Analytical Method: SM 5310B-2014
Pace Analytical Services-Asheville
Total Organic Carbon 4.5 mg/L 1.0 1 05/13/22 14:57 7440-44-0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date: 05/16/2022 02:14 PM without the written consent of Pace Analytical Services,LLC. Page 9 of 27

Pace Analytical Services,LLC
aceAnal tical 2225 Riverside Dr.
Jq/'� Asheville,NC 28804
www.pacallabs.com [phone]
ANALYTICAL RESULTS
Project: Lassonde Pappas WQ 5/10
Pace Project No.: 92603755
Sample: MW-9-20220510 Lab ID: 92603755006 Collected: 05/10/22 10:29 Received: 05/10/22 14:56 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
2540C Total Dissolved Solids Analytical Method: SM 2540C-2015
Pace Analytical Services-Asheville
Total Dissolved Solids 67.0 mg/L 25.0 1 05/13/22 09:26
MBIO 9222D Fecal Coliform AVL Analytical Method: SM 9222D-2015 Preparation Method:SM 9222D-2015
Pace Analytical Services-Asheville
Fecal Coliforms ND CFU/100 mL 1.0 1 05/10/22 15:44 05/11/22 14:22
350.1 Ammonia Analytical Method: EPA 350.1 Rev 2.0 1993
Pace Analytical Services-Asheville
Nitrogen,Ammonia ND mg/L 0.10 1 05/12/22 12:21 7664-41-7
353.2 Nitrogen,NO2/NO3 unpres Analytical Method: EPA 353.2 Rev 2.0 1993
Pace Analytical Services-Asheville
Nitrogen, Nitrate 1.5 mg/L 0.040 1 05/11/22 03:05 14797-55-8
365.1 Phosphorus,Total Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation Method: EPA 365.1 Rev 2.0 1993
Pace Analytical Services-Asheville
Phosphorus 0.086 mg/L 0.050 1 05/12/22 17:53 05/12/22 21:28 7723-14-0
4500 Chloride Analytical Method: SM 4500-CI-E-2011
Pace Analytical Services-Asheville
Chloride 6.3 mg/L 1.0 1 05/12/22 14:37 16887-00-6
5310E TOC Analytical Method: SM 5310B-2014
Pace Analytical Services-Asheville
Total Organic Carbon 3.6 mg/L 1.0 1 05/13/22 15:54 7440-44-0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date: 05/16/2022 02:14 PM without the written consent of Pace Analytical Services,LLC. Page 10 of 27

Pace Analytical Services,LLC
aceAnal tical 2225 Riverside Dr.
Jq/'� Asheville,NC 28804
www.pacallabs.com [phone]
ANALYTICAL RESULTS
Project: Lassonde Pappas WQ 5/10
Pace Project No.: 92603755
Sample: SW-1-20220510 Lab ID: 92603755007 Collected: 05/10/22 14:05 Received: 05/10/22 14:56 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
2540C Total Dissolved Solids Analytical Method: SM 2540C-2015
Pace Analytical Services-Asheville
Total Dissolved Solids 51.0 mg/L 25.0 1 05/13/22 09:26
MBIO 9222D Fecal Coliform AVL Analytical Method: SM 9222D-2015 Preparation Method:SM 9222D-2015
Pace Analytical Services-Asheville
Fecal Coliforms 81.0 CFU/100 mL 1.0 1 05/10/22 16:10 05/11/22 14:22
350.1 Ammonia Analytical Method: EPA 350.1 Rev 2.0 1993
Pace Analytical Services-Asheville
Nitrogen,Ammonia 0.12 mg/L 0.10 1 05/12/22 12:27 7664-41-7
353.2 Nitrogen,NO2/NO3 unpres Analytical Method: EPA 353.2 Rev 2.0 1993
Pace Analytical Services-Asheville
Nitrogen, Nitrate 0.88 mg/L 0.040 1 05/11/22 03:16 14797-55-8
365.1 Phosphorus,Total Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation Method: EPA 365.1 Rev 2.0 1993
Pace Analytical Services-Asheville
Phosphorus 0.15 mg/L 0.050 1 05/12/22 17:53 05/12/22 21:29 7723-14-0
4500 Chloride Analytical Method: SM 4500-CI-E-2011
Pace Analytical Services-Asheville
Chloride 5.1 mg/L 1.0 1 05/12/22 14:38 16887-00-6
5310E TOC Analytical Method: SM 5310B-2014
Pace Analytical Services-Asheville
Total Organic Carbon 1.4 mg/L 1.0 1 05/13/22 16:11 7440-44-0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date: 05/16/2022 02:14 PM without the written consent of Pace Analytical Services,LLC. Page 11 of 27

Pace Analytical Services,LLC
aceAnal tical 2225 Riverside Dr.
Jq/'� Asheville,NC 28804
www.pacallabs.com [phone]
ANALYTICAL RESULTS
Project: Lassonde Pappas WQ 5/10
Pace Project No.: 92603755
Sample: SW-2-20220510 Lab ID: 92603755008 Collected: 05/10/22 08:40 Received: 05/10/22 14:56 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
2540C Total Dissolved Solids Analytical Method: SM 2540C-2015
Pace Analytical Services-Asheville
Total Dissolved Solids 50.0 mg/L 25.0 1 05/13/22 09:27
MBIO 9222D Fecal Coliform AVL Analytical Method: SM 9222D-2015 Preparation Method:SM 9222D-2015
Pace Analytical Services-Asheville
Fecal Coliforms 118 CFU/100 mL 1.0 1 05/10/22 15:44 05/11/22 14:22
350.1 Ammonia Analytical Method: EPA 350.1 Rev 2.0 1993
Pace Analytical Services-Asheville
Nitrogen,Ammonia ND mg/L 0.10 1 05/12/22 12:28 7664-41-7
353.2 Nitrogen,NO2/NO3 unpres Analytical Method: EPA 353.2 Rev 2.0 1993
Pace Analytical Services-Asheville
Nitrogen, Nitrate 0.87 mg/L 0.040 1 05/11/22 02:59 14797-55-8
365.1 Phosphorus,Total Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation Method: EPA 365.1 Rev 2.0 1993
Pace Analytical Services-Asheville
Phosphorus 0.16 mg/L 0.050 1 05/12/22 17:53 05/12/22 21:30 7723-14-0
4500 Chloride Analytical Method: SM 4500-CI-E-2011
Pace Analytical Services-Asheville
Chloride 4.9 mg/L 1.0 1 05/12/22 14:39 16887-00-6
5310E TOC Analytical Method: SM 5310B-2014
Pace Analytical Services-Asheville
Total Organic Carbon 1.4 mg/L 1.0 1 05/13/22 16:29 7440-44-0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date: 05/16/2022 02:14 PM without the written consent of Pace Analytical Services,LLC. Page 12 of 27

Pace Analytical Services,LLC
aceAnalytical 2225 Riverside Dr.
Jq/'� Asheville,NC 28804
www.pacellabs.caim [phone]
QUALITY CONTROL DATA
Project: Lassonde Pappas WQ 5/10
Pace Project No.: 92603755
QC Batch: 697955 Analysis Method: SM 2540C-2015
QC Batch Method: SM 2540C-2015 Analysis Description: 2540C Total Dissolved Solids
Laboratory: Pace Analytical Services-Asheville
Associated Lab Samples: 92603755001,92603755002, 92603755003,92603755004, 92603755005, 92603755006,92603755007,
92603755008
METHOD BLANK: 3644587 Matrix: Water
Associated Lab Samples: 92603755001,92603755002, 92603755003,92603755004, 92603755005, 92603755006,92603755007,
92603755008
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Total Dissolved Solids mg/L ND 25.0 05/13/22 09:26
LABORATORY CONTROL SAMPLE: 3644588
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Total Dissolved Solids mg/L 250 248 99 90-110
SAMPLE DUPLICATE: 3644589
92604026005 Dup
Parameter Units Result Result RPD Qualifiers
Total Dissolved Solids mg/L 102 97.0 5
SAMPLE DUPLICATE: 3644590
92603988001 Dup
Parameter Units Result Result RPD Qualifiers
Total Dissolved Solids mg/L 2600 2200 17
Results presented on this page are in the units indicated by the"Units'.column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date: 05/16/2022 02:14 PM without the written consent of Pace Analytical Services,LLC. Page 13 of 27

Pace Analytical Services,LLC
aceAnal tical 2225 Riverside Dr.
Jq/'� Asheville,NC 28804
www.pacellabs.caim [phone]
QUALITY CONTROL DATA
Project: Lassonde Pappas WQ 5/10
Pace Project No.: 92603755
QC Batch: 697585 Analysis Method: SM 9222D-2015
QC Batch Method: SM 9222D-2015 Analysis Description: 9222D Fecal Coliform(MF)-AVL
Laboratory: Pace Analytical Services-Asheville
Associated Lab Samples: 92603755001,92603755002, 92603755003,92603755004, 92603755005, 92603755006,92603755007,
92603755008
METHOD BLANK: 3642586 Matrix: Water
Associated Lab Samples: 92603755001,92603755002, 92603755003,92603755004, 92603755005, 92603755006,92603755007,
92603755008
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Fecal Coliforms CFU/100 mL ND 1.0 05/11/22 14:22
SAMPLE DUPLICATE: 3642587
92603577002 Dup
Parameter Units Result Result RPD Qualifiers
Fecal Coliforms CFU/100 mL ND ND
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date: 05/16/2022 02:14 PM without the written consent of Pace Analytical Services,LLC. Page 14 of 27

Pace Analytical Services,LLC
aceAnalytical 2225 Riverside Dr.
Jq/� Asheville,NC 28804
www.pacellabs.caim [phone]
QUALITY CONTROL DATA
Project: Lassonde Pappas WQ 5/10
Pace Project No.: 92603755
QC Batch: 697551 Analysis Method: EPA 350.1 Rev 2.0 1993
QC Batch Method: EPA 350.1 Rev 2.0 1993 Analysis Description: 350.1 Ammonia
Laboratory: Pace Analytical Services-Asheville
Associated Lab Samples: 92603755001,92603755002, 92603755003,92603755004
METHOD BLANK: 3642322 Matrix: Water
Associated Lab Samples: 92603755001,92603755002, 92603755003,92603755004
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Nitrogen,Ammonia mg/L ND 0.10 05/12/22 11:06
LABORATORY CONTROL SAMPLE: 3642323
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Nitrogen,Ammonia mg/L 5 5.1 102 90-110
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 3642324 3642325
MS MSD
92603580001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Nitrogen,Ammonia mg/L 0.11 5 5 5.3 5.3 103 103 90-110 0
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 3642326 3642327
MS MSD
92603580002 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Nitrogen,Ammonia mg/L ND 5 5 5.2 5.2 104 104 90-110 0
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date: 05/16/2022 02:14 PM without the written consent of Pace Analytical Services,LLC. Page 15 of 27

Pace Analytical Services,LLC
aceAnalytical 2225 Riverside Dr.
Jq/� Asheville,NC 28804
www.pacellabs.caim [phone]
QUALITY CONTROL DATA
Project: Lassonde Pappas WQ 5/10
Pace Project No.: 92603755
QC Batch: 697556 Analysis Method: EPA 350.1 Rev 2.0 1993
QC Batch Method: EPA 350.1 Rev 2.0 1993 Analysis Description: 350.1 Ammonia
Laboratory: Pace Analytical Services-Asheville
Associated Lab Samples: 92603755005,92603755006, 92603755007,92603755008
METHOD BLANK: 3642336 Matrix: Water
Associated Lab Samples: 92603755005,92603755006, 92603755007,92603755008
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Nitrogen,Ammonia mg/L ND 0.10 05/12/22 11:09
LABORATORY CONTROL SAMPLE: 3642337
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Nitrogen,Ammonia mg/L 5 5.1 101 90-110
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 3642338 3642339
MS MSD
92603755005 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Nitrogen,Ammonia mg/L ND 5 5 5.0 5.0 100 99 90-110 1
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 3642340 3642341
MS MSD
92603755006 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Nitrogen,Ammonia mg/L ND 5 5 5.2 5.2 103 103 90-110 0
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date: 05/16/2022 02:14 PM without the written consent of Pace Analytical Services,LLC. Page 16 of 27

Pace Analytical Services,LLC
aceAnalytical 2225 Riverside Dr.
Jq/� Asheville,NC 28804
www.pacellabs.caim [phone]
QUALITY CONTROL DATA
Project: Lassonde Pappas WQ 5/10
Pace Project No.: 92603755
QC Batch: 697337 Analysis Method: EPA 353.2 Rev 2.0 1993
QC Batch Method: EPA 353.2 Rev 2.0 1993 Analysis Description: 353.2 Nitrate+Nitrite, Unpres.
Laboratory: Pace Analytical Services-Asheville
Associated Lab Samples: 92603755001,92603755002, 92603755003,92603755004, 92603755005, 92603755006,92603755007,
92603755008
METHOD BLANK: 3641497 Matrix: Water
Associated Lab Samples: 92603755001,92603755002, 92603755003,92603755004, 92603755005, 92603755006,92603755007,
92603755008
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Nitrogen, Nitrate mg/L ND 0.040 05/11/22 02:51
LABORATORY CONTROL SAMPLE: 3641498
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Nitrogen, Nitrate mg/L 1.5 1.5 99 90-110
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 3641501 3641502
MS MSD
92603755001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Nitrogen, Nitrate mg/L 0.46 1.5 1.5 1.9 1.9 99 98 90-110 1
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 3641503 3641504
MS MSD
92603755005 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Nitrogen, Nitrate mg/L 3.2 1.5 1.5 6.5 7.4 220 280 90-110 13
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date: 05/16/2022 02:14 PM without the written consent of Pace Analytical Services,LLC. Page 17 of 27

Pace Analytical Services,LLC
aceAnalytical 2225 Riverside Dr.
Jq/� Asheville,NC 28804
www.pacellabs.caim [phone]
QUALITY CONTROL DATA
Project: Lassonde Pappas WQ 5/10
Pace Project No.: 92603755
QC Batch: 697658 Analysis Method: EPA 365.1 Rev 2.0 1993
QC Batch Method: EPA 365.1 Rev 2.0 1993 Analysis Description: 365.1 Phosphorus,Total
Laboratory: Pace Analytical Services-Asheville
Associated Lab Samples: 92603755001,92603755002
METHOD BLANK: 3642918 Matrix: Water
Associated Lab Samples: 92603755001,92603755002
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Phosphorus mg/L ND 0.050 05/12/22 20:51
LABORATORY CONTROL SAMPLE: 3642919
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Phosphorus mg/L 2.5 2.5 101 90-110
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 3642920 3642921
MS MSD
92599340001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Phosphorus mg/L 0.25 2.5 2.5 2.8 2.8 102 102 90-110 0
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 3642922 3642923
MS MSD
92602789002 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Phosphorus mg/L 0.87 2.5 2.5 2.7 2.8 75 76 90-110 1 M1
Results presented on this page are in the units indicated by the"Units'.column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date: 05/16/2022 02:14 PM without the written consent of Pace Analytical Services,LLC. Page 18 of 27

Pace Analytical Services,LLC
aceAnalytical 2225 Riverside Dr.
Jq/� Asheville,NC 28804
www.pacellabs.caim [phone]
QUALITY CONTROL DATA
Project: Lassonde Pappas WQ 5/10
Pace Project No.: 92603755
QC Batch: 697659 Analysis Method: EPA 365.1 Rev 2.0 1993
QC Batch Method: EPA 365.1 Rev 2.0 1993 Analysis Description: 365.1 Phosphorus,Total
Laboratory: Pace Analytical Services-Asheville
Associated Lab Samples: 92603755003,92603755004, 92603755005,92603755006, 92603755007, 92603755008
METHOD BLANK: 3642924 Matrix: Water
Associated Lab Samples: 92603755003,92603755004, 92603755005,92603755006, 92603755007, 92603755008
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Phosphorus mg/L ND 0.050 05/12/22 21:19
LABORATORY CONTROL SAMPLE: 3642925
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Phosphorus mg/L 2.5 2.5 101 90-110
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 3642926 3642927
MS MSD
92603377001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Phosphorus mg/L ND 2.5 2.5 1.5 1.3 46 37 90-110 16 M1,R1
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 3642928 3642929
MS MSD
92603755003 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Phosphorus mg/L ND 2.5 2.5 2.6 2.6 103 102 90-110 0
Results presented on this page are in the units indicated by the"Units'.column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date: 05/16/2022 02:14 PM without the written consent of Pace Analytical Services,LLC. Page 19 of 27

Pace Analytical Services,LLC
aceAnalytical 2225 Riverside Dr.
Jq/� Asheville,NC 28804
www.pacellabs.caim [phone]
QUALITY CONTROL DATA
Project: Lassonde Pappas WQ 5/10
Pace Project No.: 92603755
QC Batch: 697704 Analysis Method: SM 4500-CI-E-2011
QC Batch Method: SM 4500-CI-E-2011 Analysis Description: 4500 Chloride
Laboratory: Pace Analytical Services-Asheville
Associated Lab Samples: 92603755001,92603755002, 92603755003,92603755004, 92603755005, 92603755006,92603755007,
92603755008
METHOD BLANK: 3643000 Matrix: Water
Associated Lab Samples: 92603755001,92603755002, 92603755003,92603755004, 92603755005, 92603755006,92603755007,
92603755008
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Chloride mg/L ND 1.0 05/12/22 14:17
LABORATORY CONTROL SAMPLE: 3643001
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Chloride mg/L 20 20.5 102 90-110
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 3643002 3643003
MS MSD
92602669001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Chloride mg/L 128 10 10 140 143 128 148 90-110 1 M1
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 3643004 3643005
MS MSD
92602721004 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Chloride mg/L 8.2 10 10 17.8 18.1 97 100 90-110 2
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date: 05/16/2022 02:14 PM without the written consent of Pace Analytical Services,LLC. Page 20 of 27

Pace Analytical Services,LLC
aceAnalytical 2225 Riverside Dr.
Jq/� Asheville,NC 28804
www.pacellabs.caim [phone]
QUALITY CONTROL DATA
Project: Lassonde Pappas WQ 5/10
Pace Project No.: 92603755
QC Batch: 698019 Analysis Method: SM 5310B-2014
QC Batch Method: SM 5310B-2014 Analysis Description: 5310B TOC
Laboratory: Pace Analytical Services-Asheville
Associated Lab Samples: 92603755001,92603755002, 92603755003,92603755004, 92603755005, 92603755006,92603755007,
92603755008
METHOD BLANK: 3644741 Matrix: Water
Associated Lab Samples: 92603755001,92603755002, 92603755003,92603755004, 92603755005, 92603755006,92603755007,
92603755008
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Total Organic Carbon mg/L ND 1.0 05/13/22 12:07
LABORATORY CONTROL SAMPLE: 3644742
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Total Organic Carbon mg/L 25 24.8 99 90-110
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 3644743 3644744
MS MSD
92603755001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Total Organic Carbon mg/L 2.9 25 25 26.9 26.9 96 96 90-110 0
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 3644745 3644746
MS MSD
92603836003 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Total Organic Carbon mg/L ND 25 25 24.6 24.4 98 97 90-110 1
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date: 05/16/2022 02:14 PM without the written consent of Pace Analytical Services,LLC. Page 21 of 27

Pace Analytical Services,LLC
aceAnal tical 2225 Riverside Dr.
Jq/'� Asheville,NC 28804
www.pacallabs.com [phone]
QUALIFIERS
Project: Lassonde Pappas WQ 5/10
Pace Project No.: 92603755
DEFINITIONS
DF-Dilution Factor, if reported,represents the factor applied to the reported data due to dilution of the sample aliquot.
ND-Not Detected at or above adjusted reporting limit.
TNTC-Too Numerous To Count
J-Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL-Adjusted Method Detection Limit.
PQL-Practical Quantitation Limit.
RL-Reporting Limit-The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S-Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270.The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate%recovery and RPD values.
LCS(D)-Laboratory Control Sample(Duplicate)
MS(D)-Matrix Spike(Duplicate)
DUP-Sample Duplicate
RPD-Relative Percent Difference
NC-Not Calculable.
SG-Silica Gel-Clean-Up
U-Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis ofAcrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Reported results are not rounded until the final step prior to reporting.Therefore,calculated parameters that are typically reported as
"Total"may vary slightly from the sum of the reported component parameters.
Pace Analytical is TNI accredited.Contact your Pace PM for the current list of accredited analytes.
TNI-The NELAC Institute.
ANALYTE QUALIFIERS
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample(LCS)recovery.
R1 RPD value was outside control limits.
REPORT OF LABORATORY ANALYSIS
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Date: 05/16/2022 02:14 PM without the written consent of Pace Analytical Services,LLC. Page 22 of 27

Pace Analytical Services,LLC
aceAnalytical 2225 Riverside Dr.
Jq/� Asheville,NC 28804
www.pacallabs.com [phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: Lassonde Pappas WQ 5/10
Pace Project No.: 92603755
Analytical
Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch
92603755001 MW-4-20220510 SM 2540C-2015 697955
92603755002 MW-5-20220510 SM 2540C-2015 697955
92603755003 MW-6-20220510 SM 2540C-2015 697955
92603755004 MW-7R-20220510 SM 2540C-2015 697955
92603755005 MW-8-20220510 SM 2540C-2015 697955
92603755006 MW-9-20220510 SM 2540C-2015 697955
92603755007 SW-1-20220510 SM 2540C-2015 697955
92603755008 SW-2-20220510 SM 2540C-2015 697955
92603755001 MW-4-20220510 SM 9222D-2015 697585 SM 9222D-2015 697586
92603755002 MW-5-20220510 SM 9222D-2015 697585 SM 9222D-2015 697586
92603755003 MW-6-20220510 SM 9222D-2015 697585 SM 9222D-2015 697586
92603755004 MW-7R-20220510 SM 9222D-2015 697585 SM 9222D-2015 697586
92603755005 MW-8-20220510 SM 9222D-2015 697585 SM 9222D-2015 697586
92603755006 MW-9-20220510 SM 9222D-2015 697585 SM 9222D-2015 697586
92603755007 SW-1-20220510 SM 9222D-2015 697585 SM 9222D-2015 697586
92603755008 SW-2-20220510 SM 9222D-2015 697585 SM 9222D-2015 697586
92603755001 MW-4-20220510 EPA 350.1 Rev 2.0 1993 697551
92603755002 MW-5-20220510 EPA 350.1 Rev 2.0 1993 697551
92603755003 MW-6-20220510 EPA 350.1 Rev 2.0 1993 697551
92603755004 MW-7R-20220510 EPA 350.1 Rev 2.0 1993 697551
92603755005 MW-8-20220510 EPA 350.1 Rev 2.0 1993 697556
92603755006 MW-9-20220510 EPA 350.1 Rev 2.0 1993 697556
92603755007 SW-1-20220510 EPA 350.1 Rev 2.0 1993 697556
92603755008 SW-2-20220510 EPA 350.1 Rev 2.0 1993 697556
92603755001 MW-4-20220510 EPA 353.2 Rev 2.0 1993 697337
92603755002 MW-5-20220510 EPA 353.2 Rev 2.0 1993 697337
92603755003 MW-6-20220510 EPA 353.2 Rev 2.0 1993 697337
92603755004 MW-7R-20220510 EPA 353.2 Rev 2.0 1993 697337
92603755005 MW-8-20220510 EPA 353.2 Rev 2.0 1993 697337
92603755006 MW-9-20220510 EPA 353.2 Rev 2.0 1993 697337
92603755007 SW-1-20220510 EPA 353.2 Rev 2.0 1993 697337
92603755008 SW-2-20220510 EPA 353.2 Rev 2.0 1993 697337
92603755001 MW-4-20220510 EPA 365.1 Rev 2.0 1993 697658 EPA 365.1 Rev 2.0 1993 697930
92603755002 MW-5-20220510 EPA 365.1 Rev 2.0 1993 697658 EPA 365.1 Rev 2.0 1993 697930
92603755003 MW-6-20220510 EPA 365.1 Rev 2.0 1993 697659 EPA 365.1 Rev 2.0 1993 697932
92603755004 MW-7R-20220510 EPA 365.1 Rev 2.0 1993 697659 EPA 365.1 Rev 2.0 1993 697932
92603755005 MW-8-20220510 EPA 365.1 Rev 2.0 1993 697659 EPA 365.1 Rev 2.0 1993 697932
92603755006 MW-9-20220510 EPA 365.1 Rev 2.0 1993 697659 EPA 365.1 Rev 2.0 1993 697932
92603755007 SW-1-20220510 EPA 365.1 Rev 2.0 1993 697659 EPA 365.1 Rev 2.0 1993 697932
92603755008 SW-2-20220510 EPA 365.1 Rev 2.0 1993 697659 EPA 365.1 Rev 2.0 1993 697932
92603755001 MW-4-20220510 SM 4500-CI-E-2011 697704
92603755002 MW-5-20220510 SM 4500-CI-E-2011 697704
92603755003 MW-6-20220510 SM 4500-CI-E-2011 697704
92603755004 MW-7R-20220510 SM 4500-CI-E-2011 697704
92603755005 MW-8-20220510 SM 4500-CI-E-2011 697704
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date: 05/16/2022 02:14 PM without the written consent of Pace Analytical Services,LLC. Page 23 of 27

Pace Analytical Services,LLC
aceAnalytical 2225 Riverside Dr.
Jq/� Asheville,NC 28804
www.pacallabs.com [phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: Lassonde Pappas WQ 5/10
Pace Project No.: 92603755
Analytical
Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch
92603755006 MW-9-20220510 SM 4500-CI-E-2011 697704
92603755007 SW-1-20220510 SM 4500-CI-E-2011 697704
92603755008 SW-2-20220510 SM 4500-CI-E-2011 697704
92603755001 MW-4-20220510 SM 5310B-2014 698019
92603755002 MW-5-20220510 SM 5310B-2014 698019
92603755003 MW-6-20220510 SM 5310B-2014 698019
92603755004 MW-7R-20220510 SM 5310B-2014 698019
92603755005 MW-8-20220510 SM 5310B-2014 698019
92603755006 MW-9-20220510 SM 5310B-2014 698019
92603755007 SW-1-20220510 SM 5310B-2014 698019
92603755008 SW-2-20220510 SM 5310B-2014 698019
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date: 05/16/2022 02:14 PM without the written consent of Pace Analytical Services,LLC. Page 24 of 27

Document Name: Document Revise&November 15,2021
Sample Condition Upon Receipt(SCUR) Page 1 of 2
2
ace Analytical Document No,. Issuing Authority:
F-CAR-CS-033-Rev,08 Pace Carolinas Quality Office
Laboratory receiving samples:
Asheville?F' EdenE Greenwood —1 Huntersville fl Raleigh iViechanicsvillen Atlantan Kernersvillei]
Sampie Condition: Client Name; WO# " 92603755
UPcid RereiRt Project
Courier: E)Fed E DUPS CUSPS eCIClient I 11 I
LI Commercial OPace pOther. I 1111 ,1 I
92603755
Custody Seal Present? ElYes VINO Seals Intact? Lives IliNo
Date/Initials Person Examining Contents:
Packing Material: ,filfiebble Wrap EiBubble Bags EiNorte El Other Biological Tissue Frozen?
Thermometer:, O Oyes [IN°
zfWet rilue fiNone
Erill Gun ID /1 F,„,,,If„: Type of Ice: 4
Correction Factor:
Cooler Temp: Add/Subtract(C) Temp should he above freezing to VC
DSamples out of temp criteria Samples on ice,cooling process
Cooler Temp Corrected(7C); has begun
USDA Regulated Soil (,,r,N/A,water sample)
Did samples originate in a quarantine zone within the United States CA,NY,or SC(check maps)? Did samples originate from a foreign source(internationally,
[lees ON° including Haioz4a;i and Puerto Ricut?ares EiNo
Comments/Discrepancy:
Chain of Custody Present? E:gyii DN/A
Samples Arrived within Hold Time? 1dres { (No ON/A 2.
Short Hold Time Analysis(<72 hr4? DYes Oio DNA 3
Rush Turn Around Time Requested? [les LIMO N/A 4,
Sufficient Volume? jfes ON0 ON/A 5,
Correct Containers Used? ,dees EINo EIN/A 6.
-Pace Containers Used? Yss 01,40 oN/A
Containers intact? 1,1Yes EiNo DN/A 7.
Dissolved analysis:Samples Field Filtered? 11Yes oNo 1111 /A
Sample labels Match COC? eDYes LiMo ON/A 9
-Includes Date/Time/ID/Analysis Matrix L
Heads pace in VOA Vials(>5-6rnm)? [Trim iMNia EIN/A 113.
Trip Blank Present? Ekes !NO 1j1/A 11.
Trip Blank Custody Seals Present) OYs Oio 3N/A
COMMENTS/SAMPLE DISCREPANCY Field Data Required? -Des ON°
Lot lD of split containers:
CLIENT NOTiFICATICIN/RESOWTION
Person contacted: Date/Time
Project Manager SCURF Review: Date:
Project Manager SRF Review: Date: Page 25 of 27

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CHAIN-OF-CUSTODY/Analytical Request Document 15
`�-- The Chain-of-Custo Iy is a LEGAL DOCUMENT.All relevant fields must be completed accurately. c"
ru
Submitting a sample via this chain of custody constitutes acknowledgment and acceptance of the Pace Terms and Conditions found at https./iiafo.pacelabs.cowlhuffs/pas-standard-terms.pdf, cn
1co
Section A Section B Section C d
Required Client Information: Required Project Information: -_.. Invoice Information: _.-.. ---_ Page: 1 Of 1
Company. ANCHOR QEA OF NC.PLLC Report To. thuds nit7P�n "
--. ---_ i f #. 3 � # rIz., Attention: ---- --..
Address: 231 Haywood Street Copy To: Company Name:
Asheville,NC 28801 Address.
Regulatory Agency
Email: Purchase Order#: Pace Quote.
Phone: [phone] 1Eax.: Project Name: Lassonde Pappas Spring 2022 WQ Monitoring Pace Project Manager; forri.petton [e-mail], State I Location
[Requested Due Date: Project# Pace Profile# Pippin NC
Requested Analysts Filtered(YIN)
a 0
iare.x cobs ;, W COLLECTED _ g Preservatives `-
C nk.n5 Water DW ' SJ - 1---
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Water WT ` m 0 6
'Wonte a'lr WW s 0 a
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Pintos: P > 9. f3 .0. ?e
SAMPLE ID 6a ts�ra 2 START END I- o s, e
One Character per box. w1Pe 4`1P a a a z 0 0 o P. c, 4
Q
(A-Z,0-91.,-) Asr AP. 4 r w a P, (4 _ I— = M r
Other UT U .— , Z z= ,r00 — .a... 'Ea' Q m
Sample Ids must be unique Tsar TS x c : a ca 'a
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II a • Iin • Lo • s an • Instru nt
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• N .. Anchor QEA of North Carolina,PLLC
1111
J 231 Haywood Street
Asheville,North Carolina 28801
Low-Flow Sampling Log Well ID: MW-4
Project Name: Lassonde Pappas Spring 2022 WQ Monitoring Date: ',r ,,'I it 0 r ',(^a
Project Number. 7i
Project Location: Hendersonville,NC FacilityID or Permit#(if applicable): Permit No.WQ0004797
..,.
Sample Collectors) ° Sample ID(on COC): M
Well Diameter. 2 in Arrive at Well: ' ,) )
Screen Interval: 5-15 ft bgs Start Time: t 4ti tr
Well Depth(as constructed): 15 ft bgs Sample Time: ,.:2,4,111
Depth to Water: , t rt ft Leave Well: 1", 7,� t,
v ', /(�l° Tagged Bottom:
',Stick Upft oFlush Moat(time): , °
Measuring Point:
Depth of Pump Intake: V ft
Pump Used(circle): Peristaltc Bladder , ;'la Other(describe): Purge Rate br tnw k
Comments: 1 [Lr ° , �.)) d �1 o Y,.ai Total Volume Purged:
�l r a 6�,` o �r
k-�;�` i th,irlitb(' , � F'''t Pump Speed: .„),ti,it .t !
Specific Oxidation
Dissolved Oxygen Conductivity pH(S.U.) Reduction
Time DTW(feet) Temperature(°C) (mg/L) (pmhos/cm) report to 0.1 S.U. Potential(mV) Turbidity(NTU)
a � @eY .. 1 '� ), r �'
r
l - .1 i °Y ' @i ,E 1 j f tl,,! ,,, l 1 N
7 5 ,
dv e,
ggL7 f
.. V 2'''2!11: , ;5', ' 1 12.), L-r---7
, ,,,, i °' ,1r„ e��p �°-, i
,„ ,,
�i ¶ l,� "`�, a ... i1y y ��—II Lk s � � ;
qi 4 /Q a 4 , r �� 1 4,G' o , '" n 1, ( 4.4
Sample Analyst nature V r p 4 Name 1 �' `. I l?r Y I� .C' ! 1a4 .'�`..
i ,,Sample Analyst
P Ys 9 �(„ Date: ( �
Notes:
1:Stabilization(3 successive readings,3 minutes apart):within+/-70%D0 and turbidity, +/-3%Conductivity, +/-0.1 pH unit: +/-10 mV for ORP
from EPA-Low-Flow(Minimal Drawdown)Groundwater Sampling Procedures,April 1996(Rev 2017)
2.Documentation errors are to be crossed out with a single line,so the original text is still legible,followed by the staff members initials and date
3.Samples are analyzed immediately upon collection.
4.NC Field Laboratory Certificate Number 5445
5. 1 pmho/cm=1 pS/cm
Abbreviations: Method Reference:
°C:degrees Celsius S.U.:standard units Temperature:SM 2550 B-2010
pmhos/cm:micromhos per centimeter ft:feet Specific conductivity:EPA Method 120.1,Rev.1982
mg/L:milligrams per liter in:inches DO:SM 4500 0 G-2011
mV:millivolt bgs:below ground surface pH:SM 4500-H'B-2011
NTU:nephelometric turbidity units TOC:top of casing Turbidity:SM 2130 B-2011
Page 1 of 1

AINNI C H(,,,)R Anchor QEA of North Carolina,PLLC
231 Haywood Street
Asheville,North Carolina 28801
Low-Flo ,,, Sampling Log Well ID: MW-5
_ —
Project Name: Lassonde Pappas Spring 2022 WQ Monitoring Date:
Project Number C21482-01.01 Task'7 Weather
Project Location: Hendersonville,NC Facility ID or Permit#(if applicable): Permit No.WQ0004797
Sample Collector(s): I„1. t Sample ID(on COC): MW-5.-
Well Diameter: 2 in Arrive at Well: lItt,I I Cit.
Screen Interval: 949 ft bgrt Start Time:
Well IDepth(as constructed): 19 It bgs Sample Time:
Depth to Water: ittt, "-- ft Leave Well:
Measuring Pont: 'roc Well Type: )(Stick Up jj PFIlush Mount
,t
Depth of Pump intake: i(jj ft Tagged Bottom: j ;) I , A ft at(time): kiJ"jjt II (r1,
Pump Used(circle): (Eeristalt3) Bladder Other(describe): Purge Rate: j'tt)(1 j jtJJ(J '(`I Int\(jIli
Comments: I ( 1 Total Volume Purged:
'jt i iltll,(t7)I it.t li (i. J jt, ,t ta Pump Speed:
I Specific 1 Oxidation
..'r Dissolved Oxygen Conductivity pH(S.U.) Reduction
Time DTW(feet) Temperature CC) (mg/L) (pmhos/cm) report to 0.1 S.U. Potential(mV) Turbidity(NTU)
„)1,' () )). .+ -1 '.:,,,.;,...?..(
tri ;., n).A ), (,,,i I ,Iiiik,j, 4, , ,(,,L( -) , „ efibbi ((in Iiiii'iiii,i'iii7,J,,Iii In' •Iiii / ',Hi
— ,r--- _ •,-
--_ ,
Sample Analyst
.„,,,
(. (
Sample Analyst Signature: ''). i
t k. i .. .
Date: r)''Y 114 d. )
Notes:
1 ditabzation(3 successive readingn,3 rninutet dpartA wdhan-i i Ai l 0%DO und tgubichty, ,/,3%Conductonty; ,/-a I pH 6A,rut, t/ W?r,V for ORP
from EPA-11.bw-Flow(Minirnall Draiiindowrp Groun ati dwor Compiling Proluceires 19,April 96(RevPM 01
it i I, Name:vi,ic
2 IDocumenitatinn moms air to be crannied out with a ningie.Vine,no the original told is sidi iodide,fonnwed by the start members mitt:Ws and date
3 SanriPlle$are analyzed immediately upon collection
4 NC Ilneid II aboratory Certificate Niurnber WS
5. 1 pmficificin v 1 pdfon
Abbreviations: Method Reference:
*C'.degree5 Celsius Sib.:standard idnitn Tennperatuirei SM 2550 P-2010
ivinhobicm imicsbmhos pop coritimeter It feet Specific conductivity EPA Method 1120.1,Rev.1982
mcyll...mifiigrams per oi Is in inchen IDOi SIM 45.00 0 G P011
nbin miilivoit Lids'below ground surface PH:SIM 45004-II id:ii,011
NTLY,inephellometric turhidiiy undo IOC top of casing Turbidity.SM 21130 B 2011
Page 1 of 1

Anchor QEA of North Carolina,PLLC
231 Haywood Street
Asheville,North Carolina 28801
Low-Flow Sampling Log Well ID: MW-6
Project Name: Lassonde Pappas Spring 2022 WQ Monitoring Date: V, I V I 144,11 111)
Project Number: C21482-01.01 Task 7 Weather.
Project Location: Hendersonville,NC Facility ID or Permit#(if applicable): Permit No.WQ0004797'
Sample Collector(s): 1,1 :1) Sample ID(on COC): MW-6- 1j1„)t1. 1) .j••))1' I f,,,,
Well Diameter: 2 in Arrive at Well:
Screen Interval: 5-10 ft bgs Start Time:
Well Depth(as constructed): 10 ft bgs Sample Time:
Depth to Water: ()4!), „(41 ft Leave Well:
Measuring Point: TOC Well Type: XStic1)Up oFlush Mount
Depth of Pump Intake: III•II ft Tagged Bottom: 4i,,-7,144644-4 ft at(time):
Pump Used(circle): (15-risTaTt151') Bladder Other(describe): (141,ir-,5I1c1 1"kej_
1„!I• 4 6', %i D Purge Rate: 414)11,1)14•11I 77111,,•'Il'1:4/4
Comments: )441,I)) Ii/,, I ) ) /I( I L 4 ,1, ,,,,I, f,f,,,,,a ,, i:,(( , 1(,(1 Total Volume Purged:I(' ,„))14'5":„Ir,)1)),it i I' III IIII•1)(1)II1
II))I)(1A V)" "II I I,1 41 II141441, Iv I l 144„„111 4Pump Speed:
Specific Oxidation
Dissolved Oxygen Conductivity pH(S.U.) Reduction
Time DTW(feet) Temperature CC) (mg/L) (pmhos/cm) report to 0.1 S.U. Potential(mV) Turbidity(NTU)
..... „ . .
_ 'tt/ I cif',')'I
'
',‘ ,(,,,ii (i, , ,(7, (,, ,„i,A 4::,,,) /." 1 i
,,.. ' I ,
'41'4 I(
,.t
4'11, 46, 64 4
)6's c 44, 444 4„ 4,4
,
6;4 „44, „6,6 _not, , 6,44 44 i'6:6, 41 , 61,,, 4:4
i
L664441
1 1 1 , 1 I r; , `i',Ltvi
L.
,-,
I „ (64' 664 ) 646 ,, 4/6 41_
Sample Analyst
Sample Analyst Signature: , /t i' t i' (// / ( i7 ,
' Name: '',, 1/ / 1 ..E t,,Ct [ 14/t LI Date:
Notes:
1:Stabilization(3 successive readings,3 minutes apart):within+/-10%DO and turbidity* +/-3%Conductivity; +/-0.1 pH unit; +/-10 mV for ORP
from EPA-Low-Flow(Minimal Drawdown)Groundwater Sampling Procedures,April 1996(Rev 2017)
2.Documentation errors are to be crossed out with a single line,so the original text is still legible,followed by the staff members initials and date
3.Samples are analyzed immediately upon collection.
4.NC Field Laboratory Certificate Number 5445
5. 1 pmho/cm=1 pS/cm
Abbreviations: Method Reference:
°C:degrees Celsius S.U.:standard units Temperature:SM 2550 B-2010
gmhos/cm:micromhos per centimeter ft:feet Specific conductivity:EPA Method 120.1,Rev.1982
mg/L:milligrams per liter in:inches DO:SM 4500 0 G-2011
mV:millivolt bgs:below ground surface pH:SM 4500-H.B-2011
NTU:nephelometric turbidity units TOC:top of casing Turbidity:SM 2130 B-2011
Page 1 of 1

J R Anchor QEA of North Carolina,PLLC
231 Haywood Street
Asheville,North Carolina 28801
Low-Flow Sampling Log ' ell 1111): MW-7IP
. .. _Project Name: Lassonde Pappas Spring 20221/VO Monitoring Date:
Project Number C21482-01.01 Task 7 Weather
Project Location: Hendersonville,NC Facility ID or Permit#(if applicable): Permit No.WQ0004797
Sample Collector(s): ,(.. z Sample ID(on COC): MW-71ftiv,
Well Diameter: 2 in Arrive at Well:
Screen Interval: 515 ft bgs Start Time:
Well Depth(as constructed): 15 ft bgs Sample Time: j'' ( ,,,;"ti
Depth to Water (1.:A4; ft Leave Well
Measuring Point: TOC Well Type: itStick Up °Flush Mount
Depth of Pump Intake: L 1 ft Tagged Bottom: at(time):
03
Pump Used(circle): rzistaltit:) Madder ,2,...
Other(describe): ,c ID Purge Rate
Comments: I ,,l' hj';' 1( ) r i (1 (,(it) ), t. [It.,(c , ((( ;',.191(;()i9 Total Volume Purged:
Pump Speed:
'''''.1A'„',.(:1,'(:
Specific
: In Oxidation
Dissolved Oxygen Conductivity pli(S„U.) Reduction
Time IDTW(feet) Temperature CC) (Inagi'L)
Ormlhasicm) 1 S.U. Potentiai(mV) 'Turbidity(NTU)
(
report to 0.11 „,,^,,,Ir.) (),',,:,, t,,•,,-, r" Li i,:,,,. ,', e,", (1
i i( ,
1 P ((',„ '1 i''„IP " I ) tl )13, '
) ," 1,,
i
,,,1 ,,
IMINFAIII„ ,„3, .11 ,, 1 firiniMIIIMMIEllgallill
) (-I , .,,, ,,1 „ 5 .,,, , , t ,,
,; ;
i,,,,)
,)
N LI 't) L '",''''''( 1 , ,,—
, , 1
-i
H „ (0 1,--h, L,,
Sample Analyst
Sample Analyst Signature. ,',.., ,
lir, rnil , / i' iL.,),(VVA il ) Name. "ft 1 ( (''' L' '''' V V)(1` Date:
.................. ,„.... ... , ..
Notes:
1:Stabilization(3 successive readings,3 minutes apart):within./-70%DO and turbidity; +/-3%Conductivity; +/-0.7 pH unit; +/-70 rat/for ORP
from EPA-Low-Flow(Minimal Drawdown)Groundwater Sampling Procedures,April 1996(Rev 2017)
2.Documentation errors are to be crossed out with a single line,so the original text is still legible,followed by the staff members initials and date
3.Samples are analyzed immediately upon collection.
4.NC Field Laboratory Certificate Number 5445
5. 1 pmho/cm=1 pS/cm
Abbreviations: Method Reference:
*C:degrees Celsius S.U.:standard units Temperature:SM 2550 6-2010
pmhos/cm:micromhos per centimeter ft:feet Specific conductivity:EPA Method 120.1,Rev.1982
mg/L:milligrams per liter in:inches DO:SM 4500 0 G-2011
mV:millivolt bgs:below ground surface pH:SM 4500-H B-2011
NTU:nephelometric turbidity units TOC:top of casing Turbidity:SM 2130 B-2011
Page 1 of 1

AidslIT:1 if,)R Anchor QEA of North Carolina,PLLC
231 Haywood Street
Asheville,North Carolina 28801
Low-Flow Sampling Log well ID: MW-8
Project Name: Lassonde Pappas Spring 2022 WQ Monitoring Date: ''t1l,'d'''' k"j 1
AV 0)i
Project Number: C21482-01.01 Task 7 Weather 4 • c(AK PA/
Project Location: Hendersonville,NC Facility ID or Permit#(if applicable): Permit No.WQ0004797
Sample Collector(s): VI: Sample ID(on COC): MW-8- )1Da. •slo
Well Diameter: 2 in Arrive at Well:
Screen Interval: 3-13 ft bgs Start Time:
Well Depth(as constructed): 13 ft bgs Sample Time:
Depth to Water: l(f , ft Leave Well:
Measuring Point: TOC Well Type: tStick Up oFlush Mount
Depth of Pump Intake: a ft Tagged Bottom: ft at(time):
Pump Used(circle): (fe'ristaltiD Bladder Other(describe): Purge Rate:
Comments: (1 '„,' 4„„Je„1 111214,11 e""ii) f)',"?i,„1 el Total Volume Purged:
.1-1' '' A,l'1. ''
' 1
Pump Speed:
_—,....
Specific Oxidation
Dissolved Oxygen Conductivity pH(S.U.) Reduction
Time DTW(feet) j Temperature CC) (mg/L) (pmhos/cm) report to 0.1 S.U. Potential(mV) Turbidity(NTU)
1 ,
1 4:.; 'i '' i fij 1
C , cti i '). ,'„',,,,, 14„, 1„. k/ Ili „ „,,''''
„,
,,„ i( („)(4,„ i , (7:' ., ,( „i1 Li 1 („.„, (i:„„ „ co it(;) '1 I e 1) '4.;--"*. i '')
:, „,4e,,) ,(,)L 1i ,k , ,<, ,,-A 4,4 '-, Li IJI Cri'LZ, , ,,
, ', ,„,e '' ,L,,;, , 1:i",,in'''''i .iiii'
,iiiiiiiiiiiiii
td .16 , „ ,,
, („,/I 0, Di-1 1,,',41 r ,-'3„,'"' , f
, , ....
,--
'
1 ,
- - - -
i 1
...
. . . L
Sample Analyst
.. ,
Sample Analyst Signature: , , Name: 0/1.e ' eAria I Date:St 1 b('
Notes:
1:Stabilization(3 successive readings,3 minutes apart):within,/-70%DO and turbidity; +/-3%Conductivity; +/-0.7 pH unit +/-70 mV for ORP
from EPA-Low-Flow(Minimal Drawdown)Groundwater Sampling Procedures,April 1996(Rev 2017)
2.Documentation errors are to be crossed out with a single line,so the original text is still legible,followed by the staff members initials and date
3.Samples are analyzed immediately upon collection.
4.NC Field Laboratory Certificate Number 5445
5. 1 pmho/cm=1 pS/cm
Abbreviations: Method Reference:
°C:degrees Celsius S.U.:standard units Temperature:SM 2550 B-2010
prnhos/cm:micromhos per centimeter ft:feet Specific conductivity:EPA Method 120.1,Rev.1982
mg/L:milligrams per liter in:inches DO:SM 4500 0 G-2011
mV:millivolt bgs:below ground surface pH:SM 4500-H.B-2011
NTU:nephelometric turbidity units TOC:top of casing Turbidity:SM 2130 8-2011
Page 1 of 1

3A,, Als1C2 0 oL', Anchor QEA of North Carolina,PLLC
231 Haywood Street
Asheville,North Carolina 28801
Low-Flow Sampling Log 'Well ID: MW-9
Project Name: Lassonde Pappas Spring 2022 WQ Monitoring Date:
Project Number: C271482-01.01 Task 7 Weather:
Project Location: Hendersonville,NC Facility ID or Permit#(if applicable): Permit No.WQ0004797
Sample Collector(s): i .ijjjj j( Sample ID(on COC): MW-9-
Well Diameter: 2 in Arrive at Well:
Screen Interval: "/9/(713 t )(,,, ft bgs Start Time:
Well Depth(as constructed): (1.3. I. ,1(1; ft bgs Sample Time:
Depth to Water: (5) ( (7) ft Leave Well:
Measuring Point: TOC Well Type: 14Stick Up oFlush Mount
(
Depth of Pump Intake: ("5(k (i 57/, ifj 11/7(7 j57, I 4,);„4,) ft Tagged Bottom: f .,..' ,, ,.',.:1 ft at(time): )(I)0
0
Pump Used(circle): .. //t7e—ri'stliti ) Bladder Other(describe): Purge Rate:
Comments: pi x') 9 i)yl (,,t,I „.1()IC)(::A , f: ,c,,,,,,(„4„„) Etm'.',.,'" C I 0 Total Volume Pur ed:
9
(j.7,V5' j7 j '/,„5.— jijij_,( Pump Speed: jr„(/' , 1
1 Specific Oxidation _
Dissolved Oxygen Conductivity pH(S.U.) Reduction
Time DTW(feet) Temperature CC) (mg/L) (pmhos/cm) report to 0.7 S.U. Potential(mV) Turbidity(NTU)
,
( i
u dr
'nif) ,•ii 1'1', i , ,-3) 3,, I 'ik..3,,,4,
lo,,,Qyl ( _
ii r„ :),,9; ,
.(3, , ,,1 I 1 '13 ' , .4 c,, I t 3 ,Ai, LA,,A, il ' 1 I (,)(..,)
J (1 ,,334 1 333 .„,i m ,
NMI .
J
- - —
........
Sample Analyst,, 0 V't " (;
Sample Analyst Signature: ' \( ) ) if,,,,•)1 1 ) Name: "',4, , \ 't ' 0" e 1 it If 1) Date:
Notes:
1:Stabilization(3 successive readings,3 minutes apart):within+/-70%DO and turbidity; +/-3%Conductivity; +/-0.7 pH unit; +/-10 my for ORP
from EPA-Low-Flow(Minimal Drawdown)Groundwater Sampling Procedures,April 1996(Rev 201 7)
2.Documentation errors are to be crossed out with a single line,so the original text is still legible,followed by the staff members initials and date
3.Samples are analyzed immediately upon collection.
4.NC Field Laboratory Certificate Number 5445
5. 1 pmhoicrr.r,1 pS/cm
Abbreviations: Method Reference:
°C:degrees Celsius S.U.:standard units Temperature:SM 255013-2010
pmhos/cm:micromhos per centimeter ft:feet Specific conductivity.EPA Method 120.1,Rev.1982
mg/L:milligrams per liter in:inches DO:SM 4500 0 G-2011
mV:millivolt bgs:below ground surface pH:SM 4500-W B-2011
NTU:nephelometric turbidity units TOC:top of casing Turbidity:SM 2130 B-2011
Page 1 of 1

� s�I ,�II m�mWu� Anchor QEA of North Carolina,PLLC
m 231 Haywood Street
mal, Asheville,North Carolina 28801
Surface Water Sampling Log Location ID: SW-1
Project Name: Lassonde Pappas Spring 2022 WQ Monitoring Date: e( ,y (
Project
1 Task
Project Location: FacilityID or Permit#(if applicable):cable): Permit r
1 Hendersonville,NC7 PP ) � �No.WQ0004797� 4� �����
4
'-
Sample Collectors) � � Sample ID(on COC): SW-1 ( „
Comments:
Sample Method(circle
one): Grab Syringe Pump Bailer-Disp. Other:
L..
Specific Oxidation
Temperature Dissolved Conductivity pH(S.U.) Reduction Turbidity
Time (°C) Oxygen(mg/L) (pmhos/cm) report to 0.1 S.U. Potential(mV) (NTU) Comments
Sampling Container Number of Containers Requested Analysis
500 mL Plastic
250 mL Plastic
125 mL Plastic
40 mL Glass
1 L Glass
Other
Vegetation: ilh_ ! ( i Access: 000, ..,) d
nalyst
P Analyst Sample Name: ) 1 () ( � /I�.()1 Fr I ()
Sample � � � P' � ' � � " Date• � � � �
Notes:
1.Documentation errors are to be crossed out with a sinale line,so the original text is still leaible,followed by the staff members initials and date
2.Samples are analyzed immediately upon collection.
3.NC Field Laboratory Certificate Number 5445
Abbreviations: Method Reference:
°C:degrees Celsius Temperature:SM 2550 B-2010
pmhos/cm:micromhos per centimeter Specific conductivity:EPA Method 120.1,Rev.1982
mg/L:milligrams per liter DO:SM 4500 O G-2011
mV:millivolt pH:SM 4500-H'B-2011
NTU:nephelometric turbidity units Turbidity:SM 2130 B-2011
S.U.:standard units
Page 1 of 1

ANC11-101v Anchor QEA of North Carolina,PLLC
231 Haywood Street
Asheville,North Carolina 28801
Surface Water Sampling Log Location ID: SW-2
Project Name: Lassonde Pappas Spring 2022 WQ Monitoring Date:
Project Number: C21482-01.01 Task 7 Weather:
Project Location: Hendersonville,NC Facility ID or Permit#(if applicable): Permit No.WQ0004797
Sample Collector(s): Sample ID(on COC): SW-2- (j
Comments:
Sample Method(circle
one) Grab Syringe Pump Bailer-Disp. Other:
:
Specific Oxidation
Temperature Dissolved Conductivity pH(S.U.) Reduction Turbidity
Time (°C) Oxygen(mg/L) (limbos/cm) report to 0.1 S.U. Potential(mV) (NTU) Comments
tpfj)
Sampling Container Number of Containers Requested Analysis
500 mL Plastic
250 mL Plastic
4,L
125 mL Plastic
40 mL Glass
1 L Glass
Other
i v
Vegetation: h ovv ,„ Access: )
Sample Analyst
Sample Analyst Signature:" r'1),0/1, Name: Jj( h y Date:
Notes:
1.Documentation errors are to be crossed out with a single line,so the original text is still legible,followed by the staff members initials and date
2.Samples are analyzed immediately upon collection.
3.NC Field Laboratory Certificate Number 5445
Abbreviations: Method Reference:
°C:degrees Celsius Temperature:SM 2550 B-2010
pmhos/cm:micromhos per centimeter Specific conductivity:EPA Method 120.1,Rev.1982
mg/L:milligrams per liter DO:SM 4500 0 G-2011
mV:millivolt pH:SM 4500-H+B-2011
NTU:nephelometric turbidity units Turbidity:SM 2130 B-2011
S.U.:standard units
Page 1 of 1

_..---rt-tt,,tto it-tit 1 1.1 I k
Facility Name: '3' '3.3 t3'13V (c 1.t..331-, I-3-- ', Hach pH Meter Calibration Benchsheet Lab Certification#: 5445
Facility Permit#: ',',3,---- ‘3.33,,, .--4. t—1 7— Reference Method: SM 4500-H.B-2011(Aqueous)
pH Instrument ID:
,
( 1 kit i ..,_3
Annual Temperature Sensor Check Date: Analyst:
1 Expected 1 Buffer
11-t, .2,--11 pH Buffer Calibration or Actual pH Temp of Meter Slope, bite Date Opened, Date Comments/Data Qualifiers/Equipment
Date Time Buffer pH Vendor Buffer Lot#
Conc. Check (s.u.) Buffer°C mV(58±3) Received (In Use) Expires Maintenance
I c:--,.'ci fs.u.) j Name
10 Cal !._ ,I'J
I - 7 Cal 1 : ittett t:Pt:It "--; t
--- ._-- ..1_, I, - - i -A= ! --=-'• 1
„..
4 Cal ti-it't A 0 A Li I( ) I IL'1:titliti 2t I L I
E , __
, :,,,17,-1. 1
7* : Pre Check 'r 11 Le , jr; jk
7* 'Post Check I t ,s-t-t-ttc i 4 (i--,_, i 1** (5-: c 1 31. LL i-31 ttto t--9
pH Instrument ID: Annual Temperature Sensor Check Date: Analyst:
Expected Buffer
pH Buffer Calibration or Actual pH Temp of = Meter Slope, Date Date Opened Date Comments/Data Qualifiers/Equipment
Date Time Buffer pH Vendor Buffer Lot#
Conc. Check (s.u.) Buffer°C mV(58±3) Received (In Use) Expires Maintenance
(s.u.. Name
10 IMEMIMIIIIIIIIIIIIIMMIIIIIMITII=
7 MZEIMIIIIIIIIIIIIIIIIMIIIIIIIMI
4 MZE/M11111111111. 111 .11111111111. 1
=
7* Pre Check .111=1111111111.11.
Mill Post Check 111.1111111 **
pH Instrument ID: Annual Temperature Sensor Check Date: Analyst:
) Expected Buffer
pH Buffer Calibration or Actual pH Temp of Meter Slope, Date Date Opened Date Comments/Data Qualifiers/Equipment
Date Time Buffer pH 1 Vendor Buffer Lot#
Conc. Check J
(s.u.) Buffer°C mV(58±3) Received (In Use) Expires Maintenance
(s.u.). Name
10 Cal
7 Cal
4 Cal .
all 7* Pre Check
7* Post Check ___i___ **
pH Instrument ID: Annual Temperature Sensor Check Date: Analyst:
Expected BufferJ pH Buffer Calibration or Actual pH Temp of Meter Slope, Date Date Opened Date Comments/Data Qualifiers/Equipment
Date Time Conc. Buffer pH Vendor Buffer Lot#
Check (s.u.) Buffer*C _ mV(58±3) 1 Received (In Use) Expires Maintenance
{s.u.) I Name
10 Cal
,—
7 Cal I_
4 Cal
7* Pre Check
**
.
7* !Post Check
—
' t
*pH buffer checks are to be within±0.1 pH units of the standards true value.Report all data values to the nearest ±0.1 pH limit.
**In comments section,include indication of when the post-analysis calibration verification was performed(e.g.,time of analysis,end-of-day,etc.)
Troubleshooting:If the check buffer does not read within±0.1 s.u.,the lab should first try pouring a new aliquot of the check buffer and reading it again.If it still does not read within±0.1 s.u.,the meter must be recalibrated.
Possible corrective actions include:check the meter calibration procedure,refer to the troubleshooting section in the instrument manual,and check the buffers.If,after recalibration,the check buffer does not read within
±0.1 s.u.,the meter and/or probe operation may be suspect and may require servicing.If the laboratory does not have a back-up meter/electrode,or another meter/electrode cannot be procured,it is recommended
that the lab report the measured pH results with a qualifier that indicates the value is estimated.

CI 1(311 Anchor QEA of North Carolina,PLLC
lij PP CP liA(1('(„„,(3113--, 231 Haywood Street
Asheville,North Carolina 28801
E ui ment Documentation and Instrument Calibration Data Sheet
Project Name: Lassonde Pappas Spring 2022 WQ Monitoring Analyst Conducting Calibration: it
Project Number. C21482-01.01 Task 7 Date of Calibration:
Project Location: Hendersonville,NC Date of Field Measurements:
Facility ID or Permit#(if applicable): Permit No.WQ0004797
EQUIPMENT DOCUMENTATION
Rental sample analysis equipment or meters used to take measurements:
111==ral Brand Serial Number Date of Use Rental Company
, ,..
Select Turbidimeter ',,,, Hach 2100Q(s/n 151006045207)
HF Scientific MicroTPW(s/n 200601045)
—.....— . . ..Instrument Readings Instrument Readings ,-
(Hach 2100Q) (HF Scientific MicroTPW)
- _
Cal Std Information 10 NTU 20 NTU 100 NTU 800 NTU 1,000 NTU 10.0 NTU (1.02ATU
Lot#:,. h \A.,(n 'I ".',',— ' A i IA S'IL I'N ''''',. V
,....
Expiration Date ) '„) 5. .i ''''( `
Cal(NI , Cal(N)(y): *" Cal(N.ru),Cal), (1)11,1, „1, itt) Cal(NTU): .t Cal(NTU):
Time , Time:, , , Time: ,"" Time: Time. Time:
:
........„, ,
Calibration*Pre-Analysis Result(NTU):i Time: )))I') *Pre-Analysit' Result(NTU): Time:
1
Verification:Check(10 NTU): , , 7 ,7 () -7 -, Check flo NTU):
*Post-Analysis Result(NTU): Time: e" r.„, ,r*Post-Analysis Result(NTU): Time:
et
Check(10 NTU): Check(10 NTU):
,-- .-YSI Professional Plus Multiparameter Meter(sin 18B101802) . —
- .
Cal Std Information
Instrument Readings Date
Lot# Opened Exp.Date
. .
Dissolved Oxygen Initial(%): Cal(%): mmHg: Temperature(*C): Time:
(%saturation)
DO(Site#2, Initial(%): Cal(%): mmHg: Temperature(°C): Time:
mit arigidicable)*
Time: Result(96):, ,. Time:, ..t Result(%)' Time: Result(%):
QC°°Check:DO 1)1L....IL/ ()t 1 )
,
pH 7 S.U. Initial: pHmV: Cal(S.U.): pHmV: Time: :--
report to 0.7 S.U. _1 ,(,)
', ,7 ,1
.... .. ,„
pH 4 S.U. Initial: pHmV: et e Cal(S.U.): pHmV: Time:
report to 0.7 S.U. IC, CC
mm...m.2.2..., 0
pH 10 S.U. Initial: pHmV: tt Cal(.1,4 t, pHmV: , t: )2. Time:
report to 0.7 S.U.
* ,
QC**pH 7 S.U. Time:, , )„.i r) Result(Sy.): , Time:, , ....t Result(S.U.): Time: Result(S.U.):
report to O.7 S.U.
) ........" ...., ) I 1 .,
Spec.Cond. Initial: .. Cal(pmhos/cm)t Time: tt,
,.).i ,,)'
1,000 pmhosicm et C;) , ,,,t„ t., )(,)":
_ — —.
%Recove =
QV'Spec.Cond. Time: ) Result(pmhos/cm): Time: Result(pmhos/cm): Time: Result(pmhos/cm):
1,000 pmhos/cm (0)4))) t)))?: )10 ))) ) "t 11 ),,
) ' L.) '-..) '4 t (di(4 41.
%Recovery=
Initial:, Cal: , i ) Temperature(°C): Time:
ORP 200 mV )t,i,e (), !)(')( ) ,,' .) c , -
E)) ,
/ ,,' '
Analyst Signature: t". /A / ),(/'0 It i'j Analyst Name: '1 ( i )i' ,
)V(.„(),(,-')
) Date:1),
Notes:
Revision 6,12/20/20,MAK
1.Instruments shall be calibrated in accordance with the manufacturer's operation manual.
2.Specific Conductivity should be calibrated according to values representative of historic range.
3.Order of Calibration is as follows:Specific Conductivity,pH 7,pH 4,pH 10,DO,ORP,QC checks.
4.'When performing DO analyses at multiple sample sites(i.e.project/facility locations),the DO probe must be calibrated at each sample site prior to analysis.
5.QC Acceptable Ranges:pH+/-0.1 S.U.and Specific Conductivity 10%of the true value.If QC readings are out of range,the instrument needs to be recalibrated.
6.°°QC check must be performed prior to sampling and following completion of sampling,at a minimum.QC checks must be performed with calibration standard from a separate lot#as the initial QC.
7.%Recovery=(Value Obtained,µmhos/cm÷True Value,µmhos/cm)x 100
8.NC Field Laboratory Certificate Number 5445
9.Documentation errors are to be crossed out with a single line,so the original text is still legible,followed by the staff members initials and date
10.Unless otherwise noted,all DO calibrations and measurements are performed at 0 ppt Salinity.
11.1 timho/crn=1 tiSicm
Abbreviations: Method Reference:
µmhos/cm:micromhos per centimeter NTU:nephelometric turbidity units Temperature:SM 2550 B-2010
°C:degrees Celsius ORP:oxidation reduction potential Specific conductivity EPA Method 120 1,Rev.1982
DO:dissolved oxygen s/n:serial number DO:SM 4500 0 G-2011
mg/L:milligrams per liter S.U.:standard units pH:SM 4500-H.B-2011
mV:millivolt Spec.Cond.:Specific Conductivity Turbidity SM 2130 8-2011
Page 1 of 1

ttac nt
R 0 -5 ' — o • Iianc - - • ort For

SUBMIT FORM ON YELLOW PAPER ONLY
Mail original DEPARTMENT OF ENVIRONMENTAL QUALITY-DIV.OF WATER RESOURCES
GROUNDWATER QUALITY MONITORING: INFORMATION PROCESSING UNIT
COMPLIANCE REPORT FORM and 1 copy to: 1617 MAIL SERVICE CENTER,RALEIGH,NC27699-1617
FACILITY INFORMATION Please Print Clearly or Type PERMIT Number: Expiration Date: 7/31/2026
Facility Name: Clement Pappas Non-Discharge W00004797 UIC
Permit Name(if different): NPDES Other
Facility Address: 485 Brookside Camp Road TYPE OF PERMITTED OPERATION BEING MONITORED
Hendersonville NC 28792 County Henderson ❑ Lagoon ❑ Remediation: Infiltration Gallery
❑■ Spray Field ❑ Remediation:
Contact Person: Blake Kehoe Telephone#: [phone] ❑ Rotary Distributor ❑ Land Application of Sludge
Well Location/Site Name:Irrigation Area No. of wells to be sampled: 6 ❑ Water Source Heat Pump ❑ Other:
(from Permit)
SAMPLING INFORMATION If WELL
WELL ID NUMBER(from Permit): MW-4 Date sample collected: 5/10/2022 FIELD ANALYSES: WAS
Well Depth: 18.17 ft. Well Diameter: 2 in. pH 00400: 5.8 units Temp. 0o010: 16.1 °C DRY at
Depth to Water Level 82546:9.14 ft. below measuring point Screened Interval: 5 ft. to 15 ft. Spec.Cond. 00094: 229.7 µMhos time of
sampling,
Measuring Point is 2.43 ft. above land surface Relative M.P. Elevation: 2063.77 ft. Odor 00085. none check
Volume of water pumped/bailed before sampling: 1.11 gallons Appearance here:n
Samples for metals were collected unfiltered: •YES ❑ NO and field acidified: .YES YES ❑ NO
LABORATORY INFORMATION
Date sample analyzed:5/11/2022 Laboratory Name: Pace Analytical Services Certification No. 37712
PARAMETERS NOTE:Values should reflect dissolved and colloidal concentrations.
COD 00335 mg/L Nitrite(NO2) as N oos15 mg/L Pb-Lead 01051 ug/L
Coliform: MF Fecal 31616 <1.0 /100mL Nitrate(NO3) as N o0620 0.46 mg/L Zn-Zinc 01092 mg/L
Coliform: MF Total 31504 /100mL Phosphorus:Total as P oo665 0.063 mg/L
(Note: Use MPN method for highly turbid samples) Orthophosphate 70507 mg/L Other(Specify Compounds and Concentration Units):
Dissolved Solids:Total 70300 136 mg/L Al-Aluminum o1105 mg/L
pH (Lab) 00403 units Ba-Barium o1007 ug/L
TOC 00680 2.9 mg/L Ca-Calcium 00916 mg/L
Chloride 00940 6.8 mg/L Cd-Cadmium 01027 ug/L
Arsenic 01002 ug/L Chromium:Total 01034 ug/L
Grease and Oils 00552 mg/L Cu-Copper 01042 mg/L ORGANICS: (by GC, GC/MS, HPLC)
Phenol 32730 ug/L Fe-Iron o1045 ug/L (Specify test and method#.ATTACH LAB REPORT.)
Sulfate 00945 mg/L Hg-Mercury 71900 ug/L Lab Report Attached? ❑■ Yes (1) ❑ No (0)
Specific Conductance 00095 µMhos K-Potassium 00937 mg/L VOC 7873 , method#
Total Ammonia 00610 <0.10 mg/L Mg-Magnesium 00927 mg/L , method#
(Ammonia Nitrogen,NH3as N,Ammonia Nitrogen,Total) Mn-Manganese o1 oss ug/L , method#
TKN as N 00625 mg/L Ni-Nickel 01067 ug/L , method#
For Remediation Systems Only(Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal%
I certify that,to the best of my knowledge and belief,the information submitted in this report is true,accurate,and complete,and that the laboratory analytical data was produced using approved methods of analysis by a
DWR-certified laboratory. I am aware that there are significant penalties for submitting false information,including the possibility of fines and imprisonment for knowing violations.
Blake Kehoe, Director Engineering Blake Kehoe 06/23/2022
Permittee(or Authorized Agent)Name and Title-Please print or type Signature of Permittee(or Authorized Agent) (Date)
GW-59 Rev.06-07-2018

SUBMIT FORM ON YELLOW PAPER ONLY
Mail original DEPARTMENT OF ENVIRONMENTAL QUALITY-DIV.OF WATER RESOURCES
GROUNDWATER QUALITY MONITORING: INFORMATION PROCESSING UNIT
COMPLIANCE REPORT FORM and 1 copy to: 1617 MAIL SERVICE CENTER,RALEIGH,NC27699-1617
FACILITY INFORMATION Please Print Clearly or Type PERMIT Number: Expiration Date: 7/31/2026
Facility Name: Clement Pappas Non-Discharge W00004797 UIC
Permit Name(if different): NPDES Other
Facility Address: 485 Brookside Camp Road TYPE OF PERMITTED OPERATION BEING MONITORED
Hendersonville NC 28792 County Henderson ❑ Lagoon ❑ Remediation: Infiltration Gallery
❑■ Spray Field ❑ Remediation:
Contact Person: Blake Kehoe Telephone#: [phone] ❑ Rotary Distributor ❑ Land Application of Sludge
Well Location/Site Name:Irrigation Area No. of wells to be sampled: 6 ❑ Water Source Heat Pump ❑ Other:
(from Permit)
SAMPLING INFORMATION If WELL
WELL ID NUMBER(from Permit): MW 5 Date sample collected: 5/10/2022 FIELD ANALYSES: WAS
Well Depth: 18.58 ft. Well Diameter: 2 in. pH 00400: 5.6 units Temp. 0o010: 14.5 °C DRY at
Depth to Water Level 82546:9.15 ft. below measuring point Screened Interval: 9 ft. to 19 ft. Spec.Cond. 00094: 228.2 µMhos time of
sampling,
Measuring Point is 3.00 ft. above land surface Relative M.P. Elevation: 2085.60 ft. Odor 00085. none check
Volume of water pumped/bailed before sampling: 0.59 gallons Appearance here:n
Samples for metals were collected unfiltered: •YES ❑ NO and field acidified: .YES YES ❑ NO
LABORATORY INFORMATION
Date sample analyzed:5/11/2022 Laboratory Name: Pace Analytical Services Certification No. 37712
PARAMETERS NOTE:Values should reflect dissolved and colloidal concentrations.
COD 00335 mg/L Nitrite(NO2) as N oos15 mg/L Pb-Lead 01051 ug/L
Coliform: MF Fecal 31616 <1.0 /100mL Nitrate(NO3) as N o0620 0.10 mg/L Zn-Zinc 01092 mg/L
Coliform: MF Total 31504 /100mL Phosphorus:Total as P oo665 <0.050 mg/L
(Note: Use MPN method for highly turbid samples) Orthophosphate 70507 mg/L Other(Specify Compounds and Concentration Units):
Dissolved Solids:Total 70300 158 mg/L Al-Aluminum o1105 mg/L
pH (Lab) 00403 units Ba-Barium o1007 ug/L
TOC 00680 2.7 mg/L Ca-Calcium 00916 mg/L
Chloride 00940 49.0 mg/L Cd-Cadmium 01027 ug/L
Arsenic 01002 ug/L Chromium:Total 01034 ug/L
Grease and Oils 00552 mg/L Cu-Copper 01042 mg/L ORGANICS: (by GC, GC/MS, HPLC)
Phenol 32730 ug/L Fe-Iron o1045 ug/L (Specify test and method#.ATTACH LAB REPORT.)
Sulfate 00945 mg/L Hg-Mercury 71900 ug/L Lab Report Attached? ❑■ Yes (1) ❑ No (0)
Specific Conductance 00095 µMhos K-Potassium 00937 mg/L VOC 7873 , method#
Total Ammonia 00610 <0.10 mg/L Mg-Magnesium 00927 mg/L , method#
(Ammonia Nitrogen,NH3as N,Ammonia Nitrogen,Total) Mn-Manganese o1 oss ug/L , method#
TKN as N 00625 mg/L Ni-Nickel 01067 ug/L , method#
For Remediation Systems Only(Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal%
I certify that,to the best of my knowledge and belief,the information submitted in this report is true,accurate,and complete,and that the laboratory analytical data was produced using approved methods of analysis by a
DWR-certified laboratory. I am aware that there are significant penalties for submitting false information,including the possibility of fines and imprisonment for knowing violations.
Blake Kehoe, Director Engineering Blake Kehoe aoo 06/23/2022
Permittee(or Authorized Agent)Name and Title-Please print or type Signature of Permittee(or Authorized Agent) (Date)
GW-59 Rev.06-07-2018

SUBMIT FORM ON YELLOW PAPER ONLY
Mail original DEPARTMENT OF ENVIRONMENTAL QUALITY-DIV.OF WATER RESOURCES
GROUNDWATER QUALITY MONITORING: INFORMATION PROCESSING UNIT
COMPLIANCE REPORT FORM and 1 copy to: 1617 MAIL SERVICE CENTER,RALEIGH,NC27699-1617
FACILITY INFORMATION Please Print Clearly or Type PERMIT Number: Expiration Date: 7/31/2026
Facility Name: Clement Pappas Non-Discharge W00004797 UIC
Permit Name(if different): NPDES Other
Facility Address: 485 Brookside Camp Road TYPE OF PERMITTED OPERATION BEING MONITORED
Hendersonville NC 28792 County Henderson ❑ Lagoon ❑ Remediation: Infiltration Gallery
❑■ Spray Field ❑ Remediation:
Contact Person: Blake Kehoe Telephone#: [phone] ❑ Rotary Distributor ❑ Land Application of Sludge
Well Location/Site Name:Irrigation Area No. of wells to be sampled: 6 ❑ Water Source Heat Pump ❑ Other:
(from Permit)
SAMPLING INFORMATION If WELL
WELL ID NUMBER(from Permit): MW-6 Date sample collected: 5/10/2022 FIELD ANALYSES: WAS
Well Depth: 11.58 ft. Well Diameter: 2 in. pH 00400: 5.4 units Temp. 0o010: 17.1 °C DRY at
Depth to Water Level 82546:5.91 ft. below measuring point Screened Interval: 5 ft. to 10 ft. Spec.Cond. 00094: 157.6 µMhos time of
sampling,
Measuring Point is 3.00 ft. above land surface Relative M.P. Elevation: 2061.17 ft. Odor 00085. none check
Volume of water pumped/bailed before sampling: 2.38 gallons Appearance here:n
Samples for metals were collected unfiltered: •YES ❑ NO and field acidified: .YES YES ❑ NO
LABORATORY INFORMATION
Date sample analyzed:5/11/2022 Laboratory Name: Pace Analytical Services Certification No. 37712
PARAMETERS NOTE:Values should reflect dissolved and colloidal concentrations.
COD 00335 mg/L Nitrite(NO2) as N oos15 mg/L Pb-Lead 01051 ug/L
Coliform: MF Fecal 31616 < 1.0 /100mL Nitrate(NO3) as N 00620 <0.040 mg/L Zn-Zinc 01092 mg/L
Coliform: MF Total 31504 /100mL Phosphorus:Total as P oo665 <0.050 mg/L
(Note: Use MPN method for highly turbid samples) Orthophosphate 70507 mg/L Other(Specify Compounds and Concentration Units):
Dissolved Solids:Total 70300 96.0 mg/L Al-Aluminum o1105 mg/L
pH (Lab) 00403 units Ba-Barium 01007 ug/L
TOC 00680 1.5 mg/L Ca-Calcium 00916 mg/L
Chloride 00940 13.6 mg/L Cd-Cadmium 01027 ug/L
Arsenic 01002 ug/L Chromium:Total 01034 ug/L
Grease and Oils 00552 mg/L Cu-Copper 01042 mg/L ORGANICS: (by GC, GC/MS, HPLC)
Phenol 32730 ug/L Fe-Iron o1045 ug/L (Specify test and method#.ATTACH LAB REPORT.)
Sulfate 00945 mg/L Hg-Mercury 71900 ug/L Lab Report Attached? ❑■ Yes (1) ❑ No (0)
Specific Conductance 00095 µMhos K-Potassium 00937 mg/L VOC 7873 , method#
Total Ammonia 00610 <0.10 mg/L Mg-Magnesium 00927 mg/L , method#
(Ammonia Nitrogen,NH3as N,Ammonia Nitrogen,Total) Mn-Manganese o1 oss ug/L , method#
TKN as N 00625 mg/L Ni-Nickel 01067 ug/L , method#
For Remediation Systems Only(Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal%
I certify that,to the best of my knowledge and belief,the information submitted in this report is true,accurate,and complete,and that the laboratory analytical data was produced using approved methods of analysis by a
DWR-certified laboratory. I am aware that there are significant penalties for submitting false information,including the possibility of fines and imprisonment for knowing violations.
Blake Kehoe, Director Engineering Blake Kehoe -0aaa 06/23/2022
Date HU a e Permittee(or Authorized Agent)Name and Title-Please print or type Signature of Permittee(or Authorized Agent) (Date)
GW-59 Rev.06-07-2018

SUBMIT FORM ON YELLOW PAPER ONLY
Mail original DEPARTMENT OF ENVIRONMENTAL QUALITY-DIV.OF WATER RESOURCES
GROUNDWATER QUALITY MONITORING: INFORMATION PROCESSING UNIT
COMPLIANCE REPORT FORM and 1 copy to: 1617 MAIL SERVICE CENTER,RALEIGH,NC27699-1617
FACILITY INFORMATION Please Print Clearly or Type PERMIT Number: Expiration Date: 7/31/2026
Facility Name: Clement Pappas Non-Discharge W00004797 UIC
Permit Name(if different): NPDES Other
Facility Address: 485 Brookside Camp Road TYPE OF PERMITTED OPERATION BEING MONITORED
Hendersonville NC 28792 County Henderson ❑ Lagoon ❑ Remediation: Infiltration Gallery
❑■ Spray Field ❑ Remediation:
Contact Person: Blake Kehoe Telephone#: [phone] ❑ Rotary Distributor ❑ Land Application of Sludge
Well Location/Site Name:Irrigation AreaO No. of wells to be sampled: 6 ❑ Water Source Heat Pump ❑ Other:
(from Permit)
SAMPLING INFORMATION If WELL
WELL ID NUMBER(from Permit): MW-7R Date sample collected: 5/10/2022 FIELD ANALYSES: WAS
Well Depth: 17.29 ft. Well Diameter: 2 in. pH 00400: 5.1 units Temp. 0o010: 14.1 °C DRY at
Depth to Water Level 82546:11.66 ft. below measuring point Screened Interval: 5 ft. to 15 ft. Spec.Cond. 00094: 393.3 µMhos time of
sampling,
Measuring Point is 3.00 ft. above land surface Relative M.P. Elevation: 2062.86 ft. Odor 00085. none check
Volume of water pumped/bailed before sampling: 1.98 gallons Appearance here:n
Samples for metals were collected unfiltered: •YES ❑ NO and field acidified: .YES YES ❑ NO
LABORATORY INFORMATION
Date sample analyzed:5/11/2022 Laboratory Name: Pace Analytical Services Certification No. 37712
PARAMETERS NOTE:Values should reflect dissolved and colloidal concentrations.
COD 00335 mg/L Nitrite(NO2) as N oos15 mg/L Pb-Lead 01051 ug/L
Coliform: MF Fecal 31616 <1.0 /100mL Nitrate(NO3) as N 00620 31.0 mg/L Zn-Zinc 01092 mg/L
Coliform: MF Total 31504 /100mL Phosphorus:Total as P oo665 <0.050 mg/L
(Note: Use MPN method for highly turbid samples) Orthophosphate 70507 mg/L Other(Specify Compounds and Concentration Units):
Dissolved Solids:Total 70300 279 mg/L Al-Aluminum o1105 mg/L
pH (Lab) 00403 units Ba-Barium 01007 ug/L
TOC 00680 <1.0 mg/L Ca-Calcium 00916 mg/L
Chloride 00940 30.8 mg/L Cd-Cadmium 01027 ug/L
Arsenic o1002 ug/L Chromium:Total 01034 ug/L
Grease and Oils 00552 mg/L Cu-Copper 01042 mg/L ORGANICS: (by GC, GC/MS, HPLC)
Phenol 32730 ug/L Fe-Iron 01045 ug/L (Specify test and method#.ATTACH LAB REPORT.)
Sulfate 00945 mg/L Hg-Mercury 71900 ug/L Lab Report Attached? ❑■ Yes (1) ❑ No (0)
Specific Conductance 00095 µMhos K-Potassium 00937 mg/L VOC 7873 , method#
Total Ammonia 00610 <0.10 mg/L Mg-Magnesium 00927 mg/L , method#
(Ammonia Nitrogen,NH3as N,Ammonia Nitrogen,Total) Mn-Manganese o1055 ug/L , method#
TKN as N 00625 mg/L Ni-Nickel 01067 ug/L , method#
For Remediation Systems Only(Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal%
I certify that,to the best of my knowledge and belief,the information submitted in this report is true,accurate,and complete,and that the laboratory analytical data was produced using approved methods of analysis by a
DWR-certified laboratory. I am aware that there are significant penalties for submitting false information,including the possibility of fines and imprisonment for knowing violations.
Blake Kehoe, Director Engineering Blake Kehoe a::,,,.,,,,,.. 06/23/2022
Permittee(or Authorized Agent)Name and Title-Please print or type Signature of Permittee(or Authorized Agent) (Date)
GW-59 Rev.06-07-2018

SUBMIT FORM ON YELLOW PAPER ONLY
Mail original DEPARTMENT OF ENVIRONMENTAL QUALITY-DIV.OF WATER RESOURCES
GROUNDWATER QUALITY MONITORING: INFORMATION PROCESSING UNIT
COMPLIANCE REPORT FORM and 1 copy to: 1617 MAIL SERVICE CENTER,RALEIGH,NC27699-1617
FACILITY INFORMATION Please Print Clearly or Type PERMIT Number: Expiration Date: 7/31/2026
Facility Name: Clement Pappas Non-Discharge W00004797 UIC
Permit Name(if different): NPDES Other
Facility Address: 485 Brookside Camp Road TYPE OF PERMITTED OPERATION BEING MONITORED
Hendersonville NC 28792 County Henderson ❑ Lagoon ❑ Remediation: Infiltration Gallery
❑■ Spray Field ❑ Remediation:
Contact Person: Blake Kehoe Telephone#: [phone] ❑ Rotary Distributor ❑ Land Application of Sludge
Well Location/Site Name:Irrigation Area No. of wells to be sampled: 6 ❑ Water Source Heat Pump ❑ Other:
(from Permit)
SAMPLING INFORMATION If WELL
WELL ID NUMBER(from Permit): MW-8 Date sample collected: 5/10/2022 FIELD ANALYSES: WAS
Well Depth: 13.91 ft. Well Diameter: 2 in. pH 00400: 6.7 units Temp. 0o010: 12.8 °C DRY at
Depth to Water Level 82546:10.02 ft. below measuring point Screened Interval: 3 ft. to 13 ft. Spec.Cond. 00094: 407.9 µMhos time of
sampling,
Measuring Point is 3.00 ft. above land surface Relative M.P. Elevation: 2060.80 ft. Odor 00085. none check
Volume of water pumped/bailed before sampling: 1.11 gallons Appearance here:n
Samples for metals were collected unfiltered: •YES ❑ NO and field acidified: .YES YES ❑ NO
LABORATORY INFORMATION
Date sample analyzed:5/11/2021 Laboratory Name: Pace Analytical Services Certification No. 37712
PARAMETERS NOTE:Values should reflect dissolved and colloidal concentrations.
COD 00335 mg/L Nitrite(NO2) as N oos15 mg/L Pb-Lead 01051 ug/L
Coliform: MF Fecal 31616 <1.0 /100mL Nitrate(NO3) as N 00620 3.2 mg/L Zn-Zinc 01092 mg/L
Coliform: MF Total 31504 /100mL Phosphorus:Total as P oo665 <0.050 mg/L
(Note: Use MPN method for highly turbid samples) Orthophosphate 70507 mg/L Other(Specify Compounds and Concentration Units):
Dissolved Solids:Total 70300 240 mg/L Al-Aluminum o1105 mg/L
pH (Lab) 00403 units Ba-Barium 01007 ug/L
TOC 00680 4.5 mg/L Ca-Calcium 00916 mg/L
Chloride 00940 7.4 mg/L Cd-Cadmium 01027 ug/L
Arsenic 01002 ug/L Chromium:Total 01034 ug/L
Grease and Oils 00552 mg/L Cu-Copper 01042 mg/L ORGANICS: (by GC, GC/MS, HPLC)
Phenol 32730 ug/L Fe-Iron 01045 ug/L (Specify test and method#.ATTACH LAB REPORT.)
Sulfate 00945 mg/L Hg-Mercury 71900 ug/L Lab Report Attached? ❑■ Yes (1) ❑ No (0)
Specific Conductance 00095 µMhos K-Potassium 00937 mg/L VOC 7873 , method#
Total Ammonia 00610 <0.10 mg/L Mg-Magnesium 00927 mg/L , method#
(Ammonia Nitrogen,NH3as N,Ammonia Nitrogen,Total) Mn-Manganese o1 oss ug/L , method#
TKN as N 00625 mg/L Ni-Nickel 01067 ug/L , method#
For Remediation Systems Only(Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal%
I certify that,to the best of my knowledge and belief,the information submitted in this report is true,accurate,and complete,and that the laboratory analytical data was produced using approved methods of analysis by a
DWR-certified laboratory. I am aware that there are significant penalties for submitting false information,including the possibility of fines and imprisonment for knowing violations.
Blake Kehoe, Director Engineering Blake Kehoe aoo 06/23/2022
Permittee(or Authorized Agent)Name and Title-Please print or type Signature of Permittee(or Authorized Agent) (Date)
GW-59 Rev.06-07-2018

SUBMIT FORM ON YELLOW PAPER ONLY
Mail original DEPARTMENT OF ENVIRONMENTAL QUALITY-DIV.OF WATER RESOURCES
GROUNDWATER QUALITY MONITORING: INFORMATION PROCESSING UNIT
COMPLIANCE REPORT FORM and 1 copy to: 1617 MAIL SERVICE CENTER,RALEIGH,NC27699-1617
FACILITY INFORMATION Please Print Clearly or Type PERMIT Number: Expiration Date: 7/31/2026
Facility Name: Clement Pappas Non-Discharge W00004797 UIC
Permit Name(if different): NPDES Other
Facility Address: 485 Brookside Camp Road TYPE OF PERMITTED OPERATION BEING MONITORED
Hendersonville NC 28792 County Henderson ❑ Lagoon ❑ Remediation: Infiltration Gallery
❑■ Spray Field ❑ Remediation:
Contact Person: Blake Kehoe Telephone#: [phone] ❑ Rotary Distributor ❑ Land Application of Sludge
Well Location/Site Name:Irrigation Area No. of wells to be sampled: 6 ❑ Water Source Heat Pump ❑ Other:
(from Permit)
SAMPLING INFORMATION If WELL
WELL ID NUMBER(from Permit): MW-9 Date sample collected: 5/10/2022 FIELD ANALYSES: WAS
Well Depth: 18.12 ft. Well Diameter: 2 in. pH 00400: 5.4 units Temp. 0o010: 119 °C DRY at
Depth to Water Level 82546:5.70 ft. below measuring point Screened Interval: 6 ft. to 16 ft. Spec.Cond. 00094: 99.0 µMhos time of
sampling,
Measuring Point is 1.44 ft. above land surface Relative M.P. Elevation: 2060.23 ft. Odor 00085. none check
Volume of water pumped/bailed before sampling: 1.11 gallons Appearance here:n
Samples for metals were collected unfiltered: •YES ❑ NO and field acidified: .YES YES ❑ NO
LABORATORY INFORMATION
Date sample analyzed:10/27/2021 Laboratory Name: Pace Analytical Services Certification No. 37712
PARAMETERS NOTE:Values should reflect dissolved and colloidal concentrations.
COD 00335 mg/L Nitrite(NO2) as N oos15 mg/L Pb-Lead 01051 ug/L
Coliform: MF Fecal 31616 <1.0 /100mL Nitrate(NO3) as N 00620 1.5 mg/L Zn-Zinc 01092 mg/L
Coliform: MF Total 31504 /100mL Phosphorus:Total as P oo665 0.086 mg/L
(Note: Use MPN method for highly turbid samples) Orthophosphate 70507 mg/L Other(Specify Compounds and Concentration Units):
Dissolved Solids:Total 70300 67.0 mg/L Al-Aluminum o1105 mg/L
pH (Lab) 00403 units Ba-Barium 01007 ug/L
TOC 00680 3.6 mg/L Ca-Calcium 00916 mg/L
Chloride 00940 6.3 mg/L Cd-Cadmium 01027 ug/L
Arsenic 01002 ug/L Chromium:Total 01034 ug/L
Grease and Oils 00552 mg/L Cu-Copper 01042 mg/L ORGANICS: (by GC, GC/MS, HPLC)
Phenol 32730 ug/L Fe-Iron 01045 ug/L (Specify test and method#.ATTACH LAB REPORT.)
Sulfate 00945 mg/L Hg-Mercury 71900 ug/L Lab Report Attached? ❑■ Yes (1) ❑ No (0)
Specific Conductance 00095 µMhos K-Potassium 00937 mg/L VOC 7873 , method#
Total Ammonia 00610 <0.10 mg/L Mg-Magnesium 00927 mg/L , method#
(Ammonia Nitrogen,NH3as N,Ammonia Nitrogen,Total) Mn-Manganese o1 oss ug/L , method#
TKN as N 00625 mg/L Ni-Nickel 01067 ug/L , method#
For Remediation Systems Only(Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal%
I certify that,to the best of my knowledge and belief,the information submitted in this report is true,accurate,and complete,and that the laboratory analytical data was produced using approved methods of analysis by a
DWR-certified laboratory. I am aware that there are significant penalties for submitting false information,including the possibility of fines and imprisonment for knowing violations.
Blake Kehoe, Director Engineering Blake Kehoe ;:,j..;k03'oa° 3' ` "`""M"'""°"°"° 06/23/2022
Permittee(or Authorized Agent)Name and Title-Please print or type Signature of Permittee(or Authorized Agent) (Date)
GW-59 Rev.06-07-2018

ttac nt 5
R 0 - 5 • — roun • at r • uality
onitorin • : o • Iianc - - • ort For s

GVIV-59A COMPLIANCE la :POUT F+"ORM Permit i WQ0004797
(Suimtit 0na'erar:°It monitoring period with GW-59 i •nz)
1 Enter date monitoring results were due.( 06/30/2022 ) Will this monitoring report(GW-59 and GW-59A) YES NO
be submitted after the established due date? X
2 Was any required information missing on the GW-59 report forms? YES NO
IF the answer to question 1 or 2 is"YES", list in the space provided below the well identification number(s)and XX
explain the problems encountered in obtaining the required information.
3 Are any of the monitor wells in need of repair or maintenance(damaged casing,unlocked or missing cap,missing YES NO
identification plate,area overgrown,etc.)?If the answer is "Yes", contact the Regional Office for guidance. X
4 Are any monitored constituents equal to or above the established standards? YYS NO
If the answer to question 4 is"NO", skip to section 8.
If the answer to question 4 is"YES"list the affected wells individually with constituent(s)and concentration(s)
exceeding standards in the space provided below:
Nitrate(2L= 10mg/L):MW-7R@ 31.0 mg/L •
5 For the constituents identified in question 4 above, have standards been exceeded previously for the YES NO
same constituent(s)in the same well(s)in the last two years? X
If the answer to question 5 is"NO", skip to section 8.
If the answer to question 5 is "YES",list in the space provided below, each well with constituent(s)exceeding
standards, concentration(s)reported, and sample collection date for each occurrence(for the last two years).
Nitrate MW-7R(mg/L) 11/14/19 05/06/20 11/06/20 05/11/21 10/27/21
17.1 mg/L 21.5 mg/L 13.0 mg/L 40.4 mg/L 26.0 mg/L
6 Are the monitoring wells listed in section 5 located at or beyond the review boundary? YES NO
X
If the answer is"YES",a groundwater quality problem maybe occurring. CONTACT THE REGIONAL
OFFICE IMMEDIATELY FOR GUIDANCE.If the answer is"NO", monitoring wells may be improperly
located;contact the Regional Office.
7 Is the permittee implementing previously approved actions required by the Division involving this YES NO
groundwater quality problem? MW-7R is at or beyond the review boundary. X
If the answer to question 7 is"YES", describe those actions in the space provided below.
If the answer to question 7 is"NO",contact the Regional Office within 90 days;an evaluation may be
required to determine the impact the waste disposal system is having at the review and compliance
boundaries surrounding this facility. Failure to do so may subject the permittee to a Notice of Violation,
fines,and/or penalties.
Elevated nitrate concentrations are likely due to root growth and decay of a dense mass of root matter found in MW-7R,during monitoring well evaluation
in September 2021.Per recommendations from the Regional Office,chlorination and redevelopment of MW-7R was performed prior to the
May 2022 sampling event.However,the concentration of nitrate in the sample collected from MW-7R during the Spring 2022 sampling event remained above
the permit standard.The root mass on the outside of the casing and within the sand pack may be continuing to leach nitrogen as organic matter decays.
Per a discussion regarding the results with DEQ Hydrogeologist,Brett Laverty on 6/7/2022,Anchor QEA will continue to monitor nitrate concentrations
to determine if further action is needed.
8 The person completing this portion(GW-59A)of the monitoring report should sign below and submit this
form with GW-59 forms for required wells to the address provided at the top of the current GW-59 form.
I hereby acknowledge that the above information was evaluated and the information submitted in this
report(Compliance Report GW-59A)is true and complete to the best of my knowledge.
Blake Kehoe ' 06/23/2022
Signature of Permittee(or Authorized Agent) Date
GW '-59A I2/8/2.003