WQ0002638_Groundwater Well_20071107

NC DWQ Laboratory Section Results
County: HARNETT
River Basin
Report To FROAP
Collector. B TODD
Region: FRO
Sample Matrix: GROUNDWATER
Loc. Type: MONITORING WELL
Emergency Yes/No
COC Yes/No
YES
VisitID
Loc. Descr • TOWN OF ANGIER
Sample ID:
PO Number#
Date Received: .
Time Received:
Labworks LoginlD
Date Reported:
Report Generated:
Location ID:
6PWQ000263843
Collect Date:
11/06/2007
Collect Time:: 10:15
Sample Depth
AB23617
7G0845
11/07/2007
11:40
MMATHIS
11/19/07
11/19/2007
Sample Qualifiers and Comments
Routine Qualifiers ,
For a more detailed description of these qualifier codes -refer to www.dwglab.org.under Staff Access
A -Value reported is the average of two or more determinations
B1-Countable membranes with <20 colonies; Estimated
B2- Counts from all filters were zero.
B3- Countable membranes with more than 60 or 80 colonies; Estimated
B4-Filters have counts of both >60 or 80 and < 20; Estimated
B5-Too many colonies were present; 'too numerous to count (TNTC)
J2- Reported value failed to meet QC criteria for either precision or accuracy; Estimated
• J3-The sample matrix interfered with the ability to'make any accurate determination; Estimated
J6-The lab analysis was from an unpreserved or improperly chemically preserved sample; Estimated
N1-The component has been tentatively identified based on mass spectral library search and has an estimated value
N3-Estimated concentration is < PQL and >MDL NE -No established PQL
P-Elevated PQL due to matrix interference and/or sample dilution
- Q1-Holding time exceeded prior to receipt at lab. •
Q2- Holding time exceeded following receipt by lab
PQL- Practical Quantitation Limit -subject to change due to instrument sensitivity
U- Samples analyzed for this compound but not detected
X1- Sample not analyzed for this compound
LAB
• Laboratory Section» 1623 Mail Service Center, Raleigh, NC 27699-1623 [phone]
Page 1 of 2

Sample ID AB23617
Location ID: . 6PWQ000263843
Loc. Descr.: TOWN OF ANGIER.
e
Visit ID
NC DWQ £a6oratory Section Results
Collect Date:
Collect Time::
11/06/2007
10:15
CAS #
Analyte Name
PQL
Result Qualifier Units
Analyst/Date
Approved By /Date
Sample temperature at receipt by lab
Method Reference
1.9
°C
MMATHIS
11/7/07
JGOODWIN
11/8/07
MIC.
TOC In Ilquld
Method Reference
APHA5310B-20th
2.0
2 U mg/L BSWANSON MOVERMAN
11/14/07 11/19/07
WET
Ion Chromatography
Method Reference
EPA 300.0
_TITLE_ mg/L MIBRAHIM MOVERMAN
11/7/07 - 11/9/07
Total Dissolved Solids In Ilquld 12 92 mg/L - JSTALEY
Method Reference APHA2540C-18TH 11/9/07
CGREEN
11/14/07
Chloride -
Method Reference EPA300.0
1.0
26 - mg/L MIBRAHIM MOVERMAN
11/7/07 11/9/07
Fluoride 0.4 0.4 U mg/L MIBRAHIM -MOVERMAN
Method Reference EPA 300.0 11/7/07 11/9/07
Sulfate 2.0 8.3 mg/L MIBRAHIM MOVERMAN
Method Reference EPA 300.0
11/7/07 11/9/07
NUT
NH3 as N In Ilquld
Method Reference ,Lac10-107-06.1-J
0.02 0.02 U mg/L as N MOVERMAN CGREEN
11/8/07 11/14/07
NO2+NO3 as. N In liquid 0.02 , 1.2 mg/L as N MOVERMAN
Method Reference Lac10-107-04-1-c 11/8/07
CGREEN
11/14/07
Phosphorus total as P In Ilquld 0.02 0.17 mg/L as P _ MAJAYI CGREEN
Method Reference Lac10-115-01-1EF 11/9/07 11/14/07
Nitrate as N In Ilquld 0.02 1.2 mg/L as N MOVERMAN CGREEN
Method Reference Lachat107-04-1-c 11/9/07 11/14/07
Nitrite as N In Ilquld
Method Reference
Lachat107-04-1-c
0.01..
0.01 U mg/L as N MAJAYI CGREEN
t ' 11/7/07 11/9/07
•
Laboratory Section» 1623 Mail Service Center, Raleigh, NC 27699-1623 [phone] Page 2 of 2

GROUNDWATER FIELD/LAB FORM
Location code 6/PNVQ0002638/43
County Harnett
Quad No Serial No.
Lat. Long.
Report To: ARO,MRO, RRO, WaRO, WiRO,
WSRO, Kinston FO Fed. Trust, Central Off., Other:
Shipped by: Busouried Hand Del., Other:
C of lector(s):_B it lTodd
FIELD A AJ YSES
pH.400 6
°C
Appearance16412444�:-iez„�t:1
Temp.10
Field Analysis
By:_BillTodd
LABORATORY ANALYSES
SAMPLE TYPE
Xi Water
❑ Soil
0 Other
gi Chain of Custody
'SAMPLE PRIORITY
Routine
1.!.
Emergency
Purpose:
Time /6;/ J- *) Baseline, Complaint, Compliance LUST, Pesticide Study, Federal Trust, Other:
(circle one)
Owner ' 7 )L yst D i Al i•gn
Date /% % C 7
North Carolina
Department of Environment and Natural Resources
DIVISION OF WATER QUALITY -GROUNDWATER SECTION
Lab Number V n
Date Received. v ' Time: f / Y-6
Rec'd By: � From:Bus, .. Hand Del.,
Other:
Data Entry By:
Date Reported:
Ck:
Spec. Cond.94 at 25°C
Location or Site -6 • 4:f D firV
Odor /I/ id-e Description of sampling point LaLJ e 1 / Iti�Z,4
BOD 310
mg/L
COD High 340
mg/L
COD Low 335
mg/L
Coliform: MF Fecal 31616
/10om1
Coliform: MF Total 31504
/10om1
X
TOC 680
mg/L
Turbidity 76
NTU
Residue, Suspended 530
mg/L
pH 403
units
Alkalinity to pH 4.5 410
mg/L
Alkalinity to pH 8.3 415
mg/L
Carbonate 445
mg/L
Bicarbonate 440
mg/L
Carbon dioxide 405
mg/L
X
Chloride 940
mg/L
Chromium: Hex 1032
ug/L
Color: True 80
CU
Cyanide 720
mg/L
Lab Comments
Sampling Method
Remarks
i
j !✓�' • a 2 6-6
I Fum°. bailer. etc.
Sample Interval
X
Diss. Solids 70300
mg/L
Fluoride 951
mg/L
Hardness: Total 900
-- mg/L
Hardness (non-carb) 902
mg/L
Phenols 32730
ug/I
Specific Cond. 95
uMhos/cm
Sulfate 945
mg/L
Sulfide 745 -
mg/L
Oil and Grease'
mg/L
X
NH3 as N 610
mg/L
TKN as N 625
mg/L
X
NO2 + NO3 as N 630
mg/L
X
P: Total as P 665
mg/L
X
Nitrate (NO3as N) 620
mg/L
X
Nitrite (NO2 as N) 615
mg/L
(Pumping time, air temp., etc.)
Ag-Silver 46566
ug/L
AI -Aluminum 46557
ug/L
As -Arsenic 46551
ug/L
Ba-Barium 46558
ug/L
Ca -Calcium 46552
mg/L
Cd=Cadmium 46559
ug/L
Cr-Chromium 46559
ug/L
Cu-Copper 46562
ug/L
Fe -Iron 46563
ug/L
Hg-Mercury 71900
- ug/L
K-Potassium 46555
mg/L
Mg -Magnesium 46554
mg/L
Mn-Manganese 46565
ug/L
Na-Sodium 46556
mg/L
Ni-Nickel
ug/L
Pb-Lead 46564
ug/L
Se -Selenium
ug/L
Zn-Zinc 46567
ug/L
•
Organochlorine -Pesticides
Organophosphorus Pesticides
Nitrogen Pesticides
Acid Herbicides
PCBs
Semivolatile Organics
TPH-Diesel Range
Volatile Organics (VOA bottle)
TPH-Gasoline Range
TPH-BTEX Gasoline Range
LAB USE ONLY
Temperature on arrival (°C):
l 1.
GW-54-REV. 7/03
For Dissolved Analysis -submit filtered sample and write "DIS" in block.

1.1
WC DWQ La6oratory Section 1?esufts
County:
River Basin
Report To FROAP
Collector. -
Region:
Sample Matrix:
Loc. Type:
Emergency Yes/No
COC Yes/No
HARNETT
B TODD
FRO
GROUNDWATER
MONITORING WELL
YES
oc.
a
0
VisitID
Loc. Descr • TOWN OF ANGIER
Sample ID:
PO Number#
Date Received:,
Time Received:
Labworks LoginlD
Date Reported:
Report Generated:
Location ID:
6PWQ000263843
Collect Date: 11/06/2007
Collect Time:: 09:55
Sample Depth
AB23616
7G0844
11/07/2007
11:40
MMATHIS
11/19/07
11/19/2007
Sample Qua:ifiers and Comments
Routine Qualifiers
Fora more detailed description of these qualifier codes refer to www.dwglab.org under Staff Access
A -Value reported is the average of two or more determinations
B1-Countable membranes with <20 colonies; Estimated
B2- Counts from all filters were zero.
B3- Countable membranes with more than 60 or 80 colonies; Estimated
B4-Filters have counts of both >60 or 80 and < 20; Estimated -
B5-Too many colonies were present; too numerous to count (TNTC)
J2- Reported value failed to meet QC criteria for either precision or accuracy; Estimated
J3-The sample matrix interfered with the ability to make any accurate determination; Estimated
J6-The lab analysis was from an unpreserved or improperly chemically preserved sample; Estimated
N1-The component has been tentatively identified based on mass spectral library search and has an estimated value
N3-Estimated concentration is < PQL and >MDL
NE -No established PQL
P-Elevated PQL due to matrix interference and/or sample dilution
Q1-Holding time exceeded prior to receipt at lab:
02- Holding time exceeded following receipt by lab
PQL- Practical Quantitation Limit -subject to change due to instrument sensitivity
U- Samples analyzed for this compound but not detected
X1- Sample not analyzed for this compound
LAB'
Laboratory Section» 1623 Mall Service Center, Raleigh, NC 27699-1623 [phone]
Page 1 of 2

Sample ID AB23616
Location ID:-
Loc. Descr.:
Visit ID
6PWQ000263843
, TOWN OF ANGIER
NC DWQ Laboratory Section Results
Collect Date:
Collect Time::
11/06/2007
09:55
CAS #
Analyte Name
PQL
Result Qualifier Units Analyst/Date
Approved By /Date
Sample temperature at receipt by lab
Method Reference
1.9
°C
MMATHIS
11/7/07
JGOODWIN
11/8/07
MIC
TOC In Ilquld
Method Reference APHA53108-20th
2.0
2 U mg/L BSWANSON MOVERMAN
11/14/07 11/19/07
WET
Ion Chromatography
Method Reference
, EPA300.0
TITLE_ mg/L
MIBRAHIM MOVERMAN
11n/07 11/9/07
Total Dissolved Solids In Ilquld
Method Reference. APHA2540C-18TH
12 62 •
JSTALEY
11/9/07
CGREEN
11/14/07
Chloride
Method Reference EPA 300.0
1.0
16 mg/L
MIBRAHIM
11/7/07
MOVERMAN
11/9/07
Fluoride -
Method Reference
EPA 300.0
0.4 0.4 U
MIBRAHIM - MOVERMAN
11/7/07 11/9/07
Sulfate
Method Reference.
EPA 300.0
2.0 7.0 • mg/L
MIBRAHIM MOVERMAN
11 /7/07 11/9/07
NUT
NH3 as N In Ilquld
Method Reference
Lac10-107-06-1-J
0.02
0.02, IS
rL�
mg/L as N
MOVERMAN CGREEN
11/8/07 11/14/07
NO2+NO3 as N In liquid 0.02
Method Reference Lac10-107-04-1-c
'
.€.I
r
mg/L as N
MOVERMAN CGREEN
11/8/07 11/14/07
Phosphorus total as P In liquid 0.02 0.02 mg/L as P MAJAYI - CGREEN
Method Reference Lac10-115-01-1EF
11/9/07 11/14/07.,
Nitrate as N In Ilquld
Method Reference
Lachat107-04-1-c
0.02 - 1.4 mg/L as N MOVERMAN CGREEN
11/9/07 11/14/07
Nitrite as N In Ilquld -
Method Reference
Lachat107-04=1-c
0.01 0.01 U mg/L as N MAJAYI -
11/7/07
CGREEN
11/9/07
Laboratory Section» 1623 Mall Service Center, Raleigh, NC 27699-1623 [phone] Page 2 of 2

•
1
GROUNDWATER FIELD/LAB FORM
- r
Location -code 6/P/W00002638/43
County Harnett
Quad No Serial No.
Lat. Long.
Report To: ARO,
WSRO, Kinston FO
Shipped by: Bus,
Col lector(s):_B i I ITo
ourier
MRO, RRO, WaRO, WiRO,
Trust, Central Off,, Other:
Hand Del., Other:
SAMPLE TYPE
I1 Water
❑ Soil
❑ Other
rl
Chain of Custody
SAMPLE PRIORITY
® Routine
❑ Emergency
Purpose:
North'Carolina
Department of Environment and Natural Resources
DIVISION OF WATER QUALITY -GROUNDWATER SECTION
Lab Numb
?3W(g1),4
Date Received Tim �D
Rec'd By: f rom:Bus, r, Hand Del.,
Other:
Data Entry By:
Date Reported:
Ck:
Date �� 6 7 Time `/ a S'' 44aseline, Complaint Compliancy, LUST, Pesticide Study, Federal Trust, Other:
(circle one)
FIELD ANALYSES Owner ' /be:k)„( bf' s✓• . c:�
pH 400 S) 4 Spec. Con ..94 at 25°C Location or Site t>>C` d %b' %N9 :'�/✓L /� a:?'J SG
Temp.io °C Odor Ai C.Description of sampling point ILDescription /I fl e,2/
Appearance 0 /cs./A a Sampling Method •
Field Analysis
+By:_BillTodd
LABORATORY ANALYSES
BOD 310
mg/L
COD High 340
mg/L
COD Low 335
mg/L
Coliform: MF Fecal 31616 '
/100m1 '
Coliform: MF Total 31504
/100m1
X
TOC 680
mg/L
Turbidity 76
' NTU
Residue, Suspended 530
mg/L
pH 403
units
Alkalinity to pH 4.5 410
-. mg/L
Alkalinity to pH 8.3 415
mg/L
Carbonate 445
mg/L
Bicarbonate 440
mg/L
Carbon dioxide 405
mg/L
X
Chloride 940 .
mg/L
Chromium: Hex 1032
- ug/L
Color: True 80
CU
Cyanide 720 —
mg/L
Lab Comments
Remarks
1F'umo. bailer. etc.)
Sample Interval
X
Diss. Solids 70300
mg/L
Fluoride 951
mg/L
Hardness: Total 900
mg/L
Hardness (non-carb) 902
mg/L
Phenols 32730
ug/I
Specific Cond. 95
uMhos/cm •
Sulfate 945
mg/L
Sulfide 745
mg/L
Oil and Grease
mg/L
X
NH3 as N 610
- . ,mg/L) f
TKN as N 625
,nig(L
X
NO2 + No3 as N 630
. ;mg/LY
X
P: Total as P 665
mg/L '
X
Nitrate (NO3 as N) 620
mg/L
X
Nitrite (NO2 as N) 615
mg/L
(Pumping time, air temp:, etc.) -
Ag-Silver 46566
ug/L
Al -Aluminum 46557
ug/L
As -Arsenic 46551 -
ug/L
Ba-Barium 46558
ug/L
Ca -Calcium 46552
•-
mg/L
Cd-Cadmium 46559
ug/L
Cr-Chromium 46559
ug/L
Cu-Copper 46562
ug/L
Fe=Iron 46563
ug/L
Hg-Mercury 71900
'
ug/L '
K-Potassium 46555
mg/L
Mg -Magnesium 46554
mg/L
Mn_Manganese 46565
ug/L
;NanSodium 46556
mg/L
1°
INi Nickel •
ug/L
pb7,Lead 46564
ug/L
:
Se Selenium
ug/L
Zn-Zinc 46567
ug/L
Organochlorine Pesticides
Organophosphorus Pesticides
Nitrogen Pesticides
Acid Herbicides
PCBs
Semivolatile Organics
TPH-Diesel Range
Volatile Organics (VOA bottle)
TPH-Gasoline Range
TPH-BTEX Gasoline Range
LAB USE ONLY '
Temperature on arrival (°C): I
GW-54 REV. 7/03
• For Dissolved Analysis -submit filtered sample and write "DIS" in block...

fC DWQ Laboratory- Section Resufts
.4k
County:
River Basin
Report To - FROAP
' Collector.
Region:
Sample Matrix:
Loc. Type:
HARNETT
B TODD
FRO
GROUNDWATER
MONITORING WELL
Emergency Yes/No
COC Yes/No
YES
VisitlD
Loc. Descr • TOWN OF ANGIER
Sample ID:
PO Number #
Date Received:
Tinie Received:
Labworks LoginlD
Date Reported:
Report Generated::,
Location ID:
6PWQ000263843
Collect Date: 11/06/2007
Collect lime:: 09:15
Sample Depth
AB23615
7G0843
11/07/2007
11:40
MMATHIS
11/19/07
11/19/2007
Sample Qualifiers and Comments.
Routine Qualifiers
Fora more detailed description of these qualifier codes -refer to www.dwglab.org under Staff Access
A -Value reported is the average of two or more determinations
B1-Countable membranes with <20 colonies; Estimated-
B2- Counts. fromall filters were zero. - -
B3- Countable membranes with more than 60 or 80 colonies; Estimated ,
B4-Filters have counts of both >60 or 80 and < 20; Estimated
B5-Too many colonies were present; too numerous to count (TNTC)
J2- Reported value failed, to meet QC criteria for either precision or accuracy; Estimated
J3-The sample matrix interfered with the ability to make any accurate determination; Estimated .
J6-The lab analysis was from an unpreserved or improperly chemically preserved" sample; Estimated
NI -The component has been tentatively identified based on mass spectral library search and has an estimated value
N3-Estimated concentration is < PQL and >MDL
NE -No established PQL
P-Elevated PQL due to matrix interference and/or sample dilution
Q1-Holding time exceeded prior to receipt'at lab.
Q2- Holding time exceeded following receipt by lab
PQL- Practical Quantitation Limit -subject to change due to instrument sensitivity
U- Samples analyzed for this compound but not detected
X1- Sample not analyzed for this compound ,
LAB
"Laboratory Section» 1623 Mall Service Center, Raleigh, NC 27699-1623.y(919)4331;3908
Page 1 of 2

Sample ID AB23615
Location ID:
Loc. Descr.:
Visit ID;Y
6PWQ000263843 '
TOWN OF ANGIER
NC DWQ Laboratory Section Results •
Collect Date: 11/06/2007 •
Collect Time:: 09:15
CAS #
Analyte Name
PQL .
Result Qualifier Units
Analyst/Date
Approved By /Date
Sample temperature at receipt by lab
Method Reference
1.9
"C
MMATHIS
11/7/07
JGOODWIN
11/8/07
MIC
TOC In Ilquid
Method Reference •
APHA5310B-20th
2.0
2 'U
BSWANSON MOVERMAN
11/14/07 11/19/07
WET
Ion Chromatography
Method Reference EPA 300.0
TITLE
mg/L
MIBRAHIM MOVERMAN
11/7/07 11/9/07
Total Dissolved Solids In Ilquid 12 160
Method Reference APHA2540C-18TH
mglL
JSTALEY CGREEN
11/9/07 .. ' 11/14/07,
Chloride
Method Reference EPA 300.0
1.0
mg/L
MIBRAHIM MOVERMAN
11/7/07 11/9/07
Fluoride t 0.4
Method Reference EPA 300.0
0.4' U
MIBRAHIM
11/7/07
MOVERMAN
11/9/07
Sulfate,
Method Reference EPA 300.0
2.0
34
mg/L
MIBRAHIM ' MOVERMAN
11/7/07 11/9/07
NUT
NH3 as N In Ilquid
Method Reference
Lac10-107-06-1-J
0.02
3.6 \ mg/L as N MOVERMAN
11/8/07
CGREEN
11/14/07
NO2+NO3 as N In Ilquid 0.02 0.02 U mg/L as N MOVERMAN CGREEN
Method Reference Lac10-107-04-1-c - 11/8/07 ', 11/14/07
Phosphorus total as P In Ilquid 0.02 0.02 U mg/L as P MAJAYI CGREEN
Method Reference Lac10-115-01-1EF 11/9/07. 11/14/07
Nitrate as N In Ilquid
Method Reference,
Lachat107-04-1-c
0.02 0.02 U mglL as N MOVERMAN CGREEN
11/9/07 11/14/07
. Nitrite as N In Ilquid
Method Reference Lachat107-04-1-c
0.01 0.01 U mg/L as N MAJAYI -
11/7/07
CGREEN
11/9/07
Laboratory Section» 1623 Mail Service Center, Raleigh, NC 27699-1623 [phone] Page 2 of 2

GROUNDWATER FIELD/LAB FORM.
ar
Location code_6/PNVQ0002638/43 County Harnett
Quad No Serial No.
Lat. Long.
Report To: ARO, ROa MRO, RRO, WaRO, WiRO,
WSRO, Kinston FO, Fed. Trust, Central Off., Other:
Shipped by: Bus,6irier) Hand Del., Other:
Collector(s):_BillTodd
FIELD ANALYSES
PH 400 '.
Temp.io
Appearance £;1ct.,�,�•
Spec: Cond.94
°C Odo J
CO
SAMPLE TYPE
1 Water.
❑ Soil
❑ Other
I21 Chain of Custody
SAMPLE PRIORITY
El Routine
❑ Emergency
North Carolina
Department of Environment and Natural Resources
DIVISION OF WATER QUALITY -GROUNDWATER SECTION 5
Lab Number ' 1-,.,g3
Date Received '//f a Time: _
Rec'd By: /7 /fl rom:Bus, r . . Hand Del.,
Other:
.Data Entry By: Ck:
Date Reported:
' Puose:
Date /f -e /07 Time q t / Co Y�aseline, Complaint, mpliance LUST, Pesticide Study, Federal Trust, Other:
(circle one)
Owner . %t) d .- flriiy (re.
at 25°C Location or Site 'Pst? 2 a )l ' 2 `7R 419 / e. / /► C : 02 7 o5'L'
r• Description,of sampling point CU e // /devil
Field Analysis
By:_BillTodd
LABORATORY ANALYSES
BOD 310
mg/L
COD High 340
mg/L
COD Low 335 ,
mg/L
Coliform: MF Fecal 31616
/j0oml
Coliform: MF Total 31504
/100m1
X
TOC 680
mg/L
Turbidity 76
NTU
Residue, Suspended 530
mg/L
pH 403
units
Alkalinity to pH 4.5 410
mg/L
Alkalinity to pH 8.3 415
mg/L
Carbonate 445
mg/L
Bicarbonate 440
mg/L
Carbon dioxide 405
mg/L
X
Chloride 940
mg/L
Chromium: Hex 1032
ug/L
Color: True 80
CU
Cyanide 720
mglL
Lab Comments
Sampling Method
Remarks
n'umo. baser. etc.l.
Sample Interval '
X
Diss. Solids 70300
mg/L
Fluoride 951
mg/L '
Hardness: Total 900
mg/L
Hardness (non-carb) 902
mg/L
Phenols 32730
ug/I ) (i
'Specific Cond. 95
uMht s/cii?l;i;
Sulfate 945
Trig/ L•:;;;
Sulfide 745
mg/L '
Oil and Grease-'
mg/L
X
NH3 as N 610
mg/L
TKN as N 625
mg/L
X
NO2 + NO3 as N 630
mg/L
X
P: Total as P 665
. mg/L
X
Nitrate (NO3 as N) 620
mg/L
X
Nitrite (NO2 as N) 615
mg/L
(Pumping time, air temp., etc.)
Ag-Silver 46566
ug/L
Al -Aluminum 46557
ug/L
As -Arsenic 46551
ug/L
Ba-Barium 46558
ug/L
Ca -Calcium 46552
mg/L
5r .
Cd'Qadmium 46559 - _
ug/L
•,
Cr-Chromium 46559
ug/L
CI -,Copper 46562 -
ug/L
Fe -Iron 46563
ug/L
Hg-Mercury 71900
ug/L
K-Potassium 46555
- mg/L
Mg -Magnesium 46554
mg/L
Mn-Manganese 46565
ug/L
Na-Sodium 46556
mg/L
Ni-Nickel
ug/L
Pb-Lead 46564 -
ug/L
Se -Selenium
'ug/L
Zn-Zinc 46567
ug/L. .
Organochlorine Pesticides
Organophosphorus Pesticides
Nitrogen Pesticides
Acid Herbicides
PCBs
Semivolatile Organics
TPH-Diesel Range
Volatile Organics (VOA bottle)
TPH-Gasoline Range
TPH-BTEX Gasoline Range
LAB USE ONLY
"Temperature on arrival (°C):
GW-54 REV. 7/03 For Dissolved Analysis -submit filtered Sample and write "DIS" in block.

County:
River Basin.
Report To FROAP
Collector. B TODD
Region: FRO
Sample Matrix: GROUNDWATER
Loc. Type: MONITORING WELL
Emergency Yes/No
COC Yes/No
HARNETT
YES
ordtory Section 1' esu[ts
VisitlD
Loc. Descr • TOWN OF ANGIER
Sample' ID:
PO Number#
Date Received:
Time Received:
Labworks LoginlD
Date Reported:
Report Generated:
Location ID:
6PWQ000263843
Collect Date:
11/06/2007 "
Collect Time:: 09:35
Sample Depth
AB23614
7G0842
11/07/2007
11:40
MMATHIS
11/19/07
11/19/2007
Sample Qualifiers and Comments
Routine Qualifiers
For a more detailed description of these qualifier codes refer to www.dwglab.org under Staff Access
A -Value reported is the average of two or more determinations
B1-Countable membranes with <20 colonies; Estimated
B2- Counts from all filters were zero.
B3- Countable membranes with more than 60 or 80 colonies; Estimated
B4-Filters have counts of both >60 or•80 and < 20; Estimated
B5-Too many colonies were present; too numerous to count (TN.TC)
J2- Reported value failed to meet QC criteria for either precision or accuracy; Estimated
J3-The sample matrix interfered with the ability to make any accurate determination; Estimated
J6-The lab analysis was from an unpreserved or improperly chemically preserved sample; Estimated.
N1-The component has been tentatively identified based on mass spectral library search and has an estimated value
•
it
N3-Estimated concentration is < PQL and >MDL
NE -No established PQL
P-Elevated PQL duelo matrix interference and/or sample dilution
Q1; Holding'time exceeded prior to receipt at lab.,
Q2- Holding time exceeded following receipt by lab
PQL- Practical Quantitation Limit -subject to change due to instrument sensitivity
U- Samples analyzed for this compound but not detected
X1- Sample not analyzed for this compound,
LAB
Laboratory Section» 1623 Mail Service Center, Raleigh, NC 27699-1623 [phone]
Page 1 of 2

Sample ID AB23614
Location ID:
Loc. Descr.:
Visit ID
6PWO000263843
TOWN OF ANGIER
JVC DWQ Laboratory Section Results
Collect Date: .
Collect Time::
11/06/2007
09:35
CAS # Analyte Name
PQL
Result . ' Qualifier Units
Analyst/Date
Approved By /Date
Sample temperature at receipt by lab
Method Reference
fir; I 11,9
MMATHIS
11 /7/07
JGOODWIN
11/8/07
MIC
TOC In liquid 2.0 , 1 2.c U
Method Reference APHA5310B-20th
BSWANSON MOVERMAN
11/14/07 11/19/07
WET
Ion Chromatography
Method Reference EPA 300.0
TITLE
mg/L
MIBRAHIM MOVERMAN
1 V7/07 11/9/07
Total Dissolved Solids In Ilquld 12
Method Reference APHA2540C-18TH
mg/L
JSTALEY
11/9/07
CGREEN
11/14/07
Chloride
Method Reference EPA300.0
1.0 3.0
MIBRAHIM MOVERMAN
11 /7/07 11/9/07
Fluoride
Method Reference EPA 300.0
0.4
0.4 U
- MIBRAHIM MOVERMAN
11/7/07 11/9/07
Sulfate.
Method Reference EPA300.0
2.0 -4.2
mg/L
MIBRAHIM MOVERMAN
11 /7/07 11/9/07
,NUT
NH3 as N In Ilquld
Method Reference
Lac10-107-06.1-J
0.02 0.02 U mg/L as N MOVERMAN
11/8/07
CGREEN
11/14/07
NO2+NO3 as N In liquid 0.02 0.48 mg/L as N MOVERMAN CGREEN
Method Reference Lac10-107-04-1-c 11/8/07 11/14/07
Phosphorus total as P In Ilquld 0.02 - 0.06 mg/L as P MAJAYI - CGREEN
Method Reference Lac10-115-01-1EF - 11/9/07 11/14/07
Nitrate as N In Ilquld
• Method Reference
Lachat107-04-1-c
0.02 0.48 mg/L asN MOVERMAN CGREEN
11/9/07 11/14/07
Nitrite as N In liquid
Method Reference
Lachat107-04-1-c
0.01 0.01 U mg/L as N MAJAYI
11/7/07
CGREEN
11/9/07
Laboratory Section» 1623 Mail Service Center, Raleigh, NC 27699-1623e:(919)p7333908 • ' Page 2 of 2

GROUNDWATER FIELD/LAB FORM
Ldcation code 6/P/W00002638/43
County Harnett
Quad No Serial No.
Lat. Long.
Report To: ARO FRO • MRO, RRO, WaRO, WiRO,
WSRO, Kinston FO -.. Trust, Central Off., Other:
Shipped by: Bus, Courier Hand Del., Other:
Col lector(s):_B i I ITo..
C,OCd
SAMPLE TYPE
® Water
❑ Soil
0 Other
IR Chain of Custody
SAMPLE PRIORITY
Routine
❑ Emergency
FIELD ANALYSES
pH400 S(3
Temp.10
Appearance C.LeA/:
Spec. Cond.94 at 25°C
°C Odor /I1..c-4/ t-
Field Analysis
By:_BillTodd
LABORATORY ANALYSES
BOD 310
mg/L
COD High 340
mg/L
COD Low 335
mg/L
Coliform: MF Fecal 31616
/100m1
Coliform: MF Total 31504
/100m1
X,
TOC 680
mg/L
Turbidity 76 `
NTU
Residue, Suspended 530
mg/L
pH 403 .
units
Alkalinity to pH 4.5 410
mg/L
Alkalinity to pH 8.3 415
mg/L
Carbonate 445
mg/L
Bicarbonate 440
mg/L ,
Carbon dioxide 405
mg/L ,
X
Chloride 940
mg/L
Chromium: Hex 1032
ug/L
Color: True 80
CU
Cyanide 720 -
mg/L
Lab Comments
North Carolina
Department of Environment and Natural Resources
DIVISION OF WATER QUALITY -GROUNDWATER SECTION
Purpose:
Date ��" `D % Time l ; " I :Baseline, Complaint, Complian� LUST, Pesticide Study,
• (circle one)
Owner ,tu i/ V -f"/IrrI/ec,2
Location or Site /v&. Spx ..378 - %4it/q ie2/ Ale.
Description'oflsamplingpoint La e// //c,qd
Sampling•Method ', i 1
Remai-ls: F;,(11• ',.. I.
Lab Number 3`:2 4f L JicW02
Date Receive. 1/4 / Time: // WW
H-41 Rec'd By: Ili/From:Bus, .. i r,.Hand Del:,
Other:
Data Entry By:
Ck:
Date Reported:
(Yum°. ba°er. etc.1
Federal Trust, Other:
,27so
Sample Interval
X
Diss. Solids 70300
mg/L
Fluoride 951
mg/L
Hardness: Total 900
mg/L
Hardness (non-carb) 902 .
mg/L
Phenols 32730
ug/I
Specific Cond. 95
uMhos/cm
Sulfate 945
mg/L
Sulfide 745
mg/L
Oil and Grease
mg/L
X '
NH3 as N 610
mg/L
TKN as N 625
mg/L
X
NO2 + NO3 as N 630
mg/L
X
P: Total as P 665
mg/L
X
Nitrate (NO3as N) 620
mg/L
X
Nitrite (NO2 as N) 615
mg/L
• i
(Pumping time, air temp., etc.)
Ag-Silver 46566
ug/L
AI -Aluminum 46557
ug/L
As -Arsenic 46551
ug/L
Ba-Barium 46558
ug/L
Ca -Calcium 46552
mg/L
Cd-Cadmium 46559
ug!L
Cr-Chromium 46559
ug/L
Cu-Copper 46562
ug/L
Fe -Iron 46563
ug/L
Hg-Mercury 71900
ug/L
K-Potassium 46555
mg/L
Mg -Magnesium 46554
mg/L
Mn-Manganese 46565
ug/L
Na-Sodium 46556
mg/L
Ni-Nickel
ug/L
Pb-Lead 46564
ug/L
Se -Selenium
ug/L
Zn-Zinc 46567
ug/L
Organochlonne Pesticides
Organophosphorus Pesticides
Nitrogen Pesticides
Acid Herbicides
PCBs
Semivolatile Organics
TPH-Diesel Range
Volatile Organics (VOA bottle)
TPH-Gasoline Range
TPH-BTEX Gasoline Range
LAB USE ONLY
Temperature on arrival (°C):
GW-54 REV. 7/03 For Dissolved Analysis -submit filtered sample and write "DIS" in block.

c. Any failure of a pumping station, sewer line, or treatment facility resulting in a by-pass direc,
receiving waters without treatment of all or any portion of the influent to such station or facilit.,
d. Any time that self -monitoring information indicates. that the facility has gone out of compliance
with its permit limitations.
Occurrences outside normal business hours may also be reported to the Division's Emergency
Response personnel at telephone number (800). 662-7956, [phone], or [phone].
Persons reporting such occurrences by telephone shall also file a written report in letter form within
five-(5) days following first knowledge of the occurrence. This report must outline the actions taken
or proposed to be taken to ensure that the problem does not recur.
'rTh
IV. GROUNDWATER REQUIREMENTS
LA(IToU
1. Sampling Criteria:
a N�AY2
a.
c.
S
Monitor wells (MW-1, MW-2, MW-3, MW-4, and MW-5) shall be sampled one per year in
November for the parameters listed below. Prior to sampling the parameters, the measurement of
water levels must be taken. The depth to water in each well shall be measured from the surveyed
point on the top of the casing. The measuring points (top of well casing) of all monitoring wells
shall be surveyed relative to a common datum.
Nitrate (NO3-N)
L'd 1oride ,
vTotal Ammonia Nitrogen (NH3-N)
pH (field)
otal Organic Carbon
Pliital Dissolved Solids (TDS)'f
cal Coliforms
viotal Phosphorous
Water Level
For Total Organic Carbon (TOC), if concentrations greater than 10 mg/1 are detected in any
down -gradient monitoring well, additional sampling and analysis must be conducted to identify
the individual constituents comprising this TOC concentration. If the TOC concentration as
measured in the background monitor well exceeds 10 mg/1, this concentration will be taken to
represent the naturally occurring TOC concentration. Any exceedances of this naturally
occurring TOC concentration in the down -gradient wells shall be subject to the additional
sampling and analysis as described above.
Any laboratory selected to analyze parameters must be Division of Water Quality (DWQ)
certified for those parameters required.
2. Reporting / Documentation:
a.
All reports and documentation (GW-1, GW-30, GW-59) shall be mailed to the following address:
Groundwater Section
Permits and Compliance Unit
1636 Mail Service Center
Raleigh, NC 27699-1636
Updated blank forms (GW-1, GW-30, GW-59) may be downloaded from the Groundwater
Section's website at http://gw.ehnr.state.nc.us/ or requested from the address listed above.
The results of the'sampling and analysis must be received on Form GW-59 (Groundwater Quality.
Monitoring: Compliance Report Form) by the Groundwater Section (address listed in the
"Reporting / Documentation" section of the Groundwater Requirements), on or before the last
working day of the month following the sampling month. The data of all groundwater sampling
analyses required by the permit conditions must be reported using the most recent GW-59 form
along with attached copies of the laboratory analyses.

9)1-LT7-2011
JC DENR/DWQ LABORATORY (check one):
For Investigation of: Town of Angier
WQ0002638
Sample collector (print name)
and GW-54 forms completed by: BillTodd
CHAIN OF CUSTODY (COC)RECOKI)
c�le J (-o0
I® I CENTRAL I❑ 1 ARO 10 I WaRO
Sample collector's signature:
Incident Nc
RECEIVED
• NOV 14 2007
Field storage conditions and location (when applicable):
DENR — FAYETTEVILLF RF(fNAI OFFICE
Lab Use Only
LAB NO.
SAMPLE ID
MW-1
MW-2
MW-3
Mw-4
Mw-5
QUAD. NO.
LOCATION
Beside lagoon
Behind"lagoon
Corner of field
In the field (Southeast)
In the field (South corner)
DATE
SAMPLED
/-10-
� /- -&2
fl-L,-v7
//-(o-c
TIME
SAMPLED
NUMBER
OF
CONTAINERS
(� Vain 5
l »/ /1 5
Q 5
5
/G C>r4t1 5
Relinquished by (signature
Relinquished by (signature):
Date
Date
Time2
Time
1R% �1 Sign O"/ J'0 9 /0
Rec ived by (signature): Date
Relinquished by (signature):
Date
Time
Received by (signature):
Date
P
Time
Time
Method of Shipment (check one): State Courier® Hand -delivered❑ Federal Expresso UPS❑ Other:
Sealed by:
Security Type and Conditions:
INTRALABORATORY CHAIN OF CUSTO
NUMBER
BOTTLES
LAB NUMBERS
FROM THROUGH
r2V8
ays
ratrii
DY - Lab Use Only
TIME
ANALYSES
REQUESTED
RELINQUISHED
BY:
RECEIVED
BY:
DATE
cli
le,1—C
affibil lifiAtill
W )
-
/ r1.�
1(-i-oi
JZ;0.S
/ t 424-i
,a,,,tr-
ir_?_c_i
iz.,05.._
_.e
Valia:OP&
gp
i 1 /. t: f''''
)(--7- o
a :or
4 )

. VC TDWQ Ga6orato6 Section 1?esufts
County:
, giver Basin
Report To
Collector.
Region:
Sample Matrix:
Loc. Type:
Emergency Yes/No
COC Yes/No
HARNETT
FROAP
B TODD
FRO
GROUNDWATER
MONITORING WELL
YES
Loc. Descr • TOWN OF ANGIER
Sample ID:
PO Number#
Date Received:
Time Received: ..--
Labworks LoginlD
Date Reported:
Report Generated:
Location ID:
6PWO000263843
Collect Date: 11/06/2007
Collect Time:: 10:30
Sample Depth
AB23618
7G0846
11/07/2007
_ 11:40
MMATHIS
11/20/07
11/21/2007
Routine Qualifiers
For a more detailed description of these qualifier codes
A -Value reported is the average of two or more determinations
B1-Countable membranes with <20 colonies; Estimated
B2- Counts from all filters were zero.
B3- Countable membranes with more than 60 or 80 colonies; Estimated
B4-Filters have counts of both >60 or 80 and < 20; Estimated -
B5-Too many colonies were present; too numerous to count (TNTC)
J2- Reported value failed to meet QC criteria for either precision or accuracy; Estimated
J3-The sample matrix interfered with the ability to make any accurate determination; Estimated
J6-The lab analysis was from an unpreserved or improperly chemically preserved sample; Estimated
N1-The component has been tentatively identified based on mass spectral library search and has an estimated value
refer to www.dwglab.org under Staff Access
N3=Estimated concentration is < PQL and >MDL
NE -No established PQL
P-Elevated PQL due to matrix interference and/or sample dilution
Q1-Holding time exceeded prior to receipt at lab.
Q2- Holding time exceeded following receipt by lab
PQL- Practical Quantitation Limit -subject to change due to instrument sensitivity
U- Samples analyzed for this compound but not detected
X1- Sample not analyzed for this compound
LAB
• Laboratory Section» 1623 Mali Service Center, Raleigh, NC 27699-1623 [phone]
Page 1 of 2

Sample ID AB23618
Location ID: 6PWQ000263843
Loc.,Descr.: TOWN OF ANGIER
Visit ID
9VC DWQ Ladoratory Section Results
Collect Date:
Collect lime::
11/06/2007
10:30
CAS #
Analyte Name
PQL
Result Qualifier Units
Analyst/Date
Approved By /Date
Sample temperature at receipt by lab
Method Reference
1.9
"C
MMATHIS
11/7/07
JGOODWIN
11/8/07
MIC
TOC In liquid 2.0 2 U
Method Reference APHA5310B-20th
BSWANSON MOVERMAN
11/14/07 11/19/07
WET
Ion Chromatography
Method Reference '
EPA 300.0
TITLE mg/L
MIBRAHIM MOVERMAN
.11/7/07 11/9/07
Total Dissolved Solids In Ilquid 12 98 . mg/L JSTALEY MOVERMAN
Method Reference APHA2540C-18TH 11/13/07 11/20/07
Chloride
Method Reference EPA 300.0
1.0
24 mg/L
MIBRAHIM MOVERMAN
11/7/07 11/9/07
Fluoride
Method Reference
0.4 0.4 U . - mg/L MIBRAHIM
EPA 300.0 11 n/07
MOVERMAN
11/9/07
Sulfate 2.0
Method Reference •
EPA 300.0
6.7 mg/L
MIBRAHIM MOVERMAN
11n/o7 11/9/07
NUT
NH3 as N In liquid
Method Reference
Lac10-107-06-1-J
0.02 0.02 U mg/L as N MOVERMAN CGREEN
11/8/07 11/14/07
NO2+NO3 as N In liquid 0.02 0.11 mg/L as N MOVERMAN CGREEN
Method Reference Lac10-107-04-1-c
11/8/07 . 11/14/07
Phosphorus total as P In Ilquid 0.02 0.06 mg/L as P MAJAYI CGREEN
Method Reference Lacl0-115-01-1EF 11/9/07 11/14/07
Nitrate as N In liquid 0.02 0.11 mg/L as N MOVERMAN CGREEN
• Method Reference Lachat107-04-1-c 11/9/07 11/14/07
Nitrite as N In liquid -
Method Reference
Lachat107-04-1-c
0.01
f •bi' i'0, 01 ' U
mg/L as N
MAJAYI
11n/07 _
CGREEN
11/9/07
Laboratory Section» 1623 Mail Service Center, Raleigh, NC 27699-1623 [phone] Page 2 of 2

GROUNDWATER FIELD/LAB FORM
Location code_6/P/WQ0002638/43
County Harnett
Quad No Serial No.
Lat. - Long.
Report To: ARO, MRO, RRO, WaRO, WiRO,
WSRO, Kinston FO, Fe• Trust, Central Off., Other:
Shipped by: Bus, ourier Hand Del., Other:
SAMPLE TYPE
Water
0 Soil
El Other
NI Chain of Custody
:'SAMPLE PRIORITY
Roatirie '-
Emergency
Purpose:
Collector(s):_BiIITo• • Date //i6 r D7 Time %t :: L7 /;,r 11 Baseline, Complaint Compliance LUST, Pesticide Study, Federal Trust, Other:
(circle one)
North Carolina
Department of Environment and Natural Resources
DIVISION OF WATER QUALITY -GROUNDWATER SECTION
Lab Number W " v
Date Receivl
Rec'd By:
Other:
Data Entry By: Ck:
Date Reported:
Spec. Cond.94
°C Odor /`Cbhie
Appearance C°1e.i4. 10,
FIELD ANALYSES
pH 400
Temp.io
Field Analysis
By:_BillTodd
LABORATORY ANALYSES
Owner? w „/ D /✓ i ar-e
at 25°C Location or Site 'f r b -3 DX 7.? j eot/ /'/ .) 7 .3 6
Description of sampling point zee. f/ ih.. i 4
BOD 310
mg/L
COD High 340
mg/L
COD Low 335
mg/L
Coliform: MF Fecal 31616
/100m1
Coliform: MF Total 31504
/100m1
X
TOC 680
mg/L
Turbidity 76
NTU
Residue, Suspended 530
mg/L
pH 403
units
Alkalinity to pH 4.5 410
mg/L
Alkalinity to pH 8.3 415
mg/L
Carbonate 445
mg/L
Bicarbonate 440
mg/L
Carbon dioxide 405
mg/L
X
Chloride 940
mg/L
Chromium: Hex 1032
ug/L
Color: True 80
CU
Cyanide 720
- mg/L
Lab Comments
Sampling Method
Remarks
(i-'umo. bailer. etc.)
Sample Interval
X
Diss. Solids 70300
mg/L
Fluoride 951 .
mg/L
Hardness: Total 900
mg/L
Hardness (non-carb) 902
- mg/L
Phenols 32730
ug/I
Specific Cond. 95
uMhos/cm
Sulfate 945
mg/L
Sulfide 745
• mg/L
Oil and Grease
mg/L
X
NH3 as N 610
mg/L
TKN as •N 625
mg/L
X
NO2 + NO3 as N 630
mg/L
X
P: Total as P 665
mg/L
X
Nitrate (NO3 as N) 620
mg/L
X
Nitrite (NO2 as N) 615
mg/L
(Pumping time, air temp., etc.)
Ag-Silver 46566
ug/L
Al -Aluminum 46557
ug/L
As -Arsenic 46551
ug/L
Ba-Barium 46558
ug/L
Ca -Calcium 46552
mg/L
Cd-Cadmium 46559
ug/L
Cr-Chromium 46559
ug/L
Cu-Copper 46562
ug/L
Fe-Iron46563
ug/L
Ng -Mercury 71900
ug/L
K-Potassium 46555
mg/L
Mg -Magnesium 46554
mg/L
Mn-Manganese 46565
ug/L
Na-Sodium 46556
mg/L
Ni-Nickel
- ug/L
Pb-Lead 46564
ug/L
Se -Selenium
ug/L
Zn-Zinc 46567
ug/L
Organochlorine Pesticides
Organophosphorus Pesticides
Nitrogen Pesticides
Acid Herbicides
PCBs
Semivolatile Organics
TPH-Diesel Range
Volatile Organics (VOA bottle)
TPH-Gasoline Range
TPH-BTEX Gasoline Range
LAB USE ONLY
Temperature on arrival (°C):
GW-54 REV. 7/03 For Dissolved Analysis -submit filtered sample and write "DIS" in block.
•