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HomeMy WebLinkAboutWQ0000701_2007 Annual Report_20060216Resources, Inc. Tyson Foods 2007 Annual Report WQ0000701 Q.MA , - Resources, Inc. CE February 13, "2008 ` DENR/Water Quality Section F E_ 8 2 2008 a Non -Discharge Compliance Unit 1617 Mail Service Center Raleigh, NC 27699-1617 Re: 2007 Annual Report - Tyson Treatment and Land Application of Residuals Permit No. WQ0000701 Dear Sir or Madam: Enclosed are three copies of the 2007 Annual Report for the above referenced land application permit. During 2007 EMA Resources, Inc. land applied 1067 dry tons of biosolids to 455.7 acres of private farmland. Please contact Brent Collins - Director of Technical Services if you have any further questions concerning this report. Sincerely, Bren ollins Director of Technical Services brent,.collins@emaresourcesinc.com RIE, C E I V 2— 0 2008 fION �'rocsssing Unit Phone 336.751.1441 — Fax 336.751.1442 29 Court Square — Mocksville, NC 27028 f ANNUAL LAND APPLICATION CERTIFICATION FORM +Permii#: W 0000701 County: ty: Facility Name (as shown on permit): Land Application Operator: Iredell EMA Resources Inc. Tyson Foods Year: 2007 Phone: 336-751-1441 Land application of residual solids as allowed by the permit occurred during the past calender year? �5 Yes , No If No, skip Part A, and Part B and proceed to the certification. Also, if residuals were generated but not land applied, please attach an explanation on how the residuals were handled. Part A: Total number of application fields in permit: I 65 I Total number of fields land application occurred duringthe year: 13 Total amount of dry tons applied during, the year for all application sites'l 1067 Total number of acres land application occurred during the year-T 455.7 Part B: Facility was compliant during calendar year 2007 with all conditions of the land application permit (including but not limited to items 1-12 below) issued by the Division of Water Quality. l�1 Yes # ' No If no please, provide a written description why the facility was not compliant, the dates, and explain corrective action taken. 1. Only residuals approved for this permit were applied to the permitted sites. 2. Soil pH was adjusted as specified in the permit and lime was applied (if needed) to achieve a soil pH of at least 6.0 or the limit specified in -the permit. 3. Annual -soils analysis were performed on each site receiving residuals during the past calendar year and three (3) copies of laboratoryresults are attached. 4. Annual TCLP analysis was performed and three (3) copies of certified laboratory results are attached. 5. All other monitoring was performed in accordance with the permit and reported during the year as required and three (3) copies of certified laboratory results are attached. 6. The facility did not exceed any of the Pollutant Concentration Limits in Table) of 40 CFR Part 503.13 or the 'Pollutant Loading Rates in Table 2 of 40 CFR part 503.13 (applicable to 40 CFR Part 503 regulated facilities). 7. All general requirements in 40 CFR Part 503.12 and management practices in 40 CFR Part 503.14 were complied with (applicable to 40 CFR Part 503 regulated facilities). 8. All operations and maintenance requirements in the permit were complied with or, in the case of:a deviation, prior authorization was received from the Division of Water Quality. 9. No contravention of Ground Water Quality Standards occurred at a monitoring well or explanations of violations are attached to include appropriate actions and-remediations. 10. Vegetative cover as specified in the permit was maintained on this site and the crops grown were removed in accordance with the crop management plan. I 11. No runoff of residuals from the application sites onto adjacent propery or nearby surface waters has occurred. 12. All buffer requirements as specified on the permit were maintained during each application of residuals..' "I certify, under penalty of law, that the -above information is, to the best of my knowledge and belief, true, accurate, and,complete.'I am aware .that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." 2 ! 'D Dan Crowe =Plant Manager ! ' Permittee Name and Title (type or prin.22 Permitt R Date Signature ofPreparer* Ftw 2 5 91tu and Applier �;,o�i Date (if different from Permittee) (if diffe ent giA,,f?K iit"�'r`eparer) " Preparer is defined in 40 CFR Part 503.9 ( NC E—Ti R7 --� DENR FORM ACF (5/2003) DWQ-Aqu!re, r-1-ob- Lion ANNUAL RESIDUAL SAMPLING SUMMARY FORM Attach this -form to the corresponding Annual Report Please note that your permit may contain additional parameters to be analyzed than those required to be summarized on this form. Permit Number: WQ0000701 Laboratory: 1) . A&L Labs Facility Name: Tyson Poultry 2) NPDES # or NC0005126 3) W Q#: 4) WWTP Name: Harmony NC Rendering Plant 5) Daeirinal Analveie data Sample or Composite Date 1/4/07 3/5/07 5/2/07 7/16/07 9/4/07 11/30/07 Percent Solids 10.57 4.47 7.67 12.61 5.26 7.3 Arsenic 0.5 0.3 0.7 2.4 1.8 2.6 Cadmium 3 <1 <1 1 <1 <5 Chromium 17 11 13 9 5- <5 Copper 60 18 14 16 14 21 b Lead 20 7 9 5 6 7 g Mercury <.4 <.4 <.4 <.4 <.4 <.4 Molybdenum 11 8 6 47 <5 <5 y Nickel 19 7 7 5 5 5 Selenium 0.9 0.9 0.9 0.6 2.5 1.6 Zinc 66 86 66 668 133 114 Total Phosphorus 7000 11400 7000 8000 1030.0 7900 TKN 42400 68700 41600 31100 6240.0 36700 Ammonia -Nitro en 18900 29800 19400 12400 34600 15300 Nitrate and Nitrite <1 <1 <1 21 <1 <1 "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the, possibility of fines and imprisonment for knowing violations." Signature of Preparer Date _ DENR FORM RSSF (5/2003) w: t� ANNUAL RESIDUAL SAMPLING SUMMARY FORM Attach this form to the corresponding Annual Report Please note that your permit may contain additional parameters to be analyzed than those required to be summarized on this form. Permit Number: WQ0000701 Laboratory: 1) A&L Labs Facility Name: Tyson Poultry 2) NPDES # or NC0005126 . WQ#: WWTP Name: Harmony Rendering Plant RPcirinnl Annlvde Dgtn 3) 4) 5) Sample - or Composite Date •1 11 :111 .11 :11 11 :.1, �a���� Magnesium .Potassium �rr•����®ter �r r�� ®��®r��®■per®r��r "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance, with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." Signature of Preparer Date DENR FORM RSSF-B (5/2oa3) all F, Report M , :r: R07008-8012 Account Number: 46245 To: EMA RESOURCES ING 29 COURT SQ MOCKSVILLE, NC 27028 LAB NUMBER: 40141 SAMPLE ID: TYSON A&L EASTERN LHdORATORIES, INC. 7621 Whitepine Road - Richmond, Virginia 23237 (804) 743-9401 - Fax No. (804) 271-6446 FOR: TYSON NC CERT #257 REPORT OF ANALYSIS - copy: BRENT COLLINS DATE SAMPLED: 1 /4/2007 1200 DATE RECEIVED: 1 /5/2007 1100 DATE REPORTED: 1 /1 1 /2007 PAGE: 1 Solids, Total (As is) 10.57 105700 100 JM 01/08/07 16:00 SM 2540G Nitrogen, Total Kjeldah'I 4.24 42400 100 JM 01/09/07 16:00 EPA 351.3 Phosphorus 0.70 7000 100 JM 01/09/07 16:00 SW 846-601OB Potassium 0.20 2000 100 JM 01/09/07 16:00 SW 846-601013 Sulfur 0.32 3200 100 JM 01/09/07 16:00 SW 846-601OB Calcium 4.02 40200 100 JM, 01/09/07 16:00 SW 846-6010B Magnesium 0.07 700 100 JM 01/09/07- 16:00 SW 846-601OB Sodium 0.35 3500 100 JM , 01/09/07 16:00 SW 846-601OB Iron 1270 1 JM 01/09/07 16:00 SW 846=601OB Aluminum 3850 10 JM 01/09/07 16:00 SW 846-601OB Manganese 47 1 JM 01/09/07 16:00 SW 846-601OB Copper 60'. 1 JM 01/09/07 15:00 SW 846-601OB Zinc 66 1 JM 01/09/07 16:00 SW846-601OB Nitrogen, Ammonia (as N) 1.89 18900 10 JM 01/09/07 14:00 EPA 350.2 Nitrogen, Organic (N) 2.35 23500 100 DCH CALCULATION Nitrogen, NO3+NO2 < 1 1 KS 01/09/07 15:00 SM 4500-NO3F Cadmium 3.0 1 JM 01/09/07 16:00 SW 846-60106 Chromium 17 5 JM 01/09/07 16:00 SW 846-601OB All values are on a dry weight basis except as noted. "Detection Limit on all N series is on a wet basis. Our reports and letters are for the exclusive and confidential use of our clients, and may not be reproduced in whole or in part, nor may any reference be made to the work, the results, or the company in any advertising, news release, or other public announcements without obtaining our prior written authorization. PAUL C. H, CHU Report N►.,: ,, ,r: R07008-8012 A&L EASTERN LA80RATORIES, INC. Account Number: 7621 Whitepine Road - Richmond, Virginia 23237 46245 (804)'743-9401 - Fax:No. (804) 271-6446 To: .EMA RESOURCES INC FOR: TYSO,N copy: BRENT COLLINS 29 COURT SQ MOCKSVILLE, NC 27028 NC CERT #257 REPORT OF ANALYSIS DATE SAMPLED: 1/4/2007 1200 LAB NUMBER: 40141 DATE RECEIVED: 1 /5/2007 1100 SAMPLE ID: TYSON DATE REPORTED: 1/1 1/2007 PAGE: 2 RESULT (%PARAMETER,. RESULT DETECTION ANALYST �. •• Nickel 19 5 JM 01/09/07 16:00 SW 846-60106, Lead 20 5 JM 01/09/07 16:00 SW 846-601013 Arsenic 0.5 0.2 KM 01/10/07 '01/09/07 15:00 SW 846-7061A Mercury < 0.4 0.4 KM, 15:00 SW 846-7471A Selenium 0.9 0.2 KM 01/10/07 15:00 SW 846'7741A pH (Std. Unit, As is) 6.2 0.01 RD 01/09/07' 12:30 SW 846-9045C Molybdenum 11 5 JM 01/09/07 . 16:00 SW 846-60106 All values are on a dry weight basis except as noted. "Detection Limit on all N series is on a wet basis. Our reports and letters are for the exclusive and confidential use of our clients, and may not be reproduced in whole or in part, nor may any reference be madeto the work, the results, or the company in any advertising, news release, or other public announcements without obtaining our prior written authorization. PAUL C. H. CHU 07065-800, A&L EASTERN 1"' �IORATORIES, INC. ccount Number: 7621 Whitepine Road Richmond, Virginia.23237 1245 (804) 743-9401 • Fax No. (804) 271-6446 To: EMA RESOURCES INC 29 COURT SQ . MOCKSVILLE, NC 27028 LAB NUMBER: 41249 SAMPLE ID: TYSON FOR: TYSON NC CERT #257 REPORT OF ANALYSIS copy: EMA RESOURCES INC DATE SAMPLED: 3/5/2007 1000 DATE RECEIVED: 3/6/2007 1000 -DATE REPORTED: 3/9/2007 PAGE: 1 olids, Total (As is) 4.47 44700 100 JM 03/06/07 16:00 SM 2540G itrogen, Total Kjeldahl 6.87 68700 100 JM. 03/07/07, 16:00 EPA 351.3 hosphorus 1.14 11400 100 JM 03/07/07 16:00 SW 846-6010B otassium 0.28 2800 100 JM 03/07/07 16:00 SW 846-601 OB ulfur 0.36 3600 100 JM 03/07/07 16:00 SW 846-6010B alcium 5.80 58000 100 JM 03/07/07 16:00 SW 846-601013 lagnesium 0.14 1400 100 JM 03/07/07 16:00 SW 846-6010B odium 0.83 8300 100 'JM -03/07/07 16:00. SW 846-6010B on 1760 1 JM 03/07/07 16:00 SW 846-6010B luminum 7340 10 JM 03/07/07 16:00 SW 846-6010B langanese 65 1 JM 03/07/07 16:00 SW 846-6010B opper 18 1 JM 03/07/07 15:00 - SW 846-601013 inc 86 1 JM 03/07/07 16:00 SW846-6010B itrogen, Ammonia (as N) 2.98 29800 10 JM 03/07/07 14:00 EPA 350.2 itrogen, Organic (N) 3.89 38900 100 DCH CALCULATION itrogen, NO3+NO2 < 1 I DH 03/07/07 15:00 SM 4500-NO3F admium < 1 1 JM 03/07/07 15:00 SW 846-6010B hromium 11 5 JM 03/07/07 16:00 SW 846-6010B All values are on a dry weight basis except as noted. *Detection Limit on all N series is. on a wet basis. reports and letters are for the exclusive and confidential use of our clients, and may not be reproduced in whole or in part, nor may any reference be made he work, the results, or the company in any advertising, news release, or other public announcements without obtaining our prior written authorization. ti PAUL C. H. CHU t 07065-8007 AR AR EASTERN L ''' ORATORIES, INC. ccount Numk;,�... 7621 Whitepine Road ""Richmond, Virginia 23237 5245 (804) 743-9401'- Fax No. (804) 271-6446 TO: EMA RESOURCES INC FOR: TYSON 29 COU RT SQ MOCKSVILLE, NC 27028 NC CERT #257 LAB NUMBER: 41249 SAMPLE ID: TYSON REPORT OF ANALYSIS COPY: EMA RESOURCES INC DATE SAMPLED: 3/5/2007 1000 DATE RECEIVED: 3/6/2007 10.00 DATE REPORTED: 3/9/2007 PAGE: 2 ickel 7 5 JM 03/07/07 16:00 SW 846-6010B ead 7 5 JM 03/07/07 16:00 SW 846-6010B rsenic. 0.3 0.2 KM 03/08/07 15:00 SW 846-7061A lercury < 0.4 0.4 KM 03/07/07 15:00 SW 846-7471A elenium 0.9 0.2 KM 03/08/07 15:00 SW 846-7741A H (Std. Unit, As is) 6.0 0.01 RD 03/07/07 12:30 SW 846-9045C lolybdenum 8. 5 JM 03/07/07 . 16:00 SW 846-6010B l All values are on a dry weight basis except as noted. *Detection Limit on all N series is on a wet basis. reports:and letters are for the exclusive and confidential use of our clients, and may not be reproduced in whole or in part nor may any reference be made he work, the results, or the company in any advertising, news release, or other public announcements without obtaining our prior written authorization. PAUL C. H. CHU wpuCt NliO4ozi' .:.:.. .. ... 1-- - . . .. 07123-8002, A&L EASTERN L ORATORIES, INC. ccount Number: 7621 Whitepine Roaichmond, Virginia 23237 1245 (804) 743-9401 Fax No. (804) 271-6446 To: EMA RESOURCES INC 29 COURT SQ MOCKSVILLE, NC 27028 FOR: TYSON NC CERT #257 copy: BRENT COLLINS REPORT OF ANALYSIS' DATE SAMPLED: 5/2/2007 0800 LAB NUMBER: 42475 DATE RECEIVED: 5/3/2007 1245 SAMPLE ID: TYSON DATE REPORTED: 5/8/2007 PAGE: 1 olids, Total (As is) 7.67 76700 100 JM 05/03/07 16:00 SM 2540G itrogen, Total Kjeldahl 4.16 41600 100 100 MW DH 05/07/07 16:00 16:00. EPA 351.3 SW 846-3051/6010B hosphorus 0.70 0.15 7000. 1500 100 DH .05/04/07 05/04/07 16:00 SW 846-3051/6010B otassium ulfur 0.27 2700 100 DH 05/04/07 16:00 SW 846-3051/601013 alcium 3.26 32600 100 DH 05/04/07 16:00 SW 846-3051/601013 lagnesium 0.12 1200 100 DH 05/04/07 16:00 SW 846-3051/6010B odium 1.21 12100 100 DH 05/04/07 16:00 SW 846-3051/6010B 1400 1 DH 05/04/07 16:00 SW 846-3051/6010B on luminum 5610 10 DH 05/04/07 16:00 SW 846-3051/6010B langanese nga 103 1 DH 05/04/07 16:00 SW 846-3051/6010B 14 1 DH 05/04/07 15:00 SW 846-3051/6010B oppe 66 1 DH 05/04/07 16:00 SW 846-3051/6010B inc itrogen, Ammonia (as N) 1.94 19400 10 MW 05/04/07 14:00 EPA 0.2 itrogen, Organic (N) 2.22 22200 100 1, DCH KS 05/04/07 15:00 LA CALCULATION SM 4500-NO3F itrogen, NO3+NO2 < 1 < 1 1 DH 05/04/07 16:00 SW 846-3051/6010B admium 13 5 DH 05/04/07 16:00 SW 846-3051/6010B hromium All values are on a dry weight basis except as noted. *Detection Limit on all N series is on a wet basis. reports and letters are for the exclusive and confidential use of our clients, and may not be reproduced in whole or in part, nor may any reference be made he work, the results, or the company in any advertising, news release, or other public announcements without obtaining our prior written authorization. PAUL C. H. CHU eport Numoer�-- 07123-800': . ccount Number: 3245 To: EMA RESOURCES INC 29 COURT SQ MOCKSVILLE, NC 27028 A&L EASTERN 1, ~-'10RATORIES, INC. 7621 Whitepine Road- Richmond, Virginia 23237 (804) 743-9401 - Fax No. (804) 271-6446 FOR: TYSON - NC CERT #257 copy: BRENT COLLINS REPORT OF ANALYSIS DATE SAMPLED: 5/2/2007 0800 LAB NUMBER: 42475 DATE RECEIVED: 5/3/2007 1245 SAMPLE ID: TYSON DATE REPORTED: 5/8/2007 PAGE: 2 ickel 7 5 DH 05/04/07 ead 9 5 DH 05/04/07 0.7 0.2 KM 05/08/07 rsenic . lercury < 0.4 0.4 KM 05/07/07 elenium 0.9 0.2 KM 05/08/07 H (Std. Unit, As is) 5.5 0.01 RD 05/04/07. lolybdenum 6 5 DH 05/04/07 16:00 16:00 15:00 15:00 15:00 12:30 16:00 All values are on a dry weight basis except as noted. *Detection Limit on all N series is on a wet basis. reports and letters are for the exclusive and confidential use of our clients, and may not be reproduced in whole or in part, nor may any reference be made he work, the results, or the company in any advertising, news release, or other public announcements without obtaining our prior written authorization. SW 846-3051/6010B SW 846-3051/6010B SW 846-7061A SW 846-7471A SW 846-7741A SW 846-9045C SW 846-3051/6010B PAUL C. H, CHU Report N ;r: R07200-8001 Account Number: 46245 To: EMA RESOURCES INC 29 COURT SQ MOCKSVILLE, NC 27028 A&L EASTERN LABORATORIES, INC. 7621 Whitepine Road - Richmond, Virginia 23237 (804) 743-9401 - Fax No. (804) 271-6446 FOR: TYSON NC CERT #257 copy: BRENT COLLINS REPORT OF ANALYSIS DATE SAMPLED: 7/16/2007 1500 LAB NUMBER: 43671 DATE RECEIVED: 7/19/2007 1000 SAMPLE ID: TYSON DATE REPORTED: 7/24/2007 PAGE: 1 RESULT RESULT DETECTION - •. •• Solids, Total (As is) 12.61 126100 100 JM 07/19/07 16:00 SM 254OG Nitrogen, Total Kjeldahl . 3.11 31100 100 MW 07/20/07 16:00 EPA 351.3 Phosphorus 0.80 8000 100 DH 07/20/07 16:00 SW 846-3051/6010B Potassium 0.17 1700 100 DH 07/20/07 16:00 SW 846-3051/6010B Sulfur 0.26 2600 100 DH 07/20/07 16:00 SW 846-3051/6010B Calcium 3.28 32800 100 DH 07/20/07 16:00 SW 846-3051/6010B Magnesium 0.10 1000 100 DH 07/20/07- 16:00 SW 846-3061/6010B Sodium 0.74 7400 100 DH 07/20/07 16:00 SW 846-3051/6010B Iron 1590 1 DH 07/20/07 16:00 " SW 846-3051/6010B Aluminum 4860 10 DH 07/20/07 16:00 SW 846-3051/6010B Manganese 60 1 DH 07/20/07 16:00 SW 846-3051/6010B Copper 16 1 DH 07/20/07 15:00 SW 846-3051/6010B Zinc 668 1 DH 07/20/07 16:00 SW 846-3051/60108 Nitrogen, Ammonia (as N) 1.24 12400 10 MW 07/20/07 14:00 EPA 350.2 Nitrogen, Organic (N) 1.87 18700 100 DCH CALCULATION Nitrogen, NO3+NO2 21 1 DH 07/20/07 15:00 SM 4500-NO3F Cadmium 1.0 1 DH 07/20/07 16:00 SW 846-3051/601013 Chromium 9 5 DH 07/20/07 16:00 SW 846-3051/6010B All values are on a dry weight basis except as noted. *Detection Limit on all N series is on a wet basis. Our reports and letters are for the exclusive and confrdendal use of our clients, and may not be reproduced in whole or in part nor may any reference be made �--- to the work, the results, or the company in any advertising, news release, or other public announcements without obtaining our prior written authorization. - PAUL C. H. CHU h Report N`, :r: ' A&L EASTERN L`%60RATORIES, INC. R07200-8001 w f Account Number: 7621 Whitepine Road Richmond, Virginia 23237 I # t 46245 (804) 743-9401 Fax No. (804) 271-6446 ..... _.{• • TO: EMA RESOURCES INC FOR:. TYSON . copy: BRENT COLLINS 29 COURT SQ MOCKSVILLE, NC 27028 NC CERT #257 REPORT OF ANALYSIS DATE SAMPLED: 7/16/2007 1500 LAB NUMBER: 43671 . - DATE RECEIVED: 7/19/2007 1000 SAMPLE ID: TYSON DATE REPORTED: 7/24/2007 PAGE: 2 PARAMETER RESULT RESULT DETECTION (mg/kg) LIMIT (�.glkg) ANALYST DATE TIME METHOD Nickel 5 5 DH 07/20/07 16:00 SW 846-3051/6010B Lead 5 5 DH 07/20/07 16.00 SW 846-3051/601OB Arsenic 2.4 . 0.2 PC 07/23/07 15:00 SW 846-601 OB Mercury < 0.4 0.4 KM 07/23/07. 15:00 SW 846-7471A " Selenium 0.6 0.2 PC 07/23/07, 15:00 SW 846-601OB pH (Std. Unit, As is) 5.19 0.01 RD 07/20/07 12:30 SW 846-9045C Molybdenum .47 5 DH 07/20/07 16:00 ` SW 846-3051/601OB. All values are on a dry weight basis except as noted. *Detection Limit on all N series is on a wet basis. Our reports and letters are for the exclusive and confidential use of our clients, and may not be reproduced in whole or in part, nor may any reference be made to the work, the results, or the company in any advertising, news release, or other public announcements without obtaining our prior written authorization. ?aj _ PAUL C. H. CHU Report N, )r: R07248-8007 Account Number: 46245 To: EMA RESOURCES INC 29 COURT SQ . MOCKSVILLE, NC 27028 LAB NUMBER: 44379 .SAMPLE ID: TYSON A&L EASTERN LA80RATORIES, INC. 7621 Whitepine Road - Richmond, Virginia 23237 (804) 743-9401 - Fax No. (804) 271-6446 FOR: TYSON NC CERT #257 REPORT OF ANALYSIS 1 copy: BRENT COLLINS DATE SAMPLED: 9/4/2007 1030 DATE RECEIVED: 9/5/2007 1200 DATE REPORTED: 9/10/2007 PAGE: 1 Solids, Total (As is) 5.26 52600 100 RD 09/05/UI 1b:UU SIVI L04utz Nitrogen, Total Kjeldahl 6.24 62400 10 JM 09/07/07 16:00 EPA 351.3 Phosphorus 1.03 10300 100 DH 09/06/07 16:00 .SW 846-3051/601OB Potassium 0.33 3300 100 DH 09/06/07 16:00 SW 846-3051/601OB Sulfur 0.32 3200 100 DH 09/06/07 16:00 SW 846-3051/6010B Calcium 3.81 38100 100 DH 09/06/07 16:00 SW 846-3051/601OB Magnesium 0.15 1500 100 DH- 09/06/07 16:00 SW 846-3051/601OB Sodium 1.22 12200 100 DH 09/06/07 16:00 SW 846-3051/601OB Iron 1860 1 DH 09/06/07 16:00 SW 846-3051/6010B Aluminum 11300 10 DH 09/06/07 16:00 SW 846-3051/601OB Manganese 56 1 DH 09/06/07 16:00 SW 846-3051/601OB Copper 14 1 DH 09/06/07 15:00 SW 846-3051/601OB Zinc 133 1 DH 09/06/07 16:00 SW 846-3051/601OB Nitrogen, Ammonia (as N) 3.46 34600 10 MW . 09/06/07 14:00 EPA 350.2 Nitrogen, Organic (N) 2.78 27800 100 DCH CALCULATION Nitrogen, NO3+NO2 < 1 1 KS 09/06/07 15:00 SM 4500-NO317 Cadmium < 1 1 DH 09/06/,07 16:00 SW 846-3051/601OB Chromium 5 5 DH 09/06/07 16:00 SW 846-3051/601OB All values are on a dry weight basis, except as noted. 'Detection Limit on all N series is on a wet basis. Our reports and letters are for the exclusive and confidential use of our clients, and may not be reproduced in whole or in part, nor may any reference be madeto the work, the results, or the company in any advertising, news release,. or other public announcements without obtaining our prior written authorization. PAUL C. H. CHU Report N? :r: A&L.EASTERN L,:JORATORIES, INC. 07248-8007 Account Number: 7621, Whitepine Road - Richmond, Virginia 23237 46245 (804) 743-9401' • Fax No. (804) 271-6446 To: EMA RESOURCES INC FOR: TYSON 29 COURT SQ NC CERT #257 MOCKSVILLE, NC 27028 copy: BRENT COLLINS REPORT OF ANALYSIS DATE SAMPLED: 9/4/2007 1030 LAB NUMBER: 44379 DATE RECEIVED: 19/5/2007 1200 SAMPLE ID: TYSON DATE REPORTED: 9/10/2007 PAGE: 2 Nickel 5 6 5 5 Lead 1.8 1.0 Arsenic < 0.4 0.4 Mercury 2.5 1.0 Selenium pH (Std. Unit, As is) 6.14 0.01 Molybdenum 5 5 , DH 09/06/07 DH 09/06/07 DH 09/06/07 KM' 09/07/07 DH 09/06/07 RD '09/06/07 DH 09/06/07 16:00 SW 846-3051 /601 OB 16:00 SW 846-3051 /601013 15:00 SW 846-601 OB 15:00 SW 846-7471A 15:00 SW 846-601OB 12:30 SW 846-9045C 16:00 SW 846-3051 /601 OB All values are on a dry weight basis except as noted. *Detection Limit on all N series is on a wet basis. Our reports and letters are for the exclusive and confidential use of our clients, and may not be:reproduced in whole or in part, nor may any reference be made to the work, the results, or the company in any advertising, news release, or other public announcements without obtaining our prior written authorization. PAUL C. H. CHU Report N' w; R07337-8607 Account Number: 46245 To: EMA RESOURCES INC 29 COURT SQ MOCKSVILLE, NC 27028 LAB NUMBER: 45823 SAMPLE ID: TYSON A&L EASTERN LtidORATORIES, INC.- 7621 Whitepine Road - Richmond, Virginia 23237 (804) 743-9401 - Fax No. (804) 271-6446 FOR: TYSON NC CERT #257 REPORT OF ANALYSIS S � COPY: EMA RESOURCES INC DATE SAMPLED: 11 /30/2007 1000 DATE RECEIVED: 12/3/2007 1000 DATE REPORTED: 12/5/2007 PAGE: 1 Solids; Total (As is) 7.30 73000 100 JM 12/03/07 16:00 SM 254OG Nitrogen, Total Kjeldahl 3.67 36700 10 JM 12/04/07 16:00 EPA 351.3 Phosphorus 0.79 7900 100 JM 12/04/07 16:00 SW 846-3051/601OB Potassium 0.20 2000 100 JM 12/04/07 16:00 SW 846-3061/601OB Sulfur 0.25 2500 100 JM 12/04/07 16:00 SW 846-3051/601OB Calcium 1.89 18900 100 JM 12/04/07 16:00 SW 846-3051/601013 Magnesium 0.12 1200 .100 JM 12/04/07 16:00 SW 846-3051/601OB Sodium 1.14 11400 100 JM 12/04/07 .16:00 SW 846-3051/601013 Iron 1780 1 JM 12/04/07 16:00 SW 846-3051/601013 Aluminum 6050 10 JM 12/04/07 16:00 SW 846-3051/601OB Manganese 44 1 JM 12/04/07 16:00 SW 846-3051/601013 Copper. 21 '1 JM 12/04/07 15:00 SW 846-3051/601OB Zinc 114 1 JM. 12/04/07 16000 SW 846-3061/601OB Nitrogen, Ammonia (as N) 1.53 15300 10 JM 12/04/07 14:00 EPA 350.2 . Nitrogen, Organic (N) 2.14 21400 100 DCH CALCULATION Nitrogen, NO3+NO2 < 1 1 KS 12/04/07 15:00 SM 4500-NO3F Cadmium < 5 5 JM 12/04/07 16:00 SW 846-3051/601OB Chromium < 5 5 JM 12/04/07 16:00 SW 846-3051/6010B All values are on a dry weight basis except as noted. *Detection Limit on all N series is on a wet basis. Our reports and letters are for the exclusive and confidential use of our clients, and may not be reproduced in. whole or in part, nor may any reference be made s . + „ to the work, the results, or the company in any advertising, news release, or other public announcements without obtaining our prior written authorization. CAL— PAU L C. H. CH U Report N,. o: R07337 8007 A&L EASTERN LA . ORIES, INC. Account Number: 7621 Whitepine Road Richmond, Virginia 23237 46245 (804) 743-9401 Fax No. (804) 271-6446 To: EMA RESOURCES INC FOR: TYSON 29 COURT SO MOCKSVILLE, NC 27028 NC CERT #257. copy: EMA RESOURCES INC REPORT OF ANALYSIS DATE SAMPLED: 11/30/2007 1000 LAB NUMBER: 45823 DATE RECEIVED: 12/3/2007 1000 SAMPLE ID: TYSON DATE REPORTED: 12/5/2007 PAGE: 2 Nickel 5 5 Lead 7 5 Arsenic 2.6 1.0 Mercury < 0.4 0.4 Selenium 1.6 1.0 pH (Std. Unit, As is) 5.35 0.01 Molybdenum < 5 5 JM 12/04/07 16:00 SW 646-3Ub1/6U1Ub JM 12/04/07 16:00 SW 846-3051/601OB JM 12/04/07 15:00 SW 846-6010B KM 12/04/07 15:00 SW 846-7471A JM 12/04/07 15:00 SW 846-6010B RD 12/04/07 12:30 SW 846-9045C JM. 12/04/07 16:00 SW 846-3051/601013 All values are on a dry weight basis except as noted.. *Detection Limit on all N'series is on a wet basis. Our reports and letters are for the exclusive and conirdentlal use of our clients, and may not be reproduced in whole or in part,. nor may any reference be made s to the work, the results, or the. company in any advertising, news release; or other public announcements without obtaining our prior written authorization. 4, . . PAULC. H. CHU ENVIRONMENTAL SCIENCE CORP. Mr. Brent Collins EMA Resources 29 Court Square Mocksville, NC 27028 Report Summary Friday March 30, 2007 Report Number: L2858,65 Samples Received: 03/23/07 Client Project: Description: Tyson 12065 Lebanon Rd. Mt. Juliet, TN 37122 (615) 758-5858. 1-B00-767-5859 Fax (615) 758-5859 Tax I.D. 62-0814289 Est. 1970 The analytical results in this report are based upon information supplied by you, the client, and are for your exclusive use. If you have any questions regarding this data package, please do not hesitate to call. Reviewed By: rrie udge��'c RepIsent a ive Laboratory Certification Numbers A2LA - 1461-01, AIHA - 09221, AL - 40660, CA - I-2327, CT - PH-0197, FL - E87487 GA - 923, IN - C-TN-01, KY - 90010, KYUST - 0016, NC - ENV375,DW21704, ND - R-140 NJ - TN002, SC - 84004, TN - 2006, VA - 00109, WV - 233 AZ-- 0612, MN - 047-999-395, NY - 11742, WI - 998093910, WA - C1915 This report may not be reproduced, except in full, without written approval from Environmental science Corp. ENVIRONMENTAL SCIENCE CORP. REPORT OF ANALYSIS Mr. Brent Collins EMA Resources 29 Court Square Mocksville, NC 27028 12065 Lebanon Rd. Mt. Juliet, TN 37122 (615) 758-5858 1-800-767-5859 Fax (615) 75B-5859 Tax I.D. 62-0814289 Est. 1970 March 30, 2007 ESC Sample # : L285865-01 Date Received March_ 23, 2007 . Description Tyson Site ID : Sample ID TYSON Project Collected By Boger Hartsell Collection Date 03/22/07 10:00 Parameter Result Det. Limit Units Limit Method Date/Time By Dil TCLP Extraction - 1311 03/27/07 1222 LJN 1 Mercury BDL 0.0010 m3/l 0.20 7470A 03/28/07 0002 LKW 1 Arsenic BDL 0.050 mg/1 5.0 6010E 03/28/07 0055 LF 1 Barium 0.076 0.050 mg/1 100 6010B 03/28/07 0055 LF 1 Cadmium BDL 0.050 mg/1 1.0 6010B 03/28/07 0055 LF 1 Chromium BDL 0.050 mg/1 5.0 6010B 03/28/07 0055 LF 1 Lead BDL 0.050 mg/1 5.0 6010B 03/28/07'0055•LF 1 Selenium BDL 0.050 mg/l 1.0 6010B 03/28/07 0055 LF 1 Silver BDL 0.050 mg/1 5.0 6010B 03/28/07 0055 LF 1 TCLP ZHE Extraction - 1311 03/27/07 1222 LJN•1 TCLP Volatiles Benzene BDL 0.050 m3/1 0.50 8260B 03/28/07 0212 JCN 1 Carbon tetrachloride BDL 0.050 mg/l 0.50 8260B 03/28/07 0212 JCN 1 .Chlorobenzene BDL 0.050 mg/I 100 8260B 1)3/2B/07'0212 JCN 1 Chloroform BDL 0.25 mg/l 6.0 8260B '•03/28107'.0212 JCN-1 1,2-Dichloroethane BDL 0.050 mg/l 0.50 .826013 •'03/28/07.0212 JCN 1 1,1-Dichloroethe3ae BDL 0.050 mg/l 0.70 8260B 03/28/07:0212 'JCN.1 2-Butanone (MEC) BDL 0.50 mg/1 200 8260B '03/2B/07.A212 JCN 1 Tetrachloroethene BDL 0-050 mg/l • 0.70 8260B 03/28/07 0212 JCN 1 Trichloroethene BDL 0.050 i[g/l 0.50 8260B 03/28/07 '0212 JCN 1 Vinyl chloride BDL 0.050 mg/1 0.20. 8260B 03/28/07 0212 JCN 1 Surrogate Recovery Dibromofluoromethane 121. $ Rec. B260B 03/28/07 0212 JCN 1 Toluene. -dB 110. g Rec. 8260E 03/28/07 0212 JCN 1 4-Bromofluorobenzene 91.6 % Rec. 8260B 03/28/07 6212 JCN 1 TCLP Pesticides Chlordane BDL 0.0050 mg/l 0.030 8081A 03/28/07 1900-JSW 1 Endrin BDL 0.0050 mg/1 0.020 8081A 03/28/07 1900 JSW 1 Heptachlor BDL 0.0050 mg/l 0.0080 8081A 03/28/07 1900 JSW 1 Lindane BDL 0.0050 mg/1 0.40 80.81A 03/28/07 1900 JSW 1 Methoxychlor BDL 0.0050 mg/l 10. 8081A 03/28/07 1900 JSW 1. Toxaphene BDL 0.010 mg/l 0.50 8081A 03/28/07 1900 JSW 1 Surrogate Recovery Decachlorobiphenyl 50.4 Rec. 8081A 03/2B/07 1900 JSW 1 Tetrachloro-m-xylene 35.8 -W Rec. 8081A' 03/28/07 1900 JSW I TCLP Herbicides 2,4,5-TP (Silvex) BDL 0.0020 mg/l 1.0 8151A 03/29/07 1623 JSW 1 Page 1 of 5 Lebanon Rd. Mt. Juliet, uliet, TN 37122 (615) 758-EBSB ENVIRONMENTAL 0-767-5859 FaxO(615) 758-5859 SCIENCE CORP. Tax I.D. 62-06142H9 Est. 1970 REPORT OF ANALYSIS Mr. Brent Collins March 30, 2007 EMA Resources 29 Court Square Mocksville, NC 27028 ESC Sample # L285865-01 Date Received March 23, 2007 Description Tyson Site ID Sample ID TYSON Project : Collected By Boger Hartsell Collection Date 03/22/07 10:00 Result Det. Limit Units Limit Method Date/Time By Dil Parameter 2,4-D BDL 0.0020 mg/1 10. 8151A 03/29/07 1623 JSW 1 Surrogate Recovery 2,4-Dichlorophenyl Acetic Acid 100. Rec. B151A 03/29/07 1623 JSW 1 TCLP Semi-Volatiles 1,4-Dichlorobenzene BDL 0.10 ug/l 7.5 8270C 03/28/07 2120 BJF 1 2,4-Dinitrotoluene BDL 0.10 mg/1 0.13 B270C 03/28/07 2120 BJF 1 Hexachlorobenzene BDL 0.10 0.10 mg/1 mg/1 0.13 0.50 8270C 8270C 03/28/07 2120 BJF 1 03/28/07 2120 BJF 1 Hexachloro-1,3-butadiene BDL BDL 0.10 mg/l 3.0 8270C 03/28/07 2120 BJF 1 Hexachloroethane BDL 0.10 mg/1 2.0 8270C 03/2B/07 2120'BJF 1 Nitrobenzene Pyridine BDL 0.10 mg/1 5.0 8270C 03/28/07 2120 BJF 1 m&p-Cresol BDL 0.10 mg/1 400 8270C 03/28/07 2120 BJF 1 o-Cresol BDL 0.10 mg/1 200 8270C 03/28/07 2120 BJF 1 Pentachlorophenol BDL 0.10 mg/l 100 8270C 03/28/07 2120 BJF 1 2,4,5-Trichlorophenol BDL 0.10 mg/1 400 8270C 03/28/07 2120 BJF 1 2,4,6-Trichlorophenol BDL 0.10 mg/1 2.0 8270C 03/28/07 2120 BJF 1 Surrogate Recovery Nitrobenzene-d5 41.2 8 Rec. 8270C 03/28/07 2120 BJF 1 2-Fluorobiphenyl 53.1 8 Rec. 8270C 03/28/07 2120 BJF 1 p-Terphenyl-dl4 108. 8 Rec. 8270C 03/28/07 2120 BJF 1 Phenol-d5 38.1 % Rec. 8270C 03/28/07,2120 BJF 1 2-Fluorophenol 40.4 % Rec. 8270C 03/2B/07 2120 BJF 1 2,4,6-Tribromophenol 51.2 & Rec. 8270C 03/28/07 2120 BJF 1 BDL - Below Detection Limit Det. Limit - Estimated Quantitation Limit(EQL) Limit - Maximum Contaminant Level as established by the US EPA Note: The reported analytical results relate only to the sample submitted. This report shall not be reproduced, except in full, without the written approval from ESC. Reported: 03/30/07 15:56 Printed: 03/30/07 17:19 Page 2 of 5 7 Mt. Lebanon Rd. Mt. Juliet, TN 37122 (615) 758-5859 7� ENVIRONMENTAL 1-800-767-5859 Fax (615) 758-5859 SCIENCE CORP. Tax I.D. 62-0814289 Bet. 1970 REPORT OF ANALYSIS Mr. Brent Collins EMA Resources 29 Court Square Mocksville, NC 27028 ESC Sample # : L285865-02 Date Received March 23, 2007 Description Tyson Site ID Sample ID TYSON Project # Collected By Boger Hartsell Collection Date 03/22/07*10:00 Parameter Result Det. Limit Units Method Date Dil. Corrosivity Non=Corrosive 9040A 03/27/07 1 Ignitability See Footnote Deg. F D93 03/30/07 1 Reactive CN (SW846 7.3.3.2) BDL 0.125 mg/kg 9012A 03/30/07 1 Reactive Sulf.(SW846 7.3.4.1) BDL 25. mg/kg 9034/9030B 03/30/07 1 BDL - Below Detection Limit Det. Limit - Practical Quantitation Limit(PQL) ° Note: The reported analytical results relate only to the sample submitted. This report shall not be reproduced, except in full, without the written approval from ESC. Reported: 03/30/07 15:56 Printed: 03/30/67 17:19 L285865-02 (IGNITABILITY) - Did Not Ignite @ 170 Page 3 of 5 AttacimLent A List of Analytes with QC Qualifiers . Sample # Analyte Qualifier L285865-01 m&p-Cresol J4 2,4,5-TP (Silvex) J3 2,4-D J3 Tetrachloro-m-xylene J2 b Page 4 of 5 Attacbment B Explanation of QC Qualifier Codes Qualifier Meaning J2' surrogate recovery limits have been exceeded; values are outside lower control limits J3 The associated batch QC was outside the established quality control range for precision. J4 The associated batch QC was outside the established quality control range for accuracy. Qualifier Report Information ESC utilizes sample and result qualifiers as set forth by the.EPA Contract Laboratory Program and as required by most certifying bodies including NELAC. In addition to the EPA qualifiers adopted by ESC, we have implemented ESC qualifiers to'provide more information pertaining to our analytical results. Each qualifier is designated in the qualifier explanation as either EPA or ESC. Data qualifiers are intended to provide the ESC client with more detailed information concerning the potential bias of reported data_ Because of the wide range of constituents and variety of matrices incorporated by most EPA methods,it is common for some compounds to fall outside,of established ranges_ These exceptions are evaluated and all reported data is valid and useable unless qualified as 'R' (Rejected). Definitions Accuracy - The relationship of the observed value of a known sample to the true value of a known sample. Represented by percent recovery and relevant to samples such as: control samples, matrix spike.recoveries, surrogate recoveries, etc. 'Precision - The agreement between a set of samples or between duplicate samples. Relates to how close together the results are and is represented by Relative Percent Differrence. Surrogate - Organic compounds that are similar in chemical composition, extraction, and chromotography to analytes of interest. The surrogates are used to determine the probable response of the group of analytes that are chem- ically related to the surrogate compound_ Surrogates are added to the sample and carried through all stages of preparation and analyses. Control Limits (AQ) (SS) 2-Fluorophenol , 31=119 Nitrobenzene-d5 43-118 'Dibromfluoromethane 68-128 64-125 Phenol-d5 12-134 2-Fluorobiphenyl 45-128 Toluene-d8 76-115 69-118 2,4,6-Tribromophenol 51-141 Terphenyl-d14 ' 43-137 4-Bromofluorbbenzene 79-127 61-134 TIC - Tentatively Identified Compound: Compounds detected in saugsles that are not target compounds, internal standards, system monitoring compounds, or surrogates. Page 5 of 5 d a Y, ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM Facility Name: Tyson Foods y WWTP Name: Harmony NC Rendering Plant Permit Number: WQ000701NPDES Number: NC0005126 Monitoring Period: From 1/1/2007 To 3/31/2007 Pathogen Reduction (40 CFR 503.32) - Please indicate level achieved and alternative performed: Class A: Alternative 110 Alternative 2 Alternative 3 ;T A�temafi�ve4� Alternative 5 Alternative 6 t << If applicable to alternative performed (Class A only) indicate "Process to Further Reduce Pathogens": Compost t41 Heat Drying Heat Treatment 0 Thermophilic C Beta Ray€ ; Gamma REMO Pasteurization 0731, :.. ....... .. . -- -- Class-B: Alternative-1 Alternaffive 2 l Alternative 3 1 If applicable to alternative performed (Class B only) indicate "Process to Significantly Reduce Pathogens Lime Stabilization = Air Drying Com ostin - P g Aerobic Digestion El Anaerobic Digestion If ......... . applicable to alternative erformed (Class A or Class B) complete the following monitoring data: Parameter Allowable Level Pathogen. Density Number of Frequency Sample Analytical in Sludge Minimu Geo. Mean Maximu Units Rxcee- of Analysis Type Tech- 2 % 10 to the 6th ne power WN per 325203 332812 347826 MPN/g 0 Quarterly Grab gram of total , solids or 2 s 10 to Fecal Coliform the 6th power . 10007weh gram o Salmonella bacteria 3 MP4,(in lieu of fecal grams Vector Attraction Reduction (40 CFR 503331- RTIFICATION STATEMENT (please check the appropriate statement) "I certify, under penalty of law, that the Pathogen requirements in 40 CFR 503.32 n attraction reduction requirement in 40 CFR 503.33 have been met." and the vector '-' "I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32 and the vector attraction reduction requirement in 40 CFR 503.33 have not been met." (Please note if you check this statement attach an explanation why you have not met one or both of the requirements.) "This determination has been made under my direction and supervision in accordance with the system designed to ensure that qualified personnel properly gather and evaluate the information used to determine that the pathogen and vector attraction reduction requirements have been met. I am aware that there are significant penalties for false certification including fine and imprisonment." Dan Crowe - Plant Manager Brent Collins - Director of Technical Services Pre arer N nd Title (type or print) Land Apph a e and itle 'f applicable)(type or print) z /111-6 Y , Signature of Preparer Date Signature of Land Applier (ifAWA / RF (5/2003 )ate EMA Resources, Inc. For: Tyson 29 Court Square Mocksville NC ' 27.028 Entered 3/5/2007 Reported: 3/7/2007 Sample Remark Sample ID Parameter Cust ID Result Units Method Date Analyzed Analyst 07035-2.1, % Solids 1 4.8 % SM2540B 3/5/07 MD 07035-2.1 - Fecal Coliform MTF 1 333,333 MPN/g SM92210E 3/5/07 MD 07035-2.2 % Solids 2 4.6 % SM2540B 3/5/07 • MD 07035-2.2 Fecal Coliform MTF 2 347,826 MPN/g SM92210E 3/5/07 . MD •" '%Solids 3 4.76 % ;SM25406 3/5/07 MD j `.O'rv35-2.3 Fecal'Coliform MTF 3 336,134 MPN/g SM92210E 3/5/07 MD 07035-2.4 % Solids 4 4.9 % SM254013- :3/5/07 MD 07035.2.4 ` Fecal Coliform MTF 4 : , 326,531 MPN/g SM92210E 3/5/07 MD . 07035-Z5 % Solids 5 4.87 % SM2540B 3/5/07 MD 07035-2.5 Fecal Coliform MTF 5 328,542 MPN/g SM92210E 3/5/07 MD 07035-2.6 % Solids G 4.81 % SM2540B 3/5/07 MD 07035-2.6- Fecal Coliform MTF 6 332,640 MPN/g SM92210E 3/5/07 MD 07035-2.7 % Solids 7-.- 4.92 % SM2540B 3/5/07 MD 07035-2.7 Fecal Coliform MTF 7 325,203 MPN/g SM92210E 3/5/07 MD 07035-2.7, Geometric Mean 7 332,812 MPN/g dry wt. basis 3/6/07 MD Respectfully submitted, Dena Myers NC Cert #440, NCDW Cert #37755, 'A NCO0909 P.O. Box 228 9 Statesville, North Carolina 28687.704/872/4697 ANN UAL PATHOGEN AND VECTOR ATTRACTION -REDUCTION FORM Facility Name: Tyson Foods Y Permit Number: WQ00070.1 WWTP Name: Harmony NC Rendering Plant NPDES Number: NC0005126 Monitoring Period: From` 4/l/2007 To 6/31/07 Pathogen Reduction (40 CFR 503.32) - Please indicate level achieved and alternative performed: Class A: I Alternative 1 Alternative 2 Alternative 317 Alternative 4 Alternative 5 1: � Alternative 6 t If applicable to alternative performed (Class A only) indicate `Process to Further Reduce Pathogens' Compost I Heat Drying 0 Heat TreatmentED ThermophilicBeta Ra Gamma Ra Pasteurization Class B: Alternative 1 Z Alternative 2 ED Alternative 3 If applicable to alternative performed (Class B only) indicate "Process to Significantly Reduce Pathogens": Lime Stabilization 1 Air Drying i Composting Aerobic Digestion 0 Anaerobic Digestion If applicable to alternative performed (Class A or Class B) complete the following monitoring data: Parameter Allowable Level Pathogen Density Number of Frequency Sample Analytical in Sludge Minimu Geo. Mean MaximtAWPN1g Excee- of Analysis Tape' Tech- 2 x 10 to the 61h power MPN per 13710 48505 140350 Quarterly Grab gram of total solids or 2 x 10 to Fecal Coliform the 6th power 1000 mpn per gram of total solid, wei t), ;Salmonella bacteria 3 MPN per 4 �(in-lieu of fecal grams total solid colifonn) -(dij, weight) 'Vector Attraction Reduction (40 CFR 503.33) - Please indicate option performed: Fovector 1 10 Option 2 l.� Option 3 2 1 Option 4 Option 5 6 . Option 7 Option 8 ption 9 i�!, Option 10 attraction reduction options were performed CERTIFICATION STATEMENT (please check the appropriate statement) & "I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32 and the vector attraction reduction requirement in 40 CFR 503.33 have been met." "I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32 and the vector attraction reduction requirement in 40 CFR 503.33 have not been met." (Please note if you check this statement attach an explanation why you have not met one or both of the requirements.) "This determination has been made under my direction and supervision in accordance with the system designed to ensure that qualified personnel properly gather and evaluate the information used to determine that the pathogen and vector attraction reduction requirements have been met. I am aware that there are significant penalties for false certification including fine and imprisonment. Dan Crowe -Plant Manager Brent Collins - Director of Technical Services Pr arer Nam and Title (type or print) Land A I' e an applicable)(type or print) Signature of Preparer �� y�°� p Da e Signature of Land Applier (if�cp� RF (5/2003Date Analytical Results EMA Resources, Inc. For: Tyson 29 Court Square Mocksville NC 27028 Entered 6/26/2007 Reported: 6/29/2007 Sample Remark Sample ID Parameter Cust ID Result Units Method Date Analyzed Analyst 070626-5.1 % Solids 1 - 12.5 % SM2540B 6/27/07 MD 070626-5.1 Fecal Coliform MTF 1 128,000 MPN/g SM9221 CE 6/27/07 MD 070626-5.2 % Solids 2 11.4 % SM2540B 6/27/07 IVID 070626-5.2'` Fecal Coliform WW 2 '140,351 CFU/100mL SM9222D 6/27/07 MD 0'^526-5.3 %`Solids 3 12.4 % SM2540B 6/28/07 MD U.:-::;26=5'3 ' Fecal Coliform WW� - •3' ` 129;032 ` CFU/100mL' SM9222D 6/28/07 MD 107.0.626-5.4 % Solids 4 12.9 % SM2540B 6/27/07 MD 070626-5.4 = Fecal Coliform WW 4 23,256 CFU/100mL SM9222D 6/27/07 MD 070626-5.5 % Solids 5 11.7 % SM2540B 6/27107 `MD :070626-5.5 Fecal Coliform WW 5. 42,735 CFU/100mL SM9222D 6/27107 " MD 070626-5.6 % Solids 6 12.0 % SM2540B 6/27/07 MD 070626-5.6 Fecal Coliform WW 6 20,000 CFU/100mL SM9222D 6/27/07 MD 070626-5.7 % Solids 7 12.4 % SM2540B 6/27/07 MD 070626-5.7 Fecal Coliform WW 7 13,710 CFU/100mL SM9222D 6/27/07 MD .070626-5 j Geometric Mean .. 7 48,505 MPN/g dry wt. basis 6/27/07 MD Respectfully submitted, Dena Myers NC Cert #440, NCDW Cert #37755, S FDA NCO0909 - P.O. Box 228 • Statesville, North Carolina 28687.704/872/4697 ANN UAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM - Facility Name: T son F d s y oo s Permit Number: WQ000701 WWTP Name: Harmony NC Rendering Plant NPDES Number: NC0005126 Monitoring Period: From 7/l/2007 To 9/30/2007 Pathogen Reduction (40 CFR 503.32) - Please indicate level achieved and alternative performed: Class A: Alternative 1 U Alternative 2 1 :3 Alternative 3 El Alternative 4€b icable to alternative performer St 0 Heat Drying �y 1 Gamma Rav i Class B: . Alternative 141 pplicable to alternative performe Stabilization t Air erobic Digestions applicable to alternative performed i Parameter Allowable Level in Sludge . Mmimu; 2 x 10 to the 6th power MPN per 65617 gram of total solids or 2 x 10 to Fecal Coliform the 6th power L000 mpn per gram of total solid Alternative 5 ID Alternative 6 Class A only) indicate ".Process to Further Reduce Pathogens": Heat Treatment 0 EThermophilic . Pasteurization Alternative 2 0 Alternative 3 Class B only) indicate "Process to Significantly Reduce Pathogens": Yg �.-��-�; m Composting =" Aerobic Digestion lass A or Class B) complete the following monitoring data: Pathogen Density Number of Frequency Sample Anal3'tical r1404F053 eMaximu L3nits Excee- of Analysis Type Tech- 271186 MPN/g 0 Quarterly . Grab Salmonella bacteria 3 MPN per 4--r-T I (in lieu of fecal grams total solid colitorm) dry wei t) Vector Attraction Reduction (40 CFR 503.33) - Please indicate option performed: Option 1 i �l Option 2 Z Option 3 t Option 4 l Option 5 Option 6 ... - P ption 7 O tion 8 P Option 9 iYf Option 10 o vector attraction reduction options were performed L.'_: ......... CERTIFICATION STATEMENT (please check the appropriate statement) t "I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32 and the vector attraction reduction requirement in 40 CFR 503.33 have been met." J "I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32 and the vector attraction reduction requirement in 40 CFR 503.33 have not been met." (Please note if you check this statement attach an explanation why you have not met one or both of the requirements.) "This determination has been made under my direction and supervision in accordance with the system designed to ensure that qualified personnel properly gather and evaluate the information used to determine that the pathogen and vector attraction reduction requirements have been met. I am aware that there are significant penalties for false certification including fine and imprisonment." Dan Crowe - Plant Manager Brent Collins - Director of Technical Services Preparer N and Title (type or print) Land Appli ame and Title (if applicable)(type or print) t ature of Pre aver P Date Signature of Land, Tier t�� pp (if��c�� RF (5/2003)ate EMA Resources, Inc. For: Tyson 29 Court Square Mocksville NC 27028 Entered 7/9/2007 Repo, ted. 7/19/2007 Sample Remark Sample ID Parameter Cust ID Result Units Method Date Analyzed Analyst ,07079-1.1 % Solids 1 7.29 % SM2540B 7/9/07 CL 07079-1.1 'Fecal Coliform MTF 1 219,479 MPN/g SM9221 CE 719/07 CL 07079-1.2 % Solids 2 11.8 % SM2540B 7/9/07 CL. `07079-1.2 ":'Fecal Coliform MTF 2 135,593 MPN/g SM92210E 7/9/07 CL - s: '0' 79-1.3 % Solids 3 7.62 % SM2540B 7/9/07 CL. ,0, _ A9-1.3 Fecal Coliform MTF 3 65,617 MPN/g SM92210E 7/9/07 CL ,07079-1.4 % Solids 4 8.09 . % SM2540B 7/9/07 CL 07079-1.4 .. Fecal Coliform MTF 4 111,248 MPN/g SM92210E 7/9/07 CL = 07079-1.5 % Solids 5 -5.9 , % SM2540B 7/9/07 CL t07079-1.5 Fecal Coliform MTF $ 271,186 MPN/g SM92210E 7/9/07 CL y07079-1.6 % Solids 6 7.38 % SM2540B 7/9/07 CL `07079-1.6 Fecal Coliform MTF 6 216,802 MPN/g SM92210E 7/9/07 CL' 07079-1.7 % Solids 7 8.93 % SM2540B 7/9/07 CL '07079-1.7 Fecal Coliform MTF 7 100,784 MPN/g SM92210E 7/9/07 CL 07079-1.7" Geometric Mean 7 144,053 MPN/g dry wt. basis' 7/10/07 CL Respectfully submitted, Dena Myers NC Cert #440, NCDW Cert #37755, ' FC>A NCO0909 P.O. Box 228 • Statesville, North Carolina 28687. 704/872/4697 r.l.i. UA-L rA I ilt3GEN AND VECTOR ATTRACTION REDUCTION FORM FacilityN..I u ame: Tyson Foods Permit Number: WQ000701 WWTP Name: Harmony NC Rendering Plant b NFDES Number: NC0005126 Monitoring Periods From 10/1 /2007 To 12/31 /2007 Pathogen Reduction (40 CFR 503.32) - Please indicate level achieved and alternative performed: Class A: Alternative 1 U Alternative 2 . -�]l Alternative 3 Alternative 40 Alternative 5 -� Alternative 6 If applicable to alternative performed (Class A only.) indicate "Process to Further Reduce Pathogens": Compost t Heat D n r� g g ' ' Heat Treatment Thermophilic l= Beta Ray� . Gamma Ray Li Pasteurization 0= Class B: Alternative 1 ?�' Alternative 2 ? Alternative 3 If applicable to alternative performed (Class B only) indicate "Process to Significantly Reduce Pathogens": Lime Stabilization yinComposting 01 Aerobic Digestion 0 g Air Dr Anaerobic Digestion►�? If applicable to alternative performed (Class A or Class B) complete the following monitoring data: Parameter Allowable Level Pathogen Density Number of in Frequency Sample Analytical Sludge Minimu Geo. Mean Maximu Units E wee- 2 x 10 to the 6th of Analysis Type Tech- . powerWNper 20000 20000 20000 gram of total MPN/g 0 Quarterly Grab solids or 2 s 10 to Fecal Coliform the 6th power 1000 mpn per gram of total solid dry weight) r ;Salmonella bacteria .3 WN per 4 (in lieu offecal .grams total solid coliform) drt wei t Vector Attraction Reduction (40 CFR 503.33) - Please indicate option performed: Option 1 Ll Option 2 Option.) Option 4 is Option 5 Option 6 C �ption 7 P'Option 8 Option 9 Option 10 o vector attraction reduction options were performed CERTIFICATION STATEMENT (please check the appropriate statement) "I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32 and the vector attraction reduction requirement in 40 CFR 503.33 have been met." "I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32 and the vector attraction reduction requirement in 40 CFR 503.33 have not been met." (Please note if you check this statement attach an explanation why you have not met one or both of the requirements:) "This determination has been made under my direction and supervision in accordance with the system designed to ensure that qualified personnel properly gather and evaluate the information used to determine that the pathogen and vector attraction reduction requirements have been met. I am aware that there are significant penalties for false certification including fine and imprisonment." Dan Crowe -Plant Manager Brent Collins - Director of Technical Services Yt�parer N and Title (type or print) Land Appli ame and T�tle (if a licable .U)" ( PP )(type or print) Signature of Preparer Date Signature of Land Applier (i �� RF (5/2003Pate w Analytical Results EMA Resources, Inc. For:. Tyson '_9 Court Square Vlocksville NC 27028 Entered.. 11/30/2007 Reported: 12/6/2007 .'ample Remark ;ample ID Parameter Cust ID Result. Units Method Date Analyzed Analyst =)71130-7.1 % Solids 1 3.8 % SM2540B 11/30/07 MD 071130-7:1 -Fecal Coliform MTF 1 <20000 MPN/g SM92210E 11/30/07 MD )71130-7.2 % Solids 2 5.7 % SM2540B 11/30/07, •CL 07-1-1304.2 Fecal-Coliform MTF 2 <20000 MPN/g SM92210E 11/30/07 CL 77,.t 0-7.3 % Solids 3 3.4 % SM2540B 11/30/07 MD = 50=7.3 Fecal Coliform MTF 3 <20000 MPN/g SM92210E = 11/30/07 MD 47:1<1°WJA % Solids 4 5.04 % SM2540B 11/30/07 MD ; )Z1130-7.4 ... Fecal Coliform MTF 4 <20000 MPN/g SM92210E 11/30/07 MD 071130-7.5 % Solids 5 5.22 % SM2540B 11/30/07 -. MD ,•)71130J.5 Fecal Coliform MTF 5 <20000 MPN/g SM92210E 11/30/07 MD 071130-7.6 % Solids 6 3.11 % SM2540B 11/30/07 MD )71130-7.6 Fecal Coliform MTF 6 <20000 MPN/g SM92210E 11/30/07: MD . 071130-7.7 % Solids 7 4_27 % SM254013- .11/30/07' CL 071130-7.7 Fecal Coliform MTF 7 <20000 MPN/g SM92210E 11/30/07 CL )71130-7.7 Geometric Mean 7. -<20000 MPN/g dry wt. basis 12/1/07 CL .Respectfully submitted, ;Dena Myers NC Cert #440, °NCDW Cert #37755, ,EPA NCO0909 i - a i . P.O. Box 228 • Statesville, North Carolina 28687. 704/872/4697 SITE MONITORING REPORT In pounds per acre ' Project: Tyson Foods Owner: D. Dewitt Permit #: W00000701 Crop: Bermuda Weather Code 2 Operator: Same Field #: RM10-10 Acres: 36.4 Site Code 2 Application Method injection Date Gallons /. Solids Gal/Ac Dt/AC PAN NO3-NO2 NH3 P K Pb Zn Cu Ni Cd As Hg Se Mo 1/4/2007 19,500 10.57 535.7143 0.2361 13.3652 0.0005 8.9256 3.3058 0.9445 0.0094 0.0312 0.0283 0.0090 0.0014 0.0002 0.0002 0.0004 0.0052 1/8/2007 19,500 10.57 535,7143 0.2361 13.3652 0.0005 8.9258 3.3058 0,9445 0.0094 0.0312 0.0283 0.0090 0.0014 0.0002 0.0002 0.0004 0.0052 1/9/2007 26,000 10.57 714.2857 0,3148 17.8203 0.0006 11.9008 4.4077 1.2593 0.0126 0.0416 0.0378 0.0120 0.0019 0.0003 0.0003 0.0006 0.0069 1/10/2007 39,000 10.57 1071,429 0.4723 26.7304 0.0009. 17.8511 6.6115 1.8890 0.0189 0.0623 0.0567 0.0179 0.0028 0.0005 0.0004 0.0009 0.0104 1/11/2007 19,500 10.57 535.7143 0.2361 13.3652 0.0005 8.9256 3.3058 0.9445 0.0094 0.0312 0.0283 0.0090 0.0014 0.0002 0,0002 0.0004 0.0052 1/15/2007 39,000 10.57 1071.429 0.4723 26.7304 0.0009 17.8511 6.6115 1.8890 0.0189 0.0623 0.0567 0.0179 0.0028 0.0005 0.0004 0.0009 0.0104 1/16/2007 32,500 10.57 892.8571 0,3935 22.2754 0.0008 14.8760 5.5096 1.5742 0.0157 0.0519 0.0472 0.0150 0.0024 0.0004 0.0003 0.0007 0.0087 1/19/2007 19,500 10.57 535.7143 0.2361 13.3652 0.0005 6,9256 3.3058 0.9445 0.0094 0.0312 0.0283 0.0090 0.0014 0.0002 0.0002 0.0004 0.0052 1/20/2007 26,000 10.57 714.2857 0.3148 17.8203 0.0006 11.9008 4.4077 1.2593 0.0126 0.0416 0.0378 0.0120 0.0019 0.0003 0.0003 0.0006 0.0069 1/23/2007 39,000 10.57 1071.429 0.4723 26.7304 0.0009 17.8511 6.6115 1.8890 0.0189 0.0623 0.0567 0.0179 0.0028 0,0005 0.0004 0.0009 0,0104 12/3/2007 39,000 7.30 1071.429 0.3262 15.5647 0.0007 9.9803 5.1532 1.3046 0.0046 0.0744 0.0137 0.0033 0.0033 0.001 0.0003 0.0010 0.0003 l�I Totals: Annual: 318,500 8750 3,7106 207.1328 0.0074 137.9135 52.5359 14.8425 0.1399 0.5211 0.4198 0.1319 0.0236 0.0051 0.0030 0.0071 0,0748 Total Cumulativeg 0.2662 2.0344 1.2375 0.2498 0.0415 0.02 5 0.0068 0.0230 0.1398 Prior Years Cumulatives 0.1263 1.5133 0.8177 0.1179 0.0179 0.0194 0.0038 0.0159 0.0650 Annual Dry Tons 135.0669 SOIL MONITORING Soil DH Lime Appl. Ton/AC 6.6 0 Weather Code: 1) >90F 2) 70-90F 3)32-70F "' A) Less than 112 inch rainfall B) Greater than 1/2 inch rainfall in past 24 hours Site Condition Code: 1) Excessively Dry 2) Dry 3) Moist 4) Wet Z-Z;;24-1 esentative of EMA Resources, Inc., hereby certify that this site was operated in compliance with the conditions of Nondischarge Permit No. WQ0000701 R3 SITE MONITORING REPORT In pounds per acre Project: Tyson Foods Owner: Ralin Matthews Permit #: W00000701 Crop: Small Grain Weather Code 2 Operator: Same Field #: M08.01 Acres: 66.6 Site Code 2 Injection • Date Gallons % Solids Gal/Ac DUAc PAN NO3-NO2 NH3 P K Pb Zn CLI NI Cd As Hg Se Mo 12/4/2007 52,000 7.30 780,7808 0.2377 11.3424 0.0005 7.2729 3.7553 0.9507 0.0033 0.0542 0.0100 0.0024 0.0012 0.0002 0.0008 0.0002 12/5/2007 52,000 7.30 780.7808 0.2377 11.3424 0.0005 7,2729 3.7553 0.9507 0.0033 0,0542. 0.0100 0.0024 0,0024 0.0012 0.0002 0.0008 0.0002 12/6/2007 71,500 7.30 1073.574 0.3268 15.5959 0.0007 10.0003 5.1635 1.3072 0.0046 0.0745 0.0137 0.0033 0.0033 0.0017 0,0003 0.0010 0.0003 12/7/2007 32,500 7.30 487.988 0.1485 7,0890 0.0003 4.5456 2.3471 0.5942 0.0021 0.0339 0.0062 0.0015 0.0015 0.0008 0,0001 0.0005 0.0001 12/10/2007 39,000 7.30. 585.5856 0.1783 8.5068 0.0004. 5.4547 2.8165 0,7130 0.0025 0.0406 0.0075 0.0018 0,0018 0.0009 0.0001 0.0006 0.0002 12/11/2007 26,000 7.30 390.3904 0.1188 5.6712 0.0002 3.6365 1.8777 0.4754 0.00.17 0.0271 0.0050 0.0012 0.0012 0.0006 0:0001 0.0004 0.0001 0 , 0,0000 Q0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 Totals: Annual: 273,000 4099.099 1,2478' 59.5478 0.0025 38.1829 19.7153 4.9912 0.0175 0.2845 0.0524 0.0125 0,0101 0.0065 0.0010 0.0040 0,0012 Total Cumulatives 0.1416 1.8288 1.0216 0.1010 0.0204 0.0148 0.0026 0.0075 _ 0.0413 Prior Years Cumulatives 0.1241 1.5443. 0,9692 0.0885 0.0103 0.0083 0.0016 0.0035 0.0401 Cumulative Dry Tons 83.1039 $OIL MONITORING Soil PH Lime Appl. Ton Weather Code: 1) >90F 2) 70-90F 3)32.70F '"'"'" A) Less than 1/2 inch rainfall 8) Greater than 1/2 inch rainfall In past 24 hours Site Condition Code: 1) Excessively Dry 2) Dry 3) Moist 4) Wet representative of EMA Resources, Inc., hereby certify that this site was operated in compliance with the conditions of Nondischarge Permit No. W00000701' SITE MONITORING REPORT In pounds per acre Project: Tyson Foods Owner: Ralin Matthews Permit #: W00000701 Crop: Rye Weather Code 2 Operator: Same Field #: M010-2 Acres: 83,0 Site Code 2 Application Method Injection Date Gallons *A Solids a c DUAo PAN NO3-NO2 H PPb Zn Cu Ni Cd As r19 Se. o 3/19/2007 39,000 4.47 469.8795 . 0.0876 7.9459 0.0002 5.2201 1.9969 0.4905 0.0012 0.0151 0.0032 0.0012 0.0002 0.0001 0.0001 0.0002 0.0014 3/20/2007 45,500 4.47 548.1928 0.1022 9.2702 0.0002 0.0002 2.3298 0.5722 00014 0.0176 0.0037 0.0014 0,0002 0.0001 0,0001 0.0002 0,0016 3/21/2007 52,000 4.47 626.5060 0.1168 10.5945 0.0002 0.4111 2.6626 0.6540 0.0016 0.0201 0.0042 0.0016 0.0002 0.0001 0,0001 0.0002 0.0019 3/22/2007 52,000 4.47 626.5060 0.1168 10.5945 0,0002 1.7143 2.6626 0,6540 0.0016 0.0201 0.0042 0.0016 0.0002 0.0001 0.0001 0.0002 0.0019 3/23/2007 19,500 4.47 234,9398 0.0438 3.9729 0.0001 0.0057 0.9985 0.2452 0.0006 0.0075 O.DO16 0.0006 0.0001 0.0000 0.0000 0.0001 0.0007 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 O.D000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0,0000 0.0000 0.0000 0.0000 0.0000 0.0000 0,0000 0.0000 0.0000 0.0000 Totals: Annual: 208,000 2506,0241 0.4671 42.3781 '0.0009 7.3514 10:6503 2.6159 0.0065 0.0803 0,0168 0.0065 0.0009 0.0003 0.0004 0.0008 0.0075 Total Cumulatives 0.0921 1.4689 0.9023 0.0524 0.0075 0.0079 0.0017 0.0107 0.0537 Prior Years Cumulatives 0.0856 1.3886 0.8855 0.0459 0.0066 0.0076 0.0013 0.0099 0.0462 Cumulative Dry Tons 38,7710 SOIL MONITORING Sol p L me App. Ton/AC Code: 1 Moist Wet 500.00 125.00 C4V04111,11116L - C representative of EMA Resources, Inc., hereby certify that this site was operated in compliance with the conditions of Nondischarge Permit No. WQ0000701 N/A SITE MONITORING REPORT In pounds per acre Project: Tyson Foods Owner: Ralin Matthews Permit #: W00000701 Crop: Soybeans Weather Code 2 Operator: Same Field #: M010-3 Acres: 20.6 Site Code 2 Application Method injection Date Gallons 0/6So ids Gal/Ac Dt/Ac PAN NO3-NO2 NH3 P K Pb Zn Cu Ni Cd As Hg Se Mo 3/13/2007 39,000 4.47 1893.204 0.3529 32.0150 0.0007 21.0323 8.0459 1.9762 0:0049 0.0607 0.0127 0.0049 0.0007 0.0002 0.0003 0.0006 •0.0056 3/14/2007 39,000 4.47 1893.204 0.3529 32.0150 0.0007 21.0323 8.0459 1.9762 0.0049 0.0607 0,0127 0.0049 0.0007 0.0002 0.0003 0.0006 0.0056 3/15/2007 97,500 4.47 4733.01 6.8822 80.0375 0.0018 52.5808 20.1148 4.9405 0.0124 0.1517 0.0318 0.0124 0.0018 0.0005 0.0007 0.0016 0.0141 3/16/2007 19,500 4.47 946.6019 0.1764 16.0075 0.0004 10.5162 4.0230 0.9881 0.0025 0.0303 0.0064 0.0025 0,0004 0.0001 .0.0001 0.0003 0.0028 3/19/2007 39,000 4.47 1893.204 0.3529 32.0150 0.0007 21.0323 8.0459 1.9762 0.0049 0.0607 0.0127 0.0049 0.0007 0.0002 0.0003 0.0006 0.0056 0 0.0000 0.0000 0.0000 0.00001 0.0000 0.0000. 0.0000 0.0000 0,0000 0.000.0 0.0000 0.0000. 0.0000 0.0000 0.0000 Totals: Annual: 234,000 11359.22 2.1173 0'0296 0.3642 0.0762 0.0296 0.0042 0.0013 0.0017 0.0038 0.0339 1 192.0900 0.0042 126. 939 48.2755 11.857 Total Cumulatives 0.1097 1.8985- _ 0,9760 0.0836 0.0086 0.0094 0.0026 0.0139 0.0702 Prior Years Cumulatives 0.0801 1.5343 0.8998 0.0540 0.0044 0.0081 0.0009 0.0101 0.0363 Annual Dry Tons 43.6174 SOIL MONITORING Soil H Lime Appl. Ton/AC representative of EMA Resources, Inc., hereby certify that this site was operated in with the conditions of Nondischarge Permit No. WQ0000701 SITE MONITORING REPORT In pounds per acre Project: Tyson Foods Owner: G. Welch Permit #: W00000701 Crop: Bermuda Weather Code 2 Operator: Same Field #: MT01-02 Acres: 33.9 Site Code 2 Application Method injection ,- Date Gallons % Solids Gal/Ac Dt/Ac PAN NO3-NO2 NH3 P Pb Zn Cu Ni Cd As Hg Se Mo 5/14/2007 45,500 7.67 1342.183 0.4293 24.2811 0.0009 16.6562 6.0100 1.2878 0.0077 0.0567 0.0120 0.006D 0.0009 0.0006 0.0003 0.0008 0.0052 5/15/2007 26,000 7.67 766.9617 0.2453 13.8749 0.0005 9.5178 3.4343 0.7359 0.0044 0.0324 0.0069 0.0034 0.0005 0.0003 0.0002 0.0004 0.0029 9/10/2007 78,000 5.26 2300.885 0.5047 46.1490 0.0010 34.9239 10.3964 3.3309 0.0061 0.1342 0.0141 0.0050 0.0010 0.0018 0.0004 0.0025 0.0050 9/11/2007 78,000 5.26 2300.885 0.5047 46.1490 0.0010 34.9239 10.3964 3.3309 0.0061 .0.1342 0.0141 0.0050 0.0010 0.0018 0.0004 0.0025 0.0050 9/12/2007 71,500 5.26 2109.145 0,4626 42.3033 0.0009 32.0136 9.5301 3.0533 0.0056 0.1231 0.0130 0.0046 0.0009 0.0017 0.0004 0.0023 0.0046 9/13/2007 78,000 5.26 2300.885. 0.6047 46.1490 0.0010 34.9239 10.3964 3.3309 0.0061 0.1342 0.0141 0.0050 0.0010 0.0018 0,0004 0.0025 0,0050 0 0.0000 0.0000 0.0000 0.0000 0.0000 0,0000 0,0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0,0000 0 0.0000 0.0000 0.0000 0.0000 ' 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0,0000 0.0000 0.0000 0 0.0000 0.0000 0.0000 0,0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 Totals: Annual: 377,000 11120.94 2.6513 218,9063 0.0053 162.9593 50.1635 15,06981 0.0359 0.6148 0.0742 0.0292 0.0053 0.0081 0.0021 0.0111 0.0279 Total Cumulatives 0.3485 2.5037 1.9486 0.1897 0.0303 0.0169 0.0072 0.0257 0.1980 Prior Years Cumulatives 0.3126 1.8889 1.8744 0.1605 0.0250 0.0088 0.0051 0.0146 0.1701 Annual Dry Tons 89.87 55 SOIL MONITORING Soll H Lime A I. Ton/AC Weather Code: 1) >90F 2) 70-90F 3)32-70F '"' A) Less than 1/2 inch rainfall B) Greater than 1/2 inch rainfall in past 24 hours Site Conditlon Code: 1) Excessively Dry 2) Dry 3) Moist 4) Wet 4reprsentative of EMA Resources, Inc., hereby certify that this site was operated in compliance with the conditions of Nondischarge Permit No. W00000701 SITE MONITORING .REPORT w- ' In pounds per acre Project: Owner:, Tyson Foods . G. Welch Permit #: W00000701 Crop: Bermuda Weather Code 2 Operator: Same Field #: MT01.03 Acres: 7.5 Site Code Application Method 2 injection Date Gallons % Solids Gal/Ac Dt/Ac PAN -NO3-NO2 NH3P K Pb Zn Cu Ni Cd As Hg Se Mo 10/8/2007' 39,000 5.26 5200 1.1406 104.2968 0.0023 78,9280 23.4959 7.5278 0.0137 0,3034 0.0319 0.0114 0.0023 0.0041 0.0009 0.0057 0.0114 10/9/2007 39,000 5.26 5200 1.1406 104,2968. 0.0023 78,9280 23.4959 7.5278 0.0137 0.3034 0.0319 0.0114 .0.0023 0.0041 0.0009 0.0057 0.0114 0 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0,0000 0.0000 0.0000 0.0000 0.0000 0.0000 Totals: Annual: 78,000 10400 2,2812 _15.0556 0:0274 0.6068 0.0639 0,0228 0.0046 0.0082 0.0018 0.0114 0.0228 1 208, 935 0.0046 157.E 61 46.9918 Total Cumulatives _ 0:3322 ' 2.4223 1.8109 0.1827 0.0295 0.0166 0.0069 0.0251 0.1868 - Prior Years Cumulatives 0.3048' 1.8155 1.7470 0.1599 0.0249 0.0084 0,0051 0.0137 0.1640 Annual Dry Tons 17,1087 SOIL MONITORING .Soil PH Lime A l: Ton/AC 5.1 1.5T/acre- JSite Condition Code: 1) Excessively Dry 2) Dry 3) Moist 4) Wet resentative of EMA Resources, Inc., hereby certify that this site was operated in compliance with the conditions of Nondischarge Permit No. W00000701 ., — 0 m O d O O n m (D (D 0) < 61 m O m D CD CD O C n CD N K n O O W ca 2 0 r r CD 0 V i Ut o . n Zz' m `D 0 D -4 ono o_C3 (.�NN00 C c O O CC:,) 0 0 0 0 01 N Ql 0 WSO0 I N O O O O O Cl O S.O O O U) (n O Ut Ut N N N N N m m m m m N W W - N (w0 (Wn (w1) b. (w0 O O O p p V V( 0 D 1 N (D (Ds Ut m A A A a A N OOp O o 0 0 o O O V 000Nmm(nm A 00 S O U)(n 'm 000.-(ninoo Ono. cnm- S 0 0 0 w N N ON v- N O O O m m m m m m oo$wmmoa._ N oo ammW" C O O S N s W N O O O O O O O O O O O N N O 0 0 0 0 0 0 0 0 0 V mSn moa m0 mmoS W OOOmwwww -+N O O00 oOOOo Z. 2(D 0WW CD N V v (D SOO (D OOOA U) U)A0 (Dm-I 00000000 y O 0 0 0 0 0 0 0 0 %na)o 00000000 0) W 0) pS O O OO N N O 000003 O (;)0) W coco O O O O Op O O o O O O' N a ON p 0 0 00 0 0 0 0 0 N m Cl) 4 a -I O O O O V V W U I O O O U) A .A ( W 0o0 00000000 OSOOOOOO N (0VOOS_0)(00) ON O s 0o0 00000000 goo V O) W 00 00000' OOOONN: m0 (n OOO N V � 18 O o_o OOo00000 O O O o 0 0 0p 0 o 0 o A S 2 S S S O O O S O N (D O O o O m m w A O O O O O o 0 0 0 0 0 6 N O O O O N a -� O O O O O O O O W W N (0 V W 0 0 0 W V V m m O O O O O O o 0 0 o 0 -+ O O O o 0 0 0 0 0 A V N W S W O i I O O O O o 0 0 0 O O O O V V w U1 0 0 0 (n A A N w 0 0'U N j �• m m � o -• m y � N m 0 J O N D (D� v N N OD O (D - 0 3 a m m 0 d Q) --I m O Z a m -07�7 � N UJ/Z/•� um V TO N { t . SITE MONITORING REPORT. In pounds per acre Project: Tyson Foods Owner: G. Welch Permit M W00000701 Crop: Bermuda Weather Code 2 Operator: Same Field #: MT01-06 Acres: • 22.30 Site Code 2 Application Method injection Date Gallons % Solids Gal/Ac DVAc PAN NO3-NO2 NH3 P K Pb Zn Cu Ni Cd As Hg Se Mo 10/15/2007 13,000 5.26 582,9596 0.1279 11.6925 0.0003 8.8484 2.6341 0.8439 0.0015 0.0340 0,0036 0,0013 0.0003 0.0005 0.0001 0.0006 0.0013 10/16/2007 39,000 5.26 1748.879 0,3836 35.0774 0.0008 26.5453 7.9022 2.5318 0.0046 0.1020 0.0107 0.0038 0.0008 0.0014 0.0003 0.0019 0.0038 10/17/2007 39,000 5.26 1748.879 0.3836 35.0774 0.0008 26.5453 7.9022 2.5318 0.0046 0.1020 0.0107 0.0038 0.0008 0.0014 0,0003 0.0019 0,0038 10/18/2007 39,000 5.26 1748.879 0.3836. 35.0774 0.0008 26.5453 7.9022 2.5318 0.0046 0.1020 0.0107 0.0038 0.0008 0.0014 0.0003 0.0019 0.0038 10/19/2007 19,500 5.26 874.4395 0.1918 17.5387 0,0004 13.2726 3.9511 1.2659 0,0023 0.0510 0,0054 0.0019 0.0004 0.0007 0.0002 0.0010 0.0019 Totals: Annual: 149,500 6704.636 1.4705 0.0176 0.3911 0,0412 0.0147 0,0029 0.0053 0.0012 0.0074 0.0147 134.4633 0.0029 101.7570 30.2918 9.7051 Total Cumulatives 0.1214 1.3708 1.3689 0.0750 0.0146 0,0113 0.0037 0.0192 0.1185 Prior Years Cumulatives 0.1038 0.9797 1.3277 0.0603 0.0117 0.0060 0.0025 0.0118 0.1038 Annual Dry Tons 32.7916 SOIL MONITORING Soil PH Lime Appl. Ton/AC Weather Code: 1) >90F 2) 70-90F 3)32-70F •""' A) Less than 1/2 inch rainfall B) Greater than 112 inch rainfall in past 24 hours . Site Condition Code: 1) Excessively Dry 2) Dry 3) Moist 4) Wet representative of EMA Resources, Inc., hereby certify that this site was operated in compliance with the conditions of Nondischarge Permit No. W00000701 SITE MONITORING REPORT In pounds per acre Project: Tyson Foods Owner: G. Welch Permit #: W00000701 Crop: Bermuda Weather Code 2 Operator: Same Field #: MT01-09 Acres: 9.60 Site Code 2 Application Method Injection Date Gallons % Solids GaUAc Dt/Ac PAN NO3-NO2 NH3 P Pb Zn Cu Ni Cd As Hg Se Mo 10/12/2007 78,000 5,26 8125 1.7822 162.9637 0.0036 123.3250 36.7124 11.7622 0.0214 0.4741 0.0499 0.0178 0.0036 0.0064 0.0014 0.0089 0.0178 10/15/2007 26,000 5.26 2708.333. 0.5941 54.3212 0.0012 41.1083 12.2375 3.9207 0.0071 0.1580 0.0166 0.0059 0.0012 0.0021 0.0005 0.0030 0.0059 0 0,0000 0.0000 0.0000 0,0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 Totals: Annual: 104,000 10833.33 2.3762 1 21 .2849 0.0048 164.4334. 48.9498 15.6830 0.0285 0.6321 0.0665 0.0238 0.0048 0.0066 0,0019 0.0119 0.0238 Total Cumulatives 0.1704 1.7314 1.2874 0.0959 0.0192 0.0146 0.0046 0.0226 0.1374 Prior Years Cumulatives 0.1419 1.0993 1.2209 0.0721 0.0144 0.0060 0.0027 0.0107 0.1136 Annual Dry Tons 22.8116 SOIL MONITORING Soil DH Lime Appl. Ton/AC 5.2 1.5 T/acre Weather Code: 1) >90F 2) 70-90F_ 3)32-70F "" ' A) Less than 1/2 inch rainfall B) Greater than 1/2 inch rainfall in past 24 hours Site Condition Code: 1) Excessively Dry 2) Dry 3) Moist 4) Wet 44�srro-14'- sentative of EMA Resources, Inc., hereby certify that this site was operated in compliance with the conditions of Nondischarge Permit No. WQ0000701 SITE MONITORING REPORT • In pounds per acre Project: Tyson Foods . 2 Owner: _ G. Welch Permit #:. W00000701 Crop: Bermuda Weather Code Operator: Same Field #: MT01-10 Acres: 38.70 Site Code 2 Application Method Injection Date Gallons % Solids GaI/AC VIJAc PAN NO3-NO2 NH3 P Pb Zn Cu NI Cd As Hg Se Mo 7/6/2007 13,000 12.61 335,9173 0.1766 4,8402 0.0074 4.3806 2.8262 0.6006 0.0018 0.2360 0.0057 0.0018 0.0004 0.0008 0.0001 0.0002 0,0166 7/9/2007 39,000 12.61 '1007.752 0.5299 14.5207 0.0223 13.1418 8.4786 1.8017 0.0053 0.7080 0.0170 0,0053 0.0011 0.0025 0.0004 0.0006 0.0498 7/10/2007 39,000 12.61 1007,752 0.5299 14.5207 0.0223 13.1418 8.4786 1.8017 0.0053 0.7080 0.0170 0.0053 0.0011 0.0025 0.0004 0.0006 0,0498 7/11/2007 39,000 12.61 1007.752 0.5299 14.5207 0.0223 13.1418 8.4786 1.8017 0.0053 .0.7080 0.0170 0.0053 0,0011 0.0025 0.0004 0.0006 0.0498 7/12/2007 32,500 12.61 839,7033 0.4416 12.1006 0.0185 10,9515 7.0655 1,5014 0.0044 0.5900 0.6141 0.0044 0.0009 0,0021 0.0004 0.0005 0.0415 7/13/2007 32.500 12.61 839.7933 0,4416 12.1006 0.0185 10.9515 7.0655 1.5014 0.0044 0.5900 0.0141 0.0044 0.0009 0.0021 0.0004 0.0005 0.0415 7/14/2007 26,000 12.61 671.8346 0.3533 9.6805 0.0148 8.7612 5.6524 1,2011 0.0035 0,4720 0.0113 0.0035 0.0007 0.0017 0.0003 0.0004 0.0332 10/22/2007 13,000_ 5.26 335.9173 0.0737 4.1882 0.0001 5.0987 1.5178 0.4863 0.0009 0.0196 0.0021 0.0007 0.0001 0.0003 0.0001 0.0004 0.0007 0 0,0000 0.0000 0.0000 0,0000 0.0000 0.0000 0.0000 ; 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000' 0 0.0000 0,0000 0.0000 0.0000 0.0000 0,0000 0.0000 0,0000 0.0000 0.0000 0.0000 0.0000 0,0000 0.0000 0.0000 Totals:. Annual: 234,000 6046.512 3.0765 4.0314 0.0982 0.0308 0.0062 0.0147 0.0025 0.0040 0.2830 86.4720 0.1263 79,6692 49.5633 10.696010.0309 Total Cumulatives 0.2407 5.04.78 0.4741 0.1693 0.0276 0.0179 0.0053 0.0077 0.3833 Prior Years Cumulatives 0.2098 1.0164 0,3759 0,1385 0.0214 0.0032 0.0028 0.0037 0.1003 Annual Dry Tons 119.0614 SOIL MONITORING Soil H Lime Appl. Ton/AC Weather Code: 1) >90F 2) 70-90F 3)32-70F """' A) Less than 1/2 inch rainfall B) Greater than 1/2 inch rainfall in past 24 hours . Site Condition Code: 1) Excessively Dry 2) Dry 3) Moist 4) Wet ;or I, representative of EMA Resources, Inc., hereby certify that this site was operated in compliance with the conditions of Nondischarge Permit No. W00000701 SITE MONITORING REPORT In pounds per acre Project: Tyson Foods Owner: G. Welch Permit #: WQ0000701 Crop: Bermuda Weather Code 2 Operator: Same Field #: MT01-13 Acres: 25.10 • Site Code 2 Application Method injection Date Gallons % Solids GaVAc DIIAc PAN - NO3-NO2 NH3 P K Pb Zn Cu Ni Cd As Hg Se Mo 7/2/20D7 26,000 12.61 1035,857 0.5447 14.9256 0.0229 13.5084 8.7151 1.8520 0.0054 0.7277 0.0174 0.0054 0.0011 0.0026 0.0004 0.0007 0.0512 7/3/2007 39,000 12.61 1553.785 0,8170 22.3885 0.0343 20.2625 13.0726 2.7779 0.0082 1.0916 0.0261 0.0082 0.0016 0.0039 0.0007 0.0010 0.0768 7/5/2007 39,000 12.61 1553.785 0.8170 22.3885 0.0343 20,2625 13.0726 2.7779 0.0082 1.0916 0.0261 0.0082 0,0016 0.0039 0,0007 0.0010 0.0768 7/6/2007 26,000 12.61. 1035.857 0.5447 14.9256 0.0229 13.5084 8.7151 1.8520 0.0054 0.7277 0.0174 0.0054 0.0011 0.0026 0.0004 0.0007 0.0512 0 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0,0000 0.0000 0.0000 0.0000 0.0000 0 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 Totals: Annual: 130,000 5179.283 2.1235 1 74.6282 0.1144 67.5418 43.5753 9.2598-1 0.0272 3.6385 0.0872 0.0272 0.0054 0.0131 0.0022 0.0033 0.2560 Total Cumulatives 0.3721 5.2168 0.6487 0.5199 0,0471 0.0184 0.0067 0.0092 0.4173 Prior Years Cumulatives 0.3449 1.5783 0.5615 0.4927 0.0417 0.0053 0.0045 0.0059 0.1613 Annual Dry Tons 68,3588 PAN SOIL MONITORING Soil pH Lime Appl. TorVAC Weather Code: 1) >90F 2) 70-90F 3)32-70F A) Less than 112 inch rainfall B) Greater than 1/2 Inch rainfall in past 24 hours Site Condition Code: 1) Excessively Dry 2) Dry 3) Moist 4) Wet �representafive of EMA Resources, Inc., hereby certify that this site was operated in compliance with the conditions of Nondischarge Permit No. W00000701 L0 0 0 0 0 O m m N m N O N N m N O O o 0 0 0 0 0 O o o o 0 0 0 0 0 0 0 0 0 0 0 o000000000000000000 o o O o o o o d o o O O O o o o o o o m m C 10 M N.- m m D N O I m m m 0 0 0 0 00000000000C C, Cl 000 m o000000000p000000p0 U o 0 0 0 0' 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0000000000000000000 O O O o 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 N N 4 H 00 0 S S O S O' O O O OO O O O S O O S 00 .0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 co n CO r m M V' N n r 1n M 0 0 0 0 r S S S S S S S O O O O O o O O O O O O o o O O O O O O O O O O O O O O O O O O O O O O O O o O U m 0 a'- m mug m V N R <<D my vM �00000 0 L 0 0. U, 3 O O O O o 0 0 0 0 0 0 0 0 0 0 0 0 0 000000000000Oo 0000 rya U o000000000000000000 0000000000000000000 3�na mmN0)mm00mmmwmm1)001 0 _ m m mm N 00000o N N m N 0000000o o 0 Z o000000 0000000000000000000 r- r-- mMNNnrnmm0000 n n m r l D N.- m m n m Wul m n Co 0 0 0 00onC00000000000000 U o000000000000000000 00000000000(300.00000 O t° LnLf) coNMML0MMtr)Mcv0000 IL O C m m O m K N m v V m m O 0 m r 0 0 0 0 m M m M N O N N m t n t O m m O O O o WOf � N o000000000000000000 0000000000000000000 ' V C7 - C) MMrnMM'mCD DMco!O00000 Z D O v O m O m m O N N N m 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 O' 0 0 0 0 0 0 0 N' Q 0 d O O O O O O O O O O O O O O O o 0 0 0 O O O O o O o O O O o O O O o O o O O 1.LO '" n r V n N m m N N n m m m m O O C)O 7n mrn mmmmmmmV Vmoaoo Y ^ t O O N t O M m 0 0 0 0 a mmmm�D.N �n�nmvcirymm0000 O o0000000000.-.-0�0000 C ul Z;Z:. ------mmrnn0000 cv cvmcv o�n cvmnr�vm o00 � p. nrNnmrnVmaonm0000g000 ;^ C/ J m m r m N � m N N M m m o m I- CD, O O C)= N v n 0 0 0 0 0 Z n � � n M a00O rif7 �--nri LO! otzoOO o to to C3 otoCq 000 n O m . 000 000 O O O O O O 000 m � N O O O O o 0 o m cmi 000 00o a) I,- o of 0 0 0 v m omco 0 o O 0 (p mtO mKN3<V m M V m O O QI Z 0p000000000Cp:)p C:) m '�SoSo m O O O O O O O O O O O 0 0 O;O S 0 0 0 Z 0 0 0 0 0 0 0 0 0 0 0 0 0 0!0 0 0 0 0 0 o�p Z MV�Vm°�m�rnMm0000 MVNoo00n o dmmomvN�vvm�mM�n'.-0noo d m m�nmc cA ra mnrv(A ccco mmo(�m<pNp��fppO V V mmO1OmN pOpgppppOpppO 1D N (nY (V (nV 00�� 00 . Ea m m O O o 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 (11 U V QO V (npD�amO`NS trDmQ fOV Q�mrn m m r �" �.N•O O.0 O N m N-o io N LL LO m<' �0 y v nrnnnnrrrnrn�nmmm �O m m m m m m m m m m m N N N N n n ti n n ri r- n� r.- r-: N u. u) V i y a 0.- O pIL y 0 0 0 0 0 0 0.0 0 0 0 0 0 0 o S� o 0 0 to 0 o0 o S o c m m o o I `cDv" 0 cmiMaNirmicmv��cmvrMmc+mi Fit' O • N 3C3 N CL rrnrnnnnn O O O O O pp O O O p 0 0 0 0 0 O O O a 0 0 0 O O O O O O O O. N N H Q Q -' Q N " Q'•N N NN QT W NLV gN��N QQ S'pe �� (D fD m m fO m m m m m O) O] O] 0 �n V U Q Z 0 o f = a O m f E J O N i Project: Tyson Foods Owner: G. Welch Permit#: WQ0000701 Operator: Same ... 0,1-1;7 Is SITE MONITORING REPORT In pounds per acre Crop' Bermuda Weather Code 2 Acres. 39M0 Site Code 2 Application Method injection Date Gallons % Solids Gal/Ac OUAc PAN NO3-NO2 NH3 P - K Pb Zn Cu Ni Cd As Hg Se Mo 4/30/2007 13,000 4.47 326.6332 0.0609 5.5235 0.0001 3.6287 1.3882 0.3410 0.0009 0.0105 0.0022 0.0009 0.0001 0.0000 0.0000 0.0001 0.0010 5/1/2007 26,000 7.67 653.2663 0,2089 11.8181 0.0004 8.1069 2.9252 0.6268 0.0038 0.0276 0.0059 0.0029 0.0004 0.0003 0.0002' 0.0004 0.0025 5/2/2007 39,000 7.67 979.8995 0.3134 17,7271 0.0006 12.1603 4.3877 0.9402 0.0056 0.0414 0.0088 0.0044 0.0006 0.0004 0.0003 0.0006 0.0038 5/3/2007 39.000 7.67 979.8995 0.3134 17.727.1 0.0006 12.1603 4.3877 0.9402 0.0056 0.0414 0.0088 0.0044 0.0006 0.0004 0.0003 0.0006 0.0038 5r7/2007 32,500 7.67 816.5829 0.2612 14.7726 0.0005 10.1336 3,6565 0.7835 0.0047 0.0345 0.0073 0.0037 0.0005 0.0004 0.0002 0.0005 0.0031 5/8/2007 39,000 7.67 979.8995 0.3134 17.7271 0.0006 12.1603 4.3877 0.9402 0.0056 0.0414 0.0088 0.0044 0.0006 0.0004 -0.0003 0.0006 0.0038 5/10/2007 39,000 7.67 979.8995 0.3134 17.7271 0.0006 12,1603 4.3877 0.9402 0.0056 0.0414 0.0088 0,0044 0,0006 0.0004 0.0003 0.0006 0.0038 8/23/2007 39,000 12.61 979,8995 0.5153 14.1194 0.0216 12.7786 8.2443 1.7519 .0.0052 0.6884 0.0165 0.0052 0.0010 0.0025 0.0004 0.0006 0.0484 8/24/2007 39,000 12.61 979.8995 0.5153 14.1194 0.0216 12.7786 8.2443 1.7519 0.0052 0.6884 0.0165 0.0052 0.0010 0.0025 0.0004 0.0006 0.0484 8/27/2007 39,000 12.61 979.8995 0.5153 14.1194 0.0216 12.7786 8.2443 1.7519 0.0052 0.6884 0.0165 0.0052 0.0010 0.0025 0.0004 0.0006 0.0484 8/28/2007 39,000 12.61 979.8995 0,5153 14.1194 0.0216 .12.7786 8.2443 1.7519 0.0052 0.6884 0.0165 0.0052 0,0010 0.0025 0.0004 0.0006 0,0484 -8%29-/2007. 39,000 12.61 979.8995 0.5153. a.14.1194 0.0216 12.7786 8,2443 '1.7519 0.0052 0.6884 0.0165 0.0052 0.0010 0.0025 0.0004 0.0006 0.0484 3 i 39,000 12.61 979.8995 0,515 r;• =04:1:194 0.0216 12.7786 8.2443 1.7519 0.0052 0.6884 0.0165 0.0052 0,0010 0,0025 0,0004 0.0006 0.0484 8/31/2007 39,000 12.61 979.8995 0.5153 ' 14.-1194 0.0216 12.7786 8,244.3 1.7519 0.0052 0.6884 0.0165 0.0052 0.0010 0.0025 0.0004 0.0006 0.0464 9/6/2007 26,000 5.26 653,2663 0.1433 13.1026 0.0003 9.9156 2.9517 0.9457 0.0017 0.0381 0.0040 0.0014 0.0003 0.0005 0.0001 0.0007 0.0014 0 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 Totals: Annual: 526,500 13228.64 5:5348 f2i1,4!°ti07� 0.1553 169.8764 86.182 18,721 00.0697 5.0949 0:1699 0.0625 0.0111 0.0203 0.0044 0.0083 0,3621 Total Cumulatives 0.3578 6.7026 1.2627 0.4810 0.0316 0.0328 0.0070 0.0170 0.4878 Prior Years Cumulatives 0.2881 1.6077 1.0928 0.4185 0.0265 0.0125 0.0026 0.0087 0.1257 Annual Dry Tons 220.2850 SOIL MONITORING Soil H Lime Appl. Ton/AC Weather Code: 1) >90F 2) 70-90F 3)32-70F '"""" A) Less than 1/2 inch rainfall B) Greater than 1/2 Inch rainfall in past 24 hours Site Condition Code: 1) Excessively Dry 2) Dry 3) Moist 4) Wet t4e representative of EMA Resources, Inc.,•hereby certify that this site was operated in compliance wit't the, conditions of.Nondlscharge Permit No. Wg0000701 t.� 14660 NCDA&CS Agi..Aomic Division Phone: (919)733-2655 • Web Site: www.ncagr.com/agronomi,-�,.,..' Report No. Grower: Matthews, Ralin L. C6pies To: 5913 Hoffman Rd, k , € ✓ A , ; Soil Hoffman, NC 28347 Test Report Farm: 5689 12/07/2007 SERVING N.C. RESIDENTS FOR OVER 60 YEARS Moore County Agronomist Comments A -• 1, 3, $ Field Information Applied Lime Recommendations Sample No. Last Crap Mo Yr YIA Cr6p or Year Lime N P205 K20 Mg S Cu Zn B Mn See Note RPl 1st Crop: Tobacco FC .9T 50-80 0 140-160 0 0 0 0 0 1 2nd Crop: Soybeans . '0 0 0 80-100 0 0 0 0 0 3 Test Results Soil Class' nm% W/Y CBC BSS% Ac • pH P-I K-1 Ca% Mg% Mn-1 Mn-AI(1) Mn-AI(2) Zn-I Zn=AI Cu-1 S-1 SS -I NO3-N - NH4-N Na MIN 0.51 .1.53 3.3 52.0 �1.6 5.3 188 26 39.0 10.0 130 88 88 142 142 80, 28 0 Field Information Applied Lime Recommendations Sample No. Last Crop Mo Yr T/A Crop or Year Lime N P205 K20 Mg S Cu Zu B Mn See Note RF2 1st Crop: Tobacco FC .4T 50-80 0-20 110-130 0 20.25 $ 0 0 1 2nd Crop: Soybeans 0 0 0.20 50..-7.0 0 20.25 2 0 0 3 Test Results Soil Class BM% W/Y UC BS% Ac pH P-I K-1 Ca% Mg% Mn•I Mn-AI(2) Mn-AI(2) Zn-I Zn-AI Cu-I S-1 SS-1 NO3-N Nil4N NO MIN 0.36 1.46 3.1 61.0 1.2 5.7 65 38 41.0 13..0 75 55. 55 47 47 7 16 01 Field Information Applied Lime Recommendations Sample No. last Crop Mo Yr %A . Cr6p or Year Lime N P205 K20 Mg S­ Cu Zu B Mn See Note RF3 1st Crop: -Tobacco FC IT. 50.80 0 160-180 $ 20.25 $ 0 0 1 2nd Crop: Soybeans 0 0' 0 100-120 $ 20.25 2 0 0 3, Test Results Soil Class HM% W/Y LBC . BS% Ac pH P-I K-1 Ca% Mg% Mn-1 Mn-AI(1) Mn-AI(2) Zn-I Zn-Al Cu-1 S-I SS-1 NO3-N • NH4N Na MIN o.6 1.57 3.1 45.0 1.7 5.2 125 17 33.0 8.0 82 59 59 48 48 14. 17 0• Field Information Applied Lime Recommendations Sample.No. Last Crop Mo Yr 7/A Cr6p or Year Lime N P205 K20 Mg S Cu Zn B Mn See Note RF4 1st Crop: Tobacco'FG 1.3T 50-80 0 120-14o $ 0 $ 0 0 1 2nd Crop: Soybeans 0 0 0 60-80 $ 0 2 0 0 3 Test Results Soil Class W/Y 6L'C BS% Ac pH P-1 K-1 Ca% . Mglo Mn-I Mn-AI(1) Mn-Al(2) Zn-1 Zn-AI Cu-1 _ S-I SS -I M03-N ',NH4-N Ka MIN 5. 43.0 2:0 5.0 130 32 30.0 8,0 107 74 74 72 72 19 42 0- 4ai! vVrn i'.VLLV11111L Y.s.7.:1471V .�4; •. iVlµV}v 'a'^� T/ ✓.. .Y'!l 'a�,1 v' :..s•e�v-;. .,.,. .....� ,: ..�.. ..._.. •.:.. ... .. .....:. a!,,f.,...,.,,,.>.r•..:x.,..><\J,:-J/.a�%,n. ,,. ,a. ot, 4...a6r ..,,,.:..,.�.,, ... ,.,.: ?f�:: :. ,..ate, t, n.:.:a .�^ xi tie ext � xaasnu :rv..�^a =.�y✓r,.b; ,t.a - -- r Grower.. elch, Gary Copies To: EMA Resour( - i m'[ ' S0101 TestReport. NO Box 10 Norman, NC 28367 EMAResourcesInc Farm: MTl 2 Court Square 9 q Mocksville, NC 27028 1/3/2008 SERVING N.G. RESIDENTS FOR OVER 60 YEARS Montgomery County ,gronomist Comments ....-.-. ,. .. , .: .;n:.a. +. •a. ,.rr- .:.. r s..., tis t�tz..y.. :» rr:.,, _, .•.; ,- „rr. n::r."5 w'.',,, s r„�- .:. y,r f n...0 rr ,. ., .< .,,.. .. ,. .,,.. .. ram+ v ... .. :, .:. tN .v,e :b• .- 't ti' Ji` `a,M ,r.�x.. a'>; N ., ,. v ,.x �1, r;ti. 1:e1 MnP,•.h �.. .hl'YI .. .. .. .:.1 sii' �. S..l 5....-. t �nb l.. �. C� � 3,... ... .' ,.;.:f . F - .. V '1 .s:' ,,��yy�..YN. �t �. �.., w .•:��� �/1. � P.. v S- rrj f;f ..1 L. „ � � :r s,.: f. a .J.. P. _ w � _ ...,.`,,.. , s.:�„ : ht 1 v,. t ... .- P.....>2. , r. a .. ... W r, J :..Y -, � k . ,w. •. y YY �. "!±'�'h .Y,?V � l.,+.b�. �� {}i l,' r,�.�,y -1 cmple No. Last Crop Mo Yr T/A Crop or Year Lime P205 K20 Mg S Cu Zn B. Mn See Note )0003 1st Crop: Berm Hay/Pas,M 1.7T 180-220 0 120-140 $ 0 0 0 012 2nd Crop: 0 .st Results Pit Class HM% W/V CEC. < BS% Ac pH P-I K I Ca% Mg% Mn-I Mn-AI(1)Mn-AI(2) Zn-I Zn-AI - Cu-I S-I SS -I - NO3-N 'NH¢-N Na . MIN 0.56 1,52 5.1 65.0 1.8 5.1 356 42 52 0 9 0 105 72 411 411 294 52 0 1 �§+ :� Ti •*tia f a . .. ,.: ,. ..... :, :: ...n . .i. ... ?.rii:. .^a ,. .. n„ a . 5 :: s ».y, ....'ui- tK.: -.. .,', ..% C w• �i'x, r .: va, tl �. .irk...,.}.G 'i.., `.?•.. � Vs ,.e@,`+ 4,. ,. �..v1.'`•. »<r �1:.'"}5. ' W }..3 �<",: "v.: � im :. � � .!. .. ....h'f'•3 {LK l .Infor attYon:.., 1edY ecommendations� .a- x,�_...;,�.�.�rrv:�,��3..6.,�.��.:•�.,:�.ati��:�,�:.�e�..�,r...��,,.��.�ry,;i<,.����n�:��.�.Y�w...�.rf.1�.. x.: �... x. ,. imple No. Last Crop Mo Yr T/A Crop or Year Lime PZOs K20 Mg S Cu Zn . B Mn See Note )0004 1st Crop: Berm Hay/Pas,M 13T 180-220 0 130-150 $ 0 0 0 .0 12 2nd Crop: 0 ,st Results jil Class HM% W/V CEC BS% Ac pH P-I K-I Ca% Mg% Mn-I Mn-AI(I)Mn-AI(2) Zn-I Zn-AI Cu-I S-I SS -I NO3-N NH4-N Na MIN 0.56 1.48 4.9 63.0 1.8 5.3 283 39 52.0 7.0 102 71 330 330 329 38 01 .� X .ti 'F s`v . fi .. ..es .. .. :n ,,. r, ..,.: .?. ,..+ ♦., ,. ..s.. � r %. .x. ... .. .. S ..:.1-. F r ,....-.,. ,SS ai` r. fir. •.x:. x .. , n. � .} 6`i< • 'g-� o- ,:.:: ...'..:. ... +Z .. t ....: u. C.. ! c# .. „ .. w<-., xi°: «..:..:a <s .. .. t. '� ♦ ,x , • .... .z s-:..: sa .x.»... ! ,.. "€.. v<� / N...,.s » "`Sr' ... } �.3`:.v�a 4 � �.r . r � . �: v � - r � � <� "Cu�» im le No. Last Crop p p Mo Yr T/A p e Crop or Year Lime P20s K20 Mg S Cu Zn B Mn See Note )0009 1st Crop:. Berm Hay/Pas,M 1.7T 180-220 0 70-90 0 0 0 0, 0 12 2nd Crop: 0 :st Results lil Class MIN HM% 0.46 W/V 1.52 CEC 5.3 BS% 66.0 Ac 1.8 pH 5.2 P-I 367 K-I 67 Ca% 46.0 Mg% 14.0 Mn-I Mn-AI(IjMn-AI(2) 115 78 Zn-I 334 Zn-AI 334 Cu-I - 250 S-I 82 SS -I NO3-N NH4-N Na 0.2 NCDA&CS Agcuuomic Division = - _ Report No: 14660 Pi Grower: Matthews, Ralin L. Phone: *0733-2655 Web Site: www.ncagr.com/agronoiiii) . Field Information Applied Lime Recommendations Sample No. Last Crop Mo Yr T/A Cr6p or Year Lime N P205 K20 Mg S Cu Zn B Mn See Note RF5 1st Crop: Tobacco FC .5T 50-80 0 140-160 0 20.25 0 0 0 1 2nd Crop: Soybeans 0 0 0 70-90 0 20.25 0 0 0 3 Test Results Soil Class fim% W/V GEC BS% Ac p H P-1 K-1 Ca% Mg,-6 Mn-1 Mn-Al(1) Mn-AI(2) . Zn-I Zn-AI Cu-1 S-1 SS-1 NO3-N NH4N Ng MIN 0.56 1.46 3.4 59.0 1.4 5.7 191 27 42.0 13.0 189 123 123' 98 98 47 18 0. Field Information Applied Lime Recommendations Sample No. Last Crop Mo Yr T/A Crop or Year Lime N P20s Kz0 Mg S Cu Zn B b!n See Note RF6 1st Crop: Tobacco FC 1T 50.80 0 160-180 $ - 20.25 0 0 0 1 2nd Crop; Soybeans 0 0 0 90-110 $ 20.25 0 0 0 3 Test Results Soil Class RM% W/V GEC BS% Ac pH P-1 K-1 Ca% Mg% Mn-I Mn-AI(1) Mn-AI(2) Zn-I Zn-AI Cu-1 S-1 SS -I NO3-N NH4-N N 'MIN 0.51 1.46 3.2 47.0 1.7 5.2 100 18 35.0 9.0 131 89 89 37 37 29 21 0. Field Information Applied Lime" Recommendations Sample No. Last Crop Mo Yr TiA Cr6p or Year Lime N P205 K20 Mg S Cu Zn B Mn See Note RMI 1st Crop: Soybeans AT 0. 0 100-120 0 20.25 0 0 0 3 2nd Crop: Tobacco FC 0 50-80 0 160-180 0 20.25 0 0 0 1 Test Results - Soil Class , hm% W/V GEC BS% Ac pH P-I K-1 Ca% . Mg% Mn•l Mn-AI(1) Mn-AI(2) Zu-1 Zu-AI Cu-I S-1 SS-1 NO3•N NH4-N N MIN 0.27 1.52 3.1 61.0 1.2 5.7 130 17 44.o 16.o 62 47 47 67 67 89 15 0• Field Information Applied Lime Recommendations Sample No. Last Crop Mo Yr T/A Cr6p or Year Lime N 1205 K20 Mg S Cu Zn B Mn See Note RM2 1st Crop: - Soybeans .ST 0 0 90.110 0 20.25 0 0 0 3 2nd Crop: Tobacco FC 0 50-80 0 150-170 0 20.25 0 0 0 1 Test Results Soil Class BM% W/V CEC BS% Ac pH P-1 K 1 Ca% Mg% -Mn-I Mn-AI(I) Mn-AI(2) Zn-I Zn-Al Cu-1 S-1 SS -I NO3-N NH4-N N MIN 0.41 1.56 3.3 55.0 1.5 5.4 183 21 40.0 13.0 105 73 73 92 92 126 17 0 Field Information Applied Lime Recommendations Sample No. Last Crop Mo Yr YIA Cr6p or Year Lime N P205 K20 Mg S Cu Zn B Mn See Note RM3 1st Crop: Soybeans 7T 0 0 100.120 0 20.25 0 0 0 3 2nd Crop: Tobacco FC 0 50-80 0 160-180 0 20-25 0 0 0 1 Test Results, Soil Class I1M% W/V 6EC BS% Ac p H - P-I K-I Ca% , Mg% Mn-I Mn-AI(I) Mn-AI(2) Zn-I Zn-AI Cu-I S-/ SS-1 NO3-N NH4-N N MIN 0.32 1.57 2.9 52.0 1.4 5.4 169 17 40.0 10.0 73 54 54 83 83 126 16 0 Phones (919)733-2655 ' Web Site: www.ncagr.com/agronon,.,= Pg Grower: Matthews, Ralin L. Report No: 14660 NCDAUS hlridnomic Division Field Information Applied Lime Recommendations Sample No. Last Crap Me Yr YiA Crop or Year . Lime N P205 K20 Mg S Cu Zn B Mn See Nole RM4 1st Crop: Soybeans 9T 0 0 90-110 0 20-25 0 0 0 3 2nd Crop: Tobacco FC .0 50-80 0 • 150-170 0 20.25 0 0 0 1 Test Results Soil Class HM% W/V GEC BS% Ac p H RI K-I Ca% Mg% Mn-I Mtz-AI(1) Mn-AI(2) Zn-I Zn-AI Cu-I S-I SS-1 NO3-N AH4-N Na MIN 0.46 1.54 3.3 55.0 1.5 5.2 176 22 42.0 11.0 129 87 87 112 112 126 20 0. Field Information Applied Lime Recommendations Sample No. Last Crop Me Yr TIA Crop or Year Lime N P205 k20 Mg S Cu Zu B Mn • See Note RM5 1st Crop: Soybeans AT 0 0 90-110 0 20.25 0 0 0 3 2nd Crop: Tobacco FC 0 50.80 0 160-180 0 20.25 0 0 0 1 Test Results Soil Class 1iM% W/V GEC BS% Ac pH P-1 K-I Ca% Mg% Mn-I Mn-Al(1) Mn-AI(2) Zn-I Zn-AI Cu-I S-I SS-1 NO3-N 1VH4-N Na MIN 0.36 1.54 3.2 63.0 1.2 5.7 132 19 48.0 12.0 $7 62 62 85 85 118 13 0. Field Information Applied Lithe Recommendations Sample No. Last Crap Mo Yr YIA Crop or Year Lime N P205 K20 Mg S Cac Zn B Mn See Note RBI 1st Crop: Small Grains 1,2T 80-100 0 70-90 0 0 0 0 .0 0 3 2nd Crop: Soybeans 0 0 0 70.90 0 0 0 0 0 3 Test Results Soil Class 11M% W/V GEC BS% Ac pH P-I K-I Ca% Mg% Mu-1 Mn.AI(1) Mn-AI(2) Zn-I Zn-Al Cn-I S-I SS-1 NO3-N NH4-N Na MIN 1.02 1.47 4.4 57.0 is 5.0 169 31 43,0 10.0 115 79 79 96 96 94 42 0.