WQ0004797_Groundwater Monitoring Report (GW59) May 2022_20220621

Anchor QEA of North Carolina, PLLC ANCHOR
231 Haywood Street
Asheville, North Carolina 28801 QEA
828.281.3350
June 21, 2022
Blake Kehoe
Director, Engineering
Lassonde Pappas & Company, Inc.
125 Industrial Park Road
Hendersonville, North Carolina 28792
Re: Spring 2022 Water Quality Sampling Event
Non -Discharge Permit No. WQ0004797
Clement Pappas NC, LLC
Dear Mr. Kehoe,
Anchor QEA of North Carolina, PLLC, is pleased to present the results of the Spring 2022 water quality
monitoring event at the Clement Pappas NC, LLC (Clement Pappas) facility (the Site), located at
485 Brookside Camp Road in Hendersonville, North Carolina. As recommended by the North Carolina
Department of Environmental Quality (DEQ), Anchor QEA performed disinfection of monitoring wells
MW-5, MW-6, MW-7R, and MW-8 and redevelopment of MW-7R prior to the water quality monitoring
event. The company that operates the facility rebranded to Lassonde Pappas & Company in 2016.
However, for permitting purposes, the Hendersonville facility retains the Clement Pappas NC LLC name
that is designated on the property deed. Clement Pappas is currently permitted under a Wastewater
Irrigation System Permit by the North Carolina Department of Environmental Quality (DEQ)
Environmental Management Commission for the operation of a 99,900-gallon-per-day wastewater
treatment and irrigation facility.
Groundwater Well Chlorination and Development
The DEQ recommended disinfection of MW-5, MW-6, MW-7R, and MW-8 to address intermittent
detections of fecal coliform bacteria in the Compliance Inspection Report for the Clement Pappas
Wastewater Treatment Facility, dated January 27, 2022. Additionally, the DEQ recommended
redevelopment of MW-7R to address plant roots penetrating the well screen and buildup of organic
debris at the bottom of the casing, which may have been impacting water quality immediately
around the well screen and sand pack. As reported in the Fall Groundwater Sampling Event and Well
Integrity Evaluation, dated December 17, 2022, Anchor QEA identified root growth and organic
debris in MW-7R during the well integrity evaluation performed in October 2021.
Anchor QEA mobilized to the Site to perform chlorination of MW-5, MW-6, MW-7R, and MW-8 on
April 20, 2022, in accordance with DEQ disinfection guidelines. Based on well volume and sand pack
calculations, chlorine (68% sodium hypochlorite) mixed with deionized water was poured down each
\\Athena\Asheville\Projects\Clement Pappas\Reports\2022\May\20220621-Spring2022- Groundwater Sampling Event Clement Pappas NC, LLC.docx

June 21, 2022
Page 2
monitoring well, making sure to allow contact with the PVC well casing. A submersible pump was
then lowered into the well within the screen interval and used to recirculate the chlorinated mixture
within the well and formation. At least three well volumes were recirculated in each well.
Anchor QEA returned to the site two days later on April 22, 2022, to purge chlorinated water and
flush all five wells. A submersible pump was lowered into each well, within the screened interval, and
used to pump at least three well volumes out of the well. Purge water from each well was disposed
of on land in the vicinity of the well, in accordance with DEQ approval. The submersible pump was
decontaminated between each monitoring well during chlorination and purging activities.
On April 22, 2022, Anchor QEA began redevelopment of MW-7R with a Waterra Hydrolift pump and
surge block. Anchor QEA attempted to purge organic debris with a trash pump; however, the pump
did not function. Anchor QEA returned on May 6, 2022, to purge organic debris with a diaphragm
pump and complete redevelopment with a Waterra pump and surge block. Monitoring well
chlorination and redevelopment logs are included in Attachment 1.
Groundwater Quality
Anchor QEA performed the groundwater sampling event at the Site on March 10, 2022. A Site location
map is included in Figure 1. The groundwater sampling event was performed in accordance with DEQ
wastewater irrigation system permit No. WQ0004797 issued September 3, 2015, and renewed
May 15, 2020 (referred to as "the permit" in this letter; effective September 1, 2020, and expiring
July 31, 2026). Anchor QEA used low -flow methods to purge and collect groundwater samples from six
monitoring wells: MW-4, MW-5, MW-6, MW-7R, MW-8, and MW-9. Monitoring well MW-9 was installed
April 14, 2015, to replace the previously damaged monitoring well MW-2R. The locations of the
monitoring wells are shown in Figure 2. Anchor QEA submitted the groundwater samples to Pace
Analytical Services, Inc., a North Carolina -certified laboratory, for analysis of the parameters specified in
the permit, as follows:
• Total organic carbon
• Chloride
• Fecal coliform
• Total ammonia
Groundwater Elevation
• Total nitrate
• Phosphorous
• Total dissolved solids
Table 1 summarizes current and historical groundwater elevations from November 2018 to May 2022.
Except for monitoring well MW-9, all monitoring well concrete pads and top -of -well casing (TOC)
elevations were surveyed by Wes Cole Land Surveying, PA, on November 21, 2012. Monitoring well
MW-9 was surveyed by Wes Cole Land Surveying, PA, on May 29, 2015. The surveyed TOC elevations are
shown in Table 1.

June 21, 2022
Page 3
Groundwater Analytical Results
Table 2 summarizes the current and historical groundwater analytical results from November 2018 to
May 2022. During the current sampling event, the parameters analyzed were below or within the
groundwater standards provided in the permit,' except for nitrate and pH, which are described as follows:
• The pH of the samples collected from MW-4 (5. 8 standard units [SU]), MW-5 (5.6 SU),
MW-6 (5.4 SU), MW-7R (5.1 SU), and MW-9 (5.4 SU) were below the groundwater standard
range of 6.5 to 8.5 SU. The sample collected from the background monitoring well, MW-5, has
a pH (5.6) that is similar to the other groundwater monitoring wells.
The nitrate concentration exceeded the permit groundwater standard of 10 milligrams per
liter (mg/L) in the sample collected from one monitoring well, MW-7R (31.0 mg/L).
The 2L standard for total coliform is 1 colony -forming unit per 100 milliliters (1 CFU/100 mL). There is
no specific permit limit or 2L standard for fecal coliform; however, total coliform includes fecal
coliform. Fecal coliform was not detected at or above laboratory detection limits in any groundwater
samples.
Surface Water Quality
Beginning in May 2017, Clement Pappas voluntarily collected surface water samples from Mud Creek,
analyzing for the same constituents as those sampled in groundwater. The renewed permit issued in
May 2020 and effective September 2020 requires semiannual sampling of the surface water
locations. Sampling point SW-1 is located upstream of the Site, and sampling point SW-2 is located
downstream of the Site. Sampling locations are shown in Figure 2.
Surface Water Analytical Results
Table 3 summarizes the historical and current surface water analytical results. For the May 2022
sampling event, no parameters were detected at concentrations above the associated Title 15A
NCAC Subchapter 2B surface water standards (2B standards).
Since collection of surface water samples for all permit constituents began in May 2017, nitrate
concentrations have been similar in SW-1 (upstream) and SW-2 (downstream). The Spring 2022
sampling showed a similar relationship: upstream sample SW-1 had a nitrate concentration of
0.88 mg/L, while downstream sample SW-2 had a concentration of 0.87 mg/L. The results for total
organic carbon, chloride, total dissolved solids (TDS), ammonia, and total phosphorus were also
similar for upstream and downstream samples, indicating the unlikelihood that the Site is impacting
Mud Creek.
Most of the groundwater standards are represented by the 2L standards, with the exception of nitrate and total organic carbon,
which are set in the Wastewater Irrigation System Permit Number WQ0004797.

June 21, 2022
Page 4
Discussion and Recommendations
Based on analytical results, monitoring well disinfection appeared to address previous fecal coliform
issues. Fecal coliform was below laboratory detection limits in all groundwater samples collected
during the Spring 2022 sampling event.
Anchor QEA performed redevelopment of MW-7 to remove organic debris, which have accumulated
due to root penetration of the well screen and impacted water quality; however, the concentration of
nitrate in the sample collected from MW-7R during the Spring 2022 sampling event remained above
the permit standard. The root mass on the outside of the casing and within the sand pack may be
continuing to leach nitrogen as organic matter decays.
Nitrate concentrations were below the permit standard in samples collected from all other
monitoring wells. The results for all analyzed constituents in surface water, including nitrate, were
below applicable standards and similar for upstream and downstream samples. Per a discussion
regarding the results with DEQ Hydrogeologist, Brett Laverty, Anchor QEA will continue to monitor
nitrate concentrations to determine if further action is needed.
In accordance with the spray irrigation permit WQ0004797, Clement Pappas is required to submit the
following to the DEQ by June 30, 2022 (on or before the last working day of the month following the
sampling month):
• Laboratory analytical reports and chain -of -custody forms (Attachment 2)
• Well sampling logs and the equipment documentation and instrument calibration data sheet
(Attachment 3)
• DEQ GW-59A — Compliance Report Form (Attachment4)
• DEQ GW-59 — Groundwater Quality Monitoring: Compliance Report Form, for each
monitoring well (Attachment 5)
Anchor QEA proposes to complete the next scheduled groundwater and surface water sampling
event in November 2022.

June 21, 2022
Page 5
If you have any questions or would like additional information, please do not hesitate to contact me
at [phone] [e-mail].
Sincerely,
Jennifer Verde, PE
Managing Engineer
James Robert Howell, PG
Principal Scientist
Attachments
Table 1 Current and Historical Groundwater Elevation Measurements
Table 2 Current and Historical Groundwater Analytical Results
Table 3 Current and Historical Surface Water Analytical Results
Figure 1 Site Location Map
Figure 2 Site Map
Attachment 1 Monitoring Well Chlorination and Redevelopment Logs
Attachment 2 Laboratory Analytical Reports and Chain -of -Custody Forms
Attachment 3 Well Sampling Logs and Instrument Calibration Data Sheet
Attachment 4 DEQ GW-59A — Compliance Report Form
Attachment 5 DEQ GW-59 — Groundwater Quality Monitoring: Compliance Report Forms

Tables

Table 1
Current and Historical Groundwater Elevation Measurements
Well
Identification
Screened
Interval
(ft bgs)
Date
Measured
Depth to
Groundwater
(ft)
Top -of -Casing
Elevation
(ft AMSL)
Top -of -Casing
Height Above
Ground Surface
(ft)
Groundwater
Elevation
(ft AMSL)
MW-4
5.0 - 15.0
05/02/2018
8.44
2063.77
2.43
2055.33
11/02/2018
8.00
2055.77
05/21/2019
8.49
2055.28
11/14/2019
8.82
2054.95
05/06/2020
7.98
2055.79
11/06/2020
8.02
2055.75
05/11 /2021
8.52
2055.25
10/28/2021
9.15
2054.62
05/10/2022
9.14
2054.63
MW-5
9.0 - 19.0
05/02/2018
8.47
2085.60
3.00
2077.93
11/02/2018
8.23
2078.17
05/21/2019
8.57
2077.83
11/14/2019
8.90
2077.50
05/06/2020
8.28
2078.12
11/06/2020
8.90
2077.50
05/11 /2021
8.77
2077.63
10/28/2021
9.44
2076.96
05/10/2022
9.15
2076.45
MW-6
5.0 - 10.0
05/02/2018
5.36
2061.17
3.00
2056.54
11/02/2018
5.03
2056.87
05/21/2019
5.53
2056.37
11/14/2019
5.59
2056.31
05/06/2020
5.41
2056.49
11/06/2020
5.33
2056.57
05/11 /2021
5.68
2056.22
10/28/2021
5.94
2055.96
05/10/2022
5.91
2055.26
MW-7R
5.0 - 15.0
05/02/2018
10.99
2062.86
3.00
2051.87
11/02/2018
10.33
2052.53
05/21/2019
10.88
2051.98
11/14/2019
11.33
2051.53
05/06/2020
10.11
2052.75
11/06/2020
10.05
2052.81
05/11 /2021
10.85
2052.01
10/27/2021
11.74
2051.12
05/10/2022
11.66
2051.20
MW-8
3.0 - 13.0
05/02/2018
9.39
2060.80
3.00
2051.41
11/02/2018
8.85
2051.95
05/21/2019
9.38
2051.42
11/14/2019
9.75
2051.05
05/06/2020
8.54
2052.26
11/06/2020
8.37
2052.43
05/11 /2021
9.24
2051.56
10/27/2021
10.06
2050.74
05/10/2022
10.02
2050.78
Spring 2022 Groundwater Sampling Event Page 1 of 2
Clement Pappas, Hendersonville, North Carolina June 2022

Table 1
Current and Historical Groundwater Elevation Measurements
Well
Identification
Screened
Interval
(ft bgs)
Date
Measured
Depth to
Groundwater
(ft)
Top -of -Casing
Elevation
(ft AMSL)
Top -of -Casing
Height Above
Ground Surface
(ft)
Groundwater
Elevation
(ft AMSL)
MW-9
6.0-16.0
05/02/2018
5.07
2060.23
1.44
2055.16
11/02/2018
4.55
2055.68
05/21/2019
4.89
2055.34
11/14/2019
5.15
2055.08
05/06/2020
4.30
2055.93
11/06/2020
4.10
2056.13
05/11 /2021
4.75
2055.48
10/27/2021
5.57
2054.66
05/10/2022
5.70
2054.53
Notes:
Top -of -casing elevations: MW-5 through MW-8 top -of -casing elevations are based on a survey by Hill and Associates Surveyors,
dated January 10, 2002, through May 2012. MW-2R and MW-4 top -of -casing elevations are based on differential level
measurements made by Altamont Environmental, Inc., on June 26, 2006, through May 2012. The top -of -casing elevations for the
monitoring wells were resurveyed on November 21, 2012, by Wes Cole Land Surveying. The top -of -casing elevations for MW-9
were surveyed on May 29, 2015, bV Wes Cole Land Surveyinq.
Monitoring is performed in accordance with Permit No. WQ0004797 issued to Clement Pappas on May 15, 2020 and effective on
September 1, 2020.
AMSL: above mean sea level
bgs: below ground surface
ft: feet
Spring 2022 Groundwater Sampling Event Page 2 of 2
Clement Pappas, Hendersonville, North Carolina June 2022

Table 2
Current and Historical Groundwater Analytical Results
Sample Name
Sample Date
�.0
O=
L
v
_
LL
a
z
9
p
a
0a
=
o
E
i
S
0.S
70
d
47
Gl
i
d
S
d
o
Gi
e�
t
Gi
=
0
v
a
S
0
0
(SU)
(mg/L)
(mg/L)
(CFUs
per 100 mL)
(mg/L)
(mg/L)
(mg/L)
(mg/L)
(Ng/L)
(Ng/L)
(Ng/L)
(Ng/L)
(Ng/L)
(Ng/L)
2L Groundwater Standards
6.5 - 8.5
10
250
1
NL
500
7.5
NL
0.7
3
70
100
0.03
7
Groundwater Standards Provided in Permit No. WQ0004797
6.5 - 8.5
10
250
NL
10
500
7.5
NL
0.7
3
70
100
0.03
7
05/02/2018
5.86
3.0
10.0
< 1.0
2.1
167
<0.020
0.11
N
R
11/02/2018
5.47
3.6
9.0
<10.0
0.48
137
<0.10
0.070
<0.50 <0.50 <0.50
1 <0.50 <1.0 <0.50
05/21/2019
5.81
3.0
11.3
<1.0
3.3
170
<0.050
0.044 J
NR
11/14/2019
5.82
3.7
11
<1.0
0.42
190
<0.10
<0.050
<0.50 <0.50 <0.50
I <0.50 <1.0 <0.50
MW-4
05/06/2020
5.70
2.3
7.6
<1.0
3.7
172
<0.10
<0.050
NR
11/06/2020
5.30
2.8
6.9
<1.0
0.73
148
<0.10
<0.050
<0.50 <0.50 <0.50
I <0.50 <1.0 <0.50
05/11/2021
5.8
2.8
6.9
<1.0
1.4
169
0.14
<0.050
NR
10/28/2021
5.7
3.1
6.7
<1.0
0.084
161
<0.10
<0.050
<0.50 <0.50 <0.50
1 <0.50 <1.0 <0.50
05/10/2022
5.8
2.9
6.8
<1.0
0.46
136
<0.10
0.063
NR
05/02/2018
5.69
5.7
16.1
2.0
0.0
90
<0.10
0.097
NR
11/02/2018
5.53
5.1
23.9
<10.0
<0.020
86
<0.10
0.085
39.1 6.0 6.7 1 <0.50 <1.0 <0.50
05/21/2019
5.68
9.4
26.8
7.0
0.1
91
<0.050
0.120
NR
11/14/2019
5.59
6.0
20.1
7.0
0.055
202
<0.10
0.081
22.4 4.4 5.0 1 <0.50 <1.0 <0.50
MW-5
05/06/2020
5.90
6.9
7.3
8.0
<0.040
116
<0.10
0.083
NR
11/06/2020
5.65
4.6
6.9
8.0
<0.040
61.0
<0.10
0.060
0.80 1.0 <0.50 1 <0.50 <1.0 <0.50
05/11/2021
5.5
5.5
11.8
<2.0
<0.040
110
<0.10
0.090
NR
10/28/2021
5.7
6.6
17.3
5.0
<0.040
76.0
<0.10
0.054
30.7 11.6 12.6 <0.50 <1.0 <0.50
05/10/2022
5.6
2.7
49.0
<1.0
0.10
158
<0.10
<0.050
NR
05/02/2018
5.28
2.3
9.4
1.0
0.1
81
<0.10
0.097
NR
11/02/2018
5.02
2.5
10.1
69.0
0.6
88
<0.10
0.057
<0.50 <0.50 <0.50 1 <0.50 <1.0 <0.50
05/21/2019
5.46
3.3
11.3
23.0
0.4
78
<0.050
0.068
NR
11/14/2019
5.30
2.9
9.3
44.0
0.56
342
<0.10
0.052
<0.50 <0.50 <0.50 1 <0.50 <1.0 <0.50
MW-6
05/06/2020
5.38
2.0
9.7
3.0
1.1
96.0
<0.10
<0.050
NR
11/06/2020
5.23
2.6
12.5
3.0
3.2
139
<0.10
<0.050
<0.50 <0.50 <0.50 I <0.50 <1.0 <0.50
05/11/2021
5.5
2.2
10.9
5.0
1.4
99.0
<0.10
<0.050
NR
10/28/2021
5.4
2.3
8.7
<1.0
<0.040
85.0
<0.10
<0.050
<0.50 <0.50 <0.50 1 <0.50 <1.0 <0.50
05/10/2022
5.4
1.5
13.6
<1.0
<0.040
96.0
<0.10
<0.050
NR
Spring 2022 Groundwater Sampling Event Page 1 of 4
Clement Pappas, Hendersonville, North Carolina June 2022

Table 2
Current and Historical Groundwater Analytical Results
V
E
a
i
Os+
47
d
a=,
_
_
°1
S
a
.R
L
0
>
p
S
�-
G/
O
S
+.
Gi
Gi
M
p
L
=
d
O
O
O =
v
a
o
0.
S
o
e� o
v
_
E
�.0
LL
z
a
(CFUs
Sample Name
Sample Date
(SU)
(mg/L)
(mg/L)
per 100 mL)
(mg/L)
(mg/L)
(mg/L)
(mg/L)
(Ng/L)
(Ng/L)
(Ng/L)
(Ng/L)
(Ng/L)
(Ng/L)
05/15/2002
---
20.0
6.5
<1.1
5.2
< 40
< 0.10
NA
NR
NR
NR
NR
NR
NR
11 /05/2002
---
16.0
3.3
<1.1
1.3
68
1.4
NA
< 0.50
< 0.50
< 0.50
< 0.50
< 0.50
< 0.50
05/13/2003
---
9.7
3.6
2.2
1.8
44
0.72
NA
NR
NR
NR
NR
NR
NR
11 /04/2003
---
19.0
6.1
<1.1
0.7
< 2.0
< 0.10
NA
< 0.50
< 0.50
< 0.50
< 0.50
< 0.50
< 0.50
05/05/2004
---
3
7
<1.1
1.3
52
< 0.10
NA
NR
NR
NR
NR
NR
NR
11/09/2004
---
1 2.2
5.1
5.1
1.9
62
< 0.10
NA
< 0.50
< 0.50
< 0.50
< 0.50
< 0.50
< 0.50
05/17/2005
---
3.2
6.1
<1.1
1.2
40
< 0.10
NA
NR
NR
NR
NR
NR
NR
11 /03/2005
---
7.7
6.1
<1.1
1.0
58
0.1
NA
< 0.50
< 0.50
< 0.50
< 0.50
< 0.50
< 0.50
05/24/2006
---
8.4
5.5
<1.1
1.5
48
< 0.10
NA
NR
NR
NR
NR
NR
NR
11 /09/2006
---
1.9
7.0
<1.1
1.1
38
< 0.10
NA
< 0.50
< 0.50
< 0.50
< 0.50
< 1.0
< 0.50
MW-7
05/18/2007
---
3.6
8.6
<1.0
2.2
70
< 0.10
NA
< 0.50
< 0.50
< 0.50
< 0.50
< 0.50
< 0.50
11/13/2007
---
4.2
6.8
<1.1
1.7
42
< 0.10
NA
< 0.50
< 0.50
< 0.50
< 0.50
< 1.0
< 0.50
05/27/2008
---
7.6
11.5
<1.1
2.2
88
< 0.10
NA
NR
NR
NR
NR
NR
NR
11/18/2008
---
7.5
7.7
<1.1
1.7
30
< 0.10
NA
0.79
< 0.50
< 0.50
< 0.50
< 0.5
< 0.50
05/28/2009
---
23.4
9.8
<4.0
2.3
336
< 0.10
NA
NR
NR
NR
NR
NR
NR
11/05/2009
---
5.3
10.7
2.0
2.3
70
< 0.10
NA
< 0.50
< 0.50
< 0.50
< 0.50
< 1.0
< 0.50
05/13/2010
---
4.6
11.0
<2.0
2.5
71
< 0.10
NA
NR
NR
NR
NR
NR
NR
11/08/2010
---
15.4
8.9
<2.0
2.3
60
< 0.10
NA
< 0.50
< 0.50
< 0.50
< 0.50
< 1.0
< 0.50
05/17/2011
---
6.0
11.6
1 <2.0
1 5.3
1 103
< 0.10
NA
NR
NR
NR
NR
NR
NR
11/15/2011
---
2.2
9.9
<2.0
3.5
89
< 0.10
NA
< 0.50
< 0.50
< 0.50
< 0.50
< 1.0
< 0.50
05/17/2012
---
4.4
10.9
<2.0
3.8
67
< 0.10
NA
NR
NR
NR
NR
NR
NR
Spring 2022 Groundwater Sampling Event Page 2 of 4
Clement Pappas, Hendersonville, North Carolina June 2022

Table 2
Current and Historical Groundwater Analytical Results
Sample Name
Sample Date
�.0
V
.R
O =
E
L
0
v
_
LL
a
z
a
>
p
=
o
E
a
i
Os+
S
�-
0.
47
G/
O
S
d
a=,
S
+.
d
o
_
Gi
e� o
_
Gi
°1
M
O
v
S
a
p
L
O
(SU)
(mg/L)
(mg/L)
(CFUs
per 100 mL)
(mg/L)
(mg/L)
(mg/L)
(mg/L)
(Ng/L)
(Ng/L)
(Ng/L)
(Ng/L)
(Ng/L)
(Ng/L)
11/07/2012
---
11.6
13.1
< 100
4.0
108
< 0.10
NA
< 0.50
< 0.50
< 0.50
< 0.50
< 1.0
< 0.50
05/16/2013
---
12.8
17.1
<1.0
10.5
252
< 0.10
NA
NR
NR
NR
NR
NR
NR
11/20/2013
---
9.4
14.0
<1.0
5.5
< 250
< 0.10
NA
< 0.50
< 0.50
< 0.50
< 0.50
< 1.0
< 0.50
05/22/2014
---
8.9
13.1
<10,000
5.7
93
< 0.10
NA
NR
NR
NR
NR
NR
NR
11/18/2014
---
19.1
16.0
<20.0
7.1
93
< 0.10
NA
< 0.50
< 0.50
< 0.50
< 0.50
< 1.0
< 0.50
05/13/2015
---
8.5
17.0
<2.0
9.3
125
< 0.10
NA
NR
NR
NR
NR
NR
NR
11/04/2015
---
9.9
18.0
<2.0
8.3
129
< 0.10
0.350
< 0.50
< 0.50
< 0.50
< 0.50
< 1.0
< 0.50
05/04/2016
---
13.5
27.7
<10.0
11.2
130
< 0.10
0.780
NR
NR
NR
NR
NR
NR
06/09/2016 - Pace
---
NA
NA
NA
10.9
NA
NA
NA
NR
NR
NR
NR
NR
NR
06/09/2016 - Prism
---
NA
NA
NA
10.0
NA
NA
NA
NR
NR
NR
NR
NR
NR
MW-7R
11/09/2016
---
13.0
22.7
<20.0
12.5
147
< 0.10
1.000
< 0.50
< 0.50
< 0.50
< 0.50
< 1.0
< 0.50
05/02/2017
---
6.7
17.9
<4.0
8.9
169
<0.10
0.430
NR
NR
NR
NR
NR
NR
11/08/2017
---
3.9
17.9
19.0
36.8
376
<0.10
0.140
< 0.50
< 0.50
< 0.50
< 0.50
< 1.0
< 0.50
05/02/2018
5.41
3.2
22.6
<2.0
15.5
207
<0.10
0.320
NR
11/02/2018
5.48
1 5.3
20.2
<10.0
15.7
243
<0.10
0.170
<0.50 <0.50 <0.50
1 <0.50 <1.0 <0.50
05/21/2019
5.58
3.0
29.0
<2.0
20.2
234
<0.050
0.130
NR
11/14/2019
6.42
3.0
22.7
<2.0
17.1
73
<0.10
0.084
<0.50 <0.50 <0.50
1 <0.50 <1.0 <0.50
05/06/2020
5.20
1.2
20.9
<1.0
21.5
219
<0.10
<0.050
NR
11/06/2020
5.54
1.7
17.8
<1.0
13.0
205
<0.10
<0.050
<0.50 <0.50 <0.50
1 <0.50 <1.0 <0.50
05/11/2021
5.2
1 1.7
34.2
<1.0
40.4
296
<0.10
0.051
NR
10/27/2021
5.3
1.1
24.9
<1.0
26.0
222
<0.10
<0.050
<0.50 <0.50 <0.50
1 <0.50 <1.0 <0.50
05/10/2022
5.1
<1.0
30.8
<1.0
31.0
279
<0.10
<0.050
NR
05/02/2018
6.74
10.8
12.9
<2.0
14.4
548
<0.10
0.190
NR
11/02/2018
6.52
9.5
8.0
19.0
6.8
351
<0.10
0.250
<0.50 <0.50 <0.50 1 <0.50 <1.0 <0.50
05/21/2019
6.89
7.9
7.3
<10.0
6.2
249
<0.050
0.290
NR
11/14/2019
6.71
7.7
7.2
2.0
1.2
51
<0.10
0.100
<0.50 <0.50 <0.50 1 <0.50 <1.0 <0.50
MW-8
05/06/2020
6.41
2.7
2.8
<1.0
3.6
139
<0.10
<0.050
NR
11/06/2020
6.34
2.8
2.3
14.0
2.4
127
<0.10
<0.050
<0.50 <0.50 <0.50 1 <0.50 <1.0 <0.50
05/11/2021
6.6
3.8
2.0
<1.0
1.7
114
<0.10
<0.050
NR
10/27/2021
6.6
4.7
3.5
1.0
0.86
189
< 0.10
< 0.050
<0.50 <0.50 <0.50 1 <0.50 <1.0 <0.50
05/10/2022
6.7
4.5
7.4
<1.0
1 3.2
1 240
<0.10
<0.050
NR
Spring 2022 Groundwater Sampling Event Page 3 of 4
Clement Pappas, Hendersonville, North Carolina June 2022

Table 2
Current and Historical Groundwater Analytical Results
i
.R
L
0
>
o
�'
G7
0
S
}+
GJ
GJ
L
0
L
=
d
0
0
O=
v
a
o
ii
s
o
e�
v
_
E
�.
LL
z
a
(CFUs
Sample Name
Sample Date
(SU)
(mg/L)
(mg/L)
per 100 mL)
(mg/L)
(mg/L)
(mg/L)
(mg/L)
(Ng/L)
(Ng/L)
(Ng/L)
(Ng/L)
(Ng/L)
(Ng/L)
05/02/2018
5.52
4.6
4.9
<2.0
0.58
69
<0.10
0.370
NR
11/02/2018
5.11
8.4
5.8
<10.0
0.57
88
<0.10
0.470
<0.50 <0.50 <0.50
1 <0.50 <1.0 <0.50
05/21/2019
5.64
7.2
4.6
<10.0
0.20
80
<0.050
1 0.230
NR
11/14/2019
5.57
6.1
5.4
<1.0
0.89
56
<0.10
0.076
<0.50 <0.50 <0.50
1 <0.50 <1.0 <0.50
MW-9
05/06/2020
5.52
5.9
1.8
<1.0
<0.040
68.0
<0.10
0.099
NR
11/06/2020
4.93
4.5
1.4
16.0
0.043
88.0
<0.10
0.095
<0.50 <0.50 <0.50
1 <0.50 <1.0 <0.50
05/11/2021
5.4
3.6
9.8
<2.0
1.9
<25.0
<0.10
0.089
NR
10/27/2021
5.4
3.8
3.2
1.0
0.35
48.0
1 < 0.10
< 0.050
<0.50 <0.50 <0.50
1 <0.50 <1.0 <0.50
05/10/2022
5.4
3.6
6.3
<1.0
1.5
67.0
1 <0.10
0.086
NR
Notes:
2L standards are set in North Carolina Administrative Code, Title 15A Subchapter 2L - Groundwater Classifications and Standards, Department of Environmental Quality (Amended April 1, 2013). Total organic carbon and nitrate standards are set in Wastewater
Irrigation System Permit Number WQ0004797. There is no defined 2L standard for fecal coliform; therefore, the standard listed is for "total coliform."
Bolded values indicate a concentration equal to or above the respective groundwater standard or outside the groundwater standard range.
Shaded cells are from the May 2022 sampling event.
pH is analyzed by Anchor QEA of North Carolina, PLLC; NC lab certification number 5445.
Monitoring is performed in accordance with Permit No. WQ0004797 issued to Clement Pappas on May 15, 2020 and effective on September 1, 2020.
< indicates that the constituent concentration was not detected above the method detection limit
lag/L: micrograms per liter
CFU: coliform-forming unit
J: The concentration is above the adjusted method detection limit and below the adjusted reporting limit and is therefore considered an estimate.
mg/L: milligrams per liter
mL: milliliter
NL : No 2L standard exists.
NR: not reported
SU: standard unit
Spring 2022 Groundwater Sampling Event Page 4 of 4
Clement Pappas, Hendersonville, North Carolina June 2022

Table 3
Current and Historical Surface Water Analytical Results
Sample Name
Sample Date
Q.
O
Y �.0
L
H O V
G1
L
O
ij
E
O
IC W
°LL' v
W
L
Z
d
> N
Y N =
0 to
�
O
O
E
Q
L
O
Q.
Y O
a.
(SU)
(m /L)
(m /L)
(CFUs per 100 mL)
(m /L)
(m /L)
(m /L)
(m /L)
28 Standard
6.0 - 9.0
NL
230
200
NL
NL
NL
NL
SW-1
(Upstream)
5/2/2018
6.88
1.5
4.8
53.0
0.74
54.0
<0.10
0.044 J
11/2/2018
6.28
2.9
5.1
780
0.72
54.0
<0.10
0.077
5/21/2019
7.02
1.6
5.0
98.0
0.75
42.0
<0.050
0.067
11/14/2019
6.76
1.9
5.3
118
0.83
57.0
<0.10
0.1
5/6/2020
7.20
1.6
4.6
290
0.76
49.0
<0.10
0.092
11/6/2020
5.83
1.6
4.4
145
0.71
56.0
<0.10
<0.050
5/11/2021
6.8
1.3
5.3
191
0.80
48.0
<0.10
0.068
10/27/2021
7
1.8
5.2
145
0.72
52.0
<0.10
0.061
5/10/2022
7.1
1.4
5.1
81.0
0.88
51.0
0.12
0.15
SW-2
(Downstream)
5/2/2018
6.98
1.4
4.4
118.0
0.72
51.0
0.052 J
0.045 J
11/2/2018
7.08
2.9
4.6
940.0
0.75
53.0
0.099 J
0.076
5/21/2019
6.99
1.6
4.9
200.0
0.76
47.0
<0.050
0.068
11/14/2019
7.01
1.9
5.4
127
0.82
83.0
<0.10
0.089
5/6/2020
6.67
1.7
4.2
420
0.72
53.0
<0.10
<0.050
11/6/2020
6.19
1.6
4.4
97.0
0.70
59.0
<0.10
<0.050
5/11/2021
6.9
1.4
5.0
146
0.74
47.0
<0.10
0.061
10/27/2021
6.9
1.9
5.2
145
0.71
55.0
<0.10
0.063
5/10/2022
6.9
1.4
4.9
118
0.87
50.0
<0.10
0.16
Notes:
2B standard: surface water standard per North Carolina Administrative Code, Title 15A: Department of Environmental Quality, Subchapter 2B - Surface Water
and Wetland Standards (last amended in November 2019), or the standard obtained from the U.S. Environmental Protection Agency Nationally Recommended
Water ntiality Criteria fnr Anuatic I ife and Human Health
Bolded values indicate a concentration equal to or above the respective 2B standard or a value outside the 2B standard range.
< indicates that the constituent concentration was not detected above the laboratory reporting limit
Monitoring is performed in accordance with Permit No. WQ0004797 issued to Clement Pappas on May 15, 2020 and effective on September 1, 2020.
CFU: coliform-forming unit
J: The concentration is above the adjusted method detection limit and below the adjusted reporting limit and is therefore considered an estimate.
mg/L: milligrams per liter
mL: milliliters
NL: No INC 2B standard exists
SU: standard unit
Spring 2022 Groundwater Sampling Event Page 1 of 1
Clement Pappas, Hendersonville, North Carolina June 2022

Figures

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fj
LEGEND\ � _ .•. AREA
\
PIEZOMETER
MONITORING WELL
• . OR FORMER MONITORING
(D SURFACE WATER SAMPLE LOCATION N,
4-FOOT CONTOUR
2 -FOOT CONTOUR
0 It
STREAM CENTERLINE
11 \ `\ 1 j ,/' \\ /�• \\ / I i/ / !! �'•
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*OLD OR FORMER MONITORING WELLS WERE
NOT SAMPLED DURING THE FALL 2021 NORTH
MONITORING EVENT
.!\3/�__

Attachment 1
Monitoring Well Chlorination and
Redevelopment Logs

Daily Log
ANCHOR.
«EA
Anchor QEA of North Carolina, PLLC
231 Haywood Street
Asheville, NC 28801
Phone [phone]
PROJECT NAME: Lassonde Pappas Well Chlorination & Redevelopment DATE: ED 117
SITE ADDRESS: 485 Brookside Camp Road, Hendersonville, NC 28792 PERSONNEL: Y S S
WEATHER: WIND FROKI INLI NE I E I SE I S JSWJ W NW I H- MEDIQ HEAVY
UNN CLOUDY RAIN ?J TEMPERATURE:(- F ° c
e appropriate units]
TIME
COMMENTS
0516
'rrowd OtD (;I`te
ftn�ve 1t i c e c 'a
(Ap fNDaje. -�-YaVtA ty my)
W S 4'1 t d-�
YO
d Ckf
Irow - ao
e i Mt '
q OLL
0+ tn-WA I;f, v L2, -,
M i
oc au
xct �. lv
� t
C x
TUV affa Srcp I j 61A2.
R
G
af M W de
0 in .b l
c"
U o "V ,-0-tb InY)
d 3=
t l .t-FEo
I0� . Z
d _ 0� CWIC V�
Of pz t-C'L fYi i X -I
d4panitd fi(,- vueu
C
OL f1fk °'
a
l 0 "40' i�0 I a '-1, 5 i�ln I' n
+
li aN -
Signature: fy

Daily
Log
ANCHOR
OE A uv
Anchor QEA of North Carolina, PLLC
231 Haywood Street
Asheville, NC 28801
Phone [phone]
PROJECT NAME: Lassonde Pappas Well Chlorination & Redevelopment DATE: aol cco nIn' 'h u ed 1 I
SITE ADDRESS: 485 Brookside Camp Road, Hendersonville, NC 28792 PERSONNEL: y tS&j
WEATHER: WIND FROM: N E I E I SE I S I SWI W I NWI LIGHT(MEDIUM HEAVY
1. SUNNY I CLOUDY I RAIN I ?J TEMPERATURE:5 ° C
[5kA appropriate units]
TIME
COMMENTS
ioGw
'U L 0
M W -- 0
C t Q4 MVIA f l b
a 1 u
y
C 3
-(ULUALU JLU
n o.
0-IL)6'
2i.af r-s I, j,xe
damitca
`n
0
11 KC 1
9 ` b LQ G
#
-
-F t " �933�
to 5 111:�
f
-to eC
Do eCG
14l-
DTAti .- : S L
t-D C
h) .fio C
Ati tmt 0-(
s : S , 5ct
`
©'V)e fT,,
1-� crf jbT Loa+(v roixfd,
� W
OUTh ,0
1
i f{ ,
G
ia. 05
O
—
r `, 1 U I & 3 -
�
ayl h r L iM I Yl
-i o j e con - econ
6 i C�
-S
chk VYI UA
L I,C
o f 1-G
econ e

Daily Log
ANC R OR
�+ QEA
Anchor QEA of North Carolina, PLLC
231 Haywood Street
Asheville, NC 28801
Phone [phone]
PROJECT NAME: Lassonde Pappas Well Chlorination & Redevelopment DATE:
SITE ADDRESS: 485 Brookside Camp Road, Hendersonville, NC 28792 PERSONNEL: E v-eS
WEATHER: WIND FROM: N . E I SE I S I SW I W I NW I MGMV 7 MEDIU HEAVY
UNN CLOUDY I RAIN ?J TEMPERATURE' 1 5 1 ° C
[Circle appropriate units]
TIME
COMMENTS
o�+o�
o6 U2.eo( C i
MY
fOr h,ave,4
Vntf
a.
min
r
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Signature:
1, z Z- �- , U- L L A =—
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Daily
Log
ANCHOR
Anchor QEA of North Carolina, ALLC
231 Haywood Street
Asheville, NC 28801
Phone [phone]
PROJECT NAME: Lassonde Pappas Well Chlorination & Redevelopment DATE: I AS A -A (CO
SITE ADDRESS: 485 Brookside Camp Road, Hendersonville, NC 28792 PERSONNEL: jL j Yes
WEATHER: WINDFROM:1 XTEKA E SE S I SW W I NW LIG MEDIUD4 HEAVY
SUNNY I CLOUDY I RAIN ? AT PERURE: ° F ° C
[ .Rde appropriate units]
TIME
COMMENTS
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Signature: C1W

Daily
Log
ANCHOR
OEA ""
Anchor QEA of North Carolina, PLLC
231 Haywood Street
Asheville, NC 28801
Phone [phone]
PROJECT NAME: Lassonde Pappas Well Redevelopment DATE:& 1 2021
SITE ADDRESS: 485 Brookside Camp Road, Hendersonville, NC 28792 PERSONNEL: L
WEATHER: WIND FROM: N I NEI E I SE S W W NW LIGHT MEDI HEAVY
SUNNY JCLOUDYI CRAIN `: ? TEMPERATURE: . F' +, ° C
IOrde appropriate unns]
TIME
COMMENTS
i�i U
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>
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LW

Select Turbidimeter.[:::::::::� Hach 21000 (s/n 151006045207)
HF Scientific MicroTPW (s/n 200601045)
ANCHOR
IDEA
Equipment Documentation and Instrument Calibration Data Sheet
Project Name: Lassonde Pappas pn 7n?? O M12134� Analyst Conducting Calibration:
�.�Y
Project Number. C21482-01.01 Task ? Date of Calibration: J_ pia
Project Location: Hendersonville, NC Date of Field Measureni 6 a , A
Facility ID or Permit # (if applicable): Permit No. WQ0004797
EQUIPMENT DOCUMENTATION
Rental sample analvsis equipment or meters used to take measurements:
Equipment Type Brand Serial Number Date of Use Rental Company
bai-"t( du�-1- la) (tpIcGced y. Veco __f,�
W
Anchor QEA of North Carolina, PLLC
231 Haywood Street
Asheville, North Carolina 28801
Instrument Readings
Instrument Readings
(Hach 21000)
(HF Scientific MicroTPMB
Cal Std Information
10 NTU
20 NTU
100 NTU
800 NTU
1,000 NTU
10.0 NTU
8 NTU
Lot #:
�1
f
Expiration Date*
Cal (NTU):
2 .
Cal (T
Cal (NTV): �y
�f
Cal (NTU):
Cal.(�11U)i +
Cal (NTU);�4y+; +
Time'9��y,.y
Time: �":t3
Time: [
Time:
Time:
Time:
Calibration
*Pre -Analysis
Result (NTU : t $
Ime:
*Pre -Analysis
R I (NTU)4 '-
irhe:`
Verification:
Check (10 NTU):
C) ' 3
Check (10 NTU
*Post -Analysis
Result (NTU):
Time:
,
`Post- sys
Reap t T,L!) *
• �me:e, • a �+� t a �+
Check (10 NTU):,'
YSI Professional Plus Multiparameter Meter (s/n 18BIOIS ]
-4 r .L $
cai. td fltf* inrr
Instrument Readings
Lot #
e
ExP . Date
O ousel
t
Dissolved Oxygen
Initial (%):
Cal (%):
mmHg:
Temperature CC):
Time:
»i �, 1
+
(% saturation)
DO (Site #2,
Initial (%):
Cal (%):
mmHg:
Temperature CC):
Time:
if a livable)*
Time:
Result (%):
Time:
Result (%):
Time:
sult (%):
QC** Check: DO
PH 7 S.U.
Initial:
pHmV:
Cal (S.U.):
pHmV:
Time -
report to 0.1 S. U.
PH 4 S.U.
Initial:
pHmV:
Cal (S.U.):
pHmV:
Time:
report to 0.7 S. U.
I
PH 10 S.U.
Initial:
pHmV:
Cal (S.U.):
mV:
Time:
I
report to a S.U.
QC** pH 7 S.U.
Time:
Result (S.U.):
Ti
Result (S.U.):
Time:
Result (S.U.):
report to 0.1 S.U.
Spec Cond.
Initial:
Cal (pmh
Time:
1,000 pmhos/cm
% Recovery=
QC** Spec. Cond.
Time:
Result (pmhos/cm):
Time:
Result (pmhos/cm):
Time:
Result (pmhos/cm):
1,000 pinhostzrif
% -,very=
Initial:
Cal:
Temperature CC):
Time:
200 mV
f (�
Analyst Signature: �J V) a Analyst Name: JGL� ` C Date:
Notes:
V (` ? "SlO
Revision 6, 12/20/20, MAK
1. Instruments shall be calibrated in accordance with the manufacturer's operation manual.
2. Specific Conductivity should be calibrated according to values representative of historic range.
3. Order of Calibration is as follows: Specific Conductivity, pH 7, pH 4, PH 10, DO, ORP, QC checks.
4. *When performing DO analyses at multiple sample sites (i.e. project/facility locations), the DO probe must be calibrated at
each sample site prior to analysis.
5. QC Acceptable Ranges: pH +/- 0.1 5.U. and Specific Conductivity 10% of the true value. If QC readings are out of range, the
instrument needs to be recalibrated.
6. ** QC check must be performed prior to sampling and following completion of sampling, at a minimum. QC checks must be performed with calibration standard from a separate lot # as the
initial QC
7. % Recovery = (Value Obtained, pmhos/cm r True Value, pmhos/cm) x 100
8. NC Field Laboratory Certificate Number 5445
9. Documentation errors are to be crossed out with a single line, so the original text is still legible, followed by the staff members
initials and date
10. Unless otherwise noted, all DO calibrations and measurements are performed at 0 ppt Salinity.
I I. 1 pmho/cm = 1 PS/cm
Abbrevlatlons:
Method Reference:
pmhos.-'cm: micromhos per centimeter NTU: nephelometric turbidity units
Temperature: SM 2550 B-2010
'C: degrees Celsius OFF. oxidaton reduction potential
Specific conductivity: EPA Method 120.1, Rev. 1982
DO: dissolved oxygen s/n: serial number
DO: SM 4500 O G-2011
mg/L milligrams per liter S.U.: standard units
PH: SM 4500-H* B-2011
mv: millivolt Spec. Cond.: Specific Conductivity
Turbidity: SM 2130 B-2011
Page 1 of 1

ANCHOR '^n
C2EA to ] FA f &,V 1(J L� t W ,6 v +"
Equipment Documentation and Ins ent Calibration Data Sheet
Project Name: LassondePappas nloring Analyst Conducting Calibration:
Project Number. C21482-01.01 Task 7 Date of Calibration:
Project Location: Hendersonville, NC Date of Field Measurements:
Facility ID or Permit # (if applicable): Permit No. W00004797
EQUIPMENT DOCUMENTATION
Rental sample analysis equipment or meters used to take measurements
Equipment Type Brand 1 Serial Number Date of Use Rental Company
Select Turbidimeter. Hach 21000 (s/n 151006045207)
HF Scientific MicroTPW (s/n 200601045)
Anchor QEA of North Carolina, PLLC
231 Haywood Street
Ach-All. North rarnlinn 9AR01
Instrument Readings
(Hach 2100Q)
Instrument Readings
iHF Scientific MicroTP
Cal Std Information
10 NTU
20 NTU
100 U
800 NTU
1,000 NTU
10.0 NTU
0.02
Lot #;
Expiration Date..
Cal (N n1
Cal
Cal ( .
)Time:
Cal (NTU):
Cal (NTU):
(NTU):
Time:
Time: y 1 ±.`'`��i
Tim :' L '
Time:
Time:
on:
`Pre -Analysis
Check (10 NFU):
Resul (NT G
s ly
Time:
�,J
•Pre -Analysis
Check (10 NTU
R (NTU):
Time:
ECalflibral,ion
-Post-Analysis
Check (10 NTU):
Result (NTU):
q 1
Time:
"Port -An is
[ 10 NTU):
Result (NTU):
Time:
'YSI Professional Plus Multiparameter Meter (s/n 1913101802)
Instrument Readings
Cal Std Inform lop
Lot #
D
4 ened
Ex. Date
P
Dissolved Oxygen
(% saturation)
Initial (%):
Cal (%):
mmHg:
Temperature CQ
Time:
DO (Site #2,
'tf Iicable .
Initial (%):
Cal (%):
mmHg:
Temperature CC):
QC** Check: DO
Time:
Result (%):
Time:
Result(46):
E-Trime:JREesult
PH 7S.U.
report to 0.1 S. U.
Initial:
pHmV:
Cal (S.U.):
pHmV:
Time:
pH 4S.U.
report to 0.1 S.U.
Initial:
pHmV:
Cal (S.U.):
p
Time:
pH 10 S.U.
report to 0.1 S.U.
Initial:
pHmV:
Cal (S.U. •
pHmV:
Time:
QC-- pH 7 S.U.
r rrro0.ls.u.
Time:
Result (S.U.):
ime:
Result (S.U.):
Time:
Result (S.U.):
spec.Cond.
1.000 mhos/cm
initial:
Cal( /cm):
Time:
% Recovery-
QC­ Spec. Cond.
1,000 linihicai
Timms•
Result (pmhos/cm): I
Time:
Result (pmhos/cm):
Time:
Result (pmhos/cm):
% Recovery=
ORP 200 mV
Initial:
Cal:
Temperature CQ
Time:
Analyst Signature:
Analyst Name: 1 Date:
2,
Notes:
Revision 6,1220/20, MAK
1. Instruments shall be calibrated in accordance With the manufacturer's operation manual.
2. Specific Conductivity should be calibrated according to values representative of historic range.
3. Order of Calibration is as follows: Specific Conductivity, pH 7, pH 4, pH 10, DO, ORP, QC checks.
4. *When performing DO analyses at multiple sample sites (i.e. project/facility locations), the DO probe must be calibrated at each sample site priorto analysis.
5. QC Acceptable Ranges: pH +/- 0.1 S.U. and Specific Conductivity 107.of the true value. If QC readings are out of range, the instrument needs to be recalibrated.
6.'• QC check must be performed priorto sampling and following completion of sampling, at a minimum. CC checks must be performed with calibration standard from a separate lot # as the initial QC.
7. % Recovery = (Value Obtained, pmhos/cm a True Value, pmhos/cm) x 100
8. NC Field Laboratory Certificate Number 5445
9. Documentation errors are to be crossed out with a single line, so the original text is still legible, followed by the staff members initials and date
10. Unless otherwise noted, all DO calibrations and measurements are performed at 0 ppt Salinity.
11. 1 pmho/cm = 1 p5/cm
Abbreviatiorw
pmhos/cm: micromhcs per centimeter
'C: degrees Celsius
DO: dissolved oxygen
mg/L milligrams per liter
mV: millivolt
NTU: nephelometric turbidity units
ORP: oxidation reduction potential
s/n: serial number
S.U.: standard units
Spec Cond.: Specific Conductivity
Method Reference:
Temperature: SM 2550 B-2010
Specific conductivity: EPA Method 120.1, Rev, 1982
DO: SM 4500 O G-2011
PH: SM 4500-H' 0-2011
Turbidity: SM 2130 B-2011
Page 1 of 1

Attachment 2
Laboratory Analytical Reports and
Chain -of -Custody Forms

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
May 16, 2022
Jennifer Verde
Anchor QEA
231 Haywood Street
Asheville, NC 28801
RE: Project: Lassonde Pappas WQ 5/10
Pace Project No.: 92603755
Dear Jennifer Verde:
Enclosed are the analytical results for sample(s) received by the laboratory on May 10, 2022. The results relate only to the
samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace Analytical Services - Asheville
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Lord Patton
[e-mail]
1(828)254-7176
Project Manager
Enclosures
�pQ AC RFb
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 1 of 27

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
CERTIFICATIONS
Project: Lassonde Pappas WQ 5/10
Pace Project No.: 92603755
Pace Analytical Services Asheville
2225 Riverside Drive, Asheville, NC 28804 South Carolina Laboratory ID: 99030
Florida/NELAP Certification #: E87648 South Carolina Certification #: 99030001
North Carolina Drinking Water Certification #: 37712 Virginia/VELAP Certification #: 460222
North Carolina Wastewater Certification #: 40
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 2 of 27

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
SAMPLE ANALYTE COUNT
Project:
Pace Project No.:
Lassonde Pappas WQ 5/10
92603755
Analytes
Lab lD
Sample ID
Method
Analysts
Reported
Laboratory
92603755001
MW-4-20220510
SM 2540C-2015
MAB2
1
PASI-A
SM 9222D-2015
YEG
1
PASI-A
EPA 350.1 Rev 2.0 1993
NDS
1
PASI-A
EPA 353.2 Rev 2.0 1993
MFO
1
PASI-A
EPA 365.1 Rev 2.0 1993
SMT
1
PASI-A
SM 4500-CI-E-2011
MDW
1
PASI-A
SM 531OB-2014
MJP
1
PASI-A
92603755002
MW-5-20220510
SM 2540C-2015
MAB2
1
PASI-A
SM 9222D-2015
YEG
1
PASI-A
EPA 350.1 Rev 2.0 1993
NDS
1
PASI-A
EPA 353.2 Rev 2.0 1993
MFO
1
PASI-A
EPA 365.1 Rev 2.0 1993
SMT
1
PASI-A
SM 4500-CI-E-2011
MDW
1
PASI-A
SM 531OB-2014
MJP
1
PASI-A
92603755003
MW-6-20220510
SM 2540C-2015
MAB2
1
PASI-A
SM 9222D-2015
YEG
1
PASI-A
EPA 350.1 Rev 2.0 1993
NDS
1
PASI-A
EPA 353.2 Rev 2.0 1993
MFO
1
PASI-A
EPA 365.1 Rev 2.0 1993
SMT
1
PASI-A
SM 4500-CI-E-2011
MDW
1
PASI-A
SM 531OB-2014
MJP
1
PASI-A
92603755004
MW-7R-20220510
SM 2540C-2015
MAB2
1
PASI-A
SM 9222D-2015
YEG
1
PASI-A
EPA 350.1 Rev 2.0 1993
NDS
1
PASI-A
EPA 353.2 Rev 2.0 1993
MFO
1
PASI-A
EPA 365.1 Rev 2.0 1993
SMT
1
PASI-A
SM 4500-CI-E-2011
MDW
1
PASI-A
SM 531OB-2014
MJP
1
PASI-A
92603755005
MW-8-20220510
SM 2540C-2015
MAB2
1
PASI-A
SM 9222D-2015
YEG
1
PASI-A
EPA 350.1 Rev 2.0 1993
NDS
1
PASI-A
EPA 353.2 Rev 2.0 1993
MFO
1
PASI-A
EPA 365.1 Rev 2.0 1993
SMT
1
PASI-A
SM 4500-CI-E-2011
MDW
1
PASI-A
SM 531OB-2014
MJP
1
PASI-A
92603755006
MW-9-20220510
SM 2540C-2015
MAB2
1
PASI-A
SM 9222D-2015
YEG
1
PASI-A
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 3 of 27

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
SAMPLE ANALYTE COUNT
Project: Lassonde Pappas WQ 5/10
Pace Project No.: 92603755
Lab ID Sample ID Method
Analysts
Analytes
Reported
Laboratory
EPA 350.1 Rev 2.0 1993
NDS
1
PASI-A
EPA 353.2 Rev 2.0 1993
MFO
1
PASI-A
EPA 365.1 Rev 2.0 1993
SMT
1
PASI-A
SM 4500-CI-E-2011
MDW
1
PASI-A
SM 531OB-2014
MJP
1
PASI-A
92603755007 SW-1-20220510 SM 2540C-2015
MAB2
1
PASI-A
SM 9222D-2015
YEG
1
PASI-A
EPA 350.1 Rev 2.0 1993
NDS
1
PASI-A
EPA 353.2 Rev 2.0 1993
MFO
1
PASI-A
EPA 365.1 Rev 2.0 1993
SMT
1
PASI-A
SM 4500-CI-E-2011
MDW
1
PASI-A
SM 531OB-2014
MJP
1
PASI-A
92603755008 SW-2-20220510 SM 2540C-2015
MAB2
1
PASI-A
SM 9222D-2015
YEG
1
PASI-A
EPA 350.1 Rev 2.0 1993
NDS
1
PASI-A
EPA 353.2 Rev 2.0 1993
MFO
1
PASI-A
EPA 365.1 Rev 2.0 1993
SMT
1
PASI-A
SM 4500-CI-E-2011
MDW
1
PASI-A
SM 531OB-2014
MJP
1
PASI-A
PASI-A = Pace Analytical Services -Asheville
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 4 of 27

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Project: Lassonde Pappas WQ 5/10
Pace Project No.: 92603755
Sample: MW-4-20220510 Lab ID: 92603755001 Collected: 05/10/22 12:49 Received: 05/10/22 14:56 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
2540C Total Dissolved Solids
Analytical Method: SM 2540C-2015
Pace Analytical Services -Asheville
Total Dissolved Solids
136 mg/L 25.0
1
05/13/22 09:26
MBIO 9222D Fecal Coliform AVL
Analytical Method: SM 9222D-2015 Preparation
Method: SM 9222D-2015
Pace Analytical Services -Asheville
Fecal Coliforms
ND CFU/100 mL 1.0
1
05/10/22 16:10 05/11/22 14:22
350.1 Ammonia
Analytical Method: EPA 350.1 Rev 2.0 1993
Pace Analytical Services -Asheville
Nitrogen, Ammonia
ND mg/L 0.10
1
05/12/22 11:45
7664-41-7
353.2 Nitrogen, NO2/NO3 unpres
Analytical Method: EPA 353.2 Rev 2.0 1993
Pace Analytical Services -Asheville
Nitrogen, Nitrate
0.46 mg/L 0.040
1
05/11/22 03:09
14797-55-8
365.1 Phosphorus, Total
Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation Method: EPA 365.1 Rev 2.0 1993
Pace Analytical Services -Asheville
Phosphorus
0.063 mg/L 0.050
1
05/12/22 17:53 05/12/22 21:12
7723-14-0
4500 Chloride
Analytical Method: SM 4500-CI-E-2011
Pace Analytical Services -Asheville
Chloride
6.8 mg/L 1.0
1
05/12/2214:33
16887-00-6
531013 TOC
Analytical Method: SM 531 OB-2014
Pace Analytical Services -Asheville
Total Organic Carbon
2.9 mg/L 1.0
1
05/13/22 13:03
7440-44-0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/16/2022 02:14 PM without the written consent of Pace Analytical Services, LLC. Page 5 of 27

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Project: Lassonde Pappas WQ 5/10
Pace Project No.: 92603755
Sample: MW-5-20220510 Lab ID: 92603755002 Collected: 05/10/22 13:35 Received: 05/10/22 14:56 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
2540C Total Dissolved Solids
Analytical Method: SM 2540C-2015
Pace Analytical Services -Asheville
Total Dissolved Solids
158 mg/L 25.0
1
05/13/22 09:26
MBIO 9222D Fecal Coliform AVL
Analytical Method: SM 9222D-2015 Preparation
Method: SM 9222D-2015
Pace Analytical Services -Asheville
Fecal Coliforms
ND CFU/100 mL 1.0
1
05/10/22 16:10 05/11/22 14:22
350.1 Ammonia
Analytical Method: EPA 350.1 Rev 2.0 1993
Pace Analytical Services -Asheville
Nitrogen, Ammonia
ND mg/L 0.10
1
05/12/22 11:48
7664-41-7
353.2 Nitrogen, NO2/NO3 unpres
Analytical Method: EPA 353.2 Rev 2.0 1993
Pace Analytical Services -Asheville
Nitrogen, Nitrate
0.10 mg/L 0.040
1
05/11/22 03:12
14797-55-8
365.1 Phosphorus, Total
Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation Method: EPA 365.1 Rev 2.0 1993
Pace Analytical Services -Asheville
Phosphorus
ND mg/L 0.050
1
05/12/22 17:53 05/12/22 21:13
7723-14-0
4500 Chloride
Analytical Method: SM 4500-CI-E-2011
Pace Analytical Services -Asheville
Chloride
49.0 mg/L 2.0
2
05/12/2214:58
16887-00-6
531013 TOC
Analytical Method: SM 531 OB-2014
Pace Analytical Services -Asheville
Total Organic Carbon
2.7 mg/L 1.0
1
05/13/22 13:57
7440-44-0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/16/2022 02:14 PM without the written consent of Pace Analytical Services, LLC. Page 6 of 27

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Project: Lassonde Pappas WQ 5/10
Pace Project No.: 92603755
Sample: MW-6-20220510 Lab ID: 92603755003 Collected: 05/10/22 11:40 Received: 05/10/22 14:56 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
2540C Total Dissolved Solids
Analytical Method: SM 2540C-2015
Pace Analytical Services -Asheville
Total Dissolved Solids
96.0 mg/L 25.0
1
05/13/22 09:26
MBIO 9222D Fecal Coliform AVL
Analytical Method: SM 9222D-2015 Preparation
Method: SM 9222D-2015
Pace Analytical Services -Asheville
Fecal Coliforms
ND CFU/100 mL 1.0
1
05/10/22 16:10 05/11/22 14:22
350.1 Ammonia
Analytical Method: EPA 350.1 Rev 2.0 1993
Pace Analytical Services -Asheville
Nitrogen, Ammonia
ND mg/L 0.10
1
05/12/22 11:49
7664-41-7
353.2 Nitrogen, NO2/NO3 unpres
Analytical Method: EPA 353.2 Rev 2.0 1993
Pace Analytical Services -Asheville
Nitrogen, Nitrate
ND mg/L 0.040
1
05/11/22 03:07
14797-55-8
365.1 Phosphorus, Total
Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation Method: EPA 365.1 Rev 2.0 1993
Pace Analytical Services -Asheville
Phosphorus
ND mg/L 0.050
1
05/12/22 17:53 05/12/22 21:22
7723-14-0
4500 Chloride
Analytical Method: SM 4500-CI-E-2011
Pace Analytical Services -Asheville
Chloride
13.6 mg/L 1.0
1
05/12/2214:35
16887-00-6
531013 TOC
Analytical Method: SM 531 OB-2014
Pace Analytical Services -Asheville
Total Organic Carbon
1.5 mg/L 1.0
1
05/13/22 14:19
7440-44-0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/16/2022 02:14 PM without the written consent of Pace Analytical Services, LLC. Page 7 of 27

leAnalyiical
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2225 Riverside Dr.
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ANALYTICAL RESULTS
Project: Lassonde Pappas WQ 5/10
Pace Project No.: 92603755
Sample: MW-7R-20220510 Lab ID: 92603755004 Collected: 05/10/22 09:34 Received: 05/10/22 14:56 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
2540C Total Dissolved Solids
Analytical Method: SM 2540C-2015
Pace Analytical Services -Asheville
Total Dissolved Solids
279 mg/L 25.0
1
05/13/22 09:26
MBIO 9222D Fecal Coliform AVL
Analytical Method: SM 9222D-2015 Preparation
Method: SM 9222D-2015
Pace Analytical Services -Asheville
Fecal Coliforms
ND CFU/100 mL 1.0
1
05/10/22 15:44 05/11/22 14:22
350.1 Ammonia
Analytical Method: EPA 350.1 Rev 2.0 1993
Pace Analytical Services -Asheville
Nitrogen, Ammonia
ND mg/L 0.10
1
05/12/22 11:50
7664-41-7
353.2 Nitrogen, NO2/NO3 unpres
Analytical Method: EPA 353.2 Rev 2.0 1993
Pace Analytical Services -Asheville
Nitrogen, Nitrate
31.0 mg/L 0.40
10
05/11/22 03:20
14797-55-8
365.1 Phosphorus, Total
Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation
Method: EPA 365.1 Rev 2.0 1993
Pace Analytical Services -Asheville
Phosphorus
ND mg/L 0.050
1
05/12/22 17:53 05/12/22 21:25
7723-14-0
4500 Chloride
Analytical Method: SM 4500-CI-E-2011
Pace Analytical Services -Asheville
Chloride
30.8 mg/L 1.0
1
05/12/2214:36
16887-00-6
531013 TOC
Analytical Method: SM 531 OB-2014
Pace Analytical Services -Asheville
Total Organic Carbon
ND mg/L 1.0
1
05/13/22 14:37
7440-44-0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/16/2022 02:14 PM without the written consent of Pace Analytical Services, LLC. Page 8 of 27

leAnalyiical
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2225 Riverside Dr.
Asheville, NC 28804
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ANALYTICAL RESULTS
Project: Lassonde Pappas WQ 5/10
Pace Project No.: 92603755
Sample: MW-8-20220510 Lab ID: 92603755005 Collected: 05/10/22 08:09 Received: 05/10/22 14:56 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
2540C Total Dissolved Solids
Analytical Method: SM 2540C-2015
Pace Analytical Services -Asheville
Total Dissolved Solids
240 mg/L 25.0
1
05/13/22 09:26
MBIO 9222D Fecal Coliform AVL
Analytical Method: SM 9222D-2015 Preparation
Method: SM 9222D-2015
Pace Analytical Services -Asheville
Fecal Coliforms
ND CFU/100 mL 1.0
1
05/10/22 15:44 05/11/22 14:22
350.1 Ammonia
Analytical Method: EPA 350.1 Rev 2.0 1993
Pace Analytical Services -Asheville
Nitrogen, Ammonia
ND mg/L 0.10
1
05/12/22 11:52
7664-41-7
353.2 Nitrogen, NO2/NO3 unpres
Analytical Method: EPA 353.2 Rev 2.0 1993
Pace Analytical Services -Asheville
Nitrogen, Nitrate
3.2 mg/L 0.040
1
05/11/22 02:56
14797-55-8
365.1 Phosphorus, Total
Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation Method: EPA 365.1 Rev 2.0 1993
Pace Analytical Services -Asheville
Phosphorus
ND mg/L 0.050
1
05/12/22 17:53 05/12/22 21:28
7723-14-0
4500 Chloride
Analytical Method: SM 4500-CI-E-2011
Pace Analytical Services -Asheville
Chloride
7.4 mg/L 1.0
1
05/12/2214:36
16887-00-6
531013 TOC
Analytical Method: SM 531 OB-2014
Pace Analytical Services -Asheville
Total Organic Carbon
4.5 mg/L 1.0
1
05/13/22 14:57
7440-44-0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/16/2022 02:14 PM without the written consent of Pace Analytical Services, LLC. Page 9 of 27

leAnalyiical
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Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Project: Lassonde Pappas WQ 5/10
Pace Project No.: 92603755
Sample: MW-9-20220510 Lab ID: 92603755006 Collected: 05/10/22 10:29 Received: 05/10/22 14:56 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
2540C Total Dissolved Solids
Total Dissolved Solids
MBIO 9222D Fecal Coliform AVL
Fecal Coliforms
350.1 Ammonia
Nitrogen, Ammonia
353.2 Nitrogen, NO2/NO3 unpres
Nitrogen, Nitrate
365.1 Phosphorus, Total
Phosphorus
4500 Chloride
Chloride
531013 TOC
Total Organic Carbon
Date: 05/16/2022 02:14 PM
Analytical Method: SM 2540C-2015
Pace Analytical Services -Asheville
67.0 mg/L 25.0
1
05/13/22 09:26
Analytical Method: SM 9222D-2015 Preparation
Method: SM 9222D-2015
Pace Analytical Services -Asheville
ND CFU/100 mL 1.0
1
05/10/22 15:44 05/11/22 14:22
Analytical Method: EPA 350.1 Rev 2.0 1993
Pace Analytical Services -Asheville
ND mg/L 0.10
1
05/12/2212:21
7664-41-7
Analytical Method: EPA 353.2 Rev 2.0 1993
Pace Analytical Services -Asheville
1.5 mg/L 0.040
1
05/11/22 03:05
14797-55-8
Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation Method: EPA 365.1 Rev 2.0 1993
Pace Analytical Services -Asheville
0.086 mg/L 0.050
1
05/12/22 17:53 05/12/22 21:28
7723-14-0
Analytical Method: SM 4500-CI-E-2011
Pace Analytical Services -Asheville
6.3 mg/L 1.0
1
05/12/2214:37
16887-00-6
Analytical Method: SM 531OB-2014
Pace Analytical Services -Asheville
3.6 mg/L 1.0
1
05/13/2215:54
7440-44-0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 10 of 27

leAnalyiical
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Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Project: Lassonde Pappas WQ 5/10
Pace Project No.: 92603755
Sample: SW-1-20220510 Lab ID: 92603755007 Collected: 05/10/22 14:05 Received: 05/10/22 14:56 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
2540C Total Dissolved Solids
Total Dissolved Solids
MBIO 9222D Fecal Coliform AVL
Fecal Coliforms
350.1 Ammonia
Nitrogen, Ammonia
353.2 Nitrogen, NO2/NO3 unpres
Nitrogen, Nitrate
365.1 Phosphorus, Total
Phosphorus
4500 Chloride
Chloride
531013 TOC
Total Organic Carbon
Date: 05/16/2022 02:14 PM
Analytical Method: SM 2540C-2015
Pace Analytical Services -Asheville
51.0 mg/L 25.0
1
05/13/22 09:26
Analytical Method: SM 9222D-2015 Preparation
Method: SM 9222D-2015
Pace Analytical Services -Asheville
81.0 CFU/100 mL 1.0
1
05/10/22 16:10 05/11/22 14:22
Analytical Method: EPA 350.1 Rev 2.0 1993
Pace Analytical Services -Asheville
0.12 mg/L 0.10
1
05/12/2212:27
7664-41-7
Analytical Method: EPA 353.2 Rev 2.0 1993
Pace Analytical Services -Asheville
0.88 mg/L 0.040
1
05/11/22 03:16
14797-55-8
Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation Method: EPA 365.1 Rev 2.0 1993
Pace Analytical Services -Asheville
0.15 mg/L 0.050
1
05/12/22 17:53 05/12/22 21:29
7723-14-0
Analytical Method: SM 4500-CI-E-2011
Pace Analytical Services -Asheville
5.1 mg/L 1.0
1
05/12/2214:38
16887-00-6
Analytical Method: SM 531OB-2014
Pace Analytical Services -Asheville
1.4 mg/L 1.0
1
05/13/2216:11
7440-44-0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 11 of 27

leAnalyiical
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Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Project: Lassonde Pappas WQ 5/10
Pace Project No.: 92603755
Sample: SW-2-20220510 Lab ID: 92603755008 Collected: 05/10/22 08:40 Received: 05/10/22 14:56 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
2540C Total Dissolved Solids
Total Dissolved Solids
MBIO 9222D Fecal Coliform AVL
Fecal Coliforms
350.1 Ammonia
Nitrogen, Ammonia
353.2 Nitrogen, NO2/NO3 unpres
Nitrogen, Nitrate
365.1 Phosphorus, Total
Phosphorus
4500 Chloride
Chloride
531013 TOC
Total Organic Carbon
Date: 05/16/2022 02:14 PM
Analytical Method: SM 2540C-2015
Pace Analytical Services -Asheville
50.0 mg/L 25.0
1
05/13/22 09:27
Analytical Method: SM 9222D-2015 Preparation
Method: SM 9222D-2015
Pace Analytical Services -Asheville
118 CFU/100 mL 1.0
1
05/10/22 15:44 05/11/22 14:22
Analytical Method: EPA 350.1 Rev 2.0 1993
Pace Analytical Services -Asheville
ND mg/L 0.10
1
05/12/2212:28
7664-41-7
Analytical Method: EPA 353.2 Rev 2.0 1993
Pace Analytical Services -Asheville
0.87 mg/L 0.040
1
05/11/22 02:59
14797-55-8
Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation Method: EPA 365.1 Rev 2.0 1993
Pace Analytical Services -Asheville
0.16 mg/L 0.050
1
05/12/22 17:53 05/12/22 21:30
7723-14-0
Analytical Method: SM 4500-CI-E-2011
Pace Analytical Services -Asheville
4.9 mg/L 1.0
1
05/12/2214:39
16887-00-6
Analytical Method: SM 531OB-2014
Pace Analytical Services -Asheville
1.4 mg/L 1.0
1
05/13/2216:29
7440-44-0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 12 of 27

leAnalyiical
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Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: Lassonde Pappas WQ 5/10
Pace Project No.: 92603755
QC Batch: 697955 Analysis Method: SM 2540C-2015
QC Batch Method: SM 2540C-2015 Analysis Description: 2540C Total Dissolved Solids
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92603755001, 92603755002, 92603755003, 92603755004, 92603755005, 92603755006, 92603755007,
92603755008
METHOD BLANK: 3644587 Matrix: Water
Associated Lab Samples: 92603755001, 92603755002, 92603755003, 92603755004, 92603755005, 92603755006, 92603755007,
92603755008
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Total Dissolved Solids mg/L ND 25.0 05/13/22 09:26
LABORATORY CONTROL SAMPLE: 3644588
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Total Dissolved Solids mg/L 250 248 99 90-110
SAMPLE DUPLICATE: 3644589
92604026005
Dup
Parameter
Units
Result
Result RPD Qualifiers
Total Dissolved Solids
mg/L
102
97.0 5
SAMPLE DUPLICATE: 3644590
92603988001
Dup
Parameter
Units
Result
Result RPD Qualifiers
Total Dissolved Solids
mg/L
2600
2200 17
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/16/2022 02:14 PM without the written consent of Pace Analytical Services, LLC. Page 13 of 27

leAnalyiical
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Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: Lassonde Pappas WQ 5/10
Pace Project No.: 92603755
QC Batch: 697585 Analysis Method: SM 9222D-2015
QC Batch Method: SM 9222D-2015 Analysis Description: 9222D Fecal Coliform(MF) -AVL
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92603755001, 92603755002, 92603755003, 92603755004, 92603755005, 92603755006, 92603755007,
92603755008
METHOD BLANK: 3642586 Matrix: Water
Associated Lab Samples: 92603755001, 92603755002, 92603755003, 92603755004, 92603755005, 92603755006, 92603755007,
92603755008
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Fecal Coliforms CFU/100 mL ND 1.0 05/11/22 14:22
SAMPLE DUPLICATE: 3642587
92603577002 Dup
Parameter Units Result Result RPD Qualifiers
Fecal Coliforms CFU/100 mL ND ND
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/16/2022 02:14 PM without the written consent of Pace Analytical Services, LLC.
Page 14 of 27

leAnalyiical
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Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: Lassonde Pappas WQ 5/10
Pace Project No.: 92603755
QC Batch: 697551 Analysis Method: EPA 350.1 Rev 2.0 1993
QC Batch Method: EPA 350.1 Rev 2.0 1993 Analysis Description: 350.1 Ammonia
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92603755001, 92603755002, 92603755003, 92603755004
METHOD BLANK: 3642322
Matrix:
Water
Associated Lab Samples: 92603755001, 92603755002, 92603755003, 92603755004
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed Qualifiers
Nitrogen, Ammonia
mg/L
ND
0.10
05/12/22 11:06
LABORATORY CONTROL SAMPLE:
3642323
Spike
LCS
LCS % Rec
Parameter
Units
Conc.
Result
% Rec Limits Qualifiers
Nitrogen, Ammonia
mg/L
5
5.1
102 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3642324 3642325
MS MSD
92603580001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Nitrogen, Ammonia mg/L 0.11 5 5 5.3 5.3 103 103 90-110 0
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3642326 3642327
MS MSD
92603580002 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Nitrogen, Ammonia mg/L ND 5 5 5.2 5.2 104 104 90-110 0
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/16/2022 02:14 PM without the written consent of Pace Analytical Services, LLC.
Page 15 of 27

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: Lassonde Pappas WQ 5/10
Pace Project No.: 92603755
QC Batch: 697556 Analysis Method: EPA 350.1 Rev 2.0 1993
QC Batch Method: EPA 350.1 Rev 2.0 1993 Analysis Description: 350.1 Ammonia
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92603755005, 92603755006, 92603755007, 92603755008
METHOD BLANK: 3642336
Matrix:
Water
Associated Lab Samples: 92603755005, 92603755006, 92603755007, 92603755008
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed Qualifiers
Nitrogen, Ammonia
mg/L
ND
0.10
05/12/22 11:09
LABORATORY CONTROL SAMPLE:
3642337
Spike
LCS
LCS % Rec
Parameter
Units
Conc.
Result
% Rec Limits Qualifiers
Nitrogen, Ammonia
mg/L
5
5.1
101 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3642338 3642339
MS MSD
92603755005 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Nitrogen, Ammonia mg/L ND 5 5 5.0 5.0 100 99 90-110 1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3642340 3642341
MS MSD
92603755006 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Nitrogen, Ammonia mg/L ND 5 5 5.2 5.2 103 103 90-110 0
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/16/2022 02:14 PM without the written consent of Pace Analytical Services, LLC.
Page 16 of 27

leAnalyiical
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Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: Lassonde Pappas WQ 5/10
Pace Project No.: 92603755
QC Batch: 697337 Analysis Method: EPA 353.2 Rev 2.0 1993
QC Batch Method: EPA 353.2 Rev 2.0 1993 Analysis Description: 353.2 Nitrate + Nitrite, Unpres.
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92603755001, 92603755002, 92603755003, 92603755004, 92603755005, 92603755006, 92603755007,
92603755008
METHOD BLANK: 3641497 Matrix: Water
Associated Lab Samples: 92603755001, 92603755002, 92603755003, 92603755004, 92603755005, 92603755006, 92603755007,
92603755008
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Nitrogen, Nitrate mg/L ND 0.040 05/11/22 02:51
LABORATORY CONTROL SAMPLE: 3641498
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Nitrogen, Nitrate mg/L 1.5 1.5 99 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3641501 3641502
MS MSD
92603755001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Nitrogen, Nitrate mg/L 0.46 1.5 1.5 1.9 1.9 99 98 90-110 1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3641503 3641504
MS MSD
92603755005 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Nitrogen, Nitrate mg/L 3.2 1.5 1.5 6.5 7.4 220 280 90-110 13
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/16/2022 02:14 PM without the written consent of Pace Analytical Services, LLC.
Page 17 of 27

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: Lassonde Pappas WQ 5/10
Pace Project No.: 92603755
QC Batch: 697658 Analysis Method: EPA 365.1 Rev 2.0 1993
QC Batch Method: EPA 365.1 Rev 2.0 1993 Analysis Description: 365.1 Phosphorus, Total
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92603755001, 92603755002
METHOD BLANK: 3642918
Matrix:
Water
Associated Lab Samples: 92603755001, 92603755002
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed Qualifiers
Phosphorus
mg/L
ND
0.050
05/12/22 20:51
LABORATORY CONTROL SAMPLE:
3642919
Spike
LCS
LCS % Rec
Parameter
Units
Conc.
Result
% Rec Limits Qualifiers
Phosphorus
mg/L
2.5
2.5
101 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3642920 3642921
MS MSD
92599340001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Phosphorus mg/L 0.25 2.5 2.5 2.8 2.8 102 102 90-110 0
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3642922 3642923
MS MSD
92602789002 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Phosphorus mg/L 0.87 2.5 2.5 2.7 2.8 75 76 90-110 1 M1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/16/2022 02:14 PM without the written consent of Pace Analytical Services, LLC.
Page 18 of 27

leAnalyiical
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Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: Lassonde Pappas WQ 5/10
Pace Project No.: 92603755
QC Batch: 697659 Analysis Method: EPA 365.1 Rev 2.0 1993
QC Batch Method: EPA 365.1 Rev 2.0 1993 Analysis Description: 365.1 Phosphorus, Total
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92603755003, 92603755004, 92603755005, 92603755006, 92603755007, 92603755008
METHOD BLANK: 3642924
Matrix:
Water
Associated Lab Samples: 92603755003, 92603755004, 92603755005, 92603755006, 92603755007, 92603755008
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed Qualifiers
Phosphorus
mg/L
ND
0.050
05/12/22 21:19
LABORATORY CONTROL SAMPLE:
3642925
Spike
LCS
LCS % Rec
Parameter
Units
Conc.
Result
% Rec Limits Qualifiers
Phosphorus
mg/L
2.5
2.5
101 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3642926 3642927
MS MSD
92603377001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Phosphorus mg/L ND 2.5 2.5 1.5 1.3 46 37 90-110 16 M1,R1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3642928 3642929
MS MSD
92603755003 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Phosphorus mg/L ND 2.5 2.5 2.6 2.6 103 102 90-110 0
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/16/2022 02:14 PM without the written consent of Pace Analytical Services, LLC.
Page 19 of 27

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: Lassonde Pappas WQ 5/10
Pace Project No.: 92603755
QC Batch: 697704 Analysis Method: SM 4500-CI-E-2011
QC Batch Method: SM 4500-CI-E-2011 Analysis Description: 4500 Chloride
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92603755001, 92603755002, 92603755003, 92603755004, 92603755005, 92603755006, 92603755007,
92603755008
METHOD BLANK: 3643000 Matrix: Water
Associated Lab Samples: 92603755001, 92603755002, 92603755003, 92603755004, 92603755005, 92603755006, 92603755007,
92603755008
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Chloride mg/L ND 1.0 05/12/2214:17
LABORATORY CONTROL SAMPLE: 3643001
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Chloride mg/L 20 20.5 102 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3643002 3643003
MS MSD
92602669001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Chloride mg/L 128 10 10 140 143 128 148 90-110 1 M1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3643004 3643005
MS MSD
92602721004 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Chloride mg/L 8.2 10 10 17.8 18.1 97 100 90-110 2
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/16/2022 02:14 PM without the written consent of Pace Analytical Services, LLC.
Page 20 of 27

leAnalyiical
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Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: Lassonde Pappas WQ 5/10
Pace Project No.: 92603755
QC Batch: 698019 Analysis Method: SM 531 OB-2014
QC Batch Method: SM 531 OB-2014 Analysis Description: 5310E TOC
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92603755001, 92603755002, 92603755003, 92603755004, 92603755005, 92603755006, 92603755007,
92603755008
METHOD BLANK: 3644741 Matrix: Water
Associated Lab Samples: 92603755001, 92603755002, 92603755003, 92603755004, 92603755005, 92603755006, 92603755007,
92603755008
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Total Organic Carbon mg/L ND 1.0 05/13/22 12:07
LABORATORY CONTROL SAMPLE: 3644742
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Total Organic Carbon mg/L 25 24.8 99 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3644743 3644744
MS MSD
92603755001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Total Organic Carbon mg/L 2.9 25 25 26.9 26.9 96 96 90-110 0
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3644745 3644746
MS MSD
92603836003 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Total Organic Carbon mg/L ND 25 25 24.6 24.4 98 97 90-110 1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/16/2022 02:14 PM without the written consent of Pace Analytical Services, LLC.
Page 21 of 27

leAnalyiical
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Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALIFIERS
Project: Lassonde Pappas WQ 5/10
Pace Project No.: 92603755
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as
"Total" may vary slightly from the sum of the reported component parameters.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TN -The NELAC Institute.
ANALYTE QUALIFIERS
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
R1 RPD value was outside control limits.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/16/2022 02:14 PM without the written consent of Pace Analytical Services, LLC. Page 22 of 27

leAnalyiical
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Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: Lassonde Pappas WQ 5/10
Pace Project No.: 92603755
Analytical
Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch
92603755001
MW-4-20220510
SM
2540C-2015
697955
92603755002
MW-5-20220510
SM
2540C-2015
697955
92603755003
MW-6-20220510
SM
2540C-2015
697955
92603755004
MW-7R-20220510
SM
2540C-2015
697955
92603755005
MW-8-20220510
SM
2540C-2015
697955
92603755006
MW-9-20220510
SM
2540C-2015
697955
92603755007
SW-1-20220510
SM
2540C-2015
697955
92603755008
SW-2-20220510
SM
2540C-2015
697955
92603755001
MW-4-20220510
SM 9222D-2015
697585
SM 9222D-2015
697586
92603755002
MW-5-20220510
SM 9222D-2015
697585
SM 9222D-2015
697586
92603755003
MW-6-20220510
SM 9222D-2015
697585
SM 9222D-2015
697586
92603755004
MW-7R-20220510
SM 9222D-2015
697585
SM 9222D-2015
697586
92603755005
MW-8-20220510
SM 9222D-2015
697585
SM 9222D-2015
697586
92603755006
MW-9-20220510
SM 9222D-2015
697585
SM 9222D-2015
697586
92603755007
SW-1-20220510
SM 9222D-2015
697585
SM 9222D-2015
697586
92603755008
SW-2-20220510
SM 9222D-2015
697585
SM 9222D-2015
697586
92603755001
MW-4-20220510
EPA 350.1 Rev 2.0 1993
697551
92603755002
MW-5-20220510
EPA 350.1 Rev 2.0 1993
697551
92603755003
MW-6-20220510
EPA 350.1 Rev 2.0 1993
697551
92603755004
MW-7R-20220510
EPA 350.1 Rev 2.0 1993
697551
92603755005
MW-8-20220510
EPA 350.1 Rev 2.0 1993
697556
92603755006
MW-9-20220510
EPA 350.1 Rev 2.0 1993
697556
92603755007
SW-1-20220510
EPA 350.1 Rev 2.0 1993
697556
92603755008
SW-2-20220510
EPA 350.1 Rev 2.0 1993
697556
92603755001
MW-4-20220510
EPA 353.2 Rev 2.0 1993
697337
92603755002
MW-5-20220510
EPA 353.2 Rev 2.0 1993
697337
92603755003
MW-6-20220510
EPA 353.2 Rev 2.0 1993
697337
92603755004
MW-7R-20220510
EPA 353.2 Rev 2.0 1993
697337
92603755005
MW-8-20220510
EPA 353.2 Rev 2.0 1993
697337
92603755006
MW-9-20220510
EPA 353.2 Rev 2.0 1993
697337
92603755007
SW-1-20220510
EPA 353.2 Rev 2.0 1993
697337
92603755008
SW-2-20220510
EPA 353.2 Rev 2.0 1993
697337
92603755001
MW-4-20220510
EPA 365.1 Rev 2.0 1993
697658
EPA 365.1 Rev 2.0 1993
697930
92603755002
MW-5-20220510
EPA 365.1 Rev 2.0 1993
697658
EPA 365.1 Rev 2.0 1993
697930
92603755003
MW-6-20220510
EPA 365.1 Rev 2.0 1993
697659
EPA 365.1 Rev 2.0 1993
697932
92603755004
MW-7R-20220510
EPA 365.1 Rev 2.0 1993
697659
EPA 365.1 Rev 2.0 1993
697932
92603755005
MW-8-20220510
EPA 365.1 Rev 2.0 1993
697659
EPA 365.1 Rev 2.0 1993
697932
92603755006
MW-9-20220510
EPA 365.1 Rev 2.0 1993
697659
EPA 365.1 Rev 2.0 1993
697932
92603755007
SW-1-20220510
EPA 365.1 Rev 2.0 1993
697659
EPA 365.1 Rev 2.0 1993
697932
92603755008
SW-2-20220510
EPA 365.1 Rev 2.0 1993
697659
EPA 365.1 Rev 2.0 1993
697932
92603755001
MW-4-20220510
SM 4500-CI-E-2011
697704
92603755002
MW-5-20220510
SM 4500-CI-E-2011
697704
92603755003
MW-6-20220510
SM 4500-CI-E-2011
697704
92603755004
MW-7R-20220510
SM 4500-CI-E-2011
697704
92603755005
MW-8-20220510
SM 4500-CI-E-2011
697704
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/16/2022 02:14 PM without the written consent of Pace Analytical Services, LLC. Page 23 of 27

leAnalyiical
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Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: Lassonde Pappas WQ 5/10
Pace Project No.: 92603755
Lab ID
Sample ID
QC
Batch Method
QC Batch Analytical Method
92603755006
MW-9-20220510
SM
4500-CI-E-2011
697704
92603755007
SW-1-20220510
SM
4500-CI-E-2011
697704
92603755008
SW-2-20220510
SM
4500-CI-E-2011
697704
92603755001
MW-4-20220510
SM
5310B-2014
698019
92603755002
MW-5-20220510
SM
5310B-2014
698019
92603755003
MW-6-20220510
SM
5310B-2014
698019
92603755004
MW-7R-20220510
SM
5310B-2014
698019
92603755005
MW-8-20220510
SM
5310B-2014
698019
92603755006
MW-9-20220510
SM
5310B-2014
698019
92603755007
SW-1-20220510
SM
5310B-2014
698019
92603755008
SW-2-20220510
SM
5310B-2014
698019
Date: 05/16/2022 02:14 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Analytical
Batch
Page 24 of 27

Document Name:
Document Revised: November 15, 2021
Sample Conditlon Upon Receipt (SCUR)
Page 1 of 2
Document No.:
Issuing Authority:
aceAnaiyticai
F-CAR-CS-033-Rev.08
Pace Carolinas Quality Office
Laboratory receiving samples:
Asheville ❑ Eden❑ Greenwood ❑ Huntersville ❑ Raleigh❑ Mechanicsville[:] Atlanta[:] Kernersville❑
r
Samp
upon - ... Client Name: Protect # Wp# : 92603755
j(
,',nCVtJ� 4F
Courier: ❑fed Ex []UPS DUSPS ❑Client
❑ Commercial ❑Pate ❑Other:
92603755
Custody Seal Present? ❑Yes P3 seals Intact? ❑Yes No
Packing Material: 1]Bu bble wrap 3fubble Sags ❑None ❑ other
Date/Initials Person Examining Contents:-� ! / Z'
Biological Tissue Fro en?
Thermometer. ❑Yes ❑No /A
,-�� Wet ❑Blue []NonetGI IR Gun ID: "} Type of ice:
Correction Factor:
Cooler Temp: - — - --- Add/Subtract ('C) y Temp should be above freezing to VC
❑Samples out of temp criteria. Samples on ice, cooling process
Cooler Temp Corrected ('(4, % has begun
USDA Regulated Soil N/A, :eater sample)
Did samples originate in a gtarantine zone within the United States: CA, NY, or SC (check maps)? Did samples originate from a foreign source (internationally,
IlYas FlNo indudine Hawaii and Puerto Ricol? FlYes nNo
Comments/Discrepancy:
Chain of Custody Present?
s
[]No
❑N/A
1.
Samples Arrived within Hold Time?
©fe-s-
❑No
❑NIA
2.
Short Hold Time Analysis (472 hr.)?
hK1
[:IN.
❑NIA
3.
Rush Turn Around Time Requested?
Dyes
No
❑N/A
4.
Sufficient Volume?
Qfer,
❑No
❑N/A
5.
Correct Containers Used?
-Pace Containers Used?
Yes
es
❑No
❑No
❑N/A
❑N/A
6.
Contal ners Intact?
ElYes
❑No
❑N/A
7.
Dissolved analysis: Samples Field Filtered? ©Yes
[]No
N/A
a.
Sample Labels Match CDC?
-includes Date/Time/ID/Anafysis
4es
Matrix:
❑Na
❑N/A
9.
Heads pace inVQAVials (>5-6mm)?
(]Yes
ZNo
❑N/A
10.
Trip Blank Present?
Trip Blank Custody Seals Present?
❑Yes
❑yes
pv
❑Np
©N/A
N/A
L1.
COMMENTS/SAMPLE DISCREPANCY Field Data Required? ❑Yes ❑No
_ Lot ID of split containers: _
CLIENT NOTIFICATION/RESOLUTION
Person contacted:
Date/Time.
Project Manager SCURF Review:
Date:
Project Manager SRF Review: Date: Page 25 of 27

28ceAnalXical'
Document Name:
Condition Upon Receif
Document No.:
F-CAR-CS-033-Rev.08
*Check mark top half of box if pH and/or dechlorination is
verified and within the acceptance range for preservation
samples.
Exceptions: VOA, Coliform, TOC, oil and Grease, DRO/8015 (water) DOC, LLHg
"Bottom half of box is to list number of bottles
Document Revised: November 15, 2021
t (SCUR) Page 2 of 2
Issuing Authority:
Pace Carolinas Quality Office
Project # Wa# : 9260375
PM: LJP Due Dale: 05/17/22
CLIENT: 93-ALTAMONT
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pH Adjustment Log for Preserved Samples
Sample ID
Type of Preservative
pH upon receipt
Date preservation adjusted
Time preservation
adjusted
Amount of Preservative
added
Lot 19
Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DEHNR Certificatiun Office (i.e.
Out of hold, Incorrect preservative, out of temp, incorrect containers.
Page 26 of 27

a M r
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c a D
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r r z
M m
C
M
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W
TEMP in C
Received on
Ice
(YIN)
Custody
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Cooler
(YIN)
Samples
Intact
(YIN)
N 1 : to I- I- I- E- [- la 1w jN I- I ITEM #
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SAMPLE TYPE (G=GRAB C=COMP)
❑
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OOFCONTAINERS
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HNO3
MCI
NaOH
K
CD
Na25203
Methanol
Other
Analyses Test
YIN
TDS by 2540C
Fecal Coll
Ammonia, Total Ph°sphoru
Nitrate+Nitrite by 353,2
Chloride
TOC by 5310
Residual Chlorine (YIN)
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Page 27 of 27

Attachment 3
Well Sampling Logs and Instrument
Calibration Data Sheet

ANCHOR
QEA u
Anchor QEA of North Carolina, PLLC
231 Haywood Street
Asheville, North Carolina 28801
Low -Flow Sampling Log
well ID: MW-4
Project Name:
Project Number.
Project Location:
Sample Collector(s):_
Well Diameter.
Screen Interval:
Well Depth (as constructed):
Depth to Water:
Measuring Point:
Depth of Pump Intake:
Pump Used (circle):
Comments:
Lassonde Pappas Spring 2022 WQ Monitoring Date:
C21482-01.01 Task 7 Weather.
Hendersonville, NC Facility ID or Permit # (if applicable): Permit No. VVQ0004797
] Sample ID (on COQ: MW-4- __xA 2 [�
2 in Arrive at Well: . U1
5-15 ft bgs Start Time: i a
15 ft bgs Sample Time:
I ft Leave Well:
TOC Well Type: XStick U ❑Flush Mount
1 ft �� S-0 Tagged Bottom: I ft at (time):
Peristaltic Bladdert } Other (describe): Purge Rate:
1/j -Fi Q IAI Gib- Total Volume Purged:
(a ► l�j _ Pump Speed:
a�'1 L'f 4Vt1
.
Time
DDT1W (feet)
Temperature ('Q
Dissolved Oxygen
(mg/L)
Specific
Conductivity
(pmhos/cm)
pH (S.U.)
report to 0.1 S.U.
Oxidation
Reduction
Potential (mV)
Turbidity (NTU)
" 1 I'
D
I 30
r
s
t
aC1t
a1
t�D
r
- i�
a
a l I,.
Sample Analyst Signature:
`n Sample Analyst
( Fo r i Name:
Date:
DS
Notes:
1: Stabilization (3 successive readings, 3 minutes apart): within +/- 70% DO and turbidity, +/- 3% Conductivity, +/- 0.7 pH unit; +/- 10 mV for ORP
from EPA - Low -Flow (Minimal Drawdown) Groundwater Sampling Procedures, April 1996 (Rev 2017)
2. Documentation errors are to be crossed out with a single line, so the original text is still legible, followed by the staff members initials and date
3. Samples are analyzed immediately upon collection.
4. NC Field Laboratory Certificate Number 5445
5. 1 pnfho/cm = 1 pS/cm
Abbreviations:
Method Reference.
°C: degrees Celsius S.U.: standard units
Temperature: SM 2550 B-2010
pmhos/cm: micromhos per centimeter ft: feet
Specific conductivity: EPA Method 120.1, Rev. 1982
mg/L: milligrams per liter in: inches
DO: SM 4500 O G-2011
mV: millivolt bgs: below ground surface
pH: SM 4500-H' B-2011
NTU: nephelometric turbidity units TOC: top of casing
Turbidity: SM 2130 B-2011
Page 1 of 1

3
ANCHOR
4-C-4-1 ZQEA 4­
Anchor QEA of North Carolina, PLLC
231 Haywood Street
Asheville, North Carolina 28801
Low -Flow Sampling Log
IWO ID: MW-5
Project Name:
Project Number:
Project Location:
Sample Collector(s):
Well Diameter:
Screen Interval:
Well Depth (as constructed):
Depth to Water:
Measuring Point:
Depth of Pump Intake:
Pump Used (circle):
Comments:
Lassonde Pappas Spring 2022 WQ Monitoring Date:
C21482-01.01 Task 7 Weather:
Hendersonville, NC Facility ID or Permit # (if applicable):
rj Sample ID (on COQ:
2 rr in Arrive at Well:
9-19 ft bgs Start Time:
19 ft bgs Sample Time:
Vt r l ft Leave Well:
TOC Well Type:
j ft Tagged Bottom:
Peristaltic Bladder Other (describe):
22 oD - I V
Permit No. W00004797
MW-5- ©'A"W
ILIs
XStick Up ❑Flush Mount
1 i g ft at (time):
Purge Rate:
-3 Total Volume Purged:
Pump Speed:
(0
1 5priva' PV11 f
Time
DTW (feet)
Temperature ("C)
Dissolved Oxygen
(mg/L))/
Specific
Conductivity
(pmhos/cm)
pH (S.U.)
report to 0.1 S.U.
Oxidation
Reduction
Potential(m1)
Turbidity (NTU)
I a
+
I
^^
�i U
x.. 1
"I• of
ClI. g
L4 ,
a�/
a,
9: i
_3
1'
,J
ITT I
�a
°I I
5 ,L4
A
38
I I
Sample Analyst Signature:
Sample Analyst
[ Name:
Date: f�1s Jr
Notes:
1: Stabilization (3 successive readings, 3 minutes apart): within +/- 70% DO and turbidity, +/- 3% Conductivity,, +/- 0.1 pH unit +/- 70 mV for ORP
from EPA - Low -Flow (Minimal Drawdown) Groundwater Sampling Procedures, April 1996 (Rev 2017)
2. Documentation errors are to be crossed out with a single line, so the original text is still legible, followed by the staff members initials and date
3. Samples are analyzed immediately upon collection.
4. NC Field Laboratory Certificate Number 5445
5. 1 pmho/cm = 1 pS/cm
Abbreviations:
Method Reference:
°C: degrees Celsius S.U.: standard units
Temperature: SM 2550 B-2010
pmhos/cm: micromhos per centimeter ft: feet
Specific conductivity: EPA Method 120.1, Rev. 1982
mg/L: milligrams per liter in: inches
DO: SM 4500 O G-2011
mv: millivolt bgs: below ground surface
pH: SM 4500-H' B-2011
NTU: nephelometric turbidity units TOC: top of casing
Turbidity: SM 2130 B-2011
Page 1 of 1

('4("
of" p
Xq)
ANCHOR
QEA
Anchor QEA of North Carolina, PLLC
231 Haywood Street
Asheville, North Carolina 28801
Low -Flow Sampling Log
Well ID: MW-6
Project Name:
Lassonde Pappas Spring 2022 WQ Monitoring
Date:—�
I tv } -I A
Project Number:
C21482-01.01 Task 7
Weather:
I./ b P 1's s—
Project Location:
Hendersonville, NC
Facility ID or Permit # (if applicable):
PeI, rmit No. WQDDD4797Q
Sample Collector(s):
Sample ID (on COC):
MW-6-. tit cA- d..!r
Well Diameter:
2
in
Arrive at Well:
(.p-
Screen Interval:
5-10
ft bgs
Start Time:
I
I
Well Depth (as constructed):
10
ft bgs
Sample Time:
Depth to Water: S_ ICi
ft
Leave Well:
0
Measuring Point:
TOC
Well Type:
xstic Up -Flush Mount
Depth_of Pump Intake:
q
ft
Tagged Bottom:
ft at (time):
.l
lu
Pump Used (circle):
Peristaltic
Bladder
Other (describe):
f , Purge Rate:
Comments:
{� y l
I D [A '1
f
Total Volume Purged:
J so"- 9 11
tLOAPump
_
Speed:
Specific
Oxidation
Dissolved Oxygen
Conductivity
pH (S.U.)
Reduction
Time
DTw (feet)
Temperature ('C)
(mg/L)
(pmh�oys/crm)
report to0..1 S.U.
Potential (mV)
Turbidity (NTU)
(
S.
40
10
Ui
r
Ic 7
T
r
i V
I
U
}}�
V ,
lI Icl
7
54-
1
l to
,S
4 d
5,
to
5"}
I�()t.
Sr
L,,S4
',SJ,CcrL
l
f.1 Ll
I IS T_ o
M
J .51;
3t
6,
1
ti I
.2
s t
Sample Analyst Signature:
Sample Analyst
1 Name:
7 Date:
-
Notes:
1: Stabilization (3 successive readings, 3 minutes apart): within +/- 70% DO and turbidity, +/- 3%Conductivity,, +/- 0.1 pH unit +/- 10 mV for ORP
from EPA - Low -Flow (Minimal Drawdown) Groundwater Sampling Procedures, April 1996 (Rev 2017)
2. Documentation errors are to be crossed out with a single line, so the original text is still legible, followed by the staff members initials and date
3. Samples are analyzed immediately upon collection.
4. NC Field Laboratory Certificate Number 5445
5. 1 pmho/cm = 1 pS/cm
Abbreviations:
'C: degrees Celsius
S.U.: standard units
pmhos/cm: micromhos per centimeter
ft: feet
mg/L: milligrams per liter
in: inches
mv: millivolt
bgs: below ground surface
NTU: nephelometric turbidity units
TOC: top of casing
S low 0 �Lkmp t D H I�
!v d00 Y' I Iv,)
Method Reference:
Temperature: SM 2550 B-2010
Specific conductivity: EPA Method 120.1, Rev. 1982
DO: SM 4500 O G-2011
PH: SM 4500-H' B-2011
Turbidity: SM 2130 B-2011
Page 1 of 1

ANCHOR
QEA
Anchor QEA of North Carolina, PLLC
231 Haywood Street
Asheville, North Carolina 28801
Low -Flow Sampling Log
well ID: MW-7R
Project Name:
Lassonde Pappas Spring 2022 WQ Monitoring
Date:
11•
Project Number.
C21482-01.01 Task 7
Weather.
S ,L/,n f3t4_
Project Location:
Hendersonville, NC
Facility ID or Permit # (if applicable):
Permit No. WQ00�
Sample Collector(s):
"
Sample ID (on COC):
Well Diameter:
2
_
in
Arrive at Well:
5
Screen Interval:
5-15
ft bgs
Start Time:
-
Cl 0
Well Depth (as constructed):
15
ft bgs
Sample Time:
Depth to Water:
��
ft
Leave Well:
fi
Measuring Point:
Depth of Pump Intake:
TOC
ft
Well Type:
Tagged Bottom:
XStick Up ❑Flush Mount
ft at (time):
rik `+
Pump Used (circle):
Pc
eristalti
Bladder
Other (describe):
-�' Z i I p Purge Rate:
S 't VAL }14il'i
Comments:
pt W)
(_ I I a [)qf)
s + Q, (()(1�j
qQ
Total Volume Purged:
��s F
-
Hatr- - 1 I t p
Pump Speed:
39r
Specific
Oxidation
Dissolved Oxygen
Conductivity
pH (S.U.)
Reduction
Time
DTW (feet)
Temperature (°C)
(mg/L)
(pmhos/cm)
report to 0.1 S.U.
Potential (mV)
Turbidity (NTU)
I
t
Lrr
9
.�
.5
r
,
3q
, 0
Gi
111(
3 •
G10
qo
0011
3,
-C'J� -A
sin
a
Lf 5.
(i 9 Icl
11,1118-A
,a
SIC
3(or
•
a
llr
a
cCi a 5
110
a
�q_r.
31.E
1
r
�0
r�
at
-� [i .
1-1D
3
r
11
3, 3
1 1
Sample Analyst Signature:
f /^
/�
of) O n I /
Sample Analyst
Name:
J ,,� j
g0_11 a F+a� E Y 1 / `V l Date
Notes:
1: Stabilization (3 successive readings, 3 minutes apart): within +/- 70% DO and turbidity,' +/- 3% Conductivity,, +/- 0.7 pH unit,,./- 70 mV for ORP
from EPA - Low -Flow (Minimal Drawdown) Groundwater Sampling Procedures, April 1996 (Rev 2017)
2. Documentation errors are to be crossed out with a single line, so the original text is still legible, followed by the staff members initials and date
3. Samples are analyzed immediately upon collection.
4. NC.Field Laboratory Certificate Number 5445
5. 1 pmho/cm = 1 pS/cm
Abbreviations:
Method Reference:
°C: degrees Celsius S.U.: standard units
Temperature: SM 2550 B-2010
pmhos/cm: micromhos per centimeter ft: feet
Specific conductivity: EPA Method 120.1, Rev. 1982
mg/L. milligrams per liter in: inches
DO: SM 4500 O G-2011
mV: millivolt bgs: below ground surface
pH: SM 4500-H' B-2011
NTU: nephelometric turbidity units TOC: top of casing
Turbidity: SM 2130 B-2011
Page 1 of 1

1ZANCHOR
Q EA
Anchor QEA of North Carolina, PLLC
231 Haywood Street
Asheville, North Carolina 28801
Low -Flow Sampling Log
1well ID: MW-8
Project Name:
Project Number:
Project Location:
Sample Collector(s):
Well Diameter:
Screen Interval:
Well Depth (as constructed):
Depth to Water:
Measuring Point:
Depth of Pump Intake:
Pump Used (circle):
Comments:
Lassonde Pappas Spring 2022 WQ Monitoring Date:
C21482-01.01 Task 7 Weather. b S U N
Hendersonville, NC Facility ID or Permit # (if applicable): Permit No. WQ0004797
K Sample ID (on COC): MW-8-
2 in Arrive at Well: 4 } 3
3-13 ft bgs Start Time:
13 ft bgs Sample Time:
. D _ _ ft Leave Well: �, )
TOC Well Type: )4Stick Up ❑Flush Mount
a ft Tagged Bottom: ft at (time):
Peristaltic Bladder Other (describe): Purge Rate: ( i%AL
Total Volume Purged:
Pump Speed: .3
Time
DTW (feet)
Temperature (°C)
Dissolved Oxygen
(mg/Q
Specific
Conductivity
(pmhos/cm)
pH (S.U.)
report to 0.1 S.U.
Oxidation
Reduction
Potential (ni
Turbidity (NTU)
is
4kiLf,
(�
,
t b
i. •
L
i
4 0, a
nor
J,I
�, a
�- To
�, 4
n 0
�-
5
cl,
r
91
W'04
40
3
q.a
10,014
�.
a
• a
r
L4017_9
W,
Sample Analyst Signature:
•�
Sample Analyst
Name:'{"'��j
a��Q 1 Date:
Notes:
1: Stabilization (3 successive readings, 3 minutes apart): within,/- 70% DO and turbidity; +/- 3% Conductivity,' +/- 0.7 pmunit; +/- 70 mV for ORP
from EPA - Low -Flow (Minimal Drawdown) Groundwater Sampling Procedures, April 1996 (Rev 2017)
2. Documentation errors are to be crossed out with a single line, so the original text is still legible, followed by the. staff members initials and date
3. Samples are analyzed immediately upon collection.
4. NC Field Laboratory Certificate Number 5445
5. 1 pmho/cm = 1 pS/cm
Abbreviations:
°C: degrees Celsius
S.U.: standard units
pmhos/cm: micromhos per centimeter
ft: feet
mg/L: milligrams per liter
in: inches
mv: millivolt
bgs: below ground surface
NTU: nephelometric turbidity units
TOC: top of casing
Method Reference:
Temperature: SM 2550 B-2010
Specific conductivity: EPA Method 120.1, Rev.1982
DO: SM 4500 O G-2011
PH: SM 4500-H' B-2011
Turbidity: SM 2130 B-2011
Page 1 of 1

ANCHOR Anchor QEA of North Carolina, PLLC
QEA .`.r..-c�i 231 Haywood Street
1ZAsheville, North Carolina 28801
Low -Flow Sampling Log
1well ID: MW-9
Project Name: Lassonde Pappas Spring 2022 WQ Monitoring
Date:
(; 5 ho dt
Project Number: C21482-01.01 Task 7
Weather:
�d
Project Location: Hendersonville, NC Facility ID or Permit # (if applicable):
Permit No. WQ000479
Sample Collector(s): �- E2
Sample ID (on COC):
MW-9- _A_
)V
Well Diameter: 2 in
Arrive at Well:
!
Screen Interval: °3-tg ii7p ft bgs
Start Time:
Well Depth (as constructed): 4a3 �+ ft bgs
Sample Time:
a 3
Depth to Water: ft
Leave Well:
;
Measuring Point: TOC
Well Type:
XStick Up
❑Flush Mount
Depth of Pump Intake: 5 I () ft
Tagged Bottom:
11� ; I a ft
at (time):
0
Pump Used (circle): Peristaltic Bladder Other (describe):
Purge Rate:
9 V rat l
Comments: j _ YLrI i f `n ao:: '
t 1�
]� , n Total Volume Purged:
�r `
�",
,
Pump Speed:
4q,
Specific
Oxidation
Dissolved Oxygen
Conductivity
pH (S.U.)
Reduction
Time
DTW (feet)
Temperature ("C)
(mg/L)
(pmhos/cm)
report to 0.7 S.U.
Potential (mV)
Turbidity (NTU)
(
I
I
l—1
P
W, i
,
3,3
5,4
Q'
b"
c:E�
t
�,IL3.3
r
I
tL) 3 .3
SA100
0: �c
3
I0I1
ref
5
Sample Analyst
Sample Analyst Signature: Name:
h C
/
, Date:
Notes:
1: Stabilization (3 successive readings, 3 minutes apart): within +/- 70% DO and turbidity," +/- 3% conductivity,' +/-
0.7 pH unit, +/- 10 mV for ORP
from EPA - Low -Flow (Minimal Drawdown) Groundwater Sampling Procedures, April 1996 (Rev 2017)
2. Documentation errors are to be crossed out with a single line, so the original text is still legible, followed by the staff members initials and date
3. Samples are analyzed immediately upon collection.
4. NC Field Laboratory Certificate Number 5445
S. 1 pmho/cm.= 1 pS/cm
Abbreviations:
Method Reference:
°C: degrees Celsius S.U.: standard units
Temperature: SM 2550 B-2010
pmhos/cm: micromhos per centimeter ft: feet
Specific conductivity: EPA Method 120.1, Rev. 1982
mg/L: milligrams per liter in: inches
DO: SM 4500 O G-2011
mV: millivolt bgs: below ground surface
pH: SM 4500-H' B-2011
NTU: nephelometric turbidity units TOO top of casing
Turbidity: SM 2130 B-2011
Page 1 of 1

ANCHOR
Anchor QEA of North Carolina, PLLC
231 Haywood Street
Asheville, North Carolina 28801
Surface Water Sampling Log
Location ID: SW-1
Project Name:
Lassonde Pappas Spring 2022 WQ Monitoring
Date:
( a
Project Number:
C21482-01.01 Task 7
Weather:
Project Location:
Hendersonville, INC
Facility ID or Permit # (if applicable):
Permit No. WQ0004797
Sample Collector(s):
Sample ID (on COC):
SW-1- 0
Comments:
Sample Method (circle
one)
Grab Syringe
Pump
Bailer-Disp.
Other:
Specific
Oxidation
Temperature
Dissolved
Conductivity
pH (S.U.)
Reduction
Turbidity
Time
CC)
Oxygen (mg/L)
(pmhos/cm)
report to 0.1 S.U.
Potential (mV)
(NTU)
Comments
1l0,3
��5g
I ,�
, I
a�Q,3
31(o
Sampling Container
Number of Containers
Requested Analysis
500 mL Plastic
250 mL Plastic
125 mL Plastic
40 mL Glass
1 L Glass
Other
Vegetation: ii L)' . , J, Access: D.eaW ! / t,) w
Sample Analyst Q �j/�
Sample Analyst Signature: Name:---^ �1 LJ r Date: ` C)
Notes:
1. Documentation errors are to be crossed out with a sinole line, so the orioinal text is still leoible, followed by the staff members initials and date
2. Samples are analyzed immediately upon collection.
3. NC Field Laboratory Certificate Number 5445
Abbreviations:
Method Reference:
°C: degrees Celsius
Temperature: SM 2550 B-2010
pmhos/cm: micromhos per centimeter
Specific conductivity: EPA Method 120.1, Rev. 1982
mg/L: milligrams per liter
DO: SM 4500 O G-2011
mv: millivolt
pH: SM 4500-H' B-2011
NTU: nephelometric turbidity units
Turbiditv: SM 2130 B-2011
S.U.: standard units
Page 1 of 1

, ANCHOR
QEA w
Anchor QEA of North Carolina, PLLC
231 Haywood Street
Asheville, North Carolina 28801
Surface Water Sampling Log
Location ID: SW-2
3
Project Name: Lassonde Pappas Spring 2022 WQ Monitoring Date: �; 11t11;� 0)
Project Number: C21482-01.01 Task 7 Weather:
Project Location: Hendersonville, NC Facility ID or Permit # (if applicable): Permit No. WQ0004797
Sample Collector(s): Sample ID (on COC): SW-2-,)0,�J Z151 b
Comments:
Sample Method (circle
one):
Grab Syringe Pump
Bailer-Disp.
Other:
Time
Temperature
(°C)
Dissolved
Oxygen (mg/L)
Specific
Conductivity
(pmhos/cm)
pH (S.U.)
reportto 0.1 S.U.
Oxidation
Reduction
Potential (m1)
Turbidity
(NTU)
Comments
o�qo
15.E
Sampling Container
Number of Containers
Requested Analysis
500 mL Plastic
250 mL Plastic
cLc
V I I d L
125 mL Plastic
40 mL Glass
1 L Glass
Other
Vegetation: f 11 Oy V lS till j\ 0 Access: � ad
Sample Analyst
Sample Analyst Signature: '(Q �d
Notes: �"�— n 0J Name: IS"fi
E j. �/ a I Date: + q
1. Documentation errors are to be crossed out with a sinole line, so the orioinal text is still leoible, followed by the staff members initials and date
2. Samples are analyzed immediately upon collection.
3. NC Field Laboratory Certificate Number 5445
Abbreviations:
Method Reference:
°C: degrees Celsius
Temperature: SM 2550 B-2010
pmhos/cm: micromhos per centimeter
Specific conductivity: EPA Method 120.1, Rev. 1982
mg/L: milligrams per liter
DO: SM 4500 O G-2011
mV: millivolt
pH: SM 4500-H' B-2011
NTU: nephelometric turbidity units
Turbidity: SM 2130 B-2011
S.U.: standard units
Page 1 of 1

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ANCHOR
NC QEA
slo
Anchor QEA of North Carolina, PLLC
231 Haywood Street
Asheville, North Carolina 28801
Equipment Documentation and Instrument Calibration Data Sheet
Project Name: Lassonde Pappas Spring 2022 WQ Monitoring Analyst Conducting Calibration:
Project Number: C21482-01.01 Task 7 Date of Calibration: 4 Z 0 2-2—
Project Locatiom Hendersonville, INC Date of Field Measurements: S I c!12 027-
Facility ID or Permit # (if applicable): Permit No. WQ0004797
EQUIPMENT DOCUMENTATION
Rental sample analysis equipment or meters used to take measurements:
Equipment Type Brand Serial Number Date of Use Rental Company
Select Turbidimeter. Hch 21000 (s/n 151006045207)
Ha Scientific MicroTPW (s/n 200601045)
Instrument Readings
Instrument Readings
(Hach 2100Q)
(HF Scientific MicroTPMO `
Cal Still Information
10 NTU
20 NTU
100 NTU
800 NTU
1,000 NTU
10.0 NTU
0.02 NTU
Lot #:
-�
r
Expiration Date
r
Cal ( U .l
Cal (!til():b
Cal (
i
Cal (NTU):
Cal (NTU):
Cal (NTU):
- �
Time: t
o
Time:, (o b V
Time: I I V n '
l
Time:
Ti
Time:
Calibration
*Pre -Analysis
Result (NTU):
Time:S
*Pre-Ana
Result (NTU):
Time:
Verification:
Check (10 NTU):
'I S S 1
Ch 0 NTU):
*Post -Analysis
Result(NTU):
Time: i 1;AD
•Post -Analysis
Result(NTU):
Time:
Check (10 NTU):
q ✓0 1
1 { S
Check (10 NTU):
YSI Professional Plus Multiparameter Meter (s/n 186101802) '
Cal Std Information
Instrument Readings
Lot#
Date
Exp. Date
Opened
Dissolved Oxygen
Initial (%):
Cal (%):
100
mmHg: ' L
Temperature CC):
Time: // n�
(% saturation)
10
�� C, 3
t
t (a IDS
DO (Site #2,
Initial (%):
Cal (%):
mmHg:
Temperature CC):
Time:
if applicable)*
QC** Check: DO
Time: '
Result (%):
Time: q.
'1
Result (% '
C l
Time:
Result (%):
PH 7 S.U.
Initial:
pHmV:
Cal (S.U.):
pHmV: I
Time:
report to 0.7 S.U.-
pH 4 S.U.
ritual
pHmV: S F
Cal (S.lj.):
]�
pHmV:
Time:
'j�
(a j a i
r� 3
report to 0.7 S.U.
1
�7 c
,
Y
prt 10 S.U.
initial:
pHmV: �C 3
Cal ( V
(llll
pHmV: 4
Time:
3a
i—`a I
Ul 1
report to 0.7 S.U.
I `% s
- O
l
QC** pH 7 S.U.
Time:
b�
Result (S.U.):
Time:
i
Resultl U.):
�[
Time:
Result (S.U.):
re/�ortro0.75.U.
V
Spec. Cord.
Initial:�
Cal (mhos/cri
Time:
1,000 pmhos/cm
L�J/lrJlU
% Recovery=
QC** Spec Cond.
Time:'' i
Result (pmhos/cm):
Time:
Result (pmhos/cm):
Time:
Result (pmhos/cm):
1CS` fi
Elsa
nn I n
D
i b5
E
1,000pmhos/cm
W 1 Y
% Recovery=
ORP 200 mV
Initial:
Cal:
'l o C) O
Temperature
Time:
11.
(ya�
Q l
`-Y
Analyst Signature:
Analyst Name: - \ Date:
l b
Notes:
Revision 6, 12/20/20, MAK
1. Instruments shall be calibrated in accordance with the manufacturer's operation manual.
2. Specific Conductivity should be calibrated according to values representative of historic range.
3. Order of Calibration is as follows: Specific Conductivity, PH 7, PH 4, pH 10, DO, ORP, QC checks.
4. *When performing DO analyses at multiple sample sites (i.e. project/facility locations), the DO probe must be calibrated at each sample site prior to analysis.
5. QC Acceptable Ranges: PH +/- 0.1 S.U. and Specific Conductivity 10% of the true value. If QC readings are out of range, the instrument needs to be recalibrated.
6. ** QC check must be performed prior to sampling and following completion of sampling, at a minimum. QC checks must be performed with calibration standard from a separate lot # as the initial QC.
7. % Recovery = (Value Obtained, pmhos/cm a True Value, pmhos/cm) x 100
8. NC Field Laboratory Certificate Number 5445
9. Documentation errors are to be crossed out with a single line, so the original text is still legible, followed by the staff members initials and date
10. Unless otherwise noted, all DO calibrations and measurements are performed at 0 ppt Salinity.
11. 1 pmho/cm = 1 PS/cm
Abbreviations: Method Reference:
pmhos/cm: micromhcs per centimeter NTU: nephelometric turbidity units Temperature: SM 2550 B-201 D
°C: degrees Celsius ORP: oxidation reduction potential Specific conductivity. EPA Method 120.1, Rev. 1982
DO: dissolved oxygen s/n: serial number DO: SM 4500 0 G-2011
mg/L: milligrams per liter S.U.: standard units pH: SM 4500-H' B-2011
mV: millivolt Spec. Cond.: Specific Conductivity Turbidity SM 2130 8-2011
Page 1 of 1

Attachment 4
DEQ GW-59A — Compliance Report Form

SUBMIT FORM ON YELLOW PAPER ONLY
• •
DEPARTMENT OF ENVIRONMENTAL QUALITY - DIV. OF WATER RESOURCES
GROUNDWATER QUALITY MONITORING:
INFORMATION PROCESSING UNIT
COMPLIANCE REPORT FORM
1617 MAIL SERVICE CENTER, RALEIGH, NC 27699-1617
FACILITY INFORMATION
Please Print Clearly or Type
PERMIT Number: Expiration Date: 7/31/2026
Facility Name: Clement Pappas
Non -Discharge WQ0004797 UIC
Permit Name (if different):
NPDES Other
Facility Address: 485 Brookside Camp Road
TYPE OF PERMITTED OPERATION BEING MONITORED
Hendersonville NC
28792 County Henderson
❑ Lagoon ❑ Remediation: Infiltration Gallery
❑■ Spray Field ❑ Remediation:
Contact Person: Blake Kehoe
Telephone#: [phone]
❑ Rotary Distributor ❑ Land Application of Sludge
Well Location/Site Name: Irrigation Area
No. of wells to be sampled:
6
❑ Water Source Heat Pump ❑ Other:
(from Permit)
SAMPLING INFORMATION
If WELL
WELL ID NUMBER (from Permit): MW-4
Date sample collected: 5/10/2022
FIELD ANALYSES:
WAS
Well Depth: 18.17 ft.
Well Diameter: 2
in.
pH 00400: 5.8 units Temp. 000lo: 16.1 oC
DRY at
Depth to Water Level 82546: 9.14 ft. below measuring point Screened Interval: 5
ft. to 15
ft. Spec. Cond. 00094: 229.7 µMhos
time of
sampling,
Measuring Point is 2.43 ft. above land surface
Relative M.P. Elevation: 2063.77 ft.
Odor 00085: none
check
Volume of water pumped/bailed before sampling:
1.11
gallons
Appearance
here:❑
Samples for metals were collected unfiltered: ❑■ YES
❑ NO and field acidified: ❑■ YES
❑ NO
LABORATORY INFORMATION
Date sample analyzed: 5/11/2022
Laboratory Name: Pace Analytical Services
Certification No. 37712
PARAMETERS NOTE: Values should reflect
dissolved and colloidal concentrations.
COD 00335
mg/L
Nitrite (NOz) as N 00615
mg/L Pb - Lead 01051 ug/L
Coliform: MF Fecal 31616 <1.0
/100mL
Nitrate (1103) as N 00620 0.46
mg/L Zn - Zinc 01092 mg/L
Coliform: MF Total 31504
/100mL
Phosphorus: Total as P 00665 0.063
mg/L
(Note: Use MPN method for highly turbid samples)
Orthophosphate 70507
mg/L Other (Specify Compounds and Concentration Units):
issolved Solids:Total 70300 136
mg/L
Al -Aluminum 01105
mg/L
pH (Lab) 00403
units
Ba - Barium 01007
ug/L
TOC 00680 2.9
mg/L
Ca - Calcium oo916
mg/L
Chloride 0094o 6.8
mg/L
Cd - Cadmium 01027
ug/L
Arsenic 01002
ug/L
Chromium: Total 01034
ug/L
Grease and Oils 00552
mg/L
Cu - Copper 01042
mg/L ORGANICS: (by GC, GC/MS, HPLC)
Phenol 32730
ug/L
Fe - Iron 01045
ug/L (Specify test and method #. ATTACH LAB REPORT.)
Sulfate 00945
mg/L
Hg - Mercury 71900
ug/L Lab Report Attached? ❑■ Yes (1) ❑ No (0)
Specific Conductance 00095
µMhos
K - Potassium 00937
mg/L VOC 7873 method #
Total Ammonia oo6lo <0.10
mg/L
Mg - Magnesium 00927
mg/L
method #
(Ammonia Nitrogen; NH, as N; Ammonia Nitrogen, Total)
Mn - Manganese 01055
ug/L method #
TKN as N 00625
mg/L
Ni - Nickel 01067
ug/L method #
For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal%
Blake Kehoe, Director Engineering
Permittee (or Authorized Agent) Name and Title - Please print or type
Signature of Permittee (or Authorized Agent) (Date)
GW-59 Rev.06-07-2018

SUBMIT FORM ON YELLOW PAPER ONLY
• •
DEPARTMENT OF ENVIRONMENTAL QUALITY - DIV. OF WATER RESOURCES
GROUNDWATER QUALITY MONITORING:
INFORMATION PROCESSING UNIT
COMPLIANCE REPORT FORM
1617 MAIL SERVICE CENTER, RALEIGH, NC 27699-1617
FACILITY INFORMATION
Please Print Clearly or Type
PERMIT Number: Expiration Date: 7/31/2026
Facility Name: Clement Pappas
Non -Discharge WQ0004797 UIC
Permit Name (if different):
NPDES Other
Facility Address: 485 Brookside Camp Road
TYPE OF PERMITTED OPERATION BEING MONITORED
Hendersonville NC
28792 County Henderson
❑ Lagoon ❑ Remediation: Infiltration Gallery
❑■ Spray Field ❑ Remediation:
Contact Person: Blake Kehoe
Telephone#: [phone]
❑ Rotary Distributor ❑ Land Application of Sludge
Well Location/Site Name: Irrigation Area
No. of wells to be sampled:
6
❑ Water Source Heat Pump ❑ Other:
(from Permit)
SAMPLING INFORMATION
If WELL
WELL ID NUMBER (from Permit): MW-5
Date sample collected: 5/10/2022
FIELD ANALYSES:
WAS
Well Depth: 18.58 ft.
Well Diameter: 2
in.
pH 00400: 5.6 units Temp. 000lo: 14.5 °C
DRY at
Depth to Water Level 82546: 9.15 ft. below measuring point Screened Interval: 9
ft. to 19
ft. Spec. Cond. 00094: 228.2 µMhos
time of
sampling,
Measuring Point is 3.00 ft. above land surface
Relative M.P. Elevation: 2085.60 ft.
Odor 00085: none
check
Volume of water pumped/bailed before sampling:
0.59
gallons
Appearance
here:❑
Samples for metals were collected unfiltered: ❑■ YES
❑ NO and field acidified: ❑■ YES
❑ NO
LABORATORY INFORMATION
Date sample analyzed: 5/11/2022
Laboratory Name: Pace Analytical Services
Certification No. 37712
PARAMETERS NOTE: Values should reflect
dissolved and colloidal concentrations.
COD 00335
mg/L
Nitrite (NOz) as N 00615
mg/L Pb - Lead 01051 ug/L
Coliform: MF Fecal 31616 <1.0
/100mL
Nitrate (1103) as N 00620 0.10
mg/L Zn - Zinc 01092 mg/L
Coliform: MF Total 31504
/100mL
Phosphorus: Total as P 00665 <0.050
mg/L
(Note: Use MPN method for highly turbid samples)
Orthophosphate 70507
mg/L Other (Specify Compounds and Concentration Units):
issolved Solids:Total 70300 158
mg/L
Al -Aluminum 01105
mg/L
pH (Lab) 00403
units
Ba - Barium 01007
ug/L
TOC 00680 2.7
mg/L
Ca - Calcium oo916
mg/L
Chloride 00940 49.0
mg/L
Cd - Cadmium 01027
ug/L
Arsenic 01002
ug/L
Chromium: Total 01034
ug/L
Grease and Oils 00552
mg/L
Cu - Copper 01042
mg/L ORGANICS: (by GC, GC/MS, HPLC)
Phenol 32730
ug/L
Fe - Iron 01045
ug/L (Specify test and method #. ATTACH LAB REPORT.)
Sulfate 00945
mg/L
Hg - Mercury 71900
ug/L Lab Report Attached? ❑■ Yes (1) ❑ No (0)
Specific Conductance 00095
µMhos
K - Potassium 00937
mg/L VOC 7873 method #
Total Ammonia oo6lo <0.10
mg/L
Mg - Magnesium 00927
mg/L
method #
(Ammonia Nitrogen; NH, as N; Ammonia Nitrogen, Total)
Mn - Manganese 01055
ug/L method #
TKN as N 00625
mg/L
Ni - Nickel 01067
ug/L method #
For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal%
Blake Kehoe, Director Engineering
Permittee (or Authorized Agent) Name and Title - Please print or type
Signature of Permittee (or Authorized Agent) (Date)
GW-59 Rev.06-07-2018

SUBMIT FORM ON YELLOW PAPER ONLY
• •
DEPARTMENT OF ENVIRONMENTAL QUALITY - DIV. OF WATER RESOURCES
GROUNDWATER QUALITY MONITORING:
INFORMATION PROCESSING UNIT
COMPLIANCE REPORT FORM
1617 MAIL SERVICE CENTER, RALEIGH, NC 27699-1617
FACILITY INFORMATION
Please Print Clearly or Type
PERMIT Number: Expiration Date: 7/31/2026
Facility Name: Clement Pappas
Non -Discharge WQ0004797 UIC
Permit Name (if different):
NPDES Other
Facility Address: 485 Brookside Camp Road
TYPE OF PERMITTED OPERATION BEING MONITORED
Hendersonville NC
28792 County Henderson
❑ Lagoon ❑ Remediation: Infiltration Gallery
❑■ Spray Field ❑ Remediation:
Contact Person: Blake Kehoe
Telephone#: [phone]
❑ Rotary Distributor ❑ Land Application of Sludge
Well Location/Site Name: Irrigation Area
No. of wells to be sampled:
6
❑ Water Source Heat Pump ❑ Other:
(from Permit)
SAMPLING INFORMATION
If WELL
WELL ID NUMBER (from Permit): MW-6
Date sample collected: 5/10/2022
FIELD ANALYSES:
WAS
Well Depth: 11.58 ft.
Well Diameter: 2
in.
pH 00400: 5.4 units Temp. 000lo: 17.1 oC
DRY at
Depth to Water Level 82546: 5.91 ft. below measuring point Screened Interval: 5
ft. to 10
ft. Spec. Cond. 00094: 157.6 µMhos
time of
sampling,
Measuring Point is 3.00 ft. above land surface
Relative M.P. Elevation: 2061.17 ft.
Odor 00085: none
check
Volume of water pumped/bailed before sampling:
2.38
gallons
Appearance
here:❑
Samples for metals were collected unfiltered: ❑■ YES
❑ NO and field acidified: ❑■ YES
❑ NO
LABORATORY INFORMATION
Date sample analyzed: 5/11/2022
Laboratory Name: Pace Analytical Services
Certification No. 37712
PARAMETERS NOTE: Values should reflect
dissolved and colloidal concentrations.
COD 00335
mg/L
Nitrite (NOz) as N 00615
mg/L Pb - Lead 01051 ug/L
Coliform: MF Fecal 31616 < 1.0
/100mL
Nitrate (1103) as N 00620 <0.040
mg/L Zn - Zinc 01092 mg/L
Coliform: MF Total 31504
/100mL
Phosphorus: Total as P 00665 <0.050
mg/L
(Note: Use MPN method for highly turbid samples)
Orthophosphate 70507
mg/L Other (Specify Compounds and Concentration Units):
issolved Solids:Total 70300 96.0
mg/L
Al -Aluminum 01105
mg/L
pH (Lab) 00403
units
Ba - Barium 01007
ug/L
TOC oo680 1.5
mg/L
Ca - Calcium oo916
mg/L
Chloride 00940 13.6
mg/L
Cd - Cadmium 01027
ug/L
Arsenic 01002
ug/L
Chromium: Total 01034
ug/L
Grease and Oils 00552
mg/L
Cu - Copper 01042
mg/L ORGANICS: (by GC, GC/MS, HPLC)
Phenol 32730
ug/L
Fe - Iron 01045
ug/L (Specify test and method #. ATTACH LAB REPORT.)
Sulfate 00945
mg/L
Hg - Mercury 71900
ug/L Lab Report Attached? ❑■ Yes (1) ❑ No (0)
Specific Conductance 00095
µMhos
K - Potassium 00937
mg/L VOC 7873 method #
Total Ammonia oo6lo <0.10
mg/L
Mg - Magnesium 00927
mg/L
method #
(Ammonia Nitrogen; NH, as N; Ammonia Nitrogen, Total)
Mn - Manganese 01055
ug/L method #
TKN as N 00625
mg/L
Ni - Nickel 01067
ug/L method #
For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal%
Blake Kehoe, Director Engineering
Permittee (or Authorized Agent) Name and Title - Please print or type
Signature of Permittee (or Authorized Agent) (Date)
GW-59 Rev.06-07-2018

SUBMIT FORM ON YELLOW PAPER ONLY
• •
DEPARTMENT OF ENVIRONMENTAL QUALITY - DIV. OF WATER RESOURCES
GROUNDWATER QUALITY MONITORING:
INFORMATION PROCESSING UNIT
COMPLIANCE REPORT FORM
1617 MAIL SERVICE CENTER, RALEIGH, NC 27699-1617
FACILITY INFORMATION
Please Print Clearly or Type
PERMIT Number: Expiration Date: 7/31/2026
Facility Name: Clement Pappas
Non -Discharge WQ0004797 UIC
Permit Name (if different):
NPDES Other
Facility Address: 485 Brookside Camp Road
TYPE OF PERMITTED OPERATION BEING MONITORED
Hendersonville NC
28792 County Henderson
❑ Lagoon ❑ Remediation: Infiltration Gallery
❑■ Spray Field ❑ Remediation:
Contact Person: Blake Kehoe
Telephone#: [phone]
❑ Rotary Distributor ❑ Land Application of Sludge
Well Location/Site Name: Irrigation AreaO
No. of wells to be sampled:
6
❑ Water Source Heat Pump ❑ Other:
(from Permit)
SAMPLING INFORMATION
If WELL
WELL ID NUMBER (from Permit): MW-7R
Date sample collected: 5/10/2022
FIELD ANALYSES:
WAS
Well Depth: 17.29 ft.
Well Diameter: 2
in.
pH 00400: 5.1 units Temp. 000lo: 14.1 oC
DRY at
Depth to Water Level 82546: 11.66 ft. below measuring point Screened Interval: 5
ft. to 15
ft. Spec. Cond. 00094: 393.3 µMhos
time of
sampling,
Measuring Point is 3.00 ft. above land surface
Relative M.P. Elevation: 2062.86 ft.
Odor 00085: none
check
Volume of water pumped/bailed before sampling:
1.98
gallons
Appearance
here:❑
Samples for metals were collected unfiltered: ❑■ YES
❑ NO and field acidified: ❑■ YES
❑ NO
LABORATORY INFORMATION
Date sample analyzed: 5/11/2022
Laboratory Name: Pace Analytical Services
Certification No. 37712
PARAMETERS NOTE: Values should reflect
dissolved and colloidal concentrations.
COD 00335
mg/L
Nitrite (NOz) as N 00615
mg/L Pb - Lead 01051 ug/L
Coliform: MF Fecal 31616 <1.0
/100mL
Nitrate (NO3) as N 00620 31.0
mg/L Zn - Zinc 01092 mg/L
Coliform: MF Total 31504
/100mL
Phosphorus: Total as P 00665 <0.050
mg/L
(Note: Use MPN method for highly turbid samples)
Orthophosphate 70507
mg/L Other (Specify Compounds and Concentration Units):
issolved Solids:Total 70300 279
mg/L
Al -Aluminum 01105
mg/L
pH (Lab) 00403
units
Ba - Barium 01007
ug/L
TOC o0680 <1.0
mg/L
Ca - Calcium o0916
mg/L
Chloride 00940 30.8
mg/L
Cd - Cadmium 01027
ug/L
Arsenic 01002
ug/L
Chromium: Total 01034
ug/L
Grease and Oils 00552
mg/L
Cu - Copper 01042
mg/L ORGANICS: (by GC, GC/MS, HPLC)
Phenol 32730
ug/L
Fe - Iron 01045
ug/L (Specify test and method #. ATTACH LAB REPORT.)
Sulfate 00945
mg/L
Hg - Mercury 71900
ug/L Lab Report Attached? ❑■ Yes (1) ❑ No (0)
Specific Conductance 00095
µMhos
K - Potassium 00937
mg/L VOC 7873 method #
Total Ammonia o0610 <0.10
mg/L
Mg - Magnesium 00927
mg/L
method #
(Ammonia Nitrogen; NH, as N; Ammonia Nitrogen, Total)
Mn - Manganese 01055
ug/L method #
TKN as N 00625
mg/L
Ni - Nickel 01067
ug/L method #
For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal%
Blake Kehoe, Director Engineering
Permittee (or Authorized Agent) Name and Title - Please print or type
Signature of Permittee (or Authorized Agent) (Date)
GW-59 Rev.06-07-2018

SUBMIT FORM ON YELLOW PAPER ONLY
• •
DEPARTMENT OF ENVIRONMENTAL QUALITY - DIV. OF WATER RESOURCES
GROUNDWATER QUALITY MONITORING:
INFORMATION PROCESSING UNIT
COMPLIANCE REPORT FORM
1617 MAIL SERVICE CENTER, RALEIGH, NC 27699-1617
FACILITY INFORMATION
Please Print Clearly or Type
PERMIT Number: Expiration Date: 7/31/2026
Facility Name: Clement Pappas
Non -Discharge WQ0004797 UIC
Permit Name (if different):
NPDES Other
Facility Address: 485 Brookside Camp Road
TYPE OF PERMITTED OPERATION BEING MONITORED
Hendersonville NC
28792 County Henderson
❑ Lagoon ❑ Remediation: Infiltration Gallery
❑■ Spray Field ❑ Remediation:
Contact Person: Blake Kehoe
Telephone#: [phone]
❑ Rotary Distributor ❑ Land Application of Sludge
Well Location/Site Name: Irrigation Area
No. of wells to be sampled:
6
❑ Water Source Heat Pump ❑ Other:
(from Permit)
SAMPLING INFORMATION
If WELL
WELL ID NUMBER (from Permit): MW-8
Date sample collected: 5/10/2022
FIELD ANALYSES:
WAS
Well Depth: 13.91 ft.
Well Diameter: 2
in.
pH 00400: 6.7 units Temp. 000lo: 12.8 °C
DRY at
Depth to Water Level 82546: 10.02 ft. below measuring point Screened Interval: 3
ft. to 13
ft. Spec. Cond. 00094: 407.9 µMhos
time of
sampling,
Measuring Point is 3.00 ft. above land surface
Relative M.P. Elevation: 2060.80 ft.
Odor 00085: none
check
Volume of water pumped/bailed before sampling:
1.11
gallons
Appearance
here:❑
Samples for metals were collected unfiltered: ❑■ YES
❑ NO and field acidified: ❑■ YES
❑ NO
LABORATORY INFORMATION
Date sample analyzed: 5/11/2021
Laboratory Name: Pace Analytical Services
Certification No. 37712
PARAMETERS NOTE: Values should reflect
dissolved and colloidal concentrations.
COD 00335
mg/L
Nitrite (NOz) as N 00615
mg/L Pb - Lead 01051 ug/L
Coliform: MF Fecal 31616 <1.0
/100mL
Nitrate (1103) as N 00620 3.2
mg/L Zn - Zinc 01092 mg/L
Coliform: MF Total 31504
/100mL
Phosphorus: Total as P 00665 <0.050
mg/L
(Note: Use MPN method for highly turbid samples)
Orthophosphate 70507
mg/L Other (Specify Compounds and Concentration Units):
issolved Solids:Total 70300 240
mg/L
Al -Aluminum 01105
mg/L
pH (Lab) 00403
units
Ba - Barium 01007
ug/L
TOC 00680 4.5
mg/L
Ca - Calcium oo916
mg/L
Chloride 0094o 7.4
mg/L
Cd - Cadmium 01027
ug/L
Arsenic 01002
ug/L
Chromium: Total 01034
ug/L
Grease and Oils 00552
mg/L
Cu - Copper 01042
mg/L ORGANICS: (by GC, GC/MS, HPLC)
Phenol 32730
ug/L
Fe - Iron 01045
ug/L (Specify test and method #. ATTACH LAB REPORT.)
Sulfate 00945
mg/L
Hg - Mercury 71900
ug/L Lab Report Attached? ❑■ Yes (1) ❑ No (0)
Specific Conductance 00095
µMhos
K - Potassium 00937
mg/L VOC 7873 method #
Total Ammonia oo6lo <0.10
mg/L
Mg - Magnesium 00927
mg/L
method #
(Ammonia Nitrogen; NH, as N; Ammonia Nitrogen, Total)
Mn - Manganese 01055
ug/L method #
TKN as N 00625
mg/L
Ni - Nickel 01067
ug/L method #
For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal%
Blake Kehoe, Director Engineering
Permittee (or Authorized Agent) Name and Title - Please print or type
Signature of Permittee (or Authorized Agent) (Date)
GW-59 Rev.06-07-2018

SUBMIT FORM ON YELLOW PAPER ONLY
• •
DEPARTMENT OF ENVIRONMENTAL QUALITY - DIV. OF WATER RESOURCES
GROUNDWATER QUALITY MONITORING:
INFORMATION PROCESSING UNIT
COMPLIANCE REPORT FORM
1617 MAIL SERVICE CENTER, RALEIGH, NC 27699-1617
FACILITY INFORMATION
Please Print Clearly or Type
PERMIT Number: Expiration Date: 7/31/2026
Facility Name: Clement Pappas
Non -Discharge WQ0004797 UIC
Permit Name (if different):
NPDES Other
Facility Address: 485 Brookside Camp Road
TYPE OF PERMITTED OPERATION BEING MONITORED
Hendersonville NC
28792 County Henderson
❑ Lagoon ❑ Remediation: Infiltration Gallery
❑■ Spray Field ❑ Remediation:
Contact Person: Blake Kehoe
Telephone#: [phone]
❑ Rotary Distributor ❑ Land Application of Sludge
Well Location/Site Name: Irrigation Area
No. of wells to be sampled:
6
❑ Water Source Heat Pump ❑ Other:
(from Permit)
SAMPLING INFORMATION
If WELL
WELL ID NUMBER (from Permit): MW-9
Date sample collected: 5/10/2022
FIELD ANALYSES:
WAS
Well Depth: 18.12 ft.
Well Diameter: 2
in.
pH 00400: 5.4 units Temp. 000lo: 13.9 oC
DRY at
Depth to Water Level 82546: 5.70 ft. below measuring point Screened Interval: 6
ft. to 16
ft. Spec. Cond. 00094: 99.0 µMhos
time of
sampling,
Measuring Point is 1.44 ft. above land surface
Relative M.P. Elevation: 2060.23 ft.
Odor 00085: none
check
Volume of water pumped/bailed before sampling:
1.11
gallons
Appearance
here:❑
Samples for metals were collected unfiltered: ❑■ YES
❑ NO and field acidified: ❑■ YES
❑ NO
LABORATORY INFORMATION
Date sample analyzed: 10/27/2021
Laboratory Name: Pace Analytical Services
Certification No. 37712
PARAMETERS NOTE: Values should reflect
dissolved and colloidal concentrations.
COD 00335
mg/L
Nitrite (NOz) as N 00615
mg/L Pb - Lead 01051 ug/L
Coliform: MF Fecal 31616 <1.0
/100mL
Nitrate (1103) as N 00620 1.5
mg/L Zn - Zinc 01092 mg/L
Coliform: MF Total 31504
/100mL
Phosphorus: Total as P 00665 0.086
mg/L
(Note: Use MPN method for highly turbid samples)
Orthophosphate 70507
mg/L Other (Specify Compounds and Concentration Units):
issolved Solids:Total 703oo 67.0
mg/L
Al -Aluminum 01105
mg/L
pH (Lab) 00403
units
Ba - Barium 01007
ug/L
TOC oo68o 3.6
mg/L
Ca - Calcium oo916
mg/L
Chloride 0094o 6.3
mg/L
Cd - Cadmium 01027
ug/L
Arsenic 01002
ug/L
Chromium: Total 01034
ug/L
Grease and Oils 00552
mg/L
Cu - Copper 01042
mg/L ORGANICS: (by GC, GC/MS, HPLC)
Phenol 32730
ug/L
Fe - Iron 01045
ug/L (Specify test and method #. ATTACH LAB REPORT.)
Sulfate 00945
mg/L
Hg - Mercury 71900
ug/L Lab Report Attached? ❑■ Yes (1) ❑ No (0)
Specific Conductance 00095
µMhos
K - Potassium 00937
mg/L VOC 7873 method #
Total Ammonia oo6lo <0.10
mg/L
Mg - Magnesium 00927
mg/L
method #
(Ammonia Nitrogen; NH, as N; Ammonia Nitrogen, Total)
Mn - Manganese 01055
ug/L method #
TKN as N 00625
mg/L
Ni - Nickel 01067
ug/L method #
For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal%
Blake Kehoe, Director Engineering
Permittee (or Authorized Agent) Name and Title - Please print or type
Signature of Permittee (or Authorized Agent) (Date)
GW-59 Rev.06-07-2018

Attachment 5
DEQ GW-59 — Groundwater Quality
Monitoring: Compliance Report Forms

GW-59A COMPLIANCE REPORT FORM Permit #
(Submit one each monitoring period with GI1'-59 fornis.)
1
Enter date monitoring results were due. ( ) Will this monitoring report (GW-59 and GW-59A)
YES
NO
be submitted after the established due date?
2
Was any required information missing on the GW-59 report forms?
YES
NO
IF the answer to question 1 or 2 is "YES", list in the space provided below the well identification number(s) and
explain the problems encountered in obtaining the required information.
3
Are any of the monitor wells in need of repair or maintenance (damaged casing, unlocked or missing cap, missing
YES
NO
identification plate, area overgrown, etc.)? If the ansiver is " 3 es ", contact the Regional Office for guidance.
4
Are any monitored constituents equal to or above the established standards?
YES
NO
If the answer to question 4 is "NO", skip to section 8.
If the answer to question 4 is "YES" list the affected wells individually with constituent(s) and concentration(s)
exceeding standards in the space provided below:
5
For the constituents identified in question 4 above, have standards been exceeded previously for the
YES
NO
same constituent(s) in the same well(s) in the last two years?
If the answer to question 5 is "NO", skip to section 8.
If the answer to question 5 is "YES", list in the space provided below, each well with constituent(s) exceeding
standards, concentrations) reported, and sample collection date for each occurrence (for the last two years).
6
Are the monitoring wells listed in section 5 located at or beyond the review boundary?
YES
NO
If the answer is "YES", a groundwater quality problem may be occurring. CONTACT THE REGIONAL
OFFICE IMMEDIATELY FOR GUIDANCE. If the answer is "NO", monitoring wells may be improperly
located; contact the Regional Office.
7
Is the permittee implementing previously approved actions required by the Division involving this
YES
NO
groundwater quality problem?
If the answer to question 7 is "YES", describe those actions in the space provided below.
If the answer to question 7 is "NO", contact the Regional Office within 90 days; an evaluation may be
required to determine the impact the waste disposal system is having at the review and compliance
boundaries surrounding this facility. Failure to do so may subject the permittee to a Notice of Violation,
fines, and/or penalties.
8
The person completing this portion (GW-59A) of the monitoring report should sign below and submit this
form with G W-59 forms for required wells to the address provided at the top of the current G W-59 form.
I hereby acknowledge that the above information was evaluated and the information submitted in this
report (Compliance Report GW-59A) is true and complete to the best of my knowledge.
Signature of Permittee (or Authorized Agent) Date
GR'-59A 12/8/2003