WQ0003698_Groundwater Monitoring Report (GW59) May 2022_20220627

(p V
]
Enter date monitoring results were due. a 223 Will this monitoring report (GW-59 and GW-59A)
YES
NO
be submitted after the established due date?
2
Was any required information missing on the GW-59 report forms?
YES
NO
IF the answer to question 1 or 2 is "YES", list in the space provided below the well identification number(s) and
explain the problems encountered in obtaining the required information.
3
Are any of the monitor wells in need of repair or maintenance (damaged casing, unlocked or missing cap, missing
YES
NO
identification plate, area overgrown, etc.)? If the answer is "Yes ", contact the Regional Office for guidance.
4
Are any monitored constituents equal to or above the established standards?
YES
NO
If the answer to question 4 is "NO", skip to section 8.
If the answer to question 4 is "YES" list the affected wells individually with constituent(s) and concentration(s)
exceeding standards in the space provided below:
See- ATHV-k-61\
5
For the constituents identified in question 4 above, have standards been exceeded previously for the
YES
NO
same constituent(s) in the same well(s) in the last two years?
If the answer to question 5 is "NO", skip to section 8.
If the answer to question 5 is "YES", list in the space provided below, each well with constituent(s) exceeding
standards, concentration(s) reported, and sample collection date for each occurrence (for the last two years).
5�e e— A 6\e�-
Are the monitoring wells listed in section 5 located at or beyond the review boundary?
YES
NO
If the answer is "YES", a groundwater quality problem may be occurring. CONTACT THE REGIONAL
OFFICE IMMEDIATELY FOR GUIDANCE. If the answer is "NO", monitoring wells may be improperly
located; contact the Regional Office.
'1-j YDi1d� 02. ConfacQ
7
Is the permittee implementing previously approved actions required by the Division involving this
YES
NO
groundwater quality problem?
If the answer to question 7 is "YES", describe those actions in the space provided below.
If the answer to question 7 is "NO", contact the Regional Office within 90 days: an evaluation may be
required to determine the impact the waste disposal system is having at the review and compliance
boundaries surrounding this facility, Failure to do so may subject the permittee to a Notice of Violation,
fines, and/or penalties.
K.fi-j(DA.\j D &ei COA4 t
g
The person completing this portion (GW-59A) of the monitoring report should sign below and submit this
form with G W-59 forms for required wells to the address provided at the top of the current G W-59 form.
thereby acknowledge that the above information was evaluated and the information submitted in this
re ort (Compliance Report++GW-59A) is true and complete to. the best of my knowledge.
Signa of Permittee (o eAut nzed Agent) Date
i

Question #4
LAB DATA WHICH EXCEEDS PERMIT
DATE
MONITORING WELL #
PARAMETER
REPORTED
DATA
5/27 & 6/2022
1
pH
5.7
2
Ammonia
6.4 mg/L
Iron
43.9 mg/L
Manganese
1,200 ug/L
pH
6.3
3
Manganese
107 ug/L
pH
5.0
4
Manganese
172 ug/L
pH
5.0

QUESTION #5
LAB DATA WHICH EXCEEDS PERMIT FOR LAST 2 PREVIOUS YEARS
REPORTED
DATE MW # PARAMETER DATA
5/19-27/2020
1
Iron
0.34 mg/L
pH
5.2
2
Ammonia
6.7 mg/L
Iron
43 mg/L
Manganese
1360 ug/L
3
Nitrate
40.5
Iron
0.5 mg/L
Manganese
573 ug/L
pH
4.7
4
Manganese
149 ug/L
pH
4.5
11/16/2020
1
Iron
0.691 mg/L
Manganese
50.6 ug/L
pH
6
2
Ammonia
5.6 mg/L
Iron
21.6 mg/L
Manganese
1490 ug/L
pH
6.4
3
Nitrate
32.1 mg/L
Iron
1.07 mg/L
Manganese
434 ug/L
pH
5
4
Manganese
127 ug/L
pH
5.1
5/18 & 6/1/2021
1
Iron
0.948 mg/L
pH
5.9
2
Ammonia
7.3 mg/L
Iron
39.5mg/L
Manganese
1060 ug/L
3
Nitrate
21.2mg/L
Iron
0.937mg/L
Manganese
265 ug/L
pH
4.9
4
Manganese
207 ug/L
pH
5
11.30.21
1
pH
5.9
2
Ammonia
6.0 mg/L
Iron
28.4mg/L
Manganese
1080 ug/L

pH
6
3
Nitrate
12.1mg/L
Manganese
132 ug/L
pH
5
4
Manganese
119 ug/L
pH
5.1
5/27-6/9/2022
1
pH
5.7
2
Ammonia
6.4 mg/L
Iron
43.9 mg/L
Manganese
1,200 ug/L
pH
6.3
3
Manganese
107 ug/L
4
pH
5.0
Manganese
172 ug/L
pH
5.0

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leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
June 24, 2022
Mr. Tim Horton
City of Marion
3982 NC Hwy 226 South
Marion, NC 28752
RE: Project: CITY OF MARION MW's JUNE 2022
Pace Project No.: 92606905
Dear Mr. Horton:
Enclosed are the analytical results for sample(s) received by the laboratory between May 27, 2022 and June 09, 2022.
The results relate only to the samples included in this report. Results reported herein conform to the applicable
TNI/NELAC Standards and the laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the
report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace Analytical Services - Asheville
• Pace Analytical Services - Charlotte
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Lord Patton
[e-mail]
1(828)254-7176
Project Manager
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 1 of 28

leAnalyiical
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Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Project: CITY OF MARION MW's JUNE 2022
Pace Project No.: 92606905
Pace Analytical Services Charlotte
South Carolina Laboratory ID: 99006
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Laboratory ID: 99006
Pace Analytical Services Asheville
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
CERTIFICATIONS
South Carolina Certification #: 99006001
South Carolina Drinking Water Cert. #: 99006003
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Louisiana DoH Drinking Water #: LA029
VirginiaNELAP Certification #: 460221
South Carolina Laboratory ID: 99030
South Carolina Certification #: 99030001
VirginiaNELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 2 of 28

leAnalyiical
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Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
SAMPLE ANALYTE COUNT
Project:
Pace Project No.:
CITY OF MARION MW's JUNE 2022
92606905
Analytes
Lab ID
Sample ID
Method
Analysts
Reported
Laboratory
92606905001
MW-2
EPA 200.8 Rev 5.4
CRW, D1361
5
PASI-A
SM 254OC-2015
MAB2
1
PASI-A
SM 2540D-2015
ZMC
1
PASI-A
EPA 350.1 Rev 2.0 1993
NDS
1
PASI-A
EPA 353.2 Rev 2.0 1993
SMT
1
PASI-A
EPA420.4 Rev 1.0 1993
NDS
1
PASI-A
SM 531OB-2014
MDW
1
PASI-A
92606905002
MW-3
EPA 200.8 Rev 5.4
CRW
5
PASI-A
SM 2540C-2015
MAB2
1
PASI-A
SM 2540D-2015
ZMC
1
PASI-A
EPA 350.1 Rev 2.0 1993
NDS
1
PASI-A
EPA 353.2 Rev 2.0 1993
SMT
1
PASI-A
EPA420.4 Rev 1.0 1993
NDS
1
PASI-A
SM 531OB-2014
MDW
1
PASI-A
92606905003
MW-4
EPA 200.8 Rev 5.4
CRW
5
PASI-A
SM 2540C-2015
MAB2
1
PASI-A
SM 2540D-2015
ZMC
1
PASI-A
EPA 350.1 Rev 2.0 1993
NDS
1
PASI-A
EPA 353.2 Rev 2.0 1993
SMT
1
PASI-A
EPA420.4 Rev 1.0 1993
NDS
1
PASI-A
SM 531OB-2014
MDW
1
PASI-A
92608939001
MWA R
EPA 200.8 Rev 5.4
CRW
5
PASI-A
SM 2540C-2015
MAB2
1
PASI-A
SM 2540D-2015
MAB2
1
PASI-A
EPA 350.1 Rev 2.0 1993
NDS
1
PASI-A
EPA 353.2 Rev 2.0 1993
MFO
1
PASI-A
EPA420.4 Rev 1.0 1993
NDS
1
PASI-A
SM 531OB-2014
MJP
1
PASI-A
PASI-A = Pace Analytical Services - Asheville
PASI-C = Pace Analytical Services - Charlotte
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 3 of 28

leAnalyiical
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Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Project: CITY OF MARION MW's JUNE 2022
Pace Project No.: 92606905
Sample: MW-2 Lab ID: 92606905001 Collected: 05/27/22 12:05 Received: 05/27/22 15:30 Matrix: Water
Parameters Results Units PQL DF Prepared Analyzed CAS No. Qual
Monitoring Well Data
Performed by
Collected By
Collected Date
Collected Time
pH
Temperature
Static Water Level
Specific Conductance
Oxygen, Dissolved
Total Well Depth
Turbidity
Odor
Appearance
200.8 MET ICPMS
Arsenic
Cadmium
Iron
Lead
Manganese
2540C Total Dissolved Solids
Total Dissolved Solids
2540D Total Suspended Solids
Total Suspended Solids
350.1 Ammonia
Nitrogen, Ammonia
353.2 Nitrogen, NO2/NO3 unpres
Nitrogen, Nitrate
420.4 Phenolics, Total
Analytical Method:
Pace Analytical Services - Charlotte
Pace
1
06/20/22 13:07
R.Byas
1
06/20/22 13:07
5/27/22
1
06/20/22 13:07
12:05
1
06/20/22 13:07
6.3
Std. Units
1
06/20/22 13:07
20.0
deg C
1
06/20/22 13:07
17.03
feet
1
06/20/22 13:07
382.3
umhos/cm
1
06/20/22 13:07
0.8
mg/L
1
06/20/22 13:07 7782-44-7
38.02
feet
1
06/20/22 13:07
3.9
NTU
1
06/20/22 13:07
Sulfur
1
06/20/22 13:07
Clear
1
06/20/22 13:07
Analytical Method: EPA 200.8 Rev 5.4 Preparation Method: EPA 200.8 Rev 5.4
Pace Analytical Services -Asheville
0.57J ug/L
1.0
1
06/23/2212:25
06/23/2219:39
7440-38-2
ND ug/L
0.20
1
06/23/2212:25
06/23/2219:39
7440-43-9
43900 ug/L
500
10
06/23/2212:25
06/23/22 22:26
7439-89-6
ND ug/L
1.0
1
06/23/2212:25
06/23/2219:39
7439-92-1
1200 ug/L
20.0
10
06/23/22 12:25
06/23/22 22:26
7439-96-5
Analytical Method: SM 2540C-2015
Pace Analytical Services -Asheville
137 mg/L
25.0
1
05/31 /22 09:43
Analytical Method: SM 2540D-2015
Pace Analytical Services -Asheville
58.0 mg/L
10.0
1
06/02/2215:25
Analytical Method: EPA 350.1 Rev 2.0 1993
Pace Analytical Services -Asheville
6.4 mg/L
0.10
1
06/02/2215:13
7664-41-7
Analytical Method: EPA 353.2 Rev 2.0 1993
Pace Analytical Services -Asheville
ND mg/L
0.040
1
05/27/22 23:40
14797-55-8
Analytical Method: EPA 420.4 Rev 1.0 1993 Preparation Method: EPA 420.4 Rev 1.0 1993
Pace Analytical Services -Asheville
Phenolics, Total Recoverable ND mg/L 0.020 1 06/06/22 11:30 06/06/22 15:33 64743-03-9
531013 TOC Analytical Method: SM 531 OB-2014
Pace Analytical Services -Asheville
Total Organic Carbon 3.2 mg/L 1.0 1 06/02/22 03:40 7440-44-0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/24/2022 12:26 PM without the written consent of Pace Analytical Services, LLC.
17ifil
M1
Page 4 of 28

leAnalyiical
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Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Project: CITY OF MARION MW's JUNE 2022
Pace Project No.: 92606905
Sample: MW-3 Lab ID: 92606905002 Collected: 05/27/22 11:10 Received: 05/27/22 15:30 Matrix: Water
Parameters Results Units PQL DF Prepared Analyzed CAS No. Qual
Monitoring Well Data
Analytical Method:
Pace Analytical Services - Charlotte
Performed by
Pace
1
06/20/22 13:09
Collected By
R.Byas
1
06/20/22 13:09
Collected Date
5/27/22
1
06/20/22 13:09
Collected Time
11:10
1
06/20/22 13:09
pH
5.0 Std. Units
1
06/20/22 13:09
Temperature
21.8 deg C
1
06/20/22 13:09
Static Water Level
31.92 feet
1
06/20/22 13:09
Specific Conductance
151.9 umhos/cm
1
06/20/22 13:09
Oxygen, Dissolved
3.1 mg/L
1
06/20/22 13:09
7782-44-7
Total Well Depth
50.02 feet
1
06/20/22 13:09
Turbidity
9.7 NTU
1
06/20/22 13:09
Odor
Non
1
06/20/22 13:09
Detected
Appearance
Clear
1
06/20/22 13:09
200.8 MET ICPMS
Analytical Method: EPA 200.8 Rev 5.4 Preparation Method:
EPA 200.8 Rev 5.4
Pace Analytical Services -Asheville
Arsenic
0.12J ug/L 1.0
1
06/23/2212:25
06/23/2219:50
7440-38-2
Cadmium
0.84 ug/L 0.20
1
06/23/2212:25
06/23/2219:50
7440-43-9
Iron
242 ug/L 50.0
1
06/23/2212:25
06/23/2219:50
7439-89-6
Lead
0.381 ug/L 1.0
1
06/23/2212:25
06/23/2219:50
7439-92-1
Manganese
107 ug/L 2.0
1
06/23/2212:25
06/23/22 19:50
7439-96-5
2540C Total Dissolved Solids
Analytical Method: SM 2540C-2015
Pace Analytical Services -Asheville
Total Dissolved Solids
109 mg/L 25.0
1
05/31/22 09:43
2540D Total Suspended Solids
Analytical Method: SM 2540D-2015
Pace Analytical Services -Asheville
Total Suspended Solids
3.4 mg/L 2.6
1
06/02/22 15:25
350.1 Ammonia
Analytical Method: EPA 350.1 Rev 2.0 1993
Pace Analytical Services -Asheville
Nitrogen, Ammonia
ND mg/L 0.10
1
06/02/22 15:14
7664-41-7
353.2 Nitrogen, NO2/NO3 unpres
Analytical Method: EPA 353.2 Rev 2.0 1993
Pace Analytical Services -Asheville
Nitrogen, Nitrate
9.9 mg/L 0.20
5
05/27/22 23:58
14797-55-8
420.4 Phenolics, Total
Analytical Method: EPA 420.4 Rev 1.0 1993 Preparation Method: EPA 420.4 Rev 1.0 1993
Pace Analytical Services -Asheville
Phenolics, Total Recoverable
ND mg/L 0.020
1
06/06/22 11:30
06/06/22 15:34
64743-03-9
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/24/2022 12:26 PM without the written consent of Pace Analytical Services, LLC. Page 5 of 28

leAnalyiical
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Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Project: CITY OF MARION MW's JUNE 2022
Pace Project No.: 92606905
Sample: MW-3 Lab ID: 92606905002 Collected: 05/27/22 11:10 Received: 05/27/22 15:30 Matrix: Water
Parameters Results Units PQL DF Prepared Analyzed CAS No. Qual
5310B TOC Analytical Method: SM 531OB-2014
Pace Analytical Services -Asheville
Total Organic Carbon 0.78J mg/L 1.0 1 06/02/22 04:00 7440-44-0
Date: 06/24/2022 12:26 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 6 of 28

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Project: CITY OF MARION MW's JUNE 2022
Pace Project No.: 92606905
Sample: MW-4 Lab ID: 92606905003 Collected: 05/27/22 13:20 Received: 05/27/22 15:30 Matrix: Water
Parameters Results Units PQL DF Prepared Analyzed CAS No. Qual
Monitoring Well Data
Analytical Method:
Pace Analytical Services - Charlotte
Performed by
Pace
1
06/20/22 13:11
Collected By
R.Byas
1
06/20/22 13:11
Collected Date
5/27/22
1
06/20/22 13:11
Collected Time
13:20
1
06/20/22 13:11
pH
5.0 Std. Units
1
06/20/22 13:11
Temperature
23.8 deg C
1
06/20/22 13:11
Static Water Level
17.68 feet
1
06/20/22 13:11
Specific Conductance
52.5 umhos/cm
1
06/20/22 13:11
Oxygen, Dissolved
1.3 mg/L
1
06/20/22 13:11
7782-44-7
Total Well Depth
35.37 feet
1
06/20/22 13:11
Turbidity
3.0 NTU
1
06/20/22 13:11
Odor
Non
1
06/20/22 13:11
Detected
Appearance
Clear
1
06/20/22 13:11
200.8 MET ICPMS
Analytical Method: EPA 200.8 Rev 5.4 Preparation Method:
EPA 200.8 Rev 5.4
Pace Analytical Services -Asheville
Arsenic
ND ug/L 1.0
1
06/23/2212:25
06/23/2219:54
7440-38-2
Cadmium
0.0851 ug/L 0.20
1
06/23/2212:25
06/23/2219:54
7440-43-9
Iron
28.4J ug/L 50.0
1
06/23/2212:25
06/23/2219:54
7439-89-6
Lead
ND ug/L 1.0
1
06/23/2212:25
06/23/2219:54
7439-92-1
Manganese
172 ug/L 2.0
1
06/23/2212:25
06/23/2219:54
7439-96-5
2540C Total Dissolved Solids
Analytical Method: SM 2540C-2015
Pace Analytical Services -Asheville
Total Dissolved Solids
41.0 mg/L 25.0
1
05/31/22 09:43
2540D Total Suspended Solids
Analytical Method: SM 2540D-2015
Pace Analytical Services -Asheville
Total Suspended Solids
ND mg/L 2.7
1
06/02/22 15:26
350.1 Ammonia
Analytical Method: EPA 350.1 Rev 2.0 1993
Pace Analytical Services -Asheville
Nitrogen, Ammonia
ND mg/L 0.10
1
06/02/22 15:16
7664-41-7
353.2 Nitrogen, NO2/NO3 unpres
Analytical Method: EPA 353.2 Rev 2.0 1993
Pace Analytical Services -Asheville
Nitrogen, Nitrate
1.9 mg/L 0.040
1
05/27/22 23:46
14797-55-8
420.4 Phenolics, Total
Analytical Method: EPA 420.4 Rev 1.0 1993 Preparation Method: EPA 420.4 Rev 1.0 1993
Pace Analytical Services -Asheville
Phenolics, Total Recoverable
ND mg/L 0.020
1
06/06/22 11:30
06/06/22 15:38
64743-03-9
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/24/2022 12:26 PM without the written consent of Pace Analytical Services, LLC. Page 7 of 28

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Project: CITY OF MARION MW's JUNE 2022
Pace Project No.: 92606905
Sample: MW-4 Lab ID: 92606905003 Collected: 05/27/22 13:20 Received: 05/27/22 15:30 Matrix: Water
Parameters Results Units PQL DF Prepared Analyzed CAS No. Qual
5310B TOC Analytical Method: SM 531OB-2014
Pace Analytical Services -Asheville
Total Organic Carbon ND mg/L 1.0 1 06/02/22 04:20 7440-44-0
Date: 06/24/2022 12:26 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 8 of 28

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Project: CITY OF MARION MW's JUNE 2022
Pace Project No.: 92606905
Sample: MWAR Lab ID: 92608939001 Collected: 06/09/22 12:20 Received: 06/09/22 14:00 Matrix: Water
Parameters Results Units PQL DF Prepared Analyzed CAS No. Qual
Monitoring Well Data
Performed by
Collected By
Collected Date
Collected Time
pH
Temperature
Static Water Level
Specific Conductance
Oxygen, Dissolved
Total Well Depth
Turbidity
Odor
Appearance
200.8 MET ICPMS
Arsenic
Cadmium
Iron
Lead
Manganese
2540C Total Dissolved Solids
Total Dissolved Solids
2540D Total Suspended Solids
Total Suspended Solids
350.1 Ammonia
Nitrogen, Ammonia
353.2 Nitrogen, NO2/NO3 unpres
Nitrogen, Nitrate
420.4 Phenolics, Total
Phenolics, Total Recoverable
Date: 06/24/2022 12:26 PM
Analytical Method:
Pace Analytical Services - Charlotte
Pace
1
06/20/22 13:29
R.Byas
1
06/20/22 13:29
6/9/22
1
06/20/22 13:29
12:20
1
06/20/22 13:29
5.7 Std. Units
1
06/20/22 13:29
24.5 deg C
1
06/20/22 13:29
23.30 feet
1
06/20/22 13:29
24.6 umhos/cm
1
06/20/22 13:29
5.0 mg/L
1
06/20/22 13:29
7782-44-7
60.65 feet
1
06/20/22 13:29
28.0 NTU
1
06/20/22 13:29
Non Detect
1
06/20/22 13:29
Slightly
1
06/20/22 13:29
Cloudy
Analytical Method: EPA 200.8 Rev 5.4 Preparation Method:
EPA 200.8 Rev 5.4
Pace Analytical Services -Asheville
ND ug/L 1.0
1
06/23/22 12:25
06/23/22 20:06
7440-38-2
ND ug/L 0.20
1
06/23/22 12:25
06/23/22 20:06
7440-43-9
225 ug/L 50.0
1
06/23/22 12:25
06/23/22 20:06
7439-89-6
0.25J ug/L 1.0
1
06/23/22 12:25
06/23/22 20:06
7439-92-1
9.9 ug/L 2.0
1
06/23/22 12:25
06/23/22 20:06
7439-96-5
Analytical Method: SM 2540C-2015
Pace Analytical Services -Asheville
ND mg/L 25.0
1
06/14/2211:13
Analytical Method: SM 2540D-2015
Pace Analytical Services -Asheville
6.3 mg/L 2.5
1
06/14/2211:05
Analytical Method: EPA 350.1 Rev 2.0 1993
Pace Analytical Services -Asheville
0.039.11 mg/L 0.10
1
06/17/2212:43
7664-41-7
Analytical Method: EPA 353.2 Rev 2.0 1993
Pace Analytical Services -Asheville
0.12 mg/L 0.040
1
06/10/22 00:29
14797-55-8
Analytical Method: EPA 420.4 Rev 1.0 1993 Preparation Method: EPA 420.4 Rev 1.0 1993
Pace Analytical Services -Asheville
ND mg/L 0.020
1
06/15/2213:07
06/16/2211:59
64743-03-9
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 9 of 28

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Project: CITY OF MARION MW's JUNE 2022
Pace Project No.: 92606905
Sample: MWAR Lab ID: 92608939001 Collected: 06/09/22 12:20 Received: 06/09/22 14:00 Matrix: Water
Parameters Results Units PQL DF Prepared Analyzed CAS No. Qual
5310B TOC Analytical Method: SM 531OB-2014
Pace Analytical Services -Asheville
Total Organic Carbon ND mg/L 1.0 1 06/15/22 07:22 7440-44-0
Date: 06/24/2022 12:26 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 10 of 28

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: CITY OF MARION MW's JUNE 2022
Pace Project No.: 92606905
QC Batch: 706496 Analysis Method: EPA 200.8 Rev 5.4
QC Batch Method: EPA 200.8 Rev 5.4 Analysis Description: 200.8 MET
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92606905001, 92606905002, 92606905003, 92608939001
METHOD BLANK: 3685655
Matrix:
Water
Associated Lab Samples:
92606905001, 92606905002, 92606905003, 92608939001
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed Qualifiers
Arsenic
ug/L
ND
1.0
06/23/2219:31
Cadmium
ug/L
ND
0.20
06/23/2219:31
Iron
ug/L
ND
50.0
06/23/2219:31
Lead
ug/L
ND
1.0
06/23/2219:31
Manganese
ug/L
ND
2.0
06/23/2219:31
LABORATORY CONTROL SAMPLE:
3685656
Spike
LCS
LCS
% Rec
Parameter
Units
Conc.
Result
% Rec
Limits Qualifiers
Arsenic
ug/L
50
50.5
101
85-115
Cadmium
ug/L
50
50.9
102
85-115
Iron
ug/L
1250
1330
107
85-115
Lead
ug/L
50
50.7
101
85-115
Manganese
ug/L
50
52.1
104
85-115
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
3685657
3685658
MS
MSD
92606905001
Spike
Spike
MS
MSD
MS
MSD
% Rec
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD Qual
Arsenic
ug/L
0.57J
50
50
52.9
52.6
105
104
70-130
1
Cadmium
ug/L
ND
50
50
51.6
50.9
103
102
70-130
1
Iron
ug/L
43900
1250
1250
42700
41400
-95
-195
70-130
3 M1
Lead
ug/L
ND
50
50
53.4
52.8
107
106
70-130
1
Manganese
ug/L
1200
50
50
1200
1150
12
-98
70-130
5 M1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/24/2022 12:26 PM without the written consent of Pace Analytical Services, LLC.
Page 11 of 28

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: CITY OF MARION MW's JUNE 2022
Pace Project No.: 92606905
QC Batch: 701186 Analysis Method: SM 2540C-2015
QC Batch Method: SM 2540C-2015 Analysis Description: 2540C Total Dissolved Solids
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92606905001, 92606905002, 92606905003
METHOD BLANK: 3659973
Matrix:
Water
Associated Lab Samples: 92606905001, 92606905002, 92606905003
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed Qualifiers
Total Dissolved Solids
mg/L
ND
25.0
05/31/22 09:41
LABORATORY CONTROL SAMPLE:
3659974
Spike
LCS
LCS % Rec
Parameter
Units
Conc.
Result
% Rec Limits Qualifiers
Total Dissolved Solids
mg/L
250
246
98 90-110
SAMPLE DUPLICATE: 3659975
92606729001 Dup
Parameter Units Result Result RPD Qualifiers
Total Dissolved Solids mg/L 120 117 3
SAMPLE DUPLICATE: 3659976
92606729005 Dup
Parameter Units Result Result RPD Qualifiers
Total Dissolved Solids mg/L 263 263 0
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/24/2022 12:26 PM without the written consent of Pace Analytical Services, LLC. Page 12 of 28

Pace Analytical Services, LLC
leac,yficalAnal2225 Riverside Dr.
Asheville, NC 28804
www.pacelabs.com [phone]
QUALITY CONTROL DATA
Project: CITY OF MARION MW's JUNE 2022
Pace Project No.: 92606905
QC Batch: 704188 Analysis Method: SM 2540C-2015
QC Batch Method: SM 2540C-2015 Analysis Description: 2540C Total Dissolved Solids
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92608939001
METHOD BLANK: 3674797
Associated Lab Samples: 92608939001
Parameter
Units
Total Dissolved Solids
mg/L
LABORATORY CONTROL SAMPLE:
3674798
Parameter
Units
Total Dissolved Solids
mg/L
SAMPLE DUPLICATE: 3674799
Parameter
Units
Total Dissolved Solids
mg/L
Matrix: Water
Blank Reporting
Result Limit Analyzed Qualifiers
ND 25.0 06/14/2211:11
Spike LCS LCS % Rec
Conc. Result % Rec Limits Qualifiers
250 232 93 90-110
92609093015 Dup
Result Result RPD Qualifiers
69.0 69.0 0
SAMPLE DUPLICATE: 3674800
92608992001 Dup
Parameter Units Result Result
Total Dissolved Solids mg/L 977 998
RPD Qualifiers
2
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/24/2022 12:26 PM without the written consent of Pace Analytical Services, LLC. Page 13 of 28

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: CITY OF MARION MW's JUNE 2022
Pace Project No.: 92606905
QC Batch: 701943 Analysis Method: SM 2540D-2015
QC Batch Method: SM 2540D-2015 Analysis Description: 2540D Total Suspended Solids
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92606905001, 92606905002, 92606905003
METHOD BLANK: 3663528
Matrix:
Water
Associated Lab Samples: 92606905001, 92606905002, 92606905003
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed
Total Suspended Solids
mg/L
ND
2.5
06/02/22 15:2
LABORATORY CONTROL SAMPLE:
3663529
Spike
LCS
LCS
Parameter
Units
Conc.
Result
% Rec
Total Suspended Solids
mg/L
250
238
95
SAMPLE DUPLICATE: 3663530
92606831004
Dup
Qualifiers
% Rec
Limits Qualifiers
90-110
Parameter Units Result Result RPD Qualifiers
Total Suspended Solids mg/L 3.6 2.8 25
SAMPLE DUPLICATE: 3663584
92606905001 Dup
Parameter Units Result Result RPD Qualifiers
Total Suspended Solids mg/L 58.0 62.4 7
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/24/2022 12:26 PM without the written consent of Pace Analytical Services, LLC. Page 14 of 28

Pace Analytical Services, LLC
leac,yficalAnal2225 Riverside Dr.
Asheville, NC 28804
www.pacelabs.com [phone]
QUALITY CONTROL DATA
Project: CITY OF MARION MW's JUNE 2022
Pace Project No.: 92606905
QC Batch: 704186 Analysis Method: SM 2540D-2015
QC Batch Method: SM 2540D-2015 Analysis Description: 2540D Total Suspended Solids
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92608939001
METHOD BLANK: 3674793
Associated Lab Samples: 92608939001
Parameter
Units
Total Suspended Solids
mg/L
LABORATORY CONTROL SAMPLE:
3674794
Parameter
Units
Total Suspended Solids
mg/L
SAMPLE DUPLICATE: 3674795
Parameter
Units
Total Suspended Solids
mg/L
Matrix: Water
Blank Reporting
Result Limit Analyzed Qualifiers
ND 2.5 06/14/2210:58
Spike LCS LCS % Rec
Conc. Result % Rec Limits Qualifiers
250 238 95 90-110
92609273001 Dup
Result Result RPD Qualifiers
135 124 8
SAMPLE DUPLICATE: 3674796
92608931001 Dup
Parameter Units Result Result
Total Suspended Solids mg/L 32.0 29.0
RPD Qualifiers
10
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/24/2022 12:26 PM without the written consent of Pace Analytical Services, LLC. Page 15 of 28

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: CITY OF MARION MW's JUNE 2022
Pace Project No.: 92606905
QC Batch: 701834 Analysis Method: EPA 350.1 Rev 2.0 1993
QC Batch Method: EPA 350.1 Rev 2.0 1993 Analysis Description: 350.1 Ammonia
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92606905001, 92606905002, 92606905003
METHOD BLANK: 3663015
Matrix:
Water
Associated Lab Samples: 92606905001, 92606905002, 92606905003
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed Qualifiers
Nitrogen, Ammonia
mg/L
ND
0.10
06/02/22 11:45
LABORATORY CONTROL SAMPLE:
3663016
Spike
LCS
LCS % Rec
Parameter
Units
Conc.
Result
% Rec Limits Qualifiers
Nitrogen, Ammonia
mg/L
5
5.0
100 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3663017 3663018
MS MSD
92607347001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Nitrogen, Ammonia mg/L 1.5 5 5 6.5 6.5 99 99 90-110 0
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3663019 3663020
MS MSD
92607392001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Nitrogen, Ammonia mg/L 1.2 5 5 6.4 6.4 104 104 90-110 0
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/24/2022 12:26 PM without the written consent of Pace Analytical Services, LLC.
Page 16 of 28

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: CITY OF MARION MW's JUNE 2022
Pace Project No.: 92606905
QC Batch: 705176 Analysis Method: EPA 350.1 Rev 2.0 1993
QC Batch Method: EPA 350.1 Rev 2.0 1993 Analysis Description: 350.1 Ammonia
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92608939001
METHOD BLANK: 3679665
Associated Lab Samples: 92608939001
Parameter Units
Nitrogen, Ammonia mg/L
LABORATORY CONTROL SAMPLE: 3679666
Parameter Units
Nitrogen, Ammonia mg/L
Matrix: Water
Blank Reporting
Result Limit Analyzed Qualifiers
ND 0.10 06/17/2211:36
Spike LCS LCS % Rec
Conc. Result % Rec Limits Qualifiers
5 4.9 99 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3679667 3679668
MS MSD
92608833001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Nitrogen, Ammonia mg/L 14.4 5 5 18.8 19.1 87 93 90-110 2 M1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3679669 3679670
MS MSD
92609530002 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Nitrogen, Ammonia mg/L 0.067J 5 5 4.0 4.0 79 78 90-110 1 M1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/24/2022 12:26 PM without the written consent of Pace Analytical Services, LLC.
Page 17 of 28

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: CITY OF MARION MW's JUNE 2022
Pace Project No.: 92606905
QC Batch: 701085 Analysis Method: EPA 353.2 Rev 2.0 1993
QC Batch Method: EPA 353.2 Rev 2.0 1993 Analysis Description: 353.2 Nitrate + Nitrite, Unpres.
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92606905001, 92606905002, 92606905003
METHOD BLANK: 3659745
Matrix:
Water
Associated Lab Samples: 92606905001, 92606905002, 92606905003
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed Qualifiers
Nitrogen, Nitrate
mg/L
ND
0.040
05/27/22 23:24
LABORATORY CONTROL SAMPLE:
3659746
Spike
LCS
LCS % Rec
Parameter
Units
Conc.
Result
% Rec Limits Qualifiers
Nitrogen, Nitrate
mg/L
1.5
1.5
97 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3659749 3659750
MS MSD
92606870001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Nitrogen, Nitrate mg/L 0.26 1.5 1.5 1.6 1.6 89 89 90-110 0
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3659763 3659764
MS MSD
92606905001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Nitrogen, Nitrate mg/L ND 1.5 1.5 1.3 1.3 86 84 90-110 2
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/24/2022 12:26 PM without the written consent of Pace Analytical Services, LLC.
Page 18 of 28

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: CITY OF MARION MW's JUNE 2022
Pace Project No.: 92606905
QC Batch: 703515 Analysis Method: EPA 353.2 Rev 2.0 1993
QC Batch Method: EPA 353.2 Rev 2.0 1993 Analysis Description: 353.2 Nitrate + Nitrite, Unpres.
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92608939001
METHOD BLANK: 3671476
Associated Lab Samples: 92608939001
Parameter Units
Nitrogen, Nitrate mg/L
LABORATORY CONTROL SAMPLE: 3671477
Parameter Units
Nitrogen, Nitrate mg/L
Matrix: Water
Blank Reporting
Result Limit Analyzed Qualifiers
ND 0.040 06/10/22 00:09
Spike LCS LCS % Rec
Conc. Result % Rec Limits Qualifiers
1.5 1.5 100 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3671478 3671479
MS MSD
92608972004 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Nitrogen, Nitrate mg/L 0.35 1.5 1.5 1.9 1.9 103 103 90-110 0
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3671508 3671509
MS MSD
92608939001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Nitrogen, Nitrate mg/L 0.12 1.5 1.5 1.7 1.6 103 102 90-110 1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/24/2022 12:26 PM without the written consent of Pace Analytical Services, LLC.
Page 19 of 28

leAnalyiical
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Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: CITY OF MARION MW's JUNE 2022
Pace Project No.: 92606905
QC Batch: 702419 Analysis Method: EPA 420.4 Rev 1.0 1993
QC Batch Method: EPA 420.4 Rev 1.0 1993 Analysis Description: 420.4 Phenolics
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92606905001, 92606905002, 92606905003
METHOD BLANK: 3665743
Matrix:
Water
Associated Lab Samples: 92606905001, 92606905002, 92606905003
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed Qualifiers
Phenolics, Total Recoverable
mg/L
ND
0.020
06/06/22 14:55
LABORATORY CONTROL SAMPLE:
3665744
Spike
LCS
LCS % Rec
Parameter
Units
Conc.
Result
% Rec Limits Qualifiers
Phenolics, Total Recoverable
mg/L
0.05
0.052
103 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3665745 3665746
MS MSD
92606737001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Phenolics, Total Recoverable mg/L ND 0.05 0.05 0.041 0.047 82 94 90-110 14 M1,R1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3665747 3665748
MS MSD
92606784003 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Phenolics, Total Recoverable mg/L 0.0191 0.05 0.05 0.16 0.12 287 207 90-110 28 M1,R1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/24/2022 12:26 PM without the written consent of Pace Analytical Services, LLC.
Page 20 of 28

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: CITY OF MARION MW's JUNE 2022
Pace Project No.: 92606905
QC Batch: 704389 Analysis Method: EPA 420.4 Rev 1.0 1993
QC Batch Method: EPA 420.4 Rev 1.0 1993 Analysis Description: 420.4 Phenolics
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92608939001
METHOD BLANK: 3675646
Associated Lab Samples: 92608939001
Parameter Units
Phenolics, Total Recoverable mg/L
LABORATORY CONTROL SAMPLE: 3675647
Parameter Units
Phenolics, Total Recoverable mg/L
Matrix: Water
Blank Reporting
Result Limit Analyzed Qualifiers
ND 0.020 06/16/2210:12
Spike LCS LCS % Rec
Conc. Result % Rec Limits Qualifiers
0.05 0.054 108 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3675648 3675649
MS MSD
35722958002 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Phenolics, Total Recoverable mg/L 0.0076 0.05 0.05 0.056 0.063 112 126 90-110 12 M1,R1
U
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3675650 3675651
MS MSD
35722958003 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Phenolics, Total Recoverable mg/L 0.0076 0.05 0.05 0.060 0.061 109 110 90-110 1
U
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/24/2022 12:26 PM without the written consent of Pace Analytical Services, LLC.
Page 21 of 28

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: CITY OF MARION MW's JUNE 2022
Pace Project No.: 92606905
QC Batch: 701750 Analysis Method: SM 531 OB-2014
QC Batch Method: SM 531 OB-2014 Analysis Description: 5310E TOC
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92606905001, 92606905002, 92606905003
METHOD BLANK: 3662836
Matrix:
Water
Associated Lab Samples: 92606905001, 92606905002, 92606905003
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed Qualifiers
Total Organic Carbon
mg/L
ND
1.0
06/02/22 00:09
LABORATORY CONTROL SAMPLE:
3662837
Spike
LCS
LCS % Rec
Parameter
Units
Conc.
Result
% Rec Limits Qualifiers
Total Organic Carbon
mg/L
25
23.6
94 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3662838 3662839
MS MSD
92606807001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Total Organic Carbon mg/L 5.8 25 25 30.5 30.6 99 99 90-110 1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/24/2022 12:26 PM without the written consent of Pace Analytical Services, LLC.
Page 22 of 28

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: CITY OF MARION MW's JUNE 2022
Pace Project No.: 92606905
QC Batch: 704295 Analysis Method: SM 531 OB-2014
QC Batch Method: SM 531 OB-2014 Analysis Description: 5310E TOC
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92608939001
METHOD BLANK: 3675088
Associated Lab Samples: 92608939001
Parameter Units
Total Organic Carbon mg/L
LABORATORY CONTROL SAMPLE: 3675089
Parameter Units
Total Organic Carbon mg/L
Matrix: Water
Blank Reporting
Result Limit Analyzed Qualifiers
ND 1.0 06/15/22 03:09
Spike LCS LCS % Rec
Conc. Result % Rec Limits Qualifiers
25 24.6 98 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3675090 3675091
MS MSD
92609417014 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Total Organic Carbon mg/L 1.5 25 25 26.0 26.3 98 99 90-110 1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3675092 3675093
MS MSD
92609240002 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Total Organic Carbon mg/L 38.2 25 25 69.3 68.6 124 122 90-110 1 M1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/24/2022 12:26 PM without the written consent of Pace Analytical Services, LLC.
Page 23 of 28

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALIFIERS
Project: CITY OF MARION MW's JUNE 2022
Pace Project No.: 92606905
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as
"Total" may vary slightly from the sum of the reported component parameters.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TN -The NELAC Institute.
ANALYTE QUALIFIERS
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
R1 RPD value was outside control limits.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/24/2022 12:26 PM without the written consent of Pace Analytical Services, LLC. Page 24 of 28

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project:
Pace Project No.:
CITY OF MARION MW's JUNE 2022
92606905
Analytical
Lab ID
Sample ID
QC Batch Method
QC Batch
Analytical Method
Batch
92606905001
MW-2
92606905002
MW-3
92606905003
MW-4
92608939001
MWA R
92606905001
MW-2
EPA 200.8 Rev 5.4
706496
EPA 200.8 Rev 5.4
706540
92606905002
MW-3
EPA 200.8 Rev 5.4
706496
EPA 200.8 Rev 5.4
706540
92606905003
MW-4
EPA 200.8 Rev 5.4
706496
EPA 200.8 Rev 5.4
706540
92608939001
MWA R
EPA 200.8 Rev 5.4
706496
EPA 200.8 Rev 5.4
706540
92606905001
MW-2
SM 2540C-2015
701186
92606905002
MW-3
SM 2540C-2015
701186
92606905003
MW-4
SM 2540C-2015
701186
92608939001
MWA R
SM 254OC-2015
704188
92606905001
MW-2
SM 2540D-2015
701943
92606905002
MW-3
SM 2540D-2015
701943
92606905003
MW-4
SM 2540D-2015
701943
92608939001
MWA R
SM 254OD-2015
704186
92606905001
MW-2
EPA 350.1 Rev 2.0 1993
701834
92606905002
MW-3
EPA 350.1 Rev 2.0 1993
701834
92606905003
MW-4
EPA 350.1 Rev 2.0 1993
701834
92608939001
MWA R
EPA 350.1 Rev 2.0 1993
705176
92606905001
MW-2
EPA 353.2 Rev 2.0 1993
701085
92606905002
MW-3
EPA 353.2 Rev 2.0 1993
701085
92606905003
MW-4
EPA 353.2 Rev 2.0 1993
701085
92608939001
MWA R
EPA 353.2 Rev 2.0 1993
703515
92606905001
MW-2
EPA 420.4 Rev 1.0 1993
702419
EPA 420.4 Rev 1.0 1993
702504
92606905002
MW-3
EPA 420.4 Rev 1.0 1993
702419
EPA 420.4 Rev 1.0 1993
702504
92606905003
MW-4
EPA 420.4 Rev 1.0 1993
702419
EPA 420.4 Rev 1.0 1993
702504
92608939001
MWA R
EPA 420.4 Rev 1.0 1993
704389
EPA 420.4 Rev 1.0 1993
704734
92606905001
MW-2
SM 531OB-2014
701750
92606905002
MW-3
SM 531OB-2014
701750
92606905003
MW-4
SM 531OB-2014
701750
92608939001
MWA R
SM 5310E-2014
704295
Date: 06/24/2022 12:26 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 25 of 28

Effective Date: 051121202205/12/2022
Laboratory receiving samples:
Asheville ❑ Eden❑ Greenwood ❑ Huntersville ❑� Raleigh[] Mechanicsville❑ Atlantaf—IclientName-
wa#:92646906
❑El Co r: ❑Fe�d— ❑UPS ❑uSPs1111111111111111111111
Commercial ❑act'` a ❑Client 92606905
❑Other:
Custody seal Present? ❑Yes ❑N-0 Seals Intact? []yes ❑No
Packing Material: ❑Bubble Wrap,ETBubble Bags ❑None ❑ Other
Thermomete
Type of Ice: [Net ❑Blue
Correction factor:
Cooler Temp: � Add/Subtract,(°C) (i
Cooler Temp Corrected (°C):
USDA Regulated sail ( O N/A, water sample)
Did samples originate in a quarantine zone within the United States-, CA, NY, or SC
Chain of Custody Present?
Samples Arrived within Hold Time?
Short Hold Time Analysis (<72 hr,)?
Rush Turn Around Time Requested?
Sufficient volume?
Correct Containers Used?
-Pace Containers Used?
Containers Intact?
Dissolved analysis: Samples Field Filtered?
Sample Labeis Match COC?
-Includes Date/'TimePD/Analysis Matrix:
Headspace in VOA Vials (>5-6mm)?
Trip Blank Present?
Trip Blank Custody Seals Present?
COMMENTS/SAMPLE DISCREPANCY
CLIENT NOTIFICATION/RESOLUTION
Person contacted:
Project Manager SCURF Review:
--_---219ieG AianageLSRi-Review:--
Lames
❑No
❑NIA
❑,,Yes
- No
❑N/A
,fires -
❑Nu
❑N/A
YT -
❑Na
❑N/A
❑YW❑No.
©N/A
i
❑Yes
❑N❑
❑NIA
❑Yes -
[]NO
Cjtr A
es
[]No
❑N/A
❑y-
❑Na
eN/A
❑Yes
[3ft
[]N/A
❑Yes
nNo
nee
1.
2.
3.
4.
5.
6.
7.
8,
9-
Date/Initials Person Examining Contents• I 5— Z Z�
Biological Tissue Fr Zen?
❑Yes ❑No I/A
❑None
Temp should be above freezing to 6°C
ESj rnples out of temp criteria, Samples on ice, cooling process
has begun
Did sarngles originate from a foreign source (internationafly,
incfudrig Hawaii and Puerto Rico)? ❑Yes ❑No
Lot ID of split containers:
Date/T)me:
Date:
Field Data Required? ❑Yes ❑No
Qualtrax ID:. 69614 Page 1 of 2 Page 26 of 28

Effective Date: 05/121202205/12/2022
*Check mark top half of box if pH and/or dechlorination is verified and
within the acceptance range for preservation samples.
**Bottom half of box is to list number of bottles
***Check all unpreserved Nitrates for chlorine
Project # I WO#I . W'.606905
PM: UP Due Date: 06/13/22
CLIENT: 93—MARION
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Sample 10 Type of Preservative I pH upon receipt Date preservation adjusted Time preservation Amount of Preservative tat #
adjusted added
..V�GVYi4C-yet tt-- s a aiscrepar.cy atrdcting Nonn carolira ccrnpltance ;a„pit;, a copy of Lilis,ofal wiii be gent to the North Carolina DENR Certification Office (i.e.
Outof hold, incorrect preservative, out of temp, incorrect containers.
Qualtrax ID: 69614 Page 2 of 2 Page 27 of 28

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Page 28 of 28