NC0032077_Annual Monitoring & Pollutant Scan_20220623

Annual Monitoring and Pollutant Scan
Permit No. A/C 003g.0 7'7 Month A pn' 1
Outfall 0 0 I Year 9-Ogg-
Facility Name: Contentnea MSD _ ORC: Charles M. Smithwick,Jr.
Date of sampling: 4/21/22 Phone: [phone] RECEIVED
Analytical Laboratory: Environment 1, Inc.
J U N 2 3 2022
Parameter Analytical Quantitation Sample Units of
Parameter Sample Type
Code Method Level Result Measurem DEQIDWRINPDES
Ammonia (as N) CO610 Composite 350.I NN2 03 0.0 1 0.10 mg/L
Chlorine(total residual,TRC) 50060 Grab
Dissolved Oxygen 00300 Grab SM4500-0G2016 1.00 8.96 mg/I.
Nitrite plus Nitrate Total(as N) 00630 Composite 353.2 R2-93 0.04 0.20 mg/L
Total Kjeldahl Nitrogen 00625 Composite 351.2 R2-93 0.20 0.68 mg/L
Oil and Grease 00556 Grab 1664B 1.0 <5.0 mg/L
Total Phosphorus C0665 Composite 365.4-74 0.04 0.19 mg/I.
_
Total Dissolved Solids 70295 Composite D5907-13 1.0 240.0 mg/I.
Hardness 00900 Composite 2340C 11 0 50.0 mg,'I,
Metals(total recoverable),cyanide and total phenols
Antimony 01097 Composite EPA 200.8 3.0 < 3.0 ug/L
Arsenic 01002 Composite 3113 B-10 2.0 <2.0 ug/L
Beryllium 01012 Composite EPA 200.7 1.0 <1.0 ug/L
Cadmium 01027 Composite 3113 B-10 0.5 <0.5 ug/L
Chromium 01034 Composite EPA 200.7 5.0 <5.0 ug/L
Copper 01042 Composite EPA 200.7 2.0 <2.0 ug/L
Lead 01051 Composite 3113 B-10 2.0 <2.0 ug/L
Mercury(Method 1631E) COMER Grab EPA 1631 E 1.0 <1.0 ng/L
Nickel 01067 Composite EPA 200.7 2.0 3.0 ug/L
Selenium 01147 Composite EPA 200.8 1.0 <1.0 ug/L
Silver 01077 Composite EPA 200.7 1.0 <1.0 ug/L
Thallium 01059 Composite EPA 200.8 1.0 <1.0 ug/L
Zinc 01092 Composite EPA 200.7 10.0 23.0 ug/L
Cyanide 00720 Grab 4500 CNE-16 0.005 <0.005 mg/L
Total phenolic compounds 32730 Grab EPA 420.4-93 0.020 <0.020 mg/L
Volatile organic compounds
Acrolein 34210 Grab EPA 624.1 50.00 <50.00 ug/L
Acrylonitrile 34215 Grab EPA 624.1 50.00 <50.00 ug/L
Benzene 34030 Grab EPA 624.1 5.00 <5.00 ug/L
Bromoform 32104 Grab EPA 624.1 5.00 <5.00 ug/L
Carbon Tetrachloride 32102 Grab EPA 624.1 5.00 <5.00 ug/L
Chlorobenzene 34301 Grab EPA 624.1 5.00 <5.00 ug/L
Chlorodibromomethane 34306 Grab EPA 624.1 5.00 <5.00 ug/L
Chloroethane 85811 Grab EPA 624.1 10.00 <10.00 ug/L
2-chloroethyl vinyl ether 34576 Grab EPA 624.1 5.00 <5.00 ug/L
Chloroform 32106 Grab EPA 624.1 5.00 <5.00 ug/L
Dichlorobromomethane 32101 Grab EPA 624.1 5.00 <5.00 ug/L
1,1-dichloroethane 34496 Grab EPA 624.1 5.00 <5.00 ug/L
1,2-dichloroethane 32103 Grab EPA 624.1 5.00 <5.00 ug/L
Trans-1,2-dichloroethylene 34546 Grab EPA 624.1 5.00 <5.00 ug/L
1,1-dichloroethylene 34501 Grab EPA 624.1 5.00 <5.00 ug/L
1,2-dichloropropane 34541 Grab EPA 624.1 5.00 <5.00 ug/L
1,3-dichloropropylene 77163 Grab EPA 624.1 5.00 <5.00 ug/L
Ethylbenzene 34371 Grab EPA 624.1 5.00 <5.00 ug/L
Methyl Bromide 34413 Grab EPA 624.1 10.00 <10.00 ug/L
Methyl Chloride 34418 Grab EPA 624.1 10.00 <10.00 ug/L
Methylene Chloride 34423 Grab EPA 624.1 10.00 <10.00 ug/L
Form - DMR- PPA-1 Page 1

Annual Monitoring and Pollutant Scan
NCOD 3a20
Permit No. Month A Pr; 1
Outfall 0 0 I Year o-0 oa-a
Parameter Analytical Quantitation Sample Units of
Parameter Code Sample Type Method Level Result Measurement
1,1,2,2-tet1a(hloroethane 815-19 GI al) EPA 624.1 5.00 <5.00 ug/6
Tetrachloroethylene 34475 Grab EPA 624.1 5.00 <5.00 ug/L
Toluene 34010 Grab EPA 624.1 5.00 <5.00 ug/L
1,1,1-trichloroethane 34506 Grab EPA 624.1 5.00 <5.00 ug/L
1,1,2-trichloroethane 34511 Grab EPA 624.1 5.00 <5.00 ug/L
Trichloroethylene 39180 Grab EPA 624.1 5.00 <5.00 ug/L
Vinyl Chloride 39175 Grab EPA 624.1 10.00 <10.00 ug/L
Acid-extractable compounds
P-chloro-m-creso r 34452 I Grab EPA 625.1 20.00 <20.00 ug/L
2-chlorophenol 34586 Grab EPA 625.1 10.00 <10.00 ug/L
2,4-dichlorophenol 34601 Grab EPA 625.1 10.00 <10.00 ug/L
2,4-dimethylphenol 34606 Grab EPA 625.1 10.00 <10.00 ug/L
4,6-dinitro-o-cresol 34657 Grab EPA 625.1 50.00 <50.00 ug/L
2,4-dinitrophenol 34616 Grab EPA 625.1 50.00 <50.00 ug/L
2-nitrophenol 34591 Grab EPA 625.1 10.00 <10.00 ug/L
4-nitrophenol 34646 Grab EPA 625.1 50.00 <50.00 ug/L
Pentachlorophenol 39032 Grab EPA 625.1 50.00 <50.00 ug/L
Phenol 34694 Grab EPA 625.1 10.00 <10.00 ug/L
2,4,6-trichlorophenol 34621 Grab EPA 625.1 10.00 <10.00 ug/L
Base-neutral compounds
Acenaphthene 34205 Grab EPA 625.1 10.00 <10.00 ug/L
Acenaphthylene 34200 Grab EPA 625.1 10.00 <10.00 ug/L
Anthracene CO220 Grab EPA 625.1 10.00 <10.00 ug/L
Benzidine 39120 Grab EPA 625.1 100.00 <100.00 ug/L
Benzo(a)anthracene 34526 Grab EPA 625.1 10.00 <10.00 ug/L
Benzo(a)pyrene 34247 Grab EPA 625.1 10.00 <10.00 ug/L
3,4 benzofluoranthene 34230 Grab EPA 625.1 10.00 <10.00 ug/L
Benzo(ghi)perylene 34521 Grab EPA 625.1 10.00 <10.00 ug/L
Benzo(k)fluoranthene 34242 Grab EPA 625.1 10.00 <10.00 ug/L
Bis(2-chloroethoxy)methane 34278 Grab EPA 625.1 10.00 <10.00 ug/L
Bis(2-chloroethyl)ether 34273 Grab EPA 625.1 10.00 <10.00 ug/L
Bis(2-chloroisopropyl)ether 34283 Grab EPA 625.1 10.00 <10.00 ug/L
Bis(2-ethylhexyl)phthalate 39100 Grab EPA 625.1 20.00 <20.00 ug/L
4-bromophenyl phenyl ether 34636 Grab EPA 625.1 10.00 <10.00 ug/L
Butyl benzyl phthalate 34292 Grab EPA 625.1 10.00 <10.00 ug/L
2-chloronaphthalene 34581 Grab EPA 625.1 10.00 <10.00 ug/L
4-chlorophenyl phenyl ether 34641 Grab EPA 625.1 10.00 <10.00 ug/L
Chrysene 34320 Grab EPA 625.1 10.00 <10.00 ug/L
Di-n-butyl phthalate 39110 Grab EPA 625.1 10.00 <10.00 ug/L
Di-n-octyl phthalate 34596 Grab EPA 625.1 10.00 <10.00 ug/L
Dibenzo(a,h)anthracene 34556 Grab EPA 625.1 10.00 <10.00 ug/L
1,2-dichlorobenzene 34536 Grab EPA 625.1 10.00 <10.00 ug/L
1,3-dichlorobenzene 34566 Grab EPA 625.1 10.00 <10.00 ug/L
1,4-dichlorobenzene 34571 Grab EPA 625.1 10.00 <10.00 ug/L
3,3-dichlorobenzidine 34631 Grab EPA 625.1 10.00 <10.00 ug/L
Diethyl phthalate 34336 Grab EPA 625.1 10.00 <10.00 ug/L
Dimethyl phthalate 34341 Grab EPA 625.1 10.00 <10.00 ug/L
2,4-dinitrotoluene 34611 Grab EPA 625.1 10.00 <10.00 ug/L
2,6-dinitrotoluene C0626 Grab EPA 625.1 10.00 <10.00 ug/L
1,2-diphenylhydrazine 34346 Grab EPA 625.1 10.00 <10.00 ug/L
Fluoranthene C0376 Grab EPA 625.1 10.00 <10.00 ug/L
Fluorene 34381 Grab EPA 625.1 10.00 <10.00 ug/L
Form - DMR- PPA-1 Page 2

Annual Monitoring and Pollutant Scan
Permit No./✓C00 3a.o r77 Month NI f-; 1
Outfall O Co { Year 9-0 as
Parameter Analytical Quantitation Sample Units of
Parameter Code Sample Type Method Level Result Measurement
f lex ichlorobenzcnc C0700 Grab EPA 625.1 10.00 <10.00 ug/L
Hexachlorobutadiene 39702 Grab EPA 625.1 10.00 <10.00 ug/L
Hexachlorocyclo-pentadiene 34386 Grab EPA 625.1 10.00 <10.00 ug/L
Hexachloroethane 34396 Grab EPA 625.1 10.00 <10.00 ug/L
Indeno(1,2,3-cd)pyrene 34403 Grab EPA 625.1 10.00 <10.00 ug/L
Isophorone 34408 Grab EPA 625.1 10.00 <10.00 ug/L
Naphthalene 34696 Grab EPA 625.1 10.00 <10.00 ug/L
Nitrobenzene 34447 Grab EPA 625.1 10.00 <10.00 ug/L
N-nitrosodi-n-propylamine 34428 Grab EPA 625.1 10.00 <10.00 ug/L
N-nitrosodimethylamine 34438 Grab EPA 625.1 10.00 <10.00 ug/L
N-nitrosodiphenylamine 34433 Grab EPA 625.1 10.00 <10.00 ug/L
Phenanthrene 34461 Grab EPA 625.1 10.00 <10.00 ug/L
Pyrene 34469 Grab EPA 625.1 10.00 <10.00 ug/L
1,2,4,-trichlorobenzene 34551 Grab EPA 625.1 10.00 <10.00 ug/L
Sampling should be conducted as specified in 40 CFR Part 136.
"I certify,under penalty of law,that this document and all attachments were prepared under my direction or supervision in accordance
with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of
the person or persons who managed the system,or those persons directly responsible for gathering the information,the information
submitted is,to the best of my knowledge and belief,true,accurate,and complete. I am aware that there are significant penalties for
submitting false information,including the possibility of fines and imprisonment for knowing violations."
Auth ed Representative
resentative name
.(11:tzi
4.
Signature
lo-Jo-,26,1a
Date
Form - DMR- PPA-1 Page 3

ENCh[illEnla g DncgrpmigN
Drinking Water ID: 37715
Wastewater ID: 10
114 OAKMONT DRIVE PHONE [phone]
GREENVILLE, N.C. 27858 FAX [phone]
ID#: 253
CMSD (APA)
MR. DENNIS FOSS
P.O. BOX 477 DATE COLLECTED: 04/21/22
GRIFTON, NC 28530 DATE REPORTED : 05/26/22
REVIEWED BY:
Effluent Analysis Method
PARAMETERS Date Analyst Code
Ammonia Nitrogen as N, mg/I 0.10 04/28/22 TRJ 350.1 R2-93
Total Kjeldahl Nitrogen as N,mg/I 0.68 05/03/22 BMD 351.2 R2-93
Nitrate+Nitrite as N, mg/I 0.20 04/26/22 KES 353.2 R2-93
Total Phosphorus as P, mg/I 0.19 05/03/22 KES 365.4-74
Oil & Grease (HEM), mg/I <5.0 05/04/22 BMD 1664B
Phenol, ugh TESTED
Total Cyanide, mg/1 <0.005 04/26/22 1 MM 4500CNE-16
Total Hardness, mg/I 50 04/25/22 DNS 2340C-11
Total Dissolved Residue, mg/I 240 04/26/22 BLV D5907-13
Antimony, ugh <3.0 05/24/22 NAB EPA200.8
Arsenic, ugh <2.0 04/25/22 MTM 3113B-10
Beryllium, ugh <1.0 04/25/22 LFJ EPA200.7
Cadmium, ug/I <0.5 04/26/22 MTM 3113B-10
Total Chromium, ug/1 <5.0 04/25/22 LFJ EPA200.7
Copper, ugh <2.0 04/25/22 LFJ EPA200.7
Lead, ugh <2.0 04/25/22 MTM 3113B-10
Nickel, ug/l 3 04/25/22 LFJ EPA200.7
Selenium, ugh <1.0 05/24/22 NAB EPA200.8
Silver, ugh <1.0 04/25/22 LFJ EPA200.7
Thallium, ugh <1.0 05/24/22 NAB EPA200.8
Zinc, ug/1 23 04/25/22 LFJ EPA200.7
NOTE: Any result listed above as"TESTED"was sub-contracted to another laboratory. The corresponding results are attached.

EHFITCDRED2MI © rtI
Drinking Water ID: 37715
Wastewater ID: 10
114 OAKMONT DRIVE PHONE [phone]
GREENVILLE, N.C. 27858 FAX [phone]
CLIENT: CMSD (APA) CLIENT ID: 253
MR. DENNIS FOSS
P.O. BOX 477 ANALYST: JAP
GRIFTON, NC 28530 DATE COLLECTED: 04/21/22
DATE ANALYZED: 04/22/22
DATE REPORTED: 05/26/22
REVIEWED BY: �•/-!/l/`J
VOLATILE ORGANICS
EPA METHOD 624.1
Effluent
PARAMETERS, ugh
1. Chloromethane <10.00
2. Vinyl Chloride <10.00
3. Bromomethane <10.00
4. Chloroethane <10.00
5. Trichlorofluoromethane <5.00
6. 1,1-Dichloroethane <5.00
7. Methylene Chloride <10.00
8. trans-1,2-Dichloroethene <5.00
9. 1,1-Dichloroethene <5.00
10. Chloroform <5.00
11. 1,1,1-Trichloroethane <5.00
12. Carbon Tetrachloride <5.00
13. Benzene <5.00
14. 1,2-Dichloroethane <5.00
15. Trichloroethene <5.00
16. 1,2-Dichloropropane <5.00
17. Bromodichloromethane <5.00
18. 2-Chloroethylvinyl Ether <5.00
19. cis-1,3-Dichloropropene <5.00
20. Toluene <5.00
21. trans-1,3-Dichloropropene <5.00
22. 1,1,2-Trichloroethane <5.00
23. Tetrachloroethene <5.00
24. Dibromochloromethane <5.00
25. Chlorobenzene <5.00
26. Ethylbenzene <5.00
27. Bromoform <5.00
28. 1,1,2,2-Tetrachloroethane <5.00
29. 1,3-Dichlorobenzene <5.00
30. 1,4-Dichlorobenzene <5.00
31. 1,2-Dichlorobenzene <5.00
32. Acrolein <50.00
33. Acrylonitrile <50.00

IBEWIRDEMM -ECM TIVTER&CDrL
Drinking Water ID: 37715
Wastewater ID: 10
114 OAKMONT DRIVE PHONE [phone]
GREENVILLE, N.C. 27858 FAX [phone]
CLIENT: CMSD (APA) CLIENT ID: 253
MR. DENNIS FOSS
P.O. BOX 477 ANALYST: HIC
GRIFTON, NC 28530 DATE COLLECTED: 04/21/22 Page: 1
DATE EXTRACTED: 04/28/22
DATE ANALYZED: 05/03/22
REVIEWED BY: / DATE REPORTED: 05/26/22
SEMIVOLATILE ORGANICS
EPA METHOD 625.1
Effluent
PARAMETERS, ugh!
1. N-Nitrosodimethylamine <10.00
2. Phenol <10.00
3. Bis(2-Chloroethyl) Ether <10.00
4. 2-Chlorophenol <10.00
5. 1,3-Dichlorobenzene <10.00
6. 1,4-Dichlorobenzene <10.00
7. 1,2-Dichlorobenzene <10.00
8. Bis(2-Chloro-l-methylethyl) Ether <10.00
9. Hexachloroethane <10.00
10. N-Nitroso-Di-N-Propylamine <10.00
11. Nitrobenzene <10.00
12. Isophorone <10.00
13. 2-Nitrophenol <10.00
14. 2,4-Dimethylphenol <10.00
15. Bis(2-Chloroethoxy) Methane <10.00
16. 2,4-Dichlorophenol <10.00
17. 1,2,4-Trichlorobenzene <10.00
18. Naphthalene <10.00
19. Hexachlorobutadiene <10.00
20. 4-Chloro-3-Methylphenol <20.00
21. Hexachlorocyclopentadiene <10.00
22. 2,4,6-Trichlorophenol <10.00
23. 2-Chloronaphthalene <10.00
24. Acenaphthylene <10.00
25. Dimethylphthalate <10.00
26. 2,6-Dinitrotoluene <10.00
27. Acenaphthene <10.00
28. 2,4-Dinitrophenol <50.00
29. 4-Nitrophenol <50.00
30. 2,4-Dinitrotoluene <10.00
31. Fluorene <10.00
32. Diethylphthalate <10.00
33. 4-Chlorophenyl Phenyl Ether <10.00
34. 4,6-Dinitro-2-Methylphenol <50.00
35. N-Nitrosodiphenylamine <10.00
36. 4-Bromophenyl Phenyl Ether <10.00
37. Hexachlorobenzene <10.00
38. Pentachlorophenol <50.00
39. Phenanthrene <10.00
40. Anthracene <10.00
41. Di-N-Butylphthalate <10.00
42. Fluoranthene <10.00
43. Benzidine <100.00
44. Pyrene <10.00
45. Butylbenzylphthlate <10.00
46. Benzo[a]anthracene <10.00
47. 3,3'-Dichlorobenzidine <10.00
48. Chrysene <10.00

EfiwjaDEEM oiool,oTgoe,
Drinking Water ID: 37715
Wastewater ID: 10
114 OAKMONT DRIVE PHONE [phone]
GREENVILLE, N.C. 27858 FAX [phone]
CLIENT: CMSD (APA) CLIENT ID: 253
MR. DENNIS FOSS
P.O. BOX 477 ANALYST: HIC
GRIFTON, NC 28530 DATE COLLECTED: 04/21/22 Page: 2
DATE EXTRACTED: 04/28/22
DATE ANALYZED: 05/03/22
REVIEWED BY: DATE REPORTED: 05/26/22
/� SEMIVOLATILE ORGANICS
EPA METHOD 625.1
Effluent
PARAMETERS, ughl
49. Bis(2-Ethylhexyl)phthalate <20.00
50. Di-N-Octylphthalate <10.00
51. Benzo[b]fluoranthene <10.00
52. Benzo[k]fluoranthene <10.00
53. Benzo[a]pyrene <10.00
54. Indeno(1,2,3-C,d)pyrene <10.00
55. Dibenzo[a,h]anthracene <10.00
56. Benzo[g,h,i]perylene <10.00
57. 1,2-Diphenylhydrazine <10.00

Pace Analytical Services,LLC
Kincey Ave.
te
e 9800Huntersvvle,NCi28 08
aceAnalytical
www.pacalabs.com [phone]
Page 1 of 1
Laboratory Report
Mark Oliveira Report Date: 05/05/2022
Environment 1 Date Received: 04/28/2022
114 Oakmont Dr
Greenville, NC 27858
Project: Environment 1-CMSD
Pace Project No.:92601572
Sample: CMSD(APA)-Effluent Lab ID: 92601572001 Collected: 04/21/22 09:30 Matrix: Water
Method Parameters Results Units Report Limit Analyzed Qualifiers
EPA 420.4 Rev 1.0 1993 Phenolics,Total Recoverable ND mg/L 0.020 05/05/22 15:23
Reviewed by:
c1nu¢
Stephanie Knott
704-977-0981
[e-mail]
Pace Analytical Services Asheville
2225 Riverside Drive,Asheville,NC 28804 South Carolina Laboratory ID:99030
Florida/NELAP Certification#:E87648 South Carolina Certification#:99030001
North Carolina Drinking Water Certification#:37712 VirginiaNELAP Certification#:460222
North Carolina Wastewater Certification#:40
Page 1 of 5