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Home My WebLink AboutNC0086169_Permit (Modification)_19981008 (2)NPDES DOCIMENT 5CANNINO COVER !;MEET NC0086169 Corning / Midland facility NPDES Permit: Document Type: Permit Issuance Wasteload Allocation Authorization to Construct (AtC) Permit Modification Complete File - Historical Correspondence Speculative Limits Instream Assessment (67b) Environmental Assessment (EA) Permit History Document Date: October 8, 1998 This document is printed on reuse paper - ignore any content on the rezrerse side State of North Carolina Department of Environment and Natural Resources Division of Water Quality James B. Hunt, Jr., Governor Wayne McDevitt, Secretary A. Preston Howard, Jr., P.E., Director October 8, 1998 Mr. Eric C. Hilton. P.E. Corning Incorporated Telecommunications Products Division Post Office Box 1700 Concord, North Carolina 28026-1700 Subject: Dear Mr. Hilton: AVA NCDENR Permit Modification Corning Concord Plant NPDES Permit No. NC0086169 Cabarrus County The Division issued NPDES permit number NC0086169 to Corning Incorporated for the above referenced facility on November 14, 1997. In accordance with your request. the Division is forwarding herewith permit modifications to the aforementioned permit. Specifically, the permit has been modified to extend the June 30, 1998 deadline for inclusion of all wastewaters into outfall 003 until October 31, 1998. Additionally, the permit has been modified such that humidification boiler blowdown is permitted for discharge through outfall 002 after October 31, 1998. Enclosed please find the modified permit pages. The old pages should be discarded. This permit modification is issued pursuant to the requirements of North Carolina General Statute 143-215.1 and the Memorandum of Agreement between North Carolina and the U. S. Environmental Protection Agency dated December 6, 1983. Please take notice that this permit is not transferable. Part II, E.4. addresses the requirements to be followed in case of change in ownership or control of this discharge. This permit does not affect the legal requirement to obtain other permits which may be required by the Division of Water Quality or permits required by the Division of Land Resources, Coastal Area Management Act or any other Federal or Local government permit that may be required. If you have any questions, comments, or concerns regarding this permit modification, please do not hesitate to contact Mark Mclntire at (919) 733-5083, extension 553. cc: Central Files NPDES Unit Files Mooresville Regional Office Sincerely 624ex,,_ t'oyA. Preston Howard, Jr., P.E. P.O. Box 29535, Raleigh, North Carolina 27626-0535 Telephone (919) 733-5083 FAX (919) 733-0719 An Equal Opportunity Affirmative Action Employer 50% recycled / 10% post -consumer paper SUPPLEMENT TO PERMIT COVER SHEET Corning Incorporated is hereby authorized to: Permit No. NC0086169 1. Operate a 0.0274 MGD wastewater treatment facility consisting of an equalization tank, an off -spec tank, a Lamella clarifier, two neutralization tanks and a neutralization transfer tank located at a facility located off of Highway 601 in Midland, Cabarrus County (see Part III, A of this permit); and 2. Discharge stormwater and boiler blowdown from a wet detention pond into an unnamed . tributary of Clear Creek (outfall 002), discharge stormwater and non - contact cooling water from a wet retention pond into an unnamed tributary of Muddy Creek (Outfall 001), and discharge process wastewater from the above referenced treatment works at the location specified on the attached map into the Rocky River (Outfall 003). Beginning November 1, 1998, outfall 001 will cease discharge and non -contact cooling water will be commingled with process wastewater and discharged via outfall 003. All receiving streams are classified C waters in the Yadkin -Pee Dee River basin. A(1). EFFLUENT LIMITATIONS AND MONITORING REQUIREMENTS - FINAL Permit No. NC0086169 During the period beginning on the effective date of the permit and lasting until October 31, 1998, the Permittee is authorized to discharge non -contact cooling water from outfall(s) serial number 001. Such discharges shall be limited and monitored by the Permittee as specified below: EFFLUENT CHARACTERISTICS LIMITS MONITORING REQUIREMENTS Monthly Average Weekly Average Daily Maximum Measurement, Frequency Sample Type Sample Location1 Flow Semi-annually Estimate Effluent Temperature2 Semi-annually Grab Effluent Total residual chlorine Semi-annually Grab Effluent There shall be no chromium, zinc or copper added to the treatment system except as pre -approved additives to biocidal compounds. The effluent for this outfall shall mean a point upstream of the mixing point with stormwater. 2 The temperature of the effluent will be regulated so that the temperature of the receiving stream does not increase more than 2.8°C above the natural water temperature. Receiving water temperature will not exceed a maximum of 32°C. The permittee shall obtain authorization from the Division prior to any use of biocide in the cooling water. The permittee shall notify the Director in writing at least ninety (90) days prior to instituting use of any additonal biocide in the treatment system which may be toxic to aquatic life (other than biocides previously reported to the Division). Such notification shall include completion of Biocide Worksheet Form 101 and a map indicating the discharge point and receiving stream. The pH shall not be less than 6.0 standard units nor greater than 9.0 standard units. There shall be no discharge of floating solids or visible foam in other than trace amounts. All conditions related to the stormwater portion of this outfall can be found in Part II, Stormwater Monitoring, Controls and Limitations for Permitted Discharges. A(2). EFFLUENT LIMITATIONS AND MONITORING REQUIREMENTS - FINAL Permit No. NC0086169 During the period beginning on the effective date of the permit and lasting until expiration, the Permittee is authorized to discharge boiler blowdown from outfall(s) serial number 002. Such discharges shall be limited and monitored by the Permittee as specified below: How Temperature2 Total residual chlorine ,;:Monthly '':Average IMIT Weekly. :Average MONITORING REQUIREMENTS.. Daily Maximum Measurement Frequency Semi-annually Semi-annually Semi-annually Sample Type Estimate Grab Sample Location1 Grab Effluent Effluent Effluent There shall be no chromium, zinc or copper added to the treatment system except as pre -approved additives to biocidal compounds. The effluent for this outfall shall mean a point upstream of the mixing point with stormwater. 2 The temperature of the effluent will be regulated so that the temperature of the receiving stream does not increase more than 2.8°C above the natural water temperature. Receiving water temperature will not exceed a maximum of 32°C. The permittee shall obtain authorization from the Division prior to any use of biocide in the cooling water. The permittee shall notify the Director in writing at least ninety (90) days prior to instituting use of any additional biocide in the treatment system which may be toxic to aquatic life (other than biocides previously reported to the Division). Such notification shall include completion of Biocide Worksheet Form 101 and a map indicating the discharge point and receiving stream. The pH shall not be less than 6.0 standard units nor greater than 9.0 standard units. There shall be no discharge of floating solids or visible foam in other than trace amounts. All conditions related to the stormwater portion of this outfall can be found in Part II, Stormwater Monitoring, Controls and Limitations for Permitted Discharges. A(3). EFFLUENT LIMITATIONS AND MONITORING REQUIREMENTS - FINAL Permit No. NC0086169 During the period beginning on the effective date of the permit and lasting until October 31, 1998, the Permittee is authorized to discharge industrial process wastewater from outfall(s) serial number 003. Such discharges shall be limited and monitored by the Permittee as specified below: ?E , : gUENTZC CTE STICS r, ,: ;� ��. s - x: , _!�� ,�.. �. �, r .,��... �f �#�_. .p. - .; �� ,.� GG ,� , : r�s i` ! .t.. Y .� .. ... .-. ..,. .. r • -: r -. .... .. .. .� ^.i a �- �A-, i x >�'° . �. ...}. �j _ •yam.. : ;.;f�r: '�i` i' : ��.. •� � ��:' ..j:} �-i:Y.p W N :.... .. - .1 �h 9Ad FY.-. - - w C:� sSL- 1 , � •��,�� ::�. .�:- ��.., :,,�f �,�Y .� a : � ..� < < :� � � - ..,�y :.�x ��:� � ,� � � :.� :E'' -��° ;, ��::• .:� .�` �,w L. �"e3 .C.3;.k.. ?', i� r;. .�',; �' he ` � All.,--...v �,.. _,�t: l > r � , ,. :,._. .,. •Q��Y _ ...._ . . zl.. ..�, � .,.._ ., . �� ...,.s I ,Y l > Y'. ., 4 �j� ,�, . a=-: E I: ik ..erA.� a Y't � .'G i� `Y .'h lm ;; : f :. ,LIMITS, � ��. . :n .. .. :� ,.. �.: , .. A. ..1,,. ,fin 73}.. �<;'k. d. Y' .• Tg. + s!: 1 f. S. } i .'i .+.. �`i'.x ,.�.. : ..... 'F '�:`iJt.Cr t. � t Y NIT ,NG R O��I ENT a EQUIREM S `( S .�d' 'E. i.,..:.. !i 1 j�c. � yy 3 ':is ) •.r � ,. S. n5 i... •. ,--,- . .'f .i:.• 5 .,.f,Se i:.:,T� }i�.i' ,..1 .� .. i ...... .. ,�\.r. . 1 . � y Monthl . Y �� rr 1 �` •'i3 F Average _ - g :,• .=Week1 -_ i.. •� y : 'Av erage .v,, _ x� .-Dail Y 'Maximum :.P.s r 1Vleasurementr�-s •, , ...- ".Z%:- °Frequency ` y ... P.. .,t+�. <•� .P ��Sam le .� � ��:.. p . ..ta, ter" :Type ��, : Samp el = ^.--- i �T :? ��:• . •. Location Flow (MGD) O0274 Continuous Estimate Effluent Total Suspended Solids 30.0 mg/L 45.0 mg/L Weekly Composite Effluent Chloride 2/Week Composite Effluent Total Residual Chlorine 28 pg/L 2/Week Grab Effluent Temperature' Weekly Grab Effluent Iron 2NVeek Composite Effluent Total Phosphorus Quarterly Composite Effluent Acute Toxicity2 Quarterly Composite Effluent pH3 Weekly Grab Effluent Pollutant Analysis4 Annually 5 Effluent Notes: The temperature of the effluent will be regulated so that the temperature of the receiving stream does not increase more than 2.8'C above the natural water temperature. Receiving water temperature will not exceed a maximum of 32°C. 2 Acute Toxicity (Fathead Minnow) 24 hour P/F at 90%; January, April, July and October; See Item A(5) of the Supplement to Effluent Limitations and Monitoring Requirements. 3 The pH shall not be less than 6.0 standard units nor greater than 9.0 standard units. 4 See Item A(6) of the Supplement to Effluent Limitations and Monitoring Requirements. There shall be no discharge of floating solids or visible foam in other than trace amounts. A(4). EFFLUENT LIMITATIONS AND MONITORING REQUIREMENTS - FINAL Permit No. NC0086169 During the period beginning on November 1, 1998 and lasting until expiration, the Permittee is authorized to discharge industrial process wastewater and non -contact cooling water from outfall(s) serial number 003. Such discharges shall be limited and monitored by the Permittee as specified below: EFFLU TrCH C: ERISTICS ., .,- . -r ;�R -)!', . � ;} .i � • sF y { (ep'H . '{� ��i'.�}" 'F,., C ... ��: "•��• { i v � 7 P . l�C$.t � 1 S: r,� 5S ` -',��({j7jj:CCC '} 'f.y. ,;_ �- �l7 �.ti •" , • • , =-.;ems' rY:.~ �;, ,� ► , N i� ;.. � �. .trr , � a•• -1..ar .r .l x,wif ••-i - . :, c....... .' > ,, 5i4: , ` •. , y. -.4-y1 4.- .> , �,.� �' .,..,.LIMITS .�.. a {', r �� . -� N. ,�� r:- :s. ..E :t � >�,r � �- ..��;:%. :,.• . , :.-::. z ►R."�� MQNITORING REQUIRE ; G , � ,.� t. '3 .:r.. . •�:.�-',i� .iiFdtkg�:c{'•_•,.:. .rf'�t�r�Y �� t .. - •,a. rJw. E T r -' , -.i c.�:,. ..,,�7;':ct,�i.. .x. • ��J": , }. • .f�,?,.ii..•f�K'1F .,�. tajaplei5— • >« �<" cation _ onthl >, - , ...� . =r a > A�i^erage . ' x'Weekl r .,: , :._ Y , ,Average >_�,�.,Dail -•_. �. �. �., y•. .. r., .: ~•Maximum- ;�.. .14 , Measu a ent ;•{� Senn- . 41Fre uency, --- q � =: �Sa le:-. ,. ,;lyp,, �M1� ...a •'AkT e Yp .. Flow (MGD) 0.0274 Continuous Estimate Effluent' Total Suspended Solids 30.0 mg/L 45.0 mg/L Weekly Composite Effluent Chloride 2/Week Composite Effluent Total Residual Chlorine 28 pg/L 2/Week Grab Effluent Temperature2 Weekly Grab Effluent . Iron' 2/Week Composite Effluent Total Phosphorus Quarterly Composite Effluent Chronic Toxicity3 Quarterly Composite Effluent pH4 Weekly Grab Effluent - Pollutant Analysis5 Annually 5 Effluent Notes: The compliance point for flow shall be upstream of the non -contact cooling water and boiler blowdown internal outfall. The compliance point for all other parameters shall be at the Rocky River discharge location. 2 The temperature of the effluent will be regulated so that the temperature of the receiving stream does not increase more than 2.8°C above the natural water temperature. Receiving water temperature will not exceed a maximum of 32°C. 3 Chronic Toxicity (Ceriodaphnia) P/F at 0.31%; January, April, July and October; See Item A(7) of the Supplement to Effluent Limitations and Monitoring Requirements. 4 The pH shall not be less than 6.0 standard units nor greater than 9.0 standard units. S See Item A(6) of the Supplement to Effluent Limitations and Monitoring Requirements. There shall be no discharge of floating solids or visible foam in other than trace amounts. Corning Incorporated Permit No. NC0086169 SUPPLEMENT TO EFFLUENT LIMITATIONS AND MONITORING REQUIREMENTS SPECIAL CONDITIONS A. (5). ACUTE TOXICITY PERMIT LIMIT (QUARTERLY) The permittee shall conduct acute toxicity tests on a quarterly basis using protocols defined as definitive in EPA Document EPA/600/4-90/027 entitled "Methods for Measuring the Acute Toxicity of Effluents to Freshwater and Marine Organisms." The monitoring shall be performed as a Fathead Minnow (Pimephales promelas) 24 hour static test. The LC50 of this effluent using the previously stated methodology may at no time in any toxicity test be less than 90%. Effluent samples for self -monitoring purposes must be obtained during representative effluent discharge below all waste treatment. The tests will be performed during the months of January, April, July and October. The parameter code for this test is TAE6C. All toxicity testing results required as part of this permit condition will be entered on the Effluent Discharge Monitoring Form (MR-1) for the month in which it was performed, using the appropriate parameter code. Additionally, DWQ Form AT-1 (original) is to be sent to the following address: Attention: Environmental Sciences Branch North Carolina Division of Water Quality 4401 Reedy Creek Road Raleigh, N.C. 27607 Test data shall be complete and accurate and include all supporting chemical/physical measurements performed in association with the toxicity tests, as well as all dose/response data. Total residual chlorine of the effluent toxicity sample must be measured and reported if chlorine is employed for disinfection of the waste stream. Should there be no discharge of flow from the facility during a month in which toxicity monitoring is required, the permittee will complete the information located at the top of the aquatic toxicity (AT) test form indicating the facility name, permit number, pipe number, county, and the month/year of the report with the notation of "No Flow" in the comment area of the form. The report shall be submitted to the Environmental Sciences Branch at the address cited above. Should any single quarterly monitoring indicate a failure to meet specified limits, then monthly monitoring will begin immediately until such time that a single test is passed. Upon passing, this monthly test requirement will revert to quarterly in the months specified above. Should the permittee fail to monitor during a month in which toxicity monitoring is required, then monthly monitoring will begin immediately until such time that a single test is passed. Upon passing, this monthly test requirement will revert to quarterly in the months specified above. Should any test data from either these monitoring requirements or tests performed by the North Carolina Division of Water Quality indicate potential impacts to the receiving stream, this permit may be re -opened and modified to include alternate monitoring requirements or limits. NOTE: Failure to achieve test conditions as specified in the cited document, such as minimum control organism survival and appropriate environmental controls, shall constitute an invalid test and will require immediate follow-up testing to be completed no later than the last day of the month following the month of the initial monitoring. A. (6) POLLUTANT ANALYSIS CONDITION The Permittee shall conduct a test for pollutants annually at the effluent from the treatment plant. The discharge shall be evaluated as follows: 1) A pollutant analysis of the effluent must be completed annually using EPA approved methods for the following analytic fractions: (a) purgeables (i.e., volatile organic compounds); (b) acid extractables; (c) base/neutral extractables; Corning Incorporated Permit No. NC0086169 SUPPLEMENT TO EFFLUENT LIMITATIONS AND MONITORING REQUIREMENTS SPECIAL CONDITIONS (Continued) (d) organochlorine pesticides and PCBs; (e) herbicides; and (f) metals and other inorganics. The Annual Pollutant Analysis Monitoring (APAM) Requirement Reporting Form A and accompanying memo describes the sampling and analysis requirements and lists chemicals to be included in the pollutant analysis. This monitoring requirement is to be referred to as the "Annual Pollutant Analysis Monitoring Requirement" (APAM). 2) Other significant levels of organic chemicals must be identified and approximately quantified. For the purpose of implementing this requirement, the largest 10 GC/MS peaks in the purgeable, base/neutral extractable, and acid exractable fractions (or fewer than 10 if less than 10 unidentified peaks occur) for chemicals other than those specified on the APA Requirement Reporting Form A should be identified and approximately quantified as stated in the APAM Reporting Form A instructions. This part (item 2) of the APAM requirement is to be referred to as the "10 significant peaks rule"). A. (7) CHRONIC TOXICITY PASS/FAIL PERMIT LIMIT (QUARTERLY) The effluent discharge shall at no time exhibit chronic toxicity using test procedures outlined in the "North Carolina Ceriodaphnia Chronic Effluent Bioassay Procedure," Revised November 1995, or subsequent versions. The effluent concentration at which there may be no observable inhibition of reproduction or significant mortality is 0.31 % (defined as treatment two in the procedure document). The permit holder shall perform quarterly monitoring using this procedure to establish compliance with the permit condition. The tests will be performed during the months of January, April, July and October. Effluent sampling for this testing shall be performed at the NPDES permitted final effluent discharge below all treatment processes. All toxicity testing results required as part of this permit condition will be entered on the Effluent Discharge Monitoring Form (MR-1) for the month in which it was performed, using the parameter code TGP3B. Additionally, DWQ Form AT-1 (original) is to be sent to the following address: Attention: Environmental Sciences Branch North Carolina Division of Water Quality 4401 Reedy Creek Rd. Raleigh, N.C. 27607 Test data shall be complete and accurate and include all supporting chemical/physical measurements performed in association with the toxicity tests, as well as all dose/response data. Total residual chlorine of the effluent toxicity sample must be measured and reported if chlorine is employed for disinfection of the waste stream. Should there be no discharge of flow from the facility during a month in which toxicity monitoring is required, the permittee will complete the information located at the top of the aquatic toxicity (AT) test form indicating the facility name, permit number, pipe number, county, and the month/year of the report with the notation of "No Flow" in the comment area of the form. The report shall be submitted to the Environmental Sciences Branch at the address cited above. Should any single quarterly monitoring indicate a failure to meet specified limits, then monthly monitoring will begin immediately until such time that a single test is passed. Upon passing, this monthly test requirement will revert to quarterly in the months specified above. Should the permittee fail to monitor during a month in which toxicity monitoring is required, then monthly monitoring will begin immediately until such time that a single test is passed. Upon passing, this monthly test requirement will revert to quarterly in the months specified above. Corning Incorporated Permit No. NC0086169 ' SUPPLEMENT TO EFFLUENT LIMITATIONS AND MONITORING REQUIREMENTS SPECIAL CONDITIONS (Continued) Should any test data from this monitoring requirement or tests performed by the North Carolina Division of Water Quality indicate potential impacts to the receiving stream, this permit may be re -opened and modified to include alternate monitoring requirements or limits. NOTE: Failure to achieve test conditions as specified in the cited document, such as minimum control organism survival, minimum control organism reproduction, and appropriate environmental controls, shall constitute an invalid test and will require immediate follow-up testing to be completed no later than the last day of the month following the month of the initial monitoring. A. (8) Biological Monitoring Condition The Permittee shall conduct an upstream and downstream benthic macroinvertebrate survey beginning June 1999 and lasting through September 1999. A report of the findings of this survey shall be completed and included with the permit application package at the time of permit renewal. For technical assistance regarding this permit requirement, please contact the Division's Biological Assessment Unit at (919) 733-6946. NCDENR/DIVISION OF WATER QUALITY Water Quality Section/NPDES Unit September 28, 1998 MEMORANDUM To: File From: Mark McIntire Subject: Corning Permit Modification Corning's Concord Plant NPDES Permit Number NC0086169 Corning has requested two permit modifications to their NPDES permit issued in November 1997. Specifically, they have requested an extension from June 30, 1998 to October 31, 1998 for the inclusion of all wastewater into outfall 005. Additionally, they have requested that after the 313' of October, they be authorized to continue discharge humidification boiler blowdown through outfall 002. The time extension has been granted without additional changes. Regarding the discharge of boiler blowdown through 002, because the receiving stream for this outfall is essentially a zero flow water body, and in light of the presence of biocides in the blowdown, a chronic toxicity testing condition has been included on a quarterly basis. cc: Central Files NPDES Unit Files SEPM 16-99 15 : 19 FROM: ID: PAGE 1 Corning Incorporated Telecommunications Products Division P.O. Box 1700 Concord, North Carolina 28026-1700 704-569-6000 September 15,1998 Mark McIntire NPDES Unit NCDENR, Division of Water Quality PO Box 29535 Raleigh, NC 27626-0535 Post -it' Fax Note 7671 pate `j-lb-I f ilia ► 7 To mark m L., 1t /'e Fr= 6.8-C /Y%%TOn Co/Dept ArG 4 c„,,A Co. Phone # Phone * 7 ,' 4/34' ro,o � Fax* i l � — •727 _ o7M Fax # Subject: Request to move Humidification Boiler Blowdown to Outfall 002 Dear Mr. McIntire: CORNING I have talked to Jon Wills, the person who did the calculations showing the percentage of our discharge that our humidification boiler contributes. Our request to move this discharge to our stormwater outfall is based on two facts. The flow volume is very insignificant compared to our total discharge volume and the geographical location of our boiler in the plant is such that added equipment is needed to pump the condensate to our lift station. A stormwater outfall is . located in the vicinity. This change would save Corning tens of thousands of dollars. Below is a summary of the flow data. Attached is an analysis of the Betz chemicals in the stream for your records. There was an error in .the earlier data that Christy sent. Mr. Wills did not take into account the non -contact cooling tower blowdown in.his calculation. He thought that our 27,400 gpd flow limit included the tower blowdown, but it does not. That is more favorable for our analysis. I apologize for the change in the data, due to the situation here at the time, some things were done more hastily than they should havebeen. • Flow calculations: Process Effluent Flow 27400 • :.HVAC •Cooling•Tower Blowdown 29660 ECWS Cooling Tower Blowdown 3840 . Humidification Boiler Blowdown 960 Total flow to 003 61860 Percentage of Boiler Blowdown to Total 1.55% Thank you for your attention on this matter. I would appreciate an answer as soon as yo i can provide one. a s- . Eric C. Hilton, P.E. SEP.= 16-98 15 : 18 FROM : • ID: PAGE 2 the Ater s Controls oxygen corrosion In h feed tems and the boiler • Easily applied liquid concentrate Alkaline formulation will not caused . boiler pH depression . Available with drum -free liquid deiiverie8 through the BetzDearborn Custom Distribution $ervicr' (CDSD) DESCRIPTION AND USE CORTROL0 15104 is a concentrated, alkal le, liquid sulfite product which is designed to control oxygen corrosion in boilers and closed hot water systems. • I Dissolved oxygen is a constant threat to the integrity of a feedwater system, an economizer, and internal boiler and condensate system surfaces. Ejen minor concentrations of dissolved oxygen can cause severe pitting corrosion. Because of its highly !localized nature. pitting attack, caused by dissolve�t oxygen, can result in rapid failure of feedwater lines, econo- mizers. boiler tubes, and condensate return lines. CORTROL 15104 controls corrosion. by reacting with and removing any dissolved oxygen present in the feedwater or boiler water. In addition, it -creates a reducing environment in the boiler that promotes the formation of a protective Trion oxide film. CORTROL 18104 may also be Used to control oxygen corrosion in closed hot water systems where an oxy- gen scavenger program Is indicated. TREATMENT AND FEEDING REQUIREMENTS CORTROL IS104 may be fed neat or diluted with deaerated feedwater or condensate to a convenient strength. Dilute feed solutions (`day tanks") of this product should be made down on a daily basis to avoid excessive depletion of product activ.s through atmospheric contact. The feed solution ' can be fur- ther protected by fitting day tanks with a plastic .R •'�: .'++••'ram .,,LYi li/.r. I I f+• 1i�1� pm! Pr��duct CORTROO 1a104- Oxygen Scavenge qj dd ery yptr •riYrr ' IHt1 Iy� M1MOM Sit ,{!'1 III, • Facts 1. lc 1. 1 a., • 1•II10 1 ili'I. r..•..t,• Mho ! "floating lid" or adding a layer of hollow, floating poly- ethylene, polypropylene, or PVC balls to minimize contact with the atmosphere. - . • - y--.Chemical-fe�ed'injection quills must -be constructed• of -• fe water ;or stainless. steel or another resistant alloy. The preferred feed points for CORTROL 1S104 are to the storage section of the deaerating heater below the waterline. to the feedwater line, or to the hotwell or feedwater tank. GENERAL PROPERTIES Physical properties of CORTROL 15104 are shown on the Material Safety Data Sheet, a copy of which is available on request. PACKAGING INFORMATION CORTROL 15104 is a liquid blend, available in a wide variety of customized containers and delivery meth- ods. Contact your BetzDearborn representative for details. STORAGE Store CORTROL. IS104 at moderate temperatures and protect from freezing. If frozen, thaw completely and mix throughly prior to use. Exposure to atmcs- pheric oxygen should be minimized. SAFETY PRECAUTIONS A Material Safety Data Sheet containing detailed Information about this product is available upon request. PRICING F.0.8. Destination. Minimum freight allowed. PFB 104 9701 401997, HetzDeWrbern Water Management Group. All rtgt%ta reserved. SEP-r L 6-99 15 : 19 FROM: ID: rHA . t vU 4be f f W4 PAGE 3 PAGE 10 sE. TZDEARBO N• MATERIAL �.. FETY DATA EF1 ,ECTIVE DATE: 11-JUL-1997 PR NTED DATE: 06-JUL-1998 etz.Dearbor-, .,,,., 1) .HEMICAL•PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME : CORTROL IS104 )RODUCT APPLICATION AREA: bXYGEN SCAVENGER. 3OMPANY ADDRESS: Betz Water Management Grouri Division Betz Laboratories, Inc. 200 Witmer Road--iorsham L PA 19044 Information phone number-(14)-77-3-6269 . — iiMERGENCY TELEPHONE (HE4LTH/ACCIDENT): (800)-8774940 (USA) 2) COMPOSITION / INPORMATIONON INGREDIENTS I lfgrmation for s ecific product ingredients as required by the OSHA HA RIJ COMMUNICATION STANDARD is Iiste' Refer to z. ddltlonai sections of this MSDS for our lassessment of the potential i.azards of this formulation. IAZARDOUS INGREDIENTS: CAS# CHEM I CAL NAME 10117-38-1 r'ut,FIURouS ACTD, DIPOTASSIZJM SALT ':•13rsient irritant; potential sennit_zYr (:.kin and :Jo component is considered to b‘ a carcinogen by the National Toxicology :'rogram, the International Agency for Research on Cancer, or the P )cc ational Safety and Health Adm nistration at OSHA thresholds for . :arc%nogens. t• PA aE 1 • CONTINUED SEP7 16-99 15 : 19 FROM: ID: PAGE 4 ;RO[ :UCT NAME : CORTROL IS104 =_FFE :TIVE DATE: 11-JUL01997 . i1,4101 Pat a tti:I,is1 pp 11,11 *.+ MI 411wr iela w *PI! 10) C:;TABlLITY AND REACTIVITY ST ABILITY: table under normal storage conditionsi HL ZARDOUS POLYMERIZATION: t Vill not occur. I IN ;OMPATIBILITIES: 1 /lay react with strong oxidizers. DECOMPOSITION FRCOUCTS: I ` "hermal decompos!tion (destructive fires) yields elemental oxides. BI.,TL INTERNAL P LMr: OUT/CLEANOL IT CATEGORIES:• _Br+ 11) TOXICOLOGICAL INFORMATION Qa a1 LD5 Q RAT: NOTE - EstrimC1 red value D( .rural LD50 RAlr' IT : NOTE - Est. tmaeed value • :.1, 000 mg/kg >2,000 mg/kg 12) ECOLOGICAL :IFORMATION QUATIC TOXICOLOGY Fathead Minnow 95 Hour Static Renpral Bioassay LC50: 1760 m!J1L No Effect Level: 12E0 mg/L • • • • Daphnia magna 48 HaLir Static Screem 50% Mortality: 2^00 rng/L 0% Mortality: 1 0.0 !ng/L. LIIODEORADATION coo Data Available. 1:� DISPOSAL CO'ISIDERATION4 i If this undiluted product is discarded s a waste, the US RCRA hazardous waste i• 'entitication numb*r is : , . . Not applicable. • . Please be advised; however, that stale and local requirements for waste disposal may bo more rostrictlife or otherwise different from federal regulations. Consult state anall local regulations regarding the proper disposal of this rnatoriat.- _ P AGE 5 CONTINUED • : ! 1.41 .1 di. • .141114. SEPF ! 6-9A 15 : 19 FROM: ID: PAGE 5 PRO DUCT NAME ; CGRTROL 1S104 EFF'.'sCTIVE DATE: 11-JUL•-1997 4" ,ram 61:1.111 �+ ,-........, „, „ mow •. 14) TRANSPORT INFORMATION DOT HAZARD: Not Applicable UN / NA NUMBER: Not applicable DOT EMERGENCY RE,SL'ONS1 GUID #: Not applicable 15) REGULATORY INFORMATION T 3CA All components of this product are lis ed in the TSCA inventory. C ERCLA AND/OR SARA REPORTASL QUANTITY (RO): No regulated corntituent present at SHA thresholds F OOD AND DRUG ? DMMIINISTRA►TION: ' • All ingredients in this product are authorized for use as boiler water additives where the steakn produced may contact food. t.ARA SECTION 312 HAZARD CLASS Immediate(aaute:;Delayed(Chroric) 1;ARA SECTION 30: CHEMICALS: at OSHA thresholds No regulated cornt�t�ent Q t 1ARA SECTION 31.. CHEMICALS: No regulated coi:t;tituent present at QS1-IA thresholds C,i.IFQRNIA REG'.: LATORY INFORMATION j;ALIFORNIA SAFE :tR1NKING WATO AND TOXIC .1NFQRCEMENT A.: ; (PROPOSITION; 65) CHEMICALS PRESENT: • No regulated cons"..uent present at O$HA thresholds M:CHIGAN REGUL.:TOI Y I `IFORMATION No regulated cons7.1uent prescsnt at OSHA thresholds • PAGE 6 CONTINUED 1 1' t $:fI t w. . tl'/1101•1 SEP—LG-98 15:19 FROM: ID: PAGE 6 NO. Ily 15141.1 ,•M1 •••h.111 �f : 1II1•If Nile.1_ 4. II, Pit )duct Fi cts OPTiGUARDe MCP601 All -In -One Treatrmnt • Unique liquid femluiation provides complete boil er treatment in a single product • Blend of highly effective polymeric dispersan s with an organic sequestering agent • Superior control of deposit formation • Controls oxygen corrosion in feedwatet syst=m and boiler • Unique neutraliz▪ ing ni.iine blend provides a =c- tive system -wide protection • Available with drum-frae liquid dellveried throu ! h SetzDearborn CDS delivery services • Suitable for use in FDA/USDA- regulated plants DESCRIPTION AND USE OPTIGUARD MCP801 1i a unique liquid blend of an oxygen scavenger, internal, and condensate tr t- ment. It provides a comp'ate boiler system treatm nt in a single, easily fed, liquid product. OPTIGUARD MCP601 contains sodium sulfite control dissolved oxygen corrosion in the' prebo and boiler systems. Even with an effective deaeraF heater, sufficient dissolved oxygen can remain In feedwater to cause serous corrosion damage, high temperatures, oxyluan causes pitting, whic dangerous because of ita stationary, highly local' nature. if a day tank is u 3ed, the tank should be ered for best scavenging results. OPTIGUARD MCP601 also contains a unique bl of polymeric dispersants end an organic sequeste agent for control of soala formation on internal b, surfaces. It provides a complete internal'treat program that is highly effective In preventing the mation of both hardness and metal oxide deposits to ler ng e At is ed ov- nd ng iler ant for - The specific blend et- deposit control agent • in OPTIGUARD MCP601 maintains cleaner inte nal boiler surfaces through several meths lams. 'irst, the growth of scale-for;ning deposits isinhibit? 1 by r , I • •1 . I •I* 111.1.•13 Ilse 11:: distortion of the crystal lattice. Second, alteration of -the surface -change of.suspended particles prevents_ _.._ their attachment to other particles and to boiler sur- faces. The result is a cblloidal suspension -of 5mait particles which are readily removed by blowdown. In addition, the organic sequestering agent has the abili- ty to solubilize cationic contaminants, such as calci- um and magnesium. These are removed in soluble form in the blowdown. OPTIGUARD MCP601 contains a blend of neutral- izing amines with selected stability and volatility char- acteristics. When fed to the boiler, the amines rapidly volatilize with the steam and prevent corrosion by neutralizing carbonic acid in the condensate. The unique characteristics of this amine blend provide controlled protection at points of Initial condensation and in extended areas of complex condensate sys- tems. This reduces corrosion of both iron and copper surfaces, which extends equipment life and Increases the efficiency of heat exchange equipment, The return of corrosion products to the boiler is also reduced, significantly reducing the potential for scale formation. OPTIGUARD MC13601 is approved for use in FDA -or USDA -regulated plants where steam is used for ster- ilization or contacts food or food products. 1t is not approved for use in systems where the steam con- tacts milk or milk products. TREATMENT AND FEEDING REQUIREMENTS Proper treatment levels for OPTIGUARD MCP601 depend on many factors particular to a given installa- tion. The product should be used in accordance with control procedures that BetzDearbom establishes for a specific application. PIE] S78 9703 iiii 431997, Betz 0trborn Water Management Group. All rights reserved. ID: PAGE 7 SEP(-16-99 15:20 FROM: vv VV • OV :BETZDEARBOSiN FAX:80Q 468 7194 PAGE 2 Ilt13etzDearbor n, N EMERGENCY TELEPHONE H� ! - ...... t LT ACCIDENT): (800)-877-1940 (USAF 2) ‘'.1OMPOSITION / UUPORMATION ON iVCREDIENTS !tformation for specific product inuredierjts as required 1..S. OSHA NRAZARD COMMUNICATION� by �: a lditional sections of this MSps for STANDARD is listed. Refer to h izards of this formulation. our asse • rnent of the potential I IAZARDOUS INGREDIENTS: CAS# 100-37-8 7631-90-5 110-91-8 2809-21.-4 i f: ETZDEARBORN ATERIAL M'. fr." '1.- Z AFETY DATA SHEET E FFECTIWE DATE: 31-MAR-1997 F RINTED DATE: 01-JUN-1998 1 CHEMICAL PRODUCT AND COMPANY IDENTIFICATION ENTf FICATIt3N PRODUCT NAME p OPTIGUARD!MCp601 PRODUCT APPLICATION AREA: iNTERNA L BOILER TREATMENT. COMPANY ADDRESS: B 36Dearborn Inc, 4Sometton Road, .Trevos _P 453 Information phone number: (216 - 3 - • .. CEiEMICAL NAME DIE*YLAMINOETHANOL (DEAF) CombustiL irritant SODIUM 8 May be o sensitix le liquid; corrosive (eyes and skin); (respiratory) ; absorbed by skin SULFITE rrosiVe in aqueous solutions; irritant; r (skin and respiratory); may generate SO2 MORPEOL ?lammab liquid; corrosive; toxic (by skin absOrpt n) / potential liver and kidney toxin Cor ►ogolle ACID, (l..HYDROXYETIHYLIDINE) BIS- (HEDP le (eyes) ) . Nt component is considered to bb $ rcin Program, the International AgeR : for esearen by Cancer,the Natio or the Toxicology Oc :upatsanal Safety and Health A�dmj Ist ch ors cau cIno ens. ra#�on at OSHA A thresholds for • • • PAGE 1 ONTINUED i f • - SEPr- t 6-se 15 : 20 FROM: ID: PAGE 8 PRODUCT NAME : OPTIUARD MCP801 EFI; ECT1VE DATE: 31-MAR- i997 #' r «rq .pw• nDPf 12) ECOLOGICAL INFORMATION I. QUATIC TOXICOLOGY Fathead Minnow 98 Hour Static Screen with 48-Hour Renewal pH of test solutions was adjusted to d level of 6-9. 0% Mortality: 2000 mg/L Daphnia magna 48 Hour Static Screen! pH of test solutions was adjusted to a level of 6-9. 95% Mortality: 2000 mg/L. 0% Mortality: 1000 mg/L • 1-11ODEGRADATION COD (mg/gm): 228 Calculated TOC (mg/gm): 67 Calculated BOD-5 (mg/gm): 0 Calculated BOO-28 (mg/gm): 52 Calculated 1 I �•- 1 •.r Nil. 4r .ppl r..; 13) DISPOSAL CONSIDERATIONS` if this undiluted product is discarded as a waste, the US RCRA hazardous waste identification number is : Not applicable. Please be advised; however, that state and local requirements for waste disposal may be more restrictive ral reeu anon different federal regulations. Consult state g regarding the proper disposal of this material. MINNOW - 14) TRANSPORT INFORMATION • DOT HAZARD: Not Applicable UN / NA NUMBER: Not applicable DOT EMERGENCY RESPONSE GUI6B #: Not applicable PAGE 6 CONTINUED Corning Incorporated Telecommunications Products Division P.O. Box 1700 Concord, North Carolina 28026-1700 704-569-6000 April 28, 1998 Mr. Mark McIntire NC Dept. of Environment & Natural Resources Division of Water Quality Archdale Building (9th Floor) 512 North Salisbury Street Raleigh, North Carolina 27604 Dear Mr. McIntire: 1=t 2071 /cp,o0 CORNING As we had discussed, we will not begin operation of the force main to Outfall 003 until later than indicated in our NPDES Permit Application. Our current permit allows us to discharge non - contact cooling water to Outfall 001 until June 30, 1998. We had anticipated the force main being operational at that time. We have updated our Plant start-up schedule based on the most current business conditions. This new schedule allows for start-up of the force main and discharge to Outfall 003 by the end of October 1998. We are hereby requesting an extension of the period during which we can discharge non -contact cooling water to Outfall 001. Please extend the June 30, 1998 date to October 30, 1998. Enclosed is a check in the amount of $100.00 for this change to our permit. Thank -you for your assistance. If you require additional information, please contact me. Sincerely, CORNING INCORPORATED CL.ti Christy L. Hannan Environmental Control Engineer Concord Plant Enclosure Cc: Dave A. Goodrich Michael L. Parker Betsy Cutler Danny Smith Mike Hannan Project File