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HomeMy WebLinkAboutWQ0032016_Groundwater Monitoring Report (GW59) November 2019_20191231GW-59A COMPLIANCE REPORT FORM I Permit# Wn 003Z0I Y r ' (Suhmil one each monitoring period with G W--f(rtar) 1 Enter date monitoring results were due. ( Will this monitoring report (GW-59 and GW-SBA) YES NO be submitted after the established due date 2 Was any required information missing on the GW-59 report forms? YES rV1 IF the answer to question I or 2 is "YES", list in the space provided below the well identification number(s) and explain the problems encountered in obtaining the required information. 3 Are any of the monitor wells in need of repair or maintenance (damaged easing, unlocked or missing cap, missing YES NO identificntion plate, area overgrown, ate.)? If the ounce, a "Yes', canmcJ the Regional Office for guidance. 4 Are any monitored constituents equal to or above the established standards? ,YES O if the answer to question 4 is "NO", skip to section 8. IF the answer to question 4 is 'YES" list the affected wells individually with constituents) and concentrations) exceeding standards in the space provided below: JAN 0 3 2020 5 For the constituents identified in question 4 above, have standards been exceedgd; prevlolgdy'fotthe YES NO same constituent(s)in the same well(s) in the last two years? "" if the answer to question 5 is "NO", skip to section 8. If the answer to question 5 is "YES", list in the space provided below, each well with constituent(s) exceeding standards, concentrahon(s) reported, and sample collection date for each occurrence (for the last two years). 6 Are the monitoring wells listed in section 5located at or beyond the review boundary? YES NO If the answer is "YES", a groundwater qualityprobleer maybe occurring. CONTACT THE REGIONAL OFFICE IMMEDIATELY FOR GUIDANCE. lithe answer is "NO", monitoring wells maybe Improperly located; contact the Regional Office. 7 Is the permittee implementing previously approved actions required by the Division Involving this YES NO groundwater quality problem? If the answer to question 7 is "YES", describe those actions in the space provided below. If the answer to question? is "NO", contact the Regional Office within 90 days; an evaluation may required to determine the impact the waste disposal system is having at the review and compllance !' . boundaries surrounding this facility. Failure m do so maysubiect the penalties to a Nafice of Violatibn fines, andlorpenables. t:'r r) - aS f J6 N' g The person completing this portion(GW-59A) cfthe monitoring report should sign below and subrgJr�gllris form with GW-59 forms for required wells to the address provided at the tap of the current GW-59Yarm _, N pve ihf Pon was, vat a tiob Is-- No ' rt 'Bplp Ian ROP0 'GW'�9 lor-t Awor iwa - - Nlyr 12,31 �15 Signature of penalties (or Authorized Agent) Dare GA-59A 12/8/2003 / ) � . / ■!2! 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D, Asheville, NC 28804 (82a)254.7176 Project: ROSE HILL MW I1-12-19 Pace Project No.: 92453264 Sample: MW-1 Lab ID: 92453264001 Collected: 11/12/191150 Received: 11112/1913:36 Ma9iz: Water Parameters Results Units Report Limit OF Prepared Analyzed CAS No. Qual Monitoring Well Data Analytical Method: Collected By Joel 1 11/12/1911.50 Schlaudt Collected Date 11/12/19 1 11/1211911:50 Collected Time 11:50 1 1111211911:50 pH 8.4 Sid. Units 1 11/12I1911:50 Temperature 13.3 deg C 1 11/12/191150 Static Water Level 32.12 feet 1 11/12/19 11:50 Specific Conductance 46.5 umhas/cm 1 11/1211911:60 Turbidity 405.6 NTU 1 1114211911:50 Odor NO 1 11 IWI)11:50 Appearance Orange 1 1111211911:50 2540C Tatal Dissolved Solids Analytical Method: SM 254OC-2011 Total Dissolved Solids 73.0 mg/L 25.0 1 11//5/1908:05 9040 pH Analytical Method: EPA9040C pH at 25 Degrees C 6.3 Std. Units 0.10 1 11/2411916:38 H3 MBIO 9222D Fecal Collform AVL Analytical Method: SM 9222D-2006 Preparation Method; SM 9222D-2006 Fecal Colifonos NO CFU/100 mL 10.0 10 1111211917:37 11/13I1915:47 350.1 Ammonia Analytical Method: EPA 350.1 Rev 2.01993 Nlhogen,Ammonia NO mg/L 0.10 1 11121/1906:38 7664-41-7 363.2 Nitrogen, NO2/NO3 unpres Analytical Method: EPA 353.2 Rev 2.01993 Nitrogen, Nitrate NO mg/L 0.040 1 11/131190021 14797-55-8 365.1 Phosphorus, Total Analytical Method: EPA 365.1 Rev 2.01993 Preparation Method: EPA 365.1 Rev 2.01993 Phosphorus 0.64 mg/L 0.050 1 1111311919:03 1111311922:15 7723-14-0 4500 Chloride Analytical Method: SM 4500-CI-E-2011 Chloride 3.4 mg/L 1.0 1 11/1511920:25 16887-006 5310E TOC Analytical Method: SM 531013-2011 Total Organic Carbon ND mg/L 1.0 1 11122/1901:07 7440-44-0 REPORT OF LABORATORY ANALYSIS This.,ad,hell not be napmduced, except in full, Data 1010/201905:59PM witnouu the wdnen..rent of Pace Analytical service, U-C. Page 4 of 41 Pace Analytical Services, LL¢ lceklalAcal' 2225 RiverDr. Asheville, NC G 28 28aW WWN.Weele89smo (828)2541178 ANALYTICAL RESULTS Project: ROSE HILL MW I1-12-19 Pace Project No.: 92453264 Sample: MW-2 Lab ID: 9US3264002 Collected 11/121191040 Received: 11/12/191336 Matdx: Wafer Parameters Results Units Report Limit OF Prepared Analyzed CAS No. Oual Monitoring Well Dntn Analytical Method Collected By Joel 1 11h211910:40 Schlaudl Collected Date 11M2/19 1 1111W1910:40 Collected lime 10:40 1 11/12/1910:40 pH 5.6 Son. Units 1 11/12/19 10:40 Temperature 12.5 deg C 1 11/1211910:40 Static Water Level 12.12 feel 1 11112/1910.40 Specific Conductance 21.9 umhos/cm 1 11112/1910.49 Turbidity 668.8 NTU 1 11/12/1910:40 Odor NO 1 11/12/19 10:40 Appearance Orange 1 11/1211910:40 6200E MSV Analytical Method: SM 6200B Benzene NO ug/L 0.50 1 1112311911:36 71-43-2 Bromoberinne ND uglL 0.50 1 11/23/1911:36 108-86-1 Bromochloromelhane NO ugll- 0.50 1 1112311911:36 74-97-5 Bromodichloromethene NO ug/L 0.50 1 11/23/191136 ]5-2]-4 Bromoform NO ug/L 0.50 1 11/2311911:38 75-25-2 Bromamethane NO ug/L 5.0 1 11123/1911:W 74-63-9 n-Butylbenzene NO ug/L 0.50 1 11/2W1911:36 104-51-8 seo-Butylbenzene NO ugA- 0.50 1 11/2311911:36 13698-8 tart-Butylbenzene NO ug/L 0.50 1 1112311911:36 98-06-6 Carbon tetrachloride ND ug/L 0.50 1 112311911:36 56-23-5 Chlorobenzene NO uglL 0.50 1 11/2311911:36 108-90-7 CMoroethane NO ugll- 1.0 1 1IQ311911:36 75-00S Chloroform NO ug/I. 0.50 1 11123/1911:36 67-66-3 Chloromethane ND ug/L 1.0 1 11/23/1911:36 74-873 2-Chlorololuene NO ug/L 0.50 1 1123/19 11:36 95-493 4-Chlorotoluene NO ug/L 0.50 1 1123/19 11:36 10643-4 1,2-Dibromo-3-chlompropane NO ug/L 1.0 1 112311911:36 95-12-8 Dlbromochloromelhane ND ug1L 0.50 1 11/2W1911:36 12448-1 1,2-Dibmmoethane(EDB) NO ug/L 0.50 1 11123/1911:W 106-93-4 Dibromomethane NO ug/L 0.50 1 11123/1911:36 74-95-3 1,2-Dichlorobenzene NO ug/L 0.50 1 11/2NI911:36 95-50-1 1,3-Dichlorobenzene NO ug/L 0.50 1 1123/191136 541-93-1 1,4-Dichlorobenzene ND ug/L 0.50 1 1la31191136 103467 Dichlorodiguommethene NO ug/L 0.50 1 112311911:36 75-71-8 1,1-Dichloroethane NO ug/L 0.50 1 11/2311911:36 75-34-3 1,2-Dichloroethane NO ug/L 0.50 1 111231191136 107-06-2 1,1-Dichloroethene NO u9I1- 0.50 1 11123/1911:36 75-364 cis-1,2-Dichloroethene NO ug/L 0.50 1 11/23/1911:36 156-59-2 trans-1,2-Dichloroethene NO ug1L 0.50 1 1112311911:36 156-60-5 1,2-Dlchloropropane NO uglL 0.50 1 1123/191136 7B-B7-5 1,3-Dlchloropropane NO ugll- 0.50 1 11MI191136 14228A 2,2-Dichloropropane NO ugll- 0.50 1 111231191136 594-20-7 1,1-Dichlcropmpene NO ug/L 0.50 1 1123/191136 56358-6 cis-1,3-Dichlompropene NO ug/L 0.50 1 1112311911:36 10061-01-5 REPORT OF LABORATORY ANALYSIS This repod shall nmba repretlucetl, except in full, Data 12/10/20190559PM withautiM1e wMkn wnsentof Pecs AnalyBcal Services, LLC. Page 5 of 41 Paw Analylaar Services, LLC aceAnaoytical a 2225 Rlverxltle or wwx.paam AshaAlle, NC 28804 (828)250.7176 I ANALYTICAL RESULTS Project: ROSE HILL MW I1-12-19 Pace Project No.: 92453264 Sample: MW-2 Lab ID: 92453264002 Collected: 11/1211910:40 Received: 11112/1913:36 Matrix: Water Parameters Results Units Repor§Limit DF Prepared Analyzed CAS No. Qual 620UB MSV Analytical Method: SM 6200B trans-1,3-Dichloropropene ND ug/L 0.50 1 1112311911:36 10061-026 Diisopropyl ether ND ug/L 0.50 1 1112311911:36 108-20-3 Ethylberaene ND ug/L 0.50 1 1123/1911:36 100-414 Hexachloro-1,3-butadlene ND ug/L 2.0 1 112311911:36 87-68-3 Isopmpylbemene(Cumene) ND ug/L 0.50 1 1112311911:36 9&826 Methylene Chloride ND ug/L 2.0 1 1123/1911:36 75-09-2 Methyl -ten -butyl ether ND ug/L 0.50 1 1123/1911:36 1634-04-4 Naphthalene ND ug/L 2.0 1 11/2311911:36 91-20-3 n-Propylbemene ND ug/L 0.50 1 11123/1911:36 103-65-1 Styrene ND uglL 0.50 1 1123/1911:36 100-42-5 1,1,1,2-Telmchlomethane ND uglL 0.50 1 1123/1911:36 63&2M 1, 1,2,2-Tetmchloroethane ND ug/L 0.50 1 1112311911:36 79-34-5 Tetrachloraathene ND ug/L 0.50 1 1112311911:36 127-18-4 Toluene ND ug/L 0.50 1 11/231911:36 108-88-3 1,2,&Trlohloroben2ene ND ug/L 2.0 1 1123/1911:36 87-61-6 1,2,4-Trichlohmen2ene ND ug/L 2.0 1 11/2311911:36 120-82-1 1,1,1-Trichloroethane ND ug/L 0.50 1 111231191135 71-5541 1,1,2-Trichloroethane ND ug/L 0.50 1 11/2T1911:36 79-006 Trichlomethene ND ug/L 0.50 1 11QW1911:36 79-01-6 Tdchloro0uoromethane ND ug/L 1.0 1 1123/1811:36 75-694 1,2,3-Tdchloropropane ND ug/L 0.50 1 11123/1911:36 96-184 1,2,4Trimethylbename ND ugl- 0.50 1 1112311911:W 9"36 1,3,5-Trimethylbencene ND ug/L 0.50 1 11123/1911:W 108-67-8 Vinyl chloride ND ug/L 1.0 1 1123/1911:36 75-01-4 m5p-Xylene ND ug/L 1.0 1 11/23/191136 179601-23-1 o-%ylene ND ug/L 0.50 1 11/2311911:36 95-47-6 Surrogates 1,2-Dichloroetharil(S) 98 % 70-130 1 1112311911:36 1706&074) 4-Bremoluorebemene(9) 100 % 70-130 1 1123/1911:36 460-00-4 Toluene-d8 (S) 100 % 70-130 1 1123/1911:36 2037-26-5 2640C Thal Dissolved Solids Analytical Method: SM 254OC-2011 Total Dissolved Solitls 36.0 mg/L 25.0 1 11115/1908:05 9040 pH Analytical Method: EPA 9940C pH at 25 Degrees C 5.2 Std. Units 0.10 1 1112411916:32 H3 MBIO 9222D Fecal California AVL Analytical Method: SM 9222D-2006 Preparation Method: SM 9222D-2006 Fecal Conferral 50.0 CFU/100 mL 1.0 1 11/1211917:37 11/13/191547 350.1 Ammonia Analytical Method: EPA 350.1 Rev 2.01993 Nitrogen, Ammonia ND mglL 0.10 1 1112111905:40 766441-7 353.2 Nitrogen, NOVN03 unpres Analytical Method: EPA353.2 Rev 2.01993 Nitrogen, Nitrate 0.41 mg/L 0.040 1 111131190019 14797-55-8 REPORT OF LABORATORY ANALYSIS This repair shall not be reproduced, except in full. Dale: 121101201906:59 PM hout the wnden careen of Paw Analytical Services,LLC. Page 6 of 41 ceAnalyiical wwx.patelebsson ANALYTICAL RESULTS Pace Analytical Services, LLC 2225 Riverside Dr. AeM1evi116. NC 28804 (828)254-7176 Project: ROSE HILL MW 11-12-19 Pace Project No.: 92453264 Sample: MW-2 Lab ID: 92453264002 Collected: 111lV19 WAD Received: HAWS 13:36 Matrix: Water Parameters Results Units Report Limit OF Prepared Analyzed CAS No. Oual 365.1 Phosphorus, Total Analytical Method: EPA 365.1 Rev 2.01993 Preparation Method: EPA 365.1 Rev 2.01993 Phosphorus 0.38 mg/L 0.050 1 11113/1919:03 11113/1922:16 7723-14-0 4500 Chloride Analytical Method: SM 4500-CI-E2011 Chloride 2.1 mglL 1.0 1 11/15I1920:28 16887-00-6 5310B MC Analytical Method: SM 531OB-2011 Total Organic Carbon NO mg/L 1.0 1 11P22/1901:22 7440-44-0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/10/201905:59 PM wimout the written concert of Pace Analytical Services,LLC. Page 7 of 41 Pace Analytic an services, LLC de DC �aceAnalytical' ASM1eville, NC 2225 aNC 2BaW04 waxpanlaea.eon (828j254-7178 ANALYTICAL RESULTS Project: ROSE HILL MW 11-12-19 Pace Project No.: 92453264 Sample: MW-313 Lab ID: ONS3264003 Collected: 11112/1909.45 Recelwd: 11112/1913:36 Matdx: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual Monitoring Well Data Analytical Method: Collected By Joel 1 11/12119 09:45 Schlaudt Collected Date 11/12119 1 11/12/19 09:45 Collected Time 09:45 1 1D121i909:45 pH 8.6 Bid. Unite 1 1111211909:45 Temperature 13.0 deg 1 11/12I1909:45 Slatio Water Level 3.90 feet 1 11/12/19 09:45 Specific Conductance 'H8.6 undos/cm 1 11/12/19 09.45 Turbidity 206.4 NTU 1 11/12119 09:45 Odor ND 1 11112/1909:45 Appearance Clear/ 1 11/12/19 09:45 orange 6200B MSV Analytical Method: SM 6200B Benzene ND ug/L 0.50 1 11a3/1911:54 71-43-2 Bromobenzene ND ug/L 0.50 1 11/23/1911:64 108-86-1 Bromochloromethane NO ug/L 0.50 1 1112311911:64 74-97-5 Bromodichloromethane ND ug/L 0.50 1 11/23119 11:54 75-27-4 Bromoform ND ug/L 0.50 1 11/23/19 1154 75-25-2 Bramomethane ND ug/L 5.0 1 11/23/1911:54 74-83-9 n-Bulylbenzene ND ug/L 0.50 1 11123/19 11:54 104-51-8 sec-Bulylbenzene ND uglL 0.50 1 1112311911:54 135-98-8 tart-Bulylbenzene ND uglL 0.50 1 11/2311911:54 98-06-6 Carbon tetrachloride ND ug/L 0.50 1 11a3/19 11:54 56-23-5 Chloroberrome ND ug/L 0.50 1 1123/1911:54 108-9D-7 Chloroethane ND ug/L 1.0 1 11123/1911:54 75-00-3 Chloroform ND ug/L 0.50 1 11/23119 11:54 67-66-3 Chloroundinu a NO ug/L 1.0 1 1123/191154 74-87-3 2-Chlorotoluene ND ug/L 0.50 1 112Xli) 11:54 95-49-8 4-Chlorotoluene ND ug/L 0.50 1 1123/1911:54 108434 1,2-Dlbromo-3-chloropmpane ND ug/L 1.0 1 11/23/19 11:54 96L12-8 Dibromochloromethane ND ug/L 0.50 1 11123119 1154 124-48-1 1,2-Dibromoethene(EDE) ND ug/L 0.50 1 11/23119 11:54 106-93-4 Dibromomelhane ND ug/L 0.50 1 1123/1911:54 74-95-3 1,2-Dichlorobenzene ND ug/L 0.50 1 11/23/19 11:54 95-50-1 1,3-Dichlorobenzene ND uyl- 0.50 1 11123/19 11:54 541-73-1 1,4-Dichlorobenzene ND ug/L 0.50 1 1112311911:54 106-46-7 Dichlorodl9uoromethane ND ug/L 0.50 1 lla3H9 11:54 75-71-8 1,1-Dichloroethane ND ug/L 0.50 1 11aWl!)11:54 75-34-3 1,2-Dichloroethane NO ug/L 0.50 1 11,2NI911:54 107-06-2 1,1-Dichloroethane ND ug/L 0.50 1 11/23/19 11:54 75-354 cis-1,2-Dichloroethene ND uglL 0.50 1 11/23/19 11:54 15659-2 trans-1,2-Dichlaroethene ND uglL 0.50 1 11/23119 11:54 156-60-5 1,2-Dichloropropane ND ug]L 0.50 1 T1/23/19 11:54 78.87-5 1,3-Dichloropropane ND ug/L 0.50 1 11/23/19 11:54 142-28-9 2,2-Dichloropropane ND ug/L 0.50 1 11/23/19 11:54 594-20-7 1,1-Dichloropropane ND ug/L 0.50 1 1123/1911:54 563-SM REPORT OF LABORATORY ANALYSIS cola reVenahall not be ra,ruauced, except In for, Date: 12110201905:59 PM without the dden consent of Pace Analytical Services, LLC. Page 8 of 41 Pace Analytical services, LLC AaSeyilleNO Y035 R, NC 28�"Analytical' 04 VIIVW.fB[BIBE&MIII (020)254-7176-]1]6 ANALYTICAL RESULTS Project: ROSE HILL MW 11-12-19 Pace Project No.: 924532M Sample: Msi Lab ID: 92453264003 Collected 11MV1909:45 Received: 11112119 13:36 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 6200B MSV Analytical Method: SM 6200B ds-1,3-Dichloropropene NO uglL 0.50 1 1123/1911:IN 10061-015 trans-1,3-Dichloropropene ND ug/L 0.50 1 11123/1911:54 10061-02-6 Dlisopropyl ether NO uglL 0.50 1 1123/1911:54 108-20-3 Ethylbenzene NO ug/L 0.50 1 1123/1911:54 100414 Hexachloro-1,S-butadiane NO ug/L 2.0 1 11/23/19 11:54 87-68-3 Isopropylbenzene(Cumene) NO uglL 0.50 1 1112311911:54 98-82-8 Methylene Chloride NO ug/L 2.0 1 11/23119 11:54 75-09-2 Methyl -tart -butyl ether NO ug/L 0.50 1 1123/19 11:54 1634-04-4 Naphthalene NO uglL 2.0 1 11/2T1911:54 91-20-3 n-Propylbenzene NO ug/L 0.50 1 11123/19 11:54 103-65-1 Styrene NO ug/L 0.50 1 11/2311911:54 100-42-5 1,1,1,2-Tetmchloroethane NO uglL 0.50 1 1123/1911:54 630-2&6 1,1,2,2-Tetmchloroethane ND ug/L 0.50 1 _ 1123/19 11:54 79-34-5 Tetrachloroelhene NO ug/L 0.50 1 1123/1911:54 127-18-4 Toluene NO ug/L 0.50 1 11123/1911:54 108-88-3 - 1,2,3-Trichlorobenzene NO ug/1. 2.0 1 11/23119 11:54 87-61-6 1,2+Trichlorobeneene NO ug/L 2.0 1 11/23/19 11:54 120-82-1 1,1,1-Trichlomelhane NO ug/L 0.50 1 11/23/19 1154 71-55-6 1,1,2-Tdchloroethane NO ullL 0.50 1 1112311911:54 79-00-5 Trichlomethene NO ug/L 0.50 1 1112311911:64 79-01-6 Trichlorollu mosithane NO ug/L 1.0 1 1112311911:54 76-69-4 1,2,3-Trichlompropane NO uglL 0.50 1 11/23119 11:54 96-18-4 1,2,4-Trimelhylbenzene NO ug/L 0.50 1 11/23/19 1154 95-83-B 1,3,5-Trimethylbenzene NO ug/L 0.50 1 11/2311911:54 108l Vinyl chloride ND ug/L 1.0 1 11/2311911:54 75-014 m&p-Xylene NO ug/L 1.0 1 1112311911:64 179601-231 o-Xylene NO ug/L 0.50 1 11/2311911:54 95-47-6 Senegafes 12-Dichloroethane-d4(S) 96 % 70-130 1 1123/1911:54 17060-07-0 4-Bromo9uorobenzene (9) 97 % 70-130 1 11123/1911:54 46MO-4 Toluene-d8(S) 100 % 70-130 1 1112311911:54 2037-2&5 2640C Total Dissolved Solids Analytical Method: SM 2MOC-2011 Total Oissoloved Solid. 100 mglL 25.0 1 11/15/1908:06 9040 pH Analytical Method: EPA 9040C pH at 25 Degrees C 8.2 Std. Units 0.10 1 1112411916:27 H3 MBIO 9222D Fecal Coliform AVL Analytical Method: SM 92220-2006 Preparation Method: SM 92220-2006 Fecal Colifonns 44.0 CFU/100 mL 1.0 1 11112/1916:43 11/1311915.47 350.1 Ammonia Analytical Method: EPA 350.1 Rev 2.01993 Nitrogen, Ammonia NO mg/L 0.10 1 11121/19 06:41 7664-41-7 353.2 Nitrogen, N021NO3 Impose Analytical Method: EPA353.2 Rev 2.01993 Nitrogen, Nitrate 1.0 mg/L 0.040 1 11/13/19 00:16 14797-55-8 REPORT OF LABORATORY ANALYSIS This report shall not be reproduwd, sewpt in mil, Date: 12110201905:59 PM without the wnten consent or Pace Analytical Services,LLC. Page 9 of 41 aceAnalytical mvratp udlibamm ANALYTICAL RESULTS Pace Analytical Services, LLa 2225 Riverside or. Asheville, NO 28804 (828)254-9176 Project: ROSE HILL MW 11-12-19 Pace Project No.: 9240264 Sample: MWSB Lab ID: 92453264003 Collected: 11/12/1909:45 Received: 11112/1913:36 Matrix: Water Parameters Results Units Report Limit OF Prepared Analyzed CAS No. Oual 365A Phosphorus, Total Analytical Method: EPA 385.1 Rev 2.01993 Preparation Method: EPA 365.1 Rev 2.01993 Phosphorus 0.96 uni 0.050 1 1111311919:03 11113/1922:17 7723-14-0 4500 Chlorlde Analytical Method: SM 4501 Chloride 5.8 mg/L 1.0 1 11/15/19 2029 16887-00-6 5310B TOC Analytical Method: SM 531 OB-2011 Total Organic Carbon 1.1 mg/L 1.0 1 11/22/10 D1:37 7,ull) 4-D REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except In full, Date: 12/10/2019 05:69 PM without thowrilten consent of P. AnalyBwl Sai LLC. Page 10 of 41 /l� ^! Pace Analytical services, LLD =At aal[U 2226 Riverside Di, Asheville, NC 2e804 wwaPsisheuaa ANALYTICAL RESULTS Project: ROSE HILL MW I1-12-19 Pace Project No.: 92453264 Sample: III Reaample Lab ID: 92453264004 Collected : Received: 1112611911:05 Matrix: Water Parameters Monitoring Well Data Collected By Collected Data Collected Time pit Temperature Static Water Level Specific Conductance Turbidity Appearance Date: 12/10/2019 05:59 PM Results Unit. Report Limit DF Prepared Anall CAS No. Coal Analytical Method: Joel 1 11/2611913:35 Sclaudt 11/26/19 1 11/26/1913:35 13:35 1 1112611913:35 6.5 Std. Units 1 1112611913:35 15.3 deg C 1 11/26(1913:35 32.60 feet 1 11/2611913:35 49.4 umhos/cm 1 11/2611913:35 362.2 all 1 1112611913:35 Cloudy 1 11/2611913:35 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, withoutthe written consent of Pace Analytical Services. I.I.C. Page 11 of 41 Pace Analytical services, LLL �aceAna"cafo 225 Rive side Or wwwpaaala8a.pam Asheville, NO 28804 (828)25F7176 ANALYTICAL RESULTS Project: ROSE HILL MW I1-12-19 Pace Project No.: 92453264 Sample: MW-1 LablD: 92455269001 Collected: 1112611913:35 Received: 11/2611914:15 Matrix: Water Parameters Results units Report Limit DF Prepared Analyzed CAS No. Dual 6200B MSV Analytical Method: SM 6200B Benzene NO ug/L 0.50 1 12/09/19 1316 71-43-2 Bromobenzene NO ug/L 0.50 1 12/09/1913:16 108-86-1 Bromochloromethane NO ug/L 0.50 1 12/0911913:16 74-97-5 Bromotlichloromethane NO ug/L 0.50 1 12109/1913:16 75-27-4 Bromefman NO ugli- 0.50 1 1210911913:16 75-25-2 Bromomethane NO ug/L 5.0 1 12/0911913:16 74-83-9 n-Butylbenzene NO ug/L 0.50 1 12109/1913:16 104-51-8 sec-Butylbeneene NO ug/L 0.50 1 12I0911913:16 135-98-8 tart-Butylbenzene NO ug/L 0.50 1 12f09/1913:16 98-06-6 Carbon tetrachloride NO ug/L 0.50 1 12109/1913:16 56-23-5 Chlorobenzene NO ug/L 0.50 1 121G911913:16 108-90-7 Chloroethane NO ugA- 1.0 1 1VOW1913:16 75-003 Chlmofoon NO ug/L 0.50 1 12/09/1913:16 67-66-3 Chloromethane NO ug/L 1.0 1 1210911913:16 74-87-3 2-Chlomtoluene NO ug/L 0.50 1 12419/1913:16 95-49-8 4-Chlorousuene NO ug/L 0.50 1 1VO911913:16 10543-4 1,2-1)lbromo-e-chloropropane NO ug/L 1.0 1 1210911913:16 96-12-8 Dibromochloromethane NO ug/L 0.50 1 1W0911913:16 124-48-1 1,2-Dibromoethane(EDS) NO ug/L 0.50 1 1VO911913:16 106-93-4 Dlbromomethane NO ug/L 0.50 1 1VO911913:16 74-95-3 1,2-Dichlorobenzene NO ug/L 0.50 1 12109/1913:16 95-50-1 1,3-Dichl.robenzene NO uid- 0.50 1 1210911913:16 541-73-1 1,4-Dichlorobenzene NO ug/L 0.50 1 12/09/1913:16 10046-7 Dichio odi0umomethane NO ug/L 0.50 1 12f09/1913:16 75-71-8 1,1-Dichloroethane NO ug/L 0.50 1 12/09/1913:16 75-34-3 1,2-Dichloroethane NO ug/L 0.50 1 1210911913:16 107-06-2 1,1-Dichloroethane NO uWL 0.50 1 1VO911913:16 75-364 cis-1,2-Dichloroethene NO ug/L 0.50 1 1V0911913:16 156-59-2 trans-1,2-Dlchlomethene NO ug/L 0.50 1 1210911913:16 156-60-5 1,2-Dichloropropane NO ug/L 0.50 1 1210911913:16 78-87-5 1,3-Dlchloropropane NO uglL 0.50 1 12RKV1913:16 142-28-9 2,2-Dlchloropromme NO ug/L 0.50 1 12/09/1913:16 594-20-7 1,1-Dlchloropmpene NO ug/L 0.50 1 12/09/1913:16 563-SM cisA 3-DiOloropropene NO ug/L 0.50 1 1210911913:16 10061-01-5 trans-1,3-Dichioropropene NO ug/L 0.50 1 12109/1913:16 10061-02-S Dilsopropyl ether NO ug/L 0.60 1 12109/1913:16 108-20-3 Ethylbenzene NO ug/L 0.50 1 1009/1913:16 100414 Hexachloro-1,3-butadiene NO ug/L 2.0 1 1210911913:16 87-68-3 I80popylbenzene(Comers) NO ug/L 0.50 1 12/09/1913:16 98-92-8 Methylene Chloride NO ug/L 2.0 1 12/09/1913:16 75-09-2 Methyl-tert-butyl ether NO ug/L 0.50 1 12109/1913:16 1634-04-4 Naphthalene NO Ug/L 2.0 1 12109/19 1316 91-20-3 n-Propylbenzene NO ugA- 0.50 1 10OW1913:16 103-65-1 Styrene NO ug/L 0.50 1 12/09/1913:16 100-42-5 1,1,1,2-Tetmchlaroethane NO ug/L 0.50 1 1210911913:16 630-20-6 1,1,2,2-Tetrachloroethene NO ug/L 0.50 1 1D09/1913:16 79-34-5 Tetrachloroethene NO ug/L 0.50 1 12109/1913:16 127-18-4 REPORT OF LABORATORY ANALYSIS This repel shall not be reproduced except In full. Date: 12110/201905:59 PM wl0oul@e w4nen consent of Pecs AnelyBcel Services, lLC. Page 12 of 41 awnalytkal o onow,pMBIBbt20R ANALYTICAL RESULTS Pace Analytical bervicea, LLc 2225 RheMide Dr Asheville, NC 20804 (820)25q 7176 Project: ROSE HILL MW 11-12-19 Pace Project No.: 92453264 Sample: MIN-1 Lab ID: 92455259001 Collected: 11/26/1913:35 Received: ll26/1914:15 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Oual 0200E MSV Analytical Method: SM 6200B Toluene ND ug/L 0.50 1 1VO911913:16 108-88-3 1,2,3-Tdchlorobenzene ND ug/L 2.0 1 12/09/19 13:16 87-61-6 12,4-Tdchlorobenzene ND uglL 2.0 1 12/09/1913:16 120-82-1 11,1-Trichlaroethane ND ug/L 0.50 1 1VO9119 13:16 71-555 1,1,2-Trichlomethane ND ug/L 0.50 1 12/09/19 13:16 79-005 Trichloroethene ND ug/L 0.50 1 12/091913a6 79-01-6 Trichlore0uommethane ND ug/L 1.0 1 12109/19 13:16 75-69-4 1,2,&Trichloropropane ND ug/L 0.50 1 1VO911913:16 96-18-4 1,2,4-Trlmethylbenzene ND ug/L 0.50 1 12/09/19 13:16 95-63-6 1,3,5-Trlmethylbenzene ND ug/L 0.50 1 12/09119 13:16 108-67-8 Vinyl chloride ND ug/L 1.0 1 12109/1913:16 75-014 m&p-Xylene ND ug/L 1.0 1 - 12109/1913: 16 179601-23-1 0-Xylene ND ug/L 0.50 1 IV0911913:16 95-47-6 Surrogates 1,2-Dichloroethane-d4(S) 100 % 70-130 1 12/0911913:16 17060-07-0 4-Bromc0uorobenzene(3) 100 % 70-130 1 1VO911913:16 460-00-4 Toluene-d8 (S) 97 % 70-130 1 1VO911913:16 2037-265 REPORT OF LABORATORY ANALYSIS This report shall not be reprecuc M, except in full. Date: 12/101201905:59 PM without the wdben consent 0 Pace Analytical Services, U.C. Page 13 of 41 aceAnafytical MNW.)itddUd20N ( December 10, 2019 Mr. Robert Barr RPB Systems Inc. P.O. Box 1325 Asheville, NC 28802 RE: Project: ROSE HILL MW 11-12-19 Pace Project No.: 92453264 Pau Analytical l arvlcea, LLC 2225 Roared. Dr. Ash -ill., NC 28804 (82a)25F]P6 Dear Mr. Barr: Enclosed are the analytical results for sample(s) received by the laboratory between November 12, 2019 and November 26, 2019. The results relate only to the samples included in this report. Results reported herein conform to the most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. If you have any questions concerning this report, please feel free to contact me. Sincerely, Chris Derouen christopher.derouen@pacelabs.com (828)254-7176 Project Manager Enclosures REPORT OF LABORATORY ANALYSIS This report shall not be reprotlucea, except in full, 9 without the written censent of Pece Anelylicel5ervius, LLC. Page 1 of 41 (�;ZeAnalytical' awa.p¢rleeusm Project: ROSE HILL MW I1-12-19 Pace Project No.: 92453264 Pace Analytical Stemless Charlotte 9800 Kincey Ave. Ste 100, Huntersville, NC 28078 LouisianaMFLAP Certification # IAt 70028 North Carolina Drinking Water Certification #: 37706 North Carolina Field Services Certification #: 5342 North Carolina Wastewater Certification #: 12 Pace Analytical Services Asheville 2225 Riverside Drive, Asheville, NC 28804 Florida/NEIAP Certification #: E87648 Massachusetts Certification #: M-NC030 North Carolina Drinking Water Certification #: 37712 CERTIFICATIONS South Caroline Certification #: 99006001 Flonda)NELAP Certification #: E87627 Kentucky UST Certification #: 84 VaginiaNELAP Certification #: 460221 North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001 VirginiaNELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Pace Analytical Sionfin a, LLC .25 Riverside Dr. Asheville, NC 28804 (82e)254-1176 Page 2 of 41 aceAnalytical www.pemellcors SAMPLE ANALYTE COUNT Pace Analytical 9ervicee, LLC 2225 Riverside or. Asheville, NC 28804 (B28)2541176 Project: Pace Project No.: ROSE HILL MW I1-12-19 92453264 Analytes Lab ID Sample ID Method Analysis Reported Laboratory 92453264001 I'll SM 2540C-2011 CJL 1 PASI-A EPA9040C SMK 1 PASI-A SM 9222D-2006 ECH 1 PASI-A EPA 350.1 Rev 2.01993 MFO 1 PASI-A EPA 353.2 Rev 2.01993 MFO 1 PASI-A EPA 365.1 Rev 2.01993 MDW 1 PASI-A SM 4500-CI-E-2011 GC 1 PASI-A SM 531 OB-2011 ECH i PASI-A 9US3264002 fill SM 6200B CL 63 PASI-C SM 254OC-2011 CJL 1 PASI-A EPA9040C SMK 1 PASI-A SM 92221D-2006 ECH 1 PASI-A EPA 350.1 Rev 2.01993 MFO 1 PASI-A EPA 353.2 Rev 2.01993 MFO 1 PASI-A EPA 365.1 Rev 2.01993 MDW 1 PASI-A SM 4501 GC 1 PASI-A SM 531IDS -2011 ECH 1 PASI-A 92463284003 fill SM 6200B CL 63 PASI-C SM 254OC-2011 CJL 1 PASI-A EPA9040C SMK 1 PASI-A SM 922213-2006 ECH 1 PASI-A EPA 350.1 Rev 2.01993 MFO i PASI-A EPA 353.2 Rev 2.01993 MFO 1 PASI-A EPA 365.1 Rev 201993 MDW 1 PASI-A SM 4500-CI-E-2011 GC 1 PASI-A SM 531OB-2011 ECH 1 PASI-A 92455259001 fill SM 6200B CL 63 PASI-C REPORT OF LABORATORY ANALYSIS This hani shall not be reproduced, except in full, without the written consent or Pace Analytical services, LLO. Page 3 of 41 aceAnalytical wwx.whalsbarom ANALYTICAL RESULTS Pace Analytic al services, LLC 2225 Riversitle D,. As,eville, NC 28804 (828)254 7176 Project: ROSE HILL MW 11-12-19 Pace Project No.: 92453264 Sample: MW-1 LablID: 92453264001 Collected11/1211 91150 Received: 1111211913:36 Matrix: Water Parameters Results Units Report Limit OF Prepared Analyzed CAS No. Oual Monitoring Well Data Analytical Method: Collected By Joel 1 11/12/19 11:50 Schla alt Collected Date 11/12/19 1 11/12119 11:50 Collected Time 11:50 1 1111211911:50 pH 6.4 Bid. Units 1 11112/19 11:50 Temperature 13.3 cap C 1 11/12/19 11'.50 Static Water Level 32.12 feet 1 11/12/19 11:50 Specific Conductance 46.5 umhra/cm 1 11/12119 11:50 Turbidity 405.6 NTU 1 11/12/19 11:50 Odor NO 1 1111211911:50 Appearance Orange 1 11/121191150 2540C Total Dissolved Solids Analytical Method: SM 254OC-2011 Total Dissolved Solids 73.0 u lL 25.0 1 11/15119 08:05 9040 pH Analytical Method: EPA 9040C pH at 25 Degrees C 6.3 Sm. Units 0.10 1 11/24/1916 38 H3 MBIO 9222D Fecal Coliform AVE Analytical Method: SM 9222D-2006 Preparation Method: SM 9222D-2006 Fecal Chileans NO CFU1100 mL 10.0 10 11/1211917:37 11/1311915:47 350.1 Ammonia Analytical Method: EPA 350.1 Rev 2.01993 Nitrogen, Ammonia ND al 0.10 1 11/21/1906:38 7664-41-7 353.2 Nitrogen, N021NO3 unpres Analytical Method: EPA 353.2 Rev 2.01993 Nitrogen, Nitrate NO mglL 0.040 1 11/131190021 14797-55-8 366.1 Phosphorus, Total Analytical Method : EPA 365.1 Rev 2U 1993 Preparation Method: EPA 365.1 Rev 2.01993 Phosphorus 0.64 mg/L 0.050 1 11/i TI91903 111131192215 77223-14-0 4500 Chloride Analytical Method: SM 4500-CI-E-2011 Chloride 3.4 mg/L 1.0 1 11/1511920:25 16887-00-6 5310E TOD Analytical Method: SM 5310B-2011 Total Organic Carbon NO mg/L 1.0 1 11/22/19 0107 7440-44-0 REPORT OF LABORATORY ANALYSIS This report shell not be reproduced. except in full, Date: 12/101201905:59 PM without the wnnen consent 0 Pece Analytical Services,LLC. Page 4 of 41 Pace Analytical 9ervicea, LLC aceAnalytical 5 Riverside 28 04 Wparprttlaba.eoR AaM1e(82 NC28BW (826)259-]1]8 ANALYTICAL RESULTS Project: ROSE HILL MW I1-12-19 Pace Project No.: 92453264 Sample: MW-2 Lab ID: 9US3264002 Collected: 11/121191040 Received: 11112/1913:36 Matrix: Water Parameters Results Unite Report Limit OF Prepared Analyzed CAS No. Oual Monitoring Well Data Analytical Method: Collected By Joel 1 11/12119 10,40 Schlaudl Collected Date 11/12/19 1 11/12/19 10:40 Collected Time 10:40 1 1111211910:40 pH 5.5 Bid, Units 1 11/12/19 10:40 Temperature 12.5 deg C 1 11/12/19 10:40 Static Water Level 12.12 feet 1 11/12119 1040 Specific Conductance 21.9 umh0slcm 1 1111211910:40 Turbidity 668.8 NTU 1 11/1211910:40 Oder NO 1 11/1211910:40 Appearance Orange 1 1111211910:40 62008 MW Analytical Method: SM 6200B Benzene NO ug l- 0.50 1 11123/1911'.36 71-43-2 Bromobenzene NO ug/L 0.50 1 1112311911:36 108-86-1 Bromochloromethane NO ug/L 0.50 1 11/23/19 11:38 ]4-9]-5 Bromodichlrn0methane NO uglL 0.50 1 1123/1911:36 15-27-4 Bromoform NO uglL 0.50 1 11/23/1911:36 75-25-2 Bmmomethane NO ug/L 5.0 1 11/23/19 11:36 74-83-9 n-Buthimenzene ND ug/L 0.50 1 11/2311911'36 104-51-8 sec-Butylbenzene ND ug/L 0,50 1 1112311911:36 135-98-8 left-Bulylbenzene NO ug/L 0.50 1 11/23/1911 36 98-06-6 Carbon tetrachloride NO uglL 0.50 1 11/23119 11:36 56-23-5 Chlorobenzene NO ugh- 0.50 1 11/23/19 11:36 108-90-7 Chlomethane NO ug/L 1.0 1 11/23119 11:36 75-00-3 Chloroform NO uglL 0.50 1 11/23/1911:36 67-66-3 Chloromethane NO ug/L 1.0 1 11/23/19 11:36 74-87-3 2-Chlmotoluene NO ug/L 050 1 11/23/1911:36 95-49-8 4-Chiorotoluene NO ug/L 0.50 1 11/23/19 11:36 106-43-4 1,2-Dibromo-3-chloropropane NO ug/L 1.0 1 11/23/19 11:36 96-12-8 Dibromochloromethane ND ug/L 0.50 1 11/2311911:36 124-48-1 1,2-Dibromoethane(EDB) NO ug/L 0.50 1 11123/1911:36 106-93-4 Dibrom0methane NO ug/L 0.50 1 11/23/1911:36 74-95-3 12-Dichlorobenzene NO uglL 0.50 1 11/23/19 11:36 95-50-1 1,3-Dichlorobenzene NO ug/L 0.50 1 1112311911:36 541-73-1 1,4-Dichlorobenzene NO ug/L 0.50 1 1112311911:36 10646-7 Dichlorodiflucromelhane NO ug/L 0.50 1 1112NI9 11:36 75-71-8 1,1-Dichloroelhane NO ug/L 0,50 1 11/23/19 11:36 75-34-3 1,2-Dichlcroethane NO ug/L 0,50 1 1112311911:36 107-06-2 1,1-Dichlorcelhene ND ug/L 0.50 1 11/23/19 11:36 75-354 cis-1,2-Dichloroelhene NO ug/L 0.50 1 11/23119 11:36 156-59-2 trans-1,2-Dichloroelhene NO uglL 0.50 1 11/23/19 11:30 156-60-5 1,2-Dichlomprcpane NO ug/L 0.50 1 11/23119 11:36 78-87-5 1,3-Dichioropmpane NO ug/L 0.50 1 11/23/19 11:36 142-28-9 2,2-Dichioropropane NO uglL 0.50 1 1112311911:36 594-20-7 L I-Dichloropropene NO uglL 0.50 1 1112311911:36 563-58-6 cis-1,3-Dichlompropene NO uglL 0.50 1 11/2311911:36 10061-01-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full Date: 12/101201905:59 PM Whhoat the written consent of Pace Analytical Services LLC. Page 5 of 41 Pace Analytical service, LLC aceAnalXjcal 2225 Riverside28 0 www.pac l.b. m Asheville, NO aW (928)25941]e f ANALYTICAL RESULTS Project: ROSE HILL MW 11-12-19 Pace Projecl No.: 924532U Sample: MW-2 Lab IO: 92A63264002 Collected 111121191040 Received: 11/1211913:36 Matrix: Water Parameters Results Units Report Limit OF Prepared Analyzed CAS No. Chat 62005 MSV Analytical Method: SM 6200B trans-1,3-Dichloropropene ND ug/L 0.50 1 11/23/19 11:36 10061-02-6 Diisopropyl ether ND ug/L 0.50 1 11/2311911:36 108-20-3 Elhylbenzene ND ugh- 0.50 1 1112311911:36 100-41-4 Hasschloro-1,3-butadlene ND uglL 2.0 1 11/23/19 11:36 87 68-3 Isopropylbenzene(Cumene) NO ugi 0.50 1 11/2311911:36 98-82-8 Methylene Chloride NO ugi 2.0 1 11123/18 11:36 75-09-2 Methyl-ted-butyl ether NO ug/L 0.50 1 11/23/19 11:38 1634-0,1 4 Naphthalene ND ug/L 2.0 1 11/23/1911:36 91-20-3 n-Propylbenzene ND ug/L 0.50 1 11/23119 11:36 103-65-1 Styrene ND ug/L 0.50 1 11/23119 11:36 100-42-5 1,1,1,2-Tetrachlomethane ND uglL 0.50 1 11/2311911:36 630-20-6 1,1 ,2,2-Tetrachlmmethane ND ugi 0.5D 1 11123/19 11:36 79-34-5 Tetrachlomethene ND ugi 0.50 1 11123/19 11'.36 127-18-4 Toluene NO ugi 0.50 1 11/23/1911:36 108-88-3 1,2,3-Trichlombenzene NO bill 2.0 1 1112311911:36 87-61-6 1,2,4-Tdchlombenzene ND ug/L 2.0 1 11123/1911:36 120-82-1 1,1,1-Trichlmoethane ND ug/L 0.50 1 11/23119 11:36 91-55-6 1,1,2-Tdchloroethane ND ug/L 0.50 1 1123119 11:36 79-00-5 Trichlomethene ND ugh- 0,50 1 11MI1911:36 79-01-6 Trichlowfluoromethane ND ug/L 1.0 1 11/2311911:36 75-894 1,2,3-Trichloropropane ND ug/L 0.5D 1 11123/19 11:36 96-18-4 1,2,4-Trimethylbenzene NO ugi 0.50 1 111231191136 95-63-6 1,3,5-Trimethylbenzene NO ugi 0.50 1 11/23/19 11:36 108-67-8 Vinyl chloride NO ug/L 1 0 1 11/23/19 11:36 75-01-4 m&p-Xylene NO ug/L 1.0 1 11123/1911:36 179801-23-1 o-Xylene NO ug/L 0.50 1 1112TI 911:36 95-47-6 Surrogates 12-Dichl0r0lthane-d4(S) 98 % 70-130 1 11/23119 11:36 17060-07-0 4-BromoBuorobenzene (9) 100 % 71T130 1 11/2311911:36 480-00-4 Toluene-d8(S) 100 % 70-130 1 11/2311911:36 2037-26-5 2540C Total Dissolved Solids Analytical Method: SM 2540C-2011 Total Dissolved Solids 36.0 mg/L 25.0 1 11/15/19 08:05 9040 pH Analytical Method: EPA 9040C PH at 25 Degrees C 5.2 Slid. Units 0.10 1 11/24119 16:32 H3 MSIO 9222D Fecal Collform AVL Analytical Method: SM 9222D-2006 Preparation Method: SM 9222D-2006 Fecal Coliforms 60.0 CFU/100 mL 1.0 1 11/1211917:37 11/1311915:47 360.1 Ammonia Analytical Method: EPA 350.1 Rev 2.01993 Nitrogen, Ammonia NO mg/L 0.10 1 1112111906:40 7664-41-7 363.2 Nitrogen, N021NO3 unpres Analytical Method: EPA 353.2 Rev 2.01993 Nitrogen, Nitrate 0.41 mi 0.040 1 11/13/1900: 19 14797-55-8 REPORT OF LABORATORY ANALYSIS This report shall not be repmduced except in full, Dale: 121101201905:59 PM without the written wnsent of Pace Analytical Services,uC. Page 6 of 41 aceAnaj heal MWM0aeflab A001 ANALYTICAL RESULTS Pace Analytical services, LLC 222E Riverside or. Asheville, NC 28804 (928)254-7176 Project: ROSE HILL MW 11-12-19 Pace Project No.: 92453264 Sample: MW-2 Lab ID: 9Yt53264002 Collected: 1111211910:40 Received: 11/12/1913.36 Matrix: Water Parameters Recoils Units Report Limit DF Prepared Analyzed CAS No, Oual 365.1 Phosphorus, Total Analytical Method: EPA 365.1 Rev 2.01993 Preparation Method: EPA 365.1 Rev 2.01993 Phosphorus 0.38 mg/L 0.050 1 1111311919:03 11/1311922:16 7723-14-0 4500 Chloride Analytical Method: SM 4500-CI-E-2011 Chloride 2.1 mg/L 1.0 1 11/15/19 2028 16887-00-6 5310B TOO Analytical Method: SM 531OB-2011 Total Organic Carbon ND mg/L 1.0 1 11/22/19 01:22 7440-44-0 REPORT OF LABORATORY ANALYSIS This report shall not be reproducer, except in full, Date: 12110/201905:59 PM shoot the carmen consent off Pace Anelyticxl Services LLC. Page 7 of 41 Pace Analytic al Services, LLD ® 2225 Riverside Dr. aceAnalytical Asheville, NC 28804 awe.,nabbecpm (828)254-]1]8 ANALYTICAL RESULTS Project: ROSE HILL MW 11-12-19 Pace Project No.: 92453264 Sample: MW-313 Lab ID: 92453264003 Collected: 1111211909:45 Received: 11112/191336 MatrixWater Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual Monitoring Well Data Analytical Method: Collected By Joel 1 11/12119 09:45 Schbi Collected Date 11112/19 1 11/12/19 09:45 Collected Time 09:46 1 11/1211909:45 pH 6.6 Sid. Units 1 1111211909:45 Temperature 13.8 deg C 1 11/12/19 09:45 Static Water Level 3.90 feet 1 11/12/19 09'45 Specific Conductance 118.5 umhos/cm 1 1111211909:45 Turbidity 206.4 NTU 1 11/12119 09:45 Odor NO 1 11/12119 09:45 Appearance Clearl 1 11/12/19 09:45 Orange 6200B MSV Analytical Method: SM 6200B Benzene ND ug/L 0.50 1 11/23/19 11:54 71-43-2 Bromobenzene NO ug/L 0.50 1 11/2311911:54 108-86-1 Bromochloromethane NO ug/L 0.50 1 11/23/19 11:54 ]4-9]-5 Bromodichloromethane NO ug/L 0.5D 1 1112311911:64 16-27-4 Bromoform ND ug1L 0.50 1 11123/19 11:54 75-25-2 Bromomethane ND ugi 5.0 1 111231191154 74-83-9 n-Butylbenzene NO uglL 0.50 1 11/2311911:54 104-51-8 sec-Bulylbenzene NO ugi O50 1 11/23/19 11:54 135-98-8 tart-Butylbenzene NO ug/L 0.50 1 1112311911:54 98-06-6 Carbon tetrachloride NO ug/L 0,50 1 11/23/19 11:54 56-23-5 Chlorobenzene NO ug/L 0.50 1 11/23119 11:54 108-90-7 Chian ethane NO ug/L 1.0 1 11123/19 11:54 75-00-3 Chloroform NO uglL 0.50 1 11123/19 11:54 67-66-3 Chloromethane ND ug1L 1.0 1 11/231191154 ]4-8]-3 2-Chlorotoluene ND uglL 0.50 1 11/23/19 11:54 95-49-8 4-Chlorotoluene NO ug1L 0.50 1 11/23/1911:54 106-43-4 1,2-Dibromo-3-chloropropane NO ri lL 1 0 1 11/23119 11:54 96-12-8 Dibromochloromelhane NO ugli. 0.50 1 11123/1911:54 124-48-1 1,2-Dibromoethane(EDB) NO ug/L 050 1 11123/1911:54 106-93-4 Dibromomethane NO ug/L 0,50 1 11/23/1911:54 74-95-3 1,2-Dichlorobenzene NO ug/L 0.50 1 11/23/19 11:54 95-50-1 1,3-Dichlorobenzene NO ug/L 0.50 1 1112311911:54 541-73-1 1,4-Dichlorobenzene NO ugh- 0.50 1 11123/1911 54 106-46-7 Dlchlorodl0uoromethane ND ug1L 0.50 1 1112311911,54 75-01-8 1,1-Dichlaroethane ND uglL 0.50 1 11123/1911:54 75-34-3 1,2-Dichlaroethane ND ugi 0.50 1 11/23/1911:54 107-06-2 1,1-Dichloroethene ND ug/L 0.50 1 11/23119 11:54 75-354 cis-1,2-Dichloncethene NO ugli- 0.50 1 11/23119 11:54 156-59-2 trans-1,2-0ichloroethene NO ug/L 050 1 11/23/19 11:54 158-60-5 1,2-Dichloropropane ND ug/L 0,50 1 11/2311911:54 78-87-5 1,3-Dichloropropane NO ug/L 0.50 1 11123/1911:54 142-28-9 2,2-Dichloropropane NO ug/L 0.50 1 11/231191154 594-20-7 1,1-Dlchloropropene NO ug/L 0.50 1 11/23/19 11'.54 583-58-6 REPORT OF LABORATORY ANALYSIS This report all not be reproduced, except in full, Date: 12/10P20190559PM without the written consent of Pace Analytical Services, I.I.C. Page 8 of 41 Pace Analytical Samlcee, LLC ® 1.5 Riverside Dr. a0Analytical Asheville, NC 28804 ww.yerdebesom (e2s)254-71ee ANALYTICAL RESULTS Project: ROSE HILL MW I1-12-19 Pace Project No.: 92453264 Sample: MW31) Lill 92453264003 Chiseled: 11/1211909:45 Received: 1111211913:36 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Oual 0200E MSV Analytical Method: SM 6200B cis-1,3-Dichloropropene ND ug/L 0.50 1 1112311911,54 10061-01-5 trans-1,3-Dichlmopropene ND ug/L 050 1 1112311911:54 10061-02-6 Dilsopropyl ether ND ug/L 0.50 1 11/23/1911:54 108-20-3 Ethylbenzene NO ug/L 0.50 1 11/23/1911:54 100-41-4 Hexachloro-1,3-botanists NO ug/L 2.0 1 11123/1911:54 87-68-3 Isopropylbenzene (Cumene) NO ug/L 0.50 1 1112311911:54 98-82-8 Methylene Chloride NO ug/L 2.0 1 11/2311911:54 75-09-2 Methyl -ten -butyl ether NO uglL 0.50 1 1112311911:54 1634-04-4 Naphthalene ND ug/L 2.0 1 1112311911'.54 91-20-3 n-Propylbenzene NO ug/L 0.50 1 11/2311911:54 103-65-1 Styrene ND ug/L 0.50 1 11/23/19 ll:54 100-42-5 1,1A2-Tetrachlomethane NO uglL U0 1 11/2311911:54 630-20-6 1,1,2,2-Tetrachlomethane ND uglL 050 1 11/23/19 ll:54 79-34-5 Tetrachloroethene ND ug/L 050 1 11123/1911:54 127-18-4 Toluene NO ug/L 0,50 1 1112311911:54 108-88-3 1,2,3-Trichlambenzene ND ug/L 2.0 1 11/23/1911:54 87-61-6 1,2,4-Trichloroberl NO uglL 2.0 1 11/2311911:54 120-82-1 1,1,1-Trichloroethane NO uglL 0.50 1 111231191154 71-55-6 1,1,2-Trichloroethane NO ug/L 0.50 1 111231191154 79-00-5 Thchloraethene ND ug/L 0.50 1 11123/1911:54 79-01-6 Trichlomfluoromethane NO ug/L 1.0 1 1112311911:5,1 75-69-4 1,2,3-Tnchloropropane NO ug/L 0.50 1 11/23/1911:54 96-18-4 1,2,4-Tnmethylbenzene ND uglL U0 1 11/23/1911:54 95-63-6 1,3,5-Trimethylbenzene NO uglL 050 1 1112311911:54 108-67-8 Vinyl chloride NO ug/L 1.0 1 11/23/19 11:54 75-01-4 m&p-Xylene NO ug/L 1.0 1 11/23119 11:54 179601-23-1 o-Xylene NO ug/L 0.50 1 11/23/19 11:54 95-47-6 Surrogates 1,2-Dichlometharil(S) 96 % 70-130 1 11/23/1911:54 17060-07-0 4-BromcOuorobenzene(S) 97 % 74130 1 1112311911:54 460-00-4 Toluene-n8 (S) 100 % 70-130 1 1112311911:54 2037-26-5 2540C Total Dissolved Solids Analytical Method : SM 254OC-2011 Total Dissolved Solids 100 al 25.0 1 11/15/1908:06 9040 pH Analytical Method: EPA 9040C pH at 25 Degrees C 6.2 Sid. Units 0.10 1 11124/19 16 27 H3 IBBIO 9222D Fecal Collform AVL Analytical Method: SM 9222D-2006 Preparation Method: SM 9222D-2006 Fecal Coliforms 44.0 CFU1100 mL 1.0 1 11/121191643 111131191547 350.1 Ammonia Analytical Method: EPA 350.1 Rev 2.01993 Nitrogen, Ammonia ND al 0.10 1 11121/190641 7664-41-7 353.2 Nitrogen, N021NO3 unpres Analytical Method: EPA 353.2 Rev 2.01993 Nitrogen, Nitrate 1.0 hall 0.040 1 11113/1900:16 14797-55-8 REPORT OF LABORATORY ANALYSIS This report shell not be reproduced, except in fall. Date'. 12/10/20190559 PM without the written consent of Pace Analytical Services,LLC. Page 9 of 41 Pace Analylical Services, LLC ® 2225 Riverside Or. aceAnalytical Asheville, NC 28804 dessiurnsinns. (e29)264a176 ANALYTICAL RESULTS Project: ROSE HILL MW 11-12-19 Pace Project No.: 92453264 Sample: MWi Lab 10: 92453264003 Collected: 11/1211909:45 Received: 11/121191336 Matrix: Water Parameters 365.1 Phosphorus, Teal Phosphorus 4500 Chloride Chloride 5310E TOC Total Organic Carbon Dale: 12/10/2019 05:59 PM Results Units Report Limit OF Prepared Analyzed CAS No. Oual Analytical Method: EPA 365.1 Rev 2.01993 Preparation Method : EPA 365.1 Rev 2.01993 0.96 mg/L 01050 1 11113/1919'.03 11/131192217 7723-14-0 Analytical Method: SM 4500-CI-E-2011 5.8 mg/L 1.0 1 11/151192029 16887-00-6 Analytical Method: SM 53105-2011 1.1 m9IL 1.0 1 11/2211901:37 7440-44-0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services,LLC. Page 10 of 41 ace Analytical wew.paNrpeaa. ANALYTICAL RESULTS Pace Analytical Services, LLC 2225 Riverside Dr. Aahaville, NC 28804 (628)254-1178 Project: ROSE HILL MW 11-12-19 Pace Project No.: 924532M Sample: MW-1 Resemble Lab ID: 92453264004 Collected : Receinetl: 11/261191105 Matrix: Water Parameters Monitoring Well Data Collected By Collected Date Collected True pH Temperature Static Water Level Specific Conductance Turbidity Appearance Date: 12/10/2019 05 59 PM Results Units Report Limit DF Preperetl Analyxetl CAS No, Qual Analytical Method Joel 1 11/26/1913:35 Sell 11/26/19 1 11/26/19 1335 13:35 1 11/2611913:35 6.5 Std. Units 1 11/26/19 13:35 15.3 deg C 1 1126/1913:35 32.60 feet 1 11/2611913:35 49.4 umhas/cm 1 11125/19 13 35 362.2 NTU 1 1112811913:35 Cloudy 1 11/26/19 13:35 REPORT OF LABORATORY ANALYSIS This rated shall not be repratluceb, except in full, without the writes consent of Pace Analytical Services LLC, Page 11 of 41 Pace Analytical scroll LLC 8 2 aceAnalXical® a Rve 0 sa'a'opatabal Acheville.NC e04 (628)250-]1]6 f ANALYTICAL RESULTS Project: ROSE HILL MW 11-12-19 Pace Project Ni, 92453264 Sample: MW-1 Lab ID: 92455269001 Collected: 11/261191335 Received: 1112611914:15 Matrix: Water Parameters Results Units Report Limit OF Prepared Analyzed CAS No. Oual 6200B MSV Analytical Method: SM 6200B Benzene NO ug/L OSO 1 1210911913:16 71-43-2 Bromobenzene NO ug/L 050 1 12/0911913:16 108-86-1 Bromochlaromethane NO uglL 050 1 1210911913:16 74-97-5 Bromadichlommethane NO ug/L 0.50 1 12109/1913.16 15-27-4 Bromoform NO ug/L 0.50 1 1WO911913:16 75-25-2 Bmmomethane ND ug/L 5.0 1 1210911913:16 74-83-9 n-Butylbenzene NO ug/L 0.5D 1 12/09/1913:16 104-51-8 sec-Butylbenzene NO ug/L 0.50 1 12/0911913:16 135-98-8 tert-Butylbenzene NO ug/L 050 1 12109/19 13:16 98-06-6 Carbon tetrachloride NO ug/L 0.50 1 1210911913:16 56-23-5 Chlombenzene NO ug/L 0.50 1 12109/1913:16 108-90-7 Chlomelhane NO ug/L 1.0 1 1VO911913:16 75-00-3 Chloroform NO uldL 0.50 1 12/09/19 13:16 67-86-3 Chlaromethane NO ug/L 1.0 1 12/09/19 13:16 ]4-8]-3 2-Chlorotoluene NO ugll- 0.50 1 12/09/19 13:16 95-49-8 4-Chlorotoluene ND uglL OSO 1 12109/19 13:16 106-43-4 1,2-Dibromo-3-chlompropme, NO ug/L LO 1 1210911913,16 96-12-8 Dibromochloromethane NO ug/L 0.50 1 12/0911913:16 12448-1 1,2-Dlbromoethane(EDB) NO ug/L 0.50 1 1VO911913:16 106-93-4 Oibromomethane ND ug/L 0.50 1 12/0911913:16 74-95-3 1,2-Dichtombenzene NO ug/L 0.50 1 12/09/19 1316 95-50-1 LS-Oichlorobenzene NO ug/L 0.50 1 12109/1913'16 541-73-1 1,4-Dichlorobeizene NO uglL 0.50 1 1210911913:16 106-46-7 Dichlarodifluoromethane NO ug/L 0.50 1 1210911913:16 ]5-]1-8 1,1-Dichloroethane NO ug/L 0,50 1 1VO9119 13:16 75-34-3 1,2-Dlchlomethane ND ug/L 0,50 1 12/0911913:16 107-06-2 1,1-Dichloroethene NO ug/L 0,50 1 IV0911913:16 75-35-4 cis-1,2-Dichloroethene ND ug/L 0.50 1 12/09/19 13:16 156-59-2 trans-1,2-Dichloroethene NO ug/L OSD 1 12/0911913:16 156-60-5 1,2-Dichlompropane NO ug/L 0.50 1 12/0911913:16 ]8-8]-5 1,3-Olchloropropene NO ug/L 0.50 1 12/0911913'16 142-28-9 2,2-Dichloropmpane NO ug/L 0.50 1 12/09/1913:16 594-20-7 1,1-Dichloropropene NO ug/L 0,50 1 12109/1913:16 563-58-6 cis-1,3-Dichloropropene NO ug/L 0.50 1 1210911913:16 10061-01-5 trans-1,3-Dichloropropene ND ug/L TSO 1 12/09/19 13:16 10061-02-6 Diisopropyl ether ND ug/L 0.50 1 12/09/1913:16 108-20-3 Euhylbenzene NO ug/L 0.51) 1 12/09/1913a6 100-41-4 Hexachloro-1,3-butadlene NO ugll- 2.0 1 12109/19 13:16 87-68-3 Isopropylbenzene(Comers) NO ug/L 0.50 1 12/0911913:16 98-82-8 Methylene Chloride NO ug/L 2.0 1 12109/1913:16 75-09-2 Methyl-ted-butyl ether NO ug/L 050 1 1210911913:16 1034-04-4 Naphthalene NO ug/L 2.0 1 1VO911913:16 91-20-3 n-Propylbenzene NO ugd- 0.50 1 1210911913:16 103-65-1 Styrene ND ug/L 0,50 1 1210911913:16 100-42-5 1,1,1,2-Tetrachloroethane NO, ug/L 0.50 1 12/09/19 13:16 81 1,1,2,2-Tetrachlaroethane NO ug/L 0.50 1 12109/19 13:16 79-34-5 Tehachloroethene NO ugll- OSO 1 1210911913:16 127-18-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced except in full, Date: 121101201905:59 PM atrout the written consent of Pace Analytical Services.LLC. Page 12 of 41 Pace Analytical 5ervicee. LLC aceMalytical ® .25 Rivers de Cr. Asheville, NO 28804 ..'sis bran (628)254-]1]6 ANALYTICAL RESULTS Project: ROSE HILL MW 11-12-19 Pace Project No.: 92453264 Sample: MW-1 Lab ID: 9USS259001 Collected: 11/26/1913:35 Received 1112611914'. 15 Matrix'. Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 6200B MSV Analytical Method: SM 6200B Toluene NO ug/L 0.50 1 1210911913:16 108-88-3 1,2,3-Trichlombenzene NO ug/L 2.0 1 1VO911913:16 87-61-6 1,2,4Trichlombenzene ND ug/L 2.0 1 121091191316 120-82-1 1,1,1-Trichloroethane ND ugh- 050 1 12/09/19 13:16 71-55-6 1,1,2-Trichloroethane ND ug/L 050 1 12/09/19 13:16 79-00-5 Trichlomethene ND ug/L 0,50 1 12109/1913: 16 79-01-6 Trichlorolluommethane ND uglL 1.0 1 12/09119 13:16 75-69-4 1,2,3-Tdchloropropane NO ug/L 0.50 1 1210911913:16 96-18-4 1,2,4-Trimethylbenzene NO ug/L 0.50 1 1VO911913:16 95-63-6 1,3,5-Trimethylbenzene NO ug/L 0.50 1 1209/19 13:16 108-67-8 Vinyl chloride NO ugh- 1.0 1 12/09/19 13:16 75-014 m8p-Xylene ND ugg- 1.0 1 1210911913:16 179601-23-1 o-Xylene ND ug/L 0.50 1 1210911913:16 95-47-6 Surrogates 1,2-Dichloroethane-d4(S) 100 % 70-130 1 1210911913:16 17060-07-0 4-Bmmofluorobenzene(S) 100 % 70-130 1 1VO911913:16 460-00-4 Toluene -off (S) 97 % 70-130 1 12I09/19 13:16 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproducer, except in full, Date: 12/101201905:59 PM without the written consent of Pace Analytical Service%, LLC. Page 13 of 41 aceAnalAcal e ww.yeaesbs<om QUALITY CONTROL DATA Project: ROSE HILL MW I1-12-19 Pace Project No.: 92453264 QC Batch: 511291 Analysis Method SM 6200B QC Batch Method SM 6200B Analysis Description: 6200B MSV Associated Lab Samples: 92453264002, 92453264003 METHOD BLANK: 2742839 Associated Lab Samples: 92453264002, Parameter 92453264003 Units Matrix: Blank Result Water Reporting Limit Analyzed 1,1,1,2-Telrachloroethane ug/L NO 0.50 11123/190642 1,1,1-Trichloroethane ug/L NO 0.50 11/2311906:42 1,1,2,2-Tetrachloroethane uglL NO 0.50 11123/1906:42 1,1,2-Trichlomethane ugT ND 0.50 1112311906:42 1,1-Dichloroethane ug1L NO 0.50 1112311906:42 LI-Dichloroethene uglL NO 0.50 1112311906:42 1,1-Dichloropmpene uglL NO 0.50 1112311906:42 L2,3-Trlchlombenzene ug/L NO 2.0 1112311906:42 L2,3-Trichloropropane ug/L NO 0.50 11/23/1906:42 LZA-Trichlorobenzene ug/L ND 2.0 11123/1906:42 1,2,4Trimethylbenzene ug/L NO 050 11/23/1906:42 1,2-Dlbromo-3-chlomproparte ug1L NO 1.0 11/23/1906:42 1,2-Dibromoethane(EDB) ugi NO 0.50 11/2311906:42 L2-Dichlorobenzene ugi NO 0.50 11/2311906:42 1,2-Dichloroethane ugi NO 0.50 11/2311906:42 1,2-Dichloropropane ugi NO 0.50 1112311906:42 1,3,5-Trimethylbenzene ug/L NO 0.50 11123/1906:42 1,3-Dichlorobenzene ug/L NO 0.50 11123/1906.42 1,3-Dichloropropane uglL NO 0.50 1112311906:42 1,4-Dichlorobenzene uglL NO 0.50 11123/1906:42 2,2-Dichloropropane ugi NO 0.50 11/23119 06 42 2-Chlorotoluene ug/L NO 0.50 11/23/1906:42 4-Chlorololuene ug/L ND 0.50 11/2311906:42 Benzene ug/L NO 0.50 1112311906:42 Bromobenzene uglL NO 0.50 1112311906:42 Bromochloromethane uglL NO 0.50 11/23/1906:42 Brohnniichlorometharte ug/L NO 0.50 11/23/1906.42 Bromoform ug/L NO 0.50 11123/19 00 42 Bromomethane ug/L NO 5.0 1112311908:42 Carbon tetrachloride ug)L NO 050 1112311906:42 Chlorobenzene ugs- NO 0,50 11123/19 06 42 Chlomethane ug1L NO 1.0 11/2311906:42 Chloroform ug1L ND 0.50 11/2311906:42 Chloromethane uglL NO 1.0 1112311906:42 cis -L2-Dichloroethene uglL NO 0,50 1112311906'42 cis-1,3-Dichloropropene ug/L ND 0.50 1112311906:42 Dibramochloromethene ug/L NO 0.50 11/231190842 Dibromomethane ug/L NO 0.50 1112311006:42 Dichlorotlifluoromethane ug/L NO 0.50 11/2311906:42 Diisopaii ether ug/L NO 0.50 1112311908:42 Elhylbenzene ugi NO 0.50 11123/1906:42 Qualifiers Pace Analytical Services, LLC 2225 Riverside or Asheville, NC 28804 (e2e)254-717e Results press Mad on this page are In the units ImucabJ by the Units column swept there an customs ask 1. Maym e4 to the rare of the resell. REPORT OF LABORATORY ANALYSIS This report shall not be repm6uceQ except in full, Date: 12110/201905:59 PM without to written consent of Pace Analytical Services,LLC. Page 14 of 41 aceAnalytrcal WXW.ptplGUe.tOR QUALITY CONTROL DATA Pro l: ROSE HILL MW 11-12-19 Pace Project No.: 92453264 METHOD BLANK: 2742839 Associated Lab Samples: 92453264002,92453264003 Parameter Units Matrix: Water Blank Reporting Result Limit Analyzed Hexachloro-1,3-butadlene ug/L ND 2.0 11/23/19 06:42 Isopropylbenzene(Cumene) uglL ND 0,50 1112311906:42 m8p-Xylene uglL ND 10 11/23/1906'42 Methyl -lent -butyl ether ug/L ND 0.50 11/23/19 06:42 Methylene Chloride ug/L ND 2.0 11/23/19 06:42 n-BtAylbenzene ug/L ND 0.50 11/23119 06.42 n-Propylbenzene ug/L NO 050 11123/1906:42 Naphthalene ug/L ND 2.0 11/23119 06 42 o-Xylene ug/L ND 0.50 11/2311906:42 seo-Butylbenzene uglL ND 0.50 11/2311905:42 Styrene uglL ND 0.50 1112311906:42 tertButylbenzene ug/L NO 0.50 11123/1906:42 Tetrachloroethene ug/L ND 0.50 11/23/19 06:42 Toluene ug/L ND 0.50 11/23/1906:42 trans-1,2-Dichloroethene ug/L ND 0.50 11/23/19 06:42 trans-1,3-Dichloropropene ugT ND 0.50 111231190642 Trichloroethene Toll- ND 0.50 11/23/19 06:42 Trichlorofluoromethane ug/L NO 1.0 11/23/19 06:42 Vinyl chloride uglL NO 1.0 11/23/19 05 42 1,2-DIChlorcethan l (S) % 95 70-130 11/23/19 06:42 4-Bromofuorobenzene(S) % 101 70-130 11/23/19 06:42 Toluene-de(S) % 100 70-130 11123/19 06:42 Qualifiers LABORATORY CONTROL SAMPLE: Parameter 2742840 Units Spike Conc. LCS Result LCS % Rao %Rec Limits 1, 1,1,2-Tetrachloroethane ug/L 50 54.5 109 60-140 11,1-Trichloroethane uglL 50 50.4 101 60-140 1,1,2,2-Tetrachloroethane ug/L 50 54.1 108 60-140 1,1,2-Trichloroethane uglL 50 53.5 107 60-140 1,1-Dichlorcethane ug/L 50 51,9 104 60-140 1,1-Dichlomethene ug/L 50 505 102 60-140 1,1-Dichloropropene ug/L 50 53.8 108 60-140 1,2,3-Trichlorobenzene ug/L 50 54.8 110 60-140 1,2,3-Trichlompropaoe Toll- 50 42.4 85 60-140 1,2,4-Trichlorobenzene ug/L 50 62.6 105 60-140 1,2,4-Trimethylbenzene ug/L 50 49.8 100 60-140 1,2-Dibromo-3-chlmopropane ug/L 50 55.6 111 60-140 1,2-Dibromaethane(EDB) uglL 50 55.0 110 60-140 1,2-Dichlombenzene uglL 50 51.5 103 60-140 1,2-Dichloroethane uglL 50 44.5 89 60-140 1,2-Dichloropropane ug/L 50 53.3 107 60-140 1,3,5-Trimethylbenzene ug/L 50 51.3 103 60-140 1,3-Dichlarobenzene ug/L 50 51 4 103 60-140 Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (825)254-]1]6 Qualifiers then Its presented on this page are In the unite Indicated by the' Units" column except where an altemate unit is preaeMed M the right of reauft. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced. except in full. Date: 12110/2019 05:59 PM without the written consent Para Analytical Services, LLC. Page 15 of 41 aceAnalytical' W WM.pRaga sub Project: ROSE HILL MW 11-12-19 Pace Project No.: 92453264 LABORATORY CONTROL SAMPLE: 2742840 Parameter 1,3-Dichloropropane 1,4-Dichlorobenzene 2,2-Dichloroprapane 2-Chlorotoluene 4-Chlorotoluene Benzene Bromabenzene Bromachioromethaoe Bromotlichloromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chlomethane Chloroform Chloramethane cis-1,2-Dichloraethene cis-1,3-Dichloropropene Dibromochloromethane Dibromomethane Dichlorotli6uoromethane Dlisopropyl ether Ethylbenzene Hexachloro-1,3-butathene Isopropylbenzene(Cumene) m&p-Xylene Methyl-tert-butyl ether Methylene Chloride n-Butylbenzene n-Propylbenzene Naphthalene o-Xylene seo-Butylbenzene Styrene tert-Butylbenzene Tetrachloroethene Toluene trans-1,2-Dichloroethene trans-1,3-Oichloropropene Trichlomethene Thchloroguoromethane Vinyl chloride 1,2-Dichloroethami (S) 4-Bromofivarobenzene (S) Toluenei(S) QUALITY CONTROL DATA Spike Units Cone. 1 50 ug/L 50 ugh- 50 uglL 50 uglL 50 uglL 50 ug/L 50 1 50 ug l- 50 ug/L 50 uglL 50 uglL 50 uglL 50 ug/L 50 ug/L 50 ug/L 50 ugh- 50 uglL 50 uga- 50 uglL 50 ug/L 50 ug/L 50 ug/L 50 1 50 ug/L 50 ug/L 100 uglL 50 ug/L 50 ug/L 50 1 50 ug/L 50 ug/L 50 ug/L 50 ug,L 50 uglL 50 uglL 50 ugi 50 g/L 50 g/L 50 g/L 50 gIL 50 uglL 50 LCS Result 54.5 48.1 44.5 49.7 49.5 51.6 51 9 53.6 51.3 57.0 42.3 51.2 50 0 36.0 50.7 55.0 49.7 53.E 53.3 52.5 64.5 53.8 49.0 50.9 51.6 99.2 51.6 46.6 49.9 489 53S 51.5 50.3 54.0 41.5 49.1 48.8 52.9 527 50.3 44.4 80.5 LCS % Rae 109 96 89 99 99 103 104 107 103 114 85 102 100 ]2 101 110 99 107 107 105 129 108 98 102 103 99 103 93 100 98 107 103 101 108 83 98 98 106 105 101 89 121 101 99 99 Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28604 (828)254-7176 % Rec Limits Qualifiers 60-140 60-140 60 140 60-140 60-140 60-140 60-140 60-140 60-140 60-140 60-140 60-140 60-140 60-140 60-140 60-140 60-140 60-140 60-140 60-140 60-140 60-140 60-140 60-140 6D-140 60-140 60-140 60-140 60-140 60-140 60-140 60-140 60-140 60-140 60-140 60-140 60-140 60-140 60-140 60-140 60-140 60-140 ]0-130 ]0-130 70-130 seem Its presented on 0la page are In the units Inclosed by the rmloo' column except where an alternate unit Is Presented to the right or the result. REPORT OF LABORATORY ANALYSIS This repel shall not be reproduced, except in full, Date: 121101201905:59 PM without the Mutanconsent of Pace Anal,&al Services, LLC, Page 16 of 41 (�ace Analytical waw,se.lBbbam QUALITY CONTROL DATA Pace Analytical Servieea, LLC 2225 Riveraida On Atli NO 28804 (828)2544176 Project: ROSE HILL MW 11-12-19 Pace Project No.: 92453264 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2743536 2743537 MS MSD 92453773002 Spike Spike MS MSD MS MSD %Rec Parameter Units Result Conc, Conc. Result Result % Rae % Rae Limits RED Qual 1,1,1,2-Tetrachloroethane ug/L ND 20 20 18.7 19.5 93 97 60-140 4 1,1, 1-Trichloraethane ug/L ND 20 20 18.4 18.7 92 93 60-140 2 IA2,2-Tetrachloroethene ug/L ND 20 20 188 19.7 94 98 60-140 5 1,1,2-Trichloraethane ug/L NO 20 20 19A 20A 96 100 60-140 4 1,1-Dichloroethane ug/L ND 20 20 19.3 19.8 96 99 60-140 3 1,1-Dichlorcethene ug/L NO 20 20 18.5 18.8 92 94 60-140 2 1,1-Dichloropropene ug/L NO 20 20 20.0 20.2 100 101 60-140 1 1,2,3-Trichlorobes ens, ug/L ND 20 20 17.1 18.1 85 90 60-140 6 1,2,3-Trichloropropane ugh- ND 20 20 168 17.8 84 89 60-140 6 1,2,4-Tdchlorobenzene ugh- NO 20 20 16.5 17.1 82 86 80-140 4 1,2,4-Tdmethylbenzene ug/L NO 20 20 17.2 188 86 90 60-140 5 1,2-Dibromo-3-chloropropane ugll- ND 20 20 18.8 20.2 94 101 60-140 a 1,2-Dibmmoethene (EDB) ug/L NO 20 20 19.1 20.0 95 100 60-140 5 1,2-Dichlorobenzene ug/L NO 20 20 18.0 18.8 90 94 60-140 5 1,2-Dichlorcethane upl- ND 20 20 16.6 16.9 83 85 60-140 2 1,2-Dichlompropane ugh- NO 20 20 19.6 20.0 98 100 60-140 2 1,3,5-Trimelhylbencene ug/L ND 20 20 17.9 18.5 90 82 60-140 3 1,3-Dichlorobenzene ug/L NO 20 20 ITS 18.1 88 91 60-140 3 1,3-Dichloropropane ug/L ND 20 20 19.3 20.4 W 102 60-140 5 1,4-Dichlorobenzene ugll- NO 20 20 17.5 18A 87 92 60-140 5 2,2-Dichloropropene ug/L NO 20 20 16.2 16.6 81 83 60-140 2 2-Chlomtoluene ug/L ND 20 20 17.6 17.9 88 90 60-140 2 4-Chlorctoluene ug/L NO 20 20 17.2 18.1 86 90 60-140 5 Benzene uge- NO 20 20 19.4 20.2 97 101 80-140 4 Bromobenzene ugh- ND 20 20 18.5 19.6 93 98 60-140 6 Bromochlommethane ug/L NO 20 20 19.8 20.7 99 103 60-140 4 6romodlchloromethane ug/L NO 20 20 18.4 19.0 92 95 60-140 3 Bmmoform ug/L NO 20 20 18.5 19.3 93 96 60-140 4 Bromomethane ug/L ND 20 20 11.3 12.7 57 63 60-140 11 Ml Carbon tetrachloride ug/L NO 20 20 18.9 19.1 94 96 60-140 1 Chlorobenzene ug/L ND 20 20 17.9 18.5 90 92 60-140 3 Chloroethane ugh- ND 20 20 18.1 18.1 90 90 60-140 0 Chloroform ug/L ND 20 20 182 19.3 98 95 GO-140 0 Chlommelhane ug/L NO 20 20 19.8 20.1 99 101 60-140 2 cis-1,2-Dichlomethene ugll- NO 20 20 18.2 18A 91 94 60-140 3 cis-1,3-Olchloropropene ug/L NO 20 20 18.8 19.3 94 97 60-140 3 Dibromochloromethane ugll- NO 20 20 18.3 18.6 91 93 60-140 2 Dibromomethane ug/L NO 20 20 19.6 20.1 98 100 60-140 2 Oichlorodi8uoromethane ug/L ND 20 20 22.8 22.8 113 114 6b140 1 Diisopropyl ether Toll- ND 20 20 19.2 193 96 99 60-140 3 Ethylbenzene ug/L NO 20 20 17.3 180 87 90 80-140 4 Hexachloro-1,3-buladiene ug/L NO 20 20 177 17.9 88 80 60-140 1 Isopropylbenzene (Cumene) ug/L NO 20 20 18.4 18.8 92 94 60-140 2 m&p-Xylene ug/L NO 40 40 35.8 36.5 90 91 60-140 2 Methyl-teri-butyl ether ug/L NO 20 20 18.3 18.8 91 94 60-140 3 Methylene Chloride ug/L NO 20 20 17.0 17.1 85 86 60-140 1 Results presented on this page are In the on Its In boosted by the "Units' solemn except More an alternate unit is preserved to the debt of the result REPORT OF LABORATORY ANALYSIS This repoM1 shall not be reproduced, except in full, Date: 12/10/2019 05:59 PM without the written concert of Pace Analytical 5awices,LLG Page 17 of 41 11�;ZeAnalytical' usew, posib<am i QUALITY CONTROL DATA Project ROSE HILL MW I1-12-19 Pace Project No.: 92453264 Pace Analyflcal3etvlcea, LLC 2225 Riverside or. Asheville, NC 28804 (828)254-7176 MATRIX SPIKE & MATRIX SPIKE Parameter DUPLICATE: 2743536 MS 92453773002 Spike Units Result Conc. MSD Spike Conc. 2743537 MS Result MSD Result MS %Rec MSD %Rec %Rec Limits RPD Qual n-Butyibenzene ug/L NO 20 20 16.9 178 84 89 fi0-140 5 n-Propylbenzene ugi ND 20 20 17.4 18.0 87 90 60-140 4 Naphthalene ugo- NO 20 20 17.0 18.2 85 91 60-140 7 o-Xylene ug/L NO 20 20 18.1 18.7 91 93 60-140 3 sec-Butylbenzene ug/L NO 20 20 18.0 18.6 90 93 60-140 3 Styrene ug/L NO 20 20 18.2 18.9 91 94 60-140 4 tert-Butyibenzene ug/L ND 20 20 15.0 15.4 75 ]] 60-140 2 Tetrachloroethene ug/L NO 20 20 17.8 18.1 89 90 60-140 2 Toluene ugi NO 20 20 17.8 18.6 89 93 60-140 4 trans-1,2-Dichloroethene ugo- ND 20 20 19.7 20.1 99 100 60-140 2 trans-1,3-Dichlompropene ugi NO 20 20 182 19.1 91 95 60-140 5 Trichloroethene ug/L NO 20 20 188 19.1 94 95 60-140 1 Trichlormooromethane ug/L NO 20 20 11W 19.2 98 96 60-140 2 Vinyl chloride ug/L NO 20 20 22.2 22.5 111 112 60-140 1 1,2-Oichiorcethanei(S) % 98 95 70-130 4-Bromo9uorobenzene (S) % W 96 70-130 Toluene-ml(S) % 99 100 70-130 Results presented on this page are In the calk Indicated by th✓91nRa" column except where an alternate unit Is premmand to the debt of the reeulr. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 121101201905:59 PM without the written consent of Pace Analytical gooses,LC. Page 18 of 41 Analytical' W alf,daelaEaze. I QUALITY CONTROL DATA Pace Analytical Sarvlcea, LLC 2225 Riverside Dr. Asheville, NG 28804 (828)254-9176 Project: ROSE HILL MW I1-12-19 Pace Project No.: 92453264 QC Batch: 513704 Analysis Method: SM 6200B OC Batch Method : SM 6200B Analysis Description: 6200E MSV Associated Lab Samples: 92456259001 METHOD BLANK: 2753743 Associated Lab Samples: 92455259001 Parameter Units Matrix: Water Blank Reporting Result Limit Analyzed 1,1,1,2-Tetrachloroethane ug/L NO 0.50 12/09/19 12:57 1,1,1-Trichloroethane ug/L NO OSO 1210911912'57 1,1,2,2-Tetrachlormethane ug/L ND 0.50 1210911912:57 1,1,2-Trichloroethane ug/L ND 0.50 12109/1912:57 1,1-Dichlormethane ugli- NO 0.50 12/09/1912:57 1,1-Dichlaroethene ug1L NO 0.50 12/0911912:57 1,1-Dichlcropropene ug/L NO 0.50 12109119 1257 1,2,3-Trichlorobenzene uglL NO 2.0 1VO911912:59 1,2,3-Trichloropropane ugi NO 0.50 1WO9119 12:57 1,2,4-Trichlorobenzene ug/L NO 2.0 12/09/1912:57 1,2,4-Trimethylbenzene ag/L ND 0.50 12/0911912:57 1,2-Dibromo-3-chloropropane ug/L NO 1.0 12/0911912:57 1,2-Dibromoethane (EDB) ug/L ND 0,50 12/0911912:57 1,2-Dichlorobenzene ug/L NO 0.50 12/091191257 1,2-Dichloroethane ug1L ND 0.50 12109/1912'.57 1,2-Dichloropropane ug/L NO 0.50 1210911912'57 1,3,5-Trimethylbenzene uglL NO 0.50 12109/19 1257 1,3-Dichlorobenzene ugi NO 0.50 12109/19 1257 1,3-Dichloropropane uglL NO 0.50 1VO9119 12:57 1,4-Dichlorobenzene uglL NO 0.50 12109/191257 2,2-Dichloropropane ug/L NO 0.50 12109/1912:57 2-Chlorololuene ug/L NO 0.50 12/0911912:57 4-Chlorotoluene ug/L ND 0.50 12/0911912:57 Benzene ug1L ND 0,50 12109/1912:57 Bromobenzene uglL NO 0.50 12109/1912:57 Bromochloromethane ug1L NO 0.50 12/09/1912.57 BromOdichlormmethane ug/L NO 0.50 1210911912:57 Bromoform ug1L NO 0.50 12109/1912:57 Bramomethane ug/L ND 5.0 12/09/191257 Carbon tetrachloride ugT NO 0.50 IV0911912:57 Chlorobenzene ulyL ND 0.50 1WO911912:57 Chloroethane ug/L NO 10 12/0911912:57 Chloroform ul NO 0.50 1210911912:57 Chloomethme ug/L NO 1.0 1210911912:57 cis-1,2-Dichlaroethene ug/L NO 0.50 12/0911912:57 cis-1,3-Dlchloropropene ug/L ND 0.50 12/09/1912:57 Dibromochloromethane ug1L NO 0.50 12/09/19 12 57 Qlarommmethane ug/L NO 0.50 12109/19 12 57 Dichlorodifiuoromethane ug/L ND 0.50 12/0911912:57 Diisopropyl ether ug1L NO 0.50 12I09119 12:57 Ethylbenzene ugi NO 0.50 12109/1912:57 Qualifiers aeaulb primentad on he Is page ere In the unlb Indlwled by the "Ungar column except al am an allemale unit Is presented tothe right of the moult. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except In full, Date: 12/101201905:59 PM without the wdden consent of Pace Analytical services, LLC. Page 19 of 41 aceAnalytical wwx.pawllinges. QUALITY CONTROL DATA Project: ROSE HILL MW 11-12-19 Pace Project No.: 92453264 METHODBLANK'. 2753743 Aasociated Lab Samples: 92455259001 Parameter Units Matrix: Blank Result Water Reporting Limit Analyzed Bassani..1,3-butediene ug/L NO 2.0 12/09/1912:57 Isopropylbenzene (Cumene) ug/L NO 0.50 1210911912:57 m&p-Xylene ug/L ND 1.0 12/0911912:57 Methyl-tert-butyl ether ui ND 0.50 12109/19 12'57 Methylene Chloride ui ND 2.0 12/0911912:57 n-Butylbenzene poll- ND 0.50 1VO911912:57 n-Propylbenzene ug/L NO 050 12109/1912:57 Naphthalene ug/L ND 2.0 1210911912:57 o-Xylene ug/L ND 0.50 12/09/19 12:57 secBulylbenzene ug/L NO 0.50 12/09/1912:57 Styrene ug/L ND 0.50 12109/1912:57 tart-Butylbenzene ug1L ND 0.50 12109/1912:57 TeVachlomelhene ug1L NO 0.50 12I09/1912,57 Toluene poll- ND 0.50 1210911912:57 trans-1,2-Dichlomethene poll- ND 0.50 1210911912:57 trans-1,3-Dichloropropene ug/L ND 0.50 1210911912:57 Trichloroethene son- ND 0.50 1VO9119 12:57 Trichloromoromethane ug/L ND 1.0 1VO911912:57 Vinyl chloride ug/L ND 1.0 12/09/19 12:57 1,2-Dichloraethane-b4(S) or 101 70-130 12/09/19 1257 4-9romofiuorobencome(S) % 104 70-130 12/09/1912:57 Toluene-b9(S) % 97 70-130 12/09/19 12:57 Qualifiers LABORATORY CONTROL SAMPLE: Parameter 2753744 Units Spike Conc. LCS Result LCS %Rec %Rec Limits 1,1,1,2-Tetrachioroethane ug/L 50 52S 105 60-140 1,1,1-Trichloroethane ug/L 50 50.3 101 60-140 1,1,2,2-Tetrachloroethane ug/L 50 51.1 102 60-140 1,1,2-Trichloroethane ug/L 50 50.0 100 60-140 1,1-Dichloroethane ug/L 50 47.5 95 60-140 1,1-Dlchloroethene ug/L 50 51.1 102 60-140 1,1-Dichloropropene ug/L 50 51.9 104 60-140 12,3-Trichlorobenzene ug/L 50 53.0 106 60-140 1,2,3-Trichloropropane ug/L 50 53.4 107 60-140 1,2,4-Trichlorobenzene ug/L 50 53.2 106 60-140 1,2,4-Trimethylbenzene ug/L 50 50.4 101 60-140 1,2-Dibromo-3-chloropropane ug/L 50 54.6 109 60-140 1,2-Dibromoethane (EDB) ug/L 50 51.5 103 60-140 1,2-Dichlorobenzene poll- 50 50.9 102 60-140 1,2-Dichloroethane ug/L 50 46.5 93 60-140 1,2-Dichlompropane ui 50 49.5 99 60-140 1,3,5-Trimethylbenzene ug/L 50 51.3 103 60-140 1,3-Dichlorobenzene ug/L 50 493 99 60-140 Pace Analytical Barrettes, LLC P225 Riverside or. Asheville, NC 28804 (e26)2544176 Qualifiers Refuge Presented on th la page are In the Unlb Ind coned by the"pnital cos nesceptwhere an alternate on It Is presen ed to the right or the reap It. REPORT OF LABORATORY ANALYSIS This repel shall not be reproduced, except in full, Date', 12/101201905:59 PM without the written consent 0 Pace Analytical Services, LLC. Page 20 o141 aceAnalytical www.a..d.bsehln QUALITY CONTROL DATA Project: ROSE HILL MW 11-12-19 Pace Project No.: 92453264 Pace Analytical Services, LLc 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 LABORATORY CONTROL SAMPLE: Parameter 2753744 Units Spike Caac. LCS Result LCS % Rae % Rao Limits Qualifers 1,3-Dichloropropane ug/L 50 50.5 101 60-140 1,4-Dichlorobenzene uga- 50 50.0 100 60-140 2,2-Dichloropropene ug/L 50 50.9 102 60-140 2-Chlorotoluene ugi 50 49.8 100 60-140 4-Chlorotoluene allL 50 50 6 101 60-140 Benzene ug/L 50 50.9 102 60-140 Bromobenzene ug/L 50 51 4 103 60-140 Bromochloromethane ug/L 50 49.7 99 60-140 Bromodichlommethane ug/L 50 49.7 99 60-140 Bromofonn ug)L 50 55.2 110 60-140 Bromomethane ugh- 50 64.8 130 60-140 Carbon tetrachloride uglL 50 50.4 101 60-140 Chlorobenzene uga- 50 48.8 98 60-140 Chloroethane uglL 50 42.7 85 60-140 Chloroform di 50 481 97 60-140 Chlommethene ug/L 50 49.4 99 60-140 cis-1,2-Dichloroethene ug/L 50 41.6 95 60-140 cis-1,3-Dichloropropene ug/L 50 53S 107 60-14D Dibromochloromethane ug/L 50 53.0 106 60-140 Dibromomethene ug)L 50 48.4 97 60-140 Dichlorodiguoromethane ug/L 50 51.2 102 60-140 Diisopmpyl ether ug/L 50 48.2 98 60-140 Ethylbenzene ugi 50 47.6 85 60-140 Hearchloro-1,3-butadiene ug/L 50 55.0 110 60-140 Isopropylbenzene(Cumene) ugi 50 50.7 101 60-140 nalXylene uglL 100 96.7 97 60-140 Methyl-tert-butyl ether ug/L 50 49.1 98 60-140 Methylene Chloride ug/L 50 46.2 92 60-140 n-Butylbenzene ug/L 50 522 104 60-140 n-Propyibenzene ug/L 50 49.6 99 60L140 Naphthalene ug/L 50 52.9 106 60-140 o-Xylene ug/L 50 487 97 60-140 sec-Butylbenzene ug/L 50 50.6 101 60-140 Styrene ug/L 50 51.6 103 60-140 tert-Butylbenzene ug/L 50 42.5 85 60-140 Tetmichlumethene ug/L 50 48.6 97 60-140 Toluene uga- 50 48.5 97 60-140 trans-1,2-Dichloroethene ugi 50 48.8 98 60-140 trans-1,3-Dichloropropene uglL 50 53.1 106 60-140 Trichloroethene ug/L 50 48.9 98 60-140 Trlchloro0uammethane ug/L 50 40.0 80 60-140 Vinyl chloride ug/L 50 54 8 109 60-140 1,2-Dichloroethane-d4(S) % 106 70-130 4-Bromaguombenzene (S) % 99 70-130 Toluene-de(S) % 98 70-130 R.wIt. pres.m.E REPORT OF LABORATORY ANALYSIS This hi shall hot be reprvtluced, except in full, Date: 121101201905:59 PM without the wanted consent of Pace Analytical Servlcee LTC_ Page 21 of 41 aceAnalytical a shati,eilebsuch QUALITY CONTROL DATA Pace Analytical aervlc99, LLL 2225 Pleased or. Aahevme, NC 28804 (828)254-7178 Project: ROSE HILL MW I1-12-19 Pace Project No.: 92453264 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2753745 2753746 MS MSD 92455701001 Spike Spike MS MSD MS MSD %Rec Parameter Units Result Cone. Cone.. Result Result %Rec %Rec Limits RPD Oual 1,1,1,2-Tetrachloroethane ua1L NO 1000 loco 1050 903 105 80 fi0-140 15 1,1, 1-Trichloroethane ug/L NO 1000 1000 1020 917 102 92 60-140 11 1,1,2,2-Tetrachloroethane ug/L NO 1000 1000 1020 914 102 91 60-140 11 1,1,2-Trichloroethane ug/L NO 1000 1000 971 862 97 86 60-140 12 1,1-Dichloroethane uglL ND 1000 1000 1010 887 101 89 60-140 13 1,1-Dichlaroethene ug/L ND 1000 1000 1070 938 107 94 60-140 13 1,1-Dichloropropene ug/L ND 1000 1000 1090 953 109 95 60-140 13 1,2,3-Trichlorobenzene ug/L ND 1000 1000 1020 919 102 92 60-140 10 1,2,3-Trichlompropane ugi NO 1000 1000 805 713 81 71 60-140 12 1,2,4-Trichlorobenzene ug/L ND 1000 1000 999 900 100 90 60-140 to 1,2,4-Trimethylbenzene ugi 2460 1000 1000 3500 3280 104 82 60-140 7 1,2-Dibrom0-3-chloropropane ualL ND 1000 1000 1010 890 101 89 60-140 13 1,2-Dibromoethane (EDB) ug/L NO 1000 1000 1060 929 106 93 60-140 13 1,2-Dichlorobenzene ug/- NO 1000 1000 1030 897 103 90 60-140 14 1,2-Dichloroethane ug/L 54.0 1000 1000 1010 892 96 84 60-140 13 1,2-Dichloropmpane ug/L ND 1000 1000 1030 908 103 91 60-140 13 1,3,5-Trimethylbenzene ug/L 628 1000 1000 1700 1560 107 93 610-140 9 1,3-Dlchlorobenzene ugh- NO 1000 1000 1020 903 102 90 60-140 12 1,3-Dichlompropane ugdL ND 1000 1000 1020 906 102 91 60-140 12 1,4-Dichlorobenzene ug/L ND 1000 1000 1020 904 102 90 60-140 12 2,2-Dichloropropane ug/L NO 1000 1000 1030 911 103 91 60-140 12 2-Chlorotoluene ug/L ND 1000 1000 1280 1150 128 115 60-140 10 4-Chlorotoluene ugdL NO 1000 1000 1050 914 105 91 60-140 14 Benzene ugi 4990 1000 1000 5880 5620 89 64 60-140 4 Bromobenzene ugli- ND 1000 1000 1040 927 104 93 60-140 12 Bromnchloromethane ug/L NO 1000 1000 1030 898 103 90 60-140 14 Bromodichloromethane ug/L NO 1000 1000 988 878 99 88 60-140 12 Bromoform ug/L NO 1000 1000 1020 990 102 89 60-140 13 Bromomethane ug/L ND 1000 1000 1380 1200 138 120 60-140 14 Carbon tetrachloride ug/L ND 1000 1000 1010 908 101 91 60-140 11 Chlombenzene ui NO 1000 1000 1020 901 102 90 60-140 12 Chloroelhane ug/L ND 1000 1000 984 887 98 89 50-140 10 Chloroform ug/L ND 1000 1000 893 879 89 88 80-140 2 Chloromethane cold- ND 1000 1000 1080 993 106 99 60-140 y cis-1,2-Dichloroethene ug/L NO loco 1000 994 891 99 89 60-140 11 cis-1,3-Dichloropropene ug/L NO 1000 1000 1050 923 105 92 60-140 13 Dibromochlcromethane ug/L ND 1000 1000 1040 906 104 91 60-140 14 Dibromomethane poll- NO 1000 1000 975 862 98 86 60-140 12 Dichlorodi8uoromethane ugg- NO 1000 1000 997 879 100 88 60-140 13 Diisopropyl ether uglL ND 1000 1000 997 867 100 87 60-140 14 Ethylbenzene pall- 2520 1000 1000 3410 3230 89 TO 60-140 6 Hexachloro-1,3-butadiene uglL NO 1000 1000 1070 945 107 94 60-140 12 Isopropylbenzene (Cumene) ug/L 91.9 1000 1000 1130 1000 103 91 60-140 11 m&p-Xylene ug/L 9400 2000 2000 11000 10500 79 56 60-140 4 M1 Methyl-tert-butyl ether ug/L 428 1000 1000 1410 1130 98 70 60-140 22 Methylene Chloride ug/L ND 1000 1000 999 745 100 75 60-140 29 Range presented on this page are In the un151ndicated blithe "Untie." column except where an alternate unit Is presented lathe right or tha result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date'. 12/10/2019 05:59 PM without the wriften consent of Pace Analytical Services. LLC. Page 22 of 41 acemalytical wwd,lingle.e.. QUALITY CONTROL DATA Project: ROSE HILL MW 11-12-19 Pace Project No.: 92453264 Paceanatyticat Seremes, uc 2225 Miserable Or Asheville. NC 29804 (828)25441]8 MATRIX SPIKE & MATRIX SPIKE Parameter DUPLICATE: 2753745 MS 92455701001 Spike Units Result Coal MSD Spike Co... 2753748 MS Result MSD Result MS %Rec MSD %Rec %Rec Limits RPD Qual n-Butylbenzene ug/L NO 1000 1000 1100 983 110 98 60-140 11 n-Propylbenzene ug/L 292 1000 1000 1310 1200 102 91 60-140 9 Naphthalene uglL 764 1000 1000 1750 1670 99 90 60-140 5 o-Xylene utlL 4300 1000 1000 5250 4900 85 61 60-140 seeBulylbenzene uglL NO 1000 1000 1060 921 106 92 60-140 14 Styrene ug/L NO 1000 1000 1080 963 108 96 60-140 12 tert-Butylbenzene ug/L ND 1000 1000 875 762 88 76 60-140 14 Tetrachlcroethene ug/L NO 1000 1000 998 894 100 89 60-140 11 Toluene ug/L 9260 1000 1000 9800 9590 54 33 60-140 2 M1 trans-1,2-DichloroeUene ug/L NO 1000 1000 1030 776 103 78 60-140 28 trans-IS-Dichloropropene ug/L NO 1000 1000 1010 890 101 89 80-140 13 Thchloroethene uglL ND 1000 1000 1010 904 101 90 60-140 11 Trichlorofluoromethane ug/L NO 1000 1000 1010 913 101 91 60-140 10 Mlnyl chloride uglL NO 1000 1000 1080 988 108 99 60-140 9 1,2-Dichloroethane-tlb(S) % 101 102 70-130 4-Blnmofluambenzene (S) % 98 99 70-130 Toluene-rl8 (S) % 98 98 70.130 Results presentee on me page ere In the units Included by the"tRIpV column assert More ea nomad unit Is presented to the right or the result. REPORT OF LABORATORY ANALYSIS This report shell not be Reproduced except in full. Dale: 12/10/2019 05:59 PM wuncut the sadden consent of Pece Analytical Services, I.I.C. Page 23 of 41 aceAnalytical wwa.peeeless.een QUALITY CONTROL DATA Pace Analytical Services, LLC 2225 Riverside or. Asheville, NC 28804 (828)254-71I6 Project: ROSE HILL MW I1-12-19 Pace Project No.: 92453264 QC Batch: 509672 Analysis Method: SM 254OC-2011 QC Batch Method : SM 254OC-2011 Analysis Descriptlom 2540C Total Dissolvetl Settle Associated Lab Samples: 92453264001, 92453264002, 92453264003 METHOD BLANK: 2735337 Matrix: Water Associated Lab Samples: 92453264001, 92453264002, 92453264003 Blank Reaching Parameter Units Result Limit Analyzed Qualifiers Total Dissolved Solitls mg/L ND 25.0 11/15/1908:04 LABORATORY CONTROL SAMPLE: 2735338 Spike LCS LCS %Rec Parameter Units Cone. Result %Rec Limits Qualifiers Total Dissolved Solids mg/L 250 264 106 90-110 SAMPLE DUPLICATE: 2735339 92452972003 Dup Parameter Units Result Result RPD Qualifiers Total Dissolved Solids mi ND ND SAMPLE DUPLICATE: 2735340 92453460002 Dup Parameter Units Result Result RPD Qualifiers Total Dissolved Solids mge- 2540 2400 6 Results presented on in is page are In the no IN indicated by No Units "column aware wfiere an alternate unit le prevented to the right or the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 121101201905:59 PM witheut the written consent of pace Analytical Services,LLC. Page 24 of 41 aceAnalytical a sba'aeahba.wm QUALITY CONTROL DATA Project ROSE HILL MW I1-12-19 Pace Project No.: 92453264 QC Batch'. 511439 Analysis Method: EPA9040C QC Batch Method: EPA 9040C Analysis Description: 904D PH Associated Lab Samples: 92453264001, 92453264002, 92453264003 SAMPLE DUPLICATE: 2743493 92453233003 Dub Parameter Units Result Result RPD Qualllers PH at 25 Degrees C Bid. Units 40 3.9 1 H3 SAMPLE DUPLICATE: 2743494 92453407001 Dup Parameter Units Result Result RPD Qualifiers pH at 25 Degrees C Std. Units 5.7 5.2 10 D6,1-13 Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 2ee04 (628)254 7196 sedans preedi on ale peg. ero In Men at. bass atl by the'I)i column except where an alternate unit Is presented to the right of the reeuX. REPORT OF LABORATORY ANALYSIS This union shall not be reproduced, except in full, Date: 121101201905:69 PM without the written consent of Paw Analytical Services,LLC. Page 25 of 41 aceAnalytical ww.pacelaWspn QUALITY CONTROL DATA Project: ROSE HILL MW 11-12-19 Pace Project No.: 924532M OC Batch: 509118 Analysis Method: SM 9222D-2006 OC Batch Method : SM 9222D-2006 Analysis Description: 9222D Fecal Collform(MF) -AVL Associated Lab Samples: 92453264001, 92453264002, 92453264003 METHOD BLANK: 2732566 Assoclatetl Lab Samples: 92453264001, 924532640 Parameter Units Fecal Coliforms CFU/100 mL Matrix: Water Blank Reporting Result Limit Analyzed Qualifiers NO 1.0 11/1311915:47 SAMPLE DUPLICATE: 2732567 92453192005 Oup Parameter Units Result Result RPD Qualifers Fecal Coliforms CFU1100 mL 33.0 18.0 59 D6 PaceAlmill al 5-es, llc 2225 Rlveraltle D, Asheville, NC 28804 (828)25441I6 seeupa us eenlM mus. page me In IM1e unite InOlcand by the Units column except Mom an cannot. un t Is presented to IM1e right of the result REPORT OF LABORATORY ANALYSIS This report shall not be repmtlucea, except In fun, Date: lVl C120190559PM wiOout Ne written wnsent of Pece Anelytiwl5ervicea, uC. Page 26 of 41 • aceAnalytica! wwe.piothi samd QUALITY CONTROL DATA Pace Analytical Services, LLC 2225 Riveraltle Dr. Asheville, NC 28804 (828)254 7176 Project: ROSE HILL MW I1-12-19 Pace Project No.: 92453264 OC Balch: 510559 Analysis Method: EPA 350.1 Rev 2.01993 QC Batch Method: EPA 350.1 Rev 2.01993 Analysis Description: 350.1 Ammonia Associated Lab Samples: 92453264001, 92453264002, 92453264003 METHOD BLANK: 2739181 Matrix: Water Associated Lab Samples: 92453264001, 92453264002, 92453264003 Blank Reporting Parameter Units Result Limit Analyzed Qualifers Nitrogen,Ammonia mg/L NO 0,10 11/2111906:04 LABORATORY CONTROL SAMPLE: 2739182 Spike LCS LCS %Rec Parameter Units Canc. Result %Rec Limits Qualifers Nitrogen, Ammonia mg1L 5 5.0 99 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2739183 2739184 MS MSD 92453630007 Spike Spike MS MSD MS MSD %Rec Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPO Oual Nitrogen, Ammonia mg1L NO 5 5 5.2 5.2 104 104 90-110 0 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2739185 2739186 MS MSD 92453192002 Spike Spike MS MSD MS MSD %Rec Parameter Units Result Conc. ConcResult Result %Rec %Rec Limits RPD Oual Nitrogen, Ammonia mg/L 19.8 5 5 23.7 23.5 78 74 90-110 1 M1 Results preaeMed an this page are In the unite Indicated by in a"nnce column except meru an Wrionate unit IS prounted to the Ilan M the result. REPORT OF LABORATORY ANALYSIS This mind shall not be repmtluceb, except in full, Date: 121101201905,59 PM without the antics consent 0 Pace Analytical Services,LLC. Page 27 of 41 'J//X aceAnalyitcale / www.pttaleba.ed. QUALITY CONTROL DATA Project: ROSE HILL MW 11-12-19 Pace Project No.: 92453264 OC Batch: 509133 Analysis Method: EPA 353.2 Rev 2.01993 QC Batch Method: EPA 353.2 Rev 2.01993 Analysis Description: 353.2 Wrote +Nitrite, Unples. Associated Lab Samples: 92453264001, 92453264002, 92453264003 METHOD BLANK: 2732668 Matrix: Vander Associated Lab Samples: 92453264001, 92453264002, 92453264003 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Nitrogen, Nitrate mg/L ND 0.040 1111211923:56 Pace Analytical services, LLC 2225 Riverside Or. Ashevi e, NC 28804 (828)254-7178 LABORATORY CONTROL SAMPLE: 2732669 Spike LCS LCS %Rec Parameter Units Cone. Result %Rec Limits Qualifiers Nitrogen, Nitrate mg/L 1.5 1.5 103 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2732670 2732671 MS MSD 92453195002 Spike Spike MS MSD MS MSD %Rec Parameter Units Result Cone. Cone. Result Result %Rec %Rec Limits RPD Oual Nitrogen, Nitrate mg/L NO 1.5 1.5 1.6 1.6 104 104 90-110 0 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2732672 2732673 MS MSD 92453264003 Spike Spike MS MSD MS MSD %Rec Parameter Units Result Can.. Cone. Result Result %Rec %Rec Limits RPD Oust Nitrogen, Nitrate mg/L 1.0 15 15 2.4 2.4 92 91 90-110 1 Results presented an IMs page are In the ua Its Ire tiered by the "bans' column except wham an alternate unit Is presented to Is debt fine event. REPORT OF LABORATORY ANALYSIS This report Mail not be reproduced, except in full. Date: 12110120190559 PM without the written consent of Pace Analytical Services,LLG. Page 28 of 41 aceAnalytical' ww.peNam.wm QUALITY CONTROL DATA Project: ROSE HILL MW I1-12-19 Pace Project No.: 92453264 QC Batch: 509334 Analysis Method: EPA 365.1 Rev 2.01993 QC Batch Method: EPA 365.1 Rev 2.01993 Analysis Description: 365.1 Phosphorus, Total Associated Lab Samples: 92453264001, 92453264002, 92453264003 METHOD BLANK: 2733554 Matrix: Water Associated Lab Samples: 92453264001, 92453264002, 92453264003 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Phosphorus ral ND 0.050 11/1311921:59 Pace Analytical Seevlcee, LLC 2225 Riverside Dr. Asheville, NC 2e804 (629)254-7196 LABORATORY CONTROL SAMPLE: 2733555 Spike LCS LCS %Rec Parameter Units Conc. Result %Rec Limits Qualifiers Phosphorus bull 2.5 2.5 99 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2733556 2733557 MS MSD 92453474001 Spike Spike MS MSD MS MSD %Rec Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual Phosphorus mg/L ND 25 2.5 2.5 2.5 99 99 90-110 0 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2733568 2733659 MS MSD 92453474002 Spike Spike MS MSD MS MSD %Rec Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual Phosphorus mg/L ND 2.5 2.5 2.5 2.5 99 99 90-110 0 Results presented on In Is page are In the units Indlwled by the' units' column except where an alternate unit to Presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shell not be reproduced, except in full, Date: 121101201905:59 PM wnheut the wrimb consent of Pace Analytical Services,LLC. Page 29 of 41 aceAnalytical w w..peetlebereare QUALITY CONTROL DATA Pace Analytical Services, LLC 2225 Riverside or. Albert , NC 28804 (828)254 7176 Project: ROSE HILL MWll-12-19 Pace Project No.: 92453264 QC Batch: 509858 Analysis Method: SM 4500-CI-E-2011 QC Batch Method: SM 4500-CI-E-2011 Analysis Desedittlon: 4500 Chloride Associated Lab Samples: 92453264001, 92453264002, 92463264003 METHOD BLANK: 2736154 Matrix: Water Associated Lab Samples: 92453264001, 92453264002, 92453264003 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Chloride mg/L ND 1.0 11/1511920:13 LABORATORY CONTROL SAMPLE: 2736155 Spike LCS LCS %Rec Parameter Units Conc. Result %Rec Limits Qualifiers Chloride mg/L 20 20.3 101 90-110 MATRIX SPIKE& MATRIX SPIKE DUPLICATE: 2736156 2736157 MS MSD 92453794004 Spike Spike MS MSD MS MSD %Rec Parameter Units Result Cone. Cane. Result Result %Rec %Rec Limits RPD Qual Chloride mglL NO 10 10 9.5 9.6 92 93 90-110 1 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2736158 2736159 MS MSD 92453303001 Spike Spike MS MSD MS MSD %Rec Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RED Qual Chloride mg/L 58 10 10 15.6 15.6 98 99 90-110 0 Results material an this page are In the units Intl rated by the' Units" column except Where an eltemete on It is pneanlad tothe fight of the reeu It. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 121101201905:59 PM without the Modern consent of Pace Analytical Services.LLC. Page 30 of 41 aceAnalytical www.panlill QUALITY CONTROL DATA Pace Analytical Service¢, LL6 2225 Rlvernme Dr. Aah.e lle. NC 28804 (828)254-]1]0 Project: ROSE HILL MW 11-12-19 Pace Project No.: 92463264 QC Balch: 510940 Analysis Method: SM 531 OB-2011 OC Balch Method : SM 531OB-2011 Analysis Description: 5310B TOO Associated Lab Samples: 92453264OD1, 92453264002, 92453264003 METHOD BLANK: 2740860 Matrix: Water Associated Lab Samples: 92453264001, 92453264002, 92453264003 Blank Reporting Parameter Units Result Limit Analyzed Oualifers Total Organic Carbon mglL NO 1.0 17/21/1820'13 LABORATORY CONTROL SAMPLE: 2740861 Spike LCS LCS %Rec Parameter Units Cone. Result %Rec Limits Qualifers Total Organic Carbon mg/L 25 24] 99 9 -wi MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2740862 2740863 MS MSD 92453925056 Spike Spike MS MSD MS MSD %Rec Parameter Units Result Cone. Conn. Result Result %Rec %Rec Unnits RPD Qual Total Organic Carbon ra lL ND 25 25 24.5 24.7 97 98 90-110 1 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2741160 2741161 MS MSD 92454202002 Spike Spike MS MSD MS MSD %Rec Parameter Units Result Cone.. Cone, Result Result %Rec %Rec Limits RPD Dual Total Organic Carbon mglL 1.1 25 25 25.E 25.9 98 99 90-110 1 Results presented on this page an N the uses InOlcated by the "Units" column except Mara an alternate unit Is presented to the dam of the reault. REPORT OF LABORATORY ANALYSIS This repent shall not be reproduced, except in full Date: 12/10/201905:59 PM withoutthe written ceheart of Pace A1a118ca1 Services. LLC. Page 31 of 41 aceAnalytical Mxw.panlaba.com QUALIFIERS Project: ROSE HILL MW I1-12-19 Pace Project No.: 92453264 DEFINITIONS Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (526)254-7176 DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND- Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL-AdjustedMethod Detection Limit. POL- Practical Completion Limit, BE- Recording Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydmzine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded date are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(0) - Matrix Spike (Duplicate) CUP - Sample Duplicate RPD - Relative Percent Difference INC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected Acid preservation may not be appropriate for 2 Chlomethylvinyl ether. A separate vial presented to a pH of 4-5 is recommended in SM46 Chapter for the analysis of Acrolein and Acrylonitrlle by EPA Method 8260. N-Nilrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute, LABORATORIES PASI-A Pace Analytical Services - Asheville PASI-C Pace Analytical Services - Charlotte ANALWE QUALIFIERS US The precision between the sample and sample duplicate exceeded laboratory control limits. HIS Sample was received or analysis requested beyond the recognized method holding time. M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (_CS) recovery. REPORT OF LABORATORY ANALYSIS This report shell not be repmducei except in full, Date: 1211012019055:69 PM without the written conaent or Pace Analytical services LLG. Page 32 of 41 aceAnalytical e ...penhEusm QUALITY CONTROL DATA CROSS REFERENCE TABLE Project ROSE HILL MW 11-12-19 Pace Project No.: 92453264 Lab ID 924532640D1 92453264002 92453264003 92453264004 9245320002 92453264003 92455259001 SU53264001 9NS3264002 9US3264003 9US3264001 ON53264002 92453264003 92453264001 92463264002 92453264003 92453264001 92453264002 9US3264003 9US3264001 924532640D2 92A53264003 9US3264001 92A53264002 92453264003 92463264001 92453264002 92463264003 92453264001 92463264002 92453264003 Sample ID all all all all Resample Ml All it MW-1 all all Mail MW-2 Ml fall fill All h1W-1 MW-2 MW-3B all hill MW-3B all MW-2 MW-3B Mal MW-2 bell Ill Will b1W-3B Date: 1211012019 05:59 PM QC Batch Method SM 6200B SM 6200B SM 6200B SM 254OC-2011 SM 254OC-2011 SM 254OC-2011 EPA9040C EPA9040C EPA9040C SM 92220-2006 SM 92221D-2006 SM 9222D-2006 EPA 350.1 Rev 2.01993 EPA 350.1 Rev 2.01993 EPA 350.1 Rev 2.01993 EPA 353.2 Rev 2.0 1993 EPA 353.2 Rev 2.0 1993 EPA 353.2 Rev 20 1993 EPA 365.1 Rev 2.01993 EPA 365.1 Rev 2.01993 EPA 365.1 Rev 2.01993 SM 4500-CI-E-2011 SM 4500-CI-E-2011 SM 4500-CI-E-2011 SM 5310B-2011 SM 531OB-2011 SM 531OB-2011 Pace Analytical Services, LLC 2225 Riverside or. Asheville, NG 2e804 (020)254-7116 QC Batch Analytical Method 511291 511291 513704 509672 509672 509672 511439 511439 511439 509118 509118 509118 510559 510559 510559 509133 509133 509133 509334 509334 509334 509858 509858 509858 510940 510940 510940 REPORT OF LABORATORY ANALYSIS This report shall not be repmtluced except in full, without the writkn consent of Paca Analytical Services, LLG. SM 9222D-2006 SM 9222D-2006 SM 9222D-2006 Analytical Batch 509119 509119 509119 EPA 365.1 Rev 2.01993 609385 EPA 365.1 Rev 2.01993 509385 EPA 365.1 Rev 2.01993 501 Page 33 of 41 J, 2018 Eme- t R Pani / fiHlldlyllCAly Sample Candid m Upon R.pCl"(gCUR) ge I ofbruary F.CARCCi033Peu a6 Pace Camllnas Uhia Ry mRCE Laboratory receivingsa ples: Asheville Eden Greenwood ❑ Huntersville❑ Raleigh❑ Mechanicsville❑ • client Name: {/ WO# : 92453264 Pra(ect q: Courl¢r: _❑F dEx ❑UPS ❑LISPS ❑Client 1I'II1111I 1111111 ❑Cnmmerdal ♦_(Pace ❑Other._ 92453264 1 Custody Seal Pmsent7 Dyes �N. Seals Intact? ❑yes m(10 � ff// Date/Initials Perron Exmnlning C.rncrt:a4 �) ) ( Packing Material: []Bubble Wrap 21globle Bags ❑Nan. ❑ Other Biological Tissue en7 _ Thermometer. .r..,/ r ,��// n GunlD: li TYpeofle¢: LI t ❑Igae ❑yes ❑No N/A ❑None Cooler Temp(°C): 3A Correction Factor: Add/Subtract(°C) 610 -� Tempshould b to 6°C cooler Temp Corrected (°C :_ � '' rabove , nduelle (]Samples out of ump vileeia Samples on Ice, cooling process hasbegun USDARegolated Sail N/A, water sample) Did samples miracle in a quarantine zone within the United States: CA, NY, or SC (check mam)? Oldsuplesorigheata free, a ferelgnmerce B1tem0loeIY, P.,,Ii,nd Puartn Ricer? MYes FIN. CoCan. on? DIs, rape nry: Chain of Custody Present? vYe"a NoEINA, 1. _. Samplas Mrrmd wdhln Hold Time? +I'JPga No N/A 2. Short Hold Time Analysis (g2hr.t? No 3; RushTurn Around Time RequesteJ_ _es yea . 4 Sufficient Volume? Ye Be N/A S. Correct Containers Used? -Pace Containers Used? - Viess E]Na ❑No QN/A N/A 6. Contalne" Intact? `��Yes ❑Nn N/A J. Dissolved anal sin: Sam les Field Filteredl Yes []No--rl /A 8. Sample Labels Match COC? Induce, Dam/Time/ID/Analysis Matrix: \ _ / es yV ❑No ❑N/A 9. Heads ml celn VOA Via151>5-fimm)? ❑Yesa ❑N/A 10_____ _ up Blank Present? TFip Blank Custody Seals Present? ❑vm- yes - o ❑No ❑N/A N/A 11. COMMENTS/SAMPLE DISCREPANCY Field Data. Required? Ayes IEErvO Let lDoFs il[mntainerr CLIENTNOTIFICATION/RESOLUTION Person contacted: Project Manager SCURF Review: _ Protect Manager SRF Review: Date/Time: Date: — (/ r Date: rr Page 34 of 41 Document Name: Document upriser. February], 2018 + aoonomytmat Sample Condition Upon Maguire (SCURI Page 1 of2 Document No, IFsmodAuthority: _, rr I _ f-CAR-CS-033-Rev.06 Pace Cmolinas Cuai¢y, 0ffl. *Check mark top half of box if pit and/or dechiorination is Project WO# ' 92453264 verified and within the acceptance range for preservation samples. PN: C01 Due Date: 11/26/19 Eaceptions:VOA, Ccliform,TOC, oil and Grease,111/111, (wa[erl 001, 11, CLIENT: 83—RPB "Bottom half of box is to list number of bottle u E E y aceaJ — E —arc. E n — E g E $ Ed �' L d d C f 4dE E O EEE15n E E m E $ g EEan a z ,3 I 2 � � 3 0 5 6 B 9 10 11 12 PH Adjustment Log for Preserved Samples Sample la Tymofitesarvative pH uponreceipt Dertapasamendun adjusted Time pre areffon relined Amoontufe&eservatlem added Leta Noee: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this Rant wlllEe seat to the North Carolina DEHNRCerti0rAm. 061w(La. Ootof hold, ImomeCt preserraf r,mmof temp, Inmrrptl containers. Page 35 of 41 �lpI 1e 0 MiP fit ITEMN E9�t t k�a 3�N a 5l i"<a3a R g �D r Rig rn ass 3Re`�;ge R� a" MAmlx<OOB ue•`emwerimlen) BAMftEiYP¢ �G�GBAB C•COMpj N w t In 9RMPLEi[MP4i cOLLECiION OECONIAINGS M y -Ft [` \N V3 ,l UAPM9BIvaG y aM RN4 q i$ v 112504 -a x _ HNO3 W W NCI tl 4.28 �e NB2S208 j MCNPmI i O'he nw(kd'eb TBtt -a Nf�. +� aS0. 3 ChI Yb x x pswlooA a ' X Amn nls/TOW Phohh.ti k NboborNl r181 PH ` x X X Theby2540C y�h P N I p34j �,�' TEMPInC � HasNuel CM1b�e jYMjYM) 0.ewivetl on ke j4M)SI W Q rJ r coler o IN Samples I (YIN) 1 Page 36 of 41 Uoas ed:Ncvember2'1,2019 " j--�W^�1 iiarnenk Oa vmortNam Field date SNO I t,a�:lot Number. F.Cq[LFI.P0a1-rov.02 Iaewng Autiadty: Peca Hu�.avdle Quality Ofifica Name and Affiliation (Samplee(s):JDJ ' Yar r IField Data Sheet Review: Name and. Affiliation(Inspcctor): 94 Uate: jt-l9-19 By: B2G Well Diameter: _� ar Construction: (iv teel/Staird as Steel) s eA Cod Neer. Total Well Depth: 69 ft MulNpaetoY':©C(Ramw/92)2xA14x2.aEI BN+issr/rr Static Water level: ?�•2�2'' �po�fjj�t Casing Volume: �o� @§]Ions �,/c.d 4. L94a} 'h tf Height of Water Column:,G2At Cal.3 Volumes:,p� @ailons Pump lyd ke� Nye : _ft Purge lnfomation Date Purged:_jL_/.L%/J-L_Start. III Fi d b:w_Purge Rate: Purging Metho d_pa_ p✓n�Total Volume Purged: �' ©.5 gauons,ils) 3amolina Information /'')` Date WIected:_L)•_/lam Iq_ Time Collected: G Agw'/par) Samplingg EquipmerttUsed:(jnO Ins4umerTt ID: to W- 90Z,3 Bottle Type preservation Analysis Required $ a cAA Lbc — ._ ei. rP I�fpa�2kt/fppkuSl _ _ fdiica}Q+N NtI¢.ON SampleTemp(�TinTe' 11 .. Turbidity (ntu):�Tlme: � �.5� . SpeclRc Cortd (u5): �a .5 Tiaw 5emplepH (su)-y�_Time: ��)� ��'�7 _Odor: N7 Time: � 5iy .it>ftgr— "'"— Time:._t_x�. APPeerance: AYI Trme._� S6 "An.,.u- I fnhnr: Tune:..._ WIN m����[�i■�1'L[��■C7■�� FM m ■mmmrF��■��' i Page 37 of 41 .,.+�f baument Neme:ldeld tlala Sheet ]late➢aued:Nwemh f9,1018 1ee101,Autlioriry: PeceFluniereville Quality �,.,PeCa iJecument Number: A-CAR,FLD'001-tev.(R Olflce Name a-11 ed Affiliation (Inspector): I Date: It—l9't9 BY: jai>,C Well Diameter: ' '>` ,�rpa Construction: pyy,,,�r//Steel/Stainless Steel) Total WeIlDeptiu Aati.,a it Multi Factor-:�l'(Redlue/1R)1xa14a9A8jIA) fo4 AAA °Ao Static Water izvet: ft CaeNBVolume:=z'L g91. ee.ey (rear '✓`'aMr✓ Helot o€ Water Column:' Q I?' ft Col. a Volumes: • gallons i Pumpintake:_, —M R I purse InfnimaNnn &P oc ge Finish:'V 37 Purge Aatr. � Purging Metfiod�lnR.drw TotelVolvme Purged: f (gallons s),` i Sampling Information Date Collected:.J"12/-0— Time Collected: 950. (�ey%pm) Bottle Type - Preservation Analysis ft uired r ,�"� k" —Top,d[f/ VC, r4 51c 11 ..-nalfPlai i>zC�aeAN'+ri�, ou,�s HetdMeasarementsf��Ol�ibse``ry Sample TempeC):'1'ime:—L=Tuxbidity(nm) O`T Time: Q Time:�r_.."--Time: /") 0 S.1he.en_ e—Vk•! Sam le H eu) Time. IOW G _Odor. AQTime: • 10 g^^��{u>•Uj�T=_Time. Appearance: f�fA�Time: ... Purged. Tem . pmg Y Film Cond. pH(s.u.) Re ox T%nu)ty olm (V.+outovaad lwa r Other 1. t.C7 'ZH r tz 0. Page 38 of 41 Daument Name: Pleiddele5beet Pega loF /•},-V�V " Ca.WUMfiasl'" Iwua�g Aalh tlty'Pece Hanlemvdle (jJplity Dacommt Number PCAR-PLD-0OYreva nra�e new client'. Loeat(om�„ta,. i �'xo)ect N: j Nemeand ARHlatim (Sample<(s):.I�S `PAce. Field Data $neetReview: Name and AfflHatlon(fuspectox):�fx�r•'^---"'� -Date: (1-\9-1H BY ' Well lnformatimi WellDlameter: Construction: ( 9Stee1/StaWeae Stcel) JAI �l 4lm{'/n.✓./ 7'otel Well Deptb. '/�"1�.�� t Multi Factoc':t' b5_l'(Red:u>/s2)axa.i+xv.asl .l� fir �r of Ww7P RLu4. i Static Water Level._,L'1d ft. Casingvolume:54 Z __gallons ' �[ x7%a ratv.F9atNdxr �.., Height of Water Columm:. "bl It Col.3 Volumes: 1.•. I�_ gallons am w Pump Intake. M� k Fwaelnforma�tt�on ' Date Purged: r. r� Z /,J� $tart:Finiah:, Gvt'19 Purge 'To DR Ors 3 vn� - PingingMethad: 1�2f . . ' Totel Volume Purged: �—�'+'y"'!").' ' i &amoLiafalnfomut� i � ,,��// Date Collected: k), m7d Iq Time Collected: W"9'Pm) Heals Type - preservation Analysis Required G 4 rQ�*' dmjv�lh Gtl$r .:N_kk Nid(='yam tFi MNessus en t Obs ry a ^ C G Sample Temp'CK,-g1Yma. Q9�5 Turbidity (ntu): �(� Time: Dias Oxy(mg/I): " Time: Pe 2+mg/G: Specific Cond.(uS): a Time:Q6qq Res.d(mg/L)/(Pg/L) s Time Sample pH (s u.):--Time: 9 5 Odox: fU_ Tlnm: 'J•.G— ReDox (mV): ReDox(HHialue):Y$IPmPlus+200mVOther: 'Have — Gmeral/Weetha Obsmatione�R_\��—C•u`�•C �aa�, 77' •komvYcloudV/iam"'dLJl'emo. PP) Wind •t?i (mph) Timm purged Troop. (°C1 D Ox . (m L) Spec. (ub) Cond.PH (s.u.) Dox (V TurMility (ntu) Volume eRonsv wig) water level (it) Other 6 f3. Z. 6 Page 39 of 41 /Y'� Document Nmre: Fleid deb Wrest .PaPaAeaA4leq'' Document Nom6lr. RCA&PGDAWeeV.W Namusnd ARNmkon(Sempler(s); IField DemSheetReviaw; .. Nemmand Afiflati (Enspector)• Ait9•'•—•— . Dp 71/J(�, By.. Well lnlmmatWDam: WeRM M W •. 1 Welt Locked; /NO/Fleslwtount) Well Diameter '2" C - Construction; PVtcel/SteWmpstod) ToWWeUDgpth: ���''�'��'t MttltiFactme•�•(6� mdau/imp,a.lwai. ^ Smtle Man Level• /� • 90 ' �, CeeingVolume:621y,_gallons. Heiglet of Water Colunwil_d/ ft CaL 3 Voluinn; geilons P—P Intake• It .. pu�gr elnfaim®tinn . Date Perged•,)I Purging Method: �a;)ef Total Volume Purged: (gall /mtMA) . ' �IkpLgglnfmvmtlan .' Date Collected• I I /7J,j Iq°_ T1me Collected.!323—(an U. , F�Ijl MesBwatnente!(}bee allone Semple Temp (dq: ,� 5.3 Time: 1335 : Tu[bidity (nm):. :. Dies OxY(mg/L): ����-(��"Time: — Fe2+mVL: .•lima: Specific Cnnd.(a�.'—qLq _Tlme; I'M3 Res: 0(mg/L)/(pg/W:=_Time•+•—� SamplepH(s.u.): Ttme: Oda I Time: 1' 5 ReDox (mV): Time; Appearance: jaTlmc. 1535 ReDOx(BFiunlee)7S1ProPlus+RQQAV Othe[: Time: -- Stabillrallor(Test I0 a M.0 .. u - ps � ®®�� = .{yam` m UWFMM�N,�'A�w-�� E- e � .. =���r��r-,:��e�0 mm� i i Page 41 of