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WQ0028693_Groundwater Monitoring Report (GW59) November 2019_20191231
GW-59A COMPLIANCE REPORT FORM \ Permit # V� 03a(0 3 (Submit one each monitoring period with Glf=59 rms.) f ✓- I Enter date monitoring results were due. Will this monitoring report (GW-59 and GW-59A) YES NO be submitted after the established due date 2 Was any required information missing on the GW-59 report forms? YES IF the answer to question t or 2 is 'YES' list in the space provided below the well identification numbers) and explain the problems encountered in obtaining the required information. 3 Are any of the monitor wells in need of repair or maintenance (damaged casing, unlocked or missing cap, missing YES Ne identification plate, area overgrown, etc.)? If the answer is "Yes", contact the Regional Ofcejor guidance. 4 Are any monitored constituents equal to or above the established standards? YES If the answer to question 4 is "NO", skip to section 8. If the answer to question 4 is "YES" list the affected wells individually with constituents) and concentration(s) exceeding standards in the space provided below: 5 For the constituents identified in question 4 above, have standards been exceeded previously for the YES NO same constituent(s) in the same wells) in the last two years? If the answer to question 5 is "NO", skip to section 8. If the answer to question 5 is "YES", list in the space provided below, each well with constituents) exceeding standards, concentration(s) reported, and sample collection date for each occurrence (for the last two years). JAN 0 3 2020 6 Are the monitoring wells listed in section 5 located at or beyond the review boundary? YES NO If the answer is "YES", a groundwater quality problem maybe occurring. CONTACT THE REGIONAL OFFICE IMMEDIATELY FOR GUIDANCE. If the answer is "NO", monitoring wells maybe improperly located; contact the Regional Office. 7 Is the permittee Implementing previously approved actions required by the Division Involving this YES NO groundwater quality problem? If the answer to question 7 is 'YES" describe those actions in the space provided below. If the answer to question 7 is "NO", contact the Regional Office within 90 days: an evaluation maybe o required to determine the Impact the waste disposal system is having at the review and compliance boundaries surrounding this facility. Failure to do so may subject the permittee to a Notice of Violation.> ' fines, and/orpena/ties. ro c.a C, m �> c_r g The person completing this portion (GW-59A) of the monitoring report should sign below and submit this, form with GW-59 forms for required wells to the address provided at the top of the current GW-59 form. 1 hereby acknowledgeAfiat the above information was evaluated and the information submitted in this to the a, of report (Compliance po W-59A) is true and complete best of my knowledge. Signature of ermittee (or Authorized Agent) Date /11 GW-59A 12/812993 g t; w m O rn c N } 0 u p w ° O E v 3 a E m L v =3 ❑a w uL N c Cl a ^ M O: o Y 'c a: o .. C . V _0 c 0 o c w o X z ai Z o c g c m o —— g m 5❑ ❑ m m Q .- I �. E E c @ J w N N c .c Z o a s 'n p m z K 0 a c 0 U -° o. 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C:) n w 3 O co N w� '� N W O W a u O) N i v E J F 0 O � "n `r V m y N m E C c i m y z a a O m U m y a Z 7 0 @ O mm wUw on - o o y m Oa ccm F0 m m 1- U LL F- F oNUD F- �- `o mO w0c ci o N m 2' W O �' O o m Q -: .. o. 3 a 0 LL ' L c a v') N E z W d �] z K > > g z g z a c U Q m ' E" Y F- W 'v v W v J g a m �` a o m c v N c O Q i N LLm y d cy E E m W v m U m W ' Z v" O c z f v 'o m E m K o o a L v o O Q m E .am _ y� E Z m m '' o a Foo v > 3 (7 �' E Z J Z Z Q N a u z 0 a o c `o E W U U z y n m g �d �' L 3 w m m N'L N fn E 4 w 0 O m W m y N m O O U U N U5 N (o O N29 Q LL O. LL U O y 0 0 Y n n 7 �€ 10 J m ❑ Wy}v E uuiv -` � ❑ r N U L S N U it �- W Q' A O Y C 1 O M ,d. OF o o o O W o R z {' — — 0 c M O c o ma❑ m .. ❑"10 v o .a _— v E E J Q Y o _U L Z E E a `m o c <j Q=# ### . w O❑❑❑❑ E E E E M Q K E a U o 3" W U o U L d ro No p ri E C) E ❑ o= N U T C y Q F n v J�co O u `m Yn z c p E m a LL o (n a 0 z z a m aN QaU ayWW J � (n O K O CZ°� ❑` ay❑©❑❑w o' a� a z z r J I O) OI \OI OI OI Ol W OI Ol Ol OI OI O U) E E E E E E E E E E E E E E E E E E E E W a O Z M V a e ❑ Y o 0 M€ c r 0 o m v N I I M c Q i a — } v 2 O N ni w v 10 0 ❑ om d o Y a m E v m Co c N y N m J J m J O p O J N Y O N N U❑ a W E E` N 10 l0 d C� 'U E I-' d i N N C U LL _ pzO U ZO mm' Z Z o Q a i Z m o 0 m u c o m m m m u mU EU Z o 0 U F ❑ K N m J Z z F O C O C -0 O y L O u U O ❑ a a Q N c v .T. n v fn O - o 0>'C mOIrnrnOI L OIL - - Ol m i C7 w�C a Olq c W > NOIoo f E E E E E E E E Z 3 o y E ❑ o o o(o O m Cl) m y o co V v _ a oro(a E z o om�O 02 p a m 3 0 0 2 f }2 U. v,. M E(oo roo u `-v J F- ono `w a _ za rlrl au N N r C Z u �O m0w c � m w p a v r>❑m r ui O 0 mo o 0 o oUvghovvmq v O a p° c 'c E Oa c 0] E F v N H U 11' F- F. N F- o v y O W �-' o N U .0 O m Y,,, .. �- d 6 E �' a v 0 W p W iri T m = I`I a c L O m a (n u Z E c z uj 2 v d m z g E v U Q .c u F W a m w v w o. = a 10 m Q o F C C y _ Z m d o c z j m E y� o a r w o. 'Z C] Q m d E m m z r a a w n FW- o w`o o d > 3 (7 c. F E 4 Z Q EO a z m LLIU O a a 7 0. L Z o q 0 w 3 m m m g 02 'E lt/1 J a J L N E- N o N R d'om `m mCj o m aw m v m o m mQ `c U U W a u U 3❑ U) ❑ a u IceAnalyfical' b .patelalnxom December 10, 2019 Mr. Robert Barr RPB Systems Inc. P.O. Box 1325 Asheville, NC 28802 RE: Project: MTN TOP MW 11-25-19 Pace Project No.: 92455139 Pace Analytical services, LLC 2225 Riverside Or Asheville, NC 28804 (828)254-7176 Dear Mr. Barr: Enclosed are the analytical results for sample(s) received by the laboratory on November 25, 2019. The results relate only to the samples included in this report. Results reported herein conform to the most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. If you have any questions concerning this report, please feel free to contact me. Sincerely, 4- Chris Derouen christopher.derouen@pacelabs.com (828)254-7176 Project Manager Enclosures REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, I-C. Page 1 of 33 aceAnalytical www.pacelabs.wm I Project: MTN TOP MW 11-25-19 Pace Project No.: 92465139 Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Pace Analytical Services Charlotte 9800 Kincey Ave. Ste 100. Huntersville, NC 28078 Louisiana/NELAP Certification # LA170028 North Carolina Drinking Water Certification #: 37706 North Carolina Field Services Certification #: 5342 North Carolina Wastewater Certification #: 12 Pace Analytical Services Asheville 2225 Riverside Drive, Asheville, NC 28804 Flodda/NELAP Certification #: E87648 Massachusetts Certification #: M-NC030 North Carolina Ddnkinq Water Certification #: 37712 CERTIFICATIONS South Carolina Certification #: 99006001 Flodda/NELAP Certification #: E87627 Kentucky UST Certification #: 84 Yrginia/VELAP Certification M 460221 North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001 Vrginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytcal Services, LLC. Page 2 of 33 aceAnalytical www.pacelabs.com SAMPLE ANALYTE COUNT Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Project: Pace Project No.: MTN TOP MW 11-25-19 92455139 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92455139001 MW-01R SM 6200B CL 63 PASI-C SM 254OC-2011 CJL 1 PASI-A EPA 9040C ECH 1 PASI-A SM 9222D-2006 ECH 1 PASI-A TKN+NC3+NC2 Calculation DMN 1 PASI-A EPA 350.1 Rev 2.01993 CJH1 1 PASI-A EPA 351.2 Rev 2.0 1993 MFO 1 PASI-A EPA 353.2 Rev 2.01993 KDF1 1 PASI-A EPA 365.1 Rev 2.01993 NAL 1 PASI-A SM 4500-CI-E-2011 MDW 1 PASI-A SM 531OB-2011 ECH 1 PASI-A 92455139002 MW-2 SM 6200B CL 63 PASI-C SM 2540C-2011 CJL 1 PASI-A EPA 9040C ECH 1 PASI-A SM 9222D-2006 ECH 1 PASI-A TKN+NO3+NO2 Calculation DMN 1 PASI-A EPA 350.1 Rev 2.01993 CJH1 1 PASI-A EPA 351.2 Rev 2.01993 MFO 1 PASI-A EPA 353.2 Rev 2.01993 KDFi 1 PASI-A EPA 365.1 Rev 2.01993 NAL 1 PASI-A SM 4500-CI-E-2011 MDW 1 PASI-A SM 531OB-2011 ECH 1 PASI-A 92455139003 MW-3 SM 6200B CL 63 PASI-C SM 254OC-2011 CJL 1 PASI-A EPA 9040C ECH 1 PASI-A SM 9222D-2006 ECH 1 PASI-A TKN+NO3+NO2 Calculation DMN 1 PASI-A EPA 350.1 Rev 2.01993 CJH1 1 PASI-A EPA 351.2 Rev 2.0 1993 MFO 1 PASI-A EPA 353.2 Rev 2.01993 KDF1 1 PASI-A EPA 365.1 Rev 2.01993 NAL 1 PASI-A SM 4500-CI-E-2011 MDW 1 PASI-A SM 531OB-2011 ECH 1 PASI-A REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 33 aceAnalyiical® www.pacelabs.tom ANALYTICAL RESULTS Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Project: MTN TOP MW 11-25-19 Pace Project No.: 92455139 Sample: MW-01R Lab ID: 92455139001 Collected: 11/25/1913:30 Received: 11/25/1916:10 Matrix:Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Oual Monitoring Well Data Analytical Method: Collected By Joel 1 11/25/19 13:30 Schlaudt Collected Date 11/25/19 1 11/25/19 13:30 Collected Time 13:30 1 11/25/19 13:30 pH 5.6 Std. Units 1 11/25/19 13:30 Temperature 17.1 deg C 1 11/25/19 13:30 Static Water Level 12.75 feet 1 11/25/19 13:30 Specific Conductance 82.9 umhos/cm 1 11/25/19 13:30 Turbidity 308.7 NTU 1 11125/1913:30 Odor NO 1 11/25/19 13:30 Appearance Cloudy 1 11/25/19 13:30 6200E MSV Analytical Method: SM 6200B Benzene NO ug/L 0.50 1 12/06/1918:53 71-43-2 Bromobenzene NO ug/L 0.50 1 12106/1918:53 108-86-1 Bromochloromelhane NO ug/L 0.50 1 12/06/1918:53 74-97-5 Bromodichloromelhane NO ug/L 0.60 1 12106/1918:53 75-27-4 Bromoform NO ug/L 0.50 1 12/06/1918:53 75-25-2 Bromomethane NO ug/L 5.0 1 12106/1918:53 74-83-9 n-Butylbenzene NO ug/L 0.50 1 12106/1918:53 104-51-8 sec-Butylbenzene NO ug/L 0.50 1 1210611918:53 135-98-8 tert-Butylbenzene NO ug/L 0.50 1 12/06/1918:53 98-06-6 Carbon tetrachloride NO ug/L 0.50 1 12/06/19 18:53 56-23-5 Chlorobenzene NO ug/L 0.50 1 12106/1918:63 108-90-7 Chloroelhane NO ug/L 1.0 1 1210611918:63 75-00-3 Chloroform NO ug/L 0.50 1 12106/1918:53 67-66-3 Chloromelhane NO ug/L 1.0 1 1210611918:53 74-87-3 2-Chlorotoluene NO ug/L 0.50 1 1210611918:53 95-49-8 4-Chlorotoluene NO ug/L 0.50 1 12/06/1918:53 106-43-4 1,2-Dibromo-3-chloropropane NO ug/L 1.0 1 12/06/1918:53 96-12-8 Dibromochloromethane NO ug/L 0.50 1 12106/1918:53 124-48-1 1,2-Dibromoethane (EDB) NO ug/L 0.50 1 12/06/19 18:53 106-93-4 Dibromomethane NO ug/L 0.50 1 12106/1918:63 74-95-3 1,2-Dichlorobenzene NO ug/L 0.50 1 12/06/19 18:53 95-50-1 1,3-Dichlorobenzene NO ug/L 0.50 1 12/06/19 18:53 541-73-1 1,4-Dichlorobenzene NO ug/L 0.50 1 12/06119 18:53 106-46-7 Dichlorodifluoromethane NO ug/L 0.50 1 12106/1918:53 75-71-8 1,1-Dichloroethane NO ug/L 0.50 1 12/0611918:63 75-34-3 1,2-Dichloroethane NO ug/L 0.50 1 12/06/1918:53 107-06-2 1,1-Dichloroethene NO ug/L 0.50 1 12106/1918:53 75-35-4 cis-1,2-Dichloroethene NO ug/L 0.50 1 12106/1918:53 156-69-2 trans-1,2-Dichloroethene NO ug/L 0.50 1 1210611918:53 156-60-5 1,2-Dichloropropane NO ug/L 0.50 1 12/0611918:53 78-87-5 1,3-Dichloropropane NO ug/L 0.50 1 12/06/1918:53 142-28-9 2,2-Dichloropropane NO ug/L 0.50 1 12/06119 18:53 594-20-7 1,1-Dichloropropene NO ug/L 0.50 1 12106/1918:53 563-58-6 cis-1,3-Dichloropropene NO ug/L 0.50 1 12/06/19 18:53 10061-01-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/10/2019 08:11 PM without the written consent of Pace Analytical Services, LLC. Page 4 of 33 ® Asheville, NC Pace Analytical Services, LLC aceAnalyfical 2225 Riverside 04 www(a28)254-7176pacelabstom / 7178 ANALYTICAL RESULTS Project: MTN TOP MW 11-25-19 Pace Project No.: 92455139 Sample: MW-01R Lab ID: 92455139001 Collected: 11126/1913:30 Received: 11/2511916:10 Matdx: Water Parameters 6200E MSV trans-1,3-Dichloropropene Diisopropyl ether Elhylbenzene Hexachloro-1,3-butadiene Isopropylbenzene (Cumene) Methylene Chloride Methyl-lert-butyl ether Naphthalene n-Propylbenzene Styrene 1,1,1,2-Tetrachloroethane 1, 1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,2,3-Trichlorobenzene 1,2,4-Trichlorobenzene 1, 1, 1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorolluoromethane 1,2,3-Trichloropropane 1,2,4-Trimethylbenzene 1,3,5-Trimethylbenzene Vinyl chloride m&p-Xylene o-Xylene Surrogates 1,2-Dichloroethane-d4 (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) 2540C Total Dissolved Solids Total Dissolved Solids 9040 pH pH at 25 Degrees C MBIO 9222D Fecal Coliform AVL Fecal Coliforms Total Nitrogen Calculation Total Nitrogen 360.1 Ammonia Nitrogen, Ammonia Date: 12/10/2019 08:11 PM Results Units Analytical Method: SM 6200B Report Limit DF Prepared Analyzed CAS No. Qual ND ug/L 0.60 1 12/06/19 18:53 10061-02-6 ND ug/L 0.50 1 12/06/1918:53 108-20-3 ND ug/L 0.50 1 12/06/1918:53 100-41A ND ug/L 2.0 1 M06/1918:53 87-68-3 ND ug/L 0.50 1 12106/1918:53 98-82-8 ND ug/L 2.0 1 12/06/1918:53 75-09-2 ND ug/L 0.50 1 12/06/19 18:53 1634-04-4 ND ug/L 2.0 1 12106/1918:53 91-20-3 ND ug/L 0.50 1 12106/1918:53 103-65-1 ND ug/L 0.60 1 12/06/1918:53 100-42-5 ND ug/L 0.50 1 12106/1918:53 630-20-6 ND ug/L 0.50 1 12/06/19 18:53 79-34-5 ND ug/L 0.50 1 1210611918:63 127-18-4 ND ug/L 0.50 1 12106/1918:53 108-88-3 ND ug/L 2.0 1 12/0611918:53 87-61-6 ND ug/L 2.0 1 12/06/19 18:53 120-82-1 ND ug/L 0.50 1 12/O6/19 18:53 71-55-6 ND ug/L 0.50 1 12/06/1918:53 79-00-5 ND ug/L 0.60 1 12/O6/1918:53 79-01-6 ND ug/L 1.0 1 12/06/19 18:53 75-69A ND ug/L 0.50 1 12/06/1918:53 96-18-4 ND ug/L 0.50 1 12106/1918:53 95-63-6 ND ug/L 0.50 1 12/06/19 18:53 108-67-8 ND ug/L 1.0 1 12/06/19 18:53 75-01-4 ND ug/L 1.0 1 12/06/19 18:53 179601-23-1 ND ug/L 0.50 1 12/06/1918:53 95-47-6 96 % 70-130 1 12106/1918:63 17060-07-0 99 % 70-130 1 12/06/19 18:53 460-00-4 102 % 70-130 1 12/06/1918:53 2037-26-5 Analytical Method: SM 254OC-2011 62.0 mg/L 25.0 1 11/26/19 21:27 Analytical Method: EPA 9040C 5.7 Std. Units 0.10 1 12/08/19 14:45 H3 Analytical Method: SM 9222D-2006 Preparation Method: SM 9222D-2006 ND CFU/100 mL 100 100 11125/1917:37 11/2611915:48 Analytical Method: TKN+NO3+NO2 Calculation 0.57 mg/L 0.52 1 12110/1911:07 Analytical Method: EPA 350.1 Rev 2.0 1993 0.12 mg/L 0.10 1 1210811912:59 7664-41-7 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, U.C. Page 5 of 33 aceAnalyiical e + Y/NW.p9eet8b7teR I ANALYTICAL RESULTS Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Project: MTN TOP MW 11-25-19 Pace Project No.: 92455139 Sample: MW-01R Lab ID: 92455139001 Collected: 11126/1913:30 Received: 11/26/1916:10 Matrix: Water Parameters 351.2 Total Kjeldahl Nitrogen Nitrogen, Kjeldahl, Total 353.2 Nitrogen, NO2/NO3 unpres Nitrogen, Nitrate 366.1 Phosphorus, Total Phosphorus 4500 Chloride Chloride 5310E TOC Total Organic Carbon Date: 12/10/2019 08:11 PM Results Units Report Limit DF Prepared Analyzed CAS No. Qual Analytical Method: EPA 351.2 Rev 2.0 1993 Preparation Method: EPA 351.2 Rev 2.0 1993 0.50 mg/L 0.60 1 12/07/19 06:45 12/10/19 02:39 7727-37-9 Analytical Method: EPA 353.2 Rev 2.0 1993 0.068 mg/L 0.040 1 11126/1910:41 14797-55-8 Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation Method: EPA 365.1 Rev 2.0 1993 0.49 mg/L 0.050 1 12/02/19 20:40 12/03/19 11:19 7723-14-0 Analytical Method: SM 4500-CI-E-2011 13.5 mg/L 1.0 1 12(03/1918:19 16887-00-6 Analytical Method: SM 531OB-2011 2.9 mg/L 1.0 1 12/09/19 22:44 7440-44-0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 6 of 33 Pace Analytical Services, LLC aceAnalwwytical ® 2225 Riverside 04 � w.pacelabsxora Asheville, NC r (828)254-71767176 ANALYTICAL RESULTS Project: MTN TOP MW 11-25-19 Pace Project No.: 92455139 Sample: MW-2 Lab ID: 92455139002 Collected: 11/25/19 13:60 Received: 11/25/19 16:10 Matrix: Water Parameters Results Units Report Limit OF Prepared Analyzed CAS No. Qua] Monitoring Well Data Analytical Method Collected By Joel 1 11/25/19 13:50 Schlaudt Collected Date 11/25/19 1 11/2511913:50 Collected Time 13:50 1 11/25/19 13:50 pH 6.0 Sid. Units 1 11/2511913:50 Temperature 16.5 deg C 1 11/25/19 13:50 Static Water Level 14.80 feet 1 11/25/19 13:50 Specific Conductance 130.6 umhos/cm 1 11/25/19 13:50 Turbidity 5.0 NTU 1 11/26/1913:50 Odor NO 1 11/25/19 13:50 Appearance Clear 1 11/26/19 13:50 6200B MSV Analytical Method: SM 6200B Benzene NO ug/L 0.50 1 12/06/19 19:11 71-43-2 Bromobenzene NO ug/L 0.50 1 12106/1919:11 108-86-1 Bromochloromethane NO ug/L 0.50 1 12106/1919:11 74-97-5 Bromodichloromethane NO ug/L 0.50 1 12/06/1919:11 75-27-4 Bromoform ND ug/L 0.50 1 12106/1919:11 75-25-2 Bromomelhane NO ug/L 5.0 1 1210611919:11 74-83-9 n-Butylbenzene NO ug/L 0.50 1 12/06/19 19:11 104-51-8 sec-Butylbenzene NO ug/L 0.50 1 1210611919:11 135-98-8 tert-Butylbenzene ND ug/L 0.50 1 12/06/19 19:11 98-06-6 Carbon tetrachloride ND ug/L 0.50 1 12/06/19 19:11 56-23-5 Chlorobenzene ND ug/L 0.50 1 12/06/19 19:11 108-90-7 Chloroethane NO ug/L 1.0 1 12106/1919:11 75-00-3 Chloroform NO ug/L 0.50 1 12/06/19 19:11 67-66-3 Chloromethane ND ug/L 1.0 1 12/06119 19:11 74-87-3 2-Chlorotoluene NO ug/L 0.60 1 12106/1919:11 95-49-8 4-Chlorotoluene NO ug/L 0.50 1 12106/1919:11 106-43-4 1,2-Dibromo-3-chloropropane NO ug/L 1.0 1 12106/1919:11 96-12-8 Dibromochloromelhane NO ug/L 0.50 1 12106/1919:11 12448-1 1,2-Dibromoethane (EDB) ND ug/L 0.50 1 12/06/19 19:11 106-93-4 Dibromomethane NO ug/L 0.50 1 12106/1919:11 74-95-3 1,2-Dichlorobenzene NO ug/L 0.50 1 12/06/19 19:11 95-50-1 1,3-Dichlorobenzene NO ug/L 0.50 1 12/06/19 19:11 541-73-1 1,4-Dichlorobenzene ND ug/L _ 0.50 1 12/06/19 19:11 106-46-7 Dichlorodifluoromethane NO ug/L 0.50 1 12/06/19 19:11 75-71-8 1,1-Dichloroethane ND ug/L 0.50 1 12/0611919:11 75-34-3 1,2-Dichloroethane ND ug/L 0,50 1 12/06/19 19:11 107-06-2 1,1-Dichloroethene ND ug/L 0.50 1 12106/1919:11 75-354 cis-1,2-Dichloroethene NO ug/L 0.50 1 12t06(1919:11 156-59-2 trans-1,2-Dichloroethene NO ug/L 0.50 1 12106/1919:11 156-60-5 1,2-Dichloropropane ND ug/L 0.50 1 12106/1919:11 78-87-5 1,3-Dichloropropane NO ug/L 0.50 1 12106/1919:11 142-28-9 2,2-Dichloropropane ND ug/L 0.50 1 12/06/19 19:11 594-20-7 1,1-Dichloropropene NO ug/L 0.50 1 12106/19 19:11 563-58-6 cis-1,3-Dichloropropene NO ug/L 0.50 1 12/06/19 19:11 10061-01-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/10/2019 08:11 PM without the written consent of Pace Analytical Services, I.I.C. Page 7 of 33 Pace Analytical services, LLC aceAnalytical a 2225 Riverside Dr. Asheville, NC 2880404 unvw.pacelabs.rom (828)254-7176 ANALYTICAL RESULTS Project: MTN TOP MW 11-25-19 Pace Project No.: 92455139 Sample: MW-2 Lab ID: 92455139002 Collected: 11126/1913:50 Received: 11/2511916:10 Matrix: Water Parameters 62008 MSV trans-1,3-Dichloropropene Diisopropyl ether Elhylbenzene Hexachloro-1,3-butadiene Isopropylbenzene (Cumene) Methylene Chloride Methyl-tert-butyl ether Naphthalene n-Propylbenzene Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroetha ne Telrachlomelhene Toluene 1,2,3-Trichlorobenzene 1,2,4-Trichlorobenzene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Tdchloropropane 1,2,4-Tdmethylbenzene 1,3, 5-Tdmethylbenzene Vinyl chloride m&p-Xylene o-Xylene Surrogates 1,2-Dichloroethane-d4 (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) 2540C Total Dissolved Solids Total Dissolved Solids 9040 pH pH at 25 Degrees C 111810 9222D Fecal Coliform AVL Fecal Coliforms Total Nitrogen Calculation Total Nitrogen 350.1 Ammonia Nitrogen, Ammonia Date: 12/10/2019 08:11 PM Results Units Analytical Method: SM 6200B Report Limit DF Prepared Analyzed CAS No. Qual ND ug/L 0.50 1 12/06/19 19:11 10061-02-6 ND ug/L 0.60 1 12106/1919:11 108-20-3 ND ug/L 0.50 1 12/06/19 19:11 100-41-4 ND ug/L 2.0 1 12/06/19 19:11 87-68-3 ND ug/L 0.50 1 1210611919:11 98-82-8 ND ug/L 2.0 1 12/06/1919:11 75-09-2 NO ug/L 0.50 1 12/06119 19:11 1634-04-4 ND ug/L 2.0 1 12106/1919:11 91-20-3 ND ug/L 0.60 1 12/06/19 19:11 103-65-1 ND ug/L 0.50 1 12/06/1919:11 100-42-5 NO ug/L 0.50 1 12/0611919:11 630-20-6 NO ug/L 0.50 1 12106/1919:11 79-34-5 ND ug/L 0.50 1 12/06/19 19:11 127-18-4 ND ug/L 0.50 1 12/06/1919: 11 106-88-3 ND ug/L 2.0 1 12106/1919:11 87-61-6 ND ug/L 2.0 1 12106/1919:11 120-82-1 ND ug/L 0.50 1 12106/1919:11 71-55-6 ND ug/L 0.50 1 M06/19 19:11 79-00-5 ND ug/L 0.50 1 12JO611919:11 79-01-6 ND ug/L 1.0 1 12106/1919:11 75-69-4 ND ug/L 0.50 1 12106/1919:11 96-18-4 ND ug/L 0.50 1 12/O6/1919:11 95-63-6 NO ug/L 0.50 1 12/06/19 19:11 108-67-8 ND ug/L 1.0 1 12106/1919:11 75-01-4 ND ug/L 1.0 1 12106119 19:11 179601-23-1 ND ug/L 0.50 1 12/06/19 19:11 95-47-6 94 % 70-130 1 12106/1919:11 17060-07-0 99 % 70-130 1 1210611919:11 460-00-4 101 % 70-130 1 12/06/19 19:11 2037-26-5 Analytical Method: SM 2540C-2011 97.0 mg/L 25.0 1 11/26/1921:27 Analytical Method: EPA 9040C 6.4 Std. Units 0.10 1 12/08/19 14:51 H3 Analytical Method: SM 9222D-2006 Preparation Method: SM 9222D-2006 NO CFU/100 mL 10.0 10 11/25/19 17:37 11/26/19 15:48 Analytical Method: TKN+NO3+NO2 Calculation 1.9 mg/L 0.52 1 12/10/19 11:07 Analytical Method: EPA 350.1 Rev 2.0 1993 ND mg/L 0.10 1 12/08/19 13:03 7664-41-7 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 8 of 33 aceAnalylical o www.patatabstom ANALYTICAL RESULTS Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Project: MTN TOP MW 11-25-19 Pace Project No.: 92455139 Sample: MW-2 Lab ID: 92455139002 Collected: 11/25/19 13:50 Received: 11/25/19 16:10 Matrix: Water Parameters Results Units Report Limit OF Prepared Analyzed CAS No. Qual 351.2 Total Kjeldahl Nitrogen Nitrogen, Kjeldahl, Total 353.2 Nitrogen, NO2/NO3 unpres Nitrogen, Nitrate 365.1 Phosphorus, Total Phosphorus 4500 Chloride Chloride 5310B TOC Total Organic Carbon Date: 12/10/2019 08:11 PM Analytical Method: EPA 351.2 Rev 2.0 1993 Preparation Method: EPA 351.2 Rev 2.0 1993 NO mg/L 0.50 1 12107/1906:45 1211011902:40 7727-37-9 Analytical Method: EPA 353.2 Rev 2.0 1993 1.9 mg/L 0.040 1 11126/1910:43 14797-65-8 Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation Method: EPA 365.1 Rev 2.0 1993 NO mg/L 0.050 1 12/02/19 20:40 12/03/19 11:21 7723-14-0 Analytical Method: SM 4500-CI-E-2011 6.4 mg/L 1.0 1 1210311918:20 16887-00-6 Analytical Method: SM 531OB-2011 1.3 mg/L 1.0 1 12/09/19 22:59 7440-44-0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytcal Services, LLC. Page 9 of 33 aceAnalytical e / wsmr.peeelebsun I ANALYTICAL RESULTS Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (928)254-7176 Project: MTN TOP MW 11-26-19 Pace Project No.: 92455139 Sample: Ill Lab ID: 92465139003 Collected: 11/2611912:50 Received: 11125/1916:10 Matrix: Water Parameters Results Units Report Limit OF Prepared Analyzed CAS No. Qual Monitoring Well Data Analytical Method: Collected By Joel 1 11/2511912:50 Schlaudt Collected Date 11/25/19 1 11/25/19 12:50 Collected Time 12:50 1 11/25/19 12:50 pH 6.0 Std. Units 1 11/25/1912:50 Temperature 14.3 deg C 1 11/26/19 12:50 Static Water Level 11.89 feet 1 11/25/1912:50 Specific Conductance 95.3 umhos/cm 1 11125/19 12:50 Turbidity 9.7 NTU 1 1112611912:50 Odor NO 1 1112511912:50 Appearance Cloudy 1 11/25/19 12:50 6200E MSV Analytical Method: SM 6200B Benzene NO ug/L 0.50 1 12/06/1919:29 71-43-2 Bromobenzene ND ug/L 0.50 1 1210611919:29 108-86-1 Bromochloromethane ND ug/L 0.50 1 12/0611919:29 74-97-5 Bromodichloromethane NO ug/L 0.50 1 12106/1919:29 75-27-4 Bromoform ND ug/L 0.50 1 12106/1919:29 75-25-2 Bromomethane ND ug1L 5.0 1 12/O6/1919:29 74-83-9 n-Butylbenzene NO ug/L 0.50 1 12106/1919:29 104-51-8 sec-Bulylbenzene NO ug/L 0.50 1 12106/1919:29 135-98-8 tert-Butylbenzene ND ug/L 0.50 1 12/06/19 19:29 98-06-6 Carbon tetrachloride NO ug/L 0.50 1 12/06/19 19:29 56-23-5 Chlorobenzene ND ug/L 0.50 1 12/06/19 19:29 108-90-7 Chloroelhane NO ug/L 1.0 1 12106/1919:29 75-00-3 Chloroform ND ug/L 0.50 1 12/06/19 19:29 67-66-3 Chloromethane NO ug/L 1.0 1 12106/1919:29 74-87-3 2-Chlorololuene NO ug/L 0.50 1 12/06/19 19:29 95-49-8 4-Chlorotoluene ND ug/L 0.50 1 12106/1919:29 106-43-4 1,2-Dibromo-3-chloropropane NO ug/L 1.0 1 12106/1919:29 96-12-8 Dibromochloromethane NO ug/L 0.50 1 12106/1919:29 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 0.50 1 12/06/19 19:29 106-93-4 Dibromomethane ND ug/L 0.50 1 12106/1919:29 74-95-3 1,2-Dichlorobenzene NO ug/L 0.50 1 12/06/19 19:29 95-50-1 1,3-Dichlorobenzene NO ug/L 0.50 1 12/06/19 19:29 541-73-1 1,4-Dichlorobenzene ND ug/L 0.50 1 12/06/19 19:29 106-46-7 Dichlorodi0uoromethane NO ug/L 0.50 1 12106/1919:29 75-71-8 1,1-Dichloroethane NO ug/L 0.50 1 12/06/19 19:29 75-34-3 1,2-Dichloroethane ND ug/L 0.50 1 12/06/19 19:29 107-06-2 1,1-Dichloroethene ND ug/L 0.50 1 12/06/19 19:29 75-35-4 cis-1,2-Dichloroethene NO ug/L 0.50 1 12/06/19 19:29 156-59-2 trans-1,2-Dichloroethene NO ug/L 0.50 1 12106/19 19:29 156-60-5 1,2-Dichloropropane ND ug/L 0.50 1 12/06119 19:29 78-87-5 1,3-Dichloropropane NO ug/L 0.50 1 12106/1919:29 142-28-9 2,2-Dichloropropane ND ug/L 0.50 1 12/06/19 19:29 594-20-7 1,1-Dichloropropene NO ug/L 0.50 1 12/06/19 19:29 563-58-6 cis-1,3-Dichloropropene ND ug/L 0.50 1 12/06/19 19:29 10061-01-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/10/2019 08:11 PM without the written consent of Pace Analytical Services, LLC. Page 10 of 33 ace Analyticato ww.pacalabssem ANALYTICAL RESULTS Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Project: MTN TOP MW 11-25-19 Pace Project No.: 92455139 Sample: MW-3 Lab ID: 92456139003 Collected: 11/25/19 12:50 Received: 11/2611916:10 Matrix: Water Parameters Results Units Report Limit OF Prepared Analyzed CAS No. Qual 6200B MSV trans-1,3-Dichloropropene Diisopropyl ether Ethylbenzene Hexachloro-1,3-butadiene Isopropylbenzene (Cumene) Methylene Chloride Methyl-tert-butyl ether Naphthalene n-Propylbenzene Styrene 1,1,1,2-Tetrachloroethane 1, 1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,2,3-Trichlorobenzene 1, 2,4-Trichlorobenzene 1, 1. 1 -Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane 1,2,4-Tdmethylbenzene 1,3,5-Trimethylbenzene Vinyl chloride m&p-Xylene o-Xylene Surrogates 1,2-Dichloroethane-d4 (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) 2540C Total Dissolved Solids Total Dissolved Solids 9040 pH pH at 25 Degrees C MBIO 9222D Fecal Coliform AVL Fecal Coliforms Total Nitrogen Calculation Total Nitrogen 350.1 Ammonia Nitrogen, Ammonia Date: 12110/201908:11 PM Analytical Method: SM 6200B NO ug/L 0.50 1 12/06/19 19:29 10061-02-6 NO ug/L 0.50 1 1210611919:29 108-20-3 NO ug/L 0.50 1 1210611919:29 100-41-4 NO ug/L 2.0 1 12/06/19 19:29 87-68-3 NO ug/L 0.50 1 12/06/19 19:29 98-82-8 NO ug/L 2.0 1 12/06/1919:29 75-09-2 NO ug/L 0.50 1 12/06/19 19:29 1634-04-4 ND ug/L 2.0 1 1210611919:29 91-20-3 NO ug/L 0.50 1 12106/1919:29 103-65-1 NO ug/L 0.50 1 12/O6/1919:29 100-42-5 ND ug/L 0.50 1 12/0611919:29 630-20-6 NO ug/L 0.60 1 1210611919:29 79-34-5 NO ug/L 0.50 1 12/06/19 19:29 127-18-4 NO ug/L 0.50 1 12/0611919:29 108-88-3 NO ug/L 2.0 1 12106/1919:29 87-61-6 ND ug/L 2.0 1 12/O6/1919:29 120-82-1 NO ug/L 0.50 1 12/06/19 19:29 71-55-6 NO ug/L 0.50 1 12106/1919:29 79-00-5 NO ug/L 0.50 1 12106/1919:29 79-01-6 NO ug/L 1.0 1 12106/1919:29 76-69-4 NO ug/L 0.50 1 12106/19 19:29 96-18-4 NO ug/L 0.50 1 1210611919:29 95-63-6 NO ug/L 0.50 1 12/06/19 19:29 108-67-8 ND ug/L 1.0 1 12/06/19 19:29 75-01-4 ND ug/L 1.0 1 1210611919:29 179601-23-1 NO ug/L 0.50 1 1210611919:29 95-47-6 93 % 70-130 1 12106/1919:29 17060-07-0 97 % 70-130 1 1210611919:29 460-00-4 101 % 70-130 1 12/06/1919:29 2037-26-5 Analytical Method: SM 2540C-2011 66.0 mg/L 25.0 1 11/2611921:27 Analytical Method: EPA 9040C 6.2 Sid. Units 0.10 1 12/08/19 14:34 Analytical Method: SM 9222D-2006 Preparation Method: SM 9222D-2006 NO CFU/100 mL 10.0 10 11/25/19 17:37 11/26/19 15:48 Analytical Method: TKN+NO3+NO2 Calculation 0.63 mg/L 0.52 1 Analytical Method: EPA 350.1 Rev 2.0 1993 NO mg/L 0.10 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, L-C. 12/10/19 11:07 1210811913:05 7664-41-7 H3 Page 11 of 33 ZeAnalXical' i J Wvnv.pacelabsxom ANALYTICAL RESULTS Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (826)254-7176 Project: MTN TOP MW 11-25-19 Pace Project No.: 92455139 Sample: MW-3 Lab ID: 92456139003 Collected: 11/26/19 12:50 Received: 11125/1916:10 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 351.2 Total Kjeldahl Nitrogen Analytical Method: EPA 351.2 Rev 2.0 1993 Preparation Method: EPA 351.2 Rev 2.0 1993 Nitrogen, Kjeldahl, Total NO mg/L 0.50 1 12/07119 06:45 12/10/19 02:41 7727-37-9 353.2 Nitrogen, NO2/NO3 unpres Analytical Method: EPA 353.2 Rev 2.0 1993 Nitrogen, Nitrate 0.63 mg/L 0.040 1 11/26/19 10:40 14797-55-8 365.1 Phosphorus, Total Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation Method: EPA 365.1 Rev 2.0 1993 Phosphorus 0.054 mg/L 0.050 1 12/02/19 20:40 12/03/19 11:22 7723-14-0 4500 Chloride Analytical Method: SM 4500-CI-E-2011 Chloride 4.6 mg/L 1.0 1 12103/1918:21 16887-00-6 5310B TOC Analytical Method: SM 531OB-2011 Total Organic Carbon NO mg/L 1.0 1 12/09/19 23:48 7440-44-0 Date: 12/10/2019 08:11 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 12 of 33 aceAnalytical / vrw .paeolabscom QUALITY CONTROL DATA Project: MTN TOP MW 11-25-19 Pace Project No.: 92455139 QC Batch: 513362 Analysis Method: SM 6200E QC Balch Method: SM 6200B Analysis Description: 6200B MSV Associated Lab Samples: 92455139001, 92455139002, 92455139003 METHOD BLANK: 2752021 Matrix: Water Associated Lab Samples: 92455139001, 92455139002, 92455139003 Blank Reporting Parameter Units Result Limit Analyzed 1.1, 1,2-Telrachloroethane ug/L ND 0.50 12/06/19 18:18 1,1,1-Trichloroethane ug/L ND 0.50 12/0611918:18 1, 1, 2,2-Tetrachloroethane ug/L NO 0.50 12106/1918:18 1,1,2-Trichloroethane ug/L NO 0.50 1210611918:18 1,1-Dichloroethane ug/L NO 0.50 12/06/19 18:18 1,1-Dichloroelhene ug/L ND 0.60 12/06/19 18:18 1,1-Dichloropropene ug/L NO 0.50 12/06/19 18:18 1,2,3-Trichlorobenzene ug/L NO 2.0 1210611918:18 1,2,3-Trichloropropane ug/L NO 0.50 12/06/19 18:18 1,2,4-Trichlorobenzene ug/L NO 2.0 12/0611918:18 1,2,4-Trimethylbenzene ug/L ND 0.50 12106/1918:18 1,2-Dibromo-3-chloropropane ug/L ND 1.0 12106/1918:18 1,2-Dibromoethane (EDB) ug/L NO 0.50 12/06/19 18:18 1,2-Dichlorobenzene ug/L ND 0.50 12/06/19 18:18 1,2-Dichloroethane ug/L ND 0.50 12106/1918:18 1,2-Dichloropropane ug/L ND 0.50 12/O6/19 18:18 1,3,5-Trimethylbenzene ug/L NO 0.50 12/06/19 18:18 1,3-Dichlorobenzene ug/L NO 0.50 12/06/19 18:18 1,3-Dichloropropane ug/L NO 0.50 12/0611918:18 1,4-Dichlorobenzene ug/L NO 0.50 12106/1918:18 2,2-Dichloropropane ug/L ND 0.50 12106/1918:18 2-Chlorotoluene ug/L NO 0.50 12/0611918:18 4-Chlorotoluene ug/L NO 0.50 12/06/19 18:18 Benzene ug/L NO 0.50 12106/1918:18 Bromobenzene ug/L NO 0.50 12/O6/1918:18 Bromochloromethane ug/L ND 0.50 1210611918:18 Bromodichloromethane ug/L ND 0.50 12/06/19 18:18 Bromoform ug/L NO 0.50 12/06/19 18:18 Bromomethane ug/L NO 5.0 12106/1918:18 Carbon tetrachloride ug/L NO 0.60 12106/1918:18 Chlorobenzene ug/L NO 0.50 12/06/1918:18 Chloroethane ug/L ND 1.0 12106/1918:18 Chloroform ug/L NO 0.50 12106/1918:18 Chloromethane ug/L NO 1.0 12106/1918:18 cis-1,2-Dichloroethene ug/L NO 0.50 12106/1918:18 cis-1,3-Dichloropropene ug/L NO 0.50 12/0611918:18 Dibromochloromethane ug/L ND 0.50 1210611918:18 Dibromomethane ug/L ND 0.50 12/06/19 18:18 Dichlorodifluoromethane ug/L NO 0.50 12106/1918:18 Diisopropyl ether ug/L NO 0.50 12/06/19 18:18 Ethylbenzene ug/L NO 0.50 12106/19 18:18 Qualifiers Pace Analytical services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/1012019 08A1 PM without the written consent of Pace Analytical Services, LLC. Page 13 of 33 laceAnalyticale www.pacelehs.csw QUALITY CONTROL DATA Project: MTN TOP MW 11-25-19 Pace Project No.: 92455139 METHOD BLANK: 2752021 Matrix: Water Associated Lab Samples: 92455139001, 92455139002, 92455139003 Blank Reporting Parameter Units Result Limit Analyzed Hexachloro-1,3-butadiene ug/L ND 2.0 12106/1918:18 Isopropylbenzene (Cumene) ug/L ND 0.50 12/06/19 18:18 m&p-Xylene ug/L ND 1.0 12/0611918:18 Methyl-tert-butyl ether ug/L ND 0.50 12/06119 18:18 Methylene Chloride ug/L ND 2.0 12/06/19 18:18 n-Butylbenzene ug/L ND 0.50 12/06/19 18:18 n-Propylbenzene ug/L ND 0.50 12/06/19 18:18 Naphthalene ug/L ND 2.0 12/06/1918:18 o-Xylene ug/L ND 0.50 12/06/1918:18 see-Butylbenzene ug/L ND 0.50 12106/1918:18 Styrene ug/L ND 0.50 1210611918:18 tert-Butylbenzene ug/L ND 0.50 12t06/1918:18 Tetrachloroethene ug/L ND 0.50 12/06/1918:18 Toluene ug/L ND 0.50 12/06/19 18:18 trans-1,2-Dichloroethene ug/L ND 0.50 12/06/19 18:18 trans-1,3-Dichloropropene ug/L ND 0.50 12106/1918:18 Trichloroethene ug/L ND 0.50 12/06/1918:18 Trichlorofluoromelhane ug/L ND 1.0 12106/1918:18 Vinyl chloride ug/L ND 1.0 12/06/19 18:18 1,2-Dichloroethane-d4 (S) % 96 70-130 12106/19 18:18 4-Bromofluorobenzene (S) % 100 70-130 12/06/1918:18 Toluene-d8 (S) % 104 70-130 12/06/19 18:18 Qualifiers LABORATORY CONTROL SAMPLE: Parameter 2752022 Units Spike Cone. LCS Result LIDS % Rec %Rec Limits 1,1,1,2-Tetrachloroethane ug/L 50 43.2 86 60-140 1,1,1-Trichloroethane ug/L 50 42.5 85 60-140 1,1,2,2-Tetrachloroethane ug/L 50 41.4 83 60-140 1,1,2-Trchloroethane ug/L 50 41.7 83 60-140 1,1-Dichloroethane ug/L 50 42.8 86 60-140 1,1-Dichloroethene ug/L 50 42.7 85 60-140 1,1-Dichloropropene ug/L 50 45.5 91 60-140 1,2,3-Trichlorobenzene ug/L 50 42.4 85 60-140 1,2,3-Trichloropropane ug/L 50 40.3 81 60-140 1,2,4-Trichlorobenzene uglL 50 41.7 83 60-140 1,2,4-Tdmethylbenzene ug/L 50 38.6 77 60-140 1,2-Dibromo-3-chloropropane ug/L 50 42.3 85 60-140 1,2-Dibromoethane (EDB) ug/L 50 43.3 87 60-140 1,2-Dichlorobenzene ug/L 50 39.1 78 60-140 1,2-Dichloroethane ug/L 50 41.1 82 60-140 1,2-Dichloropropane ug/L 50 46.2 92 60-140 1,3,5-Trimethylbenzene ug/L 50 41.2 82 60-140 1,3-Dichlorobenzene ug/L 50 38.7 77 60-140 Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Qualifiers Results presented on this page are In the units Indicated by the "Unity' column except where an alternate unit Is presented to the right of the resuh. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Dale: 12/10/2019 08:11 PM without the written consent of Pace Analytical Services, L-C. Page 14 of 33 aceAnalytical nnampaceleb.com QUALITY CONTROL DATA Project: MTN TOP MW 11-25-19 Pace Project No.: 92455139 LABORATORY CONTROL SAMPLE: 2752022 Spike LCS LCS % Rec Parameter Units Conic. Result % Rec Limits 1,3-Dichloropropane ug/L 50 44.3 89 60-140 1,4-Dichlorobenzene ug/L 50 43.5 87 60-140 2,2-Dichloropropane ug/L 50 40.4 81 60-140 2-Chlorotoluene ug/L 50 40.7 81 60-140 4-Chlorotoluene ug/L 50 39.7 79 60-140 Benzene ug/L 50 42.2 84 60-140 Bromobenzene ug/L 50 41.6 83 60-140 Bromochloromethane ug/L 50 42.5 85 60-140 Bromodichloromethane ug/L 50 43.9 88 60-140 Bromoform ug/L 50 43.5 87 60-140 Bromomethane ug/L 50 37.7 75 60-140 Carbon tetrachloride ug/L 50 43.8 88 60-140 Chlombenzene ug/L 50 42.1 84 60-140 Chloroethane ug/L 50 36.0 72 60-140 Chloroform ug/L 50 43.0 86 60-140 Chloromethane ug/L 50 37.2 74 60-140 cis-1,2-Dichloroethene ug/L 50 41.0 82 60-140 cis-1,3-Olchloropropene ug/L 50 43.6 87 60-140 Dibromochloromethane ug/L 50 44.0 88 60-140 Dibromomethane ug/L 50 41.9 84 60-140 Dichlorodifluoromethane ug/L 50 39.0 78 60-140 Diisopropyl ether ug/L 50 43.7 87 60-140 Ethylbenzene ug/L 50 42.6 85 60-140 Hexachloro-1,3-butadiene ug/L 50 40.2 80 60-140 Isopropylbenzene (Cumene) ug/L 50 42.4 85 60-140 m&p-Xylene ug/L 100 83.1 83 60-140 Methyl-tert-butyl ether ug/L 50 43.0 86 60-140 Methylene Chloride ug/L 50 37.5 75 60-140 n-Butylbenzene ug/L 50 42.6 85 60-140 n-Propylbenzene ug/L 50 39.7 79 60-140 Naphthalene ug/L 50 37.5 75 60-140 o-Xylene ug/L 50 41.2 82 60-140 sec-Butylbenzene ug/L 50 39.0 78 60-140 Styrene ug/L 5o 42.5 85 60-140 tert-Butylbenzene ug/L So 35.2 70 60-140 Tetrachloroethene ug/L 50 40.9 82 60-140 Toluene ug/L 50 40.9 82 60-140 trans-1,2-Dichloroethene ug/L 50 42.0 84 60-140 trans-1,3-Dichloropropene ug/L 50 42.3 85 60-140 Tdchloroethene ug/L 50 42.5 85 60-140 Trichlorofluoromethane ug/L 50 41.4 83 60-140 Vinyl chloride ug/L 50 43.9 88 60-140 1,2-Dichloroethane-d4 (S) % 99 70-130 4-Bromofluorobenzene (S) % 100 70-130 Toluene-d8 (S) % 98 70-130 Pace Analytical services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Qualifiers Results presented on this page are in the units Indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12110/2019 08:11 PM without the written consent of Pace Analytical Services, LLC. Page 15 of 33 aceAnalyiical e wum.pacelabs.mm QUALITY CONTROL DATA Project: MTN TOP MW 11-25-19 Pace Project No.: 92455139 Pace Analytical services, LLC 2225 Riverside Dr. Asheville, NC 26604 (828)254-7176 MATRIX SPIKE & MATRIX SPIKE Parameter DUPLICATE: 2752023 MS 92455537004 Spike Units Result Conc. MSD Spike Conc. 2752024 MS Result MSD Result MS % Rec MSD % Rec % Rec Limits RPD Qual 1,1,1,2-Tetrachloroethane ug/L ND 2000 2000 1740 1720 87 86 60-140 1 1,1,1-Trichloroethane ug/L ND 2000 2000 1820 1820 91 91 60-140 0 1,1,2,2-Tetrachloroethane ug/L ND 2000 2000 1690 1620 85 81 60-140 5 1,1,2-Tdchloroethane ug/L ND 2000 2000 1780 1800 89 90 60-140 1 1,1-Dichloroethane ug/L ND 2000 2000 1770 1790 88 90 60-140 1 1,1-Dichloroelhene ug/L ND 2000 2000 1860 1890 93 95 60-140 2 1,1-Dichloropropene ug/L ND 2000 2000 1880 1910 94 96 60-140 2 1,2,3-Trichlorobenzene ug/L ND 2000 2000 1550 1680 77 84 60-140 8 1,2,3-Trichloropropane ug/L ND 2000 2000 1700 1650 85 83 60-140 3 1,2,4-Trichlorobenzene ug/L ND 2000 2000 1700 1690 85 84 60-140 1 1,2,4-Trimethylbenzene ug/L 1960 2000 2000 3820 3670 93 85 60-140 4 1,2-Dibromo-3-chloropropane ug/L ND 2000 2000 1690 1670 85 84 60-140 1 1,2-Dibromoethane(EDB) ug/L ND 2000 2000 1800 1710 90 85 60-140 5 1,2-Dichlorobenzene ug/L ND 2000 2000 1700 1650 85 83 60-140 3 1,2-Dlchloroethane ug/L 78.7 2000 2000 1740 1730 83 83 60-140 1 1,2-Dichloropropane ug/L ND 2000 2000 1940 1950 97 97 60-140 0 1,3,5-Trimethylbenzene ug/L 562 2000 2000 2400 2340 92 89 60-140 3 1,3-Dichlorobenzene ug/L ND 2000 2000 1660 1620 83 81 60-140 2 1,3-Dichloropropane ug/L ND 2000 2000 1800 1780 90 89 60-140 1 1,4-Dichlorobenzene ug/L ND 2000 2000 1840 1790 92 89 60-140 3 2,2-Dichloropropane uglL ND 2000 2000 1540 1500 77 75 60-140 3 2-Chlorotoluene ug/L ND 2000 2000 1840 1800 92 90 60-140 2 4-Chlorotoluene ug/L ND 2000 2000 1730 1670 86 84 60-140 3 Benzene ug/L 5930 2000 2000 7700 8050 88 106 60-140 4 Bromobenzene ug/L ND 2000 2000 1820 1740 91 87 60-140 5 Bromochloromelhane ug/L ND 2000 2000 1780 1760 89 88 60-140 1 Bromodichloromethane ug/L ND 2000 2000 1790 1850 90 92 60-140 3 Bromoform ug/L ND 2000 2000 1750 1690 88 84 60-140 4 Bromomethane ug/L ND 2000 2000 1560 1830 78 92 60-140 16 Carbon tetrachloride ug/L ND 2000 2000 1890 1900 95 95 60-140 0 Chlorobenzene ug/L ND 2000 2000 1820 1750 91 88 60-140 4 Chloroethane ug/L ND 2000 2000 1970 2060 98 103 60-140 5 Chloroform ug/L ND 2000 2000 1780 1790 89 90 60-140 1 Chloromethane ug/L ND 2000 2000 1630 1670 82 84 60-140 2 cis-1,2-Dichloroethene ug/L ND 2000 2000 1770 1780 89 89 60-140 0 cis-1,3-Dichloropropene ug/L ND 2000 2000 1750 1790 87 89 60-140 2 Dibromochloromethane ug/L ND 2000 2000 1810 1700 91 85 60-140 6 Dibromomethane ug/L ND 2000 2000 1710 1730 86 87 60-140 1 Dichlorodifluoromethane ug/L ND 2000 2000 1720 1760 86 88 60-140 2 Diisopropyl ether ug/L 60.5 2000 2000 1830 1810 88 87 60-140 1 Ethylbenzene ug/L 1410 2000 2000 3250 3180 92 88 60-140 2 Hexachloro-1,3-buladiene ug/L ND 2000 2000 1580 1610 79 80 60-140 2 Isopropylbenzene (Cumene) ug/L 61.2 2000 2000 1900 1850 92 89 60-140 3 m&p-Xylene ug/L 5860 4000 4000 9750 9490 97 91 60-140 3 Methyl-tert-butyl ether ug/L 276 2000 2000 2080 2080 90 90 60-140 0 Methylene Chloride ug/L ND 2000 2000 1710 1700 85 85 60-140 0 Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit Is presented to the right of the result REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/10/2019 08:11 PM without the wntten consent of Pace Analytical Services, LLC. Page 16 of 33 (�15'ceAnalyficale vaiw.pacelabsucam QUALITY CONTROL DATA Project: MTN TOP MW 11-25-19 Pace Project No.: 92465139 Pace Analytical services, LLD 2225 Riverside Dr. Asheville, NC 28604 (826)254-7176 MATRIX SPIKE & MATRIX SPIKE Parameter DUPLICATE: 2752023 MS 92455537004 Spike Units Result Conc. MSD Spike Conc. 2752024 MS Result MSD Result MS %Rec MSD %Rec %Rec Limits RPD Qual n-Butylbenzene ug/L ND 2000 2000 1890 1830 94 92 60-140 3 n-Propylbenzene ug/L 164 2000 2000 1900 1840 87 84 60-140 3 Naphthalene ug/L 602 2000 2000 2550 2430 98 91 60-140 5 o-Xylene ug/L 3130 2000 2000 6020 4910 95 89 60-140 2 sec-Butylbenzene ug/L ND 2000 2000 1710 1670 85 84 60-140 2 Styrene ug/L ND 2000 2000 1830 1780 92 89 60-140 3 tert-Butylbenzene ug/L ND 2000 2000 1570 1510 78 76 60-140 3 Tetrachloroethene ug/L ND 2000 2000 1760 1710 88 85 60-140 3 Toluene ug/L 14700 2000 2000 15900 16400 61 87 60-140 3 trans-1,2-Dichloroethene ug/L ND 2000 2000 1800 1800 90 90 60-140 0 trans-1,3-Dichloropropene ug/L ND 2000 2000 1700 1740 85 87 60-140 2 Trichloroelhene ug/L ND 2000 2000 1820 1790 91 89 60-140 2 Trichlorofluoromethane ug/L ND 2000 2000 1890 1930 95 97 60-140 2 Vinyl chloride ug/L ND 2000 2000 1970 1970 98 99 60-140 0 1,2-Dichloroelhane-d4 (S) % 98 99 70-130 4-Bromofluorobenzene (S) % 99 99 70-130 Toluene-d8 (S) % 99 101 70-130 Results presented an this page are In the units indicated by the "Units' column except where an alternate unit is presented to the tight of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/10/2019 08:11 PM without the written consent of Pace Analytical Services, U-C. Page 17 of 33 aceAnalyfical e J www.paealees.cem QUALITY CONTROL DATA Project: MTN TOP MW 11-25-19 Pace Project No.: 92455139 QC Batch: 511969 Analysis Method: SM 254OC-2011 QC Batch Method: SM 254OC-2011 Analysis Description: 2540C Total Dissolved Solids Associated Lab Samples: 92455139001, 92455139002, 92455139003 METHOD BLANK: 2745846 Matrix: Water Associated Lab Samples: 92455139001, 92455139002, 92455139003 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Total Dissolved Solids mg/L NO 25.0 11/26/19 21:26 Pace analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 LABORATORY CONTROL SAMPLE: 2746847 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Total Dissolved Solids mg/L 250 260 100 90-110 SAMPLE DUPLICATE: 2745848 92454834008 Dup Parameter Units Result Result RPD Qualifiers Total Dissolved Solids mg/L 118 117 1 SAMPLE DUPLICATE: 2745849 92465363006 Dup Parameter Units Result Result RPD Qualifiers Total Dissolved Solids mg/L 242 251 4 Results presented on this page are in the units Indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Dale: 12/10/2019 08:11 PM without the written consent of Pace Analytical Services, L-C. Page 18 of 33 ZaOAnalylical / wiampacelabseom QUALITY CONTROL DATA Project: MTN TOP MW 11-25-19 Pace Project No.: 92455139 QC Batch: 513579 Analysis Method: EPA 9040C QC Batch Method: EPA 9040C Analysis Description: 9040 pH Associated Lab Samples: 92455139001, 92455139002, 92455139003 SAMPLE DUPLICATE: 2753164 92454803001 Dup Parameter Units Result Result RPD Qualifiers pH at 25 Degrees C Bid. Units 6.8 6.7 1 H3 SAMPLE DUPLICATE: 2753165 92455461003 Dup Parameter Units Result Result RPD Qualifiers pH at 25 Degrees C Bid. Units 6.9 6.9 0 H3 Pace Analytical services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/10/2019 08:11 PM without the written consent of Pace Analytical Services, -LC. Page 19 of 33 aceAnalyfical e woew.pacelabs.com QUALITY CONTROL DATA Project: MTN TOP MW 11-26-19 Pace Project No.: 92455139 QC Batch: 511696 Analysis Method: SM 9222D-2006 QC Batch Method: SM 9222D-2006 Analysis Description: 9222D Feral Coliform(MF) -AVL Associated Lab Samples: 92455139001, 92455139002, 92455139003 METHOD BLANK: 2744689 Matrix: Water Associated Lab Samples: 92455139001, 92455139002, 92455139003 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Fecal Coliforms CFU/100 mL ND 1.0 11/26/1915:48 SAMPLE DUPLICATE: 2744690 92456025004 Cup Parameter Units Result Result RPD Qualifiers Fecal Coliforms CFU/100 mL 1020 960 6 Pace Analytical services, LLC 2226 Riverside Dr. Asheville, NC 28804 (828)254-7176 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12110/201908:11 PM without the written consent of Pace Analytical Services,LLC. Page 20 of 33 aceAnalyiicale wvw.puNslssan QUALITY CONTROL DATA Project: MTN TOP MW 11-25-19 Pace Project No.: 92455139 QC Batch: 513430 Analysis Method: EPA 350.1 Rev 2.0 1993 QC Batch Method: EPA 350.1 Rev 2.0 1993 Analysis Description: 350.1 Ammonia Associated Lab Samples: 92455139001, 92455139002, 92455139003 METHOD BLANK: 2752420 Matrix: Water Associated Lab Samples: 92455139001, 92455139002, 92455139003 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Nitrogen, Ammonia mg/L ND 0.10 12/O8/19 12:29 Pace Analytical services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)2544176 LABORATORY CONTROL SAMPLE: 2752421 Spike LCS LCS % Rec Parameter Units Cone. Result %Rec Limits Qualifiers Nitrogen, Ammonia mg/L 5 5.0 100 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2752422 2752423 MS MSD 92455352001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Cone. Cone. Result Result % Rec % Rec Limits RPD Qua] Nitrogen, Ammonia mg/L ND 5 5 5.3 5.3 105 106 90-110 1 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2752424 2752425 MS MSD 92465352002 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Cone. Cone. Result Result % Rec % Rec Limits RPD Qual Nitrogen, Ammonia mg/L ND 5 5 5.2 5.3 103 104 90-110 1 Results presented on this page are in the units indicated by the"Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This raport shall not be reproduced, except in full, Date: 12/10/2019 08:11 PM without the written consent of Pace Analytical Services, LLC. Page 21 of 33 aceAnalyfical J www.pacola Its .cam QUALITY CONTROL DATA Project: MTN TOP MW 11-25-19 Pace Project No.: 92455139 QC Balch: 513528 Analysis Method: EPA 351.2 Rev 2.0 1993 QC Batch Method: EPA 351.2 Rev 2.0 1993 Analysis Description: 351.2 TKN Associated Lab Samples: 92455139001, 92455139002, 92455139003 Pace Analytical services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 METHOD BLANK: 2763021 Matrix: Water Associated Lab Samples: 92455139001, 92455139002, 92455139003 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Nitrogen, Kjeldahl, Total mg/L NO 0.50 12110/1902:34 LABORATORY CONTROL SAMPLE: 2753022 Spike LCS LCS % Rec Parameter Units Cone. Result % Rec Limits Qualifiers Nitrogen, Kjeldahl, Total mg/L 10 9.8 98 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2753023 2753024 MS MSD 92455077001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Cone. Cone. Result Result % Rec % Rec Limits RPD Qual Nitrogen, Kjeldahl, Total mg/L 7.0 10 10 16.9 17.5 99 105 90-110 4 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2753025 2753026 MS MSD 92455945002 Spike Spike MS MSD MS MSD %Rec Parameter Units Result Cone. Cone. Result Result % Rec % Rec Limits RPD Qual Nitrogen, Kjeldahl, Total mg/L <0.50 10 10 9.7 9.7 94 93 90-110 0 Results presented on this page are in the units indicated bythe "Units" column exceptwhers an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/10/2019 08:11 PM without the written consent of Pace Analytical Services, LLC. Page 22 of 33 aceAnalytical wurm.pacelabs.com QUALITY CONTROL DATA Project: MTN TOP MW 11-25-19 Pace Project No.: 92455139 QC Batch: 511745 Analysis Method: EPA 353.2 Rev 2.0 1993 QC Batch Method: EPA 353.2 Rev 2.0 1993 Analysis Description: 353.2 Nitrate + Nitrite, Unpres. Associated Lab Samples: 92455139001, 92455139002, 92455139003 METHOD BLANK: 2744859 Matrix: Water Associated Lab Samples: 92455139001, 92455139002, 92455139003 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Nitrogen, Nitrate mg/L ND 0.040 11126/1910:30 Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254JI76 LABORATORY CONTROL SAMPLE: 2744860 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrogen, Nitrate mg/L 1.6 1.5 101 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2744861 2744862 MS MSD 92454828006 Spike Spike MS MSD MS MSD %Rec Parameter Units Result Conic. Conc. Result Result % Rec % Rec Limits RPD Qual Nitrogen, Nitrate mg/L 0.21 1.5 1.5 1.7 1.7 99 99 90-110 0 Results presented on this page are in the units Indicated by one "Units" column except where an alternate unit is Presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Dale: 12/10/201908:11 PM without the written consent of Pace Analytical Services,LLC. Page 23 of 33 ® aceAnalytica{ www.pacalabs.com QUALITY CONTROL DATA Project: MTN TOP MW 11-25-19 Pace Project No.: 92455139 QC Batch: 512439 Analysis Method: EPA 365.1 Rev 2.0 1993 QC Balch Method: EPA 365.1 Rev 2.0 1993 Analysis Description: 365.1 Phosphorus, Total Associated Lab Samples: 92455139001, 92455139002, 92455139003 METHOD BLANK: 2747809 Matrix: Water Associated Lab Samples: 92455139001, 92455139002, 92455139003 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Phosphorus mg/L ND 0.050 12/03/19 11:14 Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 LABORATORY CONTROL SAMPLE: 2747810 Spike LCS LCS %Rec Parameter Units Conc. Result % Rec Limits Qualifiers Phosphorus mg/L 2.5 2.4 97 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2747811 2747812 MS MSD 92455077001 Spike Spike MS MSD MS MSD %Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qua[ Phosphorus mg/L 1.1 2.5 2.5 3.6 3.6 100 100 90-110 0 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2747813 MS MSD 92455139001 Spike Spike Parameter Units Result Conc. Conc. Phosphorus mg/L 0.49 2.5 2.5 2747814 MS MSD Ms MSD % Rec Result Result % Rec % Rec Limits RPD Qual 3.0 2.9 99 98 90-110 0 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/10/2019 08:11 PM without the written consent of Pace Analytical Services, LLC. Page 24 of 33 aceAnalytical www.pacelabs.com f QUALITY CONTROL DATA Project: MTN TOP MW 11-25-19 Pace Project No.: 92455139 QC Batch: 512685 Analysis Method: SM 4500-CI-E-2011 QC Batch Method: SM 4500-CI-E-2011 Analysis Description: 4500 Chloride Associated Lab Samples: 92455139001, 92455139002, 92455139003 Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7178 METHOD BLANK: 2748779 Matrix: Water Associated Lab Samples: 92455139001, 92455139002, 92455139003 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Chloride mg/L NO 1.0 12t03/1918:03 LABORATORY CONTROL SAMPLE: 2748780 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Chloride mg/L 20 21.2 106 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2748781 2748782 MS MSD 92455138002 Spike Spike MS MSD MS MSD %Rec Parameter Units Result Conc. Conic. Result Result % Rec % Rec Limits RPD Qual Chloride mg/L ND 10 10 9.7 9.9 97 99 90-110 2 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2748783 2748784 MS MSD 92454827004 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Chloride mg/L 3.7 10 10 14.3 14.4 105 107 90-110 1 Results presented on this page are in the units indicated by the"Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/10/2019 08:11 PM without the written consent of Pace Analytical Services, LLC. Page 25 of 33 aceAnalyfical o www.pacalabf.cois QUALITY CONTROL DATA Project: MTN TOP MW 11-25-19 Pace Project No.: 92455139 QC Batch: 513755 Analysis Method: QC Batch Method: SM 53108-2011 Analysis Description: Associated Lab Samples: 92455139001, 92455139002, 92455139003 METHOD BLANK: 2754038 Matrix: Water Associated Lab Samples: 92455139001, 92455139002, 92455139003 Blank Reporting Parameter Units Result Limit Analyzed Total Organic Carbon mg/L ND 1.0 12/09/19 18:59 SM 531OB-2011 5310E TOC Qualifiers Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 LABORATORY CONTROL SAMPLE: 2754039 Spike LCS LCS % Rec Parameter Units Cone. Result % Rec Limits Qualifiers Total Organic Carbon mg/L 25 24.3 97 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2754040 2754041 MS MSD 92455679007 Spike Spike MS MSD MS MSD %Rec Parameter Units Result Cone. Cone. Result Result % Rec % Rec Limits RPD Qual Total Organic Carbon mg/L ND 25 25 23.6 23.5 92 92 90-110 0 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2754155 2754156 MS MSD 92455679016 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Cone. Cone. Result Result % Rec % Rec Limits RPD Qual Total Organic Carbon mg/L ND 25 25 23.7 23.7 93 93 90-110 0 Results presented on this page are in the units Indicated by the "Units" column except where an alternate unit is presented to the right or the result. REPORT OF LABORATORY ANALYSIS This report shall not be reprotluced, except in full, Dale: 12/10/2019 08:11 PM without the written consent of Paco Analytical Services, LLC. Page 26 of 33 11�aceAnalyfical e www.pacelab com QUALIFIERS Project: MTN TOP MW 11-25-19 Pace Project No.: 92455139 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. NO - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7178 PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis ofAcrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. LABORATORIES PASI-A Pace Analytical Services - Asheville PAST-C Pace Analytical Services - Charlotte ANALYTE QUALIFIERS H3 Sample was received or analysis requested beyond the recognized method holding time. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Dale: 12/10/2019 08:11 PM without the written consent of Pace Analytical Services, LLC. Page 27 of 33 aceAnalytkal e www.pacelabs.cam QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: MTN TOP MW 11-25-19 Pace Project No.: 92455139 Lab ID 92455139001 92455139002 92455139003 92455139001 92455139002 92455139003 92455139001 92465139002 92465139003 92455139001 92455139002 92455139003 92455139001 92455139002 92455139003 92455139001 Sample ID MW-01 R MW-2 MW-3 MW-01 R MW-2 MW-3 MW-01R MW-2 MW-3 MW-01 R MW-2 MW-3 MW-011R MW-2 MW-3 M W-01 R 92455139002 MW-2 92455139003 MW-3 92455139001 92455139002 92455139003 92455139001 92455139002 92455139003 92466139001 92455139002 92455139003 92455139001 92455139002 92455139003 92455139001 92455139002 92455139003 92455139001 92455139002 92455139003 MW-01R MW-2 MW-3 MW-01 R MW-2 MW-3 MW-01 R MW-2 MW-3 M W-01 R MW-2 MW-3 MW-01R MW-2 MW-3 M W-01 R M W-2 MW-3 Date: 12/10/201908: 11 PM QC Batch Method SM 6200B SM 6200B SM 6200B SM 254OC-2011 SM 2540C-2011 SM 2540C-2011 EPA 9040C EPA 9040C EPA 9040C SM 9222D-2006 SM 9222D-2006 SM 9222D-2006 TKN+NO3+NO2 Calculation TKN+NO3+NO2 Calculation TKN+NO3+NO2 Calculation EPA 350.1 Rev 2.0 1993 EPA 350.1 Rev 2.0 1993 EPA 350.1 Rev 2.0 1993 EPA 351.2 Rev 2.0 1993 EPA 351.2 Rev 2.0 1993 EPA 351.2 Rev 2.0 1993 EPA 353.2 Rev 2.0 1993 EPA 353.2 Rev 2.0 1993 EPA 353.2 Rev 2.0 1993 EPA 365.1 Rev 2.0 1993 EPA 365.1 Rev 2.01993 EPA 365.1 Rev 2.0 1993 SM 4500-CI-E-2011 SM 4500-CI-E-2011 SM 4500-CI-E-2011 SM 531OB-2011 SM 531 OB-2011 SM 531OB-2011 Pace Analytical Services, LLC 2225 Riverside Dr Asheville, NC 28804 (828)254-7176 Analytical QC Batch Analytical Method Batch 513352 513362 513362 511969 511969 511969 513579 513579 513579 511696 511696 511696 513923 513923 513923 513430 513430 513430 513528 513528 513528 511745 511745 511745 612439 512439 512439 512685 512685 512685 513755 513755 513755 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of PaceAnalytical Services, LLC. SM 9222D-2006 511955 SM 9222D-2006 511955 SM 9222D-2006 511955 EPA 351.2 Rev 2.0 1993 EPA 351.2 Rev 2.0 1993 EPA 351.2 Rev 2.0 1993 EPA 365.1 Rev 2.0 1993 EPA 365.1 Rev 2.0 1993 EPA 365.1 Rev 2.0 1993 513829 513829 513829 512483 512483 512483 Page 28 of 33 Mrs u�{ ,2 `+T9 U . F'( c .Y. �S} .... ommm....m am= no momommm MOSOMEM... RAMMIMIMMEOMMON®® Y ■■■e■■■■■©©© ■ ■■.■■■■■■©©©�IN y ME mom MEE m ` , �■■■■■■■■■■■■O■ IM, ■■■■■■■■e■■■ - MEN 9 KL Page 29 of 33 Date Issued: November 27, 2018 Document Name: Field data Sheet Pa : 1 of 1 it6E.41t21ytfCr'11 Issuing Authority: Pace Huntersville Quality � Document Number:F-CAR•FLD-001-mv.02 Office Name and Affiliation (Sampler(s):lS AGQ Field 1a /6,11l Data Sheet Review: Name and Affiliation (inspector): A) £j Well Inforrnallon Well ID: tmV-'ottL Well Locked: (YES/NO JUSk_vtau6i Sri Well Diameter: Construction: tees/StainlesaSteel) Total Well Depth: Multi Factor*:(J W r(Radius/12)2z3.14x7.481 Static Water Level: 12' S £t Casing Volume: 1.09 N gallons Height of Water Column:1c- ,_ -5 ft Cal 3 Volumes: .73 gallons. Pump Intake: M4 ft By: 0, 60- Purge Information Date Purged:-IL--.�V15/—Lo�—_ JLtt� PurgeRate: ld{ Finish: � Pur Rate: Purging Method - Total VolumePurgede gallons Sampling Information Date Collected: 1I /7 Sampling Equipment Bottle Type Time Collected: 1330 (an� Preservation G..a •To /Jny d2 ✓CU Ai 1 sis eq d_ Auk V��,klfp 1 Cd� =f1 G UoG W o Sample Temp (°C): Time: 1330 _Twbidity (ntu): 3C &I Time: j 3 3 C �. Time: i&2+��Tine: Specific Cond. (uS): Z •Z • --Time: Time: Sample pH (s.u.): `J • Time: I33r'/ Odor N(i Time 3✓�__ 3 0 ttaDw4m4'f Time Appearance: C o Time: Re +200mV -- Other: Time Temp.,fi('F). Wind(mph) Sampler Signature:_ Ca�l.ilivhnn Taaf Time Purged Temp. cc)(in( Dig k Cond. pH (s.u.) R ox (m Turbidity (ntu) Volume r oved gallons mig) Water level (ft) Other — rs o o ' 102d 15,- 98, 5. (loos Y Z 61 8 I!C6 4-- 6.3 I Page 30 of 33 Date Issued: November 27, 2018 1^^ Document Name: Field data Sheet Fl gI 1 ceMatylcai` / wing Authority: Pace Huntenville Quality Document Number; F-CAR-FLD-001-rev.02 Office Name and Affiliation Name and Affiliation (Inspector): A)P- Well Information Well ID: M W L Well Locked: li Well Diameter: Construction: Total Well Depth. ft ft Static Water Level:A • g� ft Height of Water Column 2 Z • 5,3 ft Project 41: R L 6 ` MA) D'I'" Field Data Sheet Review: Date: /aJUiil By: YES/NO 7(777777 Multi Factor*: 0. O [`(Radius/12)2 x 3.14 x 7.481 Casing Volume. 3.6 gallons Cal. 3 Volumes: I �, a gallons Pump Intake: Puree Information Date Purged: (I Start, 10 l Finish: f o� Purge Rate Volume Pureed: I (. D •To Z 2y we 3 t,40 c- Sampling Information Date Collected: _/Z5J:_ Time Collected: (3 s� (am ,pm Sampling Equipment Used: B f1 /4� 2 Instrument ro: �STo334 /�tIr9d1 3 Bottle Type Preservation Analysis Required 3x BO mL PAS A)Mr, >(125 rnL P(ASE,c 1� o m ti f X2 o mL PISS r a1 r9c^ mi call,3 rnL. o ),E I goc- P ld Measuremente/Observations 'c I i!a� by 6 W& Sample Temp ("C): I �T.ime: 135.0 Turbidity (ntu): S- O Time: t 3 SG DisgGgc(mg,/r), Time: &I,- Time; ` Specific Cond. (uS): 130.1 Time: 1150 . (mt=/�g/L). '—Time: Sam le pHsu, U Time: 3 O Odor N __Time: 3teSbfc—(nrVj: Time: — Appearance: lce-/ Timer 0 Other: Time: GenerayWeather Observations: K W — sunny loudy/rainy) Temp, ('F) Wind j ` 7•-(mph) -2$ — Stabilization Test 'Rt'�iE��et[.9� r r ■�����l�� Page 31 of 33 F- aGe'a1kl af. `-- Document Name: Field data Sheet Date Issued November 27, 2018 Pa e: 1 ofT' Document Number. F-CAR-FLD-001-rev.02 JoWng Authority. Pace Hunteraville Quality Office Name and Affiliation , Nr- Data Sheet Review: I Name. and Affiliation (Inspector): Af � �� t4 Date: 13I� 1 Iq By: Well lrt%rmation W.- Well Diameter: � Construction: (PVC)fSteel/StainlessStee o(e/r' �sn-s fy o. 6 53 Total Well Depth: �6 ft Multi Pactor-A.1 z- [(Radius/l2)2x3.14x7.48) Static Water Leveh--U-A -._ft Casing Volume: 101,arllo gallons Height of Water Column: 5 5 ft Cal-3 Volumes: 305 e 310 gallons Pump Intake: 150. O f3 g _ f/NScsr�aa o ✓ �° ¢c li o Purgelnformation /o Date Purged: 11 ./ / 25 r q Start. Finish: 2_� 15 Purge Rate: NAL S4�w v� O.Z- S P—Ag/f Pn.�Jao./ Purging Method.-fi a QomP Total Volume Purged: (gallons�S i ca f . i. �y r•a ✓ f 9r. c G/L Sampling Information Date Collected:t_/5/ Sampling Equipment Bottle Type 250 ml. Pl,.cfi,Y— �t(125 mL PI&Sfi^L WL1, Pbst.G 3)eNo m 1, V1oj _ R'X 90 htilr U iAl iel Me asutremente/Observations Time Collected.- I25& (a pm Preservation Nmn.t� ri $•6:1 _ SsJ�m rl�`oso lTa.lt, Pl,�s�fN,rti ao;d +t GL Analysis Re uired PN Ammko /, wN/`1P I rel�1: lB b yoo Sample Temp (°C): __H,_Time: 71 - SC Turbidity (ntu): 11 Time: 125 a �i j _ Time: �— =- Time: 1Z50 — Time: Specifitc Cond: (uS): � Time: ): Sample pH (s.u.): 6 . Time: Odor: N D Time: 1 Z 50 Appearance: Mujq _ Time: l: . R Other: ��� Time: General/WeatherObservations: m W -3 urmy/ loudy/rainy) Temp.-LO (°P) Wind.-L-3_(mph) . Sampler Signature C��AiliveFina T..f V'Time Purged Temp. (°C) s �Y• (m Cond. (US) � pH (s.u) Dox (m Turbidity (ntu) Remo Volume �� / Water level (ft) Other 1135 15.Q 92.9 6.6 )- a q0c) IFT ►4,0 1510 95 6-0wVr 806 IZ.Go 26.z eke 6�.0 5 IL 95- 6.0 31,E IZoc� z.rd g 0 i5.6 0 Iqe Zoe0 IZ o Page 32 of 33 Document Name: Doc7HuntersvOle tIseued: Maech 8, 2019 Field Data Sheet Page?-af l- ar aAaalyticaf° - Document Number: uetng Authority: F-CAR-FLD-001.rev.03 Pace Quality Office Client: 11f Il Location: 1_-c9'le r 1NC— Project: 'QPB — Mt+"�p Well ID: 4N^vjr- 'Rev lewed Date and Stbbllllatlon Test Rad'ell.Diaxsir_ftx h+Tvli3pItcatioscFac:Gox" j a.fi25 a_].t7580 a.UaO ' D.9dr7D a.6-106 MMM'M®Turbidity r , Page 33 of 33