WQ0015487_Industrial Wastewater Pond Closure Requirements_20170403

Iry
Water Resources
Environmental Quality
April 3, 2017
Carl B. Powell
Powell Industries, Inc.
P.O. Box 65
Waynesville, NC 28786
Subject: Closed -Loop Recycle Permit (WQ0015487)
Pond Closure Requirements
Powell Industries, Inc.
Suncrest Chip Mill
Haywood County
Dear Mr. Powell,
ROY COOPER
Governor
MIC14AEL S. REGAN
Secivai,
S. JAY ZIMMERMAN
Director
On January 17, 2017, your legal counsel requested rescission of your current Closed -Loop
Recycle System Permit (WQ0015487) and in the process convert the existing ponds into
stormwater basins.
The purpose of this letter is to inform you of the requirements necessary to close out the
Closed -Loop Recycle System prior to permit rescission. It is important to note that these closure
proceedings will apply to the 0.2-acre upper pond, referred to as the wastewater recycle pond,
and the 0.3-acre pond, referred to as the lower stormwater pond. The lower stormwater pond
is included in these closure proceedings because it was improperly used for the storage of
wastewater and wastewater residuals. The closure requirement for these two ponds will be
based on a Division of Water Resources (DWR) document titled Guidelines for the Closure of
Permitted Wastewater Ponds and Lagoons dated June 22, 2012. A copy of these closure
guidelines is enclosed.
The wastewater recycle pond was originally permitted as a non -discharge system for the
collection of wastewater from the company's wet decking operation. But from its inception, the
wastewater recycle pond was used for the collection of stormwater from the roughly 11-acre
site. Runoff from the chipping mill, log storage yard, maintenance garage area, and access roads
is routed to an open ditch and a number of stormwater drop boxes that discharge directly to
the wastewater recycle pond. Water levels in the wastewater recycle pond were managed by
regularly transferring wastewater to the lower stormwater pond in direct violation of
WQ0015487 permit conditions. While there is no longer a visible outlet to the pond, DWR
'Nothing Compares:''-._.
state orNorth Carolao I Environmental Quality I Water Resources
2090 US, Highway 70, Swannanoa North Carolina 29778
828-296-45M

Carl B. Powell
April 3, 2017
Page 2 of 3
believes that a hydraulic connection exists between the lower stormwater pond and an
adjacent stormwater drain that discharges to Jonathan Creek.
Water samples collected from the wastewater recycle pond by DWR staff and Mountain
Environmental indicate elevated biochemical oxygen demand (BOD), chemical oxygen demand
(COD), total nitrogen, and total phosphorus. In addition, concentrations of toluene, total
phenolic compounds, total suspended solids (TSS), and turbidity exceed the applicable surface
water standards. A copy of the analytical results is enclosed.
Based on these analytical results, the quality of your stormwater would likely exceed the
performance benchmarks (e.g. COD & TSS) contained in the general stormwater permit. The
presence of toluene, phenolic compounds, nutrients, BOD, and turbidity could prohibit the
permitted discharge to Jonathan Creek, a Class C stream with Trout Water designation. It is
highly recommended that you conduct a site audit with a focus on identifying potential waste
streams as well as opportunities to improve stormwater quality.
As part of the closure process, you will be required to dewater the wastewater recycle pond
and remove all wastewater residuals for proper disposal. Sampling of the wastewater residuals
and the native soils beneath the wastewater recycle pond will also be required. An adequate
number of representative and composite samples should be taken and developed respectively.
You will be required to sample for the following parameters:
• Metals — arsenic, cadmium, calcium, chromium, copper, lead, magnesium, mercury,
molybdenum, nickel, selenium, sodium, and zinc
• Nutrients —ammonia nitrogen, nitrate nitrogen, nitrite nitrogen, TKN, and total
phosphorus
• Total phenolic compounds
• Volatile organic compounds
• Semi -volatile organic compounds
Priorto disposal, the wastewater residuals will likely be stored onsite for some extended period
of time and therefore will need to be protected (e.g. tarp) against exposure to rainfall and
erosion. Additionally, you will need to provide documentation verifying the proper disposal of
the wastewater residuals. Please be aware that the wastewater residuals cannot be given away
or land applied without a separate permit.
You will also be required to investigate the hydraulic connection between the lower
stormwater pond and an adjacent stormwater drain that discharges to Jonathan Creek. DWR is
willing to assist with this effort. DWR is proposing that water from the wastewater recycle pond
be transferred to the lower stormwater pond and dosed with an appropriately colored tracking
dye. Conceptually, a discharge will be initiated if the water level in the lower stormwater pond
is raised to within 3 feet of the top of the dam. Powell Lumber will be responsible for

Carl B. Powell
April 3, 2017
Page 3 of 3
transferring the water and DWR will be responsible for dosing the pond with dye and
monitoring the outlet at Jonathan Creek. If a hydraulic connection is confirmed, then the
connection will need to be eliminated before the wastewater recycle permit can be rescinded.
The DWR is interested in being present during the various closure activities. Please keep this
office apprised of your work schedule. More importantly, you will need to contact DWR prior to
transferring any wastewater to the lower stormwater pond. Please do not hesitate to contact
me if you have any additional questions or concerns. I can be reached at [phone] or
brett.laverty@ ncden r.gov.
Sincerely,
L/
Water Quality Regional Operations
Asheville Regional Office
Attached: DWR laboratory data sheets
Pace Analytical laboratory data sheets
Guidelines for the Closure of Permitted Wastewater Ponds and Lagoons
cc: Ago file
cc: Toby Vincent —DEMUR
Bethany Georgoulias - DEMLR
Stan Aiken - DEMUR
Richard Brooks - DEMLR
David Goodrich —DWR
Max Kimel — Mountain Environmental
Billy Clarke - Roberts & Stevens, P.A.

AC29333
Lou. Deah.: POWELL LUMBER4595 JONATHAN CREEK ROAD WAYNESVILLE
Sample In
AC29333
County: Havwnod Collecbr: B LAVIE
Uait10
F—LI
PO Number#
ReOioo: ARO Repod To ARO
Location ID:
IC44POWELL
Data Repented,
b6rz61ID16
River Basin Jonathan one. Collect Date: 0612312016
Priority
ROUTINE
Time Received'.
OB_20
Emergency Wlec[Tlma 16_06
Sample Matrix:
SDRFACEWATER
LebwoRs LoginlD
MSWIFT
COG YeVNhr Yea Semple Depth NA
Loc. Type:
Sto a[w gr_
Delivery Method
NCB
a
Final Repod Date'. Gol
O
WAsrEw,f-rtl �c ecye l6 QaAW
Final Reoort
Report Print Date: T010612016
If this report is labeled preliminary report the results have not been validated.
Do not use for
Regulatory purposes.
Result/
Method Analysis
CAS # Analvte Name
PQL
Quallifer
Units
Reference
Date value
LAB
Sample temperature at receipt by lab
1.9
°C
5125116 TASCENZ01
NUT
NH3 as N in liquid
0.02
0.05
mghL a3N
EPA 350.1 REV
5I25I1s CGREEN
Nitrate as N In liquid
0.02
0.02U
mglL asN
EPA 353.2 REV 2'
5125116 CGREEN
Nitrite as N in liquid
0.01
0.01U
mglL esN
EPA 353.2 REV '
5125116 IDOREEN
1,102+NO3 as N in liquid
0,02
0.02 U
r lL as N
EPA 3532 REV 2
5125116 CGREEN
Phosphorus_ total as P in liquid
0.02
0.52
mall asP
EPA 355.1. REV
5131116 CGREEN
Total Keldahl N as N In liquid
0.2
3.5
mg/Les N
EPA 361.2 REV 2
613116 CGREEN
WET
Chemical Oxygen Demand in liquid
20
230
nxi
Hach 8000
612h16 DOREEN
Grease and Oil In liquid
10
10 U, 12
it lL
EPA 16643
5126116 CGREEN
Bromide
04
0.4U
nalL
EPA 3000 ri1
5/25/16 CGREEN
Chloride
1.0
8.5
mglL
EPA 300.0 rev2.1
5125116 CGREEN
Fluoride
0A
0.4U
nalL
EPA 3000 rev2.1
5/25/16 CGREEN
Sulfate
2.0
3.9
r lL
EPA 300.0 rev2.1
5h25116 CGREEN
Phenolics —Total in liquid 10 800 out. EPA 426.4 REV 1 shone DOREEN
Semivolatile Organics IBNAs) in liquid
83-32-9
Acenaphthere
10
Not detected
uglL
EPA62518270D
613116
CJOHNSON
208-96-8
Acenaphlhylene
20
Not detected
uglL
EPA625182700
Wafts
CJOHNSON
62-533
Aniline
10
Not detected
u01L
EPA625182700
613H6
CJOHNSON
120-127
Anthracene
20
Not detected
o91L
EPA62518270D
613116
CJOHNSON
benzeneaCellC acid
11 Ni
uglL
EPAe251890D
W3116
CJOHNSON
56-55-3
Benzo(a)anthracener
20
Not detected
oglL
EPA62518270D
BO118
CJOHNSON
50-32-8
Benzo(a)pyal
10
Not detected
tight.
EPA62518270D
613116
CJOHNSON
205-99-2
Benzo(b)fluoranthene
10
Not detected
uOhL
EPA625/8270D
60,16
GJOHNSON
191-24-2
Benzo(g,h,i)perylene
20
Not detected
ughL
EPA62518270D
613116
CJOHNSON
207-08-9
Benzo(k)fluoranthene
30
Not detected
ughL
EPA625h82200
Mile
CJOHNSON
65-85-0
Benzoic acid
100
160 P1
uglL
l EPA625h8270D
613116
CJOHNSON
100-51-6
Benzyl alcohol
30
Not detected
tight.
r EPA625/8270D
all
CJOHNSON
111-91-1
Bls(2-chloroethoxy)methane
10
Not detected
u91L
EPA52518270D
613116
CJOHNSON
fli-04-4
Bis(2-chlomethyl)ether
10
Not detected
ughL
EPA62WB270D
613h16
CJOHNSON
39838-32-9
Bis(2-chlomisopmpyl)ether
10
Not detected
uglL
EPA52WB270D
613h16
CJOHNSON
117-81-9
Bis(2-ethylhexypphthalate
30
Not detected
uglL
EPA625h8DOD
613h16
CJOHNSON
WSS Che rmil Laboratory» 1623 Mall Service Display, Raleigh, NC 27699-1623 [phone]
Not Detected" or"U" doae not indicate the sample is one" free but that the analyte is not detected at or ebove the POL.
Page 1 of 6

I 9VC1D11J$, La6amtorySection 9(psufa/Sample Cammemtr/Qmdsfiertpefimtm=
Sample 10: AC29333
CAS #
101-553
Analyte Name
Bromophenyl phenyl ether, 4-
PQL
10
ualifier
Not detected
Units
ag/1-
Reference
EPA625/8270D
Date
B13116
Valli
CJOHNSON
85-68-7
Butylbenzyl phthalate
10
Not detected
ug1L
EPA62WB270D
6/3116
CJOHNSON
59-50-7
Chlom-3-methyl phenol, 4-
10
Not detected
ug/L
EPA62&aVOD
Mile
CJOHNSON
106-47-6
Chloreanlllne, 4-
10
Not detected
uyL
EPA525/82791)
613/15
CJOHNSON
91-587
Chlomnaphthalene, 2-
10
Not detected
uga
EPA625/BVCD
6I3116
CJOHNSON
95-57-6
Chlorophenol, 2-
10
Not detected
ug/L
EPA62WB270D
613116
CJOHNSON
7005-72-3
Chlorophenyl phenyl ether, 4-
20
Not detected
ug1L
EPA625IS270D
W3116
CJOHNSON
218-01-9
Chrysene
20
Not detected
ug1L
EPA525I8279D
613118
CJOHNSON
53-70a
Dlbenzo(a,h)anthracene
20
Not detected
ug/L
EPAS25/8270D
613116
CJOHNSON
132-649
Dibenzofuran
20
Not detected
ug1L
EPA62NBVCD
Will
CJOHNSON
95-50-1
Dichlorobenzene, 1,2-
10
Not detected
ug/L
EPAS2518270D
6/3/16
CJOHNSON
541-711
Dichlorobenzene, 1,3
10
Net detected
ug1L
EPA62NBVCD
6I3/16
CJCHNSON
106-464
Dichlorobenzene, 1,4-
10
Not detected
ug/L
EPA62WB270D
613118
CJOHNSON
W-94-1
Dlchlorobenzldlne, 3,3'-
30
Net detected
ug/L
EPA625I627OD'
W3116.
CJOHNSON
120-83-2
Dichlorophenol, 2,4-
10
Not detected
u9IL
EPA62WB270D
613116
CJOHNSON
84-66-2
Diethyl phthalate
20
Net detected
uyl-
EPA52WO270D
613115
CJOHNSON
131-113
Dlmelhyl phthalate
10
Not detected
ug1L
EPA625/aVOD
6/3/16
CJCHNSON
105-67-9
Dimelhylphenol, 2,4-
10
Not detected
ug1L
EPA62WB270D
513115
CJOHNSON
84-70.2
Di-n-butyl phthalate
20
Not detected
ug1L
EPA625I8270D
6/3N6
CJOHNSON
534-52-1
Dinitro-2-methyl phenol, 4,6-
50
Not detected
ug/L
EPA62518270D
6/3/18
CJOHNSON
51-28-5
Dinitrophenol, 2,4-
50
Not detected J2
ug1L
EPA625/SVDD
6/3N6
CJOHNSON
121-14-2
Dinitrotoluene, 2,4-
20
Not detected
ug/L
EPA62WB270D
6/3/1B
CJOHNSON
606-20-2
Dinitrotoluene, 2,6-
10
Not detected
ug1L
EPA625162]OD
613116
CJOHNSON
117-84-0
Di-n-octyl phthalate
10
Not detected
u9IL
EPA62518270D
W3/16
CJOHNSON
ethyl phenol
9.0 N7
ug1L
EPA625I6270D
6/3/16
CJOHNSON
206.44-0
Fluoranthene ^ -
--20
- Not detected
ug/L
.. EPA62518270D-
e/3116
CJOHNSON-.
88-]3-]
Fluomne
20
Not detected
ug/L
EPA625/6270D
613/16
CJOHNSON
118-74-1
Hexachlerobanzene
20
Net detected
ug/L
EPA625/39OD
613115
CJOHNSON
81-68-3
Hexachlorobutadiene(SV)
10
Not detected
u9IL
EPA625(82]013
WN16
CJOHNSON
77-474
HBxaehlerocyelopentadlene
10
Not detected
ug/L
EPA62513=D
813116
CJOHNSON
69-72-1
Hexachlorcethane
10
Not detected
ug/L
EPA625)890D
813116
CJOHNSON
hydrocinnamic acid
920 N7
eg/L
EPA625(82]0D
6MI16
CJOHNSON
193-39-5
Indeno(1,2,3-cd)pyrene
20
Not detected
ug/L
EPA625I827013
WW16
CJOHNSON
78-59-1
SOphoroOe
10
Not detected
ug/L
EPA62518270D
6MI16
CJOHNSON
methyl pentanoic acid
20 N7
ug/L
EPA62518270D
W3116
CJOHNSON
methyl phenol
260 N1
u9IL
EPA625/8270D
613116
CJOHNSON
91-59-6
Methylnaphthalene, 2-
10
Not detected
uglL
EPA625182700
613116
CJOHNSON
95-48-0
Methylphenol, 2-
10
Not detected
uga-
EPA62WB270D
613/16
CJOHNSON
100-44-5
Methylphenol, 4-
10
Not detected
u9IL
- EPA625182700
613116
CJOHNSON
91-20-3
Naphthalene(SV)
10
Not detected
ug/L
EPA62518270D
613116
CJOHNSON
88-74-4
Nitmaniline, 2-
10
Not detected
u9IL
EPA62518270D
613/16
CJOHNSON
99-09-2
Nitmaniline, 3-
50
Not detected
eg/L
EPA62518270D
613116
CJOHNSON
100.016
Ntroanlline, 4-
50
Not detected
ug/L
EPA62518270D
6I3N8
CJOHNSON
WSS Chemistry Laboratory» 1623 Mail Service Center, Raleigh, NC 22699-1623 [phone]
"Not Detected" or"ll" doas not indices the sample is analyta free butthat the analyte is not betealed at or above the POL.
Page 2 of 6

n/D'KX La6omtory Section
AC29333
CAS#
98-95-3
Analvte Name
Nitrobenzene
PQLualifer
10
Not detected
Units
ug/L
Reference
EPA62518270D
Date
813118
vaiuu beau
CJOHNSON
8875-5
Nitrophenol, 2-
10
Not detected
ugll-
EPAS25182700
6MI16
CJOHNSON
100-02-7
Nitrophenol, 4-
50
Not detected
ug/L
EPA625/8270D
613116
CJOHNSON
621-64-7
N-nilrosodi-n-propylamine
10
Not detected
ug/L
EPA62518270D
613116
CJOHNSON
86-30-6
N-nitrosodiphenylamine
10
Not detected
ug/L
EPA525/8270D
813116
CJOHNSON
�
87-86.5
Pentachlorophenol
30
Not detected
411-
EPA62518270D
6MI16
CJOHNSON
65-01-6
Phenanthrene
20
Not detected
ug/L
EPA825/82700
613/16
CJOHNSON
108-95-2
Phenol
50
210 P1
ug/L
EPA62518270D
613116
CJOHNSON
phenylvaleric acid
9.6 N7
ug/L
EPA625/82700
613116
CJOHNSON
129-00-0
Pyrene
20
Not detected
ug/L
EPA525/8270D
613118
CJOHNSON
120-82-1
Trichlorobenzene, 1,2,4-
10
Not detected
ug/L
EPAS25182700
613116
CJOHNSON
95-954
Trichlorophenol, 2,4,5-
10
Not detected
ug/L
EPA825/82700
W3116
CJOHNSON
88-06-2
TtichlorOphenol, 2,4,6-
10
Not detected
ug/L
EPAS2518290D
613116
CJOHNSON
-valedc acid
24 N7
ug/L
', EPA62518270D °
613116
CJOHNSON
Volatile Organics in liquid
106-93-4
(EDB)1,2-Dibromoethane
1.0
Not detected
ug/L
EPA62418260C
5129/16
CJOHNSON
630-20-6
1, 1,12-Tetrachloroethane
1.0
Not detected
ug/L
EPA624/82600
5127/16
CJOHNSON
91-5578
1, 1, 1-Trichloroethane
1.0
Not detected
ug/L
EPA524/8260C
5127118
CJOHNSON
7934-5
1, 1,2,2-Tetrachloroethane
1.0
Not detected
ug/L
EPAS24182600
SP7116
CJOHNSON
79-00-5
1, 1,2-Trichloroethane
i0
Not detected
uglL
EPA524/8260C
5127116
CJOHNSON
95-34-3
1,1-Dichloroethane
1.0
Not detected
ug/L
EPA62418260C
5127116
CJOHNSON
75-35-4
1,1-Dichloroethene
1.0
Not detected
ug/L
EPA52418260C
5127116
CJOHNSON
563-58-6
1,1-Dichloropropene
1.0
Not detected
ug/L
EPA624/8260C
5129116
CJOHNSON
87-61-6
1,2,3-Trichlorobenzene
1.0
Not detected
ug)L
EPA62418260C
5/27116
CJOHNSON
96-18-4
1,2,3-Tdchloropropane - --
--._.1.0-
Not detected
ug/L -.
EPA624/8260C
--5127116 ,.
.. CJOHNSON ...:
120-82-1
12,4-Trichlorobenzene
1.0
Not detected
ug)L
EPA52418260C
5/27116
CJOHNSON
95-63-6
1,2A-Trlmethylbenzene
1.0
Not detected
ug/L
EPA62VB260C
5127116
CJOHNSON
98-12-8
1,2-Dibromo-3-Chloropropane
2.0
Not detected
ug)L
EPA62418260C
5/27116
CJOHNSON
107-06-2
1,2-Dichloroethane
1.0
Not detected
ug1L
EPA624/8260C
5/27/16
CJOHNSON
78-87-5
1,2-Dichloropropane
1.0
Not detected
ug1L
EPA624/8260C
5/27116
CJOHNSON
108-67-8
1,3,5-Trimethylbenzene
1.0
Not detected
ug1L
EPA62MB260C
5/27/16
CJOHNSON
142-28-9
1,3-Dichloropropane
1.0
Not detected
ug)L
EPA624/8260C
U27116
CJOHNSON
594-20-9
2,2-Dichloropropane
2.0
Not detected
ug1L
EPA62WO260C
5/27/16
CJOHNSON
0548-8
2-Chlorotol0ene
L0
Not detected
ug1L
EPA62418260C
5/27/16
CJOHNSON
105-43-4
4-Chlorolgluene
1D
Not detected
ug1L
EPA62418260C
W27116
CJOHNSON
Alkane5
13 N1
uglL
EPA624/8250C
5127116
GJUHNSUN
7143-2
Benzene
1.0
Not detected
ug1L
EPA6241S260C
W27116
CJOHNSON
io"R-1
Bromobenzene
1A
Not detected
ug1L
- EPA62418260C
5/27/16
CJOHNSON
74-97-5
Bromochloromethane
1.0
Not detected
ug/L
EPA62418260C
5127/16
CJOHNSON
75-22-4
Bromodichloromethane
1.0
Not detected
ug1L
EPA62418260C
5/27/16
CJOHNSON
75-25-2
Bromoform
2.0
Not detected
ug/L
EPA624/8260C
5rz7118
CJOHNSON
24-638
Bromomethane
2.0
Not detected
ug1L
EPA62418260C
5/27/18
CJOHNSON
VASS Chemlaby Laboratory— 1623 Mall Service Center, Raleigh, NC 22699-1623 (919)16]-3908
"Not nobodies' or"U" does not indidate the Sample i5 analyse tree but that the analgle la not reverted at or above the PQL.
Page 3 of 6

XC OWX Latiomtory Section PZpraCts/Sample Comment /Qua Auer Definitions
Sample 10: AC29333
CAS#
56-23-5
Analyte Name
Carbon Tetrachloride
PQL
1.0
ualifer
Not detected
Units
ug(L
Reference
EPA62418260C
Date
5/27I16
Validated by
CJOHNSON
108-9e-7
Chlorobenzene
1.0
Not detected
ug/L
EPA6241826OG
5/27116
CJOHNSON
75-00-3
Chloroethane
2.0
Not detected
.,IL
EPA62418260C
S127116
CJOHNSON
67-6e3
Chloroform
1.0
Not detected
eg/L
EPA62418260C
5/27116
CJOHNSON
74-87-3
Chloromethane
2.0
Not detected
uglL
EPA62418260C
5127116
CJOHNSON
156-59-2
cis-1,2-Dichlorcethene
1.0
Not detected
u9IL
EPA62418260C
5127116
CJOHNSON
10081-01-5
cis-1,3-Dichloropropene
2.0
Not detected
ug/L
EPA62418260C
5127116
CJOHNSON
12448-1
Dlbromochloromethane
2.0
Not detected
ugi
EPA62418260C
5127116
CJOHNSON
749E-3
Dibromomethane
1.0
Not detected
ug/L
EPA62416260C
5127116
CJOHNSON
75-71-6
Dichlorodlfluoromethane
2.0
Not detected
ug/L
EPA52418250C
5127116
CJOHNSON
Dimethyl sulfide
14 N7
ug/L
EPA624/8260C
5127/16
CJOHNSON
100-41-4
Ethylbenzene
1.0
Not detected
ug11-
EPA524/8280C
5127116
GJOHNSON
87-68-3
HBXachlorobotadlene
1.0
Not detected
u,IL
EPA624I62803
5W/16
CJOHNSON
98-82-8
)sopropylbenzene
1.0
Not detected
ug/L
EPA624I6260G'
5127116
CJOHNSON
100-38-3
m,p-Xylene
2.0
Not detected
ug1L
EPA624IB260C
527)18
,CJOHNSON
541-73-1
m-Dichlorobenzene(1,3)
1.0
Not detected
ug/L
EPA62418260C
5/27I16
CJOHNSON
1634-044
Methyl Ted -Butyl Ether
LO
Not detected
ug1L
EPA62418260C
52H16
CJOHNSON
75-09-2
Methylene Chloride
1.0
Not detected
ug/L
EPA62418260C
5(27116
CJOHNSON
91-20-3
Naphthalene
2.0
Not detected
ug)L
EPA624/8260C
5/27116
CJOHNSON
10-51-8
n-Butylbenzene
1.0
Not detected
un-
EPA62418260C
5127116
CJOHNSON
103-65-1
n-Propylbenzene
1.0
Not detected
ugh-
EPA62418260C
N27/16
CJOHNSON
95-50-1
o-Dlchlorobenzene(1,2)
1.0
Not detected
ug(L
EPA62418260C
5127116
CJOHNSON
95-47-6
o_XyleO&
1.0
Not detected
ug)L
EPA62418260C
U27116
CJOHNSON
106-46-7
p-Dichlorobanzene(1,4)
1.0
Not detected
ug11-
EPA62418260C
W27/16
CJOHNSON
99-87-6
p-Isopmpyltoluene
1.0
1.6
uglL
EPA62418260C
5127116
CJOHNSON
135-an8,.: .::.
Soo-Butylbenzene -
-'1:0--
Not detected'
"'.:: ug/L,
EPA62418260C.
5/271,16
.., OJOHNSON
100-42-5
Styrene
1.0
Not detected
uglL
EPA62418260C
5127116
GJOHNSON
98-66-6
tert-Butylbenzene
TO
Not detected
ug/L
EPM2418260C
5127116
CJOHNSON
127-10-4
Tetrachlonoethene
1.0
Not detected
ug11-
EPA62418260C
5/27/16
CJOHNSON
108-88-3
Toluene
"0
64
can
EPA624/8260C
517116
CJOHNSON
156-80-5
tmns-1,2-Dichloroethene
1.0
Not detected
ug/L
EPA624/8260C
5127118,
CJOHNSON
10061-02-6
trans-1,3-Dichloropropene
2.0
Not detected
ug/L
EPA624I6260C
W7116
CJOHNSON
79-01-6
Trichloroethene
1.0
Not detected
u9IL
EPA62418260C
5/27/16
CJOHNSON
75-6&4
Trichlomfluommethane
2.0
Not detected
ug/L
EPA62VB260G
5127/16
GJOHNSON
75-01-4
Vinyl Chloride
2.0
Not detected
ug/L
EPA62NB260C
5127/16
CJOHNSON
MISS chemistry Laboratory» 1623 Mail Service Center, Raleigh, NC 27099-1623 [phone]
"Not Detect ar'v" does not mcicate the sample is ani free but that the matte is not tletectetl at or above the POL.
Page 4 of 6

NC9J'WIR La6oratory Seetion R¢ruld/Sampee Commentr/Qun6fieroefinitiion,
Sample In AC29333
Result/ Method Analysis
Sample comments
Ib IJ did not meet acceptance criteria -precision.
to -tentatively Identified by MS library search.
-t analyte failed a LCL in the CV2
l4 ntatively mend by MS library search.
PQL-dilution 5x
Valid
NCDEQ-WSS-Chamistry Lab Data Qualifiers
Al The reported value is an average, where at least one result is qualified with a "I The PQL is used for the qualified result(S) to cab
B1 Coliform-Countable membranes with less than 20 colonies. Reported value is estimated or is a total of the counts on all filters repor
B2 Coliform-Counts from all filters were zero. The value reported is based on the number of colonies per 100 ml that would have been
B3 Coliform-Countable membranes with more than 60 or 80 colonies. The value reported is calculated using the count from the smaller
B( Coliform-Filters have counts of both >60 or 80 and <20. Reported value is estimated or is a total of the counts on all filters reported
B5 Coliform-Too many colonies were present; too numerous to count (TNTC). TNTC is generally defined as>150 colonies.
B6 Coliform-Estimated Value. Blank contamination evident. _
B7 Coliform-Many non-coliform or non-enteroccccus colonies or interfering non-coliform or non-enterococcus growth present. In this cc
BB1 MPN-No wells or tubes gave a positive reaction. Value based upon the appropriate MPN Index and reported as a less than "<" valid,
BB2 MPWAII wells or tubes gave positive reactions. Value based upon the MPN Index and reported as a greater than ">" value.
C Total residual chlorine was present in sample upon receipt in the laboratory; value is estimated.
G1 BOD-The dissolved oxygen (DO) depletion of the dilution water blank exceeded 0.2 mg/L.
G2 BOD-The bacterial seed controls did not meet the requirement of a DO depletion of at least 2.0 mg/L and/or a DO residual of at lea:
-. G3 BOp-No sample dilution met the requirement of aDO depletion of at least 2,.O mg/L apd/ora DO residual of at least 1.0 SI
G4 BOD-Evidence of toxicity. This is generally characterized by a significant increase in the BOD value as the sample concentration de
G5 BOD-The glucose/ glutamic acid standard exceeded the range of 198 t 30.5 mg/L.
G6 BOD-The calculated seed correction exceeded the range of 0.6 to 1.0 ril
G7 BOD-Less than 1 mg/L DO remained for all dilutions set. The reported value is an estimated greater than value and is calculated for
G8 BOD-Oxygen usage is less than 2 mg/L for all dilutions set. The reported value is an estimated less than value and is calculated for
G9 BOD-The DO depletion of the dilution water blank produced a negative value.
J1 Surrogate recovery limits have been exceeded.
J2 The reported value failed to meet the established quality control criteria for either precision or accuracy.
J3 The sample matrix interfered with the ability to make any accurate determination.
J4 The data is questionable because of improper laboratory or field protocols (e.g., composite sample was collected instead of grab, pl
J5 Temperature limits exceeded (samples frozen or>6"C) during transport or not verifiable (e.g., no temperature blank provided): non-
J6 The laboratory analysis was from an unpreserved or improperly chemically preserved sample. The data may not be accurate.
J7 This qualifier is used to identify analyte concentration exceeding the upper calibration range of the analytical instrumenUmethod. Th
J8 Temperature limits exceeded (samples frozen or>6'C) during storage, the data may not be accurate.
J9 The reported value is determined by a one -point estimation rather than against a regression equation. The estimated concentration
J10 Unidentified peak; estimated value.
J11 The reported value is determined by a one -point estimation rather than against a regression equation. The estimated concentration
J12 The calibration verification did not meet the calibration acceptance criterion for field parameters.
M Sample and duplicate results are "out of control". The sample is non-homogenous((e.g., VOA soil). The reported value is the lower,
N1 Presumptive evidence and estimated value. The component has been tentatively identified base on mass spectral library.
N2 There is an indication that the analyte is present, but quality control requirements for confirmation were not met (i.e., presence oY
N3 This code shall be used if the level is too low to permit accurate quantification, but the estimated concentration is less than the labor
N4 This code shall be used if the level is too low to permit accurate quantification, but the estimated concentration is less than the labor
N5 The component has been tentatively identified based on a retention time standard.
Q1 Holding time exceeded prior to receipt by lab.
Was Chemistry LaboMorys> 1623 Mail Service Center, Raleigh, NC 27699-1623 (919) 7334908
'Not cadaver]" or' U' doaa not indicate the Sample ra a0alya free not that Ole analyte is not detected at or above the PQL.
Page 5 of 6

S✓CtD4MX La6oratoySaotio. &,afiv/Sample Commeras/rjuaGfier0efinitirm
sample to AC29333
CAR k Acelvte Name POI
Q2 - Holding time exceeded following receipt by lab.
P Elevated PQL' due to matrix interference and/or sample dilution.
S Not enough sample provided to prepare and/or analyze a method -required matrix spike (MS) and/or matrix spike duplicate (MSD).
U Indicates that the all was analyzed for but not detected above the reported practical quanlitation limit'. The number value repo
X1 Sample not screened for this compound.
X2 Sampled, but analysis lost or not performed -field error.
X3 Sampled, but analysis lost or not performed -lab error.
V Indicates the analyte was detected in both the sample and the associated method blank. Note: The value in the blank shall not be s
V Elevated PQL* due to insufficient sample size.
Z1 Inability to analyze the sample.
Was ChGanstry Laboddi 1623 Mail Service Center, Raleigh, NC 216994623 (919) 7334908
'Nat Detected' or does not Indicate the sample is analyle free butthat the analyle is net detected at or above the PQL.
Page 6 of 6

AC29419
North Carolina Division of Water Resources Water Sciences Section Laboratory Results
Lac. Does,.:
County:
Region:
River Deain
Emergency
COG Ysi
POWELL LUMBER 4899
JONATHAN CREEK RD
HHAYA'$QOD
Collector:
BLAVERTY
ViaRID
ARO
Reparl To
AND
Location ID:
IC44POWELL PL3
Jonathan peek
Collect Date'.
0512312019
Priomy
ROUTINEICOC
Called Time'.
19_06
Sample Matrix:
SURFACEWATER
YES
Sample Depth
Loc. Type:
Statements,
Final Report
Semple ID:
AC29419
PO Number
ARO
Data Received
06n4ri
Time Received
09_00
Lebworks LoginlD
KJIMIBON2
Delivery Method
Hand delivered
Final Report Date'.
]NH6
Report Print Gate:
01MEri
If this report is labeled preliminary report the results have not been validated.
Do not use for Regulatory purposes.
Result/
Method
Analysis
CAS# Analvte Name
PDL
Q
Unitsualifier
Reference
Date
Validated
ARO
- BOD, 5-Day In liquid
2.0
95
m9IL
APHAS210B
525116
ESTAFFORDI
Residue —Suspended in liquid
6.2
34
bo lL
APHA2546G-20th
51
ESTAFFORDI
Sample temperature at receipt by lab
23
°C
5124/10
RBYRD
Total Dissolved Solids in liquid
12
296
mill
APHA2540C-18 H
5127116
ESTAFFORDI
Turbidity
1
44
NTU
APHA2130D-20th
1 5125116
ESTAFFORDI
I
WSS Chemistry LahoratoM' 1623 Mail Service Carley Raleigh, NC 27699-1623 (919)733d998
Net Detected" or'U' does not indicate the sample is analyte time but that the analyle is not detected at or above the 'i
Page 1 of 1

AC29332 North Carolina Division of Water Resources Water Sciences Section Laboratory Results
Lod. Dead,.:
POWELL LUMBER4595
JONATHAN CREEK ROAD, WAYNESVILLE
County:
Hivvmdd
Collector.
BLAVERTY
VisitlD
PL2
Region.
ARO
Radii
ARC.
Loralmn ID:
IC44POWELL
River Basin
Jonathan Creek
Collect Data
051212016
Priority
ROUTINE
Emergency
CollectTime:
14_43
Sample Matrix:
SURFAOEWATER
COG Yel
g
Sample Depth
NA
Led. Type:
st,mm ter
LOWER- S?ORAri7E/L 1ON1I Final Report
Sample ID.
AC29332
PO Number #
Cate Radeved
061262016
Time Received
0a_20
Li bworke LoginlD
Mail
Delivery Method
NC Coal
Final Report Data
6123116
Report Print Date:
071062016
If this report is labeled preliminary report, the results have not been validated. Do not use for Regulatory purposes.
Result( Units Method Analysis
CAS# Aral Name - P L Qualifier Reference Date Valid
LAB
Sample temperature at receipt by lab 1.6 °C
51 TASCENZ01
NUT
NI-13 a9 N In liquid
0.02
0.02
uni N
EPA 350.1 REV 2
5125116
DOREEN
Nitrate as N in liquid
0,02
0.02 D
hil N
EPA 353.2 REV 2,
Si
CGREEN
Nitrite as N in liquid
0.01
0.01 U
nal N
EPA 353,2 REV 2
525/16
DOREEN
NO2+NO3 as N In liquid
0.02
0.02U
miasN
EPA 3532 REV
525W16
DOREEN
Phosphorus total a8 P In liquid
0.02
0.20
mg/Las P
EPA 365.1 REV 2
5/31/16
CGREEN
Total Neldahl N as N in liquid
0.2
2.0
mg/Lae N
EPA 351.2 REV 2
613116
CORDER
Chemical Oxygen Demand in liquid.
20
170
raga
Hach 8000
B/2/16
DOREEN
Grease and Oil In liquid
10
10 U,J3
ni
EPA 1664.E
5126116
DOREEN
Bromide
0.4
0.4U
mi
EPA 300.0 rav21
rectors
DOREEN
Chloride
1.0
8.9
raga
EPA 300.0 mer2.1
5/25116
DOREEN
Fluoride
0.4
0.4U
mg/L
EPA 300.0 reap
525/16
DOREEN
Sulfate
2.0
6.0
raga
EPA 300.0 rev2.1
5/25116
DOREEN
Phenolics -Total In liquid
10
420
ul
EPA4204 REV
WW16
DOREEN
Semivolattle Organics (BNAs) in liquid
83-32-9
Acenaphthene
10
Not detected
Jl
ug/L
EPA62518270D
613/16
GJOHNSON
208S6-8
Acenaphthylene
20
Not detected
Jl
ug/L
EPA62518270D
6IW16
GJOHNSON
62-53-3
Aniline
10
Not detected
J1
ug/L
EPA62518270D
Sighs
CJOHNSON
120-12-7
Anthracene
20
Not detected
Jl
ul
EPA62518270D
6I3/16
CJOHNSON
benzeneacetlo acid
11
N1
uglL
EPA62518270D
W3116
CJOHNSON
56-55-3
Benzo a)anthracene
20
Not detected
J1
ul
EPA62518270D
6/3/16
CJOHNSON
50.32-8
Benzc(a)pyrene
10
Not clebacted
J1
ug/L
EPA62518270D
613116
CJOHNSON
20B99-2
Benzo(b)huomnthene
10
Not detected
J1
ug/L
EPA62518270D
W3116
CJOHNSON
191-24-2
Benzo(g,h,i)perylene
20
Not detected
Jl
ug-
EPA625/8270D
813/16
CJOHNSON
207-08-9
Benzo(k)0uoranthene
30
Not detected
Jl
ul
EPA62518270D
Di
COHNSON
6505-0
Benzoic acid
50
68
us-
j EPA62518270D
613/16
CJOHNSON
100,51-6
Benzyl alcohol
30
Not detected
ug/L
EPA62518270D
f
613/16
CJOHNSON
ill -91-1
BIs(2-Chlomethoxy)methane
10
Not detected
J1
uv-
EPA62518270D
8/3/16
CJOHNSON
11144-4
BIS(2-chlomethyl)ether
10
Not detected
Jl
ug/L
EPA62518270D
613/16
CJOHNSON
39638-32-9
BIs(2-Chlomisopropyl)ether
10
Not detected
J1
u91L
EPA62518270D
Warta
CJOHNSON
117-81-7
Bis(2-ethylhexyl)phthalate
30
Not detected
Jl
ul
EPA62518270D
U3116
CJOHNSON
WSS Chemistry Laboratory+> 1623 Mall Service Center, Raleigh, NC 27899-1623 [phone]
"Not Detected" or"U" do. not indicate the ample is and" free but Marine anaiyte Is not detected at Or above the POL.
Page 1 of 6

NC rDgt% LaborotmySection 4rafts/Sarapfe Comments/Qun6jier(Definitzons
Sample ID: AC29332
Result/ Method Analysis
101-553
"" - I - - .-
Bromophenyl phenyl ether, 4-
10
ualifier
Not detected
J1
units
ug/L
Reference
EPA62SM270D
Date
613116
Widened
CJOHNSON
85-68-7
Butylbenzyl phthalate
10
Not detected
J1
ug/L
EPA625/8270D
&3116
CJOHNSON
59-50a
Chloro-3-methyl phenol, 4-
10
Not detected
ug/L
EPA62SM270D
613116
CJOHNSON
106-47-8
Chloroanlllne, 4-
10
Not detected
A
ug/L
EPA62518270D
613116
CJOHNSON
Bt-58-]
Chloronaphthalene, 2-
10
Not detected
A
ug1L
EPA62518270D
613116
CJOHNSON
95-57-6
Chlorophenol, 2-
10
Not detected
ug/L
EPA62518270D
6/3116
CJOHNSON
7005-92-3
Chlorophenyl phenyl ether, 4-
20
Not detected
J1
ug/L
EPA625/8276D
61&16
CJOHNSON
218-01-9
Chrysene
20
Not detected
J1
uglL
EPA62518270D
813/16
CJOHNSON
53-70-3
Dibenzo(a,h)anlhracene
20
Not detected
A
u9/L
EPA62518270D
613116
CJOHNSON
132-64-9
Dlbenzofuran
20
Not detected
A
ug/L
EPA62WB270D
W3116
CJOHNSON
95-50-1
Dlchlorobenzene, 1,2-
10
Not detected
J7
u9/L
EPA62518270D
613116
CJOHNSON
541-73-1
Dlchlorobenzene, 1,3
10
Not detected
A
ug1L
EPA62&8270D
&3116
CJOHNSON
10&46-7
Dichlorobenzene, 1,4-
10
Not detected
J1
ug/L
EPA62518270D
Wane
CJOHNSON
91-94-1
Dichlerebenzldlne, 3,3'-
30
Not detected
J7
u9/L
. EPA62518270D
6/3116
CJOHNSON
12&83-2
DIChlorophen01, 2,4-
10
Not detected
ug/L
EPA6251B270D
.i Wane
CJOHNSON
8466-2
Diethyl phthalate
20
Not detected
J7
ug/L
EPA62518270D
613116
CJOHNSON
131-11-3
Dimethyl phthalate
10
Not detected
J7
ug/L
EPA62518270D
Rohn
CJOHNSON
10S67-9
Dimethylphenol, 2,4-
10
Not detected
ug/L
EPA62518270D
&&16
CJOHNSON
84-74-2
Di-n-butyl phthalate
20
Not detected
J7
ug/L
EPA625/8270D
M116
CJOHNSON
534-52-1
Dinitro-2-methyl phenol, 4,6-
50
Not detected
uglL
EPA62518270D
813116
CJOHNSON
51-28-5
Dlnitropheltel, 2,4-
50
Not detected
J2
ugll-
EPA62518270D
6l3/16
CJOHNSON
121-14-2
Dinitrotoluene, 2,4-
20
Not detected
A
uglL
EPA625I8270D
613116
CJOHNSON
606-20-2
Dlnllrotoluene, 2,6-
10
Not detected
J1
uglL
EPA625/SVOD
&&16
CJOHNSON
117-84-0
Di-n-octyl phthalate
10
Not detected
J7
.,IL
EPA625I82701)
&3116
CJOHNSON
206-44-8
Fluoranthene
20
Not detected
Jl
ug/L
EPA62WB270D
W3116
CJOHNSON
. ,.. 86-73-7
F111orene"-"- - - -
20
Not detected
Jl
ug/L
EPA52WO270D
Wis
CJOHNSON
118-741
HBxachlorobenzene
20
Not detected
J1
uglL
EPA62NB270D
Nwis
CJOHNSON
89-68-3
Hexachlorobutadmne(SV)
10
Not detected
J1
ug/L
EPA62USVDD
613116
CJOHNSON
22-473
Hexachlorocyclopentadiene
10
Not detected
Jl
ugl
EPA62WB270D
WW15
CJOHNSON
69-72-1
Hexachloroethane
10
Not detected
Jl
ug/L
EPA625/SrOD
613116
CJOHNSON
hydrocinnamic acid
520
N1
ug/L
EPA52&BV0D
613116
CJOHNSON
193-39-5
Indeno(1,2,3-Cd)pyrene
20
Not detected
Jl
eg/L
EPA625/8270D
Who
CJOHNSON
78-59-1
laophorone
10
Not detected
J1
ug)L
EPA82WB270D
613116
CJOHNSON
methyl pentanoic acid
14
N1
eg/L
EPA625162201)
613116
CJOHNSON
9159-6
Methylnaphthalene, 2-
10
Not detected
J1
uglL
ERA621Y8270D
613116
CJOHNSON
methylphenol
130
N1
ug1L
EPA625182700
tore
CJOHNSON
9548-9
Methylphenol, 2-
10
Not detected
uglL
EPA62&82700
613116
WOHNSON
106-44-5
Methylphenol, 4-
10
Not detected
ug1L
EPA62518270D
&311e
CJOHNSON
91-20-3
Naphthalene(SV)
10
Not detected
ug1L
EPA62518210D
613/16
CJOHNSON
66-74-4
Nitroaniline, 2-
10
Not detected
A
ug/L
EPA625M270D
613116
CJOHNSON
99-00-2
Ndroanlllne, 3-
50
Not detected
J7
ug/L
EPA625/8270D
613116
CJOHNSON
100-01-6
Nltmaniline,4
50
Not detected
Jl
ug/L
EPA62518270D
613116
CJOHNSON
98-953
Nitrobenzene
10
Not detected
u9/L
EPA62518270D
613/16
CJOHNSON
WSS Chemistry LabomtoM' 1623 Mail aeraica Center, Raleigh, NO 27699-1623 [phone]
"Not Detected"or"0"does not indicate the sampleis aralyta free but that the aah t. is not detected at or shove the POL.
Page 2 of 6

NCO`hNF, Comments/Qpalifi'er4Jefinitiwu
Semple IDAC29332
Result/ Method Anal
8875-5
NltrOphenol, 2-
10
ualifier
Not detected
Units
u9IL
Reference
EPA625/8270D
Date
W3116
vet
DJOHNSON
1 OP02-7
Nltrophenol, 4-
50
Not tletectetl
ug1L
EPA62518270D
W3116
CJOHNSON
621-64-7
N-nitrosodi-n-propylamime
10
Not detected J1
u9IL
EPA625/8270D
513116
CJOHNSON
06-30-6
N-nitrosodiphenylamine
10
Not detected J1
u9IL
EPA525/8270D
W3116
CJOHNSON
87-86-5
Pentachlorophe0ol
30
Not detected
u9IL
EPA625/8270D
613116
CJOHNSON
05-at 8
Phenanthrene
20
Not detected J1
uglL
EPA625/8270D
W3116
DJOHNSON
108-95-2
Phenol
10
110
ug1L
EPA62518=
W3116
GJOHNSON
12P 000
Pyrene
20
Not detected J7
uglL
EPA825/8270D
613118
CJOHNSON
120-82-1
Trichlorobenzene, 1,2,4-
10
Not detected J1
ug1L
EPA625/8270D
613/16
WOHNSON
95-95-4
Trichlorophenol, 2,4,5-
10
Not detected
u,IL
EPAS25/8270D
WW16
GJOHNSON
68-08-2
Trichlorophenol, 2,4,6-
10
Not tleleCletl
uglL
EPA625/8270D
W3116
DJOHNSON
Valerlc acid
12 N1
ugf-
EPA6251821'OD
WAS
CJOHNSON
108-93-4
(EDB)1,2-Dlbromoethane
VOL
Volatile Organics in liquid
1.0 Not detected
ug/L
EPA82419280C
.15127/16
CJOHNSON
6301
1,1,1,2-Tetrachloroethane
1.0
Not detected
ug/L
EPA62418260C
5/27A6
CJOHNSON
71-55-6
1,1,1-Trichloroethane
1.0
Not detected
u9IL
EPA524I5260C
5/27/16
OJOHNSON
79-345
1,1,2,2-Tetrachloroethane
1.0
Not detected
ug/L
EPA62VO260C
5127/16
CJOHNSON
78-0o5
1,1,2-Tnchloroethane
1.0
Not detected
ug-
EPAB248260C
W27116
CJOHNSON
75-343
1,1-Dlchlomelhane
1.0
Not detected
ug/L
EPA62VO260C
5129116
CJOHNSON
75-35-4
1,1-Dlchlomethene
1.0
Not detected
u9IL
EPA524/82600
W27/16
CJOHNSON
563-58-6
1,1-Dichloropropene
1.0
Not detected
uglL
EPA52418250C
W27116
CJOHNSON
87-61-6
1,2,3-Tpchlorobenzene
1.0
Not detected
u9IL
EPA624A82600
5127/16
CJOHNSON
9B-18-4
1,2,3-Trichloropropane
1.0
Not detected
ugi
EPA62418250C
W27116
WOHNSON
120-82-1
1,2,4-Trichlorobenzene
1.0
Not detected
ug/L
EPA624/8260C
5129116
CJOHNSON
95atra
12,4-Trimethyl benzene - -
--t-..o---:
Not detected
- u9/L
_EPA62418260C
5127/16
WOHNSON ...
96-12-8
1,2-Dibrgmo-3-Chloropropane
2.0
Not detected
og/L
EPA624I8360G
5r27/16
CJOHNSON
107-08-2
1,2-Dichloroethane
1.0
Not detected
ugi
EPA624/8260C
5127116
CJOHNSON
18-87-5
1,2-Dichicropropane
1.0
Not detected
ug/L
EPA624/8260C
5/27n6
CJOHNSON
108-67-8
1, 3,5-Trimethylbenzene
1,0
Not detected
ug/L
EPA62418260C
5127116
CJOHNSON
142-28-9
1,3-Dichloropropane
1.0
Not detected
ug/L
EPA624/8260C
5/27116
CJOHNSON
594-20-7
2,2-Dichloropropane
2.0
Not detected
ug11-
EPA62418260C
5/27/16
CJOHNSON
95-49-8
2-Chlorotoluene
1.0
Not detected
ug/L
EPA62418260C
W27116
CJOHNSON
106-43-4
4-Chlorotoluene
1.0
Not detected
ug1L
EPA62418260C
5/27/16
CIOHNSON
71-43-2
Benzene
1.0
Not detected
ug)L
EPA62418260C
5127116
CJOHNSON
108-86-1
Bromobenzene
'ILO
Not detected
ug1L
EPA62418260C
U27116
CJOHNSON
94-99-5
Bromorchloromelhane
1.0
Not detected
ug)L
EPA62418260C
6127/16
CJOHNSON
75274
Bromodichloromethane
1.0
Not detected
ug)L
EPA62418260C
N27116
CJOHNSON
25-25-2
Bromoform
2.0
Not detected
ug1L
- EPA624/8260C
W27115
CJOHNSON
74-83-9
Bromomethane
2.0
Not detected
ug/L
EPA62418260C
5/27/16
CJOHNSON
58-23-5
Carbon Tetrachloride
1.0
Not detected
ugf-
EPA524/82600
W27115
CJOHNSON
1081
Chlorobenzene
1.0
Not detected
ug/L
EPAS24/8260C
5127116
CJOHNSON
75-00-3
Chloroelhane
2.0
Not detected
u9IL
EPAS24/8260C
512711B
DJOHNSON
Was opened, Laborai 1623 Mall S.M. center, Raider, NC 2769/94623 (919)7334908
"Not Detected' of does not indicate the sample Is arelyte free but that the enelyte is not detected at or ebwe me POL.
Page 3 of 6

NC0'4NR. Ggbameory Section 4(�.mCte/SampCe Comment/QuafifierrDefinitioru
Sample to AC29332 -
ResulU Method Analysis
67-66-3
Chloroform
1.0
Qualifier
Not detected
Units
ug/L
Reference
EPA62418260C
Date
527/16
Validated
CJOHNSON
74-87-3
Chloromethane
10
Not detected
iSIL
EPAS241826OG
5/27/16
CJOHNSON
156-59-2
cis-1,2-Dichloroethene
1.0
Not detected
ug/L
EPAS2418260C
5/27/16
CJOHNSON
10061-01-5
cis-1,3-Dichloropropene
2.0
Not detected
u9IL
EPAS24/82600
5/27/16
CJOHNSON
124-48-1
Dibromochloromethane
2.0
Not detected
ug/L
EPA62418260C
5127/16
CJOHNSON
74-95-3
Dibromomethabe
1A
Not detected
ug/L
EPAS2418260C
27/16
CJOHNSON
75-91-6
Dichlorodlfluoromethane
2.0
Not detected
ug/L
EPAS2418260C
5/27/16
CJOHNSON
100-41-4
Ethylbenzene
1,0
Not detected
ug/L
EPA624/8260C
5127/16
CJOHNSON
87-68-3
Hexachlorobutadene
1.0
Not detected
u9IL
EPA62418260C
5/27/16
CJOHNSON
98-82-8
Isopropylbenzene
1.0
Not detected
u9IL
EPA62418260C
W22116
CJOHNSON
108-38-3
m,p-Xylene
2.0
Not defected
uiy-
EPA62418260C
5127/16
CJOHNSON
541-73-1
m-Dlchlorobenzene(1,3)
1.0
Not detected
uglL
EPA624/8260C
N22116
CJOHNSON
1634-04-4
Methyl Tert-Butyl Ether
1.0
Not detected
ug/L
EPA62418260C
5127116
CJOHNSON
75-09-2
Methylene Chloride
1.0
Not detected
u9IL
. EPA62418260C
U27116
CJOHNSON
91-20-3
Naphthalene
2.0
Not detected
ug/L
EPA62418260C
5127116
CJOHNSON
104-51-5
n-Butylbenzene
1.0
Not detected
u9IL
EPA62418260C
U27116
CJOHNSON
103-65-1
n-Propylbenzene
1.0
Not detected
ug/L
EPA624/8260C
5/27/16
CJOHNSON
95-50-1
o-Dichlorobenzene (1 2)
1.0
Not detected
ug/L
EPA62418260C
5122116
CJOHNSON
95-47-6
o-Xylene
1A
Not detected
u9/L
EPA624/8260C
5I27/16
CJOHNSON
106-46-7
p-Dichlorobenzene(1,4)
1.0
Not detected
ue/L
EPA62418260C
W27116
CJOHNSON
99-87-6
p-isopropylloluene
1.0
0.92 N3
u9IL
EPA624/8260C
5/27116
GJOHNSON
135-98-8
sec-Butylbenzene
1t0
Not detected
ug/L
EPA62418260C
5127116
CJOHNSON
100-42-5
Styrene
1A
Not detected
uty-
EPA62418260C
5/27/16
CJOHNSON
9806-6
tart-Butylbenzene
1.0
Not detected
ug/L
EPA62418260C
W27116
CJOHNSON
127-18-4
Tetrachloroethene
TO
Not detected
u9IL
EPA62418260C
5/27116
CJOHNSON
locielt,"
Toluene- -
-'.IL
'44
--'u9IL
.. EPA62418260C
5/27110
•CJOBNSQN,
156-60-5
trans-1,2-DIchlorcethene
10
Not detected
u9/L
EPA62418260C
5I27/16
CJOHNSON
10061-02-6
trans-1,3-Dichlompropene
2A
Not detected
u9IL
EPA62418260C
5/27/16
CJOHNSON
79-01-6
Trichloroethene
1.0
Not detected
u9IL
EPA62418260C
5127116
CJOHNSON
75-694
Trichlorofluoromethane
10
Not detected
ug/L
EPA62418260C
5/27/16
CJOHNSON
75-014
Vinyl Chloride
21)
Not detected
ug/L
EPA62418260C
5/27/16
CJOHNSON
WSS chemist, Laboratory» 1623 all Sellce Cenleq Ralelgb, NC 27699-1623 (818) 7333908
"Nat Dalectee" m' T Eees not inbirate the sample Is analyle free but that the armyle is not detected at or above the POL.
Page 4 of 6

X D'WIR, Laboratory Section %,,a[dSavv le CommesulQya[ifin-Definitions
Sample ID: AC29332
Result/ Method Analysis
Qualifier Units Reference Date validated
sammecamments
I-Estimated-LFM recovery was 59%due to m ll interference.
estimatedleveltoo low to permit separate pupiticatien',
is less than the laboratory POL limit and greater than the
analyte felled < LCL in this CV2.
Identified by MS library eeerch
NCDEQ-WSS-Chemistry Lab Data Qualifiers
Al The reported value is an average, where at least one result is qualified with a "U". The PQL is used for the qualified result(S) to cal
Bl Coliform-Countable membranes with less than 20 colonies. Reported value is estimated or is a total of the counts on all fillers repo
B2 Coliform-Counts from all filters were zero. The value reported is based on the number of colonies per 100 col that would have been
B3 Coliform-Countable membranes with more than 60 or BO colonies. The value reported is calculated using the count from the smalls
B4 Coliform-Filters have counts of both 160 or BO and <20. Reported value is estimated or is a total of the counts on all filters reported
B5 Coliforin Too many colonies were present, too numerous to count (TNTC). TNTC is generally defined as>150 colonies.
B6 Coliform-Estimated Value. Blank contamination evident.
B7 Coliform-Many non-coliform or non-enlerococcus colonies or interfering non-coliform or non-enterococcus growth present. In this o
BB1 MPN-No wells or tubes gave a positive reaction. Value based upon the appropriate MPN Index and reported as a less than't'va1L
3132 MPWAII wells or tubes gave positive reactions. Value based upon the MPN Index and reported as a greater than ">" value.
C Total residual chlorine was present in sample upon receipt in the laboratory; value is estimated.
G1 BOD-The dissolved oxygen (DO) depletion of the dilution water blank exceeded 0.2 mg/L.
62 BOD-The bacterial seed controls did not meet the requirement of a DO depletion of at least 2.0 mg/L and/or a DO residual of at lea
G3 ___.. BS)D No.sample dilution met the requirement of a:DO depletion of at (aast,2.Qmg/Land/of.a DO residual of at least 1.0 mg/L., _.
G4 BOD-Evidence of toxicity. This is generally characterized by a significant increase in the BOO value as the sample concentration or
G5 BOD-The glucose/ glutamic acid standard exceeded the range of 196 3 30.5 mg/L.
G6 BOD-The calculated seed correction exceeded the range of 0.6 to 1.0 mg/L.
G7 BOD-Less than 1 mg/L DO remained for all dilutions set. The reported value is an estimated greater than value and is calculated fc
GB BOD-Oxygen usage is less than 2 mg/L for all dilutions set. The reported value is an estimated less than value and is calculated to
G9 BOD-The DO depletion of the dilution water blank produced a negative value.
11 Surrogate recovery limits have been exceeded.
J2 The reported value failed to meet the established quality control criteria for either precision or accuracy.
J3 The sample matrix interfered with the ability to make any accurate determination.
J4 The data is questionable because of improper laboratory or field protocols (e.g., composite sample was collected instead of grab, If
J5 Temperature limits exceeded (samples frozen or WC) during transport or not verifiable (e.g., no temperature blank provided): non
J6 The laboratory analysis was from an unpreserved or improperly chemically preserved sample. The data may not be accurate.
J7 This qualifier is used to identify analyte concentration exceeding the upper calibration range of the analytical instrument/method. TI
JB Temperature limits exceeded (samples frozen or>6°C) during storage, the data may not be accurate.
J9 The reported value is determined by a one -point estimation rather than against a regression equation. The estimated concentration
J10 Unidentified peak; estimated value.
ill The reported value is determined by a one -point estimation rather than against a regression equation. The estimated concenlralior
J12 The calibration verification did not meet the calibration acceptance criterion for field parameters.
M Sample and duplicate results are "out of control". The sample is non -homogenous leg., VOA soil). The reported value is the lower
N1 Presumptive evidence and estimated value. The component has been tentatively identified base on mass spectral library.
N2 There is an indication that the analyte is present, but quality control requirements for confirmation were not met (i.e., presence of'.
N3 This code shall be used if the level is too low to permit accurate quantification, but the estimated concentration is less than the Iabc
N4 This code shall be used if the level is too low to permit accurate quantification, but the estimated concentration is less than the all
N5 The component has been tentatively identified based on a retention time standard.
Q1 Holdino time exceeded prior to receipt by lab.
WSs chemistry Laboratory» 1923 Mall Service Center, Ra1e194 NC 27699-1623 [phone]
'her Detested' or"0" does ma ndeate the sample is anise free but that the crash, is not detected at or above the PQL.
Page 5 of 6

NC m'W+R. Laboratory Section P�euCtr/Somp(e Comments/QuaC�tDefinitimu
Sample ID: AC29332
CAS# Anelute Neme pint
.yuuucci_ .cicicu..c ._.,
Q2 Holding time exceeded following receipt by lab.
P Elevated PQL` due to matrix interference and/or sample dilution.
S Not enough sample provided to prepare and/or analyze a method -required matrix spike (MS) and/or matrix spike duplicate (MSD).
U Indicates that the analyte was analyzed for but not detected above the reported practical quantitation limit". The number value repo
X1 Sample not screened for this compound.
X2 Sampled, but analysis lost or not performed-feld error.
X3 Sampled, but analysis lost or not performed -lab error.
V Indicates the analyte was detected in both the sample and the associated method blank. Note: The value in the blank shall not be s
Y Elevated PQL" due to insufficient sample size.
Z1 Inability to analyze the sample.
W33 Chemistry Laboratory» 1623 Men Sands. Center, SeleiBh, NC 27699-1623 (919) 9334988
"Not calectetl" or"U" does not indicate the sample Is anaym tree but that the enelyte is net detected at or ebwe the PQL.
Page 6 of 6

Lod. Oeecr.:
County.
Regicn'.
River Basin
Emergency
COD YeslNo
HAYWOOD
ARO
Jonathan Crack
YES
Collector'.
Report To
ARO
Collect Date:
0612312016
Collect Tlme:
14_43
Sample Depth
UaillD
Location ID,
1CAMPOWELL PL2
Priably
ROUTINEICOO
Sample Matrix:
SURFACEWATER
Loc Type:
Stor=water
Sample ID:
AC29418
PO Number#
ARO
Data Received:
MoNli
Time Received
09:no
Lust Un mID
H IMMIS N2
Delivery Method
Hand delivered
Final Report Date:
711116
Report Print Date:
0710612016
Final Report
If this reports labeledprelimrnary report, the results have not been validated.
Do not use for Regulatorypurposes.
Result/
Method
Analysis
CAS # Analvte Name
PAC _L Qualifierr
Units
Reference
Data
Val dated
ARO
BOO, 5-Day in liquid
2.0 120
nglL
APHAS210B
5/25116
ESTAFFORDI
Residue —Suspended in liquid
6.2 64
mg1L
APHA2540D-20th
512V16
ESTAFFORDI
Sample temperature at receipt by lab
2.3
"D
5124116
RBYRD
Total Dissolved Sonde In liquid
12 245
ng1L
APHN254cC-1m`H
5127116
ESTAFFORD1
Turbidity
1 43
NTU
APHA213OB-200
5125116
ESTAFFORDI
WSS Chemistry Laboxtuni 1623 Mail service Centeq Raleigh, NC 27699AS23 (919) 7334908
"Not Detected" or"U" done not indicate the sample is analyte free butthat Ne pull is not detached at or above the POL.
Page 1 of 1

Pane Analytical Services, LLC
a4eM,i�l y(11®
N333E RivC 2Cf
gnM1eville, NC 38e04
'.MrNYIIOOMb 0-
(e26)254]1] 6
WAs7EWflTG2
Q//
W&Fcyelt
y�7
'6
ANALYTICAL RESULTS
Project: PCvreII6-PII01-1A
Pace Project Ni 92318984
Sample: POND
Lab ID: 92318984001 Collected: 11/08/1613:00
Received 11/08/161510 Matrix: Water
Parameters
Results
Units Report Limit DF
Prepared Analyzed CAS No, Qual
8081 GCB Pesticides, TCLP
gamma-BHC (Lindane)
Chlordane(Technical)
Endrin
Heptachlor
Heptachlor epoxide
Methoxychlor
Toxaphene
Surrogates
Decachindmimenyl IS)
Tetrachloro-m-Were IS)
8151 Chlorinate Herbicide TCLP
2.4-D
2,4,5-TP(Silvex)
Surrogates
2.4-DCAA(S)
6010 MET ICP, TCLP
Arsenic
Barium
Cadmium
Chromium
Lead
Selenium
Silver
6010 MET ICP
Calcium
Magnesium
Sodium
Sodium Adsorption Ratio, BAR
Sodium Adsorption Ratio
7470 Memory, TCLP
Mercury
8270 MSSV TCLP Sep Funnel
1,4-Dichlombenzene
2,4-Dinitrololuene
Hexachlom-1,3-butadiene
Hexachlorobenzene
Date: 111221201612:52 PM
Analytical Method: EPA8081 Preparation Method: EPA3510
Leachate Methodl0ate: EPA1311; 11/11/1618:00
ND
ug/L
0,50 1
11/1511609:22
11/16/162108
58-89-9
NO
ug/L
3.0 1
11/15116 09 22
11/16/1621:08.
5]-]4-9
ND
ug/L
0.50 1
11/1511609:22
11/16/162108
72-20-8
NO
ug/L
0.50 1
11/1511609:22
1111611621:08
76-44-8
ND
ug/L
0.50 1
11/1511609:22
11116/162108
1024-57-3
ND
ug/L
1000 1
11/1511609:22
"11/1611621:08
72-43-5
ND
ug/L
30 1
11/151160922
11/1611621:08
8001-35-2 -
49
%
10-138 1
11115/1609:22
11/161162108
2051-24-3
60
%
10-110 1
11115116 09 22
11/16/162108
8]]-09-8
Analytical Method:
EPA 8151 Preparation Method. EPA3510
NO
bo lL
0.010 1
11117/1608:50
1111911601:55
94-]5-] L3,M0
ND
mi
0,010 1
11117/1608:50
1111911601:55
9372-1
104
%
39-139 1
11/17/1608:50
1111911601:55
19719-28-9
Analytical Method:
EPA6010 Preparation Method: EPA3010A
Leachate Method/Date:
EPA 1311;
11109/1618:30 Initial
pH: 2.4; Final pH: 2.4
NO
mg/L
0050 1
111101161]:48
11111/1611:14
7440-38-2
ND
mg/L
0.25 1
111101161]:48
11111/1611:14
7440-39-3
NO
mg/L
0.0050 1
11/10/161748
11/11/1611:14
7440-43-9
ND -.,
--.mg/L
0.060 1
. 111101161]:48
11/1111611:14
7440473 -
ND
mg/L
0.02E 1
111101161748
1111111611:14
7439-92-1
NO
ni
0.10 1
11/10/1617:48
11/1111611:14
]]82-49-2
ND
ni
002E 1
111101161]:48
1111111611:14
7440-224
Analytical Method:
EPA6010 Preparation Method: EPA3010A
28300
ug/L
100 1
11110/1619:05
11/12/1600:42
]440-]0-2
9970
all
100 1
11/1011619D5
11112/1600:42
7439-95-4
5520
ug/L
6000 1
111101161905
11/12116 00 42
7440-23-5
Analytical Method
: EPA6010
0.23
meg/L
1
11/151160854
N2
Analytical Method:
EPA]4]0 Preparation Method: EPA]470
Leachate Method/Dale:
EPA 1311;
11/0911618:30 Initial
pH: 2.4; Final pH: 2.4
NO
mg/L
0,00020 1
111111160735
11/1111616:16
]439-9]-6
Analytical Method:
EPA 8270 Preparation Method: EPA 3510
Leachate Method/Date:
EPA 1311;
1111111616:00
NO
ug/L
500 1
11/15/1608:00
11115/1615:12
106-46-7
NO
uglL
500 1
11115/1608:00
11115/1615:12
121-14-2
NO
uglL
50.0 1
1111511808:00
1111511615:12
87-68-3
NO
uglL
50.0 1
11115/1608:00
1111511615:12
118-74-1
REPORT OF LABORATORY ANALYSIS
This mpod shall not be reproduced, except in full.
without the written consent of Pace Analyfical Services, LLC. Page 4 of 40

xWn'p¢vN640 Pf..
ANALYTICAL RESULTS
Pace Analytical ServicO; LLC
2225 Riverside Dr.
AsheNlle, NC 28804
[phone]
Project: Powell 6-P1101-1A
Pace Project No.: 92318984
Sample: POND
Lab ID: 92318984001 Collected: 11108/1613:00
Received 11/08/161510 Matrix: Water
Parameters
Results
Units
Report Limit
DF
Prepared
Analyzed
CAS No, Qual
8270 MSSV TCLP Sep Funnel
Analytical Method:
EPA 8270 Preparation Method:
EPA 3510
Leachale Method/Date: EPA 1311; 11/1111616:00
Hexachlomelhane
ND
ugi
50.0
1
11/15/16 08:00
11/15/16 15:12
67-72-1
2-Methylphenol(o-Cresol)
ND
ug/L
50.0
1
11/15/16 08,00
11/15/16 15:12
95-48-7
3&4-Melhylphenol(m&p Cresol)
ND
ug/L
50.0
1
11/15/16 08:00
11/15/16 15:12
Nitrobenzene
NO
ug/L
560
1
11/15/16 08.00
11/15/16 15:12
98-95-3
Pentachlomphenol
ND
ug/L
100
1
1111511608.00
1111511615:12
87-86-5
Pyridine
ND
ri
50.0
1
11115/16 08:00,
11/15116,15:12
110-86-1
2,4,5-Trichlorophenol
NO
ug/L
50.0
1
11115/16 08:00
11/15/16 15:121
95-95-4. -
2,4,6-Trichlomphenol
NO
uglL
50.0
1
11/15/16 08:00
11/15/16 15:12
88-06-2
Surrogates
Nitrobenzene-d5(S)
65
%
12-102
1
11115/16 08:00
11/1511615:12
4165-60-0
2-Fluorobiphenyl(S)
57
%
13-107
1
11/15/16 08:00
1111511615:12
321-60-8
Terphenyl-dl4(S)
]]
%
21-132
1
11/15/16 08:00
11/1511615:12
1718-51-0
Phenol-d6(S)
30
%
10-110
1
11/15/16 08 00
11/1511615:12
13127-88-3
.'2-Fluorophenol(S)
39
%
10-110
1
11/15/16 08:00
1111511615:12
367-12-4
2,4,6Tribromophenol(S)
75
%
27-108
1
11115/16 08:00
1111511615:12
118-79-6
8280 MSV TCLP
Analytical Method
: EPA 8260
Leachate Method/Date: EPA 1311; 11/11/160821
Benzene
NO
ug/L
100
20
11/1411616:49
71-43-2
2-Butanone(MEK)
ND
ug/L
200
20
11114/1616:49
78-93-3
Carbon tetrachloride
ND
ug/L
100
20
ll/l4/1616:49
56-23-5
Chlorobenzene
ND
ug/L
100
20
11/1411616:49
108-90-7
Chloroform
ND
ug/L
100
20
11/14/16 16:49
67-66-3
-.. 1,4-Dichlorobenzene .....,.
- ND
ug/L
100
20
11/14/1616:49
106-46-7
1,2-Dichloroethane
ND
ug/L
100
20
11/14116 16 49
107-06-2
1,1-Dichloroethene
ND
ug/L
100
20
11/14/1816:49
75-354
Tetrachlomethene
ND
ug/L
100
20
1111411616:49
127-18-4
Trichlomethene
ND
ug/L
100
20
11/14/16 16 49
79-01-6
Vinyl chloride
ND
ug/L
100
20
1111411616:49
75-014
Surrogates
1,2-Dichloroethane-d4(S)
99
%
70-130
20
11/14/1616:49
17060-07-0
Toluene-d8(S)
104
%
67-135
20
11/14/1616 49
2037-26-5
4-Bromofluombenzene(S)
102
%
70-130
20
11114/1616:49
460-004
8260 MSV Low Level
Analytical Method
: EPA8260
Acetone
ND
ug/L
25.0
1
11/1111613:44
67-64-1
Benzene
ND
ugll-
1.0
1
1111111613:44
7143-2
Bromobenzene
ND
uglL
1.0
1
1111111613:44
108-86-1
Bromochlommethane
NO
ug/L
1.0
1
11/11/1613"
74-97-5
Bromodichloromethene
ND
ug/L
1.0
1
11/11/16 13:44
75-27-4
Bromoform
ND
ug/L
1.0
1
11/11/16 13:44
75-25-2
Bromomethame
ND
ug/L
2.0
1
-
11111/1613:44
14-83-9
2-Butanone(MEK)
ND
ugi
5.0
1
r
11111/1613:44
78-93-3
Carbon tetrachloride
NO
ug/L
1.0
1
11/11/16 13:44
56-23-5
Chlorobenzene
ND
uyl-
1.0
1
11/11/16 13:44
108-90-7
Chlomethene
ND
ug/L
L0
1
11/11/16 13:44
75-00-3
Chloroform
NO
ug/L
1.0
1
11/11/16 13:44
61-66-3
REPORT OF LABORATORY ANALYSIS
This report shall not be repcduced, except in full,
Date: 11/22/20161252 PM withoutthewntmncensenfor Para Analytical Services,LLC.
Page 5 of 40

(� Pace Analytical Services, LLC
a{reAnalyticial a 2325 Riverside
On
Asheville, NO2829804n0
rwxp¢Qal¢be eohl. (e28)254-7176
ANALYTICAL RESULTS
Project: Powell 6-PII01-1A
Pace Project No.: 92318984
Sample: POND Lab ID: 92318984001 Collected: 11/0811613:00 Received 1110811615:10 Maltlx: Water
Parameters Results Units Report Limit DE Prepared Analyzed CAS No. Qual
8260 MSV Low Level
Analytical Method:
EPA 8260
Chloromethane
ND
ug1L
1.0
1
11/11/16 13:44
74873
2-Chlomtoluene
ND
ug/L
1.0
1
11/11/16 13:44
95-49-8
4-Chlorotoluene
ND
ug/L
1.0
1
11/11/16 13:44
106-43-4
1,2-Dibromo-3-chloropropane
NO
ug/L
2.0
1
11/11/16 13:44
96-12-8
Dibromochloromethane
NO
ug/L
I'D
1
11/1111613,44
124-48-1
1,2-Dlbromoethane(EDB)
NO
ug/L
I'D
1
11/11/16 13:44
106-93-4
Dibromomethane
NO
ug/L
1.0
1
1111V1613,44
74-95-3
1,2-Dichlorobenzene
NO
ug/L
1.0
1
11/11/16 13t441
95-50-1 -
1,3-Dichlorobenzene
NO
ug/L
I'D
1
11/11/16 13'.44
541 73-1
1,4-Dichlombenzene
NO
ug/L
I'D
1
11/11/1613'.44
106-464
Dichlorodiiluoromelhane
NO
ug/L
I'D
1
11/11/16 13:44
75-71-8
1,1-Dichloroethane
NO
ug/L
1.0
1
11/11/16 13
44
15-34-3
1,2-Dichloroethane
NO
ug/L
1 0
1
11/11/16 1344
107-06-2
1,1-Dichloroethene
NO
ug/L
1 0
1
11/11/16 13
44
15-354
cis-1,2-Dichloroethene
NO
ug/L
1 0
1
11/11/16 13:44
156-59-2
trans-1,2-Dichloroethene
NO
ug/L
I'D
1
11/11/16 13:44
156-60-5
1,2-Dichlaropropane
ND
ug/L
i 0
1
11/11/16 13:44
78-87-5
1,3-Dichlaropropane
NO
ug/L
1.0
1
11/11/16 13
44
142-28-9
2,2-Dichlaropropane
NO
ug/L
1 0
1
11/1111613:44
594-20-1
1,1-Dichloropropene
NO
ug/L
10
1
1111111613:44
563-58-6
cis-1,3-Dichloropropene
NO
ugll-
1.0
1
111111161344
10061-01-5
trans-1,3-Dichloropropene
NO
uglL
1.0
1
1111111613:44
10061-02-6
Diisopropyl ether
ND
ug/L
1.0
1
1111111613:44
108-20-3
-- 6thylbenzene ....
NO
ugi
10
-.4,..
,. 111111161344
10041-4
Hexachloro-1,3-butadiene
NO
ugi
10
1
1111111613:44
87-68-3
2-Hexanone
NO
ug/L
5.0
1
11111/1613:44
59148-6
p-Isopropylloluene
ND
ugi
1.0
1
11/11/16 13
44
99-87-6
Methylene Chloride
ND
ug1L
2.0
1
11/11/16 13:44
75-09-2
4-Methyl-2-pentanone(MIBIO
ND
ug1L
5.0
1
11/11/1613:44
108-10-1
Methyl-tert-butyl ether
ND
ug1L
1.0
1
11 /11 /16 13:44
163404-4
Naphthalene
ND
ug/L
1.0
1
11/11/16 1344
91-20-3
Styrene
ND
ug1L
1.0
1
11/11/1613:44
100-42-5
1, 1, 1,2-Tetrachlorcethone
ND
ug1L
1.0
1
11/11/16 13:44
630-20-6
1,1,2,2-Tetrachloroethane
ND
ug/L
I'D
1
11/11/16 13:44
79-34-5
Tetrschloroelhene
ND
ugi
1.0
1
11/11/16 13:44
127-18-4
Toluene
6.2
uglL
1.0
1
11/11/16 13:44
108-88-3
1,2,3-Trichlorobenzene
NO
ug/L
I'D
1
11/11/16 13:44
81-61-6
1 2,4-Trichlorobenzene
NO
ug/L
1.0
1
11/11/16 13A4
120-82-1
1,1,1-Trichloroethane
NO
ug/L
1 0
1
11/11/16 13:44
71-55-6
1,1,2-Trichloroethane
NO
ug/L
1.0
1
11/11/16 13:44
19-00-5
Trichlorcethene
NO
ug/L
1 0
1
11/11/16 13:44
79-01-6
Trichlom8uoromethane
NO
ug/L
10
1
11/111161344
75-694
1,2,3-Tdchloropropane
NO
ug/L
1.0
1 r
11/11/16 13:44
96-184
Vinyl acetate
NO
ug/L
2.0
1
11/11/16 13:44
108-05-4
Vinyl chloride
NO
ug/L
10
1
1111111613:44
75-014
Xylem (Total)
NO
ug/L
10
1
1111111613:44
1330-20-7
m&p-Xylene
NO
ug/L
2.0
1
11111/1613:44
179601-23-1
REPORT OF LABORATORY ANALYSIS
L3
This report shell not be reproduced adept in full,
Date: 11 /22/2016 12:52 PM without the wnlen consent of Pace Analytical Ssrvbes, L-C. Page 6 of 40

y - Pace AnelnlceI services, LLC
aceAnalXiml Dr
o 2225 RiverskeC 25 04
Asbev Ile, NC 2ae04
' .xMMwa Nm.. (926)254-]96
ANALYTICAL RESULTS
Project: Powell 6-P1101-1A
Pace Project No.: 92318984
Sample: POND
Lab ID: 92318984001 Collected
111081161300
Received 111081161510 Matrix: Water
Parameters
Results Units Report Limit
OF
Prepared Analyzed
CAS No, Coal
8260 MSV Low Level
Analytical Method : EPA 8260
o-Xylene
NO ug/L
1.0
1
1111111613:44
95-47-6
Surrogates
4-Bromofluombenzene(S)
97 %
70-130
1
111111161344
460-00-4
1,2-Dichlowethane-d4(S)
101 %
70-130
1
11/11116 13:44
17060-07-0
Toluene-us(S)
100 %
70-130
1
11/11/16 13:44
2037-26 5
2540C Total Dissolved Solids
Analytical Method: SM 2540C
Total Unsolved Solids
226 mg/L
25.0
1
11/10/1613:37i
4500H+pH, Electremelric
Analytical Method : SM 4500-1-1+13
pH at 25 Degrees C
7.0 Stu Units
1.0
1
1111411613:42
H6
5210B BOD, 5 day
Analytical Method : SM 521013
BOD, 5day
45.0 mg/L
2.0
1
11/09/1617:54 11/14/1611 :54
Total Nitrogen Calculation
Analytical Method : TKN+NO3+NO2 Calculation
Total Nitrogen
3.1 mg/L
0.12
1
11115/1618:14
360.1 Ammonia
Analytical Method: EPA 350.11993 Rev 2.0
Nitrogen, Ammonia
NO mg/L
0.10
1
11/1111603,18
]664-41-]
351.2 Total Kjoldahl Nitrogen
Analytical Method : EPA 351.2
...... Nitrogen, Kjeldahl„Trial
3.1 mg/L
.2.5„
5..
.. ... ... .. 11115/1600:15
7727-37-9
363.2 Nitrogen, N021NO3 unpms
Analytical Method: EPA353.2
Nitrogen, Nitrate
NO mg/L
0020
1
11109/1617:25
Nitrogen, Nitrite
0.11 mg/L
0.020
1
1110911611:25
Nitrogen, NO2 plus NO3
0.039 mg/L
0A20
1
111091161725
365.1 Phosphorus, Total
Analytical. Method EPA365.1
Phosphorus
2.2 mg/L
0.050
1
11/11/16 22:32
]]23-14-0
420.4 Phenolics, Total
Analytical Method: EPA4204
Phenol
0.18 mg/L
0.030
3
11116/1510:08
4500 Chloride
Analytical Method : SM 4500-CI-E
Chloride
9.8 mglL
1.0
1
111101162341
16887-00-6
5220D COD
Analytical Method: SM 5220D
Chemical Oxygen Demand
425 mg/L
250
1
_ 1111111603:30
53108 TOO
Analytical Method : SM 5310B
Total Organic Carbon
80.4 mg/L
50
5
11/15/161011
744044-0
REPORT OF LABORATORY. ANALYSIS
This reportshall not be reproduced except in full,
Date: 11/22/201612:52 PM wimcuttb.wmmn consent of Pece Analyawl service., LLC Page 7 of 40