NC0000078_Report_20020101

NPDES DOCUMENT SCANNIN`i COVER SHEET
NC0000078
NPDES Permit:
Document Type:
Permit Issuance
Wasteload Allocation
Authorization to Construct (AtC)
Permit Modification
Complete File
- Historical
iYi71►L-,-
`Report `'
Speculative Limits
Instream Assessment
(67b)
Environmental Assessment (EA)
Permit
History
Document Date:
January 1, 2002
This document ios printed on reuse paper - ignore arty
content on the reverse side

RESTJTLTS OF 2001
FISH TISSUE SAMPLING
Prepared for:
Division of Environmental Management
North Carolina Department of Environment,
Health, and Natural Resources
Prepared by:
RFS Ecusta Inc.
Pisgah Forest, North. Carolina
January 2002

INTRODUCTION ANDSUMMARY
This report details the results of a study conducted in November 2001 to
determine the concentration of 2,3,7,8-TCDD (TCDD, dioxin) and 2,3,7,8-
TCDF (TCDF, furan) in fish from the French Broad River drainage basin in
Transylvania County, North Carolina. This study was conducted in response
to Part V of the NPDES Permit No. NC0000078 issued to the P. H. Glatfelter
Company and a study plan submitted to the North Carolina Division of
Environmental Management (NC DEM) in October of 1996. This permit
calls for triennial sampling starting in 1998.
The French Broad River is the receiving stream for many point sources of
industrial and municipal wastewater, including the industrial wastewater
discharged from the Ecusta Mill. Fish tissue monitoring conducted in 1990
quantified TCDD and TCDF in fish tissue samples collected far upstream and
downstream of the Ecusta mill's discharge. These results e that
Ecusta's discharge is not the s of all TCT)D and TCDF to the Frenc
road ' ver s ; t o not confirm that Ecusta's discharge is the source of
any TCDD of TCDF. These results have been further confirmed in each
sampling study since 1990. The location of fish tissue monitoring stations,
sampling objectives and tissue study methods are provided in Section 2.
A summary of the recent fish tissue sampling results indicate the TCDD level
to be less 1.0 ppt at all sampling locations and a TCDF level of less than 1.05
ppt.
Analytical results of the fish tissue analysis and a brief discussion of the test
results are presented in section 3. Field data sheets, analytical laboratory
reports and Chain -of -custody forms are included as Appendices.

2. MATERJALS ACID METHODS
2-1 STATION LOCATIONS
In accordance with the approved study plan, fish were collected from three
stations in the French Broad River. A control background station (stationi)
was located in the vicinity of State Road (SR) 1129 near Calvert,
approximately 22 River Miles (RM) upstream of the Ecusta Mill outfall
(Figure 2-1). Station 2 was located approximately 1 RM down stream of the
Ecusta mill discharge where Patton bridge passes over the French Broad
River (figure 2-2). Station 3 was located near Penrose, North Carolina,
approximately 5 Rlvl down stream of the discharge in the vicinity of Crab
Creek Road. Detailed sampling station information is provided in table 2-1.
Fish sampling was conducted in the immediate vicinity of each location.
However, the sample reach at each station was extended to facilitate the
collection of the required number and species of fish.
•
2-2 SAMPLING OBJECTIVES AND TECHNIQUES
The goal of the fish collection effort was to collect five composite samples at
each station. Ideally, each composite was to be comprised of fillets from 10
fish. Sample objectives for each station were:
• Three composite samples for: brown trout, rock bass, river
chub or redbreast sunfish
• Two composite samples for: northern hogsucker, black
redhorse of yellow bullheads.

Figure 2-1 Sampling Station 1 on the French Broad River

Figure 2-2 Sampling Stations 2 and 3 on the French Broad River

Table 2-1 FRENCH BROAD RIVER SAMPLING STATION INFORMATION
Station Distance
Number from Outfall
Station
Location
1 22 RM upstream of outfall In the vicinity of SR
1129 at abandoned
USGS gauging station
2 1 RM downstream of outfall Vicinity of Patton
Bridge on Everet Road
3 5 RM downstream of outfali Vicinity of Crab Creek
Road Near Penrose
Site Description/
Habitat Type
Characterized by riffle and run
habitat with some small
pocket/pools along margins.
Substrate Primarily cobble
with occasional boulder and
bedrock. Deposits of sand
and silt near margins.
Characterized by riffle and run
habitat with some small
pocket/pools along margins.
Some under cut banks.
Substrate Primarily cobble
with occasional boulder with
sand, silt and mud along
margins.
Primarily run and pools
habitat with some riffles
Substrate primarily mud
and bolder. Mature
canopy cover with eroded
banks.
Fish
Community
Dominated by redhorse,
river chub, and n. hogsucker.
Brown trout and stonerolier also
present.
Dominated by redbreast sunfish,
river chub, n. hogsucker and
yellow bullhead.
Dominated by redbreast sunfish,
rock bass, northern hogsucker
and yellow bullhead.

A crew that consisted of one fisheries scientist and one -field technician, who
also served as the Quality Assurance/Quality Control Officer, conducted
sampling during the period of November 5-7, 2001. All fish were collected
by the active method of boat electro-shocking.
At each station, the available habitat was shocked repeatedly for
approximately one hour. Sport or game fish composites were composed of
redbreast sunfish (stations 2 & 3), rock bass (station 3), brown trout
(stationi), and river chub (stations 1 & 2).
Bottom feeder composites were composed of northern hogsucker (stations 1,
2 & 3), black redhorse (station 1), and yellow bullhead (stations 2 & 3). In
several cases, it was not possible to collect 10 individual specimens for each
composite. All fish were kept on ice until sorted, weighted, measured,
wrapped, labeled and composited.
Field notes are provided in Appendix A.
2-3 SAMPLE PREPARATIONS AND SHIPMENT
Upon Completion of fish collection at each site, fish were sorted according to
species and the target organisms were identified. For each target species, 10
specimens of similar length and weight were selected for each composite
sample. If less than 10 specimens of a species were collected at a station, all
specimens, regardless of size were included in the composite.
Length and weight data were collected on each specimen and recorded in the
field notebook (Appendix A). A detailed summary of each fish composites is
provided in Table 2-2.

TABLE 2-2 FISH COMPOSITES
Station 1 Composite 5 N. Hogsuc ker
1 256 189
2 247 149
3 202 86
4 172 50
5 165 45
6 176 52
7 164 41
8 126 18
9 119 16
10 117 15
Mean 174.4 64.1
Station 2 Composite 1 Redbreast Sunfish 1 179 106
2 197 143
3 140 54
4 150 62
5 155 65
6 170 56
7 122 32
8 179 97
9 136 49
10 166 80
Mean 159.4 74.4
Station 2 Composite 2 Redbreast Sunfish 1 158 75
2 155 64
3 134 39
4 125 39
5 135 43
6 141 53
7 174 87
8 134 38
9 120 26
10 128 37
Mean 140.4 50.1
Station 2 Composite 3 River Chub 1 197 97
2 154 40
3 130 22
4 156 44
5 190 83
8 170 55
7 168 52
8 134 28
9 125 22
10 126 21
Mean 154.8 46.4

TABLE 2-2 FISH COMPOSITES
Station Composite Species Fish # Length (mm) Weight (gm)
Station 1 Composite 1 Black Redhourse 1 359 432
2 371 461
3 402 546
4 383 505
5 370 460
6 365 439
7 305 252
8 402 593
9 310 285
10 340 379
Mean 360.7 435.2
Station 1 Composite 2 Brown Trout
Station 1 Composite 3 River Chub
Station 1 Composite 4 C Stoneroller
1 252 128
2 190 93
3 204 72
4 312 259
5 194 67
Mean 230.4 123.8
1 176 52
2 165 46
3 196 68
4 171 50
5 152 38
6 170 50
7 183 37
8 165 43
9 160 40
10 158 37
Mean 187.6 46.1
1 189 76
2 122 18
3 116 15
4 145 32
5 156 38
6 100 10
7 102 11
Mean 132.9 28.6

TABLE 2-2 FISH COMPOSITES
Station 2 Composite 4 N. Hogsucker
1 286 281
2 275 229
3 240 149
4 210 89
5 242 158
6 195 80
7 184 62
8 186 71
9 227 131
10 143 31
Mean 218.8 128.1
Station 2 Composite 5 Yellow Bullhead 1 169 51
2 172 53
3 221 124
4 243 170
5 240 179
6 194 81
7 210 117
8 218 118
9 161 54
10 194 74
Mean 202.2 102.1
Station 3 Composite 1 Northern Hogsucker 1 270 238
2 216 94
3 178 60
4 156 35
5 195 72
6 175 51
7 270 232
8 258 182
9 135 24
10 171 56
Mean 202.4 104.4
Station 3 Composite 2 Yellow Bullhead 1 285 297
2 280 259
3 266 249
4 280 275
5 255 239
6 284 261
7 220 140
8 190 71
9 220 116
10 183 64
Mean 246.3 197.1

TABLE 2-2 FISH COMPOSITES
Station 3 Campsite 3 Rock Bass 1 174 93
2 210 163
3 157 67
4 185 77
5 167 76
6 154 62
7 175 89
8 170 82
9 158 68
10 160 73
Mean 169 84.8
Station 3 Composite 4 Redbreast Sunfish 1 181 108
2 178 104
3 188 81
4 172 83
5 186 113
8 166 80
7 185 82
8 185 103
9 132 43
10 141 43
Mean 167.2 84.0
Station 3 Composite 5 Redbreast Sunfish 1 171 95
2 166 77
3 175 105
4 179 107
5 175 89
6 157 68
7 157 64
8 160 71
9 140 47
10 140 52
Mean 182 77.5

All specimens were submitted as whole body organisms to the laboratory.
Samples were not prepared in any manner prior to wrapping in aluminum foil
(dull side toward the fish) and being placed in a labeled zip -lock plastic bag.
All individual specimens comprising a single composite were placed in a
second labeled plastic bag. All labels contained the following information:
- Sample identification number,
- Station location number,
- Sampler's names, date and time of collection,
- Genus species and common came and
- Composite number.
All composite samples were recorded on the chain- of -custody, which was
shipped to the laboratory with the samples (see Appendix B). United Parcel
Service shipped samples to Paradigm Analytical Laboratories, Inc.
2-4 ANALYTICAL METHODS
The final preparation of each sample was conducted by the analytical
laboratory personnel who filleted and composited the tissue samples prior to
extraction and chemical. Analysis. The fish tissue samples were analyzed
for TCDD and TCDF using U. S. EPA Method 1613A.
Paradigm Analytical Laboratories, Inc., 2627 Northchase Parkway S. E.,
Wilmington, North Carolina 28405 conducted all analyses.

3. RESULTS
3-1 ANALYTICAL RESULTS
The results from the analysis of the 15 composite fish tissue samples for
TCDD and TCDF are summarized in Table 3-1. The laboratory summary
analytical report is provided in Appendix B.
3-2 DISCUSSION
A summary and comparison of the results of nine fish tissue surveys
conducted between 1989 and 2001 are presented in Table 3-2.
The results of this ninth surge indicate that the concentration of TCDD and
TCDF in fish down stream of the mill has continue to ec one smc
surve
in 1989. The data from
e studies does not support the RFS Ecusta
Mill Being a source of dioxin of furan in the French Broad River.
The concentration of TCDD in all fish samples at all stations was well below
the 3.0 ppt health advisory threshold established by the State of North
Carolina.

Table 3-1 SUMMARY OF FISH TISSUE ANALYSIS RESULTS
Sta 1 Comp 1 Black Redhorse 10 ND 0.0581 0.6450
Sta 1 Comp 2 Brown Trout 5 ND 0.0342 0.5940
Sta 1 Comp 3 River Chub 10 ND 0.0560 0.3330
Sta 1 Comp 4 C. Stonero/ler 7 ND 0.0881 0.4420
Sta 1 Comp 5 N. Hogsucker 10 ND 0.0407 0.2650
Sta 2 Comp 1 Redbreast Sunfish 10 ND 0.0687 1.0500
Sta 2 Comp 2 Redbreast Sunfish 10 ND 0.0679 0.3310
Sta 2 Comp 3 River Chub 10 ND 0.0624 0.8410
Sta 2 Comp 4 N. Hogsucker 10 ND 0.0539 0.7240
Sta 2 Comp 5 Yellow Bullhead 10 ND 0.0405 0.3950
Sta 3 Comp 1 N. Hogsucker 10 ND 0.0111 0.3920
Sta 3 Comp 2 Yellow Bullhead 10 ND 0.0125 0.2580
Sta 3 Comp 3 Rock Bass 10 ND 0.0107 0.7160
Sta 3 Comp 4 Redbreast Sunfsh 10 ND 0.0147 0.2570
Sta 3 Comp 5 Redbreast Sunfish 10 ND 0.0939 ND 0.18

APPENDIX A
FISHERIES FIELD DATA SHEETS

FISH COLLECTION FORM
f
f J 1./ .
S 1 E �.: re�►rZ =r.-:� � err r'
Pass. Number
GGte: A.,
SPECIES • I it.. (mm) II No. 1 )
-./ qZl I
r I 341 I
(c)
3o5
Wt(g) SPECIES
ig-./ 54.1 4
OS
it
af5
3r'`0
<4 /4./44120 Igo
6 .,?0,44
61
Page _L of
Time pass ends:
Tom shoeing time:
6
/tb
No. (T). I Wt.(c)
6-
i /0
1 15
13,1
l 37
1 /0
1 //
1414.-r-e L+ /lip
/ql
4 /5
NOTES:
ao
%s
5a
Ai I. , veelr,$^ oZ
1 20;
()1 /AZ
I /69
log
s/,
C► /Li'
15"
!
M1 /6#
6-01
r
L0
fiVI /24
1'
lto

STE: rye. cam, kyra ,('vac
Psss Number:
Data: ///5/0/
FISH COLLECTION FORM
(e-
SPECIES
NOTES:
•l it (mm) I No. (##I Wt.(g) SPECIES
I 1 /Ng
/�r 1
ki
14)1
1
/64
en' /5 v
l /3171
PI
I /35
PI IV/
g..11 Wit
c
I 1 ?0
,I /
!V 11.0
I /
c"!1L/
15'4
f.2
05
Jig
re,
fa4
5-3
fi
5 .., 6,44
Page jot
Time pass ends:
Total shocking time:
��.
�{ ji 2
�1 11-) EGG
I TL(mm) I No. (#) 1
0140 1 I
D 1
��/���./ if t I I/�'
() 211.5
02#0
fr)
/1
�f
� r

FISH COLLECTION FORM
�
SITE: -c gcacti
Pass Number:
CAI
3.)
SPECIES •I t L (arn) I No. (#)
.10 1
44-/ .21c I
. /95
Page±'of.L
Time pass Ends.:
Total shocking trrie:
/,Obo
Wt(g) SPECIES
i<7.6730,r
15
1 (2
t 125 ?
a_3,1
el /Is
,24
1wh/ }
J44 / f.; G
? C ,A .210
PSI .?6f,
41 ago
fl, l P?7
a1
1,749
2�9
Jam'
(1 441
Cr I o2a0
Ago
01 1 g3 .
/440
TL(mm)
/(1
01 kg
�I 1
Ifia
el 4
Ire
/
No.0:)
\At(c)
;64
7'0
W44- rtt, /1
I4
/64
G2I /s
I
/ 19
j Apt)
NOTES:
93
1 '.
lZ
s4 's p/
(v. 6- /
keY /
0 /
do AO
/•s1-
No
•

APPENDS B
PARADIGM ANALYTICAL LABORTORIES,
ANALYTICAL LABORATORY REPORT
(INCLUDING CHAIN-

Environmental Testing Solutions, LLC
PO Box 790 Phone: [phone]
Pisgah Forest, NC 28712 Fax: [phone]
December 04, 2001
Mr. William Ashbrook
RFS Ecusta, Inc.
1 Ecusta. Road
Brevard, NC 28712
Dear Mr. Ashbrook
RE: ETS PROJECT NUMBERS: 011105.503, 011106.513, 011107.513
Enclosed are the results for samples received by Environmental Testing Solutions, LLC on
November 05, 06, and 07, 2001.
If you have any questions concerning these results, please feel free to contact me.
Sincerely,
Kelley E. Keenan
Laboratory Director

PARADIGM ANALYTICAL LABORATORIES, INC.
2627 Northchase Parkway S.E.
Wilmington, North Carolina 28405
[phone]
Fax [phone]
Monday, December 03, 2001
Kelly Kennan
Environmental Testing Solutions
PO Box 790
Pisgah Forrest, NC 23763
Dear Ms. Kennan:
Enclosed are the final results for the samples received by Paradigm.Analytical Laboratories, Inc. on
November 9, 2001 under your Project Name '=RFS Ecusta, Inc". The samples were analyzed by Method
8290 following Paradigm's Standard Operating Procedures. Please see Page 2 of this report for the case
narrative.
A summary data package has been provided.
No. of Samples Received: 15 Tissues
Your Project Number:
PAL Project No.:
Not Provided
G478-2
We appreciate your business and look forward to working with you again. Please contact me if you
have questions or need additional technical support.
Sincerf ly,
Christopher 1U. Cornwell
Assistant Director
Page I of 43
N.C. Certification #481 S.C. Certification #99029

PARADIGM ANALYTICAL LABORATORIES, INC.
Client Project No.:
Client Project Name:
No. of Samples Received:
No. of Samples Analyzed:
Method:
No. of LIMIBs:
No. of OPRs:
Case Narrative
Paradigm Project G478-2
Not Provided
RFS Ecusta, Enc.
15 Tissues
15
1613
4
• Data meet QA/QC requirements.
W.M. Larkins
Technical Director
December:). 2001
N.C. Certification #48I S.C. Certification #99029

Faradtgn2 Analytical Laboratories
List of Certifications
Ultra -Trace Analysis
US Army Corps ofEngineers
Dioxins/Furans
Methods:
1613 Water
8290 Water, Solids
Expires February 9, 2002
Stare ofArkansas
Dioxins/Furans
Expires May 8, 2002
Stare of Connecticut
Potable Water for Dioxin
Certification Number PH-0258
Expires December 31, 2001
Stare of California
Drinking Water-1613
Certification Number: 2451
Hazardous Waste-8290
Expires February 28, 2003
State of:ansas
Solids/Haz Waste
PCDDs/PCDFs by 8290, 8280A
Certification Number. E-10330
Wastewater
Dioxin by 1613
Certification Number E-10330
Expires January 31, 2002
Commonwealth oflentucky
Dioxin by HRGC/MS
2378-TCDD
Laboratory identification Number. 90120
Expires December 31, 2001
State ofNewJersey
PCDDs/PCDFs by 8290
Laboratory Identification Number. 67100
Expires June 30, 2001
Renewal Pending
Georgia
Dioxins in Water
Certification Number. 946
Expires July 31, 2002
Stare of Utah
CWA 1613E
RCRA 8280, 8290
SDWA 1613, 1613E
Expires June 30, 2002
State ofNew York
NELAC NY Lab Code:11685
Non -potable Water
2378-TCOD by EPA1613
Dioxins (all)
Potable Water
2378-TCDO by EPA1613
Expires April 01, 2002
State ofNorth Carolina
Drinking Water
2378-TCDD by 1613
Laboratory Identification Number 37776
Expires July 31, 2002
State ofSouth Carolina
Hazardous Waste
Method 8290
Certification Number: 99029002
Expires December 31, 2002
Commonwealth of Virginia
Drinking Water
2378-TCDD
Laboratory Identification Number: 00235
Expires June 2002
State of west Virginia
Dioxins/Furans•
Methods: 8280A, 8290, 1613
Certification Number: 293
Expires December 31, 2001
State of �'isconsin
PCDDs/PCDFs
Laboratory ID Number. 399001350
Expires August 31, 2002
State ofFlorida
NELAC (Primary State)
Dioxins/PCBs
Expires June 30, 2002
3

Navy IR QA Program
8280, 8290, 1668,
1613 Drinking Water
ID Number. NFESC 413
Expires March 22.2003
4

Table 1. List of Qualifiers
A Amount detected is less than the Calibration Limit
B Analyte was detected in the LMB at a level above the RL or EDL.
E Amount detected is over the Method Calibration Limit
DPE Denotes the presence of possible polychlorinated diphenylethers
EDL "Estimated Detection Limit"
EMPC "Estimated Maximum Possible Concentration"
ppt Parts -per -trillion (pg/g; ng/L)
Q Indicates the presence of quantitative interferences. They generally
result in an underestimation of the affected total homologue
groups.
R The ion ratio is outside method limits.
S The quantity of analyte has saturated the detector. This may cause
the ion ratio to be outside theoretical limits.
V Recovery is lower than 40%. The data has been validated based on
a favorable signal-to-noise and detection limit.
# Outside QC limits
* See cover letter
5

Table 2: Toxic Equivalency Factors
Anal a World Health Organization International-89 MADEP
2,3,7,8-TCDD 1 1 1
1,2,3,7,8-PeCDD 1 0.5 0.5
1,2,3,4,7,8-HxCDD 0.1 0.1 0.1
1,2,3,6,7,8-HxCDD 0.1 0.1 0.1
1,2,3,7,8,9-HxCDD 0.1 0.1 0.1
1,2,3,4,6,7,8-HpCDD 0.01 0.01 0.1
OCDD 0.0001 0.001 0.001
2,3,7,8-TCDF 0.1 0.1 0.1
1,2,3,7,8-PeCDF 0.05 0.05 0.5
2,3,4,7,8-PeCDF 0.5 0.5 0.5
1,2,3,4,7,8-HxCDF 0.1 0.1 0.1
1,2,3,6,7,8-HxCDF 0.1 0.1 0.1
2,3,4,6,7,8-HxCDF 0.1 0.1 0.1
1,2,3,7,8,9-HxCDF 0.1 0.1 0.1
1,2,3,4,6,7,8-HpCDF 0.01 0.01 0.1
1,2,3,4,7,8,9-HpCDF 0.01 0.01 0.1
OCDF 0.0001 0.001 0.001
6

Paradigm Analytical Labs
Method 1613
Station 1 Comp#1 - 10 Black Redhorse
Environmental Testing Solutions
nalydcal Data Summary Sheet
Analyte
Amount
(Pe/g)
EDL
(PO)
EMPC
(PP/€)
RT
(min.)
Ratio
Qualifier
2,3,7,8--TCDD .
EMPC
0.0581
0.235
29:02
0.31
1,2,3,7,8-PeCDD
0.414
•
32:59
1.39
A
1,2,3,4,7,8-HxCDD
ND
0.0984
1,2,3,6,7,8-HxCDD
ND
0.0876
1,2,3,7,8.9-HxCDD
ND
0.0887
•
1,2,3,4,6,7,8-HpCDD
0.789
38:17
1,18
A
OCDD
5.82
41:52
0.84
•
2,3,7,8—TCDF
0.645
28:07
0.69
1,2,3,7,8-PeCDF
0.129
32:17
1.58
A
2,3,4,7,8-PeCDF
0.100
32:49
1.34
A
1,2,3,4,7,8-HxCDF
0.0719
34:41
1.15
A
1,2,3,6,7,8-HxCDF
ND
0.0237
2,3,4,6,7,8-HxCDF
ND
0.0259
1,2,3,7,8,9-HxCDF
ND
0,0356
1,2,3,4,6,7,8-HpCDF
0.242
37:11
1.08
A
1,2,3,4,7,8,9-HpCDF
ND
0.0640
OCDF
0.666
•
42:06
0.83
A
Total TCDDs
0.218
0.689
Total PeCDDs
0.414
1.24
Total HxCDDs
ND
0.276
Total HpCDDs
1.17
_
Total TCDFs
1.02
Total PeCDFs
0.619
0.903
•
Total HxCDFs
0.418
0.448
'
Total HpCDFs
0.668
ITEF TEQ (ND=)
0.352
0.587
ITEF TEQ (ND='fi)
0.399
0.605
_
Client Information
Project Name:
Sample ID:
Laboratory Information
Project ID:
Sample ID:
Collection Date/Time:
Receipt Date:
Extraction Date:
Analysis Date:
RFS Ecusta, Inc.
Station 1 Comp#1
10 Black Redhorse
G478-2
32032
06-Nov-01 11:00
09-Nov-01
22-Nov-01
27-Nov-01
Sample Information
Matrix:
Weight / Volume:
Solids / Lipids:
Original pH : .
Batch ID:
• Filename:
Retchk:
Begin ConCal:
Initial Cal:
Fish
10.57 Grams
100 %
NA
WG6309
a26nov01b_2-8
a26nov0lb-15
a26nov01b-15
m1613-101201a
1/2
7

Paradigm Analytical Labs
Method 1613
Station 1 Comp#1 - 10 Black Redhorse
Environmental Testing Solutions
Analytical Data Summary Sheet
Labeled
Standard
.
Expected
Amount
(n)
Measured
Amount
(n0)
• Percent
Recovery
(%)
RT
(min.)
Ratio
'Qualifier
Extraction Standards
2
2
2
2
2
4
2
2
2
2
2
2
2
2
2
0.8
2
2
1.57
1.72
1.64
1.79
1.75
2.64
1.60
1.57
1.64
1.62
1.75
1.73
1.68
1.61
1.71
0.70
•
• •
78.5
85.8
81.9
89.4
87.5
65.9
80.1
78.5
81.9
81.2
87.7
86.3
83.8
803
85.5
87.4
• •
•
.
•
29:01
33:01
35:20
35:25
38:16
41:52
28:06
32:15
32:49
34:41
34:46
35:12
35:52
37:10
38:50
29:03
28:18
35:12
0.8
1.54
1.25
1.23
1.04
0.85
0.81
1.55
1.57
0.50
0.5
0.51
0.51
0.46
0.47
0.82
0.51
i
13C t2-2,3,7,8-TCDD
13C12-1,2,3,7,8-PeCDD
13C12-1,2,3,4,7,8-HxCDD
13C12-1 2,3,6,7,8-HxCDD
13C12-1,2,3;4,6,7,8-HpCDD
13C12-0CDD
13C12-2,3,7,8-TCDF
13C12-1,2,3,7,8-PeCDF
13C12-2,3,4,7,8-PeCDF
13C12-1,23,4,7,8-HxCDF
13C12-1,2,3,6,7,8-HxCDF
13Cl2-2,3,4,6,7,8-HxCDF
13C1,-1.2,3,7,8,9-HxCDF
13C12-1,2,3,4,6,7,8-HpCDF
13C 13-1.2,3,4,7,8,9-HpCDF
Cleanup Standards
37C14-2,3,7,8-TCDD
Iniection Standards
13C12-1,2,3,4-TCDD
f3C1?-1,2,3,7,8,9-HxCDD
Client Information
Project Name:
Sample ID:
Laboratory Information
Project ID:
Sample ID:
Collection Date/Time:
Receipt Date:
Extraction Date:
Analysis Date:
Analyzed by:
Date:
RFS Ecusta, Inc.
Station 1 Comp#1
10 Black Redhorse
G478-2
32032
06-Nov-01 11:00
09-Nov-01
.2-Nov-01
27-Nov-01
Sample Information
Matrix:
Weight 1 Volume:
Solids / Lipids:
=Qriginal •pH
Batch ID:
Filename:
Retchk:
Begin ConCal: •
Initial Cal:
212
Fish
10.57 Grams
100 %a
NA
WG6309
a26nov01b_2-8
a26nov01b-15
a26nov01b-15
Reviewed by:
Date:
m1613-101201a
8

Paradigm Analytical Labs
Method 1613
Station 1 Comp#2 - 5 Brown Trout
Environmental Testing Solutions
Analytical Data Summar•y Sheet •
Analyte
Amount
(PE/g)
EDL
(PP/B)
•
EMPC
(Pet)
RT
(min.)
Ratio
Qualifier
2,3,7,8--TCDD
EMPC
0.0342
0.250
29:02
0.36
1,2,3,7,8-PeCDD
EMPC
0.0266
,
•
0.226
33:00
0.79
1,2,3,4,7,8-HxCDD
0.0990
35:21
1.27
A
1,2,3,6,7,8-HxCDD
0.132
''•
35:25
1.4
A
1,2,3,7,8,9-HxCDD
ND
0.0469
1,2,3,4,6,7,8-HpCDD
0.502
38:16
1.12
A
OCDD
2.89
41:51
0.88
A
2,3,7,8--TCDF
0.594
28:06
0.75
1,2,3,7,8-PeCDF
ND
0.0271
•
2,3,4,7,8-PeCDF
0.101
32:49
1.73
A
1,2,3,4,7,8-HxCDF
ND
0.0231
. ,
1,2.3,6,7,8-HxCDF
ND
0.0231
2,3,4,6,7,8-HxCDF
ND
0.0245
1,2,3,7,8,9-HxCDF
ND
0.0344
.
1,2,3,4,6,7,8-HpCDF
0.405
37:11
0.99
A
1,2,3,4,7,8,9-HpCDF
ND
0.0611
.
OCDF
1.30
. • 42:06
, 0.77
A
Total TCDDs
ND
0.167
0.582
Total PeCDDs
ND
0.193
0.408
Total HxCDDs
0.231
•
0.396
Total HpCDDs
0.785
Total TCDFs
0.743
0.799
Total PeCDFs
0.101
Total HxCDFs
0.0642
0.108
Total HpCDFs
0.740
ITEF TEQ (ND=0)
0.146
0.509
1TEF TEQ (ND=')
0.179
0.518
Client Information
Project Name:
Sample ID:
Laboratory Information
Project ID:
Sample ID:
Collection Datefl'ime:
Receipt Date:
Extraction Date:
Analysis Date:
RFS Ecusta, Inc.
Station 1 Comp#2
Brown Trout
G478-2
32033
06-Nov-01
09-Nov-01
22-Nov-01
27-Nov-01
Sample Information
Matrix:
Weight / Volume:
. Solids / Lipids:
Original pH :
Batch ID:
'Filename:
11:00 • • Retchk:
Begin ConCal:
Initial Cal:
Fish
11.52 Grams
100 %
NA
WG6309
a26nov01b_2-9
a26nov01b-15
a26nov01b-15
m1613-101201a
1/2
9

Paradigm Analytical Labs
Method 1613
Station 1 Comp#2 - 5 Brown Trout
Environmental Testing Solutions
Analytical Data Summary Sheet
Labeled
Standard
Expected
Amount
(ng) _
Measured
Amount
(ng) -
Percent
Recovery
(%)
RT
(min,)
' Ratio
Qualifier
Extraction Standards
1'Ct2-2,3,7,8-TCDD
2
1.61
80.4
29:01
0.83
13C12-1,2,3,7,8-PeCDD
2
1.77
88.6
33:00
1.57
13C12-1,2,3,4,7,8-HxCDD
2
I.75
87.3
35:19
1.28
13C,2-1,2,3,6,7,8-HxCDD
2
1.79
89.3
35:24
1.25
13C12-1 2,3,4,6,7,8-HpCDD
2
1.71
85.4
38:16
1.04
13C12-OCDD
4
2.59
64.7
41:52
0.84
13C12-2,3,7,8-TCDF
2
1.72
85.8
28:05
0.8
13C11-1,2,3,7,8-PeCDF
2
1.62
. 81.1
32:15
1.57
13C12-2,3,4,7,8-PeCDF
2
1.71
85.5
32:49
1.56
13C12-1,2,3,4,7,8-HxCDF
2
1.68
83.9
34:41
0.50
13C12-1,2,3,6,7,8-HxCDF
2
1.78
88.8
34:46
0.5
13C12-2,3,4,6,7,8-HxCDF
2
1.80
90.2
35:12
0.53
13C12-1,2,3,7,8,9-HxCDF
2
1.72
85.9
35:52
0.52
13C12-1,2,3,4,6,7,8-HpCDF
2
1.62
80.9
37:10
0.45
13C12-1,2,3,4,7,8,9-HpCDF
2
1.68
_
84.2
38:49
0.47
Cleanup Standards
37C14-2,3,7,8-TCDD
0.8
0.68
84.8
29:02
Infection Standards
13C12-1,2,3,4-TCDD
2
28:18
0.82
,
13C12-1,2,3,7,8,9-HxCDD
2
35:12
0.53
Client Informations
Project Name:
Sample ID:
Laboratory Information
Project ID:
Sample ID:
Collection Date/Time:
Receipt Date:
Extraction Date:
Analysis Date:
Analyzed by:
Date:
RPS Ecusta, Inc.
Station 1 Comp#2
Brown Trout
0478-2
32033
06-Nov-01 11:00
09-Nov-01
22-Nov-01
27-Nov-01
Sample Information
Matrix:
Weight /Volume:
Solids / Lipids:
-:Original pH :
Batch ID:
Filename:
Retchk:
Begin ConCal:
Initial Cal:
212• •
Fish
11.52 Grams
100
NA
WG6309
a26nov01b_2-9
a26nov01b-15
a26nov01b-15
m1613- 01201a
Reviewed by:
Date:
10

Paradigm Analytical Labs
Method 1613
Station 1 Comp#3 -10 River Chub
Environmental Testing Solutions
Analytical Data Summary Sheet
Analyte
Amount
(Pglg)
EDL
(PO.)
EMPC
(Kt)
RT
(min.)
Ratio
Qualifier
2,3,7,8—TCDD .
EMPC
0.0560
0.186
29:02
0.21
1,2,3,7,8-PeCDD
EMPC
0.0461
0.166
33:00
0.92
1,2,3,4,7,8-HxCDD
ND
0.0699
1,2,3,6,7,8-HxCDD
ND
0.0622
1,2,3,7,8,9-HxCDD
ND
0.0630
1,2,3,4,6,7,8-HpCDD
0.273
38:16
1.02
A
OCDD
1.55
41:52
0.91
A
2,3,7,8—TCDF
0.333
28:06
0.72
A
1,2,3,7,8-PeCDF
EMPC
0.0250
0.0368
32:15
0.91
2,3,4,7,8-PeCDF
EMPC
0.0233
0.0665
32:49
1.2
1,2,3,4,7,8-HxCDF
ND
0.0203
•
1,2.3,6,7,8-HxCDF
ND
0.0198
2,3,4,6,7,8-HxCDF
EMPC
0.0215
. 0.0263
35:13
1.55
1,2,3,7,8,9-HxCDF
ND
0.0301 .
'
1,2,3,4,6,7,8-HpCDF
0.161
37:11
1.11
A
1,2,3,4,7,8,9-HpCDF
ND
0.0392
OCDF
0.373
42:07
0.76
A
Total TCDDs
ND
0.142
0.319
Total PeCDDs
ND
0.228
0.I66
Total HxCDDs
0,114
0.364
Total HpCDDs
0.273
0.443
Total TCDFs
0.441
Total PeCDFs
0.0525
0.156
Total HxCDFs
0.0420
0.172
Total HpCDFs
0.161
0.312
ITEF TEQ (ND=0)
0.0396
0.346
ITEF TEQ (ND=t)
0.100
0.360
Client Information
Project Name:
Sample ID:
Laboratory Information
Project ID:
Sample ID:
Collection Date/Time:
Receipt Date:
Extraction Date:
Analysis Date:
Samnle Information
RFS Ecusta, Inc.
Station 1 Comp#3 . Matrix:
10 River Chub : Weight / Volume:
Solids / Lipids:
Original pH :
G478-2 Batch ID:
32034
06-Nov-01 11:00
09-Nov-01
22-Nov-01
27-Nov-01
Filename:
Retchic:
Begin ConCa1:
Initial Cal:
Fish
11.42 Grams
100 %
NA
WG6309
a26novOlb_2-10
a26nov01b-15
a26nov01b-15
m1613-101201a
1/2
11

Paradigm Analytical Labs
Method 1613 •
Station 1 Comp#3 -10 River Chub
Environmental Testing Solutions
Analytical Data. Summar beet
Labeled
Standard
•
Expected
Amount
(na)
Measured
Amount
(ng)
Percent
-Recovery
(%)
RT
(min.)
• Ratio
•
Qualifier
Extraction Standards
13C12-2,3,7,8-TCDD
2
1.58- •
79.1 •
29:01
0.82 s
13C12-1,2,3,7,8-PeCDD
2
1.67
83.7
33:00
1.54
13C12_ 1,2,3,4,7,8-HxCDD
2
1.62
81.2
35:19
1.29
13C12-1,2,3,6,7,8-HxCDD
2
1.77
88.5
35:25
1.28
13C12_1,2,3,4,6,7,8-HpCDD
2
1.75
87.4
38:16
1.05
13Ci2-OCDD
4
2.55
63.8
41:52
0.84
13C12-2,3,7,8-TCDF
2
1.66
83.2
28:06
0.8
l3C12-1,2,3,7,8-PeCDF
2
1.54 ,
77.0
32:15
1.5
13C12-2,3,4,7,8-PeCDF
2
1.63
81.7
32:49
1.55
13C12-1,2,3,4,7,8-HxCDF
2
1.61
80.4
34:41
0.53
13C12-1,2,3,6,7,8-HxCDF
2
1.74
86.9
34:46
0.53
13C12-2,3,4,6,7,8-HxCDF
2
1.74
87.0
35:12
0.52
13C12-1,2,3,7,8,9-HxCDF
2
1.67
83.3
35:53
0.53
13C 12- 1,2,3,4,6,7, 8-HpCDF
2
1.60
.
79.9
37:11
0.47
t3C12-12,3,4,7,8,9-HpCDF
2
1.70
85.1
38:50
0.47
Cleanup Standards
•
37C14-2,3,7,8-TCDD
0.8
0.69
86.1
29:02
Iniection Standards
13C12-1,2,3,4 TCDD
2
28:18
0.82
,
13C12-1,2,3,7,8,9-HxCDD
2
35.12
0.52
Client Information
Project Name:
Sample ID:
Laboratory Information
'Sample Information
RFS Ecusta, Inc.
Station 1 Comp#3 Matrix: . Fish
10 River Chub Weight /Volume: 11.42 Grams
Solids / Lipids: 100
Original pH : NA
Project ID: G478-2 Batch ID: WG6309
Sample ID: 32034
Collection Date/Tirne:
Receipt Date:
Extraction Date:
Analysis Date:
Analyzed by:
Date:
Filename: a26nov01b_2-10
06-Nov-01 11:00 Retchk: a26nov01b-15
09-Nov-01 Begin ConCal: a26nov01b-15
22-Nov-01
27-Nov-01 Initial Cal: m1613- 0120Ia
2/2
Reviewed by:
Date: / y/ D I
12

Paradigm Analytical Labs
Method 1613
Station 1 Coxnp#4.7 Central Stoneroller
Environmental Testing Solutions
Analytical Data Summary Sheet •
Analyte
Amount
(PgFg)
EDL
(nig)
EMPC
(PB/b)
RT
(min.)
Ratio
Qualifier
2,3,7,8--TCDD
ND
0.0881
1,2,3,7,8-PeCDD
EMPC
0.0487
0.:308
32:34
2.47
1,2,3,4,7,8-HxCDD
ND
0.217 •
1,2,3,6,7,8-HxCDD
ND
0.199
'
1,2,3,7,8,9-HxCDD
ND
0.199
•
•
1,2,3,4,6,7,8-HpCDD
1.84
37:35
1
A
OCDD
15.9
•
40:58
0.84
2,3,7,8—TCDF
0.442
27:06
0.83
A
1,2,3,7,8-PeCDF
. ND
0.0452
2,3,4,7,8-PeCDF
0.124
32:25
1.62
A
I,2,3,4,7,8-HxCDF
ND
0.0758
1,2,3,6,7,8-HxCDF
ND
0.0700
2,3,4,6,7,8-HxCDF
ND
0.0819
1,2,3,7,8,9-HxCDF
ND
0.104
•
1,2,3,4,6,7,8-HpCDF
0.555
36:34
0.92
A
1,2,3,4,7,8,9-HpCDF
ND
0.142
OCDF
3.53
•
4i:11
0.86
A
Total TCDDs
0.341
0.702
Total PeCDDs
ND
0.324
1.44
Total HxCDDs
NI)
0.499
•
Total HpCDDs
2.93
Total TCDFs
0.619
Total PeCDFs
0.124
Total HxCDFs
0.345
•
Total HpCDFs
2.12
0.150
0.304
ITEF TEQ (ND=0)
0.255
0.397
,
J TEF TEQ (ND=1/2)
Client Information
Sample Information
Project Name: RFS Ecusta, Inc.
Sample ID: Station 1 Comp#4 Matrix: Fish
7 Central Stonerolier Weight / Volume: 10.31 Grams
Laboratory Information Solids / Lipids: 100 %
Original pH : NA
Project ID: G478-2 Batch ID: WG6309
Sample ID: 32035
Filename: a29nov01f-12
Collection Date/Time: 06-Nov-01 11:00 • Retchlr. • a29nov01f-1 '
Receipt Date: 09-Nov-01 Begin ConCal: 'a29nov01f-1
Extraction Date: 22-Nov-01
Analysis Date: 30-Nov-01 •Initial Cal: m1613-101201a
1/2
13

Paradigm Analytical Labs
Method 1613
Station 1 Comp#4 - 7 Central Stoneroller
Environmental Testing Solutions '
Analytical Data Summary Sheet
Labeled
Standard
Expected
Amount
(ng)
Measured
Amount
(ne)
Percent
Recovery
(%)
RT
(min.)
Ratio
Qualifier
Extraction Standards
13C12-2,3,7,8-TCDD
2
1.47
73.3
28:00 '
0.8
13C1_-1,2.3,7,8-PeCDD
2
1.56
78.0
32:35
1.56
13C12-1,2,3,4,7,8-HxCDD
2
1.71
85.4
34:49
1.24
13C12-1,2,3,6,7,8-HxCDD
2
1.74
87.2
34:54
1.24
13C12-1,2,3,4,6,7,8-HpCDD
2
1.66
83.1
37:35
1.04
13C12-OCDD
4
2.52
63.1
40:57
0.82
13C12-2,317,8-TCDF
2
1.49
74.3
27:05
0.8
:3C12-1,2,3,7,8-PeCDF
2
1.37
68.4
31:49
1.63
13C12-2,3,4,7,8-PeCDF
2
1.34
67.0
32:25
1.66
13C 12-1,2,3,4,7,8-HxCDF
2
1.73
, - 86.4
34:12 ..
0:50
13C12-1,2,3,6,7,8-HxCDF
2
1.69
84.5
34:17
0.51
13C12-2,3,4,6,7,8-HxCDF
2
1.70
85.2
34:42
0.52
'3C12-1,2,3,7,8,9-HxCDF
2
1.63
81.4
35:20 •
0.51
13C12-1,2,3,4,6,7,8-HpCDF
2
1.59
79.5
36:33
0.44
13C12-1,2,3,4,7,8,9-HpCDF
2
1.63
81.3
38:06
0.45
Cleanup Standards
37C1.1-2,3,7,8-TCDD
0.8
0.64
80.5
28:02
Injection Standards
13C12-1,2,3,4-TCDD
2
27:19
0.81
,
13C12-1,2,3,7,8,9-HxCDD
2
34:42
0.52
Client Information
Project Name:
Sample ID:
Laboratory Information
Project ID:
Sample ID:
Collection DatefTime:
Receipt Date:
Extraction Date:
Analysis Date:
Analyzed by:
Date:
RFS Ecusta, Inc.
Stations Comp#4
7 Central Stoneroller
G478-2
32035
06-Nov-01 11:00
09-Nov-01
22-Nov-01
30-Nov-01
Sample Information
Matrix:
Weight / Volume:
Solids / Lipids:
Original pH :
Batch ID:
Filename:
Retchk:
Begin ConCal:
Initial Cal:
Fish
10.31 Grams
100
NA
WG6309
a29nov01f-12
a29nov01 f-1
a29nov01 f-1
m1613-101201a
Reviewed by:
Date: _ /313%9l
2/2'
14

Paradigm Analytical Labs
Method 1613
Station 1 Comp#5 -10 Northern Hogsucker
Environmental Testing Solutions
Anal cal Data Su
Analyte
Amount
(PPS
EDL
(Prig)
EMPC
(P6/g)
RT
(min.)
Ratio
Qualifier
2,3,7,8--TCDD
EMPC
0.0407
0.181
28:01
0.28
1,2,3,7,8-PeCDD
EMPC
0.0171
0.I71
32:35
2.12
1,2,3,4,7,8-HxCDD
ND
0.118
1,2,3,6,7,8-HxCDD
ND
0.109
1,2,3,7,8,9-HxCDD
ND
0.109
1,2,3,4,6,7,8-HpCDD
0.676
37:35
1.04
A
OCDD
3.86
40:57
0.91
A
2,3,7,8--TCDF
0.265
27:06
0.82
A
1,2,3,7,8-PeCDF
ND
0.0221
.
2,3,4,7,8-PeCDF
0.0838
32:25
1.49
A
1,2,3,4,7,8-HxCDF
ND
0.0428
1,2,3,6,7,8-HxCDF
ND
0.0423
•
2,3,4,6,7,8-HxCDF
0.0890
34:41
1.24
A
1,2,3,7,8,9-HxCDF
ND
0.0604 '
' '
1,2,3,4,6,7,8-HpCDF
0.257
36:34
1.02
A
1,2,3,4,7,8,9-HpCDF
ND
0.0761
OCDF
1.03
41:10
0.88
A
Total TCDDs
ND
0.222
0.181
Total PeCDDs
ND
0.263
0.650
Total HxCDDs
ND
0359
Total HpCDDs
1.06
Total TCDFs
0.380
Total PeCDFs
0.133
0.217
Total HxCDFs
0.262
0.296
Total H CDFs
0.770
1TEF TEQ (ND=0)
0.0915
0.358
ITEF TEQ (ND=1/2) ,
0.141
0.383
Client Information
Project Name:
Sample ID:
Laboratory Information
Project ID:
Sample ID:
Collection Date/Time:
Receipt Date:
Extraction Date:
Analysis Date:
Sample Information
RFS Ecusta, Inc.
Station 1 Comp#5 Matrix:
10 Northern Hogsucker Weight / Volume:
Solids / Lipids:
Original pH :
G478-2 -Batch ID:
32036
06-Nov-01 11:00
09-Nov-01
22-Nov-01
30-Nov-01
Filename:
Retchk:
Begin ConCal:
Initial Cal:
Fish
1I.69 Grams
100 %
NA
WG6309
a29nov01f-13
a29nov01f-1
a29nov01f 1
m1613-101201a
1/2
15

Paradigm Analytical Labs
Method 1613
Station 1 Comp#5 -10 Northern Hogsucker
Environmental Testing Siolutions
AnaIytical Data Summary Sheet
Labeled
Standard
'
Expected
Amount
(ng)
Measured
Amount
(DO(%)
Percent
Recovery
RT
(min.)
Ratio
Qualifier
Extraction Standards
13C12-2,3,7,8-TCDD
2
1.61
' '
80.3
28:00
0.82
13C12-1,2,3,7,8-PeCDD
2
1.81
:90.E
32:35
1.57
13C12-1,2,3,4,7,8-HxCDD
2
1.73
86.6
34:49
1.25
13C12-1,2,3,6,7,8-HxCDD
2
1.72
86.1
34:54
1.23
13C12-1,2,3,4,6,7,8-HpCDD
2
1.73
86.6
37:35
1.04
13C12-0CDD
4
2.82
-70.5
40:57
0.84
13C12-2,3,7,8-TCDF
2
1.65
82.3
27:05
0.8
l3C12-1,2,3,7,8-PeCDF
2
1.54
77.2
31:49
1.66
'3C12-2,3,4,7,8-PeCDF
2
1.58
79.0
.
32:24
1.64
13C12-1,2,3,4,7,8-HxCDF
2
1.65
.
•82.5
34:11
0.50
'3C12-1,2,3,6,7,8-HxCDF
2
1.71
.85.5
34:17
0.51
13C12-2,3,4,6,7,8-HxCDF
2
1.71
85.3
• '
34:42
0.52
13C12-1,2,3,7,8,9-HxCDF
2
1.71
'85.6
35:19
0.51
13C12_ 1,2,3,4,6,7,8-HpCDF
2
1.63
•81.4
36:33
0.44
13C12-1,2,3,4,7,8,9-HpCDF
2
1.76
•
:87.9
38:06
0.45
Cleanup Standards
31C14-2,3,7,8-TCDD
0.8
0.70
88.0
28:01
Infection Standards
13C12-12,3,4-TCDD
2
27:18
0.82
.
13C1,-1,2,3,7,8,9-HxCDD
2
34:42
0.52
Client Information
Project Name:
Sample ID:
Laboratory Information
Sample Information
RFS Ecusta, Inc.
Station 1 Comp#5 Matrix: Fish
10 Northern Hogsucker Weight / Volume: 11.69 Grams
;Solids / Lipids: 100 %
:Original pH : NA
Project ID: G478-2 Batch ID: WG6309
Sample ID: 32036
Collection Date/Time:
Receipt Date:
Extraction Date:
Analysis Date:
Analyzed by:
Date:
Filename: a29nov01f-13
06-Nov-01 11:00 Retchk: a29nov0If--1
09-Nov-01 Begin ConCal: a29nov01f-1
22-Nov-01
30-Nov-01 Initial Cal:
2/2
Reviewed by:
Date:
m1613-101201a
16

Paradigm Analytical Labs
Method 1613
Station 2 Comp#1 - 10 Redbreast Sunfish
Environmental Testing Solutions
Analytical Data Summary Sheet
Analyte
Amount
(Pg/g)
EDL
(Pgtg)
EMPC
(Pr/g)
RT
( )
Ratio
Qualifier
2,3,7,8—TCDD
•
EMPC
0.0687 "
0.267
28:02
0.53
1,2,3,7,8-PeCDD
EMPC
0.0239
0.269
32:36
1.15
1,2,3,4,7,8-HxCDD
ND
0.144 •
1,2,3,6,7,8-HxCDD
0.325
34:54
1.1
A
1,2,3,7,8,9-HxCDD
ND
0.133
1,2,3,4,6,7,8-HpCDD
0.786
37:35
1.06
A
OCDD
4.36
40:57
0.85
A
2,3,7,8--TCDF
I.05
27:07
0.76
1,2,3,7,8-PeCDF
ND
0.0392
.
2,3,4,7,8-PeCDF
0.106
32:25
1.47
•
A
1,2,3,4,7,8-HxCDF
ND
0.0765
1,2,3,6,7,8-HxCDF
ND
0.0749 •
2,3,4,6,7,8-HxCDF
ND
0.0880
1,2,3,7,8,9-HxCDF
ND
0.109 •
•
1.2,3,4,6,7,8-HpCDF
0.253
36:34
1.11
A
1,2,3,4,7,8,9-HpCDF
ND
0.139
•
OCDF
1.16
•
41:11.
0.83
_ A
Total TCDDs
ND
0.221
0.369
Total PeCDDs
ND
0.380
. 1.30
•
Total HxCDDs
0.325
-
Total HpCDDs
1.15
Total TCDFs
1.05
1.11
Total PeCDFs
0.212
0.389
Total HxCDFs
0.221
Total HpCDFs
0.761
0.206
0.608
ITEF TEQ (ND=0)
I TEF TEQ (ND='fi)
0.280
0.641
Client Information
Sample Information
Project Name: RFS Ecusta, Inc.
Sample ID: Station 2 Comp#1 Matrix: • Fish
10 Redbreast Sunfish Weight / Volume: 11.32 Grams
.. • Solids / Lipids: 100 To
. Original pH : ' • NA
Project ID: G478-2 Batch ID: WG6309
Sample ID: 32037
Laboratory Information
Filename: a29nov01f-14
Collection Date/Time: 05-Nov-01 10:30 Retchk: a29nov01 f-1
Receipt Date: 09-Nov-01 Begin ConCal: a29nov01f-1
Extraction Date: 22-Nov-01
Analysis Date: 30-Nov-Ol Initial Cal: m1613-101201a
1)2
17

Paradigm Analytical Labs
Method 1613 .
Station 2 Comp#1-10 Redbreast Sunfish
Environmental Testing Solutions
•
Analytical Data Summary Sheet
Labeled
Standard
Expected
Amount
(ng)
-
Measured
Amount
(ng)
• Percent
Recovery
(%)
RT
(ft.)
Ratio
Qualifier
Extraction Standards
2
2
2
2
2
4
2
2
2
2
2
2
2
2
2
0.8
2
2
•
1.48
1.60
1.64
1.60
1.68 .
2.43
1.52
1.40 .
1.41
1.57
1.57
1.56
1.60
1.54
1.58
0.66
73.8
80.2
81.8
80.0
84.2
60.7
75.9
. 70.2
_ 70.6
78.6 ••34:12
7.8.6
. 78.1
80.2
76.8
78.9
'
82.5
28:01
32:35
34:49
34:54
37:35
40:57
27:06
31:49
'32:25
34:17
34:42
35:20.
36:33
38:06
28:02
27:19
34:42
'
•
•
0.81
1.55
1.24
1.25
1.06
0.81
0.8
1.64
1.64
0.51
0.51
0.5
0.51
0.45
0.46
0.82
0.5
13C12-2,3,7,8-TCDD
13C12-1,2,3,7,8-PeCDD
13C12-1,2,3,4,7,8-HxCDD
13C12-1,2,3,6,7,8-HxCDD
13C12-1,2,3,4,6,7,8-HpCDD
13C12-0CDD
13C12-2,3,7,8-TCDF
13C 12- 1,2,3,7,8-PeCDF
13C12-2,3,4,7,8-PeCDF
13C12-1,2,3,4,7,8-HxCDF
t3C12-1,2,3,6,7,8-HxCDF
13C12-2,3,4,6,7,8-HxCDF
13C,2-1,2,3,7,8,9-HxCDF
t3Ct2-1,2,3,4,6,7,8-HpCDF
13C12-1,2,3,4,7,8,9-HpCDF
Cleanup Standards
37C14-2,3,7,8-TCDD
Iniection Standards
l3C12-1,2,3,4-TCDD
13C12-1,2,3,7,8,9-HxCDD
Client Information
Project Name:
Sample ID:
Laboratory Information
Sample Information'
RFS Ecusta, Inc.
Station 2 Comp#1 ,Matrix: • Fish
10 Redbreast Sunfish Weight / Volume: 11.32 Grams
:Solids 1 Lipids: 100 %
Original pH : NA
Project ID: G478-2 Batch ID: WG6309
Sample ID: 32037
Collection Date/rime: 05-Nov-01 10:30
Receipt Date: 09-Nov-01
Extraction Date: 22-Nov-01
Analysis Date: 30-Nov-01
Analyzed by:
Date:
Filename:
Retchk:
Begin ConCal:
Initial Cal:
212
a29nov01 f-14
a29nov01f-1
a29nov01 f-1
Reviewed by:
Date:
m1613-101201a
18

Paradigm Analytical Labs
Method 1613
Station 2 Comp#2 - 10 Redbreast Sunfish
Environmental Testing Solutions
Analytical Data Summary Sheet
Analyte
Amount
(pg/g)
EDL
(pdg)
_
EMPC
(pg/g)
RT
(min.)
Ratio
Qualifier
2,3,7,8--TCDD
EMPC
0.0679
0.208
28:02
0.44
1,2,3,7,8-PeCDD
EMPC
0.0267
0.306
32:35
2.19
1,2,3,4,7,8-HxCDD
ND
0.166
,
1,2,3,6,7,8-HxCDD
EMPC
0.149
0.253
34:54
1.01
1.2,3,7,8,9-HxCDD
ND
0.151
•
. .
1,2,3,4,6,7,8-HpCDD
0.672
37:36
1.06
A
OCDD
3.35
40:58
0.89
A
2,3,7,8—TCDF
0.331
27:06
0.84
A
1,2,3,7,8-PeCDF
ND
0.0367
2,3,4,7,8-PeCDF
0.0878
32:25
1.45
A
1,2,3,4,7,8-HxCDF
WPC
0.0514
'
0.0676
34:12
1.60
1,2,3,6,7,8-HxCDF
0.0659
•
34:17
1.15
A
2,3,4,6,7,8-HxCDF
EMPC
0.0584
0.0828
34:42
1.05
1,2,3,7,8,9-HxCDF
ND
0.0757
'
-
'
1,2,3.4,6,7,8-HpCDF
EMPC
0.0753
0.182
36:34
1.21
1,2,3,4,7,8.9-HpCDF
ND
0.101
OCDF
0.726
41:11
0.82
A
Total TCDDs
ND
0.171
0.208
Total PeCDDs
ND
0.294
1.43
Total HxCDDs
ND
0345
0.253
Total HpCDDs
1.02
_
Total TCDFs
0.331
Total PeCDFs
0.181
.
Total HxCDFs
0.260
0.471
Total HpCDFs
0.277
0.459
-
0.0944
0.498
,
Ira. TEQ (ND=0)
TTEF TEQ (ND=')
0.169
0.519 _
Client Information
Project Name:
Sample ID:
Laboratory Information
Project ID:
Sample ID:
Collection Date/Time:
Receipt Date:
Extraction Date:
Analysis Date:
Sample Information
RFS Ecusta, Inc.
Station 2 Comp#2 Matrix:
10 Redbreast Sunfish Weight/ Volume:
Solids / Lipids:
Original pH :
G478-2 Batch ID:
32038
05-Nov-01 10:30
09-Nov-01
22-Nov-01
30-Nov-01
Filename:
Retchk:
Begin ConCal:
Initial Cal:
Fish
11.84 Grams
100 %
NA
WG6309
a29nov01f_2-2
a29nov01f-15
a29nov01 f-15
m1613-101201a
112
19

Paradigm Analytical Labs
Method 1613
Station 2 Comp#2 -10 Redbreast Sunfish
Environmental Testing Solutions
Analytical Data Summary Sheet
Labeled
Standard
•
Expected
Amount
(ng)
Measured
Amount
(ng)
Percent
Recovery
(%)
RT
(min.)
Ratio
Qualifier
Extraction Standards
13C12-2,3,7,8-TCDD
2
1.44
•
71.9 •
28:01
0.79
13C12-1,2,3,7,8-PeCDD
2
1.54
77.1
32:35
1.53
13C12-1,2,3,4,7,8-HxCDD
2
1.53
76.7
34:49
1.24
i3Ct2-1,2,3,6,7,8-I.1xCDD
2
1.56
78.0
34:54
1.23
13C12-1,2,3,4,6,7,8-HpCDD
2
1.58
78.8
37:35
1.04
13C12-0CDD
4
2.41
60.2
40:57
0.83
13C12-2,3,7,8-TCDF
2
1.47
73.6
27:06
0.8
13C12-1,2,3,7,8-PeCDF
2
1.35
67.4
31:49
1.64
13C12-2,3,4,7,8-PeCDF
2
1.37
68.3
32:25
1.64
13C12_1,2,3,4,7,8-HxCDF
2
1.51
75.5
34:12
051
13C12-1,2,3,6,7,8-RxCDF
2
1.59
79.7
34:17
0.52
13C13-2,3,4,6,7,8-HxCDF
2
1.56
•
78.0 •
34:42
0.51
'3C12-1,2,3,7,8,9-HxCDF
2
1.56
• 78.2•
35:20
0.51
13C12-1,2,3,4,6,7,8-HpCDF
2
1.49
74.5
36:33
0.45
13C12-1,2,3,4.7,8,9-HpCDF
2
1.55
77.7
38:06
0.46
•
Cleanup Standards
•
37C14-2,3,7,8-TCDD
0.8
0.64
80.3
28:02
Infection Standards
'3C12-1,2,3,4-TCDD
2
2 7 :19
0.8
13C12-1,2,3,7,8,9-HxCDD
2
34:42
0.51
Client Information
Project Name:
Sample ID:
Laboratory Information
Sample Information
RFS Ecusta, Inc.
Station 2 Comp##2 Matrix: Fish
10 Redbreast Sunfish Weight / Volume: 11.84 Grams
Solids / Lipids: 100 %
Original pH : NA
Project ID: G478-2 Batch ID: WG6309
Sample ID: 32038
Collection Date/Time:
Receipt Date:
Extraction Date:
Analysis Date:
Analyzed by:
Date:
Filename:
05-Nov-01 10:30 Retchk:
09-Nov-01 Begin ConCal:
22-Nov-01
30-Nov-01
2/2
a29nov01f_2-2
a29nov01f-15
a29nov01 f-15
Initial Cal: m1613-101201a
•Reviewed by:
• Date:
20

•
Paradigm Anatyrlcal Labs
Method 1613
Station 2 Comp#3 -10 River Chub
Environmental Testing Solutions
Analytical Data Summary Sheet
Analyte
Amount
(WO
EDL
(PB/g)
EMPC •
ink)
RT
(Wm)
Ratio
Qualifier
2,3,7,8--TCDD -
EMPC
0.0624
0.205
28:02
0.37
1,2,3,7,8-PeCDD
EMPC
0.0219
:,
0.227
. 32:36
0.98
1,2,3,4,7,8-HxCDD
ND
0.109
,
1,2,3,6,7,8-HxCDD
0.169
34:54
1.07
A
1,2,3,7,8,9-HxCDD
ND
0.0984
• •
. ' • •
1,2,3,4,6,7,8-HpCDD
0.484
37:36
0.95
A
OCDD
2.54
•
40:57
0.91
A
2,3,7,8 TCDF
0.841
27:06
0.77
1,2,3,7,8-PeCDF
ND
0.0324
2,3,4,7,8-PeCDF
E vIPC
0.0269
•
0.117
32:25
1.84
1.2,3,4,7,8-HxCDF
ND
0.0465
.
1,2,3,6,7,8-HxCDF
ND
0.0455
2,3,4,6,7,8-HxCDF
0.0792
34:41
1.23
A
1,2,3,7,8,9-HxCDF
ND
0.0670
1,2,3,4,6,7,8-HpCDF
EMPC
0.0441
0.174
36:34
0.88
1,2,3,4,7,8,9-HpCDF
ND
0.0587
OCDF
0.574
41:11
0.93
A
Total TCDDs
ND
0.179
0.205
Total PeCDDs
ND
0.214
0.420
Total HxCDDs
0.169
'
0.293
Total HpCDDs
0.751
Total TCDFs
0.972
•
Total PeCDFs
ND
0.0296
'
0.236
Total HxCDFs
0.165
0.255
•
Total HpCDFs
0.245 ,
0.419
0.117
0.496
1TEF TEQ (ND=0)
TTEF TEQ (ND= 4)
0.180
0.515
Client Information
Project Name:
Sample ID:
Laboratory Informatioq
Project ID:
Sample ID:
Collection Date/Time:
Receipt Date:
Extraction Date:
Analysis Date:
Sample Information
RFS Ecusta, Inc.
Station 2 Comp#3 Matrix:
10 River Chub Weight / Volume:
. Solids / Lipids:
Original pH :
G478-2 Batch ID:
32039
05-Nov-01 10:30
09-Nov-01
22-Nov-01
30-Nov-01
Filename:
Retchk:
Begin ConCal:
• Initial Cal:
Fish
11.61 Grams
100 %
NA
WG6309
a29nov01f 2-3
a29nov01f-15
a29nov01 f-15
m1613-101201a
112
21

Paradigm Analytical Labs
Method 1613
Station 2 Comp#3 -10 River Chub
Environmental Testing Solutions
Analytical Data Summary Sheet
Labeled
Standard
•
Expected
Amount
(ng)
Measured
Amount
(ng)
Percent
Recovery
(9'0)
RT
(min.)
Ratio
Qualifier
Extraction Standards
13C12-2,3,7,8-TCDD
2
1.57
78.4
28:01
0.79
13C12-1,2,3,7,8-PeCDD
2
1.62
81.2
32:35
1.52
13C1 -1,2,3,4,7,8-HxCDD
2
1.70
85.1
34:49
1.24
13C12-1,2,3,6,7,8-HxCDD
2
1.73
86.7
34:54
1.23
13C 12- 1,2,3,4,6,7,8-HpCDD
2
1.83
91.5
37:35
1.05
13C12-0CDD
4
2.69
67.3
40:57
0.81
11C12-2,3,7,8-TCDF
2
1.59
79.6
27:06
0.79
c3C12-1,2,3,7,8-PeCDF
2
1.44
72.0
31:49
1.64
13C12-2,3,4,7,8-PeCDF
2
1.48
73.8
32:25
1.61
13C12-1,2,3,4,7,8-HxCDF
2
1.64
.• 82.2
34:12
0.51
13C12-1,2,3,6,7,8-13.xCDF
2
1.73
86.3
34:I7
0.52
13C12-2,3,4,6,7,8-HxCDF
2
I.74
87.1
34:42
0.52
13C12-1,2,3,7,8,9-HxCDF
2
1.71
85.3
35:19
0.51
13Ct2-1,2,3,4,6,7,8-HpCDF
2
1.69
84.7
36:33
0.45
13C12-1,2,3,4,7,8,9-HpCDF
2
1.70
84.8
38:07
0.46
Cleanun Standards
37C14-2,3,7,8-TCDD
0.8
0.71
88.3
28:02
Infection Standards
13C12-1,2,3,4-TCDD
2
27:19
0.8
,
13C12-1,2,3,7,8,9-HxCDD
2
34:42
0.52
Client Information
Project Name:
Sample ID:
)Laboratory Information
Project ID:
Sample ID:
Collection DateiTime:
Receipt Date:
Extraction Date:
Analysis Date:
Analyzed by:
Date:
Sample Information
RFS Ecusta, Inc.
Station 2 Comp#3 Matrix:
10 River Chub Weight /Volume:
Solids / Lipids:
:Original pH :
G478-2 Batch ID:
32039
05-Nov-01 10:30
09-Nov-01
22-Nov-01
30-Nov-01
Filename:
Retchk:
Begin ConCal:
Initial Cal:
2/2
Fish
11.61 Grams
100 90
NA
WG6309
a29nov01f_2-3
a29nov01f-15
a29nov01f-15
m151-101201a
Reviewed by:
Date: jZ3 D 1
22

Paradigm Analytical Labs
Method 1613
Station 2 Comp#4 -10 Northern Bog,sucker
Environmental Testing Solutions
Analytical Data Summary Sheet
Analyte
Amount
(PS%8)
EDL •
(Prig)
EMPC -
(Pg%g)
RT
(min.)
Ratio
Qualifier
_
2,3,7,8 TCDD
EMPC
0.0539
0.246
28:01
0.35
1,2,3,7,8-PeCDD
EMPC
0.0356
0.279
32:35
1.19
12,3,4,7,8-HxCDD
ND
0.119
1,2,3,6,7,8-HxCDD
0.224
34:54
1.14
A
1,2,3,7,8,9-HxCDD
ND
0.108
1,2,3,4,6,7.8-HpCDD
0.536
37:36
1.06
A
OCDD
2.42
40:58
0.91
A
2,3,7,8—TCDF
0.724
•
27:06
0.73
1,2,3,7,8-PeCDF
ND
0.0373
2,3,4,7,8-PeCDF
0.109
32:25
1.55
A
1,2,3,4,7,8-HxCDF
ND
0.0508
1,2,3,6,7,8-HxCDF
ND
0.0510
2,3,4,6,7,8-HxCDF
ND
0.0575
1,2,3,7,8,9-HxCDF
ND
0.0749
1,2,3,4,6,7,8-HpCDF
0.284
.
36:34
0.97
A
1,2,3,4,7,8,9-HpCDF
ND
0.0749
OCDF
0.946
41:11
0.87
A
Total TCDDs
0.109
0.356
Total PeCDDs
ND
0.198
0.609
Total HxCDDs
0.224
•
Total HpCDDs
0.813
_
Total TCDFs
0.816
Total PeCDFs
0.181
Total HxCDFs
ND
0.0578
0.157
Total HpCDFs
0.604
_
,
ITEF TEQ (ND=0)
0.161
0.546
rTEF TEQ (ND=')
0.221
_ 0.571
Client Information
Project Name:
Sample ID:
Laboratory Information
Project ID:
Sample ID:
Collection Date/Time:
Receipt Date:
Extraction Date:
Analysis Date:
Samnle Information .
RFS Ecusta, Inc.
Station 2 Comp#4 Matrix:
10 Northern Hogsucker Weight / Volume:
Solids / Lipids:
Original pH :
G478-2 Batch ID:
32040
05-Nov-01 10:30
09-Nov-01
22-Nov-01
30-Nov-01
Filename:
Retchk:
Begin ConCal:
Initial Cal:
Fish
11.69 Grams
100 %
NA
WG6309
a29nov01f_2-4
a29nov01f-15
- a29nov01f-15
mI613-101201a
1/2
23

Paradigm Analytical Labs
Method 1613
Station 2 Comp#4 -10 Northern Hogsucker
Environmental Testing Solutions•
Analytical Data Summary Sheet
Labeled
Standard •
Expected
Amount
(ng)
Measured
Amount
(ng)
Percent
Recovery
(%)
RT
(min.)
Ratio
Qualifier
Extraction Standards
,
13C12-2,3,7,8-TCDD
2
1.50
74.9
28:00
0.8
13C12-1,2,3,7,8-PeCDD
2
158
79.2
32:35
1.52
13C 12-1,2,3,4,7,8-HxCDD
. 2
1.61
80.3
34:49
1.21
13C 12-1,2,3,6,7,8-HxCDD
2
1.64
81.8
34:54
1.24
13C 12-1,2,3,4,6,7,8-HpCDD
2
1.70
85.1
37:35
1.04
13C12-OCDD
4
2.58
64.4
40:57
0.83
13C12-2,3,7,8-TCDF
2
1.52
75.9
27:06
0.8
13C12-1,2,3,7,8-PeCDF
2
1.40
69.9
31:49
1.64
13C12-2,3,4,7,8-PeCDF
2
1.42
71.0
32:25
I.62
13C12-1,2,3,4,7,8-HxCDF
2
1.57
•78.4 •
34:12
0.50
13C12-1,2,3,6,7,8-HxCDF
2
1.62
81.0
34:17
0.52
13C12-2,3,4,6,7,8-HxCDF
2
1.63
• 81.5
34:42
0.51
13C12-1,2,3,7,8,9-HxCDF
2
1.62
81.1
35:20
0.52
13C12-1,2,3,4,6,7,8-HpCDF
2
1.56
78.2
36:33
0.45
13C12-1,2,3,4,7,8,9-HpCDF
2
1.67
83.4
38:06
0.45
Cleanup Standards
•
37C14-2,3,7,8-TCDD
0.8
0.70
87.3
28:02
Infection Standards
13C12-1,2,3,4-TCDD
2
27:19
0.8
'
13C1.,-1,2,3,7,8,9-HxCDD
2
34:42
0.51
Client Information
Project Name:
Sample ID:
Laboratory Information
Sample Information
RFS Ecusta, Inc.
Station 2 Comp#4 Matrix:. Fish
10 Northern Hogsucker ▪ Weight / Volume: 11.69 Grams
•Solids / Lipids: 100 %
Original pH : NA
Project ID: G478-2 Batch ID: WG6309
Sample ID: 32040
Collection Datefrime:
Receipt Date:
Extraction Date:
Analysis Date:
Analyzed by:
Date:
Filename: a29no• v01 f_2-4
05-Nov-01 10:30 Retchk: a29nov01 f-15
09-Nov-01 Begin ConCal: a29nov01 f-15
22-Nov-01
30-Nov-01 Initial Cal: m1613-101201a
Reviewed by: tal
Date' . !d% /3� /
. 2)2
24

Paradigm Analytical Labs
Method 1613
Station 2 Comp#5- 10-Yellow Bullhead
Environmental Testing Solutions
Analytical Data Summary Sheet
Analyte
Amount
(Pg/g)
EDL
(Pglg)
EMPC
(Pgig)
RT
(min.)
Ratio
Qualifier
2,3,7,8—TCDD
EMPC
0.0405
0.244
28:02
0.47
1,2,3,7,8-PeCDD
EMPC
0.0410
0,408
32:35
1,24
1,2,3,4,7,8-HxCDD
0.129
34:50
1.08
A
1,2,3,6,7,8-HxCDD
0.394
34:54
1.08
A
1,2,3,7,8,9-HxCDD
EMPC
0.163
0.158
35:06
0.85
1,2,3,4,6,7,8-HpCDD
0.703
37:36
1.04
A
OCDD
2.31
40:57
0.87
A
2,3,7,8— TCDF
0.395
27:06
0.81
A
1,2,3,7,8-PeCDF
0.0669
- •
31:49
1.63
A
2,3,4,7,8-PeCDF
0.177
32:25
1.61
A
1,2,3,4,7,8-HxCDF
0.0622
34:12
1.07
A
1,2,3,6,7,8-HxCDF
EMPC
0.0559
0.0574
34:17
0.9
2,3,4,6,7,8-HxCDF
0.0717
34:42
1.14
A
1 2,3,7,8,9-HxCDF
ND
0.0859
1,2,3,4,6,7,8-HpCDF
0.193
36:33
0.92
A
1,2,3,4,7,8,9-HpCDF
ND
0.0475
,OCDF
0.577
-
41:11
0.83
A
Total TCDDs
ND
0.177
0.476
Total PeCDDs
ND
0.194
0.408
Total HxCDDs
0.523
0.680
Total HpCDDs
0.703
0.966
Total TCDFs
0.516
Total PeCDFs
0.363
0.456
Total HxCDFs
0.309
0.367
Total HpCDFs
0.411
•
_
,
0.209
..
0.678
1TEF TEQ (ND=0)
ITEF TEQ (ND=i)
0.255
0.683
Client Information
Sample Information .
Project Name: RFS Ecusta, Inc. •
Sample ID: Station 2 Comp#5 Matrix: Fish
10 Yellow Bullhead Weight / Volume: 12.55 Grams
Solids FLipids: 100 %
Original pH : NA
Project ID: G478-2 Batch ID: WG6309
Sample ID: 32041
Laboratory Information
Filename: a29nov01 f 2-5
Collection Date/Time: 05-Nov-01 10:30 Retchk: a29nov01f 15
Receipt Date: 09-Nov-01 Begin ConCal: a29nov01 f-15
Extraction Date: 22-Nov-01
Analysis Date: 30-Nov-01 Initial Cal: m1613-101201a
1/2
25

Paradigm Analytical Labs
Method 1613 •
Station 2 Comp#S -10 Yellow Bullhead
Environmental Testing Solutions
Analytical Data Summary Sheet
Labeled
Standard
•
Expected
Amount
(ng)
.Measured
Amount
(ng)
Percent
Recovery
(%)
RT
(min.)
Ratio
Qualifier
Extraction Standards
cal N N N et N N N N N N N N N Q N N
13C12-2,3,7,8-TCDD
1.64
• 81.8
28:00
0.8
13C12-1,2,3,7,8-PeCDD
1.84
91.9
32:35
1.57
13C12-1,2,3,4,7,8-HxCDD
1.81
90.3
34:49
1.19
13C12-1,2,3,6,7,8-HxCDD
1.78
89.1
34:54
1.17
13C12-1,2,3,4,6,7,8-HpCDD
2.00
99.8
37:35
1.05
f3C12-0CDD
3.04
76.0
40:57
0.81
13C 12-2,3,7,8-TCDF
1.65
82.6
27:06
0.8
13C12-1,2,3,7,8-PeCDF
1.58
78.9
. 31:49
1.64
13C12-2,3,4,7,8-PeCDF
1.61 ,
80.5
32:25
1.62
13C12-1,2,3,4,7,8-HxCDF
1.77
88.6.
34:12
0.50
'3C12-1,2,3,6,7,8-HxCDF
1.80
89.8
34:17
0.51
13C12-2,3,4,6,7,8-HxCDF
1.76 -
87.9
34:42
0.5
13C12-1,2,3,7,8,9-HxCDF
1.77
88.4
35:20
0.5
13C12-1,2,3,4,6,7,8-HpCDF
1.79
89.3
36:33
0.44
13C12-1,2,3,4,7,8,9-HpCDF
1.89
94.6
38:06
0.46
CIeanup Standards
37C14-2,3,7,8-TCDD
0.74
• 92.0
28:02
Injection Standards
t3C12-1,2,3,4-TCDD
27:18
0.79
t3Cf2-1,2,3,7,8,9-HxCDD
34:42
0.5
Client Information
Project Name:
Sample TO:
Laboratory Information
Sample Information
RFS Ecusta, Inc.
Station 2 Comp#5 'Matrix:. Fish
10 Yellow Bullhead Weight / Volume: 12.55 Grams
Solids / Lipids: 100 90
Original pH : NA
Project ID: G478-2 Batch ID: WG6309
Sample ID: 32041
Filename: a29nov01 f_2-5
Collection DatetFime: 05-Nov-01 10:30 ,Retchk: a29nov01f-15
Receipt Date: 09-Nov-01 •Begin ConCal: a29nov01 f-15
Extraction Date: 22-Nov-01
Analysis Date: 30-Nov-01 Initial Cal: m 1613-101201 a
Analyzed by:
Date:
Reviewed by:
Date:
2/2'
26

Paradigm Analytical Labs
Method 1613
Station 3 Comp#1-10 Northern Hogsucker
Environmental Testing Solutions
Analytical Data Summary Sheet
Analyte
Amount
(Pglg)
- EDL
(PSlg)
EMPC
(Pg/g)
` RT
(min.)
Ratio
Qualifier
2,3,7,8 TCDD
EMPC
0.0111
0.188
29:02
0.30
1,2,3,7,8-PeCDD
0.0856
33:00
1.64
A
1,2,3,4,7,8-HxCDD
0.0565
35:19
1.29
A
1,2,3,6,7,8-HxCDD
ND
0.0211
1,2,3,7,8,9-HxCDD
EMPC
0.0209
0.0719
35:37
0.95
1,2,3,4,6,7,8-HpCDD
0.288
38:16
0.98
A
OCDD
1.12
41:51
0.88
A
2,3,7,8--TCDF
0.392
28:05
0.84
A
1,2,3,7,8-PeCDF
EMPC
0.0108
0.0479
32:15
1.05
2,3,4,7,8-PeCDF
0.0942
32:49
1.69
A
1,2,3,4,7,8-HxCDF
0.0548
34:41
1.18
A
1,2,3,6,7,8-HxCDF
EMPC
0.0120
0.0377 •
34:47
0.85
2,3,4,6,7,8-HxCDF
0.0462
35:12
1.41
A
1,2,3,7,8,9-HxCDF
0.0360
•
' 35:52
1.42
A
1,2,3,4,6,7,8-HpCDF
0.159
37:11
1.16
A
1,2,3,4,7,8,9-HpCDF
0.0291
38:49
1.05
A
OCDF
0.312
,
42:06
0.88
A
Total TCDDs
ND
0.104
0.200
Total PeCDDs
0.0856
0.146
Total HxCDDs
0.243
Total HpCDDs
0.467
Total TCDFs
0.551
Total PeCDFs
0.0942
0.142
Total HxCDFs
0.205
0.276
Total HpCDFs
0.188
0.315
L
i
0.155
0.356
TTEF TEQ (ND=0)
TTEF TEQ (ND=t/)
0.163
0.357
Client Information
•
Project Name:
Sample ID:
Laboratory Information
Project ID:
Sample ID:
Collection DateiTime:
Receipt Date:.
Extraction Date:
Analysis Date:
Sample Information
RFS Ecusta, Inc.
Station 3 Comp#1 Matrix:
10 Northern Hogsucker Weight / Volume:
Solids / Lipids:
Original pH :
G478-2 Batch ID:
32711
07-Nov-01 10:00
09-Nov-01
22-Nov-01
28-Nov-01
Filename:
Retchk:
Begin ConCal:
Initial Cal:
Fish
11.68 Grams
100 %
NA
WG6309
a27nov01b_2-6
a27nov01b-15
a27nov01b-15
m1613-101201a
1/2
27

Paradigm Analytical Labs
Method 1613 . .
Station 3 Comp#1 - 10.Northern Hogsucker
Environmental Testing Solutions
Analytical Data Summary Sheet
Labeled
Standard
Expected
Amount
(ng)
Measured
Amount
(ng)
Percent
• Recovery
(%)
RT
(min.)
Ratio
Qualifier
Extraction Standards
13C12-2,3,7,8-TCDD
2
1.63
81.6
29:00
0.78
13C12-1,2,3,7,8-PeCDD
2
1.71
85.7
33:00
1.54
13C12-1,2,3,4,7,8-HxCDD
2
1.91
95.3
35:19
1.23
13C 12_ 1,2,3,6,7,8-HxCDD
2
1.89
94.7
35:24
1.23
13C12-1,2,3,4,6,7,8-HpCDD
2
1.89
94.6
38:16
1.03
13C12-OCDD
4
3.49
87.2
41:51
0.84
13C12-2,3.7,8--TCDF
2
1.69
84.7
28:04
0.8
13C12-1,2,3,7.8-PeCDF
2
1.48
74.2
32:15
1.66
13C12-2,3,4,7,8-PeCDF
2
1.80
89.8
32:49 '
1.68
l3C12-1,2,3,4,7,8-HxCDF
2
1.75 .
87.4
•34:41
0.50
13C12-1,2.3,6,7,8-HxCDF
2
1.83
91.3
34:46
0.51
13C12-2,3,4,6,7,8-HxCDF
2
2.05
103
35:12
• 0.51
13C12-1,2,3,7,8,9-HxCDF
2
1.82
91.0
35:52
0.51
13C12- I ,2,3,4,6,7,8-HpCDF
2
1.78
89.2
37:10
0.47
13C12-1,2.3,4,7,8,9-HpCDF
2
1.83
91.6
38:49
0.48
Cleanup Standards
•
37CI4-2,3,7,8-TCDD
0.8
0.73
91.6
29:02
Injection Standards
13C12-1,2,3,4-TCDD
2
28:18
0.79
`
13C12-1,2,3,7,8,9-HxCDD
2
35:12
0.51
Client Information
Project Name:
Sample ID:
Laboratory Information
Sample Information
RFS Ecusta. Inc.
Station 3 Comp#1 . *Matrix:. Fish
10 Northern Hogsucker Weight / Volume: 11.68 Grams
Solids / Lipids: 100 %
Original pH : NA
Project ID: G478-2 Batch ID: WG6309
Sample ID: . 32711
Collection Date/Time: 07-Nov-01 10:00
Receipt Date: 09-Nov-01
Extraction Date: 22-Nov-01
Analysis Date: 28-Nov-01
Filename:
Retchk:
Begin ConCal:
a27nov016 2-6
a27nov01b-15
a27nov01b-15
Initial Cal: m1613-101201a
Analyzed by: Reviewed by:
Date: Dam:
212
28

Paradigm Analytical Labs
Method 1613
Station 3 Comp#2 -10 Yellow Bullhead
Environmental Testing Solutions
Analytical Data Summary Sheet
Analyte
Amount
(Prig)
EDL
(Pgig)
EMPC
(PB/g)
RT
(Wm)
Ratio
Qualifier
2,3,7,8—TCDD
•
EMPC
0.0125
0.231
29:01
0.30
1,2,3,7,8-PeCDD
0.124
33:01
1.72
A
1,2,3,4,7,8-HxCDD
0.0572
35:19
1.06
A
1,2,3,6,7,8-HxCDD
0.232
35:24
1.3
A
I.2,3,7,8,9-HxCDD
0.0756
35:36
1.42
A
1,2,3,4,6,7,8-HxCDD
0.530
38:16
1.17
A
OCDD
2.24
41:52
0.86
A
2,3,7,8— TCDF
0.258
28:06
0.79
A
1,2,3,7,8-PeCDF
0.0517
32:15
1.62
A
2,3,4,7,8-PeCDF
0.153
32:49'
1.46
A
1,2,3,4,7,8-HxCDF
0.0314
34:41
1.06
A
1,2,3,6,7,8-HxCDF
0.0277
•
34:46
1.23
A
2,3,4,6,7,8-HxCDF
ND
0.0170
'
1,2,3,7,8,9-HxCDF
ND
•6;0234'
''
".•' ''
'
1,2,3,4,6,7,8-HpCDF
0.146
.
37:10
0.93
A
1,2,3,4,7,8,9-11pCDF
ND
0.0423
OCDF
0.290
• •'
:
•• .. •
42:06
0.76
A
Total TCDDs
_
0.0849
..
0.463
Total PeCDDs
0.124
.. .
0.432
Total HxCDDs
0.452
Total HxCDDs
0.745
0.841
Total TCDFs
0.258
0.365
Total PeCDFs
0.205
Total HxCDFs
0.208
0.256
Total HpCDFs
0.321
0.330
1
•
ITEF TEQ (ND30)
0.219
0.450
ITEF TEQ (ND=')
0.227
0.452
Client Information
Project Name:
Sample ID:
Laboratory Information
Project ID:
Sample ID:
Collection Date/Time:
Receipt Date:
Extraction Date:
Analysis Date:
$$ample Information
RFS Ecusta, Inc.
Station 3 Comp#2 -10 Yellow Bullhead :Matrix:
• • Weight / Volume:
. Sojids / Lipids; - - .
',Original pH :
G478-2 .Batch ID:
32712
07-Nov-01 10:00
09-Nov-01
22-Nov-01
28-Nov-01
'Filename:
Retch1c •
;Begin ConCal:
Initial Cal:
Fish
10.84 Grams
100 %
NA
WG6309
a27nov01b 2-7
a27nov01b-15
a27nov01 b-15
m1613-101201a
1/4
29

Paradigm Analytical Labs
Method 1613
Station 3 Comp#2 -10 YellowBullhead
Environmental Testing Solutions
Analytical Data Summary Sheet
Labeled
Standard •
Expected
Amount
(ng)
Measured
Amount
(ng)
Percent
. Recovery
(%)
RT
(min.)
Ratio
Qualifier
Extraction Standards
,
13C12_2,3,7,8-TCDD
2
1:61.
80.4
29:00
0.78
l3C12-1,2,3,7,8-PeCDD
2
1.81
90.6
33:00
1.55
13C12-I,2,3,4,7,8-HxCDD
2
1.83
91.4
35:19
1.22
13C12-1,2,3,6,7,8-HxCDD
2
1.77
88.4
35:24
1.22
13C12-1,2,3,4,63,8-HpCDD
2
1.76
87.9
38:16
1.07
13C12-OCDD
4
3.29
82.3
41:51
0.84
13C12-2,3,7,8-TCDF
2
1.64
82.1
28:04
0.83
13C12-1,2,3,7,8-PeCDF
2
1.49
.74.7
32:15
1.73
13C12-2,3,4,7,8-PeCDF
2
1.72
85.9
32:49
1.72
13C12-1,2,3,4,7,8-HxCDF
2
'1.79
89.7
34:41
0.49
13C12-1,2,3,6,7,8-HxCDF
2
1.85
92.7
34:46
0.5
13C12-2,3,4,6,7,8-HxCDF
2
1.91
95.5 •
35:12
0.51
13C12-1,2,3,7,8,9-HxCDF
2
1.77
88.3
35:52
0.51
13C12-1,2,3,4,6,7,8-HpCDF
2
1.71
85.4
37:10
0.46
13C12-1,2,3,4,7,8,9-HpCDF
2
137
88.3
38:49
0.46
Cleanup Standards
37C14-2,3,7,8-TCDD
0.8
0.71
89.1
29:02
Injection Standards
•
13Ct2-1,2,3,4-TCDD
2
28:18
0.76 '
13C1$-1,2,3,7.8,9-HxCDD ,
2
35:12
0.51
Client Information
Project Name:
Sample ID:
Laboratory Information
Project ID:
Sample ID:
Collection Date/'Time:
Receipt Date:
Extraction Date:
Analysis Date:
Analyzed by:
Date:
• Sample Informati n
RFS Ecusta, Inc. . .
Station 3 Comp#2 - 10 Yellow Bullhead : Matrix: • • , Fish
Weight ! Volume: 10.84 Grams
Solids /Lipids: 100 90
Original pH : NA
G478-2 Batch ID: • WG6309
32712
Filename: a27nov0I b_2-7
07-Nov-01 10:00 . Retchk: a27nov01b-15
09-Nov-01 Begin ConCal: a27nov01 b- 15
22-Nov-01
28-Nov-01 ' Initial Cal: m 1613-101201 a
Reviewed by:
Date: /WM
2/4
30

Paradigm Analytical Labs
Method 1613
Station 3 Comp#3 -10 Rockbass
Environmental Testing Solutions
Analytical Data Summary Sheet
Analyte
Amount
(pglg)
EDL
_ WO
- • EMPC
(pglg).
RT
(mim)
1-
Ratio
Qualifier -
2,3,7,8 TCDD
EMPC
0.0107
0.250
29:01
0.40
1,2,3,7,8-PeCDD
EMPC
0.023¢
_
.
0.143 -
33:00
2.19
1,2,3,4,7,8-HxCDD
0.0526
35:19
1.19
A
1,2,3,6,7,8-HxCDD
0.156
35:24
1.09
A
1,2,3,7,8,9-HxCDD
EMPC
0.0143
•
0.0696
35:37
•
1.03
1,2,3,4,6,7,8-HpCDD
0.594
38:16
1.02
A
OCDD
3.25
41:51
0.88
A
2,3,7,8-TCDF
0.716
28:05
0.8
1,2,3,7,8-PeCDF
EMPC
0.0102
0.0390
32:15
1.81
2,3,4,7,8-PeCDF
0.138
•
•
32:49
1.78
A
1,2,3,4,7,8-HxCDF
0.0323
34:41
1.29
A
1,2,3,6,7,8-HxCDF
0.0255
34:46
I.09
A
2,3,4,6,7,8-HxCDF
0.0306
•
35:13
1.37
A
1,2,3,7,8,9-HxCDF
EMPC
0.0066
0.0153
35:53
1.57
1,2,3,4,6,7,8-HpCDF
0.141
•
37:10
1.07
A
1,2,3,4,7,8,9-HpCDF
OCDF
ND
0.407
0.0226
•
_ •
• •
.
42:06
0.76
A
T
Total TCDDs
ND
0.112
0.338
.
Total PeCDDs
ND
0.217.
0.553
•
Total HxCDDs
0.435
•
0.504 •
Total HpCDDs
0.922
•
Total TCDFs
0.857
Total PeCDFs
0.138
Total HxCDFs
Total HpCDFs
0.156
0.363
0.216
i
1TEF TEQ (ND=0)
0.181
0.513
ITEF TEQ (ND=h)
0.194
0.513
Client Information
Project Name:
Sample ID:
Laboratory Information
Project ID:
Sample ID:
Collection Date/Time:
Receipt Date:
Extraction Date:
Analysis Date:
Sample Information
RFS Ecusta, Inc.
Station 3 Comp#3 - 10 Rockbass • Matrix:
Weight / Volume:
Solids 1. Lipids:
Original pH :
G478-2 Batch ID: •
32713
07-Nov-01 10:00
09-Nov-01
22-Nov-01
28-Nov-01
Filename:
Retchk:
Begin ConCal:
Initial Cal:
Fish
11.78 Grams
100 %
NA
WG6309
a27nov01 b_2-8
a27nov01b-15
a27nov01b-15
m1613-101201a
1/4
31

Paradigm Analytical Labs
Method 1613
Station 3 Comp#3 -10 Rockbass
Environmental Testing Solutions. • '
Analytical Data Summary Sheet '
Labeled
Standard
Expected
Amount
(n$)
Measured
Amount
(ng)
Fercent
Recovery
. (%)
RT
(min.)
Ratio
Qualifier
Extraction Standards
2
2
2
2
2
4
2
2
2
2
2
2
2
2
2
0.8
2
2
1.66
1.86
1.83
1.81
1.70
3.12
1.70
1.58
1.82
1.81
1.92
1.90
1.82
1.61
1.72
0.72
'
•
82.8
93.1
91.4
90.5
85.0
78.0
85.1
78.9
91.2
.90.4 .
95.8
95.2
91.2
80.6
86.1
89.4
•
29:00
33:00
35:19
35:24
38:16
41:51
28:04
32:15
32:49
34:41
34:46
35:12
35:52
37:10
38:49
29:02
28:18
35:12
•
0.79
1.54
1.18
1.19
1.07
0.86
0.81
1.67
1.66
0.49
0.5
0.49
0.51
0.47
0.48
0.79
0.49
13C12-2,3,7,8-TCDD
l3C12-1,2,3,7,8-PeCDD
13C12-1,2,3,4,7,8-HxCDD
13C 12-1,2,3,6,7,8-HxCDD
13C 12-1,2,3,4,6,7,8-HpCDD
13C12-OCDD
13C12-2,3,7,8-TCDF
t3C12-1,2,3,7,8-PeCDF
13C12-2,3,4,7,8-PeCDF
13C12-1,2,3,4,7,8-HxCDF
13C12-1,2,3,6,7,8-HxCDF
t3C12-2,3,4,6,7,8-HxCDF
13C12-1,2,3,7,8,9-HxCDF
13C 12-1,2,3,4,6,7,8-HpCDF
13C12-1,2,3,4,7,8,9-HpCDF
Cleanup Standards
37C14-2,3,7,8-TCDD
Iniection Standards
13C12-1,2,3,4-TCDD
13C12-1,2,3,7,8,9-HxCDD
Client Information
Project Name:
Sample ID:
Laboratory Information
Sample Information
RFS Ecusta, Inc.
Station 3 Comp#3 -10 Rockbass Matrix: Fish
Weight / Volume: 11.78 Grams
Solids / Lipids: 100 9'b
Original pH : NA
Project ID: G478-2 Batch ID: WG6309
Sample ID: 32713
Collection Date/Time: 07-Nov-01 10:00
Receipt Date: 09-Nov-01
Extraction Date: 22-Nov-0I
Analysis Date: 28-Nov-O l
Analyzed by:
Date: /.-13/f1
2/4
Filename:
Retchlc:
Begin ConCal:
a27nov01b_2-8
a27nov01b-15
a27nov01b-15
Initial Cal: m1613-101201a
Reviewed by:
Date:
32

Paradigm Analytical Labs
Method 1613
Station 3 Comp#4 - 10 Redbreast Sunfish
Environmental Testing Solutions
Analytical Data Summary Sheet
Analyte
Amount
(Pg/g)
EDL
(pgWg)
EMPC
(pg/e1
RT
(min.)
Ratio
Qualifier
2,3,7,8-TCDD
EMPC
0.0147
0.230
29:02
0.34
1,2,3,7,8-PeCDD
EMPC
0.0202
0.100
33:00
2.18
1,2,3,4,7,8-HxCDD
0.0294
35:19
1.27
A
1,2,3,6,7,8-HxCDD
0.155
35:24
1.27
A
1,2,3,7,8,9-HxCDD
EMPC
0.0171
''
0.0569
' 35:36
1.53
'
1,2,3,4,6,7,8-HpCDD
0.395
38:15
1.16
A
OCDD
1.65
41:51
0.87
A
2,3,7,8-TCDF
0.257
28:05
0.68
A
1,2,3,7,8-PeCDF
0.0432
32:15
1.66
A
2,3,4,7,8-PeCDF
0.0589
32:49
1.46
A
1,2,3,4,7,8-HxCDF
0.0393
34:41
1.30
A
1,2,3,6,7,8-HxCDF
0.0236
•
• 34:47
•
1.33
A
2,3,4,6,7,8-HxCDF
EMPC
0.0155 •
0.0255
35:12
1.61
1,2,3,7,8,9-HxCDF
ND
'0.0232
'
1,2,3,4,6,7,8-HpCDF
0.118
• :•.
37:10.
1.02
A
12,3,4,7,8,9-HpCDF
ND
0.0214
OCDF
EMPC
0.0155-
•
0.234
42:06
0.77
Total TCDDs
ND
0.128
0.298
Total PeCDDs
0.0393
0.711
Total HxCDDs
0.326
0.383
• -
Total HpCDDs
0.395
0.599
Total TCDFs
0.367
0.379
Total PeCDFs
0.181
0.234
Total HxCDFs
0.239
0.340
Total HpCDFs
0.118
0.236
,
ITEF TEQ (ND0)
0.0888
0.377
ITEF TEQ (ND=i)
0.104
0.379
Client Information
'Sample Information,
Project Name: RFS Ecusta, Inc.
Sample ID: Station 3 Comp#4 ' -Matrix: Fish
10 Redbreast Sunfish ' Weight / Volume: 10.19 Grams
Laboratory Information Solids /Lipids: 100 %
Original pH : NA
Project ID: G478-2 Batch ID: WG6309
Sample 1D: 32714
Filename: a27nov01 b_2-9
Collection Date/Time: 07-Nov-01 10:00 Retchk: a27nov01 b-15
Receipt Date: 09-Nov-01 "Begin ConCal: a27nov01 b-15
Extraction Date: 22-Nov-01 .
Analysis Date: 28-Nov-01 Initial Cal: m1613-101201a
t/2
33

Paradigm Analytical Labs
Method 1613 ..
Station 3 Comp#4 -10 Redbreast Sunfish
Environmental Testing Solutions
Analytical Data Summary Sheet
Labeled
Standard
Expected
Amount
(nf)
Measured
Amount
(ng) ,•
"'• Percent
• Recovery
.. (%) :
RT
_ (min.)
Ratio
Qualifier
Extraction Standards
i3C1,-2,3,7,8-TCDD
2
1.65
1 '
' 82.4
29:00
0.79
13C12-1,2,3,7,8-PeCDD
2
1.86
93.2
33:00
1.54
13C12_ ] ,2,3,4,7,8-HxCDD
2
1.85
92.5
35:19
1.18
13C12-1,2,3,6,7,8-HxCDD
2
1.90
94.8
35:2. 44
1.19
'3C12-1,2,3,4,6,7,8-HpCDD
2
1.66
82.9
38:16
1.01
13C12-OCDD
4
3.13
•78.2
41:51
0.84
'3Ci2-2,3,7,8-TCDF
2
1.68
84.2
28:04
0.81
13C12-1,2,3,7,8-PeCDF
2
1.61
. .
80.3
..32:15
.1.69
13C12-2,3,4,7,8-PeCDF
2
1.76
,
. 88.1
. 32:49
1.7
13C12-1,2,3,4,7,8-HxCDF
2
1.84
- 91.8..
-34:41
0.49
13C12-1,2,3,6,7,8-HixCDF
2
1.91
95.5
34:46
0.49
13C12-2,3,4,6,7,8-HxCDF
2
1.99
• 99.6 '
35:12
0.49
13C12-1,2,3,7.8,9-HxCDF
2
1.81'
90.5
35:52
0.49
'3C12-1,2,3,4,6,7,8-HpCDF
2
1.66
82.8. • -
37:10
0.46.
'3C12-1,2,3,4,7,8,9-HpCDF
2
1.70
85.2 .
38:49
0.47
Cleanup Standards
.. '
37C14-2,3,7,8-TCDD
0.8
0.70
.88.0
29:02
Iniection Standards
13Ct2-1,2,3,4-TCDD
2
28f18
0.79
13C12-1,2,3,7,8,9-HpCDD
2
35:T2 _
0.49
Client Informatioq
Project Name:
Sample ID:
Laboratory Information
;'Sample Information
RFS Ecusta, Inc.
Stadon3 Comp#4 Matrix: • Fish
10 Redbreast Sunfish Weight / Volume: 10.19 Grams
Solids / Lipids: 100 %
Original pH : NA
Project ID: G478-2 . Batch ID: ' WG6309
Sample ID: 32714
Filename: . • a27nov01 b_2-9
Collection Daterl'ime: 07-Nov-01 10:00 ' : Retchk: a27nov016-15
Receipt Date: 09-Nov-01 .: Begin ConCal: a27nov01b-15
Extraction Date: 22-Nov-01 • •
Analysis Date: 28-Nov-01 .: Initial' Cal: ,
Analyzed by:
Date:
m1613-101201a
Reviewed by:
Date:
21 .
34

Paradigm Analytical Labs
Method 1613 ' . .
Station 3 Comp#5 -10 Redbreast Sunfish
Environmental Tesiing Solutions
Analytical Data Summary Sheet
Analyte
Amount
(W8)
EDL
(pg/g)
'
• EMPC
• (pglg)
• :
RT
i (min.)
Ratio
Qualifier
2,3,7,8—TCDD
•
EMPC
0.0939
0.0872
29:02
0.37
1,2,3,7,8-PeCDD
ND
0.0415
• ' • .
1,2,3,4,7,8-HxCDD
ND
0.485
1,2,3,6,7,8-HxCDD
ND
0.466
•
1,2,3,7,8,9-HxCDD
ND
0.457
. _ .
•..
'
•
1,2,3,4,6,7,8-HpCDD
0597
38:15
0.96
A
OCDD
3.26
41:51
0.97
A
2,3,7,8--TCDF
EMPC
0.0702
0.181
28:06
0.45
1,2,3,7,8-PeCDF
ND
0.0284
2,3,4,7,8-PeCDF
0.0710
32:49
1.33
A
1,2,3,4,7,8-HxCDF
ND
0.0917
1,2,3,6,7,8-HxCDF
ND
0.0907
.
2,3,4,6,7,8-HxCDF
ND
0.0914
•
1,2,3,7,8,9-HxCDF
ND
0.128
'
' '
1,2,3,0,7,8-HgCDF
ND
0.0610
• • . .
1,2,3,4,7,8,9-HpCDF
ND
0.0830
.
OCDF
EMPC
0.109
' '
0.308
. . '
. 42:05
0.82
Total TCDDs
ND
0.0939
.0.0872
• •
Total PeCDDs
ND
0.0839
Total HxCDDs
ND
0469
Total HpCDDs
0.597
0.920
Total TCDFs
ND
0.0702
0.181
Total PeCDFs
0.0710
Total HxCDFs
ND
0.0993
Total HpCDFs
,
ND
0.0709
,
•
0.0447
0.150
ITEF TEQ (ND=0)
ITEF TEQ (ND=t)
0.198
0.253
_
Client Information
Project Name:
Sample ID:
Laboratory Information
Project ID:
Sample ID:
Collection Date/Time:
Receipt Date:
Extraction Date:
Analysis Date:
' Sample Information
RFS Ecusta, Inc.
Station 3 Comp#5 :Matrix:
10 Redbreast Sunfish • Weight / VoIume:
.:Solids / Lipids:.:.
'Original pH :
G478-2 :Batch ID:
32715
07-Nov-01 10:00
09-Nov-01
22-Nov-01
29-Nov-01
Filename:
. Retchk:
.Begin ConCal:
Initial Cal:
Fish
12.39 Grams
100 %
NA
WG6309
a28nov01a-12
a28nov01a-1
a28nov01a-1
m1613-101201a
1/2
35

Paradigm Analytical Labs
Method 1613
Station 3 Comp#5 -10: Redbreast Sunfish
Environmental Testing Solutions
Analytical Data Summary Sheet
Labeled
Standard
' Expected
Amount
(ng)
Measured
Amount
(ng)
Percent
Recovery
, . (%)
RT
(min.)
Ratio
Qualifier
Extraction Standards
13C12-2,3,7,8-TCDD
2
1.53
/6:4
29:00 •
0.79
13C12-1,2,3,7,8-PeCDD
2
1,75
87.6
33:00
1.59
13C12-1,2,3,4,7,8-HxCDD
2
1.77
88.6
35:19
1.27
13C12-1,2,3,6,7,8-HxCDD
2
1.77
88.5
35:24
1.22
13C12-1,2,3,4,6,7,8-HpCDD
2
1.69
84.3
38:15
1.07
13C 12-OCDD
4
3.26
81.6
41:50
0.84
13C12-2,3,7,8-TCDF
2
1.52
75.9
28:05
0.77.
13C12-1,2,3,7,8-PeCDF
2
1.48
, 74.0
32:15
1.62
13C12-2,3,4,7,8-PeCDF
2
1.74
87.1
32:49
1.59
13C12_ 1,2,3,4,7,8-H cCDF
2
1.61
80.3
:
34:40
0.51
13C12-1,2,3,6,7,8-HxCDF
2
1.71
85.6
34:46
0,52
13C12-2,3,4,6,7,8-HxCDF
2
1.73
86.3
'
• 35:12
0.52
'3C12-1,2,3,7,8,9-HxCDF
2
1.64
$1.9
'
35:52
'0.51
13C1_-1,2,3,4,6,7,8-HpCDF
2
1.59
•79.6
37:10
0.45
'3C12-12,3,4,7,8,9-HpCDF
2
1.58
79.2
38:48
0.45
Cleanup Standards
37C14-2,3,7,8-TCDD
0.8
0.64
80.5
29:02
Infection Standards
13C12-I,2,3,4-TCDD
2
28:17
0.82
'
13C12-1?,3,7,8,9-HxCDD
2
_ 35:12
0.52
Client Information
Project Name:
Sample ID:
Laboratory Information
Project ID:
Sample ID:
Collection Date/Time:
Receipt Date:
Extraction Date:
Analysis Date:
Analyzed by:
Date:
,Sample Information
RFS Ecusta, Inc.
Station 3 Comp#5 Matrix:.
10 Redbreast Sunfish Weight / Volume:
Solids / Lipids:
_Original pH : .
G478-2 Batch ID:
32715
07-Nov-01 10:00
09-Nov-01
22-Nov-01
29-Nov-01
•
;Filename:
Retchk:
Begin ConCal:
Initial Cal:
2/2
Fish
12.39 Grams
100 9'0
NA
WG6309
a28nov01 a-12
a28nov01 a-1
a28nov01a-1
Reviewed by:
Date:
m1613-101201a
36

Paradigm Analytical Labs
Method 1613 - QC BLANK Results
LMB
Analytical Data Summary Sheet
Analyte
Amount
(Pg/g)
' EDL
(PS/g)
.. EMPC
: (Pg/g)
RT
flu.)
Ratio
Qualifier
2,3,7,8--TCDD
•
ND
0.0768
1,2,3,7,8-PeCDD
0.0620
•
33:01
1.33
A
1,2,3,4,7,8-HxCDD
ND
• 0.109
.. •
..
1,2,3,6,7,8-HxCDD
ND
0.108
. •:
.
1,2,3,7,8,9-HxCDD
ND
0.104
1,2,3,4,6,7,8-HpCDD
0.228
38:15
0.9
A
OCDD
EMPC
0.189
0.988
41:51
1.05
2,3,7,8—TCDF
0.114
28:06
0.69
A
1,2,3,7,8-PeCDF
ND
0.0344 •
•
2,3,4,7,8-PeCDF
0.0740
32:50
1.32
A
1,2,3,4,7,8-HxCDF
0.0520
34:41
1.31
A
12,3,6,7,8-HxCDF
EMPC
0.0236
0.0460
34:47
0.96
2,3,4,6,7,8-HxCDF
EMPC •
0.0252
0.0460
35:13
1.44
1.2.3,7,8,9-HxCDF
EMPC
0.0348
0.0460
35:52
0.92
1,2,3,4.6,7,8-HpCDF
0.0820
37:10
' 0.97
A
1,2,3,4,7,8,9-HpCDF
ND
0.0522
OCDF
EMPC
0.104
•
0.216 _
42:06
0.8
Total TCDDs
ND.
0.192
Total PeCDDs
0.0620
•
Total HxCDDs
ND
0.282
Total HpCDDs
0.358
Total TCDFs
0.114
Total PeCDFs
0.0740
Total HxCDFs
0.0520
0.190
Total HpCDFs
0.0820
0.170
0.0877
0.103
1TEF TEQ (ND=0)
1TEF TEQ (ND=.)
0.148
0.158
•
_
Laboratory Information
Sample ID:
Extraction Date:
Analysis Date:
WG6309-1
22-Nov-01
27-Nov-01
Sample Information •
Matrix:
Weight / Volume:
.Solids / Lipids:
Original pH :
Batch ID:
Filename:
Retchlc: •
• Begin ConCal:
Initial Cal:
Tissue
10.00 Grams
100 96
NA
WG6309
a26nov01b_2-5
a26nov01b-1
a26nov01b-1
m1613-101201a
1/2
37

Paradigm Analytical Labs
Method 1613 - QC BLANK Results
LMB
Analytical Data Summary Sheet
Labeled
Standard
Expected
Amount
(rig)
Measured
Amount
(ug)
' Percent
"Recovery
_ (%)
RT
(tnia.)
Ratio
Qualifier
Extraction Standards
•
13Ck2-2,3,7,8-TCDD
2
1.55
77.7
'29:01
0.81
13C 12-1,2,3,7, 8-PeCDD
2
1.51
75.6
33:00
1.55
13C12-1,2,3,4,7,8-HxCDD
2
1.67
83.7
35:19
1.31
13C,2-I,2,3,6,7,8-HxCDD
2
1.73
86.7
35:24
1.29
13C12-1,2,3,4,6,7,8-HpCDD
2
1.61
80.3
38:16
1.07
13C12-0CDD
4
2.41
60.3
41:51
0.83
13C12-2,3,7,8-TCDF
2
1.62
81.2
28:05
0.8
13C12-1,2,3,7,8-PeCDF
2
1.46
72.8
32:15
1.56
13C12-2,3,4,7,8-PeCDF
2
1.56
78.0
32:49
1.54
13Cl2-1,2,3,4,7,8-HxCDF
2
1.67
83.7
34:4I
, 0.51
13C12-1,2,3,6,7,8-HxCDF
2
1.76
• 87.9
34:46
0.52
13C12-2,3,4,6,7,8-HxCDF
2
1.71 .
85.7
35:12
0.52
13C12- I,2,3,7,8,9-HxCDF
2
1.65
. 82.7
35:52
0.52
13C12-1,2,3,4,6,7,8-HpCDF
2
1.55
77.7
37:10
0.44
13C12-1,2,3,4,7,8,9-HpCDF
2
1.58
78.9
38:49
0.45
Cleanup Standards
37C14-2,3,7,8-TCDD
0.8
0.69
85.8
29:02
Iniection Standards
.
13C12-1,2,3,4-TCDD
2
28:18
0.83
13C 1-1,2,3,7,8,9-HxCDD
2
,
35:12
0.52
Laboratory Information
Sample ID: WG6309-1
Extraction Date:
Analysis Date: •
Analyzed by:
Date*
Sample Information
.Matrix: • Tissue
• Weight / Volume: 10.00. Grams
Solids / Lipids: 100 %
Original pH : NA
Batch ID: WG6309
Filename: a26nov01b_2-5
Retchk: a26nov01 b-1
Begin ConCal: a26nov01b-1
22-Nov-01
27-Nov-01 Initial Cal: m1613-101201a
Reviewed by: del
Date: / Z%%b 1
22
38

Analytical Results
for
Ongoing Precision Result (OPR)
Analyte
Spiked
pglul
AMT
pglul
' REC .
%
Range pg/ul
Flag
Lower _
Upper
2,3,7,8-TCDD
10.0
10.0
100
6.7
15.8
1,2,3,7,8-PeCDD
- 50.0
49.3
98.5
35.0
71.0
1,2,3,4,7,8-HxCDD
50.0
50.7
101
35.0
82.0
1,2,3,6,7,8-HxCDD
50.0
49.9
99.8
38.0
67.0
1,2,3,7,8,9-HxCDD
50.0-
52.0
. 104
32.0
81.0
1,2,3,4,6,7,8-HpCDD
50.0
47.4
' ' 94.9
35.0
70.0
OCDD
100
96.4
96.4
78.0
144.0
2,3,7,8-TCDF
10.0
9.43
94.3
7.5
15.8
1 2,3,7, 8-PeCDF
50.0
48.3
96.5
40.0
67.0
2,3,4,7,8-PeCDF
50.0
48.1
.. 96.3
.34.0
80.0
1,2,3,4,7,8-HxCDF
50.0
49.3
_ 98.7
36.0
67.0
1,2,3,6,7,8-HxCDF
50.0
49.7
99.5
42.0
65.0
2,3,4,6,7,8-HxCDF
50.0
50.6
101 •
.35.0
78.0
1,2,3,7,8,9-11xCDF
50.0
48.2
96.4
39.0
65.0
1,2,3,4,6,7,8-HpCDF
50.0
47.0
..94.1
41.0.
61.0
1,2,3,4,7,8,9-HpCDF
50.0
48.0
96.0
39.0
69.0
OCDF .
100
105
105
63.0
170.0
# = Outside range Iimits
* = Ion Ratio Out
OC Information
OPR Project No:
Extraction Date:
Analysis Date:
Method:
Sample information
WG6309
21-Nov-01
27-NOV-01
1613
Matrix: Tissue
File Information
OPR Filename :
Retchk:
Begin ConCal:
Initial Cal:
a26nov01b_2-4
a26nov01b-15
a26nov01b-15
m1613-101201a
39

Analyti'calsults
for
Ongoing Precision Result (OPR)
Labeled
Standard
Spiked
pglu1
AMT
pg/ul
REC
%
Ranje pg/u1
Flag
+ Lower
,
Upper
_•
Extraction Standards
.
13C12-2,3,7,8-TCDD
100
76.2
...76.2
.
20
175
13C12-1,2,3,7,8-PeCDD
100
78.9
78.9
21
227
13C12-1,2,3,4,7,8-HxCDD
100
86.4
• 86.4
21
193
13Ct2-1,2,3,6,7,8-HxCDD
100
88.0
88.0
25
163
13C12-1,2,3,4,6,7,8-HpCDD
100
83.6
83.6
26
166
13C12-0CDD
200
137
. 68.6
26
397
'3C12-2,3,7,8-TCDF
100
825
82.5
22
152
13C12-1,2,3,7,8-PeCDF
100
76.3
76.3
21
192
13C12-2,3,4,7,8-PeCDF
100
80.9
80.9
13
328
13C12-1,2,3,4,7,8-HxCDF
100
86.6
86.6.
19
202
13C12-1,2,3,6,7,8-HxCDF
100
88.9
88.9
21
- 159
13C12-2,3,4,6,7,8-HxCDF
100
85.4
85.4
22
176
13C12-1,2,3,7,8,9-HxCDF
100
86.5
86.5
17
205
13C12-I,2,3,4,6,7,8-HxCDF
100
80.0
80.0
21
158
13C12-1,2,3,4,7,8,9-HpCDF
100
81.4
81.4
20
186
Cleanup Standards
37C14-2,3,7,8-TCDD
40.0
32.6
81.5
12.4
76.4
J
1
-
OC Information
OPR Project No:
Extraction Date:
Analysis Date:
Method:
Sample Information
Matrix:
WG6309
21-Nov-01
27-NOV-01
1613
Tissue
. File Information
OPR Filename : a26nov01 b_2-4
.Retchk: • a26nov01b-15
Begin ConCal: a26nov01b-15
:initial Cal: m1613-101201a
Reviewed by: tfik Date Reviewed: /2144/
40

CHAIN -OF -CUSTODY / Analytical Request
Client Name:
Address:
Report to:
Phone:
ECifela
Fax:
Environmental Testing Solutions, LLC
PO Box 790
Pisgah Forest, NC 28768
Phone: [phone]
Fax: [phone]
Project Name:
Project Number:
—D(, r r)s. 50 `9
Requested Analyses
PO Number: • pli Checked Upon Receipt
CI= < 0.2 mg/I Upon Receipt
item Number
Sample Number
L(Date Collected
MM/DD/YY)
Containers
Preservatives
Sample Identification
x
T
z
1 —
U
H x
Unpreserved
.,
O
='
M
O
z
x
NaOH + Ascorbic
O
v��
z
Field
Temp. CC)
Comments
4r, r7411/h AO
GoMr. #/
//%SAt
/0:36
,. ee
•
49 (o
2
AlegAwad 9.41AX a, //1;4)
4,4,9.14.1
_BMA/
Ale>
/1.141.4� � 4)
44743
11/$l /
m:
6
.
,
Liq./-0 ,
•
• Len n
7041_
/a3
; :
i��:1.
_�
,aMi
Lig 4 k
...... /1/1/111 Aid 6 .4.4.
e.r. A"
.ilosioi
/0:3e
f.*
a'
,.
6...es
Sample Condition
Upon Receipt (RelitiquisIt'ed
By
(Company
-
•Date
.
,
Time
(Accepted
By ; ...
« ,,..;
ti
, ice'
(Company
Daotc
.. ( Time ...'
Temperature (dC)
_.
- - . 4fri_
1W14 S.1/�
/D/
41:0 .....
I �111JQ/1��n..
1✓�S
1 1- -D%
1 b3
Received on Ice:
Y / N
Sealed Cooler:
Y / C)
1
Samples Intact:
Y / N
Additional Comments:
Sampler Name and Signature
(
Date
Printed Name of Sampler:
-� 0; iOh /
/t/s/d/
Signature of Sampler: �G����

CHAIN -OF -CUSTODY / Analytical Request
Client Name:
Address:
Report to:
Phone:
Fax:
Environmental Testing Solutions, LLC
PO Box 790
Pisgah Forest, NC 28768
Phone: [phone]
Fax: [phone]
Project Name:
Project Number:
rt's h 11)'t,vi, Tre A9
01 1100. 5t .
Reouested Analyses
PO Number: pH Checked Upon Receipt
CI, < 0.2 mg/I Upon Receipt
Sample Number
Date Collected
(MM/DD/YY)
# Containers
Preservatives
ei
Z
E
Sample Identification
:4
•�
"As
a x
H x
Unpreserved
r
O
X
6
1
HC1
NaOH + Ascorbic
o
v,�
Z
41
Field
Temp. (°C)
Comments
J6rse, 6
t'�AC�xiir
/
14/ /
:Jo
)(:-...•kk
',eV;
yly�y�}l,9jg�•{
x$4.
fh
•
1f, /PIO
4�a1
ea,
;WY 44/4 66 )41.1<t)
6107g ;g3
//AA/
JCL
yi
gl...tt
{fir:
� / S/, lsl.)
i ✓ a '
Cam. #
///G/a1
/r: 46
W. ..
. 4LL i . , of. Cit' 4 4,114)
61,A$
f% iv/O1
/'06
J
r .
ti r_
r•
1)'
Sample Condition
Temperature Cr)10t6filetie.1
Upan Receipt jRdlinyttislied
By
Company
lif f c.
:1 Date
fi%t
:
ol
3:5-5jn
Time
• [Accepted
. w.' L,41,:::1
By
w
• lCompany
t 7
' ::1.
Date
//-
.:
,-6%
J =' :Time
J5 66O
Received on ice:
/ N
Settled Cooler:
Y / el
-
Samples Intact:
Y / N
Additional Com,nents:
'
Sampler Name and Signature
Printed Name o1' Sampler:
le". ,,,Y�dAir%
) • .:Date . .
//�%l
Signature of Sampler: . %h--/

CHAIN -OF -CUSTODY / Analytical Request
Client Name:
Address:
Report to:
Phone:
Fax:
Environmental Testing Solutions, LLC
PO Box 790
Pisgah Forest, NC 28768
Phone: [phone]
Fax: [phone]
Project Name:
Project Number:
Fish D.' o)i,J—re•
Ol l tD� �3
Requested Analyses
PO Number: • pH Checked Upon Rcccipt
C li < 0.2 ms/t Upon Receipt
Sample Number
Date Collected
(MM/DD/Y Y)
Time Collected
(HH:MM)
# Containers
I'resci!•vativcs
,..
.I:
z
Sample Identification
e.
llnpreserved
'OSEH
o
i
!OH
NaOH + Ascorbic
6
ri
N
z
Field
Temp. CC)
Comments
14LL-
& ii,
l /
/i/d i
A5: d t,
r ,
"
% ivitLcof 6)
Cur 41
41/
00
M�'
5029
ge.4641. (i4')
///614
Aas
�"
:;-
30
II
g € ill r e a a ..(14 p s ' 6t�.114.70al
d'''
_
...
KS!A
6b31
5
J474 (')
415
/0 'i�`� )
lie:t
-
- ,
'
: .:
.
:,ter
+ v
.-/W [/
g
ti�,�,
a4fx
fit Y�.•.
tr,,:f.
Sammie
Condition
Upon Receipt IRetinquiglied
By
.`'Company
...
Date
.
Time
.
Accepted 13y. " •
Won -litany Mite ' ::: . Time '.
Temperature (" -')
f----•
/, .. pour /�./
44 frvt.
/, !/
f1 ai
! 1-01-OJ
1 5
Received on Ice:
(D/ N
Sealed Cooler:
Y / 0
-
Samples Intact:
.Y / N
Additional Comments:
Simpler Name and Signature •
. •
pate
Printer! Name of Sampler. 244....... .A.,
,h,d),,.
/If Wfiq
Signature of Sampler: