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HomeMy WebLinkAboutI-3_Ambient Monitoring Plans 2018-20222022 Ambient Monitoring Plan Introduction The Ambient Monitoring Program was created to fulfill requirements of the City of Durham's National Pollution Discharge Elimination System permit (NCS000249). This Program characterizes watersheds located in the City of Durham (COD) and tracks changes or trends in water quality by monitoring the water chemistry, stream biology, and stream hydrology of selected streams. Streams selected for monitoring are fixed locations strategically located inside orjust outside the City limits. Sites are monitored by COD Water Quality Unit (WQU) staff once per month and are on an even and odd year sampling rotation for particular watersheds. Therefore, the majority of sites are sampled every other year. Targeted watersheds for 2022 are Northeast Creek and Third Fork Creek in the Cape Fear River Basin and Little River, Eno River, Lick Creek, and Little Lick Creek in the Neuse River Basin. In addition to the alternating yearly sites, select sites are chosen for consistent monthly monitoring based on their potential to contribute nutrients downstream and their proximity to USGS stream gages. These "nutrient loading sites" are sampled every year and include sites located on Ellerbe Creek (EL7.1EC at Club Blvd and EL1.9EC at Glenn Rd), New Hope Creek (NH3.3SC at Cornwallis Rd), Eno River (EN8.9ER at West Point on the Eno), Little Lick Creek (LL3.4LLC at Mineral Springs Rd), and Third Fork Creek (TF3.4TC at MLK and TFI.OTC at Woodcroft Pkwy). For the 2022 sampling year, there were no updates to key project staff or staff titles for the City of Durham from the previous year. Environmental Conservation Laboratories (ENCO), will continue to be the contracted lab for the 2022 ambient sampling season. Summary of the 2022 Planning Meeting Below is a summary of the notable changes that resulted from discussions at the 2022 Ambient Planning Meeting held on November 9, 2021. For more details and a complete list of topics discussed in this meeting, please see Appendix A. 2022 Ambient Planning Meeting Document with Notes. Sampling Parameters The core parameters collected at every sampling site will remain the same as they were in 2021. These core parameters include: 5-day biological oxygen demand (5-day BOD), total suspended solids (TSS), ammonia (NH3 as N), nitrate -nitrite (NO,,as N), total Kjeldahl nitrogen (TKN), total phosphorus (TP), hardness, total calcium (Ca), total magnesium (Mg), total and dissolved copper (Cu), total and dissolved zinc (Zn), and fecal coliform. The core parameters will continue to be analyzed by the South Durham Water Reclamation Facility (SDWRF) laboratory per the Ambient Monitoring Program QAPP. Total antimony (Sb), will also be collected at sites in the Northeast Creek watershed (NE2.2NP, NEO.ONE, and NE1.2NE). Total Sb will also be analyzed by the SDWRF lab. Total Organic Carbon (TOC) samples will be collected at the following nutrient loading sites: EL1.9EC (Ellerbe Creek at Glenn Rd), EL7.1EC (Ellerbe Creek at Club Blvd and Acadia St), EN8.9ER (Eno River at West Point on the Eno), TFI.OTC (Third Fork Creek at Woodcroft Pkwy), and NH3.3SC (Sandy Creek at Cornwallis Rd). TOC samples will be analyzed by ENCO. Physical parameters will also be collected at all ambient sites and will include: water temperature, dissolved oxygen saturation and concentration, pH, specific conductivity, and turbidity. For a detailed list Page 1 of 8 Document prepared 11/30/2021, CC of parameters collected at each site please see Appendix B. Ambient Water Quality Monitoring Sampling Tables. Sampling Sites All sites will remain the same from sampling in 2020. For the complete list of sites, their locations, and associated lab numbers along with the duplicate and field blank schedule please see Appendix C. 2022 Ambient Site List. Benthic Monitoring The benthic monitoring sites will remain the same as in 2020. A separate 2022 Benthic Monitoring Plan will be prepared prior to benthic sampling in the spring of 2022. Page 2 of 8 Document prepared 11/30/2021, CC Appendix A. 2022 Ambient Planning Meeting Document with Notes 2022 Ambient Planning Meeting November 9, 2021 Attendees: Michelle Woolfolk, JV Loperfido, Jon Baker, Jim Azarelo, Joey Smith, Anna Smith, Dave Milkereit, and Blaine Lary. 2020 Monitoring Information • Focus watersheds for even years: Eno, Little River, Little Lick, Lick, Northeast, and Third Fork • Total sites sampled in 2020: 23 (12 Neuse, 11 Cape Fear) - No change for 2022 o 12 in the Neuse Basin ■ 4 in Eno (1 nutrient loading site) ■ 1 in Little River ■ 2 in Little Lick (1 nutrient loading site) ■ 2 in Lick ■ 3 in Ellerbe (2 nutrient loading sites & central park site) 0 11 in the Cape Fear Basin ■ 7 in Third Fork (2 nutrient loading sites) ■ 3 in Northeast ■ 1 in New Hope (nutrient loading site) o NOTE: No samples were collected in April and only nutrient loading sites were sampled in May and June due to COVID safety concerns. The remaining months were sampled as normal. Questions/Discussion Topics Staff gages • First up for debate — is it spelled 'gage' or 'gauge'? ➢ For water quality purposes use 'gage'. • The majority of the "original" gages were deployed in 2012 and 2013. Most have been removed or are in need of maintenance. ➢ Keep the gage at NHI.OSC (Garett Rd) as is. ➢ Attempt some recon (removing debris) from the gage at NH2.3MC (Pickett Rd). ➢ Move the staff gage at EL8.5SEC to the downstream side of the culvert near where samples are collected. • What is this data used for? ➢ Part of the stormwater management plan is to measure stream flow, also used in loading calculations and models. • Is there a better way to organize and utilize these data? ➢ How we are using the data is sufficient, continue to enter staff gage measurements into the web portal. Page 3 of 8 Document prepared 11/30/2021, CC Parameters TOC • TOC was not sampled in 2020 due to COVID and contract lab issues. • This year TOC samples were collected at EL7.1EC, EL1.9EC, EN8.9ER, TFI.OTC, and NH3.3SC (TFI.OTC and NH3.3SC were just added in 2021). • Keep this the same? • Analyzed by ENCO. Any issues? ➢ Keep same TOC sites as in 2021. ENCO to analyze samples, no issues there. Total Antimony • All results have been J qualified since we started sampling in 2019. • Continue to sample for this? • Are these data being used for anything? ➢ It was requested for total Sb to be continued to be collected as there have been ongoing issues during inspections at SCM Metals. ➢ It was also noted that SCM metals plans to begin construction work which includes surfacing and grading in 2022. Trash • Do we want to implement any trash scores into our field sheets? ➢ No. Trash surveying will be part of a separate study plan. The separate study should be completed first before we begin to think about the possibility of adding it to ambient sampling. Ambient Investigation Triggers • Trigger levels were last updated in 2017 do we want to revisit them? INVESTIGATION TRIGGER LEVELS AMBIENT MONITORING Temperature Investigation• Precipitation within 24 hours) }32° C Field pH r5 or >9 Parameters Specific Conductivity '730 µS Turbidity >_163 NTU Fecal Coliform �!60,000 cfu/1D0mL Laboratory 5-Day Biochemical Oxygen Demand 8 mg/L or Overdepletion Parameters Copper (Total or Dissolved) >-18 µg/L Zinc (Total or Dissolved) � 5 5 µg/L ➢ Leave investigation triggers as is for now. Use these numbers as a guide along with your best professional judgement and knowledge of specific sampling locations. ➢ During the discussion it was determined that our group may want to look into changing some of the field parameters numbers namely, moving to season -specific conductivity numbers similar to outfall screening. It was also discussed if we want to recalculate the turbidity number or get rid of the turbidity value altogether and go with simply a best professional judgement since Page 4 of 8 Document prepared 11/30/2021, CC certain sampling locations are naturally more turbid than others. There was also some discussion of computing watershed specific trigger levels, but there was some concern that this could result in a long list of trigger values that would be cumbersome to apply. Updating the investigation triggers should be discussed further in the coming year. Master Site List • There is a master site list that is contained within the Water Quality Database. Where is this table located outside of the database? • There is also a site list on the server. Do we need both? • What is the best place to keep this master list? ➢ Dave Milkereit (DM) and Joey Smith (JS) will work together on making a single master list that contains site ID, lab numbers, coordinates, and a brief location description for all sites. All other lists will be archived or removed. Once a master list is created a storage location will be finalized. DM and JS will speak with GIs to see if they can offer some assistance for storage location, but being able to easily update the list is a top requirement for storage location. Sampling Sites add/drop • From 2020 meeting notes: o TF2.5TCTC (Dover/Golf Course) is this site giving us useful data? We normally observe poor water quality indicators due to the buffer issues/no canopy cover on the golf course. o Sample for herbicides/pesticides? ➢ Keep this site. It is reflective of the watershed land use. This location covers a large drainage area and fecal numbers have been high. Third Fork Creek is a TMDL watershed so continuing to sample here is important, but the group will revisit sampling here in 2022. ➢ The Warren Creek site EN10.3WC is part of the pollution source tracking project. Do we need to add any extra parameters or take additional photos? ➢ Contractors already completed initial sampling at this location and found no issues. No extra parameters or photos are needed. ➢ Any requests from other groups or municipalities? ➢ None. Additional Topics Discussed at the 2022 Planning Meeting ➢ There was a discussion on TF6.5RCUT (Sima Ave at Burton Park) and if continuing ambient sampling at this site was the best approach to resolve ongoing water quality issues that have been observed there. It was decided to continue to sample at this location. It was also stated that additional sampling and inspections would be taking place at industrial sites and other locations upstream of the ambient monitoring site in the upcoming year. Continued sampling of TF6.5RCUT provides baseline data for this subwatershed. ➢ Michelle Woolfolk also brought up the discussion topic of getting rid of the even/odd year site rotation and retuning to sampling all sites every year. This would be a big change to the Page 5 of 8 Document prepared 11/30/2021, CC sampling program and will take thought and preparation to complete. The Monitoring and Assessment group stated they supported making this change and would investigate feasibility and logistics to potentially begin sampling in this fashion starting in CY 2023. Benthic Sampling • Any changes to the benthic sampling sites? ➢ No changes • 2020 benthic sites: Lat/Long Drainage River Site Sampling Watershed Stream Location (dec. Ecoregion area basin code method deg.) (mi.Z) 35.91102 Triassic Third Fork TFO.OTC Third Fork Cr. NC 751 16.1 Qual4 a M -78.96051 Basins u LL 355 .886 8 Triassic Northeast NEO.ONE Northeast Cr. Sedwick Rd. 12.9 Qual4 _ 8 8 Basins Johnson Mill 36.1416 Little LR9.6LR Little R. Slate Belt 78.2 Full Scale Rd. -78.9208 West Point on 36.0716 EN8.9ER Eno R. Slate Belt 141.1 Full Scale the Eno park -78.9100 a, 3 Eno Penny's Bend 36.0731 EN4.9ER Eno R. Slate Belt 149.3 Full Scale Z access -78.8635 Mineral 35.9850 Triassic L. Lick LL3.4LLC Little Lick Cr. 6.0 Qual4 Springs Rd. -78.8198 Basins 35.9777 Triassic Lick LC1.11-C Lick Cr. Southview Rd. 10.8 Qual4 -78.7496 Basins Page 6 of 8 Document prepared 11/30/2021, CC Appendix B. Ambient Water Quality Monitoring Sampling Tables Samples/Day 2022 Ambient Water Quality Monitoring Day 1 Day 2 Day 3 EL8.6SECUT LL4.6LLT2 TF6.5RCUT 1 EL7.1EC LL3.4LLC TFSARC 1 EL1.9EC LCIALC TF4.4TC EN4.9ER LC2.ORBC TFSATC LR9.6LR 2NE2.2NP 1 NH3.3SC 1 EN8.9ER 2NEO.ONE TF3.4TC EN10.3WC 2NE1.2NE TF2.5TCTC EN13.3ER Field Blank 1TFI.OTC Field Blank Duplicate Field Blank Duplicate Duplicate 10 9 10 1TOC analyzed by ENCO 2 Total Antimony Tentative Sampling Dates Day 1 Day 2 Day 3 January 4 11 18 February 1 8 15 March 1 8 15 April 5 12 19 May 3 10 17 June 7 14 21 July 5 12 19 August 2 9 16 September 6 13 20 October 4 11 18 *November 1 2 15 *December 6 7 13 *Sampling days for November and December were adjusted to accommodate the holidays. Ambient Parameters Fecal Coliform Nutrients: Nitrate + Nitrite N Total Kjeldahl N Total Ammonia N Total Phosphorus Total Suspended Solids 5-day BOD Total Metals: Calcium Magnesium Zinc Copper 2 Total Antimony (at all NE sites) Dissolved Metals (Field - Filtered): Copper Zinc Ha rdness (ca Icu Iated) Document prepared 11/30/2021, CC Page 7 of 8 Appendix C. 2022 Ambient Site List LAB# SITENAME SAMPLING .. WATERSHED ORDERDAY BOD, Fecal, MTe.55Is, Nutrients, 193 EL8.6SECUT 1 Jan, Sep Jan, Sep Foster St & Hunt St Ellerbe Neuse BOD, Fecal, Metals, Nutrients, 230 *EL7.1EC 2 Feb, Oct Feb, Oct Club Blvd & Acadia St Ellerbe Neuse TSS, TOC BOD, Fecal, Metals, Nutrients, 41 *EL1.9EC 3 Mar, Nov Mar, Nov Glenn Rd Ellerbe Neuse TSS, TOC BOD, Fecal, MetSals, Nutrients, 78 EN4.9ER 4 Apr, Dec Apr, Dec Penny's Bend (Snow Hill Rd) Eno Neuse 180 LR9.6LR 5 May May Patrick Rd &Johnson Mill Rd BOD, Fecal, Metals, Nutrients, Little River Neuse TSS 79 *EN8.9ER 6 Jun Jun West Point on the Eno BOD, Fecal, Metals, Nutrients, Eno Neuse TSS, TOC BOD, Fecal, Metals, Nutrients, 196 FN10.3WC 7 Jul Jul Horton Rd, East of Guess Rd Eno Neuse BOD, Metals, Nutrients, Fecal, 77 EN13.3ER 8 Aug Aug Cole Mill Rd Eno Neuse TSS 30 Duplicate - - - - - - - 223 Field Blank - - - - - - - BOD, Fecal, M etsals, Nutrients, 82 LL4.6LLT2 1 Jan, Aug Jan, Aug Lynn Rd, South of Hwy 98 Little Lick Neuse TS BOD, Metals, Nutrients, Fecal, 81 *LL3.4LLC 2 Feb, Sep Feb, Sep Mineral Springs Rd, North of 98 Little Lick Neuse TSS BOD, Fecal, Mesta Is, Nutrients, 169 LC1.1LC 3 Mar, Oct Mar, Oct Southview Rd, South of 98 Lick Creek Neuse BOD, Fecal, Metals, Nutrients, 169 LC2.ORBC 4 Apr, Nov Apr, Nov Kemp Rd & Southview Rd Lick Creek Neuse BOD, Fecal, Metals, Nutrients, 2 17 NE2.2NP 5 May, Dec May, Dec Meridian Pkwy TSS, Total Sib Northeast Cape Fear BOD, Fecal, Metals, Nutrients, 19 NEO.ONE 6 Jun Jun Sedwick Rd TSS, Total Sb Northeast Cape Fear BOD, Fecal, Metals, Nutrients, 11 NE1.2NE 7 Jul Jul Hwy54, West of Hwy 55 TSS, Total Sb Northeast Cape Fear 31 Duplicate - 224 Field Blank - BOD, Fecal, MetSals, Nutrients, 142 TF6.5RCUT 1 Jan, Sep Jan, Sep Sima Ave, at Burton Park Third Fork Cape Fear 130 TF5.1RC 2 Feb, Oct Feb, Oct Elmira Ave BOD, Fecal, Metals, Nutrients, Third Fork Cape Fear 127 TF4.4TC 3 Mar, Nov Mar, Nov Weaver St BOD, Fecal, MISS Is, Nutrients, Third Fork Cape Fear BOD, Fecal, Metals, Nutrients, 232 TF5.4TC 4 Apr, Dec Apr, Dec Forestwood Dr (Forest Hills Park) Third Fork Cape Fear BOD, Fecal, Metals, Nutrients, 100 *NH3.35C 5 May May Cornwallis Rd New Hope Cape Fear TSS, TOC 3 BOD, Fecal, M etSals, Nutrients, 198 *TF3.4TC 6 Jun Jun MLK near PWOC Third Fork Cape Fear 120 TF2.5TCTC 7 Jul Jul Dover Rd BOD, Fecal, MetSals, Nutrients, Third Fork Cape Fear 231 *TFI.OTC 8 Aug Aug Woodcroft Pkwy BOD, Fecal, Metals, Nutrients, Third Fork Cape Fear TSS, TOC 32 Duplicate - 225 Field Blank - - - - - - - * Nutrient Loading Site TOC Field Blank and Duplicate Schedule DAY LAB# SITE NAIVIE Dupficate Collected Field Blank Collected 230 EL7.1EC Jan, Jun, Nov Jan, Jun, Nov 1 41 EL1.9EC Feb, Jul, Dec Feb, Jul, Dec 79 FN8.9FR Mar, Aug, Mar, Aug, 100 NH3.3SC Apr, Sep Apr, Sep 3 231 TFI.OTC May, Oct May, Oct Page 8 of 8 Document prepared 11/30/2021, CC 2021 Ambient Monitoring Plan Introduction The Ambient Monitoring Program was created to fulfill the requirements of the City of Durham's National Pollution Discharge Elimination System (NPDES) permit (NCS000249). This Program characterizes watersheds located in the City of Durham (COD) and tracks changes or trends in water quality by monitoring the water chemistry, stream biology, and stream hydrology of selected streams. Streams selected for monitoring are fixed locations strategically located inside or just outside the City limits. Sites are monitored by COD Water Quality Unit (WQU) staff once per month and are on an even and odd year sampling rotation for particular watersheds. Therefore, the majority of sites are sampled every other year. Targeted watersheds for 2021 are New Hope Creek, Panther Creek, and Crooked Creek in the Cape Fear River Basin and Ellerbe Creek and Stirrup Iron Creek in the Neuse River Basin. In addition to the alternating yearly sites, select sites are chosen for consistent monthly monitoring based on their potential to contribute nutrients downstream and their proximity to USGS stream gages. These "nutrient loading sites" are sampled every year and include sites located on Ellerbe Creek (EL7.1EC at Club Blvd and EL1.9EC at Glenn Rd), New Hope Creek (NH3.3SC at Cornwallis Rd), Eno River (EN8.9ER at West Point on the Eno), Little Lick Creek (LL3.4LLC at Mineral Springs Rd), and Third Fork Creek (TF3.4TC at MLK and TFI.OTC at Woodcroft Pkwy). For the 2021 sampling year, there were no updates to key project staff or staff titles for the City of Durham from the previous year. Environmental Conservation Laboratories (ENCO), will be the contracted lab for the 2021 ambient sampling season. Summary of the 2021 Planning Meeting Below is a summary of the notable changes that resulted from discussions at the 2021 Ambient Planning Meeting held on November 2, 2020. For more details and a complete list of topics discussed in this meeting, please see Appendix A. 2021 Ambient Planning Meeting — with Notes. Sampling Parameters The core parameters collected at every sampling site will remain the same as they were in 2020. These core parameters include: BOD-5 Day, total suspended solids (TSS), ammonia (NH3), nitrate -nitrite (NOx), total kjeldahl nitrogen (TKN), total phosphorus (TP), hardness, total Calcium (Ca), total Magnesium (Mg), total and dissolved Copper (Cu), total and dissolved Zinc (Zn), and Fecal Coliform. The core parameters will continue to be analyzed by the South Durham Water Reclamation Facility (SDWRF) laboratory per the Ambient Monitoring Program QAPP. Total antimony (Sb), will also be collected only at S11.6SIC (Stirrup Iron Creek at Chin Page Rd) and be analyzed by the SDWRF lab. Collection of Total Organic Carbon (TOC) samples at selected sites will be resumed in 2021 and will be analyzed by ENCO. TOC samples will be collected at the following nutrient loading sites: E11.9EC (Ellerbe Creek at Glenn Rd), EL7.1EC (Ellerbe Creek at Club Blvd and Acadia St), EN8.9ER (Eno River at West Point on the Eno), TFI.OTC (Third Fork Creek at Woodcroft Pkwy), and NH3.3SC (Sandy Creek at Cornwallis Rd). Page 1 of 8 Document prepared 12/9/2020, CC Physical parameters will also be collected at all ambient sites and include: water temperature, dissolved oxygen saturation and concentration, pH, specific conductivity, and turbidity. For a detailed list of parameters collected at each site please see Appendix B. 2021 Ambient Water Quality Monitoring Sampling Tables. Sampling Sites Site TF3.4TC (Third Fork Creek at MLK) was designated as a nutrient loading site in 2018 due to the installation of a new USGS rain and stream gage that year. However, due to sampling conflicts, this site was not sampled in 2019. Starting in 2021, this site will be classified as a nutrient loading site and will be sampled yearly. PN2.4PN (Panther Creek at Burton Rd) is currently the only COD sampling site located in the Panther Creek watershed, however, localized sediment infill at this site has limited sample collection during periods of low stream flow. A new site located at the end of Cooksbury Rd was scouted and determined to be both accessible and an improvement to the previous location. Therefore, the old sampling site (PN2.4PN) will be dropped in 2021 and the new site (PN1.9PN) will be added. For the 2021 sampling season, an additional site in the Ellerbe Creek watershed was requested to provide supporting data for a future Watershed Improvement Plan. Previously, EL10.7EC (Ellerbe Creek at Bellevue Ave) was sampled as a routine odd -year site. However, due to accessibility issues it was decided that a new location should be scouted. After ambient site recon on 11/23/2020, it was determined that a new site located where Albany Street crosses Ellerbe Creek was a better candidate. Therefore, EL10.7EC will not be sampled in 2021 and will be replaced by the new site at Albany Street (EL9.9EC). The sample site located at Midland Terrace (EL5.6SC) was deemed unsafe to sample due to an eroding bank with steep, slick slopes. This site was scouted in 2019 to identify a safer way to access the sample site however, none was found. It was decided to drop EL5.6EC in 2021 due to the increasing safety issues. In 2019 NE1.2NE (New Hope Creek at Hwy 54/Hwy55) was sampled only for total Antimony. It was decided that this site will not be sampled in 2021 as NE1.2NE is not a routinely -scheduled odd -year site. All other sites will remain the same from 2019. For the complete 2021 list of sites, their locations, and associated lab numbers along with the duplicate and field blank schedule please see Appendix C. 2021 Ambient Site List. Benthic Monitoring The benthic monitoring sites will primarily remain the same as in 2019 with consideration into possibly changing the site located in the Panther Creek watershed from PN2.4PN (Panther Creek at Burton Rd) to the new site PN1.9PN (Panther Creek at Cooksbury Rd). Additional discussions on changes to the 2021 benthic sampling plan will be held in the future and all possible changes will be summarized in a separate benthic monitoring plan. Page 2 of 8 Document prepared 12/9/2020, CC Appendix A. 2021 Ambient Planning Meeting — with Notes Ambient 2021 Planning Meeting Monday November 2, 2020 Virtual Attendees: Michelle Woolfolk, JV Loperfido, Jon Baker, Jim Azarelo, Joey Smith, Dave Milkereit, Blaine Lary, and Christine Cailleret 2019 Monitoring Information • Focus watersheds for odd years: Ellerbe, New Hope, Panther, Stirrup Iron, Crooked Creek • Total Sites sampled in 2019: 22 Total sites for 2021: 22 0 11 in the Neuse watershed ■ 8 in Ellerbe Creek — same (1 site dropped and 1 added) ■ 1 in Eno River (Nutrient Loading Site) - some ■ 1 in Little Lick Creek (Nutrient Loading Site) - same ■ 1 in Stirrup Iron Creek - same 0 11 in the Cape Fear watershed ■ 7 in New Hope Creek - same ■ 1 in Panther Creek - same ■ 1 in Crooked Creek - same ■ -12 in Third Fork (Nutrient Loading Sites) ;n NeFtheast Free. (T6A4.1 Q S;+ en,) ' - site dropped Questions/Discussion Topics Parameters • Sampling for TOO o This year (2020) we did not sample for TOC, but in previous years TOC samples were collected at Nutrient Loading sites in the Neuse watershed. TOC was collected at EL1.9EC, EL7.1EC, and EN8.9ER in 2019 (TOC was not collected at LL3.4LLC due to continuous poor data and to save some money). o TOC would have to be analyzed by ENCO. ➢ Sample for TOC this year, keep LL3.4LLC dropped, but add TOC at TFI.OTC and NH3.3SC. ENCO should be contacted to set up a work order. Also there will be 1 Field Blank and 1 Duplicate TOC sample per sampling month. • Continue to sample only Total Sb at S11.6SIC and NE1.2NE? o In 2019 Total Sb was collected at S11.6SIC (Stirrup Iron at Chin Page Rd) and at NE1.2NE (Northeast Creek at Hwy 54/55) due to the fact that SCM metals began processing Sb on their property which drain to both Northeast Creek and Stirrup Iron Creek. o S11.6SIC is normally sampled in the odd years, and Sb was simply added on to the requested analyses. NE1.2NE is normally an even year site, therefore the only parameter collected here in 2019 was Total Sb. Page 3 of 8 Document prepared 12/9/2020, CC ➢ Drop NE1.2NE for 2021, but continue to collect Total Sb (in addition to all other standard parameters) at S11.6SIC. • Anions bottles — only taking NOx from this bottle. What method are the using? Can we change the label? o Currently NOx is the only anion being taken as part of the standard ambient parameters. This is taken out of a separate bottle (50 mL non -preserved plastic bottle). ➢ Check with SDWRF to confirm which method is being used. Also check with SDWRF if it is ok to stop using the current anions bottle and instead take what is needed for NOx from the current Nutrients bottle. • Do we want to consider collecting orthophosphate? o Would have to check with SDWRF first. ➢ Orthophosphate was previously collected, however, there were issues with QA/QC of the data therefore the parameter was dropped. It was also mentioned that orthophosphate is normally only present in surface water in very low levels and the samples would be processed by SDWRF which also processes waste water samples where orthophosphate levels are usually higher. Therefore, it was decided that the concern for possible machine contamination in the lab would result in unusable data and that collecting orthophosphate may be more work that would yield data that was not useful. ➢ There was also a discussion for our reasoning for collecting Hardness as well as Mg & Ca and whether or not the hardness results we received from SDWRF were calculated or lab analyzed. MW and JB remember this conservation occurring in the past, but could not recall the specifics. There was some discussion on if collecting these parameters were in relation to the Biotic Ligand Model. ➢ JB offered to look further into old notes to determine the reasoning for collecting both hardness and Mg/Cu. A possibility could be for us to only collect Mg & Cu and we calculate hardness ourselves, but we will wait to see what JB finds before we drop the hardness analysis. Proposed Add/Drop Sites Questions • TF3.4TC (MILK at PWOQ — Currently a nutrient loading site, and supposed to be sampled every year. It was not sampled in 2019 due to the high number of sites on day 2. Do we sample this site this year? o If added, it would have to be sampled on Day 2 with the other TF Loading site. ➢ Add back to Day 2. ➢ It was noted that loading calculations cannot be made for a site until there are 5 years of continuous data and trend analysis cannot be made until there has been a complete El Nino La Nina cycle (about 7 —10 Years). • EL7.6SECT (Knox St) — It was discussed in the Ambient Meeting 2019 to consider monitoring the old Knox location (EL7.6SECT) in 2020 to catch any changes due to the South Ellerbe Creek Wetland Project (Located on Trinity St). There was some discussion about adding Knox in 2019 as a baseline or pre data for the South Ellerbe Creek Wetland Project, but since construction of the wetland has already begun and limited historical data from this site exists, it was decided that it would not be the best use of resources to sample this site at this time. Notes from the 2019 meeting asked for this to be revisited in 2020. What is the status of the project? Page 4 of 8 Document prepared 12/9/2020, CC o If added, it would have to be sampled on Day 1 with the other Ellerbe sites. ➢ The construction is currently on pause until more input from surrounding communities is gathered. For now, the old building is gone and underground storage tanks have been removed. The impervious surface from the old structure is still in place and no new construction has been built. ➢ Do not add this year. There will likely be a study done of the effectiveness of the BMP once it is built rather than looking and pre and post ambient data at one location. ❖ NH1.7SCTA (Ivy Creek Blvd) —Keep sampling now that it is part of JV's contract? ➢ Continue to sample as normal. The contractor for JV's contract has collected one-time sampling data for this site which included physical and sediment parameters with a focus on DO. A second round of sampling is possible later on. Since this only a small amount of sampling, this site should continue to be treated as a normal ambient site. ➢ Continue to take photos of the site every sampling day. Take both upstream and downstream photos and save in the ambient folder. Revisit in 2023 if pictures need to continue to be taken every time. • PN2.4PN (Burton Rd) —This site was dry for 5 months (July -November) in 2019 and for 4 months (June — October) in 2015. This is the only site in PC (also a benthic site). Can we move it to a better location? o This is also a Benthic site, so would possibly have to move benthic location as well. o Next possible upstream access is at the end of Cooksbury Rd (2504 Cooksbury Rd). ➢ Recon the Cooksbury Rd location to determine if this would be a better location that would dry out less. If moved this location would need a new Site ID and lab #. ➢ UNRBA is using our data for this site, but moving the location should not affect their use of the data. • EL10.7EC (Bellevue — Golf Course) — This site was sampled for 3 months in 2017 as request from ECWA. It was not sampled in 2019, but notes from the 2019 meeting asked to revisit adding this site for 2021. o If added, it would have to be sampled on Day 1 with the other Ellerbe sites. ➢ There was a concern that if EL10.7EC was not added back, it could affect decisions made for the upcoming watershed modeling project for Ellerbe Creek as this location in the furthest upstream. If this site was not sampled, then water quality data collected at EL7.1EC (Northgate Park) would represent a lot of subwatersheads that are not nearby that sampling location. ➢ It was requested that either E110.7EC or a new site at a nearby location be added to the sampling rotation this year. ➢ As there are some access issues with EL10.7EC involving the golf course it is located on, it was suggested to recon the area where Ellerbe Creek Crosses Albany St. on the Ellerbe Creek walking trail. ■ If this new location is added, it would need a new site ID and Lab #. • EL5.6EC (Midland Terrace) —There is an ongoing safety/accessibility issue at this site. We reconned this site in 2019 and found no better access or sampling location. Do we need to keep sampling here? Page 5 of 8 Document prepared 12/9/2020, CC o Closest accessible downstream location is at Club Blvd near NDWRF. ➢ Drop this site. ➢ There were no issues with dropping this location as Ellerbe Creek is already well represented. MW remembers this location originally being added as it was the first accessible location downstream of the convergence of Ellerbe Creek and South Ellerbe Creek. • UNRBA or other association requests? ➢ None at the time of this meeting. Benthic Sampling Any changes to benthic sampling locations or procedures? ➢ No expected changes to the benthic sampling locations or procedures. There is a possibility, depending on the recon of the Panther Creek location, the Panther Creek site may move, but that will be determined at a later time. Odd year sites: River Site code Location Lat/Long (dd.ddd) Drainage area (mi.') Sampling method basin 35.9753 NH2.3MC Pickett Rd 5.4 Qual4 Q fu -78.9844 u LL 35.9571 NHI.OSC Garrett Rd 6.9 Qual4 -78.9738 36.0596 EL1.9EC Glenn Rd 21.9 Full Scale -78.8327 366 .0248 a, EL5.5GC Camden Ave 6.4 Qual4 8609 z EL7.1EC Acadia St 36.0200 5.7 Qual4 -78.8952 36.0338 PN2.4PN Burton Rd 2.6 Qual4 -78.8124 Page 6 of 8 Document prepared 12/9/2020, CC Appendix B. 2021 Ambient Water Quality Monitoring Sampling Tables 001 Samples/Day 2021 Ambient Water Quality Monitoring Day I Day 2 Day EL8.6SECUT 1EN8.9ER NH4.4SCT❑ EL8.1GC PN1.9PN 1NH3.3SC EL5.5GC LL3.4LLC NH3.ONHC 1EL1.9EC 2S11.6SIC NH2.3MC 1EL7.1EC TF3.4TC NH1.OSC EL7.ISEC 1TFI.OTC NH1.7SCTA EL8.5SEC CC2.5CC NHO.ONHC EL9.9EC 224 225 223 31 32 30 10 9 9 1TOC analyzed by ENCO 2Total Antimony Tentative Sampling Dates Day 1 Day 2 Day 3 January 5 12 19 February 2 9 16 March 2 9 16 April 6 13 20 May 4 11 18 June 8 15 22 July 6 13 20 August 3 10 17 September 7 14 21 October 5 12 19 *November 2 3 16 *December 7 8 14 *Sampling days for November and December were adjusted to accommodate the holidays. Ambient Parameters Fecal Coliform Nutrients: Nitrate + Nitrite N Total Kjeldahl N Total Ammonia N Total Phosphorus Total Suspended Solids 5-day BO ❑ Tota I Metals: Calcium Magnesium Zinc Copper ZAntimony (at S11.6SIC only) Dissolved Metals (Field - Filtered): Copper Zinc Hardness {calculatedy Document prepared 12/9/2020, CC Page 7 of 8 Appendix C. 2021 Ambient Site List SAMPLING Duplicate Field Blank .D LAB# SITE NAME LOCATION PARAMETERS WATERSHED ORDERDAY Fecal, Nutrients, BOD, TSS, 193 EL8.65ECLJT 1 Jan, Sep Jan, Sep Foster St and Hunt St Ellerbe Neuse Metals Fecal, Nutrients, SOD, TSS, 68 EL8.1GC 2 Feb, Oct Feb, Oct Holloway St Ellerbe Neuse Metals Fecal, Nutrients, BOD, TSS, 47 EL5.5GC 3 Mar, Nov Mar, Nov Camden Ave Ellerbe Neuse Metals 41 EL1.9EC* 4 Apr, Dec Apr, Dec Glenn Rd Fecal, Nutrients, BOD, T55, Ellerbe Neuse Metals TOC Fecal, Nutrients, BOD, TSS, 230 EL7.1EC* 5 May May Club Blvd and Acadia St Ellerbe Neuse Metals TOC 1 Fecal, Nutrients, BOD, TSS, 57 EL7.ISEC 6 Jun Jun Glendale Ave Ellerbe Neuse Metals Fecal, Nutrients, SOD, TSS, 72 EL8.5SEC 7 July July Club Blvd Ellerbe Neuse Metals Fecal, Nutrients, BOD, TSS, 76 EL9.9EC 8 Aug Aug Albany St Ellerbe Neuse Metals 30 Duplicate rotates 223 Field Blank rotates Fecal, Nutrients, BOD, TSS, 79 EN8.9ER* 1 Jan, Aug Jan, Aug West Point - Roxoboro Rd Eno Neuse Metals TOC Fecal, Nutrients, SOD, T55, 234 PN1.9PN 2 Feb, Sep Feb, Sep Cooksbury Rd Panther Creek Cape Fear Metals Fecal, Nutrients, SOD, TSS, 81 LL3.4LLC* 3 Mar, Oct Mar, Oct Mineral Springs Rd Little Lick Neuse Metals Fecal, Nutrients, BOD, TSS, 117 S11.6SIC 4 Apr, Nov Apr, Nov Chin Page Rd Stirrup Iron Neuse Metals Total Antimony 198 TF3.4TC* 5 May, Dec MLK near PWOC Fecal, Nutrients, BOD, T55, Third Fork Cape Fear 2 May, Dec Metals Fecal, Nutrients, SOD, TSS, 231 TF1.0TC* 6 Jun Jul Woodcraft Pkwy Third Fork Cape Fear Metals TOC Fecal, Nutrients, BOD, TSS, 205 CC2.5CC 7 July August Scott King Rd Crooked Creek Cape Fear Metals 31 Duplicate rotates 224 Field Blank rotates Fecal, Nutrients, BOD, TSS, 104 NH4.4SCTD 1 Jan, Aug Jan, Aug Academy Rd New Hope Cape Fear Metals Fecal, Nutrients, BOD, TSS, 100 NH3.3SC* 2 Feb, Sep Feb, Sep Cornwallis Rd New Hope Cape Fear Metals, TOC Fecal, Nutrients, SOD, TSS, 98 NH3.ONHC 3 Mar, Oct Mar, Oct Erwin Rd New Hope Cape Fear Metals Fecal, Nutrients, BOD, TSS, 96 NH2.3MC 4 Apr, Nov Apr, Nov Pickett Rd New Hope Cape Fear Metals Fecal, Nutrients, BOD, T55, 3 94 NH1.05C 5 May, Dec May, Dec Garrett Rd New Hope Cape Fear Metals Fecal, Nutrients, 80D, TSS, 214 NH1.7SCTA 6 Jun Jun Ivy Creek New Hope Cape Fear Metals Fecal, Nutrients, BOD, TSS, 91 NHO.ONHC 7 July July Old Chapel Hill Rd New Hope Cape Fear Metals 32 Duplicate rotates 225 1 Field Blank I rotates * Nutrient Loading Site TOC Field Blank and Duplicate Schedule LAB4 SITE NAME DAY Duplicate Collected Field Blank Collected 41 EL1.9EC 1 Jan, Jun, Nov Jan, Jun, Nov 230 EL7.1EC 1 Feb, Jul, Dec Feb, Jul, Dec 79 EN8.9ER 2 Mar, Aug Mar, Aug 231 TF1.0TC 2 Apr, Sep Apr, Sep 100 NH3.3SC 3 May, Oct May, Oct Page 8 of 8 Document prepared 12/9/2020, CC 2020 Ambient Monitoring Plan 1. Introduction The Ambient Monitoring Program was created to fulfill requirements of the City of Durham's National Pollution Discharge Elimination System (NPDES) permit (NCS000249). This Program characterizes watersheds located in the City of Durham (COD) and tracks changes or trends in water quality by monitoring the water chemistry, stream biology, and stream hydrology of selected streams. Streams selected for monitoring are fixed locations strategically located inside or just outside the City limits. Sites are monitored by COD Water Quality Unit (WQU) staff once per month and are on an even and odd year sampling rotation for particular watersheds. Therefore, the majority of sites are sampled every other year. Targeted watersheds for 2020 are Northeast Creek and Third Fork Creek in the Cape Fear River Basin and Little River, Eno River, Lick Creek, and Little Lick Creek in the Neuse River Basin. In addition to the alternating yearly sites, select sites are chosen for consistent monthly monitoring based on their potential to contribute nutrients downstream and their proximity to USGS stream gages. These "nutrient loading sites" are sampled every year and include sites located on Ellerbe Creek (EL7.1EC at Club Blvd and EL1.9EC at Glenn Rd), New Hope Creek (NH3.3SC at Cornwallis Rd), Eno River (EN8.9ER at West Point on the Eno), Little Lick Creek (LL3.4LLC at Mineral Springs Rd), and Third Fork Creek (TF3.4TC at MLK and TFI.OTC at Woodcroft Pkwy). For the 2020 sampling year, there were some updates to key project staff and staff titles. Shannon Hauschild and Susan Gale are no longer with the City of Durham. Joey Smith is the new Environmental Planning and Compliance Analyst and Blaine Lary is the new Environmental Planning and Compliance Specialist. As part of a City-wide Compensation and Classification Study, staff titles were changed for all positions in the WQU as seen in Table 1. Table 1 Water Quality Unit Job Titles Old Job Title New Job Title Water Quality Specialist Environmental Planning and Compliance Analyst Senior Water Quality Technician Environmental Planning and Compliance Coordinator Water Quality Technician Environmental Planning and Compliance Specialist At the time this report was written there is no contract lab in place however, the WQU is in the process of completing the contract process. The new contracted lab will likely start sometime in the first half of 2020. The contracted lab will run all Total Organic Carbon (TOC) samples for the Ambient Program. All other analyses (BOD-5 Day, Total Suspended Solids, Ammonia, Nitrate -Nitrite, Total Kjeldahl Nitrogen, Total Phosphorus, Hardness, Total Calcium, Total Magnesium, Total Copper, Dissolved Copper, Total Zinc, Dissolved Zinc, Total Antimony, and Fecal Coliform) will continue to be run by the South Durham Water Reclamation Facility (SDWRF) laboratory per the Ambient Monitoring Program QAPP. Page 1 of 8 Document Prepared 12/13/2019 - CC 2. Summary of the 2020 Planning Meeting Below is a summary of the notable changes that resulted from discussions at the 2020 Ambient Planning meeting held on October 31, 2019. For more details and a complete list of topics discussed in this meeting, please see Appendix 1. 2020 Ambient Planning Meeting - With Notes. Sampling Parameters The core parameters collected at every sampling site will remain the same as they were in 2019, including TOC (Total Organic Carbon) samples. For a full list of parameters collected at each site please see Appendix 2.2020 Ambient Water Quality Monitoring Sampling Tables. Continuing from last year, total antimony will be collected only at NE1.2NE (Northeast Creek at NC Hwy 54) due to a metal company located upstream of the sampling location processing antimony on site. Sampling Sites EN4.9ER (Eno River at Penny's Bend) has not been sampled since 2014 because samples were being collected at that site by the Upper Neuse River Basin Association (UNRBA) for a study that ran from 2014-2018. Since the UNRBA study is now complete EN4.9ER will be added back as a regular even year site sampled for all parameters. Due to a large amount of distance covered and driving time on Day 1, EN9.6CRC (Crooked Creek at Latta Road) was dropped. This sample site captures only a small portion of the watershed which can be represented in other ambient sites further down in the watershed. Site EL8.6SECUT (Unnamed Tributary of South Ellerbe Creek at Foster St and Hunt St) is normally an odd year site. However, due to ongoing issues with multiple parameters, most recently is very high levels of Zinc, this site will be monitored on Day 1 in 2020. There was a concern that the accelerated development rate in the downtown area could give rise to an increase in pollution sources and continued sampling of this site might help to capture some of these possible issues. In 2018 a large tree fell at sample site TF5.6TC (Third Fork Creek at Forest Hills Park). This fallen tree caused significant change to the channel due to high levels of sedimentation and also caused the site to be difficult to access. Therefore, a new sampling location, TF5.4TC (Third Fork Creek at Forestwood Dr.) was identified further downstream and it will replace TF5.6TC. The sampling location of NE1.2NE (Northeast Creek at NC Hwy 54) was determined to have shifted slightly upstream from the original sampling location. The original location was intended to be just downstream of the NC Hwy 54 bridge to capture the input of a large wetland/marsh area just upstream of the bridge. For 2020, the sampling location of NE1.2NE will be moved back downstream of the Hwy 54 bridge to the original location. The upstream location that has been sampled for the previous handful of years will be given a new site ID (NE1.3NE) and data collected at this location will be retroactively changed to this new ID. All other sites remained the same from 2018. For the complete 2020 list of sites, their locations, and associated lab numbers along with the duplicate and field blank schedule please see Appendix 3. 2020 Ambient Site List. Page 2 of 8 Document Prepared 12/13/2019 - CC Benthic Monitoring The benthic monitoring sites will primarily remain the same as in 2018. However, there will be some later consideration into possibly changing the location of TFO.OTC this year. Additional discussions on changes to the 2020 benthic sampling plan will be held in the future and all possible changes will be summarized in a separate benthic monitoring plan. Page 3 of 8 Document Prepared 12/13/2019 - CC Appendix 1. 2020 Ambient Planning Meeting - with Notes 2020 Ambient Planning Meeting with Notes Attendees: Michelle Woolfolk, JV Loperfido, John Baker, Jim Azarelo, Joey Smith, Dave Milkereit, Blaine Lary, and Christine Cailleret 2020 Monitoring Information ❖ Total proposed sites: -14 23 (12 Neuse, 11 Cape Fear) ❖ Target watersheds on the same day - Yes ❖ One team of two people per sampling day - Yes ❖ Sampling will occur on the first, second, and third Tuesday of every month and prep and meter maintenance will occur on the last Tuesday of every month - Yes ❖ QA/QC samples will be as follows: o One field blank per sampling day -Yes o One duplicate per sampling day - Yes o One TOC field blank per month -Yes o One TOC duplicate per month - Yes ■ Is there a need for equipment blanks quarterly? - It is written in the Draft QAPP that we will perform equipment blanks. This was referencing when a sampling cup was used to collect samples that were then poured into sample bottles. As we no longer use this type of pole sampler and all sample bottles are directly dipped, there is no need for equipment blanks. Additionally, the field blanks have not shown any concern for contaminated equipment. ❖ Contract lab: by May? RFP for Lab contracts closed on 10/31/2019. Questions/Discussion Topics: ❖ Make TF3.4TC (MILK at PWOC) a nutrient loading site? o It was supposed to be a nutrient loading site starting in 2018, but it was not sampled in 2019 due to too many sample sites for Day 2. Notes from 2019 state that it will become a nutrient loading site in 2020. -Yes. Make TF3.4TC a nutrient loading site, to be sampled every year from here on out. ❖ Add EN4.9ER (Penny's Bend) back? It was sampled by UNRBA from 2014 — 2018 and a note from 2018 say to sample it in 2020. o It would have to be sampled on Day 1 with the rest of the Eno Sites. - Yes, add it back to Day 1. Page 4 of 8 Document Prepared 12/13/2019 - CC - Due to a large amount of driving required for Day 1, EN9.6CRC (Latta Road) will be dropped. The Latta Road site covers a small drainage area and does not provide any information that cannot be determined from other sites on the Eno. ❖ EL8.6SECUT (Foster and Hunt) was sampled for Zinc only in 2018; do we continue to do this or make it a site sampled every year due to ongoing issues and high visibility? Or make it part of a special study? o If it is sampled every year it would have to be sampled on Day 1 with other Ellerbe sites. - Add it to Day 1 and sample all parameters due to the high visibility and the high number of investigations initiated at this site from ambient data. It was also discussed if this site should be part of a special study in the future. Ellerbe Creek watershed with be up for a watershed study plan in the coming years and it was requested for this site to be kept in mind for extra analysis as part of that study. - It was also mentioned that maybe our group should request the drainage group to TV the Stormwater pipes around this site in an attempt to identify problem areas or potential pollution sources. ❖ Continue to test for total Antimony at NE1.2NE (Chick-fil-A) and S11.6SIC (Chin Page Rd)? o 511.6SIC is an odd year site and would have to be added to Day 2. - Test all Northeast Creek sites (NE2.2NP, NEO.ONE, and NE1.2NE) for total Antimony, but do not add 511.6SIC to Day 2. Keep 511.6SIC as an odd year site and test Sb there in 2021. ❖ NE1.2NE (Chick-fil-A) Can we move this site? Not a great sampling location, it is often very deep and we cannot reach the thalweg and are likely not getting very representative samples. We would need to recon. - After a review of the current location for this site, it was determined that the current location had drifted upstream from the original location. The current location for this site is about 0.1 mile further upstream than the original location. The current location is upstream of a large marsh area that was originally intended to be captured in ambient data. It was decided that NE1.2NE will move back downstream to the original location on the downstream side of the Hwy 54 bridge. This original location will keep the site ID of NE1.2NE and the current location that is further upstream will be given a new ID and data for the past 5 years or so will retroactively be changed to this new site ID. - The new site ID for the upstream location is NE1.3NE. ❖ TF6.5RCUT (Sima Ave) do we need to move this site down to catch McDougal Terrace issues? - No, this is not the purpose of the Ambient Program. Keep this location where it is. Sampling for McDougal Terrace will occur separately as part of the IDDE program. ❖ TF5.6TC (Forest Hills Park) has an access issue. Since the tree fell on this site it is hard to access and the staff gage was damaged and completely buried in sediment. Move the site further U/S? Move staff gage or remove it? - Move the site further downstream to below the confluence and give this location a new site ID and lab number. - After recon on 11/25/2019, a new location was identified and was given the new site ID of TF5.4TC and a lab number of 132. Page 5 of 8 Document Prepared 12/13/2019 - CC ❖ 2019 Meeting notes mentioned consider adding the old Knox location (EL7.6SECT) to catch any changes due to the South Ellerbe Creek Wetland Project... what is the status of the construction of the project? - The project is projected to be completed in 2 years. As of this meeting date, the old building has been demolished and 2 underground storage tanks have been removed. As of now, EL7.6SECT will not be added to the ambient sampling rotation, but we will discuss adding it for 2021. ❖ TF2.5TCTC (Dover/Golf Course) is this site giving us useful data? We normally get not great results due to the buffer issues/no canopy cover on the golf course. o Sample for herbicides/pesticides? - Keep this site for 2020. This location covers a large drainage area and fecal numbers have been high. Discuss in 2022 if we want to continue sampling here. ❖ Add EL8.5SEC (Club at Walltown Park Rec Center) to be sampled every year due to the high amount of WQ Investigations that have been initiated due to ambient field or lab results? o Would have to go on Day 1 with other Ellerbe sites - No, keep this site as an odd year site. ❖ Any changes to the Benthic sites or the Benthic program in general? o Maybe try using benthic data to determine issue areas and/or assist with whether or not we add or drop a site in the ambient planning meetings. Select benthic sites further downstream in watersheds and move upstream if issues are found. o Benthic Sites for this year: River Lat/Long Drainage area Sampling basin Site code Location (dec. deg.) (mi.') method 35.9226 TFO.OTC NC 751 16.1 Qual4 a M -78.9524 (0 ) U NEO.ONE Sedwick Rd. 78 8998 12.9 Qual4 35.1416 LR9.6LR Johnson Mill Rd. 78.2 Full Scale -78.9208 36.0716 EN8.9ER West Point on the Eno park 141.1 Full Scale -78.9100 36.0731 EN4.9ER Penny's Bend access 149.3 Full Scale z -78.8635 35.9850 1-1-3.41-1-C Mineral Springs Rd. 6.0 Qual4 -78.8198 35.9777 LC1.1LC Southview Rd. 10.8 Qual4 -78.7496 - There was some discussion to move sites further up in the watersheds. However, there was a lot of interest to keep sites where there are currently located to keep the historical data. LL3.41-1-C and LL1.ILLC were requested to keep their locations, but one of the other sites could be moved to a new location. There was some discussion of moving TFO.OTC to the old S. Roxboro St site (was previous a bug only site), however, some recon will take place before a decision is made. Page 6 of 8 Document Prepared 12/13/2019 - CC Appendix 2.2020 Ambient Water Quality Monitoring Sampling Tables Samples/Day Day 1 Day 2 Day 3 EL8.6SECUT LL4.6LLT2 TF6.5RCUT 1 EL7.1EC LL3.4LLC TF5.1RC 1 EL1.9EC LC1.11-C TF4.4TC EN4.9ER LC2.ORBC TF5.4TC LR9.6LR 2NE2.2NP NH3.3SC 1 EN8.9ER 2NEO.ONE TF3.4TC EN10.3WC 2NE1.2NE TF2.5TCTC EN13.3ER 224 TFI.OTC 223 31 225 30 32 10 9 10 1TOC analyzed by Contract Lab 2Total Antimony Tentative Sampling Dates Day 1 Day 2 Day 3 January 7 14 21 February 4 11 18 March 3 10 17 April 7 14 21 May 5 12 19 June 2 9 16 July 7 14 21 August 4 11 18 September 1 8 15 October 6 13 20 *November 3 4 17 *December 1 8 9 *Sampling days for November and December were adjusted to accommodate the holidays. Ambient Parameters Fecal Coliform Nutrients: Nitrate + Nitrite N Total Kjeldahl N Total Ammonia N Total Phosphorus Total Suspended Solids 5-day BOD Total Metals: Calcium Magnesium Zinc Copper 2Total Antimony (at all NE sites) Dissolved Metals (Field - Filtered): Copper Zinc Hardness (calculated) Document Prepared 12/13/2019 - CC Page 7 of 8 Appendix 3.2020 Ambient Site List SITENAME DAY SAMPLIN .. WATERSHED ORDERLAB BOD, Fecal, Metals, Nutrients, 193 EL8.6SECUT 1 1 Jan, Sep Jan, Sep Foster St & Hunt St Ellerbe Neuse SS BOD, Fecal, Metals, Nutrients, 230 *EL7.1EC 1 2 Feb, Oct Feb, Oct Club Blvd & Acadia St Ellerbe Neuse TSS, TOC BOD, Fecal, Metals, Nutrients, 41 *EL1.9EC 1 3 Mar, Nov Mar, Nov Glenn Rd Ellerbe Neuse TSS, TOC 78 EN4.9ER 1 4 Apr, Dec Apr, Dec Penny's Bend (Snow Hill Rd) BOD, Fecal, Metals, Nutrients, Eno Neuse SS BOD, Fecal, Metals, Nutrients, 180 LR9.6LR 1 5 May May Patrick Rd & Johnson Mill Rd Little River Neuse SS BOD, Fecal, Metals, Nutrients, 79 *EN8.9ER 1 6 Jun Jun West Point on the Eno TSS, TOC Eno Neuse 196 EN10.3WC 1 7 Jul Jul Horton Rd, East of Guess Rd BOD, Fecal, Metals, Nutrients, Eno Neuse SS BOD, Fecal, Metals, Nutrients, 77 EN13.3ER 1 8 Aug Aug Cole Mill Rd Eno Neuse 30 Duplicate 1 - 223 Field Blank 1 - - - - - - BOD, Fecal, Metals, Nutrients, 82 LL4.6LLT2 2 1 Jan, Aug Jan, Aug Lynn Rd, South of Hwy 98 Little Lick Neuse TSS BOD, Fecal, McStals, Nutrients, 81 *LL3.4LLC 2 2 Feb, Sep Feb, Sep Mineral Springs Rd, North of 98 Little Lick Neuse BOD, Fecal, McStals, Nutrients, 168 LC1.1LC 2 3 Mar, Oct Mar, Oct Southview Rd, South of 98 Lick Creek Neuse BOD, Fecal, Metals, Nutrients, 169 LC2.ORBC 2 4 Apr, Nov Apr, Nov Kemp Rd & Southview Rd Lick Creek Neuse BOD, Fecal, Metals, Nutrients, 17 NE2.2NP 2 5 May, Dec May, Dec Meridian Pkwy Northeast Cape Fear TSS, Total Sb BOD, Fecal, Metals, Nutrients, 19 NEO.ONE 2 6 Jun Jun Sedwick Rd Northeast Cape Fear TSS, Total Sb 11 NE1.2NE 2 7 Jul Jul Hwy54, West of Hwy 55 BOD, Fecal, Metals, Nutrients, Northeast Cape Fear TSS, Total Sb 31 Duplicate 2 - 224 Field Blank 2 - BOD, Fecal, McStals, Nutrients, 142 TF6.5RCUT 3 1 lan, Sep Jan, Sep Sima Ave, at Burton Park Third Fork Cape Fear BOD, Fecal, Metals, Nutrients, 130 TF5.1RC 3 2 Feb, Oct Feb, Oct Elmira St Third Fork Cape Fear BOD, Fecal, McStals, Nutrients, 127 TF4.4TC 3 3 Mar, Nov Mar, Nov Weaver St Third Fork Cape Fear BOD, Fecal, McStals, Nutrients, 132 TF5.4TC 3 4 Apr, Dec Apr, Dec Forestwood Dr (Forest Hills Park) Third Fork Cape Fear 100 *NH3.3SC 3 5 May May Cornwallis Rd BOD, Fecal, Metals, Nutrients, New Hope Cape Fear 198 *TF3.4TC 3 6 Jun Jun MLK near PWOC BOD, Fecal, Metals, Nutrients, Third Fork Cape Fear BOD, Fecal, Metals, Nutrients, 120 TF2.5TCTC 3 7 Jul Jul Dover Rd Third Fork Cape Fear TSS BOD, Fecal, McStals, Nutrients, 231 *TFI.OTC 3 8 Aug Aug Woodcraft Pkwy Third Fork Cape Fear 32 Duplicate 3 - 225 Field Blank 3 * Nutrient Loading Site TOC Field Blank and Duplicate Schedule 230 1 EL7.1EC 1 1 1 Jan, Apr, Jul, Oct I Jan, Apr, Jul, Oct 1 41 1 EL1.9EC 1 1 1 Feb, May, Aug, Nov I Feb, May, Aug, Nov 1 79 1 EN8.9ER 1 1 1 Mar, Jun, Sep, Dec I Mar, Jun, Sep, Dec I Page 8 of 8 Document Prepared 12/13/2019 - CC 2019 Ambient Monitoring Plan 1. Introduction The Ambient Monitoring Program was created to fulfill requirements of the City of Durham's National Pollution Discharge Elimination System (NPDES). This Program characterizes City of Durham (COD) waters and tracks changes or trends in water quality by monitoring the water chemistry, stream biology, and stream hydrology of selected City of Durham streams. Streams selected for monitoring are fixed locations strategically located inside or just outside the City limits. Sites are monitored by COD Water Quality Unit (WQU) staff once per month and are on an even and odd year sampling rotation for particular watersheds. Therefore, the majority of sites are sampled every other year. Targeted watersheds for 2019 are New Hope Creek, Panther Creek and Crooked Creek in the Cape Fear River Basin and Ellerbe Creek and Stirrup Iron Creek in the Neuse River Basin. Additional sites on Eno River (EN8.9ER at West Point on the Eno) Little Lick Creek (LL3.4LLC at Mineral Springs Rd) and Third Fork Creek (TFI.OTC at Woodcroft Pkwy) are nutrient loading sites and are sampled every year. There are three additional nutrient loading sites, EL1.9EC (Ellerbe Creek at Glenn Rd), EL7.1EC (Ellerbe Creek at Club Blvd and Acadia St), and NH3.3SC (Sandy Creek at Cornwallis Rd) within the 2019 Targeted watersheds that are also sampled every year. For the 2019 sampling year there were some updates to key project staff. Shannon Hauschild is now a Water Quality Technician and Thomas Chapman is no longer with the City of Durham. Meritech will continue as the contracted laboratory that will run all Total Organic Carbon (TOC) samples. All other analyses (BOD-5 Day, Total Suspended Solids, Ammonia, Nitrate -Nitrite, Total Kjeldahl Nitrogen, Total Phosphorus, Hardness, Total Calcium, Total Magnesium, Total Copper, Dissolved Copper, Total Zinc, Dissolved Zinc, and Fecal Coliform) will continue to be run by the South Durham Water Reclamation Facility (SDWRF) in accordance with the Ambient Monitoring Program QAPP. 2. Summary of the 2019 Planning Meeting Below is a summary of the notable changes that resulted from discussions at the 2019 Ambient Planning meeting held on October 30, 2018. For more details and a complete list of topics discussed in this meeting, please see Appendix 1. 2019 Ambient Planning Meeting - With Notes. Sampling Parameters The core parameters collected at every sampling site will remain the same as they were in 2018. For a full list of parameters collected at each site please see Appendix 2. 2019 Ambient Water Quality Monitoring Sampling Tables. Starting in 2019 TOC will no longer be collected at LL3.4LLC, in efforts to save money. LL3.4LLC has had continuously poor results for TOC will little to no change over the recent sampling years. In addition, Page 1 of 9 Document Prepared 12/13/2018 - CC only one TOC field blank will be collected per month. In previous years one TOC field blank was collected per day. For a full list of what sites will have TOC collected see Appendix 2. 2019 Ambient Water Quality Monitoring Sampling Tables Sampling Sites PN2.4PN (Panther Creek at Burton Rd) was added back as an ambient sampling site for 2019. In 2017 PN2.4PN was dropped because samples were being collected at this site by UNRBA. However, UNRBA has completed their study therefore; COD WQU will collect samples at this site in 2019. In 2019 NH4.4SCTD (Sandy Creek Tributary D at Academy Rd) will replace NH4.8SCTDT (Unnamed Tributary of Tributary D of Sandy Creek at Duke University Rd). There were safety issues for sampling at NH4.8SCTDT that involved a technician stopping traffic in order to back out onto a busy road. Additionally, NH4.8SCTDT has a very small drainage area when NH4.4SCTD is a better representation of the surrounding area. In 2017 EL10.7EC (Ellerbe Creek at Bellevue Ave) was an ambient site for 3 months as part of a contract with the Ellerbe Creek Watershed Association (ECWA). In the 2019 Ambient Planning Meeting it was decided that COD WQU will not sample EL10.7EC in 2019. The WQU already samples other sites on Ellerbe Creek and there were no major issues found at EL10.7EC in the most recent sampling years. EL8.6SECUT (Unnamed Tributary of South Ellerbe Creek at Foster St and Hunt St) is normally a site that is sampled on odd years. However, due to an ongoing investigation involving high Zinc amounts, this site was sampled for Field parameters and total and dissolved Zinc in 2018. At the 2019 Ambient Planning Meeting it was discussed if this site should be incorporated into an alternative sampling project since efforts through the Ambient Program have not resulted in a solution to the issue. It was decided that due to the high visibility of the sampling site (in Durham Central Park) and the high number of issues found at this site in past sampling years, that EL8.6SECUT would remain a regular odd -year sampling site. NH1.7SCTA (Sandy Creek Tributary A at Ivy Creek Blvd) is an ambient site normally sampled in the odd years. However, due to an ongoing issue with low DO, this site was sampled quarterly for field parameters in 2018. This sample site is also a site that is part of a separate COD WQU contract with the purpose of resolving the issues involving low DO. During the 2019 Ambient Planning Meeting it was discussed if this site should be dropped as an Ambient site in 2019 because it will monitored as part of the separate contract. It was decided that NH1.7SCTA will be sampled as an Ambient site in 2019 to prevent the site from going too long without any monitoring, as the contract work with start on another location first before the moving on to NH1.7SCTA. All other sites remained the same from 2017. For the complete 2019 list of sites, their locations, and associated lab numbers along with the duplicate and field blank schedule please see Appendix 3. 2019 Ambient Site List. Page 2 of 9 Document Prepared 12/13/2018 - CC Benthic Monitoring The Benthic Monitoring sites will primarily remain the same as in 2017. However, there were some changes that were made at the separate Benthic Monitoring meeting held on 12/4/2018. Starting in 2019, Benthic samples will not be collected at EL5.6EC (Ellerbe Creek at Midland Terrace). This location was determined to not be necessary for benthic sampling as it has been consistently rated "poor" in previous sampling years and there are two other benthic sites located on Ellerbe Creek. Starting in 2019 Benthic samples will be collected at EL7.1EC (Ellerbe Creek at Club Blvd and Acadia St) instead of EL7.9EC (Ellerbe Creek at Murray Ave). EL7.9EC is no longer a regularly sampled Ambient site since the nutrient loading location was moved to EL7.1EC. It was decided that benthic samples should be collected at the new nutrient loading site. Benthic macroinvertebrate sampling for 2019 will be summarized in a separate monitoring plan. Page 3 of 9 Document Prepared 12/13/2018 - CC Appendix 1.2019 Ambient Planning Meeting - with Notes 2019 Ambient Planning Meeting Attendees: Michelle Woolfolk, JV Loperfido, Jon Baker, Jim Azarelo, Susan Gale, Dave Milkereit, Shannon Hauschild, Blaine Lary, and Christine Cailleret 2019 Monitoring Information ❖ Total pFepesed-sites: 21 (11 Neuse and 10 Cape Fear) o Focus on Ellerbe and New Hope ❖ Target watersheds sampled on the same day - Yes ❖ One team (two people) per sampling day unless there is a special circumstance (training, audit, interns, etc.) - Okay ❖ Continue with the schedule that was established this calendar year: Sampling will occur on the 1st, 2nd, and 3rd Tuesday of every month - Okay ❖ QA/QC samples will remain the same: o One field blank per sample day o One duplicate per sample day o One TOC field blank peF day per month o One TOC duplicate per month ❖ EL7.9EC (Murray Ave) — no longer the nutrient loading site, moved to EL7.1EC Acadia and Club. ❖ TFO.OTC (Hwy 751) —no longer the nutrient loading site, moved to TFI.OTC Woodcroft Pkwy. ❖ TF3.4TC (MLK at PWOC) —now a nutrient loading site, sampled every year. —Hold off on this, it will become a nutrient loading site in 2020. See notes about PN2.4PN for more info. Questions/Discussion Possible sites to drop/add ❖ EL7.9EC (Murray Ave) add to gather more data points to compare to EL7.1EC? o Would have to be sampled on Day 1 Do not add EL7.9EC back, but move benthic location from here to EL7.1EC. ❖ EL8.6SECUT (Foster St and Hunt St) very small trib, but high visibility in central park. o Suggest drop and add to JV's contract due to ongoing investigation (17WQ040)? Keep for continued monitoring due to the high visibility of the area. There have been too many recent investigations at this sight to stop monitoring. May add to JV's contract, but due to limited budget not sure how much could be determined from this contract. ❖ EL8.5SEC (Club Blvd @ Walltown Park) was a fecal only site in 2008, upgraded to a full comprehensive for Rain Catchers. o Suggest drop, small trib of SEC, we have other sites on SEC do we need this one too? Keep. Too many investigations have been initiated at this sight to stop monitoring it. Page 4 of 9 Document Prepared 12/13/2018 - CC *Also discussed in the Ambient Meeting: Consider monitoring the old Knox St location (EL7.6SECT) in 2020 to catch any changes due to the construction of the South Ellerbe Creek Wetland Project (Located on Trinity St). There was some discussion about adding Knox in 2019 as a baseline or pre data for the South Ellerbe Creek Wetland Project, but since construction of the wetland has already begun and limited historical data from this site exists, it was decided that it would not be the best use of resources to sample this site in 2019. **During recon it was determined that sampling U/S of the Club Blvd culvert would be unsafe due to a large standing dead tree leaning directly over the sampling site and a non -COD job box that was also leaning and appeared to be unstable. Sampling will now occur D/S of the culvert which can be easily and safely accessed from the Walltown Park Rec Center parking lot. ❖ NH1.7SCTA (Ivy Creek Blvd) ongoing issues with DO o Drop as an ambient site now that it is a part of JV's contract? Keep and sample in 2019. JV's contract will begin with work on Warren Creek. Therefore, Ivy Cr. Blvd should be included in ambient monitoring to prevent this site from going too long without any data being collected. ❖ PN2.4PN (Burton Rd) dropped in 2017, UNRBA was sampling it, they have now stopped and they mentioned it was a very minor trib. It often is dry and not sampled for 2-3 months a year. o If added it would have to be sampled on Day 2 Add back and sample on Day 2 to keep track of Panther Creek. In order to not make Day 2 too long (lots of driving), TF3.4TC will not be sampled this year and will be established as a nutrient loading site starting in 2020 (sampled every year from then on). ❖ EL10.7EC (Bellevue — Golf Course) sampled for 3 months in 2017 as a request from ECWA. Do we need to sample it this year? o If added it would have to be sampled on Day 1 Do not add it back this year, there are already enough sites on Ellerbe, and there were no major issues found at this location in previous years. Revisit in 2021. ❖ NHS.OSCTD (Anderson St) started as fecal only site in 2006 — moved to a complete site in 2011 due to ongoing SSO issues in the Maplewood cemetery. Was completely dropped in 2015, but we had a note to reevaluate in 2019. Do we need to add it back? o If added it would have to be sampled on Day 3 Do not add back, keep dropped. After a review of SSOs in the area it was decided that it was not a high priority to keep monitoring this location. ❖ LITCI.SLITC (Farrington Rd — on top of the spillway bridge) dropped in 2017 mainly due to safety concerns — stay dropped? Stay dropped too many safety and access concerns. ❖ UNRBA Requests We will sample PN2.4PN, but we will not sample any of the other sites they requested to sample this year. They also asked for us to coordinate our schedules with DWR. In order to keep our schedule of sampling the 15Y, 2nd and 3rd Tuesday every month, we will not adjust our schedule. We will notify UNRBA/DWR of our schedule. Page 5 of 9 Document Prepared 12/13/2018 - CC Discussion topics Parameters ❖ Are we happy with the parameters sampled? o Add fluoride? — it was asked to be revisited as a possibility for 2019 as it may be a useful parameter for Ellerbe sites (issues involving water line leaks/breaks) Fluoride is sampled when there is an Outfall Screening trigger. It was decided it was best to keep fluoride sampling with the Outfall Project. There were doubts that a water line leak/break could be detected during ambient monitoring due to dilution. o Trash? Anything else in relation to WQI 2.0 Project? We will wait until decisions are made in the WQI 2.0 Project. These changes will be reflected in future sampling years. o Alkalinity? Alkalinity is only needed for specific special projects; it does not need to be part of the main sampling parameters. ❖ Do we want to continue sampling for TOC? o Would save money from not needing glass DI and samples cost $28 each. TOC monitoring was originally initiated to support the UNRBA monitoring effort for Falls Lake, but UNRBA completed their monitoring in October 2018. However, the City of Raleigh has noted issues with high TOC levels in the past at their intake on Falls Lake. Continued monitoring of TOC will provide data to determine if Durham is a potential source in the case of any high concentrations noted in the future. Therefore, TOC will continue to be sampled at EL1.9EC, EL7.1EC, and EN8.9ER. In order to save some money LL3.4LLC will be dropped as it has had consistently poor results. Also, only one Field Blank sample will be taken every month in order to help reduce costs. ❖ Change Investigation triggers for Zn and Cu based on current hardness levels of our streams? *To be discussed in a separate meeting* ❖ Annual 5-in-30 sampling for Fecal in Northeast Creek? To be done as a special project separate from Ambient sampling (2020). Safety concerns ❖ Move NH4.8SCTDT (Duke University)? We currently have to stop traffic to back out. NH4.8SCTDT will be dropped and NH4.4SCTD (Academy Rd) will be added in its place. ❖ Sampling from culvert at S11.6SIC (Chin Page Rd) we have to use pole sampler. Samples will be collected from the side of bank using the pole sampler instead of from the top of the culvert. ❖ Access issues for EL5.6EC (Midland Terrace). This site will be reconned to determine a better way to access it. ❖ Parking issues for CC2.5CC (Scott King Road). Technicians will park on easement instead of the side of the road. ❖ Construction issues NHO.ONHC (Old Chapel Hill Rd). This site will be reconned to determine if a new sampling location is needed due to the ongoing construction project in this area. Page 6 of 9 Document Prepared 12/13/2018 - CC ❖ Performing Field Blanks at the tail gate on busy roads. This will be discussed within the M&A group to determine a solution to this issue. Benthic Monitoring *To be discussed at a separate meeting* ❖ Drop Panther creek (PN2.4PN, Burton Rd)? ❖ Drop EL 5.5GC (Camden Ave) —continuously scores poor? ❖ Any changes to frequency of sampling or overall project structure? Page 7 of 9 Document Prepared 12/13/2018 - CC Appendix 2.2019 Ambient Water Quality Monitoring Sampling Tables 2019 Ambient Water Quality Monitoring Scheduled Sampling Dates Day 1 Day 2 Day 3 *January 8 15 22 February 5 12 19 March 5 12 19 April 2 9 16 May 7 14 21 June 4 11 18 *July 9 16 23 August 6 13 20 September 3 10 17 October 1 8 15 November 5 12 19 *December 3 4 10 *Sampling days for January, July, and December were adjusted to accommodate the holidays. 10 Sample Sets/Day Day 1 Day 2 Day 3 EL8.6SECUT *EN8.9ER NH4.4SCTD EL8.1GC PN2.4PN NH3.3SC *EL1.9EC LL3.4LLC NH3.ONHC EL5.5GC 511.6SIC NH2.3MC EL5.6EC CC2.5CC NHI.OSC *EL7.1EC TFI.OTC NH1.7SCTA EL7.ISEC Field Blank NHO.ONHC EL8.5SEC Duplicate Field Blank Field Blank Duplicate Duplicate 10 8 9 * TOC analyzed by Meritech Ambient Parameters Fecal Coliform Nutrients Nitrate + Nitrite N Total Kjeldahl N Total Ammonia N Total Phosphorus Total Suspended Solids 5-day BOD Total Metals Calcium Magnesium Zinc Copper Field -Filtered Metals Copper Zinc Hardness (calculated) Page 8 of 9 Document Prepared 12/13/2018 - CC Appendix 3.2019 Ambient Site List SITE NAME DAY SAMPLING Duplicate Field Blank .. WATERSHED ORDERLAB# Fecal, Nutrients, BOD, TSS, 193 EL8.6SECUT 1 1 Jan, Sep Jan, Sep Foster and Hunt Street Ellerbe Neuse Metals Fecal, Nutrients, BOD, TSS, 68 EL8.1GC 1 2 Feb, Oct Feb, Oct Holloway Street Ellerbe Neuse Metals Fecal, Nutrients, BOD, TSS, 41 EL1.9EC* 1 3 Mar, Nov Mar, Nov Glenn Road Ellerbe Neuse Metals, TOC Fecal, Nutrients, BOD, TSS, 47 EL5.5GC 1 4 Apr, Dec Apr, Dec Camden Ave Ellerbe Neuse Metals Fecal, Nutrients, BOD, TSS, 48 EL5.6EC 1 5 May May Midland Terrace Ellerbe Neuse Metals Fecal, Nutrients, BOD, TSS, 230 EL7.1EC* 1 6 Jun Jun Club and Acadia St Ellerbe Neuse Metals, TOC Fecal, Nutrients, BOD, TSS, 57 EL7.ISEC 1 7 July July Glendale Ave Ellerbe Neuse Metals Fecal, Nutrients, BOD, TSS, 72 EL8.5SEC 1 8 Aug Aug Club Blvd Ellerbe Neuse Metals 30 Duplicate 1 rotates 223 Field Blank 1 rotates Fecal, Nutrients, BOD, TSS, 79 EN8.9ER* 2 1 Jan, Jul Jan, Jul West Point - Roxoboro Rd Eno Neuse Metals, TOC Fecal, Nutrients, BOD, TSS, 198 PN2.4PN 2 2 Feb, Aug Feb, Aug Burton Rd panther Creek Cape Fear Metals Fecal, Nutrients, BOD, TSS, 81 LL3.4LLC* 2 3 Mar, Sep Mar, Sep Mineral Springs Rd Little Lick Neuse Metals Fecal, Nutrients, BOD, TSS, 117 511.6SIC 2 4 Apr, Oct Apr, Oct Chin Page Rd Stirrup Iron Neuse Metals Fecal, Nutrients, BOD, TSS, 205 CC2.5CC 2 5 May, Nov May, Nov Scott King Rd Crooked Creek Cape Fear Metals Fecal, Nutrients, BOD, TSS, 231 TFI.OTC* 2 6 Jun, Dec Jun, Dec Woodcroft Pkwy Third Fork Cape Fear Metals 31 Duplicate 2 rotates 224 Field Blank 2 rotates Fecal, Nutrients, BOD, TSS, 108 NH4.4SCTD 3 1 Jan, Aug Jan, Aug Academy Rd New Hope Cape Fear Metals Fecal, Nutrients, BOD, TSS, 100 NH3.3SC* 3 2 Feb, Sep Feb, Sep Cornwallis Rd New Hope Cape Fear Metals Fecal, Nutrients, BOD, TSS, 98 NH3.ONHC 3 3 Mar, Oct Mar, Oct Erwin Rd New Hope Cape Fear Metals Fecal, Nutrients, BOD, TSS, 96 NH2.3MC 3 4 Apr, Nov Apr, Nov Pickett Rd New Hope Cape Fear Metals Fecal, Nutrients, BOD, TSS, 94 NHI.OSC 3 5 May, Dec May, Dec Garrett Rd New Hope Cape Fear Metals Fecal, Nutrients, BOD, TSS, 214 NH1.7SCTA 3 6 Jun Jun Ivy Creek New Hope Cape Fear Metals Fecal, Nutrients, BOD, TSS, 91 NHO.ONHC 3 7 July July Old Chapel Hill Rd New Hope Cape Fear Metals 32 Duplicate 3 rotates 225 Field Blank 1 3 rotates * Nutrient Loading Site TOC/DOC Field Blank and Duplicate Schedule Page 9 of 9 Document Prepared 12/13/2018 - CC 2018 Ambient Monitoring Plan 1. Introduction The Ambient Monitoring Program was created to fulfill requirements of the City of Durham's National Pollution Discharge Elimination System (NPDES). This Program characterizes City of Durham (COD) waters and tracks changes or trends in water quality by monitoring the water chemistry, stream biology, and stream hydrology of selected City of Durham streams. Streams selected for monitoring are fixed locations strategically located inside or just outside the City limits. Sites are monitored once per month and are on an even and odd year sampling rotation for particular watersheds. Therefore, the majority of sites are sampled every other year. Targeted watersheds for 2018 are Northeast Creek and Third Fork Creek in the Cape Fear River Basin and Eno River, Lick Creek, Little Lick Creek and Little River in the Neuse River Basin. Additional sites on Ellerbe Creek (EL7.1EC at Club Blvd. and Acadia St. and EL1.9EC at Glenn Rd.) and New Hope Creek (NH3.3SC at Cornwallis Rd.) are nutrient loading sites and are sampled every year. There are four additional nutrient loading sites, EN8.9ER (West Point on the Eno), LL3.4LLC (Little Lick Cr. at Mineral Springs), TF3.4TC (Third Fork Cr. at PWOC), and TFI.OTC (Third Fork Cr. at Woodcroft Rd.) within the 2018 Targeted watersheds that are also sampled every year. For the 2018 sampling year there were some updates to key project staff. Christine Cailleret (previously Christine Smith) and Dave Milkereit are currently both Sr. Water Quality Technicians and Thomas Chapman is currently a Water Quality Technician. Additionally, Danielle Mir is no longer with the City of Durham. Meritech will continue as the contracted laboratory that will run all Total Organic Carbon (TOC) samples and provide deionized (DI) water used for field blanks. All other analyses (BOD-5 Day, Total Suspended Solids, Ammonia, Nitrate -Nitrite, Total Kjeldahl Nitrogen, Total Phosphorus, Hardness, Total Calcium, Total Magnesium, Total Copper, Dissolved Copper, Total Zinc, Dissolved Zinc, and Fecal Coliform) will continue to be run by South Durham Water Reclamation Facility (SDWRF) in accordance with the Ambient Monitoring Program QAPP. 2. Summary of the 2018 Planning Meeting Below is a summary of the notable changes that resulted from the discussions at the 2018 Ambient Planning meeting held on November 20, 2017. For more details and a complete list of topics discussed in this meeting please see Appendix 1. Sampling Schedule During the planning meeting for the 2018 sampling year a new schedule was proposed and accepted. Previously, samples were collected on Tuesday and Wednesday of the second full week and Wednesday of the third full week of every month. On the new schedule sampling will take place on the first, second and third Tuesday of every month. Any variations to the scheduling will be due to holidays and staff availability. The scheduled sampling dates for the 2018 calendar year are in Appendix 2. Page 1 of 7 Document Prepared 1/8/2018 - CC Sampling Parameters Starting in 2018 all sample sites will be analyzed for both total and dissolved Zinc. In previous years only Dissolved Zinc was analyzed. All other parameters will remain the same. There will be additional parameters analyzed at NH3.3SC (Sandy Cr. at Cornwallis) as part of the Sandy Creek Watershed Characterization (project #16-001). These additional parameters will be collected quarterly in February, May, August, and November and will be analyzed by Meritech. For a complete list of what parameters will be collect at each site please refer to Appendix 2. Sampling Sites This year EL8.6SECUT (Ellerbe at Foster St. and Hunt St.) was added as a Zinc only site because of the ongoing investigation (17WQ040) involving continuous amounts of high zinc. Only total and dissolved Zinc and field parameters (collected from YSI meter) will be collected at this site. Site NH1.7SCTA (Sandy Cr. Tributary at IvyCreek Blvd.), which was also sampled in 2017, has also been the subject of an extensive investigation (17WQ105) based on ambient monitoring results. This site will be monitored quarterly for field parameters (DO, pH, SC, temperature, turbidity), but this sampling will be completed during site visits for another study (Sandy Creek Watershed Characterization) and results will be warehoused with ambient monitoring results. In 2018 EL7.1EC (Ellerbe Cr. at Club Blvd. and Acadia St.) will replace EL7.9EC (Ellerbe Cr. at Murray Ave.) as a nutrient loading site. Analysis on data collected from both sites in the previous year (2017) will be run to retroactively determine comparability of nutrient concentrations between the two sites. TF3.4TC (Third Fork Cr. at PWOC) will be added as a nutrient loading site due to the recent installation of new USGS rain and stream gages (Site ID: 0209725960) at this site. Starting in 2018 this site will be sampled every year. The Nutrient Loading site at TFO.OTC (Third Fork Cr. at Hwy 751) will be moved closer to the actual location of the USGS gage (Site ID: 02097280). The site is now located on Woodcroft Rd. and has been renamed TFI.OTC. This new location will be sampled every year. All other sites remained the same from 2016. For the complete 2018 list of sites, their locations, and associated lab numbers along with the duplicate and field blank schedule please see Appendix 3. Benthic Monitoring The benthic monitoring sites will primarily remain the same as in 2016. However, there will be some later consideration into not sampling at NEO.ONE this year. Additional discussions on changes to the benthic sampling plan will be held in the future and a separate benthic monitoring sampling plan will be prepared in late winter. Page 2 of 7 Document Prepared 1/8/2018 - CC Appendix 1. 2018 Ambient Planning Meeting — with Notes 2018 Ambient Planning Meeting - with Notes Attendees: Michelle Woolfolk, Jon Baker, Jim Azarelo, Susan Gale, Dave Milkereit, Tom Chapman, Christine Cailleret. Occurred on 11/20/2017 2018 Monitoring Information - All good, no changes ❖ Total proposed sites: 23 (12 Neuse and 11 Cape Fear) ❖ One team (two people) per sampling day unless there is a special circumstance (training, audit, interns, etc.) ❖ Target watersheds sampled on the same day ❖ DOC will not be sampled, TOC only as per memo prepared by Danielle Mir ❖ TOC will be collected for nutrient loading sites in the Neuse watershed (EL7.9EC, EL1.9EC, EN8.9ER, and LL3.4LLC) ❖ Rain catcher's site EL8.5SEC will not be sampled as Rain Catchers sampling has finished. ❖ Rain catcher's site TF5.6TC will be sampled as it is a regularly sampled even year site. ❖ QA/QC samples will remain the same: o One field blank per sample day o One duplicate per sample day o One TOC field blank per day o One TOC duplicate per month Questions/Discussion: ❖ New proposed schedule: 3 sampling days per month on the 15Y, 2"d, and 3rd Tuesday of every month. o Need approval from SDWRF ■ SDWRF Staff schedules their vacations around our sampling schedule. o Be cautious of TOC hold times — 28 days o Move what was normally Day 3 to Day 2 and vice versa o Prep days may be shifted to the end of the month - Get confirmation from James Blake that this is okay with the lab and its employees. If not okay with them go back to "standard" scheduling. -UPDATE as of 11/25/2017 James Blake and Lab staff have approved the new schedule - new schedule will begin in January 2018. Page 3 of 7 Document Prepared 1/8/2018 - CC ❖ Any changes to the parameters we sample? o Why do we analyze total and dissolved copper? Can we drop total copper? Lots of reasons, keep o Add something else? Lead, magnesium, manganese, fluoride? - Michelle asked for total Zinc to be added to the Cape Fear sites. We decided to add total Zinc to ALL sites to keep everything consistent as it does not call for any extra bottles or time spent at each site (we already collect a total metals bottle). -No other parameters will be added this year, but MW asked for fluoride to be revisited in 2019 as that may be a useful parameter for the Ellerbe sites (higher number of issues with water lines leaking/breaking). ❖ This sampling year (2017) we added EL7.1EC (closer to the USGS gage on Club and Acadia) to compare it to EL7.9EC (Murry Ave). Do we start sampling EL7.9EC and switch after analysis? Or do we start with both and drop one after analysis? - Switch to EL7.1EC (do not sample EL7.9EC in 2018). Run the analysis and use to retroactively determine what type of data we were possibly getting. - Consider sampling both EL7.1EC and EL7.9EC in 2019 in order to give us more than 12 data points of the two sites together. ❖ Notes from 2016 say to re-evaluate sampling at EN4.9ER (Penny's Bend) in 2018. UNRBA is sampling there 2014-2018. Do we add it back this year? Was last sampled in 2014. o It would have to go on Day 1 if added. - Do not sample in 2018, pick back up in 2020 when the UNRBA study has finished. ❖ LL2.3LLUT was previously a fecal only site dropped in 2016; any need to add it back? o If added back would have to go on Day 2 - Do not add it back for 2018, but revisit for 2020 looking at IDDE in that area. ❖ Should we add a Flat River site (FR13.OFR or FR5.2FR); they were last sampled in 2010 and 2007? o Makes the most sense to sample Flat River on Day 1 if added. May have to drop a site in order to add it due to travel time. - Do not add any FR sites, UNRBA samples it ❖ Add EL8.6SECUT (Foster & Hunt) for ongoing Zinc issue? o Would have to go on Day 1 - Yes, but only sample field parameters (meter readings) and Zinc (total and dissolved). Consider sampling it every year as it has constant issues and is a very public location. ❖ Do we need to continue sampling at LC2.ORBC (Kemp Rd)? Are there still ongoing issues with the cattle research farm? - Keep this site, it was added for other issues. It was added to get ambient data in the area before the area was developed to protect the city from getting blamed for issues that were Page 4 of 7 Document Prepared 1/8/2018 - CC already there. Also there are still persistent issues at the farm and the State will occasionally ask us for data at this site. ❖ Do we need to continue to sample NE1.2NE (Chick fil-A site)? Was it added for another reason besides the Mr. Bender issues? - Yes keep it, it was added for additional issues in the area. ❖ Benthic Monitoring questions and suggestions? Same sites as in 2016? o LR9.61-R, EN8.9ER, EN4.9ER, 1-1-3.41-1-C, TFO.OTC, LC1.11-C, NEO.ONE - Consider not sampling bugs at NEO.ONE this year, but keep everything else the same. - Additional discussions should be held to determine if the current procedure is the most useful. Consider sampling certain sites every 4 years instead of every two years. Also look at what other Triassic basin areas are using for methods. Also looks for other was this data can be used. ❖ Other topics discussed in the meeting: o Michelle requested for TFO.OTC to be moved closer to where the USGS gage is on Woodcroft Pkwy. Change the station name and lab ID. The new site will be the Nutrient loading site. o TF3.4TC is requested to become a nutrient loading site as the new USGS gages were installed there this year (2017). This site will now be sampled every year. o NH3.3SC will also have extra quarterly parameters for the Sandy Creek Watershed Study o It was discussed if TPH should be added as a parameter. The group determined TPH would be added to the Sandy Creek Watershed site for the base flow measurements (not storm sampling). Page 5 of 7 Document Prepared 1/8/2018 - CC Appendix 2. 2018 Ambient Water Quality Monitoring Sampling Tables 2018 Ambient Water Quality Monitoring This year a new sampling schedule will be implemented. Sampling will occur on the 1st, 2nd, and 3rd Tuesday of each month. Any variations to the schedule will be due to holidays and/or staff availability. Scheduled Sampling Dates Day 1 Day 2 Day 3 January 2 9 16 February 6 13 20 March 6 13 20 April 3 10 17 May 1 8 15 June 5 12 19 *July 10 17 24 August 7 14 21 September 4 11 18 October 2 9 16 *November 6 7 13 *December 4 5 11 *Sampling days for July, November, and December were adjusted to accommodate the holidays. 10 Sample Sets/Day Day 1 Day 2 Day 3 EL8.6SECUT **LC2.ORBC ***NH3.3SC *EL7.1EC LC1.1LC TF5.6TC *EL1.9EC *LL3.4LLC TF6.5RCUT LR9.6LR LL4.6LLT2 TF5.1RC *EN8.9ER NE2.2NP TF4.4TC EN9.6CRC NE1.2NE TF3.4TC EN10.3WC NEO.ONE TF2.5TCTC EN13.3ER Field Blank TF1.0TC Field Blank Duplicate Field Blank Duplicate Duplicate 10 9 10 * TOC analyzed by Meritech ** Zinc ONLY (Total and Dissolved) Ambient Parameters ***Sandy Creek Additional Parameters (Quarterly: February/May/August/November) Fecal Coliform Metals (Total & Dissolved) Aluminum Nutrients Nitrate + Nitrite N Arsenic Total Kjeldahl N Cadmium Total Ammonia N Chromium Total Phosphorus Iron Lead Manganese Nickel Total Suspended Solids 5-day BOD Total Metals Cations: Calcium Magnesium Sodium Zinc Potassium Copper Anions: Sulfate Field -Filtered Metals Copper Chloride Alkalinity Zinc Hardness (calculated) I DOC Page 6 of 7 Document Prepared 1/8/2018 - CC Appendix 3. 2018 Ambient Site List >____ v z w z w z v z v z v z v z v z v z v z v z v z„°� LLLL,� avv a V a U a V ,� v a V LLLL,�,�LLLLLL vvvvvvv a V a U a V a U a U a U a V G) Y Y Y Y Y Y a C v 2, LL -0 -0 LL LL LL LL W W N N O O w L Y Y z O z z Z H H H H H H F U O U O V OF U W i U N N N N N N N N N N N 9 Z N N N N N N N V1 VI � Vl H F H H H VI H H H H C H H H H H F F C C C C C C C C C C Q C C C C C C C N L W N N 2 Ol N N L N yj N j N Gl N 2 Ol N N G N 5 5 3 3 > > U 3 3 3 3 J JI Z ` J Z I Z Z Z Z ` J Z Z z Z C a Z z Z Z Z Z Z A Z Z V 10 Z 4 f0 VI f0 V1 l0 10 r VI f0 Z VI f0 Vi A V1 10 V1 10 N LL ` .... 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C m J F a z w z w z av, c a vUi U v U z u U V Ci F a J J LD M U l0 M m a V o m J a m N N o a V m w w Z w Ol Z Z eM-I Z Q J W N U U J J J W Z W Z W Z Q a = LL w W W W J lL H H LL Ol M a 00 ^ 01 Ol n nl N W W W 00 c-I c-I c-I M N O M V M N 01 N m M ry rl N .--I .--I '-I N •--I •--I N •--I '-I •--I •--I •--I •--I '-I N N 0 Page 7 of 7 Document Prepared 1/8/2018 - CC