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HomeMy WebLinkAboutI-23_WQSummaryTableSOP_FINAL_2021.07.09_signedTitle: Version Approvals Approved by: Approved by: CITY OF DURHAM City of Durham, North Carolina Department of Public Works Stormwater and GIS Services Water Quality Unit Standard Operating Procedures for the Calendar Year Water Quality Summary Table 1.0 Date: July 9, 2021 Michelle Woolfolk, Water Quality Manager, Stormwater & GIS Services Date: July 9, 2021 Paul Wiebke, Assistant Director for Public Works, Stormwater & GIS Services City of Durham, WQ Unit, Calendar Year Water Quality Summary Table SOP, v. 1.0 Page 1 of 16 07/09/2021 Revision Record Revision Date Updated by Description of change 1.0 July 9, 2021 Jonathan Baker SOP finalized Distribution Current copies of this approved SOP should be provided to the following positions with the City of Durham's Public Works Department, Stormwater and GIS Services Division, Water Quality Unit: • Water Quality Manager • Assistant Water Quality Manager • Senior Environmental Planning and Compliance Analyst • Environmental Planning and Compliance Analyst Abbreviations BOD biochemical oxygen demand CCC Criterion Continuous Concentration Cu Copper CY calendar year DO dissolved oxygen EPA Environmental Protection Agency MS Microsoft NO2+NO3 nitrite + nitrate NCAC North Carolina Administrative Code NPDES National Pollutant Discharge Elimination System SOP Standard Operating Procedures TKN total Kjeldahl nitrogen TN total nitrogen TP total phosphorus WQI Water Quality Index WQU Water Quality Unit Zn Zinc Units cfu colony forming units mg/L milligrams per liter mL milliliter NTU nephelometric turbidity units µg/L micrograms per liter µS/cm micro Siemens per centimeter City of Durham, WQ Unit, Calendar Year Water Quality Summary Table SOP, v. 1.0 Page 2 of 16 07/09/2021 Table of Contents Procedures.................................................................................................................................................... 4 Purposeand scope...................................................................................................................................4 Methodsummary....................................................................................................................................4 Healthand safety warnings......................................................................................................................5 Personnel qualifications and responsibilities...........................................................................................5 Equipmentand supplies...........................................................................................................................6 Data and records management...............................................................................................................6 Methods................................................................................................................................................... 6 Retrieving the Ambient Stream Monitoring Data.................................................................................6 Reviewing the Ambient Stream Monitoring Data................................................................................7 Performing the Summary Calculations.................................................................................................8 Calculation and Data Consistency.........................................................................................................9 Finalizing the CY Water Quality Summary Table................................................................................10 Quality Assurance and Quality Control (QA/QC)........................................................................................10 References..................................................................................................................................................10 Appendix 1. Example of Calendar Year Water Quality Summary Table.....................................................12 Appendix 2. Optional Method for the CY Water Quality Summary Table Template..................................13 Appendix 3. Example of Data Review Notes...............................................................................................16 City of Durham, WQ Unit, Calendar Year Water Quality Summary Table SOP, v. 1.0 Page 3 of 16 07/09/2021 Procedures Purpose and scope The purpose of this Standard Operating Procedure (SOP) is to describe the methods used by the City of Durham's Stormwater and GIS Services Division, Water Quality Unit (WQU) for: • calculating summary statistics for ambient stream monitoring water chemistry results collected during a given calendar year (CY), i.e., January 1 through December 31; and • preparing the CY Water Quality Summary Table, also known as the City of Durham Ambient Stream Sampling Summary of Compliance with Water Quality Standards and Criteria. The CY Water Quality Summary Table provides an overview of water chemistry results at the city's designated ambient stream monitoring sites. The WQU uses a rotating watershed approach for its Ambient Stream Monitoring program with water chemistry monitoring occurring in each watershed every two years. More information about the city's ambient stream monitoring program can be found in the city's Stormwater Management Plan (Durham 2019) and the Standard Operating Procedures for Water Chemistry Sampling (Durham 2020). The CY Water Quality Summary Table is completed each year for the Water Quality Assessment and Monitoring section of the city's NPDES Stormwater Permit Annual Report. The city's NPDES Stormwater Permit Annual Report is posted on the city's website under the Stormwater & GIS Services Division webpage. Data summarized in the CY Water Quality Summary Table are used in reports and infographics to inform the public about the general health of Durham's streams. Method summary In 2011, the WQU implemented the rotating -watershed approach to monitor streams in the city with a subset of sites monitored each year to calculate pollutant loads (Durham 2019). The rotating -watershed monitoring schedule is shown below in Table 1. The list of sites included in the CY Water Quality Summary Table varies from year to year due to the rotating monitoring schedule. Monitoring sites may also be added to or removed from the rotating monitoring schedule by WQU staff as part of the annual review process for the Ambient Stream Monitoring Program. Table 1. Rotating Monitoring Schedule Neuse River Basin Watersheds Cape Fear River Basin Watersheds Odd Years Ellerbe Creek Crooked Creek Panther Creek Little Creek Stirrup Iron Creek New Hope Creek Even Years Eno River Northeast Creek Lick Creek Third Fork Creek Little Lick Creek Little River The Ambient Stream Monitoring Program assesses water chemistry, aquatic macroinvertebrate communities, and hydrology in Durham's streams. The ambient water chemistry portion of the City of Durham, WQ Unit, Calendar Year Water Quality Summary Table SOP, v. 1.0 Page 4 of 16 07/09/2021 monitoring program focuses on surface water quality. WQU monitoring staff collect surface water grab samples for laboratory analysis and in -situ field measurements every month. Data from this sampling are then summarized annually in the CY Water Quality Summary Table. The WQU has prepared the CY Water Quality Summary Table each year since 2004. An example of the CY Water Quality Summary Table is shown in Appendix 1. The CY Water Quality Summary Table includes the following information and calculations that are based on monitoring results for each stream site sampled during the calendar year: • river basin name • downstream reservoir name • major stream name • site ID for the monitoring location • number of samples collected during the CY • average Water Quality Index (WQI) for the CY • geometric mean of fecal coliform concentration results for the CY • percent of fecal coliform concentration results greater than 400 cfu/100mL for the CY • percent of dissolved oxygen (DO) concentration results less than 4.0 mg/L for the CY • average dissolved oxygen concentration for the CY • average biochemical oxygen demand (BOD) concentration for the CY • average total nitrogen (TN) concentration for the CY • average total phosphorus (TP) concentration for the CY • percent of dissolved copper (Cu) concentration results greater than the Environmental Protection Agency's (EPA) Criterion Continuous Concentration (CCC) for Cu for the CY • percent of dissolved zinc (Zn) concentration results greater than the EPA's CCC for Zn for the CY • average turbidity results for the CY • percent of turbidity results greater than 50 nephelometric turbidity units (NTU) for the CY • average conductivity concentration for the CY Health and safety warnings There is no fieldwork associated with this SOP. The procedures outlined in this document are conducted in an office setting. All City of Durham office safety policies and guidelines should be followed when carrying out the procedures in this document. Personnel qualifications and responsibilities Staff members developing the CY Water Quality Summary Table should have knowledge of water quality standards, univariate statistics, and basic programming functions. The Senior Environmental Planning and Compliance Analyst is responsible for following these standard procedures to complete the CY Water Quality Summary Table annually; the Environmental Planning and Compliance Analyst may also contribute to the completion of this table, as appropriate. If the Senior Environmental Planning and Compliance Analyst position is vacant, then the responsibility to complete the CY Water Quality Summary Table will shift to the Assistant Water Quality Manager. This manual will be reviewed regularly City of Durham, WQ Unit, Calendar Year Water Quality Summary Table SOP, v. 1.0 Page 5 of 16 07/09/2021 and revised as necessary. It will be the responsibility of the Senior Environmental Planning and Compliance Analyst to maintain a current version of this SOP in the unit records. Equipment and supplies A City -assigned computer or laptop with a connection to the internet and the city's server is required to perform these standard operating procedures. An internet browser is used to access the Water Quality Unit's online data portal. A current version of MS Excel and Adobe Acrobat may be used to create the CY Water Quality Summary Table. Data and records management The CY Water Quality Summary Table may be created using MS Excel software. The final versions of the CY Water Quality Summary Tables are saved as Adobe Acrobat PDF files and stored on the Public Works Department server. The server folder path for the CY Water Quality Summary Table files and templates can be found in the document titled File and Folder References for the CY Water Quality Summary Table SOP. The CY Water Quality Summary Table files should have the following naming convention: "YYYY Stream Ambient Summary DDMmmYYYY", e.g., 2018 Stream Ambient Summary 28Feb2019. "YYYY" is the four - digit calendar year that represents when the water quality data was collected and "DDMmmYYYY" signifies the date, i.e., two -digit day, three -letter month, and four -digit year) when the file was finalized. The PDF file is given the same file name as the corresponding MS Excel file. Methods The following sections describe the sequential order and procedures for: 1. retrieving ambient stream monitoring data from the Water Quality Unit's online data portal; 2. reviewing the ambient stream monitoring data for duplicate values, nondetects, missing values, and errors; 3. preparing the data and completing summary calculations; and 4. preparing the final summary table MS Excel or other data processing computer programs may be used to organize, review, and summarize the ambient stream monitoring data. Refer to Appendix 2 for an optional method to set up the CY Water Quality Summary Table using MS Excel templates. Retrieving the Ambient Stream Monitoring Data The WQU stores all ambient stream monitoring data in an online data portal. Refer to the SOP for the Use of the Water Quality Web Portal (Durham 2018) for instructions on how to access and use the online data portal. Retrieve and download data for all ambient stream monitoring sites for the desired calendar year. Download the data for the following parameters: a. Biochemical oxygen demand (mg/L) b. Conductivity (µS/cm) c. Dissolved copper (µg/L) City of Durham, WQ Unit, Calendar Year Water Quality Summary Table SOP, v. 1.0 Page 6 of 16 07/09/2021 d. Dissolved copper criterion continuous concentration (µg/L) e. Dissolved oxygen (mg/L) f. Dissolved zinc (µg/L) g. Dissolved zinc criterion continuous concentration (µg/L) h. Fecal coliform (cfu/100mL) i. Hardness (mg/L) j. Nitrate + nitrite as N (mg/L) k. Total Kjeldahl nitrogen (mg/L) I. Total phosphorus (mg/L) m. Turbidity (NTU) n. Water Quality Index The data that are downloaded from the Water Quality Unit's online data portal to create the CY Water Quality Summary Table are referred to in this SOP as the Water Quality Summary Table dataset. Reviewing the Ambient Stream Monitoring Data Following the retrieval of the Water Quality Summary Table dataset, the data should be reviewed for suitability to include in the CY Water Quality Summary Table. Data retrieved should be reviewed for quality issues. These issues include but are not limited to duplicate values, erroneous values, missing values, and nondetect values. Nondetects, also known as left -censored values, are values with a "U" data qualifier. A nondetect value is a value less than the laboratory method detection limit. In other words, left -censored means the actual concentration of a sample is below the method detection limit but it is unknown by how much. Data with a "J7" qualifier indicates that blank sample contamination is evident and the value may not be accurate; however, data values with a "J7" qualifier are included in the Water Quality Summary Table dataset. Refer to the City of Durham Standard Operating Procedures for Use of the Water Quality Web Portal for data qualifier definitions and data quality assurance guidelines (Durham 2018). It should be noted that the following procedures are automatically performed in the Water Quality Unit's online data portal to create the Water Quality Index Report: a. values from duplicate samples are averaged; and b. a value is halved if it is a nondetect value (i.e., the data qualifier is "U") and averaged among duplicates. Steps to review the Water Quality Summary Table dataset include: 1. Review the list of sites monitored during the calendar year and compare them with the site names that appear in the Water Quality Summary Table dataset. 2. Remove data for monitoring sites that are only sampled for field parameters (i.e., dissolved oxygen, conductivity, pH, water temperature, and turbidity). 3. Review all null values in the Water Quality Summary Table dataset. Values may be missing due to errors with field sheets, chain of custody forms, lab reports, or online data portal uploads. There may be missing values in the Water Quality Summary Table dataset because samples City of Durham, WQ Unit, Calendar Year Water Quality Summary Table SOP, v. 1.0 Page 7 of 16 07/09/2021 were not collected at a monitoring site due to extreme weather, such as drought, flooding, or ice conditions. When a missing value is identified, it is important to check the paper and electronic documents that are associated with the data that are uploaded to the online data portal by WQU staff. Values may also be omitted from the Water Quality Summary Table dataset when they are rejected in the online data portal due to blank sample contamination or other data quality issues. If a result is omitted or missing in the Water Quality Summary Table dataset for a given monitoring date, then the monthly WQI will not be calculated for the respective monitoring date. Although the monthly WQI may not be calculated for a monitoring site when a sample result is missing, the annual WQI for the monitoring site will be calculated. 4. Review hardness values in the Water Quality Summary Table dataset. Hardness values are not included in the CY Water Quality Summary Table; however, hardness values are used in the equation for the EPA's CCC for dissolved Cu and dissolved Zn. It is important to review the hardness data because a missing value will result in null values for Cu CCC, Zn CCC, and the WQI score. Hardness values may be missing because the required calculations have not been performed and the values have not been uploaded to the online data portal. Typically, hardness value calculations have been performed by the laboratory providing the water chemistry data. Communicate with the Environmental Planning & Compliance Analyst in charge of the Monitoring & Assessment Program regarding any missing values or questions about the data downloaded from the Water Quality Unit's online data portal. After any corrections are made to the data in the Water Quality Unit's online data portal, download and review the corrected data. Record notes about missing values, rejected values, and other data issues to convey reasons for missing data, decisions regarding data corrections, and other data handling assumptions. Recording these notes will be helpful to staff that are responsible for reviewing the CY Water Quality Summary Table for errors, omissions, final calculations, and other quality control purposes. An example of data review notes is provided in Appendix 3. Performing the Summary Calculations Following the review of the Water Quality Summary Table dataset, perform the calculations to produce the results that are entered into the finalized CY Water Quality Summary Table. These calculations are listed below. In steps 4-11, the monitoring data are compared to State or Federal water quality standards. For example, the State's water quality standard for turbidity is 50 NTU (15A NCAC 02B.0211(21)). If a turbidity result is less than 50 NTU, then it is meeting the water quality standard. The calculation steps include: 1. Calculate total nitrogen for each monitoring event by adding the NO2+NO3 concentration and the TKN concentration. Do not calculate the TN concentration for a monitoring event when the NO2+NO3 concentration value or the TKN concentration value is rejected or missing. 2. Calculate annual averages for the following parameters at each monitoring site: a. Water Quality Index b. Dissolved oxygen (mg/L) c. Biochemical oxygen demand (mg/L) d. Total nitrogen (mg/L) City of Durham, WQ Unit, Calendar Year Water Quality Summary Table SOP, v. 1.0 Page 8 of 16 07/09/2021 e. Total phosphorus (mg/L) f. Turbidity (NTU) g. Conductivity (µS/cm) 3. Calculate the annual geometric mean for fecal coliform at each monitoring site. 4. Calculate the percent of fecal coliform samples greater than 400 cfu/100mL at each monitoring site. The formula is the number of fecal coliform sampling results greater than 400 cfu/100mL at a monitoring site divided by the total number of sampling events at the corresponding monitoring site. 5. Calculate the percent of dissolved oxygen samples less than 4 mg/L at each monitoring site. The formula is the number of dissolved oxygen sampling results less than 4 mg/L at a monitoring site divided by the total number of sampling events at the corresponding monitoring site. 6. Calculate the difference between Cu CCC and dissolved Cu for each monitoring event. The results are used in the calculation of the percent of Cu samples greater than the EPA's CCC. 7. Calculate the percent of dissolved Cu samples greater than the EPA CCC at each monitoring site. The formula is the number of dissolved Cu sampling results greater than the EPA CCC for Cu at a monitoring site (calculated in step 6) divided by the total number of sampling events at the corresponding monitoring site. 8. Calculate the difference between Zn CCC and dissolved Zn. The results are used in the calculation of the percent of Zn samples greater than the EPA's CCC. 9. Calculate the percent of dissolved Zn samples greater than the EPA CCC at each monitoring site. The formula is the number of dissolved Zn sampling results greater than the EPA CCC for Zn at a monitoring site (calculated in step 8) divided by the total number of sampling events at the corresponding monitoring site. 10. Calculate the percent of turbidity samples greater than 50 NTU at each monitoring site. The formula is the number of turbidity sampling results greater than 50 NTU at a monitoring site divided by the total number of sampling events at the corresponding monitoring site. 11. Enter all calculation results into the CY Water Quality Summary Table using the format shown in Appendix 1. Calculation and Data Consistency When finalizing the summary calculations, the following rules are applied to the data presented in the CY Water Quality Summary Table: 1. Round BOD and DO values to the tenths decimal place. 2. Round TN and TP to the hundredths decimal place. 3. Round all other values to the ones place value using normal rounding rules, except for parameters that have one or two decimal places (i.e. BOD, DO, TN, and TP). For example, if a fecal coliform geometric mean value is 1,010.764 cfu/100mL, then round the value to 1,011 cfu/100m L. 4. Round the average WQI value up to the next whole number regardless of normal rounding rules (e.g. 78.2 is rounded to 79, 78.6 is rounded to 79). City of Durham, WQ Unit, Calendar Year Water Quality Summary Table SOP, v. 1.0 Page 9 of 16 07/09/2021 Finalizing the CY Water Quality Summary Table The CY Water Quality Summary Table should be formatted consistently from year to year. The general layout and formatting for the finalized CY Water Quality Summary Table should be consistent with the example shown in Appendix 1. Consistent formatting also includes making values bold that meet certain criteria. All results in the CY Water Quality Summary Table that meet the following criteria should be shown in bold font: a. all percentages greater than 10%; b. all fecal coliform concentrations greater than 400 cfu/100mL; c. all TN concentrations greater than 1.60 mg/L; d. all TP concentrations greater than 0.10 mg/L; and e. all turbidity concentrations greater than 50 NTU. The criteria listed above for TN and TP are based on best professional judgment. The analyst may use best professional judgment and published references to adjust the criteria listed for TN and TP. Following the formatting steps listed above, convert a copy of the finalized CY Water Quality Summary Table into a PDF file and save the file in the designated folder path listed in the File and Folder References for the CY Water Quality Summary Table SOP document. The PDF file name should be consistent with the same file naming convention as the CY Water Quality Summary Table Excel file, which is "YYYY Stream Ambient Summary DDMmmYYYY" (e.g., 2018 Stream Ambient Summary 28Feb2019). "YYYY" is the four -digit calendar year that represents when the water quality data was collected and "DDMmmYYYY" signifies the date (i.e., two -digit day, three -letter month, and four -digit year) when the file was finalized. Quality Assurance and Quality Control (QA/QC) Although data uploaded to the Water Quality Unit's online data portal are reviewed and checked by WQU staff, it is important to conduct a thorough review of the Water Quality Summary Table dataset after it has been downloaded from the online data portal. The Senior Environmental Planning and Compliance Analyst is responsible for reviewing all data, formulas, and formatting in the CY Water Quality Summary Table. The Assistant Water Quality Manager and the Water Quality Manager may review the draft and final versions of the CY Water Quality Summary Table for accuracy and completeness. References City of Durham (Durham). 2018. City of Durham Water Standard Operating Procedures for Use of the Water Quality Web Portal, version 1.0. Public Works Department, Stormwater & GIS Services Division, Water Quality Unit. DRAFT. City of Durham, WQ Unit, Calendar Year Water Quality Summary Table SOP, v. 1.0 Page 10 of 16 07/09/2021 City of Durham (Durham). 2019. City of Durham Stormwater Management Plan. Public Works Department, Stormwater & GIS Services Division. Revised January 2019. City of Durham (Durham). 2020. City of Durham Standard Operating Procedures for Water Chemistry Sampling, version 1.0. Public Works Department, Stormwater & GIS Services Division, Water Quality Unit. December 23, 2020. Title 15A, Chapter 0213, Section .0211 of the North Carolina Administrative Code. Fresh Surface Water Quality Standards for Class C Waters. 15A NCAC 026.0211. Amended Eff. January 1, 2015. City of Durham, WQ Unit, Calendar Year Water Quality Summary Table SOP, v. 1.0 Page 11 of 16 07/09/2021 Appendix 1. Example of Calendar Year Water Quality Summary Table 2018 CITY OF DURHAM AMBIENT STREAM SAMPLING SUMMARY OF COMPLIANCE WITH WATER QUALITY STANDARDS AND CRITERIA Parameters of concern shown in Bold Fecal Coliform (FC) Dissolved Oxygen (DO) Nutrients Dissolve d Metals Turbidity m Percent of FC Average Average Percentof Percentof m'o a GeoMean samples Percentof Average Average Total Total Cu Zn Average Percentof Average v a Avg FC >400 DO Samples DO BOD Nitrogen Phosphorus samples> samples> Turbidity Samples> Conductivity ii cr Major Stream Site ID # WQI (cfu/100mL) cfu/100mL c4.Omg/L (mg/L) [mg/L] (mg/L) (mg/L) EPA CCC EPACCC (NTU( SONTU (15/cm) Little River LR9.6LR 12 89 146 25% 0% 10.0 1.4 0.70 0.08 89/6 0% 15 0% 90 Eno River EN8.9ER 12 89 105 17% 0% 9.5 1.3 0.76 0.07 8% 0% 16 8% 108 s Eno River EN13.3ER 12 90 92 17% 0% 9.1 1.3 0.61 0.05 8% 0% 13 0% 113 Crooked Creek EN9.6CRC 12 90 205 259Yo 0% 9.8 1.7 0.62 0.04 0% 0% 8 0% 147 m Y Warren Creek EN10.3WC 12 80 281 42% 8% 7.4 1.3 0.85 0.10 8% 0% 21 8% 197 y Ellerbe Creek EL1.9EC 12 83 225 42% 0% 8.4 1.2 1.85 0.11 0% 0% 9 0% 397 rx m � Ellerbe Creek EL7_1EC 12 89 110 33% 0% 8.2 1.3 0.61 0.13 17% 0% 9 0% 202 'm = Little Lick Creek LL3.4LLC 12 70 1011 67% 17% 7.3 1.2 0.79 0.16 33% 0% 37 33% 184 z Little Lick Creek LL4.6LLT2 12 73 1307 58% 0% 11.8 1.3 0.71 0.28 0% 0% 127 50% 266 Lick Creek LC1.1LC 11 75 813 7335 9% 8.0 1.4 0.75 0.35 0% 0% 76 45% 173 Rocky Branch LC2.0RBC 11 79 464 45% 27% 7.7 1.2 0.71 0.07 0% 0% 17 0% 236 Sandy Creek NH3.3SC 12 71 1283 75% (1% 8.1 1.9 1.31 0.16 17% 0% 42 25% 240 Third Fork Creek TFI.OTC 12 71 1293 83% 0% 7.9 1.2 0.96 0.23 17% 0% 51 25% 229 = s a Third Fork Creek TF2.5TCTC 12 68 3023 83% 0% 8.8 1.2 1.54 0.20 17% 0% 25 17% 225 ca = Third Fork Creek TF3.4TC 12 68 2136 100% 0% 7.4 1.3 1.20 0.20 0% 0% 45 25% 256 `m a Third Fork Creek TF4.4TC 12 65 2960 92% 0% 7.9 1.8 1.18 0.22 17% 0% 43 33% 306 °C Third Fork Creek TF5.6TC 12 69 2813 92% 8% 7.3 1.1 1.1b 0.13 8% 0% 18 8% 283 m Rock Creek TF5.1RC 12 61 5370 100% 17% 7.1 1.3 1.04 0.21 25% 0% 34 17% 301 aa Rock Creek TF6.5RCUT 12 55 2232 83% 25% 5.7 6.9 1.32 0.18 896 0% 13 0% 432 Northeast Creek NE0.0NE 11 68 674 64% 18% 6.3 1.6 0.80 0.19 36% 0% 75 55% 190 Northeast Creek NE1.2NE 12 68 616 50Yo 25% 6.0 2.0 0.77 0.20 42% 0% 81 67% 187 North Prong NE2.2NP 12 67 702 58% 33% 5.9 1.7 0.76 0.15 0% 0% 74 42% 162 City of Durham, WQ Unit, Calendar Year Water Quality Summary Table SOP, v. 1.0 Page 12 of 16 07/09/2021 Appendix 2. Optional Method for the CY Water Quality Summary Table Template Template Structure To keep the MS Excel workbook structure consistent, two workbook template files have been created to assist with setting up the Excel worksheets. The template file for even -numbered years is labeled as "CY Water Quality Summary Table —EVEN YEAR TEMPLATE.xlsx" and the template file for odd -numbered years is labeled as "CY Water Quality Summary Table —ODD YEAR TEMPLATE.xlsx". The workbook templates are stored on the Public Works Department's server, and the folder paths can be found in the document titled File and Folder References for the CY Water Summary Table SOP. The workbook templates contain the following worksheets, which may be modified as needed: 1. Info — this worksheet is used to describe the name, content, and creation date of each worksheet. 2. Formatted Summary —this worksheet stores the water quality summary table with specific formatting that is converted into the final PDF version. 3. WQIReport— this worksheet contains the Water Quality Index Report data that are downloaded from the Water Quality Unit's online data portal. 4. Conductivity —this worksheet contains the conductivity concentration data that are downloaded from the Water Quality Unit's online data portal. 5. SummaryCalc — this worksheet contains the data copied over from the WQIReport worksheet and the Conductivity worksheet. The summary calculations for each parameter can be performed in this worksheet. 6. MonitoringSites — this worksheet contains the ambient stream monitoring sites for the corresponding calendar year. 7. Notes — this worksheet contains the analyst's notes concerning missing values, rejected values, and other data issues to convey decisions regarding data corrections and data handling assumptions. Methods Creating the MS Excel Workbook File for the CY Water Quality Summary Table 1. Navigate to the CY Water Quality Summary Table template files on the Public Works Department's server. The folder path for the template files can be found in the document titled File and Folder References for the CY Water Quality Summary Table SOP. 2. If you are summarizing data for an even -numbered year, e.g., 2018, open the template file named "CY Water Quality Summary Table —EVEN YEAR TEMPLATE". Conversely, if you are summarizing data for an odd -numbered year, e.g., 2019, open the template file named "CY Water Quality Summary Table —ODD YEAR TEMPLATE". City of Durham, WQ Unit, Calendar Year Water Quality Summary Table SOP, v. 1.0 Page 13 of 16 07/09/2021 3. After opening the preferred workbook template, save the file as a new document and rename the file using the file naming convention described in the Standard Operating Procedures for the Calendar Year Water Quality Summary Table. 4. There are cells on the "Info" worksheet and the "Formatted Summary" worksheet with prompts in brackets, i.e., [INSERT DATE]. Replace the bracketed text with the appropriate information, e.g., four -digit calendar year, to update the worksheets. 5. Data downloaded from the Water Quality Unit's online data portal can be copied and pasted into the "WQIReport" worksheet and the "Conductivity" worksheet. Reviewing the Ambient Stream Monitoring Data 1. The data review is performed in the "SummaryCalc" worksheet since the raw data are preserved in the "WQIReport" worksheet and the "Conductivity" worksheet. 2. Add the ambient stream monitoring site list to the "MonitoringSites" worksheet. Compare the monitoring site list to the sites shown on the "Formatted Summary" worksheet and the "SummaryCalc" worksheet. Add or remove monitoring sites as necessary to ensure that the monitoring sites on the "Formatted Summary" and "SummaryCalc" worksheets agree with the calendar year monitoring site list on the "MonitoringSites" worksheet. 3. Perform the data review steps described in the Standard Operating Procedures for the Calendar Year Water Quality Summary Table. 4. Record notes about missing values, rejected values, and other data issues in text boxes at the top of the "Notes" worksheet to convey reasons for missing data, decisions regarding data corrections, and other data handling assumptions. Performing the Summary Calculations 1. All summary calculations are performed on the "SummaryCalc" worksheet. 2. Copy the data on the "wgiReport" worksheet, excluding the data column headings, and paste the data below the corresponding data column headings on the "SummaryCalc" worksheet. 3. There are four additional columns on the "SummaryCalc" worksheet for the following parameters: Conductivity (µS/cm), Copper CCC minus Copper (µg/L), Zinc CCC minus Zinc (µg/L), and Total Nitrogen (mg/L). These columns have been added to the "SummaryCalc" worksheets on the even -numbered year and the odd -numbered year workbook templates 4. Copy and paste the conductivity values on the "Conductivity" worksheet to the "Conductivity" column on the "SummaryCalc" worksheet and ensure that monitoring station names and monitoring dates match. 5. Perform all calculations described in the Standard Operating Procedures for the Calendar Year Water Quality Summary Table. 6. Enter the results of the summary calculations into the corresponding cells of the draft CY Water Quality Summary Table which is located at the top of the "SummaryCalc" worksheet. Finalizing the CY Water Quality Summary Table 1. In the draft CY Water Quality Summary Table at the top of the "SummaryCalc" worksheet, change cells to bold formatting that meet the following criteria: City of Durham, WQ Unit, Calendar Year Water Quality Summary Table SOP, v. 1.0 Page 14 of 16 07/09/2021 a. all percentages greater than 10%; b. all fecal coliform concentrations greater than 400 cfu/100mL; c. all TN concentrations greater than 1.60 mg/L; d. all TP concentrations greater than 0.1 mg/L; and e. all turbidity concentrations greater than 50 NTU. 2. Copy all values in the draft summary table at the top of the "SummaryCalc" worksheet and paste as values with formatting into the "Formatted Summary" worksheet. 3. Convert a copy of the "Formatted Summary" worksheet into a PDF file and save the file in the designated folder path listed in the File and Folder References for the CY Water Quality Summary Table SOP document. The PDF file name should be consistent with the file naming convention described in the Standard Operating Procedures for the Calendar Year Water Quality Summary Table. City of Durham, WQ Unit, Calendar Year Water Quality Summary Table SOP, v. 1.0 Page 15 of 16 07/09/2021 Appendix 3. Example of Data Review Notes Notes: 1) EL8.6SECUT was removed from the summary table because it was only monitored for field parameters and total/dissolved Zinc (See the 2018Sites worksheet). NH1.7SCTA was removed from the summary table because it was only monitored for field parameters in February, June, August, and November. 2) The WQI was calculated 7 out of 12 months for NH3.3SC due to several results missing from that site in April, May, August, November, and December. NH3.3SC was missing TKN and TP results in December and hardness calculations for May, August, and November. Hardness, TKN, and TP results for NH3.3SC were calculated/uploaded by S. Gale on 2/26/2019. Similar results were missing in December for all monitoring sites on Day 3. Upon further review of the December data, the date for the field measurements (12/11/2018) did not match up with the date for the lab results (12/12/2018). The date was incorrectly recorded as 12/12/2018 on the lab COC forms. S. Gale was aware of this issue in the web portal and made corrections on 2/26/2019. 3) There are no BOD values for sites monitored on 4/17/2018 (Day 3, Sandy Creek and Third Fork Creek sites) because the results were rejected due to blank contamination. Therefore, the WQI could not be calculated for all sites monitored on 4/17/2018 except site TF5.6TC. Site TF5.6TC had a non -detect value (<2.Omg/L, 'U' QCode) for BOD and was not rejected based on current web portal data QC protocols. After discussion with S. Gale and J.V. Loperfido, the decision was made to keep the value for TF5.6TC (1mg/L - for WQI Report calculations, the value is halved if QCode is'U') and include it the summary table calculations. 4) LC1.1LC and NEO.ONE were not able to be sampled in January due to thick ice covering the water surface. LC2.0RBC was not sampled in July due to disconnected pools of water in the channel and no streamflow. City of Durham, WQ Unit, Calendar Year Water Quality Summary Table SOP, v. 1.0 Page 16 of 16 07/09/2021