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NC0007064_Renewal (Application)_20220531
ST a:p (-Ill) ROY COOPER 0 i , 7 - , Governor ELIZABETH S.BISER ��` Secretary rs5,Quwm f,4~ RICHARD E.ROGERS,JR. NORTH CAROLINA Director Environmental Quality May 31, 2022 Duke Energy Progress, LLC Attn: Jay Ratliff, Plant Manager 8470 River Road SE Southport, NC 28461 Subject: Permit Renewal Application No. NC0007064 Brunswick Steam Electric Plant Brunswick County Dear Applicant: The Water Quality Permitting Section acknowledges the May 31, 2022 receipt of your permit renewal application and supporting documentation. Your application will be assigned to a permit writer within the Section's NPDES WW permitting branch. Per G.S. 150B-3 your current permit does not expire until permit decision on the application is made. Continuation of the current permit is contingent on timely and sufficient application for renewal of the current permit. The permit writer will contact you if additional information is required to complete your permit renewal. Please respond in a timely manner to requests for additional information necessary to allow a complete review of the application and renewal of the permit. Information regarding the status of your renewal application can be found online using the Department of Environmental Quality's Environmental Application Tracker at: https://deq.nc.gov/permits-reg ulations/permit-guidance/environmental-application-tracker If you have any additional questions about the permit, please contact the primary reviewer of the application using the links available within the Application Tracker. Sincerel 1 041i4t) Wren Thedford Administrative Assistant Water Quality Permitting Section ec: WQPS Laserfiche File w/application E Q+v North Carolina Department of Environmental Quality Division of Water Resources `►S�J�/ Wilmington Regional Office 127 Cardinal Drive Extension W'llmington.North Carolina 28405 �.r':ir�i Ui in...MaD /`, 910.796.7215 r - - Brunswick Nuclear Plant f� DUKE 8470 River Road SE ENERGY Southport, NC 28461 MAY 2 31022 RECEIVED nlo4 31 2022 Serial: RA-22-0169 NCDEQ/DWR Mr. Doug Dowden, Supervisor /N,P®ES NPDES Industrial Permitting NC DEQ/DWR/WQ Permitting Section 1617 Mail Service Center Raleigh, NC 27699-1617 Subject: Brunswick Steam Electric Plant, Unit Nos. 1 and 2 National Pollutant Discharge Elimination System NPDES Permit No. NC0007064 Renewal Application Dear Mr. Dowden: The current NPDES permit for the Brunswick Steam Electric Plant expires on November 30, 2022. Duke Energy Progress, LLC hereby requests that the NPDES permit for the facility be reissued. Enclosed are EPA Application Form 1 — General Information and EPA Application Form 2C —Wastewater Discharge Information (one original and two copies). The attached permit application package consists of the following documentation: Enclosure 1 - US EPA Form 1 — General Information Enclosure 2 - US EPA Form 2C — Existing Manufacturing, Commercial, Mining and Silvacultural Operations, including Tables A-E for Outfall 001 (Combined Discharge) and the Water Supply Intake Attachment 1 - Form 1 — Section 6 — Existing Environmental Permits Attachment 2 - Form 1 — Section 7 — Maps Attachment 3 - Form 2C — Section 2 — Line Drawing & Flow Balance Attachment 4 - Form 2C — Section 3 — Outfall Flows, Contributing Operations and Treatment Technologies Attachment 5 - Form 2C — Section 8 — Used or Manufactured Toxics (Potential Discharges Not Covered by Analysis) 316 (b) Cooling Water Intake Structure Rule In accordance with Part I, Condition A(9) of the existing NPDES permit, the Brunswick Steam Electric Plant is in the process of submitting the appropriate reports as required by Cooling Water Intake Structure Rule 40 CFR Part 125.95. Due to the significant volume associated with this submittal, these documents are hereby acknowledged by reference to be part of the permit renewal application package. The documents will be submitted to NC DEQ DWR on or before June 2, 2022. With reissuance of the NPDES permit, Duke Energy Progress, LLC requests the following: i J NC DEQ/DWR/WQ Permitting Section Page 2 of 2 Onsite Sanitary Wastewater Treatment Plant - Outfall 004 Duke Energy Progress, LLC respectfully requests Outfall 004 be removed from NPDES Permit NC0007064. This sanitary plant has been properly decommissioned and previous wastewater flows have been redirected to the upgraded Onsite Sanitary Support Facilities Wastewater Treatment Plant served by Outfall 010. If you have any questions regarding the enclosed information, please contact Mr. Don Safrit, P.E., at (919) 546-6146 or Mr. Drew Petrusic at (910) 832-2728. I certify, under penalty of law, that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations. Sincerely, Jay Ratliff Plant Manager Brunswick Steam Electric Plant Enclosure 1: EPA - Application Form 1 — General Information & Attachments Enclosure 2: EPA - Application Form 2C —Wastewater Discharge Information & Attachments cc: Mr. Thomas Tharrington, Wilmington Regional Office Mr. Drew Petrusic Mr. Don Safrit Duke Energy Progress, LLC Brunswick Steam Electric Plant National Pollutant Discharge Elimination System Permit Number NC0007064 Enclosure 1 US EPA Application Form 1 - General Information EPA Identification Number NPDES Permit Number Facility Name Form Approved 03/05/19 NCD091570960 NC0007064 Brunswick Steam Electric Plant OMB No.2040-0004 Form U.S.Environmental Protection Agency 2C \".EPA Application for NPDES Permit to Discharge Wastewater NPDES EXISTING MANUFACTURING,COMMERCIAL, MINING,AND SILVICULTURE OPERATIONS SECTION 1.OUTFALL LOCATION(40 CFR 122.21(g)(1)) 1.1 Provide information on each of the facility's outfalls in the table below. o Numbelr Receiving Water Name Latitude Longitude .� 0 3 J 001 Atlantic Ocean 33° 53' 35" N 78° 03' 25" W 7 o i n o . ., 0 SECTION 2.LINE DRAWING(40 CFR 122.21(g)(2)) a, 2.1 Have you attached a line drawing to this application that shows the water flow through your facility with a water a .3 balance?(See instructions for drawing requirements.See Exhibit 2C-1 at end of instructions for example.) J o © Yes ❑No (See Attachment 3) SECTION 3.AVERAGE FLOWS AND TREATMENT(40 CFR 122.21(g)(3)) 3.1 For each outfall identified under Item 1.1,provide average flow and treatment information.Add additional sheets if necessary **Outfall Number** All Operations Contributing to Flow Operation Average Flow See Attachment 4 mgd c mgd R mgd N mgd Treatment Units ry) Description Code from Final Disposal of Solid or (include size,flow rate through each treatment unit, Table 2C 1 Liquid Wastes Other Than > retention time,etc.) by Discharge EPA Form 3510-2C(Revised 3-19) Page I EPA Identification Number NPDES Permit Number Facility Name Form Approved 03/05/19 NCD091570960 NC0007064 Brunswick Steam Electric Plant OMB No.2040-0004 3.1 **Outfall Number** cont. Operations Contributing to Flow Operation Average Flow mgd mgd mgd mgd Treatment Units Description Code from Final Disposal of Solid or (include size,flow rate through each treatment unit, Table 2C-1 Liquid Wastes Other Than retention time,etc.) by Discharge d 0 0 m E io aD N **Outfall Number** y Operations Contributing to Flow o Operation Average Flow 1 rn mgd R d mgd mgd mgd Description Code from Final Disposal of Solid or (include size,flow rate through each treatment unit, Table 2C-1 Liquid Wastes Other Than retention time,etc.) by Discharge 3.2 Are you applying for an NPDES permit to operate a privately owned treatment works? E d ❑ Yes ❑� No 4 SKIP to Section 4. co en 3.3 Have you attached a list that identifies each user of the treatment works? ❑ Yes ❑ No EPA Form 3510-2C(Revised 3-19) Page 2 EPA Identification Number NPDES Permit Number Facility Name Form Approved 03/05/19 NCD091570960 NC0007064 Brunswick Steam Electric Plant OMB No.2040 0004 SECTION 4. INTERMITTENT FLOWS(40 CFR 122.21(g)(4)) 4.1 Except for storm runoff,leaks,or spills,are any discharges described in Sections 1 and 3 intermittent or seasonal? ❑✓ Yes ❑ No SKIP to Section 5. 4.2 Provide information on intermittent or seasonal flows for each applicable outfall.Attach additional pages,if necessary. Outfall Operation Frec uency Flow Rate Number (list) Average Average Long-Term Maximum Duration Days/Week Months/Year Average Daily Radwaste days/week months/year 0.020 mgd 0.061 mgd 0.06 days 003 100-125 Releases/Year days/week months/year mgd mgd days days/week months/year mgd mgd days Low Volume days/week months/year 1.2 mgd 1.8 mgd <7 days 5-10 Releases/Year days/week months/year mgd mgd days 005 days/week months/year mgd mgd days Low Volume days/week months/year mgd mgd days 12 Releases/Year days/week months/year 0.61 mgd 2.6 mgd <31 days 011 days/week months/year mgd mgd days SECTION 5.PRODUCTION(40 CFR 122.21(g)(5)) 5.1 Do any effluent limitation guidelines(ELGs)promulgated by EPA under Section 304 of the CWA apply to your facility? ❑✓ Yes ❑ No 4 SKIP to Section 6. 5.2 Provide the following information on applicable ELGs. w ELG Category ELG Subcategory Regulatory Citation d .75 Steam Electric Steam Electric Power Generating 40 CFR Part 423 U •Q _ Q 5.3 Are any of the applicable ELGs expressed in terms of production(or other measure of operation)? cn ❑ Yes ❑✓ No 4' SKIP to Section 6. O 5.4 Provide an actual measure of daily production expressed in terms and units of applicable ELGs. Outfall Operation,Product,or Material Quantity per Day Unit of a Number Measure co � I 0 U - O a` EPA Form 3510-2C(Revised 3-19) Page 3 EPA Identification Number NPDES Permit Number Facility Name Form Approved 03/05/19 NCD091570960 NC0007064 Brunswick Steam Electric Plant OMB No.2040-0004 SECTION 6.IMPROVEMENTS(40 CFR 122.21(g)(6)) 6.1 Are you presently required by any federal,state,or local authority to meet an implementation schedule for constructing, upgrading,or operating wastewater treatment equipment or practices or any other environmental programs that could affect the discharges described in this application? ❑ Yes ❑✓ No 4 SKIP to Item 6.3. 6.2 Briefly identify each applicable project in the table below. Affected Final Compliance Dates Brief Identification and Description of Outfalls Source(s)of Project (list outfall Discharge Required Projected a number) E U 0 -a L 45) 6.3 Have you attached sheets describing any additional water pollution control programs(or other environmental projects that may affect your discharges)that you now have underway or planned?(optional item) ❑ Yes ❑ No ✓❑ Not applicable SECTION 7.EFFLUENT AND INTAKE CHARACTERISTICS(40 CFR 122.21(g)(7)) See the instructions to determine the pollutants and parameters you are required to monitor and,in turn,the tables you must complete.Not all applicants need to complete each table. Table A.Conventional and Non-Conventional Pollutants 7.1 Are you requesting a waiver from your NPDES permitting authority for one or more of the Table A pollutants for any of your outfalls? ❑ Yes 0 No 4 SKIP to Item 7.3. 7.2 If yes,indicate the applicable outfalls below.Attach waiver request and other required information to the application. Outfall Number Outfall Number Outfall Number 7.3 Have you completed monitoring for all Table A pollutants at each of your outfalls for which a waiver has not been requested and attached the results to this application package? t' ❑✓ Yes ❑ No;a waiver has been requested from my NPDES El "Iauthority for all pollutants at all outfalls. 03 e Table B.Toxic Metals,Cyanide,Total Phenols,and Organic Toxic Pollutants 7.4 Do any of the facility's processes that contribute wastewater fall into one or more of the primary industry categories listed in Exhibit 2C-3?(See end of instructions for exhibit.) ❑✓ Yes ❑ No 4 SKIP to Item 7.8. 7.5 Have you checked"Testing Required"for all toxic metals,cyanide,and total phenols in Section 1 of Table B? ;, ❑✓ Yes ❑ No 7.6 List the applicable primary industry categories and check the boxes indicating the required GC/MS fraction(s)identified in Exhibit 2C-3. Primary Industry Category Required GC/MS Fraction(s) (Check applicable boxes.) Steam Electric Power Plants ElVolatile ID Acid 0 Base/Neutral 0 Pesticide ❑Volatile 0 Acid 0 Base/Neutral 0 Pesticide ❑Volatile 0 Acid 0 Base/Neutral 0 Pesticide EPA Form 3510-2C(Revised 3-19) Page 4 EPA Identification Number NPDES Permit Number Facility Name Form Approved 03/05/19 NCD091570960 NC0007064 Brunswick Steam Electric Plant OMB No.2040-0004 7.7 Have you checked"Testing Required"for all required pollutants in Sections 2 through 5 of Table B for each of the GC/MS fractions checked in Item 7.6? ❑✓ Yes ❑ No 7.8 Have you checked"Believed Present"or"Believed Absent"for all pollutants listed in Sections 1 through 5 of Table B where testing is not required'? ❑✓ Yes ❑ No 7.9 Have you provided(1)quantitative data for those Section 1,Table B,pollutants for which you have indicated testing is required or(2)quantitative data or other required information for those Section 1,Table B,pollutants that you have indicated are"Believed Present"in your discharge'? O Yes ❑ No 7.10 Does the applicant qualify for a small business exemption under the criteria specified in the instructions? ❑ Yes 4 Note that you qualify at the top of Table B, 0 No then SKIP to Item 7.12. 7.11 Have you provided(1)quantitative data for those Sections 2 through 5,Table B,pollutants for which you have o determined testing is required or(2)quantitative data or an explanation for those Sections 2 through 5,Table B, U pollutants you have indicated are"Believed Present"in your discharge? ❑✓ Yes 0 No w Table C.Certain Conventional and Non-Conventional Pollutants 2. 7.12 Have you indicated whether pollutants are"Believed Present"or"Believed Absent"for all pollutants listed on Table C for all outfalls? ❑✓ Yes ❑ No t' 7.13 Have you completed Table C by providing(1)quantitative data for those pollutants that are limited either directly or - indirectly in an ELG and/or(2)quantitative data or an explanation for those pollutants for which you have indicated "Believed Present"? N ❑✓ Yes ❑ No w Table D.Certain Hazardous Substances and Asbestos 7.14 Have you indicated whether pollutants are"Believed Present"or"Believed Absent"for all pollutants listed in Table D for all outfalls? ❑✓ Yes ❑ No 7.15 Have you completed Table D by(1)describing the reasons the applicable pollutants are expected to be discharged and(2)by providing quantitative data,if available? ElYes ❑ No Table E.2,3,7,8-Tetrachlorodibenzo-p-Dioxin(2,3,7,8-TCDD) 7.16 Does the facility use or manufacture one or more of the 2,3,7,8-TCDD congeners listed in the instructions,or do you know or have reason to believe that TCDD is or may be present in the effluent? ❑ Yes 4 Complete Table E. ❑✓ No 4 SKIP to Section 8. 7.17 Have you completed Table E by reporting qualitative data for TCDD? ❑✓ Yes ❑ No SECTION 8.USED OR MANUFACTURED TOXICS(40 CFR 122.21(g)(9)) 8.1 Is any pollutant listed in Table B a substance or a component of a substance used or manufactured at your facility as an intermediate or final product or byproduct? ❑✓ Yes ❑ No 4 SKIP to Section 9. ,,, 8.2 List the pollutants below. = F1. See Attachment 5 4. 7. -a 2. 5. 8. U! 3. 6. 9. EPA Form 3510-2C(Revised 3-19) Page 5 EPA Identification Number NPDES Permit Number Facility Name Form Approved 03/05/19 NCD091570960 NC0007064 Brunswick Steam Electric Plant OMB No.2040 0004 SECTION 9.BIOLOGICAL TOXICITY TESTS(40 CFR 122.21(g)(11)) 9.1 Do you have any knowledge or reason to believe that any biological test for acute or chronic toxicity has been made within the last three years on(1)any of your discharges or(2)on a receiving water in relation to your discharge? y ❑ Yes ❑✓ No 4 SKIP to Section 10. 9.2 Identify the tests and their aurposes below. Test(s) Purpose of Test(s) Submitted to NPDES Date Submitted o Permitting Authority? ❑ Yes ❑ No ❑ Yes ❑ No ❑ Yes ❑ No SECTION 10.CONTRACT ANALYSES(40 CFR 122.21(g)(12)) 10.1 Were any of the analyses reported in Section 7 performed by a contract laboratory or consulting firm? ❑✓ Yes ❑ No 4 SKIP to Section 11. 10.2 Provide information for each contract laboratory or consulting firm below. Laboratory Number 1 Laboratory Number 2 Laboratory Number 3 Name of laboratory/firm Environmental Chemists,Inc cu d Laboratory address 6602 Windmill Way, R Wilmington NC 28405 Phone number (910)392-0223 Pollutant(s)analyzed Analytes sampled and analyzed per Section 7. SECTION 11.ADDITIONAL INFORMATION(40 CFR 122.21(g)(13)) 11.1 Has the NPDES permitting authority requested additional information? ❑ Yes ❑✓ No 4 SKIP to Section 12. 0 11.2 List the information requested and attach it to this application. 1. 4. 2. 5. 3. 6. EPA Form 3510-2C(Revised 3-19) Page 6 EPA Identification Number NPDES Permit Number Facility Name Form Approved 03/05/19 NCD091570960 NC0007064 Brunswick Steam Electric Plant OMB No.2040-0004 SECTION 12.CHECKLIST AND CERTIFICATION STATEMENT(40 CFR 122.22(a)and(d)) 12.1 In Column 1 below,mark the sections of Form 2C that you have completed and are submitting with your application. For each section,specify in Column 2 any attachments that you are enclosing to alert the permitting authority. Note that not all applicants are required to complete all sections or provide attachments. Column 1 Column 2 ❑✓ Section 1:Outfall Location ❑ w/attachments ❑✓ Section 2:Line Drawing © w/line drawing* ❑ w/additional attachments Section 3:Average Flows and w/list of each user of Treatment © w/attachments** El privately owned treatment works ❑✓ Section 4: Intermittent Flows ❑ w/attachments ❑✓ Section 5:Production ❑ w/attachments w/optional additional ❑✓ Section 6:Improvements ❑ w/attachments ❑ sheets describing any additional pollution control plans ❑ wl request for a waiver and ❑ w/explanation for identical supporting information outfalls w/small business exemption❑ request w/other attachments❑ N ❑ Section 7:Effluent and Intake ❑✓ w/Table A ❑✓ w/Table B Characteristics 0 ❑✓ w/Table C ❑✓ w/Table D ✓ w/Table E w/analytical results as an c� ❑ ❑ attachment ❑ Section 8:Used or Manufactured © w/attachments (See Attachment 5) Toxics ✓❑ Section 9: Biological Toxicity ❑ w/attachments Tests c) ❑✓ Section 10:Contract Analyses ❑ w/attachments ❑✓ Section 11:Additional Information ❑ w/attachments ❑ Section 12:Checklist and ❑ w/attachments Certification Statement 12.2 Certification Statement 1 certify under penalty of law that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted.Based on my inquiry of the person or persons who manage the system,or those persons directly responsible for gathering the information,the information submitted is,to the best of my knowledge and belief, true, accurate,and complete.1 am aware that there are significant penalties for submitting false information,including the possibility of fine and imprisonment for knowing violations. Name(print or type first and last name) Official title Jay Ratliff Plant Manager Signature Date signed 61Z/ /9()ZZ * See Attachment 3 ** See Attachment 4 EPA Form 3510-2C(Revised 3-19) Page 7 This page intentionally left blank. EPA Identification Number NPDES Permit Number Facility Name Outfall Number Form Approved 03/05/19 NCD091570960 NC0007064 Brunswick Steam Electric Plant 001 OMB No.2040-0004 TABLE A.CONVENTIONAL AND NON CONVENTIONAL POLLUTANTS(40 CFR 122.21(g)(7)(iii))l Effluent Intake Waiver (Optional) Pollutant Requested Units Maximum Maximum Long-Term (if applicable) (specify) Daily Monthly Average Daily Number of Long-Term Number of Discharge Discharge Discharge Analyses Average Value Analyses (required) (if available) (if available) 0 Check here if you have applied to your NPDES permitting authority for a waiver for all of the pollutants listed on this table for the noted outfall. Biochemical oxygen demand Concentration mg/L <2 1 <2 1 1. El(RODS) Mass Chemical oxygen demand Concentration mg/L 892 1 813 1 2' El(COD) Mass Concentration mg/L 5.1 1 5.5 1 3. Total organic carbon(TOC) ❑ Mass Concentration mg/L 12.4 1 21.3 1 4. Total suspended solids(TSS) ❑ Mass Concentration mg/L <2 1 0.5 1 5. Ammonia(as N) 0 Mass 6. Flow 0 Rate MGD 1490 1490 1384 12 1384 12 Temperature(winter) ❑ °C °C 16.7 1 6.6 1 7. Temperature(summer) ❑ °C °C pH(minimum) ❑ Standard units s.u. 7.0 7.0 7.6 52 7.1 1 8. pH(maximum) ❑ Standard units s.u. 8.1 8.1 8.0 52 7.1 1 1 Sampling shall be conducted according to sufficiently sensitive test procedures(i.e.,methods)approved under 40 CFR 136 for the analysis of pollutants or pollutant parameters or required under 40 CFR chapter I,subchapter N or 0.See instructions and 40 CFR 122.21(e)(3). EPA Form 3510-2C(Revised 3-19) Page 9 This page intentionally left blank. EPA Identification Number NPDES Permit Number Facility Name Outfall Number Form Approved 03/05/19 NCD091570960 NC0007064 Brunswick Steam Electric Plant 001 OMB No.2040-0004 TABLE B.TOXIC METALS,CYANIDE,TOTAL PHENOLS,AND ORGANIC TOXIC POLLUTANTS(40 CFR 122.21(g)(7)(v))1 Presence or Absence Intake (check one) Effluent (optional) Pollutant/Parameter Testing Units Long-Term (and CAS Number,if available) Required Believed Believed (specify) Maximum Maximum Average Number Long- Number Present Absent Daily Monthly Daily of Term of Discharge e(required) (if available) Discharge Analyses AverageValue Analyses re uired ) (if available) ri Check here if you qualify as a small business per the instructions to Form 2C and,therefore,do not need to submit quantitative data for any of the organic toxic pollutants in Sections 2 through 5 of this table.Note,however,that you must still indicate in the appropriate column of this table if you believe any of the pollutants listed are present in your discharge. Section 1.Toxic Metals,Cyanide,and Total Phenols 1.1 Antimony,total 0Concentration mg/L <0.010 1 <0.010 1 El 0 (7440-36-0) Mass 1.2 Arsenic,total Concentration mg/L <0.02 1 <0.02 1 (7440-38-2) Mass 1,3 Beryllium,total ✓❑ Concentration mg/L <0.02 1 <0.02 1 El 1:1 (7440-41-7) Mass Cadmium,total Concentration mg/L <0.02 1 <0.02 1 1.4 (7440-43-9) ❑ El Mass 1.5 Chromium,total Concentration mg/L <0.02 1 <0.02 1 El El El (7440-47-3) Mass Nor 1.6 Copper,total Concentration mg/L <0.02 1 <0.02 1 (7440-50-8) Mass Lead,total Concentration mg/L <0.02 1 <0.02 1 1.7 (7439-92-1) El El Mass 1.8 Mercury,total Concentration mg/L <0.0002 1 <0.0002 1 (7439-97-6) Mass 1.9 Nickel,total Concentration mg/L <0.02 1 <0.02 1 (7440-02-0) Mass 1.10 Selenium,total ❑✓ Concentration mg/L <0.02 1 <0.02 1 El El (7782-49-2) Mass 1.11 Silver,total © Concentration mg/L <0.02 1 <0.02 1 2 El(7440-22-4) Mass EPA Form 3510-2C(Revised 3-19) Page 11 EPA Identification Number NPDES Permit Number Facility Name Outfall Number Form Approved 03/05/19 NCD091570960 NC0007064 Brunswick Steam Electric Plant 001 OMB No.2040-0004 TABLE B.TOXIC METALS,CYANIDE,TOTAL PHENOLS,AND ORGANIC TOXIC POLLUTANTS(40 CFR 122.21(g)(7)(v))1 Presence or Absence Intake (check one) Effluent (optional) Pollutant/Parameter Testing Units i Long-Term (and CAS Number,if available) Required Believed Believed (specify) Maximum Maximum Average Number Long- Number Present Absent Daily Monthly Term Daily Discharge Discharge Discharge Analyses Average Analyses (required) (if available) Value (if available) 1.12 Thallium,total O 0 ❑ Concentration mg/L <0.02 1 <0.02 1 (7440-28-0) Mass 1.13 Zinc,total ElConcentration mg/L <0.02 1 <0.02 1 El (7440-66-6) Mass 1.14 Cyanide,total ❑ Concentration mg/L <0.005 1 <0.005 1 (57-12-5) Mass Concentration mg/L <0.005 1 <0.005 1 1.15 Phenols,total ❑✓ 0 ❑✓ Mass Section 2.Organic Toxic Pollutants(GCIMS Fraction—Volatile Compounds) 2.1 Acrolein El ❑ 0 Concentration ug/L <5 1 <5 1 (107-02-8) Mass 2.2 Acrylonitrile ❑ ❑ Concentration ug/L <5 1 <5 1 (107-13-1) Mass 2.3 Benzene ❑ Concentration ug/L <0.5 1 <0.5 1 (71-43-2) Mass 2.4 Bromoform ❑ ❑ Concentration ug/L 21.3 1 <0.5 1 (75-25-2) Mass 2.5 Carbon tetrachloride ❑ Concentration ug/L <0.5 1 <0.5 1 El (56-23-5) Mass 2.6 Chlorobenzene ❑ Concentration ug/L <0.5 1 <0.5 1 (108-90-7) Mass 2.7 Chlorodibromomethane 0 0 0 Concentration ug/L 0.850 1 <0.5 1 (124-48-1) Mass 2.8 Chloroethane ❑ ❑ Concentration ug/L <0.5 1 <0.5 , 1 (75-00-3) Mass EPA Form 3510-2C(Revised 3-19) Page 12 EPA Identification Number NPDES Permit Number Facility Name Outfall Number Form Approved 03/05/19 NCD091570960 NC0007064 Brunswick Steam Electric Plant 001 OMB No.2040-0004 TABLE B.TOXIC METALS,CYANIDE,TOTAL PHENOLS,AND ORGANIC TOXIC POLLUTANTS(40 CFR 122.21(g)(7)(v))1 Presence or Absence Intake (check one) Effluent (optional) Pollutant/Parameter Testing Units Long-Term (and CAS Number,if available) Required Believed Believed (specify) Maximum Maximum Average Number Long- Number Present Absent Daily Monthly Daily of Term of D(required) avalablle) Dharge ischarge Analyses AverageValue Analyses ( q ) (if ) (if available) 2.9 2-chloroethylvinyl ether El ❑ ❑ Concentration ug/L <5.0 1 <5.0 1 (110-75-8) Mass Concentration ug/L <0.5 1 <0.5 1 2.10 Chloroform(67-66-3) 00 0 Mass 2.11 Dichlorobromomethane ❑ 0 ❑ Concentration ug/L <0.5 1 <0.5 1 (75-27-4) Mass 212 11-dichloroethane El ❑ ❑ Concentration ug/L <0.5 1 <0.5 1 (75-34-3) Mass 2.13 12-dichloroethane ❑ 0 ❑ Concentration ug/L <0.5 1 <0.5 1 (107-06-2) Mass 2.14 1,1-dichloroethylene El ❑ ❑ Concentration ug/L <0.5 1 <0.5 1 (75-35-4) Mass 2.15 12-dichloropropane El ❑ ❑ Concentration ug/L <0.5 1 <0.5 1 (78-87-5) Mass 1,3-dichloropropylene 0 Concentration ug/L <0.5 1 <0.5 1 2.16 (542-75-6) 0 ❑ Mass 2.17 Ethylbenzene ❑ ❑ 0 Concentration ug/L <0.5 1 <0.5 1 (100-41-4) Mass 2.18 Methyl bromide ID ❑ 0 Concentration ug/L <0.5 1 <0.5 1 (74-83-9) Mass 2.19 Methyl chloride ✓ ❑ 0 Concentration ug/L <0.5 1 <0.5 1 (74-87-3) Mass 2.20 Methylene chloride El ❑ ❑ Concentration ug/L <0.5 1 <0.5 1 (75-09-2) Mass 2.21 1,1,2,2-tetrachloroethane El 0 0 Concentration ug/L <0.5 1 <0.5 1 (79-34-5) Mass EPA Form 3510-2C(Revised 3-19) Page 13 EPA Identification Number NPDES Permit Number Facility Name Outfall Number Form Approved 03/05/19 NCD091570960 NC0007064 Brunswick Steam Electric Plant 001 OMB No.2040-0004 TABLE B.TOXIC METALS,CYANIDE,TOTAL PHENOLS,AND ORGANIC TOXIC POLLUTANTS(40 CFR 122.21(g)(7)(v))1 Presence or Absence (check one) Effluent Intake (optional) Pollutant(Parameter Testing Units Long-Term (and CAS Number,if available) Required Believed Believed (specify) Maximum Maximum Average Number Long- Number Present Absent Daily Monthly Daily of Term of uDisc iced) ifavalablle) Discharge Analyses ischarge AValuee Analyses (if available) 2.22 Tetrachloroethylene Concentration ug/L <0.5 1 <0.5 1 (127-18-4) Mass 2.23 Toluene Concentration ug/L <0.5 1 <0.5 1 (108-88-3) Mass 2.24 1,2-trans-dichloroethylene Concentration ug/L <0.5 1 <0.5 1 El 0 El (156-60-5) Mass 2.25 1,1,1-trichloroethane Concentration ug/L <0.5 1 <0.5 1 (71-55-6) Mass 2.26 1,1,2-trichloroethane Concentration ug/L <0.5 1 <0.5 1 (79-00-5) Mass 2.27 Trichloroethylene Concentration ug/L <0.5 1 <0.5 1 (79-01-6) Mass 2.28 Vinyl chloride Concentration ug/L <0.5 1 <0.5 1 (75-01-4) Mass Section 3.Organic Toxic Pollutants(GC/MS Fraction-Acid Compounds) 3.1 2-chlorophenol Concentration ug/L <5.10 1 <6.41 1 El El 0 (95-57-8) Mass 2,4-dichlorophenol Concentration ug/L <5.10 1 <6.41 1 3.2 (120-83-2) Mass 2 4-dimethylphenol Concentration ug/L <5.10 1 <6.41 1 3.3 (105 67 9) 0 0 Mass 3.4 4,6-dinitro-o-cresol Concentration ug/L <25.5 1 <32.1 1 El El I=1 (534-52-1) Mass 3.5 2,4-dinitrophenol Concentration ug/L <25.5 1 <32.1 1 (51-28-5) f Mass EPA Form 3510-2C(Revised 3-19) Page 14 EPA Identification Number NPDES Permit Number Facility Name Outfall Number Form Approved 03/05/19 NCD091570960 NC0007064 Brunswick Steam Electric Plant 001 OMB No.2040-0004 TABLE B.TOXIC METALS,CYANIDE,TOTAL PHENOLS,AND ORGANIC TOXIC POLLUTANTS(40 CFR 122.21(g)(7)(v))1 Presence or Absence Intake (check one) Effluent (optional) Pollutant/Parameter Testing Units Long-Term (and CAS Number,if available) Required Believed Believed (specify) Maximum Maximum Average Number Long- Number Present Absent Daily Monthly Daily of Term of Discharge Discharge Discharge Analyses Average Analyses (required) (if available) Value (if available) 3.6 2-nitrophenol Concentration ug/L <25.5 1 <32.1 1 0 El El (88-75-5) Mass Concentration ug/L <25.5 1 <32.1 1 3.7 4-nitrophenol ✓❑ 0 0 (100-02-7) Mass 3.8 p-chloro-m-cresol 0Concentration ug/L <5.10 1 <6.41 1 9 (59-50-7) Mass 3.9 Pentachlorophenol 0 Concentration ug/L <25.5 1 <32.1 1 (87-86-5) Mass Phenol Concentration ug/L <5.10 1 <6.41 1 3.10 El(108-95-2) 0 Mass 3.11 2,4,6-trichlorophenol Concentration ug/L <5.10 1 <6.41 1 El El El (88-05-2) Mass Section 4.Organic Toxic Pollutants(GC/MS Fraction-Base/Neutral Compounds) Acenaphthene Concentration ug/L <5.10 1 <6.41 1 E 9 4.1 (83-32-9) Mass Acenaphthylene Concentration ug/L <5.10 1 <6.41 1 4.2 (208-96-8) Mass 4.3 Anthracene Concentration ug/L <5.10 1 <6.41 1 (120-12-7) Mass Benzidine Concentration ug/L <10.2 1 <12.8 1 4.4 (92-87-5) El 0 Mass Benzo(a)anthracene Concentration ug/L <5.10 1 <6.41 1 4.5 0 El El (56-55-3) Mass Concentration ug/L <5.10 1 <6.41 1 4.6 Benzo(a)pyrene ❑ 0 ❑✓ 9 (50-32-8) Mass EPA Form 3510-2C(Revised 3-19) Page 15 EPA Identification Number NPDES Permit Number Facility Name Outfall Number Form Approved 03/05/19 NCD091570960 NC0007064 Brunswick Steam Electric Plant 001 OMB No.2040-0004 TABLE B.TOXIC METALS,CYANIDE,TOTAL PHENOLS,AND ORGANIC TOXIC POLLUTANTS(40 CFR 122.21(g)(7)(v))1 Presence or Absence Intake (check one) Effluent (optional) Pollutant/Parameter Testing Units Long-Term (and CAS Number,if available) Required Believed Believed (specify) Maximum Maximum Average Number Long- Number Present Absent Daily Monthly Daily of Term of Discharge Discharge Discharge Analyses Average Analyses (required) (if available) Value (if available) 4.7 3,4-benzofluoranthene 0Concentration ug/L <5.10 1 <6.41 1 0 El (205-99-2) Mass Benzo(ghi)perylene 0 Concentration ug/L <5.10 1 <6.41 1 4.8 El El (191-24-2) Mass 4.9 Benzo(k)fluoranthene 0 Concentration ug/L <5.10 1 <6.41 1 (207-08-9) Mass Bis(2-chloroethoxy)methane d Concentration ug/L <5.10 1 <6.41 1 4.10 (111-91-1) Mass 4.11 Bis(2-chloroethyl)ether � 0 Concentration ug/L <5.10 1 <6.41 1 (111-44-4) Mass Bis(2-chloroisopropyl)ether 0 Concentration ug/L <5.10 1 <6.41 1 4.12 (102-80-1) Mass Bis(2-ethylhexyl)phthalate Concentration ug/L <5.10 1 <6.41 1 4.13 (117-81-7) ❑ ❑ Mass 4.14 4-bromophenyl phenyl ether 0 Concentration ug/L <5.10 1 <6.41 1 0 El (101-55-3) Mass 4.15 Butyl benzyl phthalate 0 Concentration ug/L <5.10 1 <6.41 1 El El (85-68-7) Mass 4.16 2-chloronaphthalene 0 Concentration ug/L <5.10 1 <6.41 1 El 0 (91-58-7) Mass 4-chlorophenyl phenyl ether ✓ Concentration ug/L <5.10 1 <6.41 1 4.17 El 0 (7005-72-3) Mass Chrysene 0 Concentration ug/L <5.10 1 <6.41 1 4.18 (218-01-9) Mass 4.19 Dibenzo(a,h)anthracene ❑ 0 0 Concentration ug/L <5.10 1 <6.41 1 (53-70-3) Mass EPA Form 3510-2C(Revised 3-19) Page 16 EPA Identification Number NPDES Permit Number Facility Name Outfall Number Form Approved 03/05/19 NCD091570960 NC0007064 Brunswick Steam Electric Plant 001 OMB No.2040-0004 TABLE B.TOXIC METALS,CYANIDE,TOTAL PHENOLS,AND ORGANIC TOXIC POLLUTANTS(40 CFR 122.21(g)(7)(v))l Presence or Absence Intake (check one) Effluent (optional) Pollutant/Parameter Testing Units Long-Term (and CAS Number,if available) Required Believed Believed (specify) Maximum Maximum Average Number Long- Number Present Absent Daily Monthly Daily of Term of Discharge (ifavailablle) Discharge Analyses ischarge AValuee Analyses (req ) ( (if available) 4.20 1,2-dichlorobenzene Concentration ug/L <0.5 1 <0.5 1(95-50-1) Mass 1,3-dichlorobenzene Concentration ug/L <0.5 1 <0.5 1 4.21 (541 73 1) � � 0 Mass 1,4-dichlorobenzene EI Concentration ug/L <0.5 1 <0.5 1 4.22 (106-46-7) Mass 4.23 3,3-dichlorobenzidine Concentration ug/L <10.2 1 <12.8 1(91-94-1) Mass 4.24 Diethyl phthalate © Concentration ug/L <5.10 1 <6.41 1 0 El (84-66-2) Mass 4.25 Dimethyl phthalate 0 Concentration ug/L <5.10 1 <6.41 1 (131-11-3) Mass 4.26 Di-n-butyl phthalate © Concentration ug/L <5.10 1 <6.41 1 0 0 (84-74-2) Mass 4.27 2,4-dinitrotoluene 0 Concentration ug/L <5.10 1 <6.41 1 El 0 (121-14-2) Mass 4.28 2,6-dinitrotoluene Concentration ug/L <5.10 1 <6.41 1 (606-20-2) Mass Di-n-octyl phthalate Concentration ug/L <5.10 1 <6.41 1 4.29 El 0 (117 84 0) El Mass 4.30 1,2-Diphenylhydrazine El 0 0 Concentration ug/L <5.10 1 <6.41 1 (as azobenzene)(122-66-7) Mass 4.31 Fluoranthene 0 Concentration ug/L <5.10 1 <6.41 1 (206-44-0) Mass 4.32 Fluorene 0 Concentration ug/L <5.10 1 <6.41 1 (86-73-7) Mass EPA Form 3510-2C(Revised 3-19) Page 17 EPA Identification Number NPDES Permit Number Facility Name Outfall Number Form Approved 03/05/19 NCD091570960 NC0007064 Brunswick Steam Electric Plant 001 OMB No.2040-0004 TABLE B.TOXIC METALS,CYANIDE,TOTAL PHENOLS,AND ORGANIC TOXIC POLLUTANTS(40 CFR 122.21(g)(7)(v))1 Presence or Absence Intake (check one) Effluent (optional) Pollutant/Parameter Testing Units I Long-Term (and CAS Number,if available) Required Believed Believed (specify) Maximum Maximum Average Number Long- Number Present Absent Daily Monthly Daily of Term of Discharge Discharge Discharge Analyses Average Analyses (required) (if available) Value (if available) 4.33 Hexachlorobenzene ❑ ❑ Concentration ug/L <5.10 1 <6.41 1 (118-74-1) Mass 4.34 Hexachlorobutadiene ❑ Concentration ug/L <5.10 1 <6.41 1 0 El (87-68-3) Mass 4.35 Hexachlorocyclopentadiene ❑ 0 Concentration ug/L <5.10 1 <32.1 1 (77-47-4) Mass 4.36 Hexachloroethane �✓ Concentration ug/L <5.10 1 <6.41 1 0 El (67-72-1) Mass Indeno(1,2,3-cd)pyrene Concentration ug/L <5.10 1 <6.41 1 4.37 (193-39-5) Mass 4.38 Isophorone ❑ 0 ❑✓ Concentration ug/L <5.10 1 <6.41 1 (78-59-1) Mass Naphthalene Concentration ug/L <0.5 1 <0.5 1 4.39 (91-20-3) ❑ 0 Mass 1 4.40 Nitrobenzene ❑ Concentration ug/L <5.10 1 <6.41 1 El 0 (98-95-3) Mass 4.41 N-nitrosodimethylamine 0 Concentration ug/L <5.10 1 <6.41 1 (62-75-9) Mass 4.42 N-nitrosodi-n-propylamine ❑ Concentration ug/L <5.10 1 <6.41 1 (621-64-7) Mass 4.43 N-nitrosodiphenylamine ❑ Concentration ug/L <5.10 1 <6.41 1 0 El (86-30-6) Mass 4.44 Phenanthrene 1=1 Concentration ug/L <5.10 1 <6.41 1 El 0 (85-01-8) Mass _ Pyrene Concentration ug/L <5.10 1 <6.41 1 4.45 El 0 E✓ (129-00-0) Mass EPA Form 3510-2C(Revised 3-19) Page 18 EPA Identification Number NPDES Permit Number Facility Name Outfall Number Form Approved 03/05/19 NCD091570960 NC0007064 Brunswick Steam Electric Plant 001 OMB No.2040-0004 TABLE B.TOXIC METALS,CYANIDE,TOTAL PHENOLS,AND ORGANIC TOXIC POLLUTANTS(40 CFR 122.21(g)(7)(v))1 Presence or Absence Intake (check one) Effluent (optional) Pollutant/Parameter Testing Units Long-Term (and CAS Number,if available) Required Believed Believed (specify) Maximum Maximum Average Number Long- Number Present Absent Daily Monthly Daily of Term of Discharge(required) (if Discharge ischarge Analyses AverageValue Analyses ( q ) ( available) (if available) 1 2 4-trichlorobenzene Concentration ug/L <5.10 1 <6.41 1 4.46 (120-82-1) 0 0 0 Mass Section 5.Organic Toxic Pollutants(GC/MS Fraction-Pesticides) 5.1 Aldrin ❑ ❑ Concentration ug/L <0.05 1 <0.05 1 (309-00-2) Mass a-BHC Concentration ug/L <0.05 1 <0.05 1 5.2 (319-84-6) El 0 0 Mass R-BHC Concentration ug/L <0.05 1 <0.05 1 5.3 (319-85-7) ❑ ❑ 0 Mass y-BHC Concentration ug/L <0.05 1 <0.05 1 5.4 (58 89 9) ❑ ❑ 0Mass b-BHC Concentration ug/L <0.05 1 <0.05 1 5.5 (319-86-8) 0 ❑ 0 Mass 5.6 Chlordane 0 0 ❑ Concentration ug/L <0.5 1 <0.5 1 (57-74-9) Mass 4,4'-DDT Concentration ug/L <0.05 1 <0.05 1 5.7 (50-29-3) El 0 0 Mass 4 4'-DDE Concentration ug/L <0.05 1 <0.05 1 5.8 (72-55-9) El El Mass 5.9 4,4'-DDD 0 ❑ 0 Concentration ug/L <0.05 1 <0.05 1 (72-54-8) Mass 5.10 Dieldrin 0 0 ❑ Concentration ug/L <0.05 1 <0.05 1 (60-57-1) Mass a-endosulfan Concentration ug/L <0.05 1 <0.05 1 5.11 (115-29-7) 0 0 ❑ Mass EPA Form 3510-2C(Revised 3-19) Page 19 EPA Identification Number NPDES Permit Number Facility Name Outfall Number Form Approved 03/05/19 NCD091570960 NC0007064 Brunswick Steam Electric Plant 001 OMB No.2040-0004 TABLE B.TOXIC METALS,CYANIDE,TOTAL PHENOLS,AND ORGANIC TOXIC POLLUTANTS(40 CFR 122.21(g)(7)(v))1 Presence or Absence Intake (check one) Effluent (optional) Pollutant/Parameter Testing Units Long-Term (and CAS Number,if available) Required Believed Believed (specify) Maximum Maximum Average Number Long- Number Present Absent Daily Monthly Daily of Term of Discharge req(required) (ifavalabllee) Discharge Analyses AValuee Analyses of available) 13-endosulfan 0 Concentration ug/L <0.05 1 <0.05 1 5.12 (115-29-7) Mass 5.13 Endosulfan sulfate Concentration ug/L <0.05 1 <0.05 1 El El (1031-07-8) ✓ Mass Endrin Concentration ug/L <0.05 1 <0.05 1 5.14 (72-20-8) Mass Endrin aldehyde Concentration ug/L <0.05 1 <0.05 1 5.15 (7421-93-4) Mass 5.16 Heptachlor � Concentration ug/L <0.05 1 <0.05 1 (76-44-8) ✓ Mass Heptachlor epoxide Concentration ug/L <0.05 1 <0.05 1 5.17 (1024-57-3) 0 0 0 Mass PCB-1242 Concentration mg/L <0.001 1 <0.001 1 5.18 (53469-21-9) 0 0 0 Mass PCB-1254 Concentration mg/L <0.001 1 <0.001 1 5.19 (11097-69-1) 0 0 0 Mass PCB-1221 Concentration mg/L <0.001 1 <0.001 1 5.20 (11104-28-2) 0 El PCB-1232 Concentration mg/L <0.001 1 <0.001 1 5.21 (11141-16-5) 0 0 ❑✓ Mass PCB-1248 Concentration mg/L <0.001 1 <0.001 1 5.22 (12672-29-6) El ❑ 0 Mass PCB-1260 Concentration mg/L <0.001 1 <0.001 1 5.23 (11096-82-5) ❑ 0 0 Mass PCB-1016 Concentration mg/L <0.001 1 <0.001 1 5.24 (12674-11-2) 0 0 ❑✓ Mass EPA Form 3510-2C(Revised 3-19) Page 20 EPA Identification Number NPDES Permit Number Facility Name Outfall Number Form Approved 03/05/19 NCD091570960 NC0007064 Brunswick Steam Electric Plant 001 OMB No.2040-0004 TABLE B.TOXIC METALS,CYANIDE,TOTAL PHENOLS,AND ORGANIC TOXIC POLLUTANTS(40 CFR 122.21(g)(7)(v)p Presence or Absence Intake (check one) Effluent (optional) PollutantlParameter Testing Units Long-Term (and CAS Number,if available) Required Believed Believed (specify) Maximum Maximum Average Number Long- Number Present Absent Daily Monthly Daily of Term of (req ierd)g ifavalabe) Discharge Analyses AValuee Analyses (if available) Toxaphene Concentration ug/L <0.5 1 <0.5 1 5.25 (8001-35-2) El El I=1 Mass 1 Sampling shall be conducted according to sufficiently sensitive test procedures(i.e.,methods)approved under 40 CFR 136 for the analysis of pollutants or pollutant parameters or required under 40 CFR chapter I,subchapter N or 0.See instructions and 40 CFR 122.21(e)(3). EPA Form 3510-2C(Revised 3-19) Page 21 This page intentionally left blank. EPA Identification Number NPDES Permit Number Facility Name Outfall Number Form Approved 03/05/19 NCD091570960 NC0007064 Brunswick Steam Electric Plant 001 OMB No.2040-0004 TABLE C.CERTAIN CONVENTIONAL AND NON CONVENTIONAL POLLUTANTS(40 CFR 122.21(g)(7)(vi))1 Presence or Absence Intake (check one) Effluent (Optional) Pollutant Units Maximum • Long-Term Believed Believed (specify) Maximum Daily Long-Term Present Absent Discharge Monthly Average Daily Number of Average Number of Discharge Discharge Analyses Analyses (required) Value (if available) (if available) ❑ Check here if you believe all pollutants on Table C to be present in your discharge from the noted outfall.You need not complete the'Presence or Absence"column of Table C for each pollutant. ri❑ Check here if you believe all pollutants on Table C to be absent in your discharge from the noted outfall.You need not complete the`Presence or Absence"column of Table C for each pollutant. 1. Bromide ❑ ❑ Concentration mg/L 37.7 1 34.9 1 (24959-67-9) Mass Chlorine,total Concentration ug/L <100 <100 <100 52 <100 1 2' 0 0 residual Mass Concentration U <5 1 <5 1 3. Color ❑ 0 Mass Concentration CU/100m1 10 1 7 1 4. Fecal coliform 0 ❑ Mass 5 Fluoride ❑ ❑ Concentration mg/L 0.7 1 0.6 1 (16984-48-8) Mass Concentration mg/L 0.27 1 0.26 1 6 Nitrate-nitrite ❑ 0 Mass 7 Nitrogen,total El 0 Concentration mg/L 1.6 1 1.2 1 organic(as N) Mass Concentration mg/L 5.64 1 <5.0 1 8. Oil and grease ❑ ❑ Mass 9 Phosphorus(as El ❑ Concentration mg/L <0.04 1 <0.04 1 P),total(7723-14-0) Mass Sulfate(as SO4) Concentration mg/L 1440 1 1310 1 10. (14808-79-8) 0 El Mass Concentration mg/L <0.05 1 <0.05 1 11. Sulfide(as S) 0 E Mass EPA Form 3510-2C(Revised 3-19) Page 23 EPA Identification Number NPDES Permit Number Facility Name Outfall Number Form Approved 03/05/19 NCD091570960 NC0007064 Brunswick Steam Electric Plant 001 OMB No.2040-0004 TABLE C.CERTAIN CONVENTIONAL AND NON CONVENTIONAL POLLUTANTS(40 CFR 122.21(g)(7)(vi))1 Presence or Absence (check one) Effluent Intake (Optional) Pollutant Units Maximum Long-Term Believed Believed (specify) Maximum Daily Long-Term Present Absent Discharge Monthly Average Daily Number of Average Number of (required) Discharge Discharge Analyses Analyses (if available) (if available) Value Sulfite(as SO3) Concentration mg/L <2 1 <2 1 1 2. (14265-45-3) � El Mass Concentration mg/L <0.06 1 <0.06 1 13. Surfactants ❑ ❑✓ Mass 14. Aluminum,total ❑ ❑ Concentration mg/L 0.497 1 0.543 1 (7429-90-5) Mass 15. Barium,total ❑ ❑ Concentration mg/L 0.033 1 0.028 1 (7440-39-3) Mass Boron,total Concentration mg/L 2.69 1 2.61 1 16. (7440-42-8) � 0 Mass 17 Cobalt,total Concentration mg/L <0.02 1 <0.02 1 (7440-48-4) Mass 18 Iron,total ❑ 0 Concentration mg/L 0.332 1 0.425 1 (7439-89-6) Mass 19 Magnesium,total Concentration mg/L 106 1 863 1 (7439-95 4) Mass Molybdenum, Concentration mg/L <0.02 1 <0.02 1 20. total D 0 Mass (7439-98-7) 21. Manganese,total ❑ El Concentration mg/L <0.02 1 0.026 1 (7439-96-5) Mass Tin,total Concentration mg/L <0.05 1 <0.05 1 22. (7440-31-5) 0 0 Mass 23. Titanium,total 0 ❑ Concentration mg/L <0.02 1 <0.02 1 (7440-32-6) Mass EPA Form 3510-2C(Revised 3-19) Page 24 EPA Identification Number NPDES Permit Number Facility Name Outfall Number Form Approved 03/05/19 NCD091570960 NC0007064 Brunswick Steam Electric Plant 001 OMB No.2040-0004 TABLE C.CERTAIN CONVENTIONAL AND NON CONVENTIONAL POLLUTANTS(40 CFR 122.21(g)(7)(vi))1 Presence or Absence Intake (check one) Effluent (Optional) Pollutant Units Maximum Long-Term Believed Believed (specify) Maximum Daily Monthly Average Daily Number of Long-Term Number of Present Absent Discharge Average (required) Discharge Discharge Analyses Value Analyses (if available) (if available) 24. Radioactivity Concentration pCl/L <3 1 <3 1 Alpha,total ❑ 0 Mass Beta,total ❑✓ 0 Concentration pCl/L 210 1 191 1 Mass Radium,total El pCl/L 1.2 1 1.2 1 Mass Radium 226,total ❑ Concentration pCl/L 1.2 1 1.2 1 Mass 1 Sampling shall be conducted according to sufficiently sensitive test procedures(i.e.,methods)approved under 40 CFR 136 for the analysis of pollutants or pollutant parameters or required under 40 CFR chapter I,subchapter N or 0.See instructions and 40 CFR 122.21(e)(3). EPA Form 3510-2C(Revised 3-19) Page 25 This page intentionally left blank. EPA Identification Number NPDES Permit Number Facility Name Outfall Number Form Approved 03/05/19 NCD091570960 NC0007064 Brunswick Steam Electric Plant 001 OMB No.2040-0004 TABLE D.CERTAIN HAZARDOUS SUBSTANCES AND ASBESTOS(40 CFR 122.21(g)(7)(vii))1 Presence or Absence Pollutant (check one) Available Quantitative Data Believed Believed Reason Pollutant Believed Present in Discharge (specify units) Present Absent 1. Asbestos ❑ ❑✓ 2. Acetaldehyde 0 ❑✓ 3. Allyl alcohol 0 ❑✓ 4. Allyl chloride ❑ ❑✓ 5. Amyl acetate ❑ 0 6. Aniline ❑ 0 7. Benzonitrile 0 0 8. Benzyl chloride 0 0 9. Butyl acetate ❑ ❑✓ 10. Butylamine ❑ 0 11. Captan ❑ ❑✓ 12. Carbaryl ❑ ❑✓ 13. Carbofuran ❑ ❑✓ 14. Carbon disulfide 0 0 15. Chlorpyrifos 0 0 16. Coumaphos ❑ ❑✓ 17. Cresol ❑ ❑✓ 18. Crotonaldehyde ❑ ❑✓ 19. Cyclohexane ❑ ❑✓ EPA Form 3510-2C(Revised 3-19) Page 27 EPA Identification Number NPDES Permit Number Facility Name Outfall Number Form Approved 03/05/19 NCD091570960 NC0007064 Brunswick Steam Electric Plant 001 OMB No.2040-0004 TABLE D.CERTAIN HAZARDOUS SUBSTANCES AND ASBESTOS(40 CFR 12221(g)(7)(vii))1 Presence or Absence Pollutant (check one) Reason Pollutant Believed Present in Discharge Available Quantitative Data Believed Believed (specify units) Present Absent 20. 2,4-D(2,4-dichlorophenoxyacetic acid) ❑ ❑✓ 21. Diazinon 0 ✓❑ 22. Dicamba ❑ ❑✓ 23. Dichlobenil ❑ ❑✓ 24. Dichlone 0 ❑✓ 25. 2,2-dichloropropionic acid 0 ❑✓ 26. Dichlorvos ❑ 0 27. Diethyl amine 0 ❑✓ 28. Dimethyl amine ❑ ❑✓ 29. Dintrobenzene 0 ❑✓ 30. Diquat 0 ❑✓ 31. Disulfoton ❑ ❑✓ 32. Diuron 0 0 33. Epichlorohydrin ❑ 0 34. Ethion 0 ❑✓ 35. Ethylene diamine 0 ❑✓ 36. Ethylene dibromide 0 0 37. Formaldehyde 0 ❑✓ 38. Furfural ❑ ❑✓ EPA Form 3510-2C(Revised 3-19) Page 28 EPA Identification Number NPDES Permit Number Facility Name Outfall Number Form Approved 03/05/19 NCD091570960 NC0007064 Brunswick Steam Electric Plant 001 OMB No.2040-0004 TABLE D.CERTAIN HAZARDOUS SUBSTANCES AND ASBESTOS(40 CFR 12221(g)(7)(vii))1 Presence or Absence Pollutant (check one) Reason Pollutant Believed Present in Discharge Available Quantitative Data Believed Believed (specify units) Present Absent 39. Guthion ❑ ❑✓ 40. Isoprene 0 ❑✓ 41. Isopropanolamine ❑ ❑✓ 42. Kelthane ❑ ❑✓ 43. Kepone ❑ ❑✓ 44. Malathion ❑ ❑✓ 45. Mercaptodimethur ❑ ❑✓ 46. Methoxychlor ❑ ❑✓ 47. Methyl mercaptan 0 ❑✓ 48. Methyl methacrylate 0 ❑✓ 49. Methyl parathion ❑ ❑✓ 50. Mevinphos 0 ❑✓ 51. Mexacarbate 0 ❑✓ 52. Monoethyl amine 0 ❑✓ 53. Monomethyl amine ❑ ❑✓ 54. Naled 0 ❑✓ 55. Naphthenic acid 0 ❑✓ 56. Nitrotoluene 0 ❑✓ 57. Parathion 0 ❑✓ EPA Form 3510-2C(Revised 3-19) Page 29 EPA Identification Number NPDES Permit Number Facility Name Outfall Number Form Approved 03/05/19 NCD091570960 NC0007064 Brunswick Steam Electric Plant 001 OMB No.2040-0004 TABLE D.CERTAIN HAZARDOUS SUBSTANCES AND ASBESTOS(40 CFR 12221(g)(7)(vii))1 Presence or Absence Pollutant (check one) Available Quantitative Data Believed Believed Reason Pollutant Believed Present in Discharge (specify units) Present Absent 58. Phenolsulfonate 0 ❑✓ 59. Phosgene 0 ❑✓ 60. Propargite ❑ 0 61. Propylene oxide ❑ 0 62. Pyrethrins ❑ 0 63. Quinoline 0 ❑✓ 64. Resorcinol ❑ ❑✓ 65. Strontium ❑ ❑✓ 66. Strychnine ❑ ❑✓ 67. Styrene ❑ ❑✓ 68. 2,4 5-T(2,4,5-trichlorophenoxyacetic ❑ ❑ acid) 69. TDE(tetrachlorodiphenyl ethane) 0 ❑✓ 70 2,4,5-TP[2-(2,4,5-trichlorophenoxy) ❑ ❑ propanoic acid] 71. Trichlorofon 0 0 72. Triethanolamine 0 ❑✓ 73. Triethylamine 0 0 74. Trimethylamine 0 0 75. Uranium 0 0 76. Vanadium ❑ ❑✓ EPA Form 3510-2C(Revised 3-19) Page 30 EPA Identification Number NPDES Permit Number Facility Name Outfall Number Form Approved 03/05/19 NCD091570960 NC0007064 Brunswick Steam Electric Plant 001 OMB No.2040-0004 TABLE D.CERTAIN HAZARDOUS SUBSTANCES AND ASBESTOS(40 CFR 122.21(g)(7)(vii))1 Presence or Absence Pollutant (check one) Available Quantitative Data Believed Believed Reason Pollutant Believed Present in Discharge (specify units) Present Absent 77. Vinyl acetate ❑ ❑✓ 78. Xylene ❑ ❑✓ Eff.<1.0 ug/L,Intake<1.0 ug/L 79. Xylenol ❑ ❑✓ 80. Zirconium ❑ ❑✓ I Sampling shall be conducted according to sufficiently sensitive test procedures(i.e.,methods)approved under 40 CFR 136 for the analysis of pollutants or pollutant parameters or required under 40 CFR chapter I,subchapter N or 0.See instructions and 40 CFR 122.21(e)(3). EPA Form 3510-2C(Revised 3-19) Page 31 This page intentionally left blank. EPA Identification Number NPDES Permit Number Facility Name Outfall Number Form Approved 03/05/19 NCD091570960 NC0007064 Brunswick Steam Electric Plant 001 OMB No.2040-0004 TABLE E.2,3,7,8 TETRACHLORODIBENZO P DIOXIN(2,3,7,8 TCDD)(40 CFR 122.21(g)(7)(viii)) TCDD Presence or Congeners Absence Pollutant Used or (check one) Results of Screening Procedure Manufactured Believed Believed Present Absent ND-(Not Detected)-Method 625.1-Selective Ion Monitoring 2,3,7,8-TCDD D EPA Form 3510-2C(Revised 3-19) Page 33 Duke Energy Progress, LLC Brunswick Steam Electric Plant National Pollutant Discharge Elimination System Permit Number NC0007064 Attachment 1 Form 1 - Section 6 - Existing Environmental Permits Duke Energy Progress, LLC Brunswick Steam Electric Plant National Pollutant Discharge Elimination System Individual Industrial Stormwater Permit Application Attachment 1 Form 1 - Section 6 - Existing Environmental Permits Issuing Agency Type of Permit Permit or ID Number NCDEQ - DWR NPDES - WW NC0007064 NCDEQ - DWR NPDES - CSW NCG010000 NCDEQ - DWR NPDES - SSW SW80308117 NCDEQ - DWR NPDES - SSW SW8040344 NCDEQ - DWR NPDES - SSW SW8081006 NCDEQ - DWR NPDES - SSW SW8081010 NCDEQ - DWR NPDES - SSW SW8090528 NCDEQ - DWR NPDES - SSW SW8911203 NCDEQ - DWR NPDES - SSW SW8120103 NCDEQ - DWR NPDES - SSW SW8200709 NCDEQ - DCM Coastal Resources Commission 293 NCDEQ - DAQ Synthetic Minor 05556 NCDEQ - DWM EPA Hazardous Material Waste NCD091570960 (SQG) Generator Number Oil Spill Prevention Control and NCDEQ - DWM Countermeasure Plan (SPCC) NA incorporated into SWPPP NCDEQ - DWM Certification of Registration of Oil 104021005 Terminal Facility Nuclear Regulatory Renewed Facility Operating DPR-71, DPR-62 Commission License Duke Energy Progress, LLC Brunswick Steam Electric Plant National Pollutant Discharge Elimination System Permit Number NC0007064 Attachment 2 Form 1 - Section 7 - Maps Duke Energy Progress, LLC Brunswick Steam Electric Plant National Pollutant Discharge Elimination System Permit Number NC0007064 Attachment 2 Form 1 — Section 7 - Topographic Map - 1Y .4'.. i h ";I 1"sI I 1 ` 1 P .'.• --, - . 4,$ il , i �.- jJ (.1-.7, -4.67:7-.V7--0'-4-2.72 .- — '. \ '''''''''':-"-:',lir : - '•''''': . 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IX � ,; -4 r n 4 f "!each '4 or Fart q• ro. c'/ 1 -,411-.Ritits Rtiserved Not For Navigation --- 1 Duke Energy Progress, LLC Brunswick Steam Electric Plant National Pollutant Discharge Elimination System Permit Number NC0007064 Attachment 2 Form 1 — Section 7 - Location Map 1 D Brunswick I Steam Electric Plant NORTH Walden CAROLINA Creek \ N Fish return flume O Plant Site N 9 Discharge weir---_, Diversion structure Intake Dutchman Visitors Canal \ � Creek Center U South•OttOF �� p po Atlantic Ocean Ocean Dp Discharge Area P 2 4 n Kilometers Miles 2 Duke Energy Progress, LLC Brunswick Steam Electric Plant National Pollutant Discharge Elimination System Permit Number NC0007064 Attachment 3 Form 2C - Section 2 - Line Drawing & Flow Balance Sludge I —► Sanitary Uses i Sewage Treatment A (010) 0.150 MGD Public Water Supply ► Radwaste* Plant Processes Low Volume ► G ► Waste Sources Treatmentt System 0.201 MGD B E (003) 0.120 0.020 MGD MOD Unit 1 Condenser Water Treatment —► Cooling Water System • 4 Stormwater Metal Cleaning ► Storm Drain Wastes Unit 1 Service H Collection Basin C ► Water i Emergency release to - c 0.255 discharge canal (006) ♦ OUtfall c f6 MGD 0.005 F ► Discharge Canal 001 ► `� MGD a (001) 1,625 Unit 2 Service MGD ► Drain Holding 4 Water Facility(DHF) ISFSI Pad D (005) 0.230 MGD • Unit 2 Condenser Cape Fear River Cooling Water ► Diversion Structure ► Intake Canal 4 I K 1,625 (012) 0.022 MGD MGD (011)5.9 MGD 4 - Storm Drain Ground water well Sock Drain Stabilization 4 Extraction System 4 System Facility(SDSF) Attachment 3 Form 2C-Section 2-Line Drawing & L Flow Balance Radwaste may be combined with either Unit 1 or Unit 2 cooling/service water 0.030 MGD Page 1 Duke Energy Progress, LLC Brunswick Steam Electric Plant National Pollutant Discharge Elimination System Permit Number NC0007064 Attachment 4 Form 2C - Section 3 - Outfall Flows, Contributing Operations and Treatment Technologies Duke Energy Progress, LLC Brunswick Steam Electric Plant National Pollutant Discharge Elimination System Permit Number NC0007064 Attachment 4 Form 2C - Section 3 — Outfall Flows, Contributing Operations and Treatment Technologies Average Flow Treatment Stream Outfall (MGD) & Disposal Comments Codes A 010 0.150 3A54FB & Design capacity B 0.120 Estimated flow C 006 5,000 gals/event 4B Estimated flow D 005 0.230 3G & 4B Estimated flow 1E 003 0.020 1& Q 4B Estimated flow Maximum flow- totals for Units 1& 2 Once F 001 1,625 4B through cooling water (1509 MGD maximum) and Service Water (116 MGD maximum) G 0.201 Brunswick County Utilities Account Report H 0.255 Estimated flow I 1,625 Maximum intake J 011 5.9 3G & 4B Estimated flow per event K 012 0.022 3G & 4B Estimated Average flow per day L 0.030 Estimated Average flow per day Notes: - Radwaste is disposal at a licensed disposal facility 1 Duke Energy Progress, LLC Brunswick Steam Electric Plant National Pollutant Discharge Elimination System Permit Number NC0007064 The Brunswick Steam Electric Plant (BSEP), located approximately 2.5 miles north of Southport, North Carolina, consists of two General Electric boiling water nuclear reactors with a combined maximum dependable capacity of 1,870 MW. Cooling water for the plant is drawn from the Cape Fear River and discharges into the Atlantic Ocean approximately 2,000 feet off-shore. In addition to cooling water, all other waste streams at the plant ultimately discharge to the Atlantic Ocean. Chemical constituents contained in this discharge will, in part, be representative of the naturally occurring chemical quality and quantity of the intake water and will also have chemical constituents of such quality associated with similar discharges for nuclear generating facilities of this size, type, and in this geographical location. Either all or part of the elements in the Periodic Table, either singularly or in any combination, may from time to time be contained in the discharge. Each component of the discharge is described below. Once-Through Cooling Water, Service Water (Outfall 001) Cooling water is withdrawn from the Cape Fear River via an intake canal. At the point where the intake canal intersects the river, a diversion fence screens out larger organisms. The intake structure for once-through cooling water has 42 fine mesh screen panels and 8 coarse mesh screen panels rotating in front of all four pump bays for each unit. Normal operating configuration is for 3 CWIPs to be in service at all times for each unit, for a total of 126 fine mesh screen panels and 24 coarse mesh screen panels in service per unit. The 4th pump bay for each unit will be maintained with the with the same number of fine mesh and coarse mesh screen panels as the other three pump bays, such that if the 4th pump is put into service, there will be no impact to the number of fine or coarse mesh screen panels in operation. Aquatic organisms impinged on the traveling screens are washed off and returned to the estuary. The once-through cooling water discharge consists of water that has circulated through the condensers of Units 1 and 2. The temperature rise over the condenser is approximately 15° - 30° Fahrenheit. The service water is used to cool heat exchangers associated with the turbine and reactor closed cooling water systems. The temperature rise of the service water is approximately 10° Fahrenheit. Both of these systems discharge to the Atlantic Ocean via the 5.4-mile effluent channel and pumping station at Caswell Beach. Prior to entering the plant, both cooling water and service water are chlorinated to minimize bio-fouling in the piping, heat exchangers, and other plant components. The once-through cooling water pump flows will be verified periodically during the operating cycle. If a significant difference is found between the flow rates, the once- through cooling water pumps/valves will be adjusted during upcoming maintenance or refueling outages to reflect the appropriate flow rate. In addition, flow will be verified after changing pump/valve configurations if needed. 2 Duke Energy Progress, LLC Brunswick Steam Electric Plant National Pollutant Discharge Elimination System Permit Number NC0007064 Since the source of the cooling water and service water is near the mouth of the Cape Fear River, the chemical constituents of the discharge are representative of the water in the river. The chemical constituents, in quality and quantity, are subject to many variables such as tides, rainfall, and other discharges to the river. Radwaste Treatment (Outfall 003) The radwaste treatment system is designed to collect, store, and process any radioactive (or potentially radioactive) liquids associated with operation of the nuclear power plant. These low volume waste streams are collected in tanks and sampled for radioactivity prior to discharging to the effluent channel. A representative tank is also sampled for TSS and oil and grease in accordance with the NPDES permit. The tanks are discharged intermittently, one at a time, at a rate of up to 200 gpm. Flow rates are identified on EPA Form 2C Section 3. Radioactive components of releases are regulated by the Nuclear Regulatory Commission. These tanks are described below: Floor Drain Sample Tanks and Waste Sample Tanks (23,000 qal. capacity each) These tanks receive the majority of the radwaste, primarily from in-plant drains and sumps, which contain high purity water. After the water is treated by demineralization and filtration, it is either recycled back into the plant or released. Detergent Drain Tanks (1,200 gal. capacity) - This tank receives water from showers and other in-plant drains that may collect water used for general cleaning purposes and is treated by filtration prior to release. Salt Water Release Tank (34,250 gal. capacity) - This tank receives water used for general cleaning purposes and water that leaks into the plant from the cooling and service water systems, as well as waste water from the turbine building air wash system which cools and removes humidity from the air that is re-circulated through the turbine buildings. The water is treated by filtration prior to release. Drain Holding Facility Pond (Outfall 005) A Drain Holding Facility (low volume waste pond acronym DHF) has replaced the Storm Drain Stabilization Pond with its primary input being sheet flow from the legacy pond area. The DHF is approximately 4.2 acres and holds approximately 4 million gallons. Discharge frequencies can vary depending upon stormwater inputs. When sufficient water has accumulated in the DHF, it is released through an underflow/overflow standpipe and valve at the rate of up to 1,000 gpm. The released water flows into the intake canal at a point approximately 500 yards from the intake pumps, where it is drawn into the plant circulating and service water system, and eventually released into the effluent channel. 3 Duke Energy Progress, LLC Brunswick Steam Electric Plant National Pollutant Discharge Elimination System Permit Number NC0007064 The DHF has a Parshall flume weir and sampling station located downstream of the outfall riser structure. The DHF can be used as an alternate collection point for the same inputs described in Outfall 011. Sanitary Waste Treatment (Outfalls 010) The BSEP is served by a 0.150 million gallons per day (MGD) sequencing batch reactor (SBR) sanitary treatment plant. The SBR is a fill-and-draw activated sludge system for wastewater treatment. In this system, wastewater is added to a single "batch" reactor, treated to remove undesirable components, and then discharged. Equalization, aeration, and clarification can all be achieved using a single batch reactor. To optimize performance of the system, two or more batch reactors are used in a predetermined sequence of operations. They are uniquely suited for wastewater treatment applications characterized by low or intermittent flow conditions. Storm Drain Stabilization Facility Pond (Outfall 011) The Storm Drain Stabilization Facility (low volume waste pond acronym SDSF) is approximately 3.7 acres, holds approximately 6 million gallons of water, and discharges on a weekly basis during normal operation. Discharge frequencies can vary depending upon storm water input. When sufficient water has accumulated in the SDSF, it is released through an underflow/overflow standpipe and valve at the rate of up to 1,000 gpm for approximately one week, or as needed. The SDSF has a graded native soil berm with a geotextile liner, a lower HDPE liner, Geonet drainage layer and detection/collection sumps, leak detection layer and an upper HDPE liner. The SDSF has a Parshall flume weir and sampling station located downstream of the outfall riser structure. Low volume sources and storm water from the plant yard discharges into the Storm Drain Collector Basin (SDCB) prior to being routed to the SDSF (Outfall 011). The SDCB is equipped with an oil skimmer for treatment of the effluent prior to discharge to the SDSF. Although chemical treatment of the waste is not a general practice, there are provisions for neutralizing the waste in the collection basin, if necessary, using caustic or acid. There are eight sources, which are routed to the low volume waste system (Outfall 011), including both intermittent and routine flows. These sources are described below. 1. Auxiliary Boiler Systems The plant operates one auxiliary boiler to generate steam as necessary for various plant systems. Less than 50 gallons/week are discharged from this system as routine blowdown. About once a year, the boiler is drained and inspected, resulting in approximately 3,500 gallons of wastewater per event. 4 Duke Energy Progress, LLC Brunswick Steam Electric Plant National Pollutant Discharge Elimination System Permit Number NC0007064 2. HVAC Cooling Towers An HVAC cooling tower is used to cool each of the two Turbine Buildings. The towers blow down approximately 6.4 gpm to the Storm Drain Collector Basin. 3. Demineralized Water System The purpose of the Mobile Make Up Water Treatment Unit (MMWTU) is to provide ultra pure demineralized water for the BSEP. Demineralized water is used throughout the BSEP for many purposes. Some of which include the Fuel Pool make up, precoat tank fill, and cooling for pump bearings. The MMWTU system is also the primary supply to the Condensate Storage Tanks. The demineralized system is a reverse osmosis (RO) based system with demineralizers for final polishing, using county water as the raw influent water. The truck-mounted system takes county water from the site potable water system after passing through the charcoal bed. The demineralized system produces product water along with a brine concentrate that is drained to the storm drain system at a pH of 6.0-8.0. Amount of usage for product water, not including brine and rinse water, is 11 million gallons per year at normal flow and 12 million gallons at high flow. This creates a brine solution of 5.7 million gallons a year. Brine water consists of concentrated contaminants of the county water system. Some additives are used to enhance the system performance. Approximately 450 lbs of sodium hydroxide per year is used for Chlorine destruction, and approximately 50 lbs per year of polyaluminum chloride and 50 gallons per year of Hypersperse MDC 150 are used as an antifoulant. Rinses are done when the system is started up, this is done by dumping product water and brine water together until product water reaches certain parameters. Rinses are approximately 225,000 gallons per year. There is approximately one chemical cleaning a year for the RO membranes. The rinse consists of 70 lbs/yr of GE Water Kleen MCT 103, and 70 lbs/yr of GE Water Kleen MCT 511. The rinses are drained to the storm drain system at a pH of 8.0-9.0. 4. Standby Liquid Control Test Tank This 210 gallon tank contains demineralized water and occasionally, Borax and boric acid. The tank is released quarterly, if the Boron levels exceed 10 ppm. 5. Turbine Building Closed Cooling Water During each refueling cycle, (approximately once every 24 months), one heat exchanger containing approximately 2,100 gallons of water may be drained. Occasionally, a system feed and bleed is required to maintain Chemistry control. This process may release up to 4,500 gallons. 5 Duke Energy Progress, LLC Brunswick Steam Electric Plant National Pollutant Discharge Elimination System Permit Number NC0007064 6. Diesel Generator Cooling Water System Minor sources of non-potable water leaks from this generator system (four diesel generators) and drains into the collection basin. Additionally, the cooling water system is drained periodically for maintenance (Approximately 900 to1,000 gallons). 7. Maintenance Activities During maintenance activities at the facility it may become necessary to drain all or some portion thereof of the following plant systems; service water, circulating water, potable water, and demineralized water. Maintenance activities at the facility may also require flushing of system piping with the discharge to the storm drain system. In addition, the facility may find it necessary to wash equipment with demineralized water with the discharge to storm drains. 8. Independent Spent Fuel Storage Installation (ISFSI) An ISFSI vault was installed at the facility in 2009. Storm water runoff from the concrete surface and concrete vault will be collected and pumped to either of the active storm drain stabilization ponds. None of the spent fuel rods housed in the vault will come in contact with the storm water runoff, the runoff is expected to have characteristics similar to that of any other impervious surface (concrete) runoff. The DHF (Outfall 005) can receive the same inputs described above when the SDSF is not available for use. Ground Water Well Extraction System (Outfall 012) In March of 2011, 92 ground water extraction wells onsite began operating to remove approximately 22,000 gpd of groundwater with tritium levels of concern from the site. The wells discharge primarily into the intake canal through the Storm Drain Stabilization Facility (SDSF, Outfall 011) with the option of using Outfall 012. The discharge will consist of the extracted groundwater and approximately 30,000 gpd of seepage water from a sock drain system. Other Miscellaneous Discharges In addition to cooling water, service water, sanitary waste, low volume waste, and radwaste, there are other miscellaneous discharges (or potential discharges) at the BSEP: • Emergency storm drain collection basin overflow to the effluent channel used as necessary to prevent flooding in the plant area. • Intake screen backwash, as required, to operate the cooling water system. 6 Duke Energy Progress, LLC Brunswick Steam Electric Plant National Pollutant Discharge Elimination System Permit Number NC0007064 Attachment 5 Form 2C — Section 8 - Used or Manufactured Toxics (Potential Discharges Not Covered by Analysis) Duke Energy Progress, LLC Brunswick Steam Electric Plant National Pollutant Discharge Elimination System Permit Number NC0007064 Attachment 5 Form 2C - Section 8 — Used or Manufactured Toxics (Potential Discharges Not Covered by Analysis) Although not added or produced, the following elements could potentially be present in the discharge due to normal pipe erosion/corrosion: Copper Iron Silver Nickel Zinc The following elements could be present in oil which is used to fuel auxiliary boilers: Antimony Arsenic Beryllium Cadmium Chromium Copper Lead Mercury Nickel Selenium Silver Thallium Zinc The following chemicals are used at the plant site and may be present within the waste treatment system: Quantity Chemical (used per year, Frequency Purpose estimate) Sodium Hypochlorite Sewage Plant Biocide Treatment 15% 2,000 gals/yr As Needed & Cooling Tower Treatment Sodium Hypochlorite 1 .75 million Circ & Service Water Antifouling 15% gallons per year Daily Treatment Nalco CAT-FLOC Sewage Plant Solids Treatment 1,500 lbs/yr As Needed 8103 Plus Sodium Hydroxide 4,420 gals/yr As Needed Sewage Plant & Air Wash (4-50%) pH control Lime 100 lbs/yr As Needed Sewage Plant Sludge pH Treatment Nalco 7346 Cooling Towers Biocide & (Bromine powder 1,600 lbs/yr Daily and tablet form) Waste Water Systems 1 Duke Energy Progress, LLC Brunswick Steam Electric Plant National Pollutant Discharge Elimination System Permit Number NC0007064 Quantity Chemical (used per year, Frequency Purpose estimate) Nalco 19PULV 100 lbs/yr As Needed Aux Boiler Chemicals Sodium Nitrite 96 lbs/yr As Needed Diesel Generator Chemicals Nalco 3D Trasar Cooling Towers & Diesel 3DT198 9,000 lbs/yr As Needed Generators Nalco 3D Trasar Cooling Tower & Diesel 3DT294 6,700 lbs/yr As Needed Generators GE Water Variable As Needed Biocide Biomate MBC 2881 Sodium Hydroxide 450 lbs/yr As Needed Make Up Water RO Products 50% Polyaluminum 50 lbs/yr As Needed Make Up Water RO Products Chloride GE Hypersperse 160 lbs/yr As Needed Make Up Water RO Products MDC 150 GE Kleen MCT103 70 lbs/yr As Needed Membrane Cleaner GE Kleen MCT 511 70 lbs/yr As Needed Membrane Cleaner Sodium Borate 50 lbs/yr As Needed Diesel Generator Chemicals Disodium Phosphate 50 lbs/yr As Needed Aux Boiler Trisodium Phosphate 50 lbs/yr As Needed Aux Boiler Nalco Towerbrom 1 ,500 lbs/yr As Needed Cooling towers 991 Nalco 73310 1 ,800 lbs/yr As Needed Closed Cooling Water System Sodium Nitrite Stabrex ST70 — 4,300 lbs/yr As Needed Air Washes Liquid Bromine Redux 515 Acid Approximately 2 Pellets (80% pounds per Sulfamic Acid, 20% week per As Needed Pump and piping maintenance Boric Acid) groundwater extraction well 2 Duke Energy Progress, LLC Brunswick Steam Electric Plant National Pollutant Discharge Elimination System Permit Number NC0007064 Quantity Chemical (used per year, Frequency Purpose estimate) Approximately 5 Redux 500°Liquid gallons per As Needed Pipe cleaning Descaler (10/o HCL) month or 60 gallons per year Approximately 1 Aqua-Clear AE (60- gallon per 100% Hydroxyacetic quarter per As Needed Well cleaning and maintenance Acid) groundwater extraction well. Approximately 1 Aqua-Clear MGA pound per (60-100% Sulfamic quarter per As Needed Well cleaning and maintenance Acid) groundwater extraction well Aqua-Clear PFD (30 Approximately 1 60% Anionic cup per quarter As Needed Well cleaning and maintenance polyacrylamide) per groundwater extraction well NALCO 3DT 10,000 lbs/yr As Needed Used in Diesel Generators; TRASAR 104 TBAW NALCO 3DT 61 ,000 lbs/yr As Needed Condenser Cleaning; Silt TRASAR 121 Dispersant NALCO 73551 54,000 lbs/yr As Needed Condenser Cleaning; Biodetergent NALCO Actibrom 2,000,000 lbs/yr As Needed Bromine Biocide; Circulation 1338 Water Biodetergent Cellulose (Wood Approximately Flour) 500 lbs per As Needed Mitigate Condenser Tube Leaks treatment ScintLogic LB 3 gallons / yr As Needed Online Groundwater Analysis (Tritium) 3