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Home My WebLink AboutDWR RCN Reports week of Nov 16, 2021PO Number # Loc. Descr.:02 MINSHEW Loc. Type:Rain Water Collector:N MILLER Collect Date:11/23/2021 Collect Time:10:14 Date Received:12/03/2021 Time Received:10:00 Location ID:02 County:Cumberland Region:Fayetteville Labworks LoginID TASCENZO1Sample Matrix:EXPERIMENTAL SOLUTION Report Print Date: North Carolina Division of Water Resources Water Sciences Section Laboratory Results W111621-02VisitID Sample Depth DAQReport To River Basin 04/04/2022 Emergency YESCOC Yes/No Sample ID:AC92114 3/19/22Final Report Date: Final Report If this report is labeled preliminary report, the results have not been validated. Do not use for Regulatory purposes. Hand DeliveredDelivery Method COCPriority Analysis Date Method Reference Result/ QualifierPQLAnalyte NameCAS #Units Validated by AC92114 LAB ESTAFFORD1°CSample temperature at receipt by lab 12/3/211.8 PFA DWRPFAS EHENDERSONng/LU11Cl-PF3ONS 1/31/222<2.0 DWRPFAS EHENDERSONng/LU4:2 FTS757124-72-4 1/31/222<2.0 DWRPFAS EHENDERSONng/LU6:2 FTS27619-97-2 1/31/222<2.0 DWRPFAS EHENDERSONng/LU8:2 FTS39108-34-4 1/31/222<2.0 DWRPFAS EHENDERSONng/LU9Cl-PF3ONS73606-19-6 1/31/222<2.0 DWRPFAS EHENDERSONng/LUHFPO-DA13252-13-6 1/31/222<2.0 DWRPFAS EHENDERSONng/LUNaDONA919005-14-4 1/31/222<2.0 DWRPFAS EHENDERSONng/LUN-EtFOSAA2991-50-6 1/31/222<2.0 DWRPFAS EHENDERSONng/LUN-MeFOSAA2355-31-9 1/31/222<2.0 DWRPFAS EHENDERSONng/LUPFBA375-22-4 1/31/22210 DWRPFAS EHENDERSONng/LUPFBS375-73-5 1/31/222<2.0 DWRPFAS EHENDERSONng/LUPFDA335-76-2 1/31/222<2.0 DWRPFAS EHENDERSONng/LUPFDoA307-55-1 1/31/222<2.0 DWRPFAS EHENDERSONng/LUPFDoS79780-39-5 1/31/222<2.0 DWRPFAS EHENDERSONng/LUPFDS335-77-3 1/31/222<2.0 DWRPFAS EHENDERSONng/LUPFHpA375-85-9 1/31/222<2.0 DWRPFAS EHENDERSONng/LUPFHpS375-92-8 1/31/222<2.0 DWRPFAS EHENDERSONng/LUPFHxA307-24-4 1/31/222<2.0 DWRPFAS EHENDERSONng/LUPFHxS355-46-4 1/31/222<2.0 DWRPFAS EHENDERSONng/LUPFNA375-95-1 1/31/222<2.0 DWRPFAS EHENDERSONng/LUPFNS68259-12-1 1/31/222<2.0 DWRPFAS EHENDERSONng/LUPFOA335-67-1 1/31/222<2.0 DWRPFAS EHENDERSONng/LUPFOS1763-23-1 1/31/222<2.0 DWRPFAS EHENDERSONng/LUPFPeA2706-90-3 1/31/222<2.0 DWRPFAS EHENDERSONng/LUPFPeS2706-91-4 1/31/222<2.0 DWRPFAS EHENDERSONng/LUPFTeDA376-06-7 1/31/222<2.0 DWRPFAS EHENDERSONng/LUPFTrDA72629-94-8 1/31/222<2.0 DWRPFAS EHENDERSONng/LUPFUnA2058-94-8 1/31/222<2.0 WSS Chemistry Laboratory>> 1623 Mail Service Center, Raleigh, NC 27699-1623 (919) 733-3908 Page 1 of 3 "Not Detected" or "U" does not indicate the sample is analyte free but that the analyte is not detected at or above the PQL. AC92114Sample ID: NC DWR Laboratory Section Results/Sample Comments/Qualifier Definitions CAS #Analyte Name PQL Result/ Qualifier Units Method Reference Analysis Date Validated by PFAS: PFAS - Holding time exceeded following receipt by lab. Internal WSS guidelines specify samples must be extracted within 30 days of collection. Sample Comments NCDEQ-WSS-Chemistry Lab Data Qualifiers A1 The reported value is an average, where at least one result is qualified with a “U”. The PQL is used for the qualified result(S) to calculate the average. B1 Coliform-Countable membranes with less than 20 colonies. Reported value is estimated or is a total of the counts on all filters reported per 100 ml. B2 Coliform-Counts from all filters were zero. The value reported is based on the number of colonies per 100 ml that would have been reported if there had been one colony on the filter representing the largest filtration volume. B3 Coliform-Countable membranes with more than 60 or 80 colonies. The value reported is calculated using the count from the smallest volume filtered and reported as a greater than ">" value. B4 Coliform-Filters have counts of both >60 or 80 and <20. Reported value is estimated or is a total of the counts on all filters reported per 100 ml. B5 Coliform-Too many colonies were present; too numerous to count (TNTC). TNTC is generally defined as >150 colonies. B6 Coliform-Estimated Value. Blank contamination evident. B7 Coliform-Many non-coliform or non-enterococcus colonies or interfering non-coliform or non-enterococcus growth present. In this competitive situation, the reported value may under-represent actual density. BB1 MPN-No wells or tubes gave a positive reaction. Value based upon the appropriate MPN Index and reported as a less than “<” value. BB2 MPN-All wells or tubes gave positive reactions. Value based upon the MPN Index and reported as a greater than “>” value. C Total residual chlorine was present in sample upon receipt in the laboratory; value is estimated. G1 BOD-The dissolved oxygen (DO) depletion of the dilution water blank exceeded 0.2 mg/L. G2 BOD-The bacterial seed controls did not meet the requirement of a DO depletion of at least 2.0 mg/L and/or a DO residual of at least 1.0 mg/L. G3 BOD-No sample dilution met the requirement of a DO depletion of at least 2.0 mg/L and/or a DO residual of at least 1.0 mg/L. G4 BOD-Evidence of toxicity. This is generally characterized by a significant increase in the BOD value as the sample concentration decreases. The reported value is calculated from the highest dilution representing the maximum loading potential and G5 BOD-The glucose/ glutamic acid standard exceeded the range of 198 ± 30.5 mg/L. G7 BOD-Less than 1 mg/L DO remained for all dilutions set. The reported value is an estimated greater than value and is calculated for the dilution using the least amount of sample. G8 BOD-Oxygen usage is less than 2 mg/L for all dilutions set. The reported value is an estimated less than value and is calculated for the dilution using the most amount of sample. G9 BOD-The DO depletion of the dilution water blank produced a negative value. J1 Surrogate recovery limits have been exceeded. J10 Unidentified peak; estimated value. J11 The reported value is determined by a one-point estimation rather than against a regression equation. The estimated concentration is less than the laboratory practical quantitation limit and greater than the instrument noise level. This code is used when WSS Chemistry Laboratory>> 1623 Mail Service Center, Raleigh, NC 27699-1623 (919) 733-3908 Page 2 of 3 "Not Detected" or "U" does not indicate the sample is analyte free but that the analyte is not detected at or above the PQL. AC92114Sample ID: NC DWR Laboratory Section Results/Sample Comments/Qualifier Definitions CAS #Analyte Name PQL Result/ Qualifier Units Method Reference Analysis Date Validated by J12 The calibration verification did not meet the calibration acceptance criterion for field parameters. J2 The reported value failed to meet the established quality control criteria for either precision or accuracy. J3 The sample matrix interfered with the ability to make any accurate determination. J4 The data is questionable because of improper laboratory or field protocols (e.g., composite sample was collected instead of grab, plastic instead of glass container, etc.). J5 Temperature limits exceeded (samples frozen or >6°C) during transport or not verifiable (e.g., no temperature blank provided): non-reportable for NPDES compliance monitoring. J6 The laboratory analysis was from an unpreserved or improperly chemically preserved sample. The data may not be accurate. J7 This qualifier is used to identify analyte concentration exceeding the upper calibration range of the analytical instrument/method. The reported value should be considered estimated. J8 Temperature limits exceeded (samples frozen or >6ºC) during storage, the data may not be accurate. J9 The reported value is determined by a one-point estimation rather than against a regression equation. The estimated concentration is less than the laboratory practical quantitation limit and greater than the laboratory method detection limit. M Sample and duplicate results are "out of control". The sample is non-homogenous (e.g., VOA soil). The reported value is the lower value of duplicate analyses of a sample. N1 Presumptive evidence and estimated value. The component has been tentatively identified base on mass spectral library. N2 There is an indication that the analyte is present, but quality control requirements for confirmation were not met (i.e., presence of analyte was not confirmed by alternate procedures). N3 This code shall be used if the level is too low to permit accurate quantification, but the estimated concentration is less than the laboratory practical quantitation limit and greater than the laboratory method detection limit. This code is not routinely N4 This code shall be used if the level is too low to permit accurate quantification, but the estimated concentration is less than the laboratory practical quantitation limit and greater than the instrument noise level. This code is used when an MDL has not N5 The component has been tentatively identified based on a retention time standard. P Elevated PQL* due to matrix interference and/or sample dilution. Q1 Holding time exceeded prior to receipt by lab. Q2 Holding time exceeded following receipt by lab. S Not enough sample provided to prepare and/or analyze a method-required matrix spike (MS) and/or matrix spike duplicate (MSD). U Indicates that the analyte was analyzed for but not detected above the reported practical quantitation limit*. The number value reported with the "U" qualifier is equal to the laboratory's practical quantitation limit*. U, J6 The laboratory analysis was from an unpreserved or improperly chemically preserved sample. The data may not be accurate. UU Indicates that the analyte was not detected by a screen analysis. The number value was determined by a one-point estimation at the PQL. V Indicates the analyte was detected in both the sample and the associated method blank. Note: The value in the blank shall not be subtracted from the associated samples. X1 Sample not screened for this compound. X2 Sampled, but analysis lost or not performed-field error. X3 Sampled, but analysis lost or not performed-lab error. Y Elevated PQL* due to insufficient sample size. Z1 Inability to analyze the sample. Z2 Questions concerning data reliability. WSS Chemistry Laboratory>> 1623 Mail Service Center, Raleigh, NC 27699-1623 (919) 733-3908 Page 3 of 3 "Not Detected" or "U" does not indicate the sample is analyte free but that the analyte is not detected at or above the PQL. PO Number # Loc. Descr.:02 MINSHEW Loc. Type:Rain Water Collector:N MILLER Collect Date:11/23/2021 Collect Time:10:14 Date Received:12/03/2021 Time Received:10:00 Location ID:02 County:Cumberland Region:Fayetteville Labworks LoginID TASCENZO1Sample Matrix:EXPERIMENTAL SOLUTION Report Print Date: North Carolina Division of Water Resources Water Sciences Section Laboratory Results W111621-02VisitID Sample Depth DAQReport To River Basin 03/20/2022 Emergency YESCOC Yes/No Sample ID:AC92114 3/19/22Final Report Date: Final Report If this report is labeled preliminary report, the results have not been validated. Do not use for Regulatory purposes. Hand DeliveredDelivery Method COCPriority AC92114 Analysis Date Method Reference Result/ QualifierPQLAnalyte NameCAS #Units Validated by LAB ESTAFFORD1°CSample temperature at receipt by lab 12/3/211.8 Others DWRPFAS EHENDERSONng/LU11Cl-PF3ONS 1/31/222<2.0 DWRPFAS EHENDERSONng/LU4:2 FTS757124-72-4 1/31/222<2.0 DWRPFAS EHENDERSONng/LU6:2 FTS27619-97-2 1/31/222<2.0 DWRPFAS EHENDERSONng/LU8:2 FTS39108-34-4 1/31/222<2.0 DWRPFAS EHENDERSONng/LU9Cl-PF3ONS73606-19-6 1/31/222<2.0 DWRPFAS EHENDERSONng/LUHFPO-DA13252-13-6 1/31/222<2.0 DWRPFAS EHENDERSONng/LUNaDONA919005-14-4 1/31/222<2.0 DWRPFAS EHENDERSONng/LUN-EtFOSAA2991-50-6 1/31/222<2.0 DWRPFAS EHENDERSONng/LUN-MeFOSAA2355-31-9 1/31/222<2.0 DWRPFAS EHENDERSONPerfluorinated Compounds (PFA) in liquid 1/31/22_TITLE_ DWRPFAS EHENDERSONng/LUPFBA375-22-4 1/31/22210 DWRPFAS EHENDERSONng/LUPFBS375-73-5 1/31/222<2.0 DWRPFAS EHENDERSONng/LUPFDA335-76-2 1/31/222<2.0 DWRPFAS EHENDERSONng/LUPFDoA307-55-1 1/31/222<2.0 DWRPFAS EHENDERSONng/LUPFDoS79780-39-5 1/31/222<2.0 DWRPFAS EHENDERSONng/LUPFDS335-77-3 1/31/222<2.0 DWRPFAS EHENDERSONng/LUPFHpA375-85-9 1/31/222<2.0 DWRPFAS EHENDERSONng/LUPFHpS375-92-8 1/31/222<2.0 DWRPFAS EHENDERSONng/LUPFHxA307-24-4 1/31/222<2.0 DWRPFAS EHENDERSONng/LUPFHxS355-46-4 1/31/222<2.0 DWRPFAS EHENDERSONng/LUPFNA375-95-1 1/31/222<2.0 DWRPFAS EHENDERSONng/LUPFNS68259-12-1 1/31/222<2.0 DWRPFAS EHENDERSONng/LUPFOA335-67-1 1/31/222<2.0 DWRPFAS EHENDERSONng/LUPFOS1763-23-1 1/31/222<2.0 DWRPFAS EHENDERSONng/LUPFPeA2706-90-3 1/31/222<2.0 DWRPFAS EHENDERSONng/LUPFPeS2706-91-4 1/31/222<2.0 DWRPFAS EHENDERSONng/LUPFTeDA376-06-7 1/31/222<2.0 DWRPFAS EHENDERSONng/LUPFTrDA72629-94-8 1/31/222<2.0 DWRPFAS EHENDERSONng/LUPFUnA2058-94-8 1/31/222<2.0 WSS Chemistry Laboratory>> 1623 Mail Service Center, Raleigh, NC 27699-1623 (919) 733-3908 Page 1 of 3 "Not Detected" or "U" does not indicate the sample is analyte free but that the analyte is not detected at or above the PQL. AC92114Sample ID: NC DWR Laboratory Section Results/Sample Comments/Qualifier Definitions CAS #Analyte Name PQL Result/ Qualifier Units Method Reference Analysis Date Validated by PFAS: PFAS - Holding time exceeded following receipt by lab. Internal WSS guidelines specify samples must be extracted within 30 days of collection. Sample Comments NCDEQ-WSS-Chemistry Lab Data Qualifiers A1 The reported value is an average, where at least one result is qualified with a “U”. The PQL is used for the qualified result(S) to calculate the average. B1 Coliform-Countable membranes with less than 20 colonies. Reported value is estimated or is a total of the counts on all filters reported per 100 ml. B2 Coliform-Counts from all filters were zero. The value reported is based on the number of colonies per 100 ml that would have been reported if there had been one colony on the filter representing the largest filtration volume. B3 Coliform-Countable membranes with more than 60 or 80 colonies. The value reported is calculated using the count from the smallest volume filtered and reported as a greater than ">" value. B4 Coliform-Filters have counts of both >60 or 80 and <20. Reported value is estimated or is a total of the counts on all filters reported per 100 ml. B5 Coliform-Too many colonies were present; too numerous to count (TNTC). TNTC is generally defined as >150 colonies. B6 Coliform-Estimated Value. Blank contamination evident. B7 Coliform-Many non-coliform or non-enterococcus colonies or interfering non-coliform or non-enterococcus growth present. In this competitive situation, the reported value may under-represent actual density. BB1 MPN-No wells or tubes gave a positive reaction. Value based upon the appropriate MPN Index and reported as a less than “<” value. BB2 MPN-All wells or tubes gave positive reactions. Value based upon the MPN Index and reported as a greater than “>” value. C Total residual chlorine was present in sample upon receipt in the laboratory; value is estimated. G1 BOD-The dissolved oxygen (DO) depletion of the dilution water blank exceeded 0.2 mg/L. G2 BOD-The bacterial seed controls did not meet the requirement of a DO depletion of at least 2.0 mg/L and/or a DO residual of at least 1.0 mg/L. G3 BOD-No sample dilution met the requirement of a DO depletion of at least 2.0 mg/L and/or a DO residual of at least 1.0 mg/L. G4 BOD-Evidence of toxicity. This is generally characterized by a significant increase in the BOD value as the sample concentration decreases. The reported value is calculated from the highest dilution representing the maximum loading potential and G5 BOD-The glucose/ glutamic acid standard exceeded the range of 198 ± 30.5 mg/L. G7 BOD-Less than 1 mg/L DO remained for all dilutions set. The reported value is an estimated greater than value and is calculated for the dilution using the least amount of sample. G8 BOD-Oxygen usage is less than 2 mg/L for all dilutions set. The reported value is an estimated less than value and is calculated for the dilution using the most amount of sample. G9 BOD-The DO depletion of the dilution water blank produced a negative value. J1 Surrogate recovery limits have been exceeded. J10 Unidentified peak; estimated value. WSS Chemistry Laboratory>> 1623 Mail Service Center, Raleigh, NC 27699-1623 (919) 733-3908 Page 2 of 3 "Not Detected" or "U" does not indicate the sample is analyte free but that the analyte is not detected at or above the PQL. AC92114Sample ID: NC DWR Laboratory Section Results/Sample Comments/Qualifier Definitions CAS #Analyte Name PQL Result/ Qualifier Units Method Reference Analysis Date Validated by J11 The reported value is determined by a one-point estimation rather than against a regression equation. The estimated concentration is less than the laboratory practical quantitation limit and greater than the instrument noise level. This code is used when J12 The calibration verification did not meet the calibration acceptance criterion for field parameters. J2 The reported value failed to meet the established quality control criteria for either precision or accuracy. J3 The sample matrix interfered with the ability to make any accurate determination. J4 The data is questionable because of improper laboratory or field protocols (e.g., composite sample was collected instead of grab, plastic instead of glass container, etc.). J5 Temperature limits exceeded (samples frozen or >6°C) during transport or not verifiable (e.g., no temperature blank provided): non-reportable for NPDES compliance monitoring. J6 The laboratory analysis was from an unpreserved or improperly chemically preserved sample. The data may not be accurate. J7 This qualifier is used to identify analyte concentration exceeding the upper calibration range of the analytical instrument/method. The reported value should be considered estimated. J8 Temperature limits exceeded (samples frozen or >6ºC) during storage, the data may not be accurate. J9 The reported value is determined by a one-point estimation rather than against a regression equation. The estimated concentration is less than the laboratory practical quantitation limit and greater than the laboratory method detection limit. M Sample and duplicate results are "out of control". The sample is non-homogenous (e.g., VOA soil). The reported value is the lower value of duplicate analyses of a sample. N1 Presumptive evidence and estimated value. The component has been tentatively identified base on mass spectral library. N2 There is an indication that the analyte is present, but quality control requirements for confirmation were not met (i.e., presence of analyte was not confirmed by alternate procedures). N3 This code shall be used if the level is too low to permit accurate quantification, but the estimated concentration is less than the laboratory practical quantitation limit and greater than the laboratory method detection limit. This code is not routinely N4 This code shall be used if the level is too low to permit accurate quantification, but the estimated concentration is less than the laboratory practical quantitation limit and greater than the instrument noise level. This code is used when an MDL has not N5 The component has been tentatively identified based on a retention time standard. P Elevated PQL* due to matrix interference and/or sample dilution. Q1 Holding time exceeded prior to receipt by lab. Q2 Holding time exceeded following receipt by lab. S Not enough sample provided to prepare and/or analyze a method-required matrix spike (MS) and/or matrix spike duplicate (MSD). U Indicates that the analyte was analyzed for but not detected above the reported practical quantitation limit*. The number value reported with the "U" qualifier is equal to the laboratory's practical quantitation limit*. U, J6 The laboratory analysis was from an unpreserved or improperly chemically preserved sample. The data may not be accurate. UU Indicates that the analyte was not detected by a screen analysis. The number value was determined by a one-point estimation at the PQL. V Indicates the analyte was detected in both the sample and the associated method blank. Note: The value in the blank shall not be subtracted from the associated samples. X1 Sample not screened for this compound. X2 Sampled, but analysis lost or not performed-field error. X3 Sampled, but analysis lost or not performed-lab error. Y Elevated PQL* due to insufficient sample size. Z1 Inability to analyze the sample. Z2 Questions concerning data reliability. WSS Chemistry Laboratory>> 1623 Mail Service Center, Raleigh, NC 27699-1623 (919) 733-3908 Page 3 of 3 "Not Detected" or "U" does not indicate the sample is analyte free but that the analyte is not detected at or above the PQL. PO Number # Loc. Descr.:02 MINSHEW (DRY) Loc. Type:Rain Water Collector:N MILLER Collect Date:11/23/2021 Collect Time:10:14 Date Received:12/03/2021 Time Received:10:00 Location ID:02D County:Cumberland Region:Fayetteville Labworks LoginID TASCENZO1Sample Matrix:EXPERIMENTAL SOLUTION Report Print Date: North Carolina Division of Water Resources Water Sciences Section Laboratory Results D111621-02VisitID Sample Depth DAQReport To River Basin 03/11/2022 Emergency YESCOC Yes/No Sample ID:AC92115 3/11/22Final Report Date: Final Report If this report is labeled preliminary report, the results have not been validated. Do not use for Regulatory purposes. Hand DeliveredDelivery Method COCPriority AC92115 Analysis Date Method Reference Result/ QualifierPQLAnalyte NameCAS #Units Validated by LAB ESTAFFORD1°CSample temperature at receipt by lab 12/3/211.8 Others DWRPFAS EHENDERSONng/LU11Cl-PF3ONS 2/1/222<2.0 DWRPFAS EHENDERSONng/LU4:2 FTS757124-72-4 2/1/222<2.0 DWRPFAS EHENDERSONng/LU6:2 FTS27619-97-2 2/1/222<2.0 DWRPFAS EHENDERSONng/LU8:2 FTS39108-34-4 2/1/222<2.0 DWRPFAS EHENDERSONng/LU9Cl-PF3ONS73606-19-6 2/1/222<2.0 DWRPFAS EHENDERSONng/LHFPO-DA13252-13-6 2/1/2224.3 DWRPFAS EHENDERSONng/LUNaDONA919005-14-4 2/1/222<2.0 DWRPFAS EHENDERSONng/LUJ2N-EtFOSAA2991-50-6 2/1/222<2.0 DWRPFAS EHENDERSONng/LUJ2N-MeFOSAA2355-31-9 2/1/222<2.0 DWRPFAS EHENDERSONPerfluorinated Compounds (PFA) in liquid 2/1/22_TITLE_ DWRPFAS EHENDERSONng/LPFBA375-22-4 2/1/2225.1 DWRPFAS EHENDERSONng/LUPFBS375-73-5 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFDA335-76-2 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFDoA307-55-1 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFDoS79780-39-5 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFDS335-77-3 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFHpA375-85-9 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFHpS375-92-8 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFHxA307-24-4 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFHxS355-46-4 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFNA375-95-1 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFNS68259-12-1 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFOA335-67-1 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFOS1763-23-1 2/1/222<2.0 DWRPFAS EHENDERSONng/LPFPeA2706-90-3 2/1/2222 DWRPFAS EHENDERSONng/LUPFPeS2706-91-4 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFTeDA376-06-7 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFTrDA72629-94-8 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFUnA2058-94-8 2/1/222<2.0 WSS Chemistry Laboratory>> 1623 Mail Service Center, Raleigh, NC 27699-1623 (919) 733-3908 Page 1 of 3 "Not Detected" or "U" does not indicate the sample is analyte free but that the analyte is not detected at or above the PQL. AC92115Sample ID: NC DWR Laboratory Section Results/Sample Comments/Qualifier Definitions CAS #Analyte Name PQL Result/ Qualifier Units Method Reference Analysis Date Validated by PFAS: PFAS - Holding time exceeded following receipt by lab. Internal WSS guidelines specify samples must be extracted within 30 days of collection. PFAS: PFAS -J2 - reported value failed to meet the established quality control criteria for either precision or accuracy. Sample Comments NCDEQ-WSS-Chemistry Lab Data Qualifiers A1 The reported value is an average, where at least one result is qualified with a “U”. The PQL is used for the qualified result(S) to calculate the average. B1 Coliform-Countable membranes with less than 20 colonies. Reported value is estimated or is a total of the counts on all filters reported per 100 ml. B2 Coliform-Counts from all filters were zero. The value reported is based on the number of colonies per 100 ml that would have been reported if there had been one colony on the filter representing the largest filtration volume. B3 Coliform-Countable membranes with more than 60 or 80 colonies. The value reported is calculated using the count from the smallest volume filtered and reported as a greater than ">" value. B4 Coliform-Filters have counts of both >60 or 80 and <20. Reported value is estimated or is a total of the counts on all filters reported per 100 ml. B5 Coliform-Too many colonies were present; too numerous to count (TNTC). TNTC is generally defined as >150 colonies. B6 Coliform-Estimated Value. Blank contamination evident. B7 Coliform-Many non-coliform or non-enterococcus colonies or interfering non-coliform or non-enterococcus growth present. In this competitive situation, the reported value may under-represent actual density. BB1 MPN-No wells or tubes gave a positive reaction. Value based upon the appropriate MPN Index and reported as a less than “<” value. BB2 MPN-All wells or tubes gave positive reactions. Value based upon the MPN Index and reported as a greater than “>” value. C Total residual chlorine was present in sample upon receipt in the laboratory; value is estimated. G1 BOD-The dissolved oxygen (DO) depletion of the dilution water blank exceeded 0.2 mg/L. G2 BOD-The bacterial seed controls did not meet the requirement of a DO depletion of at least 2.0 mg/L and/or a DO residual of at least 1.0 mg/L. G3 BOD-No sample dilution met the requirement of a DO depletion of at least 2.0 mg/L and/or a DO residual of at least 1.0 mg/L. G4 BOD-Evidence of toxicity. This is generally characterized by a significant increase in the BOD value as the sample concentration decreases. The reported value is calculated from the highest dilution representing the maximum loading potential and G5 BOD-The glucose/ glutamic acid standard exceeded the range of 198 ± 30.5 mg/L. G7 BOD-Less than 1 mg/L DO remained for all dilutions set. The reported value is an estimated greater than value and is calculated for the dilution using the least amount of sample. G8 BOD-Oxygen usage is less than 2 mg/L for all dilutions set. The reported value is an estimated less than value and is calculated for the dilution using the most amount of sample. G9 BOD-The DO depletion of the dilution water blank produced a negative value. J1 Surrogate recovery limits have been exceeded. J10 Unidentified peak; estimated value. WSS Chemistry Laboratory>> 1623 Mail Service Center, Raleigh, NC 27699-1623 (919) 733-3908 Page 2 of 3 "Not Detected" or "U" does not indicate the sample is analyte free but that the analyte is not detected at or above the PQL. AC92115Sample ID: NC DWR Laboratory Section Results/Sample Comments/Qualifier Definitions CAS #Analyte Name PQL Result/ Qualifier Units Method Reference Analysis Date Validated by J11 The reported value is determined by a one-point estimation rather than against a regression equation. The estimated concentration is less than the laboratory practical quantitation limit and greater than the instrument noise level. This code is used when J12 The calibration verification did not meet the calibration acceptance criterion for field parameters. J2 The reported value failed to meet the established quality control criteria for either precision or accuracy. J3 The sample matrix interfered with the ability to make any accurate determination. J4 The data is questionable because of improper laboratory or field protocols (e.g., composite sample was collected instead of grab, plastic instead of glass container, etc.). J5 Temperature limits exceeded (samples frozen or >6°C) during transport or not verifiable (e.g., no temperature blank provided): non-reportable for NPDES compliance monitoring. J6 The laboratory analysis was from an unpreserved or improperly chemically preserved sample. The data may not be accurate. J7 This qualifier is used to identify analyte concentration exceeding the upper calibration range of the analytical instrument/method. The reported value should be considered estimated. J8 Temperature limits exceeded (samples frozen or >6ºC) during storage, the data may not be accurate. J9 The reported value is determined by a one-point estimation rather than against a regression equation. The estimated concentration is less than the laboratory practical quantitation limit and greater than the laboratory method detection limit. M Sample and duplicate results are "out of control". The sample is non-homogenous (e.g., VOA soil). The reported value is the lower value of duplicate analyses of a sample. N1 Presumptive evidence and estimated value. The component has been tentatively identified base on mass spectral library. N2 There is an indication that the analyte is present, but quality control requirements for confirmation were not met (i.e., presence of analyte was not confirmed by alternate procedures). N3 This code shall be used if the level is too low to permit accurate quantification, but the estimated concentration is less than the laboratory practical quantitation limit and greater than the laboratory method detection limit. This code is not routinely N4 This code shall be used if the level is too low to permit accurate quantification, but the estimated concentration is less than the laboratory practical quantitation limit and greater than the instrument noise level. This code is used when an MDL has not N5 The component has been tentatively identified based on a retention time standard. P Elevated PQL* due to matrix interference and/or sample dilution. Q1 Holding time exceeded prior to receipt by lab. Q2 Holding time exceeded following receipt by lab. S Not enough sample provided to prepare and/or analyze a method-required matrix spike (MS) and/or matrix spike duplicate (MSD). U Indicates that the analyte was analyzed for but not detected above the reported practical quantitation limit*. The number value reported with the "U" qualifier is equal to the laboratory's practical quantitation limit*. U, J6 The laboratory analysis was from an unpreserved or improperly chemically preserved sample. The data may not be accurate. UU Indicates that the analyte was not detected by a screen analysis. The number value was determined by a one-point estimation at the PQL. V Indicates the analyte was detected in both the sample and the associated method blank. Note: The value in the blank shall not be subtracted from the associated samples. X1 Sample not screened for this compound. X2 Sampled, but analysis lost or not performed-field error. X3 Sampled, but analysis lost or not performed-lab error. Y Elevated PQL* due to insufficient sample size. Z1 Inability to analyze the sample. Z2 Questions concerning data reliability. WSS Chemistry Laboratory>> 1623 Mail Service Center, Raleigh, NC 27699-1623 (919) 733-3908 Page 3 of 3 "Not Detected" or "U" does not indicate the sample is analyte free but that the analyte is not detected at or above the PQL. PO Number # Loc. Descr.:WATTERS_19 Loc. Type:Rain Water Collector:N MILLER Collect Date:11/23/2021 Collect Time:10:37 Date Received:12/03/2021 Time Received:10:00 Location ID:19 County:Cumberland Region:Fayetteville Labworks LoginID TASCENZO1Sample Matrix:EXPERIMENTAL SOLUTION Report Print Date: North Carolina Division of Water Resources Water Sciences Section Laboratory Results W111621-19VisitID Sample Depth DAQReport To River Basin 03/11/2022 Emergency YESCOC Yes/No Sample ID:AC92116 3/11/22Final Report Date: Final Report If this report is labeled preliminary report, the results have not been validated. Do not use for Regulatory purposes. Hand DeliveredDelivery Method COCPriority AC92116 Analysis Date Method Reference Result/ QualifierPQLAnalyte NameCAS #Units Validated by LAB ESTAFFORD1°CSample temperature at receipt by lab 12/3/211.8 Others DWRPFAS EHENDERSONng/LU11Cl-PF3ONS 2/1/222<2.0 DWRPFAS EHENDERSONng/LU4:2 FTS757124-72-4 2/1/222<2.0 DWRPFAS EHENDERSONng/LU6:2 FTS27619-97-2 2/1/222<2.0 DWRPFAS EHENDERSONng/LU8:2 FTS39108-34-4 2/1/222<2.0 DWRPFAS EHENDERSONng/LU9Cl-PF3ONS73606-19-6 2/1/222<2.0 DWRPFAS EHENDERSONng/LUHFPO-DA13252-13-6 2/1/222<2.0 DWRPFAS EHENDERSONng/LUNaDONA919005-14-4 2/1/222<2.0 DWRPFAS EHENDERSONng/LUN-EtFOSAA2991-50-6 2/1/222<2.0 DWRPFAS EHENDERSONng/LUJ2N-MeFOSAA2355-31-9 2/1/222<2.0 DWRPFAS EHENDERSONPerfluorinated Compounds (PFA) in liquid 2/1/22_TITLE_ DWRPFAS EHENDERSONng/LUPFBA375-22-4 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFBS375-73-5 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFDA335-76-2 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFDoA307-55-1 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFDoS79780-39-5 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFDS335-77-3 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFHpA375-85-9 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFHpS375-92-8 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFHxA307-24-4 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFHxS355-46-4 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFNA375-95-1 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFNS68259-12-1 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFOA335-67-1 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFOS1763-23-1 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFPeA2706-90-3 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFPeS2706-91-4 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFTeDA376-06-7 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFTrDA72629-94-8 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFUnA2058-94-8 2/1/222<2.0 WSS Chemistry Laboratory>> 1623 Mail Service Center, Raleigh, NC 27699-1623 (919) 733-3908 Page 1 of 3 "Not Detected" or "U" does not indicate the sample is analyte free but that the analyte is not detected at or above the PQL. AC92116Sample ID: NC DWR Laboratory Section Results/Sample Comments/Qualifier Definitions CAS #Analyte Name PQL Result/ Qualifier Units Method Reference Analysis Date Validated by PFAS: PFAS - Holding time exceeded following receipt by lab. Internal WSS guidelines specify samples must be extracted within 30 days of collection. PFAS: PFAS -J2 - reported value failed to meet the established quality control criteria for either precision or accuracy. Sample Comments NCDEQ-WSS-Chemistry Lab Data Qualifiers A1 The reported value is an average, where at least one result is qualified with a “U”. The PQL is used for the qualified result(S) to calculate the average. B1 Coliform-Countable membranes with less than 20 colonies. Reported value is estimated or is a total of the counts on all filters reported per 100 ml. B2 Coliform-Counts from all filters were zero. The value reported is based on the number of colonies per 100 ml that would have been reported if there had been one colony on the filter representing the largest filtration volume. B3 Coliform-Countable membranes with more than 60 or 80 colonies. The value reported is calculated using the count from the smallest volume filtered and reported as a greater than ">" value. B4 Coliform-Filters have counts of both >60 or 80 and <20. Reported value is estimated or is a total of the counts on all filters reported per 100 ml. B5 Coliform-Too many colonies were present; too numerous to count (TNTC). TNTC is generally defined as >150 colonies. B6 Coliform-Estimated Value. Blank contamination evident. B7 Coliform-Many non-coliform or non-enterococcus colonies or interfering non-coliform or non-enterococcus growth present. In this competitive situation, the reported value may under-represent actual density. BB1 MPN-No wells or tubes gave a positive reaction. Value based upon the appropriate MPN Index and reported as a less than “<” value. BB2 MPN-All wells or tubes gave positive reactions. Value based upon the MPN Index and reported as a greater than “>” value. C Total residual chlorine was present in sample upon receipt in the laboratory; value is estimated. G1 BOD-The dissolved oxygen (DO) depletion of the dilution water blank exceeded 0.2 mg/L. G2 BOD-The bacterial seed controls did not meet the requirement of a DO depletion of at least 2.0 mg/L and/or a DO residual of at least 1.0 mg/L. G3 BOD-No sample dilution met the requirement of a DO depletion of at least 2.0 mg/L and/or a DO residual of at least 1.0 mg/L. G4 BOD-Evidence of toxicity. This is generally characterized by a significant increase in the BOD value as the sample concentration decreases. The reported value is calculated from the highest dilution representing the maximum loading potential and G5 BOD-The glucose/ glutamic acid standard exceeded the range of 198 ± 30.5 mg/L. G7 BOD-Less than 1 mg/L DO remained for all dilutions set. The reported value is an estimated greater than value and is calculated for the dilution using the least amount of sample. G8 BOD-Oxygen usage is less than 2 mg/L for all dilutions set. The reported value is an estimated less than value and is calculated for the dilution using the most amount of sample. G9 BOD-The DO depletion of the dilution water blank produced a negative value. J1 Surrogate recovery limits have been exceeded. J10 Unidentified peak; estimated value. WSS Chemistry Laboratory>> 1623 Mail Service Center, Raleigh, NC 27699-1623 (919) 733-3908 Page 2 of 3 "Not Detected" or "U" does not indicate the sample is analyte free but that the analyte is not detected at or above the PQL. AC92116Sample ID: NC DWR Laboratory Section Results/Sample Comments/Qualifier Definitions CAS #Analyte Name PQL Result/ Qualifier Units Method Reference Analysis Date Validated by J11 The reported value is determined by a one-point estimation rather than against a regression equation. The estimated concentration is less than the laboratory practical quantitation limit and greater than the instrument noise level. This code is used when J12 The calibration verification did not meet the calibration acceptance criterion for field parameters. J2 The reported value failed to meet the established quality control criteria for either precision or accuracy. J3 The sample matrix interfered with the ability to make any accurate determination. J4 The data is questionable because of improper laboratory or field protocols (e.g., composite sample was collected instead of grab, plastic instead of glass container, etc.). J5 Temperature limits exceeded (samples frozen or >6°C) during transport or not verifiable (e.g., no temperature blank provided): non-reportable for NPDES compliance monitoring. J6 The laboratory analysis was from an unpreserved or improperly chemically preserved sample. The data may not be accurate. J7 This qualifier is used to identify analyte concentration exceeding the upper calibration range of the analytical instrument/method. The reported value should be considered estimated. J8 Temperature limits exceeded (samples frozen or >6ºC) during storage, the data may not be accurate. J9 The reported value is determined by a one-point estimation rather than against a regression equation. The estimated concentration is less than the laboratory practical quantitation limit and greater than the laboratory method detection limit. M Sample and duplicate results are "out of control". The sample is non-homogenous (e.g., VOA soil). The reported value is the lower value of duplicate analyses of a sample. N1 Presumptive evidence and estimated value. The component has been tentatively identified base on mass spectral library. N2 There is an indication that the analyte is present, but quality control requirements for confirmation were not met (i.e., presence of analyte was not confirmed by alternate procedures). N3 This code shall be used if the level is too low to permit accurate quantification, but the estimated concentration is less than the laboratory practical quantitation limit and greater than the laboratory method detection limit. This code is not routinely N4 This code shall be used if the level is too low to permit accurate quantification, but the estimated concentration is less than the laboratory practical quantitation limit and greater than the instrument noise level. This code is used when an MDL has not N5 The component has been tentatively identified based on a retention time standard. P Elevated PQL* due to matrix interference and/or sample dilution. Q1 Holding time exceeded prior to receipt by lab. Q2 Holding time exceeded following receipt by lab. S Not enough sample provided to prepare and/or analyze a method-required matrix spike (MS) and/or matrix spike duplicate (MSD). U Indicates that the analyte was analyzed for but not detected above the reported practical quantitation limit*. The number value reported with the "U" qualifier is equal to the laboratory's practical quantitation limit*. U, J6 The laboratory analysis was from an unpreserved or improperly chemically preserved sample. The data may not be accurate. UU Indicates that the analyte was not detected by a screen analysis. The number value was determined by a one-point estimation at the PQL. V Indicates the analyte was detected in both the sample and the associated method blank. Note: The value in the blank shall not be subtracted from the associated samples. X1 Sample not screened for this compound. X2 Sampled, but analysis lost or not performed-field error. X3 Sampled, but analysis lost or not performed-lab error. Y Elevated PQL* due to insufficient sample size. Z1 Inability to analyze the sample. Z2 Questions concerning data reliability. WSS Chemistry Laboratory>> 1623 Mail Service Center, Raleigh, NC 27699-1623 (919) 733-3908 Page 3 of 3 "Not Detected" or "U" does not indicate the sample is analyte free but that the analyte is not detected at or above the PQL. PO Number # Loc. Descr.:WATTERS_19 (DRY) Loc. Type:Rain Water Collector:N MILLER Collect Date:11/23/2021 Collect Time:10:37 Date Received:12/03/2021 Time Received:10:00 Location ID:19D County:Cumberland Region:Fayetteville Labworks LoginID TASCENZO1Sample Matrix:EXPERIMENTAL SOLUTION Report Print Date: North Carolina Division of Water Resources Water Sciences Section Laboratory Results D111621-19VisitID Sample Depth DAQReport To River Basin 03/11/2022 Emergency YESCOC Yes/No Sample ID:AC92117 3/11/22Final Report Date: Final Report If this report is labeled preliminary report, the results have not been validated. Do not use for Regulatory purposes. Hand DeliveredDelivery Method COCPriority AC92117 Analysis Date Method Reference Result/ QualifierPQLAnalyte NameCAS #Units Validated by LAB ESTAFFORD1°CSample temperature at receipt by lab 12/3/211.8 Others DWRPFAS EHENDERSONng/LU11Cl-PF3ONS 2/1/222<2.0 DWRPFAS EHENDERSONng/LU4:2 FTS757124-72-4 2/1/222<2.0 DWRPFAS EHENDERSONng/LU6:2 FTS27619-97-2 2/1/222<2.0 DWRPFAS EHENDERSONng/LU8:2 FTS39108-34-4 2/1/222<2.0 DWRPFAS EHENDERSONng/LU9Cl-PF3ONS73606-19-6 2/1/222<2.0 DWRPFAS EHENDERSONng/LUHFPO-DA13252-13-6 2/1/222<2.0 DWRPFAS EHENDERSONng/LUNaDONA919005-14-4 2/1/222<2.0 DWRPFAS EHENDERSONng/LUN-EtFOSAA2991-50-6 2/1/222<2.0 DWRPFAS EHENDERSONng/LUJ2N-MeFOSAA2355-31-9 2/1/222<2.0 DWRPFAS EHENDERSONPerfluorinated Compounds (PFA) in liquid 2/1/22_TITLE_ DWRPFAS EHENDERSONng/LUPFBA375-22-4 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFBS375-73-5 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFDA335-76-2 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFDoA307-55-1 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFDoS79780-39-5 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFDS335-77-3 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFHpA375-85-9 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFHpS375-92-8 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFHxA307-24-4 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFHxS355-46-4 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFNA375-95-1 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFNS68259-12-1 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFOA335-67-1 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFOS1763-23-1 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFPeA2706-90-3 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFPeS2706-91-4 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFTeDA376-06-7 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFTrDA72629-94-8 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFUnA2058-94-8 2/1/222<2.0 WSS Chemistry Laboratory>> 1623 Mail Service Center, Raleigh, NC 27699-1623 (919) 733-3908 Page 1 of 3 "Not Detected" or "U" does not indicate the sample is analyte free but that the analyte is not detected at or above the PQL. AC92117Sample ID: NC DWR Laboratory Section Results/Sample Comments/Qualifier Definitions CAS #Analyte Name PQL Result/ Qualifier Units Method Reference Analysis Date Validated by PFAS: PFAS - Holding time exceeded following receipt by lab. Internal WSS guidelines specify samples must be extracted within 30 days of collection. PFAS: PFAS -J2 - reported value failed to meet the established quality control criteria for either precision or accuracy. Sample Comments NCDEQ-WSS-Chemistry Lab Data Qualifiers A1 The reported value is an average, where at least one result is qualified with a “U”. The PQL is used for the qualified result(S) to calculate the average. B1 Coliform-Countable membranes with less than 20 colonies. Reported value is estimated or is a total of the counts on all filters reported per 100 ml. B2 Coliform-Counts from all filters were zero. The value reported is based on the number of colonies per 100 ml that would have been reported if there had been one colony on the filter representing the largest filtration volume. B3 Coliform-Countable membranes with more than 60 or 80 colonies. The value reported is calculated using the count from the smallest volume filtered and reported as a greater than ">" value. B4 Coliform-Filters have counts of both >60 or 80 and <20. Reported value is estimated or is a total of the counts on all filters reported per 100 ml. B5 Coliform-Too many colonies were present; too numerous to count (TNTC). TNTC is generally defined as >150 colonies. B6 Coliform-Estimated Value. Blank contamination evident. B7 Coliform-Many non-coliform or non-enterococcus colonies or interfering non-coliform or non-enterococcus growth present. In this competitive situation, the reported value may under-represent actual density. BB1 MPN-No wells or tubes gave a positive reaction. Value based upon the appropriate MPN Index and reported as a less than “<” value. BB2 MPN-All wells or tubes gave positive reactions. Value based upon the MPN Index and reported as a greater than “>” value. C Total residual chlorine was present in sample upon receipt in the laboratory; value is estimated. G1 BOD-The dissolved oxygen (DO) depletion of the dilution water blank exceeded 0.2 mg/L. G2 BOD-The bacterial seed controls did not meet the requirement of a DO depletion of at least 2.0 mg/L and/or a DO residual of at least 1.0 mg/L. G3 BOD-No sample dilution met the requirement of a DO depletion of at least 2.0 mg/L and/or a DO residual of at least 1.0 mg/L. G4 BOD-Evidence of toxicity. This is generally characterized by a significant increase in the BOD value as the sample concentration decreases. The reported value is calculated from the highest dilution representing the maximum loading potential and G5 BOD-The glucose/ glutamic acid standard exceeded the range of 198 ± 30.5 mg/L. G7 BOD-Less than 1 mg/L DO remained for all dilutions set. The reported value is an estimated greater than value and is calculated for the dilution using the least amount of sample. G8 BOD-Oxygen usage is less than 2 mg/L for all dilutions set. The reported value is an estimated less than value and is calculated for the dilution using the most amount of sample. G9 BOD-The DO depletion of the dilution water blank produced a negative value. J1 Surrogate recovery limits have been exceeded. J10 Unidentified peak; estimated value. WSS Chemistry Laboratory>> 1623 Mail Service Center, Raleigh, NC 27699-1623 (919) 733-3908 Page 2 of 3 "Not Detected" or "U" does not indicate the sample is analyte free but that the analyte is not detected at or above the PQL. AC92117Sample ID: NC DWR Laboratory Section Results/Sample Comments/Qualifier Definitions CAS #Analyte Name PQL Result/ Qualifier Units Method Reference Analysis Date Validated by J11 The reported value is determined by a one-point estimation rather than against a regression equation. The estimated concentration is less than the laboratory practical quantitation limit and greater than the instrument noise level. This code is used when J12 The calibration verification did not meet the calibration acceptance criterion for field parameters. J2 The reported value failed to meet the established quality control criteria for either precision or accuracy. J3 The sample matrix interfered with the ability to make any accurate determination. J4 The data is questionable because of improper laboratory or field protocols (e.g., composite sample was collected instead of grab, plastic instead of glass container, etc.). J5 Temperature limits exceeded (samples frozen or >6°C) during transport or not verifiable (e.g., no temperature blank provided): non-reportable for NPDES compliance monitoring. J6 The laboratory analysis was from an unpreserved or improperly chemically preserved sample. The data may not be accurate. J7 This qualifier is used to identify analyte concentration exceeding the upper calibration range of the analytical instrument/method. The reported value should be considered estimated. J8 Temperature limits exceeded (samples frozen or >6ºC) during storage, the data may not be accurate. J9 The reported value is determined by a one-point estimation rather than against a regression equation. The estimated concentration is less than the laboratory practical quantitation limit and greater than the laboratory method detection limit. M Sample and duplicate results are "out of control". The sample is non-homogenous (e.g., VOA soil). The reported value is the lower value of duplicate analyses of a sample. N1 Presumptive evidence and estimated value. The component has been tentatively identified base on mass spectral library. N2 There is an indication that the analyte is present, but quality control requirements for confirmation were not met (i.e., presence of analyte was not confirmed by alternate procedures). N3 This code shall be used if the level is too low to permit accurate quantification, but the estimated concentration is less than the laboratory practical quantitation limit and greater than the laboratory method detection limit. This code is not routinely N4 This code shall be used if the level is too low to permit accurate quantification, but the estimated concentration is less than the laboratory practical quantitation limit and greater than the instrument noise level. This code is used when an MDL has not N5 The component has been tentatively identified based on a retention time standard. P Elevated PQL* due to matrix interference and/or sample dilution. Q1 Holding time exceeded prior to receipt by lab. Q2 Holding time exceeded following receipt by lab. S Not enough sample provided to prepare and/or analyze a method-required matrix spike (MS) and/or matrix spike duplicate (MSD). U Indicates that the analyte was analyzed for but not detected above the reported practical quantitation limit*. The number value reported with the "U" qualifier is equal to the laboratory's practical quantitation limit*. U, J6 The laboratory analysis was from an unpreserved or improperly chemically preserved sample. The data may not be accurate. UU Indicates that the analyte was not detected by a screen analysis. The number value was determined by a one-point estimation at the PQL. V Indicates the analyte was detected in both the sample and the associated method blank. Note: The value in the blank shall not be subtracted from the associated samples. X1 Sample not screened for this compound. X2 Sampled, but analysis lost or not performed-field error. X3 Sampled, but analysis lost or not performed-lab error. Y Elevated PQL* due to insufficient sample size. Z1 Inability to analyze the sample. Z2 Questions concerning data reliability. WSS Chemistry Laboratory>> 1623 Mail Service Center, Raleigh, NC 27699-1623 (919) 733-3908 Page 3 of 3 "Not Detected" or "U" does not indicate the sample is analyte free but that the analyte is not detected at or above the PQL. PO Number # Loc. Descr.:BUCV BLADEN UNION CHURCH Loc. Type:Rain Water Collector:N MILLER Collect Date:11/23/2021 Collect Time:10:56 Date Received:12/03/2021 Time Received:10:00 Location ID:32 County:Cumberland Region:Fayetteville Labworks LoginID TASCENZO1Sample Matrix:EXPERIMENTAL SOLUTION Report Print Date: North Carolina Division of Water Resources Water Sciences Section Laboratory Results W111621-32VisitID Sample Depth DAQReport To River Basin 03/11/2022 Emergency YESCOC Yes/No Sample ID:AC92118 3/11/22Final Report Date: Final Report If this report is labeled preliminary report, the results have not been validated. Do not use for Regulatory purposes. Hand DeliveredDelivery Method COCPriority AC92118 Analysis Date Method Reference Result/ QualifierPQLAnalyte NameCAS #Units Validated by LAB ESTAFFORD1°CSample temperature at receipt by lab 12/3/211.8 Others DWRPFAS EHENDERSONng/LU11Cl-PF3ONS 2/1/222<2.0 DWRPFAS EHENDERSONng/LU4:2 FTS757124-72-4 2/1/222<2.0 DWRPFAS EHENDERSONng/LU6:2 FTS27619-97-2 2/1/222<2.0 DWRPFAS EHENDERSONng/LU8:2 FTS39108-34-4 2/1/222<2.0 DWRPFAS EHENDERSONng/LU9Cl-PF3ONS73606-19-6 2/1/222<2.0 DWRPFAS EHENDERSONng/LUHFPO-DA13252-13-6 2/1/222<2.0 DWRPFAS EHENDERSONng/LUNaDONA919005-14-4 2/1/222<2.0 DWRPFAS EHENDERSONng/LUN-EtFOSAA2991-50-6 2/1/222<2.0 DWRPFAS EHENDERSONng/LUJ2N-MeFOSAA2355-31-9 2/1/222<2.0 DWRPFAS EHENDERSONPerfluorinated Compounds (PFA) in liquid 2/1/22_TITLE_ DWRPFAS EHENDERSONng/LUPFBA375-22-4 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFBS375-73-5 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFDA335-76-2 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFDoA307-55-1 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFDoS79780-39-5 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFDS335-77-3 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFHpA375-85-9 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFHpS375-92-8 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFHxA307-24-4 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFHxS355-46-4 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFNA375-95-1 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFNS68259-12-1 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFOA335-67-1 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFOS1763-23-1 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFPeA2706-90-3 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFPeS2706-91-4 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFTeDA376-06-7 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFTrDA72629-94-8 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFUnA2058-94-8 2/1/222<2.0 WSS Chemistry Laboratory>> 1623 Mail Service Center, Raleigh, NC 27699-1623 (919) 733-3908 Page 1 of 3 "Not Detected" or "U" does not indicate the sample is analyte free but that the analyte is not detected at or above the PQL. AC92118Sample ID: NC DWR Laboratory Section Results/Sample Comments/Qualifier Definitions CAS #Analyte Name PQL Result/ Qualifier Units Method Reference Analysis Date Validated by PFAS: PFAS - Holding time exceeded following receipt by lab. Internal WSS guidelines specify samples must be extracted within 30 days of collection. PFAS: PFAS -J2 - reported value failed to meet the established quality control criteria for either precision or accuracy. Sample Comments NCDEQ-WSS-Chemistry Lab Data Qualifiers A1 The reported value is an average, where at least one result is qualified with a “U”. The PQL is used for the qualified result(S) to calculate the average. B1 Coliform-Countable membranes with less than 20 colonies. Reported value is estimated or is a total of the counts on all filters reported per 100 ml. B2 Coliform-Counts from all filters were zero. The value reported is based on the number of colonies per 100 ml that would have been reported if there had been one colony on the filter representing the largest filtration volume. B3 Coliform-Countable membranes with more than 60 or 80 colonies. The value reported is calculated using the count from the smallest volume filtered and reported as a greater than ">" value. B4 Coliform-Filters have counts of both >60 or 80 and <20. Reported value is estimated or is a total of the counts on all filters reported per 100 ml. B5 Coliform-Too many colonies were present; too numerous to count (TNTC). TNTC is generally defined as >150 colonies. B6 Coliform-Estimated Value. Blank contamination evident. B7 Coliform-Many non-coliform or non-enterococcus colonies or interfering non-coliform or non-enterococcus growth present. In this competitive situation, the reported value may under-represent actual density. BB1 MPN-No wells or tubes gave a positive reaction. Value based upon the appropriate MPN Index and reported as a less than “<” value. BB2 MPN-All wells or tubes gave positive reactions. Value based upon the MPN Index and reported as a greater than “>” value. C Total residual chlorine was present in sample upon receipt in the laboratory; value is estimated. G1 BOD-The dissolved oxygen (DO) depletion of the dilution water blank exceeded 0.2 mg/L. G2 BOD-The bacterial seed controls did not meet the requirement of a DO depletion of at least 2.0 mg/L and/or a DO residual of at least 1.0 mg/L. G3 BOD-No sample dilution met the requirement of a DO depletion of at least 2.0 mg/L and/or a DO residual of at least 1.0 mg/L. G4 BOD-Evidence of toxicity. This is generally characterized by a significant increase in the BOD value as the sample concentration decreases. The reported value is calculated from the highest dilution representing the maximum loading potential and G5 BOD-The glucose/ glutamic acid standard exceeded the range of 198 ± 30.5 mg/L. G7 BOD-Less than 1 mg/L DO remained for all dilutions set. The reported value is an estimated greater than value and is calculated for the dilution using the least amount of sample. G8 BOD-Oxygen usage is less than 2 mg/L for all dilutions set. The reported value is an estimated less than value and is calculated for the dilution using the most amount of sample. G9 BOD-The DO depletion of the dilution water blank produced a negative value. J1 Surrogate recovery limits have been exceeded. J10 Unidentified peak; estimated value. WSS Chemistry Laboratory>> 1623 Mail Service Center, Raleigh, NC 27699-1623 (919) 733-3908 Page 2 of 3 "Not Detected" or "U" does not indicate the sample is analyte free but that the analyte is not detected at or above the PQL. AC92118Sample ID: NC DWR Laboratory Section Results/Sample Comments/Qualifier Definitions CAS #Analyte Name PQL Result/ Qualifier Units Method Reference Analysis Date Validated by J11 The reported value is determined by a one-point estimation rather than against a regression equation. The estimated concentration is less than the laboratory practical quantitation limit and greater than the instrument noise level. This code is used when J12 The calibration verification did not meet the calibration acceptance criterion for field parameters. J2 The reported value failed to meet the established quality control criteria for either precision or accuracy. J3 The sample matrix interfered with the ability to make any accurate determination. J4 The data is questionable because of improper laboratory or field protocols (e.g., composite sample was collected instead of grab, plastic instead of glass container, etc.). J5 Temperature limits exceeded (samples frozen or >6°C) during transport or not verifiable (e.g., no temperature blank provided): non-reportable for NPDES compliance monitoring. J6 The laboratory analysis was from an unpreserved or improperly chemically preserved sample. The data may not be accurate. J7 This qualifier is used to identify analyte concentration exceeding the upper calibration range of the analytical instrument/method. The reported value should be considered estimated. J8 Temperature limits exceeded (samples frozen or >6ºC) during storage, the data may not be accurate. J9 The reported value is determined by a one-point estimation rather than against a regression equation. The estimated concentration is less than the laboratory practical quantitation limit and greater than the laboratory method detection limit. M Sample and duplicate results are "out of control". The sample is non-homogenous (e.g., VOA soil). The reported value is the lower value of duplicate analyses of a sample. N1 Presumptive evidence and estimated value. The component has been tentatively identified base on mass spectral library. N2 There is an indication that the analyte is present, but quality control requirements for confirmation were not met (i.e., presence of analyte was not confirmed by alternate procedures). N3 This code shall be used if the level is too low to permit accurate quantification, but the estimated concentration is less than the laboratory practical quantitation limit and greater than the laboratory method detection limit. This code is not routinely N4 This code shall be used if the level is too low to permit accurate quantification, but the estimated concentration is less than the laboratory practical quantitation limit and greater than the instrument noise level. This code is used when an MDL has not N5 The component has been tentatively identified based on a retention time standard. P Elevated PQL* due to matrix interference and/or sample dilution. Q1 Holding time exceeded prior to receipt by lab. Q2 Holding time exceeded following receipt by lab. S Not enough sample provided to prepare and/or analyze a method-required matrix spike (MS) and/or matrix spike duplicate (MSD). U Indicates that the analyte was analyzed for but not detected above the reported practical quantitation limit*. The number value reported with the "U" qualifier is equal to the laboratory's practical quantitation limit*. U, J6 The laboratory analysis was from an unpreserved or improperly chemically preserved sample. The data may not be accurate. UU Indicates that the analyte was not detected by a screen analysis. The number value was determined by a one-point estimation at the PQL. V Indicates the analyte was detected in both the sample and the associated method blank. Note: The value in the blank shall not be subtracted from the associated samples. X1 Sample not screened for this compound. X2 Sampled, but analysis lost or not performed-field error. X3 Sampled, but analysis lost or not performed-lab error. Y Elevated PQL* due to insufficient sample size. Z1 Inability to analyze the sample. Z2 Questions concerning data reliability. WSS Chemistry Laboratory>> 1623 Mail Service Center, Raleigh, NC 27699-1623 (919) 733-3908 Page 3 of 3 "Not Detected" or "U" does not indicate the sample is analyte free but that the analyte is not detected at or above the PQL. PO Number # Loc. Descr.:BUCV BLADEN UNION CHURCH (DRY) Loc. Type:Rain Water Collector:N MILLER Collect Date:11/23/2021 Collect Time:10:56 Date Received:12/03/2021 Time Received:10:00 Location ID:32D County:Cumberland Region:Fayetteville Labworks LoginID TASCENZO1Sample Matrix:EXPERIMENTAL SOLUTION Report Print Date: North Carolina Division of Water Resources Water Sciences Section Laboratory Results D111621-32VisitID Sample Depth DAQReport To River Basin 03/11/2022 Emergency YESCOC Yes/No Sample ID:AC92119 3/11/22Final Report Date: Final Report If this report is labeled preliminary report, the results have not been validated. Do not use for Regulatory purposes. Hand DeliveredDelivery Method COCPriority AC92119 Analysis Date Method Reference Result/ QualifierPQLAnalyte NameCAS #Units Validated by LAB ESTAFFORD1°CSample temperature at receipt by lab 12/3/211.8 Others DWRPFAS EHENDERSONng/LU11Cl-PF3ONS 2/1/222<2.0 DWRPFAS EHENDERSONng/LU4:2 FTS757124-72-4 2/1/222<2.0 DWRPFAS EHENDERSONng/LU6:2 FTS27619-97-2 2/1/222<2.0 DWRPFAS EHENDERSONng/LU8:2 FTS39108-34-4 2/1/222<2.0 DWRPFAS EHENDERSONng/LU9Cl-PF3ONS73606-19-6 2/1/222<2.0 DWRPFAS EHENDERSONng/LUHFPO-DA13252-13-6 2/1/222<2.0 DWRPFAS EHENDERSONng/LUNaDONA919005-14-4 2/1/222<2.0 DWRPFAS EHENDERSONng/LJ2N-EtFOSAA2991-50-6 2/1/222<2.0 DWRPFAS EHENDERSONng/LJ2N-MeFOSAA2355-31-9 2/1/222<2.0 DWRPFAS EHENDERSONPerfluorinated Compounds (PFA) in liquid 2/1/22_TITLE_ DWRPFAS EHENDERSONng/LUPFBA375-22-4 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFBS375-73-5 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFDA335-76-2 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFDoA307-55-1 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFDoS79780-39-5 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFDS335-77-3 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFHpA375-85-9 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFHpS375-92-8 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFHxA307-24-4 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFHxS355-46-4 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFNA375-95-1 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFNS68259-12-1 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFOA335-67-1 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFOS1763-23-1 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFPeA2706-90-3 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFPeS2706-91-4 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFTeDA376-06-7 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFTrDA72629-94-8 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFUnA2058-94-8 2/1/222<2.0 WSS Chemistry Laboratory>> 1623 Mail Service Center, Raleigh, NC 27699-1623 (919) 733-3908 Page 1 of 3 "Not Detected" or "U" does not indicate the sample is analyte free but that the analyte is not detected at or above the PQL. AC92119Sample ID: NC DWR Laboratory Section Results/Sample Comments/Qualifier Definitions CAS #Analyte Name PQL Result/ Qualifier Units Method Reference Analysis Date Validated by PFAS: PFAS - Holding time exceeded following receipt by lab. Internal WSS guidelines specify samples must be extracted within 30 days of collection. PFAS: PFAS - J2 - Estimated. The reported value failed to meet the established quality control criteria for either precision or accuracy. Sample Comments NCDEQ-WSS-Chemistry Lab Data Qualifiers A1 The reported value is an average, where at least one result is qualified with a “U”. The PQL is used for the qualified result(S) to calculate the average. B1 Coliform-Countable membranes with less than 20 colonies. Reported value is estimated or is a total of the counts on all filters reported per 100 ml. B2 Coliform-Counts from all filters were zero. The value reported is based on the number of colonies per 100 ml that would have been reported if there had been one colony on the filter representing the largest filtration volume. B3 Coliform-Countable membranes with more than 60 or 80 colonies. The value reported is calculated using the count from the smallest volume filtered and reported as a greater than ">" value. B4 Coliform-Filters have counts of both >60 or 80 and <20. Reported value is estimated or is a total of the counts on all filters reported per 100 ml. B5 Coliform-Too many colonies were present; too numerous to count (TNTC). TNTC is generally defined as >150 colonies. B6 Coliform-Estimated Value. Blank contamination evident. B7 Coliform-Many non-coliform or non-enterococcus colonies or interfering non-coliform or non-enterococcus growth present. In this competitive situation, the reported value may under-represent actual density. BB1 MPN-No wells or tubes gave a positive reaction. Value based upon the appropriate MPN Index and reported as a less than “<” value. BB2 MPN-All wells or tubes gave positive reactions. Value based upon the MPN Index and reported as a greater than “>” value. C Total residual chlorine was present in sample upon receipt in the laboratory; value is estimated. G1 BOD-The dissolved oxygen (DO) depletion of the dilution water blank exceeded 0.2 mg/L. G2 BOD-The bacterial seed controls did not meet the requirement of a DO depletion of at least 2.0 mg/L and/or a DO residual of at least 1.0 mg/L. G3 BOD-No sample dilution met the requirement of a DO depletion of at least 2.0 mg/L and/or a DO residual of at least 1.0 mg/L. G4 BOD-Evidence of toxicity. This is generally characterized by a significant increase in the BOD value as the sample concentration decreases. The reported value is calculated from the highest dilution representing the maximum loading potential and G5 BOD-The glucose/ glutamic acid standard exceeded the range of 198 ± 30.5 mg/L. G7 BOD-Less than 1 mg/L DO remained for all dilutions set. The reported value is an estimated greater than value and is calculated for the dilution using the least amount of sample. G8 BOD-Oxygen usage is less than 2 mg/L for all dilutions set. The reported value is an estimated less than value and is calculated for the dilution using the most amount of sample. G9 BOD-The DO depletion of the dilution water blank produced a negative value. J1 Surrogate recovery limits have been exceeded. J10 Unidentified peak; estimated value. WSS Chemistry Laboratory>> 1623 Mail Service Center, Raleigh, NC 27699-1623 (919) 733-3908 Page 2 of 3 "Not Detected" or "U" does not indicate the sample is analyte free but that the analyte is not detected at or above the PQL. AC92119Sample ID: NC DWR Laboratory Section Results/Sample Comments/Qualifier Definitions CAS #Analyte Name PQL Result/ Qualifier Units Method Reference Analysis Date Validated by J11 The reported value is determined by a one-point estimation rather than against a regression equation. The estimated concentration is less than the laboratory practical quantitation limit and greater than the instrument noise level. This code is used when J12 The calibration verification did not meet the calibration acceptance criterion for field parameters. J2 The reported value failed to meet the established quality control criteria for either precision or accuracy. J3 The sample matrix interfered with the ability to make any accurate determination. J4 The data is questionable because of improper laboratory or field protocols (e.g., composite sample was collected instead of grab, plastic instead of glass container, etc.). J5 Temperature limits exceeded (samples frozen or >6°C) during transport or not verifiable (e.g., no temperature blank provided): non-reportable for NPDES compliance monitoring. J6 The laboratory analysis was from an unpreserved or improperly chemically preserved sample. The data may not be accurate. J7 This qualifier is used to identify analyte concentration exceeding the upper calibration range of the analytical instrument/method. The reported value should be considered estimated. J8 Temperature limits exceeded (samples frozen or >6ºC) during storage, the data may not be accurate. J9 The reported value is determined by a one-point estimation rather than against a regression equation. The estimated concentration is less than the laboratory practical quantitation limit and greater than the laboratory method detection limit. M Sample and duplicate results are "out of control". The sample is non-homogenous (e.g., VOA soil). The reported value is the lower value of duplicate analyses of a sample. N1 Presumptive evidence and estimated value. The component has been tentatively identified base on mass spectral library. N2 There is an indication that the analyte is present, but quality control requirements for confirmation were not met (i.e., presence of analyte was not confirmed by alternate procedures). N3 This code shall be used if the level is too low to permit accurate quantification, but the estimated concentration is less than the laboratory practical quantitation limit and greater than the laboratory method detection limit. This code is not routinely N4 This code shall be used if the level is too low to permit accurate quantification, but the estimated concentration is less than the laboratory practical quantitation limit and greater than the instrument noise level. This code is used when an MDL has not N5 The component has been tentatively identified based on a retention time standard. P Elevated PQL* due to matrix interference and/or sample dilution. Q1 Holding time exceeded prior to receipt by lab. Q2 Holding time exceeded following receipt by lab. S Not enough sample provided to prepare and/or analyze a method-required matrix spike (MS) and/or matrix spike duplicate (MSD). U Indicates that the analyte was analyzed for but not detected above the reported practical quantitation limit*. The number value reported with the "U" qualifier is equal to the laboratory's practical quantitation limit*. U, J6 The laboratory analysis was from an unpreserved or improperly chemically preserved sample. The data may not be accurate. UU Indicates that the analyte was not detected by a screen analysis. The number value was determined by a one-point estimation at the PQL. V Indicates the analyte was detected in both the sample and the associated method blank. Note: The value in the blank shall not be subtracted from the associated samples. X1 Sample not screened for this compound. X2 Sampled, but analysis lost or not performed-field error. X3 Sampled, but analysis lost or not performed-lab error. Y Elevated PQL* due to insufficient sample size. Z1 Inability to analyze the sample. Z2 Questions concerning data reliability. WSS Chemistry Laboratory>> 1623 Mail Service Center, Raleigh, NC 27699-1623 (919) 733-3908 Page 3 of 3 "Not Detected" or "U" does not indicate the sample is analyte free but that the analyte is not detected at or above the PQL. PO Number # Loc. Descr.:KC KENNETH CAIN Loc. Type:Rain Water Collector:N MILLER Collect Date:11/23/2021 Collect Time:11:12 Date Received:12/03/2021 Time Received:10:00 Location ID:33 County:Bladen Region:Fayetteville Labworks LoginID TASCENZO1Sample Matrix:EXPERIMENTAL SOLUTION Report Print Date: North Carolina Division of Water Resources Water Sciences Section Laboratory Results W111621-33VisitID Sample Depth DAQReport To River Basin 03/11/2022 Emergency YESCOC Yes/No Sample ID:AC92120 3/11/22Final Report Date: Final Report If this report is labeled preliminary report, the results have not been validated. Do not use for Regulatory purposes. Hand DeliveredDelivery Method COCPriority AC92120 Analysis Date Method Reference Result/ QualifierPQLAnalyte NameCAS #Units Validated by LAB ESTAFFORD1°CSample temperature at receipt by lab 12/3/211.8 Others DWRPFAS EHENDERSONng/LU11Cl-PF3ONS 2/1/222<2.0 DWRPFAS EHENDERSONng/LU4:2 FTS757124-72-4 2/1/222<2.0 DWRPFAS EHENDERSONng/LU6:2 FTS27619-97-2 2/1/222<2.0 DWRPFAS EHENDERSONng/LU8:2 FTS39108-34-4 2/1/222<2.0 DWRPFAS EHENDERSONng/LU9Cl-PF3ONS73606-19-6 2/1/222<2.0 DWRPFAS EHENDERSONng/LUHFPO-DA13252-13-6 2/1/222<2.0 DWRPFAS EHENDERSONng/LUNaDONA919005-14-4 2/1/222<2.0 DWRPFAS EHENDERSONng/LUN-EtFOSAA2991-50-6 2/1/222<2.0 DWRPFAS EHENDERSONng/LJ2N-MeFOSAA2355-31-9 2/1/222<2.0 DWRPFAS EHENDERSONPerfluorinated Compounds (PFA) in liquid 2/1/22_TITLE_ DWRPFAS EHENDERSONng/LUPFBA375-22-4 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFBS375-73-5 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFDA335-76-2 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFDoA307-55-1 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFDoS79780-39-5 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFDS335-77-3 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFHpA375-85-9 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFHpS375-92-8 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFHxA307-24-4 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFHxS355-46-4 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFNA375-95-1 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFNS68259-12-1 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFOA335-67-1 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFOS1763-23-1 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFPeA2706-90-3 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFPeS2706-91-4 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFTeDA376-06-7 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFTrDA72629-94-8 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFUnA2058-94-8 2/1/222<2.0 WSS Chemistry Laboratory>> 1623 Mail Service Center, Raleigh, NC 27699-1623 (919) 733-3908 Page 1 of 3 "Not Detected" or "U" does not indicate the sample is analyte free but that the analyte is not detected at or above the PQL. AC92120Sample ID: NC DWR Laboratory Section Results/Sample Comments/Qualifier Definitions CAS #Analyte Name PQL Result/ Qualifier Units Method Reference Analysis Date Validated by PFAS: PFAS -J2 - reported value failed to meet the established quality control criteria for either precision or accuracy. Sample Comments NCDEQ-WSS-Chemistry Lab Data Qualifiers A1 The reported value is an average, where at least one result is qualified with a “U”. The PQL is used for the qualified result(S) to calculate the average. B1 Coliform-Countable membranes with less than 20 colonies. Reported value is estimated or is a total of the counts on all filters reported per 100 ml. B2 Coliform-Counts from all filters were zero. The value reported is based on the number of colonies per 100 ml that would have been reported if there had been one colony on the filter representing the largest filtration volume. B3 Coliform-Countable membranes with more than 60 or 80 colonies. The value reported is calculated using the count from the smallest volume filtered and reported as a greater than ">" value. B4 Coliform-Filters have counts of both >60 or 80 and <20. Reported value is estimated or is a total of the counts on all filters reported per 100 ml. B5 Coliform-Too many colonies were present; too numerous to count (TNTC). TNTC is generally defined as >150 colonies. B6 Coliform-Estimated Value. Blank contamination evident. B7 Coliform-Many non-coliform or non-enterococcus colonies or interfering non-coliform or non-enterococcus growth present. In this competitive situation, the reported value may under-represent actual density. BB1 MPN-No wells or tubes gave a positive reaction. Value based upon the appropriate MPN Index and reported as a less than “<” value. BB2 MPN-All wells or tubes gave positive reactions. Value based upon the MPN Index and reported as a greater than “>” value. C Total residual chlorine was present in sample upon receipt in the laboratory; value is estimated. G1 BOD-The dissolved oxygen (DO) depletion of the dilution water blank exceeded 0.2 mg/L. G2 BOD-The bacterial seed controls did not meet the requirement of a DO depletion of at least 2.0 mg/L and/or a DO residual of at least 1.0 mg/L. G3 BOD-No sample dilution met the requirement of a DO depletion of at least 2.0 mg/L and/or a DO residual of at least 1.0 mg/L. G4 BOD-Evidence of toxicity. This is generally characterized by a significant increase in the BOD value as the sample concentration decreases. The reported value is calculated from the highest dilution representing the maximum loading potential and G5 BOD-The glucose/ glutamic acid standard exceeded the range of 198 ± 30.5 mg/L. G7 BOD-Less than 1 mg/L DO remained for all dilutions set. The reported value is an estimated greater than value and is calculated for the dilution using the least amount of sample. G8 BOD-Oxygen usage is less than 2 mg/L for all dilutions set. The reported value is an estimated less than value and is calculated for the dilution using the most amount of sample. G9 BOD-The DO depletion of the dilution water blank produced a negative value. J1 Surrogate recovery limits have been exceeded. J10 Unidentified peak; estimated value. WSS Chemistry Laboratory>> 1623 Mail Service Center, Raleigh, NC 27699-1623 (919) 733-3908 Page 2 of 3 "Not Detected" or "U" does not indicate the sample is analyte free but that the analyte is not detected at or above the PQL. AC92120Sample ID: NC DWR Laboratory Section Results/Sample Comments/Qualifier Definitions CAS #Analyte Name PQL Result/ Qualifier Units Method Reference Analysis Date Validated by J11 The reported value is determined by a one-point estimation rather than against a regression equation. The estimated concentration is less than the laboratory practical quantitation limit and greater than the instrument noise level. This code is used when J12 The calibration verification did not meet the calibration acceptance criterion for field parameters. J2 The reported value failed to meet the established quality control criteria for either precision or accuracy. J3 The sample matrix interfered with the ability to make any accurate determination. J4 The data is questionable because of improper laboratory or field protocols (e.g., composite sample was collected instead of grab, plastic instead of glass container, etc.). J5 Temperature limits exceeded (samples frozen or >6°C) during transport or not verifiable (e.g., no temperature blank provided): non-reportable for NPDES compliance monitoring. J6 The laboratory analysis was from an unpreserved or improperly chemically preserved sample. The data may not be accurate. J7 This qualifier is used to identify analyte concentration exceeding the upper calibration range of the analytical instrument/method. The reported value should be considered estimated. J8 Temperature limits exceeded (samples frozen or >6ºC) during storage, the data may not be accurate. J9 The reported value is determined by a one-point estimation rather than against a regression equation. The estimated concentration is less than the laboratory practical quantitation limit and greater than the laboratory method detection limit. M Sample and duplicate results are "out of control". The sample is non-homogenous (e.g., VOA soil). The reported value is the lower value of duplicate analyses of a sample. N1 Presumptive evidence and estimated value. The component has been tentatively identified base on mass spectral library. N2 There is an indication that the analyte is present, but quality control requirements for confirmation were not met (i.e., presence of analyte was not confirmed by alternate procedures). N3 This code shall be used if the level is too low to permit accurate quantification, but the estimated concentration is less than the laboratory practical quantitation limit and greater than the laboratory method detection limit. This code is not routinely N4 This code shall be used if the level is too low to permit accurate quantification, but the estimated concentration is less than the laboratory practical quantitation limit and greater than the instrument noise level. This code is used when an MDL has not N5 The component has been tentatively identified based on a retention time standard. P Elevated PQL* due to matrix interference and/or sample dilution. Q1 Holding time exceeded prior to receipt by lab. Q2 Holding time exceeded following receipt by lab. S Not enough sample provided to prepare and/or analyze a method-required matrix spike (MS) and/or matrix spike duplicate (MSD). U Indicates that the analyte was analyzed for but not detected above the reported practical quantitation limit*. The number value reported with the "U" qualifier is equal to the laboratory's practical quantitation limit*. U, J6 The laboratory analysis was from an unpreserved or improperly chemically preserved sample. The data may not be accurate. UU Indicates that the analyte was not detected by a screen analysis. The number value was determined by a one-point estimation at the PQL. V Indicates the analyte was detected in both the sample and the associated method blank. Note: The value in the blank shall not be subtracted from the associated samples. X1 Sample not screened for this compound. X2 Sampled, but analysis lost or not performed-field error. X3 Sampled, but analysis lost or not performed-lab error. Y Elevated PQL* due to insufficient sample size. Z1 Inability to analyze the sample. Z2 Questions concerning data reliability. WSS Chemistry Laboratory>> 1623 Mail Service Center, Raleigh, NC 27699-1623 (919) 733-3908 Page 3 of 3 "Not Detected" or "U" does not indicate the sample is analyte free but that the analyte is not detected at or above the PQL. PO Number # Loc. Descr.:KC KENNETH CAIN (Dry) Loc. Type:Rain Water Collector:N MILLER Collect Date:11/23/2021 Collect Time:11:12 Date Received:12/03/2021 Time Received:10:00 Location ID:33D County:Bladen Region:Fayetteville Labworks LoginID TASCENZO1Sample Matrix:EXPERIMENTAL SOLUTION Report Print Date: North Carolina Division of Water Resources Water Sciences Section Laboratory Results D111621-33VisitID Sample Depth DAQReport To River Basin 03/11/2022 Emergency YESCOC Yes/No Sample ID:AC92121 3/11/22Final Report Date: Final Report If this report is labeled preliminary report, the results have not been validated. Do not use for Regulatory purposes. Hand DeliveredDelivery Method COCPriority AC92121 Analysis Date Method Reference Result/ QualifierPQLAnalyte NameCAS #Units Validated by LAB ESTAFFORD1°CSample temperature at receipt by lab 12/3/211.8 Others DWRPFAS EHENDERSONng/LU11Cl-PF3ONS 2/1/222<2.0 DWRPFAS EHENDERSONng/LU4:2 FTS757124-72-4 2/1/222<2.0 DWRPFAS EHENDERSONng/LU6:2 FTS27619-97-2 2/1/222<2.0 DWRPFAS EHENDERSONng/LU8:2 FTS39108-34-4 2/1/222<2.0 DWRPFAS EHENDERSONng/LU9Cl-PF3ONS73606-19-6 2/1/222<2.0 DWRPFAS EHENDERSONng/LUHFPO-DA13252-13-6 2/1/222<2.0 DWRPFAS EHENDERSONng/LUNaDONA919005-14-4 2/1/222<2.0 DWRPFAS EHENDERSONng/LUN-EtFOSAA2991-50-6 2/1/222<2.0 DWRPFAS EHENDERSONng/LJ2N-MeFOSAA2355-31-9 2/1/222<2.0 DWRPFAS EHENDERSONPerfluorinated Compounds (PFA) in liquid 2/1/22_TITLE_ DWRPFAS EHENDERSONng/LUPFBA375-22-4 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFBS375-73-5 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFDA335-76-2 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFDoA307-55-1 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFDoS79780-39-5 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFDS335-77-3 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFHpA375-85-9 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFHpS375-92-8 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFHxA307-24-4 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFHxS355-46-4 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFNA375-95-1 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFNS68259-12-1 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFOA335-67-1 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFOS1763-23-1 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFPeA2706-90-3 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFPeS2706-91-4 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFTeDA376-06-7 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFTrDA72629-94-8 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFUnA2058-94-8 2/1/222<2.0 WSS Chemistry Laboratory>> 1623 Mail Service Center, Raleigh, NC 27699-1623 (919) 733-3908 Page 1 of 3 "Not Detected" or "U" does not indicate the sample is analyte free but that the analyte is not detected at or above the PQL. AC92121Sample ID: NC DWR Laboratory Section Results/Sample Comments/Qualifier Definitions CAS #Analyte Name PQL Result/ Qualifier Units Method Reference Analysis Date Validated by PFAS: PFAS - Holding time exceeded following receipt by lab. Internal WSS guidelines specify samples must be extracted within 30 days of collection. PFAS: PFAS -J2 - reported value failed to meet the established quality control criteria for either precision or accuracy. Sample Comments NCDEQ-WSS-Chemistry Lab Data Qualifiers A1 The reported value is an average, where at least one result is qualified with a “U”. The PQL is used for the qualified result(S) to calculate the average. B1 Coliform-Countable membranes with less than 20 colonies. Reported value is estimated or is a total of the counts on all filters reported per 100 ml. B2 Coliform-Counts from all filters were zero. The value reported is based on the number of colonies per 100 ml that would have been reported if there had been one colony on the filter representing the largest filtration volume. B3 Coliform-Countable membranes with more than 60 or 80 colonies. The value reported is calculated using the count from the smallest volume filtered and reported as a greater than ">" value. B4 Coliform-Filters have counts of both >60 or 80 and <20. Reported value is estimated or is a total of the counts on all filters reported per 100 ml. B5 Coliform-Too many colonies were present; too numerous to count (TNTC). TNTC is generally defined as >150 colonies. B6 Coliform-Estimated Value. Blank contamination evident. B7 Coliform-Many non-coliform or non-enterococcus colonies or interfering non-coliform or non-enterococcus growth present. In this competitive situation, the reported value may under-represent actual density. BB1 MPN-No wells or tubes gave a positive reaction. Value based upon the appropriate MPN Index and reported as a less than “<” value. BB2 MPN-All wells or tubes gave positive reactions. Value based upon the MPN Index and reported as a greater than “>” value. C Total residual chlorine was present in sample upon receipt in the laboratory; value is estimated. G1 BOD-The dissolved oxygen (DO) depletion of the dilution water blank exceeded 0.2 mg/L. G2 BOD-The bacterial seed controls did not meet the requirement of a DO depletion of at least 2.0 mg/L and/or a DO residual of at least 1.0 mg/L. G3 BOD-No sample dilution met the requirement of a DO depletion of at least 2.0 mg/L and/or a DO residual of at least 1.0 mg/L. G4 BOD-Evidence of toxicity. This is generally characterized by a significant increase in the BOD value as the sample concentration decreases. The reported value is calculated from the highest dilution representing the maximum loading potential and G5 BOD-The glucose/ glutamic acid standard exceeded the range of 198 ± 30.5 mg/L. G7 BOD-Less than 1 mg/L DO remained for all dilutions set. The reported value is an estimated greater than value and is calculated for the dilution using the least amount of sample. G8 BOD-Oxygen usage is less than 2 mg/L for all dilutions set. The reported value is an estimated less than value and is calculated for the dilution using the most amount of sample. G9 BOD-The DO depletion of the dilution water blank produced a negative value. J1 Surrogate recovery limits have been exceeded. J10 Unidentified peak; estimated value. WSS Chemistry Laboratory>> 1623 Mail Service Center, Raleigh, NC 27699-1623 (919) 733-3908 Page 2 of 3 "Not Detected" or "U" does not indicate the sample is analyte free but that the analyte is not detected at or above the PQL. AC92121Sample ID: NC DWR Laboratory Section Results/Sample Comments/Qualifier Definitions CAS #Analyte Name PQL Result/ Qualifier Units Method Reference Analysis Date Validated by J11 The reported value is determined by a one-point estimation rather than against a regression equation. The estimated concentration is less than the laboratory practical quantitation limit and greater than the instrument noise level. This code is used when J12 The calibration verification did not meet the calibration acceptance criterion for field parameters. J2 The reported value failed to meet the established quality control criteria for either precision or accuracy. J3 The sample matrix interfered with the ability to make any accurate determination. J4 The data is questionable because of improper laboratory or field protocols (e.g., composite sample was collected instead of grab, plastic instead of glass container, etc.). J5 Temperature limits exceeded (samples frozen or >6°C) during transport or not verifiable (e.g., no temperature blank provided): non-reportable for NPDES compliance monitoring. J6 The laboratory analysis was from an unpreserved or improperly chemically preserved sample. The data may not be accurate. J7 This qualifier is used to identify analyte concentration exceeding the upper calibration range of the analytical instrument/method. The reported value should be considered estimated. J8 Temperature limits exceeded (samples frozen or >6ºC) during storage, the data may not be accurate. J9 The reported value is determined by a one-point estimation rather than against a regression equation. The estimated concentration is less than the laboratory practical quantitation limit and greater than the laboratory method detection limit. M Sample and duplicate results are "out of control". The sample is non-homogenous (e.g., VOA soil). The reported value is the lower value of duplicate analyses of a sample. N1 Presumptive evidence and estimated value. The component has been tentatively identified base on mass spectral library. N2 There is an indication that the analyte is present, but quality control requirements for confirmation were not met (i.e., presence of analyte was not confirmed by alternate procedures). N3 This code shall be used if the level is too low to permit accurate quantification, but the estimated concentration is less than the laboratory practical quantitation limit and greater than the laboratory method detection limit. This code is not routinely N4 This code shall be used if the level is too low to permit accurate quantification, but the estimated concentration is less than the laboratory practical quantitation limit and greater than the instrument noise level. This code is used when an MDL has not N5 The component has been tentatively identified based on a retention time standard. P Elevated PQL* due to matrix interference and/or sample dilution. Q1 Holding time exceeded prior to receipt by lab. Q2 Holding time exceeded following receipt by lab. S Not enough sample provided to prepare and/or analyze a method-required matrix spike (MS) and/or matrix spike duplicate (MSD). U Indicates that the analyte was analyzed for but not detected above the reported practical quantitation limit*. The number value reported with the "U" qualifier is equal to the laboratory's practical quantitation limit*. U, J6 The laboratory analysis was from an unpreserved or improperly chemically preserved sample. The data may not be accurate. UU Indicates that the analyte was not detected by a screen analysis. The number value was determined by a one-point estimation at the PQL. V Indicates the analyte was detected in both the sample and the associated method blank. Note: The value in the blank shall not be subtracted from the associated samples. X1 Sample not screened for this compound. X2 Sampled, but analysis lost or not performed-field error. X3 Sampled, but analysis lost or not performed-lab error. Y Elevated PQL* due to insufficient sample size. Z1 Inability to analyze the sample. Z2 Questions concerning data reliability. WSS Chemistry Laboratory>> 1623 Mail Service Center, Raleigh, NC 27699-1623 (919) 733-3908 Page 3 of 3 "Not Detected" or "U" does not indicate the sample is analyte free but that the analyte is not detected at or above the PQL. PO Number # Loc. Descr.:FISHFARM_21 Loc. Type:Rain Water Collector:N MILLER Collect Date:11/23/2021 Collect Time:11:56 Date Received:12/03/2021 Time Received:10:00 Location ID:21 County:Cumberland Region:Fayetteville Labworks LoginID TASCENZO1Sample Matrix:EXPERIMENTAL SOLUTION Report Print Date: North Carolina Division of Water Resources Water Sciences Section Laboratory Results W111621-21VisitID Sample Depth DAQReport To River Basin 03/11/2022 Emergency YESCOC Yes/No Sample ID:AC92122 3/11/22Final Report Date: Final Report If this report is labeled preliminary report, the results have not been validated. Do not use for Regulatory purposes. Hand DeliveredDelivery Method COCPriority AC92122 Analysis Date Method Reference Result/ QualifierPQLAnalyte NameCAS #Units Validated by LAB ESTAFFORD1°CSample temperature at receipt by lab 12/3/211.8 Others DWRPFAS EHENDERSONng/LU11Cl-PF3ONS 2/1/222<2.0 DWRPFAS EHENDERSONng/LU4:2 FTS757124-72-4 2/1/222<2.0 DWRPFAS EHENDERSONng/LU6:2 FTS27619-97-2 2/1/222<2.0 DWRPFAS EHENDERSONng/LU8:2 FTS39108-34-4 2/1/222<2.0 DWRPFAS EHENDERSONng/LU9Cl-PF3ONS73606-19-6 2/1/222<2.0 DWRPFAS EHENDERSONng/LUHFPO-DA13252-13-6 2/1/222<2.0 DWRPFAS EHENDERSONng/LUNaDONA919005-14-4 2/1/222<2.0 DWRPFAS EHENDERSONng/LJ2N-EtFOSAA2991-50-6 2/1/222<2.0 DWRPFAS EHENDERSONng/LJ2N-MeFOSAA2355-31-9 2/1/222<2.0 DWRPFAS EHENDERSONPerfluorinated Compounds (PFA) in liquid 2/1/22_TITLE_ DWRPFAS EHENDERSONng/LUPFBA375-22-4 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFBS375-73-5 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFDA335-76-2 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFDoA307-55-1 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFDoS79780-39-5 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFDS335-77-3 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFHpA375-85-9 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFHpS375-92-8 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFHxA307-24-4 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFHxS355-46-4 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFNA375-95-1 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFNS68259-12-1 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFOA335-67-1 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFOS1763-23-1 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFPeA2706-90-3 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFPeS2706-91-4 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFTeDA376-06-7 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFTrDA72629-94-8 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFUnA2058-94-8 2/1/222<2.0 WSS Chemistry Laboratory>> 1623 Mail Service Center, Raleigh, NC 27699-1623 (919) 733-3908 Page 1 of 3 "Not Detected" or "U" does not indicate the sample is analyte free but that the analyte is not detected at or above the PQL. AC92122Sample ID: NC DWR Laboratory Section Results/Sample Comments/Qualifier Definitions CAS #Analyte Name PQL Result/ Qualifier Units Method Reference Analysis Date Validated by PFAS: PFAS - Holding time exceeded following receipt by lab. Internal WSS guidelines specify samples must be extracted within 30 days of collection. PFAS: PFAS - J2 - Estimated. The reported value failed to meet the established quality control criteria for either precision or accuracy. Sample Comments NCDEQ-WSS-Chemistry Lab Data Qualifiers A1 The reported value is an average, where at least one result is qualified with a “U”. The PQL is used for the qualified result(S) to calculate the average. B1 Coliform-Countable membranes with less than 20 colonies. Reported value is estimated or is a total of the counts on all filters reported per 100 ml. B2 Coliform-Counts from all filters were zero. The value reported is based on the number of colonies per 100 ml that would have been reported if there had been one colony on the filter representing the largest filtration volume. B3 Coliform-Countable membranes with more than 60 or 80 colonies. The value reported is calculated using the count from the smallest volume filtered and reported as a greater than ">" value. B4 Coliform-Filters have counts of both >60 or 80 and <20. Reported value is estimated or is a total of the counts on all filters reported per 100 ml. B5 Coliform-Too many colonies were present; too numerous to count (TNTC). TNTC is generally defined as >150 colonies. B6 Coliform-Estimated Value. Blank contamination evident. B7 Coliform-Many non-coliform or non-enterococcus colonies or interfering non-coliform or non-enterococcus growth present. In this competitive situation, the reported value may under-represent actual density. BB1 MPN-No wells or tubes gave a positive reaction. Value based upon the appropriate MPN Index and reported as a less than “<” value. BB2 MPN-All wells or tubes gave positive reactions. Value based upon the MPN Index and reported as a greater than “>” value. C Total residual chlorine was present in sample upon receipt in the laboratory; value is estimated. G1 BOD-The dissolved oxygen (DO) depletion of the dilution water blank exceeded 0.2 mg/L. G2 BOD-The bacterial seed controls did not meet the requirement of a DO depletion of at least 2.0 mg/L and/or a DO residual of at least 1.0 mg/L. G3 BOD-No sample dilution met the requirement of a DO depletion of at least 2.0 mg/L and/or a DO residual of at least 1.0 mg/L. G4 BOD-Evidence of toxicity. This is generally characterized by a significant increase in the BOD value as the sample concentration decreases. The reported value is calculated from the highest dilution representing the maximum loading potential and G5 BOD-The glucose/ glutamic acid standard exceeded the range of 198 ± 30.5 mg/L. G7 BOD-Less than 1 mg/L DO remained for all dilutions set. The reported value is an estimated greater than value and is calculated for the dilution using the least amount of sample. G8 BOD-Oxygen usage is less than 2 mg/L for all dilutions set. The reported value is an estimated less than value and is calculated for the dilution using the most amount of sample. G9 BOD-The DO depletion of the dilution water blank produced a negative value. J1 Surrogate recovery limits have been exceeded. J10 Unidentified peak; estimated value. WSS Chemistry Laboratory>> 1623 Mail Service Center, Raleigh, NC 27699-1623 (919) 733-3908 Page 2 of 3 "Not Detected" or "U" does not indicate the sample is analyte free but that the analyte is not detected at or above the PQL. AC92122Sample ID: NC DWR Laboratory Section Results/Sample Comments/Qualifier Definitions CAS #Analyte Name PQL Result/ Qualifier Units Method Reference Analysis Date Validated by J11 The reported value is determined by a one-point estimation rather than against a regression equation. The estimated concentration is less than the laboratory practical quantitation limit and greater than the instrument noise level. This code is used when J12 The calibration verification did not meet the calibration acceptance criterion for field parameters. J2 The reported value failed to meet the established quality control criteria for either precision or accuracy. J3 The sample matrix interfered with the ability to make any accurate determination. J4 The data is questionable because of improper laboratory or field protocols (e.g., composite sample was collected instead of grab, plastic instead of glass container, etc.). J5 Temperature limits exceeded (samples frozen or >6°C) during transport or not verifiable (e.g., no temperature blank provided): non-reportable for NPDES compliance monitoring. J6 The laboratory analysis was from an unpreserved or improperly chemically preserved sample. The data may not be accurate. J7 This qualifier is used to identify analyte concentration exceeding the upper calibration range of the analytical instrument/method. The reported value should be considered estimated. J8 Temperature limits exceeded (samples frozen or >6ºC) during storage, the data may not be accurate. J9 The reported value is determined by a one-point estimation rather than against a regression equation. The estimated concentration is less than the laboratory practical quantitation limit and greater than the laboratory method detection limit. M Sample and duplicate results are "out of control". The sample is non-homogenous (e.g., VOA soil). The reported value is the lower value of duplicate analyses of a sample. N1 Presumptive evidence and estimated value. The component has been tentatively identified base on mass spectral library. N2 There is an indication that the analyte is present, but quality control requirements for confirmation were not met (i.e., presence of analyte was not confirmed by alternate procedures). N3 This code shall be used if the level is too low to permit accurate quantification, but the estimated concentration is less than the laboratory practical quantitation limit and greater than the laboratory method detection limit. This code is not routinely N4 This code shall be used if the level is too low to permit accurate quantification, but the estimated concentration is less than the laboratory practical quantitation limit and greater than the instrument noise level. This code is used when an MDL has not N5 The component has been tentatively identified based on a retention time standard. P Elevated PQL* due to matrix interference and/or sample dilution. Q1 Holding time exceeded prior to receipt by lab. Q2 Holding time exceeded following receipt by lab. S Not enough sample provided to prepare and/or analyze a method-required matrix spike (MS) and/or matrix spike duplicate (MSD). U Indicates that the analyte was analyzed for but not detected above the reported practical quantitation limit*. The number value reported with the "U" qualifier is equal to the laboratory's practical quantitation limit*. U, J6 The laboratory analysis was from an unpreserved or improperly chemically preserved sample. The data may not be accurate. UU Indicates that the analyte was not detected by a screen analysis. The number value was determined by a one-point estimation at the PQL. V Indicates the analyte was detected in both the sample and the associated method blank. Note: The value in the blank shall not be subtracted from the associated samples. X1 Sample not screened for this compound. X2 Sampled, but analysis lost or not performed-field error. X3 Sampled, but analysis lost or not performed-lab error. Y Elevated PQL* due to insufficient sample size. Z1 Inability to analyze the sample. Z2 Questions concerning data reliability. WSS Chemistry Laboratory>> 1623 Mail Service Center, Raleigh, NC 27699-1623 (919) 733-3908 Page 3 of 3 "Not Detected" or "U" does not indicate the sample is analyte free but that the analyte is not detected at or above the PQL. PO Number # Loc. Descr.:FISHFARM_21 (DRY) Loc. Type:Rain Water Collector:N MILLER Collect Date:11/23/2021 Collect Time:11:56 Date Received:12/03/2021 Time Received:10:00 Location ID:21D County:Cumberland Region:Fayetteville Labworks LoginID TASCENZO1Sample Matrix:EXPERIMENTAL SOLUTION Report Print Date: North Carolina Division of Water Resources Water Sciences Section Laboratory Results D111621-21VisitID Sample Depth DAQReport To River Basin 03/11/2022 Emergency YESCOC Yes/No Sample ID:AC92123 3/11/22Final Report Date: Final Report If this report is labeled preliminary report, the results have not been validated. Do not use for Regulatory purposes. Hand DeliveredDelivery Method COCPriority AC92123 Analysis Date Method Reference Result/ QualifierPQLAnalyte NameCAS #Units Validated by LAB ESTAFFORD1°CSample temperature at receipt by lab 12/3/211.8 Others DWRPFAS EHENDERSONng/LU11Cl-PF3ONS 2/1/222<2.0 DWRPFAS EHENDERSONng/LU4:2 FTS757124-72-4 2/1/222<2.0 DWRPFAS EHENDERSONng/LU6:2 FTS27619-97-2 2/1/222<2.0 DWRPFAS EHENDERSONng/LU8:2 FTS39108-34-4 2/1/222<2.0 DWRPFAS EHENDERSONng/LU9Cl-PF3ONS73606-19-6 2/1/222<2.0 DWRPFAS EHENDERSONng/LHFPO-DA13252-13-6 2/1/2226.7 DWRPFAS EHENDERSONng/LUNaDONA919005-14-4 2/1/222<2.0 DWRPFAS EHENDERSONng/LJ2N-EtFOSAA2991-50-6 2/1/222<2.0 DWRPFAS EHENDERSONng/LJ2N-MeFOSAA2355-31-9 2/1/222<2.0 DWRPFAS EHENDERSONPerfluorinated Compounds (PFA) in liquid 2/1/22_TITLE_ DWRPFAS EHENDERSONng/LUPFBA375-22-4 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFBS375-73-5 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFDA335-76-2 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFDoA307-55-1 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFDoS79780-39-5 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFDS335-77-3 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFHpA375-85-9 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFHpS375-92-8 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFHxA307-24-4 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFHxS355-46-4 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFNA375-95-1 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFNS68259-12-1 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFOA335-67-1 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFOS1763-23-1 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFPeA2706-90-3 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFPeS2706-91-4 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFTeDA376-06-7 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFTrDA72629-94-8 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFUnA2058-94-8 2/1/222<2.0 WSS Chemistry Laboratory>> 1623 Mail Service Center, Raleigh, NC 27699-1623 (919) 733-3908 Page 1 of 3 "Not Detected" or "U" does not indicate the sample is analyte free but that the analyte is not detected at or above the PQL. AC92123Sample ID: NC DWR Laboratory Section Results/Sample Comments/Qualifier Definitions CAS #Analyte Name PQL Result/ Qualifier Units Method Reference Analysis Date Validated by PFAS: PFAS - Holding time exceeded following receipt by lab. Internal WSS guidelines specify samples must be extracted within 30 days of collection. PFAS: PFAS - J2 - Estimated. The reported value failed to meet the established quality control criteria for either precision or accuracy. Sample Comments NCDEQ-WSS-Chemistry Lab Data Qualifiers A1 The reported value is an average, where at least one result is qualified with a “U”. The PQL is used for the qualified result(S) to calculate the average. B1 Coliform-Countable membranes with less than 20 colonies. Reported value is estimated or is a total of the counts on all filters reported per 100 ml. B2 Coliform-Counts from all filters were zero. The value reported is based on the number of colonies per 100 ml that would have been reported if there had been one colony on the filter representing the largest filtration volume. B3 Coliform-Countable membranes with more than 60 or 80 colonies. The value reported is calculated using the count from the smallest volume filtered and reported as a greater than ">" value. B4 Coliform-Filters have counts of both >60 or 80 and <20. Reported value is estimated or is a total of the counts on all filters reported per 100 ml. B5 Coliform-Too many colonies were present; too numerous to count (TNTC). TNTC is generally defined as >150 colonies. B6 Coliform-Estimated Value. Blank contamination evident. B7 Coliform-Many non-coliform or non-enterococcus colonies or interfering non-coliform or non-enterococcus growth present. In this competitive situation, the reported value may under-represent actual density. BB1 MPN-No wells or tubes gave a positive reaction. Value based upon the appropriate MPN Index and reported as a less than “<” value. BB2 MPN-All wells or tubes gave positive reactions. Value based upon the MPN Index and reported as a greater than “>” value. C Total residual chlorine was present in sample upon receipt in the laboratory; value is estimated. G1 BOD-The dissolved oxygen (DO) depletion of the dilution water blank exceeded 0.2 mg/L. G2 BOD-The bacterial seed controls did not meet the requirement of a DO depletion of at least 2.0 mg/L and/or a DO residual of at least 1.0 mg/L. G3 BOD-No sample dilution met the requirement of a DO depletion of at least 2.0 mg/L and/or a DO residual of at least 1.0 mg/L. G4 BOD-Evidence of toxicity. This is generally characterized by a significant increase in the BOD value as the sample concentration decreases. The reported value is calculated from the highest dilution representing the maximum loading potential and G5 BOD-The glucose/ glutamic acid standard exceeded the range of 198 ± 30.5 mg/L. G7 BOD-Less than 1 mg/L DO remained for all dilutions set. The reported value is an estimated greater than value and is calculated for the dilution using the least amount of sample. G8 BOD-Oxygen usage is less than 2 mg/L for all dilutions set. The reported value is an estimated less than value and is calculated for the dilution using the most amount of sample. G9 BOD-The DO depletion of the dilution water blank produced a negative value. J1 Surrogate recovery limits have been exceeded. J10 Unidentified peak; estimated value. WSS Chemistry Laboratory>> 1623 Mail Service Center, Raleigh, NC 27699-1623 (919) 733-3908 Page 2 of 3 "Not Detected" or "U" does not indicate the sample is analyte free but that the analyte is not detected at or above the PQL. AC92123Sample ID: NC DWR Laboratory Section Results/Sample Comments/Qualifier Definitions CAS #Analyte Name PQL Result/ Qualifier Units Method Reference Analysis Date Validated by J11 The reported value is determined by a one-point estimation rather than against a regression equation. The estimated concentration is less than the laboratory practical quantitation limit and greater than the instrument noise level. This code is used when J12 The calibration verification did not meet the calibration acceptance criterion for field parameters. J2 The reported value failed to meet the established quality control criteria for either precision or accuracy. J3 The sample matrix interfered with the ability to make any accurate determination. J4 The data is questionable because of improper laboratory or field protocols (e.g., composite sample was collected instead of grab, plastic instead of glass container, etc.). J5 Temperature limits exceeded (samples frozen or >6°C) during transport or not verifiable (e.g., no temperature blank provided): non-reportable for NPDES compliance monitoring. J6 The laboratory analysis was from an unpreserved or improperly chemically preserved sample. The data may not be accurate. J7 This qualifier is used to identify analyte concentration exceeding the upper calibration range of the analytical instrument/method. The reported value should be considered estimated. J8 Temperature limits exceeded (samples frozen or >6ºC) during storage, the data may not be accurate. J9 The reported value is determined by a one-point estimation rather than against a regression equation. The estimated concentration is less than the laboratory practical quantitation limit and greater than the laboratory method detection limit. M Sample and duplicate results are "out of control". The sample is non-homogenous (e.g., VOA soil). The reported value is the lower value of duplicate analyses of a sample. N1 Presumptive evidence and estimated value. The component has been tentatively identified base on mass spectral library. N2 There is an indication that the analyte is present, but quality control requirements for confirmation were not met (i.e., presence of analyte was not confirmed by alternate procedures). N3 This code shall be used if the level is too low to permit accurate quantification, but the estimated concentration is less than the laboratory practical quantitation limit and greater than the laboratory method detection limit. This code is not routinely N4 This code shall be used if the level is too low to permit accurate quantification, but the estimated concentration is less than the laboratory practical quantitation limit and greater than the instrument noise level. This code is used when an MDL has not N5 The component has been tentatively identified based on a retention time standard. P Elevated PQL* due to matrix interference and/or sample dilution. Q1 Holding time exceeded prior to receipt by lab. Q2 Holding time exceeded following receipt by lab. S Not enough sample provided to prepare and/or analyze a method-required matrix spike (MS) and/or matrix spike duplicate (MSD). U Indicates that the analyte was analyzed for but not detected above the reported practical quantitation limit*. The number value reported with the "U" qualifier is equal to the laboratory's practical quantitation limit*. U, J6 The laboratory analysis was from an unpreserved or improperly chemically preserved sample. The data may not be accurate. UU Indicates that the analyte was not detected by a screen analysis. The number value was determined by a one-point estimation at the PQL. V Indicates the analyte was detected in both the sample and the associated method blank. Note: The value in the blank shall not be subtracted from the associated samples. X1 Sample not screened for this compound. X2 Sampled, but analysis lost or not performed-field error. X3 Sampled, but analysis lost or not performed-lab error. Y Elevated PQL* due to insufficient sample size. Z1 Inability to analyze the sample. Z2 Questions concerning data reliability. WSS Chemistry Laboratory>> 1623 Mail Service Center, Raleigh, NC 27699-1623 (919) 733-3908 Page 3 of 3 "Not Detected" or "U" does not indicate the sample is analyte free but that the analyte is not detected at or above the PQL. PO Number # Loc. Descr.:FISH FARM COLOCATED 21C Loc. Type:Rain Water Collector:N MILLER Collect Date:11/23/2021 Collect Time:11:56 Date Received:12/03/2021 Time Received:10:00 Location ID:21C County:Cumberland Region:Fayetteville Labworks LoginID TASCENZO1Sample Matrix:EXPERIMENTAL SOLUTION Report Print Date: North Carolina Division of Water Resources Water Sciences Section Laboratory Results W111621-21CVisitID Sample Depth DAQReport To River Basin 03/11/2022 Emergency YESCOC Yes/No Sample ID:AC92124 3/11/22Final Report Date: Final Report If this report is labeled preliminary report, the results have not been validated. Do not use for Regulatory purposes. Hand DeliveredDelivery Method COCPriority AC92124 Analysis Date Method Reference Result/ QualifierPQLAnalyte NameCAS #Units Validated by LAB ESTAFFORD1°CSample temperature at receipt by lab 12/3/211.8 Others DWRPFAS EHENDERSONng/LU11Cl-PF3ONS 2/1/222<2.0 DWRPFAS EHENDERSONng/LU4:2 FTS757124-72-4 2/1/222<2.0 DWRPFAS EHENDERSONng/LU6:2 FTS27619-97-2 2/1/222<2.0 DWRPFAS EHENDERSONng/LU8:2 FTS39108-34-4 2/1/222<2.0 DWRPFAS EHENDERSONng/LU9Cl-PF3ONS73606-19-6 2/1/222<2.0 DWRPFAS EHENDERSONng/LUHFPO-DA13252-13-6 2/1/222<2.0 DWRPFAS EHENDERSONng/LUNaDONA919005-14-4 2/1/222<2.0 DWRPFAS EHENDERSONng/LJ2N-EtFOSAA2991-50-6 2/1/222<2.0 DWRPFAS EHENDERSONng/LJ2N-MeFOSAA2355-31-9 2/1/222<2.0 DWRPFAS EHENDERSONPerfluorinated Compounds (PFA) in liquid 2/1/22_TITLE_ DWRPFAS EHENDERSONng/LUPFBA375-22-4 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFBS375-73-5 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFDA335-76-2 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFDoA307-55-1 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFDoS79780-39-5 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFDS335-77-3 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFHpA375-85-9 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFHpS375-92-8 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFHxA307-24-4 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFHxS355-46-4 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFNA375-95-1 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFNS68259-12-1 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFOA335-67-1 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFOS1763-23-1 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFPeA2706-90-3 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFPeS2706-91-4 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFTeDA376-06-7 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFTrDA72629-94-8 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFUnA2058-94-8 2/1/222<2.0 WSS Chemistry Laboratory>> 1623 Mail Service Center, Raleigh, NC 27699-1623 (919) 733-3908 Page 1 of 3 "Not Detected" or "U" does not indicate the sample is analyte free but that the analyte is not detected at or above the PQL. AC92124Sample ID: NC DWR Laboratory Section Results/Sample Comments/Qualifier Definitions CAS #Analyte Name PQL Result/ Qualifier Units Method Reference Analysis Date Validated by PFAS: PFAS - Holding time exceeded following receipt by lab. Internal WSS guidelines specify samples must be extracted within 30 days of collection. PFAS: PFAS - J2 - Estimated. The reported value failed to meet the established quality control criteria for either precision or accuracy. Sample Comments NCDEQ-WSS-Chemistry Lab Data Qualifiers A1 The reported value is an average, where at least one result is qualified with a “U”. The PQL is used for the qualified result(S) to calculate the average. B1 Coliform-Countable membranes with less than 20 colonies. Reported value is estimated or is a total of the counts on all filters reported per 100 ml. B2 Coliform-Counts from all filters were zero. The value reported is based on the number of colonies per 100 ml that would have been reported if there had been one colony on the filter representing the largest filtration volume. B3 Coliform-Countable membranes with more than 60 or 80 colonies. The value reported is calculated using the count from the smallest volume filtered and reported as a greater than ">" value. B4 Coliform-Filters have counts of both >60 or 80 and <20. Reported value is estimated or is a total of the counts on all filters reported per 100 ml. B5 Coliform-Too many colonies were present; too numerous to count (TNTC). TNTC is generally defined as >150 colonies. B6 Coliform-Estimated Value. Blank contamination evident. B7 Coliform-Many non-coliform or non-enterococcus colonies or interfering non-coliform or non-enterococcus growth present. In this competitive situation, the reported value may under-represent actual density. BB1 MPN-No wells or tubes gave a positive reaction. Value based upon the appropriate MPN Index and reported as a less than “<” value. BB2 MPN-All wells or tubes gave positive reactions. Value based upon the MPN Index and reported as a greater than “>” value. C Total residual chlorine was present in sample upon receipt in the laboratory; value is estimated. G1 BOD-The dissolved oxygen (DO) depletion of the dilution water blank exceeded 0.2 mg/L. G2 BOD-The bacterial seed controls did not meet the requirement of a DO depletion of at least 2.0 mg/L and/or a DO residual of at least 1.0 mg/L. G3 BOD-No sample dilution met the requirement of a DO depletion of at least 2.0 mg/L and/or a DO residual of at least 1.0 mg/L. G4 BOD-Evidence of toxicity. This is generally characterized by a significant increase in the BOD value as the sample concentration decreases. The reported value is calculated from the highest dilution representing the maximum loading potential and G5 BOD-The glucose/ glutamic acid standard exceeded the range of 198 ± 30.5 mg/L. G7 BOD-Less than 1 mg/L DO remained for all dilutions set. The reported value is an estimated greater than value and is calculated for the dilution using the least amount of sample. G8 BOD-Oxygen usage is less than 2 mg/L for all dilutions set. The reported value is an estimated less than value and is calculated for the dilution using the most amount of sample. G9 BOD-The DO depletion of the dilution water blank produced a negative value. J1 Surrogate recovery limits have been exceeded. J10 Unidentified peak; estimated value. WSS Chemistry Laboratory>> 1623 Mail Service Center, Raleigh, NC 27699-1623 (919) 733-3908 Page 2 of 3 "Not Detected" or "U" does not indicate the sample is analyte free but that the analyte is not detected at or above the PQL. AC92124Sample ID: NC DWR Laboratory Section Results/Sample Comments/Qualifier Definitions CAS #Analyte Name PQL Result/ Qualifier Units Method Reference Analysis Date Validated by J11 The reported value is determined by a one-point estimation rather than against a regression equation. The estimated concentration is less than the laboratory practical quantitation limit and greater than the instrument noise level. This code is used when J12 The calibration verification did not meet the calibration acceptance criterion for field parameters. J2 The reported value failed to meet the established quality control criteria for either precision or accuracy. J3 The sample matrix interfered with the ability to make any accurate determination. J4 The data is questionable because of improper laboratory or field protocols (e.g., composite sample was collected instead of grab, plastic instead of glass container, etc.). J5 Temperature limits exceeded (samples frozen or >6°C) during transport or not verifiable (e.g., no temperature blank provided): non-reportable for NPDES compliance monitoring. J6 The laboratory analysis was from an unpreserved or improperly chemically preserved sample. The data may not be accurate. J7 This qualifier is used to identify analyte concentration exceeding the upper calibration range of the analytical instrument/method. The reported value should be considered estimated. J8 Temperature limits exceeded (samples frozen or >6ºC) during storage, the data may not be accurate. J9 The reported value is determined by a one-point estimation rather than against a regression equation. The estimated concentration is less than the laboratory practical quantitation limit and greater than the laboratory method detection limit. M Sample and duplicate results are "out of control". The sample is non-homogenous (e.g., VOA soil). The reported value is the lower value of duplicate analyses of a sample. N1 Presumptive evidence and estimated value. The component has been tentatively identified base on mass spectral library. N2 There is an indication that the analyte is present, but quality control requirements for confirmation were not met (i.e., presence of analyte was not confirmed by alternate procedures). N3 This code shall be used if the level is too low to permit accurate quantification, but the estimated concentration is less than the laboratory practical quantitation limit and greater than the laboratory method detection limit. This code is not routinely N4 This code shall be used if the level is too low to permit accurate quantification, but the estimated concentration is less than the laboratory practical quantitation limit and greater than the instrument noise level. This code is used when an MDL has not N5 The component has been tentatively identified based on a retention time standard. P Elevated PQL* due to matrix interference and/or sample dilution. Q1 Holding time exceeded prior to receipt by lab. Q2 Holding time exceeded following receipt by lab. S Not enough sample provided to prepare and/or analyze a method-required matrix spike (MS) and/or matrix spike duplicate (MSD). U Indicates that the analyte was analyzed for but not detected above the reported practical quantitation limit*. The number value reported with the "U" qualifier is equal to the laboratory's practical quantitation limit*. U, J6 The laboratory analysis was from an unpreserved or improperly chemically preserved sample. The data may not be accurate. UU Indicates that the analyte was not detected by a screen analysis. The number value was determined by a one-point estimation at the PQL. V Indicates the analyte was detected in both the sample and the associated method blank. Note: The value in the blank shall not be subtracted from the associated samples. X1 Sample not screened for this compound. X2 Sampled, but analysis lost or not performed-field error. X3 Sampled, but analysis lost or not performed-lab error. Y Elevated PQL* due to insufficient sample size. Z1 Inability to analyze the sample. Z2 Questions concerning data reliability. WSS Chemistry Laboratory>> 1623 Mail Service Center, Raleigh, NC 27699-1623 (919) 733-3908 Page 3 of 3 "Not Detected" or "U" does not indicate the sample is analyte free but that the analyte is not detected at or above the PQL. PO Number # Loc. Descr.:FISH FARM COLOCATED 21C (Dry) Loc. Type:Rain Water Collector:N MILLER Collect Date:11/23/2021 Collect Time:11:56 Date Received:12/03/2021 Time Received:10:00 Location ID:21CD County:Cumberland Region:Fayetteville Labworks LoginID TASCENZO1Sample Matrix:EXPERIMENTAL SOLUTION Report Print Date: North Carolina Division of Water Resources Water Sciences Section Laboratory Results D111621-21CVisitID Sample Depth DAQReport To River Basin 03/11/2022 Emergency YESCOC Yes/No Sample ID:AC92125 3/11/22Final Report Date: Final Report If this report is labeled preliminary report, the results have not been validated. Do not use for Regulatory purposes. Hand DeliveredDelivery Method COCPriority AC92125 Analysis Date Method Reference Result/ QualifierPQLAnalyte NameCAS #Units Validated by LAB ESTAFFORD1°CSample temperature at receipt by lab 12/3/211.8 Others DWRPFAS EHENDERSONng/LU11Cl-PF3ONS 2/1/222<2.0 DWRPFAS EHENDERSONng/LU4:2 FTS757124-72-4 2/1/222<2.0 DWRPFAS EHENDERSONng/LU6:2 FTS27619-97-2 2/1/222<2.0 DWRPFAS EHENDERSONng/LU8:2 FTS39108-34-4 2/1/222<2.0 DWRPFAS EHENDERSONng/LU9Cl-PF3ONS73606-19-6 2/1/222<2.0 DWRPFAS EHENDERSONng/LHFPO-DA13252-13-6 2/1/2223.7 DWRPFAS EHENDERSONng/LUNaDONA919005-14-4 2/1/222<2.0 DWRPFAS EHENDERSONng/LJ2N-EtFOSAA2991-50-6 2/1/222<2.0 DWRPFAS EHENDERSONng/LJ2N-MeFOSAA2355-31-9 2/1/222<2.0 DWRPFAS EHENDERSONPerfluorinated Compounds (PFA) in liquid 2/1/22_TITLE_ DWRPFAS EHENDERSONng/LPFBA375-22-4 2/1/2222.1 DWRPFAS EHENDERSONng/LUPFBS375-73-5 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFDA335-76-2 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFDoA307-55-1 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFDoS79780-39-5 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFDS335-77-3 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFHpA375-85-9 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFHpS375-92-8 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFHxA307-24-4 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFHxS355-46-4 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFNA375-95-1 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFNS68259-12-1 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFOA335-67-1 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFOS1763-23-1 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFPeA2706-90-3 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFPeS2706-91-4 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFTeDA376-06-7 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFTrDA72629-94-8 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFUnA2058-94-8 2/1/222<2.0 WSS Chemistry Laboratory>> 1623 Mail Service Center, Raleigh, NC 27699-1623 (919) 733-3908 Page 1 of 3 "Not Detected" or "U" does not indicate the sample is analyte free but that the analyte is not detected at or above the PQL. AC92125Sample ID: NC DWR Laboratory Section Results/Sample Comments/Qualifier Definitions CAS #Analyte Name PQL Result/ Qualifier Units Method Reference Analysis Date Validated by PFAS: PFAS - Holding time exceeded following receipt by lab. Internal WSS guidelines specify samples must be extracted within 30 days of collection. PFAS: PFAS - J2 - Estimated. The reported value failed to meet the established quality control criteria for either precision or accuracy. Sample Comments NCDEQ-WSS-Chemistry Lab Data Qualifiers A1 The reported value is an average, where at least one result is qualified with a “U”. The PQL is used for the qualified result(S) to calculate the average. B1 Coliform-Countable membranes with less than 20 colonies. Reported value is estimated or is a total of the counts on all filters reported per 100 ml. B2 Coliform-Counts from all filters were zero. The value reported is based on the number of colonies per 100 ml that would have been reported if there had been one colony on the filter representing the largest filtration volume. B3 Coliform-Countable membranes with more than 60 or 80 colonies. The value reported is calculated using the count from the smallest volume filtered and reported as a greater than ">" value. B4 Coliform-Filters have counts of both >60 or 80 and <20. Reported value is estimated or is a total of the counts on all filters reported per 100 ml. B5 Coliform-Too many colonies were present; too numerous to count (TNTC). TNTC is generally defined as >150 colonies. B6 Coliform-Estimated Value. Blank contamination evident. B7 Coliform-Many non-coliform or non-enterococcus colonies or interfering non-coliform or non-enterococcus growth present. In this competitive situation, the reported value may under-represent actual density. BB1 MPN-No wells or tubes gave a positive reaction. Value based upon the appropriate MPN Index and reported as a less than “<” value. BB2 MPN-All wells or tubes gave positive reactions. Value based upon the MPN Index and reported as a greater than “>” value. C Total residual chlorine was present in sample upon receipt in the laboratory; value is estimated. G1 BOD-The dissolved oxygen (DO) depletion of the dilution water blank exceeded 0.2 mg/L. G2 BOD-The bacterial seed controls did not meet the requirement of a DO depletion of at least 2.0 mg/L and/or a DO residual of at least 1.0 mg/L. G3 BOD-No sample dilution met the requirement of a DO depletion of at least 2.0 mg/L and/or a DO residual of at least 1.0 mg/L. G4 BOD-Evidence of toxicity. This is generally characterized by a significant increase in the BOD value as the sample concentration decreases. The reported value is calculated from the highest dilution representing the maximum loading potential and G5 BOD-The glucose/ glutamic acid standard exceeded the range of 198 ± 30.5 mg/L. G7 BOD-Less than 1 mg/L DO remained for all dilutions set. The reported value is an estimated greater than value and is calculated for the dilution using the least amount of sample. G8 BOD-Oxygen usage is less than 2 mg/L for all dilutions set. The reported value is an estimated less than value and is calculated for the dilution using the most amount of sample. G9 BOD-The DO depletion of the dilution water blank produced a negative value. J1 Surrogate recovery limits have been exceeded. J10 Unidentified peak; estimated value. WSS Chemistry Laboratory>> 1623 Mail Service Center, Raleigh, NC 27699-1623 (919) 733-3908 Page 2 of 3 "Not Detected" or "U" does not indicate the sample is analyte free but that the analyte is not detected at or above the PQL. AC92125Sample ID: NC DWR Laboratory Section Results/Sample Comments/Qualifier Definitions CAS #Analyte Name PQL Result/ Qualifier Units Method Reference Analysis Date Validated by J11 The reported value is determined by a one-point estimation rather than against a regression equation. The estimated concentration is less than the laboratory practical quantitation limit and greater than the instrument noise level. This code is used when J12 The calibration verification did not meet the calibration acceptance criterion for field parameters. J2 The reported value failed to meet the established quality control criteria for either precision or accuracy. J3 The sample matrix interfered with the ability to make any accurate determination. J4 The data is questionable because of improper laboratory or field protocols (e.g., composite sample was collected instead of grab, plastic instead of glass container, etc.). J5 Temperature limits exceeded (samples frozen or >6°C) during transport or not verifiable (e.g., no temperature blank provided): non-reportable for NPDES compliance monitoring. J6 The laboratory analysis was from an unpreserved or improperly chemically preserved sample. The data may not be accurate. J7 This qualifier is used to identify analyte concentration exceeding the upper calibration range of the analytical instrument/method. The reported value should be considered estimated. J8 Temperature limits exceeded (samples frozen or >6ºC) during storage, the data may not be accurate. J9 The reported value is determined by a one-point estimation rather than against a regression equation. The estimated concentration is less than the laboratory practical quantitation limit and greater than the laboratory method detection limit. M Sample and duplicate results are "out of control". The sample is non-homogenous (e.g., VOA soil). The reported value is the lower value of duplicate analyses of a sample. N1 Presumptive evidence and estimated value. The component has been tentatively identified base on mass spectral library. N2 There is an indication that the analyte is present, but quality control requirements for confirmation were not met (i.e., presence of analyte was not confirmed by alternate procedures). N3 This code shall be used if the level is too low to permit accurate quantification, but the estimated concentration is less than the laboratory practical quantitation limit and greater than the laboratory method detection limit. This code is not routinely N4 This code shall be used if the level is too low to permit accurate quantification, but the estimated concentration is less than the laboratory practical quantitation limit and greater than the instrument noise level. This code is used when an MDL has not N5 The component has been tentatively identified based on a retention time standard. P Elevated PQL* due to matrix interference and/or sample dilution. Q1 Holding time exceeded prior to receipt by lab. Q2 Holding time exceeded following receipt by lab. S Not enough sample provided to prepare and/or analyze a method-required matrix spike (MS) and/or matrix spike duplicate (MSD). U Indicates that the analyte was analyzed for but not detected above the reported practical quantitation limit*. The number value reported with the "U" qualifier is equal to the laboratory's practical quantitation limit*. U, J6 The laboratory analysis was from an unpreserved or improperly chemically preserved sample. The data may not be accurate. UU Indicates that the analyte was not detected by a screen analysis. The number value was determined by a one-point estimation at the PQL. V Indicates the analyte was detected in both the sample and the associated method blank. Note: The value in the blank shall not be subtracted from the associated samples. X1 Sample not screened for this compound. X2 Sampled, but analysis lost or not performed-field error. X3 Sampled, but analysis lost or not performed-lab error. Y Elevated PQL* due to insufficient sample size. Z1 Inability to analyze the sample. Z2 Questions concerning data reliability. WSS Chemistry Laboratory>> 1623 Mail Service Center, Raleigh, NC 27699-1623 (919) 733-3908 Page 3 of 3 "Not Detected" or "U" does not indicate the sample is analyte free but that the analyte is not detected at or above the PQL. PO Number # Loc. Descr.:FISHFARM_21 FILTER TAPE Loc. Type:Filter Tape Collector:N MILLER Collect Date:11/23/2021 Collect Time:12:05 Date Received:12/03/2021 Time Received:10:00 Location ID:21FT County:Cumberland Region:Fayetteville Labworks LoginID TASCENZO1Sample Matrix:EXPERIMENTAL SOLUTION Report Print Date: North Carolina Division of Water Resources Water Sciences Section Laboratory Results FT111621-21VisitID Sample Depth DAQReport To River Basin 03/11/2022 Emergency YESCOC Yes/No Sample ID:AC92126 3/11/22Final Report Date: Final Report If this report is labeled preliminary report, the results have not been validated. Do not use for Regulatory purposes. Hand DeliveredDelivery Method COCPriority AC92126 Analysis Date Method Reference Result/ QualifierPQLAnalyte NameCAS #Units Validated by LAB ESTAFFORD1°CSample temperature at receipt by lab 12/3/211.8 Others DWRPFAS EHENDERSONng/LU11Cl-PF3ONS 2/1/222<2.0 DWRPFAS EHENDERSONng/LU4:2 FTS757124-72-4 2/1/222<2.0 DWRPFAS EHENDERSONng/LU6:2 FTS27619-97-2 2/1/222<2.0 DWRPFAS EHENDERSONng/LU8:2 FTS39108-34-4 2/1/222<2.0 DWRPFAS EHENDERSONng/LU9Cl-PF3ONS73606-19-6 2/1/222<2.0 DWRPFAS EHENDERSONng/LUHFPO-DA13252-13-6 2/1/222<2.0 DWRPFAS EHENDERSONng/LUNaDONA919005-14-4 2/1/222<2.0 DWRPFAS EHENDERSONng/LJ2N-EtFOSAA2991-50-6 2/1/222<2.0 DWRPFAS EHENDERSONng/LJ2N-MeFOSAA2355-31-9 2/1/222<2.0 DWRPFAS EHENDERSONPerfluorinated Compounds (PFA) in liquid 2/1/22_TITLE_ DWRPFAS EHENDERSONng/LUPFBA375-22-4 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFBS375-73-5 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFDA335-76-2 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFDoA307-55-1 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFDoS79780-39-5 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFDS335-77-3 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFHpA375-85-9 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFHpS375-92-8 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFHxA307-24-4 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFHxS355-46-4 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFNA375-95-1 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFNS68259-12-1 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFOA335-67-1 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFOS1763-23-1 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFPeA2706-90-3 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFPeS2706-91-4 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFTeDA376-06-7 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFTrDA72629-94-8 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFUnA2058-94-8 2/1/222<2.0 WSS Chemistry Laboratory>> 1623 Mail Service Center, Raleigh, NC 27699-1623 (919) 733-3908 Page 1 of 3 "Not Detected" or "U" does not indicate the sample is analyte free but that the analyte is not detected at or above the PQL. AC92126Sample ID: NC DWR Laboratory Section Results/Sample Comments/Qualifier Definitions CAS #Analyte Name PQL Result/ Qualifier Units Method Reference Analysis Date Validated by PFAS: PFAS - Holding time exceeded following receipt by lab. Internal WSS guidelines specify samples must be extracted within 30 days of collection. Sample Comments NCDEQ-WSS-Chemistry Lab Data Qualifiers A1 The reported value is an average, where at least one result is qualified with a “U”. The PQL is used for the qualified result(S) to calculate the average. B1 Coliform-Countable membranes with less than 20 colonies. Reported value is estimated or is a total of the counts on all filters reported per 100 ml. B2 Coliform-Counts from all filters were zero. The value reported is based on the number of colonies per 100 ml that would have been reported if there had been one colony on the filter representing the largest filtration volume. B3 Coliform-Countable membranes with more than 60 or 80 colonies. The value reported is calculated using the count from the smallest volume filtered and reported as a greater than ">" value. B4 Coliform-Filters have counts of both >60 or 80 and <20. Reported value is estimated or is a total of the counts on all filters reported per 100 ml. B5 Coliform-Too many colonies were present; too numerous to count (TNTC). TNTC is generally defined as >150 colonies. B6 Coliform-Estimated Value. Blank contamination evident. B7 Coliform-Many non-coliform or non-enterococcus colonies or interfering non-coliform or non-enterococcus growth present. In this competitive situation, the reported value may under-represent actual density. BB1 MPN-No wells or tubes gave a positive reaction. Value based upon the appropriate MPN Index and reported as a less than “<” value. BB2 MPN-All wells or tubes gave positive reactions. Value based upon the MPN Index and reported as a greater than “>” value. C Total residual chlorine was present in sample upon receipt in the laboratory; value is estimated. G1 BOD-The dissolved oxygen (DO) depletion of the dilution water blank exceeded 0.2 mg/L. G2 BOD-The bacterial seed controls did not meet the requirement of a DO depletion of at least 2.0 mg/L and/or a DO residual of at least 1.0 mg/L. G3 BOD-No sample dilution met the requirement of a DO depletion of at least 2.0 mg/L and/or a DO residual of at least 1.0 mg/L. G4 BOD-Evidence of toxicity. This is generally characterized by a significant increase in the BOD value as the sample concentration decreases. The reported value is calculated from the highest dilution representing the maximum loading potential and G5 BOD-The glucose/ glutamic acid standard exceeded the range of 198 ± 30.5 mg/L. G7 BOD-Less than 1 mg/L DO remained for all dilutions set. The reported value is an estimated greater than value and is calculated for the dilution using the least amount of sample. G8 BOD-Oxygen usage is less than 2 mg/L for all dilutions set. The reported value is an estimated less than value and is calculated for the dilution using the most amount of sample. G9 BOD-The DO depletion of the dilution water blank produced a negative value. J1 Surrogate recovery limits have been exceeded. J10 Unidentified peak; estimated value. WSS Chemistry Laboratory>> 1623 Mail Service Center, Raleigh, NC 27699-1623 (919) 733-3908 Page 2 of 3 "Not Detected" or "U" does not indicate the sample is analyte free but that the analyte is not detected at or above the PQL. AC92126Sample ID: NC DWR Laboratory Section Results/Sample Comments/Qualifier Definitions CAS #Analyte Name PQL Result/ Qualifier Units Method Reference Analysis Date Validated by J11 The reported value is determined by a one-point estimation rather than against a regression equation. The estimated concentration is less than the laboratory practical quantitation limit and greater than the instrument noise level. This code is used when J12 The calibration verification did not meet the calibration acceptance criterion for field parameters. J2 The reported value failed to meet the established quality control criteria for either precision or accuracy. J3 The sample matrix interfered with the ability to make any accurate determination. J4 The data is questionable because of improper laboratory or field protocols (e.g., composite sample was collected instead of grab, plastic instead of glass container, etc.). J5 Temperature limits exceeded (samples frozen or >6°C) during transport or not verifiable (e.g., no temperature blank provided): non-reportable for NPDES compliance monitoring. J6 The laboratory analysis was from an unpreserved or improperly chemically preserved sample. The data may not be accurate. J7 This qualifier is used to identify analyte concentration exceeding the upper calibration range of the analytical instrument/method. The reported value should be considered estimated. J8 Temperature limits exceeded (samples frozen or >6ºC) during storage, the data may not be accurate. J9 The reported value is determined by a one-point estimation rather than against a regression equation. The estimated concentration is less than the laboratory practical quantitation limit and greater than the laboratory method detection limit. M Sample and duplicate results are "out of control". The sample is non-homogenous (e.g., VOA soil). The reported value is the lower value of duplicate analyses of a sample. N1 Presumptive evidence and estimated value. The component has been tentatively identified base on mass spectral library. N2 There is an indication that the analyte is present, but quality control requirements for confirmation were not met (i.e., presence of analyte was not confirmed by alternate procedures). N3 This code shall be used if the level is too low to permit accurate quantification, but the estimated concentration is less than the laboratory practical quantitation limit and greater than the laboratory method detection limit. This code is not routinely N4 This code shall be used if the level is too low to permit accurate quantification, but the estimated concentration is less than the laboratory practical quantitation limit and greater than the instrument noise level. This code is used when an MDL has not N5 The component has been tentatively identified based on a retention time standard. P Elevated PQL* due to matrix interference and/or sample dilution. Q1 Holding time exceeded prior to receipt by lab. Q2 Holding time exceeded following receipt by lab. S Not enough sample provided to prepare and/or analyze a method-required matrix spike (MS) and/or matrix spike duplicate (MSD). U Indicates that the analyte was analyzed for but not detected above the reported practical quantitation limit*. The number value reported with the "U" qualifier is equal to the laboratory's practical quantitation limit*. U, J6 The laboratory analysis was from an unpreserved or improperly chemically preserved sample. The data may not be accurate. UU Indicates that the analyte was not detected by a screen analysis. The number value was determined by a one-point estimation at the PQL. V Indicates the analyte was detected in both the sample and the associated method blank. Note: The value in the blank shall not be subtracted from the associated samples. X1 Sample not screened for this compound. X2 Sampled, but analysis lost or not performed-field error. X3 Sampled, but analysis lost or not performed-lab error. Y Elevated PQL* due to insufficient sample size. Z1 Inability to analyze the sample. Z2 Questions concerning data reliability. WSS Chemistry Laboratory>> 1623 Mail Service Center, Raleigh, NC 27699-1623 (919) 733-3908 Page 3 of 3 "Not Detected" or "U" does not indicate the sample is analyte free but that the analyte is not detected at or above the PQL. PO Number # Loc. Descr.:FISHFARM_21 FILTER TAPE BLANK Loc. Type:Filter Blank Collector:N MILLER Collect Date:11/23/2021 Collect Time:12:05 Date Received:12/03/2021 Time Received:10:00 Location ID:21FTB County:Cumberland Region:Fayetteville Labworks LoginID TASCENZO1Sample Matrix:BLANKWATER Report Print Date: North Carolina Division of Water Resources Water Sciences Section Laboratory Results FTB111621-21VisitID Sample Depth DAQReport To River Basin 03/11/2022 Emergency YESCOC Yes/No Sample ID:AC92127 3/11/22Final Report Date: Final Report If this report is labeled preliminary report, the results have not been validated. Do not use for Regulatory purposes. Hand DeliveredDelivery Method COCPriority AC92127 Analysis Date Method Reference Result/ QualifierPQLAnalyte NameCAS #Units Validated by LAB ESTAFFORD1°CSample temperature at receipt by lab 12/3/211.8 Others DWRPFAS EHENDERSONng/LU11Cl-PF3ONS 2/1/222<2.0 DWRPFAS EHENDERSONng/LU4:2 FTS757124-72-4 2/1/222<2.0 DWRPFAS EHENDERSONng/LU6:2 FTS27619-97-2 2/1/222<2.0 DWRPFAS EHENDERSONng/LU8:2 FTS39108-34-4 2/1/222<2.0 DWRPFAS EHENDERSONng/LU9Cl-PF3ONS73606-19-6 2/1/222<2.0 DWRPFAS EHENDERSONng/LUHFPO-DA13252-13-6 2/1/222<2.0 DWRPFAS EHENDERSONng/LUNaDONA919005-14-4 2/1/222<2.0 DWRPFAS EHENDERSONng/LJ2N-EtFOSAA2991-50-6 2/1/222<2.0 DWRPFAS EHENDERSONng/LJ2N-MeFOSAA2355-31-9 2/1/222<2.0 DWRPFAS EHENDERSONPerfluorinated Compounds (PFA) in liquid 2/1/22_TITLE_ DWRPFAS EHENDERSONng/LUPFBA375-22-4 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFBS375-73-5 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFDA335-76-2 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFDoA307-55-1 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFDoS79780-39-5 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFDS335-77-3 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFHpA375-85-9 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFHpS375-92-8 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFHxA307-24-4 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFHxS355-46-4 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFNA375-95-1 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFNS68259-12-1 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFOA335-67-1 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFOS1763-23-1 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFPeA2706-90-3 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFPeS2706-91-4 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFTeDA376-06-7 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFTrDA72629-94-8 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFUnA2058-94-8 2/1/222<2.0 WSS Chemistry Laboratory>> 1623 Mail Service Center, Raleigh, NC 27699-1623 (919) 733-3908 Page 1 of 3 "Not Detected" or "U" does not indicate the sample is analyte free but that the analyte is not detected at or above the PQL. AC92127Sample ID: NC DWR Laboratory Section Results/Sample Comments/Qualifier Definitions CAS #Analyte Name PQL Result/ Qualifier Units Method Reference Analysis Date Validated by PFAS: PFAS - Holding time exceeded following receipt by lab. Internal WSS guidelines specify samples must be extracted within 30 days of collection. PFAS: PFAS - J2 - Estimated. The reported value failed to meet the established quality control criteria for either precision or accuracy. Sample Comments NCDEQ-WSS-Chemistry Lab Data Qualifiers A1 The reported value is an average, where at least one result is qualified with a “U”. The PQL is used for the qualified result(S) to calculate the average. B1 Coliform-Countable membranes with less than 20 colonies. Reported value is estimated or is a total of the counts on all filters reported per 100 ml. B2 Coliform-Counts from all filters were zero. The value reported is based on the number of colonies per 100 ml that would have been reported if there had been one colony on the filter representing the largest filtration volume. B3 Coliform-Countable membranes with more than 60 or 80 colonies. The value reported is calculated using the count from the smallest volume filtered and reported as a greater than ">" value. B4 Coliform-Filters have counts of both >60 or 80 and <20. Reported value is estimated or is a total of the counts on all filters reported per 100 ml. B5 Coliform-Too many colonies were present; too numerous to count (TNTC). TNTC is generally defined as >150 colonies. B6 Coliform-Estimated Value. Blank contamination evident. B7 Coliform-Many non-coliform or non-enterococcus colonies or interfering non-coliform or non-enterococcus growth present. In this competitive situation, the reported value may under-represent actual density. BB1 MPN-No wells or tubes gave a positive reaction. Value based upon the appropriate MPN Index and reported as a less than “<” value. BB2 MPN-All wells or tubes gave positive reactions. Value based upon the MPN Index and reported as a greater than “>” value. C Total residual chlorine was present in sample upon receipt in the laboratory; value is estimated. G1 BOD-The dissolved oxygen (DO) depletion of the dilution water blank exceeded 0.2 mg/L. G2 BOD-The bacterial seed controls did not meet the requirement of a DO depletion of at least 2.0 mg/L and/or a DO residual of at least 1.0 mg/L. G3 BOD-No sample dilution met the requirement of a DO depletion of at least 2.0 mg/L and/or a DO residual of at least 1.0 mg/L. G4 BOD-Evidence of toxicity. This is generally characterized by a significant increase in the BOD value as the sample concentration decreases. The reported value is calculated from the highest dilution representing the maximum loading potential and G5 BOD-The glucose/ glutamic acid standard exceeded the range of 198 ± 30.5 mg/L. G7 BOD-Less than 1 mg/L DO remained for all dilutions set. The reported value is an estimated greater than value and is calculated for the dilution using the least amount of sample. G8 BOD-Oxygen usage is less than 2 mg/L for all dilutions set. The reported value is an estimated less than value and is calculated for the dilution using the most amount of sample. G9 BOD-The DO depletion of the dilution water blank produced a negative value. J1 Surrogate recovery limits have been exceeded. J10 Unidentified peak; estimated value. WSS Chemistry Laboratory>> 1623 Mail Service Center, Raleigh, NC 27699-1623 (919) 733-3908 Page 2 of 3 "Not Detected" or "U" does not indicate the sample is analyte free but that the analyte is not detected at or above the PQL. AC92127Sample ID: NC DWR Laboratory Section Results/Sample Comments/Qualifier Definitions CAS #Analyte Name PQL Result/ Qualifier Units Method Reference Analysis Date Validated by J11 The reported value is determined by a one-point estimation rather than against a regression equation. The estimated concentration is less than the laboratory practical quantitation limit and greater than the instrument noise level. This code is used when J12 The calibration verification did not meet the calibration acceptance criterion for field parameters. J2 The reported value failed to meet the established quality control criteria for either precision or accuracy. J3 The sample matrix interfered with the ability to make any accurate determination. J4 The data is questionable because of improper laboratory or field protocols (e.g., composite sample was collected instead of grab, plastic instead of glass container, etc.). J5 Temperature limits exceeded (samples frozen or >6°C) during transport or not verifiable (e.g., no temperature blank provided): non-reportable for NPDES compliance monitoring. J6 The laboratory analysis was from an unpreserved or improperly chemically preserved sample. The data may not be accurate. J7 This qualifier is used to identify analyte concentration exceeding the upper calibration range of the analytical instrument/method. The reported value should be considered estimated. J8 Temperature limits exceeded (samples frozen or >6ºC) during storage, the data may not be accurate. J9 The reported value is determined by a one-point estimation rather than against a regression equation. The estimated concentration is less than the laboratory practical quantitation limit and greater than the laboratory method detection limit. M Sample and duplicate results are "out of control". The sample is non-homogenous (e.g., VOA soil). The reported value is the lower value of duplicate analyses of a sample. N1 Presumptive evidence and estimated value. The component has been tentatively identified base on mass spectral library. N2 There is an indication that the analyte is present, but quality control requirements for confirmation were not met (i.e., presence of analyte was not confirmed by alternate procedures). N3 This code shall be used if the level is too low to permit accurate quantification, but the estimated concentration is less than the laboratory practical quantitation limit and greater than the laboratory method detection limit. This code is not routinely N4 This code shall be used if the level is too low to permit accurate quantification, but the estimated concentration is less than the laboratory practical quantitation limit and greater than the instrument noise level. This code is used when an MDL has not N5 The component has been tentatively identified based on a retention time standard. P Elevated PQL* due to matrix interference and/or sample dilution. Q1 Holding time exceeded prior to receipt by lab. Q2 Holding time exceeded following receipt by lab. S Not enough sample provided to prepare and/or analyze a method-required matrix spike (MS) and/or matrix spike duplicate (MSD). U Indicates that the analyte was analyzed for but not detected above the reported practical quantitation limit*. The number value reported with the "U" qualifier is equal to the laboratory's practical quantitation limit*. U, J6 The laboratory analysis was from an unpreserved or improperly chemically preserved sample. The data may not be accurate. UU Indicates that the analyte was not detected by a screen analysis. The number value was determined by a one-point estimation at the PQL. V Indicates the analyte was detected in both the sample and the associated method blank. Note: The value in the blank shall not be subtracted from the associated samples. X1 Sample not screened for this compound. X2 Sampled, but analysis lost or not performed-field error. X3 Sampled, but analysis lost or not performed-lab error. Y Elevated PQL* due to insufficient sample size. Z1 Inability to analyze the sample. Z2 Questions concerning data reliability. WSS Chemistry Laboratory>> 1623 Mail Service Center, Raleigh, NC 27699-1623 (919) 733-3908 Page 3 of 3 "Not Detected" or "U" does not indicate the sample is analyte free but that the analyte is not detected at or above the PQL. PO Number # Loc. Descr.:MILLBROOK Loc. Type:Rain Water Collector:N MILLER Collect Date:11/23/2021 Collect Time:14:38 Date Received:12/03/2021 Time Received:10:00 Location ID:MB County:Wake Region:Raleigh Labworks LoginID TASCENZO1Sample Matrix:EXPERIMENTAL SOLUTION Report Print Date: North Carolina Division of Water Resources Water Sciences Section Laboratory Results W111621-MBVisitID Sample Depth DAQReport To River Basin 03/11/2022 Emergency YESCOC Yes/No Sample ID:AC92128 3/11/22Final Report Date: Final Report If this report is labeled preliminary report, the results have not been validated. Do not use for Regulatory purposes. Hand DeliveredDelivery Method COCPriority AC92128 Analysis Date Method Reference Result/ QualifierPQLAnalyte NameCAS #Units Validated by LAB ESTAFFORD1°CSample temperature at receipt by lab 12/3/211.8 Others DWRPFAS EHENDERSONng/LU11Cl-PF3ONS 2/1/222<2.0 DWRPFAS EHENDERSONng/LU4:2 FTS757124-72-4 2/1/222<2.0 DWRPFAS EHENDERSONng/LU6:2 FTS27619-97-2 2/1/222<2.0 DWRPFAS EHENDERSONng/LU8:2 FTS39108-34-4 2/1/222<2.0 DWRPFAS EHENDERSONng/LU9Cl-PF3ONS73606-19-6 2/1/222<2.0 DWRPFAS EHENDERSONng/LUHFPO-DA13252-13-6 2/1/222<2.0 DWRPFAS EHENDERSONng/LUNaDONA919005-14-4 2/1/222<2.0 DWRPFAS EHENDERSONng/LJ2N-EtFOSAA2991-50-6 2/1/222<2.0 DWRPFAS EHENDERSONng/LJ2N-MeFOSAA2355-31-9 2/1/222<2.0 DWRPFAS EHENDERSONPerfluorinated Compounds (PFA) in liquid 2/1/22_TITLE_ DWRPFAS EHENDERSONng/LUPFBA375-22-4 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFBS375-73-5 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFDA335-76-2 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFDoA307-55-1 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFDoS79780-39-5 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFDS335-77-3 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFHpA375-85-9 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFHpS375-92-8 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFHxA307-24-4 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFHxS355-46-4 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFNA375-95-1 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFNS68259-12-1 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFOA335-67-1 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFOS1763-23-1 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFPeA2706-90-3 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFPeS2706-91-4 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFTeDA376-06-7 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFTrDA72629-94-8 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFUnA2058-94-8 2/1/222<2.0 WSS Chemistry Laboratory>> 1623 Mail Service Center, Raleigh, NC 27699-1623 (919) 733-3908 Page 1 of 3 "Not Detected" or "U" does not indicate the sample is analyte free but that the analyte is not detected at or above the PQL. AC92128Sample ID: NC DWR Laboratory Section Results/Sample Comments/Qualifier Definitions CAS #Analyte Name PQL Result/ Qualifier Units Method Reference Analysis Date Validated by PFAS: PFAS - Holding time exceeded following receipt by lab. Internal WSS guidelines specify samples must be extracted within 30 days of collection. PFAS: PFAS - J2 - Estimated. The reported value failed to meet the established quality control criteria for either precision or accuracy. Sample Comments NCDEQ-WSS-Chemistry Lab Data Qualifiers A1 The reported value is an average, where at least one result is qualified with a “U”. The PQL is used for the qualified result(S) to calculate the average. B1 Coliform-Countable membranes with less than 20 colonies. Reported value is estimated or is a total of the counts on all filters reported per 100 ml. B2 Coliform-Counts from all filters were zero. The value reported is based on the number of colonies per 100 ml that would have been reported if there had been one colony on the filter representing the largest filtration volume. B3 Coliform-Countable membranes with more than 60 or 80 colonies. The value reported is calculated using the count from the smallest volume filtered and reported as a greater than ">" value. B4 Coliform-Filters have counts of both >60 or 80 and <20. Reported value is estimated or is a total of the counts on all filters reported per 100 ml. B5 Coliform-Too many colonies were present; too numerous to count (TNTC). TNTC is generally defined as >150 colonies. B6 Coliform-Estimated Value. Blank contamination evident. B7 Coliform-Many non-coliform or non-enterococcus colonies or interfering non-coliform or non-enterococcus growth present. In this competitive situation, the reported value may under-represent actual density. BB1 MPN-No wells or tubes gave a positive reaction. Value based upon the appropriate MPN Index and reported as a less than “<” value. BB2 MPN-All wells or tubes gave positive reactions. Value based upon the MPN Index and reported as a greater than “>” value. C Total residual chlorine was present in sample upon receipt in the laboratory; value is estimated. G1 BOD-The dissolved oxygen (DO) depletion of the dilution water blank exceeded 0.2 mg/L. G2 BOD-The bacterial seed controls did not meet the requirement of a DO depletion of at least 2.0 mg/L and/or a DO residual of at least 1.0 mg/L. G3 BOD-No sample dilution met the requirement of a DO depletion of at least 2.0 mg/L and/or a DO residual of at least 1.0 mg/L. G4 BOD-Evidence of toxicity. This is generally characterized by a significant increase in the BOD value as the sample concentration decreases. The reported value is calculated from the highest dilution representing the maximum loading potential and G5 BOD-The glucose/ glutamic acid standard exceeded the range of 198 ± 30.5 mg/L. G7 BOD-Less than 1 mg/L DO remained for all dilutions set. The reported value is an estimated greater than value and is calculated for the dilution using the least amount of sample. G8 BOD-Oxygen usage is less than 2 mg/L for all dilutions set. The reported value is an estimated less than value and is calculated for the dilution using the most amount of sample. G9 BOD-The DO depletion of the dilution water blank produced a negative value. J1 Surrogate recovery limits have been exceeded. J10 Unidentified peak; estimated value. WSS Chemistry Laboratory>> 1623 Mail Service Center, Raleigh, NC 27699-1623 (919) 733-3908 Page 2 of 3 "Not Detected" or "U" does not indicate the sample is analyte free but that the analyte is not detected at or above the PQL. AC92128Sample ID: NC DWR Laboratory Section Results/Sample Comments/Qualifier Definitions CAS #Analyte Name PQL Result/ Qualifier Units Method Reference Analysis Date Validated by J11 The reported value is determined by a one-point estimation rather than against a regression equation. The estimated concentration is less than the laboratory practical quantitation limit and greater than the instrument noise level. This code is used when J12 The calibration verification did not meet the calibration acceptance criterion for field parameters. J2 The reported value failed to meet the established quality control criteria for either precision or accuracy. J3 The sample matrix interfered with the ability to make any accurate determination. J4 The data is questionable because of improper laboratory or field protocols (e.g., composite sample was collected instead of grab, plastic instead of glass container, etc.). J5 Temperature limits exceeded (samples frozen or >6°C) during transport or not verifiable (e.g., no temperature blank provided): non-reportable for NPDES compliance monitoring. J6 The laboratory analysis was from an unpreserved or improperly chemically preserved sample. The data may not be accurate. J7 This qualifier is used to identify analyte concentration exceeding the upper calibration range of the analytical instrument/method. The reported value should be considered estimated. J8 Temperature limits exceeded (samples frozen or >6ºC) during storage, the data may not be accurate. J9 The reported value is determined by a one-point estimation rather than against a regression equation. The estimated concentration is less than the laboratory practical quantitation limit and greater than the laboratory method detection limit. M Sample and duplicate results are "out of control". The sample is non-homogenous (e.g., VOA soil). The reported value is the lower value of duplicate analyses of a sample. N1 Presumptive evidence and estimated value. The component has been tentatively identified base on mass spectral library. N2 There is an indication that the analyte is present, but quality control requirements for confirmation were not met (i.e., presence of analyte was not confirmed by alternate procedures). N3 This code shall be used if the level is too low to permit accurate quantification, but the estimated concentration is less than the laboratory practical quantitation limit and greater than the laboratory method detection limit. This code is not routinely N4 This code shall be used if the level is too low to permit accurate quantification, but the estimated concentration is less than the laboratory practical quantitation limit and greater than the instrument noise level. This code is used when an MDL has not N5 The component has been tentatively identified based on a retention time standard. P Elevated PQL* due to matrix interference and/or sample dilution. Q1 Holding time exceeded prior to receipt by lab. Q2 Holding time exceeded following receipt by lab. S Not enough sample provided to prepare and/or analyze a method-required matrix spike (MS) and/or matrix spike duplicate (MSD). U Indicates that the analyte was analyzed for but not detected above the reported practical quantitation limit*. The number value reported with the "U" qualifier is equal to the laboratory's practical quantitation limit*. U, J6 The laboratory analysis was from an unpreserved or improperly chemically preserved sample. The data may not be accurate. UU Indicates that the analyte was not detected by a screen analysis. The number value was determined by a one-point estimation at the PQL. V Indicates the analyte was detected in both the sample and the associated method blank. Note: The value in the blank shall not be subtracted from the associated samples. X1 Sample not screened for this compound. X2 Sampled, but analysis lost or not performed-field error. X3 Sampled, but analysis lost or not performed-lab error. Y Elevated PQL* due to insufficient sample size. Z1 Inability to analyze the sample. Z2 Questions concerning data reliability. WSS Chemistry Laboratory>> 1623 Mail Service Center, Raleigh, NC 27699-1623 (919) 733-3908 Page 3 of 3 "Not Detected" or "U" does not indicate the sample is analyte free but that the analyte is not detected at or above the PQL. PO Number # Loc. Descr.:MILLBROOK (Dry) Loc. Type:Rain Water Collector:N MILLER Collect Date:11/23/2021 Collect Time:14:38 Date Received:12/03/2021 Time Received:10:00 Location ID:MBD County:Wake Region:Raleigh Labworks LoginID TASCENZO1Sample Matrix:EXPERIMENTAL SOLUTION Report Print Date: North Carolina Division of Water Resources Water Sciences Section Laboratory Results D111621-MBVisitID Sample Depth DAQReport To River Basin 03/11/2022 Emergency YESCOC Yes/No Sample ID:AC92129 3/11/22Final Report Date: Final Report If this report is labeled preliminary report, the results have not been validated. Do not use for Regulatory purposes. Hand DeliveredDelivery Method COCPriority AC92129 Analysis Date Method Reference Result/ QualifierPQLAnalyte NameCAS #Units Validated by LAB ESTAFFORD1°CSample temperature at receipt by lab 12/3/211.8 Others DWRPFAS EHENDERSONng/LU11Cl-PF3ONS 2/1/222<2.0 DWRPFAS EHENDERSONng/LU4:2 FTS757124-72-4 2/1/222<2.0 DWRPFAS EHENDERSONng/LU6:2 FTS27619-97-2 2/1/222<2.0 DWRPFAS EHENDERSONng/LU8:2 FTS39108-34-4 2/1/222<2.0 DWRPFAS EHENDERSONng/LU9Cl-PF3ONS73606-19-6 2/1/222<2.0 DWRPFAS EHENDERSONng/LUHFPO-DA13252-13-6 2/1/222<2.0 DWRPFAS EHENDERSONng/LUNaDONA919005-14-4 2/1/222<2.0 DWRPFAS EHENDERSONng/LJ2N-EtFOSAA2991-50-6 2/1/222<2.0 DWRPFAS EHENDERSONng/LJ2N-MeFOSAA2355-31-9 2/1/222<2.0 DWRPFAS EHENDERSONPerfluorinated Compounds (PFA) in liquid 2/1/22_TITLE_ DWRPFAS EHENDERSONng/LUPFBA375-22-4 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFBS375-73-5 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFDA335-76-2 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFDoA307-55-1 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFDoS79780-39-5 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFDS335-77-3 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFHpA375-85-9 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFHpS375-92-8 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFHxA307-24-4 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFHxS355-46-4 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFNA375-95-1 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFNS68259-12-1 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFOA335-67-1 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFOS1763-23-1 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFPeA2706-90-3 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFPeS2706-91-4 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFTeDA376-06-7 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFTrDA72629-94-8 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFUnA2058-94-8 2/1/222<2.0 WSS Chemistry Laboratory>> 1623 Mail Service Center, Raleigh, NC 27699-1623 (919) 733-3908 Page 1 of 3 "Not Detected" or "U" does not indicate the sample is analyte free but that the analyte is not detected at or above the PQL. AC92129Sample ID: NC DWR Laboratory Section Results/Sample Comments/Qualifier Definitions CAS #Analyte Name PQL Result/ Qualifier Units Method Reference Analysis Date Validated by PFAS: PFAS - Holding time exceeded following receipt by lab. Internal WSS guidelines specify samples must be extracted within 30 days of collection. PFAS: PFAS -J2 - reported value failed to meet the established quality control criteria for either precision or accuracy. Sample Comments NCDEQ-WSS-Chemistry Lab Data Qualifiers A1 The reported value is an average, where at least one result is qualified with a “U”. The PQL is used for the qualified result(S) to calculate the average. B1 Coliform-Countable membranes with less than 20 colonies. Reported value is estimated or is a total of the counts on all filters reported per 100 ml. B2 Coliform-Counts from all filters were zero. The value reported is based on the number of colonies per 100 ml that would have been reported if there had been one colony on the filter representing the largest filtration volume. B3 Coliform-Countable membranes with more than 60 or 80 colonies. The value reported is calculated using the count from the smallest volume filtered and reported as a greater than ">" value. B4 Coliform-Filters have counts of both >60 or 80 and <20. Reported value is estimated or is a total of the counts on all filters reported per 100 ml. B5 Coliform-Too many colonies were present; too numerous to count (TNTC). TNTC is generally defined as >150 colonies. B6 Coliform-Estimated Value. Blank contamination evident. B7 Coliform-Many non-coliform or non-enterococcus colonies or interfering non-coliform or non-enterococcus growth present. In this competitive situation, the reported value may under-represent actual density. BB1 MPN-No wells or tubes gave a positive reaction. Value based upon the appropriate MPN Index and reported as a less than “<” value. BB2 MPN-All wells or tubes gave positive reactions. Value based upon the MPN Index and reported as a greater than “>” value. C Total residual chlorine was present in sample upon receipt in the laboratory; value is estimated. G1 BOD-The dissolved oxygen (DO) depletion of the dilution water blank exceeded 0.2 mg/L. G2 BOD-The bacterial seed controls did not meet the requirement of a DO depletion of at least 2.0 mg/L and/or a DO residual of at least 1.0 mg/L. G3 BOD-No sample dilution met the requirement of a DO depletion of at least 2.0 mg/L and/or a DO residual of at least 1.0 mg/L. G4 BOD-Evidence of toxicity. This is generally characterized by a significant increase in the BOD value as the sample concentration decreases. The reported value is calculated from the highest dilution representing the maximum loading potential and G5 BOD-The glucose/ glutamic acid standard exceeded the range of 198 ± 30.5 mg/L. G7 BOD-Less than 1 mg/L DO remained for all dilutions set. The reported value is an estimated greater than value and is calculated for the dilution using the least amount of sample. G8 BOD-Oxygen usage is less than 2 mg/L for all dilutions set. The reported value is an estimated less than value and is calculated for the dilution using the most amount of sample. G9 BOD-The DO depletion of the dilution water blank produced a negative value. J1 Surrogate recovery limits have been exceeded. J10 Unidentified peak; estimated value. WSS Chemistry Laboratory>> 1623 Mail Service Center, Raleigh, NC 27699-1623 (919) 733-3908 Page 2 of 3 "Not Detected" or "U" does not indicate the sample is analyte free but that the analyte is not detected at or above the PQL. AC92129Sample ID: NC DWR Laboratory Section Results/Sample Comments/Qualifier Definitions CAS #Analyte Name PQL Result/ Qualifier Units Method Reference Analysis Date Validated by J11 The reported value is determined by a one-point estimation rather than against a regression equation. The estimated concentration is less than the laboratory practical quantitation limit and greater than the instrument noise level. This code is used when J12 The calibration verification did not meet the calibration acceptance criterion for field parameters. J2 The reported value failed to meet the established quality control criteria for either precision or accuracy. J3 The sample matrix interfered with the ability to make any accurate determination. J4 The data is questionable because of improper laboratory or field protocols (e.g., composite sample was collected instead of grab, plastic instead of glass container, etc.). J5 Temperature limits exceeded (samples frozen or >6°C) during transport or not verifiable (e.g., no temperature blank provided): non-reportable for NPDES compliance monitoring. J6 The laboratory analysis was from an unpreserved or improperly chemically preserved sample. The data may not be accurate. J7 This qualifier is used to identify analyte concentration exceeding the upper calibration range of the analytical instrument/method. The reported value should be considered estimated. J8 Temperature limits exceeded (samples frozen or >6ºC) during storage, the data may not be accurate. J9 The reported value is determined by a one-point estimation rather than against a regression equation. The estimated concentration is less than the laboratory practical quantitation limit and greater than the laboratory method detection limit. M Sample and duplicate results are "out of control". The sample is non-homogenous (e.g., VOA soil). The reported value is the lower value of duplicate analyses of a sample. N1 Presumptive evidence and estimated value. The component has been tentatively identified base on mass spectral library. N2 There is an indication that the analyte is present, but quality control requirements for confirmation were not met (i.e., presence of analyte was not confirmed by alternate procedures). N3 This code shall be used if the level is too low to permit accurate quantification, but the estimated concentration is less than the laboratory practical quantitation limit and greater than the laboratory method detection limit. This code is not routinely N4 This code shall be used if the level is too low to permit accurate quantification, but the estimated concentration is less than the laboratory practical quantitation limit and greater than the instrument noise level. This code is used when an MDL has not N5 The component has been tentatively identified based on a retention time standard. P Elevated PQL* due to matrix interference and/or sample dilution. Q1 Holding time exceeded prior to receipt by lab. Q2 Holding time exceeded following receipt by lab. S Not enough sample provided to prepare and/or analyze a method-required matrix spike (MS) and/or matrix spike duplicate (MSD). U Indicates that the analyte was analyzed for but not detected above the reported practical quantitation limit*. The number value reported with the "U" qualifier is equal to the laboratory's practical quantitation limit*. U, J6 The laboratory analysis was from an unpreserved or improperly chemically preserved sample. The data may not be accurate. UU Indicates that the analyte was not detected by a screen analysis. The number value was determined by a one-point estimation at the PQL. V Indicates the analyte was detected in both the sample and the associated method blank. Note: The value in the blank shall not be subtracted from the associated samples. X1 Sample not screened for this compound. X2 Sampled, but analysis lost or not performed-field error. X3 Sampled, but analysis lost or not performed-lab error. Y Elevated PQL* due to insufficient sample size. Z1 Inability to analyze the sample. Z2 Questions concerning data reliability. WSS Chemistry Laboratory>> 1623 Mail Service Center, Raleigh, NC 27699-1623 (919) 733-3908 Page 3 of 3 "Not Detected" or "U" does not indicate the sample is analyte free but that the analyte is not detected at or above the PQL. PO Number # Loc. Descr.:WATTERS_19 FIELD BLANK Loc. Type:Field Blank Collector:N MILLER Collect Date:11/23/2021 Collect Time:10:37 Date Received:12/03/2021 Time Received:10:00 Location ID:19FB County:Cumberland Region:Fayetteville Labworks LoginID TASCENZO1Sample Matrix:BLANKWATER Report Print Date: North Carolina Division of Water Resources Water Sciences Section Laboratory Results FB111621-19VisitID Sample Depth DAQReport To River Basin 03/11/2022 Emergency YESCOC Yes/No Sample ID:AC92130 3/11/22Final Report Date: Final Report If this report is labeled preliminary report, the results have not been validated. Do not use for Regulatory purposes. Hand DeliveredDelivery Method COCPriority AC92130 Analysis Date Method Reference Result/ QualifierPQLAnalyte NameCAS #Units Validated by LAB ESTAFFORD1°CSample temperature at receipt by lab 12/3/211.8 Others DWRPFAS EHENDERSONng/LU11Cl-PF3ONS 2/1/222<2.0 DWRPFAS EHENDERSONng/LU4:2 FTS757124-72-4 2/1/222<2.0 DWRPFAS EHENDERSONng/LU6:2 FTS27619-97-2 2/1/222<2.0 DWRPFAS EHENDERSONng/LU8:2 FTS39108-34-4 2/1/222<2.0 DWRPFAS EHENDERSONng/LU9Cl-PF3ONS73606-19-6 2/1/222<2.0 DWRPFAS EHENDERSONng/LUHFPO-DA13252-13-6 2/1/222<2.0 DWRPFAS EHENDERSONng/LUNaDONA919005-14-4 2/1/222<2.0 DWRPFAS EHENDERSONng/LUN-EtFOSAA2991-50-6 2/1/222<2.0 DWRPFAS EHENDERSONng/LUN-MeFOSAA2355-31-9 2/1/222<2.0 DWRPFAS EHENDERSONPerfluorinated Compounds (PFA) in liquid 2/1/22_TITLE_ DWRPFAS EHENDERSONng/LUPFBA375-22-4 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFBS375-73-5 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFDA335-76-2 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFDoA307-55-1 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFDoS79780-39-5 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFDS335-77-3 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFHpA375-85-9 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFHpS375-92-8 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFHxA307-24-4 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFHxS355-46-4 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFNA375-95-1 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFNS68259-12-1 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFOA335-67-1 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFOS1763-23-1 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFPeA2706-90-3 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFPeS2706-91-4 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFTeDA376-06-7 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFTrDA72629-94-8 2/1/222<2.0 DWRPFAS EHENDERSONng/LUPFUnA2058-94-8 2/1/222<2.0 WSS Chemistry Laboratory>> 1623 Mail Service Center, Raleigh, NC 27699-1623 (919) 733-3908 Page 1 of 3 "Not Detected" or "U" does not indicate the sample is analyte free but that the analyte is not detected at or above the PQL. AC92130Sample ID: NC DWR Laboratory Section Results/Sample Comments/Qualifier Definitions CAS #Analyte Name PQL Result/ Qualifier Units Method Reference Analysis Date Validated by PFAS: PFAS - Holding time exceeded following receipt by lab. Internal WSS guidelines specify samples must be extracted within 30 days of collection. Sample Comments NCDEQ-WSS-Chemistry Lab Data Qualifiers A1 The reported value is an average, where at least one result is qualified with a “U”. The PQL is used for the qualified result(S) to calculate the average. B1 Coliform-Countable membranes with less than 20 colonies. Reported value is estimated or is a total of the counts on all filters reported per 100 ml. B2 Coliform-Counts from all filters were zero. The value reported is based on the number of colonies per 100 ml that would have been reported if there had been one colony on the filter representing the largest filtration volume. B3 Coliform-Countable membranes with more than 60 or 80 colonies. The value reported is calculated using the count from the smallest volume filtered and reported as a greater than ">" value. B4 Coliform-Filters have counts of both >60 or 80 and <20. Reported value is estimated or is a total of the counts on all filters reported per 100 ml. B5 Coliform-Too many colonies were present; too numerous to count (TNTC). TNTC is generally defined as >150 colonies. B6 Coliform-Estimated Value. Blank contamination evident. B7 Coliform-Many non-coliform or non-enterococcus colonies or interfering non-coliform or non-enterococcus growth present. In this competitive situation, the reported value may under-represent actual density. BB1 MPN-No wells or tubes gave a positive reaction. Value based upon the appropriate MPN Index and reported as a less than “<” value. BB2 MPN-All wells or tubes gave positive reactions. Value based upon the MPN Index and reported as a greater than “>” value. C Total residual chlorine was present in sample upon receipt in the laboratory; value is estimated. G1 BOD-The dissolved oxygen (DO) depletion of the dilution water blank exceeded 0.2 mg/L. G2 BOD-The bacterial seed controls did not meet the requirement of a DO depletion of at least 2.0 mg/L and/or a DO residual of at least 1.0 mg/L. G3 BOD-No sample dilution met the requirement of a DO depletion of at least 2.0 mg/L and/or a DO residual of at least 1.0 mg/L. G4 BOD-Evidence of toxicity. This is generally characterized by a significant increase in the BOD value as the sample concentration decreases. The reported value is calculated from the highest dilution representing the maximum loading potential and G5 BOD-The glucose/ glutamic acid standard exceeded the range of 198 ± 30.5 mg/L. G7 BOD-Less than 1 mg/L DO remained for all dilutions set. The reported value is an estimated greater than value and is calculated for the dilution using the least amount of sample. G8 BOD-Oxygen usage is less than 2 mg/L for all dilutions set. The reported value is an estimated less than value and is calculated for the dilution using the most amount of sample. G9 BOD-The DO depletion of the dilution water blank produced a negative value. J1 Surrogate recovery limits have been exceeded. J10 Unidentified peak; estimated value. WSS Chemistry Laboratory>> 1623 Mail Service Center, Raleigh, NC 27699-1623 (919) 733-3908 Page 2 of 3 "Not Detected" or "U" does not indicate the sample is analyte free but that the analyte is not detected at or above the PQL. AC92130Sample ID: NC DWR Laboratory Section Results/Sample Comments/Qualifier Definitions CAS #Analyte Name PQL Result/ Qualifier Units Method Reference Analysis Date Validated by J11 The reported value is determined by a one-point estimation rather than against a regression equation. The estimated concentration is less than the laboratory practical quantitation limit and greater than the instrument noise level. This code is used when J12 The calibration verification did not meet the calibration acceptance criterion for field parameters. J2 The reported value failed to meet the established quality control criteria for either precision or accuracy. J3 The sample matrix interfered with the ability to make any accurate determination. J4 The data is questionable because of improper laboratory or field protocols (e.g., composite sample was collected instead of grab, plastic instead of glass container, etc.). J5 Temperature limits exceeded (samples frozen or >6°C) during transport or not verifiable (e.g., no temperature blank provided): non-reportable for NPDES compliance monitoring. J6 The laboratory analysis was from an unpreserved or improperly chemically preserved sample. The data may not be accurate. J7 This qualifier is used to identify analyte concentration exceeding the upper calibration range of the analytical instrument/method. The reported value should be considered estimated. J8 Temperature limits exceeded (samples frozen or >6ºC) during storage, the data may not be accurate. J9 The reported value is determined by a one-point estimation rather than against a regression equation. The estimated concentration is less than the laboratory practical quantitation limit and greater than the laboratory method detection limit. M Sample and duplicate results are "out of control". The sample is non-homogenous (e.g., VOA soil). The reported value is the lower value of duplicate analyses of a sample. N1 Presumptive evidence and estimated value. The component has been tentatively identified base on mass spectral library. N2 There is an indication that the analyte is present, but quality control requirements for confirmation were not met (i.e., presence of analyte was not confirmed by alternate procedures). N3 This code shall be used if the level is too low to permit accurate quantification, but the estimated concentration is less than the laboratory practical quantitation limit and greater than the laboratory method detection limit. This code is not routinely N4 This code shall be used if the level is too low to permit accurate quantification, but the estimated concentration is less than the laboratory practical quantitation limit and greater than the instrument noise level. This code is used when an MDL has not N5 The component has been tentatively identified based on a retention time standard. P Elevated PQL* due to matrix interference and/or sample dilution. Q1 Holding time exceeded prior to receipt by lab. Q2 Holding time exceeded following receipt by lab. S Not enough sample provided to prepare and/or analyze a method-required matrix spike (MS) and/or matrix spike duplicate (MSD). U Indicates that the analyte was analyzed for but not detected above the reported practical quantitation limit*. The number value reported with the "U" qualifier is equal to the laboratory's practical quantitation limit*. U, J6 The laboratory analysis was from an unpreserved or improperly chemically preserved sample. The data may not be accurate. UU Indicates that the analyte was not detected by a screen analysis. The number value was determined by a one-point estimation at the PQL. V Indicates the analyte was detected in both the sample and the associated method blank. Note: The value in the blank shall not be subtracted from the associated samples. X1 Sample not screened for this compound. X2 Sampled, but analysis lost or not performed-field error. X3 Sampled, but analysis lost or not performed-lab error. Y Elevated PQL* due to insufficient sample size. Z1 Inability to analyze the sample. Z2 Questions concerning data reliability. WSS Chemistry Laboratory>> 1623 Mail Service Center, Raleigh, NC 27699-1623 (919) 733-3908 Page 3 of 3 "Not Detected" or "U" does not indicate the sample is analyte free but that the analyte is not detected at or above the PQL.