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WQ0032016_Monitoring - 03-2022_20220428
n .. DWR - NonDischarge Monitoring Report Submittal y. •4 .. NORTH CAROLINA Enrlranmenlel QHaflly Monitoring Report Submittal .............................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................. Permit Number#* WQ0032016 Name of Facility:* Rose Hill Plantation Month:* March Year:* 2022 Report Information Type* Upload Document* GW-59 Rose Hill(WQ0032016)GW- 2.51MB 59 with lab results 4-28-22.pdf PDF Only Please upload one PDF containing all applicable monitoring reports (i.e., NDMR, NDAR-1, NDAR-2,NDMLR,GW-59). Confirmation Email Address:* kreese@rpbsystems.com Name of Submitter:* Kimber Reese Signature: Date of submittal: 4/28/2022 This will be filled in automatically Initial Review .............................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................. Reviewer: Gerald,Wanda Is the project number correct?* WQ0032016 Is the monitoring report accepted?* Yes No Regional Office* Asheville Accepted Date: 5/10/2022 GW-59A COMPLIANCE REPORT FORM Permit# �IQ 003 201 (Submit one each,monitoring period with GW-59 forms.) Enter date monitoring results were due.( '4130122) Will this monitoring report(GW-59 and GW-59A) YES NO be submitted after the established due date? 2 Was any required information missing on the CW-59 report forms? YES NOS. IF the answer to question I or 2 is "YES", list in the space provided below the well identification number(s)and �/ explain the problems encountered in obtaining the required information. 3 Are any of the monitor wells in need of repair or maintenance(damaged casing,unlocked or missing cap,missing YES NO identification plate,area overgrown,etc.)?lithe answer is "Yes". contact the Regional Office for guidance. 4 Are any monitored constituents equal to or above the established standards? YES NO If the answer to question 4 is "NO" skip to section 8. If the answer to question 4 is "YES"list the affected wells individually with constituent(s)and concentration(s) exceeding standards in the space provided below: 5 For the constituents identified in question 4 above, have standards been exceeded previously for the YES NO same constituent(s)in the same well(s)in the last two years? If the answer to question 5 is "NO", skip to section 8. if the answer to question 5 is"YES",list in the space provided below, each well with constituent(s)exceeding standards, concentration(s)reported, and sample collection date for each occurrence(for the last two years). MW- [ p 6.4- Fe, 0.1457 1M,W-2- p 4 5.3 MW-3 Fes. 17.4 Mn o.5ag 6 Are the monitoring wells listed in section 5 located at or beyond the review boundary? YES NO If the answer is"YES", a groundwater quality problem may be occurring. CONTACT THE REGIONAL OFFICE IMMEDIATELY FOR GUIDANCE. If the answer is "NO",monitoring wells may be improperly located;contact the Regional Office. 7 Is the permittee implementing previously approved actions required by the Division involving this YES NO groundwater quality problem? If the answer to question 7 is"YES", describe those actions in the space provided below. If the answer to question 7 is "NO", contact the Regional Office within 90 days;an evaluation may be required to determine the impact the waste disposal system is having at the review and compliance boundaries surrounding this facility. Failure to do so may subject the permittee to a Notice of Violation, fines,and/or penalties. 8 The person completing this portion(GW-59A)of the monitoring report should sign below and submit this form with GW-59 forms for required wells to the address provided at the top of the current GW-59 form. I hereby acknowledge that the above information was evaluated and the information submitted in this report(Compliance Report GW-59A) is true and complete to the best of my knowledge. OA* Signature of Permittee(or Authorized Agent) Date GW-59A 12/8/2003 SUBMIT FORM ON YELLOW PAPER ONLY GROUNDWATER QUALITY MONITORING: Mail original DEPARTMENT OF OF WATER RESOURCES INFORMATION PROCESSING UNT COMPLIANCE REPORT FORM andGOpy t0: iB17 MAIL SERVICE CENTER,RALEIGH,NC 27698 1617 FACILITY INFORMATION Please Print CleadyorType PERMIT Number: Expiration Date: 6/30/2028 Facility Name: Rose Hill Plantation Development, LLC _ Non-Discharge UIC Permit Name(if different): NPDES Other WQoo32016 Facility Address: 3041 New Leicester Highway TYPE OF PERMITTED OPERATION BEING MONITORED Leicester NC 28748 County Buncombe ❑ Lagoon ❑ Remediation: Infiltration Gallery ❑ Spray Field ❑ Remediation: Contact Person: Bob Barr Telephone#: (828)251-1900 ❑ Rotary Distributor ❑ Land Application of Sludge Well Location/Site Name:Well#2(MW B on GW-lb) No.of wells to be sampled: 3 ❑ Water Source Heat Pump ❑■ Other: Surface Irrigation (from Permit) SAMPLING INFORMATION If WELL WELL ID NUMBER(from Permit): Well#2 downgradient Date sample collected: 3/21/2022 FIELD ANALYSES: WAS Well Depth: 30 ft. Well Diameter: 2 in. pH 00400: 5.3 units Temp. 00010: 14.2 °C DRY at time of Depth to Water Level 82546:32,2 ft. below measuring point Screened Interval: 10 ft. to 30 ft. Spec. Cond. 00094: 35.7 NMhos sampling, Measuring Point is 2.5 ft. above land surface Relative M.P. Elevation: ft. Odor 00085: None check Volume of water pumped/bailed before sampling: gallons Appearance Clear here:n Samples for metals were collected unfiltered: •YES ❑ NO and field acidified: ❑■ YES ❑NO LABORATORY INFORMATION Date sample analyzed:4/14/2022 Laboratory Name: Pace Analytical Certification No. 40 PARAMETERS NOTE:Values should reflect dissolved and colloidal concentrations. COD 00336 mg/L Nitrite(NO2)as N 00615 <0.040 mg/L Pb-Lead 01051 <5.0 ug/L Coliform: MF Fecal 31616 <1 1100mL Nitrate(NO3)as N 00620 1.2 mg/L Zn-Zinc 01092 <10.0 mglL Coliform: MF Total 31504 1100mL Phosphorus:Total as P 00666 <0.050 mg/L (Note: Use MPN method for highly turbid samples) Orthophosphate 70507 mg/L Other(Specify Compounds and Concentration Units): Dissolved Solids:Total 70300 36.0 mglL Al-Aluminum o1los mg/L pH (Lab)00403 units Ba-Barium 01007 23.0 uglL TOC 00680 <1-0 mg/L Ca-Calcium o0s16 mg/L Chloride o094c 4.1 mg/L Cd-Cadmium 01027 ug/L Arsenic 01002 <10.0 ug/L Chromium:Total 01034 <5.0 ug/L Grease and Oils 00552 _ mg/L Cu-Copper 01042 <5.0 rng/L ORGANICS: (by GC, GC/MS, HPLC) Phenol 32730 ug/L Fe-Iron 01045 149 ugtL (Specify test and method#.ATTACH LAB REPORT.) Sulfate 00945 _ mg/L Hg-Mercury 71900 ug/L Lab Report Attached? LI Yes(1) © No(0) Specific Conductance 00095 µMhos K-Potassium 00937 mg/L VOC 7873 , method# Total Ammonia coot <0.10 mglL Mg-Magnesium 00927 mg/L , method# (Ammonia Nitrogen,NH,asN;Ammonia Nitrogen.Total) Mn-Manganese 01055 30.5 ug/L , method# TKN as N 00625 mg/L Ni-Nickel 01067 uglL , method# For Remediation Systems Only(Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal% I certify that,to the best of my knowledge and belief,the information submitted in this report is true,accurate,and complete,and that the laboratory analytical data was produced using approved methods of analysis by a MR-certified laboratory. I am aware that there are significant penalties for submitting false information,including the possibility of fines and imprisonment for knowing violations.Robert P.Barr/Authorized Agent OAUQt C/7� Z2.-- Permittee(or Authorized Agent)Name and Title-Please print or type Signature of Permittee(or Authorized Agent) (Date) GW-59 Rev.06-07-2018 SUBMIT FORM ON YELLOW PAPER ONLY GROUNDWATER QUALITY MONITORING: Mail original DEPARTMENT OF ENVIRONMENINFORMATIONAL QUALITY-DIV.PROCESSING UNTOFYItATERRESOURCES COMPLIANCE REPORT FORM and copy t0: 1617 MAIL SERVICE CENTER,RALEIGH,NC27669.1617 FACILITY INFORMATION Please Print Clearly or Type PERMIT Number: Expiration Date: 6/30/2028 Facility Name: Rose Hill Plantation Development,LLC Non-Discharge U!C Permit Name(if different): NPDES Other W00032016 Facility Address: 3041 New Leicester Highway TYPE OF PERMITTED OPERATION BEING MONITORED Leicester NC 28748 County Buncombe ❑ Lagoon ❑ Remediation: Infiltration Gallery ❑ Spray Field ❑ Remediation: Contact Person: Bob Barr Telephone#: (828)251-1900 ❑ Rotary Distributor ❑ Land Application of Sludge Well Location/Site Name:Well#1(MW A on GW-1b) No.of wells to be sampled: 3 ❑ Water Source Heat Pump 0 Other: Surface Irrigation tfrom Permit) SAMPLING INFORMATION If WELL WELL ID NUMBER(from Permit): Well#1 Upgradient Date sample collected: 3/21/2022 FIELD ANALYSES: WAS Well Depth: 69 ft. Well Diameter: 2 in. pH 00400: 6.4 units Temp.00010: 21.0 °C DRY at Depth to Water Level sz546:34.204Mhos time of p ft. below measuring point Screened Interval: 9 ft. to 69 ft. Spec. Cond, 00094: 50.2 p sampling, Measuring Point is 2.5 ft. above land surface Relative M.P. Elevation: ft. Odor 00085: None check Volume of water pumped/bailed before sampling: gallons Appearance Clear here: Samples for metals were collected unfiltered: ❑■ YES ❑ NO and field acidified: ❑■ YES ❑ NO LABORATORY INFORMATION Date sample analyzed:4/14/2022 Laboratory Name: Pace Analytical Certification No, 40 PARAMETERS NOTE:Values should reflect dissolved and colloidal concentrations. COD 00335 mg/L Nitrite(NO2)as N 00615 <0.040 mg/L Pb-Lead o1os1 <5.0 uglL Coliform: MF Fecal 31616 <1 /100mL Nitrate(NO3)as N 00620 <0.040 mg/L Zn-Zinc 01092 <10,0 mg/L Coliform: MF Total 31504 /100mL Phosphorus:Total as P 00665 0.081 mg/L {Note use MPN method for highly turbid samples) Orthophosphate 70507 mg/L Other(Specify Compounds and Concentration Units): 'Dissolved Solids:Total 70300 53.0 mg/L Al-Aluminum 01105 mg/L _ pH (Lab)00403 units Ba-Barium 01007 20.7 ug/L TOC 00680 <1.0 mg/L Ca-Calcium 00916 mglL _ Chloride 00940 <1.0 mglL Cd-Cadmium 01027 ug/L Arsenic 01002 <10.0 ug/L Chromium:Total 01034 <5.0 ugh_ _ Grease and Oils 00552 mg/L Cu-Copper 01042 <5.0 mg/L ORGANICS: (by GC, GC/MS, HPLC) Phenol 32730 ug/L Fe-Iron o1045 457 ug/L (Specify test and method#.ATTACH LAB REPORT.) Sulfate 00945 mg/L Hg-Mercury 71900 ug/L Lab Report Attached? ❑ Yes (1) ❑■ No(0) Specific Conductance 00095 0Mhos K- Potassium 00937 mg/L VOC 7873 , method# Total Ammonia 00610 <0.10 mg/L Mg-Magnesium o0927 mg/L , method# (Ammonia Nitrogen,NH,as N,Ammonia Nitrogen,Total) Mn-Manganese 01055 22.0 ug/L , method# TKN as N 00625 mg/L Ni-Nickel 01067 uglL , method# For Remediation Systems Only(Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal% I certify that,to the best of my knowledge and belief,the information submitted in this report is true,accurate,and complete,and that the laboratory analytical data was produced using approved methods of analysis by a DWR-certified laboratory. lam aware that there are significant penalties for submitting false information,including the possibility of fines and imprisonment for knowing violations. Robert P.Barr 1 Authorized Agent , rl -02,..-- Permittee(or Authorized Agent)Name and Title-Please print or type Signature of Permittee(or Authorized Agent) (Date) GW-59 Rev.06-07-2018 SUBMIT FORM ON YELLOW PAPER ONLY GROUNDWATER QUALITY MONITORING: Mail original RePARTIIAENrnFINFORMATIONPRONMENTAL CESSINc NALITY- ITGF WATER RE50t,RCES COMPLIANCE REPORT FORM and copy to: 1617 MAIL SERVICE CENTER,RALEIGH,NC 27699-1617 FACILITY INFORMATION Please Print cteadyorType PERMIT Number: Expiration Date: 6/3o/2028 Facility Name: Rose Hill Plantation Development,LLC Non-Discharge UIC Permit Name(if different): NPDES Other W00032016 Facility Address: 3041 New Leicester Highway TYPE OF PERMITTED OPERATION BEING MONITORED Leicester NC 28748 County Buncombe ❑ Lagoon ❑ Remediation: Infiltration Gallery ❑ Spray Field ❑ Remediation: Contact Person: Bob Barr Telephone#: (828)251-1900 ❑ Rotary Distributor ❑ Land Application of Sludge Well Location/Site Name:Well#3 No.of wells to be sampled: 3 ❑ Water Source Heat Pump ❑■ Other: Surface Irrigation (From Permit} SAMPLING INFORMATION If WELL WELL ID NUMBER(from Permit): Well#3 Date sample collected: 3/21/2022 FIELD ANALYSES: WAS Well Depth: 14 ft. Well Diameter: 2 in. pH 00400: 6.3 units Temp. onto: 16.1 °C DRY at Depth to Water Level 82546;4.23 ft. below measuring point Screened Interval: 4 ft. to 14 ft. Spec. Cond.00694: 109.2 µMhos time of sampling, Measuring Point is 0 ft. above land surface Relative M.P. Elevation: ft. Odor 00085: None check Volume of water pumped/bailed before sampling: gallons Appearance Clear here: Samples for metals were collected unfiltered: •YES ❑ NO and field acidified: ❑■ YES ❑NO LABORATORY INFORMATION Date sample analyzed:4/14/2022 Laboratory Name: Pace Analytical Certification No, 40 PARAMETERS NOTE:Values should reflect dissolved and colloidal concentrations. COD 00335 mglL Nitrite(NO2) as N 00615 <0.040 mg/L Pb-Lead most <5.0 uglL Coliform: MF Fecal 31616 <1 /100mL Nitrate(NO3)as N o0szo <0.064 mg!L Zn-Zinc 01092 <10.0 mg/L Coliform: MF Total 31504 /100mL Phosphorus: Total as P ao665 0.53 mg/L (Note. Use MPN method for highly turbid samples) - - Orthophosphate 70507 mg/L Other(Specify Compounds and Concentration Units): Dissolved Solids:Total 70300 91.0 mg/L Al-Aluminum o11o5 mg/L _ pH (Lab)00403 units Ba-Barium 01007 12.0 uglL _ TOC oeea0 <1.0 mg/L Ca-Calcium 00916 mg/L _ Chloride 0094o 4.4 mg/L Cd-Cadmium 01027 ug/L Arsenic o1002 <10.0 ug/L Chromium: Total 01034 <5.0 ug/L Grease and Oils 00552 mg/L Cu-Copper 01042 <5.0 mg/L ORGANICS: (by GC, GC/MS, HPLC) Phenol 32730 uglL Fe-Iron 010as 17600 ug/L (Specify test and method#.ATTACH LAB REPORT.) Sulfate 00945 mg!L Hg-Mercury 71900 ug/L Lab Report Attached? E Yes(1) 0 No(0) Specific Conductance aooss {Mhos K-Potassium 00937 mg!L VOC 7873 , method# Total Ammonia 00610 <0.10 mg/L Mg-Magnesium 00927 mg/L , method# (Ammonia Nitrogen,NH,asN,Ammonia Nitrogen,Total) Mn-Manganese 01055 598 ug/L , method# TKN as N 00625 mg/L Ni-Nickel 01067 ug/L , method# For Remediation Systems Only(Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg!L VOC Removal% I certify that,to the best of my knowledge and belief,the information submitted in this report is true,accurate,and complete,and that the laboratory analytical data was produced using approved methods of analysis by a DWR-certified laboratory. I am aware that there are significant penalties for submitting false information,including the possibility of fines and imprisonment for knowing violations. �JG Robert P.Barr 1 Authorized Agent �` `p '2 2______ Permittee(or Authorized Agent)Name and Title-Please print or type Signature of Permittee(or Authorized Agent) (Date) GW-59 Rev.06-07-2018 Pace Analytical Services,LLC aceAnalytical® Asheville, Riverside 2e 04 Asheville,NC 28804 www.paeelabs.enm (828)254-7176 ANALYTICAL RESULTS Project: Rose Hill MW Pace Project No.: 92594545 Sample: MW-1 Lab ID: 92594545001 Collected: 03/21/22 14:10 Received: 03/21/22 18:05 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual Monitoring Well Data Analytical Method: Pace Analytical Services-Charlotte Performed by Pace 1 04/27/22 16:03 Collected By S.Warlick 1 04/27/22 16:03 Collected Date 3/21/22 1 04/27/22 16:03 Collected Time 14:10 1 04/27/22 16:03 pH 6.4 Std. Units 1 04/27/22 16:03 Temperature 21.0 deg C 1 04/27/22 16:03 Static Water Level 34.20 feet 1 04/27/22 16:03 Specific Conductance 50.2 umhos/cm 1 04/27/22 16:03 Oxygen, Dissolved 4.2 mg/L 1 04/27/22 16:03 7782-44-7 Total Well Depth 69.0 feet 1 04/27/22 16:03 REDOX 35.3 mV 1 04/27/22 16:03 Turbidity 8.7 NTU 1 04/27/22 16:03 Odor ND 1 04/27/22 16:03 Appearance Clear 1 04/27/22 16:03 200.7 MET ICP Analytical Method: EPA 200.7 Rev 4.4 1994 Preparation Method: EPA 200.7 Rev 4.4 1994 Pace Analytical Services-Asheville Arsenic ND ug/L 10.0 1 03/24/22 11:54 03/24/22 22:12 7440-38-2 Barium 20.7 ug/L 5.0 1 03/24/22 11:54 03/24/22 22:12 7440-39-3 Chromium ND ug/L 5.0 1 03/24/22 11:54 03/24/22 22:12 7440-47-3 Copper ND ug/L 5.0 1 03/24/22 11:54 03/24/22 22:12 7440-50-8 Iron 457 ug/L 50.0 1 03/24/22 11:54 03/24/22 22:12 7439-89-6 Lead ND ug/L 5.0 1 03/24/22 11:54 03/24/22 22:12 7439-92-1 Manganese 22.0 ug/L 5.0 1 03/24/22 11:54 03/24/22 22:12 7439-96-5 Zinc ND ug/L 10.0 1 03/24/22 11:54 03/24/22 22:12 7440-66-6 2540C Total Dissolved Solids Analytical Method: SM 2540C-2015 Pace Analytical Services-Asheville Total Dissolved Solids 53.0 mg/L 25.0 1 03/22/22 15:32 350.1 Ammonia Analytical Method: EPA 350.1 Rev 2.0 1993 Pace Analytical Services-Asheville Nitrogen,Ammonia ND mg/L 0.10 1 04/01/22 09:27 7664-41-7 353.2 Nitrogen,NO2/NO3 unpres Analytical Method: EPA 353.2 Rev 2.0 1993 Pace Analytical Services-Asheville Nitrogen, Nitrate ND mg/L 0.040 1 03/22/22 15:17 14797-55-8 Nitrogen, Nitrite ND mg/L 0.040 1 03/22/22 15:17 14797-65-0 365.1 Phosphorus,Total Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation Method: EPA 365.1 Rev 2.0 1993 Pace Analytical Services-Asheville Phosphorus 0.081 mg/L 0.050 1 03/29/22 19:34 03/30/22 17:03 7723-14-0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced,except in full, Date: 04/27/2022 04:18 PM without the written consent of Pace Analytical Services,LLC. Page 4 of 26 Pace Analytical Services,LLC aceAnalytical® Asheville, Riverside 2e 04 Asheville,NC 28804 www.paeelabs.enm (828)254-7176 ANALYTICAL RESULTS Project: Rose Hill MW Pace Project No.: 92594545 Sample: MW-1 Lab ID: 92594545001 Collected: 03/21/22 14:10 Received: 03/21/22 18:05 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 4500 Chloride Analytical Method: SM 4500-CI-E-2011 Pace Analytical Services-Asheville Chloride ND mg/L 1.0 1 03/29/22 19:18 16887-00-6 5310B TOC Analytical Method: SM 5310B-2014 Pace Analytical Services-Asheville Total Organic Carbon ND mg/L 1.0 1 03/23/22 18:28 7440-44-0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced,except in full, Date: 04/27/2022 04:18 PM without the written consent of Pace Analytical Services,LLC. Page 5 of 26 Pace Analytical Services,LLC aceAnalytical® Asheville, Riverside 2e 04 Asheville,NC 28804 www.paeelabs.enm (828)254-7176 ANALYTICAL RESULTS Project: Rose Hill MW Pace Project No.: 92594545 Sample: MW-1 Lab ID: 92594825001 Collected: 03/22/22 09:25 Received: 03/22/22 10:10 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual MBIO 9222D Fecal Coliform AVL Analytical Method: SM 9222D-2015 Preparation Method:SM 9222D-2015 Pace Analytical Services-Asheville Fecal Coliforms ND CFU/100 mL 1.0 1 03/22/22 15:14 03/23/22 15:32 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced,except in full, Date: 04/27/2022 04:18 PM without the written consent of Pace Analytical Services,LLC. Page 8 of 26 Pace Analytical Services,LLC aceAnalytical® Asheville, Riverside 2e 04 Asheville,NC 28804 www.paeelabs.enm (828)254-7176 ANALYTICAL RESULTS Project: Rose Hill MW Pace Project No.: 92594545 Sample: MW-2 Lab ID: 92594545002 Collected: 03/21/22 12:30 Received: 03/21/22 18:05 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual Monitoring Well Data Analytical Method: Pace Analytical Services-Charlotte Temperature 14.2 deg C 1 04/27/22 16:05 Static Water Level 9.46 feet 1 04/27/22 16:05 Specific Conductance 35.7 umhos/cm 1 04/27/22 16:05 Oxygen, Dissolved 6.5 mg/L 1 04/27/22 16:05 7782-44-7 Total Well Depth 32.20 feet 1 04/27/22 16:05 REDOX 42.3 mV 1 04/27/22 16:05 Turbidity 2.5 NTU 1 04/27/22 16:05 Odor ND 1 04/27/22 16:05 Appearance Clear 1 04/27/22 16:05 200.7 MET ICP Analytical Method: EPA 200.7 Rev 4.4 1994 Preparation Method: EPA 200.7 Rev 4.4 1994 Pace Analytical Services-Asheville Arsenic ND ug/L 10.0 1 03/24/22 11:54 03/24/22 22:22 7440-38-2 Barium 23.0 ug/L 5.0 1 03/24/22 11:54 03/24/22 22:22 7440-39-3 Chromium ND ug/L 5.0 1 03/24/22 11:54 03/24/22 22:22 7440-47-3 Copper ND ug/L 5.0 1 03/24/22 11:54 03/24/22 22:22 7440-50-8 Iron 149 ug/L 50.0 1 03/24/22 11:54 03/24/22 22:22 7439-89-6 Lead ND ug/L 5.0 1 03/24/22 11:54 03/24/22 22:22 7439-92-1 Manganese 30.5 ug/L 5.0 1 03/24/22 11:54 03/24/22 22:22 7439-96-5 Zinc ND ug/L 10.0 1 03/24/22 11:54 03/24/22 22:22 7440-66-6 2540C Total Dissolved Solids Analytical Method: SM 2540C-2015 Pace Analytical Services-Asheville Total Dissolved Solids 36.0 mg/L 25.0 1 03/22/22 15:32 350.1 Ammonia Analytical Method: EPA 350.1 Rev 2.0 1993 Pace Analytical Services-Asheville Nitrogen,Ammonia ND mg/L 0.10 1 04/01/22 09:29 7664-41-7 353.2 Nitrogen,NO2/NO3 unpres Analytical Method: EPA 353.2 Rev 2.0 1993 Pace Analytical Services-Asheville Nitrogen, Nitrate 1.2 mg/L 0.040 1 03/22/22 15:13 14797-55-8 Nitrogen, Nitrite ND mg/L 0.040 1 03/22/22 15:13 14797-65-0 365.1 Phosphorus,Total Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation Method: EPA 365.1 Rev 2.0 1993 Pace Analytical Services-Asheville Phosphorus ND mg/L 0.050 1 03/29/22 19:34 03/30/22 17:05 7723-14-0 4500 Chloride Analytical Method: SM 4500-CI-E-2011 Pace Analytical Services-Asheville Chloride 4.1 mg/L 1.0 1 03/29/22 19:21 16887-00-6 5310B TOC Analytical Method: SM 5310B-2014 Pace Analytical Services-Asheville Total Organic Carbon ND mg/L 1.0 1 03/23/22 18:45 7440-44-0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced,except in full, Date: 04/27/2022 04:18 PM without the written consent of Pace Analytical Services,LLC. Page 6 of 26 Pace Analytical Services,LLC aceAnalytical® Asheville, Riverside 2e 04 Asheville,NC 28804 www.paeelabs.enm (828)254-7176 ANALYTICAL RESULTS Project: Rose Hill MW Pace Project No.: 92594545 Sample: MW-2 Lab ID: 92594825002 Collected: 03/22/22 09:10 Received: 03/22/22 10:10 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual MBIO 9222D Fecal Coliform AVL Analytical Method: SM 9222D-2015 Preparation Method:SM 9222D-2015 Pace Analytical Services-Asheville Fecal Coliforms ND CFU/100 mL 1.0 1 03/22/22 15:14 03/23/22 15:32 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced,except in full, Date: 04/27/2022 04:18 PM without the written consent of Pace Analytical Services,LLC. Page 9 of 26 Pace Analytical Services,LLC aceAnalytical® Asheville, Riverside 2e 04 Asheville,NC 28804 www.paeelabs.enm (828)254-7176 ANALYTICAL RESULTS Project: Rose Hill MW Pace Project No.: 92594545 Sample: MW-3B Lab ID: 92594545003 Collected: 03/21/22 17:25 Received: 03/21/22 18:05 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual Monitoring Well Data Analytical Method: Pace Analytical Services-Charlotte Temperature 16.1 deg C 1 04/27/22 16:07 Static Water Level 4.23 feet 1 04/27/22 16:07 Specific Conductance 109.2 umhos/cm 1 04/27/22 16:07 Oxygen, Dissolved 0.2 mg/L 1 04/27/22 16:07 7782-44-7 Total Well Depth 14.0 feet 1 04/27/22 16:07 REDOX -29.7 mV 1 04/27/22 16:07 Turbidity 9.9 NTU 1 04/27/22 16:07 Odor ND 1 04/27/22 16:07 Appearance Clear 1 04/27/22 16:07 200.7 MET ICP Analytical Method: EPA 200.7 Rev 4.4 1994 Preparation Method: EPA 200.7 Rev 4.4 1994 Pace Analytical Services-Asheville Arsenic ND ug/L 10.0 1 03/24/22 11:54 03/24/22 22:25 7440-38-2 Barium 12.0 ug/L 5.0 1 03/24/22 11:54 03/24/22 22:25 7440-39-3 Chromium ND ug/L 5.0 1 03/24/22 11:54 03/24/22 22:25 7440-47-3 Copper ND ug/L 5.0 1 03/24/22 11:54 03/24/22 22:25 7440-50-8 Iron 17600 ug/L 50.0 1 03/24/22 11:54 03/24/22 22:25 7439-89-6 Lead ND ug/L 5.0 1 03/24/22 11:54 03/24/22 22:25 7439-92-1 Manganese 598 ug/L 5.0 1 03/24/22 11:54 03/24/22 22:25 7439-96-5 Zinc ND ug/L 10.0 1 03/24/22 11:54 03/24/22 22:25 7440-66-6 2540C Total Dissolved Solids Analytical Method: SM 2540C-2015 Pace Analytical Services-Asheville Total Dissolved Solids 91.0 mg/L 25.0 1 03/22/22 15:32 350.1 Ammonia Analytical Method: EPA 350.1 Rev 2.0 1993 Pace Analytical Services-Asheville Nitrogen,Ammonia ND mg/L 0.10 1 04/01/22 09:30 7664-41-7 353.2 Nitrogen,NO2/NO3 unpres Analytical Method: EPA 353.2 Rev 2.0 1993 Pace Analytical Services-Asheville Nitrogen, Nitrate 0.064 mg/L 0.040 1 03/22/22 15:18 14797-55-8 Nitrogen, Nitrite ND mg/L 0.040 1 03/22/22 15:18 14797-65-0 365.1 Phosphorus,Total Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation Method: EPA 365.1 Rev 2.0 1993 Pace Analytical Services-Asheville Phosphorus 0.53 mg/L 0.050 1 03/31/22 18:49 04/01/22 09:51 7723-14-0 4500 Chloride Analytical Method: SM 4500-CI-E-2011 Pace Analytical Services-Asheville Chloride 4.4 mg/L 1.0 1 03/29/22 19:23 16887-00-6 5310B TOC Analytical Method: SM 5310B-2014 Pace Analytical Services-Asheville Total Organic Carbon ND mg/L 1.0 1 03/23/22 19:00 7440-44-0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced,except in full, Date: 04/27/2022 04:18 PM without the written consent of Pace Analytical Services,LLC. Page 7 of 26 Pace Analytical Services,LLC aceAnalytical® Asheville, Riverside 2e 04 Asheville,NC 28804 www.paeelabs.enm (828)254-7176 ANALYTICAL RESULTS Project: Rose Hill MW Pace Project No.: 92594545 Sample: MW-3B Lab ID: 92594825003 Collected: 03/22/22 09:35 Received: 03/22/22 10:10 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual MBIO 9222D Fecal Coliform AVL Analytical Method: SM 9222D-2015 Preparation Method:SM 9222D-2015 Pace Analytical Services-Asheville Fecal Coliforms ND CFU/100 mL 1.0 1 03/22/22 15:14 03/23/22 15:32 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced,except in full, Date: 04/27/2022 04:18 PM without the written consent of Pace Analytical Services,LLC. Page 10 of 26 ere CHAIN-OF-CUSTODY Analytical Request Document LAB USE ONLY-Affix Workor Pr! •r Number or Pace Analytical WO : g2 9464 Chain-of-Custody is a LEGAL DOCUMENT-Complete all relevent fields Campany:y�--15^ e j ��C' Billing Information: 11111111111111II III r Address:„3Xi 32 s I Cont 92594545 Report To: y� 1 `ter Email To: ••Preservative Types:t.r.sex,aria,(1)sulruric acid,(3)hydrochloric acid,(4)sodium hydroxide,(5)zinc acetate, I�0 i (6)methanol,(7)sodium bisulfate,(8)sodium thiosulfate,(9)hexane,(Al ascorbic acid,{8)ammonium sulfate, Copy To: Site Collection Info/Address: (C)ammonium hydroxide,(D)TSP,(U)Unpreserved,{O)Other Analyses Lab Profile/Line: Customer Project Nam, e//Number: State: County/City: Time Zone Collected. Lab Sample Receipt Checklist: 4'5e 7r�J 111 M 14) NG/,kev`•ie I )PT[ )MT[ ]CT i, rET Custody Seals Present/Intact Y N NA Phone: Site/Facility ID#: Compliance Monitoring? Custody Signatures Present Y N NA Email: Yes [ ]No Collector Signature Present Y N NA Bottles Intact Y N NA Collected By(print): Purchase Order#: OW PWS ID#; correct Bottles Y N NA Quote#: DW Location Code: Sufficient Volume Y N NA Samples Received on Ice Y N NA Collected By(signature): Turnaround Date Required: immediately Packed on Ice: _ , I VOA - Headspace Acceptable Y N NA Yes [ ]No ti- L•! USDA Regulated Soils Y N NA rr �f^ C7 Samples in Holding Time Y N NA Sample Disposal: Rush: Field Filtered(if applicable): I-- Residual Chlorine Present Y N NA [ ]Dispose as appropriate [ ]Return [ ]Same Day [ ]Next Day [ ]Yes [ )No -- /'''�7 Cl Strips: I ]Archive: [ ]2 Day [ ]3 Day [ ]4 Day [ ]5 Day `S' Sample pH Acceptable Y N NA 1 ]Hoid: (Expedite Charges Apply) Analysis: pH Strips: \! Sulfide Present Y N NA *Matrix Codes(Insert in Matrix box below):Drinking Water(DW),Ground Water(GW),Wastewater(WW), C.. 4. �1 t/1 Lead Acetate Strips: Product(P),Soil/Solid(SL),Oil(OL),Wipe(WP),Air(AR),Tissue(TS),Bioassay(B),Vapor(V),Other(OT) �� V E LAB USE ONLY: Comp/ Collected(or Res #of o Li -.1- � --I-- Lab Sample # / Comments:FeculS Yet,eiUea Customer Sample ID Matrix* Grab Composite Start) Composite End Cl Ctns U -'.S1 `- l�i .es. a�Y 5jPry' Date Time Date Time LiLt ._ l` z0.- ci21 `5 s ')w-- I w-T- CT 3(z ihz .1 w5 3/z(/22, 1 to \1 o x x n A ?5' x ) x MIA -Q L-r- G 3/z]l_ t-) \() )/i/zt, \, , - --__. 10 >c x • x x x .x , x Mi..)- 13 L i G 3j2lia i $a� 31z(iz? ,' -12 j+':' x K K x. 'IC ?c X • Customer Remarks/Special Conditions/Possible Hazards: Type of Ice Used: et' Blue Dry None SHORT HOLDS PRESENT(<72 hours):(7)N N/A Lab Sample Temperature Info: tiefi r)s-- ,'!sf `Sel t C r r CA I re/ Packing Material Used: Lab Tracking#: �] C 9 7 2 O 6 Temp lBlaa#nk Received: Y N NA Ti,, t"'^ l �n ( Q�, G[� Q Cooler 1 Temp Upon Receipt: oC M — t , H S kr q W-� j g: b r(1 Samples received via: Cooler 1 Therm Corr.Factor: oC ._ ". - - S "\ } Radchem sample(s)screened(<500 cpm): Y N NA FEDEX UPS Client Courier Pace Courier Cooler 1 Corrected Temp: oC YI_\ 4/ gPW 3f2V- Relinquished by/Company:(Signature) Date/Time: I Receiv d by/Comp :(Signature) Date/Time: C,/� MTJL LAB USE ONLY Comments: t1 e) mini' (C 't t 1?/°•0( :2- \ 0♦3 ��Z] I ii 1805 Acctnum:i Rel mquished by/Company:(Signature) ^Da e�me: Rec v b� nignature) Da e/Ti e:Iv Template: TripBlank Received: Y N NA w HCL McOH TSP Other o Prelogin: ReliN wished by/Company:(Signature) Date/Time: Received by/Company:{Signature) Date/Time: PM: Non Conformance(s): Page: PB: YES / NO of: r CHAIN-OF-CUSTODY Analytical Request Document LAI IO# : 92594825 er Number or co N Pace Analytical' 1111111 IIIIIIIII III IIIois a LEGAL DOCUMENT-Complete all relevent fieldsCompany: • Billing Information:P S S -.e con` „_ LY 92594825 a Address: iG Do1 70 I Coil I I I I I Report To: p r Email To: •••Preservative Types:(1)nitric acid,(2)sulfuric acid,(3)hydrochloric acid,(4)sodium hydroxide,(5)zinc acetate, [�� 6E., a r{r rI C/+ (6)methanol,(7)sodium bisulfate,(8)sodium thiosulfate,(9)hexane,(A)ascorbic acid,(8)ammonium sulfate, Copy To: Site Collection Info/Address: (Cl ammonium hydroxide,(D)TSP,(U)Unpreserved,(0)Other Analyses Lab Profile/Line: Customer Project Name/Number: State: County/City: Time Zone Collected: Lab sample Receipt Checklist: t1O\ �• r / / ,p [ ]PT[ ]MT[ ]CT ET I } i �7 '�. 14 I' d 9 i'�4rt 'WC- I� �L�! `t[, Y t Custody Seals Present/Intact Y N4DI A Phone: Site/Facility ID#: Compliance Monitoring? Custody Signatures Present Y N } Email: NYes [ ]No Collector Signature Present 4,N..NA Bottles Intact In N NA Collected By(print): Purchase Order#: DW PWS ID#: Correct Bottles N NA Quote#: DW Location Code: Sufficient Volume N NA Samples Received on Ice N NA Collected By(signature): Turnaround Date Required: Immediately Packed on Ice: VOA - Headspace Acceptable Y N r USDA Regulated Soils Y N I Yes [ I No Samples in Holding Time 0 N -A Sample Disposal: Rush: Field Filtered(if applicable): Residual Chlorine Present Y N pad. [ ]Dispose as appropriate [ ]Return [ ]Same Day ( [Next Day [ ]Yes [ ]No Cl Strips: •/ tfi?. [ [Archive: [ ]2 Day [ ]3 Day [ ]4 Day [ ]S Day Sample pH Acceptable Y N ✓ [ I Hold: (Expedite Charges Apply) Analysis: pH Strips: Sulfide Present Y N 1l *Matrix Codes(Insert in Matrix box below):Drinking Water(DW),Ground Water(GW),Wastewater(WW), Lead Acetate Strips: (/ Product(P),Soil/Solid(SL),Oil(OL),Wipe(WP),Air(AR),Tissue(TS),Bioassay(B),Vapor(V),Other(OT) LAB USE ONLY: Comp/ Collected(or Res #of ` Lab Sample # / Comments: Customer Sample ID Matrix" Composite End P Grab Composite Start) CI Ctns Date Time Date Time % - 67'7 5, `{ <- Z-S r �' Customer Remarks/Special Conditions/Possible Hazards: Type of Ice Used: ('' et) Blue Dry None SHORT HOLDS PRESENT(<72 hours): ON N/A Lab Sample Temperature Info: F' A�t ,� Packing Material Temp Blank Received: Y N NA 1 Used' Lab Tracking#: Temp 4 8 5 1 , _ b Therm ID#: �t1�' w A 1 7 -\ ') Cooler 1 Temp Upon Receipt: oC IAry ,J ^ .- `\ Radchem sample(s)screened(<S00 rpm): Y N NA Samples received via: Cooler 1 Therm Corr.Factor: oC FEDEX UPS Client Courier Pace Courier Cooler 1 Corrected Temp: oC Relinquished by/Company:(Signature) Date/Time: Received b Company:(Signal e) Date/Time: MTJL LAB USE ONLY Comments: f ct f 31 2.Z -2JZ Iz l -.r, Table#: 1 trfi \ Acctnum: Relinquished by/Company: ,Signature) Date/Time: Received by/Company: Signature) Date/Ti e: Template: Trip Blank Received: Y N NA Prelogin: HCL McOH TSP Other Relinquished by/Company:(Signature) Date/Time: Received by/Company:(Signature) Date/Time: PM: Non Conformance(s): Page: PB: YES / NO of: Pace Analytical Services,LLC aceAnalytical® Asheville, Riverside 2e 04 Asheville,NC 28804 www.pacelabs.cam (828)254-7176 April 27, 2022 Kimber Reese RPB Systems Inc. P.O. Box 1325 Asheville, NC 28802 RE: Project: Rose Hill MW Pace Project No.: 92594545 Dear Kimber Reese: Enclosed are the analytical results for sample(s) received by the laboratory between March 21, 2022 and March 22, 2022. The results relate only to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the laboratory's Quality Manual,where applicable, unless otherwise noted in the body of the report. The test results provided in this final report were generated by each of the following laboratories within the Pace Network: • Pace Analytical Services-Asheville • Pace Analytical Services-Charlotte Revised Report. The Field Data has been included with this report. If you have any questions concerning this report, please feel free to contact me. Sincerely, Lorri Patton lorri.patton@pacelabs.com 1(828)254-7176 Project Manager Enclosures cc: Mr. Robert Barr, RPB Systems Inc. Ms. Liz Barr, RPB Systems Inc. Cody Pannell, RPB Systems Q A«RF6 ,.,-( `i REPORT OF LABORATORY ANALYSIS I TNI This report shall not be reproduced,except in full, \4 may/ without the written consent of Pace Analytical Services,LLC. Page 1 of 26 ,80RAZ9'