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HomeMy WebLinkAboutWQ0028693_Monitoring - 03-2022_20220428 ti DWR - NonDischarge Monitoring Report Submittal ' •4 .. NORTH CAROLINA Enrlranmenlel QHaflly Monitoring Report Submittal .............................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................. Permit Number#* WQ0028693 Name of Facility:* Mountain Top Golf&Lake Club Month:* March Year:* 2022 Report Information Type* Upload Document* GW-59 Mountain Top(WQ0028693) 2.06MB GW-59 with lab results 4-28- 22.pdf PDF Only Please upload one PDF containing all applicable monitoring reports (i.e., NDMR, NDAR-1,NDAR-2,NDMLR,GW-59). Confirmation Email Address:* kreese@rpbsystems.com Name of Submitter:* Kimber Reese Signature: Date of submittal: 4/28/2022 This will be filled in automatically Initial Review Reviewer: Gerald,Wanda Is the project number correct?* WQ0028693 Is the monitoring report accepted?* Yes No Regional Office* Asheville Accepted Date: 5/10/2022 GW-59A COMPLIANCE REPORT FORM Permit# we QCZ5cog3 (Submit one each monitoring period with GW-59 forms.) 1 Enter date monitoring results were due.(1-1l50f21. ) Will this monitoring report(GW-59 and GW-59A) YES NO be submitted after the established due date? 2 Was any required information missing on the GW-59 report forms? YES N✓ IF the answer to question I or 2 is"YES', list in the space provided below the well identification number(s)and explain the problems encountered in obtaining the required information. 3 Are any of the monitor wells in need of repair or maintenance(damaged casing,unlocked or missing cap,missing YES NO identification plate,area overgrown,etc.)?lithe answer is "Yes", contact the Regional Office for guidance. 1/7 4 Are any monitored constituents equal to or above the established standards? YES N� If the answer to question 4 is "NO" skip to section 8. If the answer to question 4 is "YES"list the affected wells individually with constituent(s)and concentration(s) exceeding standards in the space provided below: 5 For the constituents identified in question 4 above, have standards been exceeded previously for the YES NO same constituent(s) in the same well(s) in the last two years? if the answer to question 5 is "NO", skip to section 8. If the answer to question 5 is "YES",list in the space provided below, each well with constituent(s)exceeding standards, concentration(s)reported, and sample collection date for each occurrence(for the last two years). A4VV--0r2 pH 5.7 MW- 2- p (p.o Nvl W- 3 P Co. 6 Are the monitoring wells listed in section 5 located at or beyond the review boundary? YES NO if the answer is "YES", a groundwater quality problem may be occurring. CONTACT THE REGIONAL OFFICE IMMEDIATELY FOR GUIDANCE. If the answer is "NO", monitoring wells may be improperly located;contact the Regional Office. 7 Is the permittee implementing previously approved actions required by the Division involving this YES NO groundwater quality problem? If the answer to question 7 is "YES", describe those actions in the space provided below. If the answer to question 7 is "NO", contact the Regional Office within 90 days;an evaluation may be required to determine the impact the waste disposal system is having at the review and compliance boundaries surrounding this facility. Failure to do so may subject the permittee to a Notice of Violation, fines, and/or penalties. 8 The person completing this portion(GW-59A)of the monitoring report should sign below and submit this form with GW-59 forms for required wells to the address provided at the top of the current GW-59 form. 1 hereby acknowledge that the above information was evaluated and the information submitted in this report(Compliance Report GW-59A)is true and complete to the best of my knowledge. Signature of permittee(or Authorized Agent) Date GW-59A 12/8/2003 SUBMIT FORM ON YELLOW PAPER ONLY Mail original DEPARTMENT OF ENVIRONMENTAL QUALITY-DIV.OF WATER RESOURCES GROUNDWATER QUALITY MONITORING: and 1 copy to: INFORMATION PROCESSING UNIT COMPLIANCE REPORT FORM 1617 MAIL SERVICE CENTER,RALEIGH,NC 27699-1617 FACILITY INFORMATION Please Print Clearly or Type PERMIT Number: Expiration Date: 4/30/2025 Facility Name: Mountaintop Golf&Lake Club Non-Discharge WQ0028693 UIC Permit Name(if different) Mountaintop Community Association Inc NPDES Other Facility Address: P.O.Box 1460 TYPE OF PERMITTED OPERATION BEING MONITORED Cashiers NC 28717 County Jackson ❑ Lagoon LI Remediation: Infiltration Gallery ❑■ Spray Field ❑ Remediation: Contact Person: Bob Barr Telephone#: (828)251-1900 ❑ Rotary Distributor ❑ Land Application of Sludge Well Location/Site Name:MW-01 R No.of wells to be sampled: 3 LI Water Source Heat Pump LI Other: dram Permit) SAMPLING INFORMATION If WELL WELL ID NUMBER(from Permit): MW-OIR Date sample collected: 3/31/2022 _ FIELD ANALYSES: WAS Well Depth: 26.6 ft. Well Diameter: 2 in. pH 00400: 5.7 units Temp.eoo10: 12.1 °C DRY at uMhos time of Depth to Water Level 82546:11.66 ft. below measuring point Screened Interval: 15.6 ft. to 25.6 ft. Spec. Cond.0oo94: 56.4 sampling, Measuring Point is 0 ft.above land surface Relative M.P. Elevation: ft. Odor 00085 None check Volume of water pumped/bailed before sampling: gallons Appearance None here:❑ Samples for metals were collected unfiltered: t YES ❑ NO and field acidified: 0 YES ❑ NO t LABORATORY INFORMATION Date sample analyzed:4/12/2022 Laboratory Name: Pace Analytical Certification No, 40 PARAMETERS NOTE:Values should reflect dissolved and colloidal concentrations. COD 00335 mg/L Nitrite(NO2)as N 00615 mglL Pb-Lead 01051 ugfL Coliform: MF Fecal 31616 <1 /100mL Nitrate(NO3)as N 00620 0.13 mg/L Zn-Zinc 01092 mg/L Coliform: MF Total 31504 1100mL Phosphorus:Total as P 00665 0.071 mg/L (Note. Use MPN method for highly turbid samples) Orthophosphate 70507 mg/L Other(Specify Compounds and Concentration Units): Dissolved Solids:Total 70300 46.0 mgfL Al-Aluminum 01105 mg/L pH (Lab)00403 units Ba-Barium 01007 ug/L TOC 00680 <1.0 mg/L Ca-Calcium 00916 mg/L Chloride 00940 3-7 mglL Cd-Cadmium 01027 ugh. Arsenic o1002 uglL Chromium: Total 01034 uglL Grease and Oils 00552 mg/L Cu-Copper 01042 mg/L ORGANICS: (by GC, GC/MS, HPLC) Phenol 32730 ug/L Fe-Iron 0104s ugfL (Specify test and method#.ATTACH LAB REPORT.) Sulfate 00945 mg/L Hg-Mercury 71900 ug/L Lab Report Attached? ❑ Yes(1) ❑II No(0) Specific Conductance 000ss µMhos K-Potassium 00937 mg/L VOC 7873 , method# Total Ammonia 0os10 <0.10 mg/L Mg-Magnesium 00927 mg/L , method# (Ammonia Nitrogen.NH,as N.Ammonia Nitrogen,Total) Mn-Manganese 01055 uglL , method# TKN as N 00625 mg/L Ni-Nickel 01067 uglL , method# For Remediation Systems Only(Attach Lab Reports): Influent Total VOCs: mgfL Effluent Total VOCs: mg/L VOC Removal% I certify that,to the best of my knowledge and belief,the information submitted in this report is true,accurate,and complete,and that the laboratory analytical data was produced using approved methods of analysis by a DWR-certified laboratory. I am aware that there are significant penalties for submitting false information,including the possibility of fines and imprisonment for knowing violations. Robert P.Barr/Authorized Agent /J /�[�'� V'ZO , Permittee(or Authorized Agent)Name and Title-Please pent or type Signature of Permittee(or Authori ed Agent) (Date) GW-59 Rev.06-D7-2018 SUBMIT FORM ON YELLOW PAPER ONLY GROUNDWATER QUALITY MONITORING: Mail original DEPARTMENT OF ENVIRONMENTNFORMATIONPROCESSINGU-NITCFwArERRESouRCE5 COMPLIANCE REPORT FORM and 1 copy to: 1017 MAIL SERVICE CENTER,RALEIGH,NC27699.1617 FACILITY INFORMATION Please Print Cleady or Type PERMIT Number: Expiration Date: 4/30/2025 Facility Name: Mountaintop Golf&Lake Club _ Non-Discharge WQ0028693 UIC Permit Name(if different): Mountaintop Community Association Inc NPDES Other Facility Address: P.O.Box 1460 _ TYPE OF PERMITTED OPERATION BEING MONITORED Cashiers NC 28717 County Jackson LI Lagoon ❑ Remediation: Infiltration Gallery ❑■ Spray Field ❑ Remediation: Contact Person: Bob Barr Telephone#: (828)251-1900 ❑ Rotary Distributor ❑ Land Application of Sludge Well Location/Site Name:MW-2 No.of wells to be sampled: 3 ❑ Water Source Heat Pump ❑Other: (from Permit) SAMPLING INFORMATION If WELL WELL ID NUMBER(from Permit): MW-2 Date sample collected: 3/31/2022 FIELD ANALYSES: WAS Well Depth, 42 ft. Well Diameter: 2 in. pH 00400: 6.0 units Temp. Nolo, 13.2 °C DRY at Depth to Water Level 82546:9-57 ft. below measuring point Screened Interval: 42 ft. to 32 ft. Spec. Cond. 00094: 151.7 µMhos time of sampling, Measuring Point is 0 ft. above land surface Relative M.P. Elevation: ft. Odor 00085: None 'check Volume of water pumpedlbailed before sampling: gallons Appearance Clear here: Samples for metals were collected unfiltered: ❑■ YES ❑ NO and field acidified: 0 YES ❑ NO LABORATORY INFORMATION Date sample analyzed:4/12/2022 Laboratory Name: Pace Analytical Certification No. 40 PARAMETERS NOTE:Values should reflect dissolved and colloidal concentrations. COD 00335 mg/L Nitrite(NO2)as N 00615 mg/L Pb-Lead 01051 uglL Conform: MF Fecal 31616 <1 1100mL Nitrate(NO3)as N 00620 1.7 mg/L Zn-Zinc o1092 mg/L Coliform: MF Total 31504 1100mL Phosphorus:Total as P 00665 <0.50 mg/L (Note: Use MPN method for highly turbid samples) Orthophosphate 70507 mg/L Other(Specify Compounds and Concentration Units): Dissolved Solids:Total 70300 111 mg/L Al-Aluminum 01105 mg/L pH (Lab)00403 units Ba-Barium 01007 ugIL TOG 06680 1.0 mg/L Ca-Calcium 00916 mg/L Chloride 00940 2.2 mg/L Cd-Cadmium 01027 ug/L Arsenic o1002 uglL Chromium: Total 01034 ugiL Grease and Oils 00552 mg/L Cu-Copper 01042 mg&L ORGANICS: (by GC, GC/MS, HPLC) Phenol 32730 uglL Fe-Iron 01045 uglL (Specify test and method#.ATTACH LAB REPORT.) Sulfate 00945 mg/L Hg-Mercury 71900 ug/L Lab Report Attached? ❑ Yes(1) ❑■ No(0) Specific Conductance 00085 µMhos K- Potassium 00937 mg/L VOC 7673 , method# Total Ammonia 00610 <0.10 mg/L Mg-Magnesium 00927 mg/L , method# (Ammonia Nitrogen.NH,as N.Ammonia Nitrogen,Total) Mn-Manganese 01055 uglL , method# TKN as N 00625 mg/L Ni-Nickel 01067 ugiL , method# For Remediation Systems Only(Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal% I certify that,to the best of my knowledge and belief,the information submitted in this report is true,accurate.and complete,and that the laboratory analytical data was produced using approved methods of analysis by a DWR-certified laboratory. I am aware that there are significant penalties for submitting false-information,including the possibility of fines and imprisonment for knowing violations.1A-4 G Robert P.Barr/Authorized Agent Y V "' ' Gd 2� Permittee(or Authorized Agent)Name and Title-Please print or type Signature of Permittee(or Authorized Agent) (Date) GW-59 Rev.06-07-2018 SUBMIT FORM ON YELLOW PAPER ONLY GROUNDWATER QUALITY MONITORING: Mail original DEPARTMENTpRIENVIRONMENTAL FORMA NPROSIIQUALITY I OFWATER RESOURCES T COMPLIANCE REPORT FORM and 9 copy to: 1617 MAIL SERVICE CENTER,RALEIGH,NC 27699-1617 FACILITY INFORMATION Please Pnpt C/ear/y or Type PERMIT Number: Expiration Date: 4/30/2025 _ Facility Name: Mountaintop Golf&Lake Club Non-Discharge WQ0028693 UIC Permit Name(if different): Mountaintop Community Association Inc NPDES Other Facility Address: P.O.Box 1460 TYPE OF PERMITTED OPERATION BEING MONITORED Cashiers NC 28717 County Jackson ❑ Lagoon ❑ Remediation: Infiltration Gallery ❑■ Spray Field ❑ Remediation: Contact Person: Bob Barr Telephone#: (828)251-1900 ❑ Rotary Distributor El Land Application of Sludge Well Location/Site Name:MW-3 No.of wells to be sampled: 3 ❑ Water Source Heat Pump ❑ Other: Warn Permit) SAMPLING INFORMATION If WELL WELL ID NUMBER(from Permit): MW-3 Date sample collected: 3131/2022 FIELD ANALYSES: WAS Well Depth: 160 ft. Well Diameter: 4 in. pH 00400: 6.0 units Temp. onto: 12.4 °C DRY at Depth to Water Level 82546:10.81 ft. below measuring point Screened Interval: ft. to ft. Spec. Cond.00094: 72.7 µMhos time of sampling, Measuring Point is 0 ft. above land surface Relative M.P. Elevation: ft. Odor moss None check Volume of water pumped/bailed before sampling: gallons Appearance Clear here: Samples for metals were collected unfiltered: ❑■ YES ❑ NO and field acidified: • YES ❑ NO LABORATORY INFORMATION Date sample analyzed:4/12/2022 Laboratory Name: Pace Analytical Certification No, 40 PARAMETERS NOTE:Values should reflect dissolved and colloidal concentrations. COD 00335 mg!L Nitrite(NO2)as N 00615 mg/L Pb-Lead 0105t ug/L Coliform: MF Fecal 31616 <1 /100mL Nitrate(NO2)as N 00620 0.37 mg/L Zn-Zinc 01092 mg/L Coliform: MF Total 31504 /100mL Phosphorus:Total as P 00665 <0.50 mglL (Note use MPN method Tor highly ream samples) Orthophosphate 70507 mg/L Other(Specify Compounds and Concentration Units): Dissolved Solids:Total 70300 56.0 mg/L Al-Aluminum ettos mg/L pH (Lab)00403 units Ba-Barium 01007 uglL TOC 00680 <1-0 mg/L Ca-Calcium oos16 mg/L Chloride 00940 3.3 mg/L Cd-Cadmium 01027 ug/L _ Arsenic at002 ug/L Chromium:Total 01034 ug/L Grease and Oils 00552 mg/L Cu-Copper 01042 mg/L ORGANICS: (by GC, GC/MS, HPLC) Phenol 32730 ug1L Fe-Iron 01045 ug1L (Specify test and method#.ATTACH LAB REPORT.) Sulfate 00945 mg/L Hg-Mercury 71900 ug/L Lab Report Attached? ❑ Yes(1) ❑■ No(0) Specific Conductance 00095 IiMhns K-Potassium 00937 mg/L VOC 7873 method# Total Ammonia 00610 <0.10 mg/L Mg-Magnesium 00927 mg/L , method# (Ammonia Nitrogen;NH,as N Ammonia Nitrogen,Total) Mn-Manganese 01055 ug/L , method# TKN as N 00625 mg/L Ni-Nickel 01067 ug/L method# For Remediation Systems Only(Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal% I certify that,to the best of my knowledge and belief,the information submitted in this report is true,accurate.and complete,and that the laboratory analytical data was produced using approved methods of analysis by a DWR-certified laboratory. I am aware that there are significant penalties for submitting false information,including the possibility of finesf a�ndimprisonment for knowing violations. 9 Robert P.Barr I Authorized Agent [ " — t— tt-Z�G2_ Permittee(or Authorized Agent)Name and Title-Please print or type Signature of Fermittee(or Authorized Agent) (Date) GW-59 Rev.06-07-2018 Pace Analytical Services,LLC aceAnalytical® Asheville, Riverside 2e 04 Asheville,NC 28804 www.paeelabs.enm (828)254-7176 ANALYTICAL RESULTS Project: Mountain Top MWs Pace Project No.: 92596520 Sample: MW-1B Lab ID: 92596520002 Collected: 03/31/22 10:00 Received: 03/31/22 15:40 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual Monitoring Well Data Analytical Method: Pace Analytical Services-Charlotte Performed by Pace 1 04/08/22 10:39 Collected By S.Warlick 1 04/08/22 10:39 Collected Date 3/31/22 1 04/08/22 10:39 Collected Time 10:00 1 04/08/22 10:39 pH 5.7 Std. Units 1 04/08/22 10:39 Temperature 12.1 deg C 1 04/08/22 10:39 Static Water Level 11.66 feet 1 04/08/22 10:39 Specific Conductance 56.4 umhos/cm 1 04/08/22 10:39 Oxygen, Dissolved 2.2 mg/L 1 04/08/22 10:39 7782-44-7 Total Well Depth 25.37 feet 1 04/08/22 10:39 REDOX 33.2 mV 1 04/08/22 10:39 Turbidity 42.05 NTU 1 04/08/22 10:39 Iron, Ferrous ND mg/L 1 04/08/22 10:39 15438-31-0 Odor ND 1 04/08/22 10:39 Appearance Clear 1 04/08/22 10:39 2540C Total Dissolved Solids Analytical Method: SM 2540C-2015 Pace Analytical Services-Asheville Total Dissolved Solids 46.0 mg/L 25.0 1 04/01/22 15:16 MBIO 9222D Fecal Coliform AVL Analytical Method: SM 9222D-2015 Preparation Method:SM 9222D-2015 Pace Analytical Services-Asheville Fecal Coliforms ND CFU/100 mL 1.0 1 03/31/22 16:50 04/01/22 15:16 350.1 Ammonia Analytical Method: EPA 350.1 Rev 2.0 1993 Pace Analytical Services-Asheville Nitrogen,Ammonia ND mg/L 0.10 1 04/12/22 12:07 7664-41-7 353.2 Nitrogen,NO2/NO3 unpres Analytical Method: EPA 353.2 Rev 2.0 1993 Pace Analytical Services-Asheville Nitrogen, Nitrate 0.13 mg/L 0.040 1 03/31/22 23:35 14797-55-8 Nitrogen, Nitrite ND mg/L 0.040 1 03/31/22 23:35 14797-65-0 365.1 Phosphorus,Total Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation Method: EPA 365.1 Rev 2.0 1993 Pace Analytical Services-Asheville Phosphorus 0.071 mg/L 0.050 1 04/07/22 20:44 04/08/22 09:08 7723-14-0 4500 Chloride Analytical Method: SM 4500-CI-E-2011 Pace Analytical Services-Asheville Chloride 3.7 mg/L 1.0 1 04/04/22 18:36 16887-00-6 5310B TOC Analytical Method: SM 5310B-2014 Pace Analytical Services-Asheville Total Organic Carbon ND mg/L 1.0 1 04/05/22 18:02 7440-44-0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced,except in full, Date: 04/12/2022 03:21 PM without the written consent of Pace Analytical Services,LLC. Page 5 of 21 Pace Analytical Services,LLC aceAnalytical® Asheville, Riverside 2e 04 Asheville,NC 28804 www.paeelabs.enm (828)254-7176 ANALYTICAL RESULTS Project: Mountain Top MWs Pace Project No.: 92596520 Sample: MW-2 Lab ID: 92596520001 Collected: 03/31/22 13:20 Received: 03/31/22 15:40 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual Monitoring Well Data Analytical Method: Pace Analytical Services-Charlotte Performed by Pace 1 04/08/22 10:37 Collected By S.Warlick 1 04/08/22 10:37 Collected Date 3/31/22 1 04/08/22 10:37 Collected Time 13:20 1 04/08/22 10:37 pH 6.0 Std. Units 1 04/08/22 10:37 Temperature 13.2 deg C 1 04/08/22 10:37 Static Water Level 9.57 feet 1 04/08/22 10:37 Specific Conductance 151.7 umhos/cm 1 04/08/22 10:37 Oxygen, Dissolved 6.5 mg/L 1 04/08/22 10:37 7782-44-7 Total Well Depth 34.25 feet 1 04/08/22 10:37 REDOX 62.5 mV 1 04/08/22 10:37 Turbidity 4.9 NTU 1 04/08/22 10:37 Iron, Ferrous ND mg/L 1 04/08/22 10:37 15438-31-0 Odor ND 1 04/08/22 10:37 Appearance Clear 1 04/08/22 10:37 2540C Total Dissolved Solids Analytical Method: SM 2540C-2015 Pace Analytical Services-Asheville Total Dissolved Solids 111 mg/L 25.0 1 04/01/22 15:16 MBIO 9222D Fecal Coliform AVL Analytical Method: SM 9222D-2015 Preparation Method:SM 9222D-2015 Pace Analytical Services-Asheville Fecal Coliforms ND CFU/100 mL 1.0 1 03/31/22 16:50 04/01/22 15:16 350.1 Ammonia Analytical Method: EPA 350.1 Rev 2.0 1993 Pace Analytical Services-Asheville Nitrogen,Ammonia ND mg/L 0.10 1 04/12/22 12:03 7664-41-7 353.2 Nitrogen,NO2/NO3 unpres Analytical Method: EPA 353.2 Rev 2.0 1993 Pace Analytical Services-Asheville Nitrogen, Nitrate 1.7 mg/L 0.040 1 03/31/22 23:45 14797-55-8 Nitrogen, Nitrite ND mg/L 0.040 1 03/31/22 23:45 14797-65-0 365.1 Phosphorus,Total Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation Method: EPA 365.1 Rev 2.0 1993 Pace Analytical Services-Asheville Phosphorus ND mg/L 0.050 1 04/06/22 17:01 04/06/22 21:23 7723-14-0 4500 Chloride Analytical Method: SM 4500-CI-E-2011 Pace Analytical Services-Asheville Chloride 2.2 mg/L 1.0 1 04/04/22 18:35 16887-00-6 5310B TOC Analytical Method: SM 5310B-2014 Pace Analytical Services-Asheville Total Organic Carbon 1.0 mg/L 1.0 1 04/05/22 17:42 7440-44-0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced,except in full, Date: 04/12/2022 03:21 PM without the written consent of Pace Analytical Services,LLC. Page 4 of 21 Pace Analytical Services,LLC aceAnalytical® Asheville, Riverside 2e 04 Asheville,NC 28804 www.paeelabs.enm (828)254-7176 ANALYTICAL RESULTS Project: Mountain Top MWs Pace Project No.: 92596520 Sample: MW-3 Lab ID: 92596520003 Collected: 03/31/22 10:55 Received: 03/31/22 15:40 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual Monitoring Well Data Analytical Method: Pace Analytical Services-Charlotte Performed by Pace 1 04/08/22 10:40 Collected By S.Warlick 1 04/08/22 10:40 Collected Date 3/31/22 1 04/08/22 10:40 Collected Time 10:55 1 04/08/22 10:40 pH 6.0 Std. Units 1 04/08/22 10:40 Temperature 12.4 deg C 1 04/08/22 10:40 Static Water Level 10.81 feet 1 04/08/22 10:40 Specific Conductance 72.7 umhos/cm 1 04/08/22 10:40 Oxygen, Dissolved 5.8 mg/L 1 04/08/22 10:40 7782-44-7 Total Well Depth 160.0 feet 1 04/08/22 10:40 REDOX 60.3 mV 1 04/08/22 10:40 Turbidity 4.7 NTU 1 04/08/22 10:40 Iron, Ferrous ND mg/L 1 04/08/22 10:40 15438-31-0 Odor ND 1 04/08/22 10:40 Appearance Clear 1 04/08/22 10:40 2540C Total Dissolved Solids Analytical Method: SM 2540C-2015 Pace Analytical Services-Asheville Total Dissolved Solids 56.0 mg/L 25.0 1 04/01/22 15:17 MBIO 9222D Fecal Coliform AVL Analytical Method: SM 9222D-2015 Preparation Method:SM 9222D-2015 Pace Analytical Services-Asheville Fecal Coliforms ND CFU/100 mL 1.0 1 03/31/22 16:50 04/01/22 15:16 350.1 Ammonia Analytical Method: EPA 350.1 Rev 2.0 1993 Pace Analytical Services-Asheville Nitrogen,Ammonia ND mg/L 0.10 1 04/12/22 12:14 7664-41-7 353.2 Nitrogen,NO2/NO3 unpres Analytical Method: EPA 353.2 Rev 2.0 1993 Pace Analytical Services-Asheville Nitrogen, Nitrate 0.37 mg/L 0.040 1 03/31/22 23:44 14797-55-8 Nitrogen, Nitrite ND mg/L 0.040 1 03/31/22 23:44 14797-65-0 365.1 Phosphorus,Total Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation Method: EPA 365.1 Rev 2.0 1993 Pace Analytical Services-Asheville Phosphorus ND mg/L 0.050 1 04/07/22 20:44 04/08/22 09:31 7723-14-0 4500 Chloride Analytical Method: SM 4500-CI-E-2011 Pace Analytical Services-Asheville Chloride 3.3 mg/L 1.0 1 04/04/22 18:37 16887-00-6 5310B TOC Analytical Method: SM 5310B-2014 Pace Analytical Services-Asheville Total Organic Carbon ND mg/L 1.0 1 04/05/22 18:50 7440-44-0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced,except in full, Date: 04/12/2022 03:21 PM without the written consent of Pace Analytical Services,LLC. Page 6 of 21 Pace Analytical Services,LLC aceAnalytical® Asheville, Riverside 2e 04 Asheville,NC 28804 www.paeelabs.enm (828)254-7176 QUALIFIERS Project: Mountain Top MWs Pace Project No.: 92596520 DEFINITIONS DF-Dilution Factor, if reported,represents the factor applied to the reported data due to dilution of the sample aliquot. ND-Not Detected at or above adjusted reporting limit. TNTC-Too Numerous To Count J-Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL-Adjusted Method Detection Limit. PQL-Practical Quantitation Limit. RL-Reporting Limit-The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S-Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270.The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate%recovery and RPD values. LCS(D)-Laboratory Control Sample(Duplicate) MS(D)-Matrix Spike(Duplicate) DUP-Sample Duplicate RPD-Relative Percent Difference NC-Not Calculable. SG-Silica Gel-Clean-Up U-Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis ofAcrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Reported results are not rounded until the final step prior to reporting.Therefore,calculated parameters that are typically reported as "Total"may vary slightly from the sum of the reported component parameters. Pace Analytical is TNI accredited.Contact your Pace PM for the current list of accredited analytes. TNI-The NELAC Institute. ANALYTE QUALIFIERS M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample(LCS)recovery. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced,except in full, Date: 04/12/2022 03:21 PM without the written consent of Pace Analytical Services,LLC. Page 17 of 21 - CHAIN-OF-CUSTODY / Analytical Request Document o / .1 The Chain-of-Custody is a LEGAL DOCUMENT.All relevant fields must be completed accurately. N • Submitting a sample via this chain of custody constitutes acknowledgment and acceptance of the Pace Terms and Conditions found at hrips://info.pacelabs.corn/hvbfsipas-standard-terms.pdf. a) Section A Section B Section C r M LL Required Client Information: Required Project Information: Invoice Information: Page: 1 Of 1 Company. RPB Systems Inc. Report To. Robert Barr Attention. Address P O.Box 1325 Copy To Company Name. Asheville.NC 28802 Address Regulatory Agency Email rbarr@rpbsystems.com Purchase Order#: Pace Quote Phone. (828)251-1900 IFax Project Name, Mountain Top MWs Pace Project Manager lorn patton@pacelabs corn. State I Location Requested Due Date: Project#: Pace Profile it MWs Requested Analysis Filtered(YIN) _ .9-7 Z MATRIS CODE o COLLECTED o Preservatives } Dnnkng Water OW U - Wain WT W -p CD Wastewater W = K ¢ Z Product P CD O In O T SAMPLE ID SOJIsoh uE SL -- P ,, L Oil OL START ENO '2m c One Character per box. Wipe wP w D. z_ COI E b v `o {A-Z,0-9 i,-) An AR oO - w 6 N � Re Other CT C] I— H Z -'- T p O U Sample Ids must be unique Tissue Ts x ru "' O y 6N m U— o �' i < f2 E W ¢ i = u a O Tr. so L C vi U n H -, 4 ¢ oto c M IZ U m m m a25QIlF �j rn DATE?? y TIME DATE TIME m ti = x = z z o 2 ¢ CI of /ti l 1 MW-2 W7ti 11�1Tr�71y �T �v 11���.� ` , x x x x x Yc)c1 2 Mw-16 wT— 73�jl( ) V3tr 1 x x x x x 02 �-.. - 3 lds^- yA f�r / 0 ' , ' ? Sa tztt kJ ` ', x x x x x QV 3 4 S - , I 7 t ;f _ — 1 5 6 7 8 9 10 11 12 I ADDITIONAL COMMENTS RELINQUISHED BY r AFFILIATION DATE TIME ACCEPTED BY!AFFILIATION DATE TIME SAMPLE CONDITIONS u;;.c 4t ,.I/07/ /i t:)-_ ' /;i/ : t')Lic; A KRLl(d j,,Ct1/4vL 5-.1/-4 /5 yb 316 7 fll 7 i SAMPLER NAME AND SIGNATURE c C o PRINT Name of SAMPLER: I , c a SIGNATURE of SAMPLER: �� /�.`t / DATE Signed:�y/.) l '�� w u? ci co.T? en"Z Pace Analytical Services,LLC aceAnalytical® Asheville, Riverside 2e 04 Asheville,NC 28804 www.pacelabs.cam (828)254-7176 April 12, 2022 Kimber Reese RPB Systems Inc. P.O. Box 1325 Asheville, NC 28802 RE: Project: Mountain Top MWs Pace Project No.: 92596520 Dear Kimber Reese: Enclosed are the analytical results for sample(s) received by the laboratory on March 31, 2022. The results relate only to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the laboratory's Quality Manual,where applicable, unless otherwise noted in the body of the report. The test results provided in this final report were generated by each of the following laboratories within the Pace Network: • Pace Analytical Services-Asheville • Pace Analytical Services-Charlotte If you have any questions concerning this report, please feel free to contact me. Sincerely, -7 -� Lorri Patton lorri.patton@pacelabs.com 1(828)254-7176 Project Manager Enclosures cc: Mr. Robert Barr, RPB Systems Inc. Ms. Liz Barr, RPB Systems Inc. Cody Pannell, RPB Systems It's, z ,.,-( ri REPORT OF LABORATORY ANALYSIS I \\ Tj This report shall not be reproduced,except in full, j without the written consent of Pace Analytical Services,LLC. Page 1 of 21 �eORAl9-