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HomeMy WebLinkAboutWQ0002857_Monitoring - 03-2022_20220426 4 DWR - NonDischarge Monitoring Report Submittal ti . � F NORTH CAROLINA ErtrYmnmrnlcl Quafily Monitoring Report Submittal ..................................................................................................................................... Permit Number#* WQ0002857 Name of Facility:* Piedmont Custom Meats WWTF Month:* March Year:* 2022 Report Information Type* Upload Document* NDMR, NDAR-1, NDAR-2, NDMLR Piedmont Custom March 2.43MB 2022.pdf PDF Only Please upload one PDF containing all applicable monitoring reports (i.e., NDMR, NDAR-1, NDAR-2, NDMLR,GW-59). Confirmation Email Address:* Jessica.Mize@pacelabs.com Name of Submitter:* Jessica Mize Signature: Date of submittal: 4/26/2022 This will be filled in automatically Initial Review Reviewer: Gerald,Wanda Is the project number correct?* WQ0002857 Is the monitoring report accepted?* Yes No Regional Office* Winston-Salem Accepted Date: 5/10/2022 Page 1 of 3 NON-DISCHARGE WASTE WATER MONITORING REPORT PERMIT NUMBER: W00002857 MONTH: March YEAR: 2022 FACILITY NAME: Piedmont Custom Meats WWTF COUNTY: Caswell Flow Monitoring Point: Effluent: Li Influent: M Parameter Monitoring Point: Effluent: U. Influent: 0 I Surface Water(SW): I ❑ SW Code/Name: Was There Effluent Flow for this Month Generated At This Facility: Yes: U No: o. Operator 50050 00400 50060 00310 00610 00530 31616 70300 00620 00625 00940 00600 00665 D Arrival Daily Rate Fecal A lime Operator ORC (Flow)into Conform T 2400 Time on on Treatment Residual BOD-5 (Geo-metric Total Total L Clock Site Site? System pH Chlorine 20°C NH-3-N T55 Mean') DS NO-3-N TKN Chloride Nitrogen Phosphorus HRS Y.11 GALLONS 12!is me I MG I. MG L MG,L /I0OML MG,L MG/L MG L \u;I, ',It;I. MII I. 1 1,1114 2 Li 14 --3 09311_ 0.25 V 1,014 6.3 <11.0 1 4 1.€114 5 863 6 863 7 863 - 6 0811 0.50 Y 863 6.1 <1).111 9 863 as 863 II 863 12 492 13 492 14 492 IS 1044 11.25 Y 492 6.2 <6.01 16 492 17 492 is - 492 19- 818 20 818 21 818 22 1111 0.25 Y 818 6.4 <11.111 23 818 24 818 25 818 '6. 765 27 765 - 2S 765 29 765 301 0910 0.75 y 765 6.3 <0.01 511.4 111.4 119 24211 419 9-9 25.2 97.3 53.6 1.9 31 765 Average 7711 t <0.01 50.4 10.4 119 2420 419 9.9 25.2 97.3 53.6 1.9 Daily Ma)(intern 1.1114 6.311 <0.01 50.4 10.4 119 2420 419 9.9 25.2 97.3 53.6 1.9 00i13 Minimum 492 6.10 <0.01 511.4 10A 119 2420 419 9.9 25.2 97.3 53.6 1.9 Slon161y Limits 1 Avg) 5000 Composite,I Grab(G) Operator in Responsible Charge(ORC): Glenn Price Grade: Si Phone: 336-996-2841 Check Box if ORC Has Changed: ORC Certification Number: 987931/20771 Certified Laboratories(1): Pace Analytical Services (2): Person(s)Collecting Samples: Glenn Price Mail ORIGINAL and Two COPIES to: ATTN:Non-Discharge Compliance Unit X DENR (SIGNATURE OF OPERATOR 1N RESPONSIBLE CFI Division of Water Quality By this signature,I certify that this report is accurate and 1617 Mail Service Center complete to the best of my knowledge. RALEIGH,NC 27 699-1 6 1 7 DENR Form NDAR-1 (5/2003) NON DISCHARGE WASTEWATER MONITORING REPORT FACILITY STATUS: Please answer the following question: Com liant(Y,N) I. Does all monitoring data and sampling frequencies meet permit requirements? If the facility is non-compliant,please explain in the space below the reason(s)the facility was not in compliance with its permit. Provide in your explanation the date(s)of the non-compliance and describe the corrective action(s)taken. Attach additional sheets if necessary. "I certify,under penalty of law,that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that a qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system,or those persons directly responsible for gathering the information,the information submitted is,to the best of my knowledge and belief true,accurate,and complete. I am aware that there are significant penalties for submitting false information,including the possibility of fines and imprisonment for knowing violations." . , -- /"ng'S-6.}-2— Baron Neal McDuffie (Signature of Permitee)* Date (Name of Signing Official-Please print or type) Baron Neal McDuffie(Authorized Agent) Field Services Director(Pace Analytical Services) (Permittee-Please print or type) (Position or Title) 9683 Kerr's Chapel Road 336-582-8247 03/31/21 Gibsonville,NC (Phone Number) (Permit Exp.Date) (Permittee Address) PARAMETER CODES 01002 Arsenic 31504 Coliform,Total 00600 Nitrogen,Total 00929 Sodium 01022 Boron 00094 Conductivity 00630 NO2 & NO3 00931 SAR 00310 BOD5 01042 Copper 00620 NO3 00745 Sulfide 01027 Cadmium 00300 Dissolved Oxygen 00556 Oil&Grease 00515 TDS 00916 Calcium 31616 Fecal Coliform WQ09 PAN(Plant Available) 00010 Temperature 00940 Chloride 01051 Lead 00400 pH 00625 TKN 50060 Chlorine,Total 00927 Magnesium 32730 Phenols 00680 TOC Residual 71900 Mercury 00665 Phosphorus,Total 00530 TSSiTSR 01034 Chromium 00610 NH3 as N 00937 Potassium 00076 Turbidity 00340 COD 01067 Nickel 00545 Settleable Matter 01092 Zinc Parameter Code assistance may be obtained by calling the Water Quality Compliance/Enforcement Unit at(919)733-5083,extension 529. The monthly average for Fecal Coliform is to be reported as a GEOMETRIC mean. Use only units designated in the reporting facility's permit for reporting data. •If signed by other than the Permittee,delegation of signatory authority must be on file with the state per I5A NCAC 2B.0506(b)(2)(D). Page 2 of 3 NON-DISCHARGE APPLICATION REPORT SPRAY IRRIGATION SITE(S) THERE ARE TWO APPLICATION FIELDS PER PAGE.USE ADDIDTIONAL PAGES AS NEEDED PERMIT NUMBER: W00002857 MONTH: March YEAR: 2022 FACILITY NAME: Piedmont Custom Meats WWTF COUNTY: Caswell Formulas: Daily Loading(inches) =[Volume Applied(gallons)x 0.1336(cubic feet/gallon)x 12(inches/foot)]/[Area Sprayed(acres)x 43,560(square feet/acre)or =[Volume Applied(gallons)/[Area Sprayed(acres)x 27,152(gallons/acre-inch). Maximum Hourly Loading(inches) =Daily Loading(inches)/[Time irrigated(minutes)/60(minuteslhour)[ Monthly Loading(inches) =Sum of Daily Loading(inches) 12 Month Floating Total(inches) =Sum of this month's Monthly Loading(inches)and previous 11 month's Monthly Loadings(inches) Average Weekly Loading(inches) _[Monthly Loading(incheslmonlh[!Number of days in the month(days/month)[x 7(days/week) Did Irrigation Occur At This Facility: Did Irngalic i t'lcetlr Or This Field: Did Irrigation Occur On This Field: Ye x No:El Yes: x No: n Yes: I .,I No:El Field Number: 1 Field NI um er: Area Sprayed(acres): 1 'Area Sprayed(acres): 1 Cover Crop: Fescue Cover Crop: Fescue Permitted Hourly Rate(inches): 0.2 Permitted Hourly ate(inches): 0.2 WEATHER CONDITIONS I Permitted Yearly Rate(inches): 52 Permitted Yearly Rate(inches): 52 D ;t Weather Temperature Storage Mannino] Mammon] Code' at Precipila• Lagoon Voltnnri Tim; Daily hourly Volume Terra Daily Dinoly application lion Frodava ti Appliul lrrignol Lauding Loading hrnliot Irritalerl L+arlie c Lading r`FY inches riot gallons minutes antis rodeo gallons intone PC 40 (I 2.4 PC 50 ll 2.3 11)000 3{lll 11.411 11.118 '1(18110 11111 (1,41) 1).110 9 Ill 11 12 13 11 15 C Sr (I 2.5 16 - 17 18 19 It -- CI 49 l.I 2.3 23 24 25 26 27 28 ul C 54 a 2.1 IIilrw 313 0.44 0.08 11988 333 0.44 f1.i10 pA T,aal Cellars!\Iwthly LmdFva amine/ V.O� O.Q7 t 12\]onlb Floating Total garb./ 3.99 'k Menage tsnkl,Loodiao it brol ighaiW2._..,�_ovio-. ,�,3 ._�,� 0.17 ' .,sue 0.17 .. *Weather Codes:Clear.PC-partly cloudy.CI-cloudy.R-roan.Sn-anow.SI-sleet Spray Irrigation Operator in Responsible Charge(ORC): Glenn Price Phone: 336-996-2841 ORC Certification Number: 987931/20771 Check Box if OR as Changed mail ORIGINAL and Two COPIES to: ATTN:Non-Discharge Compliance Unit `C DENR (SIGNATURE OF OPERATOR IN RESPONSIBLE CHARGE) Division of Water Quality By this signature,I certify that this report is accurate and 1617 Mail Service Center complete to the best of my knowledge. RALEIGH,NC 2 7699-1 6 1 7 DENR Form NDAR-1 (5/2003) FACILITY STATUS: Please indicate(by inserting Y(es)or N(o)in the appropriate box)whether the facility has been compliant with the following permit requirements: (Note: If a requirement does not apply to your facility put(NA)in the compliant box.) Compliant(Y,N) 1. The application rate(s)did not exceed the limit(s)specified in the permit. 2. Adequate measures were taken to prevent wastewater runoff from the site(s). II 3. A suitable vegetative cover was maintained on the site(s)in accordance with the permit. II 4. All buffer zones as specified in the permit were maintained during each application. II 5. The freeboard in the treatment and/or storage lagoon(s)was not less than the I limit(s)specified in the permit. If the facility is non-compliant,please explain in the space below the reason(s)the facility was not in compliance with its permit. Provide in your explanation the date(s)of the non-compliance and describe the corrective action(s)taken. Attach additional sheets if necessary. "I certify,under penalty of law,that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that a qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system,or those persons directly responsible for gathering the information,the information submitted is,to the best of my knowledge and belief true,accurate,and complete. I am aware that there are significant penalties for submitting false information,including the ossibility of fines and imprisonment for knowing violations." Baron Neal McDuffie (signature of Permitee) Date (Name of Signing Official-Please print or type) Baron Neal McDuffie(Authorized Agent) Field Services Director (Pace Analytical Services) (Permittee-Please print or type) (Position or Title) 9683 Kerr's Chapel Road 336-582-8247 03/31/21 Gibsonville.NC (Phone Number) (Permit Exp.Date) (Permittee Address) *If signed by other than the Permittee,delegation of signatory authority must be on file with the state per 15A NCAC 2B.0506(b)(2)(D). DENR Form NDAR-1 (5/2003) Page 3 of 3 NON-DISCHARGE APPLICATION REPORT SPRAY IRRIGATION SITE(S) THERE ARE TWO APPLICATION FIELDS PER PAGE.USE ADDIDTIONAL PAGES AS NEEDED PERMIT NUMBER: W00002857 MONTH: March YEAR: 2022 FACILITY NAME: Piedmont Custom Meats WWTF COUNTY: Caswell Formulas: Daily Loading(inches) _[Volume Applied(gallons)x 0.1336(cubic feet/gallon)x 12(inches/foot)]/[Area Sprayed(acres)x 43.56C(square feet/acre)or =[Volume Applied(gallons)/(Area Sprayed(acres)x 27,152(gallons/acre-inch), Maximum Hourly Loading(inches) =Daily Loading(inches)/[Time irrigated(minutes)!60(minutest hour)) Monthly Loading(inches) =Sum of Daily Loading(inches) 12 Month Floating Total(inches) =Sum of this month's Monthly Loading(inches)and previous 11 month's Monthly Loadings(Inches) Average Weekly Loading{inches) _[Monthly Loading(inches/month)/Number of days in the month(days/month)]x 7(days/week) Did Irrigation Occur At This Facility: Did Irrigation Occur On This Field: Did Irrigationr- Occur On This Field: (� Yes:® No: [] Yes0 No:® Yen No: [X[ Field Number: 3 Field Number: 4 Area Sprayed(acres): 1 Area Sprayed(acres): 1 Cover Crop: Fescue Cover Crop: Fescue Permitted Hour y Rate(inches): 0.2- Permitted Hourly ate(inches): 0.2 WEATHER CONDITIONS Permitted Yearly Rate(inches): 52 Permitted Yearly Rate(inches): 52 D A Weather Temperature Storage Afatimum Maximum '1' DaLi' al Preeipta- Lagoon Volume Time naiiy Hourly V,dwne Tine O.idv Hourly applVaiii.ri Yion PaoMurd Applied Irrigmal hvding L i ing drpiinl Irrigmut Loading ('FY irk fed gallrin nuriuew ineha m;9iti raiLVii mmaru 3 PC 46 0 .e 2.4 - 9 S 6 T r 8 PC sit II 2.3 10 11 - 12 13 15 (' ?.fr I) 2.5 16 17 18 19 20 21 22 CI .11y 1.1 2.3 23 29 15 26 27 '„ 29 311 C 5d IS 2.1 31 Trial Gallovr.']lovnd,I,oliag tivthtsi [I 0.00 12\I lh rki iiea Total(lathe.) 0.00 11 0.00 ,55entr 15'tr�Aly Leading timber.' •"•`-,r 41G1v/+"' S `' 0 00 _ _ 0.00 'Weather Codes:C-clear,PC-panty cloudy,CI-sleuth,R-rain,Se-snow,SI-sler1 Spray Irrigation Operator in Responsible Charge(ORC): Glenn Price Phone: 336-996-2541 ORC Certification Number: 987931/20771 Check Box if ORC Has Changed:❑ Mail ORIGINAL and Two COPIES to: ATTN:Non-Discharge Compliance Unit X DENR (SIGNATURE OF OPERATOR IN RESPONSIBLE CHARGE) Division of Water Quality By this signature,I certify that this report is accurate and 1617 Mail Service Center complete to the hest of my knowledge. RALEIGH,NC 27699-1617 DENR Form NDAR-1 (5/2003) FACILITY STATUS: Please indicate(by inserting Y(es)or N(o)in the appropriate box)whether the facility has been compliant with the following permit requirements: (Note: If a requirement does not apply to your facility put(NA)in the compliant box.) Compliant(Y,N) 1. The application rate(s)did not exceed the limit(s)specified in the permit. 2. Adequate measures were taken to prevent wastewater runoff from the site(s). 3. A suitable vegetative cover was maintained on the site(s)in accordance with the permit. II 4. All buffer zones as specified in the permit were maintained during each application. II 5. The freeboard in the treatment and/or storage lagoon(s)was not less than the II limit(s)specified in the permit. If the facility is non-compliant,please explain in the space below the reason(s)the facility was not in compliance with its permit. Provide in your explanation the date(s)of the non-compliance and describe the corrective action(s)taken. Attach additional sheets if necessary. "I certify,under penalty of law,that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that a qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system,or those persons directly responsible for gathering the information,the information submitted is,to the best of my knowledge and belief true,accurate,and complete. I am aware that there are significant penalties for submitting false information,including gggtthe possibility of fines and imprisonment for knowing violations." �� / ),�' d'�'' Baron Neal McDuffie (Signature of Permitee)* Date (Name of Signing Official-Please print or type) Baron Neal McDuffie(Authorized Agent) Field Services Director(Pace Analytical Services) (Permittee-Please print or type) (Position or Title) 9683 Kerr's Chanel Road 336-582-8247 03/31/21 Gibsonville,NC (Phone Number) (Permit Exp.Date) (Permittee Address) *If signed by other than the Permittee,delegation of signatory authority must be on file with the state per 15A NCAC 2B.0506(b)(2)(D). DENR Form NDAR-1 (5/2003) Pace Analytical Services,LLD aceAnalytical 1377 South Park C284 Kemen;ville,NG 27284 www.pacelabs.com (704)977-0981 April 12, 2022 Larry Moore Piedmont Custom Meats 430 NC Highway 49 South Asheboro, NC 27205 RE: Project: Piedmont Custon Meats-MW/Eff Pace Project.No.: 92596108 Dear Larry Moore: Enclosed are the analytical results for sample(s)received by the laboratory on March 30,2022. The results relate only to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the laboratory's Quality Manual,where applicable, unless otherwise noted in the body of the report. The test results provided in this final report were generated by each of the following laboratories within the Pace Network: •Pace Analytical Services-Asheville • Pace Analytical Services-Eden If you have any questions concerning this report,please feel free to contact me. Sincerely, Stephanie Knott stephanie.knott@pacela bs.corn 704-977-0981 Project Manager Enclosures AlkLtciefor" j0 a M, REPORT OF LABORATORY ANALYSIS r i 3 This report shall not be reproduced,except in full, without the written consent of Pace Analytical Services,LLC. Page 1 of 24 Pace Analytical Services,LLC 6 1377 South Park Drive (1/ aceAnalytical Kernersville,NC 27284 www.pacelabs.cam (704)977-0981 I CERTIFICATIONS Project: Piedmont Custon Meats-MW/Eff Pace Project No.: 92596108 Pace Analytical Services Asheville 2225 Riverside Drive,Asheville,NC 28804 South Carolina Laboratory ID:99030 Florida/NELAP Certification#:E87648 South Carolina Certification#:99030001 North Carolina Drinking Water Certification#:37712 VirginiaNELAP Certification#:460222 North Carolina Wastewater Certification#:40 Pace Analytical Services Eden 205 East Meadow Road Suite A,Eden,NC 27288 North Carolina Wastewater Certification#:633 North Carolina Drinking Water Certification#:37738 VirginiaNELAP Certification#:460025 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced,except in full, without the written consent of Pace Analytical Services,LLC. Page 2 of 24 Pace Analytical Services,LLC ® aceAnalytical 1377 South Park Drive Kemersville,NC 27284 www.paalabs.com (704)977-0981 SAMPLE ANALYTE COUNT Project: Piedmont Custon Meats-MW/Eff Pace Project No.: 92596108 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92596108001 MW-1 SM 2540C-2015 AED 1 PASI-E EPA 350.1 Rev 2.01993 AMI 1 PASI-E EPA 353.2 Rev 2.0 1993 AMI 1 PASI-E SM 9222D-2015 AED 1 PASI-E EPA 120.1-1982 SMS 1 PASI-A EPA 300.0 Rev 2.1 1993 CDC 2 PASI-A SM 5310B-2014 MJP 1 PASI-A 92596108002 MW-4 SM 2540C-2015 AED 1 PASI-E EPA 350.1 Rev 2.0 1993 AMI 1 PASI-E EPA 353.2 Rev 2.0 1993 AMI 1 PASI-E SM 9222D-2015 AED 1 PASI-E EPA 120.1-1982 SMS 1 PASI-A EPA 300.0 Rev 2.1 1993 CDC 2 PASI-A SM 5310B-2014 MJP 1 PASI-A 92596108003 MW-5 SM 2540C-2015 AED 1 PASI-E EPA 350.1 Rev 2.0 1993 AMI 1 PASI-E EPA 353.2 Rev 2.0 1993 AMI 1 PASI-E SM 9222D-2015 AED 1 PASI-E EPA 120.1-1982 SMS 1 PASI-A EPA 300.0 Rev 2.1 1993 CDC 2 PASI-A SM 5310B-2014 MJP 1 PASI-A 92596108004 Effluent SM 2540C-2015 AED 1 PASI-E SM 2540D-2015 AED 1 PASI-E EPA 350.1 Rev 2.01993 AMI 1 PASI-E EPA 353.2 Rev 2.0 1993 AMI 2 PASI-E SM 5210B-2016 SRS 1 PASI-E Colilert-18 • LRB 1 PASI-E TKN+NO3+NO2 Calculation MAB2 1 PASI-A EPA 300.0 Rev 2.1 1993 CDC 1 PASI-A EPA 351.2 Rev 2.0 1993 MFO 1 PASI-A EPA 365.1 Rev 2.0 1993 SMT 1 PASI-A PASI-A=Pace Analytical Services-Asheville PASI-E=Pace Analytical Services-Eden , REPORT OF LABORATORY ANALYSIS This report shall not be reproduced,except in full, without the written consent of Pace Analytical Services,LLC. Page 3 of 24 Pace Analytical Services,LLC aceAnalytical 1377 South Paris D284 Kemersvifle,NC 27284 www.pacelabs.com (704)977-0981 ANALYTICAL RESULTS Project: Piedmont Custon Meats-MW/Eff Pace Project No.: 92596108 Sample: MW-1 Lab ID: 92596108001 Collected: 03/30/22 09:49 Received: 03/30/22 11:25 Matrix:Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 2540C Total Dissolved Solids Analytical Method:SM 2540C-2015 Pace Analytical Services-Eden Total Dissolved Solids 323 mg/L 25.0 1 04/01/22 13:20 350.1 Ammonia EDN Analytical Method:EPA 350.1 Rev 2.0 1993 Pace Analytical Services-Eden Nitrogen,Ammonia ND mg/L 0.10 1 03/31/22 11:32 7664-41-7 353.2 N021NO3 unpres EDN Analytical Method:EPA 353.2 Rev 2.0 1993 Pace Analytical Services-Eden Nitrogen,Nitrate 21.1 mg/L 0.20 5 03/30/22 16:14 14797-55-8 MBIO 9222D Fecal Coliform EDN Analytical Method:SM 9222D-2015 Preparation Method:SM 9222D-2015 Pace Analytical Services-Eden Fecal Colilorms ND CFU/100 mL 1.0 1 03/30/22 15:52 03/31/22 14:48 120.1 Specific Conductance Analytical Method:EPA 120.1-1982 Pace Analytical Services-Asheville Specific Conductance 504 umhos/cm 10.0 1 04/04/22 16:27 300.0 IC Anions 28 Days Analytical Method:EPA 300.0 Rev 2.1 1993 Pace Analytical Services-Asheville Chloride 46.7 mg/L 1.0 1 04/01/22 14:49 16887-00-6 Sulfate 3.8 mg/L 1.0 1 04/01/22 14:49 14808-79-8 5310E TOC Analytical Method:SM 5310E-2014 Pace Analytical Services-Asheville Total Organic Carton ND mg/L 1.0 1 04/05/22 10:23 7440-44-0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced,except in full, Date:04/12/2022 10:46 AM without the written consent of Pace Analytical Services,LLC. Page 4 of 24 Pace Analytical Services,LLC aceAnalytical® 1377 South Park Drive Kemersville,NC 27284 www.paceiaba.ecrs (704)977.0981 f ANALYTICAL RESULTS Project: Piedmont Custon Meats-MW/Eff Pace Project No.: 92596108 Sample: MW-4 Lab ID: 92596108002 Collected: 03/30/22 09:10 Received: 03/30/22 11:25 Matrix:Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Dual 2540C Total Dissolved Solids Analytical Method:SM 2540C-2015 Pace Analytical Services-Eden Total Dissolved Solids 584 mg/L 50.0 1 04/01/22 13:21 350.1 Ammonia EDN Analytical Method:EPA 350.1 Rev 2.0 1993 Pace Analytical Services-Eden Nitrogen,Ammonia ND mg/L 0.10 1 03/31/22 11:33 7664-41-7 353.2 NO2/NO3 unpres EDN Analytical Method:EPA 353.2 Rev 2.0 1993 Pace Analytical Services-Eden Nitrogen,Nitrate 1.6 mg/L 0.040 1 03/30/22 15:59 14797-55-8 MBIO 9222D Fecal Coliform EDN Analytical Method:SM 9222D-2015 Preparation Method:SM 92220-2015 Pace Analytical Services-Eden Fecal Coliforms ND CFU/100 mL 1.0 1 03/30/22 15:52 03/31/22 14:48 120.1 Specific Conductance Analytical Method:EPA 120.1-1982 Pace Analytical Services-Asheville Specific Conductance 1140 umhos/cm 10.0 1 04/04/22 16:32 300.0 IC Anions 28 Days Analytical Method:EPA 300.0 Rev 2.1 1993 Pace Analytical Services-Asheville Chloride 246 mg/L 5.0 5 04/01/22 16:37 16887-00-6 Sulfate 5.5 mg/L 1.0 1 04/01/22 15:04 14808-79-8 5310B TOC Analytical Method:SM 5310B-2014 Pace Analytical Services-Asheville Total Organic Carbon ND mg/L 1.0 1 04/05/22 17:04 7440-44-0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced,except In full, Date:04/12/2022 10:46 AM without.the written consent of Pace Analytical Services,LLC. Page 5 of 24 Pace Analytical Services,LLC aceAnalytical 0 1377 South Park Drive Kemersville,NC 27284 www.paalobs.com (704)977-0981 I ANALYTICAL RESULTS Project: Piedmont Custon Meats-MW/Eff Pace Project No.: 92596108 Sample: MW-5 Lab ID: 92596108003 Collected: 03/30/22 09:33 Received: 03/30/22 11:25 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 2540C Total Dissolved Solids Analytical Method:SM 2540C-2015 Pace Analytical Services-Eden Total Dissolved Solids 209 mg/L 25.0 1 04/01/22 13:21 350.1 Ammonia EDN Analytical Method:EPA 350.1 Rev 2.0 1993 Pace Analytical Services-Eden Nitrogen,Ammonia ND mg/L 0.10 1 03/31/22 11:35 7664-41-7 353.2 NO21NO3 unpres EDN Analytical Method:EPA 353.2 Rev 2.0 1993 Pace Analytical Services-Eden Nitrogen,Nitrate 0.25 mg/L 0.040 1 03/30/22 16:00 14797-55-8 MBIO 9222D Fecal Coliform EDN Analytical Method:SM 9222D-2015 Preparation Method:SM 9222D-2015 Pace Analytical Services-Eden Fecal Coliforms ND CFU/100 mL 1.0 1 03/30/22 15:52 03/31/22 14:48 120.1 Specific Conductance Analytical Method:EPA 120.1-1982 Pace Analytical Services-Asheville Specific Conductance 394 umhos/cm 10.0 1 04/04/22 16:34 300.0 IC Anions 28 Days Analytical Method:EPA 300.0 Rev 2,1 1993 Pace Analytical Services-Asheville Chloride 82.8 mg/L 1.0 1 04/01/22 15:20 16887-00-6 Sulfate ND mg/L 1.0 1 04/01/22 15:20 14808-79-8 5310E TOC Analytical Method:SM 5310B-2014 Pace Analytical Services-Asheville Total Organic Carbon ND mg/L 1.0 1 04/05/22 17:23 7440-44-0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced,except in full, Date:04/12/2022 10:46 AM without the written consent of Pace Analytical Services,LLC. Page 6 of 24 Pace Analytical Services,LLC aceAnalytical m 1377 South Park Drive Kemersville,NC 27284 www.pacalabs.can (704)977-0981 ANALYTICAL RESULTS Project: Piedmont Custon Meats-MW/Eff Pace Project No.: 92596108 Sample: Effluent Lab ID: 92596108004 Collected: 03/30/22 08:48 Received: 03/30/22 11:25 Matrix:Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 2540C Total Dissolved Solids Analytical Method:SM 2540C-2015 Pace Analytical Services-Eden Total Dissolved Solids 419 mg/L 27.0 1 04/01/22 13:21 2540D Total Suspended Solids Analytical Method:SM 2540D-2015 Pace Analytical Services-Eden Total Suspended Solids 119 mg/L 35.7 1 04/01/22 09:19 350.1 Ammonia EDN Analytical Method:EPA 350.1 Rev 2.0 1993 Pace Analytical Services-Eden Nitrogen,Ammonia 10.4 mg/L 0.20 2 03/31/22 11:57 7664-41-7 353.2 NO2/NO3 unpres EDN Analytical Method:EPA 353.2 Rev 2.0 1993 Pace Analytical Services-Eden Nitrogen,Nitrate 9.9 mg/L 0,80 20 03/30/22 16:19 14797-55-8 Nitrogen,NO2 plus NO3 28.4 mg/L 0.80 20 03/30/22 16:19 5210B BOD,5 day EDN Analytical Method:SM 5210B-2016 Preparation Method:SM 5210B-2016 Pace Analytical Services-Eden BOD,5 day 50.4 mg/L 2.0 1 03/31/22 11:27 04/05/22 08:56 Colilert-18 Fecal Coliform EDN Analytical Method:Colilert-18 Preparation Method:Colilert-18 Pace Analytical Services-Eden Fecal Coliforms 2420 MPN/100mL 1.0 1 03/30/22 15:52 03/31/22 10:47 El Total Nitrogen Calculation Analytical Method:TKN+NO3+NO2 Calculation Pace Analytical Services-Asheville Total Nitrogen 53.6 mg/L 0.040 1 04/12/22 10:40 300.0 IC Anions 28 Days Analytical Method:EPA 300.0 Rev 2.1 1993 Pace Analytical Services-Asheville Chloride 97.3 mg/L 4.0 4 04/01/22 16:52 16887-00-6 M1 351.2 Total Kjeldahl Nitrogen Analytical Method:EPA 351.2 Rev 2.0 1993 Preparation Method:EPA 351.2 Rev 2.0 1993 Pace Analytical Services-Asheville Nitrogen,Kjeldahl,Total 25.2 mg/L 2.5 5 04/08/22 02:37 04/09/22 09:12 7727-37-9 365.1 Phosphorus,Total Analytical Method:EPA 365.1 Rev 2.0 1993 Preparation Method:EPA 365.1 Rev 2.0 1993 Pace Analytical Services-Asheville Phosphorus 1.9 mg/L 0,050 1 04/06/22 17:01 04/06/22 21:10 7723-14-0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced,except in full, Date:04/12/2022 10:46 AM without the written consent of Pace Analytical Services,LLC. Page 7 of 24 Pace Analytical Services,LLC aceAnalytical m 1 South Park 84 Kemersvitle,NC 27284 wtrw.paetlabs.cam (704)977-0981 QUALITY CONTROL DATA Project: Piedmont Custon Meats-MW/Eff Pace Project No.: 92596108 QC Batch: 688902 Analysis Method: SM 2540C-2015 QC Batch Method: SM 2540C-2015 Analysis Description: 2540C Total Dissolved Solids Laboratory: Pace Analytical Services-Eden Associated Lab Samples: 92596108001,92596108002,92596108003,92596108004 METHOD BLANK: 3600036 Matrix: Water Associated Lab Samples: 92596108001,92596108002,92596108003,92596108004 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Total Dissolved Solids mg/L ND 25,0 04/01/22 13:20 LABORATORY CONTROL SAMPLE: 3600037 Spike LCS LCS %Rec Parameter Units Conc. Result %Rec Limits Qualifiers Total Dissolved Solids mg/L 250 254 102 90-110 SAMPLE DUPLICATE: 3600038 92596108001 Dup Parameter Units Result Result RPD Qualifiers Total Dissolved Solids mg/L 323 333 3 Results presented on this page are In the units indicated by the"Units"column except where an alternate unit Is presented to the light of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced,except in full, Date:04/12/2022 10:46 AM without the written consent of Pace Analytical Services,LLC. Page 8 of 24 Pace Analytical Services,LLC ® 1377 South Park 84 aceAnalytical Kemersville,NC 27284 inw.paeelabs.com (704)977-0981 f QUALITY CONTROL DATA Project: Piedmont Custon Meats-MW/Eff Pace Project No.: 92596108 QC Batch: 688783 Analysis Method: SM 2540D-2015 QC Batch Method: SM 2540D-2015 Analysis Description: 2540D Total Suspended Solids Laboratory: Pace Analytical Services-Eden Associated Lab Samples: 92596108004 METHOD BLANK: 3599517 Matrix: Water Associated Lab Samples: 92596108004 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Total Suspended Solids mg/L ND 2.5 04/01/22 09:15 LABORATORY CONTROL SAMPLE: 3599518 Spike LCS LCS %Rec Parameter Units Conc. Result %Rec Limits Qualifiers Total Suspended Solids mg/L 250 248 99 90-110 SAMPLE DUPLICATE: 3599601 92596182001 Dup Parameter Units Result Result RPD Qualifiers Total Suspended Solids mg/L 35.4 37.4 5 SAMPLE DUPLICATE: 3599602 92596189001 Dup Parameter Units Result Result RPD Qualifiers Total Suspended Solids mg/L 322 271 17 Results presented on this page are In the units Indicated by the"Unite"column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced,except in full, Date:04/12/2022 10:46 AM without the written consent of Pace Analytical Services,LLC. Page 9 of 24 Pace Analytical Services,LLC aceAnalytical a 1377 South Park Drive Kemersville,NC 27284 wtw.pacelabs.com (704)977-0981 QUALITY CONTROL DATA Project Piedmont Custon Meats-MW/Eff Pace Project No.: 92596108 QC Batch: 688525 Analysis Method: EPA 350.1 Rev 2.0 1993 QC Batch Method: EPA 350.1 Rev 2.0 1993 Analysis Description: 350.1 Ammonia,EDN Laboratory: Pace Analytical Services-Eden Associated Lab Samples: 92596108001,92596108002,92596108003,92596108004 METHOD BLANK: 3598173 Matrix: Water Associated Lab Samples: 92596108001,92596108002,92596108003,92596108004 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Nitrogen,Ammonia mg/L ND 0.10 03/31/22 11:16 LABORATORY CONTROL SAMPLE: 3598174 Spike LCS LCS %Rec Parameter Units Conc. Result %Rec Limits Qualifiers Nitrogen,Ammonia mg/L 5 5.0 100 90-110 MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 3598175 3598176 MS MSD 92596243001 Spike Spike MS MSD MS MSD %Rec Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual Nitrogen,Ammonia mg/L 0.10 5 5 5.1 5.1 100 100 90-110 0 MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 3598177 3598178 MS MSD 92596248001 Spike Spike MS MSD MS MSD %Rec Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual Nitrogen,Ammonia mg/L ND 5 5 5.0 5.0 101 101 90-110 0 Results presented on this page are In the units Indicated by the"Units"column except where an alternate unit is presented to the right of the result REPORT OF LABORATORY ANALYSIS This report shall not be reproduced,except in full. Date:04/12/2022 10:46 AM without the written consent of Pace Analytical Services,LLC. Page 10 of 24 Pace Analytical Services,LLC _ aceAnalytical a 1377 South Park Drive Kemersville,NC 27284 www.pacelabs.com (704)877-0981 QUALITY CONTROL DATA Project: Piedmont Custon Meats-MW/Eff Pace Project No.: 92596108 QC Batch: 688277 Analysis Method: EPA 353.2 Rev 2.0 1993 QC Batch Method: EPA 353.2 Rev 2.01993 Analysis Description: 353.2 Nitrate+Nitrite,Unpres.EDN Laboratory: Pace Analytical Services-Eden Associated Lab Samples: 92596108001,92596108002,92596108003,92596108004 METHOD BLANK: 3597002 Matrix: Water Associated Lab Samples: 92596108001,92596108002,92596108003,92596108004 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Nitrogen,Nitrate mg/L ND 0.040 03/30/22 14:07 Nitrogen,NO2 plus NO3 mg/L ND 0.040 03/30/22 14:07 LABORATORY CONTROL SAMPLE: 3597003 Spike LCS LCS %Rec Parameter Units Conc. Result %Rec Limits Qualifiers Nitrogen,Nitrate mg/L 1.5 1.5 103 90-110 Nitrogen,NO2 plus NO3 mg/L 2.5 2.5 101 90-110 MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 3597004 3597005 MS MSD 92596013001 Spike Spike MS MSD MS MSD %Rec Parameter Units Result Conc. Conc. Result Result °Ao Rec %Rec Limits RPD Qual Nitrogen,Nitrate mg/L ND 1.5 1.5 1.5 1.5 102 102 90-110 0 Nitrogen,NO2 plus NO3 mg/L 0.058 2.5 2.5 2.5 2.6 99 100 90-110 1 Results presented on this page are In the units Indicated by the"Units'column except where an alternate unit Is presented to the right of the result REPORT OF LABORATORY ANALYSIS This report shall not be reproduced,except in full, Date:04/12/2022 10:46 AM without the written consent of Pace Analytical Services,LLC. Page 11 of 24 Pace Analytical Services,LLC aceAnalytical® 1377 South Park Drive Kemersville,NC 27284 www.paeNabs.eom (704)977-0981 r 1 QUALITY CONTROL DATA Project: Piedmont Custon Meats-MW/Eff Pace Project No.: 92596108 QC Batch: 688543 Analysis Method: SM 5210B-2016 QC Batch Method: SM 5210B-2016 Analysis Description: 5210B BOD,5 day Final EDN Laboratory: Pace Analytical Services-Eden Associated Lab Samples: 92596108004 METHOD BLANK: 3598240 Matrix: Water Associated Lab Samples: 92596108004 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers BOO,5 day mg/L ND 2.0 04/05/22 08:37 LABORATORY CONTROL SAMPLE: 3598241 Spike LCS LCS %Rec Parameter Units Conc. Result °Ao Rec Limits Qualifiers BOO,5 day mg/L 198 200 101 84.6-115 SAMPLE DUPLICATE: 3598243 92596182001 Dup Parameter Units Result Result RPD Qualifiers BOD,5 day mg/L 94.4 90.4 4 Results presented on this page are In the units Indicated by the"Untie"column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced,except in full, Date:04/12/2022 10:46 AM without the written consent of Pace Analytical Services,LLC. Page 12 of 24 Pace Analytical Services,LLC ® 1377 South Park Drive aceAnalytical Kemersville.NC 27284 www.pacelab!.can (704)977-0981 1 QUALITY CONTROL DATA Project: Piedmont Custon Meats-MW/Eff Pace Project No.: 92596108 QC Batch: 688338 Analysis Method: SM 9222D-2015 QC Batch Method: SM 9222D-2015 Analysis Description: 9222D Fecal Coliform(MF)-EDN Laboratory: Pace Analytical Services-Eden Associated Lab Samples: 92596108001,92596108002,92596108003 METHOD BLANK: 3597401 Matrix: Water Associated Lab Samples: 92596108001,92596108002,92596108003 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Fecal Coliforms CFU/100 mL ND 1.0 03/31/22 14:48 METHOD BLANK: 3597403 Matrix: Water Associated Lab Samples: 92596108001,92596108002,92596108003 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Fecal Coliforms CFU/100 mL ND 1.0 03/31/22 14:48 SAMPLE DUPLICATE: 3597402 92596108002 Dup Parameter Units Result Result RPD Qualifiers Fecal Coliforrns CFU/100 mL ND ND Results presented on this page aro In tho units Indicated by the"Units"column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced,except in full, Date:04/12/2022 10:46 AM without the written consent of Pace Analytical Services.LLC. Page 13 of 24 Pace Analytical Services,LLC aceAnalytical® 1377 South Park Drive Kemersvipe,NC 27284 www paalabs.ccm (704)977-0981 QUALITY CONTROL DATA Project: Piedmont Custon Meats-MW/Eff Pace Project No.: 92596108 QC Batch: 688335 Analysis Method: Colilert-18 QC Batch Method: Colilert-18 Analysis Description: Colilert-18 Fecal Coliforrn EDN Laboratory: Pace Analytical Services-Eden Associated Lab Samples: 92596108004 SAMPLE DUPLICATE: 3597395 92596058001 Dup Parameter Units Result Result RPD Qualifiers Fecal Colifomis MPN/100mL 1.0 ND Results presented on this page are In the units Indicated by the'Units"column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced,except in full, Date:04/12/2022 10:46 AM without the written consent of Pace Analytical Services,LLC. Page 14 of 24 Pace Analytical Services,LLC aceAnalytical® 1377 South Park Drive Kemersville,NC 27284 www.paceIabs.eam (704)977-0981 I i QUALITY CONTROL DATA Project: Piedmont Custon Meats-MW/Eff Pace Project No.: 92596108 QC Batch: 689206 Analysis Method: EPA 120.1-1982 QC Batch Method: EPA 120.1-1982 Analysis Description: 120.1 Specific Conductance Laboratory: Pace Analytical Services-Asheville Associated Lab Samples: 92596108001,92596108002,92596108003 METHOD BLANK: 3601371 Matrix: Water Associated Lab Samples: 92596108001,92596108002,92596108003 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Specific Conductance umhos/cm ND 10.0 04/04/22 16:08 LABORATORY CONTROL SAMPLE: 3601372 Spike LCS LCS %Rec Parameter Units Conc. Result %Rec Limits Qualifiers Specific Conductance umhos/cm 1410 1410 100 90-110 SAMPLE DUPLICATE: 3601373 92595633001 Dup Parameter Units Result Result RPD Qualifiers Specific Conductance umhos/cm 174 175 1 SAMPLE DUPLICATE: 3601374 92596445003 Dup Parameter Units Result Result RPD Qualifiers Specific Conductance umhos/cm 61.1 61.4 0 Results presented on this page are In the units Indicated by the"Units"column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced,except in full, Date:04/12/2022 10:46 AM without the written consent of Pace Analytical Services,LLC. Page 15 of 24 Pace Analytical Services,LLC aceAnalytical® 1377 South Park Drive Kemersville,NC 27284 www.pacelabs.com (704)977-0981 i QUALITY CONTROL DATA Project: Piedmont Custon Meats-MW/Eff Pace Project No.: 92596108 QC Batch: 688805 Analysis Method: EPA 300.0 Rev 2.1 1993 QC Batch Method: EPA 300.0 Rev 2.1 1993 Analysis Description: 300.0 IC Anions Laboratory: Pace Analytical Services-Asheville Associated Lab Samples: 92596108001,92596108002,92596108003,92596108004 METHOD BLANK: 3599579 Matrix: Water Associated Lab Samples: 92596108001,92596108002,92596108003,92596108004 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Chloride mg/L ND 1.0 04/01/22 11:43 Sulfate mg/L ND 1.0 04/01/22 11:43 LABORATORY CONTROL SAMPLE: 3599580 Spike LCS LCS %Rec Parameter Units Conc. Result %Rec Limits Qualifiers Chloride mg/L 50 47.9 96 90-110 Sulfate mg/L 50 47.9 96 90-110 MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 3599581 3599582 MS MSD 92596075001 Spike Spike MS MSD MS MSD %Rec Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual Chloride mg/L 4.5 50 50 40.1 40.2 71 72 90-110 0 M1 Sulfate mg/L 6.1 50 50 40.7 42.3 69 72 90-110 4 M1 MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 3599583 3599584 MS MSD 92596108004 Spike Spike MS MSD MS MSD %Rec Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual Chloride mg/L 97.3 50 50 128 128 61 62 90-110 1 M1 Sulfate mg/L 31.6 50 50 66.2 67.1 69 71 90-110 1 M1 Results presented on this page are In the units Indicated by the"Units"column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced,except in full, Date:04/12/2022 10:46 AM without the written consent of Pace Analytical Services,LLC. Page 16 of 24 Pace Analytical Services,LLC aceAnalytical® 1377 South Park Drive Kemersville,NC 27284 www.paeelabs.cem (704)977-0981 r I QUALITY CONTROL DATA Project: Piedmont Custon Meats-MW/Eff Pace Project No.: 92596108 QC Batch: 689956 Analysis Method: EPA 351.2 Rev 2.0 1993 QC Batch Method: EPA 351.2 Rev 2.0 1993 Analysis Description: 351.2 TKN Laboratory: Pace Analytical Services-Asheville Assodated Lab Samples: 92596108004 METHOD BLANK: 3605319 Matrix: Water Associated Lab Samples: 92596108004 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Nitrogen,Kjeldahl,Total mg/L ND 0.50 04/09/22 08:15 LABORATORY CONTROL SAMPLE: 3605320 Spike LCS LCS %Rec Parameter Units Conc. Result %Rec Limits Qualifiers Nitrogen,Kjeldahl,Total mg/L 10 9.1 91 90-110 MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 3605321 3605322 MS MSD 92596069001 Spike Spike MS MSD MS MSD %Rec Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual Nitrogen,Kjeldahl,Total mg/L 40.2 10 10 51.0 50.7 108 105 90-110 1 MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 3605323 3605324 MS MSD 92596653001 Spike Spike MS MSD MS MSD %Rec Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual Nitrogen,Kjeldahl,Total mg/L 10 10 10 19.4 19.9 94 99 90-110 3 Results presented on this page are to the units indicated by the"Units"column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced,except in full, Date:04/12/2022 10:46 AM without the written consent of Pace Analytical Services,LLC. Page 17 of 24 Pace Analytical Services,LLC aceAnalytical m 1377 South Park Drive Kemersville,NC 27284 www.pseslabt.com (704)977-0981 QUALITY CONTROL DATA Project: Piedmont Custon Meats-MW/Eff Pace Project No.: 92596108 QC Batch: 689813 Analysis Method: EPA 365.1 Rev 2.0 1993 QC Batch Method: EPA 365.1 Rev 2.0 1993 Analysis Description: 365.1 Phosphorus,Total Laboratory: Pace Analytical Services-Asheville Associated Lab Samples: 92596108004 METHOD BLANK: 3604573 Matrix: Water Associated Lab Samples: 92596108004 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Phosphorus mglL ND 0.050 04/06/22 21:05 LABORATORY CONTROL SAMPLE: 3604574 Spike LCS LCS %Rec Parameter Units Conc. Result %Rec Limits Qualifiers Phosphorus mg/L 2.5 2.5 102 90-110 MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 3604575 3604576 MS MSD 92596080001 Spike Spike MS MSD MS MSD %Rec Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual Phosphorus mg/L 15.1 2.5 2.5 17.8 17.5 107 97 90-110 1 MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 3604577 3604578 MS MSD 92596108004 Spike Spike MS MSD MS MSD %Rec Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual Phosphorus mg/L 1.9 2.5 2.5 4.6 4.6 107 108 90-110 1 Results presented on this page are In the units Indicated by the"Units"column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced,except in full, Date:04/12/2022 10:46 AM without the written consent of Pace Analytical Services,LLC. Page 18 of 24 Pace Analytical Services,LLC ® 1377 South Park Drive aceAnalytical Kemersvllle,NC 27284 www.paceleba.com (704)977-0981 QUALITY CONTROL DATA Project: Piedmont Custon Meats-MW/Eff Pace Project No.: 92596108 QC Batch: 689204 Analysis Method: SM 5310B-2014 QC Batch Method: SM 5310B-2014 Analysis Description: 5310B TOC Laboratory: Pace Analytical Services-Asheville Associated Lab Samples: 92596108001 METHOD BLANK: 3601358 Matrix: Water Associated Lab Samples: 92596108001 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Total Organic Carbon mg/L ND 1.0 04/05/22 01:46 LABORATORY CONTROL SAMPLE: 3601359 Spike LCS LCS %Rec Parameter Units Conc. Result %Rec Limits Qualifiers Total Organic Carbon mg/L 25 24.7 99 90-110 MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 3601360 3601361 MS MSD 92596527021 Spike Spike MS MSD MS MSD %Rec Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual Total Organic Carbon mg/L ND 25 25 23.9 23.8 94 94 90-110 0 MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 3601362 3601363 MS MSD 92596527022 Spike Spike MS MSD MS MSD %Rec Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual Total Organic Carbon mg/L ND 25 25 24.5 24.8 96 97 90-110 1 Results presented on this page are in the units indicated by the'Units"column except where an alternate unit Is presented to the right of the result REPORT OF LABORATORY ANALYSIS This report shall not be reproduced,except in full, Date:04/12/2022 10:46 AM without the written consent of Pace Analytical Services,LLC. Page 19 of 24 Pace Analytical Services,LLC aceAnalytical® 1377 South Park Drive Kemersville,NC 27284 www.pacelabs.ccm (704)977-0981 ii QUALITY CONTROL DATA Project: Piedmont Custon Meats-MW/Eff Pace Project No.: 92596108 QC Batch: 689485 Analysis Method: SM 5310B-2014 QC Batch Method: SM 5310B-2014 Analysis Description: 5310E TOC Laboratory: Pace Analytical Services-Asheville Associated Lab Samples: 92596108002,92596108003 METHOD BLANK: 3602876 Matrix: Water Associated Lab Samples: 92596108002,92596108003 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Total Organic Carbon mg/L ND 1.0 04/05/22 15:16 LABORATORY CONTROL SAMPLE: 3602877 Spike LCS LCS %Rec Parameter Units Conc. Result %Rec Limits Qualifiers Total Organic Carbon mg/L 25 23.7 95 90-110 MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 3602878 3602879 MS MSD 92596958001 Spike Spike MS MSD MS MSD %Rec Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual Total Organic Carbon mg/L ND 25 25 24.1 24.3 95 96 90-110 1 Results presented on this page are in the units Indicated by the"Units"column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced,except in full, Date:04/12/2022 10:46 AM without the written consent of Pace Analytical Services,LLC. Page 20 of 24 Pace Analytical Services,LLC i m 1377 South Parts 4 aceAnalytcal Kemersville,NC 27284 www.paeelabs.ecrn (704)977-0981 QUALIFIERS Project Piedmont Custon Meats-MW/Eff Pace Project No.: 92596108 DEFINITIONS DF-Dilution Factor,if reported,represents the factor applied to the reported data due to dilution of the sample aliquot. ND-Not Detected at or above adjusted reporting limit. TNTC-Too Numerous To Count J-Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL-Adjusted Method Detection Limit. PQL-Practical Quantitation Limit. RL-Reporting Limit-The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S-Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270.The result for each analyte is a combined concentration. Consistent with EPA guidelines,unrounded data are displayed and have been used to calculate%recovery and RPD values. LCS(D)-Laboratory Control Sample(Duplicate) MS(D)-Matrix Spike(Duplicate) DUP-Sample Duplicate RPD-Relative Percent Difference NC-Not Calculable. SG-Silica Gel-Clean-Up U-Indicates the compound was analyzed for,but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Reported results are not rounded until the final step prior to reporting.Therefore,calculated parameters that are typically reported as "Total"may vary slightly from the sum of the reported component parameters. Pace Analytical is TNI accredited.Contact your Pace PM for the current list of accredited analytes. TNI-The NELAC Institute. ANALYTE QUALIFIERS El Reported value should be considered a minimum estimate since it is the maximum reportable number for this method based on the sample volume used.The true value is likely greater than the value reported. M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample(LCS)recovery. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced,except in full, Date:04/12/2022 10:46 AM without the written consent of Pace Analytical Services,LLC. Page 21 of 24 Pace Analytical Services,LLC aceAnalytical m 1377 South Park 84 w Kemersville,NC 27284 / ww.pacdabs.cam (704)977-0981 I QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Piedmont Custon Meats-MW/Eff Pace Project No.: 92596108 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92596108001 MW-1 SM 2540C-2015 688902 92596108002 MW-4 SM 2540C-2015 688902 92596108003 MW-5 SM 2540C-2015 688902 92596108004 Effluent SM 2540C-2015 688902 92596108004 Effluent SM 2540D-2015 688783 92596108001 MW-1 EPA 350.1 Rev 2.0 1993 688525 92596108002 MW-4 EPA 350.1 Rev 2.0 1993 688525 92596108003 MW-5 EPA 350.1 Rev 2.0 1993 688525 92596108004 Effluent EPA 350.1 Rev 2.0 1993 688525 92596108001 MW-1 EPA 353.2 Rev 2.0 1993 688277 92596108002 MW-4 EPA 353.2 Rev 2.0 1993 688277 92596108003 MW-5 EPA 353.2 Rev 2.0 1993 688277 92596108004 Effluent EPA 353.2 Rev 2.0 1993 688277 92596108004 Effluent SM 5210B-2016 688543 SM 5210B-2016 688633 92596108001 MW-1 SM 9222D-2015 688338 SM 9222D-2015 688339 92596108002 MW-4 SM 9222D-2015 688338 SM 9222D-2015 688339 92596108003 MW-5 SM 92220-2015 688338 SM 9222D-2015 688339 92596108004 Effluent Colilert-18 688335 Colilert-18 688360 92596108001 MW-1 EPA 120.1-1982 689206 92596108002 MW-4 EPA 120.1-1982 689206 92596108003 MW-5 EPA 120.1-1982 689206 92596108004 Effluent TKN+NO3+NO2 690974 Calculation 92596108001 MW-1 EPA 300.0 Rev 2.1 1993 688805 92596108002 MW-4 EPA 300.0 Rev 2.1 1993 688805 92596108003 MW-5 EPA 300.0 Rev 2.1 1993 688805 92596108004 Effluent EPA 300.0 Rev 2.1 1993 688805 92596108004 Effluent EPA 351.2 Rev 2.0 1993 689956 EPA 351.2 Rev 2.0 1993 690536 92596108004 Effluent EPA 365.1 Rev 2.0 1993 689813 EPA 365.1 Rev 2.0 1993 689908 92596108001 MW-1 SM 5310B-2014 689204 92596108002 MW-4 SM 5310B-2014 689485 92596108003 MW-5 SM 5310B-2014 689485 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced,except in full, Date:04/12/2022 10:46 AM without the written consent of Pace Analytical Services,LLC, Page 22 of 24 i Q o ° O C eag z z z z 22.�rz�^�a z Z W0., z .c ma U � _ Su a a o E m u U a rU. c. -.E. 14 c a u 7 76. el 13 �' °' a `m m. 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