NCG030694_2022 DMR_20220317

hart '� hickman
SMARTER ENVIRONMENTAL SOLUTIONS
Via Online Portal & 2°d Day FedEx
March 16, 2022
North Carolina Department of Environmental Quality
Division of Energy, Mineral and Land Resources
450 West Hanes Mill Road, Suite 300
Winston-Salem, North Carolina 27105
Re: DMR February 2022 — NCG030694 — LLFIex, LLC
Oracle Flexible Packaging, Inc. (Former)
1300 Cunningham Avenue
Winston-Salem, Forsyth County
H&H Project No. LLF-007
Dear Madam/Sir:
On behalf of LLFIex, LLC (LLFIex), Hart & Hickman, PC (H&H) is submitting the enclosed
quarterly stormwater Discharge Monitoring Report (DMR) for the site referenced above in
accordance with the industrial stormwater permit (NCG030694). There were no benchmark value
exceedances in samples from this quarterly monitoring period.
Should you have any questions or need any additional information, please feel free to contact
me.
Sincerely,
Hart & Hickman, PC
477� a,
Gregory Kanellis, PE
Project Manager
Enclosures
CC: Mr. Jason Caple, LLFIex (PDF via email)
Mr. Shawn Sylvester, LLFIex (PDF via email)
2923 South Tryon Street, Suite 100 3921 Sunset Ridge Rd, Suite 301
Charlotte, NC 28203 Raleigh, NC 27607 www.harthickman.com
704.586.0007 main 919.847.4241 main

NCDEQ Division of Energy, Mineral and Land Resources
Stormwater Discharge Monitoring Report (DMR) Form for NCG030000
Metal Fabrication
Click here for instructions
Complete, sign, scan and submit the DMR via the Stormwater NPDES Permit Data Monitoring Report (DMR) Upload form within
30 days of receiving sampling results. Mail the original, signed hard copy of the DMR to the appropriate DEMLR Regional Office.
Certificate of Coverage No. NCG03 0694
Person Collecting Samples: Glenn Price (Pace Analytical)
Facility Name: Former Oracle 200 Facility
Laboratory Name: Pace Analytical
Facility County: Forsyth
LaboratoryCert. No.:Ash ft.NC(40), Eden. NC(633),HuntersAlle,NC(12).OnnondB—h(667)
Discharge during this period: ❑■ Yes ❑ No (if no, skip to signature and date)
Has your facility implemented mandatory Tier response actions this sample period for any benchmark exceedances? ❑ Yes ❑■ No
If so, which Tier (1, II, or Ill)?
A copy of this DMR has been uploaded electronically via https://edocs.deg.nc.gov/Forms/SW-DMR Yes ❑ No
Date Uploaded: — �6— O- a
Analytical Monitoring Requirements for Outfalls with Industrial Activities — Benchmarks in (Red)
Parameter
Parameter
Outfall SD01
Outfall SD02
Outfall SD03
Outfall SD04
Outfall SD05
Code
N/A
Receiving Stream Class
C
C
C
C
C
N/A
Date Sample Collected MM/DD/YYYY
02/23/2022
02/23/2022
02/23/2022
02/23/2022
02/23/2022
46529
24-Hour Rainfall in inches
2.1
2.1
2A
2.1
2.1
C0530
TSS in mg/L (100 or 50*)
<2.7
<2.6
<3.2
<3.0
<2.5
pH in standard units (6.0-9.0 FW,
00400
7.01
7.14
7.18
6.86
6.93
6.8-8.5 SW)
Copper, total recoverable in mg/L
01119
(0.010 FW, 0.0058 SW)
<0.0050
<0.0050
<0.0050
<0.0050
0.0076
Lead, total recoverable in mg/ L
01051
(0.075 FW, 0.22 SW)
<0.010
<0.010
<0.010
<0.010
<0.010
Zinc, total recoverable in mg/ L (0.126
01094
FW, 0.095 SW)
<0 020
<0.020
0,086
0.087
0.089
Chemical Oxygen Demand (COD) in
00340
mg/L (120)
<25,0
<25,0
<25.0
<25.0
<25.0
00552
Non -Polar Oil & Grease in mg/L (15)
<5.1
<5.1
<5.1
<5.1
<5.1
* Outfalls to0utstanding Resource Waters (ORW), High Quality Waters (HQW), Trout Waters (Tr) and Primary Nursery Areas (PNA)
have a benchmark TSS limit of 50 mg/L. All other water classifications have a benchmark of 100 mg/L
FW (Freshwater) SW (Saltwater)
Notes (optional):
"I certify by my signature below, under penalty of law, that this document and all attachments were prepared under my direction or supervision in
accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my
inquiry of the person or persons who manage the system, or those persons directly responsible for gathering the information, the information
submitted is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting
false information, including the ossibility of fines and imprisonment for knowing violations."
s 3 _4 Z-Z
Signature of Permittee ortelegated Authorized Individual
,ss
Email Address
Date
336 -- 9D3 -14 5,Y
Phone Number
Page 27 of 27

aceAnalytical
www,patelabs.com
March 04, 2022
Greg Kanellis
Hart & Hickman
3921 Sunset Ridge Rd.
Suite 301
Raleigh, NC 27607
RE: Project: Hart & Hickman Oracle 200
Pace Project No.: 92589693
Dear Greg Kanellis:
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Enclosed are the analytical results for sample(s) received by the laboratory on February 23, 2022. The results relate only
to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace Analytical Services - Asheville
• Pace Analytical Services - Charlotte
• Pace Analytical Services - Eden
• Pace Analytical Services - Kernersville, NC
• Pace Analytical Services - Ormond Beach
Rev.01: Final report revised on 3/4/22; Units updated to mg/L.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kevin Godwin
[e-mail]
1(704)875-9092
Project Manager
Enclosures
REPORT OF LABORATORY ANALYSIS
This report small not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 1 of 27

aceAnalyfical
www.pacelabsxoh
Project: Hart & Hickman Oracle 200
Pace Project No.: 92589693
Pace Analytical Services Ormond Beach
8 East Tower Circle, Ormond Beach, FL 32174
Alaska DEC- CSIUST/LUST
Alabama Certification M 41320
Colorado Certification: FL NELAC Reciprocity
Connecticut Certification M PH-0216
Delaware Certification: FL NELAC Reciprocity
Florida Certification #: E83079
Georgia Certification #: 955
Guam Certification: FL NELAC Reciprocity
Hawaii Certification: FL NELAC Reciprocity
Illinois Certification #: 200068
Indiana Certification: FL NELAC Reciprocity
Kansas Certification #: E-10383
Kentucky Certification #: 90050
Louisiana Certification M FL NELAC Reciprocity
Louisiana Environmental Certificate #: 05007
Maine Certification #: FLO1264
Maryland Certification: #346
Michigan Certification #: 9911
Mississippi Certification: FL NELAC Reciprocity
Missouri Certification #: 236
Pace Analytical Services Charlotte
South Carolina Laboratory ID: 99006
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification M 37706
North Carolina Field Services Certification M 5342
North Carolina Wastewater Certification #: 12
South Carolina Laboratory ID: 99006
Pace Analytical Services Asheville
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification M E87648
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
Pace Analytical Services Eden
205 East Meadow Road Suite A, Eden, NC 27288
North Carolina Drinking Water Certification M 37738
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
CERTIFICATIONS
Montana Certification M Cert 0074
Nebraska Certification: NE-OS-28-14
New Hampshire Certification #: 2958
New Jersey Certification #: FL022
New York Certification #: 11608
North Carolina Environmental Certificate #: 667
North Carolina Certification #: 12710
North Dakota Certification #: R-216
Ohio DEP 87780
Oklahoma Certification M D9947
Pennsylvania Certification #: 68-00547
Puerto Rico Certification #: FLO1264
South Carolina Certification: #96042001
Tennessee Certification #: TN02974
Texas Certification: FL NELAC Reciprocity
US Virgin Islands Certification: FL NELAC Reciprocity
Virginia Environmental Certification #: 460165
West Virginia Certification A 9962C
Wisconsin Certification #: 399079670
Wyoming (EPA Region 8): FL NELAC Reciprocity
South Carolina Certification #: 99006001
South Carolina Drinking Water Cert. #: 99006003
Florida/NELAP Certification #: E87627
Kentucky UST Certification M 84
Louisiana DoH Drinking Water#: LA029
Virginia/VELAP Certification M 460221
South Carolina Laboratory ID: 99030
South Carolina Certification #: 99030001
Virginia/VELAP Certification M 460222
North Carolina Wastewater Certification #: 633
VirginiafVELAP Certification #: 460025
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analylical Services, LLC. Page 2 of 27

aceAna1jdica1
www.pactiab$.com
SAMPLE ANALYTE COUNT
Project: Hart & Hickman Oracle 200
Pace Project No.: 92589693
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Lab I❑
Sample ID
Method
Analysts
Analytes
Reported
Laboratory
92589693001
OUTFALL SD01
SM 2540D-2015
LRB
1
PASI-E
EPA 1664B
ICO
1
PASI-C
EPA 200.7
EMG
3
PASI-O
KRG
4
PASI-KR
SM 5220D-2011
JP1
1
PASI-A
92589693002
OUTFALL SD02
SM 2540D-2015
LRB
1
PASI-E
EPA 1664B
ICO
1
PASI-C
EPA200.7
EMG
3
PASI-O
KRG
4
PASI-KR
SM 5220D-2011
JP1
1
PASI-A
92589693003
OUTFALL SD03
SM 2540D-2015
LRB
1
PASI-E
EPA 1664E
ICO
1
PASI-C
EPA 200.7
EMG
3
PASI-O
KRG
4
PASI-KR
SM 5220D-2011
JP1
1
PASI-A
92589693004
OUTFALL SD04
SM 2540D-2015
LRB
1
PASI-E
EPA 1664B
ICO
1
PASI-C
EPA 200.7
EMG
3
PASI-O
KRG
4
PASI-KR
SM 5220D-2011
J131
1
PASI-A
92589693005
OUTFALL SD05
SM 254OD-2015
LRB
1
PASI-E
EPA1664B
ICO
1
PASI-C
EPA 200.7
EMG
3
PASI-O
KRG
4
PASI-KR
SM 5220D-2011
JP1
1
PASI-A
PASI-A = Pace Analytical Services - Asheville
PAS I-C = Pace Analytical Services - Charlotte
PAS I-E = Pace Analytical Services - Eden
PASI-KR = Pace Analytical Services - Kernersville, NC
PASI-O = Pace Analytical Services - Ormond Beach
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 3 of 27

aceAnalytical
www.pacelebs.cero
ANALYTICAL RESULTS
Project: Hart & Hickman Oracle 200
Pace Project No.: 92589693
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Sample: OUTFALL SD01 Lab ID: 92589693001 Collected: 02/23/22 08:26 Received: 02/23/22 11:30 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
2540D Total Suspended Solids
Analytical Method: SM 254OD-2015
Pace Analytical Services - Eden
Total Suspended Solids
ND mglL 2.7
1
03/01/22 09:21
1664 SGT-HEM, TPH
Analytical Method: EPA 1664B
Pace Analytical Services - Charlotte
Total Petroleum Hydrocarbons
ND mglL 5.1
1
02/24/22 23:03
200.7 MET ICP
Analytical Method: EPA 200.7 Preparation Method: EPA 200.7
Pace Analytical Services - Ormond Beach
Capper
ND mglL 0.0050
1
02/28/22 05:19 03/01/22 12:50 7440-50-8
Lead
ND mglL 0.010
1
02/28/22 05:19 03/01/22 12:50 7439-92-1
Zinc
ND mglL 0.020
1
02/28/22 05:19 03/01/22 12:50 7440-66-6
Field Data Kernersville
Analytical Method:
Pace Analytical Services - Kernersvil le, NC
Performed by
Pace
1
02/23/22 08:26
Collected By
Glenn
1
02/23/22 08:26
Price
pH
7.01 Std. Units
1
02/23/22 08:26
Temperature
14.3 deg C
1
02/23/22 08:26
5220D COD
Analytical Method: SM 52200-2011 Preparation Method:
SM 5220D-2011
Pace Analytical Services -Asheville
Chemical Oxygen Demand
NO mglL 25.0
1
03/02/22 02:32 03/02/22 05:41
Date: 03/04/2022 02:35 PM
REPORT OF LABORATORY ANALYSIS
This report shO not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 4 of 27

aceAnalytical
www.pacelabs.com
ANALYTICAL RESULTS
Project: Hart & Hickman Oracle 200
Pace Project No.: 92589693
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Sample: OUTFALL SD02 Lab ID: 92589693002 Collected: 02/23/22 08:33 Received: 02/23/22 11:30 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
2540D Total Suspended Solids
Analytical Method: SM 254OD-2015
Pace Analytical Services - Eden
Total Suspended Solids
ND mg1L 2.6
1
03/01/22 09:21
1664 SGT-HEM, TPH
Analytical Method: EPA 1664B
Pace Analytical Services - Charlotte
Total Petroleum Hydrocarbons
ND mg1L 5.1
1
02/24/22 23:03
200.7 MET IC
Analytical Method: EPA200.7 Preparation Method: EPA200.7
Pace Analytical Services - Ormond Beach
Copper
ND mg/L 0.0050
1 02/28/22 05:19
03/01/22 12:54 7440-50-8
Lead
ND mg1L 0.010
1 02128/2205:19
03101/2212:54 7439-92-1
Zinc
ND mg1L 0.020
1 02/28/2205:19
03101/2212:54 7440-66-6
Field Data Kernersville
Analytical Method:
Pace Analytical Services - Kernersville, NC
Performed by
Pace
1
02/23/22 08:33
Collected By
Glenn
1
02123/22 08:33
Price
pH
7.14 Std. Units
1
02123/22 08:33
Temperature
15.1 deg C
1
02123/22 08:33
5220D COD
Analytical Method: SM 5220D-2011 Preparation Method: SM 5220D-2011
Pace Analytical Services -Asheville
Chemical Oxygen Demand
ND mg/L 25.0
1 03/02/22 02:32
03/02/22 05:41
Date: 03/04/2022 02:35 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC,
Page 5 of 27

aceAnalj cal
www.pacerabs.com
ANALYTICAL RESULTS
Project: Hart & Hickman Oracle 200
Pace Project No.: 92589693
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Sample: OUTFALL SD03 Lab ID: 92589693003 Collected: 02/23/22 08:44 Received: 02/23/22 11:30 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
2540D Total Suspended Solids
Analytical Method: SM 254OD-2015
Pace Analytical Services - Eden
Total Suspended Solids
ND mg/L 3.2
1
03/01/22 09:22
1664 SGT-HEM, TPH
Analytical Method: EPA 1664B
Pace Analytical Services - Charlotte
Total Petroleum Hydrocarbons
ND mg/L 5.1
1
02/24/22 23:03
200.7 MET lCP
Analytical Method: EPA 200.7 Preparation Method: EPA 200.7
Pace Analytical Services - Ormond Beach
Copper
ND mg/L 0.0050
1 02/28/22 05:19
03/01/22 12:57 7440-50-8
Lead
ND mg/L 0.010
1 02/28/22 05:19
03/01/22 12:57 7439-92-1
Zinc
0.086 mg/L 0.020
1 02/28/22 05:19
03/01/22 12:57 7440-66-6
Field Data Kernersville
Analytical Method:
Pace Analytical Services - Kernersville, NC
Performed by
Pace
1
02/23/22 08:44
Collected By
Glenn
1
02/23/22 08:44
Price
pH
7.18 Std. Units
1
02/23/22 08:44
Temperature
14.4 deg C
1
02/23/22 08:44
5220D COD
Analytical Method: SM 5220D-2011 Preparation Method: SM 5220D-2011
PaceAnaiytical Services -Asheville
Chemical Oxygen Demand
ND mg/L 25.0
1 03/02/22 02:32
03/02/22 05:42
Date: 03/04/2022 02:35 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 6 of 27

aoAnalytical
www.pacolabs.com
ANALYTICAL RESULTS
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: Hart & Hickman Oracle 200
Pace Project No.: 92589693
Sample: OUTFALL SD04 Lab ID: 92589693004 Collected: 02/23/22 08:52 Received: 02/23/22 11:30 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
2540D Total Suspended Solids
Analytical Method: SM 254OD-2015
Pace Analytical Services - Eden
Total Suspended Solids
ND mg1L 3.0
1
03/01/22 09:22
1664 SGT-HEM, TPH
Analytical Method: EPA 1664B
Pace Analytical Services - Charlotte
Total Petroleum Hydrocarbons
ND mg1L 5.1
1
02/24/22 23:03
200.7 MET ICP
Analytical Method: EPA200.7 Preparation Method: EPA200.7
Pace Analytical Services - Ormond Beach
Copper
ND mg1L 0.0050
1
02/28/22 05:19 03/01/22 13:09 7440-50-8
Lead
ND mglL 0.010
1
02/28/22 05:19 03/01/22 13:09 7439-92-1
Zinc
0.087 mg1L 0.020
1
02/28/22 05:19 03/01/22 13:09 7440-66-6
Field Data Kernersville
Analytical Method:
Pace Analytical Services - Kernersville, NC
Performed by
Pace
1
02/23/22 08:52
Collected By
Glenn
1
02/23/22 08:52
Price
pH
6.86 Std. Units
1
02/23/22 08:52
Temperature
14.9 deg C
1
02/23/22 08:52
5220D COD
Analytical Method: SM 5220D-2011 Preparation Method: SM 5220D-2011
Pace Analytical Services - Asheville
Chemical Oxygen Demand
ND mg1L 25.0
1
03/02/22 02:32 03/02/22 05:42
Date: 03/04/2022 02:35 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 7 of 27

acmnalyi#ical
www.pacelabs.cots
ANALYTICAL RESULTS
Project: Hart & Hickman Oracle 200
Pace Project No.: 92589693
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Sample: OUTFALL SD05
Parameters
Lab ID: 92589693005 Collected: 02/23/22 09:00
Results Units Report Limit OF
Received: 02/23/22 11:30 Matrix: Water
Prepared Analyzed GAS No, Qual
2540D Total Suspended Solids
Analytical Method: SM 254OD-2015
Pace Analytical Services - Eden
Total Suspended Solids
NO mg1L 2.5
1
03/01/22 09:22
1664 SGT-HEM, TPH
Analytical Method: EPA 1664B
Pace Analytical Services - Charlotte
Total Petroleum Hydrocarbons
ND mg/L 5.1
1
02124/22 23:03
200.7 MET ICP
Analytical Method: EPA 200.7 Preparation Method: EPA200.7
Pace Analytical Services - Ormond Beach
Copper
0.0076 mg1L 0.0050
1
02/28/22 05:19
03/01/22 13:12
7440-50-8
Lead
NO mg/L 0.010
1
02/28/22 05:19
03/01/22 13:12
7439-92-1
Zinc
0.089 mg1L 0,020
1
0212812205:19
03101/2213:12
7440-66-6
Field Data Kernersville
Analytical Method:
Pace Analytical Services - Kernersviile, NC
Performed by
Pace
1
02/23/22 09:00
Collected By
Gienn
1
02/23/22 09:00
Price
pH
6.93 Sid. Units
1
02/23/22 09:00
Temperature
14.9 deg C
1
02/23/22 09:00
5220D COD
Analytical Method: SM 5220D-2011 Preparation
Method: SM 5220D-2011
Pace Analytical Services -Asheville
Chemical Oxygen Demand
NO mg/L 25.0
1
03/02/22 02:32
03/02/22 05:42
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 03/04/2022 02:35 PM without the written consent of Pace Analytical Services, LLC. Page 8 of 27

aceAnalytical
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QUALITY CONTROL DATA
Project: Hart & Hickman Oracle 200
Pace Project No.: 92589693
QC Batch: 680591 Analysis Method: SM 2540D-2015
QC Batch Method: SM 2540D-2015 Analysis Description: 2540D Total Suspended Solids
Laboratory: Pace Analytical Services - Eden
Associated Lab Samples: 92589693001, 92589693002, 92589693003, 92589693004, 92589693005
METHOD BLANK: 3560534 Matrix: Water
Associated Lab Samples: 92589693001, 92589693002, 92589693003, 92589693004, 92589693005
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Total Suspended Solids mg/L ND 2.5 03/01/22 09:20
LABORATORY CONTROL SAMPLE:
3560535
Spike
Parameter
Units
Cone.
Total Suspended Solids
mg/L
250
SAMPLE DUPLICATE: 3565298
92589688001
Parameter
Units
Result
Total Suspended Solids
mg/L
161
SAMPLE DUPLICATE: 3565299
Parameter
Total Suspended Solids
LCS LCS
Result % Rec
228 91
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
% Rec
Limits Qualifiers
90-110
Dup
Result RPD Qualifiers
144 11
92589690001 Dup
Units Result Result
mg/L 525 515
RPD Qualifiers
2
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 03/04/2022 02:35 PM without the written consent of Pace Analytical Services, LLC. Pago 9 of 27

aceAna,(Xicai
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QUALITY CONTROL DATA
Project: Hart & Hickman Oracle 200
Pace Project No.: 92589693
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QC Batch: 680761
Analysis Method: EPA 1664B
QC Batch Method: EPA 1664B
Analysis Description: 1664 SGT-HEM, TPH
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92589693001, 92589693002,
92589693003, 92589693004, 92589693005
METHOD BLANK: 3561443
Matrix: Water
Associated Lab Samples: 92589693001, 92589693002,
92589693003, 92589693004, 92589693005
Blank Reporting
Parameter
Units
Result Limit Analyzed Qualifiers
Total Petroleum Hydrocarbons
mg/L
ND 5.0 02/24/22 23:03
LABORATORY CONTROL SAMPLE:
3561444
Spike LCS LCS % Rec
Parameter
Units
Cone. Result % Rae Limits Qualifiers
Total Petroleum Hydrocarbons
mg1L
20 13.2 66 64-132
MATRIX SPIKE SAMPLE:
3561445
92589780002 Spike MS MS % Rec
Parameter
Units
Result Cone. Result % Rec Limits Qualifiers
Total Petroleum Hydrocarbons
mglL
ND 19.6 12.0 53 64-132 M1
SAMPLE DUPLICATE: 3561446
92589764002 ❑up
Parameter
Units
Result Result RPD Qualifiers
Total Petroleum Hydrocarbons
mglL
ND ND
Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 03/04/2022 02:35 PM without the written consent of Pace Analytical Services, LLC. Page 10 of 27

acemalytical
www.pacelabs.tota
QUALITY CONTROL DATA
Pace Analytical Services, LLC
9800 KinceyAve. Suite 100
Huntersville, NC 28078
[phone]
Project: Hart & Hickman Oracle 200
Pace Project No.: 92589693
QC Batch: 803664
Analysis Method: EPA 200.7
QC Batch Method: EPA 200.7
Analysis Description: 200.7 MET
Laboratory: Pace Analytical Services - Ormond Beach
Associated Lab Samples: 92589693001, 92589693002,
92589693003, 92589693004, 92589693005
METHOD BLANK: 4412899
Matrix: Water
Associated Lab Samples: 92589693001, 92589693002,
92589693003, 92589693004, 92589693005
Blank Reporting
Parameter
Units
Result Limit
Analyzed Qualifiers
Copper
mg/L
NO 0.0050
0310212211:18
Lead
mg1L
NO 0.010
03/0212211:18
Zinc
mg/L
ND 0,020
03/0212211:18
LABORATORY CONTROL SAMPLE:
4412900
Spike LCS
LCS % Rec
Parameter
Units
Cone. Result
% Rec Limits Qualifiers
Copper
mg/L
0.25 0.26
103 85-115
Lead
mg1L
0.25 0.26
105 85-115
Zinc
mg1L
1.2 1.3
104 85-115
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4412901 4412902
MS MSD
35699610001
Spike Spike MS
MSD MS MSD
% Rec
Parameter
Units Result
Cone. Cone. Result
Result % Rec % Rec
Limits
RPD Qual
Copper
mg/L 246
0.25 0.25 0.53
0.53 112 112
70-130
0
ug/L
Lead
mg/L C)AJ
0,25 0.25 0.25
0.25 97 97
70-130
1
ug/L
Zinc
mg/L lag
1.2 1.2 1.4
1.4 99 99
70-130
0
ug/L
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4412903 4412904
MS MSD
92590266003
Spike Spike MS
MSD MS MSD
% Rec
Parameter
Units Result
Cone. Cone. Result
Result % Rec % Rec
Limits
RPD Qual
Copper
mg/L 5.3 ug/L
0,25 0.25 0.27
0.27 105 104
70-130
1
Lead
mg1L NO
0.25 0.25 0.26
0.26 104 103
70-130
1
Zinc
mg1L 50.5
1.2 1.2 1.3
1.3 102 101
70-130
1
ug/L
Results presented on this page are in the units indicated by the 'Tnits" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 03/04/2022 02:35 PM without the written consent of Pace Analytical Services, LLC.
Page 11 of 27

aceAnalytical
wwwpacelsbsxtim
QUALITY CONTROL DATA
Project: Hart & Hickman Oracle 200
Pace Project No.: 92589693
QC Batch: 681784 Analysis Method: SM 5220D-2011
QC Batch Method: SM 5220D-2011 Analysis Description: 5220D COD
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92589693001, 92589693002, 92589693003, 92589693004, 92589693005
METHOD BLANK: 3566369 Matrix: Water
Associated Lab Samples: 92589693001, 92589693002, 92589693003, 92589693004, 92589693005
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Chemical Oxygen Demand mglL ND 25.0 03/02/22 05:37
Pace Analytical Services, LLC
9800 KinceyAve. Suite 100
Huntersville, NC 28078
[phone]
LABORATORY CONTROL SAMPLE: 3566370
Spike LCS LCS % Rec
Parameter Units Cone. Result % Rec Limits Qualifiers
Chemical Oxygen Demand mglL 750 768 102 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3566371 3566372
MS MSD
92589412001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Cone. Conc. Result Result % Rec % Rec Limits RPD Qual
Chemical Oxygen Demand mg/L 48.0 100 100 209 176 161 128 90-110 17 M1,R1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3566373 3566374
MS MSD
92589412002 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qua]
Chemical Oxygen Demand mg/L 444 100 100 514 553 70 109 90-110 7 M1,R1
Results presented on this page are In the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 03/04/2022 02:35 PM without the written consent of Pace Analytical Services, LLC.
Page 12 of 27

_ aceAnaljftal
www.pacelab3.catn
QUALIFIERS
Project: Hart & Hickman Oracle 200
Pace Project No.: 92589693
DEFINITIONS
OF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected
Acid preservation may not be appropriate for 2 Chloroethyivinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as
"Total" may vary slightly from the sum of the reported component parameters.
Pace Analytical is TNI accredited, Contact your Pace PM for the current list of accredited analytes.
11►1d�Ta►1 ��a[NI�ItitiC�
ANALYTE QUALIFIERS
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
R11 RPD value was outside control limits,
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in fu1i,
Date: 03/04/2022 02:35 PM without the written consent of Pace Analytical Services, LLC. Page 13 of 27

aceAnalytical
www.pacelabuam
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: Hart & Hickman Oracle 200
Pace Project No.: 92589693
Analytical
Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch
92589693001
OUTFALL SD01
SM 254OD-2015
680591
92589693002
OUTFALL SD02
SM 2540D-2015
680591
92589693003
OUTFALL SD03
SM 25400-2015
680591
92589693004
OUTFALL 811304
SM 254OD-2015
680591
92589693005
OUTFALL SD05
SM 2540D-2015
680591
92589693001
OUTFALL SD01
EPA 1664E
680761
92589693002
OUTFALL SD02
EPA 1664B
680761
92589693003
OUTFALL SD03
EPA 1664B
680761
92589693004
OUTFALL SD04
EPA 1664B
680761
92589693005
OUTFALL S1305
EPA 16646
680761
92589693001
OUTFALLSD01
EPA200.7
803664
EPA200.7
803716
92589693002
OUTFALL SD02
EPA 200.7
803664
EPA 200.7
803716
92589693003
OUTFALLSD03
EPA200.7
803664
EPA200.7
803716
92589693004
OUTFALL S1304
EPA 200.7
803664
EPA 200.7
803716
92589693005
OUTFALL SD05
EPA 200.7
803664
EPA 200.7
803716
92589693001
OUTFALL SD01
92589693002
OUTFALL SD02
92589693003
OUTFALL SD03
92589693004
OUTFALL SD04
92589693005
OUTFALL SD05
92589693001
OUTFALL SD01
SM 5220D-2011
681784
SM 5220D-2011
681808
92589693002
OUTFALL SD02
SM 5220D-2011
681784
SM 5220D-2011
681808
92589693003
OUTFALL S1303
SM 5220D-2011
681784
SM 5220D-2011
681808
92589693004
OUTFALL SD04
SM 5220D-2011
681784
SM 5220D-2011
681808
92589693005
OUTFALL SD05
SM 5220D-2011
681784
SM 5220D-2011
681808
Date: 03/04/2022 02:35 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 14 of 27

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Page 15 of 27

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