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HomeMy WebLinkAboutNCG240019_2022 DMR_20220330MECKLENBURG COUNTY Land Use & Environmental Services Agency Solid Waste March 29, 2022 DEQ Mooresville Regional Office Attn: DEMLR Stormwater Program 610 East Center Avenue Suite 301 Mooresville, NC 28115 Attention: DEMLR Stormwater Program Subject: Discharge Monitoring Report Mecklenburg County Compost Central (new) — Certificate of Coverage No. NCG240019 Dear Central Files: Please find enclosed the Discharge Monitoring Report, March 2022, for Mecklenburg County Compost Central (new), a Type I facility located at 140 Valleydale Road, North Carolina. If you have any questions, please contact me at 704-634-7705 or by email at khaliem.adams@mecklenbur cg ountync.gov. Sincerely, Khaliem Adams Solid Waste Environmental Specialist Enclosed: 2022 DMR PEOPLE • PRIDE PROGRESS • PARTNERSHIP 2145 Suttle Avenue Charlotte, North Carolina 28208 www.wipeoutwaste.com NCDEQ Division of Energy, Mineral and Land Resources Stormwater Discharge Monitoring Report (DMR) Form for NCG240000 Compost Operations Click here for instructions Complete, sign, scan and submit the DMR via the Stormwater NPDES Permit Data Monitoring Report (DMR) Upload form within 30 days of receiving sampling results. Mail the original, signed hard copy of the DMR to the appropriate DEMLR Regional Office. Certificate of Coverage No. NCG24 0019 Person Collecting Samples: Khaliem Adams Facility Name: Mecklenburg County Compost Central (new) Laboratory Name: Pace Analytical Facility County: Mecklenburg Laboratory Cert. No.: Discharge during this period: ✓❑ Yes ❑ No (if no, skip to signature and date) Has your facility implemented mandatory Tier response actions this sample period for any benchmark exceedances? ❑✓ Yes ❑ No If so, which Tier (I, II, or III)? Tier 2 A copy of this DMR has been uploaded electronically via https://edocs.deg.nc.gov/Forms/SW-DMR ❑✓ Yes ❑ No Date Uploaded: j Analytical Monitoring Requirements for Outfalls with Industrial Activities — Benchmarks in (Red) Parameter Parameter Outfall 1 Outfall Outfall Outfall Outfall Code N/A Receiving Stream Class N/A Date Sample Collected MM/DD/YYYY 03/10/2022 46529 24-Hour Rainfall in inches 2.60 in C0530 TSS in mg/L (100) 16.5 00340 Chemical Oxygen Demand (120) 150 31615 Fecal Coliform in colonies per 100 ml 6000 (1000) 600 Total Nitrogen in mg/L (30) 3.1 665 Total Phosphorus in mg/L (2) 2.3 400 pH in standard units (6.0-9.0) 8.90 Copper, total recoverable in mg/L 01119 (0.030) <0.020 Lead, total recoverable in mg/ L 01051 (0.075) <0.025 Zinc, total recoverable in mg/ L 01094 (0.126) 0.0261 Additional parameters for outfalls in drainage areas that use >55 gallons per month of new hydraulic oil on average 00552 Non -Polar Oil & Grease in mg/L (15) <4.9 Estimated New Motor/Hydraulic Oil NCOIL Usage in gal/month 75ga1/month Notes (optional): "I certify by my signature below, under penalty of law, that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false info<Zti including the o ibility of fines and imprisonment for knowing violations." LZI I- .3 fzq [Z z— ittee or Delegated Authorized Individual Date Email Address Phone Number Facility Name Sample Location Sample Time pH Date Device used to Sample Mecklenburg County Compost Central Outfall 2 1126 8.64 3/10/2022 Horiba pH meter aceAnalytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 March 18, 2022 Darren Steinhilber Mecklenburg County Solid Waste 2145 Suttle Ave Charlotte, NC 28208 RE: Project: COMPOST CENTRAL 2 Pace Project No.: 92592702 Dear Darren Steinhilber: Enclosed are the analytical results for sample(s) received by the laboratory on March 10, 2022. The results relate only to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report. The test results provided in this final report were generated by each of the following laboratories within the Pace Network: • Pace Analytical Services -Asheville • Pace Analytical Services - Charlotte • Pace Analytical Services - Peachtree Corners, GA If you have any questions concerning this report, please feel free to contact me. Sincerely, Matthew Brainard matthew.brainard@pacelabs.com (704)875-9092 Project Manager Enclosures cc: Khaliem Adams, Meclenburg County Solid Waste REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 18 aceAnalytical www.paeelabs.enm Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: COMPOST CENTRAL 2 Pace Project No.: 92592702 Pace Analytical Services Charlotte South Carolina Laboratory ID: 99006 9800 Kincey Ave. Ste 100, Huntersville, NC 28078 North Carolina Drinking Water Certification #: 37706 North Carolina Field Services Certification #: 5342 North Carolina Wastewater Certification #: 12 South Carolina Laboratory ID: 99006 Pace Analytical Services Asheville 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 North Carolina Drinking Water Certification #: 37712 North Carolina Wastewater Certification #: 40 Pace Analytical Services Peachtree Corners 110 Technology Pkwy, Peachtree Corners, GA 30092 Florida DOH Certification #: E87315 Georgia DW Inorganics Certification #: 812 CERTIFICATIONS South Carolina Certification #: 99006001 South Carolina Drinking Water Cert. #: 99006003 Florida/NELAP Certification #: E87627 Kentucky UST Certification #: 84 Louisiana DoH Drinking Water#: LA029 Virginia/VELAP Certification #: 460221 South Carolina Laboratory ID: 99030 South Carolina Certification #: 99030001 Virginia/VELAP Certification #: 460222 North Carolina Certification #: 381 South Carolina Certification #: 98011001 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 18 aceAnalytical www.paeelabs.enm Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: Pace Project No.: COMPOST CENTRAL 2 92592702 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92592702001 OUTFALL 1 EPA 1664B ICO 1 PASI-C EPA 1664B ICO 1 PASI-C EPA 200.7 DRB 3 PASI-GA SM 9222D-2015 KDF 1 PASI-C SM 254OD-2015 MAB2 1 PASI-A TKN+NO3+NO2 Calculation EWS 1 PASI-A EPA 351.2 Rev 2.0 1993 MFO 1 PASI-A EPA 353.2 Rev 2.0 1993 KDF1 1 PASI-A EPA 365.1 Rev 2.0 1993 SMT 1 PASI-A SM 5220D-2011 JP1 1 PASI-A PASI-A = Pace Analytical Services - Asheville PASI-C = Pace Analytical Services - Charlotte PASI-GA = Pace Analytical Services - Peachtree Corners, GA REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 18 aceAnalytical www.paeelabs.enm Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: COMPOST CENTRAL 2 Pace Project No.: 92592702 Sample: OUTFALL 1 Lab ID: 92592702001 Collected: 03/10/22 11:07 Received: 03/10/22 12:45 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual HEM, Oil and Grease Analytical Method: EPA 1664B Pace Analytical Services - Charlotte Oil and Grease ND mg/L 4.9 1 03/10/22 22:38 1664 SGT-HEM, TPH Analytical Method: EPA 1664B Pace Analytical Services - Charlotte Total Petroleum Hydrocarbons ND mg/L 4.9 1 03/10/22 22:38 200.7 MET ICP Analytical Method: EPA200.7 Preparation Method: EPA 200.7 Pace Analytical Services - Peachtree Corners, GA Copper ND ug/L 20.0 1 03/11/22 14:03 03/11/22 20:48 7440-50-8 Lead ND ug/L 25.0 1 03/11/22 14:03 03/11/22 20:48 7439-92-1 Zinc 26.1 ug/L 20.0 1 03/11/22 14:03 03/11/22 20:48 7440-66-6 MBIO 9222D Fecal Coliform CHT Analytical Method: SM 9222D-2015 Preparation Method: SM 9222D-2015 Pace Analytical Services - Charlotte Fecal Coliforms 6000 CFU/100 mL 1.0 1 03/10/22 17:01 03/11/22 15:16 u2 2540D Total Suspended Solids Analytical Method: SM 2540D-2015 Pace Analytical Services - Asheville Total Suspended Solids 16.5 mg/L 12.5 1 03/12/22 10:59 Total Nitrogen Calculation Analytical Method: TKN+NO3+NO2 Calculation Pace Analytical Services - Asheville Total Nitrogen 3.1 mg/L 0.040 1 03/18/22 10:34 351.2 Total Kjeldahl Nitrogen Analytical Method: EPA 351.2 Rev 2.0 1993 Preparation Method: EPA 351.2 Rev 2.0 1993 Pace Analytical Services - Asheville Nitrogen, Kjeldahl, Total 3.1 mg/L 0.50 1 03/15/22 19:15 03/16/22 04:41 7727-37-9 353.2 Nitrogen, NO2/NO3 pres. Analytical Method: EPA 353.2 Rev 2.0 1993 Pace Analytical Services - Asheville Nitrogen, NO2 plus NO3 ND mg/L 0.040 1 03/17/22 12:01 365.1 Phosphorus, Total Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation Method: EPA 365.1 Rev 2.0 1993 Pace Analytical Services - Asheville Phosphorus 2.3 mg/L 0.050 1 03/14/2214:08 03/15/2212:42 7723-14-0 5220D COD Analytical Method: SM 5220D-2011 Preparation Method: SM 5220D-2011 Pace Analytical Services - Asheville Chemical Oxygen Demand 150 mg/L 25.0 1 03/15/22 02:44 03/15/22 05:55 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/18/2022 10:35 AM without the written consent of Pace Analytical Services, LLC. Page 4 of 18 aceAnalytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: COMPOST CENTRAL 2 Pace Project No.: 92592702 QC Batch: 683979 Analysis Method: EPA 1664B QC Batch Method: EPA 1664B Analysis Description: 1664 HEM, Oil and Grease Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92592702001 METHOD BLANK: 3577594 Associated Lab Samples: 92592702001 Parameter Units Oil and Grease mg/L LABORATORY CONTROL SAMPLE: 3577595 Parameter Units Oil and Grease mg/L MATRIX SPIKE SAMPLE: 3577596 Parameter Units Oil and Grease mg/L Matrix: Water Blank Reporting Result Limit Analyzed Qualifiers ND 5.0 03/10/22 22:38 Spike LCS LCS % Rec Cone. Result % Rec Limits Qualifiers 40 32.4 81 78-114 92592702001 Spike MS MS % Rec Result Cone. Result % Rec Limits Qualifiers ND 38.8 31.1 79 78-114 SAMPLE DUPLICATE: 3577597 92592191002 Dup Parameter Units Result Result Oil and Grease mg/L ND 3.7J RPD Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/18/2022 10:35 AM without the written consent of Pace Analytical Services, LLC. Page 5 of 18 aceAnalytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: COMPOST CENTRAL 2 Pace Project No.: 92592702 QC Batch: 683981 Analysis Method: EPA 1664B QC Batch Method: EPA 1664B Analysis Description: 1664 SGT-HEM, TPH Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92592702001 METHOD BLANK: 3577601 Associated Lab Samples: 92592702001 Parameter Units Total Petroleum Hydrocarbons mg/L LABORATORY CONTROL SAMPLE: 3577602 Parameter Units Total Petroleum Hydrocarbons mg/L MATRIX SPIKE SAMPLE: 3577603 Parameter Units Total Petroleum Hydrocarbons mg/L Matrix: Water Blank Reporting Result Limit Analyzed Qualifiers ND 5.0 03/10/22 22:38 Spike LCS LCS % Rec Cone. Result % Rec Limits Qualifiers 20 14.7 74 64-132 92592702001 Spike MS MS % Rec Result Cone. Result % Rec Limits Qualifiers ND 19.4 13.6 67 64-132 SAMPLE DUPLICATE: 3577604 92592191002 Dup Parameter Units Result Result Total Petroleum Hydrocarbons mg/L ND ND RPD Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/18/2022 10:35 AM without the written consent of Pace Analytical Services, LLC. Page 6 of 18 aceAnalytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: COMPOST CENTRAL 2 Pace Project No.: 92592702 QC Batch: 684173 Analysis Method: EPA 200.7 QC Batch Method: EPA 200.7 Analysis Description: 200.7 Metals Total Laboratory: Pace Analytical Services - Peachtree Corners, GA Associated Lab Samples: 92592702001 METHOD BLANK: 3578362 Matrix: Water Associated Lab Samples: 92592702001 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Copper ug/L ND 20.0 03/11/22 20:09 Lead ug/L ND 25.0 03/11/22 20:09 Zinc ug/L ND 20.0 03/11/22 20:09 LABORATORY CONTROL SAMPLE: 3578363 Spike LCS LCS % Rec Parameter Units Cone. Result % Rec Limits Qualifiers Copper ug/L 1000 1020 102 85-115 Lead ug/L 1000 995 99 85-115 Zinc ug/L 1000 963 96 85-115 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3578364 3578365 MS MSD 92592595001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Cone. Cone. Result Result % Rec % Rec Limits RPD Qual Copper ug/L ND 1000 1000 1060 1040 105 103 70-130 2 Lead ug/L ND 1000 1000 1110 1100 111 110 70-130 1 Zinc ug/L 76.1 1000 1000 1110 1110 104 103 70-130 0 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3578366 3578367 MS MSD 92592716001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Cone. Cone. Result Result % Rec % Rec Limits RPD Qual Copper ug/L ND 1000 1000 1010 1000 100 100 70-130 1 Lead ug/L ND 1000 1000 1080 1070 107 106 70-130 1 Zinc ug/L 0.037 1000 1000 1050 1040 101 100 70-130 1 mg/L Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/18/2022 10:35 AM without the written consent of Pace Analytical Services, LLC. Page 7 of 18 aceAnalytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: COMPOST CENTRAL 2 Pace Project No.: 92592702 QC Batch: 683991 Analysis Method: SM 9222D-2015 QC Batch Method: SM 9222D-2015 Analysis Description: 9222D Fecal Coliform(MF) - CHT Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92592702001 METHOD BLANK: 3577641 Associated Lab Samples: 92592702001 Parameter Fecal Coliforms SAMPLE DUPLICATE: 3577642 Parameter Fecal Coliforms Matrix: Water Blank Reporting Units Result Limit Analyzed Qualifiers CFU/100 mL ND 1.0 03/11/22 15:16 92592783002 Dup Units Result Result RPD Qualifiers CFU/100 mL 864 870 1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/18/2022 10:35 AM without the written consent of Pace Analytical Services, LLC. Page 8 of 18 aceAnalytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: COMPOST CENTRAL 2 Pace Project No.: 92592702 QC Batch: 684317 Analysis Method: SM 2540D-2015 QC Batch Method: SM 254OD-2015 Analysis Description: 2540D Total Suspended Solids Laboratory: Pace Analytical Services - Asheville Associated Lab Samples: 92592702001 METHOD BLANK: 3579131 Associated Lab Samples: 92592702001 Parameter Units Total Suspended Solids mg/L LABORATORY CONTROL SAMPLE: 3579132 Parameter Units Total Suspended Solids mg/L SAMPLE DUPLICATE: 3579168 Parameter Units Total Suspended Solids mg/L Matrix: Water Blank Reporting Result Limit Analyzed Qualifiers ND 2.5 03/12/2210:54 Spike 1-CS LCS % Rec Conc. Result % Rec Limits Qualifiers 250 242 97 90-110 92592695001 Dup Result Result RPD Qualifiers ND ND SAMPLE DUPLICATE: 3579169 92592702001 Dup Parameter Units Result Result Total Suspended Solids mg/L 16.5 15.5 RPD Qualifiers 6 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/18/2022 10:35 AM without the written consent of Pace Analytical Services, LLC. Page 9 of 18 aceAnalytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: COMPOST CENTRAL 2 Pace Project No.: 92592702 QC Batch: 684852 Analysis Method: EPA 351.2 Rev 2.0 1993 QC Batch Method: EPA 351.2 Rev 2.0 1993 Analysis Description: 351.2 TKN Laboratory: Pace Analytical Services - Asheville Associated Lab Samples: 92592702001 METHOD BLANK: 3581258 Associated Lab Samples: 92592702001 Parameter Units Nitrogen, Kjeldahl, Total mg/L LABORATORY CONTROL SAMPLE: 3581259 Parameter Units Nitrogen, Kjeldahl, Total mg/L Matrix: Water Blank Reporting Result Limit Analyzed Qualifiers ND 0.50 03/16/22 04:33 Spike LCS LCS % Rec Cone. Result % Rec Limits Qualifiers 10 10.1 101 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3581260 3581261 MS MSD 92592711001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Cone. Cone. Result Result % Rec % Rec Limits RPD Qual Nitrogen, Kjeldahl, Total mg/L 2.0 10 10 12.0 10.9 100 89 90-110 10 M1 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3581262 3581263 MS MSD 92592715001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Cone. Cone. Result Result % Rec % Rec Limits RPD Qual Nitrogen, Kjeldahl, Total mg/L 3.3 10 10 12.4 12.2 91 89 90-110 2 M1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/18/2022 10:35 AM without the written consent of Pace Analytical Services, LLC. Page 10 of 18 aceAnalytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: COMPOST CENTRAL 2 Pace Project No.: 92592702 QC Batch: 685354 Analysis Method: EPA 353.2 Rev 2.0 1993 QC Batch Method: EPA 353.2 Rev 2.0 1993 Analysis Description: 353.2 Nitrate + Nitrite, preserved Laboratory: Pace Analytical Services - Asheville Associated Lab Samples: 92592702001 METHOD BLANK: 3583756 Associated Lab Samples: 92592702001 Parameter Units Nitrogen, NO2 plus NO3 mg/L LABORATORY CONTROL SAMPLE: 3583757 Parameter Units Nitrogen, NO2 plus NO3 mg/L Matrix: Water Blank Reporting Result Limit Analyzed Qualifiers ND 0.040 03/17/2211:55 Spike LCS LCS % Rec Cone. Result % Rec Limits Qualifiers 2.5 2.5 100 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3583758 3583759 MS MSD 92592702001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Cone. Cone. Result Result % Rec % Rec Limits RPD Qual Nitrogen, NO2 plus NO3 mg/L ND 2.5 2.5 2.3 2.3 92 91 90-110 2 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3583760 3583761 MS MSD 92592711001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Cone. Cone. Result Result % Rec % Rec Limits RPD Qual Nitrogen, NO2 plus NO3 mg/L 8.9 2.5 2.5 11.4 11.4 101 99 90-110 0 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/18/2022 10:35 AM without the written consent of Pace Analytical Services, LLC. Page 11 of 18 aceAnalytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: COMPOST CENTRAL 2 Pace Project No.: 92592702 QC Batch: 684424 Analysis Method: EPA 365.1 Rev 2.0 1993 QC Batch Method: EPA 365.1 Rev 2.0 1993 Analysis Description: 365.1 Phosphorus, Total Laboratory: Pace Analytical Services - Asheville Associated Lab Samples: 92592702001 METHOD BLANK: 3579449 Associated Lab Samples: 92592702001 Parameter Units Phosphorus mg/L LABORATORY CONTROL SAMPLE: 3579450 Parameter Units Phosphorus mg/L Matrix: Water Blank Reporting Result Limit Analyzed Qualifiers ND 0.050 03/15/2212:19 Spike 1-CS LCS % Rec Cone. Result % Rec Limits Qualifiers 2.5 2.5 100 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3579451 3579452 MS MSD 92591347001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Cone. Cone. Result Result % Rec % Rec Limits RPD Qual Phosphorus mg/L 3.0 2.5 2.5 6.0 5.5 118 100 90-110 8 M1 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3579453 3579454 MS MSD 92591359001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Cone. Cone. Result Result % Rec % Rec Limits RPD Qual Phosphorus mg/L 0.59 2.5 2.5 3.3 3.1 109 101 90-110 7 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/18/2022 10:35 AM without the written consent of Pace Analytical Services, LLC. Page 12 of 18 aceAnalytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: COMPOST CENTRAL 2 Pace Project No.: 92592702 QC Batch: 684686 Analysis Method: SM 5220D-2011 QC Batch Method: SM 5220D-2011 Analysis Description: 5220D COD Laboratory: Pace Analytical Services - Asheville Associated Lab Samples: 92592702001 METHOD BLANK: 3580585 Associated Lab Samples: 92592702001 Parameter Units Chemical Oxygen Demand mg/L LABORATORY CONTROL SAMPLE: 3580586 Parameter Units Chemical Oxygen Demand mg/L Matrix: Water Blank Reporting Result Limit Analyzed Qualifiers ND 25.0 03/15/22 05:50 Spike LCS LCS % Rec Cone. Result % Rec Limits Qualifiers 750 767 102 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3580587 3580588 MS MSD 92592269001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Cone. Cone. Result Result % Rec % Rec Limits RPD Qual Chemical Oxygen Demand mg/L 238 100 100 330 316 92 79 90-110 4 M1,R1 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3580589 3580590 MS MSD 92592273004 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Cone. Cone. Result Result % Rec % Rec Limits RPD Qual Chemical Oxygen Demand mg/L 27.2 100 100 134 138 106 111 90-110 3 M1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/18/2022 10:35 AM without the written consent of Pace Analytical Services, LLC. Page 13 of 18 aceAnalytical www.paeelabs.enm Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALIFIERS Project: COMPOST CENTRAL 2 Pace Project No.: 92592702 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis ofAcrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as "Total" may vary slightly from the sum of the reported component parameters. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. ANALYTE QUALIFIERS M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. R1 RPD value was outside control limits. u2 Colonies are too numerous to count. Actual result may be greater than reported. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/18/2022 10:35 AM without the written consent of Pace Analytical Services, LLC. Page 14 of 18 aceAnalytical www.paeelabs.enm Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Pace Project No.: COMPOST CENTRAL 2 92592702 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92592702001 OUTFALL 1 EPA 1664B 683979 92592702001 OUTFALL 1 EPA 1664B 683981 92592702001 OUTFALL 1 EPA 200.7 684173 EPA 200.7 684244 92592702001 OUTFALL 1 SM 9222D-2015 683991 SM 9222D-2015 683992 92592702001 OUTFALL 1 SM 254OD-2015 684317 92592702001 OUTFALL 1 TKN+NO3+NO2 685724 Calculation 92592702001 OUTFALL 1 EPA 351.2 Rev 2.0 1993 684852 EPA 351.2 Rev 2.0 1993 684991 92592702001 OUTFALL 1 EPA 353.2 Rev 2.0 1993 685354 92592702001 OUTFALL 1 EPA 365.1 Rev 2.0 1993 684424 EPA 365.1 Rev 2.0 1993 684721 92592702001 OUTFALL 1 SM 5220D-2011 684686 SM 5220D-2011 684696 Date: 03/18/2022 10:35 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 15 of 18 Document Name: Document Revised: November 1S, 2021 aceAndlyfrcal- Sample Condition Upon Receipt (SCUR) Page 1 of 2 Document No.: issuing Authority: F-CAR-CS-033-Rev.08 Pace Carolinas Quality Office Laboratory receiving samples: Asheville ❑ Eden[] Greenwood ❑ Huntersvilie` §% Raleigh❑ Mechanicsville❑ Atlanta❑ Kernersville❑ Sample Condition Client Name: II/ Pr ec #: rW011: 92592702 �. ff ,i Courier: Fed Ex ❑UPS ❑LISPS lent ❑ Commercial ❑Pace ❑Other: I 92592'102 Custody Seal present? [:]Yes❑N+' Seals Intact? []Yes\—PNo Date/Initla[s Person EMamining{ontents:AA- _31022, Packing Material: ❑Bubble Wrap ❑Bubble bags None ❑ Other Biological Tissue Frozen? Thermometer ❑ �I1A ©D Gun 10: �!7 1 i Type of Ire: (:]Wet t ❑Blue ❑None []Yes No Correction Factor: Cooler Temp: — Add/Subtract VC) U Temp should be above freezing to 6°C [--]Samples out of temp criteria. Samples on ice, cooling aracess USDA Regulated Soil (Jj XIA, water samples Did samples originate in a quarantine zone within the United States: CA, NY, or SC (check maps)? Old samples originate from a Foreign source (internationally, I1YPc FINn . ,.__ Comments/Discrepancy: u Chain of Custody Present? \ Yews ❑No El NIA 1. Samples Arrived within Hold Time? \ 5'es ❑"¢_[)NIA 2, Short Hold Time Analysis (c72 hr.)? Elves MN N/A 3. Rush Turn Around Time Requested? Yes No ❑N/A 4. Sufficient Volume? Yes [:]No ❑N/A S. Correct Containers Used? -Pace Containers Used? �01es ❑Yes ❑No ❑No ❑N/A ❑N/A 6. Containers Intact? �,❑�es CIND N/A 7. Dissolved analysis: Samples Field Filtered? []Yes oNo ,❑NJA 8. Sample Labels Match COC? -includesDate/Time/ID/Analysis Matrk: (fix s []No ❑N/A s. Headspace in VOA Vials >5.6mm)? ❑Yes ❑No alfA 10. Trip Blank Present? Trip Blank Custody Seals Present? ❑Yes []Yes ❑No ❑No '0N/A ri/A 11. COMMENTS/SAMPLE DISCREPANCY ' CLIENT NOTIFICATION/RESOLUTION Person contacted: Project Manager SCURF Review: Project Manager SRF Review: Lot ID of split conta1 Date/Time: Date: Date: Field Data Required? ❑Yes ❑No Page 16 of 18 Document Name: Document Revised: November 15, 2021 ., aCEAll8ijlCal. ' 11 Sample Condition on Receipt (SCt1R) Page 2 of 2 Document No.: Issuing Authority: F-CAR-CS-033-Rev-011 Pace Carolinas Quality Office *Check mark top half of box if pH and/or dechlorination is verified and within the acceptance range for preservation samples. fKceptl0n3: VOA, Coliform, TOC, Oil and Grease, DRO/8015 (water) DOC, LLHS *"Bottom halt of box is to list number of bottles Project# WN : 92592702 PM: MI4B Due Date: 03/17/22 CLIENT: 92-MECK CO 2 z y = u a z z Q u, [7 a = Z b Z ,gyp Z y N z _ rV ? A n M 0J p V v d rN-I A = a? 0 N U Z V V 2 E ? y o4i Z 'O Z Q) ° a V o � a = n Z 2 m a Y o Z z V1di v c c Z 4 0 � a � O N E ? � ° z � M o a u Y N y N Z c� a c O a a C 7 c C 2 = N Z y S Vi T x Q U N C Ln Y y l0 V U U E = Z .� N N 9 V N ZFL+ y N 9 o N n El E C+ a 0 ¢ O 4 Q d O} ¢ t y �o E = E J J J d J d E a Q 1 Q J N O CL N J J E J E Lnn E o E o a E E O E E M v v •-• a`, }• pOE c� - E P ran E E O E O 9 M •� E ,�yn E Ln E qq C E O E G Ln N .ve Ar1J ~ v1 N IV. O Y 4 m. v rl N ,n N �_ N - q rl N in .i N ,Ny N " vi —T �' G ac a c a E a— N o a r+ .� m .a m RI m ai M o G. 6 6 G. to 6 m 6 en 6 6 m a a a a a a a y >' a in v6i cca anm M 2 3 \N 4 5 6 . 7 8 NN 9 10 11 12 NN\1 PH Adjustment log for Preserved Samples Sample 1D Type of Preservative pH upon recelpt Date preservation adjusted Time preservarlbn adjusted Amaunt of Preservative added lot k Note: Whenever there is a discrepancy affecting North Carailna compliance samples, a copy of thlS form will a sent o the NOrAhLarclina Uh"NK Lertilication Utlice ii.e. Out of hold, incorrect preservative, out of temp incorrect containers, Page 17 of 18 d O Q v 0 ° J � m d � a N � N 3 m U � m @ � a C m � a E U O V v .0 A O y a Q 3 V W y f d > t Q � � m a m � v ¢ D F N Z � L � a C = U a U N C V C c v E E O W - 3 z v v a L r ra@ G G C C .. ] p` N N d 0 [�i 'o n d 6 n m u d E a m a 1 in C L o Q U Q 2 d a m O U c O W Z C V u a�@ U C = m ro E v y N O � C y 0 u 9 U @ O E a o0 7 E r � oa` m L 7 ` p F 00 N m Z i! v z 3 0 r v c Y1 fY u tr U d a` o. a� n cc > 0 cc N U > a ` O Q E L U U Z c a c c - C m W 0¢ U w a w 0 O F CJ o tT o ry U N J a a N (NIA) auuol43 lenplsaa 17991 Aq aseai0 pue 110 r OOOIsru0gds04d 1e1a1 11991 W3H-1EJS 14di !I00 )eaad aleJ)!u+N>lll ua80i1!N lelol ' slelayy dOl L'OOZ SSl >� NU ;sey sasd(euy ja410 pue4pvy LO EOZSZeN HOaN y Uf 10H 0- SON 4OSZH paniasaiduN 7< S4i3NIV1N00 d0 # I— N0110311001V dW31 3ldHV5 z_ uZi W E ti F H of F L (dHD0=0 SVH!)=Cl) 3dAl 37dWVS (42101 saR03 plleA aas) 3000 XR11M oir3 a r o❑33amoi�d0r L x L - aY� so`;;Sui'03do� W a o E N N y a �E s -I -1 H ml C-I 0"I O d a (NIA) loelul saldweS NET 'a100O paleas Apalsn-) (NIA) aal uo pan183aa � w diN�l ns Z S � w \r a �1 � W J rn E 2 d 4 4 x V) a o 0 W N LU E ro z z � 18 of 18 Environmental Quality Stormwater Discharge Outfall (SDO) Qualitative Monitoring Report For guidance on filling out this form, please visit https://deg.ne.gov/about/divisions/energy-mineral-land- resources/enere/y-mineral-land-permits/stormwater-permits/npdes-industrial-sw#tabb-41� j Permit No.: N/C/ ei '�//� �/ or Certificate of Coverage No.: N/C/G/`j$ Facility Name: !n"' l (fir✓ l/I ' O f C r6! p County: VIP C ICU b U—f-cg Phone Nb. (, / I t 6 rS V Inspector: 'A jnL Date of Inspection: ��p ! a b ,;� Time of Inspection: O� n( 0 Total Event Precipitation (inches): -, 6lv� All permits require qualitative monitoring to be performed during a "measurable storm event." A "measurable storm event" is a storm event that results in an actual discharge from the permitted site outfall. The previous measurable storm event must have been at least 72 hours prior. The 72-hour storm interval does not apply if the permittee is able to document that a shorter interval is representative for local storm events during the sampling period, and the permittee obtains approval from the local DEMLR Regional Office. By this signature, I certify that this report is accurate and complete to the best of my knowledge: (Signature of Permittee or Designee) 1. Outfall Description: (� Outfall No. I Structure i (p pe, ditch, etc.): Receiving Stream: Describe the industrial activities that occur within the outfall drainage area: Ve 1 CivY� cel Page 1 of 2 SWU-242, Last modified 07/28/2017 2. Color: Describe the color of (light, medium, dark) as descriptors: _ using basic colors (red, brown, blue, etc.) and tint 3. Odor: Describe a y distinct dos tha the ischarge ma have (i.e smells strongly of il, chlorine odor, etc.): ( � (D 4. Clarity: Choose the number which best describes the clarity of the discharge, where 1 is clear and 5 is very cloudy: 1 2 3 4 5 5. Floating Solids: Choose the number which best describes the amount of floating solids in the stormwater discharge, where 1 is no solids and 5 is the surface covered with floating solids: 1 2 3 4 5 6. Suspended Solids: Choose the number which best describes the amount of suspended solids in the stormwater discharge, where 1 is no solids and 5 is extremely muddy: 1 2 3 Pees 7. Is there any foam in the stonnwater discharge? O t4, 8. Is there an oil sheen in the stormwater discharge? OYes 9/ 1 9. Is there evidence of erosion or deposition at the outfall? O Yes 10. Other Obvious Indicators of Stormwater Pollution: List and describe N n 04U)-f M AU,, Note: Low clarity, high solids, and/or the presence of foam, oil sheen, or erosion/deposition may be indicative of pollutant exposure. These conditions warrant further investigation. Page 2 of 2 SWU-242, Last modified 07/28/2017