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HomeMy WebLinkAboutWQ0000485_Monitoring - 03-2022_20220413 (2) . may : DWR - NonDischarge Monitoring Report Submittal NORTH CAROLINA ErtNmnmerticl Quelffly Monitoring Report Submittal Permit Number#* WQ0000485 Name of Facility:* Valley Proteins Inc-Rose Hill Month:* March Year:* 2022 Report Information Type* Upload Document* GW-59 scan WQ0000485 GW-59 2.15MB part 1 2022-03 VPRH.pdf PDF Only GW-59 scan WQ0000485 GW-59 1.87MB part 2 2022-03 VPRH.pdf PDF Only Please upload one PDF containing all applicable monitoring reports (i.e., NDMR, NDAR-1, NDAR-2,NDMLR,GW-59). Confirmation Email Address:* clanier@valleyproteins.com Name of Submitter:* Corey Lanier Signature: Date of submittal: 4/13/2022 This will be filled in automatically Initial Review ........................................................................................................................................................................................................................................................................................................................................................................................................................................................................................ Reviewer: Gerald,Wanda Is the project number correct?* WQ0000485 Is the monitoring report accepted?* Yes No Regional Office* Wilmington Accepted Date: 4/25/2022 ANALYTICAL & CONSULTING CHEMISTS EnvironmentalChemists, Inc. 6602 Windmill Way, Wilmington, NC 28405 • 910.392.0223 Lab • 910.392.4424 Fax 710 Bowsertown Road, Manteo, NC 27954 • 252.473.5702 Lab/Fax 255-A Wilmington Highway, Jacksonville, NC 28540 • 910.347.5843 Lab/Fax info@environmentalchemists.com Valley Proteins - Rose Hill Date of Report: Mar 29, 2022 Post Office Box 1026 Customer PO #: Rose Hill NC 28458 Customer ID: 08100027 Attention: Corey Lanier Report #: 2022-04985 Project ID: Monitoring Wells Lab ID Sample ID: Collect Date/Time Matrix Sampled by 22-11991 Site: MW-11A 3/17/2022 11:15 AM Water jcb/envirochem Test Method Results Date Analyzed Color Color Clear 03/17/2022 Depth to water, ft. Depth to Water, Ft. 5.1 feet 03/17/2022 Sodium EPA 200.7, Rev 4.4, 1994 67.1 mg/L 03123/2022 Sulfate EPA 300.0, Rev. 2.1, 1993 166 mg/L 03121/2022 Ammonia Nitrogen EPA 350.1, Rev. 2.0, 1993 < 0.2 mg/L 03/23/2022 Gallons bailed before sampling Gallons Bailed before sampling 5.0 gallons 03/17/2022 Odor Qualitative None 03/17/2022 Total Dissolved Solids (TDS) SM 2540 C-2015 527 mg/L 03/18/2022 Temperature SM 2550 B-2010 15.0 C 03/17/2022 pH SM 4500 H B-2011 4.4 units 03/17/2022 Total Phosphorus SM 4500 P (F-H)-2011 < 0.04 mg/L 03/23/2022 Total Organic Carbon (TOC) SM 5310 B-2014 2.3 mg/L 03/21/2022 Fecal Coliform SM 9222 D-2015 MF <1 Colonies/100ml- 03/17/2022 Chloride SM4500 C! E-2011 133 mg/L 03/21 /2022 Nitrate Nitrogen (Calc) Nitrite Nitrogen EPA 353.2, Rev. 2.0, 1993 < 0.02 mg/L 03/17/2022 Nitrate+Nitrite-Nitrogen EPA 353.2, Rev. 2.0, 1993 0.64 mg/L 03/22/2022 Nitrate Nitrogen Subtraction Method 0.64 mg/L 03/24/2022 Total Nitrogen (Calc) Total Kjeldahl Nitrogen (TKN) EPA 351.2, Rev. 2.0, 1993 < 0.5 mg/L 03/23/2022 Total Nitrogen Total Nitrogen 0.6 mg/L 03/24/2022 Report #:: 2022-04985 Page 8 of 11 ANALYTICAL & CONSULTING CHEMISTS Environmentale is s, Inc. 6602 Windmill Way, Wilmington, NC 28405 • 910.392.0223 Lab • 910.392.4424 Fax 710 Bowsertown Road, Manteo, NC 27954 • 252.473.5702 Lab/Fax 255-A Wilmington Highway, Jacksonville, NC 28540 • 910.347.5843 Lab/Fax info Cenvironmentalchemis ts. com Valley Proteins - Rose Hill Date of Report: Mar 29, 2022 Post Office Box 1026 Customer PO #: Rose Hill NC 28458 Customer ID: 08100027 Attention: Corey Lanier Report M 2022-04985 Project ID: Monitoring Wells Lab ID Sample ID: Collect Date/Time Matrix Sampled by 22-11992 Site: MW-12B 3/17/2022 11:00 AM Water jcb/envirochem Test Method Results Date Analyzed Color Color Clear 03/17/2022 Depth to water, ft. Depth to Water, Ft. 6.4 feet 03/17/2022 Sodium EPA 200.7, Rev 4.4. 1994 94.8 mg/L 03/23/2022 Sulfate EPA 300.0, Rev. 2.1, 1993 169 mg/L 03/21/2022 Ammonia Nitrogen EPA 350.1, Rev. 2.0, 1993 < 0.2 mg/L 03/23/2022 Gallons bailed before sampling Gallons Bailed before sampling 5.0 gallons 03/17/2022 Odor Qualitative None 03/17/2022 Total Dissolved Solids (TDS) SM 2540 C-2015 460 mg/L 03/18/2022 Temperature SM 2550 B-2010 15.0 C 03/17/2022 pH SM 4500 H B-2011 4.2 units 03/17/2022 Total Phosphorus SM 4500 P (F-H)-2011 < 0.04 mg/L 03/23/2022 Total Organic Carbon (TOC) SM 5310 B-2014 1.9 mg/L 03/21/2022 Fecal Coliform SM 9222 D-2015 MF <1 Colonies/100ml- 03/17/2022 Chloride SM4500 Cl E-2011 132 mg/L 03/21/2022 Nitrate Nitrogen (Calc) Nitrite Nitrogen EPA 353.2, Rev. 2.0, 1993 < 0.02 mg/L 03/17/2022 Nitrate+Nitrite-Nitrogen EPA 353.2, Rev. 2.0, 1993 0.10 mg/L 03/22/2022 Nitrate Nitrogen Subtraction Method 0.10 mg/L 03/24/2022 Total Nitrogen (Calc) Total Kjeldahl Nitrogen (TKN) EPA 351.2, Rev. 2.0, 1993 0.6 mg/L 03/23/2022 Total Nitrogen Total Nitrogen 0.7 mg/L 03/24/2022 Report #:: 2022-04985 Page 9 of 11 ANALYTICAL & CONSULTING CHEMISTS Environmental Chemists, Inc. 6602 Windmill Way, Wilmington, NC 28405 • 910.392.0223 Lab • 910.392.4424 Fax 710 Bowsertown Road, Manteo, NC 27954 • 252.473.5702 Lab/Fax 255-A Wilmington Highway, Jacksonville, NC 28540 • 910.347.5843 Lab/Fax info@environmentalchemists.com Valley Proteins - Rose Hill Date of Report: Mar 29, 2022 Post Office Box 1026 Customer PO #: Rose Mill NC 28458 Customer ID: 08100027 Attention: Corey Lanier Report #: 2022-04985 Project ID: Monitoring Wells Lab ID Sample ID: Collect Date/Time Matrix Sampled by 22-11993 Site: MW-13A 3/17/2022 10:45 AM Water jcb/envirochem Test Method Results Date Analyzed Color Color Clear 03/17/2022 Depth to water, ft. Depth to Water, Ft. 6.0 feet 03/17/2022 Sodium EPA 200.7. Rev 4.4,1994 5.55 mg/L 03/23/2022 Sulfate EPA 300.0, Rev. 2.1, 1993 5 mg/L 03/21/2022 Ammonia Nitrogen EPA 350.1, Rev. 2.0,1993 < 0.2 mg/L 03/23/2022 Gallons bailed before sampling Gallons Bailed before sampling 5.0 gallons 03/17/2022 Odor Qualitative None 03/17/2022 Total Dissolved Solids (TDS) SM 2540 C-2015 25 mg/L 03/18/2022 Temperature SM 2550 B-2010 15.9 C 03/17/2022 pH SM 4500 H B-2011 4.7 units 03/17/2022 Total Phosphorus SM 4500 P (F-H)-2011 < 0.04 mg/L 03/23/2022 Total Organic Carbon (TOC) SM 5310 B-2014 <0.5 mg/L 03/21/2022 Fecal Coliform SM 92M D-2015 MF <1 Colonies/100ml- 03/17/2022 Chloride SM4500 Cl E-2011 7 mg/L 03/21/2022 Nitrate Nitrogen (Cale) Nitrite Nitrogen EPA 353.2, Rev. 2.0, 1993 0.06 mg/L 03/17/2022 Nitrate+Nitrite-Nitrogen EPA353.2, Rev. 2.0, 1993 0.05 mg/L 03/22/2022 Nitrate Nitrogen Subtraction Method <0.02 mg/L 03/24/2022 Total Nitrogen (Cale) Total Kjeldahl Nitrogen (TKN) EPA 351.2, Rev. 2.0, 1993 < 0.5 mg/L 03/23/2022 Total Nitrogen Total Nitrogen <0.5 mg/L 03/24/2022 Report #:: 2022-04985 Page 10 of 11 Valley Proteins - Rose Hill Date of Report: Mar 29, 2022 Post Office Box 1026 Customer PO #: Rose Hill NC 28458 Customer ID: 08100027 Attention: Corey Lanier Report #: 2022-04985 Project ID: Monitoring Wells Lab ID Sample ID: Collect Date/Time Matrix Sampled by 22-11994 Site: MW-14A 3/17/2022 12:45 PM Water jcb/envirochem Test Method Results Date Analyzed Color color Clear/Tan 03/17/2022 Depth to water, ft. Depth to water, Ft 3.9 feet 03/17/2022 Sodium EPA 200.7, Rev 4 4. 1994 113mg/L 03/23/2022 Sulfate EPA 300.0, Rev 2 1, 1993 277 mg/L 03/21/2022 Ammonia Nitrogen EPA 350.1, Rev. 20, 1993 < 0.2 mg/L 03/23/2022 Gallons bailed before sampling Gallons Balled before sampling 5.0 gallons 03/17/2022 Odor Qualitative None 03/17/2022 Total Dissolved Solids (TDS) SM 2540 C-2015 1100 mg/L 03/18/2022 Temperature SM 2550 8-2010 16.8 C 03/17/2022 pH SM 4500 H B-2011 5.2 units 03/17/2022 Total Phosphorus SM 4500 P (F-H)-2011 < 0.04 mg/L 03/23/2022 Total Organic Carbon (TOC) SM 5310 B-2014 3.6 mg/L 03/21/2022 Fecal Coliform SM 9222 D-2015 MF <1 Colonies/100ml- 03/17/2022 Chloride SM4500 Cl E-2011 325 mg/L 03/21/2022 Nitrate Nitrogen (Calc) Nitrite Nitrogen EPA 353.2, Rev. 2 0,1993 < 0.02 mg/L 03/17/2022 Nitrate+Nitrite-Nitrogen EPA 353.2, Rev. 2.0,1993 0.46 mg/L 03/22/2022 Nitrate Nitrogen Subtraction Method 0.46 mg/L 03/24/2022 Total Nitrogen (Calc) Total Kjeldahl Nitrogen (TKN) EPA 351.2, Rev. 2.0, 1993 < 0.5 mg/L 03/23/2022 Total Nitrogen Total Nitrogen <0.5 mg/L 03/24/2022 Comment: Reviewed by: f Report #.: 2022-04985 Page 11 of 11 Date. _. —1 Analyst:, Jay Baker Calibration Time Cal Buffer 4 0 s u. Cal Cerlificatluti # �t Facility Name: ,_,i (61-157'1 c) _ � Permit N• F I PH Reference Mcihud: SM4500 H+B -2011 10.0 s.u. I Check Buffer SD 00 10,DI 7.03 *pH check buffer must read within t 0, 1 pH units of the buffer's true value. 4 su buffer Lot#/ Ricca 4112969 E°Sj 1_M 7 su buffer Lotlli. Ricca 211 ZA38 Exn, 12/23 Insirument Comments 10 su buffer Lot#: RICCA'2112750 W, 3 ._ Sample location Sample Collection Time• Sample Analysis Time♦ pH Result s.0 ►Post -analysis Buffer Check value s u. Comments/Data Qualifiers +M yJ 1l'•3S GID •oo I coL �.. _. ln,l r ►3�,►5 I � I l0 lk 5 5 ► post analysis culler crteca is required wnen periomting analyses at munipie sampnng locations ana must oe wunin S v. i units of the nulici Z, true vaawc All pH values in pH units (i.e., s.u.). Record all data to the nearest 0.01 s.u. and report to the nearesl0.1 s.u. Total Residual Chlorine (TRC) Reference Method. SM 4500 CI-Cr'?011: Hach 8167 HR: Please circle applicable Metliod Post -analysis... .. _� Daily Check Time check Sample Sample Check Std. Sample TRC Result Standard Result Standard Collection Analysis (when analyzing Location µg/L or mg/L µg/L or mg/L ,,- , Analyzed Time Time Comments/Data Qualifiers TRC Daily, Check Standard true value pt:g11, or mg/L acceptance range, 1ig/L or mg/L. Check standards must recover within u:10% of the cheek standard's true value Annual Calibration Curve Verification Date: _ LOT # v1DEXX 2109792 Exp. Date: 0 /31/22 Reagent Blank Value: (When applicable. Analyze and document a reagent blank when standards, sample dilutions or PT Samples are prepared) Dissolved Oxygen (DO) Reference Method:SM 4500 O 0,-201 1 Instrument 0: Calibration variable •Post -analysis calibration Calibration/ Meter reading verification (when necessary) Verification or % efficiency Comments Time Barometric after calibration Theoretical Calculated Temperature pressure Value me11 Value mPJL f I I I I I I Use this row when performing a verification Instead of Sample Collection 'Sample Analysis DO reeding Semple Location Time Time m L Comments/Data Qualifiers • When performing analyses at multiple locations, the meter must be recalibrated at each site before analysis or a post -analysis calibration verification must be performed If sample is measured directly in the stream and/or onsite, only time analyzed would be recorded with a note that they are measured in situ or immediately Temperature etA icon i _tinin c nuemnr r Sample Location Mom- 1 Sample Collection Time I-L •Sample Analysis Time IZ'•31 Temperature °C 1-7•a Comments/Data Qualifiers (v3 2 12:I0 FT HV4-H 1 I'• 3S 1I.3b 15 I- 1­1 Vj --1P- 1 13"v lot 13 15 13 ►� l�i� w llsample is rneasured n.ireell In the Stream andor on site, only time anaiyzeu wnum tie rvcw LJt1U„ witn a nutc create i,cio-:y aic i11CLLbUJ° nr bit" m ur a ova-14P Annual Verification Date _ � Z� Field Personnel Note: QA.001 Rev 1-2022 Z rtificatinn # 04 Date: I J Facllity Name: � /"t;, I I t VT-w" T o hs Analyst: Jav Baker Permit It: '. Reference Metho& SM4500 H+B -2011 Instrument ID: Calibration Time Cal Buffer 4.0 s u. Cal Buffer 10.0 s.u. Check Buffer 7.0 s.u. Comments *pH check buffer must read within t 0.1 pH units of the buffer's true value. 4 su buffer Lot#/-. _dticca 4U1J09 7 su buffer Lot#/: a2 i8 u . J 2/2 10 su buffer Lot4:, � It t„ 1 B275Q 5Q3 Sample location Sample Collection Sample Analysis pH Result No -Post -analysis Buffer CommenLs/Deta Qualifiers Time• Time* s.0 Check value s u 11,1 W- d I'A- 1030 I o 32 ,Ioo ''I 11I �- 4.. w- z3 l °C i �d� I�..___......._ L+v� _...... "v�- I3 Pr 1b' -F5 1 10'.4(,, 1 4' ::w 1p-'Post analysis buffer check is required when performing analyses at multiple sampling locations and must be within f 0 1 units of the buffer's true value All pH values in pH units (i.e., sm.). Record all data to the nearest 0.01 s.u. and report to the nearest 0.1 s u Reference Method: SM 4500 CI-G2011: Daily Check Post -analysis Time check Check Std. Standard Result (when analyzing Standard µg/L or mg/L at multiple sites) Analyzed Total Residual Chlorine (TRC) Hach 8167 HR f Please circle amiscable Method Sample Sample Sample, TRC Result Collection V Analysis Location Time Time µg1L or mglL Instrnmcnt ID Comments/Data Qualifiers TRC Daily Check Standard true value µg/L or mg/L acceptance range a.--., µg/t. or nag/L Check standards must recover within t10%of the check standard's true value Annual Calibration Curve Verification Date: _ w_ w_ LOT # -IDEXX 210 792 Exp. Date: 18/31/2" Reagent Blank Value: When applicable. Analyze and document a reagent blank when standards, sample dilutions or PT Samples are prepared) Dissolved Oxygen (DO) Reference Method:SM 4,500 O G: 201 l Insiniment 113; Calibration/ Calibration variable Meter reading •Post -analysis calibration verification (when necessary) Verification I or % efficiency Comments Time Barometric after calibration Theoretical Calculated Temperature pressure Value melt Value mFVL Use this row when performing a verification instead of Sample Collection *Sample Analysis DO reading Sample Location Time Time m Comments/Data Qualifiers • When performing analyses at multiple locations, the meter must be recalibrated at each site before analysis or a post -analysis calibration verification must be performed * If sample is measured directly in the stream and/or onsite, only time analyzed would be recorded with a note that they are measured in situ or immediately Temperature Reference Mciho& ISM 2550 B-2010 Instrument 11d; Sample 'Sample Temperature Sample Location Collection Analysis °C Comments/Data Qualifiers Time Time VIj-G III _I I1 L+'D wV - I C)A- I D v 0 I D 3-2— 1+-;- 11✓1 v\J —1 1 A ills 11 1-7 IS-0 VA-la3 11:Dv D2, 15,D 1v4-13MY IC)LVS 10`'- I5-01 * I (sample is measured d'irecA°y in the stream and/or on site, only time analyzed would he recorded, with a note that they are measured in situ or irmnediately Annual Verification Date - ` 2 Field PersonnelNote: QA.001 Rev 1-2022 Date: — t / %^7), Analyst: Jav Baker C'tdficatian# 94 Facility Name: v. Y f u f� r crf� Permit #: ICN F I L F _ PH Reference Method: SM4500 H+.B -201 1 Calibration Time Cal Buffer 4 0 s u. Cal Buffer 10.0 s.u. Check Buffer 7.0 s.0 rj q,00 r7, 0 3 L •pH check buffer must read within t 0.1 pH units of the buffer's true value, 4 su buffer Lot k _Ricca 4112969 Exp 11r22 7 su buffer Lot#/: Ricca 211.2A38 rxp,_12/ Sample location Sample Collection Sample AnalysisEpHesult No -Post -analysis Buffer Time♦ Time• u Check value s.u, w 1, n —i 11 n I 3 -..a n r I, ... — IC "1 Instrument. ID Comments 10 su buffer LoW: RICCA 2 t I2 SfD Exn. S123.. Comments/Data Qualifiers No. Post analysis buffer check is required when perforating analyses at multiple sampling locations and must be within ± 0 1 units of the buffer's true value All pH values in pH units (i.e., s.u.). Record all data to the nearest 0.01 s.u, and report to the nearest 0.1 s.u. Total Residual Chlorine (TRC) Rcfercncc Method: SM 4500 CI-G'201 I Hach $1671iR; ( Please circle Hoolicable Method Instrument ID: Daily Check Post -analysis Trme check Semple Sample Check Std. Sample TRC Result Standard Result Standard Collection Analysis Comments/Data Qualifiers pg/L or mg/L (when analyzing Analyzed Location Time Time pR/L or mg/L at multiple sites) TRC" DaOly Check. Standard true value µg;/L or mg/L acceptance range µg/L or mg/L Check standards must recover within t 10% of the check standard's true value Annual Calibration Curve Verification Date: _ LOT # jDEXX 210Q19 _, Exp. Date, 08/31 /2 Reagent Blank Value: (When applicable. Analyze and document a reagent blank when standards, sample dilutions or PT Samples are prepared) Dissolved Oxygen (DO) Reference Ivlethod SM 4500 O G,-201 I Instrument ID: on Calibration/ Calibration variable Meter reading • Posttion (when necessary Verification verification (when necessary) Verification or %efficiency Comments Time Barometric after calibration Theorelical Calculated Temperature nressure Value me/L Value me/L Use this row when performing a verification instead of Sample Collection •Sample Analysis DO reading Sample Location Time Time Corn antslData Qualifiers m L sis on verification • If sample ishen orming measuredalyses at multiple directly n the streamtand/orh nsiteee only time r must be recalibrated at each site before analysis or a analy ed would be recorded with a note thatt they arelymeasur d in situ or immediately be performed. Temperature Reference Mcthot%: SM 255'0 B•2910 bisirumem ID: Sample 'Sample Temperature Sample Location Collection Analysis °C Comments/Data Qualifiers Time Time hA,-I-IL�fk IT-gS _ I ZA-1 1 t,,.£S _. I If sample is measured directly in the stream and/or on sire, only time analyzed would be recorded„ with a note that they are measured in situ or Annual Verification Date — - Field Personnel Note: Rev 1-2022 QA.001 Environmental Chemist, Inc., Wilmington, NC Lab #94 6602 Windmill Way Wilmington, NC 28405 910.392.0223 Sample Receipt Checklist Date: Report Number:AL_» Receipt of sample: ECHEM Pickup Client Delivery ❑ UPS ❑ FedEx ❑Other ❑ ❑ YES JE3 NO N/A 1. Were custody seals present on the cooler? ❑ YES ❑ NO N/A 2. If custtady seals were present, were they intact/unbroken? Original temperature upon receipt "C Corrected temperature upon receipt How temperature taken: ❑ Temperature Blank ❑ Against Bottles IR Gun ID: Thomas Traceable S/N 192511657 IR Gun Correction Factor "C: 0.0 ❑ YES 10 NO 3. If temperature of cooler exceeded 6*C, was Project Mgr./QA notified? YES ❑ NO 4. Were proper custody procedures (rellnquished/received) followed? JX YES ❑ NO 5. Were sample ID's listed on the COC? YES ❑ NO 6. Were samples ID's listed on sample containers? YES ❑ NO 7. Were collection date and time listed on the COC? YES ❑ NO 8. Were tests to be performed listed on the COC? m YES M NO 9. Did samples arrive in proper containers for each test? IQ YES ❑ NO 10. Did samptles arrive in ,good condition for each test? YES ❑ NO 11. Was adequate sample volume available?' YES ❑ NO 12. Were samples received within proper holding time for requested tests? YE5 ❑ NO 13. Were acid preserved samples received at a pH of <2? YES ❑ NO 14. Were cyanide samples received at a pH >12? ❑' YES ❑ NO 15. Were sulfide samples received at a pH >9?91 _,... YES ❑ NO 16. Were NH3/TKN/Phenol received at a chlorine residual of <0.5 m/L? ** YES ❑ NO 17. Were Sulfide/Cyanide received at a chlorine residual of <0.5 m/L? YES 10 NO 18. Were orthophosphate samples filtered in the field within 15 minutes? TOC/Volatiles are pH checked at time of analysis and recorded on the benchsheet. ** Bacteria samples are checked for Chlorine at time of analysis and recorded on the benchsheet. Sample Preservation: (Must be completed for any sample(s) incorrectly preserved or with headspace) Sample(s) - were received incorrectly preserved and were adjusted accordingly by adding (circle one): H2SO4 HNO3 HCI NaOH Time of preservation: If more than one preservative is needed, notate in comments below rote: Notify customer service immediately for incorrectly preserved samples. Obtain a new sample or notify the state lab if directed to analyzed by the customer. Who was notified, date and time: Volatiles Sample(s) were received with headspace L.UNI V.tNi5: DOC. QA.002 Rev 1 Ell 6 N o 0 0 CL 2 N o ° o s sy n v o �_ CL m m FA .� _ / w � N 7 C ci O CL r �' W Sample Type Composite or G) G Grab Container (P or G) v Chlorine mglL LAB ID NUMBER �( NONE HCL *9 �(.... X x H2SO4 M �( HNO3 NAOH CL X TRIO m OTHER 0 0 m W 0 0 n i n w,. 01 W d• fV dr 0 2 0 M o "' ° a 3 —I d a Q �, �� DCD r 7 z 0 fn e 7t1 0 u N c IT! o n c ap c m _— co v 0 P m 1 z z v 0 2 a z 0 TI 0 C rA 0 v MI z 0 0 m z' 0 A n m T a O z A z 0 v x cn t7 N 0 m M �_ O z a v N V N 10 w 0 T o 'rl N Q@m:� �. w a 3 P om N w 3 5y 3 30 i o 0 ca , O o n, O C_ M CD 3 � � v 1 M wp�gc f z M 0 C• ua W cm a i o CL 2 0 0 n�i ° c 0 0 ? 3 Q. Q Q w :E ID � � w I 7 C M 1 r /► tD 0 Sample Type Composite to G) 0 G) 0 G) 0 G) 0 G) 0 G) 0 G) 0 G) 0 G) 0 or V Grab �r m G) G) G) `0 G) G) G) G) G) G) nta iner Coto(P or G) m Chlorine II mglL I~ LAB ID NUMBER Im II M X NONE �( HCL 'D M 2 �( X H2SO4 m II HNO3 X C NAOH �( THIO z N OTHER O O ID go 3 m m 0 O n n v w !� Z C) z S O II < W O D o OM. CL m3 -, r 0 zcn N l �i co m CL V c m rn m O z M ti z 0 0 m i A n m T D z A z n 0 x o x N l7 t7 m 0 z V w . to z ME CD O � o 8 =� N (D m a 0 3 =ad N rf W 3 - �e � Cl N 0 N A o N o (D cO 3 CD fD ,`°=, a N W RCA CID CL 0 •a o n 2 G 0 9 0 0 CD ju O. Ncr O 'D r« EL .•r O a � v n v` 3 n fD F co a o c z (o vj 3 CL y b Sample Type a Composite G) 0 0 n G) 0 G) n O 0 G) n G) 0 G) n G) 0 or Grab r In Container (P or G) m v Chlorine II mg/L 3 M `D LAB ID NUMBER .�► m II l x NONE HCL TI c X �( H2SO4 N m u J HNO3 e) NAOH O N -I CL x THIO Z OTHER O O m v O O 0 C) w W N O II 0 < M c O �; 0 = CA)0 2: -, CL a Z a r r N r 7 Z (v/1 cc 11 IFy d K A CL ID n a M 3 m O to v m If R t'o CL CD 7 um o Y m 3 a c�D o _ 3 a o V cr .. n ..... 7 y......... _ ^._.. f' N\ W O �D O L M ML µc Sample Type Composite G) n G) 0 G) 0 G) 0 G) 0 G) 0 G) n G) 0 G) 0 or I Grab !� -o Container G) G) G) G) ,O G) G) G) (P or G) v Chlorine mg/L 3 CD ,,,. �... LAB ID �( NUMBER NONE HCL H2SO4 M IT) X HNO3 NAOH )( THIO •� OTHER z z O O d ON M YO O O 2 2: rn O w o y cr im Z r r CD o z y c IT! � (D v Doi 3 = o m O z -0 m O z O e P0 0 n S N ur Z n m z !D 0 m a O Z A 0 v _0 2 Vl v y n m n O Z 4& V J V N m 541, 0 CD 3 4c a N 5 m eD c f�D Z M o 0 C O a _ o g 10 CL (D ^ CD H -A'M � O1 O w � O ID ID w ,p 7 C � \ �f. 3 a 00 Sample Type G) C) G) n G) n G) n G) 0 G) n G) n G) n G) 0 Composite or Grab G) G) -0 G) 'O G) -0 G) -u G) -0 G) -0 G) -V G) - Container (P or G) v mChlorine mg/L N LAB ID NUMBER ! �( NONE HCL }( m, �( }( H2804 N m HNOJ A�( �? NAOH a4 CID� O a THIO Z OD OTHER O O m ID p p 0 n N W N O O 2 � m o °J ° Q m Z z CD 7 Z to M v 0 (� A c C t m 3 m �o v a s t' I' y o cp 0 CID C ,d.► oCL .0a)) CO)°° 87 m o � t ; m °1 a 0 1 10 V1 M (D w 3 ^ 3 „a w .e Sample Type compositeG70G)0G:0000000G)n0n0Ci or Grab 0 '0 G) -0 0 "0 Gi � Gi -0 G) '0 G) Container (P or G) v Chlorine mg1L fD c,0 LAB ID �( NUMBER NONE HCL 'D }( }( �( H2SO4 M �q Itl 91 HNO3 m NAOH' C CL III )( THIO IK OTHER 0_ 0 (D N 0 0 ii 0 pa) W N Z n Z S N O W O —I CL Z Q rD- 7 Z y cn �f Cn p e► f� � C k -^ m cn 3 m ce t7 1�V4 I ° S 0CD s a Q S FD } b a a to M � K ill _ 0 M so r CD n M 3 to 0 c � � a W *c Sample Type Composite 'tn � n� n� n� n� n� n'� 00 n� n or D 3 Grab 'm G) -0 G) -V G) 6i -u G) -o G) -0 Container (P or G) rn o Chlorine p mglL W LAB ID .m NUMBER 11 M )( NONE �( HCL T X �( X H2SO4 M 2' m 11 HNO3 C fD NAOH m 0 -I CL )( THIO Z' II W y OTHER '... Ie 0 N 0 0 (D o s ? n 0 W tea f�D p 0, Z 0 13 CL 3 �� 1p cn cn 6ai (n p IT! m � N O CP O z m O n m r a O z A z n v S 2 N v r to C� m d :0 a O z w v N �D N:, 0 cn 0 � OQ _ D OQ CD a H ! 1 I w"w"nr 0 C r 3 Sample i Type Composite 000000000000 T Grab G7 0Q Q Q Q Gi Container (P or G) O I Chlorine mg1L 3 LAB ID NUMBER )( NONE )r(.... HCL '.. i< X H2SO4 171 M A HNO3 NAOH Q., �( THIO Z WOTHER O Q (D Q Q 0 ci R CA) N 0 z 0 0 2 M a W 0 M. 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