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HomeMy WebLinkAboutNC0006254_ARO Groundwater Split Samples with Blue Ridge Tissue_20220301PO Number # Loc. Descr.:BLUE RIDGE TISSUE COPORATION; 1427 STAT ROAD 1560, LENOIR NC Loc. Type:Monitoring Well Collector:B LAVERTY Collect Date:03/01/2022 Collect Time:10:40 Date Received:03/03/2022 Time Received:08:20 Location ID:1P14BLUERIDGEMW1 County:Caldwell Region:Asheville Labworks LoginID TASCENZO1Sample Matrix:GROUNDWATER Report Print Date: North Carolina Division of Water Resources Water Sciences Section Laboratory Results VisitID Sample Depth AROReport To River Basin 04/21/2022 Emergency COC Yes/No Sample ID:AC95159 3/25/22Final Report Date: Final Report If this report is labeled preliminary report, the results have not been validated. Do not use for Regulatory purposes. NC CourierDelivery Method ROUTINEPriority Analysis Date Method Reference Result/ QualifierPQLAnalyte NameCAS #Units Validated by AC95159 LAB ESTAFFORD1°CSample temperature at receipt by lab 3/3/220.3 NUT EPA 350.1 REV 2 ALWILLIAMSmg/L as NNH3 as N in liquid7664-41-7 3/4/220.02 0.24 EPA 353.2 REV 2 ALWILLIAMSmg/L as NU,PNO2+NO3 as N in liquidE701177 3/4/220.2 0.20 EPA 365.1 REV 2 ALWILLIAMSmg/L as PPhosphorus_total as P in liquid7723-14-0 3/17/220.02 0.06 EPA 351.2 REV 2 ALWILLIAMSmg/L as NTotal Kjeldahl N as N in liquidTKN_N 3/16/220.3 0.42 MET EPA 200.8 Rev5.4 JJURGEVICHug/LUAs by ICPMS7440-38-2 3/9/222.0 2.0 EPA 200.7 Rev4.4 JJURGEVICHug/LBa by ICP7440-38-3 3/10/2210130 EPA 200.8 Rev5.4 JJURGEVICHug/LUCd by ICPMS7440-43-9 3/9/220.50 0.50 EPA 200.7 Rev4.4 JJURGEVICHug/LUCobalt by ICP7440-48-4 3/10/225050 EPA 200.8 Rev5.4 JJURGEVICHug/LUCr by ICPMS7440-47-3 3/9/225.0 5.0 EPA 200.8 Rev5.4 JJURGEVICHug/LUCu by ICPMS7440-50-8 3/9/222.0 2.0 EPA 200.7 Rev4.4 JJURGEVICHug/LFe by ICP7439-89-6 3/10/225014000 EPA 200.7 Rev4.4 JJURGEVICHug/LPMn by ICP7439-96-5 3/10/22202300 EPA 200.8 Rev5.4 JJURGEVICHug/LUNi by ICPMS7440-02-0 3/9/222.0 2.0 EPA 200.8 Rev5.4 JJURGEVICHug/LUPb by ICPMS7439-92-1 3/9/222.0 2.0 EPA 200.8 Rev5.4 JJURGEVICHug/LUZn by ICPMS7440-66-6 3/9/221010 WSS Chemistry Laboratory>> 1623 Mail Service Center, Raleigh, NC 27699-1623 (919) 733-3908 Page 1 of 1 "Not Detected" or "U" does not indicate the sample is analyte free but that the analyte is not detected at or above the PQL. PO Number # Loc. Descr.:BLUE RIDGE TISSUE CORPORATION; 1427 STATE RD 1560, LENOIR NC Loc. Type:Monitoring Well Collector:B LAVERTY Collect Date:03/01/2022 Collect Time:12:00 Date Received:03/03/2022 Time Received:08:20 Location ID:1P14BLUERIDGEMW8 County:Caldwell Region:Asheville Labworks LoginID TASCENZO1Sample Matrix:GROUNDWATER Report Print Date: North Carolina Division of Water Resources Water Sciences Section Laboratory Results VisitID Sample Depth AROReport To River Basin 04/21/2022 Emergency COC Yes/No Sample ID:AC95160 3/25/22Final Report Date: Final Report If this report is labeled preliminary report, the results have not been validated. Do not use for Regulatory purposes. NC CourierDelivery Method ROUTINEPriority Analysis Date Method Reference Result/ QualifierPQLAnalyte NameCAS #Units Validated by AC95160 LAB ESTAFFORD1°CSample temperature at receipt by lab 3/3/220.3 NUT EPA 350.1 REV 2 ALWILLIAMSmg/L as NUNH3 as N in liquid7664-41-7 3/4/220.02 0.02 EPA 353.2 REV 2 ALWILLIAMSmg/L as NPNO2+NO3 as N in liquidE701177 3/4/220.1 2.7 EPA 365.1 REV 2 ALWILLIAMSmg/L as PUPhosphorus_total as P in liquid7723-14-0 3/17/220.02 0.02 EPA 351.2 REV 2 ALWILLIAMSmg/L as NUTotal Kjeldahl N as N in liquidTKN_N 3/16/220.3 0.3 MET EPA 200.8 Rev5.4 JJURGEVICHug/LUAs by ICPMS7440-38-2 3/9/222.0 2.0 EPA 200.7 Rev4.4 JJURGEVICHug/LBa by ICP7440-38-3 3/10/221013 EPA 200.8 Rev5.4 JJURGEVICHug/LUCd by ICPMS7440-43-9 3/9/220.50 0.50 EPA 200.7 Rev4.4 JJURGEVICHug/LUCobalt by ICP7440-48-4 3/10/225050 EPA 200.8 Rev5.4 JJURGEVICHug/LUCr by ICPMS7440-47-3 3/9/225.0 5.0 EPA 200.8 Rev5.4 JJURGEVICHug/LUCu by ICPMS7440-50-8 3/9/222.0 2.0 EPA 200.7 Rev4.4 JJURGEVICHug/LUFe by ICP7439-89-6 3/10/225050 EPA 200.7 Rev4.4 JJURGEVICHug/LUMn by ICP7439-96-5 3/10/221010 EPA 200.8 Rev5.4 JJURGEVICHug/LUNi by ICPMS7440-02-0 3/9/222.0 2.0 EPA 200.8 Rev5.4 JJURGEVICHug/LUPb by ICPMS7439-92-1 3/9/222.0 2.0 EPA 200.8 Rev5.4 JJURGEVICHug/LUZn by ICPMS7440-66-6 3/9/221010 WSS Chemistry Laboratory>> 1623 Mail Service Center, Raleigh, NC 27699-1623 (919) 733-3908 Page 1 of 1 "Not Detected" or "U" does not indicate the sample is analyte free but that the analyte is not detected at or above the PQL. PO Number # Loc. Descr.:BLUE RIDGE TISSUE CORPOARTION Loc. Type:Monitoring Well Collector:B LAVERTY Collect Date:03/01/2022 Collect Time:12:43 Date Received:03/03/2022 Time Received:08:20 Location ID:1P14BLUERIDGEMW6 County:Caldwell Region:Asheville Labworks LoginID TASCENZO1Sample Matrix:GROUNDWATER Report Print Date: North Carolina Division of Water Resources Water Sciences Section Laboratory Results VisitID Sample Depth AROReport To River Basin 04/21/2022 Emergency COC Yes/No Sample ID:AC95161 3/25/22Final Report Date: Final Report If this report is labeled preliminary report, the results have not been validated. Do not use for Regulatory purposes. NC CourierDelivery Method ROUTINEPriority Analysis Date Method Reference Result/ QualifierPQLAnalyte NameCAS #Units Validated by AC95161 LAB ESTAFFORD1°CSample temperature at receipt by lab 3/3/220.3 NUT EPA 350.1 REV 2 ALWILLIAMSmg/L as NUNH3 as N in liquid7664-41-7 3/4/220.02 0.02 EPA 353.2 REV 2 ALWILLIAMSmg/L as NUNO2+NO3 as N in liquidE701177 3/4/220.02 0.02 EPA 365.1 REV 2 ALWILLIAMSmg/L as PUPhosphorus_total as P in liquid7723-14-0 3/17/220.02 0.02 EPA 351.2 REV 2 ALWILLIAMSmg/L as NUTotal Kjeldahl N as N in liquidTKN_N 3/16/220.3 0.3 MET EPA 200.8 Rev5.4 JJURGEVICHug/LUAs by ICPMS7440-38-2 3/9/222.0 2.0 EPA 200.7 Rev4.4 JJURGEVICHug/LBa by ICP7440-38-3 3/10/221077 EPA 200.8 Rev5.4 JJURGEVICHug/LUCd by ICPMS7440-43-9 3/9/220.50 0.50 EPA 200.7 Rev4.4 JJURGEVICHug/LUCobalt by ICP7440-48-4 3/10/225050 EPA 200.8 Rev5.4 JJURGEVICHug/LUCr by ICPMS7440-47-3 3/9/225.0 5.0 EPA 200.8 Rev5.4 JJURGEVICHug/LUCu by ICPMS7440-50-8 3/9/222.0 2.0 EPA 200.7 Rev4.4 JJURGEVICHug/LUFe by ICP7439-89-6 3/10/225050 EPA 200.7 Rev4.4 JJURGEVICHug/LMn by ICP7439-96-5 3/10/221017 EPA 200.8 Rev5.4 JJURGEVICHug/LUNi by ICPMS7440-02-0 3/9/222.0 2.0 EPA 200.8 Rev5.4 JJURGEVICHug/LUPb by ICPMS7439-92-1 3/9/222.0 2.0 EPA 200.8 Rev5.4 JJURGEVICHug/LUZn by ICPMS7440-66-6 3/9/221010 WSS Chemistry Laboratory>> 1623 Mail Service Center, Raleigh, NC 27699-1623 (919) 733-3908 Page 1 of 1 "Not Detected" or "U" does not indicate the sample is analyte free but that the analyte is not detected at or above the PQL. PO Number # Loc. Descr.:BLUE RIDGE TISSUE CORPORATION; 1427 STATE RD 1560, LENOIR NC Loc. Type:Monitoring Well Collector:B LAVERTY Collect Date:03/01/2022 Collect Time:13:16 Date Received:03/03/2022 Time Received:08:20 Location ID:1P14BLUERIDGEMW7 County:Caldwell Region:Asheville Labworks LoginID TASCENZO1Sample Matrix:GROUNDWATER Report Print Date: North Carolina Division of Water Resources Water Sciences Section Laboratory Results VisitID Sample Depth AROReport To River Basin 04/21/2022 Emergency COC Yes/No Sample ID:AC95162 3/25/22Final Report Date: Final Report If this report is labeled preliminary report, the results have not been validated. Do not use for Regulatory purposes. NC CourierDelivery Method ROUTINEPriority Analysis Date Method Reference Result/ QualifierPQLAnalyte NameCAS #Units Validated by AC95162 LAB ESTAFFORD1°CSample temperature at receipt by lab 3/3/220.3 NUT EPA 350.1 REV 2 ALWILLIAMSmg/L as NUNH3 as N in liquid7664-41-7 3/4/220.02 0.02 EPA 353.2 REV 2 ALWILLIAMSmg/L as NNO2+NO3 as N in liquidE701177 3/4/220.02 0.96 EPA 365.1 REV 2 ALWILLIAMSmg/L as PPhosphorus_total as P in liquid7723-14-0 3/17/220.02 0.04 EPA 351.2 REV 2 ALWILLIAMSmg/L as NUTotal Kjeldahl N as N in liquidTKN_N 3/16/220.3 0.3 MET EPA 200.8 Rev5.4 JJURGEVICHug/LUAs by ICPMS7440-38-2 3/9/222.0 2.0 EPA 200.7 Rev4.4 JJURGEVICHug/LBa by ICP7440-38-3 3/10/221058 EPA 200.8 Rev5.4 JJURGEVICHug/LUCd by ICPMS7440-43-9 3/9/220.50 0.50 EPA 200.7 Rev4.4 JJURGEVICHug/LUCobalt by ICP7440-48-4 3/10/225050 EPA 200.8 Rev5.4 JJURGEVICHug/LUCr by ICPMS7440-47-3 3/9/225.0 5.0 EPA 200.8 Rev5.4 JJURGEVICHug/LUCu by ICPMS7440-50-8 3/9/222.0 2.0 EPA 200.7 Rev4.4 JJURGEVICHug/LUFe by ICP7439-89-6 3/10/225050 EPA 200.7 Rev4.4 JJURGEVICHug/LUMn by ICP7439-96-5 3/10/221010 EPA 200.8 Rev5.4 JJURGEVICHug/LUNi by ICPMS7440-02-0 3/9/222.0 2.0 EPA 200.8 Rev5.4 JJURGEVICHug/LUPb by ICPMS7439-92-1 3/9/222.0 2.0 EPA 200.8 Rev5.4 JJURGEVICHug/LUZn by ICPMS7440-66-6 3/9/221010 WSS Chemistry Laboratory>> 1623 Mail Service Center, Raleigh, NC 27699-1623 (919) 733-3908 Page 1 of 1 "Not Detected" or "U" does not indicate the sample is analyte free but that the analyte is not detected at or above the PQL. PO Number # Loc. Descr.:BLUE RIDGE TISSUE COPORATION; 1427 STAT ROAD 1560, LENOIR NC Loc. Type:Monitoring Well Collector:B LAVERTY Collect Date:03/01/2022 Collect Time:14:06 Date Received:03/03/2022 Time Received:08:20 Location ID:1P14BLUERIDGEMW4 County:Caldwell Region:Asheville Labworks LoginID TASCENZO1Sample Matrix:GROUNDWATER Report Print Date: North Carolina Division of Water Resources Water Sciences Section Laboratory Results VisitID Sample Depth AROReport To River Basin 04/21/2022 Emergency COC Yes/No Sample ID:AC95163 3/31/22Final Report Date: Final Report If this report is labeled preliminary report, the results have not been validated. Do not use for Regulatory purposes. NC CourierDelivery Method ROUTINEPriority Analysis Date Method Reference Result/ QualifierPQLAnalyte NameCAS #Units Validated by AC95163 LAB ESTAFFORD1°CSample temperature at receipt by lab 3/3/220.3 NUT EPA 350.1 REV 2 ALWILLIAMSmg/L as NNH3 as N in liquid7664-41-7 3/4/220.02 1.0 EPA 353.2 REV 2 ALWILLIAMSmg/L as NPNO2+NO3 as N in liquidE701177 3/4/220.1 2.7 EPA 365.1 REV 2 ALWILLIAMSmg/L as PPhosphorus_total as P in liquid7723-14-0 3/23/220.02 0.08 EPA 351.2 REV 2 ALWILLIAMSmg/L as NTotal Kjeldahl N as N in liquidTKN_N 3/22/220.3 1.7 MET EPA 200.8 Rev5.4 JJURGEVICHug/LUAs by ICPMS7440-38-2 3/9/222.0 2.0 EPA 200.7 Rev4.4 JJURGEVICHug/LBa by ICP7440-38-3 3/10/2210150 EPA 200.8 Rev5.4 JJURGEVICHug/LUCd by ICPMS7440-43-9 3/9/220.50 0.50 EPA 200.7 Rev4.4 JJURGEVICHug/LUCobalt by ICP7440-48-4 3/10/225050 EPA 200.8 Rev5.4 JJURGEVICHug/LUCr by ICPMS7440-47-3 3/9/225.0 5.0 EPA 200.8 Rev5.4 JJURGEVICHug/LUCu by ICPMS7440-50-8 3/9/222.0 2.0 EPA 200.7 Rev4.4 JJURGEVICHug/LFe by ICP7439-89-6 3/10/22501300 EPA 200.7 Rev4.4 JJURGEVICHug/LMn by ICP7439-96-5 3/10/22101000 EPA 200.8 Rev5.4 JJURGEVICHug/LNi by ICPMS7440-02-0 3/9/222.0 2.6 EPA 200.8 Rev5.4 JJURGEVICHug/LUPb by ICPMS7439-92-1 3/9/222.0 2.0 EPA 200.8 Rev5.4 JJURGEVICHug/LZn by ICPMS7440-66-6 3/9/221011 WSS Chemistry Laboratory>> 1623 Mail Service Center, Raleigh, NC 27699-1623 (919) 733-3908 Page 1 of 1 "Not Detected" or "U" does not indicate the sample is analyte free but that the analyte is not detected at or above the PQL. PO Number # Loc. Descr.:YADKIN RIVER AT WHISNANT ROAD Loc. Type:River/Stream Collector:B LAVERTY Collect Date:03/01/2022 Collect Time:14:27 Date Received:03/03/2022 Time Received:08:20 Location ID:1P14YADKIN County:Caldwell Region:Asheville Labworks LoginID TASCENZO1Sample Matrix:SURFACEWATER Report Print Date: North Carolina Division of Water Resources Water Sciences Section Laboratory Results VisitID Sample Depth AROReport To River Basin 04/21/2022 Emergency COC Yes/No Sample ID:AC95164 3/31/22Final Report Date: Final Report If this report is labeled preliminary report, the results have not been validated. Do not use for Regulatory purposes. NC CourierDelivery Method ROUTINEPriority Analysis Date Method Reference Result/ QualifierPQLAnalyte NameCAS #Units Validated by AC95164 LAB ESTAFFORD1°CSample temperature at receipt by lab 3/3/220.3 NUT EPA 350.1 REV 2 ALWILLIAMSmg/L as NUNH3 as N in liquid7664-41-7 3/4/220.02 0.02 EPA 353.2 REV 2 ALWILLIAMSmg/L as NNO2+NO3 as N in liquidE701177 3/4/220.02 0.18 EPA 365.1 REV 2 ALWILLIAMSmg/L as PUPhosphorus_total as P in liquid7723-14-0 3/23/220.02 0.02 EPA 351.2 REV 2 ALWILLIAMSmg/L as NUTotal Kjeldahl N as N in liquidTKN_N 3/16/220.3 0.3 WSS Chemistry Laboratory>> 1623 Mail Service Center, Raleigh, NC 27699-1623 (919) 733-3908 Page 1 of 1 "Not Detected" or "U" does not indicate the sample is analyte free but that the analyte is not detected at or above the PQL. X X X X Thallium (Tl) Tin (Sn) X Titanium (Ti) X Vanadium (V) X Zinc (Zn) X Mercury 1631, low-level X X X X X X X X X X X Phytoplankton / Algae Composite Grab De-chlorinated in Field ChlorinatedSampling Method: Other:Dissolved analysis: Enter "DIS" in check-boxes for parameters Sample Depth: Lab Comments: Sodium (Na)E Cyanotoxins: C - L A Organochlorine Pesticides Organonitrogen Pesticides Organophosphorus Pesticides Blue Ridge Tissue - 1427 Yadkin River Road Lenoir, NCLocation Description: DWR Region: (based on county) River Basin: Surface Ground Water SupplyFoam Other: Metals Parameters: E E E E E E PCBs (polychlorinated biphenyls) Semi-Volatile Organics (BNAs) E E ECalcium (Ca) Chromium (Cr), Total Tag ID Visit ID: (optional) Laboratory Sample Number: Collector: DWR Office: (or agency name) Date (m/d/y): (begin/end) MW-1 1 Priority: Ambient Location Code:1P14BLUERIDGEMW1 Brett Laverty Location Type: Monitoring Well Trip Blank/ / Influent Filter Blank Lab Use Only: Time Received: (24 hr format) Date Received: M/D/Y : North Carolina Division of Water Resources Laboratory (Water Sciences Section)Water Sample Collection & Submittal Form Waste Blank Notes:Monitoring well MW-1 County:Caldwell Water Matrix: ARO Solution Routine Compliance COC Emergency QATime (24 hr): (begin/end)10:40 AM : 3/1/2022 Received By: Hand Delivered State Courier . Canal Stormwater LakeRiver/Stream Estuary Effluent Field Blank / / Lithium (Li)A - C A - C A - C E A - C Temperature on Arrival (°C): Delivery Method: Barium (Ba) Beryllium (Be) Cadmium (Cd) Copper (Cu) Iron (Fe) Lead (Pb) E E E E E E Other: E A - C Login file: Selenium (Se) Silver (Ag) Total Kjeldahl Nitrogen as N (TKN) TPH Diesel Range Boron (B) Hardness, Total as CaCO3 - by titration Acid Herbicides Molybdenum (Mo) Nickel (Ni) Secchi Depth: Lot #s / Collector Comments: Filtered in Field A - J A A A A Water Temp (oC):pH (s.u.):Conductivity (µmhos/cm): Microcystin Cobalt (Co) Oil and Grease, HEM, Total Recoverable TPH Gasoline Range A - D - MA - C - D Potassium (K) A - D A - D A A - Z E A A - I Preservative Organics Parameters: Dissolved Oxygen (ppm): Salinity (ppt): Nitrite as N (NO2-N) Total Phosphorus as P (TP) Nitrate as N (NO3-N calculated) A A Phenols, Total Recoverable Residue: Total (Total Solids ) Residue: Volatile/Fixed, Total Residue: Settleable Residue: Suspended (Suspended Solids ) Residue: Volatile/Fixed, Suspended TDS - Total Dissolved SolidsOrthophosphate as P (PO4) Ammonia as N (NH3-N) Nitrate-Nitrite as N (NO3+NO2-N) A A - D Arsenic (As) Color: Platinum Cobalt Preservative A Preservative E E E E E E E Preservative Alkalinity, as CaCO3, to pH 4.5/8.3 BOD: Biochemical Oxygen Demand, 5-day cBOD: Carbonaceous BOD, 5-day Coliform: Fecal MF Coliform: Total MF Nutrients Parameters: A - H - P COD: Chemical Oxygen Demand A A A A B - C B - C A A - G Fluoride Sulfate A A Hexavalent Chromium (Cr6+) MBAS (surfactants) A A - D A A Color: ADMI Cyanide, Total Specific Conductance, at 25 oC TOC - Total Organic Carbon Turbidity pH Bromide Chloride A Other Parameters: Microbiology Parameters:Wet Chemistry Parameters:Metals Parameters Con't: E E Aluminum (Al) Antimony (Sb) Chlorophyll a Field Parameters (optional): Preservative : Y Y A - C A - R Biological: E Silica Sulfide Perfluorinated Compounds (PFAS) Tannin & Lignin A - T A - C - F - LVolatile Organics (VOA) 1,4-Dioxane A - D A - C - F - L A - C Magnesium (Mg) E Manganese (Mn) Mercury (Hg) Strontium (Sr) Revision 6/10/2021Required: 1) Collector Initials and Date, 2) Circle each preservative option utilized next to each parameter. Preservative Legend (circle above as needed): (A) cool ≤6°C, (B) cool <10°C, (C) 0.008% Na2S2O3 [when chlorine is present], (D) H2SO4 to pH <2, (E) HNO3 to pH <2, (F) HCl to pH <2, (G) H3PO4 to pH <2, (H) 6N NaOH to pH >10<11, (I) (NH4)2SO4 pH=9.3-9.7, (J) zinc acetate & NaOH to pH to >9, (K) pH 6-9 ascorbic acid [when chlorine is present], (L) leave no headspace, (M) ferrous ammonium sulfate [when chlorine is present], (P) ascorbic acid [when chlorine is present], (R) Lugols, (T) Trizma [when chlorine is present], (Y) analyzed within 15 minutes of sample collection, (Z) filtered in field within 15 minutes using 0.45um pore size X X X X Thallium (Tl) Tin (Sn) X Titanium (Ti) X Vanadium (V) X Zinc (Zn) X Mercury 1631, low-level X X X X X X X X X X X Phytoplankton / Algae Composite Grab De-chlorinated in Field ChlorinatedSampling Method: Other:Dissolved analysis: Enter "DIS" in check-boxes for parameters Sample Depth: Lab Comments: Sodium (Na)E Cyanotoxins: C - L A Organochlorine Pesticides Organonitrogen Pesticides Organophosphorus Pesticides Blue Ridge Tissue - 1427 Yadkin River Road Lenoir, NCLocation Description: DWR Region: (based on county) River Basin: Surface Ground Water SupplyFoam Other: Metals Parameters: E E E E E E PCBs (polychlorinated biphenyls) Semi-Volatile Organics (BNAs) E E ECalcium (Ca) Chromium (Cr), Total Tag ID Visit ID: (optional) Laboratory Sample Number: Collector: DWR Office: (or agency name) Date (m/d/y): (begin/end) MW-8 2 Priority: Ambient Location Code:1P14BLUERIDGEMW8 Brett Laverty Location Type: Monitoring Well Trip Blank/ / Influent Filter Blank Lab Use Only: Time Received: (24 hr format) Date Received: M/D/Y : North Carolina Division of Water Resources Laboratory (Water Sciences Section)Water Sample Collection & Submittal Form Waste Blank Notes:Monitoring well MW-8 County:Caldwell Water Matrix: ARO Solution Routine Compliance COC Emergency QATime (24 hr): (begin/end)12:00 PM : 3/1/2022 Received By: Hand Delivered State Courier . Canal Stormwater LakeRiver/Stream Estuary Effluent Field Blank / / Lithium (Li)A - C A - C A - C E A - C Temperature on Arrival (°C): Delivery Method: Barium (Ba) Beryllium (Be) Cadmium (Cd) Copper (Cu) Iron (Fe) Lead (Pb) E E E E E E Other: E A - C Login file: Selenium (Se) Silver (Ag) Total Kjeldahl Nitrogen as N (TKN) TPH Diesel Range Boron (B) Hardness, Total as CaCO3 - by titration Acid Herbicides Molybdenum (Mo) Nickel (Ni) Secchi Depth: Lot #s / Collector Comments: Filtered in Field A - J A A A A Water Temp (oC):pH (s.u.):Conductivity (µmhos/cm): Microcystin Cobalt (Co) Oil and Grease, HEM, Total Recoverable TPH Gasoline Range A - D - MA - C - D Potassium (K) A - D A - D A A - Z E A A - I Preservative Organics Parameters: Dissolved Oxygen (ppm): Salinity (ppt): Nitrite as N (NO2-N) Total Phosphorus as P (TP) Nitrate as N (NO3-N calculated) A A Phenols, Total Recoverable Residue: Total (Total Solids ) Residue: Volatile/Fixed, Total Residue: Settleable Residue: Suspended (Suspended Solids ) Residue: Volatile/Fixed, Suspended TDS - Total Dissolved SolidsOrthophosphate as P (PO4) Ammonia as N (NH3-N) Nitrate-Nitrite as N (NO3+NO2-N) A A - D Arsenic (As) Color: Platinum Cobalt Preservative A Preservative E E E E E E E Preservative Alkalinity, as CaCO3, to pH 4.5/8.3 BOD: Biochemical Oxygen Demand, 5-day cBOD: Carbonaceous BOD, 5-day Coliform: Fecal MF Coliform: Total MF Nutrients Parameters: A - H - P COD: Chemical Oxygen Demand A A A A B - C B - C A A - G Fluoride Sulfate A A Hexavalent Chromium (Cr6+) MBAS (surfactants) A A - D A A Color: ADMI Cyanide, Total Specific Conductance, at 25 oC TOC - Total Organic Carbon Turbidity pH Bromide Chloride A Other Parameters: Microbiology Parameters:Wet Chemistry Parameters:Metals Parameters Con't: E E Aluminum (Al) Antimony (Sb) Chlorophyll a Field Parameters (optional): Preservative : Y Y A - C A - R Biological: E Silica Sulfide Perfluorinated Compounds (PFAS) Tannin & Lignin A - T A - C - F - LVolatile Organics (VOA) 1,4-Dioxane A - D A - C - F - L A - C Magnesium (Mg) E Manganese (Mn) Mercury (Hg) Strontium (Sr) Revision 6/10/2021Required: 1) Collector Initials and Date, 2) Circle each preservative option utilized next to each parameter. Preservative Legend (circle above as needed): (A) cool ≤6°C, (B) cool <10°C, (C) 0.008% Na2S2O3 [when chlorine is present], (D) H2SO4 to pH <2, (E) HNO3 to pH <2, (F) HCl to pH <2, (G) H3PO4 to pH <2, (H) 6N NaOH to pH >10<11, (I) (NH4)2SO4 pH=9.3-9.7, (J) zinc acetate & NaOH to pH to >9, (K) pH 6-9 ascorbic acid [when chlorine is present], (L) leave no headspace, (M) ferrous ammonium sulfate [when chlorine is present], (P) ascorbic acid [when chlorine is present], (R) Lugols, (T) Trizma [when chlorine is present], (Y) analyzed within 15 minutes of sample collection, (Z) filtered in field within 15 minutes using 0.45um pore size X X X X Thallium (Tl) Tin (Sn) X Titanium (Ti) X Vanadium (V) X Zinc (Zn) X Mercury 1631, low-level X X X X X X X X X X X Phytoplankton / Algae Composite Grab De-chlorinated in Field ChlorinatedSampling Method: Other:Dissolved analysis: Enter "DIS" in check-boxes for parameters Sample Depth: Lab Comments: Sodium (Na)E Cyanotoxins: C - L A Organochlorine Pesticides Organonitrogen Pesticides Organophosphorus Pesticides Blue Ridge Tissue - 1427 Yadkin River Road Lenoir, NCLocation Description: DWR Region: (based on county) River Basin: Surface Ground Water SupplyFoam Other: Metals Parameters: E E E E E E PCBs (polychlorinated biphenyls) Semi-Volatile Organics (BNAs) E E ECalcium (Ca) Chromium (Cr), Total Tag ID Visit ID: (optional) Laboratory Sample Number: Collector: DWR Office: (or agency name) Date (m/d/y): (begin/end) MW-6 3 Priority: Ambient Location Code:1P14BLUERIDGEMW6 Brett Laverty Location Type: Monitoring Well Trip Blank/ / Influent Filter Blank Lab Use Only: Time Received: (24 hr format) Date Received: M/D/Y : North Carolina Division of Water Resources Laboratory (Water Sciences Section)Water Sample Collection & Submittal Form Waste Blank Notes:Monitoring well MW-6 County:Caldwell Water Matrix: ARO Solution Routine Compliance COC Emergency QATime (24 hr): (begin/end)12:43 PM : 3/1/2022 Received By: Hand Delivered State Courier . Canal Stormwater LakeRiver/Stream Estuary Effluent Field Blank / / Lithium (Li)A - C A - C A - C E A - C Temperature on Arrival (°C): Delivery Method: Barium (Ba) Beryllium (Be) Cadmium (Cd) Copper (Cu) Iron (Fe) Lead (Pb) E E E E E E Other: E A - C Login file: Selenium (Se) Silver (Ag) Total Kjeldahl Nitrogen as N (TKN) TPH Diesel Range Boron (B) Hardness, Total as CaCO3 - by titration Acid Herbicides Molybdenum (Mo) Nickel (Ni) Secchi Depth: Lot #s / Collector Comments: Filtered in Field A - J A A A A Water Temp (oC):pH (s.u.):Conductivity (µmhos/cm): Microcystin Cobalt (Co) Oil and Grease, HEM, Total Recoverable TPH Gasoline Range A - D - MA - C - D Potassium (K) A - D A - D A A - Z E A A - I Preservative Organics Parameters: Dissolved Oxygen (ppm): Salinity (ppt): Nitrite as N (NO2-N) Total Phosphorus as P (TP) Nitrate as N (NO3-N calculated) A A Phenols, Total Recoverable Residue: Total (Total Solids ) Residue: Volatile/Fixed, Total Residue: Settleable Residue: Suspended (Suspended Solids ) Residue: Volatile/Fixed, Suspended TDS - Total Dissolved SolidsOrthophosphate as P (PO4) Ammonia as N (NH3-N) Nitrate-Nitrite as N (NO3+NO2-N) A A - D Arsenic (As) Color: Platinum Cobalt Preservative A Preservative E E E E E E E Preservative Alkalinity, as CaCO3, to pH 4.5/8.3 BOD: Biochemical Oxygen Demand, 5-day cBOD: Carbonaceous BOD, 5-day Coliform: Fecal MF Coliform: Total MF Nutrients Parameters: A - H - P COD: Chemical Oxygen Demand A A A A B - C B - C A A - G Fluoride Sulfate A A Hexavalent Chromium (Cr6+) MBAS (surfactants) A A - D A A Color: ADMI Cyanide, Total Specific Conductance, at 25 oC TOC - Total Organic Carbon Turbidity pH Bromide Chloride A Other Parameters: Microbiology Parameters:Wet Chemistry Parameters:Metals Parameters Con't: E E Aluminum (Al) Antimony (Sb) Chlorophyll a Field Parameters (optional): Preservative : Y Y A - C A - R Biological: E Silica Sulfide Perfluorinated Compounds (PFAS) Tannin & Lignin A - T A - C - F - LVolatile Organics (VOA) 1,4-Dioxane A - D A - C - F - L A - C Magnesium (Mg) E Manganese (Mn) Mercury (Hg) Strontium (Sr) Revision 6/10/2021Required: 1) Collector Initials and Date, 2) Circle each preservative option utilized next to each parameter. Preservative Legend (circle above as needed): (A) cool ≤6°C, (B) cool <10°C, (C) 0.008% Na2S2O3 [when chlorine is present], (D) H2SO4 to pH <2, (E) HNO3 to pH <2, (F) HCl to pH <2, (G) H3PO4 to pH <2, (H) 6N NaOH to pH >10<11, (I) (NH4)2SO4 pH=9.3-9.7, (J) zinc acetate & NaOH to pH to >9, (K) pH 6-9 ascorbic acid [when chlorine is present], (L) leave no headspace, (M) ferrous ammonium sulfate [when chlorine is present], (P) ascorbic acid [when chlorine is present], (R) Lugols, (T) Trizma [when chlorine is present], (Y) analyzed within 15 minutes of sample collection, (Z) filtered in field within 15 minutes using 0.45um pore size X X X X Thallium (Tl) Tin (Sn) X Titanium (Ti) X Vanadium (V) X Zinc (Zn) X Mercury 1631, low-level X X X X X X X X X X X Phytoplankton / Algae Composite Grab De-chlorinated in Field ChlorinatedSampling Method: Other:Dissolved analysis: Enter "DIS" in check-boxes for parameters Sample Depth: Lab Comments: Sodium (Na)E Cyanotoxins: C - L A Organochlorine Pesticides Organonitrogen Pesticides Organophosphorus Pesticides Blue Ridge Tissue - 1427 Yadkin River Road Lenoir, NCLocation Description: DWR Region: (based on county) River Basin: Surface Ground Water SupplyFoam Other: Metals Parameters: E E E E E E PCBs (polychlorinated biphenyls) Semi-Volatile Organics (BNAs) E E ECalcium (Ca) Chromium (Cr), Total Tag ID Visit ID: (optional) Laboratory Sample Number: Collector: DWR Office: (or agency name) Date (m/d/y): (begin/end) MW-7 4 Priority: Ambient Location Code:1P14BLUERIDGEMW7 Brett Laverty Location Type: Monitoring Well Trip Blank/ / Influent Filter Blank Lab Use Only: Time Received: (24 hr format) Date Received: M/D/Y : North Carolina Division of Water Resources Laboratory (Water Sciences Section)Water Sample Collection & Submittal Form Waste Blank Notes:Monitoring well MW-7 County:Caldwell Water Matrix: ARO Solution Routine Compliance COC Emergency QATime (24 hr): (begin/end)1:16 PM : 3/1/2022 Received By: Hand Delivered State Courier . Canal Stormwater LakeRiver/Stream Estuary Effluent Field Blank / / Lithium (Li)A - C A - C A - C E A - C Temperature on Arrival (°C): Delivery Method: Barium (Ba) Beryllium (Be) Cadmium (Cd) Copper (Cu) Iron (Fe) Lead (Pb) E E E E E E Other: E A - C Login file: Selenium (Se) Silver (Ag) Total Kjeldahl Nitrogen as N (TKN) TPH Diesel Range Boron (B) Hardness, Total as CaCO3 - by titration Acid Herbicides Molybdenum (Mo) Nickel (Ni) Secchi Depth: Lot #s / Collector Comments: Filtered in Field A - J A A A A Water Temp (oC):pH (s.u.):Conductivity (µmhos/cm): Microcystin Cobalt (Co) Oil and Grease, HEM, Total Recoverable TPH Gasoline Range A - D - MA - C - D Potassium (K) A - D A - D A A - Z E A A - I Preservative Organics Parameters: Dissolved Oxygen (ppm): Salinity (ppt): Nitrite as N (NO2-N) Total Phosphorus as P (TP) Nitrate as N (NO3-N calculated) A A Phenols, Total Recoverable Residue: Total (Total Solids ) Residue: Volatile/Fixed, Total Residue: Settleable Residue: Suspended (Suspended Solids ) Residue: Volatile/Fixed, Suspended TDS - Total Dissolved SolidsOrthophosphate as P (PO4) Ammonia as N (NH3-N) Nitrate-Nitrite as N (NO3+NO2-N) A A - D Arsenic (As) Color: Platinum Cobalt Preservative A Preservative E E E E E E E Preservative Alkalinity, as CaCO3, to pH 4.5/8.3 BOD: Biochemical Oxygen Demand, 5-day cBOD: Carbonaceous BOD, 5-day Coliform: Fecal MF Coliform: Total MF Nutrients Parameters: A - H - P COD: Chemical Oxygen Demand A A A A B - C B - C A A - G Fluoride Sulfate A A Hexavalent Chromium (Cr6+) MBAS (surfactants) A A - D A A Color: ADMI Cyanide, Total Specific Conductance, at 25 oC TOC - Total Organic Carbon Turbidity pH Bromide Chloride A Other Parameters: Microbiology Parameters:Wet Chemistry Parameters:Metals Parameters Con't: E E Aluminum (Al) Antimony (Sb) Chlorophyll a Field Parameters (optional): Preservative : Y Y A - C A - R Biological: E Silica Sulfide Perfluorinated Compounds (PFAS) Tannin & Lignin A - T A - C - F - LVolatile Organics (VOA) 1,4-Dioxane A - D A - C - F - L A - C Magnesium (Mg) E Manganese (Mn) Mercury (Hg) Strontium (Sr) Revision 6/10/2021Required: 1) Collector Initials and Date, 2) Circle each preservative option utilized next to each parameter. Preservative Legend (circle above as needed): (A) cool ≤6°C, (B) cool <10°C, (C) 0.008% Na2S2O3 [when chlorine is present], (D) H2SO4 to pH <2, (E) HNO3 to pH <2, (F) HCl to pH <2, (G) H3PO4 to pH <2, (H) 6N NaOH to pH >10<11, (I) (NH4)2SO4 pH=9.3-9.7, (J) zinc acetate & NaOH to pH to >9, (K) pH 6-9 ascorbic acid [when chlorine is present], (L) leave no headspace, (M) ferrous ammonium sulfate [when chlorine is present], (P) ascorbic acid [when chlorine is present], (R) Lugols, (T) Trizma [when chlorine is present], (Y) analyzed within 15 minutes of sample collection, (Z) filtered in field within 15 minutes using 0.45um pore size X X X X Thallium (Tl) Tin (Sn) X Titanium (Ti) X Vanadium (V) X Zinc (Zn) X Mercury 1631, low-level X X X X X X X X X X X Phytoplankton / Algae Composite Grab De-chlorinated in Field ChlorinatedSampling Method: Other:Dissolved analysis: Enter "DIS" in check-boxes for parameters Sample Depth: Lab Comments: Sodium (Na)E Cyanotoxins: C - L A Organochlorine Pesticides Organonitrogen Pesticides Organophosphorus Pesticides Blue Ridge Tissue - 1427 Yadkin River Road Lenoir, NCLocation Description: DWR Region: (based on county) River Basin: Surface Ground Water SupplyFoam Other: Metals Parameters: E E E E E E PCBs (polychlorinated biphenyls) Semi-Volatile Organics (BNAs) E E ECalcium (Ca) Chromium (Cr), Total Tag ID Visit ID: (optional) Laboratory Sample Number: Collector: DWR Office: (or agency name) Date (m/d/y): (begin/end) MW-4 5 Priority: Ambient Location Code:1P14BLUERIDGEMW4 Brett Laverty Location Type: Monitoring Well Trip Blank/ / Influent Filter Blank Lab Use Only: Time Received: (24 hr format) Date Received: M/D/Y : North Carolina Division of Water Resources Laboratory (Water Sciences Section)Water Sample Collection & Submittal Form Waste Blank Notes:Monitoring well MW-4 County:Caldwell Water Matrix: ARO Solution Routine Compliance COC Emergency QATime (24 hr): (begin/end)2:06 PM : 3/1/2022 Received By: Hand Delivered State Courier . Canal Stormwater LakeRiver/Stream Estuary Effluent Field Blank / / Lithium (Li)A - C A - C A - C E A - C Temperature on Arrival (°C): Delivery Method: Barium (Ba) Beryllium (Be) Cadmium (Cd) Copper (Cu) Iron (Fe) Lead (Pb) E E E E E E Other: E A - C Login file: Selenium (Se) Silver (Ag) Total Kjeldahl Nitrogen as N (TKN) TPH Diesel Range Boron (B) Hardness, Total as CaCO3 - by titration Acid Herbicides Molybdenum (Mo) Nickel (Ni) Secchi Depth: Lot #s / Collector Comments: Filtered in Field A - J A A A A Water Temp (oC):pH (s.u.):Conductivity (µmhos/cm): Microcystin Cobalt (Co) Oil and Grease, HEM, Total Recoverable TPH Gasoline Range A - D - MA - C - D Potassium (K) A - D A - D A A - Z E A A - I Preservative Organics Parameters: Dissolved Oxygen (ppm): Salinity (ppt): Nitrite as N (NO2-N) Total Phosphorus as P (TP) Nitrate as N (NO3-N calculated) A A Phenols, Total Recoverable Residue: Total (Total Solids ) Residue: Volatile/Fixed, Total Residue: Settleable Residue: Suspended (Suspended Solids ) Residue: Volatile/Fixed, Suspended TDS - Total Dissolved SolidsOrthophosphate as P (PO4) Ammonia as N (NH3-N) Nitrate-Nitrite as N (NO3+NO2-N) A A - D Arsenic (As) Color: Platinum Cobalt Preservative A Preservative E E E E E E E Preservative Alkalinity, as CaCO3, to pH 4.5/8.3 BOD: Biochemical Oxygen Demand, 5-day cBOD: Carbonaceous BOD, 5-day Coliform: Fecal MF Coliform: Total MF Nutrients Parameters: A - H - P COD: Chemical Oxygen Demand A A A A B - C B - C A A - G Fluoride Sulfate A A Hexavalent Chromium (Cr6+) MBAS (surfactants) A A - D A A Color: ADMI Cyanide, Total Specific Conductance, at 25 oC TOC - Total Organic Carbon Turbidity pH Bromide Chloride A Other Parameters: Microbiology Parameters:Wet Chemistry Parameters:Metals Parameters Con't: E E Aluminum (Al) Antimony (Sb) Chlorophyll a Field Parameters (optional): Preservative : Y Y A - C A - R Biological: E Silica Sulfide Perfluorinated Compounds (PFAS) Tannin & Lignin A - T A - C - F - LVolatile Organics (VOA) 1,4-Dioxane A - D A - C - F - L A - C Magnesium (Mg) E Manganese (Mn) Mercury (Hg) Strontium (Sr) Revision 6/10/2021Required: 1) Collector Initials and Date, 2) Circle each preservative option utilized next to each parameter. Preservative Legend (circle above as needed): (A) cool ≤6°C, (B) cool <10°C, (C) 0.008% Na2S2O3 [when chlorine is present], (D) H2SO4 to pH <2, (E) HNO3 to pH <2, (F) HCl to pH <2, (G) H3PO4 to pH <2, (H) 6N NaOH to pH >10<11, (I) (NH4)2SO4 pH=9.3-9.7, (J) zinc acetate & NaOH to pH to >9, (K) pH 6-9 ascorbic acid [when chlorine is present], (L) leave no headspace, (M) ferrous ammonium sulfate [when chlorine is present], (P) ascorbic acid [when chlorine is present], (R) Lugols, (T) Trizma [when chlorine is present], (Y) analyzed within 15 minutes of sample collection, (Z) filtered in field within 15 minutes using 0.45um pore size X X X X Thallium (Tl) Tin (Sn) Titanium (Ti) Vanadium (V) Zinc (Zn) Mercury 1631, low-level X X X X Phytoplankton / Algae Composite Grab De-chlorinated in Field ChlorinatedSampling Method: Other:Dissolved analysis: Enter "DIS" in check-boxes for parameters Sample Depth: Lab Comments: Sodium (Na)E Cyanotoxins: C - L A Organochlorine Pesticides Organonitrogen Pesticides Organophosphorus Pesticides Yadkin River @ Whisnant RoadLocation Description: DWR Region: (based on county) River Basin: Surface Ground Water SupplyFoam Other: Metals Parameters: E E E E E E PCBs (polychlorinated biphenyls) Semi-Volatile Organics (BNAs) E E ECalcium (Ca) Chromium (Cr), Total Tag ID Visit ID: (optional) Laboratory Sample Number: Collector: DWR Office: (or agency name) Date (m/d/y): (begin/end) 6 Priority: Ambient Location Code:1P14YADKIN Brett Laverty Location Type: Monitoring Well Trip Blank/ / Influent Filter Blank Lab Use Only: Time Received: (24 hr format) Date Received: M/D/Y : North Carolina Division of Water Resources Laboratory (Water Sciences Section)Water Sample Collection & Submittal Form Waste Blank Notes: County:Caldwell Water Matrix: ARO Yadkin River Solution Routine Compliance COC Emergency QATime (24 hr): (begin/end)2:27 PM : 3/1/2022 Received By: Hand Delivered State Courier . Canal Stormwater LakeRiver/Stream Estuary Effluent Field Blank / / Lithium (Li)A - C A - C A - C E A - C Temperature on Arrival (°C): Delivery Method: Barium (Ba) Beryllium (Be) Cadmium (Cd) Copper (Cu) Iron (Fe) Lead (Pb) E E E E E E Other: E A - C Login file: Selenium (Se) Silver (Ag) Total Kjeldahl Nitrogen as N (TKN) TPH Diesel Range Boron (B) Hardness, Total as CaCO3 - by titration Acid Herbicides Molybdenum (Mo) Nickel (Ni) Secchi Depth: Lot #s / Collector Comments: Filtered in Field A - J A A A A Water Temp (oC):pH (s.u.):Conductivity (µmhos/cm): Microcystin Cobalt (Co) Oil and Grease, HEM, Total Recoverable TPH Gasoline Range A - D - MA - C - D Potassium (K) A - D A - D A A - Z E A A - I Preservative Organics Parameters: Dissolved Oxygen (ppm): Salinity (ppt): Nitrite as N (NO2-N) Total Phosphorus as P (TP) Nitrate as N (NO3-N calculated) A A Phenols, Total Recoverable Residue: Total (Total Solids ) Residue: Volatile/Fixed, Total Residue: Settleable Residue: Suspended (Suspended Solids ) Residue: Volatile/Fixed, Suspended TDS - Total Dissolved SolidsOrthophosphate as P (PO4) Ammonia as N (NH3-N) Nitrate-Nitrite as N (NO3+NO2-N) A A - D Arsenic (As) Color: Platinum Cobalt Preservative A Preservative E E E E E E E Preservative Alkalinity, as CaCO3, to pH 4.5/8.3 BOD: Biochemical Oxygen Demand, 5-day cBOD: Carbonaceous BOD, 5-day Coliform: Fecal MF Coliform: Total MF Nutrients Parameters: A - H - P COD: Chemical Oxygen Demand A A A A B - C B - C A A - G Fluoride Sulfate A A Hexavalent Chromium (Cr6+) MBAS (surfactants) A A - D A A Color: ADMI Cyanide, Total Specific Conductance, at 25 oC TOC - Total Organic Carbon Turbidity pH Bromide Chloride A Other Parameters: Microbiology Parameters:Wet Chemistry Parameters:Metals Parameters Con't: E E Aluminum (Al) Antimony (Sb) Chlorophyll a Field Parameters (optional): Preservative : Y Y A - C A - R Biological: E Silica Sulfide Perfluorinated Compounds (PFAS) Tannin & Lignin A - T A - C - F - LVolatile Organics (VOA) 1,4-Dioxane A - D A - C - F - L A - C Magnesium (Mg) E Manganese (Mn) Mercury (Hg) Strontium (Sr) Revision 6/10/2021Required: 1) Collector Initials and Date, 2) Circle each preservative option utilized next to each parameter. Preservative Legend (circle above as needed): (A) cool ≤6°C, (B) cool <10°C, (C) 0.008% Na2S2O3 [when chlorine is present], (D) H2SO4 to pH <2, (E) HNO3 to pH <2, (F) HCl to pH <2, (G) H3PO4 to pH <2, (H) 6N NaOH to pH >10<11, (I) (NH4)2SO4 pH=9.3-9.7, (J) zinc acetate & NaOH to pH to >9, (K) pH 6-9 ascorbic acid [when chlorine is present], (L) leave no headspace, (M) ferrous ammonium sulfate [when chlorine is present], (P) ascorbic acid [when chlorine is present], (R) Lugols, (T) Trizma [when chlorine is present], (Y) analyzed within 15 minutes of sample collection, (Z) filtered in field within 15 minutes using 0.45um pore size