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HomeMy WebLinkAboutNC0006254_ARO Split Groundwater Samples with Blue Ridge Tissue_20190903PO Number # Loc. Descr.:Blue Ridge Tissue - 1427 Yadkin River Road Lenoir, NC Loc. Type:MONITORING WELL Collector:B LAVERTY Collect Date:09/03/2019 Collect Time:09:16 Date Received:09/05/2019 Time Received:08:20 Location ID:1P14BLUERIDGEMW1 County:Caldwell Region:Asheville Labworks LoginID TASCENZO1Sample Matrix:GROUNDWATER Report Print Date: North Carolina Division of Water Resources Water Sciences Section Laboratory Results VisitID Sample Depth AROReport To River Basin 01/09/2020 Emergency COC Yes/No Sample ID:AC67626 11/6/19Final Report Date: Final Report If this report is labeled preliminary report, the results have not been validated. Do not use for Regulatory purposes. NC CourierDelivery Method ROUTINEPriority AC67626 Analysis Date Method Reference Result/ QualifierPQLAnalyte NameCAS #Units Validated by LAB Sample temperature at receipt by lab MSWIFT°CSample temperature at receipt by lab 9/5/191.1 MET As by ICPMS EPA 200.8 Rev5.4 ESTAFFORD1ug/LUAs by ICPMS7440-38-2 10/10/192.0 2.0 Ba by ICP EPA 200.7 Rev4.4 ESTAFFORD1ug/LBa by ICP7440-38-3 10/22/1910650 Ca by ICP EPA 200.7 Rev4.4 ESTAFFORD1mg/LCa by ICP7440-70-2 10/22/190.10 85 Cd by ICPMS EPA 200.8 Rev5.4 ESTAFFORD1ug/LUCd by ICPMS7440-43-9 10/10/190.50 0.50 Cobalt by ICP EPA 200.7 Rev4.4 ESTAFFORD1ug/LUCobalt by ICP7440-48-4 10/22/195050 Cr by ICPMS EPA 200.8 Rev5.4 ESTAFFORD1ug/LUCr by ICPMS7440-47-3 10/10/195.0 5.0 Cu by ICPMS EPA 200.8 Rev5.4 ESTAFFORD1ug/LUCu by ICPMS7440-50-8 10/10/192.0 2.0 Fe by ICP EPA 200.7 Rev4.4 ESTAFFORD1ug/LFe by ICP7439-89-6 10/22/195045000 Hg 245.1 EPA 245.1 Rev3 ESTAFFORD1ug/LUHg 245.17439-97-6 9/18/190.2 0.20 Mg by ICP EPA 200.7 Rev4.4 ESTAFFORD1mg/LMg by ICP7439-95-4 10/22/190.10 11 Mn by ICP EPA 200.7 Rev4.4 ESTAFFORD1ug/LMn by ICP7439-96-5 10/22/19109800 Na by ICP EPA 200.7 Rev4.4 ESTAFFORD1mg/LNa by ICP7440-23-5 10/22/190.10 37 Pb by ICPMS WSS Chemistry Laboratory>> 1623 Mail Service Center, Raleigh, NC 27699-1623 (919) 733-3908 Page 1 of 2 "Not Detected" or "U" does not indicate the sample is analyte free but that the analyte is not detected at or above the PQL. AC67626Sample ID: NC DWR Laboratory Section Results/Sample Comments/Qualifier Definitions CAS #Analyte Name PQL Result/ Qualifier Units Method Reference Analysis Date Validated by EPA 200.8 Rev5.4 ESTAFFORD1ug/LUPb by ICPMS7439-92-1 10/10/192.0 2.0 Sr by ICPMS EPA 200.8 Rev5.4 ESTAFFORD1ug/LSr by ICPMS7440-24-6 10/10/19101500 Zn by ICPMS EPA 200.8 Rev5.4 ESTAFFORD1ug/LUZn by ICPMS7440-66-6 10/10/191010 NUT NH3 as N in liquid EPA 350.1 REV 2 MIBRAHIM1mg/L as NNH3 as N in liquid 9/17/190.02 0.34 NO2+NO3 as N in liquid EPA 353.2 REV 2 MIBRAHIM1mg/L as NUNO2+NO3 as N in liquid 9/17/190.02 0.02 Phosphorus_total as P in liquid EPA 365.1 REV 2 MIBRAHIM1mg/L as PPhosphorus_total as P in liquid 9/20/190.02 0.09 Total Kjeldahl N as N in liquid EPA 351.2 REV 2 MIBRAHIM1mg/L as NTotal Kjeldahl N as N in liquid 9/30/190.2 0.83 WSS Chemistry Laboratory>> 1623 Mail Service Center, Raleigh, NC 27699-1623 (919) 733-3908 Page 2 of 2 "Not Detected" or "U" does not indicate the sample is analyte free but that the analyte is not detected at or above the PQL. PO Number # Loc. Descr.:Blue Ridge Tissue - 1427 Yadkin River Road Lenoir, NC Loc. Type:MONITORING WELL Collector:B LAVERTY Collect Date:09/03/2019 Collect Time:10:10 Date Received:09/05/2019 Time Received:08:20 Location ID:1P14BLUERIDGEMW3 County:Caldwell Region:Asheville Labworks LoginID TASCENZO1Sample Matrix:GROUNDWATER Report Print Date: North Carolina Division of Water Resources Water Sciences Section Laboratory Results VisitID Sample Depth AROReport To River Basin 01/09/2020 Emergency COC Yes/No Sample ID:AC67627 11/6/19Final Report Date: Final Report If this report is labeled preliminary report, the results have not been validated. Do not use for Regulatory purposes. NC CourierDelivery Method ROUTINEPriority AC67627 Analysis Date Method Reference Result/ QualifierPQLAnalyte NameCAS #Units Validated by LAB Sample temperature at receipt by lab MSWIFT°CSample temperature at receipt by lab 9/5/191.1 MET As by ICPMS EPA 200.8 Rev5.4 ESTAFFORD1ug/LAs by ICPMS7440-38-2 10/10/192.0 4.2 Ba by ICP EPA 200.7 Rev4.4 ESTAFFORD1ug/LBa by ICP7440-38-3 10/22/1910220 Ca by ICP EPA 200.7 Rev4.4 ESTAFFORD1mg/LCa by ICP7440-70-2 10/22/190.10 47 Cd by ICPMS EPA 200.8 Rev5.4 ESTAFFORD1ug/LUCd by ICPMS7440-43-9 10/10/190.50 0.50 Cobalt by ICP EPA 200.7 Rev4.4 ESTAFFORD1ug/LUCobalt by ICP7440-48-4 10/22/195050 Cr by ICPMS EPA 200.8 Rev5.4 ESTAFFORD1ug/LUCr by ICPMS7440-47-3 10/10/195.0 5.0 Cu by ICPMS EPA 200.8 Rev5.4 ESTAFFORD1ug/LUCu by ICPMS7440-50-8 10/10/192.0 2.0 Fe by ICP EPA 200.7 Rev4.4 ESTAFFORD1ug/LFe by ICP7439-89-6 10/22/195040000 Hg 245.1 EPA 245.1 Rev3 ESTAFFORD1ug/LUHg 245.17439-97-6 9/18/190.2 0.20 Mg by ICP EPA 200.7 Rev4.4 ESTAFFORD1mg/LMg by ICP7439-95-4 10/22/190.10 3.2 Mn by ICP EPA 200.7 Rev4.4 ESTAFFORD1ug/LMn by ICP7439-96-5 10/22/19104300 Na by ICP EPA 200.7 Rev4.4 ESTAFFORD1mg/LNa by ICP7440-23-5 10/22/190.10 35 Pb by ICPMS WSS Chemistry Laboratory>> 1623 Mail Service Center, Raleigh, NC 27699-1623 (919) 733-3908 Page 1 of 2 "Not Detected" or "U" does not indicate the sample is analyte free but that the analyte is not detected at or above the PQL. AC67627Sample ID: NC DWR Laboratory Section Results/Sample Comments/Qualifier Definitions CAS #Analyte Name PQL Result/ Qualifier Units Method Reference Analysis Date Validated by EPA 200.8 Rev5.4 ESTAFFORD1ug/LUPb by ICPMS7439-92-1 10/10/192.0 2.0 Sr by ICPMS EPA 200.8 Rev5.4 ESTAFFORD1ug/LSr by ICPMS7440-24-6 10/10/1910350 Zn by ICPMS EPA 200.8 Rev5.4 ESTAFFORD1ug/LUZn by ICPMS7440-66-6 10/10/191010 NUT NH3 as N in liquid EPA 350.1 REV 2 MIBRAHIM1mg/L as NNH3 as N in liquid 9/17/190.02 6.6 NO2+NO3 as N in liquid EPA 353.2 REV 2 MIBRAHIM1mg/L as NUNO2+NO3 as N in liquid 9/17/190.02 0.02 Phosphorus_total as P in liquid EPA 365.1 REV 2 MIBRAHIM1mg/L as PUPhosphorus_total as P in liquid 9/20/190.02 0.02 Total Kjeldahl N as N in liquid EPA 351.2 REV 2 MIBRAHIM1mg/L as NTotal Kjeldahl N as N in liquid 9/30/190.2 6.9 WSS Chemistry Laboratory>> 1623 Mail Service Center, Raleigh, NC 27699-1623 (919) 733-3908 Page 2 of 2 "Not Detected" or "U" does not indicate the sample is analyte free but that the analyte is not detected at or above the PQL. PO Number # Loc. Descr.:Blue Ridge Tissue - 1427 Yadkin River Road Lenoir, NC Loc. Type:MONITORING WELL Collector:B LAVERTY Collect Date:09/03/2019 Collect Time:10:39 Date Received:09/05/2019 Time Received:08:20 Location ID:1P14BLUERIDGEMW2 County:Caldwell Region:Asheville Labworks LoginID TASCENZO1Sample Matrix:GROUNDWATER Report Print Date: North Carolina Division of Water Resources Water Sciences Section Laboratory Results VisitID Sample Depth AROReport To River Basin 01/09/2020 Emergency COC Yes/No Sample ID:AC67628 11/6/19Final Report Date: Final Report If this report is labeled preliminary report, the results have not been validated. Do not use for Regulatory purposes. NC CourierDelivery Method ROUTINEPriority AC67628 Analysis Date Method Reference Result/ QualifierPQLAnalyte NameCAS #Units Validated by LAB Sample temperature at receipt by lab MSWIFT°CSample temperature at receipt by lab 9/5/191.1 MET As by ICPMS EPA 200.8 Rev5.4 ESTAFFORD1ug/LAs by ICPMS7440-38-2 10/10/192.0 15 Ba by ICP EPA 200.7 Rev4.4 ESTAFFORD1ug/LBa by ICP7440-38-3 10/22/19102000 Ca by ICP EPA 200.7 Rev4.4 ESTAFFORD1mg/LCa by ICP7440-70-2 10/22/190.10 60 Cd by ICPMS EPA 200.8 Rev5.4 ESTAFFORD1ug/LUCd by ICPMS7440-43-9 10/10/190.50 0.50 Cobalt by ICP EPA 200.7 Rev4.4 ESTAFFORD1ug/LCobalt by ICP7440-48-4 10/22/195060 Cr by ICPMS EPA 200.8 Rev5.4 ESTAFFORD1ug/LCr by ICPMS7440-47-3 10/10/195.0 72 Cu by ICPMS EPA 200.8 Rev5.4 ESTAFFORD1ug/LJ2Cu by ICPMS7440-50-8 10/10/192.0 49 Fe by ICP EPA 200.7 Rev4.4 ESTAFFORD1ug/LFe by ICP7439-89-6 10/22/1950120000 Hg 245.1 EPA 245.1 Rev3 ESTAFFORD1ug/LUHg 245.17439-97-6 9/18/190.2 0.20 Mg by ICP EPA 200.7 Rev4.4 ESTAFFORD1mg/LMg by ICP7439-95-4 10/22/190.10 7.7 Mn by ICP EPA 200.7 Rev4.4 ESTAFFORD1ug/LMn by ICP7439-96-5 10/22/19101000 Na by ICP EPA 200.7 Rev4.4 ESTAFFORD1mg/LNa by ICP7440-23-5 10/22/190.10 34 Pb by ICPMS WSS Chemistry Laboratory>> 1623 Mail Service Center, Raleigh, NC 27699-1623 (919) 733-3908 Page 1 of 4 "Not Detected" or "U" does not indicate the sample is analyte free but that the analyte is not detected at or above the PQL. AC67628Sample ID: NC DWR Laboratory Section Results/Sample Comments/Qualifier Definitions CAS #Analyte Name PQL Result/ Qualifier Units Method Reference Analysis Date Validated by EPA 200.8 Rev5.4 ESTAFFORD1ug/LPb by ICPMS7439-92-1 10/10/192.0 30 Sr by ICPMS EPA 200.8 Rev5.4 ESTAFFORD1ug/LSr by ICPMS7440-24-6 10/10/1910160 Zn by ICPMS EPA 200.8 Rev5.4 ESTAFFORD1ug/LZn by ICPMS7440-66-6 10/10/1910350 NUT NH3 as N in liquid EPA 350.1 REV 2 MIBRAHIM1mg/L as NNH3 as N in liquid 9/17/190.02 9.3 NO2+NO3 as N in liquid EPA 353.2 REV 2 MIBRAHIM1mg/L as NUNO2+NO3 as N in liquid 9/17/190.02 0.02 Phosphorus_total as P in liquid EPA 365.1 REV 2 MIBRAHIM1mg/L as PPhosphorus_total as P in liquid 9/20/190.02 0.71 Total Kjeldahl N as N in liquid EPA 351.2 REV 2 MIBRAHIM1mg/L as NTotal Kjeldahl N as N in liquid 9/30/190.2 14 WSS Chemistry Laboratory>> 1623 Mail Service Center, Raleigh, NC 27699-1623 (919) 733-3908 Page 2 of 4 "Not Detected" or "U" does not indicate the sample is analyte free but that the analyte is not detected at or above the PQL. AC67628Sample ID: NC DWR Laboratory Section Results/Sample Comments/Qualifier Definitions CAS #Analyte Name PQL Result/ Qualifier Units Method Reference Analysis Date Validated by MET:Cu 200.8-J2-Estimated-LFM failed LCL 68% recovery. Sample Comments NCDEQ-WSS-Chemistry Lab Data Qualifiers A1 The reported value is an average, where at least one result is qualified with a “U”. The PQL is used for the qualified result(S) to calculate the average. B1 Coliform-Countable membranes with less than 20 colonies. Reported value is estimated or is a total of the counts on all filters reported per 100 ml. B2 Coliform-Counts from all filters were zero. The value reported is based on the number of colonies per 100 ml that would have been reported if there had been one colony on the filter representing the largest filtration volume. B3 Coliform-Countable membranes with more than 60 or 80 colonies. The value reported is calculated using the count from the smallest volume filtered and reported as a greater than ">" value. B4 Coliform-Filters have counts of both >60 or 80 and <20. Reported value is estimated or is a total of the counts on all filters reported per 100 ml. B5 Coliform-Too many colonies were present; too numerous to count (TNTC). TNTC is generally defined as >150 colonies. B6 Coliform-Estimated Value. Blank contamination evident. B7 Coliform-Many non-coliform or non-enterococcus colonies or interfering non-coliform or non-enterococcus growth present. In this competitive situation, the reported value may under-represent actual density. BB1 MPN-No wells or tubes gave a positive reaction. Value based upon the appropriate MPN Index and reported as a less than “<” value. BB2 MPN-All wells or tubes gave positive reactions. Value based upon the MPN Index and reported as a greater than “>” value. C Total residual chlorine was present in sample upon receipt in the laboratory; value is estimated. G1 BOD-The dissolved oxygen (DO) depletion of the dilution water blank exceeded 0.2 mg/L. G2 BOD-The bacterial seed controls did not meet the requirement of a DO depletion of at least 2.0 mg/L and/or a DO residual of at least 1.0 mg/L. G3 BOD-No sample dilution met the requirement of a DO depletion of at least 2.0 mg/L and/or a DO residual of at least 1.0 mg/L. G4 BOD-Evidence of toxicity. This is generally characterized by a significant increase in the BOD value as the sample concentration decreases. The reported value is calculated from the highest dilution representing the maximum loading potential and G5 BOD-The glucose/ glutamic acid standard exceeded the range of 198 ± 30.5 mg/L. G6 BOD-The calculated seed correction exceeded the range of 0.6 to 1.0 mg/L. G7 BOD-Less than 1 mg/L DO remained for all dilutions set. The reported value is an estimated greater than value and is calculated for the dilution using the least amount of sample. G8 BOD-Oxygen usage is less than 2 mg/L for all dilutions set. The reported value is an estimated less than value and is calculated for the dilution using the most amount of sample. G9 BOD-The DO depletion of the dilution water blank produced a negative value. J1 Surrogate recovery limits have been exceeded. J2 The reported value failed to meet the established quality control criteria for either precision or accuracy. WSS Chemistry Laboratory>> 1623 Mail Service Center, Raleigh, NC 27699-1623 (919) 733-3908 Page 3 of 4 "Not Detected" or "U" does not indicate the sample is analyte free but that the analyte is not detected at or above the PQL. AC67628Sample ID: NC DWR Laboratory Section Results/Sample Comments/Qualifier Definitions CAS #Analyte Name PQL Result/ Qualifier Units Method Reference Analysis Date Validated by J3 The sample matrix interfered with the ability to make any accurate determination. J4 The data is questionable because of improper laboratory or field protocols (e.g., composite sample was collected instead of grab, plastic instead of glass container, etc.). J5 Temperature limits exceeded (samples frozen or >6°C) during transport or not verifiable (e.g., no temperature blank provided): non-reportable for NPDES compliance monitoring. J6 The laboratory analysis was from an unpreserved or improperly chemically preserved sample. The data may not be accurate. J7 This qualifier is used to identify analyte concentration exceeding the upper calibration range of the analytical instrument/method. The reported value should be considered estimated. J8 Temperature limits exceeded (samples frozen or >6ºC) during storage, the data may not be accurate. J9 The reported value is determined by a one-point estimation rather than against a regression equation. The estimated concentration is less than the laboratory practical quantitation limit and greater than the laboratory method detection limit. J10 Unidentified peak; estimated value. J11 The reported value is determined by a one-point estimation rather than against a regression equation. The estimated concentration is less than the laboratory practical quantitation limit and greater than the instrument noise level. This code is used when J12 The calibration verification did not meet the calibration acceptance criterion for field parameters. M Sample and duplicate results are "out of control". The sample is non-homogenous (e.g., VOA soil). The reported value is the lower value of duplicate analyses of a sample. N1 Presumptive evidence and estimated value. The component has been tentatively identified base on mass spectral library. N2 There is an indication that the analyte is present, but quality control requirements for confirmation were not met (i.e., presence of analyte was not confirmed by alternate procedures). N3 This code shall be used if the level is too low to permit accurate quantification, but the estimated concentration is less than the laboratory practical quantitation limit and greater than the laboratory method detection limit. This code is not routinely N4 This code shall be used if the level is too low to permit accurate quantification, but the estimated concentration is less than the laboratory practical quantitation limit and greater than the instrument noise level. This code is used when an MDL has not N5 The component has been tentatively identified based on a retention time standard. Q1 Holding time exceeded prior to receipt by lab. Q2 Holding time exceeded following receipt by lab. P Elevated PQL* due to matrix interference and/or sample dilution. S Not enough sample provided to prepare and/or analyze a method-required matrix spike (MS) and/or matrix spike duplicate (MSD). U Indicates that the analyte was analyzed for but not detected above the reported practical quantitation limit*. The number value reported with the "U" qualifier is equal to the laboratory's practical quantitation limit*. X1 Sample not screened for this compound. X2 Sampled, but analysis lost or not performed-field error. X3 Sampled, but analysis lost or not performed-lab error. V Indicates the analyte was detected in both the sample and the associated method blank. Note: The value in the blank shall not be subtracted from the associated samples. Y Elevated PQL* due to insufficient sample size. Z1 Inability to analyze the sample. Z2 Questions concerning data reliability. U, J6 The laboratory analysis was from an unpreserved or improperly chemically preserved sample. The data may not be accurate. UU Indicates that the analyte was not detected by a screen analysis. The number value was determined by a one-point estimation at the PQL. WSS Chemistry Laboratory>> 1623 Mail Service Center, Raleigh, NC 27699-1623 (919) 733-3908 Page 4 of 4 "Not Detected" or "U" does not indicate the sample is analyte free but that the analyte is not detected at or above the PQL. PO Number # Loc. Descr.:Blue Ridge Tissue - 1427 Yadkin River Road Lenoir, NC Loc. Type:MONITORING WELL Collector:B LAVERTY Collect Date:09/03/2019 Collect Time:11:28 Date Received:09/05/2019 Time Received:08:20 Location ID:1P14BLUERIDGEMW8 County:Caldwell Region:Asheville Labworks LoginID TASCENZO1Sample Matrix:GROUNDWATER Report Print Date: North Carolina Division of Water Resources Water Sciences Section Laboratory Results VisitID Sample Depth AROReport To River Basin 01/09/2020 Emergency COC Yes/No Sample ID:AC67629 11/6/19Final Report Date: Final Report If this report is labeled preliminary report, the results have not been validated. Do not use for Regulatory purposes. NC CourierDelivery Method ROUTINEPriority AC67629 Analysis Date Method Reference Result/ QualifierPQLAnalyte NameCAS #Units Validated by LAB Sample temperature at receipt by lab MSWIFT°CSample temperature at receipt by lab 9/5/191.1 MET As by ICPMS EPA 200.8 Rev5.4 ESTAFFORD1ug/LUAs by ICPMS7440-38-2 10/10/192.0 2.0 Ba by ICP EPA 200.7 Rev4.4 ESTAFFORD1ug/LBa by ICP7440-38-3 10/22/191019 Ca by ICP EPA 200.7 Rev4.4 ESTAFFORD1mg/LCa by ICP7440-70-2 10/22/190.10 11 Cd by ICPMS EPA 200.8 Rev5.4 ESTAFFORD1ug/LUCd by ICPMS7440-43-9 10/10/190.50 0.50 Cobalt by ICP EPA 200.7 Rev4.4 ESTAFFORD1ug/LUCobalt by ICP7440-48-4 10/22/195050 Cr by ICPMS EPA 200.8 Rev5.4 ESTAFFORD1ug/LUCr by ICPMS7440-47-3 10/10/195.0 5.0 Cu by ICPMS EPA 200.8 Rev5.4 ESTAFFORD1ug/LUCu by ICPMS7440-50-8 10/10/192.0 2.0 Fe by ICP EPA 200.7 Rev4.4 ESTAFFORD1ug/LUFe by ICP7439-89-6 10/22/195050 Hg 245.1 EPA 245.1 Rev3 ESTAFFORD1ug/LUHg 245.17439-97-6 9/18/190.2 0.20 Mg by ICP EPA 200.7 Rev4.4 ESTAFFORD1mg/LMg by ICP7439-95-4 10/22/190.10 4.3 Mn by ICP EPA 200.7 Rev4.4 ESTAFFORD1ug/LUMn by ICP7439-96-5 10/22/191010 Na by ICP EPA 200.7 Rev4.4 ESTAFFORD1mg/LNa by ICP7440-23-5 10/22/190.10 6.6 Pb by ICPMS WSS Chemistry Laboratory>> 1623 Mail Service Center, Raleigh, NC 27699-1623 (919) 733-3908 Page 1 of 2 "Not Detected" or "U" does not indicate the sample is analyte free but that the analyte is not detected at or above the PQL. AC67629Sample ID: NC DWR Laboratory Section Results/Sample Comments/Qualifier Definitions CAS #Analyte Name PQL Result/ Qualifier Units Method Reference Analysis Date Validated by EPA 200.8 Rev5.4 ESTAFFORD1ug/LUPb by ICPMS7439-92-1 10/10/192.0 2.0 Sr by ICPMS EPA 200.8 Rev5.4 ESTAFFORD1ug/LSr by ICPMS7440-24-6 10/10/191086 Zn by ICPMS EPA 200.8 Rev5.4 ESTAFFORD1ug/LUZn by ICPMS7440-66-6 10/10/191010 NUT NH3 as N in liquid EPA 350.1 REV 2 MIBRAHIM1mg/L as NUNH3 as N in liquid 9/17/190.02 0.02 NO2+NO3 as N in liquid EPA 353.2 REV 2 MIBRAHIM1mg/L as NNO2+NO3 as N in liquid 9/17/190.02 4.4 Phosphorus_total as P in liquid EPA 365.1 REV 2 MIBRAHIM1mg/L as PUPhosphorus_total as P in liquid 9/20/190.02 0.02 Total Kjeldahl N as N in liquid EPA 351.2 REV 2 MIBRAHIM1mg/L as NUTotal Kjeldahl N as N in liquid 9/30/190.2 0.20 WSS Chemistry Laboratory>> 1623 Mail Service Center, Raleigh, NC 27699-1623 (919) 733-3908 Page 2 of 2 "Not Detected" or "U" does not indicate the sample is analyte free but that the analyte is not detected at or above the PQL. PO Number # Loc. Descr.:Blue Ridge Tissue - 1427 Yadkin River Road Lenoir, NC Loc. Type:MONITORING WELL Collector:B LAVERTY Collect Date:09/03/2019 Collect Time:12:04 Date Received:09/05/2019 Time Received:08:20 Location ID:1P14BLUERIDGEMW6 County:Caldwell Region:Asheville Labworks LoginID TASCENZO1Sample Matrix:GROUNDWATER Report Print Date: North Carolina Division of Water Resources Water Sciences Section Laboratory Results VisitID Sample Depth AROReport To River Basin 01/09/2020 Emergency COC Yes/No Sample ID:AC67630 11/6/19Final Report Date: Final Report If this report is labeled preliminary report, the results have not been validated. Do not use for Regulatory purposes. NC CourierDelivery Method ROUTINEPriority AC67630 Analysis Date Method Reference Result/ QualifierPQLAnalyte NameCAS #Units Validated by LAB Sample temperature at receipt by lab MSWIFT°CSample temperature at receipt by lab 9/5/191.1 MET As by ICPMS EPA 200.8 Rev5.4 ESTAFFORD1ug/LUAs by ICPMS7440-38-2 10/10/192.0 2.0 Ba by ICP EPA 200.7 Rev4.4 ESTAFFORD1ug/LBa by ICP7440-38-3 10/22/191088 Ca by ICP EPA 200.7 Rev4.4 ESTAFFORD1mg/LCa by ICP7440-70-2 10/22/190.10 0.92 Cd by ICPMS EPA 200.8 Rev5.4 ESTAFFORD1ug/LUCd by ICPMS7440-43-9 10/10/190.50 0.50 Cobalt by ICP EPA 200.7 Rev4.4 ESTAFFORD1ug/LUCobalt by ICP7440-48-4 10/22/195050 Cr by ICPMS EPA 200.8 Rev5.4 ESTAFFORD1ug/LUCr by ICPMS7440-47-3 10/10/195.0 5.0 Cu by ICPMS EPA 200.8 Rev5.4 ESTAFFORD1ug/LUCu by ICPMS7440-50-8 10/10/192.0 2.0 Fe by ICP EPA 200.7 Rev4.4 ESTAFFORD1ug/LUFe by ICP7439-89-6 10/22/195050 Hg 245.1 EPA 245.1 Rev3 ESTAFFORD1ug/LUHg 245.17439-97-6 9/18/190.2 0.20 Mg by ICP EPA 200.7 Rev4.4 ESTAFFORD1mg/LMg by ICP7439-95-4 10/22/190.10 0.24 Mn by ICP EPA 200.7 Rev4.4 ESTAFFORD1ug/LMn by ICP7439-96-5 10/22/191067 Na by ICP EPA 200.7 Rev4.4 ESTAFFORD1mg/LNa by ICP7440-23-5 10/22/190.10 2.3 Pb by ICPMS WSS Chemistry Laboratory>> 1623 Mail Service Center, Raleigh, NC 27699-1623 (919) 733-3908 Page 1 of 2 "Not Detected" or "U" does not indicate the sample is analyte free but that the analyte is not detected at or above the PQL. AC67630Sample ID: NC DWR Laboratory Section Results/Sample Comments/Qualifier Definitions CAS #Analyte Name PQL Result/ Qualifier Units Method Reference Analysis Date Validated by EPA 200.8 Rev5.4 ESTAFFORD1ug/LUPb by ICPMS7439-92-1 10/10/192.0 2.0 Sr by ICPMS EPA 200.8 Rev5.4 ESTAFFORD1ug/LSr by ICPMS7440-24-6 10/10/191036 Zn by ICPMS EPA 200.8 Rev5.4 ESTAFFORD1ug/LUZn by ICPMS7440-66-6 10/10/191010 NUT NH3 as N in liquid EPA 350.1 REV 2 MIBRAHIM1mg/L as NUNH3 as N in liquid 9/17/190.02 0.02 NO2+NO3 as N in liquid EPA 353.2 REV 2 MIBRAHIM1mg/L as NUNO2+NO3 as N in liquid 9/17/190.02 0.02 Phosphorus_total as P in liquid EPA 365.1 REV 2 MIBRAHIM1mg/L as PUPhosphorus_total as P in liquid 9/20/190.02 0.02 Total Kjeldahl N as N in liquid EPA 351.2 REV 2 MIBRAHIM1mg/L as NUTotal Kjeldahl N as N in liquid 9/30/190.2 0.20 WSS Chemistry Laboratory>> 1623 Mail Service Center, Raleigh, NC 27699-1623 (919) 733-3908 Page 2 of 2 "Not Detected" or "U" does not indicate the sample is analyte free but that the analyte is not detected at or above the PQL. PO Number # Loc. Descr.:Blue Ridge Tissue - 1427 Yadkin River Road Lenoir, NC Loc. Type:MONITORING WELL Collector:B LAVERTY Collect Date:09/03/2019 Collect Time:12:30 Date Received:09/05/2019 Time Received:08:20 Location ID:1P14BLUERIDGEMW7 County:Caldwell Region:Asheville Labworks LoginID TASCENZO1Sample Matrix:GROUNDWATER Report Print Date: North Carolina Division of Water Resources Water Sciences Section Laboratory Results VisitID Sample Depth AROReport To River Basin 01/09/2020 Emergency COC Yes/No Sample ID:AC67631 11/6/19Final Report Date: Final Report If this report is labeled preliminary report, the results have not been validated. Do not use for Regulatory purposes. NC CourierDelivery Method ROUTINEPriority AC67631 Analysis Date Method Reference Result/ QualifierPQLAnalyte NameCAS #Units Validated by LAB Sample temperature at receipt by lab MSWIFT°CSample temperature at receipt by lab 9/5/191.1 MET As by ICPMS EPA 200.8 Rev5.4 ESTAFFORD1ug/LUAs by ICPMS7440-38-2 10/10/192.0 2.0 Ba by ICP EPA 200.7 Rev4.4 ESTAFFORD1ug/LBa by ICP7440-38-3 10/22/191058 Ca by ICP EPA 200.7 Rev4.4 ESTAFFORD1mg/LCa by ICP7440-70-2 10/22/190.10 14 Cd by ICPMS EPA 200.8 Rev5.4 ESTAFFORD1ug/LUCd by ICPMS7440-43-9 10/10/190.50 0.50 Cobalt by ICP EPA 200.7 Rev4.4 ESTAFFORD1ug/LUCobalt by ICP7440-48-4 10/22/195050 Cr by ICPMS EPA 200.8 Rev5.4 ESTAFFORD1ug/LUCr by ICPMS7440-47-3 10/10/195.0 5.0 Cu by ICPMS EPA 200.8 Rev5.4 ESTAFFORD1ug/LUCu by ICPMS7440-50-8 10/10/192.0 2.0 Fe by ICP EPA 200.7 Rev4.4 ESTAFFORD1ug/LUFe by ICP7439-89-6 10/22/195050 Hg 245.1 EPA 245.1 Rev3 ESTAFFORD1ug/LUHg 245.17439-97-6 9/18/190.2 0.20 Mg by ICP EPA 200.7 Rev4.4 ESTAFFORD1mg/LMg by ICP7439-95-4 10/22/190.10 1.3 Mn by ICP EPA 200.7 Rev4.4 ESTAFFORD1ug/LUMn by ICP7439-96-5 10/22/191010 Na by ICP EPA 200.7 Rev4.4 ESTAFFORD1mg/LNa by ICP7440-23-5 10/22/190.10 5.4 Pb by ICPMS WSS Chemistry Laboratory>> 1623 Mail Service Center, Raleigh, NC 27699-1623 (919) 733-3908 Page 1 of 2 "Not Detected" or "U" does not indicate the sample is analyte free but that the analyte is not detected at or above the PQL. AC67631Sample ID: NC DWR Laboratory Section Results/Sample Comments/Qualifier Definitions CAS #Analyte Name PQL Result/ Qualifier Units Method Reference Analysis Date Validated by EPA 200.8 Rev5.4 ESTAFFORD1ug/LUPb by ICPMS7439-92-1 10/10/192.0 2.0 Sr by ICPMS EPA 200.8 Rev5.4 ESTAFFORD1ug/LSr by ICPMS7440-24-6 10/10/1910130 Zn by ICPMS EPA 200.8 Rev5.4 ESTAFFORD1ug/LUZn by ICPMS7440-66-6 10/10/191010 NUT NH3 as N in liquid EPA 350.1 REV 2 MIBRAHIM1mg/L as NUNH3 as N in liquid 9/17/190.02 0.02 NO2+NO3 as N in liquid EPA 353.2 REV 2 MIBRAHIM1mg/L as NNO2+NO3 as N in liquid 9/17/190.02 1.0 Phosphorus_total as P in liquid EPA 365.1 REV 2 MIBRAHIM1mg/L as PPhosphorus_total as P in liquid 9/20/190.02 0.04 Total Kjeldahl N as N in liquid EPA 351.2 REV 2 MIBRAHIM1mg/L as NUTotal Kjeldahl N as N in liquid 9/30/190.2 0.20 WSS Chemistry Laboratory>> 1623 Mail Service Center, Raleigh, NC 27699-1623 (919) 733-3908 Page 2 of 2 "Not Detected" or "U" does not indicate the sample is analyte free but that the analyte is not detected at or above the PQL. PO Number # Loc. Descr.:Blue Ridge Tissue - 1427 Yadkin River Road Lenoir, NC Loc. Type:MONITORING WELL Collector:B LAVERTY Collect Date:09/03/2019 Collect Time:12:57 Date Received:09/05/2019 Time Received:08:20 Location ID:1P14BLUERIDGEMW4 County:Caldwell Region:Asheville Labworks LoginID TASCENZO1Sample Matrix:GROUNDWATER Report Print Date: North Carolina Division of Water Resources Water Sciences Section Laboratory Results VisitID Sample Depth AROReport To River Basin 01/09/2020 Emergency COC Yes/No Sample ID:AC67632 11/6/19Final Report Date: Final Report If this report is labeled preliminary report, the results have not been validated. Do not use for Regulatory purposes. NC CourierDelivery Method ROUTINEPriority AC67632 Analysis Date Method Reference Result/ QualifierPQLAnalyte NameCAS #Units Validated by LAB Sample temperature at receipt by lab MSWIFT°CSample temperature at receipt by lab 9/5/191.1 MET As by ICPMS EPA 200.8 Rev5.4 ESTAFFORD1ug/LAs by ICPMS7440-38-2 10/10/192.0 2.2 Ba by ICP EPA 200.7 Rev4.4 ESTAFFORD1ug/LBa by ICP7440-38-3 10/22/191092 Ca by ICP EPA 200.7 Rev4.4 ESTAFFORD1mg/LCa by ICP7440-70-2 10/22/190.10 30 Cd by ICPMS EPA 200.8 Rev5.4 ESTAFFORD1ug/LUCd by ICPMS7440-43-9 10/10/190.50 0.50 Cobalt by ICP EPA 200.7 Rev4.4 ESTAFFORD1ug/LUCobalt by ICP7440-48-4 10/22/195050 Cr by ICPMS EPA 200.8 Rev5.4 ESTAFFORD1ug/LUCr by ICPMS7440-47-3 10/10/195.0 5.0 Cu by ICPMS EPA 200.8 Rev5.4 ESTAFFORD1ug/LUCu by ICPMS7440-50-8 10/10/192.0 2.0 Fe by ICP EPA 200.7 Rev4.4 ESTAFFORD1ug/LFe by ICP7439-89-6 10/22/195012000 Hg 245.1 EPA 245.1 Rev3 ESTAFFORD1ug/LUHg 245.17439-97-6 9/18/190.2 0.20 Mg by ICP EPA 200.7 Rev4.4 ESTAFFORD1mg/LMg by ICP7439-95-4 10/22/190.10 4.0 Mn by ICP EPA 200.7 Rev4.4 ESTAFFORD1ug/LMn by ICP7439-96-5 10/22/19101100 Na by ICP EPA 200.7 Rev4.4 ESTAFFORD1mg/LNa by ICP7440-23-5 10/22/190.10 18 Pb by ICPMS WSS Chemistry Laboratory>> 1623 Mail Service Center, Raleigh, NC 27699-1623 (919) 733-3908 Page 1 of 2 "Not Detected" or "U" does not indicate the sample is analyte free but that the analyte is not detected at or above the PQL. AC67632Sample ID: NC DWR Laboratory Section Results/Sample Comments/Qualifier Definitions CAS #Analyte Name PQL Result/ Qualifier Units Method Reference Analysis Date Validated by EPA 200.8 Rev5.4 ESTAFFORD1ug/LUPb by ICPMS7439-92-1 10/10/192.0 2.0 Sr by ICPMS EPA 200.8 Rev5.4 ESTAFFORD1ug/LSr by ICPMS7440-24-6 10/10/1910260 Zn by ICPMS EPA 200.8 Rev5.4 ESTAFFORD1ug/LZn by ICPMS7440-66-6 10/10/191010 NUT NH3 as N in liquid EPA 350.1 REV 2 MIBRAHIM1mg/L as NNH3 as N in liquid 9/17/190.02 0.62 NO2+NO3 as N in liquid EPA 353.2 REV 2 MIBRAHIM1mg/L as NUNO2+NO3 as N in liquid 9/17/190.02 0.02 Phosphorus_total as P in liquid EPA 365.1 REV 2 MIBRAHIM1mg/L as PPhosphorus_total as P in liquid 9/20/190.02 0.35 Total Kjeldahl N as N in liquid EPA 351.2 REV 2 MIBRAHIM1mg/L as NTotal Kjeldahl N as N in liquid 9/30/190.2 1.0 WSS Chemistry Laboratory>> 1623 Mail Service Center, Raleigh, NC 27699-1623 (919) 733-3908 Page 2 of 2 "Not Detected" or "U" does not indicate the sample is analyte free but that the analyte is not detected at or above the PQL. Tag ID Laboratory Sample Number: River/Stream Estuary Stormwater State Courier Hand Delivery Waste Effluent Influent Grab Composite Field Blank Filter Blank Filtered in Field Solution Other: mg/L µg/L mg/L mg/L µg/L µg/L mg/L µg/L µg/L µg/L mg/L mg/L X µg/L X µg/L mg/L mg/L X µg/L /100ml mg/L µg/L µg/L /100ml mg/L X µg/L ng/L /100ml mg/L X mg/L /100ml mg/L X µg/L umhos/cm mg/L X µg/L mg/L mg/L X µg/L NTU X µg/L X µg/L s.u.µg/L Bromide mg/L mg/L X mg/L Chloride mg/L X µg/L Fluoride mg/L X µg/L Sulfate mg/L µg/L µg/L X mg/L µg/L c.u.X mg/L mg/L c.u.X mg/L µg/L mg/L X mg/L µg/L mg/L mg/L X mg/L mg/L mg/L X µg/L mg/L mg/L µg/L Water Temp (oC): 9:16 AM Water Sample Collection & Submittal Form Visit ID: (optional)MW-1 1 Conductivity (µmhos/cm): Lab Use Only: Temperature (°C) on Arrival : Total Phosphorus as P (TP) Silver (Ag) Sodium (Na) Strontium (Sr) Beryllium (Be) QA Water Matrix: Ground Surface Location Code: Coliform: Total MF Caldwell Aluminum (Al) MBAS (surfactants) Method: Sampling Received By: Residue: Total (Total Solids ) Residue: Volatile/Fixed, Total Residue: Suspended (Suspended Solids ) Residue: Volatile/Fixed, Suspended Antimony (Sb) Arsenic (As) Barium (Ba) Cadmium (Cd) Notes: Date Received: Time Received: Location Description: Vanadium (V) Zinc (Zn) Blue Ridge Tissue - 1427 Yadkin River Road Lenoir, NC Monitoring well MW-1 1P14BLUERIDGEMW1 Location Type: Trip Blank Priority: Time: Lake Canal Emergency Other: Monitoring Well Water Supply Collector: Date: DWR Office: (or agency name) Phytoplankton / Algae North Carolina Division of Water Resources Central Laboratory (Water Sciences Section) Brett Laverty Regional Operations 9/3/2019 Routine Compliance COC Organics Parameters: Biological: Other Parameters: Hardness, Total as CaCO3 - by titration Tin (Sn) Microbiology Parameters:Metals Parameters: River Basin: Ambient County: DWR Region: (based on county) Dissolved Oxygen (ppm): Asheville Revision: 2/06/2015 LAB COMMENTS : Ammonia as N (NH3-N) Nitrate-Nitrite as N (NO3+NO2-N) Nitrite as N (NO2-N) Nutrients Parameters: Mercury (Hg) Chlorophyll a Color: ADMI Color: Platinum Cobalt Total Kjeldahl Nitrogen as N (TKN) Nitrate as N (NO3-N calculated) Orthophosphate as P (PO4) COD: Chemical Oxygen Demand Cyanide, Total Formaldehyde Hexavalent Chromium (Cr6+) pH (s.u.): Thallium (Tl) Potassium (K) Delivery Method: Field Parameters(optional): Wet Chemistry Parameters: Oil and Grease, HEM, Total Recoverable pH Acid Herbicides Organochlorine Pesticides Organonitrogen Pesticides Acidity, as CaCO3, to pH 4.5/8.3 Alkalinity, as CaCO3, to pH 4.5/8.3 BOD: Biochemical Oxygen Demand, 5-day cBOD: Carbonaceous BOD, 5-day Coliform: Fecal MF Titanium (Ti) Phenols, Total Recoverable Salinity (ppt): Other: Molybdenum (Mo) Nickel (Ni) Selenium (Se) Copper (Cu) Iron (Fe) Lead (Pb) Organophosphorus Pesticides PCBs (polychlorinated biphenyls) Semi-Volatile Organics (BNAs) Lithium (Li) Blank Magnesium (Mg) Manganese (Mn) TPH Diesel Range Volatile Organics (VOA) TPH Gasoline Range Turbidity Coliform: Tube Fecal Coliform: Tube Total Specific Conductance, at 25 oC TOC - Total Organic Carbon Sample Depth: Calcium (Ca) Chromium (Cr), Total Cobalt (Co) Collector's Comments: TDS - Total Dissolved Solids Silica Sulfide Mercury 1631, low-level Boron (B), Total Tannin & Lignin Chlorinated Dissolved analysis: Enter "DIS" in check-boxes for parameters De-chlorinated in Field Tag ID Laboratory Sample Number: River/Stream Estuary Stormwater State Courier Hand Delivery Waste Effluent Influent Grab Composite Field Blank Filter Blank Filtered in Field Solution Other: mg/L µg/L mg/L mg/L µg/L µg/L mg/L µg/L µg/L µg/L mg/L mg/L X µg/L X µg/L mg/L mg/L X µg/L /100ml mg/L µg/L µg/L /100ml mg/L X µg/L ng/L /100ml mg/L X mg/L /100ml mg/L X µg/L umhos/cm mg/L X µg/L mg/L mg/L X µg/L NTU X µg/L X µg/L s.u.µg/L Bromide mg/L mg/L X mg/L Chloride mg/L X µg/L Fluoride mg/L X µg/L Sulfate mg/L µg/L µg/L X mg/L µg/L c.u.X mg/L mg/L c.u.X mg/L µg/L mg/L X mg/L µg/L mg/L mg/L X mg/L mg/L mg/L X µg/L mg/L mg/L µg/L Water Temp (oC): 10:10 AM Water Sample Collection & Submittal Form Visit ID: (optional)MW-3 2 Conductivity (µmhos/cm): Lab Use Only: Temperature (°C) on Arrival : Total Phosphorus as P (TP) Silver (Ag) Sodium (Na) Strontium (Sr) Beryllium (Be) QA Water Matrix: Ground Surface Location Code: Coliform: Total MF Caldwell Aluminum (Al) MBAS (surfactants) Method: Sampling Received By: Residue: Total (Total Solids ) Residue: Volatile/Fixed, Total Residue: Suspended (Suspended Solids ) Residue: Volatile/Fixed, Suspended Antimony (Sb) Arsenic (As) Barium (Ba) Cadmium (Cd) Notes: Date Received: Time Received: Location Description: Vanadium (V) Zinc (Zn) Blue Ridge Tissue - 1427 Yadkin River Road Lenoir, NC Monitoring well MW-3 1P14BLUERIDGEMW3 Location Type: Trip Blank Priority: Time: Lake Canal Emergency Other: Monitoring Well Water Supply Collector: Date: DWR Office: (or agency name) Phytoplankton / Algae North Carolina Division of Water Resources Central Laboratory (Water Sciences Section) Brett Laverty Regional Operations 9/3/2019 Routine Compliance COC Organics Parameters: Biological: Other Parameters: Hardness, Total as CaCO3 - by titration Tin (Sn) Microbiology Parameters:Metals Parameters: River Basin: Ambient County: DWR Region: (based on county) Dissolved Oxygen (ppm): Asheville Revision: 2/06/2015 LAB COMMENTS : Ammonia as N (NH3-N) Nitrate-Nitrite as N (NO3+NO2-N) Nitrite as N (NO2-N) Nutrients Parameters: Mercury (Hg) Chlorophyll a Color: ADMI Color: Platinum Cobalt Total Kjeldahl Nitrogen as N (TKN) Nitrate as N (NO3-N calculated) Orthophosphate as P (PO4) COD: Chemical Oxygen Demand Cyanide, Total Formaldehyde Hexavalent Chromium (Cr6+) pH (s.u.): Thallium (Tl) Potassium (K) Delivery Method: Field Parameters(optional): Wet Chemistry Parameters: Oil and Grease, HEM, Total Recoverable pH Acid Herbicides Organochlorine Pesticides Organonitrogen Pesticides Acidity, as CaCO3, to pH 4.5/8.3 Alkalinity, as CaCO3, to pH 4.5/8.3 BOD: Biochemical Oxygen Demand, 5-day cBOD: Carbonaceous BOD, 5-day Coliform: Fecal MF Titanium (Ti) Phenols, Total Recoverable Salinity (ppt): Other: Molybdenum (Mo) Nickel (Ni) Selenium (Se) Copper (Cu) Iron (Fe) Lead (Pb) Organophosphorus Pesticides PCBs (polychlorinated biphenyls) Semi-Volatile Organics (BNAs) Lithium (Li) Blank Magnesium (Mg) Manganese (Mn) TPH Diesel Range Volatile Organics (VOA) TPH Gasoline Range Turbidity Coliform: Tube Fecal Coliform: Tube Total Specific Conductance, at 25 oC TOC - Total Organic Carbon Sample Depth: Calcium (Ca) Chromium (Cr), Total Cobalt (Co) Collector's Comments: TDS - Total Dissolved Solids Silica Sulfide Mercury 1631, low-level Boron (B), Total Tannin & Lignin Chlorinated Dissolved analysis: Enter "DIS" in check-boxes for parameters De-chlorinated in Field Tag ID Laboratory Sample Number: River/Stream Estuary Stormwater State Courier Hand Delivery Waste Effluent Influent Grab Composite Field Blank Filter Blank Filtered in Field Solution Other: mg/L µg/L mg/L mg/L µg/L µg/L mg/L µg/L µg/L µg/L mg/L mg/L X µg/L X µg/L mg/L mg/L X µg/L /100ml mg/L µg/L µg/L /100ml mg/L X µg/L ng/L /100ml mg/L X mg/L /100ml mg/L X µg/L umhos/cm mg/L X µg/L mg/L mg/L X µg/L NTU X µg/L X µg/L s.u.µg/L Bromide mg/L mg/L X mg/L Chloride mg/L X µg/L Fluoride mg/L X µg/L Sulfate mg/L µg/L µg/L X mg/L µg/L c.u.X mg/L mg/L c.u.X mg/L µg/L mg/L X mg/L µg/L mg/L mg/L X mg/L mg/L mg/L X µg/L mg/L mg/L µg/L Water Temp (oC): 10:39 AM Water Sample Collection & Submittal Form Visit ID: (optional)MW-2 3 Conductivity (µmhos/cm): Lab Use Only: Temperature (°C) on Arrival : Total Phosphorus as P (TP) Silver (Ag) Sodium (Na) Strontium (Sr) Beryllium (Be) QA Water Matrix: Ground Surface Location Code: Coliform: Total MF Caldwell Aluminum (Al) MBAS (surfactants) Method: Sampling Received By: Residue: Total (Total Solids ) Residue: Volatile/Fixed, Total Residue: Suspended (Suspended Solids ) Residue: Volatile/Fixed, Suspended Antimony (Sb) Arsenic (As) Barium (Ba) Cadmium (Cd) Notes: Date Received: Time Received: Location Description: Vanadium (V) Zinc (Zn) Blue Ridge Tissue - 1427 Yadkin River Road Lenoir, NC Monitoring well MW-2 1P14BLUERIDGEMW2 Location Type: Trip Blank Priority: Time: Lake Canal Emergency Other: Monitoring Well Water Supply Collector: Date: DWR Office: (or agency name) Phytoplankton / Algae North Carolina Division of Water Resources Central Laboratory (Water Sciences Section) Brett Laverty Regional Operations 9/3/2019 Routine Compliance COC Organics Parameters: Biological: Other Parameters: Hardness, Total as CaCO3 - by titration Tin (Sn) Microbiology Parameters:Metals Parameters: River Basin: Ambient County: DWR Region: (based on county) Dissolved Oxygen (ppm): Asheville Revision: 2/06/2015 LAB COMMENTS : Ammonia as N (NH3-N) Nitrate-Nitrite as N (NO3+NO2-N) Nitrite as N (NO2-N) Nutrients Parameters: Mercury (Hg) Chlorophyll a Color: ADMI Color: Platinum Cobalt Total Kjeldahl Nitrogen as N (TKN) Nitrate as N (NO3-N calculated) Orthophosphate as P (PO4) COD: Chemical Oxygen Demand Cyanide, Total Formaldehyde Hexavalent Chromium (Cr6+) pH (s.u.): Thallium (Tl) Potassium (K) Delivery Method: Field Parameters(optional): Wet Chemistry Parameters: Oil and Grease, HEM, Total Recoverable pH Acid Herbicides Organochlorine Pesticides Organonitrogen Pesticides Acidity, as CaCO3, to pH 4.5/8.3 Alkalinity, as CaCO3, to pH 4.5/8.3 BOD: Biochemical Oxygen Demand, 5-day cBOD: Carbonaceous BOD, 5-day Coliform: Fecal MF Titanium (Ti) Phenols, Total Recoverable Salinity (ppt): Other: Molybdenum (Mo) Nickel (Ni) Selenium (Se) Copper (Cu) Iron (Fe) Lead (Pb) Organophosphorus Pesticides PCBs (polychlorinated biphenyls) Semi-Volatile Organics (BNAs) Lithium (Li) Blank Magnesium (Mg) Manganese (Mn) TPH Diesel Range Volatile Organics (VOA) TPH Gasoline Range Turbidity Coliform: Tube Fecal Coliform: Tube Total Specific Conductance, at 25 oC TOC - Total Organic Carbon Sample Depth: Calcium (Ca) Chromium (Cr), Total Cobalt (Co) Collector's Comments: TDS - Total Dissolved Solids Silica Sulfide Mercury 1631, low-level Boron (B), Total Tannin & Lignin Chlorinated Dissolved analysis: Enter "DIS" in check-boxes for parameters De-chlorinated in Field Tag ID Laboratory Sample Number: River/Stream Estuary Stormwater State Courier Hand Delivery Waste Effluent Influent Grab Composite Field Blank Filter Blank Filtered in Field Solution Other: mg/L µg/L mg/L mg/L µg/L µg/L mg/L µg/L µg/L µg/L mg/L mg/L X µg/L X µg/L mg/L mg/L X µg/L /100ml mg/L µg/L µg/L /100ml mg/L X µg/L ng/L /100ml mg/L X mg/L /100ml mg/L X µg/L umhos/cm mg/L X µg/L mg/L mg/L X µg/L NTU X µg/L X µg/L s.u.µg/L Bromide mg/L mg/L X mg/L Chloride mg/L X µg/L Fluoride mg/L X µg/L Sulfate mg/L µg/L µg/L X mg/L µg/L c.u.X mg/L mg/L c.u.X mg/L µg/L mg/L X mg/L µg/L mg/L mg/L X mg/L mg/L mg/L X µg/L mg/L mg/L µg/L Water Temp (oC): 11:28 AM Water Sample Collection & Submittal Form Visit ID: (optional)MW-8 4 Conductivity (µmhos/cm): Lab Use Only: Temperature (°C) on Arrival : Total Phosphorus as P (TP) Silver (Ag) Sodium (Na) Strontium (Sr) Beryllium (Be) QA Water Matrix: Ground Surface Location Code: Coliform: Total MF Caldwell Aluminum (Al) MBAS (surfactants) Method: Sampling Received By: Residue: Total (Total Solids ) Residue: Volatile/Fixed, Total Residue: Suspended (Suspended Solids ) Residue: Volatile/Fixed, Suspended Antimony (Sb) Arsenic (As) Barium (Ba) Cadmium (Cd) Notes: Date Received: Time Received: Location Description: Vanadium (V) Zinc (Zn) Blue Ridge Tissue - 1427 Yadkin River Road Lenoir, NC Monitoring well MW-8 1P14BLUERIDGEMW8 Location Type: Trip Blank Priority: Time: Lake Canal Emergency Other: Monitoring Well Water Supply Collector: Date: DWR Office: (or agency name) Phytoplankton / Algae North Carolina Division of Water Resources Central Laboratory (Water Sciences Section) Brett Laverty Regional Operations 9/3/2019 Routine Compliance COC Organics Parameters: Biological: Other Parameters: Hardness, Total as CaCO3 - by titration Tin (Sn) Microbiology Parameters:Metals Parameters: River Basin: Ambient County: DWR Region: (based on county) Dissolved Oxygen (ppm): Asheville Revision: 2/06/2015 LAB COMMENTS : Ammonia as N (NH3-N) Nitrate-Nitrite as N (NO3+NO2-N) Nitrite as N (NO2-N) Nutrients Parameters: Mercury (Hg) Chlorophyll a Color: ADMI Color: Platinum Cobalt Total Kjeldahl Nitrogen as N (TKN) Nitrate as N (NO3-N calculated) Orthophosphate as P (PO4) COD: Chemical Oxygen Demand Cyanide, Total Formaldehyde Hexavalent Chromium (Cr6+) pH (s.u.): Thallium (Tl) Potassium (K) Delivery Method: Field Parameters(optional): Wet Chemistry Parameters: Oil and Grease, HEM, Total Recoverable pH Acid Herbicides Organochlorine Pesticides Organonitrogen Pesticides Acidity, as CaCO3, to pH 4.5/8.3 Alkalinity, as CaCO3, to pH 4.5/8.3 BOD: Biochemical Oxygen Demand, 5-day cBOD: Carbonaceous BOD, 5-day Coliform: Fecal MF Titanium (Ti) Phenols, Total Recoverable Salinity (ppt): Other: Molybdenum (Mo) Nickel (Ni) Selenium (Se) Copper (Cu) Iron (Fe) Lead (Pb) Organophosphorus Pesticides PCBs (polychlorinated biphenyls) Semi-Volatile Organics (BNAs) Lithium (Li) Blank Magnesium (Mg) Manganese (Mn) TPH Diesel Range Volatile Organics (VOA) TPH Gasoline Range Turbidity Coliform: Tube Fecal Coliform: Tube Total Specific Conductance, at 25 oC TOC - Total Organic Carbon Sample Depth: Calcium (Ca) Chromium (Cr), Total Cobalt (Co) Collector's Comments: TDS - Total Dissolved Solids Silica Sulfide Mercury 1631, low-level Boron (B), Total Tannin & Lignin Chlorinated Dissolved analysis: Enter "DIS" in check-boxes for parameters De-chlorinated in Field Tag ID Laboratory Sample Number: River/Stream Estuary Stormwater State Courier Hand Delivery Waste Effluent Influent Grab Composite Field Blank Filter Blank Filtered in Field Solution Other: mg/L µg/L mg/L mg/L µg/L µg/L mg/L µg/L µg/L µg/L mg/L mg/L X µg/L X µg/L mg/L mg/L X µg/L /100ml mg/L µg/L µg/L /100ml mg/L X µg/L ng/L /100ml mg/L X mg/L /100ml mg/L X µg/L umhos/cm mg/L X µg/L mg/L mg/L X µg/L NTU X µg/L X µg/L s.u.µg/L Bromide mg/L mg/L X mg/L Chloride mg/L X µg/L Fluoride mg/L X µg/L Sulfate mg/L µg/L µg/L X mg/L µg/L c.u.X mg/L mg/L c.u.X mg/L µg/L mg/L X mg/L µg/L mg/L mg/L X mg/L mg/L mg/L X µg/L mg/L mg/L µg/L Water Temp (oC): 12:04 PM Water Sample Collection & Submittal Form Visit ID: (optional)MW-6 5 Conductivity (µmhos/cm): Lab Use Only: Temperature (°C) on Arrival : Total Phosphorus as P (TP) Silver (Ag) Sodium (Na) Strontium (Sr) Beryllium (Be) QA Water Matrix: Ground Surface Location Code: Coliform: Total MF Caldwell Aluminum (Al) MBAS (surfactants) Method: Sampling Received By: Residue: Total (Total Solids ) Residue: Volatile/Fixed, Total Residue: Suspended (Suspended Solids ) Residue: Volatile/Fixed, Suspended Antimony (Sb) Arsenic (As) Barium (Ba) Cadmium (Cd) Notes: Date Received: Time Received: Location Description: Vanadium (V) Zinc (Zn) Blue Ridge Tissue - 1427 Yadkin River Road Lenoir, NC Monitoring well MW-6 1P14BLUERIDGEMW6 Location Type: Trip Blank Priority: Time: Lake Canal Emergency Other: Monitoring Well Water Supply Collector: Date: DWR Office: (or agency name) Phytoplankton / Algae North Carolina Division of Water Resources Central Laboratory (Water Sciences Section) Brett Laverty Regional Operations 9/3/2019 Routine Compliance COC Organics Parameters: Biological: Other Parameters: Hardness, Total as CaCO3 - by titration Tin (Sn) Microbiology Parameters:Metals Parameters: River Basin: Ambient County: DWR Region: (based on county) Dissolved Oxygen (ppm): Asheville Revision: 2/06/2015 LAB COMMENTS : Ammonia as N (NH3-N) Nitrate-Nitrite as N (NO3+NO2-N) Nitrite as N (NO2-N) Nutrients Parameters: Mercury (Hg) Chlorophyll a Color: ADMI Color: Platinum Cobalt Total Kjeldahl Nitrogen as N (TKN) Nitrate as N (NO3-N calculated) Orthophosphate as P (PO4) COD: Chemical Oxygen Demand Cyanide, Total Formaldehyde Hexavalent Chromium (Cr6+) pH (s.u.): Thallium (Tl) Potassium (K) Delivery Method: Field Parameters(optional): Wet Chemistry Parameters: Oil and Grease, HEM, Total Recoverable pH Acid Herbicides Organochlorine Pesticides Organonitrogen Pesticides Acidity, as CaCO3, to pH 4.5/8.3 Alkalinity, as CaCO3, to pH 4.5/8.3 BOD: Biochemical Oxygen Demand, 5-day cBOD: Carbonaceous BOD, 5-day Coliform: Fecal MF Titanium (Ti) Phenols, Total Recoverable Salinity (ppt): Other: Molybdenum (Mo) Nickel (Ni) Selenium (Se) Copper (Cu) Iron (Fe) Lead (Pb) Organophosphorus Pesticides PCBs (polychlorinated biphenyls) Semi-Volatile Organics (BNAs) Lithium (Li) Blank Magnesium (Mg) Manganese (Mn) TPH Diesel Range Volatile Organics (VOA) TPH Gasoline Range Turbidity Coliform: Tube Fecal Coliform: Tube Total Specific Conductance, at 25 oC TOC - Total Organic Carbon Sample Depth: Calcium (Ca) Chromium (Cr), Total Cobalt (Co) Collector's Comments: TDS - Total Dissolved Solids Silica Sulfide Mercury 1631, low-level Boron (B), Total Tannin & Lignin Chlorinated Dissolved analysis: Enter "DIS" in check-boxes for parameters De-chlorinated in Field Tag ID Laboratory Sample Number: River/Stream Estuary Stormwater State Courier Hand Delivery Waste Effluent Influent Grab Composite Field Blank Filter Blank Filtered in Field Solution Other: mg/L µg/L mg/L mg/L µg/L µg/L mg/L µg/L µg/L µg/L mg/L mg/L X µg/L X µg/L mg/L mg/L X µg/L /100ml mg/L µg/L µg/L /100ml mg/L X µg/L ng/L /100ml mg/L X mg/L /100ml mg/L X µg/L umhos/cm mg/L X µg/L mg/L mg/L X µg/L NTU X µg/L X µg/L s.u.µg/L Bromide mg/L mg/L X mg/L Chloride mg/L X µg/L Fluoride mg/L X µg/L Sulfate mg/L µg/L µg/L X mg/L µg/L c.u.X mg/L mg/L c.u.X mg/L µg/L mg/L X mg/L µg/L mg/L mg/L X mg/L mg/L mg/L X µg/L mg/L mg/L µg/L Water Temp (oC): 12:30 PM Water Sample Collection & Submittal Form Visit ID: (optional)MW-7 6 Conductivity (µmhos/cm): Lab Use Only: Temperature (°C) on Arrival : Total Phosphorus as P (TP) Silver (Ag) Sodium (Na) Strontium (Sr) Beryllium (Be) QA Water Matrix: Ground Surface Location Code: Coliform: Total MF Caldwell Aluminum (Al) MBAS (surfactants) Method: Sampling Received By: Residue: Total (Total Solids ) Residue: Volatile/Fixed, Total Residue: Suspended (Suspended Solids ) Residue: Volatile/Fixed, Suspended Antimony (Sb) Arsenic (As) Barium (Ba) Cadmium (Cd) Notes: Date Received: Time Received: Location Description: Vanadium (V) Zinc (Zn) Blue Ridge Tissue - 1427 Yadkin River Road Lenoir, NC Monitoring well MW-7 1P14BLUERIDGEMW7 Location Type: Trip Blank Priority: Time: Lake Canal Emergency Other: Monitoring Well Water Supply Collector: Date: DWR Office: (or agency name) Phytoplankton / Algae North Carolina Division of Water Resources Central Laboratory (Water Sciences Section) Brett Laverty Regional Operations 9/3/2019 Routine Compliance COC Organics Parameters: Biological: Other Parameters: Hardness, Total as CaCO3 - by titration Tin (Sn) Microbiology Parameters:Metals Parameters: River Basin: Ambient County: DWR Region: (based on county) Dissolved Oxygen (ppm): Asheville Revision: 2/06/2015 LAB COMMENTS : Ammonia as N (NH3-N) Nitrate-Nitrite as N (NO3+NO2-N) Nitrite as N (NO2-N) Nutrients Parameters: Mercury (Hg) Chlorophyll a Color: ADMI Color: Platinum Cobalt Total Kjeldahl Nitrogen as N (TKN) Nitrate as N (NO3-N calculated) Orthophosphate as P (PO4) COD: Chemical Oxygen Demand Cyanide, Total Formaldehyde Hexavalent Chromium (Cr6+) pH (s.u.): Thallium (Tl) Potassium (K) Delivery Method: Field Parameters(optional): Wet Chemistry Parameters: Oil and Grease, HEM, Total Recoverable pH Acid Herbicides Organochlorine Pesticides Organonitrogen Pesticides Acidity, as CaCO3, to pH 4.5/8.3 Alkalinity, as CaCO3, to pH 4.5/8.3 BOD: Biochemical Oxygen Demand, 5-day cBOD: Carbonaceous BOD, 5-day Coliform: Fecal MF Titanium (Ti) Phenols, Total Recoverable Salinity (ppt): Other: Molybdenum (Mo) Nickel (Ni) Selenium (Se) Copper (Cu) Iron (Fe) Lead (Pb) Organophosphorus Pesticides PCBs (polychlorinated biphenyls) Semi-Volatile Organics (BNAs) Lithium (Li) Blank Magnesium (Mg) Manganese (Mn) TPH Diesel Range Volatile Organics (VOA) TPH Gasoline Range Turbidity Coliform: Tube Fecal Coliform: Tube Total Specific Conductance, at 25 oC TOC - Total Organic Carbon Sample Depth: Calcium (Ca) Chromium (Cr), Total Cobalt (Co) Collector's Comments: TDS - Total Dissolved Solids Silica Sulfide Mercury 1631, low-level Boron (B), Total Tannin & Lignin Chlorinated Dissolved analysis: Enter "DIS" in check-boxes for parameters De-chlorinated in Field Tag ID Laboratory Sample Number: River/Stream Estuary Stormwater State Courier Hand Delivery Waste Effluent Influent Grab Composite Field Blank Filter Blank Filtered in Field Solution Other: mg/L µg/L mg/L mg/L µg/L µg/L mg/L µg/L µg/L µg/L mg/L mg/L X µg/L X µg/L mg/L mg/L X µg/L /100ml mg/L µg/L µg/L /100ml mg/L X µg/L ng/L /100ml mg/L X mg/L /100ml mg/L X µg/L umhos/cm mg/L X µg/L mg/L mg/L X µg/L NTU X µg/L X µg/L s.u.µg/L Bromide mg/L mg/L X mg/L Chloride mg/L X µg/L Fluoride mg/L X µg/L Sulfate mg/L µg/L µg/L X mg/L µg/L c.u.X mg/L mg/L c.u.X mg/L µg/L mg/L X mg/L µg/L mg/L mg/L X mg/L mg/L mg/L X µg/L mg/L mg/L µg/L Water Temp (oC): 12:57 AM Water Sample Collection & Submittal Form Visit ID: (optional)MW-4 7 Conductivity (µmhos/cm): Lab Use Only: Temperature (°C) on Arrival : Total Phosphorus as P (TP) Silver (Ag) Sodium (Na) Strontium (Sr) Beryllium (Be) QA Water Matrix: Ground Surface Location Code: Coliform: Total MF Caldwell Aluminum (Al) MBAS (surfactants) Method: Sampling Received By: Residue: Total (Total Solids ) Residue: Volatile/Fixed, Total Residue: Suspended (Suspended Solids ) Residue: Volatile/Fixed, Suspended Antimony (Sb) Arsenic (As) Barium (Ba) Cadmium (Cd) Notes: Date Received: Time Received: Location Description: Vanadium (V) Zinc (Zn) Blue Ridge Tissue - 1427 Yadkin River Road Lenoir, NC Monitoring well MW-4 1P14BLUERIDGEMW4 Location Type: Trip Blank Priority: Time: Lake Canal Emergency Other: Monitoring Well Water Supply Collector: Date: DWR Office: (or agency name) Phytoplankton / Algae North Carolina Division of Water Resources Central Laboratory (Water Sciences Section) Brett Laverty Regional Operations 9/3/2019 Routine Compliance COC Organics Parameters: Biological: Other Parameters: Hardness, Total as CaCO3 - by titration Tin (Sn) Microbiology Parameters:Metals Parameters: River Basin: Ambient County: DWR Region: (based on county) Dissolved Oxygen (ppm): Asheville Revision: 2/06/2015 LAB COMMENTS : Ammonia as N (NH3-N) Nitrate-Nitrite as N (NO3+NO2-N) Nitrite as N (NO2-N) Nutrients Parameters: Mercury (Hg) Chlorophyll a Color: ADMI Color: Platinum Cobalt Total Kjeldahl Nitrogen as N (TKN) Nitrate as N (NO3-N calculated) Orthophosphate as P (PO4) COD: Chemical Oxygen Demand Cyanide, Total Formaldehyde Hexavalent Chromium (Cr6+) pH (s.u.): Thallium (Tl) Potassium (K) Delivery Method: Field Parameters(optional): Wet Chemistry Parameters: Oil and Grease, HEM, Total Recoverable pH Acid Herbicides Organochlorine Pesticides Organonitrogen Pesticides Acidity, as CaCO3, to pH 4.5/8.3 Alkalinity, as CaCO3, to pH 4.5/8.3 BOD: Biochemical Oxygen Demand, 5-day cBOD: Carbonaceous BOD, 5-day Coliform: Fecal MF Titanium (Ti) Phenols, Total Recoverable Salinity (ppt): Other: Molybdenum (Mo) Nickel (Ni) Selenium (Se) Copper (Cu) Iron (Fe) Lead (Pb) Organophosphorus Pesticides PCBs (polychlorinated biphenyls) Semi-Volatile Organics (BNAs) Lithium (Li) Blank Magnesium (Mg) Manganese (Mn) TPH Diesel Range Volatile Organics (VOA) TPH Gasoline Range Turbidity Coliform: Tube Fecal Coliform: Tube Total Specific Conductance, at 25 oC TOC - Total Organic Carbon Sample Depth: Calcium (Ca) Chromium (Cr), Total Cobalt (Co) Collector's Comments: TDS - Total Dissolved Solids Silica Sulfide Mercury 1631, low-level Boron (B), Total Tannin & Lignin Chlorinated Dissolved analysis: Enter "DIS" in check-boxes for parameters De-chlorinated in Field