HomeMy WebLinkAboutNC0006254_Groundwater Monitoring Report April 2017_20170504Memorandum
AECOM
1600 Perimeter Park Drive
Suite 400
Morrisville, NC 27560
www.aecom.com
919.461.1100 tel
919.461.1415 fax
To Brett Laverty, NCDEQ Division of Water Resources, Water Quality
Regional Operations, Asheville Regional Office
Page 1
CC Dave Hallock, Blue Ridge Tissue Corporation
Subject Summary of April 2017 Groundwater Monitoring
Blue Ridge Tissue Corporation, Patterson, North Carolina
From Maureen Conorozzo and Elizabeth Maurer, AECOM
Date May 4, 2017
AECOM Technical Services of North Carolina, Inc. (AECOM) is submitting this memorandum on
behalf of Blue Ridge Tissue Corporation to summarize groundwater monitoring activities conducted
on April 13, 2017, at Blue Ridge Tissue Corporation’s facility located at 1427 Yadkin River Road in
Patterson (Lenoir), North Carolina.
AECOM gauged site monitoring wells MW-1 through MW-8 on April 13, 2017. Well locations are
shown on Figure 1. Depth to groundwater and groundwater elevation data, as measured during the
April 2017 event, are provided in Table 1. Groundwater elevations were similar to those measured
during previous sampling events and ranged from approximately 1,312 to 1,239 feet above mean
sea level. An analysis of groundwater flow direction will be provided in the annual groundwater
monitoring report.
Seven of the eight existing site monitoring wells were sampled during the April 2017 monitoring
event; sampling was not required for well MW-5. Monitoring wells were purged and sampled using
low-flow techniques utilizing a peristaltic pump at three of the wells (MW-1, MW-4, and MW-6) and a
bladder pump at three wells (MW-3, MW-7, and MW-8). During purging of each well, water quality
measurements were collected to evaluate well stabilization. Parameters for pH, specific
conductance, temperature, oxidation-reduction potential, and dissolved oxygen were measured
using a multi-parameter water quality meter (YSI 556) equipped with a flow-through cell, and
turbidity measurements were collected using a portable turbidity meter (Hanna HI-98703). Once
water quality parameters stabilized, a groundwater sample was collected in laboratory provided pre-
preserved sample containers, labeled, and placed on ice. One well (MW-2) was purged dry using a
disposable bailer because there was not enough water available in the well to allow use of a pump
for purging. The sample from MW-2 was collected from the bailer into a laboratory provided pre-
preserved sample container, labeled, and placed on ice. A duplicate sample was collected from well
MW-4 for quality assurance purposes. The groundwater samples were submitted to Prism
Laboratories, Inc. and analyzed for total iron, total manganese, and total barium.
During purging at MW-4, a slight visible sheen was observed in the purge water. No odor was
observed. Due to the slight nature of the sheen, observations of physical characteristics (i.e.
whether the sheen broke apart when disturbed, as is typical of bacterial sheen) did not provide a
conclusive indication as to the sheen’s origin. A sample was collected and submitted to Prism
Laboratories for analysis of benzene, toluene, ethylbenzene, and xylenes (BTEX) and total
petroleum hydrocarbons – diesel range organics (TPH-DRO) to assist in evaluating whether the
sheen was from a petroleum or natural source.
AECOM
2
Analytical data for the April 2017 event is shown in Table 2, and the laboratory report is provided in
Appendix A. Consistent with data collected from previous sampling events, the following items
summarize the data collected during the April 2017 groundwater sampling event:
Total iron exceeded the Title 15A North Carolina Administrative Code, Subchapter 2L
Groundwater Quality Standard (2L Standard) of 0.3 milligrams per liter (mg/L) in samples
collected from MW-1, MW-2, MW-3, and MW-4.
Total manganese exceeded the 2L Standard of 0.05 mg/L in samples collected from MW-
1, MW-2, MW-3, MW-4, and MW-6.
Total barium was detected in all of the wells sampled; however, concentrations exceeded
the 2L Standard of 0.7 mg/L in samples collected from MW-2 only.
The sample from background well MW-6 contained total manganese at a concentration
that slightly exceeded the 2L Standard. Total barium was detected in MW-6 at a
concentration below the 2L Standard. Total iron was not detected above the laboratory
reporting limit in MW-6.
Samples from property boundary monitoring wells MW-7 and MW-8 continue to be well
within compliance of 2L Standards.
A visible sheen was present in monitoring well MW-4. BTEX and TPH-DRO samples
were collected to determine if the sheen was from a petroleum source. No BTEX or TPH-
DRO constituents were detected above the laboratory reporting limits, indicating that the
sheen is not the result of a petroleum source. The sheen may be caused by iron bacteria
in the well.
Future 2017 sampling events are tentatively planned for July and November 2017, with a
comprehensive annual groundwater report anticipated in December 2017.
Sincerely yours,
Maureen Conorozzo, PG Elizabeth Maurer, PG
maureen.conorozzo@aecom.com elizabeth.maurer@aecom.com
Attachments
Tables
Table 1Monitoring Well Construction and Groundwater Elevation DataBlue Ridge Tissue Corporation - Patterson, North Carolina04/13/1712.411,241.3004/13/1752.041,270.9904/13/1719.731,279.2904/13/175.491,241.7404/13/1714.231,271.2304/13/1729.261,312.2904/13/1719.441,254.9704/13/1714.031,239.11Notes:bls - feet below land surfaceBTOC - below top of casingmsl - above mean sea levelNG - not gauged6-111253.71MW-2 08/12/095040-501323.03MW-1 02/08/11 11MW-8 08/06/142010-201253.14MW-6 08/06/142919-291341.55MW-7 08/06/142414-241274.41MW-4 08/13/09155-151247.23MW-5 08/16/112111-211285.46MW-3 08/13/092010-201299.02Depth to Water (feet BTOC)Groundwater Elevation (feet msl)Well ID Date InstalledTotal Depth (feet bls)Screened Interval (feet bls)Top of Casing Elevation (feet msl)Date Water Level MeasuredAECOM
Table 2Groundwater Analytical Results SummaryBlue Ridge Tissue Corporation - Patterson, North CarolinaSample ID Sample Date04/13/17 04/13/17 04/13/17 04/13/17DUP4/13/201704/13/17 04/13/17 04/13/17Field ParametersTemperature (°C) NS 17.27 - 21.09 19.01 19.01 21.81 18.22 18.67pH (standard units) NS 6.36 - 6.16 6.16 6.16 5.23 6.11 5.73Specific Conductance (µS/cm) NS 602 - 712 361 361 29 82 121Dissoved Oxygen (mg/L) NS 0.69 - 0.96 0.66 0.66 4.97 4.95 5.60ORP (mV) NS -31.3 - -4.9 -16.0 -16.0 23.9 80.4 120.0Turbidity (NTU) NS 0.29 187 6.09 9.95 9.95 3.28 3.37 6.33Analytical ParametersTotal Iron (mg/L) 0.336 87 85 16 16<0.10 <0.10 0.11Total Barium (mg/L) 0.7 0.441.10.16 0.14 0.13 0.074 0.053 0.020Total Manganese (mg/L) 0.058.2 0.41 7.6 1.6 1.6 0.083<0.010 <0.010Notes:Samples analyzed for total and dissolved iron, barium and manganese by EPA Method 60102L Standard - North Carolina groundwater quality standards established in Title 15A of the North Carolina Administrative Code, Subchapter 2L, Section 0.202°C - degrees CelsiusµS/cm - microsiemens per centimeterEPA - United States Environmental Protection Agencymg/L - milligrams per litermV - millivoltNA - Not analyzedNS - No standardNTU - Nephelometric Turbidity Unit RCRA - Resource Conservation Recovery ActBold samples indicate concentrations above the 2L Standard*MW-2 purged with disposable bailer, water quality parameters not collectedMW-6 MW-7 MW-82L StandardMW-1 MW-2* MW-3 MW-4AECOM
Figure
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MW-2
MW-3
MW-4
MW-1
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MW-5
MW-7
MW-6
MW-8
1
2
8
0
12601
3
2
0
1340
1360
1380
124014201240
1420
Source: Esri, DigitalGlobe, GeoEye, Earthstar Geographics, CNES/AirbusDS, USDA, USGS, AEX, Getmapping, Aerogrid, IGN, IGP, swisstopo, and theGIS User Community
AECOM Environment1600 Perimeter Park Drive, Suite 400Morrisville, North Carolina 27560P: (919) 461 1100www.aecom.com
Figure
60540673
1
May 2017
§
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Site Layout MapBlue Ridge Tissue CorporationPatterson, North Carolina
Legend
Property Boundary
Yadkin River Flow Direction
#Land Surface Elevation Contour (ft above mean sea level)
Monitoring Well Location
Abandoned Water Well#0@A
Appendix A
Analytical Laboratory Report
This data package contains the analytical results for the project identified above and includes a Case Narrative, Sample
Results and Chain of Custody. Unless otherwise noted, all samples were received in acceptable condition and processed
according to the referenced methods.
Data qualifiers are flagged individually on each sample. A key reference for the data qualifiers appears at the end of this case
narrative.
NC Certification No. 402
NC Drinking Water Cert No. 37735
SC Certification No. 99012
Case Narrative
04/26/2017
AECOM
Maureen Conorozzo
1600 Perimeter Park Drive, Suite 400
Morrisville, NC 27560
Project: Blue Ridge Tissue Water April 2017
Lab Submittal Date: 04/18/2017
Prism Work Order: 7040319
The results in this report relate only to the samples as submitted to the laboratory and the test results meet all requirements of
NELAC except for those instances indicated in the case narrative and/or test comments.
Please call if you have any questions relating to this analytical report.
Respectfully,
PRISM LABORATORIES, INC.
President/Project Manager
Reviewed ByRobbi A. Jones Robbi A. Jones
President/Project Manager
Data Qualifiers Key Reference:
A MB (0.006) greater than one half of the RL, but the sample concentrations are either less than the RL or greater
than 10x the MB.
BH MB greater than one half of the RL, but the sample concentrations are greater than 10x the MB.
BL MB greater than one half of the RL, but the sample concentrations are less than the RL.
D RPD value outside of the control limits.
Method Detection LimitMDL
Below Reporting LimitBRL
Relative Percent DifferenceRPD
*Results reported to the reporting limit. All other results are reported to the MDL with values between MDL and
reporting limit indicated with a J.
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 1 of 18
Sample Receipt Summary
04/26/2017
Prism Work Order: 7040319
Client Sample ID MatrixLab Sample ID Date Sampled Date Received
7040319-01 04/13/17MW-1 04/18/17Water
7040319-02 04/13/17MW-2 04/18/17Water
7040319-03 04/13/17MW-3 04/18/17Water
7040319-04 04/13/17MW-4 04/18/17Water
7040319-05 04/13/17MW-6 04/18/17Water
7040319-06 04/13/17MW-7 04/18/17Water
7040319-07 04/13/17MW-8 04/18/17Water
7040319-08 04/13/17DUP-04132017 04/18/17Water
Samples were received in good condition at 2.2 degrees C unless otherwise noted.
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 2 of 18
Laboratory Report
04/26/2017
ResultParameter Batch
ID
Report
Limit
Analysis
Date/Time
MethodDilution
Factor
Units MDL Analyst
1600 Perimeter Park Drive, Suite 400
Project: Blue Ridge Tissue Water April
2017
AECOM
Morrisville, NC 27560
Attn: Maureen Conorozzo
Sample Matrix: Water
Client Sample ID:
Prism Sample ID: 7040319-01
Prism Work Order: 7040319
Time Collected: 04/13/17 14:30
Time Submitted: 04/18/17 08:55
MW-1
Total Metals
0.44 *6010D P7D028610.010 4/20/17 18:14 bgmmg/L 0.0013Barium
36 *6010D P7D028610.10 4/20/17 18:14 bgmmg/L 0.030Iron
8.2 *6010D P7D0286100.10 4/25/17 16:02 bgmBHmg/L 0.017Manganese
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 3 of 18
Laboratory Report
04/26/2017
ResultParameter Batch
ID
Report
Limit
Analysis
Date/Time
MethodDilution
Factor
Units MDL Analyst
1600 Perimeter Park Drive, Suite 400
Project: Blue Ridge Tissue Water April
2017
AECOM
Morrisville, NC 27560
Attn: Maureen Conorozzo
Sample Matrix: Water
Client Sample ID:
Prism Sample ID: 7040319-02
Prism Work Order: 7040319
Time Collected: 04/13/17 14:10
Time Submitted: 04/18/17 08:55
MW-2
Total Metals
1.1 *6010D P7D028610.010 4/20/17 18:22 bgmmg/L 0.0013Barium
87 *6010D P7D0286202.0 4/24/17 20:35 bgmmg/L 0.60Iron
0.41 *6010D P7D028610.010 4/20/17 18:22 bgmBHmg/L 0.0017Manganese
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 4 of 18
Laboratory Report
04/26/2017
ResultParameter Batch
ID
Report
Limit
Analysis
Date/Time
MethodDilution
Factor
Units MDL Analyst
1600 Perimeter Park Drive, Suite 400
Project: Blue Ridge Tissue Water April
2017
AECOM
Morrisville, NC 27560
Attn: Maureen Conorozzo
Sample Matrix: Water
Client Sample ID:
Prism Sample ID: 7040319-03
Prism Work Order: 7040319
Time Collected: 04/13/17 11:50
Time Submitted: 04/18/17 08:55
MW-3
Total Metals
0.16 *6010D P7D028610.010 4/20/17 18:42 bgmmg/L 0.0013Barium
85 *6010D P7D0286202.0 4/24/17 20:41 bgmmg/L 0.60Iron
7.6 *6010D P7D0286200.20 4/24/17 20:41 bgmBHmg/L 0.034Manganese
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 5 of 18
Laboratory Report
04/26/2017
ResultParameter Batch
ID
Report
Limit
Analysis
Date/Time
MethodDilution
Factor
Units MDL Analyst
1600 Perimeter Park Drive, Suite 400
Project: Blue Ridge Tissue Water April
2017
AECOM
Morrisville, NC 27560
Attn: Maureen Conorozzo
Sample Matrix: Water
Client Sample ID:
Prism Sample ID: 7040319-04
Prism Work Order: 7040319
Time Collected: 04/13/17 12:05
Time Submitted: 04/18/17 08:55
MW-4
Diesel Range Organics by GC/FID
BRL *8015C P7D035310.52 4/21/17 12:37 ZRCmg/L 0.19Diesel Range Organics
Surrogate Recovery Control Limits
50-14459 %o-Terphenyl
Total Metals
0.14 *6010D P7D028610.010 4/20/17 18:50 bgmmg/L 0.0013Barium
16 *6010D P7D028610.10 4/20/17 18:50 bgmmg/L 0.030Iron
1.6 *6010D P7D028610.010 4/20/17 18:50 bgmBHmg/L 0.0017Manganese
Volatile Organic Compounds by GC/MS
BRL 8260B P7D034910.50 4/21/17 20:58 KDMug/L 0.048Benzene
BRL 8260B P7D034910.50 4/21/17 20:58 KDMug/L 0.061Ethylbenzene
BRL 8260B P7D034911.0 4/21/17 20:58 KDMug/L 0.12m,p-Xylenes
BRL 8260B P7D034910.50 4/21/17 20:58 KDMug/L 0.044o-Xylene
BRL 8260B P7D034910.50 4/21/17 20:58 KDMug/L 0.044Toluene
BRL 8260B P7D034911.5 4/21/17 20:58 KDMug/L 0.15Xylenes, total
Surrogate Recovery Control Limits
80-12497 %4-Bromofluorobenzene
75-129107 %Dibromofluoromethane
77-12394 %Toluene-d8
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 6 of 18
Laboratory Report
04/26/2017
ResultParameter Batch
ID
Report
Limit
Analysis
Date/Time
MethodDilution
Factor
Units MDL Analyst
1600 Perimeter Park Drive, Suite 400
Project: Blue Ridge Tissue Water April
2017
AECOM
Morrisville, NC 27560
Attn: Maureen Conorozzo
Sample Matrix: Water
Client Sample ID:
Prism Sample ID: 7040319-05
Prism Work Order: 7040319
Time Collected: 04/13/17 16:05
Time Submitted: 04/18/17 08:55
MW-6
Total Metals
0.074 *6010D P7D028610.010 4/20/17 18:59 bgmmg/L 0.0013Barium
BRL *6010D P7D028610.10 4/20/17 18:59 bgmmg/L 0.030Iron
0.083 *6010D P7D028610.010 4/20/17 18:59 bgmBHmg/L 0.0017Manganese
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 7 of 18
Laboratory Report
04/26/2017
ResultParameter Batch
ID
Report
Limit
Analysis
Date/Time
MethodDilution
Factor
Units MDL Analyst
1600 Perimeter Park Drive, Suite 400
Project: Blue Ridge Tissue Water April
2017
AECOM
Morrisville, NC 27560
Attn: Maureen Conorozzo
Sample Matrix: Water
Client Sample ID:
Prism Sample ID: 7040319-06
Prism Work Order: 7040319
Time Collected: 04/13/17 13:23
Time Submitted: 04/18/17 08:55
MW-7
Total Metals
0.053 *6010D P7D028610.010 4/20/17 19:05 bgmmg/L 0.0013Barium
BRL *6010D P7D028610.10 4/20/17 19:05 bgmmg/L 0.030Iron
BRL *6010D P7D028610.010 4/20/17 19:05 bgmBLmg/L 0.0017Manganese
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 8 of 18
Laboratory Report
04/26/2017
ResultParameter Batch
ID
Report
Limit
Analysis
Date/Time
MethodDilution
Factor
Units MDL Analyst
1600 Perimeter Park Drive, Suite 400
Project: Blue Ridge Tissue Water April
2017
AECOM
Morrisville, NC 27560
Attn: Maureen Conorozzo
Sample Matrix: Water
Client Sample ID:
Prism Sample ID: 7040319-07
Prism Work Order: 7040319
Time Collected: 04/13/17 15:37
Time Submitted: 04/18/17 08:55
MW-8
Total Metals
0.020 *6010D P7D028610.010 4/20/17 19:14 bgmmg/L 0.0013Barium
0.11 *6010D P7D028610.10 4/20/17 19:14 bgmmg/L 0.030Iron
BRL *6010D P7D028610.010 4/20/17 19:14 bgmBLmg/L 0.0017Manganese
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 9 of 18
Laboratory Report
04/26/2017
ResultParameter Batch
ID
Report
Limit
Analysis
Date/Time
MethodDilution
Factor
Units MDL Analyst
1600 Perimeter Park Drive, Suite 400
Project: Blue Ridge Tissue Water April
2017
AECOM
Morrisville, NC 27560
Attn: Maureen Conorozzo
Sample Matrix: Water
Client Sample ID:
Prism Sample ID: 7040319-08
Prism Work Order: 7040319
Time Collected: 04/13/17 00:00
Time Submitted: 04/18/17 08:55
DUP-04132017
Total Metals
0.13 *6010D P7D028610.010 4/20/17 19:22 bgmmg/L 0.0013Barium
16 *6010D P7D028610.10 4/20/17 19:22 bgmmg/L 0.030Iron
1.6 *6010D P7D028610.010 4/20/17 19:22 bgmBHmg/L 0.0017Manganese
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 10 of 18
4/26/17
Level II QC Report
1600 Perimeter Park Drive, Suite 400
Project: Blue Ridge Tissue Water April
2017
AECOM
Morrisville, NC 27560
Attn: Maureen Conorozzo
Prism Work Order: 7040319
Time Submitted: 4/18/2017 8:55:00AM
Result Limit
Reporting
Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Notes Analyte
Volatile Organic Compounds by GC/MS - Quality Control
Batch P7D0349 - 5030B
Blank (P7D0349-BLK1)Prepared & Analyzed: 04/21/17
1,1,1,2-Tetrachloroethane ug/LBRL0.50
1,1,1-Trichloroethane ug/LBRL0.50
1,1,2,2-Tetrachloroethane ug/LBRL0.50
1,1,2-Trichloroethane ug/LBRL0.50
1,1-Dichloroethane ug/LBRL0.50
1,1-Dichloroethylene ug/LBRL0.50
1,1-Dichloropropylene ug/LBRL0.50
1,2,3-Trichlorobenzene ug/LBRL2.0
1,2,3-Trichloropropane ug/LBRL1.0
1,2,4-Trichlorobenzene ug/LBRL1.0
1,2,4-Trimethylbenzene ug/LBRL0.50
1,2-Dibromo-3-chloropropane ug/LBRL2.0
1,2-Dibromoethane ug/LBRL0.50
1,2-Dichlorobenzene ug/LBRL0.50
1,2-Dichloroethane ug/LBRL0.50
1,2-Dichloropropane ug/LBRL0.50
1,3,5-Trimethylbenzene ug/LBRL0.50
1,3-Dichlorobenzene ug/LBRL0.50
1,3-Dichloropropane ug/LBRL0.50
1,4-Dichlorobenzene ug/LBRL0.50
2,2-Dichloropropane ug/LBRL2.0
2-Chlorotoluene ug/LBRL0.50
4-Chlorotoluene ug/LBRL0.50
4-Isopropyltoluene ug/LBRL0.50
Acetone ug/LBRL5.0
Acrolein ug/LBRL20
Acrylonitrile ug/LBRL20
Benzene ug/LBRL0.50
Bromobenzene ug/LBRL0.50
Bromochloromethane ug/LBRL0.50
Bromodichloromethane ug/LBRL0.50
Bromoform ug/LBRL1.0
Bromomethane ug/LBRL1.0
Carbon disulfide ug/LBRL5.0
Carbon Tetrachloride ug/LBRL0.50
Chlorobenzene ug/LBRL0.50
Chloroethane ug/LBRL0.50
Chloroform ug/LBRL0.50
Chloromethane ug/LBRL0.50
cis-1,2-Dichloroethylene ug/LBRL0.50
cis-1,3-Dichloropropylene ug/LBRL0.50
Dibromochloromethane ug/LBRL0.50
Dibromomethane ug/LBRL0.50
Dichlorodifluoromethane ug/LBRL1.0
Ethylbenzene ug/LBRL0.50
Hexachlorobutadiene ug/LBRL2.0
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 11 of 18
4/26/17
Level II QC Report
1600 Perimeter Park Drive, Suite 400
Project: Blue Ridge Tissue Water April
2017
AECOM
Morrisville, NC 27560
Attn: Maureen Conorozzo
Prism Work Order: 7040319
Time Submitted: 4/18/2017 8:55:00AM
Result Limit
Reporting
Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Notes Analyte
Volatile Organic Compounds by GC/MS - Quality Control
Batch P7D0349 - 5030B
Blank (P7D0349-BLK1)Prepared & Analyzed: 04/21/17
Isopropyl Ether ug/LBRL0.50
Isopropylbenzene (Cumene)ug/LBRL0.50
m,p-Xylenes ug/LBRL1.0
Methyl Butyl Ketone (2-Hexanone)ug/LBRL5.0
Methyl Ethyl Ketone (2-Butanone)ug/LBRL5.0
Methyl Isobutyl Ketone ug/LBRL5.0
Methylene Chloride ug/LBRL1.0
Methyl-tert-Butyl Ether ug/LBRL0.50
Naphthalene ug/LBRL1.0
n-Butylbenzene ug/LBRL1.0
n-Propylbenzene ug/LBRL0.50
o-Xylene ug/LBRL0.50
sec-Butylbenzene ug/LBRL0.50
Styrene ug/LBRL0.50
tert-Butylbenzene ug/LBRL0.50
Tetrachloroethylene ug/LBRL0.50
Toluene ug/LBRL0.50
trans-1,2-Dichloroethylene ug/LBRL0.50
trans-1,3-Dichloropropylene ug/LBRL0.50
Trichloroethylene ug/LBRL0.50
Trichlorofluoromethane ug/LBRL0.50
Vinyl acetate ug/LBRL2.0
Vinyl chloride ug/LBRL0.50
ug/L 50.00 80-124Surrogate: 4-Bromofluorobenzene 9849.0
ug/L 50.00 75-129Surrogate: Dibromofluoromethane 10854.1
ug/L 50.00 77-123Surrogate: Toluene-d8 9547.3
LCS (P7D0349-BS1)Prepared & Analyzed: 04/21/17
1,1,1,2-Tetrachloroethane ug/L20.5 0.50 20.00 79-134103
1,1,1-Trichloroethane ug/L22.3 0.50 20.00 75-136112
1,1,2,2-Tetrachloroethane ug/L19.1 0.50 20.00 62-12796
1,1,2-Trichloroethane ug/L21.2 0.50 20.00 70-140106
1,1-Dichloroethane ug/L20.0 0.50 20.00 78-130100
1,1-Dichloroethylene ug/L21.4 0.50 20.00 70-154107
1,1-Dichloropropylene ug/L20.3 0.50 20.00 71-136101
1,2,3-Trichlorobenzene ug/L18.8 2.0 20.00 58-14494
1,2,3-Trichloropropane ug/L19.7 1.0 20.00 71-12798
1,2,4-Trichlorobenzene ug/L18.4 1.0 20.00 66-13992
1,2,4-Trimethylbenzene ug/L19.0 0.50 20.00 75-13395
1,2-Dibromo-3-chloropropane ug/L19.5 2.0 20.00 63-13498
1,2-Dibromoethane ug/L20.3 0.50 20.00 77-135102
1,2-Dichlorobenzene ug/L20.1 0.50 20.00 78-128101
1,2-Dichloroethane ug/L20.7 0.50 20.00 68-131103
1,2-Dichloropropane ug/L19.9 0.50 20.00 77-13099
1,3,5-Trimethylbenzene ug/L20.4 0.50 20.00 75-131102
1,3-Dichlorobenzene ug/L20.2 0.50 20.00 77-125101
1,3-Dichloropropane ug/L20.1 0.50 20.00 76-132100
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 12 of 18
4/26/17
Level II QC Report
1600 Perimeter Park Drive, Suite 400
Project: Blue Ridge Tissue Water April
2017
AECOM
Morrisville, NC 27560
Attn: Maureen Conorozzo
Prism Work Order: 7040319
Time Submitted: 4/18/2017 8:55:00AM
Result Limit
Reporting
Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Notes Analyte
Volatile Organic Compounds by GC/MS - Quality Control
Batch P7D0349 - 5030B
LCS (P7D0349-BS1)Prepared & Analyzed: 04/21/17
1,4-Dichlorobenzene ug/L19.4 0.50 20.00 75-12697
2,2-Dichloropropane ug/L21.9 2.0 20.00 29-149110
2-Chlorotoluene ug/L19.0 0.50 20.00 74-12695
4-Chlorotoluene ug/L19.6 0.50 20.00 78-12998
4-Isopropyltoluene ug/L19.2 0.50 20.00 69-13296
Acetone ug/L34.9 5.0 40.00 40-16687
Acrolein ug/L50.9 20 40.00 70-130127
Acrylonitrile ug/L42.5 20 40.00 81-127106
Benzene ug/L19.9 0.50 20.00 77-12899
Bromobenzene ug/L18.5 0.50 20.00 78-12992
Bromochloromethane ug/L19.6 0.50 20.00 78-13598
Bromodichloromethane ug/L20.7 0.50 20.00 76-138104
Bromoform ug/L20.2 1.0 20.00 71-135101
Bromomethane ug/L16.3 1.0 20.00 41-16881
Carbon disulfide ug/L21.6 5.0 20.00 59-135108
Carbon Tetrachloride ug/L21.3 0.50 20.00 72-142106
Chlorobenzene ug/L19.9 0.50 20.00 78-119100
Chloroethane ug/L20.6 0.50 20.00 57-142103
Chloroform ug/L19.1 0.50 20.00 77-13096
Chloromethane ug/L15.7 0.50 20.00 47-14579
cis-1,2-Dichloroethylene ug/L19.9 0.50 20.00 76-141100
cis-1,3-Dichloropropylene ug/L20.5 0.50 20.00 65-140102
Dibromochloromethane ug/L20.6 0.50 20.00 75-134103
Dibromomethane ug/L20.8 0.50 20.00 76-138104
Dichlorodifluoromethane ug/L17.2 1.0 20.00 28-16386
Ethylbenzene ug/L20.2 0.50 20.00 80-127101
Hexachlorobutadiene ug/L20.8 2.0 20.00 61-134104
Isopropyl Ether ug/L19.2 0.50 20.00 60-15496
Isopropylbenzene (Cumene)ug/L20.7 0.50 20.00 70-130103
m,p-Xylenes ug/L42.5 1.0 40.00 77-133106
Methyl Butyl Ketone (2-Hexanone)ug/L17.9 5.0 20.00 64-13790
Methyl Ethyl Ketone (2-Butanone)ug/L16.7 5.0 20.00 71-13483
Methyl Isobutyl Ketone ug/L19.7 5.0 20.00 69-13498
Methylene Chloride ug/L19.5 1.0 20.00 73-13198
Methyl-tert-Butyl Ether ug/L21.3 0.50 20.00 68-135107
Naphthalene ug/L17.2 1.0 20.00 64-13686
n-Butylbenzene ug/L19.2 1.0 20.00 68-13496
n-Propylbenzene ug/L20.1 0.50 20.00 72-132101
o-Xylene ug/L20.0 0.50 20.00 78-128100
sec-Butylbenzene ug/L18.8 0.50 20.00 71-13194
Styrene ug/L18.9 0.50 20.00 78-12994
tert-Butylbenzene ug/L20.4 0.50 20.00 70-132102
Tetrachloroethylene ug/L21.3 0.50 20.00 80-129106
Toluene ug/L20.3 0.50 20.00 76-131102
trans-1,2-Dichloroethylene ug/L21.3 0.50 20.00 76-135107
trans-1,3-Dichloropropylene ug/L21.0 0.50 20.00 67-140105
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 13 of 18
4/26/17
Level II QC Report
1600 Perimeter Park Drive, Suite 400
Project: Blue Ridge Tissue Water April
2017
AECOM
Morrisville, NC 27560
Attn: Maureen Conorozzo
Prism Work Order: 7040319
Time Submitted: 4/18/2017 8:55:00AM
Result Limit
Reporting
Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Notes Analyte
Volatile Organic Compounds by GC/MS - Quality Control
Batch P7D0349 - 5030B
LCS (P7D0349-BS1)Prepared & Analyzed: 04/21/17
Trichloroethylene ug/L21.1 0.50 20.00 77-133105
Trichlorofluoromethane ug/L23.2 0.50 20.00 62-148116
Vinyl acetate ug/L21.0 2.0 20.00 34-167105
Vinyl chloride ug/L19.4 0.50 20.00 57-14197
ug/L 50.00 80-124Surrogate: 4-Bromofluorobenzene 9547.6
ug/L 50.00 75-129Surrogate: Dibromofluoromethane 9949.4
ug/L 50.00 77-123Surrogate: Toluene-d8 9547.5
LCS Dup (P7D0349-BSD1)Prepared & Analyzed: 04/21/17
1,1,1,2-Tetrachloroethane ug/L20.3 0.50 20.00 2079-134102 1
1,1,1-Trichloroethane ug/L22.0 0.50 20.00 2075-136110 2
1,1,2,2-Tetrachloroethane ug/L18.1 0.50 20.00 2062-12790 5
1,1,2-Trichloroethane ug/L19.8 0.50 20.00 2070-14099 7
1,1-Dichloroethane ug/L20.0 0.50 20.00 2078-130100 0.3
1,1-Dichloroethylene ug/L22.6 0.50 20.00 2070-154113 5
1,1-Dichloropropylene ug/L20.6 0.50 20.00 2071-136103 1
1,2,3-Trichlorobenzene ug/L19.2 2.0 20.00 2058-14496 2
1,2,3-Trichloropropane ug/L20.9 1.0 20.00 2071-127104 6
1,2,4-Trichlorobenzene ug/L18.9 1.0 20.00 2066-13994 2
1,2,4-Trimethylbenzene ug/L19.7 0.50 20.00 2075-13399 4
1,2-Dibromo-3-chloropropane ug/L18.8 2.0 20.00 2063-13494 4
1,2-Dibromoethane ug/L20.6 0.50 20.00 2077-135103 2
1,2-Dichlorobenzene ug/L20.4 0.50 20.00 2078-128102 1
1,2-Dichloroethane ug/L20.6 0.50 20.00 2068-131103 0.2
1,2-Dichloropropane ug/L19.6 0.50 20.00 2077-13098 2
1,3,5-Trimethylbenzene ug/L20.8 0.50 20.00 2075-131104 2
1,3-Dichlorobenzene ug/L20.3 0.50 20.00 2077-125101 0.2
1,3-Dichloropropane ug/L20.2 0.50 20.00 2076-132101 0.4
1,4-Dichlorobenzene ug/L19.6 0.50 20.00 2075-12698 1
2,2-Dichloropropane ug/L21.6 2.0 20.00 2029-149108 2
2-Chlorotoluene ug/L19.5 0.50 20.00 2074-12697 3
4-Chlorotoluene ug/L20.5 0.50 20.00 2078-129103 4
4-Isopropyltoluene ug/L20.2 0.50 20.00 2069-132101 5
Acetone ug/L36.3 5.0 40.00 2040-16691 4
Acrolein ug/L47.2 20 40.00 2070-130118 7
Acrylonitrile ug/L38.1 20 40.00 2081-12795 11
Benzene ug/L20.0 0.50 20.00 2077-128100 0.4
Bromobenzene ug/L18.8 0.50 20.00 2078-12994 2
Bromochloromethane ug/L19.3 0.50 20.00 2078-13596 2
Bromodichloromethane ug/L20.4 0.50 20.00 2076-138102 2
Bromoform ug/L19.7 1.0 20.00 2071-13598 3
Bromomethane ug/L17.2 1.0 20.00 2041-16886 6
Carbon disulfide ug/L21.8 5.0 20.00 2059-135109 1
Carbon Tetrachloride ug/L22.0 0.50 20.00 2072-142110 3
Chlorobenzene ug/L20.4 0.50 20.00 2078-119102 2
Chloroethane ug/L21.1 0.50 20.00 2057-142105 2
Chloroform ug/L19.4 0.50 20.00 2077-13097 1
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 14 of 18
4/26/17
Level II QC Report
1600 Perimeter Park Drive, Suite 400
Project: Blue Ridge Tissue Water April
2017
AECOM
Morrisville, NC 27560
Attn: Maureen Conorozzo
Prism Work Order: 7040319
Time Submitted: 4/18/2017 8:55:00AM
Result Limit
Reporting
Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Notes Analyte
Volatile Organic Compounds by GC/MS - Quality Control
Batch P7D0349 - 5030B
LCS Dup (P7D0349-BSD1)Prepared & Analyzed: 04/21/17
Chloromethane ug/L16.3 0.50 20.00 2047-14582 4
cis-1,2-Dichloroethylene ug/L19.9 0.50 20.00 2076-14199 0.3
cis-1,3-Dichloropropylene ug/L20.7 0.50 20.00 2065-140103 1
Dibromochloromethane ug/L21.0 0.50 20.00 2075-134105 2
Dibromomethane ug/L20.8 0.50 20.00 2076-138104 0.3
Dichlorodifluoromethane ug/L16.9 1.0 20.00 2028-16384 2
Ethylbenzene ug/L20.8 0.50 20.00 2080-127104 3
Hexachlorobutadiene ug/L21.8 2.0 20.00 2061-134109 5
Isopropyl Ether ug/L19.1 0.50 20.00 2060-15496 0.4
Isopropylbenzene (Cumene)ug/L21.5 0.50 20.00 2070-130108 4
m,p-Xylenes ug/L43.2 1.0 40.00 2077-133108 2
Methyl Butyl Ketone (2-Hexanone)ug/L17.6 5.0 20.00 2064-13788 2
Methyl Ethyl Ketone (2-Butanone)ug/L18.8 5.0 20.00 2071-13494 12
Methyl Isobutyl Ketone ug/L18.8 5.0 20.00 2069-13494 5
Methylene Chloride ug/L19.5 1.0 20.00 2073-13198 0
Methyl-tert-Butyl Ether ug/L20.3 0.50 20.00 2068-135102 5
Naphthalene ug/L17.6 1.0 20.00 2064-13688 2
n-Butylbenzene ug/L19.9 1.0 20.00 2068-134100 4
n-Propylbenzene ug/L20.6 0.50 20.00 2072-132103 2
o-Xylene ug/L20.8 0.50 20.00 2078-128104 4
sec-Butylbenzene ug/L19.7 0.50 20.00 2071-13199 5
Styrene ug/L19.4 0.50 20.00 2078-12997 3
tert-Butylbenzene ug/L21.3 0.50 20.00 2070-132107 5
Tetrachloroethylene ug/L22.7 0.50 20.00 2080-129113 6
Toluene ug/L20.5 0.50 20.00 2076-131103 1
trans-1,2-Dichloroethylene ug/L21.2 0.50 20.00 2076-135106 0.7
trans-1,3-Dichloropropylene ug/L20.6 0.50 20.00 2067-140103 2
Trichloroethylene ug/L21.6 0.50 20.00 2077-133108 2
Trichlorofluoromethane ug/L23.6 0.50 20.00 2062-148118 2
Vinyl acetate ug/L22.2 2.0 20.00 2034-167111 6
Vinyl chloride ug/L20.2 0.50 20.00 2057-141101 4
ug/L 50.00 80-124Surrogate: 4-Bromofluorobenzene 9647.9
ug/L 50.00 75-129Surrogate: Dibromofluoromethane 9547.5
ug/L 50.00 77-123Surrogate: Toluene-d8 9547.4
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 15 of 18
4/26/17
Level II QC Report
1600 Perimeter Park Drive, Suite 400
Project: Blue Ridge Tissue Water April
2017
AECOM
Morrisville, NC 27560
Attn: Maureen Conorozzo
Prism Work Order: 7040319
Time Submitted: 4/18/2017 8:55:00AM
Result Limit
Reporting
Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Notes Analyte
Diesel Range Organics by GC/FID - Quality Control
Batch P7D0353 - 3510C GC
Blank (P7D0353-BLK1)Prepared: 04/20/17 Analyzed: 04/21/17
Diesel Range Organics mg/LBRL0.50
mg/L 0.04000 50-144Surrogate: o-Terphenyl 650.0261
LCS (P7D0353-BS1)Prepared: 04/20/17 Analyzed: 04/21/17
Diesel Range Organics mg/L1.71 0.50 2.000 53-13586
mg/L 0.04000 50-144Surrogate: o-Terphenyl 640.0257
LCS Dup (P7D0353-BSD1)Prepared: 04/20/17 Analyzed: 04/21/17
Diesel Range Organics mg/L1.36 0.50 2.000 20 D53-13568 23
mg/L 0.04000 50-144Surrogate: o-Terphenyl 550.0220
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 16 of 18
4/26/17
Level II QC Report
1600 Perimeter Park Drive, Suite 400
Project: Blue Ridge Tissue Water April
2017
AECOM
Morrisville, NC 27560
Attn: Maureen Conorozzo
Prism Work Order: 7040319
Time Submitted: 4/18/2017 8:55:00AM
Result Limit
Reporting
Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Notes Analyte
Total Metals - Quality Control
Batch P7D0286 - 3010A
Blank (P7D0286-BLK1)Prepared: 04/19/17 Analyzed: 04/20/17
Barium mg/LBRL0.010
Iron mg/LBRL0.10
Manganese mg/LBRL0.010 A
LCS (P7D0286-BS1)Prepared: 04/19/17 Analyzed: 04/20/17
Barium mg/L0.252 0.010 0.2500 80-120101
Iron mg/L5.13 0.10 5.000 80-120103
Manganese mg/L0.253 0.010 0.2500 80-120101
Sample Extraction Data
Prep Method: 3510C GC
Lab Number Batch Date/TimeInitialFinal
P7D03537040319-04 04/20/17 16:009701mLmL
Prep Method: 3010A
Lab Number Batch Date/TimeInitialFinal
P7D02867040319-01 04/19/17 7:555050mLmL
P7D02867040319-01 04/19/17 7:555050mLmL
P7D02867040319-02 04/19/17 7:555050mLmL
P7D02867040319-02 04/19/17 7:555050mLmL
P7D02867040319-03 04/19/17 7:555050mLmL
P7D02867040319-03 04/19/17 7:555050mLmL
P7D02867040319-04 04/19/17 7:555050mLmL
P7D02867040319-05 04/19/17 7:555050mLmL
P7D02867040319-06 04/19/17 7:555050mLmL
P7D02867040319-07 04/19/17 7:555050mLmL
P7D02867040319-08 04/19/17 7:555050mLmL
Prep Method: 5030B
Lab Number Batch Date/TimeInitialFinal
P7D03497040319-04 04/21/17 12:161010mLmL
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 17 of 18
Page 18 of 18