NC0006254_Groundwater Monitoring Report March 2020_20200406

PO Box 604 ▪ Fletcher, NC 28732 ▪ PH: 828-667-5001 ▪ Cell: 828-508-4510

April 6, 2020
Mr. Brett Laverty
NCDEQ Division of Water Resources
Asheville Regional Office
2090 US Highway 70
Swannanoa, NC 28778

RE: Groundwater Analytical Results – March 2019
Blue Ridge Tissue Corporation
1427 Yadkin River Road
Patterson, North Carolina

Mr. Laverty:

On March 26, 2020, Singleton Environmental, Inc. (SEI) visited the Blue Ridge Tissue site located
at 1427 Yadkin River Road in Patterson, North Carolina, to collect groundwater samples from
monitoring wells MW-1, MW-2, MW-3, MW-4, MW-6, MW-7 and MW-8. The depth to
groundwater in the monitoring wells ranged from 4.76 feet in MW-4 to 49.80 feet in MW-2.
Refer to Table 1 for all monitoring well groundwater depths and Figure 1 for all monitoring well
locations.

All groundwater samples, with the exception of MW-2, were collected using a peristaltic pump
connected to a Horiba U52-2 water quality meter with a flow through cell to collect groundwater
parameters (temperature, pH, specific conductivity, dissolved oxygen, ORP, and turbidity).
Groundwater sample MW-2 was collected using a bailer once three well volumes were removed.
Groundwater from the same bail as the sample was also poured into the flow cell to collect the
approximate parameters. The groundwater samples were submitted on ice to Pace Analytical for
the analysis of barium, iron, manganese, ammonia, TKN, nitrogen, nitrite and nitrate. MW-2 was
also analyzed for total dissolved solids (TDS) using EPA Method SM 2540C. The groundwater
parameters for all samples are outlined in Table 2.

The laboratory analysis of groundwater samples MW-1 detected levels of iron and manganese
above the NCAC 2L groundwater standards. The laboratory analysis of MW-2 detected levels of
barium, iron, manganese and ammonia above the NCAC 2L groundwater standards. The
laboratory analysis of groundwater samples MW-3 detected levels of iron, manganese and
ammonia above the NCAC 2L groundwater standards. The laboratory analysis of groundwater
samples MW-4 detected levels of iron and manganese above the NCAC 2L groundwater
standards. Laboratory analysis of groundwater samples MW-6, MW-7 and MW-8 did not detect
any compounds exceeding the NCAC 2L groundwater standards. The analytical results are shown
on attached Table 2 and the attached laboratory data sheets.

During the April 2017 groundwater sampling event, AECOM reported a possible sheen on the
groundwater in monitoring well MW-4. During the March 2020 event a sheen was not observed,
therefore, a volatile organic compound (VOC) analysis was not performed on the sample.
Singleton Environmental, Inc.
Singleton Environmental, Inc.

The compound levels detected in the groundwater analysis for the March 2020 sampling event
were comparable to the September 2019 event, with the exception of manganese detected below
the NCAC 2L groundwater standards in MW-6. Singleton Environmental, Inc. recommends
sampling the monitoring wells again in July 2020.

If you have any questions you can reach me at [phone].

Sincerely,

Chris Singleton, P.G.
Singleton Environmental, Inc.

cc: Dave Hallock, Blue Ridge Tissue Corporation

Attachments
@A
@A @A
@A
@A
@A
@A
@A
MW-2
MW-3
MW-4
MW-1
@A
MW-5
MW-7
MW-6
MW-8
1
2
8
0
12601
3
2
0
1340
1360
1380
124014201240
1420
Source: Esri, DigitalGlobe, GeoEye, Earthstar Geographics, CNES/AirbusDS, USDA, USGS, AEX, Getmapping, Aerogrid, IGN, IGP, swisstopo, and theGIS User Community
Figure
60540673
1
May 2017
§
0 200 400Feet
1 inch = 200 feet
Y
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k
i
n

R
i
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R
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Whisnant RdYad
k
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n

R
i
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Yadkin
R
iver
Roby Martin Rd#0
Site Layout MapBlue Ridge Tissue CorporationPatterson, North Carolina
Legend
Property Boundary
Yadkin River Flow Direction
#Land Surface Elevation Contour (ft above mean sea level)
Monitoring Well Location
Abandoned Water Well#0@A
Well ID Date Installed Total Depth (feet
bls)
Screened Interval
(feet bls)
Top of Casing
Elevation (feet msl)
Date Water Level
Measured
Depth to Water (feet
BTOC)
Groundwater Elevation
(feet msl)
MW-1 02/08/11 11 6-11 1253.71 03/26/20 11.87 1,241.84
MW-2 08/12/09 50 40-50 1323.03 03/26/20 49.80 1,273.23
MW-3 08/13/09 20 10-20 1299.02 03/26/20 16.64 1,282.38
MW-4 08/13/09 15 5-15 1247.23 03/26/20 4.76 1,242.47
MW-5 08/16/11 21 11-21 1285.46 N/A N/A N/A
MW-6 08/06/14 29 19-29 1341.55 03/26/20 26.26 1,315.29
MW-7 08/06/14 24 14-24 1274.41 03/26/20 16.68 1,257.73
MW-8 08/06/14 20 10-20 1253.14 03/26/20 13.40 1,239.74
Notes:
bls - feet below land surface BTOC - below top of casing msl - above mean sea level NG - not gauged
AECOM
Table 1
Monitoring Well Construction and Groundwater Elevations
Blue Ridge Tissue Corporation
1427 Yadkin River Road
Patterson, North Carolina
Sample ID MW-1 MW-2*MW-3 MW-4 MW-6 MW-7 MW-8
Sample Date 03/26/20 03/26/20 03/26/20 03/26/20 03/26/20 03/26/20 03/26/20
Temperature (°C)NS 11.05 N/A 14.68 14.00 12.26 13.39 13.57
pH (standard units)NS 6.16 N/A 6.17 6.10 4.81 5.88 5.53
Specific Conductivity (mS/cm)NS 0.615 N/A 0.538 0.223 0.027 0.116 0.139
Dissolved Oxygen (mg/L)NS 3.50 N/A 0.00 0.00 9.61 5.95 6.11
ORP (mV)NS -71.0 N/A -22.0 -16.0 325.0 247.0 24.0
Turbidity (NTU)NS 5.8 N/A 8.4 6.6 4.4 4.4 2.4
Total Barium (ug/L)700 433 1,630 243 66 89.9 57.2 16.4
Total Iron (ug/L)300 38,500 75,500 26,800 11,300 ND 179 ND
Total Manganese (ug/L)50 7,550 978 2,720 930 24.6 ND ND
Amonia (mg/L)1.5 0.62 13.7 15.1 0.86 ND ND ND
TKN (mg/L)N/A 1.6 15.8 17.5 1.9 ND ND ND
Nitrogen NO2 plus NO3 (mg/L)N/A 0.069 0.073 0.38 ND ND 1.5 3.6
Nitrate (mg/L)10.0 ND ND 0.33 ND ND 1.5 3.6
Nitrite (mg/L)1.0 0.07 0.13 0.049 ND ND ND ND
Total Disolved Solids (mg/L)N/A N/A 376 N/A N/A N/A N/A N/A
Notes:
Samples analyzed for total and dissolved iron, barium and manganese by EPA Method 200.7
2L Standard - North Carolina groundwater quality standards established in Title 15A of the North Carolina Administrative Code, Subchapter 2L, Section 0.20
°C - degrees Celsius
µS/cm - microsiemens per centimeter
EPA - United States Environmental Protection Agency mg/L - milligrams per liter
mV - millivolt
NA - Not analyzed NS - No standard
NTU - Nephelometric Turbidity Unit
RCRA - Resource Conservation Recovery Act
Bold samples indicate concentrations above the 2L Standard
*MW-2 purged with disposable bailer, water quality parameters collected from same bail as sample.
2L
Standard
Field Parameters
Analytical Parameters
Table 2
Blue Ridge Tissue Corporation
1427 Yadkin River Road
Patterson, North Carolina
#=CL#
April 03, 2020
LIMS USE: FR - CHRIS SINGLETON
LIMS OBJECT ID: 92471177
92471177
Project:
Pace Project No.:
RE:
Chris Singleton
Singleton Environmental
P.O. Box 2012
Enka, NC 28728
BLUE RIDGE TISSUE 032620
Dear Chris Singleton:
Enclosed are the analytical results for sample(s) received by the laboratory on March 26, 2020. The results relate only to
the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace Analytical Services - Asheville
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Chris Derouen for
[e-mail]
Project Manager
Lorri Patton
1(828)254-7176
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 1 of 21
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92471177
BLUE RIDGE TISSUE 032620
Pace Analytical Services Asheville
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 2 of 21
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92471177
BLUE RIDGE TISSUE 032620
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92471177001 MW-1 EPA 200.7 Rev 4.4 1994 3 PASI-ASH1
EPA 350.1 Rev 2.0 1993 1 PASI-AKDF1
EPA 351.2 Rev 2.0 1993 1 PASI-AMFO
EPA 353.2 Rev 2.0 1993 3 PASI-AKDF1
92471177002 MW-2 EPA 200.7 Rev 4.4 1994 3 PASI-ASH1
SM 2540C-2011 1 PASI-AJNS
EPA 350.1 Rev 2.0 1993 1 PASI-AKDF1
EPA 351.2 Rev 2.0 1993 1 PASI-AMFO
EPA 353.2 Rev 2.0 1993 3 PASI-AKDF1
92471177003 MW-3 EPA 200.7 Rev 4.4 1994 3 PASI-ASH1
EPA 350.1 Rev 2.0 1993 1 PASI-AKDF1
EPA 351.2 Rev 2.0 1993 1 PASI-AMFO
EPA 353.2 Rev 2.0 1993 3 PASI-AKDF1
92471177004 MW-4 EPA 200.7 Rev 4.4 1994 3 PASI-ASH1
EPA 350.1 Rev 2.0 1993 1 PASI-AKDF1
EPA 351.2 Rev 2.0 1993 1 PASI-AMFO
EPA 353.2 Rev 2.0 1993 3 PASI-AKDF1
92471177005 MW-6 EPA 200.7 Rev 4.4 1994 3 PASI-ASH1
EPA 350.1 Rev 2.0 1993 1 PASI-AKDF1
EPA 351.2 Rev 2.0 1993 1 PASI-AMFO
EPA 353.2 Rev 2.0 1993 3 PASI-AKDF1
92471177006 MW-7 EPA 200.7 Rev 4.4 1994 3 PASI-ASH1
EPA 350.1 Rev 2.0 1993 1 PASI-AKDF1
EPA 351.2 Rev 2.0 1993 1 PASI-AMFO
EPA 353.2 Rev 2.0 1993 3 PASI-AKDF1
92471177007 MW-8 EPA 200.7 Rev 4.4 1994 3 PASI-ASH1
EPA 350.1 Rev 2.0 1993 1 PASI-AKDF1
EPA 351.2 Rev 2.0 1993 1 PASI-AMFO
EPA 353.2 Rev 2.0 1993 3 PASI-AKDF1
PASI-A = Pace Analytical Services - Asheville
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 3 of 21
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92471177
BLUE RIDGE TISSUE 032620
Sample:MW-1 Lab ID:92471177001 Collected:03/26/20 10:10 Received:03/26/20 14:22 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 200.7 Rev 4.4 1994 Preparation Method: EPA 200.7 Rev 4.4 1994
Pace Analytical Services - Asheville
200.7 MET ICP
Barium 433 ug/L 03/27/20 20:36 7440-39-303/27/20 00:565.0 1
Iron 38500 ug/L 03/27/20 20:36 7439-89-6 M103/27/20 00:5650.0 1
Manganese 7550 ug/L 03/27/20 20:36 7439-96-5 M103/27/20 00:565.0 1
Analytical Method: EPA 350.1 Rev 2.0 1993
Pace Analytical Services - Asheville
350.1 Ammonia
Nitrogen, Ammonia 0.62 mg/L 04/01/20 13:50 7664-41-70.10 1
Analytical Method: EPA 351.2 Rev 2.0 1993 Preparation Method: EPA 351.2 Rev 2.0 1993
Pace Analytical Services - Asheville
351.2 Total Kjeldahl Nitrogen
Nitrogen, Kjeldahl, Total 1.6 mg/L 04/03/20 07:02 7727-37-904/02/20 10:060.50 1
Analytical Method: EPA 353.2 Rev 2.0 1993
Pace Analytical Services - Asheville
353.2 Nitrogen, NO2/NO3 unpres
Nitrogen, NO2 plus NO3 0.069 mg/L 03/27/20 09:220.040 1
Nitrogen, Nitrate ND mg/L 03/27/20 09:22 14797-55-80.040 1
Nitrogen, Nitrite 0.070 mg/L 03/27/20 09:22 14797-65-00.040 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/03/2020 05:04 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 4 of 21
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92471177
BLUE RIDGE TISSUE 032620
Sample:MW-2 Lab ID:92471177002 Collected:03/26/20 10:30 Received:03/26/20 14:22 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 200.7 Rev 4.4 1994 Preparation Method: EPA 200.7 Rev 4.4 1994
Pace Analytical Services - Asheville
200.7 MET ICP
Barium 1630 ug/L 03/27/20 20:51 7440-39-303/27/20 00:565.0 1
Iron 75500 ug/L 03/27/20 20:51 7439-89-603/27/20 00:5650.0 1
Manganese 978 ug/L 03/27/20 20:51 7439-96-503/27/20 00:565.0 1
Analytical Method: SM 2540C-2011
Pace Analytical Services - Asheville
2540C Total Dissolved Solids
Total Dissolved Solids 376 mg/L 03/30/20 14:0725.0 1
Analytical Method: EPA 350.1 Rev 2.0 1993
Pace Analytical Services - Asheville
350.1 Ammonia
Nitrogen, Ammonia 13.7 mg/L 04/01/20 14:22 7664-41-70.30 3
Analytical Method: EPA 351.2 Rev 2.0 1993 Preparation Method: EPA 351.2 Rev 2.0 1993
Pace Analytical Services - Asheville
351.2 Total Kjeldahl Nitrogen
Nitrogen, Kjeldahl, Total 15.8 mg/L 04/03/20 07:03 7727-37-904/02/20 10:060.50 1
Analytical Method: EPA 353.2 Rev 2.0 1993
Pace Analytical Services - Asheville
353.2 Nitrogen, NO2/NO3 unpres
Nitrogen, NO2 plus NO3 0.073 mg/L 03/27/20 09:240.040 1
Nitrogen, Nitrate ND mg/L 03/27/20 09:24 14797-55-80.040 1
Nitrogen, Nitrite 0.13 mg/L 03/27/20 09:24 14797-65-00.040 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/03/2020 05:04 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 5 of 21
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92471177
BLUE RIDGE TISSUE 032620
Sample:MW-3 Lab ID:92471177003 Collected:03/26/20 10:55 Received:03/26/20 14:22 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 200.7 Rev 4.4 1994 Preparation Method: EPA 200.7 Rev 4.4 1994
Pace Analytical Services - Asheville
200.7 MET ICP
Barium 243 ug/L 03/27/20 20:54 7440-39-303/27/20 00:565.0 1
Iron 26800 ug/L 03/27/20 20:54 7439-89-603/27/20 00:5650.0 1
Manganese 2720 ug/L 03/27/20 20:54 7439-96-503/27/20 00:565.0 1
Analytical Method: EPA 350.1 Rev 2.0 1993
Pace Analytical Services - Asheville
350.1 Ammonia
Nitrogen, Ammonia 15.1 mg/L 04/01/20 14:24 7664-41-70.30 3
Analytical Method: EPA 351.2 Rev 2.0 1993 Preparation Method: EPA 351.2 Rev 2.0 1993
Pace Analytical Services - Asheville
351.2 Total Kjeldahl Nitrogen
Nitrogen, Kjeldahl, Total 17.5 mg/L 04/03/20 07:06 7727-37-904/02/20 10:060.50 1
Analytical Method: EPA 353.2 Rev 2.0 1993
Pace Analytical Services - Asheville
353.2 Nitrogen, NO2/NO3 unpres
Nitrogen, NO2 plus NO3 0.38 mg/L 03/27/20 09:260.040 1
Nitrogen, Nitrate 0.33 mg/L 03/27/20 09:26 14797-55-80.040 1
Nitrogen, Nitrite 0.049 mg/L 03/27/20 09:26 14797-65-00.040 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/03/2020 05:04 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 6 of 21
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92471177
BLUE RIDGE TISSUE 032620
Sample:MW-4 Lab ID:92471177004 Collected:03/26/20 12:40 Received:03/26/20 14:22 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 200.7 Rev 4.4 1994 Preparation Method: EPA 200.7 Rev 4.4 1994
Pace Analytical Services - Asheville
200.7 MET ICP
Barium 65.8 ug/L 03/27/20 20:57 7440-39-303/27/20 00:565.0 1
Iron 11300 ug/L 03/27/20 20:57 7439-89-603/27/20 00:5650.0 1
Manganese 930 ug/L 03/27/20 20:57 7439-96-503/27/20 00:565.0 1
Analytical Method: EPA 350.1 Rev 2.0 1993
Pace Analytical Services - Asheville
350.1 Ammonia
Nitrogen, Ammonia 0.86 mg/L 04/01/20 14:00 7664-41-70.10 1
Analytical Method: EPA 351.2 Rev 2.0 1993 Preparation Method: EPA 351.2 Rev 2.0 1993
Pace Analytical Services - Asheville
351.2 Total Kjeldahl Nitrogen
Nitrogen, Kjeldahl, Total 1.9 mg/L 04/03/20 07:07 7727-37-904/02/20 10:060.50 1
Analytical Method: EPA 353.2 Rev 2.0 1993
Pace Analytical Services - Asheville
353.2 Nitrogen, NO2/NO3 unpres
Nitrogen, NO2 plus NO3 ND mg/L 03/27/20 09:330.040 1
Nitrogen, Nitrate ND mg/L 03/27/20 09:33 14797-55-80.040 1
Nitrogen, Nitrite ND mg/L 03/27/20 09:33 14797-65-00.040 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/03/2020 05:04 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 7 of 21
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92471177
BLUE RIDGE TISSUE 032620
Sample:MW-6 Lab ID:92471177005 Collected:03/26/20 11:40 Received:03/26/20 14:22 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 200.7 Rev 4.4 1994 Preparation Method: EPA 200.7 Rev 4.4 1994
Pace Analytical Services - Asheville
200.7 MET ICP
Barium 89.9 ug/L 03/27/20 21:00 7440-39-303/27/20 00:565.0 1
Iron ND ug/L 03/27/20 21:00 7439-89-603/27/20 00:5650.0 1
Manganese 24.6 ug/L 03/27/20 21:00 7439-96-503/27/20 00:565.0 1
Analytical Method: EPA 350.1 Rev 2.0 1993
Pace Analytical Services - Asheville
350.1 Ammonia
Nitrogen, Ammonia ND mg/L 04/01/20 14:02 7664-41-70.10 1
Analytical Method: EPA 351.2 Rev 2.0 1993 Preparation Method: EPA 351.2 Rev 2.0 1993
Pace Analytical Services - Asheville
351.2 Total Kjeldahl Nitrogen
Nitrogen, Kjeldahl, Total ND mg/L 04/03/20 07:08 7727-37-904/02/20 10:060.50 1
Analytical Method: EPA 353.2 Rev 2.0 1993
Pace Analytical Services - Asheville
353.2 Nitrogen, NO2/NO3 unpres
Nitrogen, NO2 plus NO3 ND mg/L 03/27/20 09:280.040 1
Nitrogen, Nitrate ND mg/L 03/27/20 09:28 14797-55-80.040 1
Nitrogen, Nitrite ND mg/L 03/27/20 09:28 14797-65-00.040 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/03/2020 05:04 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 8 of 21
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92471177
BLUE RIDGE TISSUE 032620
Sample:MW-7 Lab ID:92471177006 Collected:03/26/20 12:05 Received:03/26/20 14:22 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 200.7 Rev 4.4 1994 Preparation Method: EPA 200.7 Rev 4.4 1994
Pace Analytical Services - Asheville
200.7 MET ICP
Barium 57.2 ug/L 03/27/20 21:03 7440-39-303/27/20 00:565.0 1
Iron 179 ug/L 03/27/20 21:03 7439-89-603/27/20 00:5650.0 1
Manganese ND ug/L 03/27/20 21:03 7439-96-503/27/20 00:565.0 1
Analytical Method: EPA 350.1 Rev 2.0 1993
Pace Analytical Services - Asheville
350.1 Ammonia
Nitrogen, Ammonia ND mg/L 04/01/20 14:03 7664-41-70.10 1
Analytical Method: EPA 351.2 Rev 2.0 1993 Preparation Method: EPA 351.2 Rev 2.0 1993
Pace Analytical Services - Asheville
351.2 Total Kjeldahl Nitrogen
Nitrogen, Kjeldahl, Total ND mg/L 04/03/20 07:27 7727-37-904/02/20 15:450.50 1
Analytical Method: EPA 353.2 Rev 2.0 1993
Pace Analytical Services - Asheville
353.2 Nitrogen, NO2/NO3 unpres
Nitrogen, NO2 plus NO3 1.5 mg/L 03/27/20 09:300.040 1
Nitrogen, Nitrate 1.5 mg/L 03/27/20 09:30 14797-55-80.040 1
Nitrogen, Nitrite ND mg/L 03/27/20 09:30 14797-65-00.040 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/03/2020 05:04 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 9 of 21
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92471177
BLUE RIDGE TISSUE 032620
Sample:MW-8 Lab ID:92471177007 Collected:03/26/20 11:10 Received:03/26/20 14:22 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 200.7 Rev 4.4 1994 Preparation Method: EPA 200.7 Rev 4.4 1994
Pace Analytical Services - Asheville
200.7 MET ICP
Barium 16.4 ug/L 03/27/20 21:12 7440-39-303/27/20 00:565.0 1
Iron ND ug/L 03/27/20 21:12 7439-89-603/27/20 00:5650.0 1
Manganese ND ug/L 03/27/20 21:12 7439-96-503/27/20 00:565.0 1
Analytical Method: EPA 350.1 Rev 2.0 1993
Pace Analytical Services - Asheville
350.1 Ammonia
Nitrogen, Ammonia ND mg/L 04/01/20 14:05 7664-41-70.10 1
Analytical Method: EPA 351.2 Rev 2.0 1993 Preparation Method: EPA 351.2 Rev 2.0 1993
Pace Analytical Services - Asheville
351.2 Total Kjeldahl Nitrogen
Nitrogen, Kjeldahl, Total ND mg/L 04/03/20 07:28 7727-37-904/02/20 15:450.50 1
Analytical Method: EPA 353.2 Rev 2.0 1993
Pace Analytical Services - Asheville
353.2 Nitrogen, NO2/NO3 unpres
Nitrogen, NO2 plus NO3 3.6 mg/L 03/27/20 09:270.040 1
Nitrogen, Nitrate 3.6 mg/L 03/27/20 09:27 14797-55-80.040 1
Nitrogen, Nitrite ND mg/L 03/27/20 09:27 14797-65-00.040 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/03/2020 05:04 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 10 of 21
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92471177
BLUE RIDGE TISSUE 032620
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
532849
EPA 200.7 Rev 4.4 1994
EPA 200.7 Rev 4.4 1994
200.7 MET
Laboratory:Pace Analytical Services - Asheville
Associated Lab Samples:92471177001, 92471177002, 92471177003, 92471177004, 92471177005, 92471177006, 92471177007
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:2844225
Associated Lab Samples:92471177001, 92471177002, 92471177003, 92471177004, 92471177005, 92471177006, 92471177007
Matrix:Water
Analyzed
Barium ug/L ND 5.0 03/27/20 20:15
Iron ug/L ND 50.0 03/27/20 20:15
Manganese ug/L ND 5.0 03/27/20 20:15
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2844226LABORATORY CONTROL SAMPLE:
LCSSpike
Barium ug/L 499500 100 85-115
Iron ug/L 49105000 98 85-115
Manganese ug/L 492500 98 85-115
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2844227MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92471177001
2844228
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Barium ug/L 500 100 70-13098 1500433935924
Iron ug/L M150006770-13065 05000385004190041700
Manganese ug/L M15003870-13039 0500755077407740
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2844229MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92471177006
2844230
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Barium ug/L 500 108 70-130104 350057.2 595 577
Iron ug/L 5000 103 70-130101 3500017953505210
Manganese ug/L 500 106 70-130103 3500ND534519
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 04/03/2020 05:04 PM
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Page 11 of 21
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92471177
BLUE RIDGE TISSUE 032620
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
533242
SM 2540C-2011
SM 2540C-2011
2540C Total Dissolved Solids
Laboratory:Pace Analytical Services - Asheville
Associated Lab Samples:92471177002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:2846489
Associated Lab Samples:92471177002
Matrix:Water
Analyzed
Total Dissolved Solids mg/L ND 25.0 03/30/20 14:04
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2846490LABORATORY CONTROL SAMPLE:
LCSSpike
Total Dissolved Solids mg/L 234250 94 90-110
Parameter Units
Dup
Result QualifiersRPDResult
92470868027
2846491SAMPLE DUPLICATE:
Total Dissolved Solids mg/L 45.0 D63133.0
Parameter Units
Dup
Result QualifiersRPDResult
92471177002
2846492SAMPLE DUPLICATE:
Total Dissolved Solids mg/L 355 6376
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 04/03/2020 05:04 PM
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Asheville, NC 28804
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Page 12 of 21
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92471177
BLUE RIDGE TISSUE 032620
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
533420
EPA 350.1 Rev 2.0 1993
EPA 350.1 Rev 2.0 1993
350.1 Ammonia
Laboratory:Pace Analytical Services - Asheville
Associated Lab Samples:92471177001, 92471177002, 92471177003, 92471177004, 92471177005, 92471177006, 92471177007
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:2847527
Associated Lab Samples:92471177001, 92471177002, 92471177003, 92471177004, 92471177005, 92471177006, 92471177007
Matrix:Water
Analyzed
Nitrogen, Ammonia mg/L ND 0.10 04/01/20 13:27
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2847528LABORATORY CONTROL SAMPLE:
LCSSpike
Nitrogen, Ammonia mg/L 5.15 102 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2847529MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92470734008
2847530
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Nitrogen, Ammonia mg/L 5 103 90-110103 05ND5.1 5.1
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2847531MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92470779001
2847532
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Nitrogen, Ammonia mg/L 5 105 90-110104 0510.6 15.9 15.8
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 04/03/2020 05:04 PM
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Asheville, NC 28804
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Page 13 of 21
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92471177
BLUE RIDGE TISSUE 032620
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
533652
EPA 351.2 Rev 2.0 1993
EPA 351.2 Rev 2.0 1993
351.2 TKN
Laboratory:Pace Analytical Services - Asheville
Associated Lab Samples:92471177001, 92471177002, 92471177003, 92471177004, 92471177005
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:2848473
Associated Lab Samples:92471177001, 92471177002, 92471177003, 92471177004, 92471177005
Matrix:Water
Analyzed
Nitrogen, Kjeldahl, Total mg/L ND 0.50 04/03/20 06:52
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2848474LABORATORY CONTROL SAMPLE:
LCSSpike
Nitrogen, Kjeldahl, Total mg/L 10.210 102 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2848475MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92471017003
2848476
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Nitrogen, Kjeldahl, Total mg/L M11015390-110149 3101.8 17.1 16.6
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 04/03/2020 05:04 PM
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Asheville, NC 28804
[phone]
Page 14 of 21
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92471177
BLUE RIDGE TISSUE 032620
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
533655
EPA 351.2 Rev 2.0 1993
EPA 351.2 Rev 2.0 1993
351.2 TKN
Laboratory:Pace Analytical Services - Asheville
Associated Lab Samples:92471177006, 92471177007
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:2848480
Associated Lab Samples:92471177006, 92471177007
Matrix:Water
Analyzed
Nitrogen, Kjeldahl, Total mg/L ND 0.50 04/03/20 07:11
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2848481LABORATORY CONTROL SAMPLE:
LCSSpike
Nitrogen, Kjeldahl, Total mg/L 10.310 103 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2848482MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92470474001
2848483
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Nitrogen, Kjeldahl, Total mg/L M1,R11013790-11071 151032.5 46.2 39.6
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2848484MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
2630410001
2848485
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Nitrogen, Kjeldahl, Total mg/L M11011090-110112 1105.9 16.9 17.0
REPORT OF LABORATORY ANALYSIS
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Asheville, NC 28804
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Page 15 of 21
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92471177
BLUE RIDGE TISSUE 032620
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
532886
EPA 353.2 Rev 2.0 1993
EPA 353.2 Rev 2.0 1993
353.2 Nitrate + Nitrite, Unpres.
Laboratory:Pace Analytical Services - Asheville
Associated Lab Samples:92471177001, 92471177002, 92471177003, 92471177004, 92471177005, 92471177006, 92471177007
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:2844307
Associated Lab Samples:92471177001, 92471177002, 92471177003, 92471177004, 92471177005, 92471177006, 92471177007
Matrix:Water
Analyzed
Nitrogen, Nitrate mg/L ND 0.040 03/27/20 08:04
Nitrogen, Nitrite mg/L ND 0.040 03/27/20 08:04
Nitrogen, NO2 plus NO3 mg/L ND 0.040 03/27/20 08:04
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2844308LABORATORY CONTROL SAMPLE:
LCSSpike
Nitrogen, Nitrate mg/L 1.41.5 95 90-110
Nitrogen, Nitrite mg/L 0.971 97 90-110
Nitrogen, NO2 plus NO3 mg/L 2.42.5 96 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2844309MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92471197001
2844310
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Nitrogen, Nitrate mg/L M11.5 83 90-11078 51.5ND 1.2 1.2
Nitrogen, Nitrite mg/L M117790-11079 210.26 1.0 1.0
Nitrogen, NO2 plus NO3 mg/L M12.5 86 90-11085 22.50.11 2.3 2.2
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2844311MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92471193001
2844312
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Nitrogen, Nitrate mg/L 1.5 115 90-11093 11.524.8 26.5 26.2
Nitrogen, Nitrite mg/L 1 95 90-11097 21ND0.95 0.97
Nitrogen, NO2 plus NO3 mg/L 2.5 107 90-11094 12.524.8 27.5 27.2
REPORT OF LABORATORY ANALYSIS
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Page 16 of 21
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92471177
BLUE RIDGE TISSUE 032620
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
ANALYTE QUALIFIERS
The precision between the sample and sample duplicate exceeded laboratory control limits.D6
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
RPD value was outside control limits.R1
REPORT OF LABORATORY ANALYSIS
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Page 17 of 21
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92471177
BLUE RIDGE TISSUE 032620
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92471177001 532849 532869MW-1 EPA 200.7 Rev 4.4 1994 EPA 200.7 Rev 4.4 1994
92471177002 532849 532869MW-2 EPA 200.7 Rev 4.4 1994 EPA 200.7 Rev 4.4 1994
92471177003 532849 532869MW-3 EPA 200.7 Rev 4.4 1994 EPA 200.7 Rev 4.4 1994
92471177004 532849 532869MW-4 EPA 200.7 Rev 4.4 1994 EPA 200.7 Rev 4.4 1994
92471177005 532849 532869MW-6 EPA 200.7 Rev 4.4 1994 EPA 200.7 Rev 4.4 1994
92471177006 532849 532869MW-7 EPA 200.7 Rev 4.4 1994 EPA 200.7 Rev 4.4 1994
92471177007 532849 532869MW-8 EPA 200.7 Rev 4.4 1994 EPA 200.7 Rev 4.4 1994
92471177002 533242MW-2 SM 2540C-2011
92471177001 533420MW-1 EPA 350.1 Rev 2.0 1993
92471177002 533420MW-2 EPA 350.1 Rev 2.0 1993
92471177003 533420MW-3 EPA 350.1 Rev 2.0 1993
92471177004 533420MW-4 EPA 350.1 Rev 2.0 1993
92471177005 533420MW-6 EPA 350.1 Rev 2.0 1993
92471177006 533420MW-7 EPA 350.1 Rev 2.0 1993
92471177007 533420MW-8 EPA 350.1 Rev 2.0 1993
92471177001 533652 534205MW-1 EPA 351.2 Rev 2.0 1993 EPA 351.2 Rev 2.0 1993
92471177002 533652 534205MW-2 EPA 351.2 Rev 2.0 1993 EPA 351.2 Rev 2.0 1993
92471177003 533652 534205MW-3 EPA 351.2 Rev 2.0 1993 EPA 351.2 Rev 2.0 1993
92471177004 533652 534205MW-4 EPA 351.2 Rev 2.0 1993 EPA 351.2 Rev 2.0 1993
92471177005 533652 534205MW-6 EPA 351.2 Rev 2.0 1993 EPA 351.2 Rev 2.0 1993
92471177006 533655 534206MW-7 EPA 351.2 Rev 2.0 1993 EPA 351.2 Rev 2.0 1993
92471177007 533655 534206MW-8 EPA 351.2 Rev 2.0 1993 EPA 351.2 Rev 2.0 1993
92471177001 532886MW-1 EPA 353.2 Rev 2.0 1993
92471177002 532886MW-2 EPA 353.2 Rev 2.0 1993
92471177003 532886MW-3 EPA 353.2 Rev 2.0 1993
92471177004 532886MW-4 EPA 353.2 Rev 2.0 1993
92471177005 532886MW-6 EPA 353.2 Rev 2.0 1993
92471177006 532886MW-7 EPA 353.2 Rev 2.0 1993
92471177007 532886MW-8 EPA 353.2 Rev 2.0 1993
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 04/03/2020 05:04 PM
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Asheville, NC 28804
[phone]
Page 18 of 21
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