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NC0026565_Fact Sheet_20220406
Fact Sheet NPDES Permit No. NCOO26565 Permit Writer/Email Contact Gary Perlmutter, gary.perlmutter@ncdenr.gov: Date: April 6, 2022 Division/Branch: NC Division of Water Resources / NPDES Municipal Permitting Unit Fact Sheet Template: Version 09Jan2017 Permitting Action: ® Renewal ❑ Renewal with Expansion ❑ New Discharge ❑ Modification (Fact Sheet should be tailored to mod request) Note: A complete application should include the following: • For New Dischargers, EPA Form 2A or 2D requirements, Engineering Alternatives Analysis, Fee • For Existing Dischargers (POTW), EPA Form 2A, 3 effluent pollutant scans, 4 2nd species WET tests. • For Existing Dischargers (Non-POTW), EPA Form 2C with correct analytical requirements based on industry category. Complete applicable sections below. If not applicable, enter NA. 1. Basic Facility Information Facility Information Applicant / Facility Name: Town of Ramseur / Ramseur WWTP Applicant Address: P.O. Box 545 / 724 Liberty Street, Ramseur, NC 27316 Facility Address: 4735 Roundleaf Rd, Ramseur, NC 27316 Permitted Flow: 0.480 MGD Facility Type/Waste: MAJOR Municipal / 94.8% domestic, 5.2% industrial' Facility Class: Grade II Treatment Units: Aeration Basin, Clarifier, Polishing Pond (Lagoon), Chlorination, Dechlorination, Sludge Storage (Lagoon) Pretreatment Program (Y/N) Yes County: Randolph Region Winston-Salem Footnote: 1. Based on 0.0250 MGD permitted industrial flow. Briefly describe the proposed permitting action and facility background: The Town of Ramseur had applied for an NPDES permit renewal for its WWTP, received by DWR on November 5, 2020. Review of the application found it to be complete. This 0.480 MGD facility serves the Town of Ramseur (pop. —1690). Page 1 of 12 The WWTP is classified as a POTW that treats domestic and industrial wastewater with an active pretreatment program involving one Significant Industrial User (SIU). The pretreatment program includes a Short -Term Monitoring Program (STMP) involving 14 Parameters of Concern (POCs). 2. Receiving Waterbody Information Receiving Waterbody Information Outfall(s) / Receiving Stream(s): Outfall 001 / Deep River Stream Segment: 17-(10.5)d2 Stream Classification: C Drainage Area (mi2): 349 Summer 7Q10 (cfs) 11 Winter 7Q10 (cfs): 23 30Q2 (cfs): - Average Flow (cfs): 350 IWC (% effluent): 6 2020 NC 303(d) listed / parameter: Copper Subject to TMDL / parameter: State-wide Mercury TMDL Basin / Sub -basin / HUC: Cape Fear / 03-06-09 / 03030003 USGS Topo Quad: E20NW / Ramseur, NC 3. Effluent Data Summary Effluent data for Outfall 001 is summarized in Table 1 for the period of June 2017-May 2021. Table 1. Effluent Data Summary Outfall 001. Parameter Units Average Max Min Permit Limit 1 Flow' MGD 0.194 1.602 0.027 MA = 0.480 BOD5 mg/L 11.9 146 < 2 MA = 30.0 WA = 45.0 BOD removal % 94.5 99.1 83.0 > 85 TSS mg/L 10.6 66 < 7.5 MA = 30.0 WA = 45.0 TSS removal % 94.8 99._ 78.2 > 85 NH3-N (summer) mg/L 7.8 21.6 0.3 MA = 18.0 WA = 35.0 NH3-N (winter) mg/L 8.3 19.8 0.4 Monitor & Report DO mg/L 6.1 7.8 5.8 DA > 5.0 Page 2 of 12 Parameter Units Average Max Min Permit Limit 1 pH S.U. 6.9 7.5 6.7 6.0 — 9.0 Temperature °C 18.6 34.0 3.0 Monitor & Report Fecal Coliform (geometric mean) #/100 mL 1.7 3200 < 1 MA = 200 WA = 400 TRC µg/L All non -detects at < 15, < 10 and < 1 DM = 28 3 Total Nitrogen (NO2 + NO3 + TKN) mg/L 10.74 24.35 3.47 Monitor & Report Total Phosphorus mg/L 2.79 6.77 1.37 Monitor & Report Total Copper µg/L 303 3792 4 Monitor & Report Total Mercury ng/L 1.3 3.5 < 1.0 Monitor & Report 1 MA = Monthly Average, WA = Weekly Average, DM = Daily Maximum; DA = Daily Average. 2 Average for CY2020 = 0.210 MGD, 44% of design flow. 3 Values < 50 µg/L considered compliant. High values of BOD in October 2017 and TSS in July 2018 were caused by stratification and algal growth in the lagoon, respectively. See attached DMR notes. Units for Total Copper were not specified in the current permit, which resulted in values being expressed in the default unit of mg/L in submitted DMRs. Data reviewed in the original lab reports are expressed in µg/L. Because the DWR database is linked to the current permit, correction to the units for this parameter cannot be made until the next permit is issued. 4. Instream Data Summary Instream monitoring may be required in certain situations, for example: 1) to verify model predictions when model results for instream DO are within 1 mg/L of instream standard at full permitted flow; 2) to verify model predictions for outfall diffuser; 3) to provide data for future TMDL; 4) based on other instream concerns. Instream monitoring may be conducted by the Permittee, and there are also Monitoring Coalitions established in several basins that conduct instream sampling for the Permittee (in which case instream monitoring is waived in the permit as long as coalition membership is maintained). If applicable, summarize any instream data and what instream monitoring will be proposed for this permit action: The current permit requires instream monitoring for Dissolved Oxygen (DO) and Temperature (Conductivity and Fecal Coliform were removed in the 2007 permit based on Division guidance). Instream monitoring locations in the current permit include one upstream at — 50 ft upstream of the outfall and one downstream at NCSR 2628, — 4.0 miles from the outfall. Instream monitoring is waived so long as the Permittee is a member of the Upper Cape Fear River Basin Association (UCFRBA). The nearest UCFRBA monitoring stations are B5070000 - DEEP RIVER AT SR 2615 AT RAMSEUR (upstream; —0.75 miles from the outfall) and B5100000 - DEEP RIVER AT SR 2628 HINSHAW TOWN RD NEAR PARKS CROSSROADS (downstream; same as in the permit). Instream data from June 2017—December 2020 were obtained from the DWR Monitoring Coalition Coordinator and compared with concurrent effluent data, and against state water quality standards where applicable. Data were tested statistically for significant differences among means using Single Factor ANOVA; where differences were detected, follow-up testing was conducted using two -sample t tests. Level of significance is 0.05. Instream data review findings for each parameter are summarized in Table 2 below. Page 3 of 12 Table 2. Instream and concurrent effluent monitoring summary statistics. Parameter Upstream Downstream Effluent Standard Dissolved Oxygen (DO), mg/L Average = 8.4 Range: 6.2-13.2 Average = 8.2 Range: 5.9-12.8 Average = 6.1 Range: 5.8-6.7 5.0 Temperature, °C Average = 20.1 Range: 2.7-31.8 Average = 19.9 Range: 2.2-30.7 Average = 20.6 Range: 3.0-32.0 32.0 Specific Conductance, µS/cm Average = 182 Range: 65-406 Average = 179 Range: 66-423 NA NA Dissolved Oxygen (DO) — DO remains in the permit as a parameter of concern for aquatic life. Reviewed instream DO data showed seasonal variation with summer lows and winter highs at both instream locations. Instream summer minima were above the 5 mg/L daily average water quality standard for non -trout waters (15A NCAC 02B .0211) at both locations. No statistically significant differences were detected between average temperature values of the two instream locations. While the overall average of the effluent DO was lower than that instream, it does not seem to affect the instream DO. Temperature Temperature remains in the permit as a parameter of concern for aquatic life. Reviewed instream temperature data showed seasonal patterns of summer highs and winter lows at both locations. Summer temperature maxima at both stations were below the water quality standard of 32°C for lower piedmont and coastal plain waters (15A NCAC 02B .0211). No statistically significant differences were detected between average temperature values of the two instream locations. Review of paired up- to downstream temperatures found no exceedences of the 2.8°C increase standard (15A NCAC 02B .0211). Effluent temperatures are very similar to instream temperatures; the effluent does not appear to affect instream temperature. Conductivity — Conductivity is not in the current permit; neither effluent nor instream monitoring is required. However, the facility has a pretreatment program involving one SIU (a metal finisher), and instream Specific Conductance data are available for review. Review of the data found no statistically significant differences between upstream and downstream Specific Conductance, suggesting no effluent effects. Fecal Coliform — Instream monitoring for Fecal Coliform is not required in the current permit, as the receiving water is neither Class B nor is it impaired due to Fecal Coliform as per Division guidance. No changes are proposed concerning instream monitoring. Is this facility a member of a Monitoring Coalition with waived instream monitoring (Y/N): YES. Name of Monitoring Coalition: Upper Cape Fear River Basin Association (UCFRBA). 5. Compliance Summary Summarize the compliance record with permit effluent limits (past 5 years): From July 2016 through June 2021, a total of 14 limit exceedences were reported (Table 3). The exceedences resulted in 12 Notices of Violation (NOVs), one Notice of Deficiency (NOD) and one no action. Most exceedences were due to an algal bloom in the finishing pond from June -August 2018; the Fecal Coliform exceedance was due to a high rain event that exceeded design flow and inhibited chlorination. The one Ammonia exceedance, in May 2021, did not result in a violation action. Page 4 of 12 Table 3. Monitoring Report Violations: 2016-2021. Parameter -IIINViolation Type Number of Violations BOD Monthly Average Exceeded 1 BOD Weekly Average Exceeded 3 Fecal Coliform Weekly Geometric Mean Exceeded 1 Ammonia-N Monthly Average Exceeded 1 TSS Monthly Average Exceeded 3 TSS Weekly Average Exceeded 5 Summarize the compliance record with aquatic toxicity test limits and any second species test results (past 5 years): The facility passed 17 of 17 quarterly chronic toxicity tests from March 2017 through March 2021. Summarize the results from the most recent compliance inspection: The most recent facility inspection, conducted on 01/10/2019, reported that the facility to be satisfactory; compliance issues in 2018 relating to an algal bloom in the finishing pond are noted. 6. Water Quality -Based Effluent Limitations (WQBELs) Dilution and Mixing Zones In accordance with 15A NCAC 2B.0206, the following stream flows are used for dilution considerations for development of WQBELs: 1 Q 10 streamflow (acute Aquatic Life); 7Q10 streamflow (chronic Aquatic Life; non -carcinogen HH); 30Q2 streamflow (aesthetics); annual average flow (carcinogen, HH). If applicable, describe any other dilution factors considered (e.g., based on CORMIX model results): NA. If applicable, describe any mixing zones established in accordance with 1 SA NCAC 2B. 0204(b): NA. Oxygen -Consuming Waste Limitations Limitations for oxygen -consuming waste (e.g., BOD) are generally based on water quality modeling to ensure protection of the instream dissolved oxygen (DO) water quality standard. Secondary TBEL limits (e.g., BOD = 30 mg/L for Municipals) may be appropriate if deemed more stringent based on dilution and model results. If permit limits are more stringent than TBELs, describe how limits were developed: Year-round BOD limits in the current permit are based on the TBEL of 30/45 mg/L monthly average/weekly average, and have been in the permit since 2007 or earlier. No changes are proposed. Ammonia and Total Residual Chlorine Limitations Limitations for ammonia are based on protection of aquatic life utilizing an ammonia chronic criterion of 1.0 mg/L (summer) and 1.8 mg/L (winter). Acute ammonia limits are derived from chronic criteria, utilizing a multiplication factor of 3 for Municipals and a multiplication factor of 5 for Non -Municipals. Limitations for Total Residual Chlorine (TRC) are based on the NC water quality standard for protection of aquatic life (17 µg/L) and capped at 28 µg/L (acute impacts). Due to analytical issues, all TRC values reported below 50 µg/L are considered compliant with their permit limit. Page 5 of 12 Describe any proposed changes to ammonia and/or TRC limits for this permit renewal. Ammonia limits in the current permit are toxicity -based, first placed in the permit before 2007 Ammonia was reviewed in the attached Wasteload Allocation (WLA) sheet using the flow design of 0.48 MGD and receiving stream low flows of 7Q 10s = 11 cfs and 7Q 10w = 23 cfs. The resulting allowable concentrations were found to be the same as the current limits. The current Ammonia limits will be maintained in the permit. WLA calculations for TRC cap the allowable concentration at 28 µg/L, the same value as the current permit limit. The current TRC limit will be maintained in the permit. Reasonable Potential Analysis (RPA) for Toxicants If applicable, conduct RPA analysis and complete information below. The need for toxicant limits is based upon a demonstration of reasonable potential to exceed water quality standards, a statistical evaluation that is conducted during every permit renewal utilizing the most recent effluent data for each outfall. The RPA is conducted in accordance with 40 CFR 122.44 (d) (i). The NC RPA procedure utilizes the following: 1) 95% Confidence Level/95% Probability; 2) assumption of zero background; 3) use of Y2 detection limit for "less than" values; and 4) stream flows used for dilution consideration based on 15A NCAC 2B.0206. Effective April 6, 2016, NC began implementation of dissolved metals criteria in the RPA process in accordance with guidance titled NPDES Implementation of Instream Dissolved Metals Standards, dated June 10, 2016. A data set of six effluent and upstream Hardness results, from quarterly sampling from March 2020—June 2021, were provided by the ORC upon request. Average upstream hardness was 36 mg/L, greater than the default value of 25 mg/L, and therefore were used in the RPA. A reasonable potential analysis was conducted on effluent toxicant data collected from June 2017—May 2021. Pollutants of concern included toxicants with positive detections and associated water quality standards/criteria. Based on this analysis, the following permitting actions are proposed for this permit: • Effluent Limit with Monitoring. The following parameters will receive a water quality -based effluent limit (WQBEL) since they demonstrated a reasonable potential to exceed applicable water quality standards/criteria: Copper. • Monitoring Only. The following parameters will receive a monitor -only requirement since they did not demonstrate reasonable potential to exceed applicable water quality standards/criteria, but the maximum predicted concentration was > 50% of the allowable concentration: None. • No Limit or Monitoring: The following parameters will not receive a limit or monitoring, since they did not demonstrate reasonable potential to exceed applicable water quality standards/criteria and the maximum predicted concentration was < 50% of the allowable concentration: Arsenic, Cadmium, Total Chromium, Cyanide, Lead, Nickel, Silver, Zinc. If applicable, attach a spreadsheet of the RPA results as well as a copy of the Dissolved Metals Implementation Fact Sheet for freshwater/saltwater to this Fact Sheet. Include a printout of the RPA Dissolved to Total Metal Calculator sheet if this is a Municipality with a Pretreatment Program. Toxicity Testing Limitations Permit limits and monitoring requirements for Whole Effluent Toxicity (WET) have been established in accordance with Division guidance (per WET Memo, 8/2/1999). Per WET guidance, all NPDES permits issued to Major facilities or any facility discharging "complex" wastewater (contains anything other than domestic waste) will contain appropriate WET limits and monitoring requirements, with several exceptions. The State has received prior EPA approval to use an Alternative WET Test Procedure in NPDES permits, using single concentration screening tests, with multiple dilution follow-up upon a test failure. Page 6 of 12 Describe proposed toxicity test requirement: The facility is a POTW with a chronic WET limit at 6% effluent, which will continue at a quarterly frequency. The WET limit is based on the Instream Waste Concentration (IWC) as calculated from the design flow of 0.48 MGD and the receiving stream 7Q10s of 11 cfs (WET Permitting Limits and Monitoring Requirements guidance memo, 8/2/1999). Mercury Statewide TMDL Evaluation There is a statewide TMDL for mercury approved by EPA in 2012. The TMDL target was to comply with EPA's mercury fish tissue criteria (0.3 mg/kg) for human health protection. The TMDL established a wasteload allocation for point sources of 37 kg/year (81 lb/year) and is applicable to municipals and industrial facilities with known mercury discharges. Given the small contribution of mercury from point sources (-2% of total load), the TMDL emphasizes mercury minimization plans (MMPs) for point source control. Municipal facilities > 2 MGD and discharging quantifiable levels of mercury (> 1 ng/L) will receive an MMP requirement. Industrials are evaluated on a case -by -case basis, depending on if mercury is a pollutant of concern. Effluent limits may also be added if annual average effluent concentrations exceed the WQBEL value (based on the NC WQS of 12 ng/L) and/or if any individual value exceeds a TBEL value of 47 ng/L. Describe proposed permit actions based on mercury evaluation: Quarterly low-level mercury monitoring is required in the current permit as well as a Mercury TMDL Reopener special condition. Submitted mercury data from July 2017—June 2021 were reviewed for TMDL evaluation. Results included detections with no annual averages exceeding the WQBEL of 189.4 ng/L and no individual values exceeding the TBEL of 47 ng/L (Table 4). Because the design flow is < 2 MGD, no MMP is required; quarterly monitoring for mercury and the Mercury TMDL Reopener special condition were removed from the permit. Table 4. Mercury Effluent Data Summary 1E7 2018 2019 2020 202i # of Samples 3 4 5 4 1 Annual Average Conc. ng/L 0.5 1.0 0.7 1.5 1.4 Maximum Conc., ng/L 0.50 1.90 1.60 3.5 1.40 TBEL, ng/L 47 WQBEL, ng/L 189.4 Other TMDL/Nutrient Management Strategy Considerations If applicable, describe any other TMDLs/Nutrient Management Strategies and their implementation within this permit: NA. Other WQBEL Considerations If applicable, describe any other parameters of concern evaluated for WQBELs: The current permit has a permit-reopener special condition for any additional effluent monitoring deemed necessary to support water quality protection and restoration efforts in the receiving stream. Ramseur WWTP had participated in a basin -wide survey for the emerging contaminants 1,4-Dioxane and PFAS chemical group in 2019. Three rounds of influent sampling were conducted in July, August, and September 2019. Reviewed data from the sampling found effluent concentrations to be below the EPA Drinking Water Health Advisory Levels (HALs) for 1,4-Dioxane and that for PFAS + PFOA (Table 5). Table 5. Influent Monitoring Results of Emerging Contaminants, 2019. Parameter Average (Range) HAL Page 7 of 12 1,4-Dioxane, µg/L 2.04 (< 1.0-2.08) 35 PFOA + PFOS, ng/L 22.39 (9.45-47.7) 70 The POTW lies downstream of where the discharge from Asheboro WWTP enters the Deep River, a discharge that has reported high levels of 1,4-Dioxane. The Ramseur WWTP discharges into a Class C waterbody with the nearest WS boundary at 43.9 miles downstream. Based on the calculated mass loading of average 1,4-Dioxane concentrations reported from July —September 2019 and associated average discharge flow, the calculated instream concentration is 0.001 µg/L. With limited data (< 12 samples), monthly monitoring for this parameter will be added to the permit. The supplemental sampling reopener special condition is maintained in the permit. An additional permit reopener special condition regarding 1,4-Dioxane based on changes toward limits, monitoring or treatment has been added to the permit. Based on detection of PFAS chemicals in the influent from the 2019 samplings, which was also provided as an attachment to the NPDES application received on 1/20/2022, monitoring of PFAS chemicals were added to the permit at a frequency of 2/year. Since an EPA method for sampling and analyzing PFAS in wastewater is not currently available, the PFAS monitoring requirement in the permit includes the effective date that is delayed until the first full calendar quarter beginning 6 months after EPA has a final wastewater method in 40 CFR 136 published in the Federal Register. This date may be extended upon request if there are no NC -certified labs. If applicable, describe any special actions (HQW or ORW) this receiving stream and classification shall comply with in order to protect the designated waterbody: NA. If applicable, describe any compliance schedules proposed for this permit renewal in accordance with 15A NCAC 2H.0107(c)(2)(B), 40CFR 122.47, and EPA May 2007 Memo: A three-year compliance schedule with a WER study option for the new Copper limits has been added to the permit. If applicable, describe any water quality standards variances proposed in accordance with NCGS 143- 215.3(e) and 15A NCAC 2B. 0226 for this permit renewal: NA. 7. Technology -Based Effluent Limitations (TBELs) Municipals (if not applicable, delete and skip to Industrials) Are concentration limits in the permit at least as stringent as secondary treatment requirements (30 mg/L BOD5/TSSfor Monthly Average, and 45 mg/L for BOD5/TSSfor Weekly Average). Yes. If NO, provide a justification for alternative limitations (e.g., waste stabilization pond). NA. Are 85% removal requirements for BOD5/TSS included in the permit? YES. If NO, provide a justification (e.g., waste stabilization pond). NA. 8. Antidegradation Review (New/Expanding Discharge) The objective of an antidegradation review is to ensure that a new or increased pollutant loading will not degrade water quality. Permitting actions for new or expanding discharges require an antidegradation Page 8 of 12 review in accordance with 15A NCAC 2B.0201. Each applicant for a new/expanding NPDES permit must document an effort to consider non -discharge alternatives per 15A NCAC 2H.0105(c)(2). In all cases, existing instream water uses and the level of water quality necessary to protect the existing use is maintained and protected. If applicable, describe the results of the antidegradation review, including the Engineering Alternatives Analysis (EAA) and any water quality modeling results: NA. 9. Antibacksliding Review Sections 402(o)(2) and 303(d)(4) of the CWA and federal regulations at 40 CFR 122.44(1) prohibit backsliding of effluent limitations in NPDES permits. These provisions require effluent limitations in a reissued permit to be as stringent as those in the previous permit, with some exceptions where limitations may be relaxed (e.g., based on new information, increases in production may warrant less stringent TBEL limits, or WQBELs may be less stringent based on updated RPA or dilution). Are any effluent limitations less stringent than previous permit (YES/NO): NO. If YES, confirm that antibacksliding provisions are not violated: NA. 10. Monitoring Requirements Monitoring frequencies for NPDES permitting are established in accordance with the following regulations and guidance: 1) State Regulation for Surface Water Monitoring, 15A NCAC 2B.0500; 2) NPDES Guidance, Monitoring Frequency for Toxic Substances (7/15/2010 Memo); 3) NPDES Guidance, Reduced Monitoring Frequencies for Facilities with Superior Compliance (10/22/2012 Memo); 4) Best Professional Judgement (BPJ). Per US EPA (Interim Guidance, 1996), monitoring requirements are not considered effluent limitations under Section 402(o) of the Clean Water Act, and therefore anti -backsliding prohibitions would not be triggered by reductions in monitoring frequencies. All parameters in the current permit are monitored according to 15A NCAC 2B .0500. For instream monitoring, refer to Section 4. 11. Electronic Reporting Requirements The US EPA NPDES Electronic Reporting Rule was finalized on December 21, 2015. Effective December 21, 2016, NPDES regulated facilities are required to submit Discharge Monitoring Reports (DMRs) electronically. Effective December 21, 2020, NPDES regulated facilities will be required to submit additional NPDES reports electronically. This permit contains the requirements for electronic reporting, consistent with Federal requirements. 12. Summary of Proposed Permitting Actions Table 6. Current Permit Conditions and Proposed Changes. Parameter Current Permit' Proposed Change Basis for Condition/Change Page 9 of 12 Flow 0.48 MGD No change 15A NCAC 2B .0505 BOD5 MA = 30.0 mg/L WA = 45.0 mg/L Monitor weekly No change TBEL. Secondary treatment standards / 40 CFR 133 / 15A NCAC 2B .0406. State WQ reporting requirements 15A NCAC 2B .0500. TSS MA = 30.0 mg/L WA = 45.0 mg/L Monitor weekly No change TBEL. Secondary treatment standards / 40 CFR 133 / 15A NCAC 2B .0406. State WQ reporting requirements 15A NCAC 2B .0500. NH3-N Summer MA = 18.0 mg/L WA = 35.0 mg/L Summer Monitor only Monitor 2/month No change WQBEL. Calculation results based on statewide 1.0/1.8 mg/L summer/winter values in wasteload allocations to protect against NH3-N toxicity (see WLA sheet attached). DO DA > 5.0 Monitor weekly No change WQBEL. State WQ standard, 15A NCAC 2B .0200. pH 6-9 SU Monitor weekly No change WQBEL. State WQ standard, 15A NCAC 2B .0200. Temperature Monitor weekly No change State WQ reporting requirements 15A NCAC 2B .0500. Fecal Coliform MA = 200 /100 mL WA = 400 /100 mL Monitor weekly No change WQBEL. State WQ standard, 15A NCAC 2B .0200. and .0500. Total Residual Chlorine (TRC) DM = 28 µg/L Monitor 2/week No change WQBEL. State WQ acute standard, 15A NCAC 2B .0200 Total Nitrogen (NO3+NO2 + TKN) Monitor quarterly No change State WQ reporting requirements 15A NCAC 2B .0500. Total Phosphorus Monitor quarterly No change State WQ reporting requirements 15A NCAC 2B .0500. Total Hardness No requirement Add quarterly monitoring at effluent and instream, upstream of discharge Hardness -dependent dissolved metals water quality standards, approved in 2016, need effluent and instream hardness data for calculations of permit limitations. Total Copper Monitor quarterly MA = 175 µg/L DM = 204 µg/L Add 3-yr compliance schedule with WER study option WQBEL. Reasonable potential to exceed allowable discharge concentration (RP) found. Parameter Current Permit' Proposed Change Basis for Condition/Change Total Mercury Monitor quarterly TMDL permit reopener special condition Remove from permit In accordance with 2012 Statewide Mercury TMDL Implementation, per facility size and monitoring data criteria. Page 10 of 12 Toxicity Test Chronic Ceriodaphniadubia Pass/Fail at 6 /0 effluent No change WQBEL. No toxics in toxic amounts. 15A NCAC 2B.0200 and 15A NCAC 2B.0500. 1,4-Dioxane No requirement Add monthly monitoring Based limited influent data showing detection, more results are needed to evaluate. PFAS No requirement Add monitoring 2/year with delayed implementation Based limited influent data showing detection, more results are needed to evaluate. Implementation delayed until after EPA certified method becomes available. Electronic Reporting Electronic Reporting Special Condition Update condition to remove submittal of hardcopies and extended Phase 2 deadline to 2025. In accordance with EPA Electronic Reporting Rule 2015. Footnote. 1. MGD = Million gallons per day; MA = Monthly Average; WA = Weekly Average; DM = Daily Maximum. 13. Public Notice Schedule: Permit to Public Notice: 11/23/2021, 2/12/2022 Per 15A NCAC 2H .0109 & .0111, The Division will receive comments for a period of 30 days following the publication date of the public notice. Any request for a public hearing shall be submitted to the Director within the 30 days comment period indicating the interest of the party filing such request and the reasons why a hearing is warranted. 14. NPDES Division Contact: If you have questions regarding any of the above information or on the attached permit, please contact Gary Perlmutter at (919) 707-3611 or via email at gary.perlmutter@ncdenr.gov. 15. Fact Sheet Addendum (if applicable): Were there any changes made since the Draft Permit was public noticed (Yes/No): Yes; comments were provided by the Southern Environmental Law Center (SELC) regarding the disclosure of emerging contaminants PFAS and 1,4-Dioxane during the permitting process. Information regarding PFAS and 1,4- Dioxane in the draft permit fact sheet is from sampling conducted in 2019 and the data from which are available on the Division's website. The Division requested supplemental information on 1/4/2022, which was then received on 1/7/2022 via a Chemical Addendum package to the permit application. It should be noted that the Permittee included information on 1,4-Dioxane on the Chemical Addendum form in addition to providing additional material on PFAS as supplemental. The limited dataset (n = 3 for each parameter) precludes assessment for limitations or management strategies but necessitates monitoring to build a more robust dataset for such assessment. Page 11 of 12 The proposed 1,4-Dioxane monitoring requirement and the 1,4-Dioxane permit reopener special condition address 1,4-Dioxane. In addition, a PFAS monitoring requirement special condition has been added to address PFAS. These changes were sent out in a second draft permit, public noticed on 11/23/2021. Comments were received from SELC; none from any other party. Second Draft SELC comments included: • Ramseur has not adequately disclosed discharges of PFAS and 1,4-Dioxane. • Monitoring for PFAS cannot wait for EPA to publish a final wastewater method. • Ramseur should use its pretreatment authority to control any industrial sources. The Division disagrees with the first two comments, responding that the monitoring requirements placed in the permit are adequate to address the paucity of data currently available from Ramseur. Further, monitoring for PFAS will begin when a final method is published and state laboratories are certified in the new method. A reminder to update the Town's pretreatment program is noted in the cover letter to the final permit. Ramseur is required to comply with pretreatment conditions found in 15A NCAC 02H .0900. If Yes, list changes and their basis below: Revisions based on first draft, public noticed on 11/23/2021: • Quarterly monitoring of 1,4-Dioxane have been increased to monthly to build a more robust dataset for evaluation. • A PFAS monitoring special condition has been added to the permit with a frequency of 2/year to be implemented six months after EPA publishes a final wastewater method in 40 CFR Part 136 in the Federal Register. The schedule is to allow time for laboratories to receive state certification for the method. • Permit expiration date has been extended to January 31, 2027 to better fit a five-year cycle. No changes have been made to the second draft, public noticed on 2/12/2022. 16. Fact Sheet Attachments (if applicable): • 2018 NC Final 303(d) list, page 12 • Effluent summary charts and tables • DMR notes explaining high reported values • Instream Monitoring summary charts and tables • Monitoring Report (MR) Violations page • WET testing and Self -Monitoring Summary, page 91 • Compliance Inspection Report • NH3/TRC WLA Calculations sheet • RPA Spreadsheet Summary • Dissolved Metals Implementation Freshwater • Permittee-collected Hardness data • Mercury WQBEL/TBEL Evaluation data and summary table • Emerging Compounds Influent Monitoring Data • Public Notice Affidavit • Comments by SELC and DWR responses • Chemical Addendum package from Permittee • Comments by SELC to the second draft permit Page 12 of 12 A B I C I D I E I F I G I H I I I J I K I L I M N I 0 I P 1 2 3 4 5 6 7 8 9 0 11 12 14 15 16 17 18 19 20 21 22 23 24 25 26 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 NPDES/PT POC Review Form 1. Facility's General Information Version: 2022.03.04 Date of (draft) Review 11/23/2021 a. POC review due to: e. Contact Information Date of (final) Review 4/4/2022 Municipal NPDES renewal Regional Office (RO) (Winston-Salem Regional Office (WSRO) NPDES Permit Writer Gary Perlmutter New Industries RO PT Staff Alexander Lowe and Jim Gonsiewski RO NPDES Staff (Lon Snider Pennittee-Facility Name Town of Ramseur- Ramseur WWTP WWTP expansion 0 Facility PT Staff, email I Lisa Ostheus olisaopretreat56gmail.com> NPDES Permit Number NC0026565 Stream reclassJadjustment 0 f. Receiving Stream NPDES Permit Effective Date 9/1/2016 Outfall relocation/adjustment 0 Duffel! I NPDES Permit Renewal Application Date 4/30/2021 7010 updateReceiving 0 9 Stream: Deep River OA, cis: 350 NPDES Permit Public Notice Date 10/23/2021, 2/12/2022 Other, explain below 0 Stream Class C 7Q10 (S), cis: 11 eDMR data evaluated from: 6/1 /2016 I to I 5/31/2021 Comments on POC review trigger: Oufall Lat. 35' 43' 07" N Outfall Long. 79. 39' 0T N a. WWTP Capacity Summary Duffel! 11 Current Permitted Flow, mgd 0.480 Designed Flow, mgd g d 0.480 Permit renewal Receiving Stream: QA, cis: Permitted SIU Flow, mgd 0.0250 d. IU Summary Stream Class 7Q10, cfs: b. PT Docs. Summary # IUs 1 Oufan Lat. Outfall Long. IWS approval date 5/5/2021 # Ms 1 Comments: L/STMP approval date: 10/2/2015 # Gills 1 # NSCIUs 0 Based on SIU discharge, monitoring for 1,4-Dioxane and PFAS monitroing is recommended. H W A m # approval date Industrial User (IU) Name 2/8/2018 IU Activity # IUs w/Local Permits or Other Types IU Conventional 0 2. Pollutants Industrial Users' Info IU Non Conventional Pdlutans & Toxic Pollutant IUP Effective Date 3 1 'E Matlab, Inc. a33.11 Metal Finisher, pH, Temperature Cd, Cr, Cu, CN, Pb, Hg, Ni, Ag, TTO, Zn 7/30/2021 a 0 m 3 0 a a Z s Comment: 3. Comments from NPDES pw Facility Summary and NPDES regulatory action: Comments from NPDES pw to PT staff (Central, RO, Facility): The Town of Ramseur had applied for an NPDES permit renewal for received by DWR on November 5, 2020. Review of the application its WWTP, found it to be Please maintain the following POC-NPDES required pollutants: pH, Temperature, Cd, Cr, Cu, Pb, Hg, Ni, Ag, TTO, Zn complete. This 0.480 MGD facility serves the Town of Ramseur (pop. WWTP is classified as a POTW that treats domestic and industrial with an active involving one Significant Industrial —1690). The wastewater User POC that need to be added/mgdigea in USTMP sampling plan: 1 4-Dioxane, PFAS pretreatment program (SIU). POC that may be removed from USTMP sampling plan: ORC's comments on IU/POC: Additional pollutants added to USTMP due to POTWs concerns: NPDES pw's comments on IUs 4. Status of Pretreatment Program (check all that apply) Status of Pretreatment Program (check all that apply) ❑ 1) facility has no SIU's, does have Division approved Pretreatment Program that is INACTIVE ❑ 2) facility has no SIU's, does not have Division approved Pretreatment Program 0 3) facility has Sills and DWQ approved Pretreatment Program ❑ 3a) Full Program with LTMP 0 3b) Modified Program with STMP 4) additional conditions regarding Pretreatment attached or listed below 17 5) facility's sludge is being land applied or composted n • ❑ 6) facility's sludge is incinerated (add 7) facility's sludge is taken to a landfill, 8) other Beryllium and Mercury sampling if yes which landfill: accord ng to § 503.43) Sludge Disposal Plan: Land application 55 Sludge Permit No: W40010528 Page 1 26565 POC Review Form 2022 PARAMETER AU Name AU ID Description Little Troublesome Creek 13502 From SR2600 to Haw River IR CATEGORY CRITERIA STATUS Ai Benthos (Nar, AL, FW) NORTH CAROLINA 2020 303(D) LIST Haw Cape Fear River Basin AU Number Classification Length or Area Units 16-7-(2) WS-IV;NSW 0.9 FW Miles REASON FOR RATING 303D YEAR '5 lExceeding Criteria Fair, Poor or Severe Bioclassification 2020 Cape Fear River Basin 1111111111MM.m=1111111 Deep DEEP RIVER 4128 From Haskett Creek to Gabriels Creek 17-(10.5)d1 C 2.7 FW Miles PARAMETER IR CATEGORY CRITERIA STATUS REASON FOR RATING 303D YEAR Chlorophyll a (40 µg/I, AL, NC) DEEP RIVER 129771 5 Exceeding Criteria Exceeding Criteria with Statistical Confidence From Gabriels Creek to Brush Creek 17-(10.5)d2 C 2008 18.2 FW Miles PARAMETER IR CATEGORY CRITERIA STATUS REASON FOR RATING 303D YEAR Copper (7 µg/I, AL, FW) 5 Data Inconclusive Legacy Category 5 Total Metals Assessment Deep River 17-(3.7) WS-IV;CA:* 2.0 FW Miles 4136 From Guilford County SR 1334 to dam at Oakdale Cotton Mills, Inc. (Town of Jamestown water supply intake) PARAMETER IR CATEGORY CRITERIA STATUS REASON FOR RATING 303D YEAR Benthos (Nar, AL, FW) Exceeding Criteria Fair, Poor or Severe Bioclassification 2018 Penwood Branch 4161 From source to Haskett Creek 17-12-1 6.1 FW Miles PARAMETER IR CATEGORY CRITERIA STATUS REASON FOR RATING 303D YEAR Benthos (Nar, AL, FW) Sandy Creek 4164 From source to SR 2495 5 Exceeding Criteria Fair, Poor or Severe Bioclassification 2006 17-16-(1)a WS-III 16.1 FW Miles PARAMETER IR CATEGORY CRITERIA STATUS REASON FOR RATING 303D YEAR Chlorophyll a (40 µg/I, AL, NC) 5 Exceeding Criteria Exceeding Criteria with Statistical Confidence 2018 7/21/2021 NC 2020 303d List- Approved by EPA June 23,2021 Page 12 of 188 Ramseur WWTP Effluent Monitoring NC0026565 0.60 0.50 0.40 0 � 0.30 0.20 0.10 0.00 Al oti' otio oti'' o''' otio otio 01' 01' 01' 01' Flow • Mo Avg -Limit • • •• • ••N •• • •• •• • • • ••• •• •N•� • •• ••�• • 90 80 70 60 �� 50 o E 40 30 20 10 0 Biological Oxygen Demand (BOD) Wk Avg ♦ Mo Avg WA Limit — — MA Limit otio' otio' otio otio oti° otiti otiti otio Summary Statistics N 1460 Avg 0.194 SD 0.171 Min 0.027 Max 1.602 Summary Statistics N 213 Avg 11.9 SD 13.1 Min 2.0 Max 146.0 Summary Statistics N 214 Avg 10.6 SD 12.6 Min 2.5 Max 66.0 Page 1 of 4 GB Perlmutter 11/23/2021 Effluent Monitoring NCOO26565 Ramseur WWTP 40.0 35.0 30.0 25.0 J n 20.0 15.0 pH • Effluent - - - L. Limit U. Limit 9.5 - 9.0 - 8.5 - 8.0 - IU • • • O�� O� O,� O,� O,� Off° ol> O�y O1� Summary Statistics summer N 55 Avg 7.8 SD 5.0 Min 0.3 Max 21.6 winter N 43 Avg 8.3 SD 6.2 Min 0.4 Max 19.8 Summary Statistics N 904 Avg 6.1 SD 0.3 Min 5.8 Max 7.8 Summary Statistics N 904 Avg 6.9 SD 0.1 Min 6.7 Max 7.5 Page 2 of 4 GB Perlmutter 11/23/2021 Ramseur WWTP Effluent Monitoring N C0026565 40 35 30 25 ;-' 20 15 10 5 0 Temperature - IP slie 8 ifilfr% _if —I . - 1 1 et s d Is 1 si ik jet IV V t tit 411 oti oti oti oti oti° oti° oti° oti otiy oti \o o\vti\� \ti°\� y°\y�\n h\ti`'\� y\N• o\tiw\� y\°\ti 1,000.0 E 100.0 4 U E 10.0 0 v C7 Fecal Coliform Wk Avg • Mo Avg WA Limit - - - MA Limit • • •A• N • sit AA • • %. •• •• • • • • • • • N • • •N • • -- 11=0 oti oti' oti oti' oti° oti° 61' 61' oti• o�\moo\ti o\�\y�\ti\ti o\�4\ti • ••• • • • sigainesbeat• Summary Statistics N 903 Avg 18.6 SD 8.1 Min 3.0 Max 34.0 Summary Statistics N 212 Geomean 1.7 Min 1 Max 3200 Summa Statistics N 26 Avg 9.26 SD 4.81 Min 1.73 Max 19.60 TKN N 22 Avg 1.10 SD 0.85 Min 0.12 Max 3.15 NO2+NO3 N 32 Avg 10.74 SD 4.80 Min 3.47 Max 24.35 Page 3 of 4 GB Perlmutter 11/23/2021 Ramseur WWTP Effluent Monitoring NC0026565 Summary Statistics N 32 Avg 2.79 SD 1.13 Min 1.37 Max 6.77 Page 4 of 4 GB Perlmutter 11/23/2021 Ramseur WWTP DMR Notes NC0026565 October 2017 10/10: Effluent BOD - No dilution depleted at least 2.0 mg/I with a residual of at least 1.0 mg/I Exceeded the weekly BOD limit during the 2nd & 3rd week and the monthly average BOD. Violation resulted from stratification of the finishing pond. June 2018 The Ramseur Wastewater Treatment Facility design incorporates an activated sludge treatment system followed by a finishing pond prior to final discharge. During this reporting period the finishing pond experienced excessive algae growth which adversely affected effluent quality and contributed to noncompliance of a weekly and monthly TSS as well as a weekly BOD exceedance for the last week of June. July 2018 The Ramseur WWTP experienced elevated effluent Total Suspended Solids levels which exceeded the weekly and monthly TSS limitations. The Ramseur WWTP treatment scheme includes an activated sludge system with secondary clarification followed by a finishing lagoon prior to disinfection and dechlorination. The elevated TSS concentrations were due to an excessive algal bloom in the lagoon. Corrective measures have included treatment of the lagoon to reduce the algae issue. August 2018 Exceeded Effluent weekly and monthly TSS due to algal bloom in finishing pond prior to discharge. Corrective measures are being taken to reduce algae concentrations. December 2018 The treatment plant received 1.2 inches of rainfall overnight from 12/27 to 12/28 and the flow increased from 0.35 MGD to over 1.0 MGD during that period. The design flow capacity of this facility is 0.480 MGD. The fecal coliform sample was collected at 11:15 am on the 28th. The extraneous flow inhibited the proper chlorination of the wastewater. In addition, the sample schedule was altered due to the holiday. Normal sample schedule includes sampling on Tuesdays which affords time to resample if needed. Ramseur WWTP Instream Monitoring NC0026565 Dissolved oxygen (DO), mg/L Date Upstream Dnstream Effluent Standard 2017-06-06 7.8 7 6.2 5.0 2017-06-23 7.1 7.4 6 5.0 2017-07-14 6.9 6.9 5.9 5.0 2017-07-27 7 6.3 6 5.0 2017-08-07 6.8 6.1 6 5.0 2017-08-25 7 6.7 5.9 5.0 2017-09-15 7.2 6.8 5.9 5.0 2017-09-29 7.2 6.1 6 5.0 2017-10-31 9.2 8.7 6.1 5.0 2017-11-22 10.5 10.3 6 5.0 2017-12-08 11.3 10.7 6 5.0 2018-01-10 13.2 12.8 6.2 5.0 2018-02-19 10.2 9.9 6.1 5.0 2018-03-23 11.4 11.1 6.3 5.0 2018-04-20 8.9 8.8 6.1 5.0 2018-05-02 8.8 8.7 6 5.0 2018-05-31 6.9 6.6 6 5.0 2018-06-08 6.7 6.6 5.9 5.0 2018-06-19 6.8 7 6 5.0 2018-07-02 6.9 6.9 5.9 5.0 2018-07-18 6.6 6.8 5.9 5.0 2018-08-06 7.3 6.9 5.9 5.0 2018-08-31 7.2 6 6.2 5.0 2018-09-14 6.2 5.9 6.2 5.0 2018-09-28 7.5 7 6.2 5.0 2018-10-29 9.1 8.8 6.4 5.0 2018-11-09 8.8 8.4 6.5 5.0 2018-12-17 13.1 12.5 6.1 5.0 2019-01-18 11.5 10.9 6.2 5.0 2019-02-12 11 10.9 6 5.0 2019-03-01 11.2 10.9 6.1 5.0 2019-04-05 9.6 9 6 5.0 2019-05-08 7.8 7.2 6.1 5.0 2019-05-28 7.4 6.8 5.8 5.0 2019-06-20 7.2 7 6 5.0 2019-06-28 6.6 6.5 5.9 5.0 2019-07-08 6.2 6.4 5.8 5.0 2019-07-24 7.3 6.9 5.9 5.0 2019-08-02 7.3 6.3 5.8 5.0 2019-08-19 7.4 7.3 5.8 5.0 2019-09-12 6.9 6.8 5.8 5.0 2019-09-26 7.5 7.7 5.8 5.0 2019-10-25 8.4 8.8 5.8 5.0 2019-11-13 10.8 10.6 6.3 5.0 2019-12-31 10.8 10.7 6.7 5.0 2020-01-31 11 10.9 6.3 5.0 2020-02-12 10.9 10.9 6.5 5.0 1 of 9 GB Perlmutter 11/23/2021 Ramseur WWTP Instream Monitoring NC0026565 Dissolved oxygen (DO), mg/L Date Upstream Dnstream Effluent Standard 2020-03-09 10.4 10.3 6.2 5.0 2020-04-07 10.5 10.2 6.2 5.0 2020-05-08 8.4 8.4 6.1 5.0 2020-05-20 8.9 8.7 6.4 5.0 2020-06-12 7 7.2 6.2 5.0 2020-06-26 7.2 7.2 6 5.0 2020-07-10 7.2 7.1 6 5.0 2020-07-28 6.2 6.2 5.9 5.0 2020-08-04 7.2 7 5.9 5.0 2020-08-21 6.7 6.6 5.8 5.0 2020-09-04 7.2 7.1 5.9 5.0 2020-09-24 7.5 7.3 6 5.0 2020-10-14 8.1 7.9 5.0 2020-10-15 6 5.0 2020-11-02 9 8.8 5.0 2020-11-03 6 5.0 2020-12-15 6.1 5.0 2020-12-17 11.2 11.2 5.0 N Avg SD Min Max 62 62 62 8.4 8.2 6.1 #N/A #N/A #N/A 6.2 5.9 5.8 13.2 12.8 6.7 14.0 12.0 10.0 E 8.0 6.0 4.0 2.0 0.0 Dissolved Oxygen (DO) • Upstream • Effluent ♦ Dnstream -Standard 2 • ♦ • 2 n nr)no • 2 !. n Asnivl bSIN■ ■ li■�■1 ■ lON' yON' 10,E Oh 'C O(O O' 0A' 2 of 9 GB Perlmutter 11/23/2021 Ramseur WWTP Instream Monitoring NC0026565 Dissolved oxygen (DO), mg/L Date Upstream Dnstream Effluent Standard t-Test: Two -Sample Assuming Unequal Variances Upstream Dnstream Mean 8.437097 8.183871 Variance 3.404995 3.383998 Observations 62 62 Hypothesized Mean Difference 0 df 122 t Stat 0.765246 P(T<=t) one -tail 0.222801 t Critical one -tail 1.657439 P(T<=t) two -tail 0.445603 t Critical two -tail 1.9796 3 of 9 GB Perlmutter 11/23/2021 Ramseur WWTP Instream Monitoring NC0026565 Temperature, water ('CJ Date Upstream Dnstream D-U Diff Effluent Standard 2017-06-06 23.6 23.6 0 25 32 2017-06-23 26 26.2 0.2 24 32 2017-07-14 30.3 29.5 -0.8 27 32 2017-07-27 28.7 28.4 -0.3 28 32 2017-08-07 26.5 25.9 -0.6 25 32 2017-08-25 26 25.5 -0.5 25 32 2017-09-15 23.1 22.4 -0.7 21 32 2017-09-29 24.4 23.4 -1 23 32 2017-10-31 13.2 12.9 -0.3 11.8 32 2017-11-22 10.5 9.8 -0.7 9 32 2017-12-08 9.3 9 -0.3 7 32 2018-01-10 2.7 2.2 -0.5 3 32 2018-02-19 11.3 11 -0.3 12 32 2018-03-23 9.4 10.1 0.7 9 32 2018-04-20 16 15.4 -0.6 16 32 2018-05-02 18.5 18.1 -0.4 17 32 2018-05-31 24.3 24 -0.3 23 32 2018-06-08 26.4 25.6 -0.8 24 32 2018-06-19 29.9 28.6 -1.3 24 32 2018-07-02 29.9 29.7 -0.2 28 32 2018-07-18 29.3 27.8 -1.5 26 32 2018-08-06 27.5 27.4 -0.1 25 32 2018-08-31 27.4 26.9 -0.5 27 32 2018-09-14 24.6 24.8 0.2 27 32 2018-09-28 24.1 24.1 0 23 32 2018-10-29 15.3 15.2 -0.1 13 32 2018-11-09 15.4 15.1 -0.3 15 32 2018-12-17 7.7 7.7 0 7 32 2019-01-18 7.6 7.6 0 7 32 2019-02-12 9.3 9.5 0.2 8 32 2019-03-01 9.5 10 0.5 10 32 2019-04-05 14.1 14.6 0.5 14 32 2019-05-08 22.5 22.2 -0.3 24 32 2019-05-28 27.3 27.4 0.1 26 32 2019-06-20 26.2 26.1 -0.1 24 32 2019-06-28 27.6 27.1 -0.5 26 32 2019-07-08 28.9 28.5 -0.4 32 32 2019-07-24 23.8 24.8 1 28 32 2019-08-02 26.4 25.5 -0.9 27 32 2019-08-19 27.1 27.9 0.8 29 32 2019-09-12 28 27.6 -0.4 27 32 2019-09-26 25.1 24 -1.1 27 32 2019-10-25 16.1 16.1 0 23 32 2019-11-13 10.3 9.1 -1.2 16 32 2019-12-31 11.1 11.1 0 10 32 2020-01-31 7.8 7.9 0.1 10 32 2020-02-12 11.6 11.6 0 12 32 4 of 9 GB Perlmutter 11/23/2021 Ramseur WWTP Instream Monitoring NCOO26565 Temperature, water ('CJ Date Upstream Dnstream D-U Diff Effluent Standard 2020-03-09 11.4 11.5 0.1 14 32 2020-04-07 20.3 19.2 -1.1 22 32 2020-05-08 17.6 17.6 0 22 32 2020-05-20 17.5 17.6 0.1 22 32 2020-06-12 26.1 26.1 0 28 32 2020-06-26 26.7 26.8 0.1 30 32 2020-07-10 27.2 27.3 0.1 31 32 2020-07-28 30.1 30 -0.1 29 32 2020-08-04 27.4 27.3 -0.1 30 32 2020-08-21 23.8 23.8 0 29 32 2020-09-04 29.1 28.9 -0.2 29 32 2020-09-24 19.9 20.1 0.2 19 32 2020-10-14 20.2 20.3 0.1 32 2020-10-15 17.9 32 2020-11-02 15.6 15.7 0.1 32 2020-11-03 18.5 32 2020-12-15 10 32 2020-12-17 9.4 9.3 -0.1 32 N Avg SD Min Max 62 62 62 62 20.4 20.2 -0.2 20.6 7.7 7.6 0.5 7.7 2.7 2.2 -1.5 3.0 30.3 30.0 1.0 32.0 35.0 30.0 25.0 20.0 U 15.0 10.0 5.0 0.0 Temperature • Upstream • Effluent ♦ Dnstream -Standard ▪ ■. ri • f+' IF 0 I') �� /\ L' ■ • • erg • N■ Ore 0 5 of 9 GB Perlmutter 11/23/2021 Ramseur WWTP Instream Monitoring NC0026565 Temperature, water ('C) Date Upstream Dnstream D-U Diff Effluent Standard t-Test: Two -Sample Assuming Unequal Variances Upstream Dnstream Mean 20.38548 20.16774 Variance 59.48487 58.0196 Observations 62 62 Hypothesized Mean Difference 0 df 122 t Stat 0.158165 P(T<=t) one -tail 0.437294 t Critical one -tail 1.657439 P(T<=t) two -tail 0.874588 t Critical two -tail 1.9796 6 of 9 GB Perlmutter 11/23/2021 Ramseur WWTP Instream Monitoring NC0026565 Specific conductance (uS/cm) Date Upstream Dnstream 2015-01-14 238 2015-02-03 238 2015-03-04 185 2015-04-07 232 2015-05-01 162 2015-05-15 210 2015-06-15 263 2015-06-30 207 2015-07-15 191 2015-07-29 261 2015-08-07 313 2015-08-20 269 2015-09-04 403 2015-09-18 406 2015-10-14 289 2015-11-03 168 2015-12-08 184 2016-01-11 137 2016-02-05 120 2016-03-16 122 2016-04-01 110 2016-05-03 201 2016-05-24 161 2016-06-17 193 2016-06-30 258 2016-07-18 192 2016-07-29 282 2016-08-11 244 2016-08-29 279 2016-09-21 96 2016-09-30 86 2016-10-07 127 2016-11-11 263 2016-12-02 265 2017-01-27 169 2017-02-10 189 2017-03-31 193 2017-04-28 189 2017-05-05 182 2017-05-19 201 2017-06-06 192 2017-06-23 149 2017-07-14 193 2017-07-27 239 2017-08-07 245 2017-08-25 173 2017-09-15 186 96 133 133 143 181 66 119 123 118 129 114 92 133 132 144 102 136 156 167 138 258 195 156 116 156 166 144 127 167 122 126 112 132 120 98 124 127 159 169 182 214 211 242 234 192 136 168 7 of 9 GB Perlmutter 11/23/2021 Ramseur WWTP Instream Monitoring NC0026565 Specific conductance (uS/cm) Date Upstream Dnstream 2017-09-29 263 2017-10-31 237 2017-11-22 251 2017-12-08 255 2018-01-10 231 2018-02-19 201 2018-03-23 180 2018-04-20 174 2018-05-02 175 2018-05-31 147 2018-06-08 195 2018-06-19 238 2018-07-02 247 2018-07-18 238 2018-08-06 215 2018-08-31 205 2018-09-14 176 2018-09-28 174 2018-10-29 131 2018-11-09 126 2018-12-17 98 2019-01-18 120 2019-02-12 137 2019-03-01 114 2019-04-05 129 2019-05-08 119 2019-05-28 162 2019-06-20 125 2019-06-28 138 2019-07-08 134 2019-07-24 95 2019-08-02 147 2019-08-19 144 2019-09-12 200 2019-09-26 258 2019-10-25 135 2019-11-13 192 2019-12-31 140 2020-01-31 131 2020-02-12 102 2020-03-09 140 2020-04-07 128 2020-05-08 120 2020-05-20 92 2020-06-12 117 169 175 193 228 250 265 263 259 185 225 256 243 191 148 186 198 186 179 181 178 167 259 238 122 88 103 266 232 266 183 245 167 159 179 113 130 116 135 182 164 274 423 391 208 281 8 of 9 GB Perlmutter 11/23/2021 Ramseur WWTP Instream Monitoring NC0026565 Specific conductance (uS/cm) Date Upstream Dnstream 2020-06-26 122 256 2020-07-10 124 154 2020-07-28 119 212 2020-08-04 116 256 2020-08-21 65 202 2020-09-04 178 132 2020-09-24 133 224 2020-10-14 120 241 2020-11-02 129 213 2020-12-17 96 226 N Avg SD Min Max 102 102 181.7 179.1 64.2 61.1 65.0 66.0 406.0 423.0 450 400 350 300 250 i 200 150 100 50 0 Specific Conductance • Upstream • • Dnstream ♦ ♦ • -•1 ♦ 4 • ? ♦� A• •♦ u oil.. • 4♦ 0:11 Ep f he reit it & 11r ♦ M ' ♦ • ♦ ♦ ♦ • •�•• • ♦ • ti• '1, do 'L, o ti• -5 tiO�� ti'O'� tiON' tiON' tiON' ti01' ti01' t-Test: Two -Sample Assuming Unequal Variances Upstream Dnstream Mean 181.6961 179.1471 Variance 4117.303 3738.028 Observations 102 102 Hypothesized Mean Difference 0 df 202 t Stat 0.290463 P(T<=t) one -tail 0.38588 t Critical one -tail 1.652432 P(T<=t) two -tail 0.77176 t Critical two -tail 1.971777 9 of 9 GB Perlmutter 11/23/2021 MONITORING REPORT(MR) VIOLATIONS for: Report Date: 07/13/21 Page 1 01 1 Permit: NC0026565 MRs Betweei 7 - 2016 and 7 - 2021 Region: % Facility Name: % Param Nam( % County: % Major Minor: Violation Category:Limit Violation Subbasin:% Program Category: NPDES WW Violation Action: % PERMIT: NC0026565 FACILITY: Town of Ramseur - Ramseur WWTP COUNTY: Randolph REGION: Winston-Salem Limit Violation MONITORING OUTFACE REPORT LOCATION PARAMETER VIOLATION DATE FREQUENCY MEASURE UNIT OF LIMIT CALCULATED VALUE Over VIOLATION TYPE VIOLATION ACTION 10-2017 001 10-2017 001 10-2017 001 06-2018 001 12-2018 001 05-2021 001 06-2018 001 06-2018 001 07-2018 001 07-2018 001 07-2018 001 08-2018 001 08-2018 001 08-2018 001 Effluent Effluent Effluent Effluent Effluent Effluent Effluent Effluent Effluent Effluent Effluent Effluent Effluent Effluent BOD, 5-Day (20 Deg. C) - Concentration BOD, 5-Day (20 Deg. C) - Concentration BOD, 5-Day (20 Deg. C) - Concentration BOD, 5-Day (20 Deg. C) - Concentration Coliform, Fecal MF, MFC Broth, 44.5 C Nitrogen, Ammonia Total (as N) - Concentration Solids, Total Suspended - Concentration Solids, Total Suspended - Concentration Solids, Total Suspended - Concentration Solids, Total Suspended - Concentration Solids, Total Suspended - Concentration Solids, Total Suspended - Concentration Solids, Total Suspended - Concentration Solids, Total Suspended - Concentration 10/14/17 Weekly mg/I 10/21/17 Weekly mg/I 10/31/17 Weekly mg/I 06/30/18 Weekly mg/I 12/29/18 Weekly #/100m1 05/31/21 2 X month mg/1 06/30/18 Weekly mg/I 06/30/18 Weekly mg/1 07/07/18 Weekly mg/I 07/28/18 Weekly mg/1 07/31/18 Weekly mg/1 08/04/18 Weekly mg/I 08/11/18 Weekly mg/1 08/31/18 Weekly mg/I 45 71 57.8 Weekly Average Exceeded 45 85.5 90 Weekly Average Exceeded 30 31.74 5.8 Monthly Average Exceeded 45 47 4.4 Weekly Average Exceeded 400 420 5 Weekly Geometric Mean Exceeded 18 18.62 3.4 Monthly Average Exceeded 45 53.33 18.5 Weekly Average Exceeded 30 45 36.83 60 22.8 33.3 45 56.33 25.2 Monthly Average Exceeded Weekly Average Exceeded Weekly Average Exceeded 30 47.36 57.9 Monthly Average Exceeded 45 51 13.3 Weekly Average Exceeded 45 47 4.4 Weekly Average Exceeded 30 30.25 0.8 Monthly Average Exceeded Proceed to NOV Proceed to NOV Proceed to NOV Proceed to NOV Proceed to NOD None Proceed to NOV Proceed to NOV Proceed to NOV Proceed to NOV Proceed to NOV Proceed to NOV Proceed to NOV Proceed to NOV United States Environmental Protection Agency E PA Washington, D.C. 20460 Water Compliance Inspection Report Form Approved. OMB No. 2040-0057 Approval expires 8-31-98 Section A: National Data System Coding (i.e., PCS) Transaction Code NPDES yr/mo/day Inspection 1 IN I 2 LI 3 I NC0026565 111 121 19/01/10 117 Type 1810I IIIIIIIIIII Inspector Fac Type 19I S I 2011 21IIIIII IIIIIIIIIIIIIIIIII I IIIIII P6 Inspection Work Days Facility Self -Monitoring Evaluation Rating B1 QA Reserved 671 I 70I I 711 172 I N I 731 1 74 71 I I I I I I I I 180 Section B: Facility Data Name and Location of Facility Inspected (For Industrial Users discharging to POTW, also include POTW name and NPDES permit Number) Ramseur WWTP Roundleaf Rd Ramseur NC 27316 Entry Time/Date 02:15PM 19/01/10 Permit Effective Date 16/09/01 Exit Time/Date 03:45PM 19/01/10 Permit Expiration Date 21/04/30 Name(s) of Onsite Representative(s)/Titles(s)/Phone and Fax Number(s) /// Daniel Mark Grose/ORC/336-824-8891/ Terry Cheyenne Lewallen/ORC/336-824-3939/ Other Facility Data Name, Address of Responsible Official/Title/Phone and Fax Number Contacted Terry Cheyenne Lewallen,PO Box 725 Ramseur NC 27316//336-824-3939/ No Section C: Areas Evaluated During Inspection (Check only those areas evaluated) Permit Flow Measurement Operations & Maintenar Records/Reports Self -Monitoring Progran Sludge Handling DispoFacility Site Review Effluent/Receiving Wate Section D: Summary of Finding/Comments (Attach additional sheets of narrative and checklists as necessary) (See attachment summary) Name(s) and Signature(s) of Inspector(s) Agency/Office/Phone and Fax Numbers Date Jennifer F Graznak DWR/WSRO WQ/336-776-9800/ Signature of Management Q A Reviewer Agency/Office/Phone and Fax Numbers Date EPA Form 3560-3 (Rev 9-94) Previous editions are obsolete. Page# 1 31 NPDES yr/mo/day NC0026565 111 121 19/01/10 117 Inspection Type 18 [j (Cont.) 1 Section D: Summary of Finding/Comments (Attach additional sheets of narrative and checklists as necessary) The inspection found the facility to be satisfactory. Please note these pertinent findings from the inspection: (1) The facility had several violations of Total Suspended Solids during the summer of 2018 (June, July, August). During this time, the ORC stated that algae had grown in the finishing pond, which he believes caused the violations. He treated the algae in the pond with copper sulfate. (2) There is no sludge digester at the plant. Instead, solids from the secondary clarifier are lime -stabilized in the sludge mixing tank prior to disposal in the 10-acre sludge storage lagoon on site. This surface disposal method is covered under permit # WQ0010528 from the Division of Water Resources. Page# 2 Permit: NC0026565 Inspection Date: 01/10/2019 Owner - Facility: Ramseur WWTP Inspection Type: Compliance Evaluation Operations & Maintenance Yes No NA NE Is the plant generally clean with acceptable housekeeping? • ❑ ❑ ❑ Does the facility analyze process control parameters, for ex: MLSS, MCRT, Settleable II ❑ ❑ ❑ Solids, pH, DO, Sludge Judge, and other that are applicable? Comment: Permit Yes No NA NE (If the present permit expires in 6 months or less). Has the permittee submitted a new ❑ El ❑ application? Is the facility as described in the permit? • ❑ ❑ ❑ # Are there any special conditions for the permit? ❑ • ❑ ❑ Is access to the plant site restricted to the general public? • ❑ ❑ ❑ Is the inspector granted access to all areas for inspection? • ❑ ❑ ❑ Comment: The permit became effective on September 1, 2016 and will expire April 30, 2021. Record Keeping Yes No NA NE Are records kept and maintained as required by the permit? • ❑ ❑ ❑ Is all required information readily available, complete and current? • ❑ ❑ ❑ Are all records maintained for 3 years (lab. reg. required 5 years)? • ❑ ❑ ❑ Are analytical results consistent with data reported on DMRs? • ❑ ❑ ❑ Is the chain -of -custody complete? • ❑ ❑ ❑ Dates, times and location of sampling • Name of individual performing the sampling • Results of analysis and calibration • Dates of analysis • Name of person performing analyses • Transported COCs ■ Are DMRs complete: do they include all permit parameters? • ❑ ❑ ❑ Has the facility submitted its annual compliance report to users and DWQ? ❑ ❑ • ❑ (If the facility is = or > 5 MGD permitted flow) Do they operate 24/7 with a certified ❑ ❑ • ❑ operator on each shift? Is the ORC visitation log available and current? • ❑ ❑ ❑ Is the ORC certified at grade equal to or higher than the facility classification? • ❑ ❑ ❑ Is the backup operator certified at one grade less or greater than the facility • ❑ ❑ ❑ classification? Page# 3 Permit: NC0026565 Inspection Date: 01/10/2019 Owner - Facility: Ramseur WWTP Inspection Type: Compliance Evaluation Record Keeping Is a copy of the current NPDES permit available on site? Facility has copy of previous year's Annual Report on file for review? Yes No NA NE • ❑ ❑ ❑ ❑ ❑ • ❑ Comment: Mr. Lewallen measures dissolved oxygen, temperature, and pH under field parameter certification #5103. His thermometer was verified by Meritech on December 2, 2018. All other samples are analyzed by Environment One. Mr. Lewallen delivers samples to the Ramseur water treatment plant, and Environment One picks them up there. Effluent Pipe Is right of way to the outfall properly maintained? Are the receiving water free of foam other than trace amounts and other debris? If effluent (diffuser pipes are required) are they operating properly? Comment: Flow Measurement - Influent # Is flow meter used for reporting? Is flow meter calibrated annually? Is the flow meter operational? (If units are separated) Does the chart recorder match the flow meter? Yes No NA NE • ❑ ❑ ❑ • ❑ ❑ ❑ • ❑ • ❑ Yes No NA NE • ❑ ❑ ❑ • ❑ ❑ ❑ • ❑ ❑ ❑ • ❑ ❑ ❑ Comment: An ultrasonic meter is used to report influent flow on the DMRs. Carolina Technical Services calibrated the meter on April 9, 2018. Bar Screens Type of bar screen a.Manual b.Mechanical Are the bars adequately screening debris? Is the screen free of excessive debris? Is disposal of screening in compliance? Is the unit in good condition? Comment: Bar screenings are disposed of in the Town's dead animal pit on site. Yes No NA NE Aeration Basins Yes No NA NE Mode of operation Ext. Air Type of aeration system Diffused Is the basin free of dead spots? • ❑ ❑ ❑ Page# 4 Permit: NC0026565 Inspection Date: 01/10/2019 Owner - Facility: Ramseur WWTP Inspection Type: Compliance Evaluation Aeration Basins Yes No NA NE Are surface aerators and mixers operational? ❑ ❑ • ❑ Are the diffusers operational? • ❑ ❑ ❑ Is the foam the proper color for the treatment process? ■ ❑ ❑ ❑ Does the foam cover less than 25% of the basin's surface? • ❑ ❑ ❑ Is the DO level acceptable? ❑ ❑ ❑ • Is the DO level acceptable?(1.0 to 3.0 mg/I) El El El • Comment: The aeration basin appeared black in color, which the ORC said is due to a local dye house that discharges to the plant. Secondary Clarifier Is the clarifier free of black and odorous wastewater? Is the site free of excessive buildup of solids in center well of circular clarifier? Are weirs level? Is the site free of weir blockage? Is the site free of evidence of short-circuiting? Is scum removal adequate? Is the site free of excessive floating sludge? Is the drive unit operational? Is the return rate acceptable (low turbulence)? Is the overflow clear of excessive solids/pin floc? Is the sludge blanket level acceptable? (Approximately'/4 of the sidewall depth) Comment: Influent Sampling # Is composite sampling flow proportional? Is sample collected above side streams? Is proper volume collected? Is the tubing clean? # Is proper temperature set for sample storage (kept at less than or equal to 6.0 degrees Celsius)? Is sampling performed according to the permit? Yes No NA NE • ❑ ❑ ❑ • ❑ ❑ ❑ • ❑ ❑ ❑ • ❑ ❑ ❑ • ❑ ❑ ❑ Yes No NA NE ❑ • ❑ ❑ • ❑ ❑ ❑ Comment: Effluent Sampling Yes No NA NE Page# 5 Permit: NC0026565 Inspection Date: 01/10/2019 Owner - Facility: Ramseur WWTP Inspection Type: Compliance Evaluation Effluent Sampling Yes No NA NE Is composite sampling flow proportional? ❑ • ❑ ❑ Is sample collected below all treatment units? • ❑ ❑ ❑ Is proper volume collected? ■ ❑ ❑ ❑ Is the tubing clean? • ❑ ❑ ❑ # Is proper temperature set for sample storage (kept at less than or equal to 6.0 • ❑ ❑ ❑ degrees Celsius)? Is the facility sampling performed as required by the permit (frequency, sampling type • El El El representative)? Comment: Composite sampling is not flow proportional due to the holding time of the 5-acre finishing lagoon, which equalizes effluent flow. Time composite sampling is used instead. Lagoons Yes No NA NE Type of lagoons? # Number of lagoons in operation at time of visit? 1 Are lagoons operated in? # Is a re -circulation line present? ❑ ❑ • ❑ Is lagoon free of excessive floating materials? ■ ❑ ❑ ❑ # Are baffles between ponds or effluent baffles adjustable? El El • El Are dike slopes clear of woody vegetation? • El El El Are weeds controlled around the edge of the lagoon? • ❑ ❑ ❑ Are dikes free of seepage? ■ El El El Are dikes free of erosion? • El El El Are dikes free of burrowing animals? • El El El # Has the sludge blanket in the lagoon (s) been measured periodically in multiple ❑ ❑ ❑ • locations? # If excessive algae is present, has barley straw been used to help control the growth? El El El Is the lagoon surface free of weeds? • El El El Is the lagoon free of short circuiting? • El El El Comment: The 5-acre finishing pond the regulates effluent flow for the plant. Disinfection -Gas Are cylinders secured adequately? Are cylinders protected from direct sunlight? Is there adequate reserve supply of disinfectant? Yes No NA NE Page# 6 Permit: NC0026565 Inspection Date: 01/10/2019 Owner - Facility: Ramseur WWTP Inspection Type: Compliance Evaluation Disinfection -Gas Yes No NA NE Is the level of chlorine residual acceptable? ❑ ❑ ❑ • Is the contact chamber free of growth, or sludge buildup? • ❑ ❑ ❑ Is there chlorine residual prior to de -chlorination? ❑ ❑ El • Does the Stationary Source have more than 2500 Ibs of Chlorine (CAS No. ❑ ❑ ❑ • 7782-50-5)? If yes, then is there a Risk Management Plan on site? ❑ ❑ ❑ • If yes, then what is the EPA twelve digit ID Number? (1000- ) If yes, then when was the RMP last updated? Comment: Chlorine gas is added in the manhole prior to the chlorine contact chamber. The ORC lifted the manhole during the inspection so the inspectors could see the line. De -chlorination Yes No NA NE Type of system ? Gas Is the feed ratio proportional to chlorine amount (1 to 1)? ❑ ❑ ❑ • Is storage appropriate for cylinders? • El ❑ ❑ # Is de -chlorination substance stored away from chlorine containers? • ❑ ❑ ❑ Are the tablets the proper size and type? El El • El Comment: Sulfur dioxide gas is added at the end of the chlorine contact chamber right before discharge. Are tablet de -chlorinators operational? El ❑ • ❑ Number of tubes in use? Comment: Upstream / Downstream Sampling Yes No NA NE Is the facility sampling performed as required by the permit (frequency, sampling type, El El El and sampling location)? Comment: Page# 7 NH3/TRC WLA Calculations Facility: Ramseur WWTP PermitNo. NC0026565 Prepared By: Gary Perlmutter Enter Design Flow (MGD): 0.48 Enter s7Q10 (cfs): 11 Enter w7Q10 (cfs): 23 Total Residual Chlorine (TRC) Daily Maximum Limit (ug/I) s7Q10 (CFS) DESIGN FLOW (MGD) DESIGN FLOW (CFS) STREAM STD (UG/L) Upstream Bkgd (ug/I) IWC (%) Allowable Conc. (ug/I) Fecal Coliform Monthly Average Limit: (If DF >331; Monitor) (If DF<331; Limit) Dilution Factor (DF) 11 0.48 0.744 17.0 0 6.34 268 Ammonia (Summer) Monthly Average Limit (mg NH3-N/I) s7Q10 (CFS) DESIGN FLOW (MGD) DESIGN FLOW (CFS) STREAM STD (MG/L) Upstream Bkgd (mg/I) IWC (%) Allowable Conc. (mg/I) Ammonia (Winter) Monthly Average Limit (mg NH3-N/I) w7Q10 (CFS) 200/100m1 DESIGN FLOW (MGD) DESIGN FLOW (CFS) STREAM STD (MG/L) 15.78 Upstream Bkgd (mg/I) IWC (%) Allowable Conc. (mg/I) Total Residual Chlorine 1. Cap Daily Max limit at 28 ug/I to protect for acute toxicity Ammonia (as NH3-N) 1. If Allowable Conc > 35 mg/I, Monitor Only 2. Monthly Avg limit x 3 = Weekly Avg limit (Municipals) 3. Monthly Avg limit x 5 = Daily Max limit (Non-Munis) If the allowable ammonia concentration is > 35 mg/L, no limit shall be imposed 11 0.48 0.744 1.0 0.22 6.34 12.5 23 0.48 0.744 1.8 0.22 3.13 50.6 Fecal Coliform 1. Monthly Avg limit x 2 = 400/100 ml = Weekly Avg limit (Municipals) = Daily Max limit (Non -Muni) Whole Effluent Toxicity Testing and Self Monitoring Summary 0 7I V 0 Mar Jun Sep Dec 0 cc •O 00 0) 00 NC0026565/001 Ramseur WWTP Cf 7Q10: 11.0 NonComp: Single chr lim: 6.0% n m m o 0 0 0 0 0 1) O v O Jan Apr Jul Oct Cf 0 N � O lac 0) CC NC0087866 Randleman Lake WTP-Piedmont Triad Chr Monit: 90% O N 0 -I C .00 m LL a N n 0) U Oa i a H n C0 m 0 0 000 Ott 0 0 O 0 O Jan Apr Jul Oct NC0025445/001 Randleman WWTP NonComp: Single chr lim: 35% 0 0 0 i i H z C L h n000 m o 000000 CO Ott U O I V 0 Jan Apr Jul Oct 0 LL O Ea 0) 00 NC0025577/001 Red Springs WWTP Ol LL 7Q10: 0.07 NonComp: Single chr lim: 90% N O C .00 CO0 z rit to co m o ssss U O VI O Mar Jun Sep Dec O 0 Y 0 n O 00 0) 00 NC0083291/001 Reddies River WTP V 0 d r- Ac P/F Monit: 90% Ft V sl M C 00 000 LL C N N a L LL 0 x x x 2 1 z ao m o 0s0s Page 91 of 120 Legend: P= Fathead minnow (Pimohales oromelasl. H=No Flow (facility is active). s = Solit test between Certified Labs Freshwater RPA - 95% Probability/95% Confidence Using Metal Translators MAXIMUM DATA POINTS = 58 REQUIRED DATA ENTRY Table 1. Project Information Facility Name WWTP/WTP Class NPDES Permit Outfall Flow, Qw (MGD) Receiving Stream HUC Number Stream Class ❑CHECK IF HQW OR ORW WQS Ramseur WWTP Grade II NC0026565 001 0.480 Deep River 03030003 C ['Apply WS Hardness WQC 7Q10s (cfs) 7Q1Ow (cfs) 30Q2 (cfs) QA (cfs) 1Q10s (cfs) 11.00 23.00 350.00 I 9.12 - Effluent Hardness Upstream Hardness Combined Hardness Chronic Combined Hardness Acute 56.47 mg/L (Avg) 36 mg/L (Avg) 37.3 mg/L 37.54 mg/L Effluent data from submitted DMRs; Hardness data provided by ORC upon request Data Source(s) ❑CHECK TO APPLY MODEL Table 2. Parameters of Concern Par01 Par02 Par03 Par04 Par05 Par06 Par07 Par08 Par09 Par10 Par11 Par12 Par13 Par14 Par15 Par16 Par17 Par18 Par19 Par20 Par21 Par22 Par23 Par24 Name WQS Type Chronic Modifier Acute PQL Units Arsenic Aquactic Life C 150 FW 340 ug/L Arsenic Human Health Water Supply C 10 HH/WS N/A ug/L Beryllium Aquatic Life NC 6.5 FW 65 ug/L Cadmium Aquatic Life NC 0.7982 FW 4.6202 ug/L Chlorides Aquatic Life NC 230 FW Chlorinated Phenolic Compounds Water Supply NC 1 A ug/L 4 Total Phenolic Compounds Aquatic Life NC 300 A ug/L Chromium III Aquatic Life NC 163.3741 FW 1262.7686 ug/L Chromium VI Aquatic Life NC 11 FW 16 pg/L Chromium, Total Aquatic Life NC N/A FW N/A pg/L Copper Aquatic Life NC 11.0921 FW 15.3611 ug/L Cyanide Aquatic Life NC 5 FW 22 10 ug/L Fluoride Aquatic Life NC 1,800 FW ug/L Lead Aquatic Life NC 4.6076 FW 119.1148 ug/L Mercury Aquatic Life NC 12 FW 0.5 ng/L Molybdenum Human Health NC 2000 HH ug/L Nickel Aquatic Life NC 52.2259 FW 472.8457 pg/L Nickel Water Supply NC 25.0000 WS N/A pg/L Selenium Aquatic Life NC 5 FW 56 ug/L Silver Aquatic Life NC 0.06 FW 0.5965 ug/L Zinc Aquatic Life NC 177.8666 FW 177.4136 ug/L 26565 RPA 2021, input 11/23/2021 REASONABLE POTENTIAL ANALYSIS H1 Effluent Hardness Date Data BDL=1/2DL Results 1 6/13/2017 52 52 Std Dev. 2 9/19/2017 44 44 Mean 3 12/12/2017 60 60 C.V. 4 3/13/2018 44 44 n 5 6/12/2018 52 52 10th Per value 6 9/25/2018 113 113 Average Value 7 12/18/2018 40 40 Max. Value 8 3/12/2019 41 41 9 6/11/2019 100 100 10 9/17/2019 57 57 11 12/10/2019 54 54 12 3/10/2020 46 46 13 6/9/2020 42 42 14 9/22/2020 53 53 15 12/15/2020 51 51 16 3/9/2021 46 46 17 6/15/2021 65 65 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 Use "PASTE SPECIAL Values" then "COPY" . Maximum data points = 58 H2 Upstream Hardness 20.1777 56.4706 0.3573 17 41.60 mg/L 56.47 mg/L 113.00 mg/L Date Data BDL=1/2DL Results 1 3/10/2020 36 36 Std Dev. 2 6/9/2020 36 36 Mean 3 9/22/2020 38 38 C.V. (default) 4 12/15/2020 34 34 n 5 3/9/2021 40 40 10th Per value 6 6/15/2021 32 32 Average Value 7 Max. Value 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 Use "PASTE SPECIAL Values" then "COPY" . Maximum data points = 58 2.8284 36.0000 0.6000 6 33.00 mg/L 36.00 mg/L 40.00 mg/L -3- 26565 RPA 2021, data 11/23/2021 REASONABLE POTENTIAL ANALYSIS Par01 & Par02 Arsenic Date Data BDL=1/2DL Results 1 6/13/2017 < 5 2.5 Std Dev. 2 9/19/2017 < 5 2.5 Mean 3 12/12/2017 < 5 2.5 C.V. (default) 4 3/13/2018 < 5 2.5 n 5 6/13/2017 < 5 2.5 6 9/19/2017 < 5 2.5 Mult Factor = 7 12/12/2017 < 5 2.5 Max. Value 8 3/13/2018 < 5 2.5 Max. Pred Cw 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 Use "PASTE SPECIAL Values" then "COPY" . Maximum data points = 58 Par03 Beryllium 0.0000 2.5000 0.6000 8 1.90 2.5 ug/L 4.8 ug/L Date Data BDL=1/2DL Results 1 Std Dev. 2 Mean 3 C.V. 4 n 5 6 Mult Factor = 7 Max. Value 8 Max. Pred Cw 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 Use "PASTE SPECIAL Values" then "COPY" . Maximum data points = 58 NO DATA NO DATA NO DATA 0 N/A N/A ug/L N/A ug/L -4- 26565 RPA 2021, data 11/23/2021 REASONABLE POTENTIAL ANALYSIS Par04 Cadmium Date Data BDL=1/2DL Results 1 6/13/2017 < 1 0.5 Std Dev. 2 9/19/2017 < 1 0.5 Mean 3 12/12/2017 < 1 0.5 C.V. (default) 4 3/13/2018 < 1 0.5 n 5 6/13/2017 < 1 0.5 6 9/19/2017 < 1 0.5 Mult Factor = 7 12/12/2017 < 1 0.5 Max. Value 8 3/13/2018 < 1 0.5 Max. Pred Cw 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 Use "PASTE SPECIAL Values" then "COPY" . Maximum data points = 58 Par05 Chlorides 0.0000 0.5000 0.6000 8 1.90 0.500 ug/L 0.950 ug/L Date Data BDL=1/2DL Results Std Dev. Mean C.V. n Mult Factor = Max. Value Max. Pred Cw Use "PASTE SPECIAL - Values" then "COPY" . Maximum data points = 58 NO DATA NO DATA NO DATA 0 N/A N/A mg/L N/A mg/L 26565 RPA 2021, data - 5 - 11/23/2021 REASONABLE POTENTIAL ANALYSIS Par06 Chlorinated Phenolic Compounds Date Data BDL=1/2DL Results 1 Std Dev. 2 Mean 3 C.V. 4 n 5 6 Mult Factor = 7 Max. Value 8 Max. Pred Cw 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 Use "PASTE SPECIAL Values" then "COPY" . Maximum data points = 58 Par07 Total Phenolic Compounds NO DATA NO DATA NO DATA 0 N/A N/A ug/L N/A ug/L Date Data BDL=1/2DL Results 1 Std Dev. 2 Mean 3 C.V. 4 n 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 Use "PASTE SPECIAL Values" then "COPY" . Maximum data points = 58 NO DATA NO DATA NO DATA 0 Mult Factor = N/A Max. Value N/A ug/L Max. Pred Cw N/A ug/L 26565 RPA 2021, data - 6 - 11/23/2021 REASONABLE POTENTIAL ANALYSIS Par08 Chromium III Date Data BDL=1/2DL Results 1 Std Dev. 2 Mean 3 C.V. 4 n 5 6 Mult Factor = 7 Max. Value 8 Max. Pred Cw 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 Use "PASTE SPECIAL Values" then "COPY" . Maximum data points = 58 Par09 Chromium VI NO DATA NO DATA NO DATA 0 N/A N/A pg/L N/A pg/L Date Data BDL=1/2DL Results 1 Std Dev. 2 Mean 3 C.V. 4 n 5 6 Mult Factor = 7 Max. Value 8 Max. Pred Cw 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 Use "PASTE SPECIAL Values" then "COPY" . Maximum data points = 58 NO DATA NO DATA NO DATA 0 N/A N/A pg/L N/A pg/L -7- 26565 RPA 2021, data 11/23/2021 REASONABLE POTENTIAL ANALYSIS Par10 Chromium, Total Date Data BDL=1/2DL Results 1 6/13/2017 < 5 2.5 Std Dev. 2 9/19/2017 < 5 2.5 Mean 3 12/12/2017 < 5 2.5 C.V. (default) 4 3/13/2018 < 5 2.5 n 5 6/13/2017 < 5 2.5 6 9/19/2017 < 5 2.5 Mult Factor = 7 12/12/2017 < 5 2.5 Max. Value 8 3/13/2018 < 5 2.5 Max. Pred Cw 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 Use "PASTE SPECIAL Values" then "COPY" . Maximum data points = 58 Pall Copper 0.0000 2.5000 0.6000 8 1.90 2.5 pg/L 4.8 pg/L Date Data BDL=1/2DL Results 1 6/13/2017 5 5 Std Dev. 2 9/19/2017 4 4 Mean 3 12/12/2017 5 5 C.V. 4 3/13/2018 5 5 n 5 6/12/2018 10 10 6 9/25/2018 3792 3792 Mult Factor = 7 12/18/2018 18 18 Max. Value 8 3/12/2019 12 12 Max. Pred Cw 9 6/11/2019 113 113 10 9/17/2019 609 609 11 12/10/2019 19 19 12 3/10/2020 131 131 13 6/9/2020 46 46 14 9/22/2020 17 17 15 12/15/2020 18 18 16 3/9/2021 43 43 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 Use "PASTE SPECIAL values" then "COPY" . Maximum data points = 58 942.2432 302.9375 3.1104 16 2.91 3792.00 ug/L 11034.72 ug/L 26565 RPA 2021, data - 8 - 11/23/2021 REASONABLE POTENTIAL ANALYSIS Par12 Cyanide Date Data BDL=1/2DL Results 1 6/13/2017 < 5 5 Std Dev. 2 9/19/2017 < 5 5 Mean 3 12/12/2017 < 5 5 C.V. (default) 4 3/13/2018 < 5 5 n 5 6/13/2017 < 5 5 6 9/19/2017 < 5 5 Mult Factor = 7 12/12/2017 < 5 5 Max. Value 8 3/13/2018 < 5 5 Max. Pred Cw 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 Use "PASTE SPECIAL Values" then "COPY" . Maximum data points = 58 Par13 Fluoride 0.0000 5.00 0.6000 8 1.90 5.0 ug/L 9.5 ug/L Date Data BDL=1/2DL Results 1 Std Dev. 2 Mean 3 C.V. 4 n 5 6 Mult Factor = 7 Max. Value 8 Max. Pred Cw 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 Use "PASTE SPECIAL values" then "COPY" . Maximum data points = 58 NO DATA NO DATA NO DATA 0 N/A N/A ug/L N/A ug/L 26565 RPA 2021, data - 9 - 11/23/2021 REASONABLE POTENTIAL ANALYSIS Par14 Lead Date 6/13/2017 < 5 9/19/2017 < 5 12/12/2017 < 5 6/13/2017 < 5 9/19/2017 < 5 12/12/2017 < 5 3/13/2018 < 5 BDL=1/2DL Results 2.5 Std Dev. 2.5 Mean 2.5 C.V. (default) 2.5 n 2.5 2.5 Mult Factor = 2.5 Max. Value Max. Pred Cw Use "PASTE SPECIAL Values" then "COPY" . Maximum data points = 58 Par15 Mercury 0.0000 2.5000 0.6000 7 2.01 2.500 ug/L 5.025 ug/L Date Data BDL=1/2DL Results 1 Std Dev. 2 Mean 3 C.V. 4 n 5 6 Mult Factor = 7 Max. Value 8 Max. Pred Cw 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 Use "PASTE SPECIAL values" then "COPY" . Maximum data points = 58 NO DATA NO DATA NO DATA 0 N/A N/A ng/L N/A ng/L -10- 26565 RPA 2021, data 11/23/2021 REASONABLE POTENTIAL ANALYSIS Par16 Molybdenum Date Data BDL=1/2DL Results 1 Std Dev. 2 Mean 3 C.V. 4 n 5 6 Mult Factor = 7 Max. Value 8 Max. Pred Cw 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 Use "PASTE SPECIAL Values" then "COPY" . Maximum data points = 58 Par17 & Par18 Nickel NO DATA NO DATA NO DATA 0 N/A N/A ug/L N/A ug/L Date Data BDL=1/2DL Results 1 6/13/2017 < 10 5 Std Dev. 2 9/19/2017 < 10 5 Mean 3 12/12/2017 < 10 5 C.V. (default) 4 3/13/2018 < 10 5 n 5 6/13/2017 11 11 6 9/19/2017 < 10 5 Mult Factor = 7 12/12/2017 < 10 5 Max. Value 8 3/13/2018 < 10 5 Max. Pred Cw 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 Use "PASTE SPECIAL Values" then "COPY" . Maximum data points = 58 2.1213 5.7500 0.6000 8 1.90 11.0 pg/L 20.9 pg/L -11- 26565 RPA 2021, data 11/23/2021 REASONABLE POTENTIAL ANALYSIS Par19 Selenium Date Data BDL=1/2DL Results 1 Std Dev. 2 Mean 3 C.V. 4 n 5 6 Mult Factor = 7 Max. Value 8 Max. Pred Cw 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 Use "PASTE SPECIAL Values" then "COPY" . Maximum data points = 58 Par20 Silver NO DATA NO DATA NO DATA 0 N/A N/A ug/L N/A ug/L Date Data BDL=1/2DL Results 1 6/13/2017 < 1 0.5 Std Dev. 2 9/19/2017 < 1 0.5 Mean 3 12/12/2017 < 1 0.5 C.V. (default) 4 3/13/2018 < 1 0.5 n 5 6/13/2017 < 1 0.5 6 9/19/2017 < 1 0.5 Mult Factor = 7 12/12/2017 < 1 0.5 Max. Value 8 3/13/2018 < 1 0.5 Max. Pred Cw 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 Use "PASTE SPECIAL values" then "COPY" . Maximum data points = 58 0.0000 0.5000 0.6000 8 1.90 0.500 ug/L 0.950 ug/L -12- 26565 RPA 2021, data 11/23/2021 REASONABLE POTENTIAL ANALYSIS Par21 Zinc Date Data BDL=1/2DL Results 1 6/13/2017 26 26 Std Dev. 2 9/19/2017 36 36 Mean 3 12/12/2017 42 42 C.V. (default) 4 3/13/2018 36 36 n 5 6/13/2017 182 182 6 9/19/2017 140 140 Mult Factor = 7 12/12/2017 123 123 Max. Value 8 3/13/2018 65 65 Max. Pred Cw 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 Use "PASTE SPECIAL Values" then "COPY" . Maximum data points = 58 Par22 0 58.9158 81.2500 0.6000 8 1.90 182.0 ug/L 345.8 ug/L Date Data BDL=1/2DL Results Std Dev. Mean C.V. n Mult Factor = Max. Value Max. Pred Cw Use "PASTE SPECIAL Values" then "COPY" . Maximum data points = 58 NO DATA NO DATA NO DATA 0 N/A N/A N/A -13- 26565 RPA 2021, data 11/23/2021 Ramseur WWTP - Outfall 001 NC0026565 Freshwater RPA - 95% Probability/95% Confidence Using Metal Translators Qw = 0.48 MGD MAXIMUM DATA POINTS = 58 Qw (MGD) = 0.4800 1Q10S (cfs) = 9.12 7Q1OS (cfs) = 11.00 7Q1OW (cfs) = 23.00 30Q2 (cfs) = NO 30Q2 DATA Avg. Stream Flow, QA (cfs) = 350.00 Receiving Stream: Deep River HUC 03030003 WWTP/WTP Class: Grade II IWC% @ 1Q10S = 7.542579075 IWC% @ 7Q1OS = 6.335149864 IWC% @ 7Q1OW = 3.133423181 IWC% @ 30Q2 = N/A IW%C @ QA = 0.212120521 Stream Class: C COMBINED HARDNESS (mg/L) Acute = 37.54 mg/L Chronic = 37.3 mg/L PARAMETER TYPE NC STANDARDS OR EPA CRITERIA _1 a REASONABLE POTENTIAL RESULTS RECOMMENDED ACTION Chronic Applied Acute Standard 11 # Det. Max Pred Cw Allowable Cw Arsenic Arsenic C C 150 FW(7Q10s) 340 10 HH/WS(Qavg) ug L ug/L 8 0 Note: n < 9 Limited data set 4.8 C.V. (default) NO DETECTS Acute (FW): 4,507.7 _ _ Chronic (FW): 2,367.7 Max MDL = 5 _ _ _ Chronic (HH): 4,714.3 Max MDL = 5 _ _ _ _ _ no detects _ _ _ _ _ Beryllium NC 6.5 FW(7Q10s) 65 ug/L 0 0 N/A Acute: 861.77 ___ _ _______ _ ___ Chronic: 102.60 Cadmium NC 0.7982 FW(7Q10s) 4.6202 ug/L 8 0 Note: n < 9 Limited data set 0.950 C.V. (default) NO DETECTS Acute: 61.255 _ _ _ _ _ _ _ _ Chronic: 12.600 Max MDL = 1 _ _ _ _ _ _ _ _ _ _ _ _ _ _ No detects Chlorides NC 230 FW(7Q10s) mg/L 0 0 N/A Acute: NO WQS ___ _ _ ---- _ _ ----------------------------- Chronic: 3,630.5 Chlorinated Phenolic Compounds NC 1 A(30Q2) ug/L 0 0 N/A Acute: NO WQS -- _ _ _ _ _ -----IWC?------------------------------ Chronic: Total Phenolic Compounds NC 300 A(30Q2) ug/L 0 0 N A Acute: NO WQS — — — — — — — — Chronic: IWC? — — — — — — — — — — — — — — Chromium III NC 163.3741 FW(7Q10s) 1262.7686 µg/L 0 0 N A Acute: 16,741.9 -- _ _ _ ---- _ _ ----------------------------- Chronic: 2,578.9 Chromium VI NC 11 FW(7Q10s) 16 µg L 0 0 N/A Acute: 212.1 -- _ _ _ ----- _ _ ------------------------------ Chronic: 173.6 Chromium, Total NC µg'L 8 0 Note: n < 9 Limited data set 4.8 C.V. (default) NO DETECTS Max reported value = 2.5 Max MDL = 5 no detects Page 14 of 15 26565 RPA 2021, rpa 11/23/2021 Ramseur WWTP NC0026565 Freshwater RPA - 95% Probability/95% Confidence Using Metal Translators Outfall 001 Qw = 0.48 MGD Copper NC 11.0921 FW(7Q10s) 15.3611 ug/L 16 16 11,034.72 Acute: 203.66 ___ _ _______ _ ___ Chronic: 175.09 2 value(s) > Allowable Cw _ _ _ _ _ _ _ _ _ _ ___ RP shown - apply Monthly Monitoring with Limit Cyanide NC 5 FW(7Q10s) 22 10 ug/L 8 0 Note: n < 9 Limited data set 9.5 C.V. (default) NO DETECTS Acute: 291.7 _ _ _ _ _ _ _ _ _ Chronic: 78.9 Max MDL = 10 _ _ _ _ _ _ _ _ _ _ _ _ _ _ Fluoride NC 1800 FW(7Q10s) ug/L 0 0 N/A Acute: NO WQS — _ _ _ Chronic:----28,412.9_ ---------------------------- Lead NC 4.6076 FW(7Q10s) 119.1148 ug/L 7 0 Note: n < 9 Limited data set 5.025 C.V. (default) NO DETECTS Acute: 1,579.232 _ _ _ _ _ _ _ _ _ Chronic: 72.731 Max MDL = 5 _ _ _ _ _ _ _ _ _ _ _ _ _ _ no detects Mercury NC 12 FW(7Q10s) 0.5 ng/L 0 0 N/A Acute: NO WQS — _ _ Chronic:----- 189.4 — — — — — — — — — — — — Molybdenum NC 2000 HH(7Q10s) ug/L 0 0 N/A Acute: NO WQS -- Chronic:----31,569.9 ------ Nickel Nickel NC NC 52.2259 FW(7Q10s) 472.8457 25.0000 WS(7Q10s) µg/L µg/L 8 1 Note: n < 9 Limited data set 20.9 C.V. (default) Acute (FW): 6,269.0 _ _ _ _ _ _ _ Chronic (FW): 824.4 No_value > Allowab_le_Cw Chronic (WS): 394.6 No value > Allowable Cw _ _ _ _ _ _ _ _ _ _ _ _ No RP, Predicted Max < 50% of Allowable Cw - No Monitoring required Selenium NC 5 FW(7Q10s) 56 ug/L 0 0 N/A Acute: 742.5 ------------------------- Silver NC 0.06 FW(7Q10s) 0.5965 ug/L 8 0 Note: n < 9 Limited data set 0.950 C.V. (default) NO DETECTS Acute: 7.909 _ _ _ _ _ _ _ _ _ Chronic: 0.947 Max MDL = 1 _ _ _ _ _ _ _ _ _ _ _ _ _ _ no detects Zinc NC 177.8666 FW(7Q10s) 177.4136 ug/L 8 8 Note: n < 9 Limited data set 345.8 C.V. (default) Acute: 2,352.2 _ _ _ _ _ _ _ _ _ _ _ _ _ Chronic: 2,807.6 No value > Allowable Cw _ _ _ _ _ _ _ _ _ _ _ _ _ _ No RP, Predicted Max < 50% of Allowable Cw - No Monitoring required 0 0 N/A Acute: 0 0 N/A Acute: -- Chronic: ------------ Page 15 of 15 26565 RPA 2021, rpa 11/23/2021 FACILITY: Ramseur WWTP Outfall 001 NPDES PERMIT: NC0026565 Dissolved to Total Metal Calculator In accordance with Federal Regulations, permit limitations must be written as Total Metals per 40 CFR 122.45(c) Receiving Stream summer 7Q10 (CFS) Receiung Stream summer 7Q10 (MGD) Rec. Stream 1Q10 [MGD] NPDES Flow Limit [MGD] Total Suspended Solids -Fixed Value- (mg/L) Combined Hardness chronic (mg/L) Combined Hardness Acute (mg/L) Instream Wastewater Concentration (Chronic) Instream Wastewater Concentration (Acute) Hardness Average (mg/L) EffluentUpstream Hardness Average (mg/L) 11.0000 7.0968 5.8839 0.4800 10 37.297 37.544 6.3351 7.5426 36 56.4706 PARAMETER Dissolved Metals Criteria after applying hardness equation Chronic Acute [ug/I] [ug/I] US EPA Translators- using Default Partition Coefficients (streams) Total Metal Criteria Total Metal = Dissolved Metal + Translator Chronic Acute Upstream Hard Avg (mg/L) = 36 EFF Hard Avg (mg/L) = 56.4706 [ug/I] [ug/I] Cadmium (d) Cd -Trout streams Chromium III (d)(h) Chromium VI (d) 0.20 0.20 33 11 1.17 0.73 255 16 0.252 0.252 0.202 1.000 0.80 0.80 163.37 11.00 4.62 2.87 1262.77 16.00 Chromium, Total (t) Copper (d)(h) Lead (d)(h) 3.9 0.85 5.3 22 0.348 0.184 N/A 11.09 4.61 N/A 15.36 119.11 Nickel (d)(h) 23 204 0.432 Ni - WS streams (t) Silver (d)(h,acute) 0.06 0.60 1.000 52.23 472.85 N/A 0.06 0.60 Zinc (d)(h) 51 51 0.288 177.87 177.41 Beryllium 1.000 6.5 65 Arsenic (d) 1.000 150 340 COMMENTS (identify parameters to PERCS Branch to maintain in facility's LTMP/STMP): (d) = dissolved metal standard. See 15A NCAC 02B .0211 for more information. (h) = hardness -dependent dissolved metal standard. See 15A NCAC 02B .0211 for more information. (t) = based upon measurement of total recoveable metal. See 15A NCAC 02B .0211 for more information. The Human Health standard for Nickel in Water Supply Streams is 25 mg/L which is Total Recoverable metal standard. The Human Health standard for Arsenic is 10 µg/L which is Total Recoverable metal standard. Permit No. NC0026565 NPDES Implementation of Instream Dissolved Metals Standards - Freshwater Standards The NC 2007-2015 Water Quality Standard (WQS) Triennial Review was approved by the NC Environmental Management Commission (EMC) on November 13, 2014. The US EPA subsequently approved the WQS revisions on April 6, 2016, with some exceptions. Therefore, metal limits in draft permits out to public notice after April 6, 2016 must be calculated to protect the new standards - as approved. Table 1. NC Dissolved Metals Water Quality Standards/Aquatic Life Protection Parameter Acute FW, µg/1 (Dissolved) Chronic FW, µg/1 (Dissolved) Acute SW, µg/1 (Dissolved) Chronic SW, µg/1 (Dissolved) Arsenic 340 150 69 36 Beryllium 65 6.5 --- --- Cadmium Calculation Calculation 40 8.8 Chromium III Calculation Calculation --- --- Chromium VI 16 11 1100 50 Copper Calculation Calculation 4.8 3.1 Lead Calculation Calculation 210 8.1 Nickel Calculation Calculation 74 8.2 Silver Calculation 0.06 1.9 0.1 Zinc Calculation Calculation 90 81 Table 1 Notes: 1. FW= Freshwater, SW= Saltwater 2. Calculation = Hardness dependent standard 3. Only the aquatic life standards listed above are expressed in dissolved form. Aquatic life standards for Mercury and selenium are still expressed as Total Recoverable Metals due to bioaccumulative concerns (as are all human health standards for all metals). It is still necessary to evaluate total recoverable aquatic life and human health standards listed in 15A NCAC 2B.0200 (e.g., arsenic at 10 1.1g/1 for human health protection; cyanide at 5 µg/L and fluoride at 1.8 mg/L for aquatic life protection). Table 2. Dissolved Freshwater Standards for Hardness -Dependent Metals The Water Effects Ratio (WER) is equal to one unless determined otherwise under 15A NCAC 02B .0211 Subparagraph (11)(d) Metal NC Dissolved Standard, µg/I Cadmium, Acute WER*{1.136672-[ln hardness](0.041838)} • e^{0.9151 [In hardness]-3.1485} Cadmium, Acute Trout waters WER*{1.136672-[ln hardness](0.041838)} • e^{0.9151[ln hardness]-3.6236} Cadmium, Chronic WER*{1.101672-[ln hardness](0.041838)} • e^{0.7998[ln hardness]-4.4451} Chromium III, Acute WER*0.316 • e^{0.8190[ln hardness]+3.7256} Chromium III, Chronic WER*0.860 • e^{0.8190[ln hardness]+0.6848} Copper, Acute WER*0.960 • e^{0.9422[In hardness]-1.700} Copper, Chronic WER*0.960 • e^{0.8545[ln hardness]-1.702} Lead, Acute WER*{1.46203-[ln hardness](0.145712)} • e^{1.273[In hardness]-1.460} Lead, Chronic WER*{1.46203-[ln hardness](0.145712)} • e^{1.273[In hardness]-4.705} Nickel, Acute WER*0.998 • e^{0.8460[ln hardness]+2.255} Nickel, Chronic WER*0.997 • e^{0.8460[ln hardness]+0.0584} Page 1 of 4 Permit No. NC0026565 Silver, Acute WER*0.85 • e^{1.72[In hardness]-6.59} Silver, Chronic Not applicable Zinc, Acute WER*0.978 • e^{0.8473[ln hardness]+0.884} Zinc, Chronic WER*0.986 • e^{0.8473[ln hardness]+0.884} General Information on the Reasonable Potential Analysis (RPA) The RPA process itself did not change as the result of the new metals standards. However, application of the dissolved and hardness -dependent standards requires additional consideration in order to establish the numeric standard for each metal of concern of each individual discharge. The hardness -based standards require some knowledge of the effluent and instream (upstream) hardness and so must be calculated case -by -case for each discharge. Metals limits must be expressed as `total recoverable' metals in accordance with 40 CFR 122.45(c). The discharge -specific standards must be converted to the equivalent total values for use in the RPA calculations. We will generally rely on default translator values developed for each metal (more on that below), but it is also possible to consider case -specific translators developed in accordance with established methodology. RPA Permitting Guidance/WQBELs for Hardness -Dependent Metals - Freshwater The RPA is designed to predict the maximum likely effluent concentrations for each metal of concern, based on recent effluent data, and calculate the allowable effluent concentrations, based on applicable standards and the critical low -flow values for the receiving stream. If the maximum predicted value is greater than the maximum allowed value (chronic or acute), the discharge has reasonable potential to exceed the standard, which warrants a permit limit in most cases. If monitoring for a particular pollutant indicates that the pollutant is not present (i.e. consistently below detection level), then the Division may remove the monitoring requirement in the reissued permit. 1. To perform a RPA on the Freshwater hardness -dependent metals the Permit Writer compiles the following information: • Critical low flow of the receiving stream, 7Q10 (the spreadsheet automatically calculates the 1Q10 using the formula 1Q10 = 0.843 (s7Q10, cfs) 0.993 • Effluent hardness and upstream hardness, site -specific data is preferred • Permitted flow • Receiving stream classification 2. In order to establish the numeric standard for each hardness -dependent metal of concern and for each individual discharge, the Permit Writer must first determine what effluent and instream (upstream) hardness values to use in the equations. The permit writer reviews DMR's, Effluent Pollutant Scans, and Toxicity Test results for any hardness data and contacts the Permittee to see if any additional data is available for instream hardness values, upstream of the discharge. If no hardness data is available, the permit writer may choose to do an initial evaluation using a default hardness of 25 mg/L (CaCO3 or (Ca + Mg)). Minimum and maximum limits on the hardness value used for water quality calculations are 25 mg/L and 400 mg/L, respectively. If the use of a default hardness value results in a hardness -dependent metal showing reasonable potential, the permit writer contacts the Permittee and requests 5 site -specific effluent and upstream hardness samples over a period of one week. The RPA is rerun using the new data. Page 2 of 4 Permit No. NC0026565 The overall hardness value used in the water quality calculations is calculated as follows: Combined Hardness (chronic) = (Permitted Flow, cfs *Avg. Effluent Hardness, mg/L) + (s7Q10, cfs *Avg. Upstream Hardness, mg/L) (Permitted Flow, cfs + s7Q 10, cfs) The Combined Hardness for acute is the same but the calculation uses the 1Q10 flow. 3. The permit writer converts the numeric standard for each metal of concern to a total recoverable metal, using the EPA Default Partition Coefficients (DPCs) or site -specific translators, if any have been developed using federally approved methodology. EPA default partition coefficients or the "Fraction Dissolved" converts the value for dissolved metal at laboratory conditions to total recoverable metal at in -stream ambient conditions. This factor is calculated using the linear partition coefficients found in The Metals Translator: Guidance for Calculating a Total Recoverable Permit Limit from a Dissolved Criterion (EPA 823-B-96-007, June 1996) and the equation: Cdiss = 1 Ctotal 1 + { [Kpo] [SS(1+a)] [10-6] } Where: ss = in -stream suspended solids concentration [mg/1], minimum of 10 mg/L used, and Kpo and a = constants that express the equilibrium relationship between dissolved and adsorbed forms of metals. A list of constants used for each hardness -dependent metal can also be found in the RPA program under a sheet labeled DPCs. 4. The numeric standard for each metal of concern is divided by the default partition coefficient (or site -specific translator) to obtain a Total Recoverable Metal at ambient conditions. In some cases, where an EPA default partition coefficient translator does not exist (ie. silver), the dissolved numeric standard for each metal of concern is divided by the EPA conversion factor to obtain a Total Recoverable Metal at ambient conditions. This method presumes that the metal is dissolved to the same extent as it was during EPA's criteria development for metals. For more information on conversion factors see the June, 1996 EPA Translator Guidance Document. 5. The RPA spreadsheet uses a mass balance equation to determine the total allowable concentration (permit limits) for each pollutant using the following equation: Ca = (s7Q10 + Qw) (Cwqs) — (s7Q10) (Cb) Qw Where: Ca = allowable effluent concentration (µg/L or mg/L) Cwqs = NC Water Quality Standard or federal criteria (µg/L or mg/L) Cb = background concentration: assume zero for all toxicants except NH3* (µg/L or mg/L) Qw = permitted effluent flow (cfs, match s7Q10) s7Q 10 = summer low flow used to protect aquatic life from chronic toxicity and human health through the consumption of water, fish, and shellfish from noncarcinogens (cfs) * Discussions are on -going with EPA on how best to address background concentrations Flows other than s7Q10 may be incorporated as applicable: 1Q10 = used in the equation to protect aquatic life from acute toxicity Page 3 of 4 Permit No. NC0026565 QA = used in the equation to protect human health through the consumption of water, fish, and shellfish from carcinogens 30Q2 = used in the equation to protect aesthetic quality 6. The permit writer enters the most recent 2-3 years of effluent data for each pollutant of concern. Data entered must have been taken within four and one-half years prior to the date of the permit application (40 CFR 122.21). The RPA spreadsheet estimates the 95th percentile upper concentration of each pollutant. The Predicted Max concentrations are compared to the Total allowable concentrations to determine if a permit limit is necessary. If the predicted max exceeds the acute or chronic Total allowable concentrations, the discharge is considered to show reasonable potential to violate the water quality standard, and a permit limit (Total allowable concentration) is included in the permit in accordance with the U.S. EPA Technical Support Document for Water Quality -Based Toxics Control published in 1991. 7. When appropriate, permit writers develop facility specific compliance schedules in accordance with the EPA Headquarters Memo dated May 10, 2007 from James Hanlon to Alexis Strauss on 40 CFR 122.47 Compliance Schedule Requirements. 8. The Total Chromium NC WQS was removed and replaced with trivalent chromium and hexavalent chromium Water Quality Standards. As a cost savings measure, total chromium data results may be used as a conservative surrogate in cases where there are no analytical results based on chromium III or VI. In these cases, the projected maximum concentration (95th %) for total chromium will be compared against water quality standards for chromium III and chromium VI. 9. Effluent hardness sampling and instream hardness sampling, upstream of the discharge, are inserted into all permits with facilities monitoring for hardness -dependent metals to ensure the accuracy of the permit limits and to build a more robust hardness dataset. 10. Hardness and flow values used in the Reasonable Potential Analysis for this permit included: Parameter Value Comments (Data Source) Average Effluent Hardness, mg/L (Total as CaCO3) 56.5 Data provided by Permittee Average Upstream Hardness, mg/L (Total as CaCO3) 36 Data provided by Permittee 7Q10 summer (cfs) 11 Reported in previous permit Fact Sheet 1Q10 (cfs) 9.12 Calculated in RPA spreadsheet Permitted Flow (MGD) 0.480 Design flow Date: July 20, 2021 Permit Writer: Gary Perlmutter Page 4 of 4 Environment 1, Incorporated P.O. BOX 7085, 114 OAKMONT DRIVE GREENVILLE, N.C. 27835-7085 SUEZ WATER (RAMSEUR WWTP) NADINE BLACKWELL P.O. BOX 1279 CLEMMONS ,NC 27012 Drinking;Water .ID,. 37715j Waete,Natet' ID1 10:. PHONE (252) 756.6208 FAX (252) 756.0633 ID#: 956 T DATE COLLECTED: 03/10/20 DATE REPORTED : 03/27/20 REVIEWED BY: Effluent Upstream Analysis Method PARAMETERS Date Analyst Code Ar:nonia Nitrogen as N, mg/I 4.00 Total Kjeldahl Nitrogen as N,mg/I 5.30 Nitrate -Nitrite as N, mg/1 0.52 Total Phosphorus as P, mg/1 2.80 Total Hardness, :ng/l 46 Copper, ug/1 131 Total Nitrogen, mg/1 (calc) 5.82 03/11/20 BLD 350.1 R2-93 03/13/20 AKS 351.2 R2-93 03/11/20 AKS 353.2 R2-93 03/13/20 BLD 365.4-74 03/16/20 TMR 2340C-11 03/16/20 LFJ EPA200.7 Environment 1, Incorporated P.O. BOX 7085, 114 OAKMONT DRIVE GREENVILLE, N.C. 27835-7085 SUEZ WATER (RAMSEUR WWTP) NADINE BLACKWELL P.O. BOX 1279 CLEMMONS ,NC 27012 Drinking:,,Nater;LID 1, 3771.5' -Waeteria ter. SD:.10 PHONE (252) 756-6208 FAX (252) 756-0633 ID#: 956 T DATE COLLECTED: 06/09/20 DATE REPORTED : 06/18/20 REVIEWED BY: Effluent Upstream Analysis Method PARAMETERS Date Analyst Code Ammonia Nitrogen as N, mg/1 Total Kjeldahl Nitrogen as N,mg/l Nitrate -Nitrite as N, mg/1 Total Phosphorus as P, mg/I Total Hardness, mg/1 Copper, ug/l Total Nitrogen, mg/I (calc) 4.69 5.19 0.73 2.12 46 5.92 06/10/20 TCW 350.1 R2-93 06/16/20 TLH 351.2 R2-93 06/16/20 DTL 353.2 R2-93 06/16/20 DTL 365.4-74 06/15/20 GNB 2340C-11 06/15/20 LFJ EPA200.7 Anaa haupdg6 )AKMONT DRIVE AENVILLE, N.C. 27858 SUEZ WATER (RAMSEUR WWTP) NADINE BLACKWELL P.O. BOX 1279 CLEMMONS , NC 27 012 PARAMETERS Ammonia Nitrogen as N, mg/1 Total Kjeldahl Nitrogen as N,mg/l Nitrate -Nitrite as N, mg/1 Total Phosphorus as P, mg/l Total Hardness, mg/1 Copper, ug/l Total Nitrogen, mg/1 (calc) Drinking Water ID: 371 w_ate water,ID: 10 PHONE (252) 756-62( FAX (252) 756-06; ID#: 956 T DATE COLLECTED? 09/22/20 00/12/20 DATE REPORTED REVIEWED BY: Analysis Method Effluent Upstream Anal Y Date Analyst Code 12.16 09/24/20 KES 350.1 R2-93 12.44 09/29/20 TLH 351.2 R2-93 0.17 09/24/20 TLH 353.2 R2-93 3.55 09/29/20 KES 365.4-74 �� 09/28/20 JMS 2340C-11 10/05/20 LFJ EPA200.7 ,Lokatugml 114 OAKMONT DRIVE GREENVILLE, N.C. 27858 i7 ECCIpcg(gaco RAMSEUR WWTP 724 LIBERTY STREET P.O. BOX 545 RAMSEUR ,NC 27316 PARAMETERS Ammonia Nitrogen as -N, mg/I --Total Ijjeldahl Nitrogen as N,tng/I Nitrate -Nitrite as N, mg/I "Total Phosphorus as P, mg/l Total Hardness, mg/I Copper, ng/I Total Nitrogen, mg/1 (calc) 262) 750. 28 FAX '(252) 756 0533 ID#: 473 T DATE COLLECTED: 12/15/20 DATE REPORTED 12/30/20 REVIEWED BY: Effluent Upstream Analysis Method Date Analyst Code yZ •a -r6s 7`7 �. b (eta,' Z 2.34 12/16/20 KES 350,1 R2-93. 4,15 12/23/20 TLH 351.2 R2-93 1.05 12/16/20 DTL 353.2 R2-93 4.7 12/23/20 KES 365.4-74 34 12/21/20 TMR 2340C-11 18 12/21/20 LFJ EPA200.7 5.20 .1.1Pawhilogild 114 OAKMONT DRIVE' GREENVILLE, N.C. 27858 RAMSEUR WWTP 724 LIBERTY STREET P.O. BOX 545 RAMSEUR ,NC 27316 PARAMETERS ID##: 473 T rAX (2$2) 756-0633 DATE COLLECTED: 03/09/21 DATE REPORTED : 03/29/21 REVIEWED BY: Effluent Upstream Analysis Method Date Analyst Code - Ammonia Nitrogen as N, mg/1 3.88 Total Kjeldahl Nitrogen as N,mg/I 4,98 Nitrate+Nitrite as N, mg/I 1.00 '-'Total Phosphorus as P, mg/I 2.23 Total Hardness, mg/1 4G Copper, ug/l 43 .. Total Nitrogen, mg/I (calc) 5,98 03/10/21 DTL 350.1 R2-93 03/16/21 KES 351.2 R2-93 03/11/21 DTL 353,21R2-93 03/16/21 DTL 365,4-74 03/15/21 DIJ 2340C-11 03/15/21 LFJ EPA200.7 l7/1714 T W T©T gntt 114 OAKMONT DRIVE GREENVILLE, N.C. 27858 tom RAMSEUR WWTP 724 LIBERTY STREET P.O. BOX 545 RAMSEUR, NC 27316 PARAMETERS Ammonia Nitrogen as N, mg/1 Total Kjeldahl Nitrogen as N,mg/1 Nitrate+Nitrite as N, mg/1 '.Total Phosphorus as P, mg/1 Total Hardness, mg/1 Copper, ug/1 Total Nitrogen, mg/1 (talc) Komitcof PHONE (252) 756-6208 FAX (252) 756-0633 ID#: 473 T DATE COLLECTED: 06/15/21 DATE REPORTED : 06/28/21 REVIEWED BY: Effluent Upstream Analysis Method Date Analyst Code 13.56 06/22/21 TCW 350.1 R2-93 17,25 06/17/21 TLH 351.2 R2-93 0.08 06/21/21 TLH 353.2 R2-93 5,41 06/17/21 RES 365.4-74 6S 32 J % 06/21/21 BLV 2340C-11 06/17/21 LFJ EPA200.7 17.33 11/23/21 WQS = 12 ng/L Facility Name Ramseur WWTP / NC0026565 /Permit No. : MERCURY WQBEL/TBEL EVALUATION V:2013-6 Total Mercury 1631E PQL = 0.5 ng/L 7Q10s = Date Modifier Data Entry Value Permitted Flow = 6/13/17 < 1 9/19/17 < 1 12/12/17 < 1 3/13/18 < 1 6/12/18 < 1 9/25/18 1 12/18/18 1.9 3/12/19 < 1 6/11/19 < 1 7/23/19 1.6 9/17/19 < 1 12/10/19 < 1 3/10/20 3.5 6/9/20 1.1 9/22/20 < 1 12/15/20 1 3/9/21 1.4 No Limit Required No MMP Required 0.5 0.5 0.5 0.5 0.5 1 1.9 0.5 0.5 1.6 0.5 0.5 3.5 1.1 0.5 1 1.4 11.000 0.480 cfs WQBEL = 189.42 ng/L 47 ng/L 0.5 ng/L - Annual Average for 2017 1.0 ng/L - Annual Average for 2018 0.7 ng/L - Annual Average for 2019 1.5 ng/L - Annual Average for 2020 1.4 ng/L - Annual Average for 2021 Ramseur WWTP / NC0026565 Mercury Data Statistics (Method 1631E) 2017 2018 2019 2020 2021 # of Samples 3 4 5 4 1 Annual Average, ng/L 0.5 1.0 0.7 1.5 1.4 Maximum Value, ng/L 0.50 1.90 1.60 3.50 1.40 TBEL, ng/L 47 WQBEL, ng/L 189.4 Proof Of Publication in COURIER -TRIBUNE NCDENR/DWQINPDES ATTN: WREN THEDFORD 1617 MAIL SERVICE CENTER RALEIGH, NC 276991617 STATE OF NORTH CAROLINA, RANDOLPH COUNTY To Whom It May Concern: This is to certify the advertisement attached hereto has been published in COURIER -TRIBUNE 1 time(s) in issues dated: November 26, 2021 the last day of said publication being the 26th day of November, 2021 Notary Public, Stat Wisconsin, County of Brown My commissiaFl expires sworn to before me and subscribed in my presence by this the 26th day of November, 2021 FEE: $95.42 AD #: 0001435026 ACCT: 54948 AMY KOKOTT Notary Public State of Wisconsin Public Notice North Carolina Environmental Management Commission/ NPDES Unit 1617 Mail Service Center Raleigh, NC 27699-1617 Notice of Intent to Issue a NPDES Wastewater Permit NC0026565 Ramseur WWTP The North Caroli- na Environmental Management Commission proposes to issue a NPDES wastewater discharge per- mit to the person(s) listed below. Written comments regarding the proposed permit will be accepted until 30 days after the publish date of this notice. The Director of the NC Division of Water Resour- ces (DWR) may hold a public hear- ing should there be a significant degree of public interest. Please mail comments and/or informa- tion requests to DWR at the above address. Interested persons may visit the DWR at 512 N. Salisbury Street, Raleigh, NC 27604 to review information on file. Additional in- formation on NPDES permits and this notice may be found on our website: http://deq.nc.gov/about/ divisions/water-resources/water- resou rces-permits/wastewater- branch/npdes-wastewater/ public-notices,or by calling (919) 707-3601. The Town of Ramseur [P. O. BOx 545, Ramseur, NC 27316] has requested renewal of NPDES Permit NC0026565 for its Ramseur WWTP located in Randolph Coun- ty. This permitted facility permit- ted discharges treated municipal and industrial wastewater to the Deep River, a Class C water in the Cape Fear River Basin. Some of the parameters in the permit are water -quality limited. This dis- charge may affect future alloca- tions in this segment of the Deep River. It: 11/26/21 Page 1 of 1 SOUTHERN ENV RONMENTAL CENTER Via U.S. e-mail Gary Perlmutter NCDEQ/DWR/NPDES Water Quality Permitting Section 1617 Mail Service Center Raleigh, NC 27699-1617 gary.perlmutter@ncdenr.gov 601 West Rosemary Street, Suite 220 Telephone 919-967-1450 Chapel Hill, NC 27516 Facsimile 919-929-9421 December 17, 2021 RE: Southern Environmental Law Center Comments on NPDES Wastewater Permit NC0026565 — Ramseur WWTP Dear Mr. Perlmutter: The Southern Environmental Law Center offers the following comments on Draft National Pollutant Discharge Elimination System ("NPDES") Permit NC0026565, issued by the North Carolina Department of Environmental Quality ("DEQ") to the Town of Ramseur. The permit allows Ramseur to discharge wastewater likely contaminated with per- and polyfluoroalkyl substances, or PFAS, from its wastewater treatment plant ("WWTP") into downstream drinking water supplies in the Cape Fear River basin. Communities in Sanford, Harnett, Dunn, and Fayetteville are downstream of the treatment plant and their drinking water supplies have previously contained PFAS,1 which are known to harm human health. Based on previous sampling, Ramseur's discharge almost certainly contains PFAS. The town did not, however, disclose its discharge of PFAS in its permit application, and DEQ did not evaluate limits for the chemicals in its draft permit, as required by the Clean Water Act and state laws. Because Ramseur did not disclose its PFAS discharges in its application, any permit issued by the agency will necessarily prohibit all discharges of the chemicals. DEQ has the authority to issue a permit that allows discharges, but it cannot do so by ignoring what pollutants are in the discharge. DEQ, therefore, must require disclosure of PFAS and include necessary limits in the town's permit. EPA's PFAS Strategic Roadmap recently affirmed that "existing NPDES authorities" can be used to "reduce discharges of PFAS at the source."2 EPA's plan further confirms that the Clean Water Act pretreatment program can be used to control sources of PFAS, and the agency plans to "require pretreatment programs to include source control."3 North Carolina has already 1 EPA, Occurrence Data for the Unregulated Contaminant Monitoring Rule (UCMR) 3, https://perma.cc/2EXD- AKPQ. 2 EPA, PFAS Strategic Roadmap: EPA's Commitments to Action 2021-2024 at 14, https://perma.cc/LK4U-RLBH. 3 Id. Charlottesville Chapel Hill Atlanta Asheville Birmingham Charleston Nashville Richmond Washington, DC faced a PFAS drinking water crisis. Because communities continue to suffer from exposure to these chemicals, DEQ must act now to stop PFAS from entering our rivers, streams, and drinking water supplies. The need for action is most urgent in the Cape Fear River, where sources upstream from Chemours, such as Ramseur, are significant contributors to PFAS contamination. For each permit issued for facilities that discharge PFAS, DEQ must use its existing authority under the Clean Water Act to require disclosure and evaluate limits. Similarly, previous sampling has indicated that Ramseur's discharge likely contains 1,4- dioxane, another toxic chemical. Ramseur also did not disclose whether it discharges 1,4-dioxane and DEQ did not evaluate limits for the chemical in its draft permit. Instead, the draft permit includes a monthly monitoring requirement for the toxic chemical. Monitoring is not a substitute for the mandatory permitting process that DEQ must conduct. In order to comply with the Clean Water Act, DEQ should withdraw this draft permit, return Ramseur's application, and re -start the permitting process after the town makes the necessary disclosures. A. The Ramseur WWTP discharges toxic PFAS. Sampling conducted in 2019 reveals that the influent to Ramseur's WWTP has contained PFAS concentrations above 499 parts per trillion ("ppt").4 Because the treatment plant is not equipped to remove PFAS, it is almost certain that Ramseur is releasing PFAS into the Cape Fear River basin, a source of drinking water for nearly one million North Carolinians. It is also likely that the influent data is an underestimate of how much PFAS the town is releasing in its wastewater discharge. PFAS sampling conducted at WWTPs often find that concentrations of PFAS increase from the influent to the effluent because treatment plant influent often contains PFAS precursors that cannot be found using certain analytical methods. As studies have found, there can be a "substantial increase" in specific PFAS after wastewater treatment, and that the "degradation of precursor compounds is a significant contributor to PFAS contamination in the environment."5 PFAS are a serious threat to human health and the environment. Two of the most commonly studied PFAS—perfluorooctanoic acid ("PFOA") and perfluorooctane sulfonate ("PFOS")—have been found to cause developmental effects to fetuses and infants, kidney and testicular cancer, liver malfunction, hypothyroidism, high cholesterol, ulcerative colitis, lower birth weight and size, obesity, decreased immune response to vaccines, reduced hormone levels, and delayed puberty.6 In 2016, EPA established a lifetime health advisory of 70 ppt for the 4 2019 Sampling Data — Ramseur WWTP (Attachment 1). 5 Ulrika Eriksson, et al., Contribution of precursor compounds to the release of per- and polyfluoroalkyl substances (PFASs) from waste water treatment plants (WWTPs), 61 J. ENvIRoN. SCI.80-90 (2017); see also Mich. Dep't of Env't, Great Lakes, and Energy, Summary Report: Initiatives to Evaluate the Presence of PFAS in Municipal Wastewater and Associated Residuals (Sludge/Biosolids) in Michigan, at 9-10, https://perma.cc/C2Z8-DT99. 6 Arlene Blum et al., The Madrid Statement on Poly- and Perfluoroalkyl Substances (PFASs), 123 ENVTL. HEALTH PERSPECTIVES 5, A 107 (2015); U.S. EPA, Fact Sheet: PFOA & PFOS Drinking Water Health Advisories, at 2, https://perma.cc/CX95-N67K. combined concentrations of PFOA and PFOS in drinking water. EPA has since updated toxicity assessments for the chemicals, suggesting that the health values for the chemicals should be magnitudes lower. The updated toxicity assessments would translate to health advisories of .006 ppt for PFOA and .029 ppt for PFOS.8 Epidemiological studies show that other PFAS similarly harm human health at low levels.9 Given that PFAS concentrations less than 1 ppt can be harmful to human health, DEQ cannot ignore sampling data showing that Ramseur may be discharging PFAS at 499 ppt, or even higher. B. The Ramseur WWTP likely discharges 1,4-dioxane, another toxic chemical. Sampling at the Ramseur WWTP from 2019 also found 1,4-dioxane in the treatment plant's influent.10 Because the treatment plant is also not equipped to remove 1,4-dioxane, it is likely that Ramseur is releasing the chemical in its wastewater. 1,4-dioxane is a clear, man-made chemical that is a byproduct of many industrial processes.11 The chemical is toxic to humans, causing liver and kidney damage.12 As a result of the harms caused by 1,4-dioxane, EPA established a drinking water health advisory with an associated lifetime cancer risk of one -in - one -million at a concentration of 0.35 parts per billion ("ppb"),13 and North Carolina's rules prohibit the release of 1,4-dioxane that would cause or contribute to an exceedance of 0.35 ppb in water supply waters.14 C. DEQ must require Ramseur to disclose any PFAS or 1,4-dioxane that the town is discharging from its treatment plant. The Clean Water Act prohibits the discharge of any pollutant without a NPDES permit. The discharge of a specific pollutant (or group of pollutants) cannot be permitted if it is not disclosed in a NPDES permit application. Therefore, Ramseur is required to disclose any discharges of PFAS or 1,4-dioxane in its permit application —as DEQ recognized in its 2017 enforcement action against Chemours. 7 EPA, Fact Sheet: PFOA & PFOS Drinking Water Health Advisories at 2. 8 Garret Ellison, No safe PFAS exposure level? EPA toxicity drafts point that way, MLIVE, Nov. 20, 2021, https://perma.cc/S7GW-DUCA. 9 EPA, Human Health Toxicity Values for Hexafluoropropylene Oxide (HFPO) Dimer Acid and Its Ammonium Salt (CASRN 13252-13-6 and CASRN 62037-80-3) (2021), https://perma.cc/FG6A-TXQ9. 10 2019 Sampling Data — Ramseur WWTP (Attachment 1). 11 EPA, Technical Fact Sheet—1,4-Dioxane, at 1-2 (2017), https://perma.cc/NM9K-2P84 ("EPA 1,4-dioxane fact sheet"). 12Id.; EPA, Integrated Risk Information System, Chemical Assessment Summary: 1,4-dioxane at 2, https://perma.cc/B2A2-R4M5. 13 EPA, 2018 Edition of the Drinking Water Standards and Health Advisories, at 4 (2018), https://perma.cc/N8N4- BA3R; N.C. Div. of Water Res., I,4-dioxane Monitoring in the Cape Fear River Basin of North Carolina: An Ongoing Screening, Source Identification, and Abatement Verification Study, at 2 (2017), https://perma.cc/7MMR- B9SQ. 14 Frequently Asked Questions (FAQ), Special Order by Consent (SOC) for the City of Greensboro T.Z. Osborne WWTP, https://perma.cc/E8YY-8YFV (interpreting 15A N.C. Admin Code 2B.0208). If a NPDES permit applicant does not adequately disclose its release of a pollutant, the applicant does not have approval to discharge the pollutant.15 Disclosure is considered adequate when the applicant provides enough information for a permitting agency to "be[] able to judge whether the discharge of a particular pollutant constitutes a significant threat to the environment."16 To meet this burden, an applicant must include all relevant information, including the concentration, volume, and frequency of the discharge.17 The Clean Water Act places the burden of disclosure on the permit applicant because they are in the best position to know what is in their discharge.'$ The EPA has stressed the need for disclosure of pollutants during the permitting process: [D]ischargers have a duty to be aware of any significant pollutant levels in their discharge. [...] Most important, [the disclosure requirements] provide the information which the permit writers need to determine what pollutants are likely to be discharged in significant amounts and to set appropriate permit limits. [...] [P]ermit writers need to know what pollutants are present in an effluent to determine approval permit limits in the absence of applicable effluent guidelines.' 9 The EPA Environmental Appeals Board's decision in In re: Ketchikan Pulp Company further emphasized the importance of disclosure,20 and this decision has been adopted by the Fourth Circuit. In Piney Run Pres. Ass 'n v. Cty. Comm 'rs of Carroll Cty., Maryland, the Fourth Circuit stated: The Ketchikan decision therefore made clear that a permit holder is in compliance with the [Clean Water Act] even if it discharges pollutants that are not listed in its permit, as long as it only discharges pollutants that have been adequately disclosed to the permitting authority. [...] To the extent that a permit holder discharges a pollutant that it did not disclose, it violates the NPDES permit and the [Clean Water Act].2' 15 See In re Ketchikan Pulp Co., 7 E.A.D. 605 (EPA) (1998); Piney Run Pres. Ass 'n v. Cty. Comm'rs of Carroll Cty., Maryland, 268 F.3d. 255 (4th Cir. 2001); Southern Appalachian Mountain Stewards v. A & G Coal Corp., 758 F.3d 560 (4th Cir. 2014). 16 Piney Run, 268 F.3d at 268 ("Because the permitting scheme is dependent on the permitting authority being able to judge whether the discharge of a particular pollutant constitutes a significant threat to the environment, discharges not within the reasonable contemplation of the permitting authority during the permit application process, whether spills or otherwise, do not come within the protection of the permit shield."). 17 See In re Ketchikan Pulp Co., 7 E.A.D. 605 ("In explaining the provisions of 40 C.F.R. § 122.53(d)(7)(iii), which required dischargers to submit quantitative data relating to certain conventional and nonconventional pollutants that dischargers know or have reason to believe are present in their effluent, the [EPA] stated: `permit writers need to know what pollutants are present in an effluent to determine appropriate limits in the absence of effluent guidelines.'"). 18 S. Appalachian Mountain Stewards, 758 F.3d at 566. 19 Consolidated Permit Application Forms for EPA Programs, 45 Fed. Reg. 33,526-31 (May 19, 1980). 20 See In re Ketchikan Pulp Co., 7 E.A.D. 605. 21 Piney Run, 268 F.3d. at 268 (emphasis added). Moreover, municipalities that own and operate wastewater treatment plants are required to "fully and effectively exercise[] and implement[]" their authority to "[i]dentify the character and volume of pollutants contributed to the [publicly owned treatment works]" by Industrial Users.22 DEQ has acknowledged that disclosure of toxic pollutants, including PFAS, is required by the Clean Water Act and state water quality laws. In its enforcement action against The Chemours Company, LLC for the company's discharge of GenX and other PFAS into the Cape Fear River, the agency stated: Part of the permit applicant's burden in this regard is to disclose all relevant information, such as the presence of known constituents in a discharge that pose a potential risk to human health. The permit applicant is required to disclose "all known toxic components that can be reasonably expected to be in the discharge, including but not limited to those contained in a priority pollutant analysis." 15A N.C.A.C. 2H .0105(j) (emphasis added). [...] These disclosure obligations are critical, in part, because they define the scope of the Clean Water Act's "permit shield." While compliance with the express terms of an NPDES permit generally "shields" the permittee from liability for violations of 33 U.S.C. § 1311, the permit does not shield the permittee from liability where the pollutant being discharged was not within the "reasonable contemplation" of the permitting agency when it issued the permit due to nondisclosure by the permittee.23 The agency further acknowledged that the company had violated its NPDES permit and state water quality laws by "failing to fully disclose all known toxic components reasonably expected to be in [the company's] discharge."24 DEQ's position in the Chemours enforcement case was correct and should be applied to Ramseur in this permit renewal. Ramseur likely discharges PFAS and 1,4-dioxane, and the town was required to disclose the pollutant in its permit application so that DEQ can "judge whether the discharge" "constitutes a significant threat to the environment."25 Because Ramseur failed to do so,26 DEQ does not have the information it needs to make an informed decision on the town's application.27 DEQ must require Ramseur to disclose any discharge of PFAS or 1,4-dioxane in the town's permit application before moving forward with the draft permit. 22 40 C.F.R. § 403.8(f)(1)(vi)(B). 23 Amended Complaint, N.C. Dept. of Environmental Quality v. Chemours, 17 CVS 580, 67 (N.C. Super. 2018) (citing 33 U.S.C. § 1342(k), Piney Run Pres. Ass v. Cty. Comm 'rs of Carroll Cty., MD, 268 F.3d 255, 265 (4th Cir. 2001)). 24 Id. at 33. 25 Piney Run, 268 F.3d at 268. 26 See Town of Ramseur, Permit Renewal, Application No. NC0026565, Nov. 10, 2020. 27 See S. Appalachian Mountain Stewards, 758 F.3d at 566 ("[T]he CWA and its implementing regulations focus on the information that the permit applicant must gather and provide to the permitting agency, so that it can make a fully informed decision to issue the requested permit."). In addition, DEQ's mandated monitoring for 1,4-dioxane does not absolve Ramseur's obligation to disclose its 1,4-dioxane discharge in its application. Without disclosure during the application process, the agency cannot evaluate the discharge for compliance with permitting requirements and the public does not have sufficient information to meaningfully review and comment on the draft permit. Because public notice and informed participation are mandated by law,28 monitoring reports sent only to the agency after the permit has been issued cannot be considered adequate disclosure. D. DEQ must analyze appropriate effluent limits for PFAS and 1,4-dioxane in Ramseur's NPDES permit. Because Ramseur is likely discharging PFAS and 1,4-dioxane, DEQ must consider appropriate permit limits for these chemicals. Ramseur can then comply with any limits in its permit by properly regulating its industries —for instance, by requiring industries to use alternative chemicals, or to install treatment technology to remove pollutants from their wastewater before sending it to the town's treatment plant. The Clean Water Act requires permitting agencies to, at the very least, incorporate, technology -based effluent limitations on the discharge of pollutants.29 North Carolina water quality laws further state that municipalities must be treated like an industrial discharger if an industry "significantly impact[s]" a municipal treatment system.30 In this situation, the agency must consider technology -based effluent limits for the municipality, even if effluent limits and guidelines have not been published and adopted. Effective treatment technologies for PFAS and 1,4-dioxane are available. A granular activated carbon treatment system has been used at Chemours' facility to reduce PFAS as high as 345,000 ppt from a creek contaminated by groundwater beneath the facility to nearly nondetectable concentrations.31 Similarly, 1,4-dioxane can be removed using advanced oxidation processes, such as using ultraviolet light in combination with hydrogen peroxide.32 Such a process has been used at the Tucson International Airport Area Superfund Site to remove legacy 1,4-dioxane contamination.33 DEQ must consider the feasibility of Ramseur's industries installing similarly effective treatment technologies. 28 40 C.F.R. § 124.10 (a); 15A N.C. Admin. Code 2H.0109(a). 29 40 C.F.R. § 125.3(a); see also 33 U.S.C. § 1311. 3° 15A N.C. Admin Code 02B .0406 (a), (e). 31 Ted Schoenberg, Parsons, Old Outfall 002 GAC Pilot Study Interim Results Report, Chemours Fayetteville, North Carolina Facility, 4-5 (Aug. 5, 2019), https://perma.cc/DU3Y-25AW; Parsons, Old Outfall 002 Surface Water Sampling Results (Sept. 30, 2019) at Table 1, https://perma.cc/6BYQ-RNXZ. 32 Amie C. McElroy, et al., 1,4-Dioxane in drinking water: emerging for 40 years and still unregulated, 7 CURRENT OPINION IN ENv'T SCIENCE & HEALTH 117, 119 (2019), https://perma.cc/P8L3-CC5G. 33 See Advanced Treatment for 1,4-Dioxane — Tucson Removes Contamination Through UV -oxidation, TROJANUV CASESTUDIES (2019), https://perma.cc/Z95X-D6A5; see also Educational Brochure, TUCSON AIRPORT AREA REMEDIATION PROJECT, https://perma.cc/XUH8-W4DZ. If these limits are not enough to ensure compliance with water quality standards, then water quality -based effluent limits must be included in the town's permit.34 PFAS are known to harm human health, and their discharge threatens to violate multiple water quality standards, including the state toxic substances standard.35 DEQ itself has stated in its lawsuit against Chemours that PFAS "meet the definition of `toxic substance' under North Carolina rules.36 DEQ has also applied the toxic substances standard to 1,4-dioxane, interpreting the standard to require concentrations of 1,4-dioxane be less than 0.35 ppb in rivers and streams that serve as drinking water supplies.37 In order to comply with the Clean Water Act, therefore, DEQ must limit Ramseur's discharge so that it will not cause, or contribute to concentrations of 1,4-dioxane exceeding 0.35 ppb in any downstream drinking water supplies.38 Once appropriate limits are included in a Ramseur's NPDES permit, the town must regulate its industries so that industries do not cause the treatment plant to violate its own NPDES permit.39 This is how the Clean Water Act "assures the public that [industrial] dischargers cannot contravene the [Clean Water Act's] objectives of eliminating or at least minimizing discharges of toxic and other pollutants simply by discharging indirectly through [wastewater treatment plants] rather than directly to receiving waters."40 As is appropriate, the pretreatment program is intended to place the burden of treating polluted discharges on the entity that creates the pollution, rather than on the taxpayers that support municipally owned treatment plants. Moreover, municipalities like Ramseur that own and operate wastewater treatment plants are required to "immediately and effectively to halt or prevent any discharge of pollutants to the [publicly owned treatment works] which reasonably appears to present an imminent endangerment to the health or welfare of persons."41 Together, these laws ensure that such municipally owned treatment plants do not become dumping grounds for uncontrolled industrial waste. Ramseur, therefore, cannot allow industries to cause its treatment plant to violate the town's own NPDES permit.42 Ramseur could prevent violations of its permit by requiring industries to use alternative chemicals, or to install treatment technology to remove PFAS or 1,4- 34 15A N.C. Admin. Code 2H.0112(c) (stating that DWR must "reasonably ensure compliance with applicable water quality standards and regulations."); see 33 U.S.C. § 1311(b)(1)(c) (requiring that permit limits be established as necessary to comply with water quality standards). 35 15A N.C. Admin. Code 2B.0208(a). 36 Amended Complaint, N.C. Dept. of Environmental Quality v. Chemours, 17 CVS 580, 32 (N.C. Super. 2018) (stating that "the process wastewater from [Chemours'] Fluoromonomers/Nafion® Membrane Manufacturing Area contains and has contained substances or combinations of substances which meet the definition of "toxic substance" set forth in 15A N.C.A.C. 2B .0202," referring to GenX and other PFAS). 37 N.C. Div. of Water Res., I, 4-dioxane Monitoring in the Cape Fear River Basin of North Carolina: An Ongoing Screening, Source Identification, and Abatement Verification Study, at 2 (2017), https://perma.cc/3RK6-8T4D. 38 40 C.F.R. § 122.44(d)(1)(i); see also 15A N.C. Admin. Code 2B.0203 ("Water quality based effluent limitations and management practices for direct or indirect discharges of waste or for other sources of water pollution shall be developed by the Division such that the water quality standards and best usage of receiving waters and all downstream waters will not be impaired."). 39 40 C.F.R. § 403.8(f)(1). 40 General Pretreatment Regulations for Existing and New Sources, 52 Fed. Reg. 1586, 1590 (Jan. 14, 1987) (codified at 40 C.F.R. § 403). 41 40 C.F.R. § 403.8(f)(2)(ii). 42 Id. § 403.8(f)(1). dioxane from their wastewater before sending wastewater to the town's treatment plant. In Michigan, for instance, municipalities have been effectively reducing their PFAS discharges by requiring industrial users to install treatment technology. Municipalities in Michigan had discovered that industries, such as metal finishers, paper manufacturers, and fabric/leather treaters, were sending PFAS-contaminated wastewater to their treatment plants.43 After industrial users installed treatment systems to remove PFAS, PFOS levels in the discharges of several treatment plants were reduced by up to 99 percent.44 By including appropriate limits in Ramseur's NPDES permit (as well as permits for other municipalities), DEQ can put the burden of cleaning up toxic pollution on the industries that create it. In summary, DEQ must require Ramseur to disclose any discharges of PFAS or 1,4- dioxane in its permit application so that DEQ and the public have adequate information to evaluate the discharge. If the town does not make that disclosure, any discharge of these chemicals is illegal and subject to agency or citizen enforcement. DEQ must then evaluate available treatment technologies and impose necessary limits. Because the draft permit fails to meet these requirements, it should be withdrawn. Thank you for considering these comments. Please contact me at 919-967-1450 or jzhuang@selcnc.org if you have any questions regarding this letter. Sincerely, e5'----a Jean Zhuang SOUTHERN ENVIRONMENTAL LAW CENTER 601 W. Rosemary Street, Suite 220 Chapel Hill, NC 27516 919-967-1450 43 Michigan.gov, Michigan PFAS Action Response Team, Wastewater Treatment Plants/Industrial Pretreatment Program, https://perma.cc/2AZ7-ASHH. 44 Id. ATTACHMENT 1 POTW Name: Town of Ramseur WWTP NPDES #: NC0026565 Influent Grab (ng/L) CAS Number Analyte Name Acronym 7/8/2019 Lab Qualifer(s) 8/6/2019 Lab Qualifer(s) 9/4/2019 Lab Qualifer(s) 375-22-4 Perfluorobutanoic acid PFBA ND U (<0.311) ND U (<1.25) ND U (<1.24) 375-73-5 Perfluorobutanesulfonic acid PFBS ND U (<0.311) 344 ND U (<1.24) 335-77-3 Perfluorodecanesulfonic acid PFDS ND U (<0.311) ND U (<1.25) ND U (<1.24) 335-76-2 Perfluorodecanoic acid PFDA 0.586 ND U (<1.25) ND U (<1.24) 307-55-1 Perfluorododecanoic acid PFDoA ND U (<0.311) ND U (<1.25) ND U (<1.24) 375-92-8 Perfluoroheptanesulfonic acid PFHpS ND U (<0.311) ND U (<1.25) ND U (<1.24) 375-85-9 Perfluoroheptanoic acid PFHpA 1.24 ND U (<1.25) ND U (<1.24) 355-46-4 Perfluorohexanesulfonic acid PFHxS ND U (<0.311) ND U (<1.25) ND U (<1.24) 307-24-4 Perfluorohexanoic acid PFHxA 6.97 4.77 4.64 68259-12-1 Perfluorononanesulfonic acid PFNS ND U (<0.31) ND U (<1.25) ND U (<1.24) 375-95-1 Perfluorononanoic acid PFNA 0.782 ND U (<1.25) ND U (<1.24) 754-91-6 Perfluorooctanesulfonamide PFOSA ND U (<0.316) ND U (<1.25) ND U (<1.24) 2991-50-6 2-(N-Ethylperfluorooctanesulfonamido) acetic acid N-EtFOSAA ND U (<0.311) ND U (<1.25) ND U (<1.24) 2355-31-9 2-(N-Methylperfluorooctanesulfonamido) acetic acid N-MeFOSAA ND U (<0.311) ND U (<1.25) ND U (<1.24) 2706-91-4 Perfluoropentanesulfonic acid PFPeS ND U (<0.311) ND U (<1.25) ND U (<1.24) 2706-90-3 Perfluoropentanoic acid PFPeA 41.8 103 313 376-06-7 Perfluorotetradecanoic acid PFTeA (PFTA) 0.761 ND U (<1.25) ND U (<1.24) 72629-94-8 Perfluorotridecanoic acid PFTriA (PFTrA) ND U (<0.311) ND U (<1.25) ND U (<1.24) 2058-94-8 Perfluoroundecanoic acid PFUnA ND U (<0.311) ND U (<1.25) ND U (<1.24) 62037-80-3 Gen-X HFPO-DA ND U (<10.90) ND U (<43.9) ND U (<43.3) 757124-72-4 4:2 Fluorotelomer sulfonate 4:2 FTS ND U (<0.311) ND U (<1.25) ND U (<1.24) 27619-97-2 6:2 Fluorotelomer sulfonate 6:2 FTS ND U (<0.311) ND U (<1.25) ND U (<1.24) 39108-34-4 8:2 Fluorotelomer sulfonate 8:2 FTS ND U (<0.311) ND U (<1.25) ND U (<1.24) 335-67-1 Perfluorooctanoic acid PFOA 2.93 2 1.96 1763-23-1 Perfluorooctanesulfonic acid PFOS 6.52 45.7 8.06 Sum of PFOA and PFOS 9.45 47.7 10.02 Total PFAS 61.589 499.47 327.66 Influent Grab ug/L) 7/8/2019 Lab Qualifer(s) 8/6/2019 Lab Qualifer(s) 9/4/2019 Lab Qualifer(s) 1, 4 - Dioxane ND U (<1.0) 2 2.08 Lab Qualifiers ND - Analyte concentration is not detected above the detection limit. B - Analyte found in the sample and associated method blank. J - The reported value is an estimate. The value is less than the Reporting Limit. U - The sample was not detected in the sample at the Reporting Limit. Responses to Comments for Ramseur WWTP January 27, 2022 Comments from SELC Comment: DEQ must require Ramseur to disclose any discharges of PFAS or 1,4-Dioxane in its permit application so that DEQ and the public have adequate information to evaluate the discharge. If the town does not make that disclosure, any discharge of these chemicals is illegal and subject to agency or citizen enforcement. DEQ must then evaluate available treatment technologies and impose necessary limits. Because the draft permit fails to meet these requirements, it should be withdrawn. DWR Response: The City of Ramseur had submitted results of PFAS and 1,4-Dioxane sampling conducted in 2019 to the Division, and these results are available online via the Division's Emerging Compound Facility Sampling map application (https://ncdenr.maps.arcgis.com/apps/instant/attachmentviewer/index.html?appid=ed308373c97e4a2 3a29210fa53a3d404¢er=- 78.8049%2C35.4812&level=9&attachmentlndex=0&selectedLayerld=Buffer of Facility to Data 5130& defaultObjectld=70). This information was supplemented with a Chemical Addendum, received by the Division on 1/20/2022. The submitted data represent three samplings, a total of which is insufficient to adequately assess Ramseur's discharge of PFAS and 1,4-Dioxane chemicals. Therefore, the monitoring requirement for 1,4-Dioxane as proposed is appropriate to gather effluent data needed to properly assess discharge concentrations and appropriate actions including potential limits and treatment strategies. Based on detection of PFAS chemicals in the influent from the 2019 samplings, which was also provided via as an attachment to the NPDES application received on 1/20/2022, monitoring of PFAS chemicals has been added to the permit at a frequency of 2/year. Since an EPA method for sampling and analyzing PFAS in wastewater is not currently available, the PFAS sampling requirement in the Permit includes a compliance schedule which delays the effective date of this requirement until the first full calendar quarter beginning 6 months after EPA has a final wastewater method in 40 CFR136 published in the Federal Register. This date may be extended upon request and if there are no NC -certified labs. rtamseur Where Family and Friends Meet TOWN OF RAMSEUR 724 Liberty Street, PO Box 545 Ramseur, North Carolina 27316 336-824-8530 / 336-824-4111 COMMISSIONERS MAYOR TOWN CLERK / FINANCE OFFICER Jim McIntosh VICKI CAUDLE Carol Akers J.C. Parrish Tim Cranford DEPUTY TOWN CLERK / FINANCE OFFICER Joy Hooker Diana Brower Adrienne Hagood January 7, 2022 Mr. Michael Montebello NC Department of Environmental Quality Division of Water Resources Water Quality Permitting - NPDES 1617 Mail Service Center Raleigh, NC 27699-1617 RE: Town of Ramseur WWTP NPDES Permit Renewal - Chemical Addendum Permit # 0026565 Dear Mr. Montebello: As a supplement to the Ramseur Wastewater Treatment Plant NPDES Application Package that is currently under review, the Town of Ramseur is submitting additional information per Session Law 2018-5, Senate Bill 99, Section 13.1(r). At the request of the Division of Environmental Quality (DEQ), the Town conducted additional WWTP influent sampling in July, August, and September 2019 for 1,4-Dioxane_ The analysis was done in accordance with EPA Method 624.1, which is a certified method in 40 CFR Part 136. Accordingly, the Town is providing a Chemical Addendum to the NPDES Application for the 1,4 Dioxane influent sampling results. Additionally, at the request of DEQ, the Town performed WWTP influent sampling for a series of PFOA/PFAS analytes in July, August, and September 2019. This sampling is not certified by the Town as there is not a 40 CFR Part 136 certified analysis method for the analytes. This data was previously provided to DEQ following the three sampling events in 2019. Although this data is not being certified by the Town and was already provided to DEQ, we are providing a summary of the results as an attachment to this for clarity. The following attachments are being provided as a supplement to the Ramseur WWTP NPDES Permit Application. Attachment 1: Attachment 2: Attachment 3: Chemical Addendum to NPDES Application Lab Reports from 1,4 Dioxane Sampling Results Uncertified Emerging Compound Sampling Data Summary PIease let us know if you have any questions on the information provided. Respectfully, TO)WN OF RAMSEU McIntosh, ORC Mayor Pro Tem/Commissioner EPA Identification Number FRSID110006710648 Pollutant (Required) NPDES Number NC0026565 Method Number (if CAS number Applicable) Facility Name Town of Ramseur WWTP Outfall Number 001 Reason Pollutant Believed Present in Discharge Estimated Concentration (If Known) 1,4 Dioxane 123-91-1 EPA624.1 Influent sampling results (July, August, September 2019) Median of three influent sampling events (July, August, September 2019) was 2 ug/L NPDES#: Oaz Phone: 33 '19z Y;xlI Fax: Email: Project: P.O.#: Turn Around Time* *RUSH work needs prior approval, Charges Apply 3-5 Da s 24 - 48 Firs Lab Use Only X X p 0 ° Temperature Upon Receipt: Compositor # Jug # Report results in: , mg/L 1 mg/kg L ug/L Received by: ! J p /(9 Time: / O _ M E .y ro ) io .._>C1t u m CC Received tc(rtiab: j } r i .Date:, Time: o ai z c Person T g Sa ple Sign/Print}: 11 Test(s) required s. CI IQ *** Dechlorination (<0.5 ppm) of Ammonia,yanide, Phenol and TKN samples must be done in the field prior to preservation. *** Comments: ry. Client: 51'7- 14,r 0 Address: q1 g s Gecuft-cici /ll_C Attenton: (Larne¢ 131>z/fv How would you like your report senf Circle all that apply: Email (preferred}, Fax, Are these results for regulatory purposes? Yes No Le E T d CC E V" L ED a E v V 8/9/18 Chain of Custody Record (COC) ICI ERITECH, INC. ENVIRONMENTAL LABORATORIES 642 Tamco Rd. Phone: 336-342-4748 . ,i Reidsville NC 27320 Fax: 336-342-1522 d4 4A..:. Email: info@meritechlabs.com www.meritechlabs.com Sampling Dates & Times m E F- p O w Date r Start a, ep f0 h 1 r Sample Location and/or ID # Method of Shipment: VY I Fed Ex 7 O "C N ate-+ Meritech, Inc. Environmental Laboratory Laboratory Certification No. 165 Contact: Nadine Blackweel & Terry LewaIlan Client: Suez Environmental 4735 Roundleaf Rd Ramseur, NC 27316 Report Date: 7/19/2019 NPDES#: NC0026565 Date Sample Rcvd: 7/10/2019 Meritech Work Order # 071019173 Sample: Influent Grab 7/8/19 Parameters Results Analysis Date Reporting Limit Method 1,4 Dioxane + Trip Blank Attached 7/11/19 EPA 624,1 1 hereby certify that 1 have reviewed and approve these data. Laboratory Representative 642 Tamco Road, Reidsville, North Carolina 27320 tel.(336)342-4748 fax.(336)342-1522 MERITECH, INC. Environmental Laboratories Laboratory Certification #165 Client: Suez Water / Ramseur WWTP Meritech ID#: 071019173 Project: 1,4 Dioxane Analysis: 07/11/19 Client Sample ID: Influent Analyst: VWV Sample Collection: 07/08/19 Dilution Factor: 1 Report Date: 07/15/19 EPA 624.1 VOLATILE ORGANICS Parameter Result 1,4-Dioxane (p-Dioxane) < 1.00 ug/L Trip Blank < 1.00 ug/L Batclt Blank = Below Reporting Limit (Yes) / No Internal Standards method criteria acceptable (Yes) / No Surrogate Recoveries Toluene-d8 Bromofluorobenzene Spike Conc Spike Recovery Limits 30 ug/1:. 97% 67-151% 30 ug/L 97% 45-161% * - if "no" is selected, see second page for details. I hereby certify that 1 have reviewed and approve these data. 642 Tamco Road * Reidsville, NC 27320 (336) 342-4748 * info@meritechlabs.com Laborat ry Repre tive 1 NPDES#: 0026,565 hone: 3 z-%1 31-3et Fax: Email: Project: Turn Around Time* *RUSH work needs prior approval, Charges Aonlv Std(10 days) 3 s 24 - 48 Hrs Lab Use Only pH OK? Cl OK? On Ice? Ces / No Person Taking Sample (Sign/Print): Test(s) Required 7J-- ...,:, 4.g.- O. '... *** Dechlorination (<0.5 ppm) of Ammonia, Cyanide, Phenol and TKN samples must be done in the field prior to preservation. *** Comments: r- g Client: 544 7:4241efr-/Palvt-iiviuki-r Address: 4736 RIZ knit/Av. 141,-, 7_7 Attention: Atad67-0 8&a-kt..-6/1 How would you like your report sent Circle all that apply: Email (preferred} , Fax ,c) us. N-) a 0 8/9/18 Chain of Custody Record (COC) MERITECH INC. ENVIRONMENTAL LABORATORIES 642 Tamco Rd. Phone: 336-342-4748 z . Reidsville NC 27320 Fax 336-342-1522 Email: info@meritechlabs.com www.meritechlabs.com Sampling Dates & Times L End E I= ---- K1) Date %) .1-. ....g, (Z)Z Start a) E 1= a cr ,c) G, ,. cs— Sample Location and/or ID # --i- Q.. Client: Project: Client Sample ID: Sample Collection: MERITECH, INC. Environmental Laboratories Laboratory Certification #165 Suez Water / Ramseur WWTP 1,4-Dioxane Influent 08/06/19 Meritech ID#: Analysis: Analyst: Dilution Factor: Report Date: EPA 624.1 VOLATILE ORGANICS Parameter 1,4-Dioxane (p-Dioxane) Trip Blank Batch Blank = Below Reporting Limit Internal Standards method criteria acceptable Surrogate Recoveries Toluene-d8 Bromofluorobenzene Result 2.00 ug/L < 1.00 ug/L (Yes V No f Vesl / No 080819164 08/12/19 VWV 1 08/16/19 Spike Cone Spike Recovery Limits 30 ug/L 101% 67.151% 30 ug/L 97% 45-161% * -If "no" is selected, see second page for details. I hereby certify that I have reviewed and approve these data. Laboratory Rep`rsentative 642 Tamco Road * Reidsville, NC 27320 (336) 342-4748 * info@meritechlabs.com Meritech, Inc. Environmental Laboratory Laboratory Certification No. 165 Contact: Nadine Blackwell Client: Suez Environmental 4735 Roundleaf Rd Ramseur, NC 27316 Report Date: 8/20/2019 NPDES#: NC0026565 Date Sample Rcvd: 8/8/2019 Meritech Work Order # 080819164 Sample: Influent Grab 8/6/19 Parameters Results Analysis Date Reporting Limit Method 1,4 Dioxane + Trip Blank Attached 8/12/19 EPA 624.1 I hereby certify that 1 have reviewed and approve these data. Laboratory Representative 642 Tamco Road, Reidsville, North Carolina 27320 tel.(336)342-4748 fax.(336)342-1522 NPDES#: l% 7----4c6(QS Phone: 33%- Fax: Email: Project: P_O.#: Turn Around Time* *RUSH work needs prior approval, Charees Aoply 3-5 Days 24-48Hrs Lab Use Only On Ice? pH OK? Yes / No CI OK? Temperature Upon Receipt: U O W O E O V an 7 Report results in: mg/L [ mg/kg i t ug/L mN I_ " fi. im. 6 U'- P S in''-' U cc Received by Lab: ^ t '; mat n Time:: y n Person Taking Sa ple (Sig 4'Plrint): tik 7:tvv-c4 Lod Test(srRequired :: ql C3 CD pies must be done in the field prior to preservation. *** Comments: m Client: 54'Z1{r Address:Z3 a CL1Ldr Ract-.5-oxit,-4ILA- C- 73I ,Attention: NAV/Vtet How would you like your report sent Circle all that apply: Email (preferred) , Fax, Are these results for regulatory purposes? Yes No ,f# hi E t= -'k/- 7.- Relinquished by:/ Date: Time: 4 hi E I vl ° o t� **" Dechlorination {<0.5 ppm) of Ammonia, Cyanide, Phenol and TKN sam 3/9/18 Chain of Custody Record (COC) MERITECH INC. ENVIRONMENTAL LABORATORIES •,4 .„ 642 Tamco Rd_ Phone: 336-342-4748 Reidsville NC 27320 Fax: 336-342-1522 - Email: info@meritechlabs.com www.meritechlabs.com Sampling Dates & Times End Time A a O v Start Time I .0 0 O m.. Date Cr Sample Location and/or ID # --t- Method of Shipment: Fed Ex v iTu Other Client: Project: Client Sample ID: Sample Collection: MERITECH, INC. Environmental Laboratories Laboratory Certification #165 Suez Water / Ramseur WWTP 1,4-Dioxane Influent 09/04/19 Meritech ID#: Analysis: Analyst: Dilution Factor: Report Date: EPA 624.1 VOLATILE ORGANICS Parameter 1,4-Dioxane (p-Dioxane) Trip Blank Batch Blank = Below Reporting Limit Internal Standards method criteria acceptable Surrogate Recoveries Toluene-d8 Bromofluorobenzene Result 2.08 ug/L < 1.00 ug/L (Yes) / No (Yes) / No 09051984 09/06/19 VWV 2 09/09/19 Spike Cone Spike Recovery Limits 30 ug/L 110% 30 ug/L 102% * - If "no" is selected, see second page for details. I hereby certify that 1 have reviewed and approve these data. 642 Tamco Road * Reidsville, NC 27320 (336) 342-4748 * info@meritechlabs.com 67-151% 45-16I% Meritech, Inc. Environmental Laboratory Laboratory Certification No. 165 Contact: Nadine Blackwell Client: Suez Environmental 4.735 Roundleaf Rd Ramseur, NC 27316 Report Date: 9/11/2019 NPDES#: NC0026565 Date Sample Rcvd: 9/5/2019 Meritech Work Order # 09051984 Sample: Influent Grab 9/4/19 Parameters Results Analysis Date Reporting Limit Method 1,4 Dioxane + Trip Blank Attached 9/6/19 EPA 624.1 1 hereby certify that 1 have reviewed and approve these data. baboratory Representative 642 Tamco Road, Reidsville, North Carolina 27320 tel.(336)342-4748 fax.(336)342-1522 11Z ‘.a ENTI-1ALPY A 1. v r l c, i Narrative Summary EU # 0919-708 R 23 of 33 Enthalpy Analytical Narrative Summary Company Suez Water Ramseur Job# 0919-708 PFAS — Legacy 24 + Gen-X , Client Project # n/a Custody Hunter Allen of Enthalpy Analytical Wilmington received the sample on 09/08/19 on ice at 2.6°C. Braidy May of Enthalpy Analytical Wilmington observed the samples were in good condition on 09/09/19. Prior to, during, and after analysis, the sample was stored in the laboratory with access only by authorized personnel of Enthalpy Analytical, LLC. Analysis The sample was analyzed by isotope dilution method for PFAS using Waters Acquity UPLC equipped with Xevo TQ MS (LC/MS/MS "Kili"). For aqueous samples, 250mL aliquot was weighed and spiked with Extraction Standard (ES). The sample was then mixed well and centrifuged. Cleanup procedures were performed on the supernatant and then extracted via SPE. Each final sample extract was transferred to an autosampler vial and spiked with 400 µL of Injection Standard (IS), prior to analysis. Calibration The analytes and labeled standards in the initial calibration exhibited RSDs less than 50% with exception of the following: M8FOSA and d3-N-MeFOSAA All analytes passed the R2 coefficient correlation criteria. Per DoD QSM 5.3 Table B-15, the ICAL is acceptable for all analytes since R2 met criteria. All analytes will be reported. The ICV and continuing calibration (concal) injections met the ±30% recovery criteria and ±50% ES recovery criteria for all analytes of interest. QC Notes The QC injections of the initial extraction did not meet method criteria requiring re -extraction of samples. The QC of re -extracted samples met the ±50% criteria for ES recoveries with the exception of analyte M2PFTeDA, which fell below the lower limit in the method blank. However, this compound was recovered within limits for the OPR for both native and labeled criteria. Therefore, the data are considered acceptable and no impact on sample data. EN-1-H A LI'Y No analytes were detected above the LOD (MDL) in the method blank. The samples were extracted within the 14-day from collection holding time (initial extraction — Sept 17 and re -extraction — Sept 20). Extracts EU # 0919-708 R 24 of 33 QC Notes (continued) Reporting Notes Enthalpy Analytical Narrative Summary (continued) were analyzed within the 28-days from extraction to analysis holding time required by the method. Results from the re -extraction are included in this report. Analyte PFPeA had elevated values that were not consistent with past patterns. After investigation, it was concluded the values were valid and are reported. Some analytes in the samples fell outside the limits for ES recoveries. Although the cause was undetermined, it is theorized to be matrix effects. Based on the native results in the OPR meeting criteria, the out -of- range ES recoveries have no impact on the accuracy of the target analyte (native) compounds. Therefore, the data are considered acceptable. These analyses met the requirements of the TNI Standard. Any deviations from the requirements of the reference method or TNI Standard have been stated above. The results presented in this report are representative of the samples as provided to the laboratory. The samples, calibrations and standards for the data presented in this report were analyzed at 2714 Exchange Drive, Wilmington, NC 28405. ENTH A LP' EU # 0919-708 R 25 of 33 NCDENR/DWQ/NPDES ATTN: WREN THEDFORD 1617 MAIL SERVICE CENTER RALEIGH, NC 276991617 STATE OF NORTH CAROLINA, RANDOLPH COUNTY To Whom It May Concern: This is to certify the advertisement attached hereto has been published in COURIER -TRIBUNE 1 time(s) in issues dated: February 12, 2022 the last day of said publication being the 12th day of February, 2022 Legal Cle Led Notary Public, State is onsin, County of Brown CP My commissl 1 expires sworn to before me and subscribed in my presence by this the 12th day of February, 2022 FEE: $56.68 AD #: 0001444202 ACCT: 54948 Proof Of Publication in COURIER -TRIBUNE AMY KOKOTT Notary Public State of Wisconsin Public Notice North Carolina Environmental Management Commission/NPDES Unit 1617 Mail Service Center Raleigh, NC 27699-1617 Notice of Intent to Issue a NPDES Wastewater Permit NC0026565 Ramseur WWTP The North Carolina Environmental Management Commission propos- es to issue a NPDES wastewater discharge permit to the person(s) listed below. Written comments regarding the proposed permit will be accepted until 30 days af- ter the publish date of this notice. The Director of the NC Division of Water Resources (DWR) may hold a public hearing should there be a significant degree of public inter- est. Please mail comments and/or information requests to DWR at the above address. Interested per- sons may visit the DWR at 512 N. Salisbury Street. Raleigh, NC 27604 to review information on file. Ad- ditional information on NPDES permits and this notice may be found on our website: http://deq.nc.gov/about/division: /water-resources/water- reso urces-perm its/wastewater- branch/npdes- wastewater/pub lic-notices, or by calling (919) 707-3601. The Town of Ramseur [P. O. Box 545 Ramseur, NC 27316] has requested renewal of NPDES Permit NC0026565 for its Ramseur WWTP, located in Randolph County. This permitted facility permitted dis- charges treated municipal and in- dustrial wastewater to the Deep River. a Class C water in the Cape Fear River Basin. Some of the pa- rameters in the permit are water - quality limited. This discharge may affect future allocations in this segment of the Deep River. it: 2/12/2022 Page 1 of 1 SOUTHERN ENVIRONMENTAL NVRONMENTAL LAW CENTER Via U.S. e-mail Gary Perlmutter NCDEQ/DWR/NPDES Water Quality Permitting Section 1617 Mail Service Center Raleigh, NC 27699-1617 gary.perlmutter@ncdenr.gov 601 West Rosemary Street, Suite 220 Telephone 919-967-1450 Chapel Hill, NC 27516 Facsimile 919-929-9421 March 2, 2022 Re: Southern Environmental Law Center Comments on the 2nd Draft NPDES Permit NC0026565 Renewal — Ramseur Wastewater Treatment Plant Dear Mr. Perlmutter: The Southern Environmental Law Center offers the following comments on the second draft renewal for National Pollutant Discharge Elimination System ("NPDES") Permit NC0026565, issued by the North Carolina Department of Environmental Quality ("DEQ") to the Town of Ramseur. It is a first step for Ramseur to submit information on PFAS and 1,4-dioxane as part of the permitting process, but the town has not adequately disclosed any discharges of these chemicals. DEQ admits as much in concluding that the data is "insufficient to adequately assess Ramseur's discharge of PFAS and 1,4-Dioxane chemicals."' In addition, while failing to request adequate information from the town on its PFAS discharges, DEQ delays mandatory monitoring for PFAS. Finally, the agency fails to require Ramseur to use its pretreatment authority to identify and control industrial sources of PFAS and 1,4-dioxane, and to evaluate limits on the chemicals as part of the permitting process. 1. Ramseur has not adequately disclosed discharges of PFAS and 1,4-dioxane. The information that Ramseur provided on PFAS and 1,4-dioxane is inadequate and does not constitute disclosure. The agency concedes that it does not have enough information to "be[] able to judge whether the discharge of a particular pollutant constitutes a significant threat to the environment,"2 and therefore, that there has not been adequate disclosure. 1 Ramseur WWTP, Draft Fact Sheet, Responses to Comments for Ramseur WWTP, Jan. 27, 2022. 2 Piney Run Pres. Ass 'n v. Cty. Comm 'rs of Carroll Cly., Maryland, 268 F.3d. 255, 268 (4th Cir. 2001) ("Because the permitting scheme is dependent on the permitting authority being able to judge whether the discharge of a particular pollutant constitutes a significant threat to the environment, discharges not within the reasonable Charlottesville Chapel Hill Atlanta Asheville Birmingham Charleston Nashville Richmond Washington, DC First, the data that the town provided was only on the influent of the treatment plant, not on the town's discharges. As a result, DEQ has no information on the amount of PFAS or 1,4-dioxane in the treatment plant's wastewater discharge. Even more, as discussed in prior comments, influent data cannot substitute for effluent data, as influent data often underestimates PFAS levels in treatment plant effluent. As studies have found, there can be a "substantial increase" in specific PFAS after treatment, and the "degradation of precursor compounds is a significant contributor to PFAS contamination in the environment."3 The data submitted is also from 2019 and is several years old. DEQ does not have any current information on 1,4-dioxane or PFAS levels at the plant. DEQ did not appear to request, and Ramseur did not submit, any new data for this permitting process. As discussed in prior comments, without adequate disclosure of PFAS and 1,4- dioxane, DEQ cannot authorize Ramseur to discharge the chemicals and any discharge of them is unlawful.4 2. Monitoring for PFAS cannot wait for EPA to publish a final wastewater method. While citing a lack of data for its failure to limit PFAS in Ramseur's discharge, DEQ delays any monitoring of the chemicals until EPA publishes a final PFAS method for wastewater in the Federal Register. But the lack of a final, EPA -approved method cannot be a barrier for controlling PFAS discharges. When there is no approved analytical method, the Clean Water Act states that permit applicants "may use any suitable method but must provide a description of the method."5 PFAS testing methods have proliferated in recent years. In addition to targeted methods for potable and non -potable waters, commercial labs offer testing of up to 75 PFAS.6 The Total Oxidizable Precursor (TOP) Assay and Total Organic Fluorine methods can provide valuable information on PFAS discharges that targeted methods cannot provide. Recent experience of states, municipalities, and non -governmental organizations demonstrate the ability to test for PFAS. Many states, including North Carolina, have issued draft or final permits that require contemplation of the permitting authority during the permit application process, whether spills or otherwise, do not come within the protection of the permit shield."). 3 Ulrika Eriksson, et al., Contribution of precursor compounds to the release of per- and polyfluoroalkyl substances (PFASs) from waste water treatment plants (WWTPs), 61 J. ENVIRON. SCI.80 (2017); see also Mich. Dep't of Env't, Great Lakes, and Energy, Summary Report: Initiatives to Evaluate the Presence of PFAS in Municipal Wastewater and Associated Residuals (Sludge/Biosolids) in Michigan, at 9-10, https://perma.cc/C2Z8-DT99. 4 Letter from Southern Environmental Law Center, to Gary Perlmutter, NC DEQ, Southern Environmental Law Center Comments on NPDES Wastewater Permit NC0026565 — Ramseur WWTP (Dec. 17, 2021) (Attachment 1); see also In re Ketchikan Pulp Co., 7 E.A.D. 605 (EPA) (1998); Piney Run, 268 F.3d. 255 (2001); Southern Appalachian Mountain Stewards v. A & G Coal Corp., 758 F.3d 560 (4th Cir. 2014). 5 40 C.F.R. § 122.21(g)(7)(i). 6 PFAS Testing, EUROFINS, https://www.eurofinsus.com/environment-testing/pfas-testing/ (last updated Oct. 18, 2021). 2 entities to control PFAS and submit discharge monitoring reports to demonstrate compliance. Municipalities and utilities have tested for PFAS in wastewater and intake water,8 as well as treated drinking water.9 NGOs have tested wastewater and surface waters for dozens of PFAS.1° This experience demonstrates that dischargers like Ramseur can detect a wide variety of PFAS through broadly available and relatively inexpensive testing. 3. Ramseur should use its pretreatment authority to control any industrial sources. Sampling conducted in 2019 found that the influent to Ramseur's wastewater treatment plant has contained PFAS concentrations above 499 parts per trillion.11 But the draft permit only requires monitoring for 1,4-dioxane and PFAS and therefore does nothing to control such discharges or protect downstream communities. EPA's PFAS Strategic Roadmap affirmed that "existing NPDES authorities" can be used to "reduce discharges of PFAS at the source."12 The same applies for 1,4-dioxane. EPA plans to use such existing authorities to "require pretreatment programs to include source control" in order "to protect wastewater treatment plant discharges and biosolid applications."13 Given that North Carolina continues to suffer from a drinking water crisis caused by Chemours, DEQ should immediately begin requiring municipalities like Ramseur to use existing NPDES authorities to prevent industrial discharges of PFAS and 1,4- dioxane. Using existing authority is the only way that Ramseur and other municipalities can protect communities downstream and avoid violating the Clean Water Act's prohibitions on pass through and interference. As the EPA previewed in its Roadmap, PFAS can harm or interfere with wastewater treatment plant discharges and biosolid applications, and it is essential to control 7 N.C. Dep't of Envt. Quality, The Chemours Company FC, LLC, NPDES Permit NC0089915 (Sept. 18, 2020), https://deq.nc.gov/media/16999/download; Colo. Dep't of Public Health and the Envt. Suncor Energy (USA) Inc., Draft Permit C00001147 (Nov. 12, 2021), https://drive.google.com/drive/folders/1g5A3sQ_zkpGOdkwblyTspRht8HfJ -F; Pennsylvania Dep't of Envt. Protection, Horsham Air Guard Station, NPDES Permit No. PA0245046 (Oct. 2020), https://files. dep. state.pa.us/Water/Wastewater%20Management/eDMRPortalFiles/Permits/PA0245046_NPDES_PE RMIT_20210323_Final_V 2.pdf. 8 PFAS/1,4-dioxane Information, CITY OF BURLINGTON, N.C., https://www.burlingtonnc.gov/2121/PFAS14- DIOXANE-INFORMATION (last visited Feb. 16, 2022); MICHIGAN DEP'T OF ENV'T, GREAT LAKES, AND ENERGY, SUMMARY REPORT: INITIATIVES TO EVALUATE THE PRESENCE OF PFAS IN MUNICIPAL WASTEWATER AND ASSOCIATED RESIDUALS (SLUDGE/BIOSOLIDS) IN MICHIGAN (2020), https://www.michigan.gov/documents/egle/wrd-pfas-initiatives 691391_7.pdf. 9 Latest PFAS Test Results, CAPE FEAR PUB. UTIL. AUTH., https://www.cfpua.org/779/Latest-PFAS-Test-Results (last visited Feb. 16, 2022); Drinking Water Resources: Public Water System PFAS Information and Resources, CALIFORNIA STATE WATER RES. CONTROL BD., https://www.waterboards.ca.gov/pfas/drinking_water.html (last updated Dec. 20, 2021). 10 Letter from Southern Environmental Law Center, to City of Burlington, on Notice of Intent to Sue the City of Burlington for Violations of the Clean Water Act and the Resource Conservation and Recovery Act at 9-25 (Nov. 7, 2019), https://www.southernenvironment.org/wp-content/uploads/legacy/words_docs/2019_11_07_- Notice_of Intent_-_City_of Burlington_.pdf. 11 2019 Sampling Data — Ramseur WWTP (Attachment 2). 12 EPA, PFAS Strategic Roadmap: EPA's Commitments to Action 2021-2024 at 14, https://perma.cc/LK4U-RLBH. 13 Id. 3 industrial discharges "to protect" plant discharges and biosolid management systems,14 and therefore, to prevent interference.15 Municipalities like Ramseur have the tools to prohibit PFAS and 1,4-dioxane discharges from being introduced into publicly owned treatment works ("POTWs") like Ramseur's.16 First, the Clean Water Act pretreatment program allows municipalities to promptly identify any dischargers, and it puts the burden on industries to produce information about their discharges. As EPA has recognized, industrial users are "in a better position than the POTW to know what pollutants are currently being discharged and are most likely to be discharged in the future."17 The permitting process requires requiring industrial users to identify their pollutants in an industrial waste survey,'$ and when applying for a pretreatment permit, to disclose "effluent data," including on internal wastestreams when necessary to evaluate pollution controls.'9 Significant industrial users are further required to provide information "[p]rincipal products and raw materials ... that affect or contribute to the [significant industrial user's] discharge."20 Ramseur's POTW has one significant industrial user. If that discharger is responsible for PFAS or 1,4-dioxane in the POTW's influent, then it must be held accountable for its pollution —preventing contamination of sludge and effluent. At the very least, that industry should be required to conduct sampling of its waste stream to determine if it is a source of these chemicals into Ramseur's treatment plant. Once Ramseur identifies any industrial sources of PFAS or 1,4-dioxane, the Clean Water Act also gives the town the tools to control those sources. For instance, POTWs can establish local limits for PFAS or 1,4-dioxane.21 POTWs also have discretion to set permit limits for industrial users through a case -by -case analysis "based on the discharger's current loading, its need for a continued loading allocation, its ability to apply pretreatment to achieve certain discharge pollutant levels (i.e. treatability), or any other factor that the POTW determines is relevant."22 Controls can go beyond pretreatment permit limits and "may contain but need not be limited to" conditions including "[r]equirements for the installation of pretreatment technology, pollution control, or construction of appropriate containment devices designed to reduce, eliminate, or prevent the introduction of pollutants into the treatment works."23 Ramseur should 14 Id. 15 Interference occurs when a discharge disrupts POTW operation or sludge use or disposal and violates the facility's NPDES permit or other applicable laws. 40 C.F.R. § 403.3(k). 16 See EPA, INDUSTRIAL USER PERMITTING GUIDANCE MANUAL at 3-1 to 3-2 (2012), https://www.epa.gov/sites/default/files/2015-10/documents/industrial_user_permitting_ manual_full.pdf (describing requirements for pretreatment program, including "Authority to regulate all Industrial Users contributing wastewater to the POTW."). 17 Id. 18 EPA, INTRODUCTION TO THE NATIONAL PRETREATMENT PROGRAM at 4-3 (2011), https://www.evansvillegov.org/egov/documents/1499266949_62063.pdf. 19 INDUSTRIAL USER PERMITTING GUIDANCE MANUAL, supra note 16 at 4-2 to 4-3. 20 40 CFR § 122.21(j)(6)(ii)(C). 21 See EPA, LOCAL LIMITS DEVELOPMENT GUIDANCE at 5-11 to 5-21 (2004), https://www3.epa.gov/npdes/pubs/final_locallimits_guidance.pdf. 22 Id. at 6-12. 23 EPA OFFICE OF WASTEWATER MGT., EPA MODEL PRETREATMENT ORDINANCE at 24 (2007), https://www3.epa.gov/npdes/pubs/pretreatment_model_suo.pdf. 4 use these tools here to stop any industrial sources of PFAS or 1,4-dioxane from entering the POTW. In addition, as discussed in our prior comment letter, the Clean Water Act requires that DEQ consider limits on PFAS and 1,4-dioxane in all NPDES permits.24 By declining to require more of the permittee, DEQ continues to put the burden of PFAS and 1,4-dioxane pollution on downstream communities. The status quo —a watershed contaminated by PFAS and 1,4- dioxane—is unacceptable and DEQ must use its existing authority to address all sources of these toxic chemicals. Given that these chemicals are toxic at such low levels and communities have been exposed to them for decades, waiting for future permit cycles to fulfill permitting requirements —and to control pollution at the source —fails to provide the necessary protection. Thank you for considering these comments. Please contact me at 919-967-1450 or jzhuang@selcnc.org if you have any questions regarding this letter. Sincerely, Jean Zhuang -...1)04 lZ tvo---- Geoff Gisler SOUTHERN ENVIRONMENTAL LAW CENTER 601 W. Rosemary Street, Suite 220 Chapel Hill, NC 27516 919-967-1450 24 See Letter from Southern Environmental Law Center, to Gary Perlmutter, NC DEQ, supra note 4 (Attachment 1). 5 ATTACHMENT 1 SOUTHERN ENV RONMENTAL CENTER Via U.S. e-mail Gary Perlmutter NCDEQ/DWR/NPDES Water Quality Permitting Section 1617 Mail Service Center Raleigh, NC 27699-1617 gary.perlmutter@ncdenr.gov 601 West Rosemary Street, Suite 220 Telephone 919-967-1450 Chapel Hill, NC 27516 Facsimile 919-929-9421 December 17, 2021 RE: Southern Environmental Law Center Comments on NPDES Wastewater Permit NC0026565 — Ramseur WWTP Dear Mr. Perlmutter: The Southern Environmental Law Center offers the following comments on Draft National Pollutant Discharge Elimination System ("NPDES") Permit NC0026565, issued by the North Carolina Department of Environmental Quality ("DEQ") to the Town of Ramseur. The permit allows Ramseur to discharge wastewater likely contaminated with per- and polyfluoroalkyl substances, or PFAS, from its wastewater treatment plant ("WWTP") into downstream drinking water supplies in the Cape Fear River basin. Communities in Sanford, Harnett, Dunn, and Fayetteville are downstream of the treatment plant and their drinking water supplies have previously contained PFAS,1 which are known to harm human health. Based on previous sampling, Ramseur's discharge almost certainly contains PFAS. The town did not, however, disclose its discharge of PFAS in its permit application, and DEQ did not evaluate limits for the chemicals in its draft permit, as required by the Clean Water Act and state laws. Because Ramseur did not disclose its PFAS discharges in its application, any permit issued by the agency will necessarily prohibit all discharges of the chemicals. DEQ has the authority to issue a permit that allows discharges, but it cannot do so by ignoring what pollutants are in the discharge. DEQ, therefore, must require disclosure of PFAS and include necessary limits in the town's permit. EPA's PFAS Strategic Roadmap recently affirmed that "existing NPDES authorities" can be used to "reduce discharges of PFAS at the source."2 EPA's plan further confirms that the Clean Water Act pretreatment program can be used to control sources of PFAS, and the agency plans to "require pretreatment programs to include source control."3 North Carolina has already 1 EPA, Occurrence Data for the Unregulated Contaminant Monitoring Rule (UCMR) 3, https://perma.cc/2EXD- AKPQ. 2 EPA, PFAS Strategic Roadmap: EPA's Commitments to Action 2021-2024 at 14, https://perma.cc/LK4U-RLBH. 3 Id. Charlottesville Chapel Hill Atlanta Asheville Birmingham Charleston Nashville Richmond Washington, DC faced a PFAS drinking water crisis. Because communities continue to suffer from exposure to these chemicals, DEQ must act now to stop PFAS from entering our rivers, streams, and drinking water supplies. The need for action is most urgent in the Cape Fear River, where sources upstream from Chemours, such as Ramseur, are significant contributors to PFAS contamination. For each permit issued for facilities that discharge PFAS, DEQ must use its existing authority under the Clean Water Act to require disclosure and evaluate limits. Similarly, previous sampling has indicated that Ramseur's discharge likely contains 1,4- dioxane, another toxic chemical. Ramseur also did not disclose whether it discharges 1,4-dioxane and DEQ did not evaluate limits for the chemical in its draft permit. Instead, the draft permit includes a monthly monitoring requirement for the toxic chemical. Monitoring is not a substitute for the mandatory permitting process that DEQ must conduct. In order to comply with the Clean Water Act, DEQ should withdraw this draft permit, return Ramseur's application, and re -start the permitting process after the town makes the necessary disclosures. A. The Ramseur WWTP discharges toxic PFAS. Sampling conducted in 2019 reveals that the influent to Ramseur's WWTP has contained PFAS concentrations above 499 parts per trillion ("ppt").4 Because the treatment plant is not equipped to remove PFAS, it is almost certain that Ramseur is releasing PFAS into the Cape Fear River basin, a source of drinking water for nearly one million North Carolinians. It is also likely that the influent data is an underestimate of how much PFAS the town is releasing in its wastewater discharge. PFAS sampling conducted at WWTPs often find that concentrations of PFAS increase from the influent to the effluent because treatment plant influent often contains PFAS precursors that cannot be found using certain analytical methods. As studies have found, there can be a "substantial increase" in specific PFAS after wastewater treatment, and that the "degradation of precursor compounds is a significant contributor to PFAS contamination in the environment."5 PFAS are a serious threat to human health and the environment. Two of the most commonly studied PFAS—perfluorooctanoic acid ("PFOA") and perfluorooctane sulfonate ("PFOS")—have been found to cause developmental effects to fetuses and infants, kidney and testicular cancer, liver malfunction, hypothyroidism, high cholesterol, ulcerative colitis, lower birth weight and size, obesity, decreased immune response to vaccines, reduced hormone levels, and delayed puberty.6 In 2016, EPA established a lifetime health advisory of 70 ppt for the 4 2019 Sampling Data — Ramseur WWTP (Attachment 1). 5 Ulrika Eriksson, et al., Contribution of precursor compounds to the release of per- and polyfluoroalkyl substances (PFASs) from waste water treatment plants (WWTPs), 61 J. ENvIRoN. SCI.80-90 (2017); see also Mich. Dep't of Env't, Great Lakes, and Energy, Summary Report: Initiatives to Evaluate the Presence of PFAS in Municipal Wastewater and Associated Residuals (Sludge/Biosolids) in Michigan, at 9-10, https://perma.cc/C2Z8-DT99. 6 Arlene Blum et al., The Madrid Statement on Poly- and Perfluoroalkyl Substances (PFASs), 123 ENVTL. HEALTH PERSPECTIVES 5, A 107 (2015); U.S. EPA, Fact Sheet: PFOA & PFOS Drinking Water Health Advisories, at 2, https://perma.cc/CX95-N67K. combined concentrations of PFOA and PFOS in drinking water. EPA has since updated toxicity assessments for the chemicals, suggesting that the health values for the chemicals should be magnitudes lower. The updated toxicity assessments would translate to health advisories of .006 ppt for PFOA and .029 ppt for PFOS.8 Epidemiological studies show that other PFAS similarly harm human health at low levels.9 Given that PFAS concentrations less than 1 ppt can be harmful to human health, DEQ cannot ignore sampling data showing that Ramseur may be discharging PFAS at 499 ppt, or even higher. B. The Ramseur WWTP likely discharges 1,4-dioxane, another toxic chemical. Sampling at the Ramseur WWTP from 2019 also found 1,4-dioxane in the treatment plant's influent.10 Because the treatment plant is also not equipped to remove 1,4-dioxane, it is likely that Ramseur is releasing the chemical in its wastewater. 1,4-dioxane is a clear, man-made chemical that is a byproduct of many industrial processes.11 The chemical is toxic to humans, causing liver and kidney damage.12 As a result of the harms caused by 1,4-dioxane, EPA established a drinking water health advisory with an associated lifetime cancer risk of one -in - one -million at a concentration of 0.35 parts per billion ("ppb"),13 and North Carolina's rules prohibit the release of 1,4-dioxane that would cause or contribute to an exceedance of 0.35 ppb in water supply waters.14 C. DEQ must require Ramseur to disclose any PFAS or 1,4-dioxane that the town is discharging from its treatment plant. The Clean Water Act prohibits the discharge of any pollutant without a NPDES permit. The discharge of a specific pollutant (or group of pollutants) cannot be permitted if it is not disclosed in a NPDES permit application. Therefore, Ramseur is required to disclose any discharges of PFAS or 1,4-dioxane in its permit application —as DEQ recognized in its 2017 enforcement action against Chemours. 7 EPA, Fact Sheet: PFOA & PFOS Drinking Water Health Advisories at 2. 8 Garret Ellison, No safe PFAS exposure level? EPA toxicity drafts point that way, MLIVE, Nov. 20, 2021, https://perma.cc/S7GW-DUCA. 9 EPA, Human Health Toxicity Values for Hexafluoropropylene Oxide (HFPO) Dimer Acid and Its Ammonium Salt (CASRN 13252-13-6 and CASRN 62037-80-3) (2021), https://perma.cc/FG6A-TXQ9. 10 2019 Sampling Data — Ramseur WWTP (Attachment 1). 11 EPA, Technical Fact Sheet—1,4-Dioxane, at 1-2 (2017), https://perma.cc/NM9K-2P84 ("EPA 1,4-dioxane fact sheet"). 12Id.; EPA, Integrated Risk Information System, Chemical Assessment Summary: 1,4-dioxane at 2, https://perma.cc/B2A2-R4M5. 13 EPA, 2018 Edition of the Drinking Water Standards and Health Advisories, at 4 (2018), https://perma.cc/N8N4- BA3R; N.C. Div. of Water Res., I,4-dioxane Monitoring in the Cape Fear River Basin of North Carolina: An Ongoing Screening, Source Identification, and Abatement Verification Study, at 2 (2017), https://perma.cc/7MMR- B9SQ. 14 Frequently Asked Questions (FAQ), Special Order by Consent (SOC) for the City of Greensboro T.Z. Osborne WWTP, https://perma.cc/E8YY-8YFV (interpreting 15A N.C. Admin Code 2B.0208). If a NPDES permit applicant does not adequately disclose its release of a pollutant, the applicant does not have approval to discharge the pollutant.15 Disclosure is considered adequate when the applicant provides enough information for a permitting agency to "be[] able to judge whether the discharge of a particular pollutant constitutes a significant threat to the environment."16 To meet this burden, an applicant must include all relevant information, including the concentration, volume, and frequency of the discharge.17 The Clean Water Act places the burden of disclosure on the permit applicant because they are in the best position to know what is in their discharge.'$ The EPA has stressed the need for disclosure of pollutants during the permitting process: [D]ischargers have a duty to be aware of any significant pollutant levels in their discharge. [...] Most important, [the disclosure requirements] provide the information which the permit writers need to determine what pollutants are likely to be discharged in significant amounts and to set appropriate permit limits. [...] [P]ermit writers need to know what pollutants are present in an effluent to determine approval permit limits in the absence of applicable effluent guidelines.' 9 The EPA Environmental Appeals Board's decision in In re: Ketchikan Pulp Company further emphasized the importance of disclosure,20 and this decision has been adopted by the Fourth Circuit. In Piney Run Pres. Ass 'n v. Cty. Comm 'rs of Carroll Cty., Maryland, the Fourth Circuit stated: The Ketchikan decision therefore made clear that a permit holder is in compliance with the [Clean Water Act] even if it discharges pollutants that are not listed in its permit, as long as it only discharges pollutants that have been adequately disclosed to the permitting authority. [...] To the extent that a permit holder discharges a pollutant that it did not disclose, it violates the NPDES permit and the [Clean Water Act].2' 15 See In re Ketchikan Pulp Co., 7 E.A.D. 605 (EPA) (1998); Piney Run Pres. Ass 'n v. Cty. Comm'rs of Carroll Cty., Maryland, 268 F.3d. 255 (4th Cir. 2001); Southern Appalachian Mountain Stewards v. A & G Coal Corp., 758 F.3d 560 (4th Cir. 2014). 16 Piney Run, 268 F.3d at 268 ("Because the permitting scheme is dependent on the permitting authority being able to judge whether the discharge of a particular pollutant constitutes a significant threat to the environment, discharges not within the reasonable contemplation of the permitting authority during the permit application process, whether spills or otherwise, do not come within the protection of the permit shield."). 17 See In re Ketchikan Pulp Co., 7 E.A.D. 605 ("In explaining the provisions of 40 C.F.R. § 122.53(d)(7)(iii), which required dischargers to submit quantitative data relating to certain conventional and nonconventional pollutants that dischargers know or have reason to believe are present in their effluent, the [EPA] stated: `permit writers need to know what pollutants are present in an effluent to determine appropriate limits in the absence of effluent guidelines.'"). 18 S. Appalachian Mountain Stewards, 758 F.3d at 566. 19 Consolidated Permit Application Forms for EPA Programs, 45 Fed. Reg. 33,526-31 (May 19, 1980). 20 See In re Ketchikan Pulp Co., 7 E.A.D. 605. 21 Piney Run, 268 F.3d. at 268 (emphasis added). Moreover, municipalities that own and operate wastewater treatment plants are required to "fully and effectively exercise[] and implement[]" their authority to "[i]dentify the character and volume of pollutants contributed to the [publicly owned treatment works]" by Industrial Users.22 DEQ has acknowledged that disclosure of toxic pollutants, including PFAS, is required by the Clean Water Act and state water quality laws. In its enforcement action against The Chemours Company, LLC for the company's discharge of GenX and other PFAS into the Cape Fear River, the agency stated: Part of the permit applicant's burden in this regard is to disclose all relevant information, such as the presence of known constituents in a discharge that pose a potential risk to human health. The permit applicant is required to disclose "all known toxic components that can be reasonably expected to be in the discharge, including but not limited to those contained in a priority pollutant analysis." 15A N.C.A.C. 2H .0105(j) (emphasis added). [...] These disclosure obligations are critical, in part, because they define the scope of the Clean Water Act's "permit shield." While compliance with the express terms of an NPDES permit generally "shields" the permittee from liability for violations of 33 U.S.C. § 1311, the permit does not shield the permittee from liability where the pollutant being discharged was not within the "reasonable contemplation" of the permitting agency when it issued the permit due to nondisclosure by the permittee.23 The agency further acknowledged that the company had violated its NPDES permit and state water quality laws by "failing to fully disclose all known toxic components reasonably expected to be in [the company's] discharge."24 DEQ's position in the Chemours enforcement case was correct and should be applied to Ramseur in this permit renewal. Ramseur likely discharges PFAS and 1,4-dioxane, and the town was required to disclose the pollutant in its permit application so that DEQ can "judge whether the discharge" "constitutes a significant threat to the environment."25 Because Ramseur failed to do so,26 DEQ does not have the information it needs to make an informed decision on the town's application.27 DEQ must require Ramseur to disclose any discharge of PFAS or 1,4-dioxane in the town's permit application before moving forward with the draft permit. 22 40 C.F.R. § 403.8(f)(1)(vi)(B). 23 Amended Complaint, N.C. Dept. of Environmental Quality v. Chemours, 17 CVS 580, 67 (N.C. Super. 2018) (citing 33 U.S.C. § 1342(k), Piney Run Pres. Ass v. Cty. Comm 'rs of Carroll Cty., MD, 268 F.3d 255, 265 (4th Cir. 2001)). 24 Id. at 33. 25 Piney Run, 268 F.3d at 268. 26 See Town of Ramseur, Permit Renewal, Application No. NC0026565, Nov. 10, 2020. 27 See S. Appalachian Mountain Stewards, 758 F.3d at 566 ("[T]he CWA and its implementing regulations focus on the information that the permit applicant must gather and provide to the permitting agency, so that it can make a fully informed decision to issue the requested permit."). In addition, DEQ's mandated monitoring for 1,4-dioxane does not absolve Ramseur's obligation to disclose its 1,4-dioxane discharge in its application. Without disclosure during the application process, the agency cannot evaluate the discharge for compliance with permitting requirements and the public does not have sufficient information to meaningfully review and comment on the draft permit. Because public notice and informed participation are mandated by law,28 monitoring reports sent only to the agency after the permit has been issued cannot be considered adequate disclosure. D. DEQ must analyze appropriate effluent limits for PFAS and 1,4-dioxane in Ramseur's NPDES permit. Because Ramseur is likely discharging PFAS and 1,4-dioxane, DEQ must consider appropriate permit limits for these chemicals. Ramseur can then comply with any limits in its permit by properly regulating its industries —for instance, by requiring industries to use alternative chemicals, or to install treatment technology to remove pollutants from their wastewater before sending it to the town's treatment plant. The Clean Water Act requires permitting agencies to, at the very least, incorporate, technology -based effluent limitations on the discharge of pollutants.29 North Carolina water quality laws further state that municipalities must be treated like an industrial discharger if an industry "significantly impact[s]" a municipal treatment system.30 In this situation, the agency must consider technology -based effluent limits for the municipality, even if effluent limits and guidelines have not been published and adopted. Effective treatment technologies for PFAS and 1,4-dioxane are available. A granular activated carbon treatment system has been used at Chemours' facility to reduce PFAS as high as 345,000 ppt from a creek contaminated by groundwater beneath the facility to nearly nondetectable concentrations.31 Similarly, 1,4-dioxane can be removed using advanced oxidation processes, such as using ultraviolet light in combination with hydrogen peroxide.32 Such a process has been used at the Tucson International Airport Area Superfund Site to remove legacy 1,4-dioxane contamination.33 DEQ must consider the feasibility of Ramseur's industries installing similarly effective treatment technologies. 28 40 C.F.R. § 124.10 (a); 15A N.C. Admin. Code 2H.0109(a). 29 40 C.F.R. § 125.3(a); see also 33 U.S.C. § 1311. 3° 15A N.C. Admin Code 02B .0406 (a), (e). 31 Ted Schoenberg, Parsons, Old Outfall 002 GAC Pilot Study Interim Results Report, Chemours Fayetteville, North Carolina Facility, 4-5 (Aug. 5, 2019), https://perma.cc/DU3Y-25AW; Parsons, Old Outfall 002 Surface Water Sampling Results (Sept. 30, 2019) at Table 1, https://perma.cc/6BYQ-RNXZ. 32 Amie C. McElroy, et al., 1,4-Dioxane in drinking water: emerging for 40 years and still unregulated, 7 CURRENT OPINION IN ENv'T SCIENCE & HEALTH 117, 119 (2019), https://perma.cc/P8L3-CC5G. 33 See Advanced Treatment for 1,4-Dioxane — Tucson Removes Contamination Through UV -oxidation, TROJANUV CASESTUDIES (2019), https://perma.cc/Z95X-D6A5; see also Educational Brochure, TUCSON AIRPORT AREA REMEDIATION PROJECT, https://perma.cc/XUH8-W4DZ. If these limits are not enough to ensure compliance with water quality standards, then water quality -based effluent limits must be included in the town's permit.34 PFAS are known to harm human health, and their discharge threatens to violate multiple water quality standards, including the state toxic substances standard.35 DEQ itself has stated in its lawsuit against Chemours that PFAS "meet the definition of `toxic substance' under North Carolina rules.36 DEQ has also applied the toxic substances standard to 1,4-dioxane, interpreting the standard to require concentrations of 1,4-dioxane be less than 0.35 ppb in rivers and streams that serve as drinking water supplies.37 In order to comply with the Clean Water Act, therefore, DEQ must limit Ramseur's discharge so that it will not cause, or contribute to concentrations of 1,4-dioxane exceeding 0.35 ppb in any downstream drinking water supplies.38 Once appropriate limits are included in a Ramseur's NPDES permit, the town must regulate its industries so that industries do not cause the treatment plant to violate its own NPDES permit.39 This is how the Clean Water Act "assures the public that [industrial] dischargers cannot contravene the [Clean Water Act's] objectives of eliminating or at least minimizing discharges of toxic and other pollutants simply by discharging indirectly through [wastewater treatment plants] rather than directly to receiving waters."40 As is appropriate, the pretreatment program is intended to place the burden of treating polluted discharges on the entity that creates the pollution, rather than on the taxpayers that support municipally owned treatment plants. Moreover, municipalities like Ramseur that own and operate wastewater treatment plants are required to "immediately and effectively to halt or prevent any discharge of pollutants to the [publicly owned treatment works] which reasonably appears to present an imminent endangerment to the health or welfare of persons."41 Together, these laws ensure that such municipally owned treatment plants do not become dumping grounds for uncontrolled industrial waste. Ramseur, therefore, cannot allow industries to cause its treatment plant to violate the town's own NPDES permit.42 Ramseur could prevent violations of its permit by requiring industries to use alternative chemicals, or to install treatment technology to remove PFAS or 1,4- 34 15A N.C. Admin. Code 2H.0112(c) (stating that DWR must "reasonably ensure compliance with applicable water quality standards and regulations."); see 33 U.S.C. § 1311(b)(1)(c) (requiring that permit limits be established as necessary to comply with water quality standards). 35 15A N.C. Admin. Code 2B.0208(a). 36 Amended Complaint, N.C. Dept. of Environmental Quality v. Chemours, 17 CVS 580, 32 (N.C. Super. 2018) (stating that "the process wastewater from [Chemours'] Fluoromonomers/Nafion® Membrane Manufacturing Area contains and has contained substances or combinations of substances which meet the definition of "toxic substance" set forth in 15A N.C.A.C. 2B .0202," referring to GenX and other PFAS). 37 N.C. Div. of Water Res., I, 4-dioxane Monitoring in the Cape Fear River Basin of North Carolina: An Ongoing Screening, Source Identification, and Abatement Verification Study, at 2 (2017), https://perma.cc/3RK6-8T4D. 38 40 C.F.R. § 122.44(d)(1)(i); see also 15A N.C. Admin. Code 2B.0203 ("Water quality based effluent limitations and management practices for direct or indirect discharges of waste or for other sources of water pollution shall be developed by the Division such that the water quality standards and best usage of receiving waters and all downstream waters will not be impaired."). 39 40 C.F.R. § 403.8(f)(1). 40 General Pretreatment Regulations for Existing and New Sources, 52 Fed. Reg. 1586, 1590 (Jan. 14, 1987) (codified at 40 C.F.R. § 403). 41 40 C.F.R. § 403.8(f)(2)(ii). 42 Id. § 403.8(f)(1). dioxane from their wastewater before sending wastewater to the town's treatment plant. In Michigan, for instance, municipalities have been effectively reducing their PFAS discharges by requiring industrial users to install treatment technology. Municipalities in Michigan had discovered that industries, such as metal finishers, paper manufacturers, and fabric/leather treaters, were sending PFAS-contaminated wastewater to their treatment plants.43 After industrial users installed treatment systems to remove PFAS, PFOS levels in the discharges of several treatment plants were reduced by up to 99 percent.44 By including appropriate limits in Ramseur's NPDES permit (as well as permits for other municipalities), DEQ can put the burden of cleaning up toxic pollution on the industries that create it. In summary, DEQ must require Ramseur to disclose any discharges of PFAS or 1,4- dioxane in its permit application so that DEQ and the public have adequate information to evaluate the discharge. If the town does not make that disclosure, any discharge of these chemicals is illegal and subject to agency or citizen enforcement. DEQ must then evaluate available treatment technologies and impose necessary limits. Because the draft permit fails to meet these requirements, it should be withdrawn. Thank you for considering these comments. Please contact me at 919-967-1450 or jzhuang@selcnc.org if you have any questions regarding this letter. Sincerely, e5'----a Jean Zhuang SOUTHERN ENVIRONMENTAL LAW CENTER 601 W. Rosemary Street, Suite 220 Chapel Hill, NC 27516 919-967-1450 43 Michigan.gov, Michigan PFAS Action Response Team, Wastewater Treatment Plants/Industrial Pretreatment Program, https://perma.cc/2AZ7-ASHH. 44 Id. ATTACHMENT 2 POTW Name: Town of Ramseur WWTP NPDES #: NC0026565 Influent Grab (ng/L) CAS Number Analyte Name Acronym 7/8/2019 Lab Qualifer(s) 8/6/2019 Lab Qualifer(s) 9/4/2019 Lab Qualifer(s) 375-22-4 Perfluorobutanoic acid PFBA ND U (<0.311) ND U (<1.25) ND U (<1.24) 375-73-5 Perfluorobutanesulfonic acid PFBS ND U (<0.311) 344 ND U (<1.24) 335-77-3 Perfluorodecanesulfonic acid PFDS ND U (<0.311) ND U (<1.25) ND U (<1.24) 335-76-2 Perfluorodecanoic acid PFDA 0.586 ND U (<1.25) ND U (<1.24) 307-55-1 Perfluorododecanoic acid PFDoA ND U (<0.311) ND U (<1.25) ND U (<1.24) 375-92-8 Perfluoroheptanesulfonic acid PFHpS ND U (<0.311) ND U (<1.25) ND U (<1.24) 375-85-9 Perfluoroheptanoic acid PFHpA 1.24 ND U (<1.25) ND U (<1.24) 355-46-4 Perfluorohexanesulfonic acid PFHxS ND U (<0.311) ND U (<1.25) ND U (<1.24) 307-24-4 Perfluorohexanoic acid PFHxA 6.97 4.77 4.64 68259-12-1 Perfluorononanesulfonic acid PFNS ND U (<0.31) ND U (<1.25) ND U (<1.24) 375-95-1 Perfluorononanoic acid PFNA 0.782 ND U (<1.25) ND U (<1.24) 754-91-6 Perfluorooctanesulfonamide PFOSA ND U (<0.316) ND U (<1.25) ND U (<1.24) 2991-50-6 2-(N-Ethylperfluorooctanesulfonamido) acetic acid N-EtFOSAA ND U (<0.311) ND U (<1.25) ND U (<1.24) 2355-31-9 2-(N-Methylperfluorooctanesulfonamido) acetic acid N-MeFOSAA ND U (<0.311) ND U (<1.25) ND U (<1.24) 2706-91-4 Perfluoropentanesulfonic acid PFPeS ND U (<0.311) ND U (<1.25) ND U (<1.24) 2706-90-3 Perfluoropentanoic acid PFPeA 41.8 103 313 376-06-7 Perfluorotetradecanoic acid PFTeA (PFTA) 0.761 ND U (<1.25) ND U (<1.24) 72629-94-8 Perfluorotridecanoic acid PFTriA (PFTrA) ND U (<0.311) ND U (<1.25) ND U (<1.24) 2058-94-8 Perfluoroundecanoic acid PFUnA ND U (<0.311) ND U (<1.25) ND U (<1.24) 62037-80-3 Gen-X HFPO-DA ND U (<10.90) ND U (<43.9) ND U (<43.3) 757124-72-4 4:2 Fluorotelomer sulfonate 4:2 FTS ND U (<0.311) ND U (<1.25) ND U (<1.24) 27619-97-2 6:2 Fluorotelomer sulfonate 6:2 FTS ND U (<0.311) ND U (<1.25) ND U (<1.24) 39108-34-4 8:2 Fluorotelomer sulfonate 8:2 FTS ND U (<0.311) ND U (<1.25) ND U (<1.24) 335-67-1 Perfluorooctanoic acid PFOA 2.93 2 1.96 1763-23-1 Perfluorooctanesulfonic acid PFOS 6.52 45.7 8.06 Sum of PFOA and PFOS 9.45 47.7 10.02 Total PFAS 61.589 499.47 327.66 Influent Grab ug/L) 7/8/2019 Lab Qualifer(s) 8/6/2019 Lab Qualifer(s) 9/4/2019 Lab Qualifer(s) 1, 4 - Dioxane ND U (<1.0) 2 2.08 Lab Qualifiers ND - Analyte concentration is not detected above the detection limit. B - Analyte found in the sample and associated method blank. J - The reported value is an estimate. The value is less than the Reporting Limit. U - The sample was not detected in the sample at the Reporting Limit.