NC0004952_Wasteload Allocation_19900730

/WOES DOCIMENT SCANNINC COVER SHEET
NPDES Permit:
NC0004952
Celanese Shelby Facility
Document Type:
Permit Issuance
•
,
Wasteload Allocation')
Authorization to Construct (AtC)
Permit Modification
Complete File - Historical
Engineering Alternatives (EAA)
Correspondence
Owner Name Change
Instream Assessment (67b)
Speculative Limits
Environmental Assessment (EA)
Document Date:
July 30, 1990
Thies cloctiutxterat ion prim-ted cork retiose paperr — igrkw-e xicy
content cm. the 'e're taidle

_
it ri -4;
PERMIT NO,: NC0004,45z
FACILITY NAME: I-bech5f - Ce,10.1)Por
Facility Status:
Permit Status:
Major
"Wenehv
Pipe No.: Op
Minor
Design Capacity:
0,&5
NPDES WASTE LOAD ALLOCATION
Domestic (% of Flow): /9 Yo
Industrial (% of Flow): g Tt.
Comments:
7k5 G4h9f=844Z/ Ar717 rePre0C/76 Chany) /Yr/it. ib 4V/9
5kge 6/411 z
RECEIVING STREAM: air -alb (Yee,
Class: C
Sub -Basin: - Oapg-O
Reference USGS Quad: 6/2AX
County: Ciev'efaid
Regional Office: ARO
Requested by: R eartra
Prepared by:
Reviewed by:
1,)0
b3( 6- L._
(please attach)
Date:
Date: 17
Date: /
Drainage Area (mi2 )
Modeler
Date Rec.
cj
k54
9/11/51
ortat3v4Le-T
Avg. Streamflow (cfs):
7Q10 (cfs) 20 Winter 7Q10 (cfs)
4,i(p 30Q2 (cfs)
sita tonal
2/Li
Toxicity Limits: rwc Acute/Chronic
Instream Monitoring:
Parameters
Upstream Location
Downstream Location
Effluent
Characteristics
/-10 . 4 Vc5 _
Dy . Ho
3o,4_-z (Jbid)
R5S
212. 2
Ta5 (OH)
16 2 . 0
315. 0
Gee at/ached
fry acIdihnai I
c_Ojr=glide,l0-2
hinii5.
cSee crboaf
1.xy9 -5,s‘%)3 A(
Oil)er hinds
A)hiCh iDte
ild cireed (Thi3
Awl eloki
cOnkti as
el/ cc,6eLs )
Comments:
IMO di/ 5 5 --

• Not ee ciRus,0
Request No.:5403 Update
WASTELOAD ALLOCATION APPROVAL FORM
Facility Name: Hoechst Celanese
NPDES No.: NC0004952
Type of Waste: 81% Industrial (Polyester Fibers)
Status: Existing
Receiving Stream: Buffalo Creek
Classification: C (Becomes WS-III 0.5 mi. below discharge)
Subbasin: 030805 Drainage area: 154
County: Cleveland
Regional Office: ARO
Requestor: Barona
Date of Request: 9/11/89
Quad: G12NE
Summer 7Q10:
Winter 7Q10:
Average flow:
30Q2:
RECOMMENDED EFFLUENT LIM4S
Recommended
Mo Avg Dly Max
Wasteflow (mgd): 0.55
BOD5 (lb/d): 85.8 212.2
TSS (lb/d): 152.8 395.0
See attached for additional OCPSF limits.
MONITORING
Upstream (Y/N): N
Downstream (Y/N): N
Location:
Location:
COMMENTS
20.00
46.00
216
65.00
This approval form represent changes made to WLA 5403 finalized 6/6/90.
Limits not included are same as in last WLA.
See aliockled awn° kw Wionahond CkrArTis.
Recommended by:
Reviewed by
Tech Support Supervisor:
Regional Supervisor:
Permits & Engineering:
C. ,c,c,_k
6•••""
RETURN TO TECHNICAL SUPPORT BY:
AUG 04 1990
Date: 7101c0
Date: 1 &
Date: 143 00)kA
Date: 27200.)
RECEIVED
Water Quality Secticni
JUL. 1 0 1990
Asheville Regional, Office
Asheville, North Carolina

Additional Limits for Hoechst Celanese Corp., NPDES No. NC0004952
Buffalo Creek - 030805 - Cleveland County
Parameter
Acenapthene ( lb/d) :
Acrylonitrile ( lb/d) :
Benzene ( lb/d) :
Carbon Tetrochloride (lb/d):
Chlorobenzene (lb/d):
1,2,4-
Trichlorobenzene (lb/d):
Hexachlorobenzene (lb/d):
1,2-Dichloroethane ( lb/d) :
1,1,1-Trichloroethane (lb/d):
Hexachloroethane (lb/d):
1,1-Dichloroethane (lb/d):
1,1,2-Trichloroethane (lb/d):
Chloroethane (lb/d):
Chloroform (lb/d):
2-Chlorophenol (lb/d):
1,2-Dichlorobenzene (lb/d):
1,3-Dichlorobenzene (lb/d):
1,4-Dichlorobenzene (lb/d):
1,1-Dichloroethylene (lb/d):
1,2-Trans-
Dichloroethylene (lb/d):
2,4-Dichlorophenol (lb/d):
1,2-Dichloropropane (lb/d):
1,3-Dichloropropylene (lb/d):
2,4-Dimethylphenol (lb/d):
2,4-Dinitrotoluene (lb/d):
2,6-Dinitrotoluene (lb/d):
Ethylbenzene (lb/d):
Fluoranthene (lb/d):
Bis(2-Chloroisopropyl
Ether (lb/d):
Methylene Chloride (lb/d):
Methyl Chloride (lb/d):
Hexachlorobutadiene (lb/d):
Napthalene ( lb/d) :
Nitrobenzene (1b/d):
2-Nitrophenol (lb/d):
4-Nitrophenol (lb/d):
2,4-Dinitrophenol (lb/d):
Daily Max Mo. Avg. EL/WQ
0.003 (WQ)
= 0.718 ug/1
0.069-
=15.1 ug/1
0.132 (WQ)
=28.8 ug/1
0.092
0.068
0.003 (WQ)
=0.718 ug/1
0.069
=15.1 ug/1
0.089 (BAT,
0.339
0.001
= 0.185 ug/1 =
0.447 (WQ)
= 97.5 ug/1
0.131
0.131
0.143
0.131
0.648
0.111
0.011
= 2.42 ug/1 =
0.394
0.106
0.068
0.060
0.131
0.010
= 2.25 ug/1 =
0.556
0.106
0.087
0.129 (WQ)
=28.2 ug/1
1.550
0.261
0.164
1.831
0.215
0.460
0.119
0.003 (WQ)
= 0.718 ug/1
0.164
0.167
0.300
0.297
0.044
0.036
0.164
0.001
0.185
0.122
WQ
NSPS)
BAT, NSPS
BAT, NSPS
BAT, NSPS
WQ
ug/1
(BAT, NSPS)
0.051
0.051
0.053
0.051
0.252
0.051
0.011
2.42 ug/1
0.186
0.075
0.036
0.039
0.051
0.010
2.25 ug/1
0.370
0.070
0.044
0.129 (WQ)
=28.2 ug/1
0.617
0.077
0.060
0.728
0.097
0.208
0.048
0.003 (WQ)
= 0.718 ug/1
0.065
0.099
0.174
0.172
BAT, NSPS
BAT, NSPS
BAT, NSPS
BAT, NSPS
BAT, NSPS
BAT, NSPS
WQ
BAT, NSPS
BAT, NSPS
BAT, NSPS
BAT, NSPS
BAT, NSPS
WQ
BAT, NSPS
BAT, NSPS
BAT, NSPS
BAT, NSPS
BAT, NSPS
BAT, NSPS
BAT, NSPS
BAT, NSPS
BAT, NSPS
BAT, NSPS
BAT, NSPS
BAT, NSPS
BAT, NSPS
BAT, NSPS

Parameter
4,6-Dinitro-o-cresol (lb/d):
Phenol (lb/d):
Bis(2-ethylhexyl)
phthalate (lb/d):
Di-n-butyl phthalate (lb/d):
Diethyl phthalate (lb/d):
Dimethyl phthalate (lb/d):
Benzo(a)anthracene (lb/d):
Benzo(a)pyrene (lb/d):
3,4-Benzofluoranthene (lb/d):
Benzo(k)fluoranthene (lb/d):
Chrysene (lb/d):
Acenaphthylene (lb/d) :
Anthracene (lb/d) :
Fluorene (lb/d) :
Phenanthrene (lb/d) :
Pyrene (lb/d) :
Tetrachloroethylene (lb/d) :
Toluene (lb/d):
Trichloroethylene (lb/d):
Vinyl Chloride (lb/d):
Total Chromium (lb/d):
Daily Max Mo. Avg. EL/WO
0.670
0.063
0.675
0.138
0.491
0.114
0.003 (WQ)
= 0.718 ug/1
0.003 (WQ)
= 0.718 ug/1
0.003 (WQ)
= 0.718 ug/1
0.003 (WQ)
= 0.718 ug/1
0.003 (WQ)
= 0.718 ug/1
0.003 (WQ)
= 0.718 ug/1
0.003 (WQ)
= 0.718 ug/1
0.003 (WQ)
= 0.718 ug/1
0.003 (WQ)
= 0.718 ug/1
0.003 (WQ)
= 0.718 ug/1
0.089 (WQ)
=19.3 ug/1
0.193
0.131
0.222 (WQ)
=48.4 ug/1 =
5.154 (WQ)
= 1.123 mg/1
Total Copper (lb/d): 8.175 1.016 BAT,NSPS
Action level for copper will be exceeded for both limits.
Total Cyanide (lb/d): 0.515 (WQ) 0.515 (WQ)
Total Cyanide (ug/1): 112 112
Total Lead (lb/d): .2-1-5-77•1.ULA 2.577*0.1'4 BAT,NSPS
Total Nickel (lb/d): 2.779 (WQ) 2.779 (WQ)
=606 ug/1 =606 ug/1
Total Zinc (lb/d): 6.313 2.540 BAT,NSPS
Action level for zinc will be exceeded for both limits.
0.189
0.036
BAT, NSPS
BAT, NSPS
BAT, NSPS
BAT, NSPS
BAT, NSPS
BAT, NSPS
0.249
0.065
0.196
0.046
0.003
0.718
0.003
0.718
0.003
0.718
0.003
0.718
0.003
0.718
0.003
0.718
0.003
0.718
0.003
0.718
0.003
0.718
0.003
0.718
0.039
(WQ)
ug/1
(WQ)
ug/1
(WQ)
ug/1
(WQ)
ug/1
(WQ)
ug/1
(WQ)
ug/1
(WQ)
ug/1
(WQ)
ug/1
(WQ)
ug/1
(WQ)
ug/1
(BAT, NSPS)
0.063
0.051
0.222 (WQ)
48.4 ug/1
2.685 (BAT,NSPS)
BAT,NSPS
BAT,NSPS
Total phenolic compounds shall not exceed 0.111 lb/day (24.2 ug/1).

MEMORANDUM
TO:
DIVISION OF ENVIRONMENTAL MANAGEMENT
July 2, 1990
Hoechst Celanese WLA File
NPDES No. NC0004952
Buffalo Creek - 030805
FROM: Ruth Swanek
SUBJECT: Revised limits from WLA 5403 (finalized 6/6/90)
The limits assigned in the above WLA were changed due to the
following reasons:
1. Revised amount of process water - The Permits and Engi-
neering Unit (P/E) revised the amount of process wastewater
used to calculate the BOD, TSS, and OCPSF limits. P/E
received further information from the applicant (attached)
which indicated that vapors from the condensor are ejected
into the cooling tower. Therefore, the cooling tower is
acting as a giant scrubber, and this water was used in the
calculation of limits.
2. The OCPSF guideline limits were further revised based on
the 6/6/90 .memo from Julia Storm (attached). The average flow
was used for human health based limits for noncarcinogens in
the previous analysis. The 7Q10 flow should be used for non -
carcinogens.
The methodology used to determine the limits is similar to
that described in the 6/6/90 WLA.

C004.10.15, "M0410.1.
Stt
__ 4
5
titexia•uP WRTEL
STEAM C kso R
PROCESS COOLING TOWER SYSTEM
te
11. casirwanni.
RANT
(flitAaGni Ftit.
permq
ATTACHMENT .4.
• CaNDINSE
Mg I MA. TANK
® 01PC:4(40
Eartear acycoc.
sytampir
1. Raw materials are added into a heated vessel where the
slurry is agitated under pressure. (Ethylene glycol,
butanediol, and dimethyl-terephthalate are the major raw
materials used in the manufacture of polyester resins.)
2. The raw material slurry is polymerized into molten
polyester "polymer" over a batch cycle time in the
Polymerization Vessel.
3. During the -polymerization process excess raw materials
and reaction by-products are liberated as vapors and are
drawn into a condenser.
4. The condensed raw materials (mostly ethylene glycol or
butanediol) is collected in the receiver tank.
5. The condensed materials are blended with virgin raw
materials and recycled in the process.
6. Those vapors which do not condense are vented, and steam
ejected into the process cooling tower system as a form of
air pollution abatement.
7. These vapors are condensed in the cooling water as they
are water soluble.
8. The cooling tower water is recirculated back to the
actual cooling tower.
9. The recirculated water enters the top .of the tower where
the water cascades down the induced air draft system and is
cooled. Make-up water is added as necessary, dependant on
evaporative losses.
10. The "cooled" water is then pumped back through the vapor
collection header and is re -used.
11. A constant blow -down to the NPDES wastewater plant of the
cooling tower water is maintained to prevent saturation by
the vapors of the by-products/excess raw materials. The
blowdown is approximately 75,000 gallons per day.

MEMO
TO: 'UV/ 01-14//ebliE(
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North Carolina Department of Environment
Health, and Natural Resources
DATE•
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FOR APPROPRIATE DISCHARGERS. LIST COMPLETE GUIDELINE LIMITATIONS BELOW
Effluent Characteristics
Monthly _44_
Average -"ft/
/ Daily
aximum
1
Comments
see affached
---/-5S
/5. N1
3 Fc.—. 0
Ca f cti 14.1-1 (sits
14-
. 6' •
,
. .
.
. .
•
_.
,
, •
..
Type of Product Produced
Lbs/Day Produced
Effluent Guideline Reference
Oil eStek- "P be 1-.) polyes-frr res;17
0 c P 5 F uA it'', es ,
f)
ciber. 14 0-1,5 I
,
; I)
5-5.5; 000 lb
re5(h gig, Lf I .
. -g;b-ek-
_

OCPSF Subpart I
A
B
C
D
E
F
1
OCPSF Regulations Subpart 1
2
Daily Max
Monthly Avg
Flow
Daily Max
Monthly Avg
3
Effluent Characteristics
(ug/1)
(uq/1)
(MGD)
(lb/day)
(lb/day)
4
5
Acenapthene
5 9
22
0.290
t.,5$ 0.143
00. 0.053
6
Acrylonitrile
242
96
Oct 0.585
\pa 0.232
7
Benzene
136
37
OCt 0.329
(IL, 0.089
8
Carbon Tetrachloride e L.
3 8
1 8
0.092
0.044
9
Chlorobenzene L..
28
1 5
0.068
0.036
1 0
1,214-Trichlorobenzene CL.,
140
6 8
0.339
0.164
1 1
Hexachlorobenzene
28
1 5
t..)L,1 0.068
Oa 0.036
1 2
1,2-Dichloroethane
211
6 8
tora 0.510
C.1.- 0.164
1 3
111,1-Trichloroethane -6k-
5 4
21
0.131
0.051
1 4
Hexachloroethane • 6L
5 4
21
0.131
0.051
1 5
1,1-Dichloroethane - 0,-
5 9
22
0.143
0.053
1 6
1,1,2-Trichloroethane -0..
54
21
0.131
0.051
1 7
Chloroethane .. el...
268
104
0.648
0.252
1 8
Chloroform - ..
4 6
21
0.111
0.051
1 9
2-Chlorophenol
98
31
140 0.237
t*:10.075
0.186
2 0
1,2-Dichlorobenzene c.,, L
163
7 7
0.394
2 1
1,3-Dichlorobenzene d..t.
4 4
31
0.106
0.075
2 2
1,4-Dichlorobenzene 4i..
28
15
0.068
0.036
2 3
1,1-Dichloroethylene 6. L
25
1 6
0.060
0.039
2 4
1,2-trans-DichloroethyleneE.,..
5 4
21
0.131
0.051
2 5
2,4-Dichlorophenol
112
3 9
w: 0.271
0Q 0.094
2 6
1,2-Dichloropropane L.
230
153
0.556
0.370
2 7
1,3-Dichloropropylene et.
4 4
29
0.106
0.070
2 8
2,4-Dimethylphenol cit.
3 6
1 8
0.087
0.044
2 9
2,4-Dinitrotoluene
285
113
,01-1 0.689
LoC1 0.273
3 0
2,6-Dinitrotoluene .-,(...
641
255
1.550
0.617
3 1
Ethylbenzene di-
108
3 2
0.261
0.077
3 2
Fluoranthene 6L-
6 8
25
0.164
0.060
3 3
Bis(2-Chloroisopropyl)ether
0, 757
301
1.831
0.728
3 4
Methylene Chloride 61..
8 9
4 0
0.215
0.097
3 5
Methyl Chloride 0..
190
86
0.460
0.208
3 6
Hexachlorobutadiene ,L-
4 9
2 0
0.119
0.048
3 7
Naphthalene
59
22
00 0.143
torl 0.053
3 8
Nitrobenzene 6-L-
68
2 7
0.164
0.065
3 9
2-Nitrophenol (,..i-
69
41
0.167
0.099
4 0
4-Nitrophenol 6L
124
72
0.300
0.174
4 1
2,4-Dintrophenol c,,.
123
71
0.297
0.172
4 2
4,6-Dintro-o-cresol 6.L.
277
78
0.670
0.189
4 3
Phenol er.L
26
1 5
0.063
0.036
4 4
Bis(2-ethylhexyl)phthalate6-
279
103
0.675
0.249
4 5
Di-n-butyl phthalate 4:-,i...
5 7
2 7
0.138
0.065
4 6
Diethyl phthalate 6L-
203
81
0.491
0.196
4 7
Dimethyl phthalate 6,-L.
4 7
1 9
0.114
0.046
4 8
Benzo(a)anthracene
5 9
22
oca 0.143
Lon 0.053
Page 1

OCPSF Subpart I
A
B
C
D
E
F
4 9
Benzo(a)pyrene
61
23
uyo 0.148
v.ya 0.056
5 0
3,4-Benzofluoranthene
61
23
ou 0.148
tx.)ca 0.056
5 1
Benzo(k)fluoranthene
59
22
kyia 0.143
tiiii 0.053
5 2
Chrysene
59
22
,00. 0.143
ocl 0.053
5 3
Acenaphthylene
59
22
0.70. 0.143
oia 0.053
5 4
Anthracene
59
22
ipci. 0.143
1.0c1 0.053
5 5
Fluorene St`.
59
22
vx. 0.143
IA, 0.053
5 6
Phenanthrene
59
22
kxra 0.143
,DO 0.053
5 7
Pyrene
67
25
Loo. 0.162
0,0 0 . 0 6 0
5 8
Tetrachloroethylene
56
22
01 0.135
01605.053
59
Toluene 6u
80
26
0.193
0.063
6 0
Trichloroethylene a t--
54
21
0.131
0.051
6 1
Vinyl Chloride
268
104
u,Q 0.648
wo. 0.252
6 2
Total Chromium
2770
1110
LP I 6.700
D-. 2.685
6 3
Total Copper CI,
3380
1450
8.175
3.507
6 4
Total Cyanide
1200
420
WO 2.902
00. 1.016
6 5
Total Lead
690
320
1.669
0.774
6 6
Total Nickel
3980
1690
9.626
4.087
6 7
Total Zinc
2610
1050
6.313
2.540
Page 2