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HomeMy WebLinkAboutNC0040797_Plan of Action_20040528NPDES DOCUMENT ! CANNINO COVER :SHEET NPDES Permit: NC0040797 Henry Fork WWTP Document Type: Permit Issuance Wasteload Allocation Authorization to Construct (AtC) Permit Modification Complete File - Historical Engineering Alternatives (EAA) Correspondence Owner Name Change (744 D( 7_f0 Instream Assessment (67b) Speculative Limits Environmental Assessment (EA) Document Date: May 28, 2004 This document is printed on reuse paper - ignore any content on the reirerse side ilickory Where Bus ness and Pieosure Grow Together - May 28, 2004 Alan Klimek, P • erector Division of . ter Quality NCDE 1617 ail Service Center eigh, NC 27699-1617 Subject: NPDES NC0040797 A. (3.) Color Reduction Study Dear Mr. Klimek: Public Utilities Pretreatment City of Hickory 4014 River Road Hickory, NC 28602 Telephone 828.294-6484 Fax 828.294-1740 smcneely@ci.hickoq.nc.us JO i 200! D/V. OF V►, Dl� �TFR QUALITY Y Enclosed you will find the Color Reduction Study and cost estimates for the Henry Fork Wastewater Treatment Plant. The evaluation performed by Degussa/Stockhausen Inc, estimates cost for reducing color by 75% and 90% using Praestol 193k (see enclosure). Also included, is data from fiscal years 2002-2003 and thru April of 2003-2004 for color monitoring and removal from the normal treatment processes (see enclosures). The Henry Fork WWTP was able to reach these removal percentages without incurring additional expenditures. In order to reach the 75% and 90% thresholds, chemical addition would be required. These levels could be reached at significant additional cost the City of Hickory. These costs would increase/decrease with variations in flow and color level of the influent. The enclosed charts give increasing cost estimates for 75% and 90% as the plant influent flow increases. Sincerely, -7,c/t-vq Robert Shaver, HF WWTP ORC City of Hickory Cc: Dave Goodrich, NPDES Unit GREATER HICKORY METRO ♦ `• min NCDENR North Carolina Department of Environment and Natural Resources Division of Pollution Prevention and Environmental Assistance Michael F. Easley, Govemor William G. Ross Jr., Secretary Gary Hunt, Director May 17, 2004 Dear Mrs. McNeely: Please find the attached color reduction reports for those facilities identified by the City of Hickory as having color discharge. DPPEA visited Crystal Dyeing and Finishing on May 10th but a power outage during the dyeing process disrupted the sampling program. Since the facility only dyes two days every other week a color reduction report will not be available by the reporting deadline with the State of North Carolina. DPPEA will complete this color reduction visit and send the results to the City of Hickory. If you have any questions please contact me at 336-249-1480. Sincerely ohn Burke 1639 Mail Service Center, Raleigh, North Carolina 27699-1639 Phone: (919) 715-65001 FAX: (919) 715-67941 Internet: www.p2pays.org An Equal Opportunity 1 Affirmative Action Employer — 100% Recycled 1 100% Post Consumer Paper May 17, 2004 Bob Shaver Plant Supervisor Henry Fork WWTP 4014 River Road Hickory, NC 28602 Re: ADMI Color Removal Evaluation Dear Bob, Thank you, on behalf of Stockhausen, Inc. and myself, for the opportunity to evaluate our Praestol line of flocculants and coagulants at your facility. Your staff was extremely helpful; please extend my thanks to them. As you are aware, on April 28, 2004 I performed chemical treatment on your MLSS. The purpose was to select a product to reduce the ADMI color increments of your final effluent. Testing entailed addition of Dimdac and Polyamine products @15 & 3OPPM. After a five minute settling period, the supernatant was drawn off and analyzed. The instrument of choice was a Milton Roy Spectronics Genesys 5. See attached tables. From the test results, our Praestol 193K achieved the results necessary to meet your discharge requirements. The Praestol 193K is a high molecular weight Polyamine. It is available in drums, totes or bulk quantities. Based on a flow of 2MGD, you would need 30gallons/day for an average daily dosage of 15PPM. This of course is dependent on the production of color waste into your system. In conclusion, feel free to phone 1-336-210-4065 for any concerns. Sincerely, Degussa. / Stockhausen, Inc. W. Patrick Matthews Senior Sales Representative Water Chemicals Division PC: Ron Jones Neal Powell 4/29/2004 10:31 Hrvi �% FORM 403e rev 3f99 LLE WASTEWATER TREATMENT PLANT CITY OF MARTINSVI Dilution Factor 1 41:Z9l2004 82.70 85.60 8,5.20 64.70 83.40 82.50 82.20 82.30 82.40 83.20 84.70 87.40 189K 15ym 1B9 K 34w or 495.2 97.90 88.70 J 93.40 90.80 1 f b.1 u 0.4•, 92.70 97.50 • 98.80 _ 77.80 515.2 1 98.80 91.40 93.30 97.80 99.00 529.8 99.20 95.90 92.00 79.10 97.30 92.50 80.00 93.80 98.00 99.10 541.4 99.40 544.3 99.50 , 97.60 92.70 80.20 93.90 98.10 99.20 551.8 99.70 98.20 93.00 80.50 94.20 98.20 99.20 561.9 99.80 98.90 93.60 80.80 94.60 98.40 99.40 564.1 99.90 99.00 93.70 80,90 94.80 98.50 99.40 572.5 99.90 99.20 94.20 81.30 95.10 98.60 99.50 w 577.4 99.90 99.30 94.40 81.50 95.30 98.70 99.50 �- 584.8 99.90 99.40 94.70 81.80 95.60 95.80 98.80 98.90 99.50 99.60 588.7 99.90 99.40 99.50 94.90 82.10 599.6 _ 99.90 95.30 - - 82.50 96.10 99.00 600.8 99.90 99.80 99.80 99.70 99.60 0.041 4g 99.50 99.60 95.30 95.70 82.60 610.9 _ 624.2 96.10 99.10 �� � 99.50 83.10 84.20 84 � 87.10 0.229 96,40 99.20 99.70 99.30 99.60 99.60 99.50 99.50 0.222 96.10 96.20 97.00 0.099 128 627.3 645,9 ADMI 96.70 96.80 97.50 99.30 99.60 99.40 gg.g=--.... 0.086 0.04 0.02 we 310 110 Date of Calibration Curve Slope X intercept R2 value 913/2003 1395.261963 -9.52333164 0.999957502 ANALYST 22 - FORM 403c rev 3/99 4/29/2004 10:41 AM E 2 CD Z W 1 CITY OF MARTINSVILLE WASTEWATER TREATMENT PLANT 188K 30ppm 193K 15ppm 193K 30ppm� SamTie Name 50 STD 300 STD 188K l5ppm 1 1 1 1 1 Dilution Factor 1 4/28/2004 Sample Date 4/29/2004 4/29/2004 4/28/2004 4/28/2004 4128/2004 96.80 422.2 96.80 82.70 94.50 95.90 94.60 ✓"" 432 97.30 85.50 95.00 96.30 95.10 97.20 95.10 96.50 95.20 97.30 435.5 97.20 85.20 97.40 438.6 97.20 84.60 95.30 96.60 95.40 96.90 83.40 95.50 96.80 95.60 97.60 444.4 450.1 96.80 82.50 95.80 97.00 95.80 97.70 97,20 96.10 97.90 455.9 96.70 82.10 96.00 461.2 96.70 82.30 _ 96.20 97.30 96.30 98.00 96.20 97.30 96.30 98.00 462 96.80 82.40 468.7 96.90 83.20 96.40 97.40 96.40 98.10 477.7 97.20 84.70 96.50 97.60 96.60 98.20 96.70 97.70 96.80 98.40 489.5 97.70 87.30 495.2 98.00 8B.70 96.90 97.80 96.90 98.50 515.2 98.80 93.40 97.20 98.10 97.30 . 98.70 529.8 99.20 95.90 97.50 98.30 97.60 98.90 541.4 99.50 97.40 97.80 98.50 97.90 99.00 544.3 99.60 97.70 97.90 98.60 97.90 99.00 551.8 99.70 5,8.30 98.10 98.70 98.10 - 99.10 561.9 99.90 98.90 98.30 98.90 98.40 99.30 99.30 564.1 99.90 99.00 98.40 98.90 98.50 _ 572.5 99.90 99.30 98.50 99.10 98.60 99.40 577.4 99.90 99.40 - 98.60 , 99,10 98.70 99.40 584.8 100.00 99.50 98.80 99.20 98.90 99.50 ._ 588.7 99.90 99.50 98.80 99.30 98.90 99.50 599.6 99.90 99.60 99.00 99.40 99.10 99.60 600.8 99.90 99.60 99.00 99.40 99.10 99.60 5109 99.80 99.60 99.10 99.40 99.20 99.60 624.2 99.80 99.60 99_20 99.50 99.30 99.70 627.3 99.80 99.60 99.20 99.50 99.30 99,70 645.9 99.70 99.70 99.40 99.50 99.50 99.70 0.042 r 0.224 0.043 0.033 0.043 0.03 �ADMI 49 302 51 36 51 28 Date of Calibration Curve 9/312003 Slope 1395,261963 X intercept -9.52333164 R2 value 0.999957502 ANALYST AOMf $300,000.00 $250, 000.00 $200,000.00 $150,000.00 $100,000.00 $50, 000.00 $- COST PER YEAR FOR 75 PERCENT REMOVAL $246,572.1 $232,873.65 S205.476.75 S178,079.85 $150,682.95 $123,286.05 $95,889.15 $68,492.25 S54,793.80 2.0MGD 2.5MGD 3.5MGD 4.5MGD 5.5MGD 6.5MGD 7.5MGD 8.5MGD 9.0MGD 0 L❑ COST PER YEAR FOR 75 PERCENT REMOVAL $600,000.00 $500,000.00 S400,000.00 S300,000.00 $200,000.00 $100,000.00 $- COST PER YEAR FOR 90 PERCENT REMOVAL $493,144.2 $465,747.30 $410,953.50 $356,159.40 S301,365.70 $246,572.10 $191,778,30 $136,984.50 109,587.60 2.0MGD 2.5MGD 3.5MGD 4.5MGD 5.5MGD 6.5MGD 7.5MGD 8.5MGD 9.0MGD 0 ❑ COST PER YEAR FOR 90 PERCENT REMOVAL ADMI COLOR ANALYSIS 1400 1200 1000 800 600 400 200 0 COLOR MONITORING 2002-2003 .NA �J�� �4Q- o��Q- ���Q- ��<Q- JPe-1 JP�-1 PJ Q��� OZ) OJT �G� P4 4<Q- c,<4 MONTH 0 INFLUENT II EFFLUENT 0 UPSTREAM 0 DOWNSTREAM PERCENT REMOVAL 100 90 80 70 60 50 40 30 20 10 0 PERCENT REMOVAL 20002-2003 28 63 0 86 76 - 94 81 73 73 68 0.7 0 Q4¢ 4'Q- Q'PQl �-1 G.� \ 4i'.k \..J\'JOJ44.Qi,0S 4 JPJP�` <ZI.' \`‘‘ e Q. PQ�OO? �\'‘ '0Qi 4� QMONTH t7 PERCENT REMOVAL 600 500 v) 400 >- a 2 300 J O U E o a 200 100 0 COLOR MONITORING-2003-2004 JULY AUG SEPT OCT NOV DEC JAN FEB MARCH APRIL MAY JUNE MONTH ❑ INFLUENT El EFFLUENT ❑ UPSTREAM ❑ DOWNSTREAM PERCENT REMOVAL 100 90 - 80 - 70 - 60 - 50 - 40 - 30 - 20 - 10- 0 PERCENT REMOVAL 2003-2004 86 81 36 78 87 0 52 55 62 74 g O MONTH El PERCENT REMOVAL Division of Pollution Prevention and Environmental Assistance North Carolina Department of Environment and Natural Resources Color Reduction Assessment Longview Yarns Hickory, North Carolina DPPEA John Burke April 13, 2004 Post Office Box 29569, Raleigh, North Carolina 27626-9569 Telephone: (919) 715-6500: FAX: (919) 715-6794 Longview Yarns - 1 - April 28, 2004 Disclaimer This report is intended to offer information and guidance for identifying opportunities and options for waste reduction. Compliance with environmental and occupational safety and health laws is the sole responsibility of each business. All legal and regulatory references within this document are intended only for informational purposes and are not to be taken as reliable sources of legal reference. Businesses should contact the appropriate legal and regulatory authorities for current regulatory requirements as well as for interpretation and implementation. All references and vendor materials (when available) mentioned in the report are included. Mention of a vendor or manufacturer does not represent an endorsement by the State of North Carolina. Neither the State of North Carolina nor the authors of this report are responsible for practices or procedures implemented by individual firms. Longview Yarns 2 April 28, 2004 Longview Yarns: Color Reduction Assessment 1.0 Introduction The City of Hickory and Longview Yarns requested assistance from the Division of Pollution Prevention and Environmental Assistance (DPPEA) in assessing opportunities for reducing effluent color. The City of Hickory was required by the North Carolina Division of Water Quality to perform a color reduction assessment to identify best management practices for the major sources of color in its wastewater. Longview Yarns was identified by the City of Hickory as a source of color. Color testing of Longview Yarns' effluent was 175 ADMI 2"d half of 2002, 104 ADMI 1 S` half 2003, and 458 2"d half of 2003. On April 13th, John Burke, of DPPEA, met with Russ Perkins, Owner, to discuss current operations and sample selected dyebath discharges. The following report provides information on the generation of color from the Longview Yarns' operations and options for potentially reducing the level of color. 2.0 Facility Background and Color Analysis Longview Yarns dyes and finishes rayon blended yarns (70% rayon 30% cotton) and some nylon yarns. Direct dyes are used for dyeing the rayon/cotton yarn and acids are used for dyeing the nylon. The facility operates 1 shift 5 days per week. 100% of production is dyed goods. The dyehouse is equipped with 1 — 600 pound, 1 — 220 pound, 1 —150 pound, and 1 — 100 pound skein dyeing machines that operate at a 20:1 liquor ratio. Machines are typically operated at 90% of full load. The facility currently produces an average of 1,500 pounds per day of finished yarn and discharges approximately 16,000 gallons per day of wastewater. DPPEA targeted the darker shade dyeings for color analysis due to relative large impact these shades have on effluent color. DPPEA sampled two dyebaths to estimate the percent exhaustion of dye on the yarn for a khaki shade (direct) and green shade (acid). Figure 1 provides the procedure used for the green shade and Figure 2 shows the procedure for the khaki shade. DPPEA performed a visual determination of the exhaustion for these shades by comparing the spent bath color to a series of diluted samples of the initial dyebath. The dilutions for the khaki and green shades were 80%, 90% and 95%. Based on this analysis, the khaki and green were estimated at +90% dye exhaustion. Final fixation of dyestuff will be impacted by additional processing steps and was not evaluated through this analysis. 3.0 Color Reduction Options Based on the dyebath exhaustion samples study, Longview Yarns appears to be getting high exhaustion. DPPEA does not have any suggestions related to these dyeing operations. Figure 1 Green Shade 130 lbs in 150 Ibs Package Procedure Fill tub Add leveler Add oxalic acid Add Dye Heat to 130°F at 1 ° rise Hold 10 minutes Heat to 160°F at 1 ° rise Hold 10 minutes Heat to 190°F at 2° rise Hold 10 minutes Drain 0.5% 1.5% 0.1% Figure 2 Khaki Shade 75 Ibs in 100 lbs Package Procedure Fill tub Add leveler Add scour 0.2% 0.2% Add Dye 1.0% Add Salt 2.5% Heat to 190°F 2° rise Hold 15 minutes Drain Longview Yarns - 3 April 28, 2004 Division of Pollution Prevention and Environmental Assistance North Carolina Department of Environment and Natural Resources Color Reduction Assessment Kentucky Derby Hosiery Hickory, North Carolina DPPEA John Burke March 10, 2004 Post Office Box 29569, Raleigh, North Carolina 27626-9569 Telephone: (919) 715-6500: FAX: (919) 715-6794 Kentucky Derby Hosiery - 1 - April 28, 2004 Disclaimer This report is intended to offer information and guidance for identifying opportunities and options for waste reduction. Compliance with environmental and occupational safety and health laws is the sole responsibility of each business. All legal and regulatory references within this document are intended only for informational purposes and are not to be taken as reliable sources of legal reference. Businesses should contact the appropriate legal and regulatory authorities for current regulatory requirements as well as for interpretation and implementation. All references and vendor materials (when available) mentioned in the report are included. Mention of a vendor or manufacturer does not represent an endorsement by the State of North Carolina. Neither the State of North Carolina nor the authors of this report are responsible for practices or procedures implemented by individual firms. Kentucky Derby Hosiery - 2 April 28, 2004 Kentucky Derby Hosiery: Color Reduction Assessment 1.0 Introduction The City of Hickory and Kentucky Derby Hosiery requested assistance from the Division of Pollution Prevention and Environmental Assistance (DPPEA) in assessing opportunities for reducing effluent color. The City of Hickory was required by the North Carolina Division of Water Quality to perform a color reduction assessment to identify best management practices for the major sources of color in its wastewater. Kentucky Derby Hosiery was identified by the City of Hickory as a source of color. Color testing of Kentucky Derby Hosiery' effluent was <35 ADM12"d half of 2002, <59 ADMI 1st half 2003, and <111 2"d half of 2003. On March 22"d, John Burke, of DPPEA, met with Mike Waller, Dyehouse Manager, to discuss current operations and sample selected dyebath discharges. The following report provides information on the generation of color from the Kentucky Derby Hosiery' operations and options for potentially reducing the level of color. 2.0 Facility Background and Color Analysis Kentucky Derby Hosiery bleaches, dyes and finishes hosiery blends of cotton and nylon. Direct and acid dyes are used for dyeing the hosiery. The facility operates 2 shifts 5 days per week. Currently, 90% of production is white goods and 10% dyeing. Approximately 20% of the dyeing is dark shades. The dyehouse is equipped with 3 — 200 pound, 3 —150 pound, 1 — 100 pound, 1 — 75 pound, 1 — 60 pound, 1 — 50 pound, and 1 — 25 pound paddle dye machines that operate at a 25:1 liquor ratio. Machines are typically operated at 100% full Toad or more. The facility currently produces an average of 7,400 pounds per day of finished hosiery and discharges approximately 75,000 gallons per day of wastewater. DPPEA targeted dark shade dyeing of the hosiery for color analysis due to relative large impact these shades have on effluent color. DPPEA sampled one dyebath to estimate the percent exhaustion of dye on the hosiery for a black shade using direct and acid dyes. Figure 1 provides the procedure used for the black shade. DPPEA performed a visual determination of the exhaustion for these shades by comparing the spent bath color to a series of diluted samples of the initial dyebath. The dilutions for the black shade were 60%, 70%, 80%, and 90%. Based on this analysis, the black shade was estimated at 80% dye exhaustion. Final fixation of dyestuff will be impacted by additional processing steps and was not evaluated through this analysis. Fixation of direct dyes on cotton goods is typically in the range of 70 to 95% and acid dyes on nylon is 80 to 93%'. The final fixation of dye for the black would probably be within this range for the respective dye types utilized. Figure 1 Black Shade 210 lbs in 200 lbs Paddle Procedure Fill tub Add oil Add lubricant Add acid dyes Add direct dyes Heat to 90°F 5 min Heat to 160°F at 8° per min Heat to 200°F at 3° per min Hold 10 minutes Add Salt Hold 20 minutes Drop bath 2.0% 1.0% 0.5% 3.3% 40.0% Best Management Practices for Pollution Prevention in the Textile industry, EPA/625/R-96/004 Kentucky Derby Hosiery - 3 - April 28, 2004 3.0 Color Reduction Options Based on the dyebath exhaustion samples study, Kentucky appears to be getting average exhaustion on the darker shades. Some practices that can assist in increasing exhaustion include: > Maintain lowest achievable liquor ratio. Underloading machines will increase liquor ratios and may result in reduced exhaustion. If feasible smaller lots should be matched to smaller tubs. Larger tubs could be marked for a lower fill level for smaller loads that maintain the lowest achievable liquor ratio while still allowing circulation of goods in the tub. > Optimize time -temperature profile scheme to achieve maximum exhaustion of dye. Work with dye supplier to identify most appropriate profile for darker shades. Rate of temperature rise, final hold temperature and length of exhaustion phase will impact final exhaustion. > The facility may want to consider adding salt in 3 stages of increase load with a 10-minute interval instead of loading at one time. > The facility may want to evaluate the use of both oil and lubricant in the dybath. Kentucky Derby Hosiery - 4 - April 28, 2004 Division of Pollution Prevention and Environmental Assistance North Carolina Department of Environment and Natural Resources Color Reduction Assessment Ward Hosiery Hickory, North Carolina DPPEA John Burke April 22, 2004 Post Office Box 29569, Raleigh, North Carolina 27626-9569 Telephone: (919) 715-6500; FAX: (919) 715-6794 Ward Hosiery - I - April 28, 2004 Disclaimer This report is intended to offer information and guidance for identifying opportunities and options for waste reduction. Compliance with environmental and occupational safety and health laws is the sole responsibility of each business. All legal and regulatory references within this document are intended only for informational purposes and are not to be taken as reliable sources of legal reference. Businesses should contact the appropriate legal and regulatory authorities for current regulatory requirements as well as for interpretation and implementation. All references and vendor materials (when available) mentioned in the report are included. Mention of a vendor or manufacturer does not represent an endorsement by the State of North Carolina. Neither the State of North Carolina nor the authors of this report are responsible for practices or procedures implemented by individual firms. Ward Hosiery 2 April 28, 2004 Ward Hosiery: Color Reduction Assessment 1.0 Introduction The City of Hickory and Ward Hosiery requested assistance from the Division of Pollution Prevention and Environmental Assistance (DPPEA) in assessing opportunities for reducing effluent color. The City of Hickory was required by the North Carolina Division of Water Quality to perform a color reduction assessment to identify best management practices for the major sources of color in its wastewater. Ward Hosiery was identified by the City of Hickory as a source of color. Color testing of Ward Hosiery's effluent was <195 ADMI 2"d half of 2002, <378 ADMI 1st half 2003, and <513 2"d half of 2003. On April 22"d, John Burke, of DPPEA, met with Rick Ward, Owner, to discuss current operations and sample selected dyebath discharges. The following report provides information on the generation of color from the Ward Hosiery's operations and options for potentially reducing the level of color. 2.0 Facility Background and Color Analysis Ward Hosiery dyes and finishes cotton, nylon and wool blends. Direct dyes are used for dyeing the cotton and acids are used for dyeing the nylon and wool. The facility operates 1 shift 5 days per week. The dyehouse is equipped with 2 — 300 pound, 2 — 200 pound, 5 —150 pound, 1 —100 pound, 1 — 50 pound, and 1-10 pound paddle dye machines that operate at a 25:1 liquor ratio. Machines are typically operated at full load. The facility currently produces an average of 1,600 pounds per day of hosiery and discharges approximately 28,000 gallons per day of wastewater. DPPEA targeted the darker shade dyeings for color analysis due to relative large impact these shades have on effluent color. DPPEA sampled one dyebath to estimate the percent exhaustion of dye on the hosiery for a black shade. Figure 1 provides the procedure used for the black shade. DPPEA performed a visual determination of the exhaustion for this shade by comparing the spent bath color to a series of diluted samples of the initial dyebath. The dilutions for the black shade were 80%, 90% and 95%. Based on this analysis, the black shade was estimated at just below 90% dye exhaustion. Fixation of direct dyes on cotton goods is typically in the range of 70 to 95% and acid dyes on nylon is 80 to 93%'. Final fixation of dyestuff will be impacted by additional processing steps and was not evaluated through this analysis. Figure 1 Black Shade 150 lbs in 150 lbs Paddle Procedure Fill tub Add leveler 2.0% Raise to 100°F Add Dye 5.2% Add salt 80% Raise to 200oF Hold 25 min Add acid 0.5% Hold 10 min Drain 3.0 Color Reduction Options Based on the dyebath exhaustion samples study, Ward Hosiery appears to be getting high exhaustion. DPPEA does not have any suggestions related to these dyeing operations. Best Management Practices for Pollution Prevention in the Textile Industry, EPA/625/R-96/004 Ward Hosiery - 3 - April 28, 2004 Division of Pollution Prevention and Environmental Assistance North Carolina Department of Environment and Natural Resources Color Reduction Assessment Johnson Hosiery Mills Hickory, North Carolina DPPEA John Burke January 29, 2004 Post Office Box 29569, Raleigh, North Carolina 27626-9569 Telephone: (919) 715-6500: FAX: (919) 715-6794 Johnson Hosiery Mills - i - April 28, 2004 Disclaimer This report is intended to offer information and guidance for identifying opportunities and options for waste reduction. Compliance with environmental and occupational safety and health laws is the sole responsibility of each business. All legal and regulatory references within this document are intended only for informational purposes and are not to be taken as reliable sources of legal reference. Businesses should contact the appropriate legal and regulatory authorities for current regulatory requirements as well as for interpretation and implementation. An references and vendor materials (when available) mentioned in the report are included. Mention of a vendor or manufacturer does not represent an endorsement by the State of North Carolina. Neither the State of North Carolina nor the authors of this report are responsible for practices or procedures implemented by individual firms. Johnson Hosiery Mills 2 April 28, 2004 Johnson Hosiery Mills: Color Reduction Assessment 1.0 Introduction The City of Hickory and Johnson Hosiery Mills requested assistance from the Division of Pollution Prevention and Environmental Assistance (DPPEA) in assessing opportunities for reducing effluent color. The City of Hickory was required by the North Carolina Division of Water Quality to perform a color reduction assessment to identify best management practices for the major sources of color in its wastewater. Johnson Hosiery Mills was identified by the City of Hickory as a source of color. Color testing of Johnson Hosiery Mills' effluent was 634 ADMI 2nd half of 2002, <562 ADMI 1' half 2003, and <245 2nd half of 2003. On January 29th, John Burke, of DPPEA, met with Scott Wilson, Dyehouse Manager, to discuss current operations and sample selected dyebath discharges. The following report provides information on the generation of color from the Johnson Hosiery Mills' operations and options for potentially reducing the level of effluent color. 2.0 Facility Background and Color Analysis Johnson Hosiery Mills bleaches, dyes and finishes hosiery blends of cotton, nylon, and acrylic. Reactive, acid and basic dyes are used for dyeing the hosiery. The facility operates 1 shift 5 days per week. Currently, 50% of production is washouts and 50% is dyed goods. The dyehouse is equipped with 1 — 600 pound Braun and 2 — 240 pound, 1 — 200 pound, 2 —100 pound, and 2 — 40 pound paddle tubs operating at 30:1 liquor ratio. The facility currently produces an average of 3,000 pounds per day of finished hosiery and discharges approximately 80,000 gallons per day of wastewater. DPPEA targeted dark shade dyeing of the hosiery for color analysis due to relative large impact these shades have on effluent color. DPPEA sampled one two-step dyeing to estimate the percent exhaustion of dye on the hosiery for a black shade (cotton with reactive and nylon with acid). Figure 1 provides the procedure used for the black shade. DPPEA performed a visual determination of the exhaustion for this shade by comparing the spent bath color to a series of diluted samples of the initial dyebath. The dilutions for the acid dyeing were 30%, 40%, 50%, 60%, and 70% and they were 50%, 60%, 70%, and 80% for the reactive dyeing. Based on this analysis, the acid dye was estimated lower than 40% exhaustion and the reactive dye was estimated at 55% exhaustion. Final fixation of dyestuff will be impacted by additional processing steps and was not evaluated through this analysis. Fixation of reactive dyes on cotton goods is typically in Figure 1 Black Shade 243 lbs in 240 lbs Paddle Procedure Add leveler 1.0% Add Ammonium sulfate2.0% Add acid dye 2.2% Heat to 205°F (3°F rate of rise) Run 20 minutes Drop Fill and Heat to 90°F Add lubricant Add leveler Add wetter Add salt 4.0% 1.0% 1.0% 296.2% Add reactive dye 6.6% Two 5 minute increments Heat to 140°F (3°f rate of rise) Run 5 minutes (leveling) Add alkali 1.8% Wait 10 minutes Add alkali Wait 10 minutes Add alkali (split) Wait 5 minutes Add alkali aid Maintain 140°F Run for 50 minutes Drop bath 5.3% 10.6% 2.9% Johnson Hosiery Mills - 3 April 28, 2004 the range of 50 to 80% and acid dyes on nylon is 80 to 93%1. The final fixation of dye for both of these dye types would probably be below these levels and in the case of the acid dye well below. 3.0 Color Reduction Options Based on the dyebath exhaustion samples study Johnson appears to getting below average exhaustion rates for the dye types used. There may be some opportunities to reduce color discharge through increasing exhaustion and final fixation on these dark shade dyeings. Johnson Hosiery Mills should consider some of the following practices to increase dye exhaustion. The mill may already be doing some of these things. Dyeing ➢ Maintain lowest achievable liquor ratio. Paddle tubs inherently require higher liquor ratios that result in larger salt requirements and more auxiliary chemical usage as well as poor exhaustion and shade repeatability. Johnson may want to consider increasing the use of the Braun dyeing machine for dark shades due to the ability to operate this machine at liquor ratios as low as 10:1. Another option for Johnson would be to reduce the upper fill level of the paddle tubs so that a 20:1 liquor ratio could be obtained (as long as the paddles will still circulate goods effectively). > Optimize time -temperature profile scheme to achieve maximum exhaustion of dye. Based on the dye samples the exhaustion for both dye types is poor. The cause of this is not clear, but increasing the time of dyeing for the acid dye may improve exhaustion. Increasing dye time prior to alkali addition or dropping temperature to 120°F for 15 minutes prior to alkali addition may increase exhaustion of reactive dyes. > Johnson should work with its dye suppliers to optimize the dyeing procedure. The excessive amount of salt use does not appear to be aiding in dye exhaustion. > Reduce dependence on auxiliaries like dye levelers that impede exhaustion. Make sure that excess leveler is not being added beyond the specified amount in the dye formula. Both a leveling agent and sulfate, used for leveling of acid dye, is being used in this formula. ➢ Evaluate need for high percentage of lubricant in reactive dyebath. ➢ Johnson may want to consider utilizing direct dyes in place of reactive dyes if the markets are open to these dyestuffs. Johnson could reduce run time and salt consumption with the use of Direct dyes over neutral reactive dyes. Acid and direct dyes can be dye together significantly reducing run time as compared to the neutral reactive dyes. Or, consider use of bi-functional reactive dyes that required less salt and typically have a higher exhaustion. If Johnson's customers are not open to other dyestuffs then the facility should work with its current supplier for opportunities to improve dye exhaustion. Best Management Practices for Pollution Prevention in the Textile Industry, EPA/625/R-96/004 Johnson Hosiery Mills - 4 - April 28, 2004 Division of Pollution Prevention and Environmental Assistance North Carolina Department of Environment and Natural Resources Color Reduction Assessment Ellis Hosiery Mills Hickory, North Carolina DPPEA John Burke February 20, 2004 Post Office Box 29569, Raleigh, North Carolina 27626-9569 Telephone: (919) 715-6500; FAX: (919) 715-6794 Ellis Hosiery Mills - 1 - April 28, 2004 Disclaimer This report is intended to offer information and guidance for identifying opportunities and options for waste reduction. Compliance with environmental and occupational safety and health laws is the sole responsibility of each business. All legal and regulatory references within this document are intended only for informational purposes and are not to be taken as reliable sources of legal reference. Businesses should contact the appropriate legal and regulatory authorities for current regulatory requirements as well as for interpretation and implementation. All references and vendor materials (when available) mentioned in the report are included. Mention of a vendor or manufacturer does not represent an endorsement by the State of North Carolina. Neither the State of North Carolina nor the authors of this report are responsible for practices or procedures implemented by individual firms. Ellis Hosiery Mills 2 April 28, 2004 Ellis Hosiery Mills: Color Reduction Assessment 1.0 Introduction The City of Hickory and Ellis Hosiery Mills requested assistance from the Division of Pollution Prevention and Environmental Assistance (DPPEA) in assessing opportunities for reducing effluent color. The City of Hickory was required by the North Carolina Division of Water Quality to perform a color reduction assessment to identify best management practices for the major sources of color in its wastewater. Ellis Hosiery Mills was identified by the City of Hickory as a source of color. Color testing of Ellis Hosiery Mills' effluent was 1332 ADMI 2°d half of 2002, 2974 ADMI 1 ' half 2003, and 1815 2nd half of 2003. Based on these color samples and the typical effluent flow, Ellis is on of the larger contributors of color. On January 21 S', John Burke, of DPPEA, met with Karl Powell, Dyehouse Manager, to discuss current operations and sample selected dyebath discharges. The following report provides information on the generation of color from the Ellis Hosiery Mills' operations and options for potentially reducing the level of color. 2.0 Facility Background and Color Analysis Ellis Hosiery Mills bleaches, dyes and finishes hosiery blends of cotton, nylon, and acrylic. Direct, reactive, acid and basic dyes are used for dyeing the hosiery. The facility operates 3 shifts 3-4 days per week. Currently, 15% of production is white goods (bleach and optical), 15% acid dyeing, 14% direct dyeing, 30% reactive dyeing, and 25% basic dyeing. Some goods are dyed with more than one dye type. A majority of dyed goods are dark shades. The dyehouse is equipped with 6 — 600 pound, 4 — 400 pound, 3 - 200 pound Braun dye machine that operates at a 10:1 liquor ratio for reactive dyeing and 15:1 for basic dyeing. Machines are typically operated at 60% full load. The facility currently produces an average of 20,000 pounds per day of finished hosiery and discharges approximately 140,000 gallons per day of wastewater. DPPEA targeted dark shade dyeing of the hosiery for color analysis due to relative large impact these shades have on effluent color. DPPEA sampled two dyebaths to estimate the percent exhaustion of dye on the hosiery for a black shade (86% cotton with reactive and 14% nylon with acid) and navy shade (80% acrylic with basic and 20% nylon with acid). Figure 1 provides the procedure used for the black shade and Figure 2 provides the procedure used for the navy shade. DPPEA performed a visual determination of the exhaustion for these shades by comparing the spent bath color to a series of diluted samples of the initial dyebath. The dilutions for the black shade were 60%, 70%, 80%, and 90% and for the navy shade 70%, 80%, and 90%. The black shade was sampled twice before the drop once when the color sample was taken and once after a 15- minute extension on the bath. Based on this analysis, the black shade was estimated at 75% dye exhaustion at the time the shade sample was taken and it had dropped below 70% after the additional 15 minutes prior to the actual drop. The navy shade was 85% exhaustion. Final fixation of dyestuff will be impacted by additional processing steps and was not evaluated through this analysis. Fixation of reactive Figure 1 Black Shade 360 lbs in 600 lbs Braun Procedure Heat 100°F Add salt Add soap Run 10 minutes Heat 140°F Add dye assist Add reactive dyes Run 15 minutes Add alkali Run 45 minutes Drop bath 100% 1.0% 2.0% 7.9% 10.0% Ellis Hosiery Mills - 3 - April 28, 2004 dyes on cotton goods is typically in the range of 50 to 80%, acid dyes on nylon is 80 to 93%, and basic dyes on acrylic is 97-981. The final fixation of dye for both the black and navy dyeing would probably be within these ranges for the respective dye types utilized. 3.0 Color Reduction Options Based on the dyebath exhaustion samples study, Ellis appears to be getting average exhaustion rates for the dye types used. The facility may want to consider the following options for increasing exhaustion and reducing the volume of color discharged: > Consider increasing the percentage of full load dyeing. Currently, Ellis dyes all loads at 60% full load. Increasing the • percent of full load should decrease the liquor ratio and increase exhaustion. There may be other issues that limit the facility's ability to increase loads. ➢ Based on the reactive dyebath samples it appears that extending the dye time after alkali addition had a negative affect on dye exhaustion. Ellis may want to consider extending the cycle time prior to alkali addition to increase dye exhaustion. Extending the dye cycle by 15 minutes prior to alkali addition at a cooler temperature (120°F) has been shown to increase exhaustion and reaction efficiency for some cold type reactive dye Figure 2 Navy Shade 360 lbs in 600 lbs Braun Procedure Temp 100°F Add salt Add leveler Add lubricant Add acid Run 1 minute Heat 110oF Add dye assistant 3.0% Add acid dyes 1.2% Add basic dyes 1.1% Rise to 210°F at 3° per minute Run 45 minutes Cool down 120°F Drop bath 15.0% 3.0% 2.0% 1.0% s2. > Minimize dependence on leveling agents that can reduce dye exhaustion. While leveling agents may be necessary the facility may be able to reduce the percent owg utilized while maintaining uniform shade. ➢ Implement a program to track over -dyes, strips, and re -dyes and establish goals of reducing the percentage of goods requiring these practices. 1 Best Management Practices for Pollution Prevention in the Textile Industry, EPA/625/R-96/004 2 Discussions with Dr. Brent Smith NCSU College of Textiles. Ellis Hosiery Mills - 4 - April 28, 2004 Division of Pollution Prevention and Environmental Assistance North Carolina Department of Environment and Natural Resources Color Reduction Assessment Neuville Industries Hickory, North Carolina DPPEA John Burke February 20, 2004 Post Office Box 29569, Raleigh, North Carolina 27626-9569 Telephone: (919) 715-6500; FAX: (919) 715-6794 Neuville Industries - 1 - April 28, 2004 Disclaimer This report is intended to offer information and guidance for identifying opportunities and options for waste reduction. Compliance with environmental and occupational safety and health laws is the sole responsibility of each business. All legal and regulatory references within this document are intended only for informational purposes and are not to be taken as reliable sources of legal reference. Businesses should contact the appropriate legal and regulatory authorities for current regulatory requirements as well as for interpretation and implementation. All references and vendor materials (when available) mentioned in the report are included. Mention of a vendor or manufacturer does not represent an endorsement by the State of North Carolina. Neither the State of North Carolina nor the authors of this report are responsible for practices or procedures implemented by individual firms. Neuville Industries 2 April 28, 2004 Neuville Industries: Color Reduction Assessment 1.0 Introduction The City of Hickory and Neuville Industries requested assistance from the Division of Pollution Prevention and Environmental Assistance (DPPEA) in assessing opportunities for reducing effluent color. The City of Hickory was required by the North Carolina Division of Water Quality to perform a color reduction assessment to identify best management practices for the major sources of color in its wastewater. Neuville Industries was identified by the City of Hickory as a source of color. Color testing of Neuville Industries' effluent was 240 ADMI 2nd half of 2002, 230 ADMI 1' half 2003, and 160 2nd half of 2003. On February 20th, John Burke, of DPPEA, met with David Keaton, Dyehouse Manager, to discuss current operations and sample selected dyebath discharges. The following report provides information on the generation of color from the Neuville Industries' operations and options for potentially reducing the level of color. 2.0 Facility Background and Color Analysis Neuville Industries bleaches, dyes and finishes hosiery blends of cotton, nylon, and acrylic. Direct, acid and basic dyes are used for dyeing the hosiery. The facility operates 3 shifts 5 days per week. Currently, 60% of production is white goods and 40% dyeing. Some goods are dyed with more than one dye type. A majority of dyed goods are dark shades. The dyehouse is equipped with 1 — 300 pound, 5 —160 pound, 5 — 100 pound, 4 — 50 pound paddle dye machines that operate at a 25:1 liquor ratio. Machines are typically operated at 100% full load or more. The facility currently produces an average of 13,000 pounds per day of finished hosiery and discharges approximately 110,000 gallons per day of wastewater.. DPPEA targeted dark shade dyeing of the hosiery for color analysis due to relative large impact these shades have on effluent color. DPPEA sampled two dyebaths to estimate the percent exhaustion of dye on the hosiery for a black shade (75% cotton with direct and 25% nylon with acid) and navy shade (75% cotton with direct and 25% nylon with acid). Figure 1 provides the procedure used for the black shade and Figure 2 provides the procedure used for the navy shade. Figure 1 Black Shade 260 lbs in 160 lbs Paddle Procedure Fill tub Add wetter 2.0% Add acid dyes 0.8% Heat to 190°F Add direct dyes 3.6% Heat to 200°F Heat to 206°F at 1 ° per minute Hold 10 minutes Add Salt 4.8% Run 5 minutes Add Salt Run 5 minutes Add Salt Add Sulfate Run 20 minutes Drop bath 14.4% 31.2% 2.0% DPPEA performed a visual determination of the exhaustion for these shades by comparing the spent bath color to a series of diluted samples of the initial dyebath. The dilutions for the black shade were 70%, 80%, and 90% and for the navy shade 70%, 80%, and 90%. Based on this analysis, the black shade was estimated at 90% dye exhaustion and the navy shade was 85% exhaustion. Final fixation of dyestuff will be impacted by additional processing steps and was not evaluated through this analysis. Fixation of direct dyes on cotton goods is typically in the range of 70 to Neuville Industries 3 April 28, 2004 95% and acid dyes on nylon is 80 to 93%'. The final fixation of dye for both the black and navy dyeing would probably be within these ranges for the respective dye types utilized. 3.0 Color Reduction Options Based on the dyebath exhaustion samples study, Neuville appears to be getting good exhaustion rates for the dyebaths analyzed types used. The facility should continue efforts to maintain high exhaustion of dyestuffs to reduce color in the effluent. The facility may want to consider dry clean-up only in the dye room to eliminate the disposal of raw dyes into the wastewater. Figure 2 Navy Shade 206 lbs in 160 lbs Paddle Procedure Fill tub Add wetter 2.0% Add acid dyes 2.0% Heat to 190°F Add direct dyes 2.9% Heat to 200°F Heat to 206°F at 1 ° per minute Hold 10 minutes Add Salt 4.8% Run 5 minutes Add Salt 14.4% Run 5 minutes Add Salt 31.2% Add Sulfate 2.0% Run 20 minutes Drop bath l Best Management Practices for Pollution Prevention in the Textile Industry, EPA/625/R-96/004 Neuville Industries - 4 - April 28, 2004 Division of Pollution Prevention and Environmental Assistance North Carolina Department of Environment and Natural Resources Color Reduction Assessment Nu -Sox Finishing Hickory, North Carolina DPPEA John Burke March 10, 2004 Post Office Box 29569, Raleigh, North Carolina 27626-9569 Telephone: (919) 715-6500; FAX: (919) 715-6794 Nu -Sox Finishing - 1 - April 28, 2004 Disclaimer This report is intended to offer information and guidance for identifying opportunities and options for waste reduction. Compliance with environmental and occupational safety and health laws is the sole responsibility of each business. All legal and regulatory references within this document are intended only for informational purposes and are not to be taken as reliable sources of legal reference. Businesses should contact the appropriate legal and regulatory authorities for current regulatory requirements as well as for interpretation and implementation. All references and vendor materials (when available) mentioned in the report are included. Mention of a vendor or manufacturer does not represent an endorsement by the State of North Carolina. Neither the State of North Carolina nor the authors of this report are responsible for practices or procedures implemented by individual firms. Nu -Sox Finishing 2 April 28, 2004 Nu -Sox Finishing: Color Reduction Assessment 1.0 Introduction The City of Hickory and Nu -Sox Finishing requested assistance from the Division of Pollution Prevention and Environmental Assistance (DPPEA) in assessing opportunities for reducing effluent color. The City of Hickory was required by the North Carolina Division of Water Quality to perform a color reduction assessment to identify best management practices for the major sources of color in its wastewater. Nu -Sox Finishing was identified by the City of Hickory as a source of color. Color testing of Nu -Sox Finishing's effluent was 5600 ADMI 2" half of 2002, 343 ADMI 1st half 2003, and <184 2" half of 2003. On March 10th, John Burke, of DPPEA, met with Micheal Banks, Owner, to discuss current operations and sample selected dyebath discharges. The following report provides information on the generation of color from the Nu -Sox Finishing' operations and options for potentially reducing the level of color. 2.0 Facility Background and Color Analysis Nu -Sox Finishing bleaches, dyes and finishes hosiery blends of cotton and nylon. Direct and acid dyes are used for dyeing the hosiery. The facility operates 1 shifts 4 days per week. Currently, 90% of production is white goods and 10% dyeing. The dyehouse is equipped with 1 — 400 pound, 1 — 250 pound, 1 —150 pound, 1 — 100 pound, 1 — 50 pound, and 2 — 25 pound paddle dye machines that operate at a 25:1 liquor ratio. Machines are typically operated at 100% full Toad or more. The facility currently produces an average of 3,000 pounds per day of finished hosiery and discharges approximately 1,000 gallons per day of wastewater. DPPEA targeted dark shade dyeing of the hosiery for color analysis due to relative large impact these shades have on effluent color. DPPEA sampled two dyebaths to estimate the percent exhaustion of dye on the hosiery for a black shade and a navy shade, both used direct and acid dyes. Figure 1 provides the procedure used for the black shade and Figure 2 provides the procedure used for the navy shade. DPPEA performed a visual determination of the exhaustion for these shades by comparing the spent bath color to a series of diluted samples of the initial dyebath. The dilutions for the black shade were 80%, 90% and 95% for the navy shade 60%, 70%, and 80%. Based on this analysis, the black shade was estimated at +90% dye exhaustion and the navy shade was just above 70% exhaustion. Final fixation of dyestuff will be impacted by additional processing steps and was not evaluated through this analysis. Fixation of direct dyes on cotton goods is typically in the range of 70 to Figure 1 Black Shade 30 lbs in 50 lbs Paddle Procedure Fill tub Add leveler Add soda ash Add acid dyes Add direct dyes Heat to 210°F Hold 10 minutes Add salt in three parts Hold 10 minutes Add acetic acid Hold 15 minutes Reduce Heat Hold for 15 minutes Drop bath 1.0% 0.5% 0.7% 5.6% 60.0% 0.5% Nu -Sox Finishing 3 - April 28, 2004 95% and acid dyes on nylon is 80 to 93%'. The final fixation of dye for both the black would probably be within this range for the respective dye types utilized but the navy would be below these ranges. 3.0 Color Reduction Options Based on the dyebath exhaustion samples study, there may be some opportunities to increase dye exhaustion. The facility may want to consider the following options. ➢ Installing temperature gauges on all the dye machines to improve control of rate of temperature increase and set operating temperatures. > Ensure operators are adding salt in required amounts and emphasize the importance of staggering salt additions. The black shade salt addition was added in three parts but that did not appear to be the case for the navy shade. > Optimize time -temperature profile scheme to achieve maximum exhaustion of dye. Work with dye supplier to identify most appropriate profile for darker shades. Rate of temperature rise, final hold temperature and length of exhaustion phase will impact final exhaustion. > Reduce dependence on auxiliaries like dye levelers that impede exhaustion. Assess the value in adding sulfate and leveler at the end of the dye cycle, which may reduce dye exhaustion. The increase percent of leveler used in the navy bath may have impacted exhaustion levels. Figure 2 Navy Shade 196 lbs in 150 lbs Paddle Procedure Fill tub Add leveler 2.0% Add acid dyes 0.4% Add direct dyes 2.5% Heat to 210°F Hold 10 minutes Add Salt in three parts 40.0% Hold 10 minutes Add Ammonium Sulfate 1.0% Hold 15 minutes Reduce heat Hold 15 minutes Add Leveler 0.5% Hold 10 minutes Drop bath 1 Best Management Practices for Pollution Prevention in the Textile Industry, EPA/625/R-96/004 Nu -Sox Finishing - 4 - April 28, 2004 Division of Pollution Prevention and Environmental Assistance North Carolina Department of Environment and Natural Resources Color Reduction Assessment Spectrum Textured Yarns Hickory, North Carolina DPPEA John Burke March 23, 2004 Post Office Box 29569, Raleigh, North Carolina 27626-9569 Telephone: (919) 715-6500; FAX: (919) 715-6794 Spectrum Textured Yarns - 1 - April 28, 2004 Disclaimer This report is intended to offer information and guidance for identifying opportunities and options for waste reduction. Compliance with environmental and occupational safety and health laws is the sole responsibility of each business. All legal and regulatory references within this document are intended only for informational purposes and are not to be taken as reliable sources of legal reference. Businesses should contact the appropriate legal and regulatory authorities for current regulatory requirements as well as for interpretation and implementation. All references and vendor materials (when available) mentioned in the report are included. Mention of a vendor or manufacturer does not represent an endorsement by the State of North Carolina. Neither the State of North Carolina nor the authors of this report are responsible for practices or procedures implemented by individual firms. Spectrum Textured Yarns - 2 April 28, 2004 Spectrum Textured Yarns: Color Reduction Assessment 1.0 Introduction The City of Hickory and Spectrum Textured Yarns requested assistance from the. Division of Pollution Prevention and Environmental Assistance (DPPEA) in assessing opportunities for reducing effluent color. The City of Hickory was required by the North Carolina Division of Water Quality to perform a color reduction assessment to identify best management practices for the major sources of color in its wastewater. Spectrum Textured Yarns was identified by the Cif of Hickory as a source of color. Color testing of Spectrum Textured Yarns' effluent was 410 ADMI 2 half of 2002, 220 ADMI 1' half 2003, and 382 2nd half of 2003. On March 23'd, John Burke, of DPPEA, met with Tim Harris, Dyehouse Manager, to discuss current operations and sample selected dyebath discharges. The following report provides information on the generation of color from the Spectrum Textured Yarns' operations and options for potentially reducing the level of color. 2.0 Facility Background and Color Analysis Spectrum Textured Yarns dyes and finishes polyester and nylon yarn. Disperse and acid dyes are used for dyeing the yarn. The facility operates 3 shifts 6 days per week. 100% of production is dyed goods. The dyehouse is equipped with 3 — 2200 pound, 2 —1100 pound, 1 — 800 pound, 2 — 525 pound, 2 — 250 pound, and 1 —180 pound package dye machines that operate at a 8:1 liquor ratio. Machines are typically operated at 90% of full load. The facility currently produces an average of 33,000 pounds per day of finished yarn and discharges approximately 400,000 gallons per day of wastewater. DPPEA targeted dark shade dyeing of polyester yarn for color analysis due to relative large impact these shades have on effluent color. DPPEA sampled one dyebath to estimate the percent exhaustion of dye on the yarn for a black shade using disperse dyes. Figure 1 provides the procedure used for the black shade. DPPEA performed a visual determination of the exhaustion for these shades by comparing the spent bath color to a series of diluted samples of the initial dyebath. The dilutions for the black shade were 80%, 90% and 95%. Based on this analysis, the black shade was estimated at +90% dye exhaustion. Final fixation of dyestuff will be impacted by additional processing steps and was not evaluated through this analysis. Fixation of disperse dyes on polyester goods is typically in the range of 80 to 92%'. The final fixation of dye for the black would probably be within this range for the respective dye types utilized but the navy would be below these ranges. 3.0 Color Reduction Options Figure 1 Black Shade 2223 lbs in 2400 lbs Package Procedure Fill tub 140°F Add acetic acid 56% Add lubricant Hold 9 min Add dispersant Add disperse dyes Hold 3 min Circulate 5 min at 205°F Circulate 5 min at 230°F Circulate 25 min at 272°F Circulate 1 min at 170°F Drain 0.5% 0.7% 0.7% 3.8% 1 Best Management Practices for Pollution Prevention in the Textile Industry, EPA/625/R-96/004 Spectrum Textured Yarns - 3 - April 28, 2004 Based on the dyebath exhaustion samples study, Spectrum Yarns appears to be getting high exhaustion. DPPEA does not have any suggestions related to these dyeing operations. This dye sample did not include the using of leveling agents, which can significantly reduce exhaustion if added in excess. Spectrum Textured Yarns 4 April 28, 2004 Division of Pollution Prevention and Environmental Assistance North Carolina Department of Environment and Natural Resources Color Reduction Assessment Moretz Mills Hickory, North Carolina DPPEA John Burke April 28, 2004 Post Office Box 29569, Raleigh, North Carolina 27626-9569 Telephone: (919) 715-6500: FAX: (919) 715-6794 Moretz Mills - 1 - April 28. 2004 • Disclaimer This report is intended to offer information and guidance for identifying opportunities and options for waste reduction. Compliance with environmental and occupational safety and health laws is the sole responsibility of each business. All legal and regulatory references within this document are intended only for informational purposes and are not to be taken as reliable sources of legal reference. Businesses should contact the appropriate legal and regulatory authorities for current regulatory requirements as well as for interpretation and implementation. All references and vendor materials (when available) mentioned in the report are included. Mention of a vendor or manufacturer does not represent an endorsement by the State of North Carolina. Neither the State of North Carolina nor the authors of this report are responsible for practices or procedures implemented by individual firms. Moretz Mills 2 April 28, 2004 ctp Moretz Mills: Color Reduction Assessment 1.0 Introduction The City of Hickory and Moretz Mills requested assistance from the Division of Pollution Prevention and Environmental Assistance (DPPEA) in assessing opportunities for reducing effluent color. The City of Hickory was required by the North Carolina Division of Water Quality to perform a color reduction assessment to identify best management practices for the major sources of color in its wastewater. Moretz Mills was identified by the City of Hickory as a source of color. Color testing of Moretz Mills' effluent was 703 ADMI 2nd half of 2002, 240 ADMI 1' half 2003, and 93 2"d half of 2003. On April 28th, John Burke, of DPPEA, talked with Bennett Hanchey regarding the operations at the Hickory facility. The company is not currently dyeing at the Hickory facility. 2.0 Facility Background Moretz Mills bleaches, washes and finishes hosiery. The facility operates 1 shift 5 days per week produces 4,000 pounds of hosiery and discharges 27,000 gallons per day. The dyehouse is equipped with 2 — 600 pound Braun dyeing machines. 3.0 Color Reduction Options DPPEA does not have any suggestions related to these operations since dyeing is not currently performed. Moretz Mills 3 - April 28, 2004