NC0000272_Analytical Results 6-28-2019_20220401

Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
June 28, 2019
Hartwell Carson
Mountain True
29 N market St Suite 610
Asheville, NC 28801
RE: Project: CHAMPION LANDFILLS 6-19-19
Pace Project No.: 92434177
Dear Hartwell Carson:
Enclosed are the analytical results for sample(s) received by the laboratory on June 24, 2019. The
results relate only to the samples included in this report. Results reported herein conform to the most
current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where
applicable, unless otherwise noted in the body of the report.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Chris Derouen
[e-mail]
[phone]
Project Manager
Enclosures
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC. Page 1 of 13

CERTIFICATIONS
Project: CHAMPION LANDFILLS 6-19-19
Pace Project No.: 92434177
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Asheville Certification Ds
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
VirginiaNELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
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SAMPLE ANALYTE COUNT
Project: CHAMPION LANDFILLS 6-19-19
Pace Project No.: 92434177
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Lab ID Sample ID
Method
Analytes
Analysts Reported Laboratory
92434177001 LF1
92434177002 LF 1-2
92434177003 LF 1-3
92434177004 LF 2
EPA 200.7 Rev 4.4 1994 SH1 19 PASI-A
EPA 245.1 Rev 3.0 1994 JMW1 1 PASI-A
EPA 200.7 Rev 4.4 1994 SH1 19 PASI-A
EPA 245.1 Rev 3.0 1994 JMW1 1 PASI-A
EPA 200.7 Rev 4.4 1994 SH1 19 PASI-A
EPA 245.1 Rev 3.0 1994 JMW1 1 PASI-A
EPA 200.7 Rev 4.4 1994 SH1 19 PASI-A
EPA 245.1 Rev 3.0 1994 JMW1 1 PASI-A
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC. Page 3 of 13

ANALYTICAL RESULTS
Project: CHAMPION LANDFILLS 6-19-19
Pace Project No.: 92434177
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Sample: LF1 Lab ID: 92434177001 Collected: 06/19/19 14:30 Received: 06/24/19 11:00 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
200.7 MET ICP Analytical Method: EPA 200.7 Rev 4.4 1994 Preparation Method: EPA 200.7 Rev 4.4 1994
Aluminum ND ug/L 100 1 06/26/19 12:11 06/27/19 04:31 7429-90-5
Arsenic ND ug/L 10.0 1 06/26/19 12:11 06/27/19 04:31 7440-38-2
Barium 38.7 ug/L 5.0 1 06/26/19 12:11 06/27/19 04:31 7440-39-3
Boron ND ug/L 50.0 1 06/26/19 12:11 06/27/19 04:31 7440-42-8
Cadmium ND ug/L 1.0 1 06/26/19 12:11 06/27/19 04:31 7440-43-9
Chromium ND ug/L 5.0 1 06/26/19 12:11 06/27/19 04:31 7440-47-3
Cobalt ND ug/L 5.0 1 06/26/19 12:11 06/27/19 04:31 7440-48-4
Copper ND ug/L 5.0 1 06/26/19 12:11 06/27/19 04:31 7440-50-8
Iron 22300 ug/L 50.0 1 06/26/19 12:11 06/27/19 04:31 7439-89-6
Lead ND ug/L 5.0 1 06/26/19 12:11 06/27/19 04:31 7439-92-1
Manganese 6070 ug/L 5.0 1 06/26/19 12:11 06/27/19 04:31 7439-96-5
Molybdenum ND ug/L 5.0 1 06/26/19 12:11 06/27/19 04:31 7439-98-7
Nickel ND ug/L 5.0 1 06/26/19 12:11 06/27/19 04:31 7440-02-0
Selenium ND ug/L 10.0 1 06/26/19 12:11 06/27/19 04:31 7782-49-2
Strontium 87.7 ug/L 5.0 1 06/26/19 12:11 06/27/19 04:31 7440-24-6
Thallium ND ug/L 10.0 1 06/26/19 12:11 06/27/19 04:31 7440-28-0
Hardness, Total(SM 2340B) 91200 ug/L 662 1 06/26/19 12:11 06/27/19 04:31
Vanadium ND ug/L 5.0 1 06/26/19 12:11 06/27/19 04:31 7440-62-2
Zinc 105 ug/L 10.0 1 06/26/19 12:11 06/27/19 04:31 7440-66-6
245.1 Mercury Analytical Method: EPA 245.1 Rev 3.0 1994 Preparation Method: EPA 245.1 Rev 3.0 1994
Mercury ND ug/L 0.20 1 06/25/19 10:56 06/25/19 13:40 7439-97-6
Sample: LF 1-2 Lab ID: 92434177002 Collected: 06/19/19 14:50 Received: 06/24/19 11:00 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
200.7 MET ICP Analytical Method: EPA 200.7 Rev 4.4 1994 Preparation Method: EPA 200.7 Rev 4.4 1994
Aluminum ND ug/L 100 1 06/26/19 12:11 06/27/19 04:41 7429-90-5
Arsenic ND ug/L 10.0 1 06/26/19 12:11 06/27/19 04:41 7440-38-2
Barium 307 ug/L 5.0 1 06/26/19 12:11 06/27/19 04:41 7440-39-3
Boron 803 ug/L 50.0 1 06/26/19 12:11 06/27/19 04:41 7440-42-8
Cadmium ND ug/L 1.0 1 06/26/19 12:11 06/27/19 04:41 7440-43-9
Chromium ND ug/L 5.0 1 06/26/19 12:11 06/27/19 04:41 7440-47-3
Cobalt 5.4 ug/L 5.0 1 06/26/19 12:11 06/27/19 04:41 7440-48-4
Copper ND ug/L 5.0 1 06/26/19 12:11 06/27/19 04:41 7440-50-8
Iron 14500 ug/L 50.0 1 06/26/19 12:11 06/27/19 04:41 7439-89-6
Lead ND ug/L 5.0 1 06/26/19 12:11 06/27/19 04:41 7439-92-1
Manganese 1010 ug/L 5.0 1 06/26/19 12:11 06/27/19 04:41 7439-96-5
Molybdenum 19.7 ug/L 5.0 1 06/26/19 12:11 06/27/19 04:41 7439-98-7
Nickel ND ug/L 5.0 1 06/26/19 12:11 06/27/19 04:41 7440-02-0
Selenium ND ug/L 10.0 1 06/26/19 12:11 06/27/19 04:41 7782-49-2
Strontium 3260 ug/L 5.0 1 06/26/19 12:11 06/27/19 04:41 7440-24-6
Thallium ND ug/L 10.0 1 06/26/19 12:11 06/27/19 04:41 7440-28-0
Hardness, Total(SM 2340B) 598000 ug/L 662 1 06/26/19 12:11 06/27/19 04:41
REPORT OF LABORATORY ANALYSIS
Date: 06/28/2019 08:11 AM
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without the written consent of Pace Analytical Services, LLC. Page 4 of 13

ANALYTICAL RESULTS
Project: CHAMPION LANDFILLS 6-19-19
Pace Project No.: 92434177
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Sample: LF 1-2 Lab ID: 92434177002 Collected: 06/19/19 14:50 Received: 06/24/19 11:00 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
200.7 MET ICP Analytical Method: EPA 200.7 Rev 4.4 1994 Preparation Method: EPA 200.7 Rev 4.4 1994
Vanadium ND ug/L 5.0 1 06/26/19 12:11 06/27/19 04:41 7440-62-2
Zinc ND ug/L 10.0 1 06/26/19 12:11 06/27/19 04:41 7440-66-6
245.1 Mercury Analytical Method: EPA 245.1 Rev 3.0 1994 Preparation Method: EPA 245.1 Rev 3.0 1994
Mercury ND ug/L 0.20 1 06/25/19 10:56 06/25/19 13:42 7439-97-6
Sample: LF 1-3 Lab ID: 92434177003 Collected: 06/19/19 15:00 Received: 06/24/19 11:00 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
200.7 MET ICP Analytical Method: EPA 200.7 Rev 4.4 1994 Preparation Method: EPA 200.7 Rev 4.4 1994
Aluminum ND ug/L 100 1 06/26/19 12:11 06/27/19 04:44 7429-90-5
Arsenic ND ug/L 10.0 1 06/26/19 12:11 06/27/19 04:44 7440-38-2
Barium 377 ug/L 5.0 1 06/26/19 12:11 06/27/19 04:44 7440-39-3
Boron 639 ug/L 50.0 1 06/26/19 12:11 06/27/19 04:44 7440-42-8
Cadmium ND ug/L 1.0 1 06/26/19 12:11 06/27/19 04:44 7440-43-9
Chromium ND ug/L 5.0 1 06/26/19 12:11 06/27/19 04:44 7440-47-3
Cobalt ND ug/L 5.0 1 06/26/19 12:11 06/27/19 04:44 7440-48-4
Copper ND ug/L 5.0 1 06/26/19 12:11 06/27/19 04:44 7440-50-8
Iron 3470 ug/L 50.0 1 06/26/19 12:11 06/27/19 04:44 7439-89-6
Lead ND ug/L 5.0 1 06/26/19 12:11 06/27/19 04:44 7439-92-1
Manganese 1940 ug/L 5.0 1 06/26/19 12:11 06/27/19 04:44 7439-96-5
Molybdenum 16.0 ug/L 5.0 1 06/26/19 12:11 06/27/19 04:44 7439-98-7
Nickel ND ug/L 5.0 1 06/26/19 12:11 06/27/19 04:44 7440-02-0
Selenium ND ug/L 10.0 1 06/26/19 12:11 06/27/19 04:44 7782-49-2
Strontium 2070 ug/L 5.0 1 06/26/19 12:11 06/27/19 04:44 7440-24-6
Thallium ND ug/L 10.0 1 06/26/19 12:11 06/27/19 04:44 7440-28-0
Hardness, Total(SM 2340B) 418000 ug/L 662 1 06/26/19 12:11 06/27/19 04:44
Vanadium ND ug/L 5.0 1 06/26/19 12:11 06/27/19 04:44 7440-62-2
Zinc ND ug/L 10.0 1 06/26/19 12:11 06/27/19 04:44 7440-66-6
245.1 Mercury Analytical Method: EPA 245.1 Rev 3.0 1994 Preparation Method: EPA 245.1 Rev 3.0 1994
Mercury ND ug/L 0.20 1 06/25/19 10:56 06/25/19 13:44 7439-97-6
Sample: LF 2 Lab ID: 92434177004 Collected: 06/19/19 16:00 Received: 06/24/19 11:00 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
200.7 MET ICP Analytical Method: EPA 200.7 Rev 4.4 1994 Preparation Method: EPA 200.7 Rev 4.4 1994
Aluminum ND ug/L 100 1 06/26/19 12:11 06/27/19 04:47 7429-90-5
Arsenic ND ug/L 10.0 1 06/26/19 12:11 06/27/19 04:47 7440-38-2
Barium 84.8 ug/L 5.0 1 06/26/19 12:11 06/27/19 04:47 7440-39-3
Boron ND ug/L 50.0 1 06/26/19 12:11 06/27/19 04:47 7440-42-8
Cadmium 1.1 ug/L 1.0 1 06/26/19 12:11 06/27/19 04:47 7440-43-9
REPORT OF LABORATORY ANALYSIS
Date: 06/28/2019 08:11 AM
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without the written consent of Pace Analytical Services, LLC. Page 5 of 13

ANALYTICAL RESULTS
Project: CHAMPION LANDFILLS 6-19-19
Pace Project No.: 92434177
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Sample: LF 2 Lab ID: 92434177004 Collected: 06/19/19 16:00 Received: 06/24/19 11:00 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
200.7 MET ICP Analytical Method: EPA 200.7 Rev 4.4 1994 Preparation Method: EPA 200.7 Rev 4.4 1994
Chromium ND ug/L 5.0 1 06/26/19 12:11 06/27/19 04:47 7440-47-3
Cobalt ND ug/L 5.0 1 06/26/19 12:11 06/27/19 04:47 7440-48-4
Copper ND ug/L 5.0 1 06/26/19 12:11 06/27/19 04:47 7440-50-8
Iron 537 ug/L 50.0 1 06/26/19 12:11 06/27/19 04:47 7439-89-6
Lead ND ug/L 5.0 1 06/26/19 12:11 06/27/19 04:47 7439-92-1
Manganese 232 ug/L 5.0 1 06/26/19 12:11 06/27/19 04:47 7439-96-5
Molybdenum ND ug/L 5.0 1 06/26/19 12:11 06/27/19 04:47 7439-98-7
Nickel ND ug/L 5.0 1 06/26/19 12:11 06/27/19 04:47 7440-02-0
Selenium ND ug/L 10.0 1 06/26/19 12:11 06/27/19 04:47 7782-49-2
Strontium 111 ug/L 5.0 1 06/26/19 12:11 06/27/19 04:47 7440-24-6
Thallium ND ug/L 10.0 1 06/26/19 12:11 06/27/19 04:47 7440-28-0
Hardness, Total(SM 2340B) 66400 ug/L 662 1 06/26/19 12:11 06/27/19 04:47
Vanadium ND ug/L 5.0 1 06/26/19 12:11 06/27/19 04:47 7440-62-2
Zinc ND ug/L 10.0 1 06/26/19 12:11 06/27/19 04:47 7440-66-6
245.1 Mercury Analytical Method: EPA 245.1 Rev 3.0 1994 Preparation Method: EPA 245.1 Rev 3.0 1994
Mercury ND ug/L 0.20 1 06/25/19 10:56 06/25/19 13:47 7439-97-6
REPORT OF LABORATORY ANALYSIS
Date: 06/28/2019 08:11 AM
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QUALITY CONTROL DATA
Project: CHAMPION LANDFILLS 6-19-19
Pace Project No.: 92434177
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QC Batch: 483064 Analysis Method: EPA 245.1 Rev 3.0 1994
QC Batch Method: EPA 245.1 Rev 3.0 1994 Analysis Description: 245.1 Mercury
Associated Lab Samples: 92434177001, 92434177002, 92434177003, 92434177004
METHOD BLANK: 2611205 Matrix: Water
Associated Lab Samples: 92434177001, 92434177002, 92434177003, 92434177004
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Mercury ug/L ND 0.20 06/25/1913:18
LABORATORY CONTROL SAMPLE: 2611206
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Mercury ug/L 2.5 2.7 107 85-115
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2611207 2611208
MS MSD
92434025001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Mercury
ug/L ND 2.5 2.5 2.7 2.7 108 107 70-130 1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
Date: 06/28/2019 08:11 AM
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QUALITY CONTROL DATA
Project: CHAMPION LANDFILLS 6-19-19
Pace Project No.: 92434177
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QC Batch: 483330 Analysis Method: EPA 200.7 Rev 4.4 1994
QC Batch Method: EPA 200.7 Rev 4.4 1994 Analysis Description: 200.7 MET
Associated Lab Samples: 92434177001, 92434177002, 92434177003, 92434177004
METHOD BLANK: 2612364 Matrix: Water
Associated Lab Samples: 92434177001, 92434177002, 92434177003, 92434177004
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Aluminum ug/L ND 100 06/27/19 03:44
Arsenic ug/L ND 10.0 06/27/19 03:44
Barium ug/L ND 5.0 06/27/19 03:44
Boron ug/L ND 50.0 06/27/19 03:44
Cadmium ug/L ND 1.0 06/27/19 03:44
Chromium ug/L ND 5.0 06/27/19 03:44
Cobalt ug/L ND 5.0 06/27/19 03:44
Copper ug/L ND 5.0 06/27/19 03:44
Hardness, Total(SM 2340B) ug/L ND 662 06/27/19 03:44
Iron ug/L ND 50.0 06/27/19 03:44
Lead ug/L ND 5.0 06/27/19 03:44
Manganese ug/L ND 5.0 06/27/19 03:44
Molybdenum ug/L ND 5.0 06/27/19 03:44
Nickel ug/L ND 5.0 06/27/19 03:44
Selenium ug/L ND 10.0 06/27/19 03:44
Strontium ug/L ND 5.0 06/27/19 03:44
Thallium ug/L ND 10.0 06/27/19 03:44
Vanadium ug/L ND 5.0 06/27/19 03:44
Zinc ug/L ND 10.0 06/27/19 03:44
LABORATORY CONTROL SAMPLE: 2612365
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Aluminum ug/L 5000 5000 100 85-115
Arsenic ug/L 500 472 94 85-115
Barium ug/L 500 509 102 85-115
Boron ug/L 500 500 100 85-115
Cadmium ug/L 500 504 101 85-115
Chromium ug/L 500 505 101 85-115
Cobalt ug/L 500 499 100 85-115
Copper ug/L 500 503 101 85-115
Hardness, Total(SM 2340B) ug/L 33100 32100 97 85-115
Iron ug/L 5000 4830 97 85-115
Lead ug/L 500 490 98 85-115
Manganese ug/L 500 489 98 85-115
Molybdenum ug/L 500 477 95 85-115
Nickel ug/L 500 502 100 85-115
Selenium ug/L 500 493 99 85-115
Strontium ug/L 500 491 98 85-115
Thallium ug/L 500 476 95 85-115
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
Date: 06/28/2019 08:11 AM
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without the written consent of Pace Analytical Services, LLC. Page 8 of 13

QUALITY CONTROL DATA
Project: CHAMPION LANDFILLS 6-19-19
Pace Project No.: 92434177
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
LABORATORY CONTROL SAMPLE: 2612365
Parameter
Units
Spike LCS LCS % Rec
Conc. Result % Rec Limits
Qualifiers
Vanadium
Zinc
ug/L
ug/L
500 490 98 85-115
500 489 98 85-115
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2612366
MS
92434026001 Spike
Parameter Units Result Conc.
2612367
MSD
Spike MS MSD MS MSD % Rec
Conc. Result Result % Rec % Rec Limits RPD Qual
Aluminum
Arsenic
Barium
Boron
Cadmium
Chromium
Cobalt
Copper
Hardness, Total(SM 2340B)
Iron
Lead
Manganese
Molybdenum
Nickel
Selenium
Strontium
Thallium
Vanadium
Zinc
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ND
ND
6.6
ND
ND
ND
ND
17.6
5730
88.1
ND
16.2
ND
ND
ND
23.0
ND
ND
168
5000 5000 5130 4830 101 95 70-130 6
500 500 474 456 95 91 70-130 4
500 500 507 480 100 95 70-130 5
500 500 512 490 99 95 70-130 4
500 500 508 485 102 97 70-130 5
500 500 501 473 100 95 70-130 6
500 500 493 469 99 94 70-130 5
500 500 511 490 99 94 70-130 4
33100 33100 38000 36100 98 92 70-130 5
5000 5000 4880 4640 96 91 70-130 5
500 500 491 464 97 92 70-130 6
500 500 500 473 97 91 70-130 6
500 500 469 447 94 89 70-130 5
500 500 497 472 99 94 70-130 5
500 500 512 497 102 99 70-130 3
500 500 506 480 96 91 70-130 5
500 500 476 451 95 90 70-130 5
500 500 484 459 97 92 70-130 5
500 500 665 636 99 94 70-130 4
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2612368
MS
92434177001 Spike
Parameter Units Result Conc.
2612369
MSD
Spike MS MSD MS MSD
Conc. Result Result % Rec % Rec
% Rec
Limits RPD Qual
Aluminum
Arsenic
Barium
Boron
Cadmium
Chromium
Cobalt
Copper
Hardness, Total(SM 2340B)
Iron
Lead
Manganese
Molybdenum
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ND
ND
38.7
ND
ND
ND
ND
ND
91200
22300
ND
6070
ND
5000 5000 4800 4800 96 96
500 500 447 460 89 92
500 500 512 514 95 95
500 500 486 496 95 97
500 500 475 490 95 98
500 500 470 476 94 95
500 500 461 470 92 94
500 500 472 481 94 96
33100 33100 123000 121000 96 89
5000 5000 27100 26500 97 84
500 500 458 468 91 93
500 500 6550 6430 96 73
500 500 441 453 88 91
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
0
3
0
2
3
1
2
2
2
2
2
2
3
Date: 06/28/2019 08:11 AM
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without the written consent of Pace Analytical Services, LLC. Page 9 of 13

QUALITY CONTROL DATA
Project: CHAMPION LANDFILLS 6-19-19
Pace Project No.: 92434177
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2612368 2612369
MS MSD
92434177001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Nickel ug/L ND 500 500 460 472 92 94 70-130 3
Selenium ug/L ND 500 500 480 496 96 99 70-130 3
Strontium ug/L 87.7 500 500 552 552 93 93 70-130 0
Thallium ug/L ND 500 500 444 458 88 91 70-130 3
Vanadium ug/L ND 500 500 462 467 92 93 70-130 1
Zinc ug/L 105 500 500 569 574 93 94 70-130 1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
Date: 06/28/2019 08:11 AM
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without the written consent of Pace Analytical Services, LLC. Page 10 of 13

QUALIFIERS
Project: CHAMPION LANDFILLS 6-19-19
Pace Project No.: 92434177
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
PASI-A Pace Analytical Services - Asheville
REPORT OF LABORATORY ANALYSIS
Date: 06/28/2019 08:11 AM
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 11 of 13

Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: CHAMPION LANDFILLS 6-19-19
Pace Project No.: 92434177
Lab ID Sample ID
Analytical
QC Batch Method QC Batch Analytical Method Batch
92434177001 LF1 EPA 200.7 Rev 4.4 1994 483330 EPA 200.7 Rev 4.4 1994 483435
92434177002 LF 1-2 EPA 200.7 Rev 4.4 1994 483330 EPA 200.7 Rev 4.4 1994 483435
92434177003 LF 1-3 EPA 200.7 Rev 4.4 1994 483330 EPA 200.7 Rev 4.4 1994 483435
92434177004 LF 2 EPA 200.7 Rev 4.4 1994 483330 EPA 200.7 Rev 4.4 1994 483435
92434177001 LF1 EPA 245.1 Rev 3.0 1994 483064 EPA 245.1 Rev 3.0 1994 483105
92434177002 LF 1-2 EPA 245.1 Rev 3.0 1994 483064 EPA 245.1 Rev 3.0 1994 483105
92434177003 LF 1-3 EPA 245.1 Rev 3.0 1994 483064 EPA 245.1 Rev 3.0 1994 483105
92434177004 LF 2 EPA 245.1 Rev 3.0 1994 483064 EPA 245.1 Rev 3.0 1994 483105
REPORT OF LABORATORY ANALYSIS
Date: 06/28/2019 08:11 AM
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 12 of 13

Relinquished by/Company: (Signature)
Relinquished by/Company: (Signature)
Relin uished by/Company: (Signature)
Customer Remarks / Special Conditions / Possible hazards:
),]
__
i
V
P
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Customer Sample ID
* Matrix Codes (insert in Matrix box below): Drinking Water (DW), Ground Water (GW), Wastewater (WW),
Product (P), Soil/Solid (SL), Oil (OL), Wipe (WP), Air (AR), Tissue (TS), Bioassay (B), Vapor (V), Other (OT)
Sample Disposal:
[ ] Dispose as appropriate [ ] Return
[ ] Archive:
I ] Hold:
0
=
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Collected By (pr"nt):
Phone:
Email:
ICustom�erJProject Name/Numbfer:: j1�
CY `�`Y • `pk.OL \ lam^ W' 0'
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!Report To:
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Company:
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CHAIN -OF -CUSTODY Analytical Request Document
Pace Analytical
Chain -of -Custody is a LEGAL DOCUMENT - Complete all relevent fields
).
Matrix *
Rush:
[ ] Same Day [ ] Next Day
[ ] 2 Day [ ] 3 Day [ ] 4 Day [ ] 5 Day
(Expedite Charges Apply)
Turnaround Date Required:
Purchase Order#:
Quote #:
Site/Facility ID #:
rs
QD
Date/Time:
o
C7
rt.
Collected [or
Composite Start)
State: County/City: Time Zone Collected:
/ [ ]PT[ ]MT[ ]CT [ ]ET
Site Collection Info/Address:
m
d
Billing Information:
-1
2
._
i1 ) Po
r
i
Radchem sample(s) screened (<500 cpm): Y N
Packing Material Used:
A/0 N6;
Type of Ice Used: Wet Blue Dry 1 1e
j
r
m
i
Received by/Company: (signature)
feceived by/Company: (Signattret
R ived by/ mpany: (Signat e)
Composite End
Field Filtered (if applicable):
JYes [ ]No
Analysis:
Immediately Packed on Ice:
[ ] Yes [ ] No
DW PWS ID #:
uW Location Code:
Compliance Monitoring?
[ ] Yes [ ] No
4
�1
1
W
w
•
(1
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3
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No
" Preservative Types: (1) nitric acid, (2) sulfuric acid, (3) hydrochloric acid, (4) sodium hydroxide, (5) zinc acetate,
(6) methanol, (7) sodium bisulfate, (3) sodium thiosulfate, (9) hexane, (A) ascorbic acid, (B) ammonium sulfate,
IC)ammonium hydroxide, (D)TSP,)U)Unpreserved,(0) Other
is
X
>(
i 1 A>, as, 6, C/A c, Cu, L.
Samples received via:
FEDEX UPS Ct Courier Pace Courier
Lab Tracking #: 2 34958 5
SHORT HOLDS PRESENT (<72 hours): Y ): N/A
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Date/Time:
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..U.TL, 50, S.-, Hovdrves Jro
Acctnum:
Template:
Prelogin:
PM:
Pe:
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MTiL LAB USE ONLY
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Lab Sample Receipt Checklist:
Custody Seals Present/Intact Y ti NA
Y
Custody Signatures Present Y NA
Collector Signature Present N NA
Bottles Intact N NA
Correct Bottles N NA
Sufficient Volume N NA
Samples Received on Ice Y NA
VOA - Headspace Acceptable Y N 3T�.
USDA Regulated Soils Y N WC.
Samples in Holding Time /N NA
Residual Chlorine Present Y .247(
Cl Strips:
Sample pH AccZejtir V ` N NA
pH Strips:
Sulfide Present Y N y\ee
Lead Acetate Strips:
LAB USE ONLY:
Lab Sample # / Comments:
9293'1/ r
Lab Profile/Line:
1 Non Conformance(s):
YES / N
Trip Blank Received: Y 3( NA
HCL McOH TSP Other
Cooler 1 Temp'Upon Ri
Cooler 1 Therm Corr. F.
Cooler 1 Corrected Ten
Comments:
O
v
CO
R.