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NC0026441_Fact Sheet_20220323
Fact Sheet NPDES Permit No. NC0026441 Permit Writer/Email Contact: Gary Perlmutter, gary.perlmutter@ncdenr.gov Date: March 22, 2022 Division/Branch: NC Division of Water Resources/NPDES Municipal Permitting Fact Sheet Template: Version 09Jan2022 Permitting Action: ❑ Renewal ® Renewal with Expansion ❑ New Discharge ❑ Modification (Fact Sheet should be tailored to mod request) Note: A complete application should include the following: • For New Dischargers, EPA Form 2A or 2D requirements, Engineering Alternatives Analysis, Fee • For Existing Dischargers (POTW), EPA Form 2A, 3 effluent pollutant scans, 4 2nd species WET tests. • For Existing Dischargers (Non-POTW), EPA Form 2C with correct analytical requirements based on industry category. Complete applicable sections below. If not applicable, enter NA. 1. Basic Facility Information NIIII Facility Information Applicant/Facility Name: Town of Siler City / Siler City WWTP Applicant Address: P.O. Box 769, Siler City, NC 27344 Facility Address: 198 Utility Drive, Siler City, NC 27344 Permitted Flow: 4.0 MGD (current), 6.0 MGD (proposed) Facility Type/Waste: MAJOR Municipal: 68 % Domestic, 32 % Industrial' Facility Class: Grade IV Treatment Units: .0 MGD; Bar screen, Grit collection, Influent equalization basins, Oxidation ditches with aeration, Secondary clarifiers, Tertiary filters, Aerobic digesters, Lime stabilization, Sludge thickening, Chlorination, De -chlorination, Step -aeration. Pretreatment Program (Y/N) Yes County: Chatham Region Raleigh Footnote. 1. Permitted industrial flow is 1.28 MGD. Briefly describe the proposed permitting action and facility background: The Town of Siler City had applied for NPDES permit renewal and submitted a renewal application dated November 30, 2018 to DWR, Page 1 of 24 received that day. In 2019, the Division reopened and modified the permit in response to the facility accepting industrial wastewater from Mountaire Farms Poultry Processing Plant that increased nutrient input. The permit modification added a Total Nitrogen (TN) load limit of 73,058 lb/yr, to become effective no later than January 1, 2023; and an interim TN load limit of 667 lb/day (243,455 lb/yr), effective from January 1, 2020 through December 31, 2022. The modified permit became effective May 1, 2019, expiring May 30, 2019. The permit is currently administratively extended. The modified permit was contested by the Permittee and Rocky River Watch, both on May 30, 2019. The petitions to contest the permit were consolidated and, and a settlement agreement among the parties and the Division was signed on June 5, 2020. Conditions in the settlement agreement pertinent to the permit include submission of a permit application to the Division for revised TN limits as specified in the agreement and a 6.0 MGD expansion tier (provided all other procedural information is received, e.g., EAA for 6.0 MGD). The permit renewal with expansion is to include a revised TN load limit, increased effluent TN monitoring (both load and concentration), and changes to instream monitoring requirements. The permit application submittal deadline in the agreement was December 31, 2020 so long as the environmental review was complete. The Town had requested a deadline extension to April 30, 2021 to allow more time for the environmental review. The Permittee submitted a preliminary engineering report in February 2021, which includes the required EAA for design flow expansion, to meet compliance with the "80/90 rule" (15A NCAC 02T .0118) as the 2019 average flow was 2.95 MGD or 74% of the 4.0 MGD design flow. The original document detailed the preferred alternative as a two-phase upgrade and expansion. The first phase aims to improve nutrient removal while maintaining 4.0 MGD flow capacity. The second phase includes expansion to 6.0 MGD with an additional treatment train. Proposed system components of the 6.0 MGD expansion include: • Upgraded headworks (influent screens & grit removal) • Upgraded influent pump station • Upgraded splitter box • One additional oxidation ditch • One return pump station • One additional 90 ft diameter clarifier • Denitrification filters • UV disinfection • Post aeration • Upgraded discharge pipe • Belt filter press The revised permit application (for the 6.0 MGD expansion) was received on April 30, 2021; its review found the application complete with a completed and signed Form 2A and attachments, and a preliminary engineering report including an EAA for system improvements and expansion to 6 MGD. The three Effluent Pollutant Scans were sampled in 3/20/2018, 9/10/2019 and 6/9/2020; the four second species toxicity tests were sampled in 3/20/2017, 6/12/2017, 9/11/2017 and 12/11/2017. The EAA portion of the original Preliminary Engineering Report was reviewed and found incomplete; which included an incomplete accounting of protected species, incomplete evaluation of alternatives (including incomplete economic feasibility evaluations) and an outdated estimate project schedule. A revised Engineering Report was received on 8/18/2021 and was found complete upon review. Due to unforeseen delays, a revised schedule for the expansion was submitted and approved on March 15, 2022. This schedule consolidated the project into a single phase of construction due to both timing issues and concerns over operation of the treatment facility while under construction. The Division issued speculative limits for the 6.0 MGD expansion on 9/20/2021. This facility serves a population of —8225 residents in the Town of Siler City and operates a pretreatment program with 2 Significant Industrial Users (SIUs). The industrial sources are Mountaire Farms (poultry processing) and Brookfield Farms (poultry, pork and beef processing). Page 2 of 24 A 6.0 MGD expansion flow tier will be added to the permit, along with a second list of system components on the Supplement to Permit Cover Sheet for the expansion. 2. Receiving Waterbody Information Receiving Waterbody Information Outfalls/Receiving Stream(s): Outfall 001 - Loves Creek Stream Segment: 17-43-1Oc Stream Classification: C Drainage Area (mi2): 41le 8.19 Summer 7Q10 (cfs) 0.0 Winter 7Q10 (cfs): 0.23 30Q2 (cfs): 0.32 Average Flow (cfs): 7.8 IWC (% effluent): 90 at 4.0 and 6.0 303(d) listed/parameter: Benthos (Nar, AL, FW) Subject to TMDL/parameter: Statewide TMDL for Mercury Subbasin/HUC: 03-06-12 / 03030003 USGS Topo Quad: E21NW / Siler City, NC Updated stream flow information was received from USGS on July 28, 2021 per request. The receiving stream is listed impaired for Benthos in the NC 2020 final 303(d) list. The Benthos impairment listing is based on a Fair bioclassification from a sampling in 2003. 3. Effluent Data Summary I Effluent data is summarized in Table 1 for the period of Fedbruary 2018 through January 2022. Table 1. Effluent Data Summary. Parameter Units Average Max Min Limit 1 Flow MGD 2.79 10.89 0.86 4.0 Total Monthly Flow (effective 5/1/2019) MG/mo 89.39 130.16 68.30 BOD5 (April 1- October 31) mg/L 4.2 31.0 < 2.0 MA = 5.0 WA = 7.5 BOD5 (November 1 - March 31) mg/L 5.7 76.9 < 2.0 MA = 10.0 WA = 15.0 BOD5 removal % 97.5 99.5 41.3 > 85 Page 3 of 24 Parameter Units Average Max Min Limit' Total Suspended Solids (TSS) mg/L 3.7 206 1.7 MA = 30.0 WA = 45.0 TSS removal % 96.3 99.8 -281 > 85 Ammonia-N (NH3-N) mg/L 1.7 27.0 < 0.5 MA = 1.0 WA = 3.0 (April 1 - October 31) Ammonia-N (NH3-N) (November 1 - March 31) mg/L 3.1 34.0 < 0.5 MA = 2.0 WA = 6.0 Fecal Coliform (geometric mean) #/100 mL 10.7 > 80000 < 1.0 MA = 200 WA = 400 Total Residual Chlorine (TRC) µg/L All values < 10 DM = 17 2 Temperature °C 21 ' 31 0 Dissolved Oxygen (DO) mg/L 12.0 DA > 6.0 pH SU 7.4 8.1 6.7 6.0-9.0 NO3-N + NO2-N mg/L 8.1 33.0 p < 0.2 TKN mg/L 3.4 25.4 < 0.2 1 Total Nitrogen (TN) mg/L 11.4 39.0 1.1 TN Load lb/mo _ 22,264 ,521 TN Load lb/yr 9,419 CY2020 = 90,571 CY2021 = 75,749 Interim = 243,455 3 Total Phosphorus (TP) (April 1 - October 31) mg/L 0.17 1.30 < 0.04 QA = 0.5 Total Phosphorus (TP) (November 1 - March 31) mg/L 019 1.90 < 0.02 QA = 2.0 Total Cadmium µg/L 3.0 < 2.0 Total Copper µg/L 7.8 16 4 Total Zinc µg/L 19.7 31 < 10 Chloride mg/L 109 212 28.3 Footnotes. 1. MA = Monthly Average; WA = Weekly Average; DM = Daily Maximum; DA = Daily Average; QA = Quarterly Average. 2. TRC compliance level of 50 µg/L approved by EPA effective March 1, 2008 to address analytical difficulties with TRC measurements. 3. Interim TN Load limit effective January 1, 2020-December 31, 2022. The final limit and its effective date have been modified since the current permit based on the 2020 Settlement Agreement; see discussion under "Other TMDL/Nutrient Management Strategy Considerations" in Section 6. below. Average monthly flow has increased from 1.72 MGD in February 2018 to 3.03 MGD in January 2022. The annual average flow for calendar year 2020 was 3.212 MGD or 80.3% of the design flow of 4.0 MGD, over the 80% threshold at which the Permittee must submit an evaluation of future wastewater treatment which may include a proposal for facility expansion (15A NCAC 02T .0118, or "80/90 rule"). As a result, the Page 4 of 24 Permittee was imposed a sewer line moratorium on May 19, 2021. After review of the preliminary engineering report, dated February 17, 2021, containing engineering alternatives analysis and selection of the alternative that includes upgrading the facility to 6.0 MGD, it was deemed in compliance with the 80/90 rule and the moratorium was retracted on July 1, 2021. From March 2021 through January 2022, the plant experienced several exceedences in multiple parameters, including BOD, NH3, TSS and Fecal Coliform. From the DMR comments, plant operations had experienced multiple issues contributing to the high values, including high flow events, high sludge retention in the plant due to an inability to land apply due to the wet weather, and a potentially high carbon load interfering with the treatment process. Further high rainfall events in February 2021 caused high concentrations in several parameters, including flow, BOD, NH3, Fecal Coliform and TN. Most recently, multiple exceedences have occurred in January 2021 due to equipment failure and resultant maintenance. The proposed expansion to 6 MGD will include significant improvement to nutrient treatment. 4. Instream Data Summary Instream monitoring may be required in certain situations, for example: 1) to verify model predictions when model results for instream DO are within 1 mg/L of instream standard at full permitted flow; 2) to verify model predictions for outfall diffuser; 3) to provide data for future TMDL; 4) based on other instream concerns. Instream monitoring may be conducted by the Permittee, and there are also Monitoring Coalitions established in several basins that conduct instream sampling for the Permittee (in which case instream monitoring is waived in the permit as long as coalition membership is maintained). If applicable, summarize any instream data and what instream monitoring will be proposed for this permit action: The current permit requires instream monitoring for Dissolved Oxygen (DO), Temperature, Total Phosphorus, TKN and NO2-N + NO3-N. Four instream monitoring locations are in the permit: • LCU — Loves Creek, upstream of the discharge; • LCD — Loves Creek, downstream of the discharge and above the confluence with the Rocky River; • RRU — Rocky River, upstream of the confluence with Loves Creek; and • RRD — Rocky River, downstream of the confluence with Loves Creek. The Permittee is a member of the Upper Cape Fear River Basin Association (UCFRBA), and data are available from the corresponding UCFRBA stations: • B5890000 — Loves Creek at Wastewater Treatment Plant Rd, —450 ft upstream of discharge; • B5920000 — Loves Creek at Progress Blvd, —1200 ft downstream of discharge; • B5950000 — Rocky River at US 64 NR, —985 ft upstream of confluence with Loves Creek; and • B5980000 — Rocky River at SR 2170 Rives Chapel Rd near Siler City, —22,450 ft or 4.25 miles downstream of confluence with Loves Creek. Instream data were obtained from DWR Ecosystems Branch / Monitoring Coalition Program for review. A data summary is provided in Tables 2 and 3. Patterns of the above prameters plus Fecal Coliform, Conductivity, and Ammonia -Nitrogen (NH3-N) are discussed below. Page 5 of 24 Table 2. Summary of UCFRBA Data from January 2017-December 2020 - Loves Creek. Parameter Upstream - B5890000 Downstream - B5920000 Average Max Min average Max Min DO (mg/L) 8.4 11.9 5.1 8.7 13.3 5.4 Temperature (°C) 18.0 26.8 3.3 20.5 29.5 5.9 TP (mg/L) 0.049 0.158 0.020 0.051 0.219 0.020 TKN (mg/L) 0.69 2.45 0.20 1.13 8.13 0.15 NO2-N + NO3-N (mg/L) 0.48 1.24 0.06 .20 25.4 0.34 NH3-N (mg/L) 0.04 0.21 < 0.02 0.48 7.52 < 0.02 Fecal Coliform (geomean) (cfu/100 mL) 226 12,200 5 127 8400 14 Specific Conductance (µS/cm) 192 1044 78 633 1210 100 Table 3. Summary of UCFRBA Data from January 2017-December 2020 - Rocky River. Parameter Upstream - B5950000 Downstream - B5980000 Average Max Min Average Max Min DO (mg/L) 7.7 11.8 3.2 7.8 12.6 5.0 Temperature (°C) 19.9 30.8 4.9 19.2 29.7 4.4 TP (mg/L) 0.101 0.296 0.020 0.095 0.311 0.020 TKN (mg/L) 1.05 3.15 0.20 1.16 2.51 0.53 NO2-N + NO3-N (mg/L) 0.32 1.07 0.02 2.16 8.15 0.15 NH3-N (mg/L) IN 0.04 0.22 40.02 0.05 0.51 < 0.02 Fecal Coliform (geomean) (cfu/100 mL) 113 12,600 6 195 9800 30 Specific Conductance (1.6/14.. 88 124 53 243 913 75 Dissolved Oxygen (DO) remains in the permit as a parameter of concern for aquatic life. The receiving stream is meeting the 4 mg/L instantaneous DO standard, but the Rocky River segment that Loves Creek flows into is impaired due to DO in the 2020 Integrated Report. Review of instream DO data from November 2017-December 2020 indicated that the stream daily average DO standard of 5.0 mg/L (15A NCAC 02B .0211) was maintained in the Loves Creek stations, but summer minima dipped below the standard at the upstream Rocky River stations and reached to the standard at the downstream Rocky River station. Concurrent effluent DO values were narrower in range with higher summer minima (average = 8.41 mg/L; range: 7.0-12.0 mg/L). Averages of the four instream stations plus concurrent effluent were found to differ statistically (ANOVA; F = 2.5; p < 0.05). However, no statistically significant differences were detected between the upstream and downstream location in Loves Creek (t- test: t = -0.93; p > 0.05). Therefore, the effluent does not appear to affect the instream DO. The current instream DO monitoring will be maintained in the permit. Temperature remains in the permit as a parameter of concern for aquatic life. The receiving stream is meeting the 32°C Temperature standard in the 2020 Integrated Report. Review of instream temperature data from November 2017-December 2020 indicated that the stream Temperature standard of 32°C for Page 6 of 24 lower piedmont and coastal plain waters (15A NCAC 02B .0211) was maintained at all stations. Concurrent effluent Temperature values from November 2017—December 2020 were narrower in range with higher winter minima (average = 22.0°C; range: 11.0-30.0°C). Averages of the four instream stations plus concurrent effluent were not found to differ statistically (ANOVA; F = 2.4; p > 0.05). However, differences between concurrent up- and downstream temperatures in Loves Creek averaged at a 2.4°C increase downstream with 15 out of 49 differences > 2.8°C increase standard (15A NCAC 02B .0211). Differences between concurrent up- and downstream temperatures in the Rocky River averaged at a 0.7°C decrease downstream with only 1 difference > 2.8°C increase standard. The effluent appears to increase the instream temperature in Loves Creek, but not Rocky River. The current instream Temperature monitoring will be maintained in the permit. Conductivity is a parameter of concern because of industrial discharges. The permit does not currently require instream monitoring, but data are available for the monitoring stations noted above. Review of instream data from November 2017—December 2020 found statistically significant average increases at both downstream stations when compared to their respective upstream stations (paired two -sample t-test; Loves Cr.: t = -9.49; p < 0001; Rocky R.: t = -6.11; p < 0001). The current permit does not require effluent conductivity sampling; however, the WWTP has a pretreatment program with two SIUs. Despite the absence of effluent data, the instream patterns suggest that the effluent is affecting the instream conductivity both in Loves Creek and downstream in Rocky River. Based on this information, instream monitoring for Conductivity will be added to the permit at a frequency of at least 2/month from May to September, and at least 1/month from October until April. In addition, effluent monitoring for Conductivity will be added to the permit at a daily frequency per 15A NCAC 2B .0500. Fecal Coliform is a parameter of concern for aquatic life and human health. The permit does not currently require instream monitoring for Fecal Coliform; the receiving stream is neither impaired for coliform nor is it a Class B waterbody. However, data are available for review. Instream coliform counts were similar among the four instream locations (Tables 2 and 3), all substantially greater than concurrent effluent coliform counts, which include a geomean of 7 cfu/100 mL and a range of 1-308 cfu/100 mL. The effluent does not appear to affect instream Fecal Coliform. However, based on the 2020 Settlement Agreement recommendations, instream monitoring for Fecal Coliform will be added to the permit at a frequency of at least 1/month. Nutrients (Nitrogen and Phosphorus). Excess nutrients in waterbodies can lead to harmful algal blooms, which have been documented with elevated Chlorophyll -a and nutrient (TN and TP) concentrations in Loves Creek and Rocky River since prior to 1990. The Rocky River Nutrient Budget report in 1991 concluded that while nonpoint sources contributed > 80% of the nutrient input to the subbasin, point sources were important during low flow periods, and Siler City WWTP was identified as the largest point source contributor of nutruents. The report recommended limiting TP in the Siler City NPDES permit as the best means to control instream algal growth. Along with TP effluent limits, instream monitoring for TP was added to the permit in 1996, and TN components Total Kjeldahl Nitrogen (TKN) and Nitrate -Nitrite (NO2+NO3) were added in 2014. Review of instream nutrient data (TKN, NO2+NO3, NH3-N and TP) found downstream average NO2+NO3 to be higher with strong statistical significance in both Loves Creek (t-test; t = -7.72 p < 0.0001) and Rocky River (t-test; t = -5.74; p < 0.0001), but no statistically significant differences were found involving the remaining nutrient parameters. When tested with concurrent effluent data, significant differences were found for all parameters, indicating higher effluent concentrations of TKN (ANOVA: F = 6.29; p < 0.0001), NO2+NO3 (ANOVA: F = 55.36; p < 0.0001), NH3-N (ANOVA: F = 4.77; p < 0.005), and TP (ANOVA: F = 3.01; p < 0.05). Among nutrient parameters, effluent was found to affect only the instream NO2+NO3 water quality in Loves Creek and in Rocky River. The current instream TP, TKN and NO2+NO3 monitoring will be maintained in the permit, and instream NH3-N monitoring will be added to the permit, all at a frequency of at least 1/month. Page 7 of 24 Permit -required instream monitoring will continue to be waived as long as the Permittee maintains membership in the Upper Cape Fear Basin Association (monitoring coalition). Is this facility a member of a Monitoring Coalition with waived instream monitoring (Y/N): YES, since May 2000. Name of Monitoring Coalition: Upper Cape Fear River Basin Association (UCFRBA) 5. Compliance Summary Summarize the compliance record with permit effluent limits (past 5 years): The facility has reported a total of 84 limit violations over the past five years (February 2017-January 2022), involving BOD, Cadmium, Fecal Coliform, NH3-N, and TSS exceedences. Seventy (70) of these proceeded to enforcement cases, while eleven (11) proceeded to Notice of Violation (NOV) and three (3) to Notice of Deficiency. Table 4. Monitoring Report Violations: 2017-2022. Parameter r Violation Type Number of Violations BOD Monthly Average Exceeded 13 BOD Weekly Average Exceeded 21 Total Cadmium Monthly Average Exceeded 4 Fecal Coliform Monthly Geometric Mean Exceeded 1 Fecal Coliform -Weekly Geometric Mean Exceeded 4 Flow Monthly Average Exceeded 1 Ammonia-N Monthly Average Exceeded 12 Ammonia-N Weekly Average Exceeded 28 TSS Al Weekly Average Exceeded 1 A review of the Permittee's enforcement history includes a total of 17 penalties assessed since 2017. Two of these enforcement cases are still open: • LV-2022-0076 for a monitoring report violation in October 2021 • LV-2022-0041 for a monitoring report violation in September 2021. The most recent violations reported in January 2022 have not been fully processed as of this writing. Summarize the compliance record with aquatic toxicity test limits and any second species test results (past 5 years): The facility passed 17 of 20 quarterly chronic toxicity tests from March 2018-December 2021, with three test failures, two of which had passed in subsequent tests. The third failed test occurred in December 2021. The four required second species chronic toxicity tests, collected in March, June, September and December 2017, passed as well as two additional tests in June and December 2021. Summarize the results from the most recent compliance inspection: The most recent inspection was a sampling compliance evaluation conducted on 3/16/2022, which found the facility to be out of compliance and in upset condition since January 2022, due to receiving sludge from the water treatment plant, undersized force main and pump station, plus blower issues in the oxidation ditches; the report has not yet been prepared (Cheng Zhuang, Raleigh Regional Office, 3/22/2022). The prior insection, on 07/21/2020, found effluent sampling to be in compliance. An inspection on 6/3/2020 focused on operations and maintenance and sludge handling. The 6/3/2020 inspection report noted that the plant had insufficient Page 8 of 24 storage space for waste sludge, causing high Mixed Liquor Settlable Solids (MLSS) and other issues. According to the report, the ORC noted that the planned facility upgrade per the 2020 settlement agreement will address the sludge capacity issues. 6. Water Quality -Based Effluent Limitations (WQBELs) Dilution and Mixing Zones In accordance with 15A NCAC 2B.0206, the following streamflows are used for dilution considerations for development of WQBELs: 1 Q 10 streamflow (acute Aquatic Life); 7Q10 streamflow (chronic Aquatic Life; non -carcinogen HH); 30Q2 streamflow (aesthetics); annual average flow (carcinogen, HH). If applicable, describe any other dilution factors considered (e.g., based on CORMIX model results): NA If applicable, describe any mixing zones established in accordance with 15A NCAC 2B.0204(b): NA Oxygen -Consuming Waste Limitations Limitations for oxygen -consuming waste (e.g., BOD) are generally based on water quality modeling to ensure protection of the instream dissolved oxygen (DO) water quality standard. Secondary TBEL limits (e.g., BOD = 30 mg/L for Municipals) may be appropriate if deemed more stringent based on dilution and model results. If permit limits are more stringent than TBELs, describe how limits were developed: The current BOD limits were set from a wasteload allocation (WLA) based on a Level-C model run in 1991. No changes are proposed for the 4.0 MGD flow tier. The speculative limits for the 6.0 MGD expansion flow tier include those that are the same as for the 4.0 MGD (BOD, TSS, summer NH3-N), more stringent (winter NH3-N, DO), and new [summer Organic Nitrogen (NO2+NO3)], and are based on the following: • BOD/NH3/TSS Limits. Assimilative capacity to protect the instream dissolved oxygen standard of 5.0 mg/L is based on prior stream modeling which showed that the receiving stream's dissolved oxygen is sensitive to organic nitrogen. The resultant limits are considered technologically feasible. Ammonia and Total Residual Chlorine Limitations Limitations for ammonia are based on protection of aquatic life utilizing an ammonia chronic criterion of 1.0 mg/L (summer) and 1.8 mg/L (winter). Acute ammonia limits are derived from chronic criteria, utilizing a multiplication factor of 3 for Municipals and a multiplication factor of 5 for Non -Municipals. Limitations for Total Residual Chlorine (TRC) are based on the NC water quality standard for protection of aquatic life (17 ug/L) and capped at 28 ug/L (acute impacts). Due to analytical issues, all TRC values reported below 50 ug/L are considered compliant with their permit limit. Describe any proposed changes to ammonia and/or TRC limits for this permit renewal: The current NH3- N limits were set from a wasteload allocation (WLA) based on a Level-C model run in 1991. Ammonia and TRC were reviewed in the attached Wasteload Allocation (WLA) sheets for both the 4.0 MGD and 6.0 MGD flow tiers with the updated streamflow estimates provided by USGS. Current limits for ammonia were found to be as stringent as the IWC-based calculated results in the WLA sheet and will remain in the permit. The resulting allowable concentrations at 6.0 MGD are the same as those at 4 MGD. Speculative ammonia limits for the 6.0 MGD flow tier were more stringent at the weekly average at 1.9 mg/L monthly average and 5.7 mg/L weekly average in winter, but the same as at 4.0 MGD in summer. The speculative limits will be added to the permit for 6.0 MGD. Page 9 of 24 The current TRC limit of 17 µg/L was first placed in the 1991 permit, capped at the water quality standard of 17 µg/L. The resulting TRC allowable concentration from the IWC-based calculation is 17 µg/L at both 4.0 and 6.0 MGD. The submitted plans for the 6.0 MGD upgrade include installation of UV disinfection. The current limit will be maintained in the current permit at 4.0 MGD, and will be carried over to 6.0 MGD in the event that chlorination will be used as a backup to the planned UV system. Reasonable Potential Analysis (RPA) for Toxicants If applicable, conduct RPA analysis and complete information below. The need for toxicant limits is based upon a demonstration of reasonable potential to exceed water quality standards, a statistical evaluation that is conducted during every permit renewal utilizing the most recent effluent data for each outfall. The RPA is conducted in accordance with 40 CFR 122.44 (d) (i). The NC RPA procedure utilizes the following: 1) 95% Confidence Level/95% Probability; 2) assumption of zero background; 3) use of 1/2 detection limit for "less than" values; and 4) streamflows used for dilution consideration based on 15A NCAC 2B.0206. Effective April 6, 2016, NC began implementation of dissolved metals criteria in the RPA process in accordance with guidance titled NPDES Implementation of Instream Dissolved Metals Standards, dated June 10, 2016. A reasonable potential analysis was conducted on effluent toxicant data collected between February 2018 and January 2022 for both the current 4.0 MGD permitted flow and the 6.0 MGD expansion flow tiers. Pollutants of concern included toxicants with positive detections and associated water quality standards/criteria. Based on this analysis, the following permitting actions are proposed for this permit: • Effluent Limit with Monitoring. The following parameters will receive a water quality -based effluent limit (WQBEL) since they demonstrated a reasonable potential to exceed applicable water quality standards/criteria: None. • Monitoring Only. The following parameters will receive a monitor -only requirement since they did not demonstrate reasonable potential to exceed applicable water quality standards/criteria, but the maximum predicted concentration was > 50% of the allowable concentration: Cadmium, Chloride, Copper, Selenium, Silver at both flow tiers. o Cadmium — 1 detect at 3 µg/L on 11/4/2019, and 47 nondetects < 2 µg/L; DWR lab PQL = 0.5 µg/L and Allowable Cw = 1.636 µg/L at 4.0 MGD and 1.632 µg/L at 6.0 MGD. Samples shall be tested and reported to the lower reporting level. o Selenium — all nondetects, 15 out of 16 < 10 µg/L; DWR lab PQL = 1.0 µg/L and Allowable Cw = 5.1 µg/L at 4.0 MGD and 5.0 µg/L at 6.0 MGD. Samples shall be tested and reported to the lower reporting level. o Silver all nondetects < 5 µg/L; DWR lab PQL = 1.0 µg/L and Allowable Cw = 0.061 µg/L at both flow tiers. Samples shall be tested and reported to the lower reporting level. o Chloride, Copper — based on effluent data. • No Limit or Monitoring: The following parameters will not receive a limit or monitoring, since they did not demonstrate reasonable potential to exceed applicable water quality standards/criteria and the maximum predicted concentration was < 50% of the allowable concentration: Arsenic, Beryllium, Total Phenolic Compounds, Total Chromium, Cyanide, Lead, Molybdenum, Nickel and Zinc at both flow tiers. • POTW Effluent Pollutant Scan Review: Three effluent pollutant scans were evaluated for additional pollutants of concern. o The following parameter(s) will receive a water quality -based effluent limit (WQBEL) with monitoring, since as part of a limited data set, two samples exceeded the allowable discharge concentration: None. o The following parameter(s) will receive a monitor -only requirement, since as part of a limited data set, one sample exceeded the allowable discharge concentration: Bis (2- ethylhexyl) phthalate at both flow tiers. Page 10 of 24 o No Limit or Monitoring: The following parameters that showed detections will not receive a limit or monitoring, since they did not demonstrate reasonable potential to exceed applicable water quality standards/criteria based on limited dataset (n < 8 samples): Chloroform, Dichlorobromomethane. If applicable, attach a spreadsheet of the RPA results as well as a copy of the Dissolved Metals Implementation Fact Sheet for freshwater/saltwater to this Fact Sheet. Include a printout of the RPA Dissolved to Total Metal Calculator sheet if this is a Municipality with a Pretreatment Program. Toxicity Testing Limitations Permit limits and monitoring requirements for Whole Effluent Toxicity (WET) have been established in accordance with Division guidance (per WET Memo, 8/2/1999). Per WET guidance, all NPDES permits issued to Major facilities or any facility discharging "complex" wastewater (contains anything other than domestic waste) will contain appropriate WET limits and monitoring requirements, with several exceptions. The State has received prior EPA approval to use an Alternative WET Test Procedure in NPDES permits, using single concentration screening tests, with multiple dilution follow-up upon a test failure. Describe proposed toxicity test requirement: Siler City WWTP is a Major POTW discharging complex wastewater with a chronic WET limit capped at 90% effluent, based on the instream waste concentration (IWC) calculation using the permitted flow of 4.0 MGD and updated summer minimum stream flow 7Q10 of 0.09 cfs. WET testing will continue on a quarterly frequency. For the 6.0 MGD flow tier, the chronic WET limit capped at 90% effluent will be added to the permit, based on the IWC calculation using the expansion flow and updated summer 7Q10. Mercury Statewide TMDL Evaluation There is a statewide TMDL for mercury approved by EPA in 2012. The TMDL target was to comply with EPA's mercury fish tissue criteria (0.3 mg/kg) for human health protection. The TMDL established a wasteload allocation for point sources of 37 kg/year (81 lb/year), and is applicable to municipals and industrial facilities with known mercury discharges. Given the small contribution of mercury from point sources (-2% of total load), the TMDL emphasizes mercury minimization plans (MMPs) for point source control. Municipal facilities > 2 MGD and discharging quantifiable levels of mercury (> 1 ng/L) will receive an MMP requirement. Industrials are evaluated on a case -by -case basis, depending if mercury is a pollutant of concern. Effluent limits may also be added if annual average effluent concentrations exceed the WQBEL value (based on the NC WQS of 12 ng/L) and/or if any individual value exceeds a TBEL value of 47 ng/L. The current permit contains an MMP special condition. The Permittee included a summary of MMP actions taken in their submitted Annual Pretreatment Report Narrative, dated February 19, 2021. Describe proposed permit actions based on mercury evaluation: Review of effluent data from February 2018 through January 2022 revealed no annual average mercury concentration exceeded the WQBEL, and no individual mercury sample exceeded the TBEL at either flow tier (Table 5). Therefore, no mercury limit is required. Because the facility's permitted flow is greater than 2 MGD and mercury levels > 1 ng/L were detected among samples, a mercury minimization plan (MMP) is required and will be maintained in the permit. Page 11 of 24 Table 5. Mercury Effluent Data Summary. Parameter 2018 2019 2020 2021 No. of Samples 4 4 4 5 Annual Average Conc. ng/L 10.0 2.8 4.0 1.0 Maximum Conc., ng/L 30.00 4.47 12.7 3.15 TBEL, ng/L 47 WQBEL, ng/L at 4.0 MGD 12.17 WQBEL, ng/L at 6.0 MGD 12.12 Other TMDL/Nutrient Management Strategy Considerations If applicable, describe any other TMDLs/Nutrient Management Strategies and their implementation within this permit: The facility lies in the Rocky River watershed, which has a history of algal blooms, Chlorophyll -a exceedences and excessive nutrient issues since prior to 1990. The watershed does not currently have a TMDL or nutrient management strategy, but the WWTP has nutrient requirements in its permit to address downstream Chlorophyll -a issues. Nutrient requirements in the form of a summer monthly limit of 0.5 mg/L TP with weekly monitoring were first placed in the permit in 1996. The TP requirements were based on the recommendations of the Division's 1991 Rocky River Subbasin Nutrient Budget report, which concluded that the Rocky River was TP-limited and controlling effluent TP was the best approach to control instream algal blooms. The current seasonal quarterly TP limits of 0.5 mg/L summer and 2.0 mg/L winter were added in the 2008 permit modification. Effluent TN monitoring was increased from monthly to weekly and TN components of TKN and NO2+NO3 weekly monitoring were also added in that modification as was a nutrient removal optimization plan special condition. The changes were based on recommendations in a public hearing report dated July 14, 2008. Siler City lost two poultry processing facilities in 2008 and 2011 followed by a significant decrease in Effluent TN concentration. In the 2014 permit renewal, the nutrient removal optimization plan special condition was removed and replaced by a nutrient reopener special condition with a trigger mechanism for evaluation of any future high nutrient -bearing industries. In December 2016 the reopener was triggered when the Town informed the Division of Mountaire Farms' plans to locate a processing facility in Siler City. The permit was reopened in June 2017, and a modification issued in April 2019, following a public hearing in 2018. Nutrient -related changes included a Total Nitrogen (TN) load limit of 73,058 lb/yr, to become effective no later than January 1, 2023; and an interim TN load limit of 243,455 lb/yr, effective from January 1, 2020 through December 31, 2022. The modified permit was contested by the Permittee and Rocky River Watch on May 30, 2019. The petitions to contest the permit were consolidated and a settlement agreement was signed on June 5, 2020. One of the settlement agreement conditions is to test facility optimization under current configuration as proposed in the Preliminary Wastewater Nitrogen Removal Optimization Plan, prepared in October 2019. The resulting report, Wastewater Nitrogen Removal Optimization Plan Results and Recommendations, prepared in October 2020, concludes that the facility can achieve the target effluent concentration of 15 mg/L or less TN as specified in the Settlement Agreement. TN limits are in place in terms of loading, and concentration monitoring will be maintained in the permit. The engineering report submitted with the permit application proposed a target TN loading of 73,058 lb/yr with the first phase of facility upgrade at 4.0 MGD and 54,800 lb/yr with the second phase at 6.0 MGD. Page 12 of 24 Based on the Permittee's concerns of timing issues and potential upsets during the first phase when one treatment train is taken out of service for nutrient improvement installation, the proposed construction was revised to a single phase for the 6.0 MGD expansion with a proposed effective date of January 1, 2025 for the final TN load limit of 54,800 lb/yr, approved by the Division on 3/15/2022. The above interim TN load limits of 243,455 lb/yr and 73,058 lb/yr will be maintained in the permit at 4.0 MGD with an additional interim limit of 63,929 lb/yr (the average of 73,058 lb/yr limit for one-half year and 54,800 lb/yr limit for one-half year) effective in each successive year (Table 6.). A compliance schedule for the 6.0 MGD expansion and TN load limits will be added to the permit. Table 6. Total Nitrogen interim and final effluent load limits for compliance schedule. Limit Type Annual Load Limit (lb/yr) Flow Tier (MGD) Effective Dates Interim 243,455 4.0 Permit effective date — 12/31/2022 Interim 73,058 4.0 1/1/2023 — 12/31/2023 Interim 63,929 4.0 / 6.0 1/1/2024 — 12/31/2024 or upon 6.0 MGD expansion Final 54,800 6.0 Beginning 1/1/2025 or upon 6.0 MGD expansion To further address nutrient loadings as well as protection of the dissolved oxygen w quality standard from organic nitrogen, summer (April -October) limits of 3.0/4.5 mg/L monthly avera e/weekly average NO2+NO3 will be added to the permit at the 6.0 MGD flow tier. Other WQBEL Considerations If applicable, describe any other parameters of concern evaluated for WQBELs: Siler City WWTP had participated in a basin -wide survey for the emerging contaminants 1,4-Dioxane and PFAS chemical group in 2019. Three rounds of influent sampling were conducted in July, August and September 2019, results of which were submitted along with a completed Chemical Addendum form for all 40 CFR 136 pollutants, received on 3/1/2022. Reviewed data from the sampling found effluent concentrations to be below the EPA Drinking Water Health Advisory Levels (HALs) for 1,4-Dioxane and PFAS + PFOA (Table 7). Table 7. Influent Monitoring Results of Emerging Contaminants, July -August 2019. Parameter Average (Range), µg/L 1 HAL (µg/L) 1.29 (< 1.0-1.58) 35 1,4-Dioxane ' PFOA + PFOS I 8.87 (7.60-11.15) 70 The POTW lies in the Cape Fear River Basin, where high levels of 1,4-Dioxane have been reported. The Siler City WWTP discharges into a Class C waterbody with the nearest water supply boundary at 43.9 miles downstream. Because 1,4-Dioxane was detected in the influent at a concentration high enough for further evaluation, monthly monitoring for this parameter will be added to the permit. In addition, a permit reopener special condition regarding 1,4-Dioxane based on changes toward limits, monitoring or treatment will be added to the permit. Based on detection of PFAS chemicals in the influent from the 2019 samplings, which was also provided via as an attachment to the NPDES application received on 1/4/2022, monitoring of PFAS chemicals will be added to the permit at a frequency of 2/year, since the preliminary data are well below the HAL. Since an EPA method for sampling and analyzing PFAS in wastewater is not currently available, the PFAS sampling requirement in the Permit includes a compliance schedule which delays the effective date of this requirement until the first full calendar quarter beginning 6 months after EPA has a final wastewater method Page 13 of 24 in 40 CFR136 published in the Federal Register. This date may be extended upon request and if there are no NC -certified labs. If applicable, describe any special actions (HQW or ORW) this receiving stream and classification shall comply with in order to protect the designated waterbody: NA If applicable, describe any compliance schedules proposed for this permit renewal in accordance with 15A NCAC 2H.0107(c)(2)(B), 40CFR 122.47, and EPA May 2007 Memo: A compliance schedule has been added to the permit for the expansion to 6.0 MGD and corresponding TN load limit of 54,800 lb/yr, with the TN load limit compliance date of January 1, 2025. If applicable, describe any water quality standards variances proposed in accordance with NCGS 143- 215.3(e) and 15A NCAC 2B. 0226 for this permit renewal: NA 7. Technology -Based Effluent Limitations (TBELs) Municipals (if not applicable, delete and skip to Industrials) Are concentration limits in the permit at least as stringent as secondary treatment requirements (30 mg/L BOD5/ TSS for Monthly Average, and 45 mg/L for BOD5/TSS for Weekly Average). YES Are 85% removal requirements for BODS/TSS included in the permit? YES If NO, provide a justification (e.g., waste stabilization pond). NA 8. Antidegradation Review (New/Expanding Discharge) The objective of an antidegradation review is to ensure that a new or increased pollutant loading will not degrade water quality. Permitting actions for new or expanding discharges require an antidegradation review in accordance with 15A NCAC 2B .0201. Each applicant for a new/expanding NPDES permit must document an effort to consider non -discharge alternatives per 15A NCAC 2H .0105(c)(2). In all cases, existing instream water uses and the level of water quality necessary to protect the existing use is maintained and protected. If applicable, describe the results of the antidegradation review, including the Engineering Alternatives Analysis (EAA) and any water quality modeling results: A preliminary engineering report dated February 2021 was submitted with the permit modification application on April 30, 2021. Review of the Engineering Report found it incomplete with an incomplete accounting of protected species, incomplete evaluation of alternatives (including incomplete economic feasibility evaluations) and an outdated estimate project schedule. A revised Engineering Report was received on 8/18/2021 and was found complete. The report includes an evaluation of four alternatives, including: 1) no action, 2) connection to a regional WWTP, 3) wastewater irrigation or reuse of additiona flow, and 4) upgrade and expansion of the WWTP to 6.0 MGD. The fourth alternative was selected as the others were deemed infeasible. The expansion of the facility to 6.0 MGD and include following upgrades: an expanded headworks and influent pump station; a third oxidation ditch with nutrient removal modifications as described above along with a third clarifier; denitrification effluent filters; UV disinfection; a new solids handling facility; and an upgraded influent sewer to handle flow from Mountaire Farms. Projected TN discharge is 54,800 lb/yr (based on 3 mg/L) at 6.0 MGD. Page 14 of 24 Speculative limits for the 6.0 MGD expansion were prepared on 9/20/2021 and are tabulated below. Table 8. Speculative Limits for 6.0 MGD expansion. Effluent Characteristic Effluent Limitations Monthly Average Weekly Average Daily Maximum Flow 6.0 MGD BOD5 (Apr. -Oct.) 5.0 mg/L 7.5 mg/L BOD5 (Nov. -Mar.) 10.0 mg/L 15.0 mg/L TSS 1 20 mg/L 30 mg/L NH3 as N (Apr. -Oct.) 1.0 mg/L 3.0 mg/L NH3 as N (Nov. -Mar.) 1.8 mg/L 5.4 mg/L Dissolved Oxygen (minimum daily average) 7.0 mg/L jr TRC 17 µg/L Fecal coliform (geometric mean) 200/100 mL 400/100 mL Organic Nitrogen (Apr. -Oct.) 3.0 mg/L 4.5 mg/L Total Nitrogen Load 54,800 lbs/year 2 Total Phosphorus (Apr. -Oct.) ' 0.5 mg/L (quarterly average) / Total Phosphorus (Nov. -Mar.) 3 2.0 mg/L (quarterly average) Chronic Toxicity Pass/Fail (Quarterly test) 90% Footnotes: 1. TSS is reduced based on addition of denitrification filters as part of final effluent treatment. 2. Equivalent to a 3.0 mg/L concentration (on an annual basis). Monitor and report pounds per month. 3. Total Phosphorus requirements will be consistent with the existing permit. 9. Antibacksliding Review Sections 402(o)(2) and 303(d)(4) of the CWA and federal regulations at 40 CFR 122.44(1) prohibit backsliding of effluent limitations in NPDES permits. These provisions require effluent limitations in a reissued permit to be as stringent as those in the previous permit, with some exceptions where limitations may be relaxed (e.g., based on new information, increases in production may warrant less stringent TBEL limits, or WQBELs may be less stringent based on updated RPA or dilution). Are any effluent limitations less stringent than previous permit (YES/NO): NO If YES, confirm that antibacksliding provisions are not violated: NA Page 15 of 24 10. Monitoring Requirements Monitoring frequencies for NPDES permitting are established in accordance with the following regulations and guidance: 1) State Regulation for Surface Water Monitoring, 15A NCAC 2B.0500; 2) NPDES Guidance, Monitoring Frequency for Toxic Substances (7/15/2010 Memo); 3) NPDES Guidance, Reduced Monitoring Frequencies for Facilities with Superior Compliance (10/22/2012 Memo); 4) Best Professional Judgement (BPJ). Per US EPA (Interim Guidance, 1996), monitoring requirements are not considered effluent limitations under Section 402(o) of the Clean Water Act, and therefore anti -backsliding prohibitions would not be triggered by reductions in monitoring frequencies. The current permit has reduced monitoring frequencies for BOD, TSS, and Fecal Coliform, requested by the Permittee in 2015. The Permittee requested to maintain reduced monitoring frequencies for the above parameters plus Ammonia on January 6, 2021. Upon review, the facility's compliance status on EPA's ECHO detailed history report is Significant/Category 1 Noncompliance, yielding the facility not eligible for reduced monitoring frequencies. All target parameters will have monitoring increased to daily. For instream monitoring, refer to Section 4. 11. Electronic Reporting Requirements The US EPA NPDES Electronic Reporting Rule was finalized on December 21, 2015. Effective December 21, 2016, NPDES regulated facilities are required to submit Discharge Monitoring Reports (DMRs) electronically. Effective December 21, 2020, NPDES regulated facilities will be required to submit additional NPDES reports electronically. This permit contains the requirements for electronic reporting, consistent with Federal requirements. 12. Summary of Proposed Permitting Actions Tables 9 and 10 summarize permit conditions and proposed changes affecting effluent parameters at 4.0 and 6.0 MGD, respectively. Table 10 summarizes permit conditions and proposed changes affecting instream parameters. Table 9. Current Permit Conditions and Proposed Changes at 4.0 MGD flow 1. Parameter I Current Permit Proposed Change Basis for Condition/Change Flow MA = 4.0 MGD No change 15A NCAC 2B .0505 Total Monthly Flow (TMF) Monitor monthly No change For calculation of Total Nitrogen and Total Phosphorus loads. Biological Oxygen Demand, 5-day (BOD5) Summer MA = 5.0 mg/L WA = 7.5 mg/L Winter MA = 10.0 mg/L WA = 15.0 mg/L Monitor 2/week No change in limits Monitor daily WQBEL. Based on protection of DO standard via Wasteload Allocation (WLA) calculated in 1987 and 1989. Monitoring Frequency Reduction (MFR) criteria were not met. Page 16 of 24 Parameter Current Permit _ Proposed Change Basis for Condition/Change Total Suspended Solids (TSS) MA — 30.0 mg/L WA = 45.0 mg/L Monitor 2/week No change in limits Monitor daily TBEL. Secondary treatment standards / 40 CFR 133 / 15A NCAC 2B .0406. MFR criteria were not met. Ammonia-N Summer No change WQBEL. Calculation results based on NC's use of EPA criteria in developing 1.0 mg/L summer and 1.8 mg/L winter values in wasteload allocations to protect against NH3-N toxicity (see WLA sheet attached). MFR criteria were not met. MA 1.0 mg/L WA = 3.0 mg/L Winter MA = 2.0 mg/L WA = 6.O mg/L Monitor daily (NH3-N) Fecal Coliform (geometric mean) MA = 200 cfu/100 mL WA = 400 cfu/100 mL Monitor 2/week No change in limits Monitor daily WQBEL. State WQ standard, 15A NCAC 2B .0200. MFR criteria were not met. Total Residual Chlorine (TRC) DM = 17 µg/L Monitor daily No change WQBEL. State WQ standard, 15A NCAC 2B .0200 and .0500. Dissolved Oxygen (DO) >_ 6 mg/L Monitor daily No change WQBEL. Based on protection of the DO standard, 15A NCAC 2B .0200 and .0500. Temperature Monitor daily No change State WQ reporting requirements 15A NCAC 2B .0500. pH 6-9 SU Monitor daily No change WQBEL. State WQ standard, 15A NCAC 2B .0200 and .0500. Conductivity No requirement Add daily monitoring State WQ reporting requirements 15A NCAC 2B .0500. Increased downstream levels suggest effluent impact. NO3 + NO2 Monitor weekly No change For TN calculation, 15A NCAC 02B .0500. TKN Monitor weekly No change For Total Nitrogen (TN) calculation, 15A NCAC 02B .0500. Total Nitrogen (TN) Monitor weekly No change State WQ reporting requirements 15A NCAC 2B .0500. Page 17 of 24 Parameter Current Permit Proposed Change Basis for Condition/Change TN Load Interim limit: 243,455 lb/yr (eff. 1/1/2020- 12/31/2022) Final limit: 73,058 lb/yr (eff. 1/1/2023) Monitor monthly, annually Interim limits: • 243,455 lb/yr (eff. through 12/31/2022) • 73,058 lb/yr (eff. 1/1/2023-12/31/2023) • 63,929 lb/yr (eff. 1/1/2024-12/31/2024*) Final limit: 54,800 lb/yr (eff. 1/1/2025*) Add compliance schedule for expansion & final limits Monitor monthly, annually WQBEL. To protect the Chlorophyll -a water quality standard. *Or upon 6.0 MGD flow expansion. Total Phosphorus Summer QA = 0.5 mg/L Winter QA = 2.0 mg/L Monitor weekly No change Summer limit: Rocky River Subbasin Nutrient Budget (Division 1991 document) recommendations to control algal blooms. Winter limit: Public Hearing Officer's recommendation to contested 2007 permit renewal. Nutrient Reopener Special Condition No change NCAC 02H .0100 [permit approval procedures for point discharges] Nutrient Water Quality Modeling Reopener Special Condition No change NCAC 05H .0100; 2005 Cape Fear River Basinwide Water Quality Plan recommentation 0 Total Hardness No requiremet Add quarterly monitoring Hardness -dependent dissolved metals water quality standards, approved in 2016, need effluent and instream hardness data for calculations of permit limitations. Total Cadmium MA = 2.1 µg/L DM = 15.5 µg/L Monitor quarterly Reasonable potential found to exceed state water quality standards (WQS) by one detect at 3 µg/L. All other data nondetects > PQL and above allowable concentration. Total Copper Monitor quarterly No change No RP found, but predicted maximum value > 50% of allowable concentration. Total Selenium No requirement Add quarterly monitoring All data nondetects > PQL and above allowable concentration. Total Silver No requirement Add quarterly monitoring All data nondetects > PQL and allowable concentration. Page 18 of 24 Parameter Current Permit Proposed Change Basis for Condition/Change Total Zinc Monitor quarterly Remove from permit No RP found and predicted maximum value < 50% of Allowable Cw. Chloride Monitor quarterly No change No RP found, but predicted maximum value > 50% of allowable concentration. Bis (2-ethylhexyl) phthalate No requirement Add quarterly monitoring RP found for limited dataset (n < 8 samples) with all values including 2 nondetects above allowable concentration. 1,4-Dioxane No requirement Add monthly monitoring; add reopener condition 1,4-Dioxane detected, limited data (< 12 samples). PFAS No requirement Add monitoring 2/year with delayed implementation Based limited influent data showing detection, more results are needed to evaluate. Implementation delayed until after EPA certified method becomes available. Total Mercury Mercury Minimization Plan (MMP) Maintain MMP In accordance with 2012 Statewide Mercury TMDL Implementation, per facility size 'and monitoring data criteria. Toxicity Test Chronic Ceriodaphnia dubia Pass/Fail at 90% effluent, monitor quarterly No change WQBEL. No toxics in toxic amounts. 15A NCAC 02B .0200, 15A NCAC 02B .0500. Effluent Pollutant Scan Three times per permit cycle Update sample years to 2023, 2024 and 2025 40 CFR 122 Electronic Reporting Special Condition Update condition to remove submittal of hardcopies and extended Phase 2 deadline to 2025. In accordance with EPA Electronic Reporting Rule 2015, and final regulation change published in the November 2, 2020 Federal Register. Footnote. 1. MGD = Million gallons per day; MA = Monthly Average; WA = Weekly Average; DM = Daily Maximum; QA = Quarterly Average. Table 10. Proposed Permit Conditions at 6.0 MGD flow 1. Parameter Proposed Condition r• Basis for Condition Flow MA = 6.0 MGD 15A NCAC 2B .0505 Total Monthly Flow (TMF) Monitor monthly For calculation of Total Nitrogen and Total Phosphorus loads. Page 19 of 24 Parameter Proposed Condition Basis for Condition Biological Oxygen Demand, 5-day (BOD5) Summer MA = 5.O mg/L WA = 7.5 mg/L Winter MA = 10.0 mg/L WA = 15.0 mg/L Monitor daily WQBEL. Based on speculative limits for protection of DO standard. State WQ reporting requirements 15A NCAC 2B .0500. Total Suspended Solids (TSS) MA = 20.0 mg/L WA = 30.0 mg/L Monitor daily TBEL. Based on speculative limits for protection of the DO standard. State WQ reporting requirements 15A NCAC 2B .0500. Ammonia-N (NH3-N) Summer MA = 1.0 mg/L WA = 3.0 mg/L Winter MA = 1.9 mg/L WA = 5.7 mg/L Monitor daily I WQBEL. Based on speculative limits for protection of the DO standard. Fecal Coliform (geometric mean) MA = 200 cfu/100 mL WA = 400 cfu/100 mL Monitor daily WQBEL. State WQ standard, 15A NCAC 2B .0200 and .0500. Total Residual Chlorine (TRC) DM = 17 µg/L Monitor daily WQBEL. State WQ standard, 15A NCAC 2B .0200 and .0500. To be implemented when chlorination is used. Dissolved Oxygen (DO) ? 7 mg/L Monitor daily WQBEL. Based on speculative limits for protection of the DO standard, 15A NCAC 2B .0200 and .0500. Temperature Monitor daily State WQ reporting requirements 15A NCAC 2B .0500. A pH 6-9 SU Monitor daily WQBEL. State WQ standard, 15A NCAC 2B .0200 0 and .0500. Conductivity Add daily monitoring State WQ reporting requirements 15A NCAC 2B .0500. Total Organic Nitrogen MA = 3.0 mg/L WA = 3.0 mg/L Monitor weekly (Apr. -Oct.) WQBEL. Based on speculative limits to protect the instream DO standard. NO3 + NO2 Monitor weekly For Total Nitrogen (TN) calculation, 15A NCAC 02B .0500. TKN Monitor weekly For Total Nitrogen (TN) calculation, 15A NCAC 02B .0500. Total Nitrogen (TN) Monitor weekly WQBEL. Based on speculative limits for protection of the Chlorophyll -a standard per 2020 Settlement Agreement. State WQ reporting requirements 15A NCAC 2B .0500. TN Load Weighted limit = 63,9291b/yr (eft'. 1/1/2024-1/1/2025*) WQBEL. Based on speculative limits for protection of the Chlorophyll -a standard. Page 20 of 24 Final limit = 54,800 lb/yr (eff. 1/1/2025) Monitor monthly *Effective 1/1/2024, provided expansion is completed by 12/31/2023. Average of previous and final limit (each for 6 months of the year). This effectively places the final limit in effect in July 1, 2024; however, it is a calendar year limit. Total Phosphorus Summer QA = 0.5 mg/L Winter QA = 2.0 mg/L Monitor weekly WQBEL. Based on speculative limits for protection of the Chlorophyll -a standard. Summer limit: Rocky River Subbasin Nutrient Budget (Division 1991 document) recommendations to control algal blooms. Winter limit: Public Hearing Officer's recommendation to contested 2007 permit renewal. Nutrient Reopener Special Condition NCAC 02H .0100 [permit approval procedures for point discharges] Nutrient Water Quality Modeling Reopener Special Condition NCAC 05H .0100; 2005 Cape Fear River Basinwide Water Quality Plan recommentation Total Hardness Monitor quareterly Hardness -dependent dissolved metals water quality standards, approved in 2016, need effluent and instream hardness data for calculations of permit limitations. Total Cadmium Monitor quarterly Reasonable potential found to exceed state water quality standards (WQS) by one detect at 3 µg/L. All other data nondetects > PQL and above allowable concentration. Total Copper Monitor quarterly No RP found, but predicted maximum value > 50% of allowable concentration. Total Selenium Monitor quarterly All data nondetects; 15 out of 16 > PQL and above $owable concentration. Total Silver Monitor quarterly All data nondetects > PQL and allowable concentration. Chloride I Monitor quarterly No RP found, but predicted maximum value > 50% of allowable concentration. Bis (2-ethylhexyl) phthalate Monitor quarterly RP found for limited dataset (n < 8 samples) with all values including 2 nondetects above allowable concentration. 1 4-Dioxane ' Monitor monthly; add reopener special condition 1,4-Dioxane detected, limited data (< 12 samples). PFAS Add monitoring 2/year with delayed implementation Based limited influent data showing detection, more results are needed to evaluate. Implementation delayed until after EPA certified method becomes available. Total Mercury Mercury Minimization Plan (MMP) In accordance with 2012 Statewide Mercury TMDL Implementation, per facility size and monitoring data criteria. Page 21 of 24 Parameter Proposed Condition Basis for Condition Toxicity Test Chronic Ceriodaphnia dubia Pass/Fail at 90% effluent, monitor quarterly WQBEL. No toxics in toxic amounts. 15A NCAC 02B .0200, 15A NCAC 02B .0500. Effluent Pollutant Scan Three times per permit cycle 40 CFR 122 Electronic Reporting Special Condition In accordance with EPA Electronic Reporting Rule 2015. Footnote on next page Footnote. 1. MGD = Million gallons per day; MA = Monthly Average; WA = Weekly Average; DM = Daily Maximum; QA = Quarterly Average. Table 11. Current Permit Conditions and Proposed Changes for Instream Monitoring. Parameter Current Permit Proposed Change Basis for Condition/Change Dissolved Oxygen (DO) Up- and downstream Loves Creek, up- and downstream Rocky River at frequencies: 3/week (Jun —Sep) 1/week (Oct —May) No change 15A NCAC 02B .0500 Temperature i Up- and downstream Loves Creek, up- and downstream Rocky River at frequencies: 3/week (Jun —Sep) 1/week (Oct —May) No change 15A NCAC 02B .0500 INdownstream Fecal Coli No requirement Add up- and Loves Creek, up- and downstream Rocky River at 1/month 2020 Settlement Agreement Conductivity No requirement Add up- and downstream Loves Creek, up- and downstream Rocky River at frequencies: 2/month (May —Sep) 1/month (Oct —Apr) Data assessment Total Phosphorus (TP) Up- and downstream Loves Creek, up- and downstream Rocky River at frequencies: 3/week (Jun —Sep) 1/week (Oct —May) No change 1991 Division's Rocky River Nutrient Budget recommendations; data assessment. Page 22 of 24 Parameter Current Permit Proposed Change Basis for Condition/Change Total Kjeldahl Nitrogen (TKN) Up- and downstream Loves Creek, up- and downstream Rocky River at frequencies: 3/week (Jun —Sep) 1/week (Oct —May) No change 1991 Division's Rocky River Nutrient Budget recommendations implemented in 2014 permit; data assessment. Nitrate -Nitrite Nitrogen (NO3+NO2) Up- and downstream Loves Creek, up- and downstream Rocky River at frequencies: 3/week (Jun —Sep) 1/week (Oct —May) No change 1991 Division's Rocky River Nutrient Budget recommendations implemented in 2014 permit; data assessment Ammonia-N (NH3-N) No requirement Add up- and downstream Loves Creek, up- and downstream Rocky River at 1/month Data assessment Total Hardness (as CaCO3) No requirement Add upstream Loves Creek at 1/quarter Hardness -dependent dissolved metals water quality standards, approved in 2016, need effluent and instream hardness data for calculations of permit limitations. 13. Public Notice Schedule: Permit to Public Notice: 03/23/2022 Per 15A NCAC 2H .0109 & .0111, The Division will receive comments for a period of 30 days following the publication date of the public notice. Any request for a public hearing shall be submitted to the Director within the 30 days comment period indicating the interest of the party filing such request and the reasons why a hearing is warranted. 14. NPDES Division Contact: If you have questions regarding any of the above information or on the attached permit, please contact Gary Perlmutter at (919) 707-3611 or via email at gary.perlmutter@ncdenr.gov. 15. Fact Sheet Addendum (if applicable): Were there any changes made since the Draft Permit was public noticed (Yes/No): NO If Yes, list changes and their basis below: NA Page 23 of 24 16. Fact Sheet Attachments (if applicable): • Reduced Monitoring Frequency Request letter • NPDES/PT POC Review sheet • USGS e-mail with updated streamflow estimates • NC 2020 Intagrated Report, p 138 • NC 2020 303(d) list, p. 16 • Loves Creek Benthos Site details page • Effluent data trend charts and data summaries • DMR comments • Instream monitoring trend charts and data summaries • Monitoring Report (MR) Violations sheet • WET Testing and Self Monitoring sheet, page 89 • Compliance Evaluation Reports: 07/21/2020 (sampling compliance), 06/03/2020 (O&M, sludge handling) • NH3/TRC WLA Calculations sheets for 4.0 MGD and 6.0 MGD • RPA Spreadsheet Summaries for 4.0 MGD and 6.0 MGD • Dissolved Metals Implementation/Freshwater • Mercury Data Statistics tables and data for 4.0 MGD and 6.0 MGD • Annual Pretreatment Report Narrative, 02/19/2021 • Monitoring Reduction Evaluation spreadsheet • EPA ECHO Detailed Facility Report • Speculative Limits letter for 6.0 MGD expansion, 9/20/2021 • Updated proposed expansion schedule and DWR approval letter • Chemical Addendum Page 24 of 24 4.4 Tram of !rarer Cttp Town Manager's Office January 06,2021 Attn: Gary Perlmutter 1617 Mail Service Center Raleigh, NC 27699-1617 Subject: NPDES Permit Modification Request Sampling Reduction Request NPDES Permit #NC0026441 Town of Siler City, Chatham County Dear Mr. Perlmutter, The Town of Slier City is requesting to continue the reduced monitoring that was previously approved on our last permit cycle (2015) for NPDES# NC0026441. We are requesting that the monitoring for BODs, TSS, Ammonia Nitrogen and Fecal Coliform continue to be reduced to the criteria to two times a week. The attached data (summarized in the following table) indicates that the WWTP effluent has exceeded the minimum criteria for reduced monitoring. in addition to the test results attached, the Siler City WWTP follows all other criteria listed in Section B Approved Criteria of the October 22,2012 guidance document regarding reduction of monitoring frequencies. The data used for the analysis was for the period ofJanuary 2016 — December 2018. The Town appreciates the Division's effort to reduce the regulatory and monetary burden on systems that strive consistently to provide exceptional wastewater treatment. We thank you for your consideration in this matter. If you have any additional questions or comments, please call Brittany York at 919-742-4581. If you have any questions, please do not hesitate to contact me. Sincerely, Roy Lynch cc: Chris McCorquodale, Public Works and Utilities Director, Brittany York, Wastewater Superintendent Roy Lynch Town Manager PO Box 769.311 N Second Avenue Mier City, NC 27344-0769 rlynch@silercity.org Phone: 919-742-4731 • Fax: 919-663-3874 www.silercity,org To advance a framework for our success through balanced governance, dynamic partnerships, and an engaged community. Three Year Data Summary - Siler City NPDED # 0026441 2016 BOD Ave. BOD Max. TSS Ave. TSS Max. FC Ave. F January 2.3 5 0.3 2.7 2 3 0.1 ...., 1.w... February 3.1 5,4 1.1 5.7 2 10 0,3 3.7 March 1.5 4.7 0,0 <2.5 2 14 0.1 1.5 April 3.0 4.9 0.0 <2.5 10 53 0.1 1.7 May 1.5 4.7 0.0 <2,5 17 42 0.0 <0.5 June 0.0 0 0.0 <2.5 22 34 0,0 - <0.5 July 0.0 0 _ 0.0 <2.5 34 181 0.0 <0.5 August 0.5 4.5 0.0 <2.5 25 390 0.0 <0.5 September 2.4 10.3 1,2 5,7 25 1414 0.0 <0.5 October 0.3 3.3 0.9 2.4 4 39 0.5 3.3 November 0.9 2.7 0.0 <2.5 2 8 0.0 <0.5 _ December 2.0 3.9 1.2 8.5 2 7 1.0 6.5 2017 BOD Ave. BOD Max. TSS Ave, TSS Max. FC Ave. F January 2.5 2.5 6.7 6.7 1 2 1.1 v 1.8 February 3.4 4.9 1.0 1.0 3 5 0.0 <0.5 March 3.1 4.3 1.0 <2.5 1 0 0.0 <0.5 April 3.2 5.0 22.3 22.3 28 4 2.2 2.7 May 4.4 11.8 5.5 <2.5 10 16 0.0 <0.5 June 4.9 7.1 1.0 7.1 26 240 0.0 <0.5 July 3.3 6.2 1.3 <2.5 22 55 0.0 <0.5 August 4.0 5.7 0.0 <2.5 16 30 0.0 <0.5 September 5,0 6.9 0.0 <2.5 16 75 0.0 <0.5 October 5.7 8.3 0.0 <2.5 5 21 0.0 _ <0,5 November 1.1 5.6 0.0 <2.5 2 0 0.0 <0.5 December 0,0 <2.0 0.0 <2.5 3 7 0.0 0.5 2018 BOD Ave. BOO Max. TSS Ave. TSS Max. FC Ave. FC Max. January 0.9 3.8 0.0 <2.5 9 85 0.0 <0,5 February 0.4 2.8 0.0 <2.5 1 1 0.0 <0.5 March 1.2 8.2 0.0 <2.5 1 0 0.0 <0.5 April 0.8 4.5 0.0 <2.5 3 9 0,0 <0,5 May 1.4 3,6 0.0 <2.5 6 22 0.0 <0.5 June 1.0 3.2 0.0 <2.5 28 590 0.0 <0.5 - July 0.9 3.6 0.0 <2.5 11 25 0.0 <0.5 August 1.1 4.0 0.0 <2.5 17 127 0.0 _ <0.5 September 1.0 5.2 2.3 18.5 4 22 0.0 <0.5 October 0.2 2.0 0.0 <2.5 5 40 0.0 <0.5 November 0.0 2.0 0.4 3.4 2 5 0.0 <0.5 December 0.4 31.0 1.2 6.5 1 1 0.0 <0.5 3-Year Arithmetic Average 3-Year Geometric Mean Average Permit Limit % of Limit 37.4% 1.9 5 1.3 30.0 4.4% 5.7 200 0.1 1.0 2.9% 14.7 Y NPDES/PT POCs Review Form Version:2021.00 NPDES PERMIT WRITER (PW) COMPLETES when drafting NPDES permit: Date of Review 8/12/2021 Gary Perlmutter i'own of Siler City WWTP NC0026441 Raleigh Cheng Zhang Chris McCorquodale 5/15/2018 Cape Fear River Basin C Check all that apply PW, please: section below if you deem POC in LTMP/STMP office, regional office, and office, regional office, and (Note effective date bottom of this form) staff in central office and it to the respective SharePoint Permit) up) (coming up) - Notify PT in comment necessary to keep a specific - Email PT staff in central Facility: draft permit package. - Email PT staff in central Facility: final permit package. and 180 days after at the - Email this form to PT regional office and add PT Town Folder (04. PT_Towns> NCOOXXXXX>NPDES - PQL review note (coming - Notification about DMRs Permit Writer municipal renewal Facility Name new industries Permit Number WWTP expansion X Region Speculative limits X Regional PT Staff stream reclass. Facility PT Staff outfall relocation IWS approval date 7Q10 change Basin other Stream Class other PT staff central office contact: Kristin Litzenberger Comments from NPDES pw to PT staff (Central, RO, to Facility): has two non -categorical SlUs: Montaire Farms, authrorized MGD, and Brookwood Farms, Inc., authorized to discharge Please keep all the current POCs in LTMP, and ensure the addresses the comments in the POC table. Facility Summary and NPDES regulatory action: 2018 a design Loves 6.0 MGD, within The Facility dishcarge 1.25 0.035 MGD. STMP update The Town applied for NPDES permit renewal for Siler City WWTP in November then applied for a modification for expansion in April 2021. The WWTP has capacity of 4.0 MGD and is currently authorized to discharge 4.0 MGD into Creek, a class C and 0.25 7Q10 flow stream. The proposed expansion is to and 7Q10 has been updated to 0.09 The Facility serves about 8225 customers Status of Pretreatment Program 1) facility has no SIU's, does have 2) facility has no SIU's, does not have 3) facility has SlUs and DWQ approved 3a) Full Program with LTMP 3b) Modified Program with STMP 4) additional conditions regarding (check all that apply) Division approved Pretreatment Program that is INACTIVE Division approved Pretreatment Program Pretreatment Program (list "DEV" if program still under development) Pretreatment attached or listed below Permitted Last Reported i ime period for last reported Actual i ime period for actual L/STMP, approval date: LTMP, 05/06/2016 Industrial Flow, MGD 1.28 0.014 2016 2016 Most recent: 5/6/2016 Uncontrollable Flow, MGD NA 1.705 11/10/2016 2016 Next Cycle: 5/5/2021 PW: Find S/LTMP document for next section. POC in LTMP/ STMP Parameter of Concern (POC) Check List POC due to New effluent limit or monitoring in NPDES permit POC due to previous NPDES/ Non- Disch Permit Limit or monitoring Required by EPA* Required by 503 Sludge** POC due to SIU*** POTW POC (Explain below)*** STMP Effluent Freq LTMP Effluent Freq PQLs review From LTMP, mg/L Comments X BOD X X M X TSS X X M 2.5 X NH3 X X M 0.1 X Arsenic X M 0.010 X Cadmium* X X M 0.002 X Chromium* X X M 0.005 X Copper* X X X M 0.002 X Lead* X X M 0.010 X Mercury X X M 1 ng/I Effluent only X Molybdenum M 0.005 X Nickel* X X M 0.010 X Selenium X M 0.010 X Zinc* X X X M 0.010 X Oil & Grease X M 5.0 X TN X M 0.010 X TP X M 0.002 X Chloride X 0.010 X %Solids X M X Sludge to disposal flow X M Footnotes: *Always in the LTMP/STMP ** Only in LTMP/STMP if sludge land app or composte (dif POCs for incinerators) *** Only in LTMP/STMP while SIU still discharges to POTW **** Only in LTMP/STMP when pollutant is still of concern to POTW Updated by pw POCs that need to be added to STMP Is all data required on STMP on DMRs? Yes 1 No 26641 NPDES_PT POCs review Revised: July 24, 2007 i NPDES PERMIT WRITER (PW) COMPLETES when issuing NPDES permit: 26641 NPDES_PT POCs review Revised: July 24, 2007 NPDES Permit Public Notice Date: Effective date: 180 days after effective (date): CENTRAL OFFICE PRETREATMENT STAFF COMPLETES THIS PART: Comments from PT central to NPDES pw, PT staff Facility, and PT staff region ((ex., explanation of any POCs; info you have on IU related investigations into NPDES problems):: HWAs/AT and STMP needs to be updated by permittee 180 days after the effective date. One IUP has a copper limit of 0.2 mg/I (MAHL for copper will go from 1.11 lb/day to 0.67 lb/day) - No overallocation expected. Is all data required on STMP in spreadsheets with HWA/AT submittal? Yes No 1 REGIONAL OFFICE PRETREATMENT STAFF COMPLETES THIS PART: Comments from PT RO Staff to NPDES pw, PT staff Facility, and PT staff central (ex. issues noted missed above, updates on the actions required above 26641 NPDES_PT POCs review Revised: July 24, 2007 Perlmutter, Gary From: Hill, David A Sent: Thursday, July 29, 2021 7:08 AM To: Perlmutter, Gary Subject: Fw: USGS response to DWR USGS Low Flows request # 2021-129 (dated 2021/06/30) for Loves Creek Chatham County...RE: [EXTERNAL] Low -flow request approval Hi Gary, Here's the updated flow stats for Siler City. David Hill Environmental Specialist II Industrial Permitting Unit **Email preferred during this time* NC DEQ / Division of Water Resources / Water Quality Permitting Section NPDES Industrial Permitting Unit 919 707 3612 office 919 707 9000 main office david.hill@ncdenr.gov Physical Address: 512 North Salisbury St.,Raleigh, NC, 27604 Mailing Address: 1617 Mail Service Center, Raleigh, NC, 27699-1617 Email correspondence to and from this address is subject to the North Carolina Public Records Law and may be disclosed to third parties. From: Weaver, John C <jcweaver@usgs.gov> Sent: Wednesday, July 28, 2021 5:02 PM To: david.hill@ndenr.gov <david.hill@ndenr.gov> Cc: Hill, David A <david.hill@ncdenr.gov>; Kebede, Adugna <adugna.kebede@ncdenr.gov>; Montebello, Michael J <Michael.Montebello@ncdenr.gov>; Albertin, Klaus P <klaus.albertin@ncdenr.gov>; Weaver, John C <jcweaver@usgs.gov> Subject: USGS response to DWR USGS Low Flows request # 2021-129 (dated 2021/06/30) for Loves Creek Chatham County...RE: [EXTERNAL] Low -flow request approval CAUTION: External email. Do not click links or open attachments unless you verify. Send all suspicious email as an attachment to Report Spam. David, Note: This is part 2 of 2 of a response to two low -flow requests for this part of the Rocky River basin simultaneously received from this requestor. In response to your inquiry about the low -flow characteristics for a location on Loves Creek near Siler City in western Chatham County, the following information is provided: A check of the low -flow files here at the USGS South Atlantic Water Science Center (SAWSC, Raleigh office) indicates low -flow estimates previously determined upstream and downstream of the point of interest, identified by the lat/long i coordinates (35.729647, -79.428065) provided via email dated 06/30/2021 from the DWR USGS Low Flow portal following your request submission. Completed in 1963 and 1989, the low -flow characteristics were estimated based on transfer of flow characteristics (by drainage -area proration) from nearby index sites in vicinity of the point of interest. No USGS discharge records are known to exist for the point of interest. In the absence of site -specific discharge records sufficient for a low -flow analysis, estimates of low -flow characteristics at ungaged locations are determined by assessing a range in the low -flow yields (expressed as flow per square mile drainage area, or cfsm) at nearby sites where estimates have previously been determined. A basin delineation completed using the online USGS StreamStats application for North Carolina (https://streamstats.usgs.gov/ss/) indicates the drainage area for the point of interest (StreamStats adjusted coordinates 35.72961, -79.42806 NAD83) is 8.19 sqmi. For streams in Chatham County, low -flow characteristics published by the USGS are provided in the following reports: (1) The first is a statewide report completed in the early 1990's. It is USGS Water -Supply Paper 2403, "Low -flow characteristics of streams in North Carolina" (Giese and Mason, 1993). An online version of the report is available at http://pubs.usgs.gov/wsp/2403/report.pdf. The report provides the low -flow characteristics (based on data through 1988) via regional relations and at -site values for sites with drainage basins between 1 and 400 sqmi and not considered or known to be affected by regulation and/or diversions. (2) The second is a basin -wide report for the Cape Fear River basin published in 2001. It is USGS Water -Resources Investigations Report 01-4094, "Low -flow characteristics and discharge profiles for selected streams in the Cape Fear River Basin, North Carolina, through 1998 " (Weaver and Pope, 2001). An online version of the report is available through http://nc.water.usgs.gov/reports/wri014094/. The report provides the low -flow characteristics (based on data through 1998) for continuous -record gaging stations and partial -record sites within the Cape Fear River basin. The report also provides low -flow discharge profiles (7Q10, 30Q2, winter 7Q10, and 7Q2) for the Cape Fear River and selected tributaries within the basin. (3) The third is a statewide report published in March 2015. It is USGS Scientific Investigations Report 2015-5001, "Low -flow characteristics and flow -duration statistics for selected USGS continuous -record streamgaging stations in North Carolina through 2012" (Weaver, 2015). The report is available online at http://pubs.usgs.gov/sir/2015/5001/. The report provides updated low -flow characteristics and flow -duration statistics for 266 active (as of 2012 water year) and discontinued streamgages across the state where a minimum of 10 climatic years discharge records were available for flow analyses. Low -flow characteristics estimated for point of interest: Inspection of the latter two reports indicates the presence of six (6) nearby selected USGS partial -record sites (4) and continuous -record streamgages (2) in the general vicinity of the point of interest where low -flow characteristics were published. Added to this group of index sites are provisional low -flow characteristics (newly determined for this analysis) for the nearby active continuous -record streamgage on the Rocky River at U.S. Highway 64 near Siler City (station id 02101726, drainage area 68.7 sqmi, POR continuous since February 2009). Among these 7 index sites, the low -flow discharge yields for the indicated flow statistics are as follows: Annual 7Q10 low -flow yields ==> from 0 to 0.011 cfsm (average about 0.0044 cfsm, median about 0.004 cfsm) (zero flow at 2 of 7 index sites) 2 Annual 30Q2 low -flow yields ==> from 0 to 0.089 cfsm (average about 0.039 cfsm, median about 0.044 cfsm) (zero flow at 1 of 7 index sites) Winter 7Q10 low -flow yields ==> from 0 to 0.066 cfsm (average about 0.028 cfsm, median about 0.031 cfsm) (zero flow at 1 of 7 index sites) Annual 7Q2 low -flow yields ==> from 0 to 0.044 cfsm (average about 0.022 cfsm, median about 0.027 cfsm) (zero flow at 1 of 7 index sites) Average annual discharge yields ==> from 0.85 to 1.2 cfsm (average about 0.95 cfsm, median about 0.9 cfsm) Application of the above range in yields to the drainage area (8.19 sqmi) for the point of interest results in the following estimated low -flow discharges: Annual 7Q10 low -flow discharges ==> from 0 to 0.09 cfs (average about 0.036 cfs, median about 0.033 cfs) Annual 30Q2 low -flow discharges ==> from 0 to 0.73 cfs (average about 0.32 cfs, median about 0.36 cfs) Winter 7Q10 low -flow discharges ==> from 0 to 0.54 cfs (average about 0.23 cfs, median about 0.25 cfs) Annual 7Q2 low -flow discharges ==> from 0 to 0.36 cfs (average about 0.18 cfs, median about 0.22 cfs) Average annual discharge discharges ==> from 7 to 9.8 cfs (average about 7.8 cfs, median about 7.4 cfs) Please note: (1) The estimated flows are provided in units of cubic feet per second (cfs). (2) The low -flow yields provided above are rounded to 2 significant figures. Estimated low -flow discharges less than 1 cfs are rounded to 2 significant figures. If between 1 and 100 cfs, then rounded to 1 decimal place; if greater than 100, then rounded to the nearest whole number (zero decimal places). (3) The information provided in this message is based on a preliminary assessment and considered provisional, subject to revision pending collection of future data and further analyses. These provisional streamflow statistics are provided via the DWR USGS Low Flows cooperative agreement between the USGS and the N.C. Department of Environmental Quality, Division of Water Resources. Hope this information is helpful. Thank you. Curtis Weaver J. Curtis Weaver, Hydrologist, PE Email; icweaver@usgs.gov USGS South Atlantic Water Science Center Online: https://www.usgs.gov/centers/sa-water North Carolina - South Carolina - Georgia 3916 Sunset Ridge Road Raleigh, NC 27607 Phone: (919) 571-4043 // Fax: (919) 571-4041 From: Albertin, Klaus P <klaus.albertin@ncdenr.gov> Sent: Wednesday, June 30, 2021 10:14 AM To: david.hill@ndenr.gov Cc: Albertin, Klaus P <klaus.albertin@ncdenr.gov>; Hill, David A <david.hill@ncdenr.gov>; adugna.kebede@ncdenr.gov; 3 Weaver, John C <jcweaver@usgs.gov>; Montebello, Michael J <Michael.Montebello@ncdenr.gov> Subject: [EXTERNAL] Low -flow request approval This email has been received from outside of DOI - Use caution before clicking on links, opening attachments, or responding. Your request has been approved and will be forwarded to USGS. A response from USGS usually takes 7 - 10 business days. Request Flow Statistic Approval Request ID: 129 Requestor: David Hill Requestor e-mail: david.hill@ndenr.gov Requestor Phone: 919-707-3612 Local Government: Public Water Supply: Consultant: Contact: Reason: Permit River/Stream: Loves Creek Drainage Area (sq. mi.): 7.9 Latitude: 35.729647 Longitude: -79.428065 Other Information: Statististics: ["7Q10","7Q10 - Winter","30Q2","Average Annual"] Approved by: Hill, David A 4 NORTH CAROLINA 2020 INTEGRATED REPORT Deep AU Name AU ID Description 'Loves Creek 13711 From US 421 to Siler City WWTP Cape Fear River Basin AU Number Classification AU LengthArea AU Units 17-43-10b2 C 0.2 FW Miles 2020 Draft Water Quality Assessments PARAMETER IR CATEGORY CRITERIA STATUS REASON FOR RATING OW Benthos (Nar, AL, FW) Fish Community (Nar, AL, FW) Water Temperature (322C, AL, LP&CP) Dissolved Oxygen (4 mg/I, AL, FW) pH (6 su, AL, FW) pH (9.0, AL, FW) Turbidity (50 NTU, AL, FW miles) Fecal Coliform (GM 200/400, REC, FW) Loves Creek 4307 From Siler City WWTP to Rocky River 5 Exceeding Criteria Fair, Poor or Severe Bioclassificatior 5 Exceeding Criteria Fair, Poor or Severe Bioclassificatior 1 Meeting Criteria Meeting Criteria with Statistical Con 1 Meeting Criteria Meeting Criteria with Statistical Con 1 Meeting Criteria Meeting Criteria with Statistical Con 1 Meeting Criteria Meeting Criteria with Statistical Con 1 Meeting Criteria Meeting Criteria with Statistical Con 3a Data Inconclusive Pathogen Indicator Screening Excur 17-43-10c C 0.4 FW Miles 2020 Draft Water Quality Assessments PARAMETER IR CATEGORY CRITERIA STATUS REASON FOR RATING Benthos (Nar, AL, FW) Water Temperature (322C, AL, LP&CP) Dissolved Oxygen (4 mg/I, AL, FW) pH (6 su, AL, FW) pH (9.0, AL, FW) Turbidity (50 NTU, AL, FW miles) Fecal Coliform (GM 200/400, REC, FW) 5 Exceeding Criteria Fair, Poor or Severe Bioclassificatior 1 Meeting Criteria Meeting Criteria with Statistical Con 1 Meeting Criteria Meeting Criteria with Statistical Con 1 Meeting Criteria Meeting Criteria with Statistical Con 1 Meeting Criteria Meeting Criteria with Statistical Con 1 Meeting Criteria Meeting Criteria with Statistical Con 3a Data Inconclusive Pathogen Indicator Screening Excur 7/21/2021 NC 2020 INTEGRATED REPORT Category 5 assessments approved by EPA June 23,2021 Page 138 of 1334 AU Name AU ID Description NORTH CAROLINA 2020 303(D) LIST Deep Cape Fear River Basin AU Number Classification Length or Area Units 'Loves Creek 17-43-10b1 C 2.3 13505 From Chatham Avenue to US 421 PARAMETER IR CATEGORY CRITERIA STATUS REASON FOR RATING 303D YEAR FW Miles Dissolved Oxygen (4 mg/I, AL, FW) Loves Creek '5 lExceeding Criteria Legacy RAMS Assessments 2012 13711 From US 421 to Siler City WWTP PARAMETER Benthos (Nar, AL, FW) Fish Community (Nar, AL, FW) 17-43-10b2 C 0.2 FW Miles IR CATEGORY CRITERIA STATUS REASON FOR RATING 303D YEAR 5 Exceeding Criteria Fair, Poor or Severe Bioclassification 1998 5 Exceeding Criteria 1Fair, Poor or Severe Bioclassification 2020 Loves Creek 17-43-10c 4307 From Siler City WWTP to Rocky River C 0.4 FW Miles PARAMETER IR CATEGORY CRITERIA STATUS REASON FOR RATING 303D YEAR Benthos (Nar, AL, FW) Tick Creek 4312 From source to US 421 PARAMETER Fish Community (Nar, AL, FW) 5 Exceeding Criteria Fair, Poor or Severe Bioclassification 1998 IR CATEGORY 1'5 17-43-13a C 8.2 FW Miles CRITERIA STATUS MI REASON FOR RATING 303D YEAR Exceeding Criteria Fair, Poor or Severe Bioclassification 2006 Tick Creek 4313 From US 421 to Rocky River 17-43-13b C 4.9 FW Miles PARAMETER IR CATEGORY CRITERIA STATUS REASON FOR RATING 303D YEAR Benthos (Nar, AL, FW) 5 Exceeding Criteria Fair, Poor or Severe Bioclassification 2020 Harlands Creek(Hollands Creek) 17-43-15 4316' From source to Rocky River IR CATEGORY CRITERIA STATUS REASON FOR RATING 303D YEAR 5 Exceeding Criteria _ Fair, Poor or Severe Bioclassification 2020 PARAMETER 1Benthos (Nar, AL, FW) 10.2 FW Miles Bear Creek I17-43-16b C 4318 From SR 2189 to SR 2187 PARAMETER IR CATEGORY CRITERIA STATUS REASON FOR RATING 303D YEAR Benthos (Nar, AL, FW) 5 Exceeding Criteria Fair, Poor or Severe Bioclassification 2010 2.0 FW Miles 7/21/2021 NC 2020 303d List- Approved by EPA June 23,2021 Page 16 of 188 5/7/2021 NCDEQ-DWR :: Benthos Site Details NC Division of Water Resources • di Ili Benthos Site Details Waterbody Location Station ID Date I Bioclassification LOVES CR NR US 64 BB174 24 Jun 2003 Fair County 8 digit HUC Latitude Longitude Elevation (ft) Chatham 03030003 35.730560 -79.426110 499 Level IV Ecoregion Carolina Slate Belt Drainage Area (mi2) Stream Width (m) Stream Depth (m) 8.2 6.0 0.3 Upstream NPDES Dischargers (>1 MGD or <1 MGD and within 1 mile) Landuse (%) Forest Developed NPDES Number Impervious Cultivation Grass/Herb/Shrub Water Quality Parameters 2003 1997 1989 Temperature (°C) 23.0 26.0 0.0 Dissolved Oxygen(mg/L) 8.5 6.0 0.0 Specific Conductance (pS/cm) 570 490 0 pH (s.u.) 7.6 7.2 0.0 Habitat Assessment Scores (max score) Volume (MGD) Wetland Water Barren so\'' �1 v•,4 SNixo Substrate (%) Boulder (35), Cobble (35), Gravel (20), Sand (10), Silt (0) Water Clarity Slightly Turbid Sample Date Sample ID Method ST 24 Jun 2003 9164 Full Scale 40 27 Jun 1997 7309 Full Scale 36 01 Aug 1989 5004 Full Scale 27 EPT 6 4 2 Print Page BI EPT BI 6.82 6.96 7.45 6.35 8.33 6.92 Bioclassification Fair Poor Poor https://www.ncwater.org/?page=672&SitelD=BB174 1/1 Siler City WWTP Effluent Monitoring NC0026441 5.0 4.5 4.0 3.5 3.0 C7 2.5 2 2.0 1.5 1.0 0.5 0.0 Flow • Mo Avg Limit • ••• • • • ••• • ••• • •• • •• •• ••••• • • ••• • • ••• oti� oti� oti� oti� oti° oti° otiti otiti oti� 61' °\���ti �\�h�ti y�\ti�ti o\y��ti \I>, ��ti 50 45 40 35 30 own 25 20 120% 100% 80% 60% 40% 20% 0% BOD Removal • % Removal —Limit Wet -.. 4-vir - e►I�"��1 • • • • O�� O,� OHO O,� Off° O�y o�ti°\� o\��\ti ��ti�\� titi�y\� �o�ti�\� ti\�\� A\��\� Summary Statistics N 1444 Avg 2.790 SD 1.095 Min 0.863 Max 10.894 Summary Statistics Summer N 270 Avg 4.2 SD 4.2 Min 2.0 Max 31.0 Winter N 195 Avg 5.7 SD 9.5 Min 2 Max 76.9 Summary Statistics N 465 Avg 0.975 SD 0.044 Min 0.413 Max 0.995 Page 1 of 6 GB Perlmutter 3/23/2022 Siler City WWTP Effluent Monitoring NC0026441 E 120 100 80 60 40 20 0 • Wk Avg Total Suspended Solids (TSS) • Mo Avg otio ON' otio' otio otio oti° o\C\t . o\�\ti h\' ' N'1 o\y��ti Wk Limit - MA Limit 01> 01> 011' 011' 150.0% 100.0% 50.0% 0.0% -50.0% • -100.0% - 150.0% - 200.0% -250.0% -300.0% -350.0% TSS Removal 00 co rn m 0 %-1 c-I ci ,--I N 0 0 0 0 0 N N N N N '-N c-I - cr 0 Ln c-I LO N 0 N N 0 N CA N n N N 0 N 00 N • N N 0 N n N 00 PnrDI Cnlifnrm Summary Statistics N Avg SD Min Max 468 3.7 9.9 1.7 206.0 Summary Statistics N Avg SD Min Max 443 0.963 0.184 -2.815 0.998 Summary Statistics N Avg SD Min Max N Avg SD Min Max Summer 606 1.7 3.6 0.5 27.0 Winter 411 3.1 6.2 0.5 34 Page 2 of 6 GB Perlmutter 3/23/2022 Siler City WWTP Effluent Monitoring NC0026441 Geomean, cfu/100 mL 10,000 1,000 100 10 • • • •• 1 •• • ' Wk Avg I Cl.Q1 1.V III VI III • Mo Avg Wk Limit - - - MA Limit • • -----t --- - - - • • • r-- .•,• 6eat tilt; • ii, iil • 11* • • ,AS • • ' a • r ON' oti oti�' oti° oti�' oti° otiti otiti oti� oti� pH Summary Statistics N 418 Geomean 11 Min 1 Max 80,000 Summary Statistics N 994 Avg 21.2 SD 5.7 Min 10.0 Max 31.0 Summary Statistics N 994 Avg 8.6 SD 1.2 Min 6.1 Max 12.0 Page 3 of 6 GB Perlmutter 3/23/2022 Siler City WWTP Effluent Monitoring NC0026441 J E 10 9 8 7 5 4 3 2 1 0 • Effluent L. Limit U. Limit vrwityPesavirimiramoisvimot oti ON' oti' ON' oti° oti° 01> 01> oti' oti' °�vti ° �\�ti yo��ti �\yh\ti y'ti�ti °\���ti N,\ �\��ti '1, �\�\ti —TKN 45 40 35 30 25 E 20 15 10 5 0 Nitrogen NO2+NO3 —TN /,, ' oti° oti° oti° 61> 61> oti oti ��ti �\y��ti y�\ti�ti Total Phosphorus (TP) • Qtr Avg QA Limit Summary Statistics N 994 Avg 7.4 SD 0.2 Min 6.7 Max 8.1 Summa Statistics N 305 Avg 11.4 SD 7.5 Min 1.1 Max 39.0 NO2+NO3 N 305 Avg 8.1 SD 7.7 Min 0.2 Max 33 TKN N 305 Avg 3.4 SD 4.7 Min 0.2 Max 25.4 Summary Statistics N 33 Avg 9,419 SD 5,647 Min 1,521 Max 22,264 Summary Statistics Summer Page 4 of 6 GB Perlmutter 3/23/2022 Siler City WWTP Effluent Monitoring NC0026441 2.5 2.0 1.5 1.0 0.5 0.0 •' • • 1 • • 1 • ,r _ • ON ON ON ON ON ON ono otiti 01' 01' 01' 35 30 25 \ 20 ao 15 10 5 0 Total Zinc (Zn) Ain/ oti� oti�' oti�' oti�' otio oti° otiti otiti oti� oti� o\�ti t. y\' ' yo\, \ti \ )\ N1' � o\y4�ti �\��ti 1' '1 (1,1' ti Chloride 250 r N 125 Avg 0.17 SD 0.27 Min 0.04 Max 1.30 Winter N 88 Avg 0.19 SD 0.35 Min 0.02 Max 1.90 Summary Statistics N 17 Avg 8 SD 3 Min 4 Max 16 Summary Statistics N 18 Avg 20 SD 7 Min 10 Max 31 Page 5 of 6 GB Perlmutter 3/23/2022 Effluent Monitoring NCOO26441 Siler City WWTP 200 J 150 be 100 50 0 Summary Statistics N 16 Avg 109 SD 56 Min 28 Max 212 Page 6 of 6 GB Perlmutter 3/23/2022 Siler City WWTP DMR Comments NC0026441 Mar 2020 - Week #5 NH3-N = 11.5 mg/I Making us over our weekly limit of 6 mg/I. Also over our monthly limit of 2 mg/I @ 2.81 mg/I. It is my belief that this happened due to a few high flow events in the month of March and the fact that we are holding onto more sludge due to not being able to land apply during these wet months. We had no available storage to waste and in result had to turn off the blowers to our Oxidation ditches several times during the month to prevent from having a Clarifier bulk. We have since had Synagro here to press out sludge. Giving us available space to waste. 3/30/2020 - BOD - GGA > 228.5 mg/I due to a dirty probe. Apr 2020 - Week #1 NH3-N = 5.7 mg/I Week #2 NH3-N = 8.8 mg/I Putting us over our weekly limit of 3.0 mg/I and our monthly limit of 1.0 m/I @ 2.5 mg/I. It is my belief that this is due to high flow events in the month of April, also due to the fact that we are still holding onto more sludge then average due to not being able to land apply as frequently due to wet weather leaving us with no available storage to waste. In result having to turn off blowers to our Oxidation ditch's a few times a month to prevent from having a Clarifier bulk due to high sludge blankets. 4/7/20 BOD = 8.1 mg/I 4/9/20 BOD= 8.3 mg/I putting us over our weekly BOD limit of 7.5 mg/I GGA = > 228.5 mg/I Results could have been affected from dirty probe. Cleaned probe and replaced membrane. May 2020 - Week #4 BOD = 10 mg/I putting us over our limit of 7.5 mg/I Monthly BOD = 5.5 mg/I putting us over our monthly limit of 5.0 mg/I Week # 5 NH3-N = 3.8 mg/I over our weekly limit of 3.0 mg/I NH3-N monthly = 1.4 putting us over our monthly limit of 1.0 mg/I After making corrections of Fecal week #4 we were over our weekly limit of 400 with a reported amount of 5,280 Since we were experiencing these issues: on 6/17/2020, we consulted with Kin Ferrall from Maryland Biochemical (our bug consultant) about our treatment process and the condition of our plant. We went over lab results and sludge characteristics for the past couple of months. Based on this information it was his assumption that we could have had a high load of carbon source in the plant potentially bound up in the return sludge, causing our plant process to not be as efficient. We increased our wasting in hopes of removing the high carbon sludge. We also investigated outside sources. However, around 6/21 - 6/22 the plant seemed to be slowly recovering from the upset. The plant began to return back to normal results. It is believed this high carbon load could have been a contributing factor for the past few violations. Jun 2020 - The following parameters exceed limit value: BOD, 5-Day weekly limit value = 7.5 Week 1 reported value = 16.1, Week 2 reported value = 14.4, Week 4 reported value = 9.5, Week 5 reported value = 13.1 BOD 5-Day Monthly limit value = 5.0 Monthly reported value = 11.5 NH3-N Weekly limit value = 3.0 Week 1 reported value= 7.7, Week 2 reported value = 6.5, Week 4 reported value = 3.6 NH3-N Monthly limit = 1.0 Monthly reported value= 4.8 Siler City WWTP DMR Comments NC0026441 It is believed that these parameters exceeded limit value due to the continuous situation that we have been experiencing for the past few months. A combination of issues could be to blame, to include high flow events, holding onto sludge longer due to not being able to land apply during the wet season, and a potential high load of carbon interfering with our treatment process. We have still been working closely with Synagro and wasting as much as our storage allows us to. The plant seems to be getting closer to more consistent numbers. Moving into the month of July sampling results show great improvement. We will continue to closely monitor plant process and do what we can to produce quality Effluent. Jul 2020 - The following parameters exceeded limit value: Week #1 BOD, 5-Day weekly limit value = 7.5 mg/I Reported value = 8.5 mg/I NH3-N weekly limit value = 3 mg/I Reported limit = 6.95 mg/I These parameters were exceeded due to the continuous conditions we have been experiencing the past few months. We were unable to waste due to sludge storage being full. Synagro has been unable to land apply due to field conditions being to wet. Synagro was able to come and hauled 900,000 gallons at the beginning of July allowing us the ability to waste. Jan 2021 Exceeded the following parameters: - BOD - Weekly Limit = 15 mg/I Reported week 4 = 43.25 mg/I Monthly Limit = 10 Reported = 17.13 mg/I - NH3 as N - Weekly Limit = 6 mg/I Reported week 2 = 10.38 mg/I Reported week 4 = 12.425 mg/I Reported week 5 = 26.86 mg/I Reported week 6 = 28.1 mg/I Monthly Limit = 2 mg/I Reported = 14.35 mg/I - TSS - Weekly Limit = 45 Reported week 4 = 105.4 mg/I - Fecal Coliform - Weekly limit = 400 Reported week 5 = 2420 It is believed we exceeded these parameters due to maintenance to the Tertiary filters and blowers to the Oxidation ditches. During the process of this maintenance to the blowers we were not able to provide the proper amount of air to biologically treat the oxidation ditches. Also, the filters had to be taken completely offline for the maintenance to be completed. Blowers and Filters are back online therefore sampling results are expected to improve. This maintenance was due to equipment failure not general maintenance. Dissolved Oxygen (mg/L) Start Date LC -Up Effluent 2017-11-29 9 9.9 2017-12-15 10.5 10.5 2018-01-23 9.4 12 2018-02-26 7.5 10.5 2018-03-13 10.4 10.8 2018-04-30 9.2 8.6 2018-05-09 6.9 8.3 2018-05-25 7.6 9.3 2018-06-06 7.5 7 2018-06-29 6.3 7 2018-07-17 6 7.3 2018-07-30 6.9 7.7 2018-08-15 6.5 7.5 2018-08-28 7.3 7.5 2018-09-20 7.4 7.7 2018-10-10 6.8 7.3 2018-11-26 10.8 9.3 2018-12-18 11.3 8.6 2019-01-22 11.3 8.8 2019-02-13 11.9 9.4 2019-03-26 10.2 8.7 2019-04-22 9.4 8.6 2019-05-13 8.3 7.8 2019-05-30 7 7.1 2019-06-11 7.7 7.3 2019-06-21 7.9 7.9 2019-07-19 5.1 7.2 2019-07-29 7.1 7.8 2019-08-14 6.8 7.1 2019-08-27 7.2 7.9 2019-09-16 6.3 7.3 2019-09-30 7.6 9 2019-10-22 7.6 7 2019-11-14 10.9 8.7 2019-12-10 10.7 9.1 2020-01-28 11 10.1 2020-02-24 11.3 10.2 2020-03-30 9.4 9.1 2020-04-30 9.2 8.6 2020-05-12 9.1 8.9 2020-05-27 8.3 9.1 2020-06-17 8.6 7.9 2020-06-30 7.1 7.4 2020-07-20 6.77 7.3 2020-07-31 7.08 7.4 LC-Dn 9.9 11.2 10.2 9.5 11.4 9.2 8.5 8 7.7 7.3 7.4 7 7.5 7.4 7.5 7.4 11.2 11.7 13.3 11.9 10.2 9.2 8.2 7.2 8.2 7.5 6.9 7.3 7.1 7.4 7.2 7.2 8.5 10.1 10.9 11.2 11 8.6 9.3 9 7.8 8.3 5.4 6.96 7.83 RR-UIIIIIIMILd 9.7 10.4 5.0 5.0 5.0 5.0 11.2 11.4 5.0 10.2 10.5 11.3 9.8 8.6 5.5 8.7 8 5.0 6.4 6.3 5.0 6.9 6.8 5.0 5.0 5.0 5.0 4.1 5.1 5.0 6.9 6.4 4.1 5.9 4.3 5 6.9 6.2 5.0 3.3 5 5.0 5.0 5.0 10.5 5.0 1 1.9 5.0 12.6 5.0 11 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 4.6 5.5 5.0 5.0 5.0 5.0 1 1.7 5.0 10.5 5.0 1 1.2 5.0 5.0 5.0 5.0 7.7 7.3 5.0 7.1 6.9 5.8 6.1 11.4 11.8 10.3 10.9 10 9.8 8.8 8.7 7.8 7.1 5.5 6.8 8.1 7 6.7 6.5 5 7.4 7.1 6.9 6.1 6.7 7.2 6.4 3.2 5.2 7.2 7.6 9.8 10.9 10.9 10.7 11.1 9.4 7.8 9.3 9.1 8.3 8.8 8.2 8.1 5.0 5.9 6.61 5.0 6.98 6.85 5.0 6.54 6.49 5.0 2020-08-06 7.19 7.5 6.73 7.16 6.56 5.0 2020-08-31 6.83 7.5 7.49 4.01 6.63 5.0 2020-09-15 7.19 7.6 7.42 5.91 5.27 5.0 2020-09-29 7.43 7.4 7.89 7.79 6.61 5.0 2020-10-26 8.4 8.6 8.7 7.2 6.5 5.0 2020-11-10 8.6 8.7 8.9 7.7 7 5.0 2020-12-08 11.2 10.4 10.3 10.5 10.4 5.0 N Avg SD Min Max 52 52 52 52 52 8.37 8.41 8.68 7.74 7.83 1.71 1.18 1.68 2.32 2.11 5.1 7 5.4 3.2 5 11.9 12 13.3 11.8 12.6 Anova: Single Factor SUMMARY Groups Count Sum Average Variance LC -Up 52 434.99 8.365192 2.919614 Effluent 52 437.2 8.407692 1.398763 LC-Dn 52 451.12 8.675385 2.83201 RR -Up 52 402.29 7.736346 5.368337 RR-Dn 52 407.21 7.830962 4.453966 ANOVA irce of Variat SS df MS F P-value F crit F crit Between Grc 33.67161 4 8.417901 2.479837 0.044499 2.407043 2.409257 Within Grou 865.6072 255 3.394538 Total 899.2788 259 Conclusion: average DO is not different among instream stations and effluent. t-Test: Two -Sample Assuming Unequal Variances LC -Up LC-Dn Mean 8.365192 8.675385 Variance 2.919614 2.83201 Observations 52 52 Hypothesized Mean Difference 0 df 102 t Stat -0.93269 P(T<=t) one -tail 0.176591 t Critical one -tail 1.65993 P(T<=t) two -tail 0.353182 t Critical two -tail 1.983495 Temperature (°C Start Date LC -Up Effluent LC-Dn 2017-11-29 8.2 15 14.2 2017-12-15 5.3 12 10.5 2018-01-23 12.4 13 12.1 2018-02-26 15.9 16 16.1 2018-03-13 5.4 12 7.6 2018-04-30 14.2 17 16.4 2018-05-09 17.6 21 20.1 2018-05-25 22 23 22.4 2018-06-06 21.3 25 23.3 2018-06-29 24 27 26.7 2018-07-17 24 28 27.5 2018-07-30 24.5 28 25.2 2018-08-15 23.9 26 26.2 2018-08-28 24.1 25 26.6 2018-09-20 23.6 24 24.1 2018-10-10 22.3 26 24.5 2018-11-26 11.1 15 11.7 2018-12-18 7.9 12 9.4 2019-01-22 3.3 11 5.9 2019-02-13 9.5 13 10.6 2019-03-26 13 16 13.8 2019-04-22 15.3 19 16.4 2019-05-13 20.4 23 21.8 2019-05-30 24.4 26 26.8 2019-06-11 22.8 25 24.3 2019-06-21 23.6 27 25.6 2019-07-19 25.7 30 29.5 2019-07-29 24.4 29 28.5 2019-08-14 25.2 28 27.8 2019-08-27 21.9 27 26 2019-09-16 23.7 28 27.5 2019-09-30 26.7 28 23.5 2019-10-22 17.3 23 21.6 2019-11-14 6.6 17 13.8 2019-12-10 11.6 18 17 2020-01-28 8.7 15 11.8 2020-02-24 9.4 15 11.9 2020-03-30 19.2 20 19.8 2020-04-30 15.8 21 16.7 2020-05-12 13.1 21 19.2 2020-05-27 20.4 22 20.3 2020-06-17 17.8 22 19.5 2020-06-30 24.2 27 26.7 2020-07-20 26.8 30 29.1 2020-07-31 26 30 28.6 2020-08-06 25.4 29 28.1 R RR-Dn 8.2 7.6 4.9 4.4 6.2 11 15.1 7.8 17.8 21.9 25.5 16 7.6 16 20.51 23.6 26.6 24 27.6 25.6 29 27 26.1 26.1 27.3 26.1 26.6 25.8 25.8 23.7 23.6 23.2 9 10.1 6.8 7.4 5.6 4.8 9.5 9.4 13.2 13 18 17 22.3 21.6 27.3 26.9 26.3 24.1 26.9 25.6 30.5 28.5 28.2 26.4 29.6 27.8 23.1 22.9 27.5 25.6 25.4 24.6 16.9 17.1 9 8.2 10.2 11.2 9 9.6 9.4 9.4 19.6 19.5 17.4 16.8 17.6 16.9 21.9 20.9 21 19 26.8 30.8 29.3 28.8 26.7 29.7 28.6 27.5 Loves Cr Rocky R Standard Dn-Up Dn-Up 32.0 6.0 -0.6 32.0 5.2 -0.5 32.0 -0.3 4.8 32.0 0.2 0.9 32.0 2.2 -0.2 32.0 2.2 -1.8 32.0 2.5 -1.4 32.0 0.4 -1.9 32.0 2.0 -2.6 32.0 2.7 -2 32.0 3.5 -2 32.0 0.7 0 32.0 2.3 -1.2 32.0 2.5 -0.8 32.0 0.5 -2.1 32.0 2.2 -0.4 32.0 0.6 1.1 32.0 1.5 0.6 32.0 2.6 -0.8 32.0 1.1 -0.1 32.0 0.8 -0.2 32.0 1.1 -1 32.0 1.4 -0.7 32.0 2.4 -0.4 32.0 1.5 -2.2 32.0 2.0 -1.3 32.0 3.8 -2 32.0 4.1 -1.8 32.0 2.6 -1.8 32.0 4.1 -0.2 32.0 3.8 -1.9 32.0 -3.2 -0.8 32.0 4.3 0.2 32.0 7.2 -0.8 32.0 5.4 1 32.0 3.1 0.6 32.0 2.5 0 32.0 0.6 -0.1 32.0 0.9 -0.6 32.0 6.1 -0.7 32.0 -0.1 -1 32.0 1.7 -2 32.0 2.5 -0.1 32.0 2.3 -1.1 32.0 2.6 -0.7 32.0 2.7 -1.3 2020-08-31 24.4 28 27.7 27.1 27.3 32.0 3.3 0.2 2020-09-15 21 28 25.7 24.9 24 32.0 4.7 -0.9 2020-09-29 21 25 23.9 21.9 21.9 32.0 2.9 0 2020-10-26 16.4 22 20.6 17.9 18 32.0 4.2 0.1 2020-11-10 16.8 22 21.2 16.8 16 32.0 4.4 -0.8 2020-12-08 6.9 16 11.2 8.8 8.3 32.0 4.3 -0.5 N Avg SD Min Max 52 52 52 52 52 18.0 22.0 20.5 19.9 19.2 6.8 5.8 6.6 8.1 7.5 3.3 11 5.9 4.9 4.4 26.8 30 29.5 30.8 29.7 52 52 2.5 -0.7 1.9 1.2 -3.2 -2.6 7.2 4.8 No. increases > 2.8° C 18 1 Temperature O LC -Up • Effluent • LC-Dn A RR -Up ♦ RR-Dn -Standard 35 - 30 25 20 15 - I I g 10 - I 5 - QA O 0 A.� A sa t. • • g A A A Coe • O e A p t • en • A '1ti do ,y, N Oti ' . O� ti3 o°) 0 ' • 0 tiff 0 oti oA Anova: Single Factor SUMMARY Groups Count Sum Average Variance LC -Up 52 936.4 18.007692 46.37406 Effluent 52 1146 22.038462 33.37104 LC-Dn 52 1067 20.519231 43.39923 RR -Up 52 1034.3 19.890385 65.24442 RR-Dn 52 1000.5 19.240385 55.55736 ANOVA irce of Variat. SS df MS F P-value F crit F crit Between Grc 466.1687 4 116.54217 2.388687 0.051487 2.407043 2.409257 Within Groin 12441.25 255 48.78922 Total 12907.42 259 Conclusion: differences in average temperature were not detected among sampling sites. Specific Conductance (µS/cm) Start Date LC -Up LC-D 2017-11-29 254 696 2017-12-15 253 653 2018-01-23 200 395 2018-02-26 250 588 2018-03-13 129 250 2018-04-30 156 394 2018-05-09 198 640 2018-05-25 139 316 2018-06-06 163 489 2018-06-29 288 779 2018-07-17 234 747 2018-07-30 103 275 2018-08-15 183 561 2018-08-28 185 667 2018-09-20 138 213 2018-10-10 201 589 2018-11-26 128 154 2018-12-18 122 219 2019-01-22 121 243 2019-02-13 123 308 2019-03-26 98 224 2019-04-22 115 229 2019-05-13 184 600 2019-05-30 195 928 2019-06-11 133 543 2019-06-21 136 790 2019-07-19 213 1210 2019-07-29 169 1205 2019-08-14 229 846 2019-08-27 190 1043 2019-09-16 285 1142 2019-09-30 1044 355 2019-10-22 169 1010 2019-11-14 164 905 2019-12-10 220 1060 2020-01-28 123 501 2020-02-24 133 500 2020-03-30 150 643 2020-04-30 78 178 2020-05-12 188 869 2020-05-27 167 100 2020-06-17 99 309 2020-06-30 192 891 2020-07-20 151 830 2020-07-31 163 814 MI R-Up RR-Dn 991506 96 332 124 303 97 202 91 96 77 106 85 205 87 119 84 131 105 297 104 313 80 200 84 116 89 194 53 80 75 231 72 82 69 85 81 100 86 144 75 100 67 92 83 160 88 251 86 134 94 285 123 643 114 645 89 535 86 136 113 712 121 913 92 154 109 316 99 401 77 112 75 79 88 172 71 75 85 265 66 116 60 89 72 269 76 134 83 273 2020-08-06 166 957 83 158 2020-08-31 272 956 87 167 2020-09-15 202 1011 91 370 2020-09-29 202 799 94 159 2020-10-26 231 848 105 396 2020-11-10 229 978 103 366 2020-12-08 137 460 82 126 N Avg SD Min Max 52 52 52 52 192.2 632.9 88.0 243.2 130.6 308.5 15.5 182.4 78 100 53 75 1044 1210 124 913 Anova: Single Factor SUMMARY Groups Count Sum Average Variance LC -Up LC-Dn RR -Up RR-Dn 52 9995 192.2115 17043.54 52 32910 632.8846 95169.44 52 4575 87.98077 238.882 52 12645 243.1731 33272.85 0 0 #DIV/0! #DIV/0! ANOVA Ira, of Variat SS df MS F P-value F crit Between Grn 8846940 4 2211735 60.41235 1.54E-33 2.41613 Within Grou 7431960 203 36610.64 Total 16278900 207 Conclusion: average Conductivity differences were found among the four stations t-Test: Two -Sample Assuming Unequal Variances LC -Up LC-Dn Mean 192.2115 632.8846 Variance 17043.54 95169.44 Observations 52 52 Hypothesized Mean Difference 0 df 69 t Stat -9.4863 P(T<=t) one -tail 1.96E-14 t Critical one -tail 1.667239 P(T<=t) two -tail 3.92E-14 t Critical two -tail 1.994945 Conclusion: downstream Loves Creek has higher Conductivity than has upstream Loves Creek t-Test: Two -Sample Assuming Unequal Variances RR -Up RR-Dn Mean 87.98077 243.1731 Variance 238.882 33272.85 Observations 52 52 Hypothesized Mean Difference 0 df 52 t Stat -6.11327 P(T<=t) one -tail 6.37E-08 t Critical one -tail 1.674689 P(T<=t) two -tail 1.27E-07 t Critical two -tail 2.006647 Conclusion: downstream Rocky River has higher Conductivity than has upstream Rocky River. Fecal Coliform (cfu/100 mL) Start Date LC -Up Effluent LC-Dn RR -Up RR-Dn 2017-11-28 1 2017-11-29 5 50 105 31 2017-12-14 1 2017-12-15 6 23 48 37 2018-01-22 1 2018-01-23 7600 4000 1000 4200 2018-02-26 6800 1600 31 35 2018-02-27 1 2018-03-13 1000 1 460 420 800 2018-04-30 36 9 27 16 32 2018-05-09 114 29 37 30 2018-05-10 1 2018-06-28 14 2018-06-29 171 41 95 105 2018-07-17 510 25 152 14 49 2018-08-28 52 6 24 6 67 2018-09-20 200 171 76 105 2018-09-21 2 2018-10-10 133 8 230 86 86 2018-11-26 280 197 270 240 2018-11-27 1 2018-12-18 31 1 22 1400 800 2019-01-22 35 1 19 95 114 2019-02-13 460 1 230 105 600 2019-03-26 450 6 230 250 1000 2019-04-22 200 124 230 105 2019-04-23 8 2019-05-13 7600 53 1400 95 124 2019-06-11 1600 31 530 800 370 2019-07-17 20 2019-07-19 143 76 16 67 2019-08-14 1000 7 152 23 162 2019-09-16 37 29 152 14 95 2019-10-22 360 14 86 800 800 2019-11-14 220 20 76 610 410 2019-12-10 76 10 22 21 133 2020-01-28 162 57 1600 1400 2020-01-29 16 2020-02-24 95 6 57 76 57 2020-03-30 124 6 14 40 48 2020-04-29 8 2020-04-30 12200 8400 12600 9800 2020-05-12 9 47 10 52 2020-05-13 10 2020-06-17 2400 308 1400 1600 6400 2020-07-20 260 43 181 76 105 2020-08-05 33 2020-08-06 350 143 133 450 2020-09-15 370 114 67 95 2020-09-16 38 2020-10-26 171 28 133 124 600 2020-11-10 129 17 57 19 105 2020-12-08 220 11 105 440 280 N Geomean Min Max 38 38 38 38 38 226 7 127 113 195 5 1 14 6 30 12200 308 8400 12600 9800 100000 10000 1000 100 10 ° c2 Fecal Coliform O LC -Up ■ Effluent • LC-Dn ° RR -Up ♦ RR-Dn iO O § A ° 0 Q;2 OSA8A•.a�c• g A: • • maa• • b• o • ■• ■ ■■� ■ 1 MEM ■ .L'L N. tit ,. oti ,. o° 'V o°) 0 N. 0 tiff ov 0 6� TKN (mg/L) Start Date LC -Up Effluent LC-Dn RR -Up RR-Dn 2017-11-28 0.2 2017-11-29 0.2 0.2 0.2 0.53 2017-12-14 0.2 2017-12-15 0.35 0.94 0.4 0.92 2018-01-22 2.7 2018-01-23 1.13 1.15 0.93 1.47 2018-02-26 0.99 0.52 0.94 1.73 2018-02-27 0.2 2018-03-13 0.51 1 0.54 0.85 0.93 2018-04-30 0.82 0.59 1.33 1.12 2018-05-02 1.5 2018-05-08 1.4 2018-05-09 0.5 0.2 1.12 1.25 2018-06-29 0.52 0.2 0.94 0.99 2018-07-03 3.3 2018-07-17 0.34 0.5 0.2 0.86 1.05 2018-08-28 1.22 1.3 0.2 1.78 1.3 2018-09-20 2.45 10.4 1.94 3.15 2.51 2018-10-08 1.8 2018-10-10 1.19 1.16 2.31 2.33 2018-11-26 1.33 1.1 1.35 1.16 2018-11-27 0.5 2018-12-18 0.47 0.5 0.36 1.13 1.11 2019-01-22 0.63 0.5 0.37 1.15 1.09 2019-02-11 1.1 2019-02-13 1.59 0.88 1.49 1.46 2019-03-26 0.52 2.2 0.72 0.84 0.75 2019-04-22 0.36 0.15 1.36 0.71 2019-04-23 2.1 2019-05-13 1.54 1.2 0.24 1.05 1.06 2019-05-28 3 2019-05-30 0.91 2019-06-11 0.55 2.7 0.2 0.78 0.87 2019-06-21 0.94 2019-07-19 0.46 0.2 0.55 1.02 2019-07-23 2 2019-07-29 3 0.72 2019-08-12 1.8 2019-08-14 0.23 1.07 0.59 1.14 2019-08-26 0.5 2019-08-27 0.87 2019-09-16 0.2 0.2 0.72 1 2019-09-30 0.67 2019-10-01 2.7 2019-10-22 0.53 0.2 0.68 0.74 2019-10-24 2019-11-12 2019-11-14 2019-12-10 2020-01-28 2020-01-29 2020-02-24 2020-03-30 2020-04-01 2020-04-29 2020-04-30 2020-05-12 2020-05-13 2020-05-27 2020-05-28 2020-06-17 2020-06-29 2020-06-30 2020-07-20 2020-07-30 2020-07-31 2020-08-05 2020-08-06 2020-08-31 2020-09-01 2020-09-15 2020-09-16 2020-09-29 2020-09-30 2020-10-26 2020-11-10 2020-12-08 0.78 0.2 0.2 2 6 0.2 1.9 0.2 0.94 0.5 1.01 0.54 0.87 0.6 0.53 0.73 0.5 0.81 0.95 1.08 1.5 0.29 7.79 1 1.28 1.16 0.57 0.39 0.95 0.55 0.53 0.42 0.44 0.42 1.4 3.2 2.5 5.3 1.2 1.8 1.2 1.5 1.5 1 1.2 1.6 0.67 1.21 1.67 3.98 0.99 1.61 0.9 1.06 1.86 1.04 0.72 1.54 1.27 0.84 8.13 0.89 0.71 1.04 1.95 1.12 2.07 0.2 0.2 1.05 0.94 0.88 0.88 1.15 0.97 0.96 1.12 N 38 46 38 48 38 Avg 0.69 1.93 1.13 1.05 1.16 SD 0.48 1.78 1.79 0.48 0.45 Min 0.20 0.20 0.15 0.20 0.53 Max 2.45 10.4 8.13 3.15 2.51 12 10 8 J ern 6 ■ E ■ 4 - ■ • • U. • 20 teAtce tOligktela.took4614. ti� ti6 tiA h tioti ti, o� ti� 6) 6 , 6 tiff , 6 6 Total Kjeldahl Nitrogen (TKN) O LC -Up ■ Effluent • LC-Dn 0 RR -Up ♦ RR-Dn ■ • • Anova: Single Factor SUMMARY Groups Count Sum Average Variance LC-U p 38 26.03 0.685 0.230166 Effluent 46 88.68 1.927826 3.176564 LC-Dn 38 42.99 1.131316 3.206758 RR -Up 48 50.3 1.047917 0.232404 RR-Dn 38 43.96 1.156842 0.204325 ANOVA irce of Variat SS df MS F P-value F crit Between Grc 35.77964 4 8.944911 6.29193 8.6E-05 2.41613 Within Grou 288.5946 203 1.421648 Total 324.3742 207 Conclusion: differences detected among the five sampling sites. t-Test: Two -Sample Assuming Unequal Variances LC -Up LC-Dn Mean 0.685 1.131316 Variance 0.230166 3.206758 Observations 38 38 Hypothesized Mean Difference 0 df 42 t Stat -1.48405 P(T<=t) one -tail 0.072631 t Critical one -tail 1.681952 P(T<=t) two -tail 0.145262 t Critical two -tail 2.018082 Conclusion: no difference detected between up- and downstream Loves Creek. t-Test: Two -Sample Assuming Unequal Variances RR -Up RR-Dn Mean 1.047917 1.156842 Variance 0.232404 0.204325 Observations 48 38 Hypothesized Mean Difference 0 df 82 t Stat -1.07753 P(T<=t) one -tail 0.142201 t Critical one -tail 1.663649 P(T<=t) two -tail 0.284402 t Critical two -tail 1.989319 Conclusion: no difference detected between up- and downstream Rocky River. NO2+NO3 (mg/L) Start Date LC -Up Effluent LC-Dn RR -Up RR-Dn 2017-11-28 15.5 2017-11-29 0.06 15.1 0.02 8.15 2017-12-14 12.6 2017-12-15 0.43 13.4 0.04 5.04 2018-01-22 12.2 2018-01-23 1.24 5.69 0.12 1.52 2018-02-26 0.31 14.2 0.69 3.25 2018-02-27 20.6 2018-03-13 0.92 11.4 3.63 0.49 0.66 2018-04-30 0.37 4.24 0.33 0.64 2018-05-02 18.1 2018-05-08 17.3 2018-05-09 0.33 19.4 0.35 2.78 2018-06-29 0.78 25.4 0.17 3.17 2018-07-03 19.4 2018-07-17 0.28 17 15.7 0.2 3.56 2018-08-28 0.28 15.9 14.6 0.23 1.89 2018-09-20 0.86 5.9 1.52 0.47 0.73 2018-10-08 17.2 2018-10-10 0.16 13.5 0.23 3.1 2018-11-26 0.65 1.62 0.84 1.01 2018-11-27 8.2 2018-12-18 0.7 2.45 0.73 0.95 2019-01-22 0.56 8.1 3.76 0.68 0.92 2019-02-11 14.4 2019-02-13 0.44 5.94 0.66 1.58 2019-03-26 0.39 1.7 0.77 0.64 0.67 2019-04-22 0.49 3.06 0.43 0.77 2019-04-23 10 2019-05-13 0.43 27 15.5 0.24 1.97 2019-05-28 23 2019-05-30 0.16 2019-06-11 1.11 21 3.6 0.11 1.27 2019-06-21 0.07 2019-06-25 18.9 2019-07-19 0.34 16.9 0.32 2.13 2019-07-23 20 2019-07-29 0.02 2019-08-12 7.7 2019-08-14 0.41 3.86 0.08 1.31 2019-08-26 23.4 2019-08-27 0.21 2019-09-16 0.13 24.4 24.9 0.14 6.43 2019-09-30 0.11 2019-10-01 26.2 2019-10-22 0.68 19.6 0.58 1.68 2019-10-24 23.4 2019-11-12 33 2019-11-14 0.53 16.6 0.24 4.51 2019-12-10 0.31 27.1 18.4 0.27 6.14 2020-01-28 0.58 8.48 1.07 1.07 2020-01-29 9.8 2020-02-24 0.52 6.5 4.8 0.83 0.83 2020-03-30 0.3 0.64 0.06 0.93 2020-04-01 2 2020-04-29 7.9 2020-04-30 0.29 0.34 0.21 0.22 2020-05-12 0.53 6.66 0.38 0.94 2020-05-13 2020-05-27 0.29 2020-05-28 0.72 2020-06-17 0.39 0.98 0.48 0.51 0.64 2020-06-29 1.2 2020-06-30 0.29 2020-07-20 0.74 4.8 8.78 0.03 0.15 2020-07-31 0.1 2020-08-05 3 2020-08-06 0.6 0.52 0.09 0.42 2020-08-31 0.09 2020-09-01 6.2 2020-09-15 0.42 1.47 0.11 0.83 2020-09-16 1.7 2020-09-29 0.1 2020-09-30 3.2 2020-10-26 0.2 13.9 14.8 0.34 3.73 2020-11-10 0.11 20.4 16 0.32 5.54 2020-12-08 0.45 8 3.34 0.54 0.98 N 38 44 38 48 38 Avg 0.48 13.43 9.20 0.32 2.16 SD 0.26 8.58 7.47 0.25 1.97 Min 0.06 0.72 0.34 0.02 0.15 Max 1.24 33 25.4 1.07 8.15 Nitrite+Nitrate Nitrogen (NO2+NO3) O LC -Up ■ Effluent • LC-Dn 0 RR -Up ♦ RR-Dn 4" - - - -J _i^ .A_,k AA, Anova: Single Factor SUMMARY Groups Count Sum Average Variance LC -Up 38 18.32 0.482105 0.068487 Effluent 44 590.9 13.42955 73.62559 LC-Dn 38 349.65 9.201316 55.86546 RR -Up 48 15.23 0.317292 0.064327 RR-Dn 38 82.11 2.160789 3.865937 ANOVA irce of Variat SS df MS F P-value F crit Between Grc 5928.411 4 1482.103 55.3566 2.06E-31 2.416574 Within Grou 5381.519 201 26.77373 Total 11309.93 205 Conclusion: highly significant differences were detected among the five sites. t-Test: Two -Sample Assuming Unequal Variances LC -Up LC-Dn Mean 0.482105 9.201316 Variance 0.068487 55.86546 Observations 38 38 Hypothesized Mean Difference 0 df 37 t Stat -7.18673 P(T<=t) one -tail 8E-09 t Critical one -tail 1.687094 P(T<=t) two -tail 1.6E-08 t Critical two -tail 2.026192 Conclusion: Loves Creek NO2+NO3 was strongly significantly higher downstream. t-Test: Two -Sample Assuming Unequal Variances RR -Up RR-Dn Mean 0.317292 2.160789 Variance 0.064327 3.865937 Observations 48 38 Hypothesized Mean Difference 0 df 38 t Stat -5.74203 P(T<=t) one -tail 6.43E-07 t Critical one -tail 1.685954 P(T<=t) two -tail 1.29E-06 t Critical two -tail 2.024394 Conclusion: Rocky River NO2+NO3 was strongly significantly higher downstream. NH 3 (mq/L) Start Date LC -Up Effluent LC-Dn RR -Up RR-Dn 2017-11-29 0.02 0.5 0.04 0.02 0.02 2017-12-15 0.02 0.5 0.05 0.02 0.02 2018-01-23 0.03 0.5 0.02 0.02 0.09 2018-02-26 0.21 0.5 0.07 0.08 0.08 2018-03-13 0.1 0.5 0.09 0.11 0.11 2018-04-30 0.02 0.5 0.02 0.02 0.02 2018-05-09 0.04 0.5 0.04 0.09 0.09 2018-06-29 0.02 0.5 0.02 0.11 0.04 2018-07-17 0.02 0.5 0.02 0.02 0.02 2018-08-28 0.02 0.5 0.02 0.11 0.04 2018-09-20 0.16 2.6 0.25 0.04 0.06 2018-10-10 0.02 0.5 0.02 0.02 0.02 2018-11-26 0.02 0.5 0.02 0.02 0.02 2018-12-18 0.02 0.5 0.02 0.02 0.02 2019-01-22 0.02 0.5 0.02 0.02 0.02 2019-02-13 0.02 0.5 0.02 0.02 0.02 2019-03-26 0.02 1.6 0.02 0.02 0.02 2019-04-22 0.02 0.5 0.02 0.06 0.02 2019-05-13 0.07 0.5 0.02 0.02 0.02 2019-05-30 0.5 0.22 2019-06-11 0.15 0.5 0.03 0.02 0.02 2019-06-21 0.5 0.02 2019-07-19 0.02 0.5 0.02 0.02 0.02 2019-07-29 0.5 0.02 2019-08-14 0.02 0.5 0.08 0.02 0.02 2019-08-27 0.5 0.02 2019-09-16 0.02 0.5 0.02 0.02 0.02 2019-09-30 0.5 0.03 2019-10-22 0.02 0.5 0.02 0.02 0.02 2019-11-14 0.02 0.5 0.02 0.02 0.02 2019-12-10 0.02 0.5 0.02 0.02 0.02 2020-01-28 0.02 0.5 0.02 0.03 0.06 2020-02-24 0.02 0.5 0.02 0.02 0.02 2020-03-30 0.02 14 7.11 0.02 0.51 2020-04-30 0.12 0.5 0.14 0.13 0.13 2020-05-12 0.02 0.5 0.04 0.04 0.02 2020-05-27 0.5 0.03 2020-06-17 0.02 1.2 2.23 0.18 0.08 2020-06-30 0.5 0.03 2020-07-20 0.02 0.5 0.02 0.02 0.02 2020-08-06 0.02 3.2 7.52 0.03 0.03 2020-09-15 0.02 0.5 0.02 0.02 0.02 2020-10-26 0.02 0.5 0.02 0.02 0.02 2020-11-10 0.02 0.5 0.02 0.02 0.02 2020-12-08 0.02 0.5 0.02 0.06 0.04 N Avg SD Min Max 38 45 38 45 38 0.04 0.95 0.48 0.04 0.05 0.05 2.06 1.67 0.05 0.08 0.02 0.5 0.02 0.02 0.02 0.21 14 7.52 0.22 0.51 0 LC -Up ■ Effluent • LC-Dn A RR -Up ♦ RR-Dn Anova: Single Factor SUMMARY Groups Count Sum Average Variance LC -Up 38 1.48 0.038947 0.002118 Effluent 45 42.6 0.946667 4.242545 LC-Dn 38 18.19 0.478684 2.796968 RR -Up 45 1.94 0.043111 0.002067 RR-Dn 38 1.86 0.048947 0.006756 ANOVA irce of Variat SS df MS F P-value F crit Between Grc 27.86933 4 6.967332 4.771503 0.00107 2.417028 Within Grou 290.5791 199 1.460197 Total 318.4484 203 Conclusion: differences were detected among all sampling sites. t-Test: Two -Sample Assuming Unequal Variances LC -Up LC-Dn Mean 0.038947 0.478684 Variance 0.002118 2.796968 Observations 38 38 Hypothesized Mean Difference 0 df 37 t Stat -1.62023 P(T<=t) one -tail 0.056838 t Critical one -tail 1.687094 P(T<=t) two -tail 0.113676 t Critical two -tail 2.026192 Conclusion: differences were not detected between the Loves Creek stations. t-Test: Two -Sample Assuming Unequal Variances RR -Up RR-Dn Mean 0.043111 0.048947 Variance 0.002067 0.006756 Observations 45 38 Hypothesized Mean Difference 0 df 55 t Stat -0.39019 P(T<=t) one -tail 0.34895 t Critical one -tail 1.673034 P(T<=t) two -tail 0.6979 t Critical two -tail 2.004045 Conclusion: differences were not detected between the Rocky River stations. Total Phosphorus (mg/L) Start Date LC -Up Effluent LC-Dn RR -Up RR-Dn 2017-11-28 0.02 2017-11-29 0.02 0.02 0.02 0.02 2017-12-14 0.02 2017-12-15 0.032 0.027 0.02 0.02 2018-01-22 0.02 2018-01-23 0.158 0.081 0.067 0.175 2018-02-26 0.05 0.033 0.088 0.072 2018-02-27 0.046 2018-03-13 0.035 0.059 0.031 0.101 0.11 2018-04-30 0.033 0.025 0.099 0.083 2018-05-02 0.04 2018-05-08 0.04 2018-05-09 0.041 0.023 0.096 0.08 2018-06-29 0.041 0.021 0.059 0.039 2018-07-03 0.04 2018-07-17 0.044 0.04 0.024 0.067 0.045 2018-08-28 0.041 0.04 0.02 0.075 0.064 2018-09-20 0.03 0.044 0.028 0.23 0.178 2018-10-08 0.04 2018-10-10 0.054 0.036 0.114 0.088 2018-11-26 0.022 0.025 0.155 0.136 2018-11-27 0.04 2018-12-18 0.02 0.04 0.02 0.172 0.136 2019-01-22 0.02 0.04 0.02 0.109 0.086 2019-02-11 0.041 2019-02-13 0.02 0.025 0.06 0.041 2019-03-26 0.032 0.06 0.036 0.095 0.076 2019-04-22 0.038 0.034 0.16 0.116 2019-04-23 0.04 2019-05-13 0.08 0.04 0.051 0.079 0.075 2019-05-28 0.09 2019-05-30 0.058 2019-06-11 0.106 0.08 0.09 0.099 0.102 2019-06-21 0.067 2019-06-25 0.08 2019-07-19 0.059 0.066 0.091 0.067 2019-07-23 0.09 2019-07-29 0.04 0.065 2019-08-12 0.06 2019-08-14 0.056 0.061 0.067 0.064 2019-08-26 0.06 2019-08-27 0.185 2019-09-16 0.038 0.07 0.055 0.089 0.067 2019-09-30 0.095 2019-10-01 0.07 2019-10-22 0.055 0.064 0.166 0.096 2019-10-24 0.07 2019-11-12 0.08 2019-11-14 0.054 0.055 0.048 0.069 2019-12-10 0.02 0.05 0.02 0.04 0.028 2020-01-27 0.05 2020-01-28 0.025 0.03 0.139 0.144 2020-02-24 0.02 0.06 0.024 0.08 0.084 2020-03-30 0.042 0.112 0.079 0.059 2020-04-01 0.05 2020-04-30 0.125 0.126 0.296 0.311 2020-05-11 0.05 2020-05-12 0.026 0.039 0.073 0.067 2020-05-26 0.16 2020-05-27 0.168 2020-06-17 0.085 0.15 0.219 0.229 0.284 2020-06-30 0.107 2020-07-20 0.095 0.09 0.085 0.1 0.095 2020-07-31 0.079 2020-08-03 0.05 2020-08-06 0.061 0.172 0.088 0.101 2020-08-11 0.49 2020-08-31 0.074 2020-09-01 0.85 2020-09-14 1.1 2020-09-15 0.073 0.041 0.073 0.086 2020-09-28 0.04 2020-09-29 0.075 2020-10-26 0.033 0.05 0.027 0.056 0.054 2020-11-10 0.034 0.05 0.038 0.049 0.039 2020-12-08 0.027 0.08 0.029 0.164 0.137 N 38 46 38 48 38 Avg 0.049 0.107 0.051 0.101 0.095 SD 0.031 0.201 0.044 0.056 0.062 Min 0.020 0.020 0.020 0.020 0.020 Max 0.158 1.100 0.219 0.296 0.311 1.20 1.00 0.80 J awn 0.60 0.40 0.20 0.00 Total Phosphorus (TP) O LC -Up ■ Effluent • LC-Dn 0 RR -Up ♦ RR-Dn ■ ■ • ,LQ Al Ai , r �ii i 4 +i i 01 �OyN' tiON' ti`' oti ti(4' o°` y'' o`'' titi o(0' oti oA �ti otio' �oti�' �01' tio'ti tiol' Anova: Single Factor SUMMARY Groups Count Sum Average Variance LC -Up 38 1.845 0.048553 0.000972 Effluent 46 4.91 0.106739 0.040541 LC-Dn 38 1.933 0.050868 0.001913 RR -Up 48 4.865 0.101354 0.003101 RR-Dn 38 3.594 0.094579 0.003818 ANOVA irce of Variat SS df MS F P-value F crit Between Grc 0.131446 4 0.032862 3.007473 0.019359 2.41613 Within Grou 2.218109 203 0.010927 Total 2.349555 207 Conclusion: differences were detected among sampling sites. t-Test: Two -Sample Assuming Unequal Variances LC -Up LC-Dn Mean 0.048553 0.050868 Variance 0.000972 0.001913 Observations 38 38 Hypothesized Mean Difference 0 df 67 t Stat -0.26578 P(T<=t) one -tail 0.395612 t Critical one -tail 1.667916 P(T<=t) two -tail 0.791224 t Critical two -tail 1.996008 Conclusion: no differences were detected between Loves Creek stations. t-Test: Two -Sample Assuming Unequal Variances RR -Up RR-Dn Mean 0.101354 0.094579 Variance 0.003101 0.003818 Observations 48 38 Hypothesized Mean Difference 0 df 75 t Stat 0.527298 P(T<=t) one -tail 0.299772 t Critical one -tail 1.665425 P(T<=t) two -tail 0.599543 t Critical two -tail 1.992102 Conclusion: no differences were detected between Rocky River stations. Chlorophyll- a (mg/L) `Start Date RR -up 2019-01-22 5.38 2019-02-13 9.73 2019-03-26 11 2019-04-22 7 2019-05-13 21.9 2019-05-30 11.8 2019-06-11 36 2019-06-21 19.7 2019-07-19 1.83 2019-07-29 13.6 2019-08-14 10.8 2019-08-27 26.1 2019-09-16 3.23 2019-09-30 2.4 2019-10-22 2.49 2019-11-14 4.78 2019-12-10 20.6 2020-01-28 6.06 2020-02-24 4.45 2020-03-30 28.2 2020-04-30 15.8 2020-05-12 5.03 2020-05-27 19.2 2020-06-17 8.98 2020-06-30 10.8 2020-07-20 2020-07-31 2020-08-06 2020-08-31 2020-09-15 2020-09-29 2020-10-26 2020-11-10 2020-12-08 46.2 13.7 38.1 9.6 12.4 44.4 3.28 5.07 4.63 N 34 Avg 14.24 SD 12.18 Min 1.83 Max 46.20 Chlorophyll -a (Chl-a) RR -up 50 45 40 35 30 oao 25 E 20 15 10 5 0 o ,tip o N• 1, o ' • N•%1, o N• ', o o o N• o OHO o o o tiON' P tiON' ti3O " tiON' ti01' ti01' ti01' ti01' ti��� Whole Effluent Toxicity Testing and Self Monitoring Summary U 0 U 0 Feb May Aug Nov O 0▪ _ U m 0 cc O .00 O 1 CC NC0039586/006 Shearon Harris Nuclear Power Plant 7Q10: LAKE 24hr p/f ac lim: 90% a-1 N 0 N O Ol C .FLO m LL CL N a t LL rA z[a a a • a a a a a C L CO CO CO CO 0 0 O 0 0 0 0 0 0 0 U O Jan Apr Jul Oct NC0027197/001 Shelby WTP, City of 0 LL Chr Monit: 90% LL CL N n U C Q a a a a C 0o m o rq r IN IN 0 0 0 0 0 U 0 U 0 N Feb May Aug Nov NC0024538/001 Shelby WWTP 0 LL chr lim: 17% m 0 O N N C 00 CO zan'kg a Q a a a a C CL CL ca m o 0 0 0 0 U 0 UI 0 N Jan Apr Jul Oct a) U C O U NC0000175/001 Sibelco North America (Unimin Corp.) 7Q10: 45.0 NonComp: Single chr lim: 11% Z Q or'''; -Ca C Q a a a a C a a a U 0 VI 0 N Mar Jun Sep Dec 0 z 00 O a) 0) K 0 IWC: 96.1 7Q10: 0.25 cu 00 C_ In rO C1 6 ▪ ▪ O U C 0 C 0 O U NC0026441/001 Siler City WWTP chr lim: 90% Q a 0a _ 0 O O C 0 a a a ^ co m o O 0 0 N Page 89 of 109 Legend: P= Fathead minnow (Pimohales oromelas). H=No Flow (facility is active). s = Solit test between Certified Labs MONITORING REPORT(MR) VIOLATIONS for: Report Date: 03/22/22 Page 1 of 7 Permit: NC0026441 MRs Betweei 2 - 2017 and 3 - 2022 Facility Name: % Param Nam( % Major Minor: Region: % County: % Violation Category:% Subbasin:% Program Category: % Violation Action: % PERMIT: NC0026441 FACILITY: Town of Siler City - Siler City WWTP COUNTY: Chatham REGION: Raleigh Limit Violation MONITORING OUTFACE REPORT LOCATION PARAMETER VIOLATION DATE FREQUENCY MEASURE UNIT OF LIMIT CALCULATED VALUE Over VIOLATION TYPE VIOLATION ACTION 05-2017 001 06-2017 001 09-2017 001 10-2017 001 04-2020 001 05-2020 001 05-2020 001 06-2020 001 06-2020 001 06-2020 001 06-2020 001 07-2020 001 02-2021 001 02-2021 001 02-2021 001 Effluent BOD, 5-Day (20 Deg. C) - 05/31/17 2 X week Concentration Effluent BOD, 5-Day (20 Deg. C) - 06/03/17 2 X week Concentration Effluent BOD, 5-Day (20 Deg. C) - 09/30/17 2 X week Concentration Effluent BOD, 5-Day (20 Deg. C) - 10/31/17 2 X week Concentration Effluent BOD, 5-Day (20 Deg. C) - 04/11/20 2 X week Concentration Effluent BOD, 5-Day (20 Deg. C) - 05/23/20 2 X week Concentration Effluent BOD, 5-Day (20 Deg. C) - 05/31/20 2 X week Concentration Effluent BOD, 5-Day (20 Deg. C) - 06/06/20 2 X week Concentration Effluent BOD, 5-Day (20 Deg. C) - 06/13/20 2 X week Concentration Effluent BOD, 5-Day (20 Deg. C) - 06/27/20 2 X week Concentration Effluent BOD, 5-Day (20 Deg. C) - 06/30/20 2 X week Concentration Effluent BOD, 5-Day (20 Deg. C) - 07/04/20 2 X week Concentration Effluent BOD, 5-Day (20 Deg. C) - 02/13/21 2 X week Concentration Effluent BOD, 5-Day (20 Deg. C) - 02/20/21 2 X week Concentration Effluent BOD, 5-Day (20 Deg. C) - 02/27/21 2 X week Concentration mg/I mg/I mg/I mg/I mg/I mg/I mg/I mg/I mg/I mg/I mg/I mg/I mg/I mg/I mg/I 5 5.18 3.6 Monthly Average Exceeded 7.5 8.5 13.3 Weekly Average Exceeded 5 5.03 0.5 Monthly Average Exceeded 5 5.67 13.3 Monthly Average Exceeded 7.5 8.2 9.3 Weekly Average Exceeded 7.5 10 33.3 Weekly Average Exceeded 5 5.53 10.5 Monthly Average Exceeded 7.5 16.17 115.6 Weekly Average Exceeded 7.5 14.45 92.7 Weekly Average Exceeded 7.5 9.53 27.1 Weekly Average Exceeded 5 11.51 130.2 Monthly Average Exceeded 7.5 10.8 44 Weekly Average Exceeded 15 22.77 51.8 Weekly Average Exceeded 15 33.7 124.7 Weekly Average Exceeded 15 30.6 104 Weekly Average Exceeded Proceed to Enforcement Case Proceed to NOV Proceed to NOD Proceed to NOV Penalty Retracted Proceed to Enforcement Case Proceed to Enforcement Case Proceed to Enforcement Case Proceed to Enforcement Case Proceed to Enforcement Case Proceed to Enforcement Case Proceed to Enforcement Case Proceed to Enforcement Case Proceed to Enforcement Case Proceed to Enforcement Case MONITORING REPORT(MR) VIOLATIONS for: Report Date: 03/22/22 Page 2 of 7 Permit: NC0026441 MRs Betweei 2 - 2017 and 3 - 2022 Region: % Violation Category:% Program Category: % Facility Name: % Param Nam(% County: % Subbasin:% Violation Action: % Major Minor: % PERMIT: NC0026441 FACILITY: Town of Siler City - Siler City WWTP COUNTY: Chatham REGION: Raleigh Limit Violation MONITORING UNIT OF OUTFALL LOCATION PARAMETER VIOLATION FREQUENCY REPORT DATE MEASURE LIMIT CALCULATED VALUE Over VIOLATION TYPE VIOLATION ACTION 02 - 2021 001 Effluent BOD, 5-Day (20 Deg. C) - 02/28/21 2 X week mg/I 10 24.59 145.9 Monthly Average Proceed to Concentration Exceeded Enforcement Case 03 - 2021 001 Effluent BOD, 5-Day (20 Deg. C) - 03/20/21 2 X week mg/I 15 34.73 131.6 Weekly Average Proceed to Concentration Exceeded Enforcement Case 03 - 2021 001 Effluent BOD, 5-Day (20 Deg. C) - 03/31/21 2 X week mg/I 10 12.68 26.8 Monthly Average Proceed to Concentration Exceeded Enforcement Case 04 - 2021 001 Effluent BOD, 5-Day (20 Deg. C) - 04/30/21 2 X week mg/I 5 5.68 13.7 Monthly Average Proceed to Concentration Exceeded Enforcement Case 07 - 2021 001 Effluent BOD, 5-Day (20 Deg. C) - 07/31/21 2 X week mg/I 7.5 11.25 50 Weekly Average Proceed to Concentration Exceeded Enforcement Case 07 - 2021 001 Effluent BOD, 5-Day (20 Deg. C) - 07/31/21 2 X week mg/I 5 7.64 52.8 Monthly Average Proceed to Concentration Exceeded Enforcement Case 08 - 2021 001 Effluent BOD, 5-Day (20 Deg. C) - 08/07/21 2 X week mg/I 7.5 10.5 40 Weekly Average Proceed to Concentration Exceeded Enforcement Case 08 - 2021 001 Effluent BOD, 5-Day (20 Deg. C) - 08/14/21 2 X week mg/I 7.5 10.35 38 Weekly Average Proceed to Concentration Exceeded Enforcement Case 08 - 2021 001 Effluent BOD, 5-Day (20 Deg. C) - 08/28/21 2 X week mg/I 7.5 14.5 93.3 Weekly Average Proceed to Concentration Exceeded Enforcement Case 08 - 2021 001 Effluent BOD, 5-Day (20 Deg. C) - 08/31/21 2 X week mg/I 5 10.7 114 Monthly Average Proceed to Concentration Exceeded Enforcement Case 09 - 2021 001 Effluent BOD, 5-Day (20 Deg. C) - 09/04/21 2 X week mg/I 7.5 13.6 81.3 Weekly Average Proceed to Concentration Exceeded Enforcement Case 09 - 2021 001 Effluent BOD, 5-Day (20 Deg. C) - 09/11/21 2 X week mg/I 7.5 26.5 253.3 Weekly Average Proceed to Concentration Exceeded Enforcement Case 09 - 2021 001 Effluent BOD, 5-Day (20 Deg. C) - 09/18/21 2 X week mg/I 7.5 19.1 154.7 Weekly Average Proceed to Concentration Exceeded Enforcement Case 09 - 2021 001 Effluent BOD, 5-Day (20 Deg. C) - 09/30/21 2 X week mg/I 5 14.86 197.2 Monthly Average Proceed to Concentration Exceeded Enforcement Case 10 - 2021 001 Effluent BOD, 5-Day (20 Deg. C) - 10/02/21 2 X week mg/I 7.5 10.25 36.7 Weekly Average Proceed to Concentration Exceeded Enforcement Case 10 - 2021 001 Effluent BOD, 5-Day (20 Deg. C) - 10/16/21 2 X week mg/I 7.5 9.8 30.7 Weekly Average Proceed to Concentration Exceeded Enforcement Case MONITORING REPORT(MR) VIOLATIONS for: Report Date: 03/22/22 Page 3 of 7 Permit: NC0026441 MRs Betweei 2 - 2017 and 3 - 2022 Facility Name: % Param Nam( % Major Minor: % Region: County: % Violation Category:% Subbasin:% Program Category: % Violation Action: % PERMIT: NC0026441 FACILITY: Town of Siler City - Siler City WWTP COUNTY: Chatham REGION: Raleigh Limit Violation MONITORING OUTFACE REPORT LOCATION PARAMETER VIOLATION UNIT OF FREQUENCY DATE MEASURE LIMIT CALCULATED VALUE Over VIOLATION TYPE VIOLATION ACTION 10-2021 001 01-2022 001 01-2022 001 04-2017 001 05-2017 001 11-2017 001 01-2018 001 11-2019 001 05-2020 001 02-2021 001 02-2021 001 02-2021 001 01-2022 001 02-2021 001 02-2020 001 03-2020 001 Effluent Effluent Effluent Effluent Effluent Effluent Effluent Effluent Effluent Effluent Effluent Effluent Effluent Effluent Effluent Effluent BOD, 5-Day (20 Deg. C) - Concentration BOD, 5-Day (20 Deg. C) - Concentration BOD, 5-Day (20 Deg. C) - Concentration Cadmium, Total (as Cd) 10/31/21 01/22/22 01 /31 /22 04/30/17 2 X week 2 X week 2 X week Monthly Cadmium, Total (as Cd) 05/31/17 Monthly Cadmium, Total (as Cd) 11/30/17 Monthly Cadmium, Total (as Cd) 01/31/18 Monthly Cadmium, Total (as Cd) 11/30/19 Monthly Coliform, Fecal MF, MFC Broth, 44.5 C Coliform, Fecal MF, MFC Broth, 44.5 C Coliform, Fecal MF, MFC Broth, 44.5 C Coliform, Fecal MF, MFC Broth, 44.5 C Coliform, Fecal MF, MFC Broth, 44.5 C Flow, in conduit or thru treatment plant Nitrogen, Ammonia Total (as N) - Concentration Nitrogen, Ammonia Total (as N) - Concentration 05/23/20 02/13/21 02/20/21 02/28/21 01/29/22 2 X week 2 X week 2 X week 2 X week 2 X week 02/28/21 Continuous 02/29/20 5 X week 03/31/20 5 X week mg/I mg/I mg/I ug/I ug/I ug/I ug/I ug/I #/100m1 #/100m1 #/100m1 #/100m1 #/100m1 mgd mg/I mg/I 5 5.6 12.0 15 43.25 188.3 10 17.14 71.4 2.1 4 90.5 2.1 5 138.1 2.1 5 138.1 2.1 7.3 2.1 3 400 5,280.02 400 1,006.88 400 3,902 200 310.43 400 2,420 4 4.65 2 2.01 2 2.81 247.6 42.9 1,220.0 151.7 875.5 55.2 Monthly Average Exceeded Weekly Average Exceeded Monthly Average Exceeded Monthly Average Exceeded Monthly Average Exceeded Monthly Average Exceeded Monthly Average Exceeded Monthly Average Exceeded Weekly Geometric Mean Exceeded Weekly Geometric Mean Exceeded Weekly Geometric Mean Exceeded Monthly Geometric Mean Exceeded 505 Weekly Geometric Mean Exceeded 16.2 Monthly Average Exceeded 0.7 Monthly Average Exceeded 40.3 Monthly Average Exceeded Proceed to Enforcement Case Proceed to NOV Proceed to NOV Proceed to NOV Proceed to Enforcement Case Proceed to Enforcement Case Proceed to Enforcement Case Proceed to Enforcement Case Proceed to Enforcement Case Proceed to Enforcement Case Proceed to Enforcement Case Proceed to Enforcement Case Proceed to NOV Proceed to Enforcement Case Proceed to NOD Proceed to Enforcement Case MONITORING REPORT(MR) VIOLATIONS for: Report Date: 03/22/22 Page 4 of 7 Permit: NC0026441 MRs Betweei 2 - 2017 and 3 - 2022 Facility Name: % Param Nam( % Major Minor: % Region: County: % Violation Category:% Subbasin:% Program Category: % Violation Action: % PERMIT: NC0026441 FACILITY: Town of Siler City - Siler City WWTP COUNTY: Chatham REGION: Raleigh Limit Violation MONITORING OUTFACE REPORT LOCATION PARAMETER VIOLATION UNIT OF FREQUENCY DATE MEASURE LIMIT CALCULATED VALUE Over VIOLATION TYPE VIOLATION ACTION 04-2020 001 04-2020 001 04-2020 001 05-2020 001 05-2020 001 06-2020 001 06-2020 001 06-2020 001 06-2020 001 07-2020 001 02-2021 001 02-2021 001 02-2021 001 02-2021 001 02-2021 001 03-2021 001 Effluent Effluent Effluent Effluent Effluent Effluent Effluent Effluent Effluent Effluent Effluent Effluent Effluent Effluent Effluent Effluent Nitrogen, Ammonia Total (as N) - Concentration Nitrogen, Ammonia Total (as N) - Concentration Nitrogen, Ammonia Total (as N) - Concentration Nitrogen, Ammonia Total (as N) - Concentration Nitrogen, Ammonia Total (as N) - Concentration Nitrogen, Ammonia Total (as N) - Concentration Nitrogen, Ammonia Total (as N) - Concentration Nitrogen, Ammonia Total (as N) - Concentration Nitrogen, Ammonia Total (as N) - Concentration Nitrogen, Ammonia Total (as N) - Concentration Nitrogen, Ammonia Total (as N) - Concentration Nitrogen, Ammonia Total (as N) - Concentration Nitrogen, Ammonia Total (as N) - Concentration Nitrogen, Ammonia Total (as N) - Concentration Nitrogen, Ammonia Total (as N) - Concentration Nitrogen, Ammonia Total (as N) - Concentration 04/04/20 04/11/20 04/30/20 05/30/20 05/31/20 06/06/20 06/13/20 06/27/20 06/30/20 07/04/20 02/06/21 02/13/21 02/20/21 02/27/21 02/28/21 03/20/21 5 X week 5 X week 5 X week 5 X week 5 X week 5 X week 5 X week 5 X week 5 X week 5 X week 5 X week 5 X week 5 X week 5 X week 5 X week 5 X week mg/I mg/I mg/I mg/I mg/I mg/I mg/I mg/I mg/I mg/I mg/I mg/I mg/I mg/I mg/I mg/I 3 3 1 3 1 3 3 3 1 3 6 6 6 6 2 6 8 8.85 2.58 166.7 195 157.6 Weekly Average Exceeded Weekly Average Exceeded Monthly Average Exceeded 3.82 27.5 Weekly Average Exceeded 1.47 47.0 Monthly Average Exceeded 7.7 156.7 Weekly Average Exceeded 6.56 118.7 Weekly Average Exceeded 3.6 20 Weekly Average Exceeded 4.81 380.7 Monthly Average Exceeded 4.22 40.8 Weekly Average Exceeded 18.62 210.3 21.88 264.7 18.86 214.3 18.76 212.7 19.49 874.3 21.92 265.3 Weekly Average Exceeded Weekly Average Exceeded Weekly Average Exceeded Weekly Average Exceeded Monthly Average Exceeded Weekly Average Exceeded Proceed to Enforcement Case Proceed to Enforcement Case Proceed to Enforcement Case Proceed to Enforcement Case Proceed to Enforcement Case Proceed to Enforcement Case Proceed to Enforcement Case Proceed to Enforcement Case Proceed to Enforcement Case Proceed to Enforcement Case Proceed to Enforcement Case Proceed to Enforcement Case Proceed to Enforcement Case Proceed to Enforcement Case Proceed to Enforcement Case Proceed to Enforcement Case MONITORING REPORT(MR) VIOLATIONS for: Report Date: 03/22/22 Page 5 of 7 Permit: NC0026441 MRs Betweei 2 - 2017 and 3 - 2022 Facility Name: % Param Nam( % Major Minor: % Region: County: % Violation Category:% Subbasin:% Program Category: % Violation Action: % PERMIT: NC0026441 FACILITY: Town of Siler City - Siler City WWTP COUNTY: Chatham REGION: Raleigh Limit Violation MONITORING OUTFACE REPORT LOCATION PARAMETER VIOLATION UNIT OF FREQUENCY DATE MEASURE LIMIT CALCULATED VALUE Over VIOLATION TYPE VIOLATION ACTION 03-2021 001 03-2021 001 04-2021 001 05-2021 001 07-2021 001 07-2021 001 08-2021 001 08-2021 001 08-2021 001 08-2021 001 08-2021 001 09-2021 001 09-2021 001 09-2021 001 09-2021 001 09-2021 001 Effluent Effluent Effluent Effluent Effluent Effluent Effluent Effluent Effluent Effluent Effluent Effluent Effluent Effluent Effluent Effluent Nitrogen, Ammonia Total (as N) - Concentration Nitrogen, Ammonia Total (as N) - Concentration Nitrogen, Ammonia Total (as N) - Concentration Nitrogen, Ammonia Total (as N) - Concentration Nitrogen, Ammonia Total (as N) - Concentration Nitrogen, Ammonia Total (as N) - Concentration Nitrogen, Ammonia Total (as N) - Concentration Nitrogen, Ammonia Total (as N) - Concentration Nitrogen, Ammonia Total (as N) - Concentration Nitrogen, Ammonia Total (as N) - Concentration Nitrogen, Ammonia Total (as N) - Concentration Nitrogen, Ammonia Total (as N) - Concentration Nitrogen, Ammonia Total (as N) - Concentration Nitrogen, Ammonia Total (as N) - Concentration Nitrogen, Ammonia Total (as N) - Concentration Nitrogen, Ammonia Total (as N) - Concentration 03/27/21 03/31/21 04/03/21 05/31 /21 07/24/21 07/31 /21 08/07/21 08/14/21 08/21/21 08/28/21 08/31 /21 09/04/21 09/11 /21 09/18/21 09/25/21 09/30/21 5 X week 5 X week 5 X week 5 X week 5 X week 5 X week 5 X week 5 X week 5 X week 5 X week 5 X week 5 X week 5 X week 5 X week 5 X week 5 X week mg/I mg/I mg/I mg/I mg/I mg/I mg/I mg/I mg/I mg/I mg/I mg/I mg/I mg/I mg/I mg/I 6 2 3 1 3 1 3 3 3 3 1 3 3 3 3 1 7.02 17 Weekly Average Exceeded 7.6 280.2 Monthly Average Exceeded 6.08 102.5 Weekly Average Exceeded 1.01 0.5 Monthly Average Exceeded 7.28 142.7 Weekly Average Exceeded 2.57 156.5 Monthly Average Exceeded 13.66 355.3 Weekly Average Exceeded 9.22 207.3 Weekly Average Exceeded 8.98 199.3 Weekly Average Exceeded 12.56 318.7 Weekly Average Exceeded 11.93 1,093.2 Monthly Average Exceeded 17.22 474 Weekly Average Exceeded 5.05 68.3 Weekly Average Exceeded 10.32 244 Weekly Average Exceeded 3.24 8.0 Weekly Average Exceeded 8.18 718.1 Monthly Average Exceeded Proceed to Enforcement Case Proceed to Enforcement Case Proceed to Enforcement Case Proceed to NOD Proceed to Enforcement Case Proceed to Enforcement Case Proceed to Enforcement Case Proceed to Enforcement Case Proceed to Enforcement Case Proceed to Enforcement Case Proceed to Enforcement Case Proceed to Enforcement Case Proceed to Enforcement Case Proceed to Enforcement Case Proceed to Enforcement Case Proceed to Enforcement Case MONITORING REPORT(MR) VIOLATIONS for: Report Date: 03/22/22 Page 6 of 7 Permit: NC0026441 MRs Betweei 2 - 2017 and 3 - 2022 Facility Name: % Param Nam( % Major Minor: % Region: County: % Violation Category:% Subbasin:% Program Category: % Violation Action: % PERMIT: NC0026441 FACILITY: Town of Siler City - Siler City WWTP COUNTY: Chatham REGION: Raleigh Limit Violation MONITORING OUTFALL REPORT LOCATION PARAMETER VIOLATION UNIT OF FREQUENCY DATE MEASURE LIMIT CALCULATED VALUE Over VIOLATION TYPE VIOLATION ACTION 10-2021 001 01-2022 001 01-2022 001 01-2022 001 01-2022 001 01-2022 001 Monitoring Violation MONITORING OUTFALL REPORT Effluent Effluent Effluent Effluent Effluent Effluent LOCATION Nitrogen, Ammonia Total (as N) - Concentration Nitrogen, Ammonia Total (as N) - Concentration Nitrogen, Ammonia Total (as N) - Concentration Nitrogen, Ammonia Total (as N) - Concentration Nitrogen, Ammonia Total (as N) - Concentration Solids, Total Suspended - Concentration PARAMETER 10/02/21 5 X week 01/08/22 5 X week 01/22/22 5 X week 01/29/22 5 X week 01/31/22 5 X week 01/22/22 2 X week mg/I mg/I mg/I mg/I mg/I mg/I VIOLATION UNIT OF DATE FREQUENCY MEASURE 3 6 6 7.9 163.3 Weekly Average Exceeded 10.38 73 Weekly Average Exceeded 12.42 107.1 Weekly Average Exceeded 6 26.86 347.7 2 14.35 617.5 45 105.4 134.2 LIMIT CALCULATED VALUE Over Weekly Average Exceeded Monthly Average Exceeded Weekly Average Exceeded VIOLATION TYPE Proceed to Enforcement Case Proceed to NOV Proceed to NOV Proceed to NOV Proceed to NOV Proceed to NOV VIOLATION ACTION 11-2018 001 11-2018 001 06-2019 001 05-2019 001 06-2019 001 05-2019 001 06-2019 001 Other Violation MONITORING OUTFALL REPORT Effluent Effluent Effluent Effluent Effluent Effluent Effluent LOCATION Flow, in conduit or thru treatment plant Flow, in conduit or thru treatment plant Flow, in conduit or thru treatment plant Flow, Total Flow, Total Nitrogen, Total - Quantity (Monthly) Nitrogen, Total - Quantity (Monthly) PARAMETER 11/29/18 Continuous 11/30/18 Continuous 06/15/19 Continuous 05/31/19 Monthly 06/30/19 Monthly 05/31/19 Monthly 06/30/19 Monthly mgd mgd mgd mgal/month mgal/month lb/mon lb/mon VIOLATION UNIT OF DATE FREQUENCY MEASURE LIMIT CALCULATED VALUE Over Frequency Violation Frequency Violation Frequency Violation Frequency Violation Frequency Violation Frequency Violation Frequency Violation No Action, BPJ No Action, BIMS Calculation Error Proceed to NOV Proceed to NOV Proceed to NOV Proceed to NOV Proceed to NOV VIOLATION TYPE VIOLATION ACTION MONITORING REPORT(MR) VIOLATIONS for: Report Date: 03/22/22 Page 7 of 7 Permit: NC0026441 Facility Name: Major Minor: % MRs Betweei 2 - 2017 and 3 - 2022 Region: % Param Nam( % County: % Violation Category:% Subbasin:% ligProgram Category: % Violation Action: PERMIT: NC0026441 FACILITY: Town of Siler City - Siler City WWTP COUNTY: Chatham REGION: Raleigh Other Violation MONITORING OUTFACE REPORT LOCATION PARAMETER VIOLATION UNIT OF FREQUENCY DATE MEASURE LIMIT CALCULATED VALUE Over VIOLATION TYPE VIOLATION ACTION 09-2020 09-2021 12-2021 09/14/20 09/13/21 12/06/21 Aquatic toxicity permit limit violation Aquatic toxicity permit limit violation Aquatic toxicity permit limit violation Proceed to NOV Proceed to NOV Proceed to NOV United States Environmental Protection Agency EPA Washington, D.C. 20460 Water Compliance Inspection Report Form Approved. OMB No. 2040-0057 Approval expires 8-31-98 Section A: National Data System Coding (i.e., PCS) Transaction Code NPDES yr/mo/day Inspection 1 IN I 2 IL I 3 I NC0026441 111 121 20/07/21 117 Type 181 I IIIIIIIIIII Inspector Fac Type 19I S I 2011 21IIIIII IIIIIIIIIII IIIIIII I IIIIII P6 Inspection Work Days Facility Self -Monitoring Evaluation Rating B1 QA Reserved 671 I 7° I3 I 711 I 72 I N I 73I I 74 71 I I I I I I I I 180 Section B: Facility Data Name and Location of Facility Inspected (For Industrial Users discharging to POTW, also include POTW name and NPDES permit Number) Siler City WWTP 370 Waste Treatment Plant Rd Siler City NC 27344 Entry Time/Date 10:00AM 20/07/21 Permit Effective Date 19/05/01 Exit Time/Date 11:00AM 20/07/21 Permit Expiration Date 19/05/31 Name(s) of Onsite Representative(s)/Titles(s)/Phone and Fax Number(s) /// Brittany Nicole York/ORC/919-742-4581/ Other Facility Data Name, Address of Responsible Official/Title/Phone and Fax Number Contacted Roy Lynch,PO Box 769 Siler City NC 27344/Town Manager/919-742-4581/ No Section C: Areas Evaluated During Inspection (Check only those areas evaluated) Operations & Maintenar Records/Reports Self -Monitoring Progran Laboratory Section D: Summary of Finding/Comments (Attach additional sheets of narrative and checklists as necessary) (See attachment summary) Name(s) and Signature(s) of Inspector(s) Agency/Office/Phone and Fax Numbers Date Cheng Zhang DWR/RRO WQ/919-791-4200/ Signature of Management Q A Reviewer Agency/Office/Phone and Fax Numbers Date EPA Form 3560-3 (Rev 9-94) Previous editions are obsolete. Page# 1 3I NPDES yr/mo/day N C 0026441 111 121 20/07/21 117 Inspection Type 18[j (Cont.) 1 Section D: Summary of Finding/Comments (Attach additional sheets of narrative and checklists as necessary) 24-hour composite effluent sample (started at 10:19 am, July 20, 2020, ended at 10:19 am, July 21, 2020, time paced, 100 ml/20 minutes) was collected using DWR portable sampler, composite samples were collected on July 21, 2020 for BOD, TSS, ammonia nitrogen, nitrate/nitrite, TKN, and total phosphorous. Effluent sample was also collected for fecal coliform. Field parameters (except total residula chlorine) were measured using a DWR YSI Proplus meter. Analytical results BOD: 4.2 mg/L; ammonia nitrogen: 0.06 mg/L; TSS: <6.2 mg/L; nitrate plus nitrite: 9.4 mg/L; TKN: 1.2 mg/L; total phosphorous: 0.09 mg/L; fecal coliform: 230 CFU/100m1. Field parameters: Temperature: 29.4 degree C; pH: 7.58; DO: 7.08 mg/L. Influent and effluent sampling and field parameter measurement condocted by the facility were observed and found to meet permit requirements. The facility was found to be compliant for the sampling compliance inspection. Page# 2 Permit: NC0026441 Owner - Facility: Siler City WWTP Inspection Date: 07/21/2020 Inspection Type: Compliance Sampling Operations & Maintenance Is the plant generally clean with acceptable housekeeping? Does the facility analyze process control parameters, for ex: MLSS, MCRT, Settleable Solids, pH, DO, Sludge Judge, and other that are applicable? Comment: The facility analyzes MLSS, DO, pH, sludge blankets, etc. for process control. Influent Sampling # Is composite sampling flow proportional? Is sample collected above side streams? Is proper volume collected? Is the tubing clean? # Is proper temperature set for sample storage (kept at less than or equal to 6.0 degrees Celsius)? Is sampling performed according to the permit? Comment: Effluent Sampling Is composite sampling flow proportional? Is sample collected below all treatment units? Is proper volume collected? Is the tubing clean? # Is proper temperature set for sample storage (kept at less than or equal to 6.0 degrees Celsius)? Is the facility sampling performed as required by the permit (frequency, sampling type representative)? Comment: A part needed to be replaced to perform flow proportional sampling Yes No NA NE • ❑ ❑ ❑ El El El El Yes No NA NE • ❑ ❑ ❑ • ❑ ❑ ❑ Yes No NA NE ❑ • ❑ ❑ • ❑ ❑ ❑ • ❑ ❑ ❑ • ❑ ❑ ❑ • ❑ ❑ ❑ • ❑ ❑ ❑ Laboratory Yes No NA NE Are field parameters performed by certified personnel or laboratory? • ❑ ❑ ❑ Are all other parameters(excluding field parameters) performed by a certified lab? • ❑ ❑ ❑ # Is the facility using a contract lab? • El El El # Is proper temperature set for sample storage (kept at less than or equal to 6.0 degrees • ❑ ❑ ❑ Celsius)? Incubator (Fecal Coliform) set to 44.5 degrees Celsius+/- 0.2 degrees? • ❑ ❑ ❑ Incubator (BOD) set to 20.0 degrees Celsius +/- 1.0 degrees? • ❑ El El Comment: Page# 3 Permit: NC0026441 Inspection Date: 07/21/2020 Owner - Facility: Siler City WWTP Inspection Type: Compliance Sampling Laboratory Yes No NA NE Page# 4 United States Environmental Protection Agency EPA Washington, D.C. 20460 Water Compliance Inspection Report Form Approved. OMB No. 2040-0057 Approval expires 8-31-98 Section A: National Data System Coding (i.e., PCS) Transaction Code NPDES yr/mo/day Inspection 1 IN I 2 IL I 3 I NC0026441 111 121 20/06/03 117 Type 181 p I IIIIIIIIIII Inspector Fac Type 191 S I 2011 21IIIIII IIIIIIIIIIIIIIIIII I IIIIII P6 Inspection Work Days Facility Self -Monitoring Evaluation Rating B1 QA Reserved 671 I 761 I 711 I 72 I N I 73I I 74 71 I I I I I I I I 180 Section B: Facility Data Name and Location of Facility Inspected (For Industrial Users discharging to POTW, also include POTW name and NPDES permit Number) Siler City WWTP 370 Waste Treatment Plant Rd Siler City NC 27344 Entry Time/Date 10:00AM 20/06/03 Permit Effective Date 19/05/01 Exit Time/Date 11:30AM 20/06/03 Permit Expiration Date 19/05/31 Name(s) of Onsite Representative(s)/Titles(s)/Phone and Fax Number(s) /// Brittany Nicole York/ORC/919-742-4581/ Chris McCorquodale/super wwtp// Other Facility Data Name, Address of Responsible Official/Title/Phone and Fax Number Contacted Roy Lynch,PO Box 769 Siler City NC 27344/Town Manager/919-742-4581/ No Section C: Areas Evaluated During Inspection (Check only those areas evaluated) Operations & Maintenar Sludge Handling Dispot Section D: Summary of Finding/Comments (Attach additional sheets of narrative and checklists as necessary) (See attachment summary) Name(s) and Signature(s) of Inspector(s) Agency/Office/Phone and Fax Numbers Date Cheng Zhang DWR/RRO WQ/919-791-4200/ Signature of Management Q A Reviewer Agency/Office/Phone and Fax Numbers Date EPA Form 3560-3 (Rev 9-94) Previous editions are obsolete. Page# 1 31 NPDES yr/mo/day N C 0026441 111 121 20/06/03 117 Inspection Type 18 101 (Cont.) 1 Section D: Summary of Finding/Comments (Attach additional sheets of narrative and checklists as necessary) Cheng Zhang visited the plant this morning, met with Chris McCorquodale, Public Works and Utilities Director, Brittany York, WWTP ORC, and Joey Smith, collection system ORC. At the time of visit, the plant was under "normal" operational mode. Here are some items I noted: • The plant still did not have enough storage space to waste sludge, as a result, MLSS was high (around 8000 mg/L), targeted range is from 4000 to 5000, settleometer reading was 535 (1-hour) and 700 (30-min), mixed liquor DO was 0.2, 0.5, 0.1, and 0.7 mg/L (from four locations in oxidation ditches) • Equalization basins 3a and 3b (converted from old clarifiers) were used to hold wasted sludge, which were almost full (less than 1ft to the V-notch), sludge from 3a and 3b was being transferred to sludge thickening basin at the time of visit to get space for sludge wasting. With EQ basins 3a and 3b being occupied, the plant has less EQ space during storm events (EQ basin 2 has capacity of 2 million gallons, not in use at the time of visit; EQ basin 1 (250,000 gallons) contains overflow from influent pump station wetwell); • Sludge thickening basin (with capacity of 768,000 gallons, 15 feet deep) had about 2 feet space available, Synagro was scheduled to haul 900,000 gallons sludge next Monday (June 8); • Filter backwash basin (with same dimension as sludge thickening basin) had about 4 feet space available; four tertiary filters were all on line. The filters have design capacity of 4 million gallons, once flow is more than that, filters have to be partially bypassed; • Due to high MLSS, sludge blankets were high in both secondary clarifiers (#1, 9 feet, #2, 9.5 feet, sidewall depth is 14 feet), ORC stated that normal blanket would be 3 to 5 feet; • ORC stated that during high flow periods (while filters were bypassed), aerators at both oxidation ditches were turned off to prevent loss of solids, resulted in very little nitrification at the ditches and higl- ammonia in the effluent. ORC also stated that they planned to add one more aerator to the ditches in order to have higher DO in the ditches. They also plan to try limited aeration (instead of no aeration at all) at ditches during future storm events. Chris mentioned that an agreement had been reached recently among the Town, DWR, and Friends of Rocky River. By the end of 2023, the WWTP upgrade will be completed. Plant upgrade include add one more oxidation ditch, one more clarifier, four more tertiary filters, and sludge handling facility (belt press), all three oxidation ditches will have BNR capability, flow will increase to 6 MGD (4 MGD now). Cheng Zhang also asked about I&I in the collection system and was told that the Town has just completed a $3M project in the North Avenue pump station area (sewer main and lateral replacement, area with repeated SSOs in 2018 hurricanes). The Town is also in planning stage to rehab sewer around Elder Road pump station (Blood Run Creek), including relocate the pump station (right now in flood zone) and sewer interceptor replacement. Page# 2 Permit: NC0026441 Inspection Date: 06/03/2020 Owner - Facility: Siler City WWTP Inspection Type: Reconnaissance Operations & Maintenance Is the plant generally clean with acceptable housekeeping? Does the facility analyze process control parameters, for ex: MLSS, MCRT, Settleable Solids, pH, DO, Sludge Judge, and other that are applicable? Comment: MLSS, DO, pH, sludge blankets, etc. Oxidation Ditches Are the aerators operational? Are the aerators free of excessive solids build up? # Is the foam the proper color for the treatment process? Does the foam cover less than 25% of the basin's surface? Is the DO level acceptable? Are settleometer results acceptable (> 30 minutes)? Is the DO level acceptable?(1.0 to 3.0 mg/I) Are settelometer results acceptable?(400 to 800 ml/I in 30 minutes) Yes No NA NE • ❑ ❑ ❑ • ❑ ❑ ❑ Yes No NA NE • ❑ ❑ ❑ • ❑ ❑ ❑ • ❑ ❑ ❑ • ❑ ❑ ❑ ❑ • ❑ ❑ ❑ • ❑ ❑ ❑ • ❑ ❑ • ❑ ❑ ❑ Comment: MLSS were about 8000 mg/L about 60% higher than targeted value (5000 mg/L). DO was 0.2, 0.5, 0.1, and 0.7 mg/L (from four locations in oxidation ditches) Secondary Clarifier Yes No NA NE Is the clarifier free of black and odorous wastewater? Is the site free of excessive buildup of solids in center well of circular clarifier? Are weirs level? Is the site free of weir blockage? Is the site free of evidence of short-circuiting? Is scum removal adequate? Is the site free of excessive floating sludge? Is the drive unit operational? Is the return rate acceptable (low turbulence)? Is the overflow clear of excessive solids/pin floc? Is the sludge blanket level acceptable? (Approximately'/ of the sidewall depth) • ❑ ❑ ❑ • ❑ ❑ ❑ • ❑ ❑ ❑ • ❑ ❑ ❑ • ❑ ❑ ❑ • ❑ ❑ ❑ • ❑ ❑ ❑ • ❑ ❑ ❑ • ❑ ❑ ❑ • ❑ ❑ ❑ ❑ • ❑ ❑ Comment: sludge blankets were high in both secondary clarifiers (#1, 9 feet, #2, 9.5 feet, sidewall dept is 14 feet) Aerobic Digester Yes No NA NE Is the capacity adequate? ❑ • ❑ ❑ Page# 3 Permit: NC0026441 Inspection Date: 06/03/2020 Owner - Facility: Siler City WWTP Inspection Type: Reconnaissance Aerobic Digester Is the mixing adequate? Is the site free of excessive foaming in the tank? # Is the odor acceptable? # Is tankage available for properly waste sludge? Yes No NA NE • ❑ ❑ ❑ ❑ • ❑ ❑ Comment: Digester A and B were almost full, the facility was using EQ Basin 3A and 3B as digesters at the time of inspection, which were also full. Sludge thickening basin had about two feet space availabe. Sludge was being transfered from EQ Basins 3A and 3B to the sludge thickening basin at the time of site visit. Page# 4 NH3/TRC WLA Calculations Siler City WWTP PermitNo. NC0026441 Prepared By: Gary Perlmutter Enter Design Flow (MGD): 4 Enter s7Q10 (cfs): 0.09 Enter w7Q10 (cfs): 0.23 Total Residual Chlorine (TRC) Daily Maximum Limit (ug/l) s7Q10 (CFS) DESIGN FLOW (MGD) DESIGN FLOW (CFS) STREAM STD (UG/L) Upstream Bkgd (ug/l) IWC (%) Allowable Conc. (ug/l) Fecal Coliform Monthly Average Limit: (If DF >331; Monitor) (If DF<331; Limit) Dilution Factor (DF) 0.09 4 6.2 17.0 0 98.57 17 Ammonia (Summer) Monthly Average Limit (mg NH3-N/I) s7Q10 (CFS) DESIGN FLOW (MGD) DESIGN FLOW (CFS) STREAM STD (MG/L) Upstream Bkgd (mg/I) IWC (%) Allowable Conc. (mg/I) Ammonia (Winter) Monthly Average Limit (mg NH3-N/I) w7Q10 (CFS) 200/100m1 DESIGN FLOW (MGD) DESIGN FLOW (CFS) STREAM STD (MG/L) 1.01 Upstream Bkgd (mg/I) IWC (%) Allowable Conc. (mg/I) Total Residual Chlorine 1. Cap Daily Max limit at 28 ug/I to protect for acute toxicity Ammonia (as NH3-N) 1. If Allowable Conc > 35 mg/I, Monitor Only 2. Monthly Avg limit x 3 = Weekly Avg limit (Municipals); capped at 35 mg/I 3. Monthly Avg limit x 5 = Daily Max limit (Non-Munis); capped at 35 mg/I 0.09 4 6.2 1.0 0.22 98.57 1.0 0.23 4 6.2 1.8 0.22 96.42 1.9 Fecal Coliform 1. Monthly Avg limit x 2 = 400/100 ml = Weekly Avg limit (Municipals) = Daily Max limit (Non -Muni) NH3/TRC WLA Calculations Siler City WWTP PermitNo. NC0026441 Prepared By: Gary Perlmutter Enter Design Flow (MGD): 6 Enter s7Q10 (cfs): 0.09 Enter w7Q10 (cfs): 0.23 Total Residual Chlorine (TRC) Daily Maximum Limit (ug/l) s7Q10 (CFS) DESIGN FLOW (MGD) DESIGN FLOW (CFS) STREAM STD (UG/L) Upstream Bkgd (ug/l) IWC (%) Allowable Conc. (ug/l) Fecal Coliform Monthly Average Limit: (If DF >331; Monitor) (If DF<331; Limit) Dilution Factor (DF) 0.09 6 9.3 17.0 0 99.04 17 Ammonia (Summer) Monthly Average Limit (mg NH3-N/I) s7Q10 (CFS) DESIGN FLOW (MGD) DESIGN FLOW (CFS) STREAM STD (MG/L) Upstream Bkgd (mg/I) IWC (%) Allowable Conc. (mg/I) Ammonia (Winter) Monthly Average Limit (mg NH3-N/I) w7Q10 (CFS) 200/100m1 DESIGN FLOW (MGD) DESIGN FLOW (CFS) STREAM STD (MG/L) 1.01 Upstream Bkgd (mg/I) IWC (%) Allowable Conc. (mg/I) Total Residual Chlorine 1. Cap Daily Max limit at 28 ug/I to protect for acute toxicity Ammonia (as NH3-N) 1. If Allowable Conc > 35 mg/I, Monitor Only 2. Monthly Avg limit x 3 = Weekly Avg limit (Municipals); capped at 35 mg/I 3. Monthly Avg limit x 5 = Daily Max limit (Non-Munis); capped at 35 mg/I 0.09 6 9.3 1.0 0.22 99.04 1.0 0.23 6 9.3 1.8 0.22 97.59 1.8 Fecal Coliform 1. Monthly Avg limit x 2 = 400/100 ml = Weekly Avg limit (Municipals) = Daily Max limit (Non -Muni) Facility Name WWTP/WTP Class NPDES Permit Outfall Flow, Qw (MGD) Receiving Stream HUC Number Stream Class Freshwater RPA - 95% Probability/95% Confidence Using Metal Translators MAXIMUM DATA POINTS = 58 REQUIRED DATA ENTRY Table 1. Project Information ❑ CHECK IF HQW OR ORW WQS Siler City WWTP Grade IV NC0026441 001 6.000 Loves Creek 03030003 ❑ Apply WS Hardness WQC 7Q10s (cfs) 7Q1Ow (cfs) 30Q2 (cfs) QA (cfs) 1 Q1 Os (cfs) 0.09 0.23 0.32 8.70 0.08 Effluent Hardness 95.5 mg/L (Avg) Upstream Hardness 39.2 mg/L (Avg) Combined Hardness Chronic Combined Hardness Acute 94.96 mg/L 95.02 mg/L Data Source(s) ❑ CHECK TO APPLY MODEL Data from submitted DMRs and PPAs; Hardness data provided by the permittee by request. Streamflows updated by USGS per request in July 2021. Table 2. Parameters of Concern Par01 Par02 Par03 Par04 Par05 Par06 Par07 Par08 Par09 Par10 Par11 Par12 Par13 Par14 Par15 Par16 Par17 Par18 Par19 Par20 Par21 Par22 Par23 Par24 Name WQS Type Chronic Modifier Acute PQL Units Arsenic Aquactic Life C 150 FW 340 ug/L Arsenic Human Health Water Supply C 10 HH/WS N/A ug/L Beryllium Aquatic Life NC 6.5 FW 65 ug/L Cadmium Aquatic Life NC 1.6162 FW 10.3806 ug/L Chlorides Aquatic Life NC 230 FW mg/L Chlorinated Phenolic Compounds Water Supply NC 1 A ug/L ♦ Total Phenolic Compounds Aquatic Life NC 300 A ug/L Chromium Ill Aquatic Life NC 351.2295 FW 2701.4991 ug/L Chromium VI Aquatic Life NC 11 FW 16 pg/L Chromium, Total Aquatic Life NC N/A FW N/A pg/L Copper Aquatic Life NC 24.6508 FW 36.8457 ug/L Cyanide Aquatic Life NC 5 FW 22 10 ug/L Fluoride Aquatic Life NC 1,800 FW ug/L Lead Aquatic Life NC 12.9350 FW 332.1605 ug/L Mercury Aquatic Life NC 12 FW 0.5 ng/L Molybdenum Human Health NC 2000 HH ug/L Nickel Aquatic Life NC 115.1469 FW 1037.2630 pg/L Nickel Water Supply NC 25.0000 WS N/A pg/L Selenium Aquatic Life NC 5 FW 56 ug/L Silver Aquatic Life NC 0.06 FW 2.9462 ug/L Zinc Aquatic Life NC 392.6345 FW 389.6554 ug/L Chloroform Human Health NC 2000 HH pg/L Dichlorobromomethane Human Health C 27 HH pg/L Bis (2-ethylhexyl) phthalate Human Health C 0.37 HH pg/L 26641 RPA 4.0 MGD, input 3/23/2022 REASONABLE POTENTIAL ANALYSIS H1 Effluent Hardness Date Data 3/20/2018 9/10/2019 9/10/2020 3/4/2021 3/5/2021 3/6/2021 3/7/2021 3/8/2021 212 128 100 76 72 68 56 52 BDL=1/2DL Results 212 Std Dev. 53.1709 128 Mean 95.5000 100 C.V. (default) 0.6000 76 n 8 72 10th Per value 54.80 mg/L 68 Average Value 95.50 mg/L 56 Max. Value 212.00 mg/L Use "PASTE SPECIAL - Values" then "COPY" . Maximum data points = 58 52 H2 Upstream Hardness Date Data 3/4/2021 3/5/2021 3/6/2021 3/7/2021 3/8/2021 36 40 40 40 40 BDL=1/2DL 36 40 40 40 40 Results Std Dev. Mean C.V. (default) n 10th Per value Average Value Max. Value Use "PASTE SPECIAL - Values" then "COPY" . Maximum data points = 58 1.7889 39.2000 0.6000 5 37.60 mg/L 39.20 mg/L 40.00 mg/L 26641 RPA 4.0 MGD, data - 3 - 3/23/2022 REASONABLE POTENTIAL ANALYSIS Par01 & Par02 Arsenic Date Data BDL=1/2DL Results 1 3/20/2018 < 10 5 Std Dev. 0.0000 2 6/12/2018 < 10 5 Mean 5.0000 3 9/11/2018 < 10 5 C.V. 0.0000 4 12/18/2018 < 10 5 n 16 5 3/12/2019 < 10 5 6 6/11/2019 < 10 5 Mult Factor= 1.00 7 9/10/2019 < 10 5 Max. Value 5.0 ug/L 8 12/10/2019 < 10 5 Max. Pred Cw 5.0 ug/L 9 3/10/2020 < 10 5 10 6/9/2020 < 10 5 11 9/14/2020 < 10 5 12 12/8/2020 < 10 5 13 3/8/2021 < 10 5 14 6/8/2021 < 10 5 15 9/14/2021 < 10 5 16 12/6/2021 < 10 5 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 Use "PASTE SPECIAL - Values" then "COPY" . Maximum data points = 58 Par03 Beryllium Date Data BDL=1/2DL Results 1 3/20/2018 < 5 2.5 Std Dev. 0.0000 2 9/10/2019 < 5 2.5 Mean 2.5000 3 9/10/2020 < 5 2.5 C.V. (default) 0.6000 4 n 3 5 6 Mult Factor = 3.00 7 Max. Value 2.50 ug/L 8 Max. Pred Cw 7.50 ug/L 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 Use "PASTE SPECIAL - Values" then "COPY" . Maximum data points = 58 26641 RPA 4.0 MGD, data - 4 - 3/23/2022 REASONABLE POTENTIAL ANALYSIS Par04 Cadmium Date 2/5/2018 3/20/2018 4/3/2018 5/8/2018 6/12/2018 7/9/2018 8/1/2018 9/25/2018 10/2/2018 11/15/2018 12/18/2018 1/2/2019 2/5/2019 3/12/2019 4/4/2019 5/7/2019 6/11/2019 7/9/2019 8/6/2019 9/10/2019 10/3/2019 11/4/2019 12/10/2019 1/9/2020 2/6/2020 3/10/2020 4/1/2020 5/7/2020 6/9/2020 7/6/2020 8/5/2020 9/14/2020 10/13/2020 11/10/2020 12/8/2020 1 /5/2021 2/2/2021 3/8/2021 4/8/2021 5/5/2021 6/8/2021 7/8/2021 8/3/2021 9/14/2021 10/5/2021 11/2/2021 12/6/2021 1/5/2022 Data BDL=1/2DL 2 1 2 1 2 1 2 1 2 1 2 1 2 1 2 1 2 1 2 1 2 1 2 1 2 1 2 1 2 1 2 1 2 1 2 1 2 1 2 1 2 1 3 1 2 3 2 1 2 1 2 1 2 1 2 1 2 1 2 1 2 1 2 1 2 1 2 1 2 1 2 1 2 1 2 1 2 1 2 1 2 1 2 1 2 1 2 1 2 1 2 1 2 1 2 1 Results Std Dev. Mean C.V. n Mult Factor = Max. Value Max. Pred Cw Use "PASTE SPECIAL - Values" then "COPY" . Maximum data points = 58 0.2887 1.0417 0.2771 48 1.03 3.000 ug/L 3.090 ug/L Par05 Chlorides Date Data 11/7/2017 12/4/2017 3/20/2018 6/12/2018 9/11/2018 12/18/2018 3/12/2019 6/11/2019 9/10/2019 12/10/2019 3/10/2020 6/9/2020 9/14/2020 12/8/2020 3/8/2021 45.6 49 40 48 48.3 28.3 57.3 89 150 158 131 119 117 89 128 BDL=1/2DL 45.6 49 40 48 48.3 28.3 57.3 89 150 158 131 119 117 89 128 Results Std Dev. Mean C.V. n Mult Factor = Max. Value Max. Pred Cw Use "PASTE SPECIAL - Values" then "COPY" . Maximum data points = 58 44.1335 86.5 0.5102 15 1.4 158.0 mg/L 224.4 mg/L 26641 RPA 4.0 MGD, data - 5 - 3/23/2022 REASONABLE POTENTIAL ANALYSIS Par06 Chlorinated Phenolic Compounds Date Data BDL=1/2DL Results Std Dev. Mean C.V. n Mult Factor = Max. Value Max. Pred Cw Use "PASTE SPECIAL - Values" then "COPY" . Maximum data points = 58 NO DATA NO DATA NO DATA 0 N/A N/A ug/L N/A ug/L Par07 Total Phenolic Compounds Date Data 3/20/2018 9/10/2019 9/10/2020 < 23 11 10 BDL=1/2DL 23 11 5 Results Std Dev. Mean C.V. (default) n Mult Factor = Max. Value Max. Pred Cw Use "PASTE SPECIAL - Values" then "COPY" . Maximum data points = 58 9.1652 13.0000 0.6000 3 3.00 23.0 ug/L 69.0 ug/L 26641 RPA 4.0 MGD, data - 6 - 3/23/2022 REASONABLE POTENTIAL ANALYSIS Par08 Chromium III Date Data BDL=1/2DL Results Std Dev. Mean C.V. n Mult Factor = Max. Value Max. Pred Cw Use "PASTE SPECIAL - Values" then "COPY" . Maximum data points = 58 NO DATA NO DATA NO DATA 0 N/A N/A pg/L N/A pg/L Par09 Chromium VI Date Data BDL=1/2DL Results Std Dev. Mean C.V. n Mult Factor = Max. Value Max. Pred Cw Use "PASTE SPECIAL - Values" then "COPY" . Maximum data points = 58 NO DATA NO DATA NO DATA 0 N/A N/A pg/L N/A pg/L 26641 RPA 4.0 MGD, data - 7 - 3/23/2022 REASONABLE POTENTIAL ANALYSIS Par10 Chromium, Total Date Data BDL=1/2DL Results 1 3/20/2018 < 5 2.5 Std Dev. 0.0000 2 6/12/2018 < 5 2.5 Mean 2.5000 3 9/11/2018 < 5 2.5 C.V. 0.0000 4 12/18/2018 < 5 2.5 n 17 5 3/12/2019 < 5 2.5 6 6/11/2019 < 5 2.5 Mult Factor= 1.00 7 9/10/2019 < 5 2.5 Max. Value 2.5 .g/L 8 12/10/2019 < 5 2.5 Max. Pred Cw 2.5 pg/L 9 3/10/2020 < 5 2.5 10 6/9/2020 < 5 2.5 11 9/14/2020 < 5 2.5 12 12/8/2020 < 5 2.5 13 1/8/2021 < 5 2.5 14 3/8/2021 < 5 2.5 15 6/8/2021 < 5 2.5 16 9/14/2021 < 5 2.5 17 12/6/2021 < 5 2.5 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 Use "PASTE SPECIAL - Values" then "COPY" . Maximum data points = 58 Pall Copper Date Data BDL=1/2DL Results 1 3/20/2018 4 4 Std Dev. 3.4192 2 6/12/2018 7 7 Mean 7.7647 3 9/11/2018 10 10 C.V. 0.4404 4 12/18/2018 5 5 n 17 5 3/12/2019 7 7 6 6/11/2019 11 11 Mult Factor = 1.32 7 9/10/2019 11 11 Max. Value 16.00 ug/L 8 12/10/2019 13 13 Max. Pred Cw 21.12 ug/L 9 3/10/2020 16 16 10 6/9/2020 4 4 11 9/14/2020 6 6 12 12/8/2020 6 6 13 1/8/2021 6 6 14 3/8/2021 7 7 15 6/8/2021 6 6 16 9/14/2021 4 4 17 12/6/2021 9 9 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 Use "PASTE SPECIAL - Values" then "COPY" . Maximum data points = 58 26641 RPA 4.0 MGD, data - 8 - 3/23/2022 REASONABLE POTENTIAL ANALYSIS Par12 Cyanide Date Data 3/20/2018 9/10/2019 < 9/10/2020 BDL=1/2DL 8 5 5 5 6 5 Results Std Dev. Mean C.V. (default) n Mult Factor = Max. Value Max. Pred Cw Use "PASTE SPECIAL - Values" then "COPY" . Maximum data points = 58 0.0000 5.00 0.6000 3 3.00 5.0 ug/L 15.0 ug/L Par13 Fluoride Date Data BDL=1/2DL Results Std Dev. Mean C.V. n Mult Factor = Max. Value Max. Pred Cw Use "PASTE SPECIAL - Values" then "COPY" . Maximum data points = 58 NO DATA NO DATA NO DATA 0 N/A N/A ug/L N/A ug/L 26641 RPA 4.0 MGD, data - 9 - 3/23/2022 REASONABLE POTENTIAL ANALYSIS Par14 Lead Date 3/20/2018 6/12/2018 9/11/2018 12/18/2018 3/12/2019 6/11/2019 9/10/2019 12/10/2019 3/10/2020 6/9/2020 9/14/2020 12/8/2020 1 /8/2021 3/8/2021 6/8/2021 9/14/2021 12/6/2021 BDL=1/2DL Results < 10 5 Std Dev. < 10 5 Mean < 10 5 C.V. < 10 5 n < 10 5 < 10 5 Mult Factor = < 10 5 Max. Value < 10 5 Max. Pred Cw < 10 5 < 10 5 < 10 5 < 10 5 < 10 5 < 10 5 < 10 5 < 10 5 < 10 5 Use "PASTE SPECIAL - Values" then "COPY" . Maximum data points = 58 0.0000 5.0000 0.0000 17 1.00 5.000 ug/L 5.000 ug/L Par15 Mercury Date Data BDL=1/2DL Results Std Dev. Mean C.V. n Mult Factor = Max. Value Max. Pred Cw Use "PASTE SPECIAL - Values" then "COPY" . Maximum data points = 58 NO DATA NO DATA NO DATA 0 N/A N/A ng/L N/A ng/L 26641 RPA 4.0 MGD, data - 10 - 3/23/2022 REASONABLE POTENTIAL ANALYSIS Par16 Molybdenum Date Data BDL=1/2DL Results 1 3/20/2018 < 5 2.5 Std Dev. 0.0000 2 6/12/2018 < 5 2.5 Mean 2.5000 3 9/11/2018 < 5 2.5 C.V. 0.0000 4 12/18/2018 < 5 2.5 n 17 5 3/12/2019 < 5 2.5 6 6/11/2019 < 5 2.5 Mult Factor= 1.00 7 9/10/2019 < 5 2.5 Max. Value 2.5 ug/L 8 12/10/2019 < 5 2.5 Max. Pred Cw 2.5 ug/L 9 3/10/2020 < 5 2.5 10 6/9/2020 < 5 2.5 11 9/14/2020 < 5 2.5 12 12/8/2020 < 5 2.5 13 1/8/2021 < 5 2.5 14 3/8/2021 < 5 2.5 15 6/8/2021 < 5 2.5 16 9/14/2021 < 5 2.5 17 12/6/2021 < 5 2.5 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 Use "PASTE SPECIAL - Values" then "COPY" . Maximum data points = 58 Par17 & Par18 Nickel Date Data BDL=1/2DL Results 1 3/20/2018 < 10 5 Std Dev. 2.3570 2 6/12/2018 < 10 5 Mean 5.5556 3 9/11/2018 < 10 5 C.V. 0.4243 4 10/11/2018 < 10 5 n 18 5 12/18/2018 < 10 5 6 3/12/2019 < 10 5 Mult Factor = 1.29 7 6/11/2019 < 10 5 Max. Value 15.0 pg/L 8 9/10/2019 < 10 5 Max. Pred Cw 19.4 pg/L 9 12/10/2019 < 10 5 10 3/10/2020 < 10 5 11 6/9/2020 < 10 5 12 9/14/2020 < 10 5 13 12/8/2020 < 10 5 14 1/8/2021 < 10 5 15 3/8/2021 < 10 5 16 6/8/2021 < 10 5 17 9/14/2021 15 15 18 12/6/2021 < 10 5 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 Use "PASTE SPECIAL - Values" then "COPY" . Maximum data points = 58 26641 RPA 4.0 MGD, data - 11 - 3/23/2022 REASONABLE POTENTIAL ANALYSIS Par19 Selenium Date Data BDL=1/2DL Results 1 3/20/2018 < 10 5 Std Dev. 0.0000 2 6/12/2018 < 10 5 Mean 5.0000 3 9/11/2018 < 10 5 C.V. 0.0000 4 11/11/2018 < 10 5 n 18 5 12/18/2018 < 10 5 6 3/12/2019 < 10 5 Mult Factor = 1.00 7 6/11/2019 < 10 5 Max. Value 5.0 ug/L 8 9/10/2019 < 10 5 Max. Pred Cw 5.0 ug/L 9 12/10/2019 < 10 5 10 3/10/2020 < 10 5 11 6/9/2020 < 10 5 12 9/14/2020 < 10 5 13 12/8/2020 < 10 5 14 1/8/2021 < 10 5 15 3/8/2021 < 10 5 16 6/8/2021 < 10 5 17 9/14/2021 < 10 5 18 12/6/2021 < 10 5 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 Use "PASTE SPECIAL - Values" then "COPY" . Maximum data points = 58 Par20 Silver Date Data BDL=1/2DL Results 1 3/20/2018 < 5 2.5 Std Dev. 0.0000 2 9/10/2019 < 5 2.5 Mean 2.5000 3 9/10/2020 < 5 2.5 C.V. (default) 0.6000 4 n 3 5 6 Mult Factor = 3.00 7 Max. Value 2.500 ug/L 8 Max. Pred Cw 7.500 ug/L 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 Use "PASTE SPECIAL - Values" then "COPY" . Maximum data points = 58 26641 RPA 4.0 MGD, data - 12 - 3/23/2022 REASONABLE POTENTIAL ANALYSIS Par21 Zinc Date Data 3/20/2018 6/12/2018 9/11/2018 < 11/11/2018 < 12/18/2018 3/12/2019 6/11/2019 9/10/2019 12/10/2019 3/10/2020 6/9/2020 9/14/2020 12/8/2020 1 /8/2021 3/8/2021 6/8/2021 9/14/2021 12/6/2021 16 12 10 10 13 21 17 15 15 31 16 24 26 26 26 28 19 30 BDL=1/2DL 16 12 5 5 13 21 17 15 15 31 16 24 26 26 26 28 19 30 Results Std Dev. Mean C.V. n Mult Factor = Max. Value Max. Pred Cw Use "PASTE SPECIAL - Values" then "COPY" . Maximum data points = 58 Par22 Chloroform 7.8684 19.1667 0.4105 18 1.28 31.0 ug/L 39.7 ug/L Date Data 3/20/2018 3.82 9/10/2019 6.92 9/10/2020 < 1 BDL=1/2DL 3.82 6.92 0.5 Results Std Dev. Mean C.V. (default) n Use "PASTE SPECIAL - Values" then "COPY" . Maximum data points = 58 3.2106 3.7467 0.6000 3 Mult Factor = 3.00 Max. Value 6.920000 dig/L Max. Pred Cw 20.760000 .Ig/L 26641 RPA 4.0 MGD, data - 13 - 3/23/2022 REASONABLE POTENTIAL ANALYSIS Par23 Dichlorobromomethane Date Data 3/20/2018 9/10/2019 < 9/10/2020 < BDL=1/2DL 1.25 1.25 1 0.5 1 0.5 Results Std Dev. Mean C.V. (default) n Mult Factor = Max. Value Max. Pred Cw Use "PASTE SPECIAL - Values" then "COPY" . Maximum data points = 58 0.4330 0.7500 0.6000 3 3.00 1.250000 pg/L 3.750000 pg/L Par24 Bis (2-ethylhexyl) phthalate Date Data 3/20/2018 9/10/2019 < 9/10/2020 < BDL=1/2DL 15.1 15.1 10 5 10 5 Results Std Dev. Mean C.V. (default) n Use "PASTE SPECIAL - Values" then "COPY" . Maximum data points = 58 5.8312 8.3667 0.6000 3 Mult Factor = 3.00 Max. Value 15.100000 pg/L Max. Pred Cw 45.300000 pg/L -14- 26641 RPA 4.0 MGD, data 3/23/2022 REASONABLE POTENTIAL ANALYSIS Par25 0 Date Data BDL=1/2DL Results 1 Std Dev. 2 Mean 3 C.V. 4 n 5 6 Mult Factor = 7 Max. Value 8 Max. Pred Cw 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 Use "PASTE SPECIAL - Values" then "COPY" . Maximum data points = 58 NO DATA NO DATA NO DATA 0 N/A N/A N/A 26641 RPA 4.0 MGD, data - 15 - 3/23/2022 Slier City WWTP NC0026441 Freshwater RPA - 95% Probability/95% Confidence Using Metal Translators MAXIMUM DATA POINTS = 58 Qw (MGD) = 6.0000 1Q1OS (cfs) = 0.08 7Q1OS (cfs) = 0.09 7Q1OW (cfs) = 0.23 30Q2 (cfs) = 0.32 Avg. Stream Flow, QA (cfs) = 8.70 Receiving Stream: Loves Creek HUC 03030003 WWTP/WTP Class: IWC% @ 1Q1OS = IWC% @ 7Q1OS = IWC% @ 7Q1OW = IWC% @ 30Q2 = IW%C @ QA = Stream Class: Grade IV 99.14712154 99.04153355 97.58656873 96.67359667 51.66666667 C Outfall 001 Qw=6MGD COMBINED HARDNESS (mg/L) Acute = 95.02 mg/L Chronic = 94.96 mg/L PARAMETER TYPE NC STANDARDS OR EPA CRITERIA _1 co = REASONABLE POTENTIAL RESULTS RECOMMENDED ACTION Chronic Applied Acute Standard 11 # Det. Max Pred Cw Allowable Cw Arsenic Arsenic _ C C 150 FW(7Q10s) 340 10 EIH/WS(Qavg) ug/L ug/L 16 0 5.0 NO DETECTS Acute (FW): 342.9 _ _ _ _____ _______________________________ Chronic (FW): 151.5 _Max_MDL = 10 ___ Chronic (HH): 19.4 Max MDL = 10 _ _ _ _ _ _ _ _ _ _ _ ____ No detects at < 10 ug/L. No monitoring or limits required. Beryllium NC 6.5 FW(7Q10s) 65 ug/L' 3 0 Note: n < 9 Limited data set 7.50 C.V. (default) NO DETECTS Acute: 65.56 ___ _ ______ ___ Chronic: 6.56 Max MDL = 5 _ _ _ _ _ _ _ _ _ _ _ _____ No detects at < 5 ug/L. No monitoring or limits required. Cadmium NC 1.6162 FW(7Q10s) 10.3806 ug/L 48 2 3.090 Acute: 10.470 _ _ _ _ _ _ _ _ _ _ _ _ _ Chronic: 1.632 1 value(s) > Allowable Cw _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ RP found based on 1 detect: 3 ug/L on 10/3/2019, and many ND < 2 ug/L. Apply qtrly monitoring. Chlorides NC 230 FW(7Q10s) mg/L 15 15 224.4 Acute: NO WQS _ _ _ _ _ _ _ _ _ _ _ _ Chronic: 232.2 No value > Allowable Cw _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ No RP , Predicted Max >_ 50% of Allowable Cw - apply Quarterly Monitoring Chlorinated Phenolic Compounds NC 1 A(30Q2) ug/L 0 0 N/A Acute: NO WQS -_ _ ----- _ -------------------------------- Chronic: 1.0 Total Phenolic Compounds NC 300 A(30Q2) ug/L 3 2 Note: n < 9 Limited data set 69.0 C.V. (default) Acute: NO WQS ___ _ ____ _ ________________ Chronic: 310.3 No value > Allowable Cw _______ No RP for limited dataset (n<8 samples) Chromium III NC 351.2295 FW(7Q10s) 2701.4991 µg/L 0 0 N/A Acute: 2,724.7 -_ _ ---- _ _ ------------------------------- Chronic: 354.6 Chromium VI NC 11 FW(7Q10s) 16 µg/L' 0 0 N/A Acute: 16.1 -_ _ ---- _ _ ------------------------------- Chronic: -11.1 Chromium, Total NC Kg/17 0 2.5 NO DETECTS Max reported value = 2.5 Max MDL = 5 a: No monitoring required if all Total Chromium samples are < 5 pg/L or Pred. max for Total Cr is < allowable Cw for Cr VI. Page 16 of 19 26641 RPA 4.0 MGD, rpa 3/23/2022 Slier City WWTP NC0026441 Freshwater RPA - 95% Probability/95% Confidence Using Metal Translators Outfall 001 Qw=6MGD Copper NC 24.6508 FW(7Q10s) 36.8457 ug/L 17 17 21.12 Acute: 37.16 _ _ _ _ _ _ _ _ _ _ _ _ Chronic: 24.89 No value > Allowable Cw _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ No RP , Predicted Max >_ 50% of Allowable Cw - apply Quarterly Monitoring Cyanide NC 5 FW(7Q10s) 22 10 ug/L 3 2 Note: n < 9 Limited data set 15.0 C.V. (default) Acute: 22.2 ___ _ ______ ___ Chronic: 5.0 No value > Allowable Cw _ _ _ _ _ _ _ ___ _ _ _ ___ No value > 10 ug/L; all results < 10 ug/L considered compliant due to analytical issues. No monitoring. Fluoride NC 1800 FW(7Q10s) ug/L 0 0 N/A Acute: NO WQS -_ _ ---_ _ ------------------------------- Chronic: -1,817.4 Lead NC 12.9350 FW(7Q10s) 332.1605 ug/L 17 0 5.000 NO DETECTS Acute: 335.018 _ _ _ _ _ _ _ _ _ _ _ _ Chronic: 13.060 Max MDL = 10 _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ All nondetects at < 10 ug/L; no monitoring required. Mercury NC 12 FW(7Q10s) 0.5 ng/L 0 0 N/A Acute: NO WQS -- _ _ ------------------------------------ Chronic:12 1 Molybdenum NC 2000 HH(7Q10s) ug/L 17 0 2.5 NO DETECTS Acute: NO WQS ___ _ ____ _ ___ Chronic: 2,019.4 Max MDL = 5 _ ___ _ _ _ _ _ _ _ _ _ ___ No RP, Predicted Max < 50% of Allowable Cw - No Monitoring required Nickel Nickel NC NC 115.1469 FW(7Q10s) 1037.2630 25.0000 WS(7Q10s) µg/L µg/L 18 1 19.4 Acute (FW): 1,046.2 _ _ _ _ _ _ _ _ _ _ _ Chronic (FW): 116.3 No value > Allowable Cw Chronic (WS): 25.2 No value > Allowable Cw _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ All nondetects at < 10 ug/L with one detect of 29 ug/L in 12/12/2017. No monitoring required. Selenium NC 5 FW(7Q10s) 56 ug/L 18 0 5.0 NO DETECTS Acute: 56.5 ___ _ ______ ___ Chronic: 5.0 Max MDL = 10 _ _ _ _ _ _ _ _ _ _ _ _ ___ All nondetects at < 10 ug/L; PQL = 1 ug/L. Apply quarterly monitoring, test to lower level. Silver _ NC 0.06 FW(7Q10s) 2.9462 ug/L 3 0 Note: n < 9 Limited data set 7.500 C.V. (default) NO DETECTS Acute: 2.972 ___ _ ____ _ ___ Chronic: 0.061 Max MDL = 5 _ _ _ _ _ _ _ _ _ _ _ _____ All nondetects < 5 ug/L; PQL = 1.0 ug/L. Apply quarterly monitoring and test to lower limit. Zinc NC 392.6345 FW(7Q10s) 389.6554 ug/L 18 16 39.7 Acute: 393.0 _ _ _ _ _ _ _ _ _ _ _ _ Chronic: 396.4 No value > Allowable Cw _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ No RP, Predicted Max < 50% of Allowable Cw - No Monitoring required Chloroform _ NC 2000 HH(7Q10s) µg/L 3 2 Note: n < 9 Limited data set 20.76000 C.V. (default) Acute: NO WQS ___ _ ____ _ _ ______________ Chronic: 2019.35484 No value > Allowable Cw _______ No RP for limited dataset (n<8 samples) Dichlorobromomethane C 27 HH(Qavg) µg/L 3 1 Note: n < 9 Limited data set 3.75000 C.V. (default) Acute: NO WQS ___ _ ____ _ _ _____________ Chronic: 52.25806 No value > Allowable Cw _______ No RP for limited dataset (n<8 samples) Bis (2-ethylhexyl) phthalate C 0.37 HH(Qavg) µg/L 3 1 Note: n < 9 Limited data set 45.30000 C.V. (default) Acute: NO WQS _ _ _ _ _ _ _ _ _ _ _ Chronic: 0.71613 3 value(s) > Allowable Cw _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ RP for Limited Dataset (n<8 samples) - apply Quarterly Monitoring Page 17 of 19 26641 RPA 4.0 MGD, rpa 3/23/2022 Date: 3/23/2022 Dissolved to Total Metal Calculator Do NOT enter any data directly into this spreadsheet. Enter data onto "Table 1" under the Input Sheet and enter "Effluent Hardness" under the Data Sheet. In accordance with 40 CFR 122.45 (c ), permits are, have and must be written as total metals. This calculator has been inserted into the RPA to calculate Total Metal allowable allocations once Table 1 has been completed (Input Sheet) and Effluent hardness has been entered (Data Sheet). 1) Following the spreadsheet from left to right. First the allowable allocations for the dissolved metals will appear for all the metals listed once Table 1 is complete and effluent hardness entered. Use a default value of 25 mg/L if no hardness data is available. Second, the Dissolved Metal allocations are divided by the Translators to determine the Total Metals that can be allocated to the Permittee. These Total Metals values are automatically inserted into Table 2 and are the allowable Total Metal allocations determined for the Permittee prior to allowing for dilution. See Input sheet Table 2. The final acute and chronic values shown under the RPA sheet are the Total Metal values listed in Table 2 divided by the acute and chronic IWC, respectively. 2) The Translators used in the freshwater RPA are the Partition Coefficients published by US EPA in 1984. They are TSS dependent equations and can be found listed with the WQS hardness dependent equations under the sheet labeled Equations. A fixed TSS value of 10 mg/L is used to calculate the Translator values. 3) Pretreatment Facilities - PERCS will need a copy of the Dissolved to Total Metal Calculator spreadsheet and the RPA sheet along with the Final Permit. Pretreatment Facilities are required to renew their Headwords Analysis after renewal of their permits. Since all their metal allocations are likely to change PERCS needs to see any new metal permit limits and the allowable allocations for the dissolved metals to assess Maximum Allowable Headworks Loading (MAHL) numbers for each metal based on the Combined Hardness values used in the permit writers RPA calculations. 4) For Cadmium, Lead, Nickel, Chromium and Beryllium, if all the effluent sampling data for the last three to five years shows the pollutant at concentrations less than the Practical Quantitative Level (PQL), it is not likely a limit or monitoring will be put in the permit. However, if the estimated NPDES permit limit is less than the Practical Quantitative Limit (particularly, Cadmium and Lead) and the pollutant is believed to be present, to assess compliance with the new standards and for future permit limit development, monitoring for the pollutant will be required. If the facility is monitoring for the pollutant in its Pretreatment LTMP, no monitoring is needed in the permit. FACILITY: Siler City WWTP Outfall 001 NPDES PERMIT: NC0026441 Dissolved to Total Metal Calculator In accordance with Federal Regulations, permit limitations must be written as Total Metals per 40 CFR 122.45(c) Receiving Stream summer 7Q10 (CFS) Receiving Stream summer 7Q10 (MGD) Rec. Stream 1Q10 [MGD] NPDES Flow Limit [MGD] Total Suspended Solids -Fixed Value- (mg/L) Combined Hardness chronic (mg/L) Combined Hardness Acute (mg/L) Instream Wastewater Concentration (Chronic) Instream Wastewater Concentration (Acute) Upstream Hardness Average (mg/L) Effluent Hardness Average (mg/L) 0.0900 I 0.0581 0.0516 6.0000 , 10 94.960 95.020 99.0415 99.1471 I 39.2 j 95.5 PARAMETER Cadmium (d) Cd -Trout streams Chromium Ill (d)(h) Chromium VI (d) Chromium, Total (t) Copper (d)(h) Lead (d)(h) Nickel (d)(h) Dissolved Metals Criteria after applying hardness equation Chronic Acute [ug/I] 0.41 0.41 71 11 [ug/I] 2.62 US EPA Translators- using Default Partition Coefficients (streams) 0.252 Total Metal Criteria Total Metal = Dissolved Metal = Translator Chronic Acute Upstream Hard Avg (mg/L) = EFF Hard Avg (mg/L) = 95.5 39.2 1.631 0.2521 546 16 8.6 12.8 2.38 61 Ni - WS streams (t) Silver (d)(h,acute) Zinc (d)(h) 50 448 0.06 113 2.95 112 0.202 1.000 0.348 0.184 0.432 1.000 0.288 [ug/I] [ug/I] 1.62 10.38 1.62 6.45 351.23 2701.50 11.00 16.00 N/A N/A 24.65 36.85 12.93 332.16 115.15 1037.26 25 N/A 0.06 2.95 392.63 389.66 Beryllium Arsenic (d) 6.5 65 1.000 150 340 1.000 6 150 65 340 COMMENTS (identify parameters to PERCS Branch to maintain in facility's LTMP/STMP): (d) = dissolved metal standard. See 15A NCAC 02B .0211 for more information. (h) = hardness -dependent dissolved metal standard. See 15A NCAC 02B .0211 for more information. (t) = based upon measurement of total recoveable metal. See 15A NCAC 02B .0211 for more information. The Human Health standard for Nickel in Water Supply Streams is 25 mg/L which is Total Recoverable metal standard. The Human Health standard for Arsenic is 10 µg/L which is Total Recoverable metal standard. ACAH 95.01983 ACCH 94.96038 Facility Name WWTP/WTP Class NPDES Permit Outfall Flow, Qw (MGD) Receiving Stream HUC Number Stream Class Freshwater RPA - 95% Probability/95% Confidence Using Metal Translators MAXIMUM DATA POINTS = 58 REQUIRED DATA ENTRY Table 1. Project Information ❑ CHECK IF HQW OR ORW WQS Siler City WWTP Grade IV NC0026441 001 6.000 Loves Creek 03030003 ❑ Apply WS Hardness WQC 7Q10s (cfs) 7Q1Ow (cfs) 30Q2 (cfs) QA (cfs) 1 Q1 Os (cfs) 0.09 0.23 0.32 8.70 0.08 Effluent Hardness 95.5 mg/L (Avg) Upstream Hardness 39.2 mg/L (Avg) Combined Hardness Chronic Combined Hardness Acute 94.96 mg/L 95.02 mg/L Data Source(s) ❑ CHECK TO APPLY MODEL Data from submitted DMRs and PPAs; Hardness data provided by the permittee by request. Streamflows updated by USGS per request in July 2021. Table 2. Parameters of Concern Par01 Par02 Par03 Par04 Par05 Par06 Par07 Par08 Par09 Par10 Par11 Par12 Par13 Par14 Par15 Par16 Par17 Par18 Par19 Par20 Par21 Par22 Par23 Par24 Name WQS Type Chronic Modifier Acute PQL Units Arsenic Aquactic Life C 150 FW 340 ug/L Arsenic Human Health Water Supply C 10 HH/WS N/A ug/L Beryllium Aquatic Life NC 6.5 FW 65 ug/L Cadmium Aquatic Life NC 1.6162 FW 10.3806 ug/L Chlorides Aquatic Life NC 230 FW mg/L Chlorinated Phenolic Compounds Water Supply NC 1 A ug/L ♦ Total Phenolic Compounds Aquatic Life NC 300 A ug/L Chromium III Aquatic Life NC 351.2295 FW 2701.4991 ug/L Chromium VI Aquatic Life NC 11 FW 16 pg/L Chromium, Total Aquatic Life NC N/A FW N/A pg/L Copper Aquatic Life NC 24.6508 FW 36.8457 ug/L Cyanide Aquatic Life NC 5 FW 22 10 ug/L Fluoride Aquatic Life NC 1,800 FW ug/L Lead Aquatic Life NC 12.9350 FW 332.1605 ug/L Mercury Aquatic Life NC 12 FW 0.5 ng/L Molybdenum Human Health NC 2000 HH ug/L Nickel Aquatic Life NC 115.1469 FW 1037.2630 pg/L Nickel Water Supply NC 25.0000 WS N/A pg/L Selenium Aquatic Life NC 5 FW 56 ug/L Silver Aquatic Life NC 0.06 FW 2.9462 ug/L Zinc Aquatic Life NC 392.6345 FW 389.6554 ug/L Chloroform Human Health NC 2000 HH pg/L Dichlorobromomethane Human Health C 27 HH pg/L Bis (2-ethylhexyl) phthalate Human Health C 0.37 HH pg/L 26641 RPA 6.0 MGD, input 3/23/2022 Slier City WWTP NC0026441 Freshwater RPA - 95% Probability/95% Confidence Using Metal Translators MAXIMUM DATA POINTS = 58 Qw (MGD) = 6.0000 1Q1OS (cfs) = 0.08 7Q1OS (cfs) = 0.09 7Q1OW (cfs) = 0.23 30Q2 (cfs) = 0.32 Avg. Stream Flow, QA (cfs) = 8.70 Receiving Stream: Loves Creek HUC 03030003 WWTP/WTP Class: IWC% @ 1Q1OS = IWC% @ 7Q1OS = IWC% @ 7Q1OW = IWC% @ 30Q2 = IW%C @ QA = Stream Class: Grade IV 99.14712154 99.04153355 97.58656873 96.67359667 51.66666667 C Outfall 001 Qw=6MGD COMBINED HARDNESS (mg/L) Acute = 95.02 mg/L Chronic = 94.96 mg/L PARAMETER TYPE NC STANDARDS OR EPA CRITERIA _1 co = REASONABLE POTENTIAL RESULTS RECOMMENDED ACTION Chronic Applied Acute Standard 11 # Det. Max Pred Cw Allowable Cw Arsenic Arsenic _ C C 150 FW(7Q10s) 340 10 EIH/WS(Qavg) ug/L ug/L 16 0 5.0 NO DETECTS Acute (FW): 342.9 _ _ _ _ _____ _______________________________ Chronic (FW) 151.5 _Max_MDL = 10 ___ Chronic (HH): 19.4 Max MDL = 10 _ _ _ _ _ _ _ _ _ _ _ ____ No detects at < 10 ug/L. No monitoring or limits required. Beryllium NC 6.5 FW(7Q10s) 65 ug/L' 3 0 Note: n < 9 Limited data set 7.50 C.V. (default) NO DETECTS Acute: 65.56 ___ _ ______ ___ Chronic: 6.56 Max MDL = 5 _ _ _ _ _ _ _ _ _ _ _ _____ No detects at < 5 ug/L. No monitoring or limits required. Cadmium NC 1.6162 FW(7Q10s) 10.3806 ug/L 48 2 3.090 Acute: 10.470 ___ _ ______ ___ Chronic: 1.632 1 value(s) > Allowable Cw _ _ _ _ _ _ _ _ _ _ _ _ ___ RP found based on 1 detect: 3 ug/L on 10/3/2019, and many ND < 2 ug/L. Apply qtrly monitoring. Chlorides NC 230 FW(7Q10s) mg/L 15 15 224.4 Acute: NO WQS _ _ _ _ _ _ _ _ _ _ _ _ Chronic: 232.2 No value > Allowable Cw _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ No RP , Predicted Max >_ 50% of Allowable Cw - apply Quarterly Monitoring Chlorinated Phenolic Compounds NC 1 A(30Q2) ug/L 0 0 N/A Acute: NO WQS -_ _ ----- _ -------------------------------- Chronic: 1.0 Total Phenolic Compounds NC 300 A(30Q2) ug/L 3 2 Note: n < 9 Limited data set 69.0 C.V. (default) Acute: NO WQS ___ _ ____ _ ________________ Chronic: 310.3 No value > Allowable Cw _______ No RP for limited dataset (n<8 samples) Chromium III NC 351.2295 FW(7Q10s) 2701.4991 µg/L 0 0 N/A Acute: 2,724.7 -_ _ ---- _ _ ------------------------------- Chronic: 354.6 Chromium VI NC 11 FW(7Q10s) 16 µg/L 0 0 N/A Acute: 16.1 -_ _ ---- _ _ ------------------------------- Chronic: -11.1 Chromium, Total NC µg/L 17 0 2.5 NO DETECTS Max reported value = 2.5 Max MDL = 5 a: No monitoring required if all Total Chromium samples are < 5 pg/L or Pred. max for Total Cr is < allowable Cw for Cr VI. Page 3 of 6 26641 RPA 6.0 MGD, rpa 3/23/2022 Slier City WWTP NC0026441 Freshwater RPA - 95% Probability/95% Confidence Using Metal Translators Outfall 001 Qw=6MGD Copper NC 24.6508 FW(7Q10s) 36.8457 ug/L 17 17 21.12 Acute: 37.16 _ _ _ _ _ _ _ _ _ _ _ _ Chronic: 24.89 No value > Allowable Cw _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ No RP , Predicted Max >_ 50% of Allowable Cw - apply Quarterly Monitoring Cyanide NC 5 FW(7Q10s) 22 10 ug/L 3 2 Note: n < 9 Limited data set 15.0 C.V. (default) Acute: 22.2 ___ _ ______ ___ Chronic: 5.0 No value > Allowable Cw _ _ _ _ _ _ _ ___ _ _ _ ___ No value > 10 ug/L; all results < 10 ug/L considered compliant due to analytical issues. No monitoring. Fluoride NC 1800 FW(7Q10s) ug/L 0 0 N/A Acute: NO WQS -_ _ ---_ _ ------------------------------- Chronic: -1,817.4 Lead NC 12.9350 FW(7Q10s) 332.1605 ug/L 17 0 5.000 NO DETECTS Acute: 335.018 _ _ _ _ _ _ _ _ _ _ _ _ Chronic: 13.060 Max MDL = 10 _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ All nondetects at < 10 ug/L; no monitoring required. Mercury NC 12 FW(7Q10s) 0.5 ng/L 0 0 N/A Acute: NO WQS -- _ _ ------------------------------------ Chronic:12 1 Molybdenum NC 2000 HH(7Q10s) ug/L 17 0 2.5 NO DETECTS Acute: NO WQS ___ _ ____ _ ___ Chronic: 2,019.4 Max MDL = 5 _ ___ _ _ _ _ _ _ _ _ _ ___ No RP, Predicted Max < 50% of Allowable Cw - No Monitoring required Nickel Nickel NC NC 115.1469 FW(7Q10s) 1037.2630 25.0000 WS(7Q10s) µg/L µg/L 18 1 19.4 Acute (FW): 1,046.2 _ _ _ _ _ _ _ _ _ _ _ Chronic (FW): 116.3 No value > Allowable Cw Chronic (WS): 25.2 No value > Allowable Cw _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ All nondetects at < 10 ug/L with one detect of 29 ug/L in 12/12/2017. No monitoring required. Selenium NC 5 FW(7Q10s) 56 ug/L 18 0 5.0 NO DETECTS Acute: 56.5 ___ _ ______ ___ Chronic: 5.0 Max MDL = 10 _ _ _ _ _ _ _ _ _ _ _ _ ___ All but one nondetects at < 10 ug/L; PQL = 1 ug/L. Apply quarterly monitoring, test to lower level. Silver _ NC 0.06 FW(7Q10s) 2.9462 ug/L 3 0 Note: n < 9 Limited data set 7.500 C.V. (default) NO DETECTS Acute: 2.972 ___ _ ____ _ ___ Chronic: 0.061 Max MDL = 5 _ _ _ _ _ _ _ _ _ _ _ _____ All nondetects < 5 ug/L; PQL = 1.0 ug/L. Apply quarterly monitoring and test to lower limit. Zinc NC 392.6345 FW(7Q10s) 389.6554 ug/L 18 16 39.7 Acute: 393.0 _ _ _ _ _ _ _ _ _ _ _ _ Chronic: 396.4 No value > Allowable Cw _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ No RP, Predicted Max < 50% of Allowable Cw - No Monitoring required Chloroform _ NC 2000 HH(7Q10s) µg/L 3 2 Note: n < 9 Limited data set 20.76000 C.V. (default) Acute: NO WQS ___ _ ____ _ _ ______________ Chronic: 2019.35484 No value > Allowable Cw _______ No RP for limited dataset (n<8 samples) Dichlorobromomethane C 27 HH(Qavg) µg/L 3 1 Note: n < 9 Limited data set 3.75000 C.V. (default) Acute: NO WQS ___ _ ____ _ _ ______________ Chronic: 52.25806 No value > Allowable Cw _______ No RP for limited dataset (n<8 samples) Bis (2-ethylhexyl) phthalate C 0.37 HH(Qavg) µg/L 3 1 Note: n < 9 Limited data set 45.30000 C.V. (default) Acute: NO WQS _ _ _ _ _ _ _ _ _ _ _ Chronic: 0.71613 3 value(s) > Allowable Cw _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ RP for Limited Dataset (n<8 samples) - apply Quarterly Monitoring Page 4 of 6 26641 RPA 6.0 MGD, rpa 3/23/2022 Date: 3/23/2022 Dissolved to Total Metal Calculator Do NOT enter any data directly into this spreadsheet. Enter data onto "Table 1" under the Input Sheet and enter "Effluent Hardness" under the Data Sheet. In accordance with 40 CFR 122.45 (c ), permits are, have and must be written as total metals. This calculator has been inserted into the RPA to calculate Total Metal allowable allocations once Table 1 has been completed (Input Sheet) and Effluent hardness has been entered (Data Sheet). 1) Following the spreadsheet from left to right. First the allowable allocations for the dissolved metals will appear for all the metals listed once Table 1 is complete and effluent hardness entered. Use a default value of 25 mg/L if no hardness data is available. Second, the Dissolved Metal allocations are divided by the Translators to determine the Total Metals that can be allocated to the Permittee. These Total Metals values are automatically inserted into Table 2 and are the allowable Total Metal allocations determined for the Permittee prior to allowing for dilution. See Input sheet Table 2. The final acute and chronic values shown under the RPA sheet are the Total Metal values listed in Table 2 divided by the acute and chronic IWC, respectively. 2) The Translators used in the freshwater RPA are the Partition Coefficients published by US EPA in 1984. They are TSS dependent equations and can be found listed with the WQS hardness dependent equations under the sheet labeled Equations. A fixed TSS value of 10 mg/L is used to calculate the Translator values. 3) Pretreatment Facilities - PERCS will need a copy of the Dissolved to Total Metal Calculator spreadsheet and the RPA sheet along with the Final Permit. Pretreatment Facilities are required to renew their Headwords Analysis after renewal of their permits. Since all their metal allocations are likely to change PERCS needs to see any new metal permit limits and the allowable allocations for the dissolved metals to assess Maximum Allowable Headworks Loading (MAHL) numbers for each metal based on the Combined Hardness values used in the permit writers RPA calculations. 4) For Cadmium, Lead, Nickel, Chromium and Beryllium, if all the effluent sampling data for the last three to five years shows the pollutant at concentrations less than the Practical Quantitative Level (PQL), it is not likely a limit or monitoring will be put in the permit. However, if the estimated NPDES permit limit is less than the Practical Quantitative Limit (particularly, Cadmium and Lead) and the pollutant is believed to be present, to assess compliance with the new standards and for future permit limit development, monitoring for the pollutant will be required. If the facility is monitoring for the pollutant in its Pretreatment LTMP, no monitoring is needed in the permit. FACILITY: Siler City WWTP Outfall 001 NPDES PERMIT: NC0026441 Dissolved to Total Metal Calculator In accordance with Federal Regulations, permit limitations must be written as Total Metals per 40 CFR 122.45(c) Receiving Stream summer 7Q10 (CFS) Receiving Stream summer 7Q10 (MGD) Rec. Stream 1Q10 [MGD] NPDES Flow Limit [MGD] Total Suspended Solids -Fixed Value- (mg/L) Combined Hardness chronic (mg/L) Combined Hardness Acute (mg/L) Instream Wastewater Concentration (Chronic) Instream Wastewater Concentration (Acute) Upstream Hardness Average (mg/L) Effluent Hardness Average (mg/L) 0.0900 I 0.0581 0.0516 6.0000 10 94.960 95.020 99.0415 99.1471 I 39.2 j 95.5 PARAMETER Cadmium (d) Cd -Trout streams Chromium Ill (d)(h) Chromium VI (d) Chromium, Total (t) Copper (d)(h) Lead (d)(h) Nickel (d)(h) Dissolved Metals Criteria after applying hardness equation Chronic Acute [ug/I] 0.41 0.41 71 11 [ug/I] 2.62 US EPA Translators- using Default Partition Coefficients (streams) 0.252 Total Metal Criteria Total Metal = Dissolved Metal = Translator Chronic Acute Upstream Hard Avg (mg/L) = EFF Hard Avg (mg/L) = 95.5 39.2 1.631 0.2521 546 16 8.6 12.8 0.202 1.000 0.348 [ug/I] [ug/I] 1.62 10.38 1.62 6.45 351.23 2701.50 11.00 16.00 N/A N/A 24.65 36.85 Ni - WS streams (t) Silver (d)(h,acute) Zinc (d)(h) 2.38 61 50 448 0.06 113 2.95 112 0.1841 0.432 12.93 115.15 332.16 1037.26 25 N/A 1.0001 0.06 0.2881 392.63 2.95 389.66 Beryllium Arsenic (d) 6.5 65 1.000 150 340 1.000 6 150 65 340 COMMENTS (identify parameters to PERCS Branch to maintain in facility's LTMP/STMP): (d) = dissolved metal standard. See 15A NCAC 02B .0211 for more information. (h) = hardness -dependent dissolved metal standard. See 15A NCAC 02B .0211 for more information. (t) = based upon measurement of total recoveable metal. See 15A NCAC 02B .0211 for more information. The Human Health standard for Nickel in Water Supply Streams is 25 mg/L which is Total Recoverable metal standard. The Human Health standard for Arsenic is 10 µg/L which is Total Recoverable metal standard. ACAH 95.01983 ACCH 94.96038 Permit No. NC0026441 NPDES Implementation of Instream Dissolved Metals Standards - Freshwater Standards The NC 2007-2015 Water Quality Standard (WQS) Triennial Review was approved by the NC Environmental Management Commission (EMC) on November 13, 2014. The US EPA subsequently approved the WQS revisions on April 6, 2016, with some exceptions. Therefore, metal limits in draft permits out to public notice after April 6, 2016 must be calculated to protect the new standards - as approved. Table 1. NC Dissolved Metals Water Quality Standards/Aquatic Life Protection Parameter Acute FW, µg/1 (Dissolved) Chronic FW, µg/1 (Dissolved) Acute SW, 1.1g/1 (Dissolved) Chronic SW, µg/1 (Dissolved) Arsenic 340 150 69 36 Beryllium 65 6.5 --- --- Cadmium Calculation Calculation 40 8.8 Chromium III Calculation Calculation --- --- Chromium VI 16 11 1100 50 Copper Calculation Calculation 4.8 3.1 Lead Calculation Calculation 210 8.1 Nickel Calculation Calculation 74 8.2 Silver Calculation 0.06 1.9 0.1 Zinc Calculation Calculation 90 81 Table 1 Notes: 1. FW= Freshwater, SW= Saltwater 2. Calculation = Hardness dependent standard 3. Only the aquatic life standards listed above are expressed in dissolved form. Aquatic life standards for Mercury and selenium are still expressed as Total Recoverable Metals due to bioaccumulative concerns (as are all human health standards for all metals). It is still necessary to evaluate total recoverable aquatic life and human health standards listed in 15A NCAC 2B.0200 (e.g., arsenic at 10 µg/1 for human health protection; cyanide at 5 µg/L and fluoride at 1.8 mg/L for aquatic life protection). Table 2. Dissolved Freshwater Standards for Hardness -Dependent Metals The Water Effects Ratio (WER) is equal to one unless determined otherwise under 15A NCAC 02B .0211 Subparagraph (11)(d) Metal NC Dissolved Standard, µg/I Cadmium, Acute WER*{1.136672-[ln hardness](0.041838)} • e^{0.9151 [In hardness]-3.1485} Cadmium, Acute Trout waters WER*{1.136672-[ln hardness](0.041838)} • e^{0.9151[ln hardness]-3.6236} Cadmium, Chronic WER* { 1.101672-[ln hardness](0.041838)} • e^ {0.7998[ln hardness]-4.4451 } Chromium III, Acute WER*0.316 • e^{0.8190[ln hardness]+3.7256} Chromium III, Chronic WER*0.860 • e^{0.8190[ln hardness]+0.6848} Copper, Acute WER*0.960 • e^{0.9422[ln hardness]-1.700} Copper, Chronic WER*0.960 • e^{0.8545[ln hardness]-1.702} Lead, Acute WER*{1.46203-[ln hardness](0.145712)} • e^{1.273[In hardness]-1.460} Lead, Chronic WER*{1.46203-[ln hardness](0.145712)} • e^{1.273[ln hardness]-4.705} Nickel, Acute WER*0.998 • e^{0.8460[ln hardness]+2.255} Nickel, Chronic WER*0.997 • e^{0.8460[ln hardness]+0.0584} Page 1 of 4 Permit No. NC0026441 Silver, Acute WER*0.85 • e^{1.72[ln hardness]-6.59} Silver, Chronic Not applicable Zinc, Acute WER*0.978 • e^{0.8473[ln hardness]+0.884} Zinc, Chronic WER*0.986 • e^{0.8473[In hardness]+0.884} General Information on the Reasonable Potential Analysis (RPA) The RPA process itself did not change as the result of the new metals standards. However, application of the dissolved and hardness -dependent standards requires additional consideration in order to establish the numeric standard for each metal of concern of each individual discharge. The hardness -based standards require some knowledge of the effluent and instream (upstream) hardness and so must be calculated case -by -case for each discharge. Metals limits must be expressed as `total recoverable' metals in accordance with 40 CFR 122.45(c). The discharge -specific standards must be converted to the equivalent total values for use in the RPA calculations. We will generally rely on default translator values developed for each metal (more on that below), but it is also possible to consider case -specific translators developed in accordance with established methodology. RPA Permitting Guidance/WQBELs for Hardness -Dependent Metals - Freshwater The RPA is designed to predict the maximum likely effluent concentrations for each metal of concern, based on recent effluent data, and calculate the allowable effluent concentrations, based on applicable standards and the critical low -flow values for the receiving stream. If the maximum predicted value is greater than the maximum allowed value (chronic or acute), the discharge has reasonable potential to exceed the standard, which warrants a permit limit in most cases. If monitoring for a particular pollutant indicates that the pollutant is not present (i.e. consistently below detection level), then the Division may remove the monitoring requirement in the reissued permit. 1. To perform a RPA on the Freshwater hardness -dependent metals the Permit Writer compiles the following information: • Critical low flow of the receiving stream, 7Q10 (the spreadsheet automatically calculates the 1Q10 using the formula 1Q10 = 0.843 (s7Q10, cfs) 0.993 • Effluent hardness and upstream hardness, site -specific data is preferred • Permitted flow • Receiving stream classification 2. In order to establish the numeric standard for each hardness -dependent metal of concern and for each individual discharge, the Permit Writer must first determine what effluent and instream (upstream) hardness values to use in the equations. The permit writer reviews DMR's, Effluent Pollutant Scans, and Toxicity Test results for any hardness data and contacts the Permittee to see if any additional data is available for instream hardness values, upstream of the discharge. If no hardness data is available, the permit writer may choose to do an initial evaluation using a default hardness of 25 mg/L (CaCO3 or (Ca + Mg)). Minimum and maximum limits on the hardness value used for water quality calculations are 25 mg/L and 400 mg/L, respectively. If the use of a default hardness value results in a hardness -dependent metal showing reasonable potential, the permit writer contacts the Permittee and requests 5 site -specific effluent and upstream hardness samples over a period of one week. The RPA is rerun using the new data. Page 2 of 4 Permit No. NC0026441 The overall hardness value used in the water quality calculations is calculated as follows: Combined Hardness (chronic) = (Permitted Flow, cfs *Avg. Effluent Hardness, mg/L) + (s7Q10, cfs *Avg. Upstream Hardness, mg/L) (Permitted Flow, cfs + s7Q10, cfs) The Combined Hardness for acute is the same but the calculation uses the 1Q10 flow. 3. The permit writer converts the numeric standard for each metal of concern to a total recoverable metal, using the EPA Default Partition Coefficients (DPCs) or site -specific translators, if any have been developed using federally approved methodology. EPA default partition coefficients or the "Fraction Dissolved" converts the value for dissolved metal at laboratory conditions to total recoverable metal at in -stream ambient conditions. This factor is calculated using the linear partition coefficients found in The Metals Translator: Guidance for Calculating a Total Recoverable Permit Limit from a Dissolved Criterion (EPA 823-B-96-007, June 1996) and the equation: Cdiss = 1 Ctotal 1 + { [Kpo] [ SS( i+a)] [10-6] } Where: ss = in -stream suspended solids concentration [mg/1], minimum of 10 mg/L used, and Kpo and a = constants that express the equilibrium relationship between dissolved and adsorbed forms of metals. A list of constants used for each hardness -dependent metal can also be found in the RPA program under a sheet labeled DPCs. 4. The numeric standard for each metal of concern is divided by the default partition coefficient (or site -specific translator) to obtain a Total Recoverable Metal at ambient conditions. In some cases, where an EPA default partition coefficient translator does not exist (ie. silver), the dissolved numeric standard for each metal of concern is divided by the EPA conversion factor to obtain a Total Recoverable Metal at ambient conditions. This method presumes that the metal is dissolved to the same extent as it was during EPA's criteria development for metals. For more information on conversion factors see the June, 1996 EPA Translator Guidance Document. 5. The RPA spreadsheet uses a mass balance equation to determine the total allowable concentration (permit limits) for each pollutant using the following equation: Ca = (s7Q10 + Qw) (Cwqs) — (s7Q10) (Cb) Qw Where: Ca = allowable effluent concentration (µg/L or mg/L) Cwqs = NC Water Quality Standard or federal criteria (µg/L or mg/L) Cb = background concentration: assume zero for all toxicants except NH3* (µg/L or mg/L) Qw = permitted effluent flow (cfs, match s7Q10) s7Q 10 = summer low flow used to protect aquatic life from chronic toxicity and human health through the consumption of water, fish, and shellfish from noncarcinogens (cfs) * Discussions are on -going with EPA on how best to address background concentrations Flows other than s7Q10 may be incorporated as applicable: 1Q10 = used in the equation to protect aquatic life from acute toxicity Page 3 of 4 Permit No. NC0026441 QA = used in the equation to protect human health through the consumption of water, fish, and shellfish from carcinogens 30Q2 = used in the equation to protect aesthetic quality 6. The permit writer enters the most recent 2-3 years of effluent data for each pollutant of concern. Data entered must have been taken within four and one-half years prior to the date of the permit application (40 CFR 122.21). The RPA spreadsheet estimates the 95th percentile upper concentration of each pollutant. The Predicted Max concentrations are compared to the Total allowable concentrations to determine if a permit limit is necessary. If the predicted max exceeds the acute or chronic Total allowable concentrations, the discharge is considered to show reasonable potential to violate the water quality standard, and a permit limit (Total allowable concentration) is included in the permit in accordance with the U.S. EPA Technical Support Document for Water Quality -Based Toxics Control published in 1991. 7. When appropriate, permit writers develop facility specific compliance schedules in accordance with the EPA Headquarters Memo dated May 10, 2007 from James Hanlon to Alexis Strauss on 40 CFR 122.47 Compliance Schedule Requirements. 8. The Total Chromium NC WQS was removed and replaced with trivalent chromium and hexavalent chromium Water Quality Standards. As a cost savings measure, total chromium data results may be used as a conservative surrogate in cases where there are no analytical results based on chromium III or VI. In these cases, the projected maximum concentration (95th %) for total chromium will be compared against water quality standards for chromium III and chromium VI. 9. Effluent hardness sampling and instream hardness sampling, upstream of the discharge, are inserted into all permits with facilities monitoring for hardness -dependent metals to ensure the accuracy of the permit limits and to build a more robust hardness dataset. 10. Hardness and flow values used in the Reasonable Potential Analysis for this permit included: Parameter Value Comments (Data Source) Average Effluent Hardness, mg/L (Total as CaCO3) 95.8 Data provided by Permittee Average Upstream Hardness, mg/L (Total as CaCO3) 39.2 Data provided by Permitte 7Q10 summer (cfs) 0.25 Reported in previous permit Fact Sheet 1Q10 (cfs) 0.21 Calculated in RPA spreadsheet Permitted Flow (MGD) 4.0/6.0 Design flow/expansion tier Date: May 7, 2021 Permit Writer: Gary Perlmutter Page 4 of 4 Siler City WWTP / NC0026441 Mercury Data Statistics (Method 1631E) 2017 2018 2019 2020 # of Samples 1 4 4 3 Annual Average, ng/L 2.0 10.0 2.8 5.2 Maximum Value, ng/L 1.95 30.00 4.47 12.70 TBEL, ng/L 47 WQBEL, ng/L 6.2 3/23/22 WQS = 6 ng/L Facility Name Siler City WWTP / NC0026441 /Permit No. : MERCURY WQBEL/TBEL EVALUATION V:2013-6 Total Mercury 1631E PQL = 0.5 ng/L 7Q10s = Date Modifier Data Entry Value Permitted Flow = 12/12/17 3/20/18 6/12/18 9/11/18 12/18/18 2/14/19 6/11/19 9/10/19 12/10/19 3/10/20 6/9/20 9/14/20 1.95 1.16 5.24 30 3.54 4.47 3.8 2.25 1 1.69 12.7 1.16 FALSE MMP Required 1.95 1.16 5.24 30 3.54 4.47 3.8 2.25 0.5 1.69 12.7 1.16 0.250 4.000 cfs WQBEL = 6.24 ng/L 47 ng/L 2.0 ng/L - Annual Average for 2017 WQBEL< 10.0 ng/L - Annual Average for 2018 2.8 ng/L - Annual Average for 2019 5.2 ng/L - Annual Average for 2020 Siler City WWTP / NC0026441 Mercury Data Statistics (Method 1631E) 2018 2019 2020 2021 # of Samples 4 4 4 5 Annual Average, ng/L 10.0 2.8 4.0 1.0 Maximum Value, ng/L 30.00 4.47 12.70 3.15 TBEL, ng/L 47 WQBEL, ng/L 12.1 3/23/22 WQS = 12 ng/L Facility Name Slier City WWTP / NC0026441 /Permit No. : MERCURY WQBEL/TBEL EVALUATION V:2013-6 Total Mercury 1631E PQL = 0.5 ng/L 7Q10s = Date Modifier Data Entry Value Permitted Flow = 3/20/18 1.16 6/12/18 5.21 9/11/18 30 12/18/18 3.54 2/14/19 4.47 6/11/19 3.8 9/10/19 2.25 12/10/19 < 1 3/10/20 1.69 6/9/20 12.7 9/14/20 1.16 12/8/20 < 1 1/8/21 < 1 3/8/21 < 1 6/22/21 3.15 9/14/21 < 1 12/9/21 < 1 No Limit Required MMP Required 1.16 5.21 30 3.54 4.47 3.8 2.25 0.5 1.69 12.7 1.16 0.5 0.5 0.5 3.15 0.5 0.5 0.090 6.000 cfs WQBEL = 12.12 ng/L 47 ng/L 10.0 ng/L - Annual Average for 2018 2.8 ng/L - Annual Average for 2019 4.0 ng/L - Annual Average for 2020 1.0 ng/L - Annual Average for 2021 1obun of iter Cap Public Works and Utilities February 19, 2021 ANNUAL PRETREATMENT REPORT NARRATIVE NOTICE OF NONCOMPLIANCE Brookwood Farms, Inc. — I.U. 003 Brookwood Farms, Inc. did not have any violations through the Town's monitoring program for the 2020 year. Mountaire Farms, Inc. — I.U. 004 Mountaire Farms, Inc. had one violation through the Town's monitoring program for the 2020 year. This violation was for failure to report weekly BOD for 06/30/2020. Brookwood Farms and Mountaire Farms were issued new pretreatment permits 01/01/2021 and will expire at midnight 12/31/2025. HWA is due this year and will be updated to include Mountaire Farms. There are currently eight dental offices within the Town of Siler City's collection system. Letters along with a one-time compliance report and a dental mercury survey were mailed out 04/30/2020. As of 02/01/2021 only three have filled out and return their forms. Since dental offices were closed most of the year because of Covid, I plan to resend these forms again 04/30/2021. Chris McCorquodale Director of Public Works and Utilities Town of Siler City Chris McCorquodale WWTP Superintendent PO Box 769. 198 Utility Drive Siler City, NC 27344-0769 scwastewater@silercity.org Phone: 919-742-4581 • Fax: 919-742-5499 www.silercity.org To advance a framework for our success through balanced governance, dynamic partnerships, and an engaged community. Reduction in Frequency Evalaution Facility: Siler City WWTP Permit No. NC0026441 Review period (use 3 yrs) 02/2018 - 01/2022 Approval Criteria: Y/N? 1. Not currently under SOC Y 2. Not on EPA Quarterly noncompliance report N 3. Facility or employees convicted of CWA violations N Weekly average limit Monthly average limit 50% MA 3-yr mean (geo mean for FC) < 50%? 200% MA # daily samples > 200% < 15? 200% WA # daily samples >200% < 20? # of non - monthly limit violations > 27 # civil penalty asessment > 1? Reduce Frequency? (Yes/No) BOD (Weighted) mg/L 12.08 6.04 3 2.49 Y 12.1 21 N 7 Y 0 N N TSS mg/L 45 30 15 1.04 Y 60 0 Y 0 N 0 N N Ammonia (weighted) mg/L 18 6 3 0.40 Y 12 0 Y 7 Y 1 N N Fecal Coliform #/100 400 200 100 10.57 Y 800 8 Y 1 N 0 N N Y/N Y/N Y/N **From Y/N **From BIMS Y/N BIMS 3/22/22, 1:31 PM Detailed Facility Report I ECHO I US EPA ECH Enforcement and Compliance History Online Detailed Facility Report Facility Summary SILER CITY WWTP NCSR 1363 US HWY 64, SILER CITY, NC 27344 FRS (Facility,,,Registry,,,Seryi. ID: 110040028332 EPA Region: 04 Latitude: 35.760856 Longitude: -79.462201 Locational Data Source: FRS Industries: -- Indian Country: N Enforcement and Compliance Summary Statute Compliance Monitoring Activities (5 years) Date of Last Compliance Monitoring Activity 5 09/29/2021 Compliance Status .ignificant/Category I Noncompliance Qtrs in Noncompliance (of 12) Qtrs with Significant Violation Informal Enforcement Actions (5 years) Formal Enforcement Actions (5 years) Penalties from Formal Enforcement Actions (5 years) EPA Cases (5 years) Penalties from EPA Cases (5 years) Regulatory Information Other Regulatory Reports 12 5 25 16 $115,427 Clean Air Act (CAA): No Information Air Emissions Inventory (EIS): No Information Clean Water Act (CWA): Major, Permit Expired (NC0026441), Minor, Permit Effective (NCL026441) Greenhouse Gas Emissions (eGGRT): No Information Resource Conservation and Recovery Act (RCRA): No Information Toxic Releases (TRI): No Information Safe Drinking Water Act (SDWA): No Information Compliance and Emissions Data Reporting Interface (CEDRI): No Information https://echo.epa.gov/detailed-facility-report?fid=110040028332 1/7 3/22/22, 1:31 PM Detailed Facility Report I ECHO I US EPA Go To Enforcement/Compliance Details Known Data Problems Facility/System Characteristics Facility/System Characteristics i FRS Statute ICIS-NPDES CWA ICIS-NPDES CWA Facility Address Identifier mil Universe 110040028332 I NC0026441 Major: NPDES Individual Permit NCL026441 Minor: Associated Permit Record Status ' Expired Effective Areas Biosolids, POTW, Pretreatment Biosolids .■ Permit Expiration Date Indian Country Latitude Longitude N 35.760856 -79.462201 05/31/2019 N 35.729722 -79.428056 12/31/2025 N 35.760856 -79.462201 System - FRS ICIS-NPDES Statute CWA Identifier 110040028332 NC0026441 I. Facility Name ICIS-NPDES CWA NCL026441 SILER CITY WWTP SILER CITY WWTP TOWN OF SILER CITY I I NCSR 1363 US HWY 64, SILER CITY, NC 27344 Facility Address 370 WASTE TREATMENT PLANT RD, SILER CITY, NC 27344 _■ Facility County Chatham County PO BOX 769, SILER CITY, NC 27344 Chatham County Chatham County Facility SIC (StandardInd.tstrial,Classification) Codes System ICIS-NPDES NPDES Identifier NC0026441 NC0026441 Facility Industrial Effluent Guidelines SIC Code 4952 4952 - SIC Description Sewerage Systems Sewerage Systems Identifier Effluent Guideline (40 CFR Part) NC0026441 401 Effluent Guideline Description General provisions Enforcement and Compliance Compliance Monitoring History (5 years) Facility NAICS „(North American Industry Classification System) Codes ............... nys=em Identifier Facility Tribe Information NAICS Code No data records returned Reservation Name Tribe Name EPA Tribal ID No data records returned NAICS Description Distance to Tribe (miles) Statute CWA Source ID' _ System NC0026441 ICIS-NPDES CWA CWA CWA CWA NC0026441 NC0026441 NC0026441 NC0026441 CWA NC0026441 ICIS-NPDES ICIS-NPDES ICIS-NPDES ICIS-NPDES Activity Type Inspection/Evaluation Inspection/Evaluation Inspection/Evaluation Inspection/Evaluation ICIS-NPDES Inspection/Evaluation Inspection/Evaluation Compliance Monitoring Type Base Program - Audit Base Program - Evaluation Base Program - Sampling Base Program - Reconnaissance without Sampling Base Program - Evaluation Base Program - Biomonitoring Lead Agency State State 09/29/2021 State State State 08/24/2020 07/21/2020 06/03/2020 05/10/2019 State 03/12/2019 Finding (if applicable) Entries in italics are not counted in EPA compliance monitoring strategies or annual results. Compliance Summary Data Statute CWA CWA Source ID Current SNC.(SignifcantNoncompliance)/HPV (n)gh Pr iority_Viniation) NC0026441 NCL026441 Yes No Current As Of 12/31/2021 12/31/2021 Qtrs with NC (N9pcomliance) (of 12) 12 0 Data Last Refreshed 03/18/2022 03/18/2022 Three -Year Compliance History by Quarter https://echo.epa.gov/detailed-facility-report?fid=110040028332 2/7 3/22/22, 1:31 PM Detailed Facility Report I ECHO I US EPA Statute Progrem/Pallutant/Vloletlon Type QTR 1 QTR 2 QTR 3 QTR 4 QTR S QTR 6 QTR 7 QTR S CWA (Source ID: NC0026441) 01/01-03/31/19 04/01-06/30/19 07/01-09/30/19 10/01-12/31/19 01/01-03/31/20 04/01-06/30/20 07/01-09/30/20 10/01-12/31/20 Facility -Level Status Violation Violation Violation Violation Violation Significant/Category Violation Identified Identified Identified Identified Identified I Noncompliance Identified Quarterly Noncompliance Report Reportable Reportable Reportable Reportable Reportable Effluent - Monthly Reportable Resolved History Noncompliance Noncompliance Noncompliance Noncompliance Noncompliance Average Limit Noncompliance Pollutant Disch Mon Freq Point Loc CWA BOD 5- day 20 deg. C 001 - Effluent Mthly M Gross BOD, 5- day:0 ► CWA deg. C Cadmium total Im CWA CWA ►CWA Coliform fecal MF, MFC broth, 44.5 C Coliform fecal MF, MFC broth, 44.5 C 001 - Effluent NMth M Gross 001 - Effluent Mthly M Gross 001 - Effluent M Gross 001 - Effluent M Gross Flow in conduit or thru ► CWA treatment 001 - Effluent plant M Gross Mthly NMth Mthly 43% 130% 116% 1220% 44% QTR 9 01/01-03/31/21 QTR 10 04/01-06/30/21 QTR 11 07/01-09/30/21 Significant/Category I Noncompliance Significant/Category I Noncompliance Significant/Category I Noncompliance QTR 12 10/01-12/31/21 Significant/Category I Noncompliance Effluent - Monthly Effluent - Monthly Effluent - Monthly Effluent - Monthly Average Limit Average Limit Average Limit Average Limit QTR 13+ 01/01-03/18/22 Violation Identified 146% 14% 197% 12% 71% 132% 253% 37% 188% 55% 876% 505% 16% Nitrogen, ammonia total Im 001 - Effluent CWA d M Gross Mthly 40% 381% 874% 1% 1093% 618% Nitrogen, ammonia ► CWA total as CWA CWA Solids, total sus ended 001 - Effluent NMth M Gross 001 - Effluent NMth M Gross Single Event Violations Agency Permit Violations - State Unapproved Operation 195% 41% 265% 103% 06/03/2020 474% 163% 348% 134% https://echo.epa.gov/detailed-facility-report?fid=110040028332 3/7 3/22/22, 1:31 PM Detailed Facility Report I ECHO I US EPA Statute Program/Pollutant/Violation Type CWA Permit Violations - Unapproved Operation State Late or Missing Discharge Monitoring Report (DMR) Measurements QTR1 QTR2 QTR3 QTR4 QTR5 QTR6 QTR 10 QTR 11 QTR 12 J 09/29/2021 QTR 13+ I Counts of Late DMR Measurements 3 3 33 3 3 3 3 CWA (Source ID: NCL026441) 01/01-03/31/19 04/01-06/30/19 07/01-09/30/19 10/01-12/31/19 01/01-03/31/20 04/01-06/30/20 07/01-09/30/20 10/01-12/31/20 01/01-03/31/21 04/01-06/30/21 07/01-09/30/21 10/01-12/31/21 01/01-03/18/22 Facility -Level Status Quarterly Noncompliance Report History P No Violation No Violation No Violation No Violation No Violation No Violation No Violation No Violation No Violation No Violation No Violation No Vr Identified Identified Identified Identified Identified Identified Identified Identified Identified Midentified I Undetermined Informal Enforcement Actions (5 Years) Statute CWA CWA CWA CWA CWA CWA CWA CWA CWA CWA System ICIS-NPDES ICIS-NPDES ICIS-NPDES ICIS-NPDES ICIS-NPDES ICIS-NPDES ICIS-NPDES ICIS-NPDES ICIS-NPDES ICIS-NPDES Source ID Type of Action Lead Agency NC0026441 Base Program - Notice of Violation State NC0026441 Base Program - Notice of Violation State NC0026441 Base Program - Notice of Violation State NC0026441 Base Program - Notice of Violation State NC0026441 Base Program - Notice of Violation State NC0026441 Base Program - Notice of Violation State NC0026441 Base Program - Notice of Violation State NC0026441 Base Program - Notice of Violation State NC0026441 Base Program - Notice of Violation State NC0026441 Base Program - Notice of Violation State CWA ICIS-NPDES NC0026441 Base Program - Notice of Violation State CWA ICIS-NPDES NC0026441 Base Program - Notice of Violation State CWA CWA CWA CWA CWA ICIS-NPDES ICIS-NPDES ICIS-NPDES ICIS-NPDES ICIS-NPDES CWA CWA CWA CWA CWA CWA CWA ICIS-NPDES ICIS-NPDES ICIS-NPDES ICIS-NPDES ICIS-NPDES ICIS-NPDES ICIS-NPDES CWA ICIS-NPDES NC0026441 Base Program - Notice of Violation State NC0026441 Base Program - Notice of Violation State NC0026441 Base Program - Notice of Violation State NC0026441 Base Program - Notice of Violation State NC0026441 Base Program - Notice of Violation State NC0026441 Base Program - Notice of Violation State NC0026441 Base Program - Notice of Violation State NC0026441 Base Program - Notice of Violation State NC0026441 Base Program - Notice of Violation State NC0026441 Base Program - Notice of Violation State NC0026441 Base Program - Notice of Violation State NC0026441 Base Program - Notice of Violation State NC0026441 Base Program - Notice of Violation State Date 02/24/2022 12/10/2021 11/15/2021 11/09/2021 11/01/2021 10/13/2021 09/30/2021 06/01/2021 05/26/2021 12/29/2020 09/22/2020 08/11/2020 07/29/2020 07/14/2020 06/15/2020 05/06/2020 02/05/2020 09/27/2019 09/17/2019 02/26/2019 04/13/2018 02/09/2018 02/06/2018 01/25/2018 07/13/2017 Entries in italics are not counted as "informal enforcement actions" in EPA policies pertaining to enforcement response tools. Formal Enforcement Actions (5 Years) Statute CWA CWA CWA System Law/Section Si ICIS- NPDES ICIS- L NPDES ICIS- NPDES OTHER NPDES/NC0026441 OTHER NPDES/NC0026441 OTHER NPDES/NC0026441 Type of Action Administrative - Formal Administrative - Formal Administrative - Formal I Lead Agency NC-LV-2022- State 0041 NC-LV 2021- 0342 NC-LV-2021- 0341 State State Case Name Town of Siler City Town of Siler City Town of Siler City I_ Ie Settlement/Action ed/Filed Settlements/Actions Date Date 02/21/2022 12/15/2021 12/15/2021 02/21/2022 12/15/2021 1 12/15/2021 Federal Penalty Assessed SO $0 $0 State/Local Penalty Penalty Amount SEP Comp Action Assessed Collected Cost Cost $18,044 $16,294 $0 SO $0 SO $10,044 -- $0 $0 https://echo.epa.gov/detailed-facility-report?fid=110040028332 4/7 3/22/22, 1:31 PM Detailed Facility Report I ECHO I US EPA Statute System Law/Section Source ID CWA CWA ICIS- NPDES ICIS- NPDES CWA ICIS- NPDES CWA ICIS- NPDES CWA CWA CWA ICIS- NPDES ICIS- NPDES ICIS- NPDES CWA CWA ICIS- NPDES ICIS- NPDES CWA CWA CWA ICIS- NPDES ICIS- NPDES ICIS- NPDES OTHER I NPDES/NC0026441 OTHER NPDES/NC0026441 OTHER NPDES/NC0026441 OTHER I NPDES/NC0026441 OTHER NPDES/NC0026441 OTHER NPDES/NC0026441 OTHER NPDES/NC0026441 OTHER NPDES/NC0026441 OTHER NPDES/NC0026441 OTHER NPDES/NC0026441 OTHER NPDES/NC0026441 OTHER I NPDES/NC0026441 Type of Action Administrative - Formal Administrative - Formal Administrative - Formal Administrative - Formal Administrative - Formal Case No. NC-LV 2021- 0338 Lead Agency State NC-LV 2021- 0339 NC-LV 2021- 0279 NC-PC-2020- 0045 NC-LV 2021- 0031 Administrative - Formal Administrative - Formal Administrative - Formal Administrative - Formal NC-LV 2020- 0338 NC-LV 2020- 0294 NC-LV 2020- 0292 NC-LV 2020- 0194 Administrative - NC-LV 2020- Formal 0127 State State State State Case Name Town of Siler City Town of Siler City Town of Siler City Town of Suter City Town of Slier City Issued/Filed Date 11/22/2021 11/22/2021 11/15/2021 08/27/2021 02/15/2021 Settlements/Actions l 1 1 1 Settlement/Action Federal Penalty State/Local Penalty Penalty Amount SEP Comp Action Date Assessed Assessed Collected Cost Cost 11/22/2021 11/22/2021 11/15/2021 08/27/2021 02/15/2021 State State State State State Administrative - NC-LV 2018- Formal 0193 Administrative - NC-LV 2018- Formal 0084 State State Town of Siler City 11/23/2020 Town of Siler City Town of Siler City Town of Suter City Town of Siler City 10/19/2020 10/12/2020 07/15/2020 07/01/2020 Town of Siler City 08/08/2018 1 1 11/23/2020 1 1 10/19/2020 10/12/2020 07/15/2020 07/01/2020 08/08/2018 Town of Siler City 04/13/2018 1 04/13/2018 $0 $0 $0 $0 $0 $0 $0 $0 $0 $0 $0 $0 $6,919 $981 $18,481 $20,044 $1,544 $8,544 $4,292 $2,542 $1,542 $1,542 $1,538 $1,538 $0 $0 $0 $0 $0 $0 $0 $0 $0 $0 $0 $0 $0 $0 $0 $0 $0 $0 $0 $0 $0 $0 $0 $0 CWA ICIS- NPDES OTHER NPDES/NC0026441 Administrative - Formal Environmental Conditions Watersheds NC-LV 2018- 0075 State Town of Siler City 04/12/2018 04/12/2018 $0 $1,538 $0 $0 12-Digit WBD,(Watershed Boundary Dataset) HUC (RAD (Reach Address Database)) ...................... 030300030502 030300030503 WBD (WatershedBoundary„Dataset) Subwatershed Name each s Database Address (BAD (R......... ......................)) State Water Body Name (ICIS(Integrated Compliance Information System)) Beach Closures Within Last Year Lacys Creek -Rocky River -- No Loves Creek -Rocky River LOVES CREEK No Beach Closures Within Last Two Years No No Pollutants Potentially Related to Impairment BOD, 5-day, 20 deg. C Oxygen, dissolved (DO) Watershed with ESA (Endangered Species Act) -listed Aquatic Species? Yes Ycs Assessed Waters From Latest State Submission (ATTAINS) State Report Cycle NC 2020 NC 2020 NC 2020 Assessment Unit ID NC17-43-10b1 NC 17-43-10c NC 17-43-10b2 Assessment Unit Name Loves Creek Loves Creek Loves Creek Water Condition Cause Groups Impaired ■ Impaired - 303(d) Listed - With Restoration Plan ORGANIC ENRICHMENT/OXYGEN DEPLETION Impaired - 303(d) Listed - With Restoration Plan Impaired - 303(d) Listed - With Restoration Plan CAUSE UNKNOWN - IMPAIRED BIOTA CAUSE UNKNOWN - IMPAIRED BIOTA Drinking Water Use Aquatic Life -- Not Supporting -- Not Supporting -- Not Supporting Fish Consumption Use Fully Supporting Recreation Use Insufficient Information Insufficient Information Other Use Fully Supporting Air Quality Nonattainment Areas Within Nonattainment Status Area? Nonattainment Status Applicable Standard(s) Within Maintenance Status Area? No data records returned Pollutants Toxics Release Inventory History of Reported Chemicals Released in Pounds per Year at Site Maintenance Status Applicable Standard(s) TRI Facility ID Year Total Air Emissions Surface Water Discharges Off -Site Transfers to POTWs.(Ppbltcly_Owned t:gatmeat-Works) Underground Injections Releases to Land Total On -Site Releases Total Off -Site Transfers No data records returned https://echo.epa.gov/detailed-facility-report?fid=110040028332 5/7 3/22/22, 1:31 PM Toxics Release Inventory Total Releases and Transfers in Pounds by Chemical and Year Detailed Facility Report I ECHO I US EPA Chemical Name Community EJSCREEN EJ Indexes No data records returned Eleven environmental justice (EJ) indexes of EJSCREEN, EPA's screening tool for EJ concerns. EPA uses these indexes to identify geographic areas that may warrant further consideration or analysis for potential EJ concerns. The index values below are for the Census block group in which the facility is located. Note that use of these indexes does not designate an area as an "EJ community" or "EJ facility." EJSCREEN provides screening level indicators, not a determination of the existence or absence of EJ concerns. For more information, see the EJSCREEN home page. Census Block Group EJ Indexes (percentile) Particulate Matter (PM 2.5) Ozone NATA Diesel PM NATA Air Toxics Cancer Risk NATA Respiratory Hazard Index (HI) Traffic Proximity Lead Paint Indicator National Priority List (NPL) Site Proximity Risk Management Plan (RMP) Site Proximity Hazardous Waste Proximity Wastewater Discharge Proximity 92 93.6 81 92.4 91.7 80.3 82.4 75.2 94.1 65.9 94.8 Demographic Profile of Surrounding Area (1 mile) Number of EJ Indexes Above 80th Percentile 9 View EJSCREEN Report This section provides demographic information regarding the community surrounding the facility. ECHO compliance data alone are not sufficient to determine whether violations at a particular facility had negative impacts on public health or the environment. Statistics are based upon the 2010 U.S. Census and 2014 - 2018 American Community Survey (ACS) 5-year Summary and are accurate to the extent that the facility latitude and longitude listed below are correct. EPA's spatial processing methodology considers the overlap between the selected radii and the census blocks (for U.S. Census demographics) and census block groups (for ACS demographics) in determining the demographics surrounding the facility. For more detail about this methodology, see the DFR Data Dictionary. General Statistics (U.S. Census) Elsa Total Persons Population Density Housing Units in Area 425 141/sq.mi. 174 General Statistics (ACS..(Americap_Commugity_Survey)) Total Persons Percent People of Color Households in Area Households on Public Assistance Persons With Low Income Percent With Low Income 1,258 77% 417 0 598 48% Radius of Selected Area Center Latitude Center Longitude Land Area Water Area 1 mi. 35.760856 -79.462201 98% 2% Income Breakdown (ACS..(Americap_CommuoitySuwey)) - Households CM Less Less than $15,000 70 (16.83%) Age Breakdown (U.S. Census) - Persons (%) Children 5 years and younger Minors 17 years and younger Adults 18 years and older Seniors 65 years and older 37 (9%) 126 (30%) 299 (70%) 41 (10%) Race Breakdown (U.S. Census) - Persons (%) White African -American Hispanic -Origin Asian/Pacific Islander American Indian Other/Multiracial 253 (60%) 97 (23%) 114 (27%) 2 (0%) 2 (0%) 72 (17%) Education Level (Persons 25 & older) (AC5„(Amet7e8n, Community,.. prygy)) - Persons Less than 9th Grade 9th through 12th Grade High School Diploma Some College/2-year B,S./B.A. (Bachelor of Science/Bachelor of Arts.) or More _............................................................................................ 167 (23.89%) 71 (10.16%) 173 (24.75%) 202 (28.9%) 85 (12.16%) https://echo.epa.gov/detailed-facility-report?fid=110040028332 6/7 3/22/22, 1:31 PM Detailed Facility Report I ECHO I US EPA Income Breakdown(ACS..(American_CommunitySurvey)) - Households (%) $15,000 - $25,000 $25,000 - $50,000 $50,000 - $75,000 Greater than $75,000 72 (17.31%) 107 (25.72%) 80 (19.23%) 87 (20.91 %) LAST UPDATED ON MARCH 18, 2022 DATA REFRESH INFORMATION https://echo.epa.gov/detailed-facility-report?fid=110040028332 7/7 DocuSign Envelope ID: 89DD9E16-4D1 C-431 D-B97B-602931 B3912E ROY COOPER Governor ELIZABETH S. BISER Secretary S. DANIEL SMITH Director David Honeycutt, P.E. McGill Associates, PA 5 Regional Circle, Suite A Pinehurst, North Carolina 28734 Dear Mr. Honeycutt: NORTH CAROLINA Environmental Quality December 10, 2021 Subject: Speculative Effluent Limits Siler City WWTP NC0026441 Chatham County Cape Fear River Basin This letter provides speculative effluent limits for expanding the WWTP serving Siler City located on Loves Creek with a proposed flow of 6.0 MGD. These speculative limits replace the September 17, 2021 speculative limits to incorporate changes made at the request of the City to increase the weekly average limit for organic nitrogen and corrects an error in seasonal loading. Please recognize that any future speculative limits requests may change based on future water quality initiatives. Receiving Streams. Loves Creek is located within the Cape Fear River Basin. Loves Creek has a stream classification of C, and waters with this classification have a best usage for aquatic life propagation and maintenance of biological integrity, wildlife, secondary recreation, and agriculture. Loves Creek has a summer 7Q10 flow of 0.0 cfs, a winter 7Q10 flow of 0.23 cfs, a 30Q2 flow of 0.32 cfs, and an annual average flow of 7.4 cfs. Loves Creek is currently listed as an impaired waterbody on the 2020 North Carolina 303(d) Impaired Waters List for exceeding benthic criteria. There are no specific permitting strategies or TMDL for this stream. Loves Creek is also part of the Middle Cape Fear River Basin, many segments of which suffer from Chlorophyll -a impairment due to excess nutrients. Nutrient criteria development and modeling are currently underway to address these impairments and may affect future permit limits. Based upon a review of information available from the North Carolina Natural Heritage Program Online Map Viewer, there are Federally Listed threatened or endangered aquatic species identified within a 5-mile radius of the proposed discharge location. If there are any identified threatened/endangered species, it is recommended that the applicant discuss the proposed project with the US Fish and Wildlife Service to determine whether the proposed discharge location might impact such species. NOCTH CAROLINA 1 E Department of EnvInnmenpl Duel` North Carolina Department of Environmental Quality Division of Water Resources 512 North Salisbury Street 11617 Mail Service Center I Raleigh, North Carolina 27699-1617 919.707.9000 DocuSign Envelope ID: 89DD9E16-4D1 C-431 D-B97B-60293183912E Speculative Effluent Limits. Based on Division review of receiving stream conditions and prior water quality modeling results, speculative limits for an expansion to 6.0 MGD are presented in Table 1. A complete evaluation of these limits and monitoring requirements for metals and other toxicants, as well as potential instream monitoring requirements, will be addressed upon review of the formal NPDES permit application which is under review. Some features of the speculative limit development include the following: • BOD/NH3/TSS Limits. Assimilative capacity to protect the instream dissolved oxygen standard of 5.0 mg/L is based on prior stream modeling which showed that the receiving stream's dissolved oxygen is sensitive to organic nitrogen. Seasonal BOD limits from the prior speculative limits were dropped to comply with 15A NCAC 2B .0404. The resultant limits are considered technologically feasible. • Total Nitrogen Load Limits. The annual load is based on the June 2020 Settlement Agreement between Siler City, the Division, and the Rocky River Watch based on a treatment level of 3.0 mg/L of Total Nitrogen to protect the Rocky River watershed and Middle Cape Fear River Basin from Chlorophyll -a impacts. Please note that there is nutrient criteria development and modeling of the basin which may result in stricter limits than those found in Table 1 (at some time in the future). TABLE 1. Speculative Limits for Siler City WWTP proposed expansion. Effluent Characteristic Effluent Limitations Monthly Average Weekly Average Daily Maximum Flow 6.0 MGD BOD5 5.0 mg/L 7.5 mg/L NH3 as N (Apr. -Oct.) 1.0 mg/L 3.0 mg/L NH3 as N (Nov. -Mar.) 1.8 mg/L 5.4 mg/L Dissolved Oxygen (minimum daily average) 7.0 mg/L Organic Nitrogen (Apr. -Oct.) 3.0 mg/L 4.5 mg/L Total Phosphorus (Apr -Sept.) 0.5 mg/L (quarterly average) Total Phosphorus (Oct -Mar.) 2.0 mg/L (quarterly average) Total Nitrogen Load 54,800 lbs/year 1 TSS 20 mg/L 30 mg/L TRC 17 µg/L Fecal coliform (geometric mean) 200/100 mL 400/100 mL Chronic Toxicity Pass/Fail (Quarterly test) 90% 1. Equivalent to a 3.0 mg/L concentration (on an Annual basis). Monitor and report pounds per month. 2. The total phosphorus requirements will be consistent with the existing permit. NORTH Department of Emim.mmrt.i au.nq North Carolina Department of Environmental Quality I Division of Water Resources 512 North Salisbury Street 11617 Mail Service Center I Raleigh, North Carolina 27699-1617 919.707.9000 DocuSign Envelope ID: 89DD9E16-4D1C-431D-B97B-602931B3912E Engineering Alternatives Analysis (EAA). Please note that the Division cannot guarantee that an NPDES permit for a new or expanding discharge will be issued with these speculative limits. Final decisions can only be made after the Division evaluates the formal permit application for the expanded discharge. In accordance with North Carolina Administrative Code 15A NCAC 2H.0105(c), the most environmentally sound alternative should be selected from all reasonably cost-effective options. Therefore, as a component of all NPDES permit applications for new or expanding flow, a detailed engineering alternatives analysis (EAA) must be prepared (in this case we have this information which is under review). The EAA must justify requested flows and provide an analysis of potential wastewater treatment alternatives. State Environmental Policy Act (SEPA) EA/EIS Requirements. A SEPA EA/EIS document may be required for projects that: 1) involve $10 Million or more of state funds; or 2) will significantly and permanently impact 10 or more acres of public lands. Please check with the DWR SEPA coordinator (David Wainwright, 919-707-9045) as to whether your project requires SEPA review. For projects that are subject to SEPA, the EAA requirements discussed above will need to be folded into the SEPA document. Additionally, if subject to SEPA, the NPDES Unit will not accept an NPDES permit application for a new/expanding discharge until the Division has approved the SEPA document and sent a Finding of No Significant Impact (FONSI) to the State Clearinghouse for review and comment. Should you have any questions about these speculative limits or NPDES permitting requirements, please feel free to contact David Hill at david.hill@ncdenr.gov or (919) 707- 3612. Respectfully, r6DocuSigned AAo������by: o1. �'e.'' ` C464531431644FE... Michael Montebello Supervisor, NPDES Municipal Permitting Unit Electronic Copy: NC WRC, Eastern Piedmont Coordinator, gabriela.garrison@ncwildlife.org US Fish and Wildlife Service, sara_ward@fws.gov DWR/Water Quality Regional Office/Raleigh/Scott Vinson DWR/Basinwide Planning/Nora Deamer DWR/Modeling and Assessment Branch/Pam Behm Siler City: Roy Lynch (rlynch@silercity.org), Chris McCorquodale (cmccorquodale@silercity.org) SELC: Blakely Hildebrand (bhildebrand@selcnc.org) , Jean Zhuang (jzhuang@selc.org) NORTH Department of Emimemmrt.i au.nq North Carolina Department of Environmental Quality I Division of Water Resources 512 North Salisbury Street 11617 Mail Service Center I Raleigh, North Carolina 27699-1617 919.707.9000 DocuSign Envelope ID: A3DD6EC1-8A1 F-4231-A273-E5DFD8FBD986 ROY COOPER Governor ELIZABETH S. BISER Secretary S. DANIEL SMITH Director David Honeycutt, P.E. McGill Associates, PA 5 Regional Circle, Suite A Pinehurst, North Carolina 28734 Dear Mr. Honeycutt: NORTH CAROLINA Environmental Quality March 15, 2022 Subject: Revised Expansion Schedule Review Permit NC0026441 Siler City WWTP Chatham County The Divisions of Water Resources (DWR) has reviewed the revised schedule for the expansion of Siler City WWTP to 6.0 MGD, submitted on February 16, 2022 (attached). After consulting with the Division of Water Infrastructure and Rocky River Watch, DWR hereby approves the schedule revision pursuant to Paragraph 3.b. of the Settlement Agreement between DWR, the Town of Siler City and Rocky River Watch dated June 5, 2020, the Divisions and Rocky River Watch find the proposed expansion schedule revision acceptable. Thank you for your continued cooperation with the NPDES program. If you have any questions or comments, please contact, Gary Perlmutter, Environmental Specialist II, DWR at gary.perlmutter@ncdenr.gov or 919-306-1017 (cell). Sincerely, LDocuSigned b/y�:, L tt 14-4014d C464531431644FE... Michael Montebello Supervisor, NPDES Municipal Permitting Unit eCopy: NCDEQ / DWI / Jonathan Risgaard and Ken Pohlig Siler City: Roy Lynch (rlynch@silercity.org) and Chris McCorquodale (cmmc orquodale(a, silercity. org) SELC: Blakely Hildebrand (bhildebrand@selc.org) and Jean Zhuang (j zhuang@ selc. org) =D.E NORTH CAROLINA Department of Environmental Duality North Carolina Department of Environmental Quality I Division of Water Resources 512 North Salisbury Street 11617 Mail Service Center I Raleigh, North Carolina 27699-1617 919.707.9000 DocuSign Envelope ID: A3DD6EC1-8A1 F-4231-A273-E5DFD8FBD986 From: To: Subject: Date: Dunn, Glenn Blakely Hildebrand; Jean Zhuanq; Perlmutter, Gary; mike.montebelloPncdenr.gov [External] FW: Slier City WWTP Schedule Request Wednesday, February 16, 2022 10:11:22 AM CAUTION: External email. Do not click links or open attachments unless you verify. Send all suspicious email as an attachment to Report Spam. I am forwarding to you the proposed revised upgrade schedule that David Honeycutt and the Town propose . As you suggested at our meeting week before last , some margin has been built in . After you review it , please let me know whether you find it acceptable .Regarding the proposed plan for managing BOD and ammonia , unfortunately it is more complex than originally thought and David is working with Chris and Brittany on additional measures and we hope to let you know more soon . we're sorry about the delay . NPDES Permit Modification Public Notice NPDES Permit Modification Issuance Complete Design and submit Authorization to Construct Permit to NCDEQ Authorization to Construct Permit Approval 2022 Award Construction Contract for 6 MGD Expansion Complete Construction of 3rd Treatment Train with a capacity of 2 MGD Complete Construction of 6 MGD Expansion 2024 Total Nitrogen limit of 54,800 Ibs/year effective mcgill Shaping Communities Together ® David Honeycutt, P.E. Principal/Pinehurst Office Manager McGill Associates, PA 5 Regional Circle, Suite A, Pinehurst, NC 28374 T 910.295.3159 C 910.690.2583 david.honeycutt@mcgillassociates.com mcgillassociates.com ********* March 2022 April 30, 2022 August 1, 2022 December 31, April 30, 2023 April 30, 2024 December 31, January 1, 2025 This message constitutes a confidential attorney -client communication. If you have received this communication in error, do not read it. It is not intended for transmission to, or receipt by, any unauthorized persons. Please delete it from your system without copying it, and notify the sender by reply email or by February 28, 2022 Mr. Gary Perlmutter, Environmental Specialist NCDEQ/Division of Water Resources NPDES Municipal Permitting Unit 1617 Mail Service Center Raleigh, North Carolina 27699-1617 RE: Town of Siler City Siler City WWTP NPDES Permit Renewal — Chemical Addendum Permit No. NC0026441 Dear Mr. Perlmutter: As a supplement to the Siler City Wastewater Treatment Plant NPDES Application package that is currently under review the Town of Siler City is submitting additional information per Session Law 2018-5, Senate Bill 99, Section 13.1 (r). At the request of the Division of Water Quality (DEQ), the Town conducted WWTP effluent sampling during the months of July, August, and September of 2019 for 1,4 Dioxane and PFAS. The analysis for 1,4 Dioxane was done in accordance with EPA Method 624.1 which is a certified method in 40 CFR Part 136. The Analysis for PFAS was done in accordance with EPA Draft Method 1633. This PFAS Sampling method is not certified. The following three attachments are being provide as a supplement to the Siler City WWTP NPDES Permit: • Attachment 1: Chemical Addendum to NPDES Application • Attachment 2: Lab Report Summary Data from PFAS Sampling Results • Attachment 3: Lab Report Summary Data from 1,4 Dioxane Sampling Results If you have any questions or require further information regarding this project please let us know. Sincerely, TOWN OF SILER CITY ROY LYNCH Town Manager Enclosures EPA Identification Number NPDES Number Facility Name Outfall Number Estimated Concentration (If Known) FRS ID: 110022547243 Pollutant (Required) NC 0026441 CAS number Method Number (if Applicable) Town of Siler City WWTP Reason Pollutant Believed 001 Present in Discharge PFBA 375-22-4 1633 (Not Detected) PFPeA 2706-90-3 1633 Effluent Sampling Results (July, August, September 2019) Median of three influent sampling events (July, August, and September 2019) was 13.75 ng/L PFHxA 307-24-4 1633 Effluent Sampling Results (July, August, September 2019) Median of three influent sampling events (July, August, and September 2019) was 6.15 ng/L PFHpA 375-85-9 1633 Effluent Sampling Results (July, August, September 2019) Median of three influent sampling events (July, August, and September 2019) was 2.05 ng/L PFOA 335-67-1 1633 Effluent Sampling Results (July, August, September 2019) Median of three influent sampling events (July, August, and September 2019) was 4.02 ng/L PFNA 375-95-1 1633 (Not Detected) PFDA 335-76-2 1633 (Not Detected) PFUnA 2058-94-8 1633 (Not Detected) PFDoDA 307-55-1 1633 (Not Detected) PFTrDA 72629-94-8 1633 (Not Detected) PFTeDA 376-06-7 1633 (Not Detected) L-PFBS 375-73-5 1633 (Not Detected) PFPeS 2706-91-4 1633 (Not Detected) PFHxS 355-46-4 1633 Effluent Sampling Results (July, August, September 2019) Median of three influent sampling events (July, August, and September 2019) was 1.73 ng/L PFHpS 375-92-8 1633 (Not Detected) PF05 1763-23-1 1633 Effluent Sampling Results (July, August, September 2019) Median of three influent sampling events (July, August, and September 2019) was 3.89 ng/L PFNS 68259-12-1 1633 (Not Detected) PFDS 335-77-3 1633 (Not Detected) PFOSA 754-91-6 1633 (Not Detected) N-MeFOSAA 2355-31-9 1633 (Not Detected) N-EtF05AA 2991-50-6 1633 (Not Detected) 1,4 Dioxane 123-91-1 EPA 624.1 Effluent Sampling Results (July, August, September 2019) Median of three influent sampling events (July, August, and September 2019) was 1.3 Ug/L I certify that to the best of my knowledge all analytical data presented in this report: • Have been checked for completeness • Are accurate, error -free, and legible • Have been conducted in accordance with approved protocol, and that all deviations and analytical problems are summarized in the appropriate narrative(s) This analytical report was prepared in Portable Document Format (.PDF) and contains 26 pages. QA ' iew Performed by: Juanica L. Thomas r. lira "4- ENTHALPY Report Issued Date: 08/09/19 EU # 0719-708R 2 of 26 �� ENTHALPY Summary of Results: PFAS Enthalpy Ultratrace Batch # 10383 PFAS Analyte Method Blank Effluent ng/L ng/L Acids PFBA NDU ND U PFPeA 2.21 J 14.5 B PFHpA 3.39 9.94 B PFHpA NDU 2.101 PFOA ND U 5.49 PFNA NDU ND U PFDA NDU ND U PFUnA NDU ND U PFDoA NDU ND U PFTrA NDU ND U PFTA NDU ND U Sulfonates L-PFBS NDU ND U PFPeS NDU ND U PFHxS NDU 2.001. PFHpS NDU ND U PFOS ND U 5.66 PFNS NDU ND U PFDS NDU ND U Other PFOSA NDU ND U N-MeFOSAA NDU ND U N-EtFOSAA ND U ND U Lab Sample ID LMB_10383 0719-708_10383_001R EU # 0719-708R 4 of 26 a) U E a, m m 8 m ti 0 F- N I certify that to the best of my knowledge all analytical data presented in this report: • Have been checked for completeness • Are accurate, error -free, and legible • Have been conducted in accordance with approved protocol, and that all deviations and analytical problems are summarized in the appropriate narrative(s) This analytical report was prepared in Portable Document Format (.PDF) and contains 25 pages. Associate II iew Performed by: Juanica L. Thomas ,,,,„,10. ba 40_ ENTHALPY Report Issued Date: 09-10-19 EU # 0819-709 2 of 25 101;1 ENTHALPY ___. ANALYTICAL Summary of Results: PFAS Enthalpy Ultratrace Batch # 10443 PFAS Analyte Method Blank ng/L Effluent ng/L Acids PFBA NDU ND U PFPeA ND U 13.0 PFHxA NDU 5.89 J PFHpA NDU 0.717 J PFOA ND U 4.02 J PFNA NDU ND U PFDA NDU ND U PFUnA NDU ND U PFDoA NDU ND U PFTrA NDU ND U PFTA NDU ND U Sulfonates L-PFBS NDU ND U PFPeS NDU ND U PFHpS NDU ND U PFHpS NDU ND U PFOS NDU 3.841 PFNS NDU ND U PFDS NDU ND U Other PFOSA NDU ND U N-MeFOSAA NDU ND U N-EtFOSAA ND U ND U Lab Sample ID MB_10443 0819-709_10443_001 EU # 0819-709 4 of 25 og-9 Special Handling: ,0'Sitandard Turn Around Time ❑ Rush Turn Around Time — Date Needed • All Fast TATs Subject to Approval by Enthalpy Analytical, Inc. • All Samples Disposed of After 6 months Unless Otherwise Instructed. Enthalpy Analytical -Wilmington, NC has added enhancements to standard methods to improve accuracy, precision and permit an assessment of laboratory performance in the Context of your specific data needs. For more information email CindyJames@enthalpy.com. This Chain of Custody is applicable to Non -Air samples. Standard TAT differ per analysis and are provided by request. Notes: e tif Sample Temperature Upon Receipt p� feed o'Ambient °C o Iced ❑ Ambient °C Iced ❑ Ambient °C (i3 T 2714 Exchange Drive • Wilmingtcki, NC 28405 • (910) 12-5858 • www.enthalpy.com 1 PO#: Telephone#: Email: J-') h I (C P10H uo aid weS m SW21H/3021H Aq sHVd a SW/SW/01 A9 SVdd 80d 0/8/V9991. Poglaj 06Z8 Poinew `- E R.'a 0 M ii £691• PONI3W ro- tr- lel `,iji a_ Chain of Custody Record ENTHAIILPY Enthalpy Ultratrace Job#: COC Page of 12 c 'o Received/By: )��`,) U'N. i y Project Number: Site Name: ,Oa L( Location: ° U Ja430 # I saer;o # saillog to # OS 'Client Special Instructions: Matrix: GW-Groundwater, WW-Wastewater, NW -Non -Potable Water, DW-Drinking Water, S-Soil, SL-Sludge, BT- Biological Tissue, O-Other Type: G=Grab C=Composite Q=Quality Control x F Sample Volume 0 ('F li` °J i V .� y ... 1 iN y Client Name: UJ5 Tf Project Manager: Report To: -7(C-DO.i� of - E E i= l3� I c Relinquished By: r1 'ill 0- t Sample ID w D 4 III L a k t I certify that to the best of my knowledge all analytical data presented in this report: • Have been checked for completeness • Are accurate, error -free, and legible • Have been conducted in accordance with approved protocol, and that all deviations and analytical problems are summarized in the appropriate narrative(s) This analytical report was prepared in Portable Document Format (.PDF) and contains 33 pages. ENTHALPY QA Revie Performed by: Bryan A. Vi Report Issued Date: 01 OCT 19 EU#0919-711 Page 2 of 33 '� ENTHALPY Summary of Results: PFAS Enthalpy Ultratrace Batch # 10463 PFAS Analyte Method Blank ng/L Effluent ng/L Acids PFBA NDU ND U PFPeA NDU ND U PFHxA NDU 6.15 PFHpA NDU 2.05 PFOA ND U 3.71 PFNA NDU ND U PFDA NDU ND U PFUnA NDU ND U PFDoA NDU ND U PFTrA NDU ND U PFTA 0.594J ND U Sulfonates L-PFBS NDU ND U PFPeS PFHxS NDU NDU ND U 1.46J PFHpS NDU ND U PFOS ND U 3.89 PFNS NDU ND U PFDS NDU ND U Other PFOSA NDU ND U N-MeFOSAA NDU ND U N-EtFOSAA ND U ND U Lab Sample ID MB_10463 0919 711_10463_001R EU#0919-711 Page 4 of 33 pecial Handling: Standard Turn Around Time ❑ Rush Turn Around Time — Date Needed • All Fast TATs Subject to Approval by Enthalpy Analytical, Inc. • All Sam les Disposed of After 6 months Unless Otherwise Instructed. Enthalpy Analytical.Wllmington,NC has added enhancements to standard methods to improve accuracy, I precision and permit an assessment of laboratory performance in the context of your specific data needs. For more information email CindyJames@enthalpy.com. This Chain of Custody is applicable to Non -Air samples. Standard TAT differ per analysis and are provided by request. Notes: Sample Temperature Upon Receipt ❑ Iced ❑ Ambient °C 2G.* U 0 c a) 16 Q 0) U 10 0 Iced ❑ Ambient °C (l• L`' I,y 4-€tr4 2714 Exchange Drive • Wilmington, NC 28405 • (910) 212-5858 • www.enthalpy.com y PO#: Telephone#: Email: b17,1/ �''->,1-t-rvC"; -y,OGy-7 1 wok uo aidweS a) SW>H/OONH /:Q SHtld a a SW/SW/O1 A4 SVAd \, 93d 0/9/V9991. po41a1R1 06Z8 Po41MW E ( — £196 Po41eW Chain of Custody Record ENTHALPY Enthalpy Ultratrace Job#: _ COC Page of ai t 6. is Project Number: (' " Site Name: _5r�P r fi r+t (.L: Location: /Ci m c I at V., o o u Ja410 # m I. I s6e9 to # saef to # samo9 jo # c'a Client Special Instructions: Matrix: GW-Groundwater, WW-Wastewater, NW -Non -Potable Water, DW-Drinking Water, S-Soil, SL-Sludge, eT- Biological Tissue, O-Other Type: G=Grab C=Composite Q=Quality Control Matrix j Client Name: 5: i t% !'t LA.; Project Manager: Report To: trZ.n 't C?, I j Sample Volume a a- E VI 11 Relinquished By: m o lii Cr- T 1 Sample ID cr- sZt aJ In A .Q 4 Meritech, Inc. Environmental Laboratory Laboratory Certification No. 165 Contact: Bobbie Hill Client: Town of Siler City 198 Utility Dr Siler City, NC 27344 Report Date: NPDES#: Date Sample Rcvd: 7/18/2019 NC0026441 7/9/2019 Meritech Work Order # 07091982 Parameters Cadmium, total Results <0.002 mg/L Sample: Effluent Composite Analysis Date 7/11/19 Reporting Limit 0.002 mg/L 7/8-9/19 Method EPA 200.7 Meritech Work Order # 07091983 Parameters 1,4 Dioxane + Trip Blank Results Attached Sample: Effluent Grab Analysis Date 7/11/19 Reporting Limit 7/9/19 Method EPA 624.1 I hereby certify that 1 have reviewed and approve these data. Laboratory Representative 642 Tamco Road, Reidsville, North Carolina 27320 tel.(336)342-4748 fax.(336)342-1522 Client: Project: Client Sample ID: Sample Collection: MERITECH, INC. Town of Suter City 1,4 Dioxane Effluent 07/09/19 Environmental Laboratories Laboratory Certification #165 Meritech ID#: Analysis: Analyst: Dilution Factor: Report Date: EPA 624.1 VOLATILE ORGANICS Parameter 1,4-Dioxane (p-Dioxane) Trip Blank Batch Blank = Below Reporting Limit Internal Standards method criteria acceptable Surrogate Recoveries Toluene-d8 Bromofluorobenzene Spike Conc 30 ug/L 30 ug/L * - If "no" is selected, see second page for details. I hereby certify that I have reviewed and approve these data. Result 1.30 ug/L < 1,00 ug/L (Yes ) / No (Yes) / No 07091983 07/11/19 VWV 1 07/15/19 Spike Recovery Limits 94% 99% 67-151% 45-161% Laboratory Rep ve 642 Tamco Road * Reidsville, NC 27320 (336) 342-4748 * info@meritechlabs.com R \ » / rt 2 m Sample Location and/or ID # 8/9/18 Chain of Custody Record (COC) Q Hand Delivery ° , sal ✓lethod of >hipment: .m MERIT ENVIRONMEP E;. 642 Tamco Rd. Reidsville NC 27320 Email: info( www.meritech \ \ P , Relinquished by:. _J y--m / 4eSe:, _ Time: %, Relinquished by: `,`/�_` Date:7 c!—f<i Time: JJ_Ujctp,.„ Are these results for regulatory purposes? Yes Comments: *** Dechlorination (<0.5 ppm)_of Ammonia, Cyanide, Phenol and TKN samples must be done in the field prior to preservation. *** \ 2 « VI Sampling Dates & Times * \ , -I $ \ / i I Date \ ! t / , e ƒ g . ) How would you like Circle all that app Em: ( op ) rop ± _ o. Efl •• - /_` \ \( _ * C - Received by Lab: E ;,.f Datg:,' Time: 9�= j � -N. \ �U /c Report results in: mg/L + A y e / [ tint): 1WyL t te: Ti me: v,..4•7a / 4©C. »\ My. t(s) Required ~ 0.1 NPDES#: /'JO O,- (n clY/ Phone: Fax: Email: hh17e4;"i cci-by- Project: P.O.#: mg/kg Turn Around Ti *RUSH work needs pri Char A 1$ b Compositor # Jug If On Ice? Yes / No Lab Use Only rcu in En me* or approval, Iv Upon 6 I00 Meritech, Inc. Environmental Laboratory Laboratory Certification No.165 Contact: Bobbie Hill Client: Town of Siler City 198 Utility Dr Siler City, NC 27344 Report Date: NPDES#: Date Sample Rcvd: 8/20/2019 NC0026441 8/8/2019 Meritech Work Order # 08081980 Parameters Cadmium, total Results <0.002 mg/L Sample: Effluent Composite Analysis Date 8/14/19 Reporting Limit 0.002 mg/L 8/5-6/19 Method EPA 200.7 Meritech Work Order # 08081981 Parameters 1,4 Dioxane + Trip Blank Results Attached Sample: Effluent Grab Analysis Date 8/12/19 Reporting Limit 8/8/19 Method EPA 624.1 I hereby certify that I have reviewed and approve these data. 72abO tar ory 4rQ !presentative 642 Tamco Road, Reidsville, North Carolina 27320 tel.(336)342-4748 fax.(336)342-1522 Client: Project: Client Sample ID: Sample Collection: MERITECH, INC. Environmental Laboratories Laboratory Certification #165 Town of Slier City WWTP 1,4-Dioxane Effluent 08/08/19 Meritech ID#: Analysis: Analyst: Dilution Factor: Report Date: EPA 624.1 VOLATILE ORGANICS Parameter 1,4-Dioxane (p-Dioxane) Trip Blank Batch Blank = Below Reporting Limit Internal Standards method criteria acceptable Surrogate Recoveries Toluene-d8 Bromofluorobenzene Spike Cone 30 ug/L 30 ug/L * - If "no" is selected, see second page for details. 1 hereby certify that I have reviewed and approve these data. Result 1.58 ug/L < 1.00 ug/L (Yes) / No (Yes) / No 08081981 08/12/19 VWV 1 08/16/19 Spike Recovery Limits 101% 98% 67-151% 45-161% 642 Tamco Road * Reidsville, NC 27320 (336) 342-4748 * info@meritechlabs.com HandDelivery m srn Sample Location and/or ID # 15 92016 Chain of Custody Record (COC) "9 o c• . S te . 2), 'b Fed Ex Sdn Vlethod of Shipment: —D C• C fi. Cm* 4 Relinquished by- e Date: TI e Relinquisheit an. Pits ate: Time: Relinquished PO- -� - Date:_rime: Are these results for regulatory purposes? Yes n 3 3 ro D rfr ** Dechlorination (<0.5 ppm) of Ammonia, Cyanide, Phenol and TKN samples must be done in the field prior to preservation.*** o ru Start Sampling Dates & Times vi 1 RI DNN 7320 ill: in. -nrl (460 - l 3 n) f Q j ..i. a m m -.0 CO 116 9oao Time 3 a LCjI Z 0 G(, 2o 0 n Person Taking Sample (Sign/Print): How would yo' Circle all that applyr Address: /(10 r1 Se ev' (rh! / /UC Q133`f Attention: R-thhi e }-4a( # of Cont. E l,q clicsccift `e C c4 ceci <C} Q l 1,„ n fr V i Recei by: ff' _AS A' Date: 1. Time;� Report results in: mg/L Rel Email: bhg)(c< 3 ao w Turn Around Time* *RUSH work needs prior approval. A H H i Compositor # Jug #' Temperature Upon Receipt: On Ice? Yes / No Lab Use Only - s ug/L n a Co z 'v 'J Client: Project: Client Sample ID: Sample Collection: MERITECH, INC. Sher City WWTP 1,4 Dioxane Plant Effluent 09/10/19 Environmental Laboratories Laboratory Certification #165 Merited" ID#: Analysis: Analyst: Dilution Factor: Report Date: EPA 624.1 VOLATILE ORGANICS Parameter 1,4-Dioxane (p-Dioxane) Trip Blank Batch Blank = Below Reporting Limit Internal Standards method criteria acceptable Surrogate Recoveries Toluene-d8 Bromofluorobenzene Result <1.00ug/L <1.00 ug/L (Yes ) I No (Yes) / No 091019157 09/12/19 VWV 1 09/17/19 Spike Cone Spike Recovery Limits 30 ug/L 30 ug/L * - If "no" is selected, see second page for details. I hereby certify that I have reviewed and approve these data. 108% 67-151% 99% 45-161% Lab atory Rtative 642 Talmo Road * Reidsville, NC 27320 (336) 342-4748 * info@meritechlabs,com POTW Name: Town of Siler City NPDES#: NC0026441 Effluent Grab (ng/L) CAS Number Analyte Name Acronym 8-Jul-19 6-Aug-19 14-Sep-19 375-22-4 Perfluorobutanoic Acid PFBA ND ND ND 2706-90-3 Perfluoropentanoic Acid PFPeA 14.5 13 ND 307-24-4 Perfluorohexanoic Acid PFHxA 9.94 5.89 6.15 375-85-9 Perfluoroheptanoic Acid PFHpA 2.1 0.717 2.05 335-67-1 Perfluorooctanoic Acid PFOA 5.49 4.02 3.71 375-95-1 Perfluorononanoic Acid PFNA ND ND ND 335-76-2 Perfluorodecanoic Acid PFDA ND ND ND 2058-94-8 Perfluoroundecanoic Acid PFUnA ND ND ND 307-55-1 Perfluorododecanoic Acid PFDoDA ND ND ND 72629-94-8 Perfluorotridecanoic Acid PFTrDA ND ND ND 376-06-7 Perfluorotetradecanoic Acid PFTeDA ND ND ND 375-73-5 Perfluorobutanesulfonic Aid L-PFBS ND ND ND 2706-91-4 Perfluoropentane Sulfate PFPeS ND ND ND 355-46-4 Perfluorohexane Sulfate PFHxS 2 ND 1.46 375-92-8 Perfluoroheptane Sulfate PFHpS ND ND ND 1763-23-1 Perfluorooctane Sulfate PFOS 5.66 3.84 3.89 68259-12-1 Perfluorononane Sulfate PFNS ND ND ND 335-77-3 Perfluorodecane Sulfate PFDS ND ND ND 754-91-6 Perfluorooctane Sulfonamide PFOSA ND ND ND 2355-31-9 N-methyl Perfluorooctane Sulfonamido Acetic Acid N-MeFOSAA ND ND ND 2991-50-6 N-ethyl Perfluorooctane Sulfonamido Acetic Acid N-EtFOSAA ND ND ND 123-91-1 1,4 Dioxane 1.3 1.58 < 1