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Home My WebLink AboutNC0004944_Permit Issuance_20000117NPDES DOCYHENT SCANNING COVER SHEET NPDES Permit: NC0004944 Document Type: Permit Issuance Wasteload Allocation Authorization to Construct (AtC) Permit Modification Complete File - Historical Engineering Alternatives (EAA) Compliance Instream Assessment (67b) Speculative Limits Environmental Assessment (EA) Permit History Document Date: January 17, 2000 This document is printed on reuse paper - i$izore any content on the resTerse side State of North Carolina Department of Environment and Natural Resources Division of Water Quality James B. Hunt, Jr., Governor Bill Holman, Secretary Kerr T. Stevens, Director January 17, 2000 Mr. Tony Branecky, Plant Manager Arteva Specialties, d/b/a KOSA Post Office Box 4 Salisbury, North Carolina 28145-0004 Dear Mr. Branecky: rA NCDENR NORTH CAROLINA DEPARTMENT OF ENVIRONMENT AND NATURAL RESOURCES Subject: NPDES Permit Issuance Permit Number NC0004944 KOSA — Salisbury Plant Rowan County In accordance with the application for discharge permit received on June 1, 1998, the Division is fonvarding herewith the subject state - NPDES permit. This permit is issued pursuant to the requirements of North Carolina General Statute 143-215.1 and the Memorandum of Agreement between North Carolina and the U.S. Environmental Protection Agency dated December 6, 1983. The following are responses to the comments received on December 13, 1999 from Stephen Lamb of your office. • All references to HNA Holdings, Inc., have been changed to Arteva Specialties, S.a.r.l. d/b/a KOSA (KOSA). • The total suspended solids (TSS) allocations have been recalculated by applying 40 CFR 414 subpart D to the process stormwater and adding the result to the figures present in the draft permit. The exclusion of process stormwater from the determination of process wastewater was an oversight. No TSS allocation has been given for water treatment plant blowdown or wastewaters from boilers and chillers. • Given the facility's historically low effluent ammonia levels. the monitoring frequency for ammonia has been reduced from three times per week to weekly. • Given the consistent presence of copper in the effluent, monthly monitoring remains appropriate. Monitoring for zinc has been reduced from monthly to annually given the non -detect nature of the analytical data. • The monitoring frequency for benzene and bis (2-ethylhexyl) pthalate (BEHP) has been reduced from quarterly to annually. Additionally, you requested mass limits for all OCPSF parameters. Parameters that are listed as concentrations are actually based on more stringent state standards or federal criteria. Where these standards and/or criteria exist, and they are more stringent than the levels indicated in the OCPSF rules, effluent limitations must be developed using these standards and reported as concentrations in the NPDES permit. • The sample type for stormwater samples has been changed from composite to grab. 1617 MAIL SERVICE CENTER. RRLEIGH, NORTH CAROLINA 27699-1617 - TELEPHONE 919-733-5083/FAX 919-733-0719 AN EQUAL OPPORTUNITY AFFIRMATIVE ACTION EMPLOYER - S0% RECYCLED/ 10% POST -CONSUMER PAPER • Additional language has been added to the effluent limitations page. The language indicates that analytical data which is less than the detection level shall be reported as such and that it shall be averaged as zero for reporting of both concentration and mass. The comment letter requested that the below detection level data be reported as zero. Below detection level data must be reported as Tess than the detection level for the analysis. • The comment letter presented a method for judging compliance with pH during months when algae could potentially grow on the polishing ponds. The polishing ponds are considered part of the treatment system. As such, compliance with the pH limits established by the federal guidelines must be applied at the polishing pond effluent. Although there are other facilities with a compliance method similar to the one proposed in your comment letter, the Division is moving away from such methods as they do not adequately judge what is seen by the receiving stream. Additionally, such a system makes compliance judgement logistically difficult. If any parts, measurement frequencies or sampling requirements contained in this permit are unacceptable to you, you have the right to an adjudicatory hearing upon written request within thirty (30) days following receipt of this letter. This request must be in the form of a written petition, conforming to Chapter 150B of the North Carolina General Statutes, and filed with the Office of Administrative Hearings, 6714 Mail Service Center, Raleigh, North Carolina 27699-6714. Unless such a demand is made. this permit shall be final and binding. This permit does not affect the legal requirements to obtain other permits which may be required by the Division of Water Quality or permits required by the Division of Land Resources, Coastal Area Management Act, or any other Federal or Local governmental permits which may be required. If you have any questions or comments regarding these speculative limitations. please do not hesitate to contact Mark Mclntire at telephone number (919) 733-5083, extension 553. Sincerely Original Signed By David A. Goodrich Kerr T. Stevens Cc: Central Files NPDES Permit File Mooresville Regional Office, Water Quality EPA, Roosevelt Childress Point Source Compliance/Enforcement Unit Permit No. NC0004944 STATE OF NORTH CAROLINA DEPARTMENT OF ENVIRONMENT AND NATURAL RESOURCES DIVISION OF WATER QUALITY PERMIT TO DISCHARGE WASTEWATER UNDER THE NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM In compliance with the provision of North Carolina General Statute 143-215.1, other lawful standards and regulations promulgated and adopted by the North Carolina Environmental Management Commission, and the Federal Water Pollution Control Act. as amended, Arteva Specialties S.a.r.l. d/b/a KOSA is hereby authorized to discharge wastewater from a facility located at KOSA - Salisbury Facility Highway 70 at Highway 801 West of Salisbury Rowan County to receiving waters designated as North Second Creek in the Yadkin -Pee Dee River Basin in accordance with effluent limitations, monitoring requirements, and other conditions set forth in Parts I, II, III and IV hereof. This permit shall become effective March 1, 2000. This permit and authorization to discharge shall expire at midnight on March 51, 2004. Signed this day January 17, 2000. Original Signed By David A. Goodrich Kerr T. Stevens, Director Division of Water Quality By Authority of the Environmental Management Commission Permit No. NC0004944 SUPPLEMENT TO PERMIT COVER SHEET Arteva Specialties S.a.r.l. d/b/a KOSA is hereby authorized to: 1. Continue to operate an existing 2.305 MGD activated sludge wastewater treatment facility consisting of a bar screen and grit chamber. UV/peroxide. equalization tanks. mechanical aeration basins, anaerobic groundwater treatment unit. secondary clarifiers, three (3) aerated polishing ponds with portable aerators and chemical addition facilities, aerobic digestion. sludge dewatering, sludge holding. and instrumented flow measurement located at KOSA's Salisbury facility at the intersection of Highway 70 and Highway 801, west of Salisbury in Rowan County; 2. Discharge from said treatment works at the location specified on the attached map into North Second Creek. a class C water in the Yadkin -Pee Dee River Basin; and 3. Continue to discharge stormwater associated with industrial activity through the five outfalls (outfalls A. B. C. D. and 5) as shown on the attached map. Modifications to the stormwater conveyance system are authorized by this permit in accordance with documentation to be included in the facility's Stormwater Pollution Prevention Plan (construction activities must be authorized under General Permit No. NCG010000). Latitude: Longitude: Ouad #: Stream Class: Receiving Stream: Permitted Flow: 35°42'34" Sub -Basin: 80°34'31" E16NE, Rowan Mills C North Second Creek 2.305 MGD 03-07-06 Arteva SpeciNCalties00049 S.a.r.l. d/b/a KOSA - . Salisbury Facility - Rowan County A (1). EFFLUENT LIMITATIONS AND MONITORING REQUIREMENTS - FINAL Permit No. NC0004944 During the period beginning on the effective date of the permit and lasting until expiration. the Permittee is authorized to discharge from outfall(s) serial number 001- Wastewater Treatment Plant Effluent. Such discharges shall be limited and monitored by the Permittee as specified below: U T C ARACTE STICS EFFL Eli_ H RI :,..:, S, , DTS�C i�AT�IO �� S x xh ....: Y. .% � .., »�`,.:g �: -'E .; ..... � . T C� N RI1 w :�3I�t h�E S ... , . ... �... - .� - ........�. r. .. i9p,t „ :. } gI. , e.. !°� i:,�n .�A#. r: ii:arS.... ...,....,->•F.'.�!., �... J._ .i .. .. .. � :, .i+S..1 xw., ..,, �' ver. e..,= � . _.. . .rv. r, k, , , , . � . { .y a';s ,+�r„ � - '.. ,.... n.•' ..�� j.,.. gg 1. � ',y.. r.� _ .!? i� ...,«.. ... ��,kk..�...:.'�. � .. . ,..� ;.�";r': .i, • •,...,: r._r...•_. yT.. 1.:.. -Dail Y.,'�`a`�nni�tun• r,. *pt ci'f �a�ix .._rAk� r K T 'i'�'k�e.. . '4, �, :Ld w. Wa� -,•.n._y,.• �!y .r ..;r+, � ,c � .7.l. .:v��a'i�v, �y .-�, ��.��r��em!a�� .x >, . ys,,� F .��;,; , , , ,; y'.'+'ai �ys'�' . Y,. ,s�`• X+? { .�'. .,(tt.. 4r .t. •:i :..,°F .:.5: t ...t, p �:.: " p..xe :��1. .t• �47� -..s44_ a_ :�,:� � o. t .r. i <t 2 .:r:,.<, ��t �� . le 'e _ .. .. a�� `? . _ i,• JJS.�L�► le cY 1 %o anon Flow (MGD) I 2.305 Continuous Recording E BOD. 5-day. 20°C (April 1 - October 31) 150.0 lbs/day 300.0 lbs/day Daily Composite E BOD. 5-day, 20°C (November 1 - March 31) 278.0 lbs/day 600.0 lbs/day Daily Composite E NH,, as N 23.0 lbs/day 46.0 lbs/day Weekly Composite E Total Suspended Residue 435.0 lbs/day 1382.0 lbs/day Daily Composite E Fecal Coliform (geometric mean) 200 / 100 ml 400 / 100 ml Weekly Grab E Dissolved Oxygen' Daily Grab E Dissolved Oxygen' 1 Grab U, D Total Copper Monthly Composite E Iron Monthly Composite _ E Manganese Monthly Composite E Conductivity 1 Grab U, D Temperature 1 Grab U. D Chronic Toxicity' Quarterly Composite E NOTES: Sample Locations: E — Effluent, U — Upstream at least 100 feet above the outfall. D — Downstream approximately eight miles from the outfall or at Highway 601. Upstream and downstream samples shall be grab samples. Stream samples shall be collected three times per week during June, July. August and September and once per week during the remaining months of the year. instream sampling requirements are provisionally waived in light of the permittee's participation in the Yadkin -Pee Dee River Basin Association. All instream sampling requirements are immediately reinstated should the permittee cease participation in the Association. 2 The daily average dissolved oxygen effluent concentration shall not be less than 5.0 mg/L. 3 Chronic Toxicity (Ceriodaphnia) P/F @ 34%; February, May, August. November; See condition A(3) of the Supplement to Effluent Limitations and Monitoring page. 4 The pH shall not be less than 6.0 standard units nor greater than 9.0 standard units and shall be monitored daily at the effluent by grab sample. THERE SHALL BE NO DISCHARGE OF FLOATING SOLIDS OR VISIBLE FOAM IN OTHER THAN TRACE AMOUNTS. ANALYTICAL DATA WHICH 1S LESS THAN THE DETECTION LEVEL SHALL BE REPORTED AS SUCH AND AVERAGED AS ZERO FOR REPORTING OF BOTH CONCENTRATION AND MASS. A(2). EFFLUENT LIMITATIONS AND MONITORING REQUIREMENTS - FINAL NC0004944 During the period beginning on the effective date of the permit and lasting until expiration. the Permittee is authorized to discharge OCPSF related process wastewater from outfall serial number 001. Such discharges shall be limited and monitored by the Permittee as specified below: Effluent Characteristic Daily Maximum lbs/day Monthly Average lbs/day Daily Maximum µg/L Measurement Frequency Ace naphthe ne Acenaphthylene Acrylonitrile Anthracene Benzene Be nzo(a)anthracene 3.4-Benzofluoranthene Benzo(k) f luoranthene Benzo(a)pyrene Bis(2-ethylhexyl) phthalate Carbon Tetrachloride Chlorobenzene Chloroethane Chloroform 2-Chlorophenol Chtysene Di-n-butyl phthalate 1,2-Dichlorobenzene 1.3-Dichlorobenzene 1.4-Dichlorobenzene l.1-Dichloroethane 1.2-Dichloroethane 1.1-Dichloroethylene I ,2-trans-Dichloroethylene 2.4-Dichlorophenol 1 ,2-Dichloropropane 1,5-Dichloropropylene Diethyl phthalate 2.4-Dimethylphenol Dimethyl'phthalate 4,6-Dinitro-o-cresol' 2.4-Dinitrophenol 2,4-Dinitrotoluene 2,6-Dinitrotoluene Ethylbenzene Fluoranthene fluorene I-lexachlorobenzene l-le xach lorob u tad ie ne Hexachloroethane Methyl Chloride Methylene Chloride Naphthalene Nitrobenzene 2-Nitrophenol 4-Nitrophenol Pltenanthrene Phenol Pyre ne Tetrachloroe thylene Toluene 0.650 0.630 0.630 1.452 0.651 0.299 2.861 0.491 1.046 0.608 1.740 0.470 0.299 0.630 2.252 0.576 1.196 0.470 2.167 0.384 0.502 2.957 1.313 6.843 1.153 0.726 0.630 0.523 2.028 0.950 0.630 0.726 0.737 1.324 0.630 0.278 0.715 0.235 0.235 0.235 0.395 0.246 0.192 0.160 1.110 0.224 0.331 0.288 0.822 0.331 0.160 0.235 0.726 0.I71 0.224 0.416.. _... 1.633 0.310 0.865....... 0.192 0.203 0.833 0.758 2.722 0.342 0.267 0.235 0.214 0.224 0.918 0.427 0.235 0.288 0.438 0.769 0.235 0.160 0.267 0.235 0.278 0.09 0.09 0.09 17 13 0.09 114 27 0.0023 26.0884 26 32 Annually Annually Annually Annually Annually Annually Annually Annually Annually Annually Annually Annually Annually Annually Annually Annually Annually Annually Annually Annually Annually Annually Annually Annually Annually Annually Annually Annually .Annually Annually Annually Annually Annually Annually Annually Annually Annually Annually Annually Annually Annually Annually Annually Annually Annually Annually Annually Annually Annually Annually Annually Sample Type Sample Location' Composite E Composite F_ Composite E Composite E Composite E Composite E Composite E Composite E Composite E Composite Composite E Composite E Composite E Composite E Composite E Composite E Composite E Composite E Composite . E Composite E Composite E Composite E Composite E Composite E Composite E Composite E Composite E Composite E Composite E Composite E Composite E . Composite E Composite E Composite E Composite E Composite E Composite E Composite E Composite E Composite E Composite E Composite E Composite E Composite E Composite E Composite E Composite E Composite E Composite E Composite E Composite E A(2). EFFLUENT LIMITATIONS AND MONITORING REQUIREMENTS - FINAL NC0004944 Effluent Characteristic Daily Maximum lbs/day Monthly Average lbs/day Daily Maximum ug/L Measurement Frequency Sample Type Sample Location[ Total Chromium Total Copper Total Cyanide Total Lead Total Nickel Total Zinc 1,2,4-Trichlorobenzene 1,1,1-Trichloroethane 1 ,1,2-Trichloroe thane Trichloroethylene Vinyl Chloride 1.495 0.576 0.576 0.576 2.861 0.726 0.224 0.224 0.224 1.110 Annually Monthly Annually Annually Annually Annually Annually Annually Annually Annually Annually Composite Composite Composite Composite Composite Composite Composite Composite Composite Composite Composite E E E E E E E E E Permit No. NC0004944 SUPPLEMENT TO EFFLUENT LIMITATIONS AND MONITORING REQUIREMENTS SPECIAL CONDITIONS A.(3) QUARTERLY PASS/FAIL CHRONIC TOXICITY TESTING - OUTFALL 001 The effluent discharge shall at no time exhibit observable inhibition of reproduction or significant mortality to Ceriodaphnia dubia at an effluent concentration of 34%. The permit holder shall perform at a minimum, auarterly monitoring using test procedures outlined in the "North Carolina Ceriodaphnia Chronic Effluent Bioassay Procedure." Revised February 1998. or subsequent versions or "North Carolina Phase 1I Chronic Whole Effluent Toxicity Test Procedure" (Revised -February 1998) or subsequent versions. The tests will be performed during the months of February. May, August. and November. Effluent sampling for this testing shall be performed at the NPDES permitted final effluent discharge below all treatment processes. If the test procedure performed as the first test of any single quarter results in a failure or ChV below the permit limit, then multiple -concentration testing shall be performed at a minimum, in each of the two following months as described in "North Carolina Phase II Chronic Whole Effluent Toxicity Test Procedure" (Revised - February 1998) or subsequent versions. The chronic value for multiple concentration tests will be determined using the geometric mean of the highest concentration having no detectable impairment of reproduction or survival and the lowest concentration that does have a detectable impairment of reproduction or survival. The definition of "detectable impairment." collection methods, exposure regimes, and further statistical methods are specified in the "North Carolina Phase II Chronic Whole Effluent Toxicity Test Procedure" (Revised -February 1998) or subsequent versions. All toxicity testing results required as part of this permit condition will be entered on the Effluent Discharge Monitoring Form (MR-1) for the months in which tests were performed, using the parameter code TGP3B for the pass/fail results and THP3B for the Chronic Value. Additionally, DWQ Form AT-3 (original) is to be sent to the following address: Attention: Environmental Sciences Branch North Carolina Division of Water Quality 1621 Mail Service Center Raleigh, North Carolina 27699-1621 Completed Aquatic Toxicity Test Forms shall be filed with the Environmental Sciences Branch no later than 30 days after the end of the reporting period for which the report is made. Test data shall be complete. accurate. include all supporting chemical/physical measurements and all concentration/response data, and be certified by laboratory supervisor and ORC or approved designate signature. Total residual chlorine of the effluent toxicity sample must be measured and reported if chlorine is employed for disinfection of the waste stream. Permit No. NC0004944 SUPPLEMENT TO EFFLUENT LIMITATIONS AND MONITORING REQUIREMENTS SPECIAL CONDITIONS (Continued) Should there be no discharge of flow from the facility during a month in which toxicity monitoring is required, the permittee will complete the information located at the top of the aquatic toxicity (AT) test form indicating the facility name, permit number, pipe number, county, and the month/year of the report with the notation of "No Flow" in the comment area of the form. The report shall be submitted to the Environmental Sciences Branch at the address cited above. Should the permittee fail to monitor during a month in which toxicity monitoring is required, monitoring will be required during the following month. Should any test data from this monitoring requirement or tests performed by the North Carolina Division of Water Quality indicate potential impacts to the receiving stream. this permit may be re -opened and modified to include alternate monitoring requirements or limits. NOTE: Failure to achieve test conditions as specified in the cited document. such as minimum control organism survival, minimum control organism reproduction, and appropriate environmental controls. shall constitute an invalid test and will require immediate follow-up testing to be completed no later than the last day of the month following the month of the initial monitoring. Permit No. NC0004944 PART I CONTINUED A.(4) FINAL LIMITATIONS AND CONTROLS FOR STORMWATER DISCHARGES During the period beginning on the effective date of the permit and lasting until expiration. the permittee is authorized to discharge stormwater from outfalls A, B. C, D. and 5. Such discharges shall be controlled. limited and monitored as specified below. 1. Stormwater Pollution Prevention Plans The permittee shall develop and continue to update a Stormwater Pollution Prevention Plan, herein after referred to as the Plan. The Plan shall be considered public information and shall include, at a minimum. the following items: a. Site Plan: The site plan shall provide a description of the physical facility and the potential pollutant sources which may be expected to contribute to contamination of regulated stormwater discharges. The site plan shall contain the following: (1) A general location map (USGS quadrangle map. or appropriately drafted equivalent map). showing the facility's location in relation to transportation routes and surface waters. and the name of the receiving water(s) to which the stormwater outfall(s) discharges. If the discharge is to a municipal separate storm sewer system. the name of the municipality and the ultimate receiving waters. and accurate latitude and longitude of the point(s) of discharge must be shown. (2) A narrative description of storage practices, loading and unloading activities, outdoor process areas, dust or particulate generating or control processes. and waste disposal practices. (3) A site map (or series of maps) drawn to scale with the distance legend indicating location of industrial activities (including storage of materials, disposal areas. process areas. and loading and unloading areas), drainage structures. drainage areas for each outfall and activities occurring in the drainage area. building locations and impervious surfaces. the percentage of each drainage area that is impervious. For each outfall. a narrative description of the potential pollutants which could be expected to be present in the regulated stormwater discharge. (4) A list of significant spills or leaks of pollutants that have occurred at the facility during the 3 previous years and any corrective actions taken to mitigate spill impacts. (5) Certification that the stormwater outfalls have been evaluated for the presence of non- stormwater discharges. b. Stormwater Management Plan: The stormwater management plan shall contain a narrative description of the materials management practices employed which control or minimize the exposure of significant materials to stormwater. including structural and non-structural measures. The stormwater management plan, at a minimum, shall incorporate the following: (1) A study addressing the technical and economic feasibility of changing the methods of operations and/or storage practices to eliminate or reduce exposure of materials and processes to stormwater. Wherever practicable the permittee should consider covering storage areas, material handling operations. manufacturing or fueling operations to prevent materials exposure to stormwater. In areas where elimination of exposure is not practicable. the stormwater management plan shall document the feasibility of diverting the stormwater runoff away from areas of potential contamination. (2) A schedule to provide secondary containment for bulk storage of liquid materials, storage of Section 313 of Title III of the Superfund Amendments and Reauthorization Act (SARA) water priority chemicals. or storage of hazardous materials to prevent leaks and spills from contaminating stormwater runoff. If the secondary containment devices are connected directly to stormwater conveyance systems. the connection shall be controlled by manually activated valves or other similar devices [which shall be secured with a locking mechanism] and any stormwater that accumulates in the containment area shall be at a minimum visually observed prior to release of the accumulated stormwater. Accumulated stormwater shall be released if found to be uncontaminated. Records documenting the individual making the observation, the description of the accumulated stormwater and the date and time of the release shall be kept for a period of five years. (3) A narrative description of Best Management Practices (BMPs) to be considered such as, but not limited to. oil and grease separation, debris control. vegetative filter strips, infiltration and stormwater detention or retention. where necessary. The need for structural BMPs shall be based on the assessment of potential of sources contributing significant quantities of pollutants to stormwater discharges and data collected through monitoring of stormwater discharges. (4) Inspection schedules of stormwater conveyances and controls and measures to be taken to limit or prevent erosion associated with the stormwater systems. c. Spill Prevention and Response Plan: The Spill Prevention and Response Plan shall incorporate a risk assessment of potential pollutant sources based on a materials inventory of the facility. Facility personnel (or team) responsible for implementing the plan shall be identified in the plan. A responsible person shall be on -site at all times during facility operations that have the potential to contaminate stormwater runoff through spills or exposure of materials associated with the facility ope rations. d. Preventative Maintenance and Good Housekeeping Program: A preventative maintenance program shall be developed. The program shall document schedules of inspections and maintenance activities of stormwater control systems. plant equipment and systems. Inspection of material handling areas and regular cleaning schedules of these areas shall be incorporated into the program. e. Training schedules shall be developed and training provided at a minimum on an annual basis on proper spill response and cleanup procedures and preventative maintenance activities for all personnel involved in any of the facility's operations that have the potential to contaminate stormwater runoff. Facility personnel (or team) responsible for implementing the training shall be identified in the plan. f. The Stormwater Pollution Prevention Plan shall identify a specific position(s) responsible for the overall coordination. development, implementation, and revision to the Plan. Responsibilities for all components of the Plan shall be documented and position.(s) assignments provided. g. Plan Amendment: The permittee shall amend the Plan whenever there is a change in design. construction. operation, or maintenance which has a significant effect on the potential for the discharge of pollutants via a point source to surface waters. The Stormwater Pollution Prevention Plan shall be reviewed and updated on an annual basis. The Director may notify the permittee when the Plan does not meet one or more of the minimum requirements of the permit. Within 30 days of such notice, the permittee shall submit a time schedule to the Director for modifying the Plan to meet minimum requirements. The permittee shall provide certification in writing to the Director that the changes have been made. h. Facility Inspections: Inspections of the facility and all stormwater systems shall occur at a minimum on a semiannual schedule. once in the fall (September - November) and once during the spring (April - June). The inspection and any subsequent maintenance activities performed shall be documented. recording date and time of inspection, individual(s) making the inspection and a narrative description of the facility's stormwater control systems. plant equipment and systems. Records of these inspections shall be incorporated into the Stormwater Pollution Prevention Plan. i. Implementation: Implementation of the Plan shall include documentation of all monitoring. measurements, inspections. maintenance activities and training provided to employees. including the log of the sampling data. Activities taken to implement BMPs associated with the industrial activities. including vehicle maintenance activities, must also be recorded. All required documentation shall be kept on -site for a period of five years and made available to the Director or his authorized representative immediately upon request. A.(5) MINIMUM MONITORING AND REPORTING REQUIREMENTS 1. The Stormwater Pollution Prevention Plan shall be reviewed and updated on an annual basis. Implementation of the plan shall include documentation of all sampling, measurements. inspections and maintenance activities, and training provided to employees. including the log of the sampling data and of activities taken to implement BMPs associated with the industrial activities. including vehicle maintenance activities. Such documentation shall be kept on -site for a period of five years and made available to the Director or his authorized representative immediately upon request. 2. The Director may notify the permittee when the Plan does not meet one or more of the minimum requirements of the permit. Within 30 days of such notice, the permittee shall submit a time schedule to the Director for modifying the Plan to meet minimum requirements. The permittee shall provide certification in writing to the Director that the changes have been made. 3. Inspections of the facility and all stormwater systems shall occur at a minimum on a semi-annual schedule, once in the fall (September — November) and once during the spring (April — June). The inspection and any subsequent maintenance activities performed shall be documented, recording date and time of inspection. individual(s) making the inspection and a narrative description of the facility's stormwater control systems, plant equipment and systems. Records of these inspections shall be incorporated into the Stormwater Pollution Prevention Plan. 4. Sample collection and visual monitoring for color. foam, outfall staining, visible sheens and dry weather flow, shall be performed at all stormwater discharge outfall locations. If a facility has multiple discharge locations that are required to be sampled, the permittee may petition the Director to sample at a reduced number of outfalls if it is established that the stormwater discharges are substantially identical. Visual observations shall be recorded for all outfall locations. 5. For purposes of the stormwater sampling required in this permit. all samples shall be collected from a discharge resulting from a representative storm event. Failure to monitor storm events in accordance with the specified frequency shall constitute a violation of this permit. If the stormwater runoff is controlled by a detention pond. the following sampling shall apply: a. If the detention pond detains the runoff generated by one inch of rainfall for 24 hours. a grab sample of the discharge from the pond shall be collected during the storm event. b. If the detention pond discharges only in response to a storm event exceeding a 10-year design storm. visual observations for color, foam. outfall staining. visible sheens, and dry weather flow are required. but analytical sampling shall not be required. c. If the detention pond discharges only in response to a storm event exceeding a 25-year. 24- hour storm, the pond shall be considered a non -discharging stormwater control system and not subject to NPDES requirements, unless the discharge causes a violation of water quality standards. 6. Samples analyzed in accordance with the terms of this permit shall be submitted on forms provided by the Director no later than January 31 following the year in which sampling was required. 7. Specific Monitoring Requirements a. Stormwater from KOSA — Salisbury. Monitoring applies to all of the stormwater discharges. Monitoring is not required for stormwater which does not discharge to the surface waters of the state. b. Story Pr IVO,DISC " e t ,t L s . _ is% Cbs� ( a i!'.i " .. _...... . k; _,. y,�;y„ r%,rf;. e.. _.,�' •Total £ ! S ' .. }Units ; , , anaiio .ec u�em�n , br= P�ric}.r +ti ,� ` SAY 1 � .` �.�" Y _ � : L R€ 4 �r� a >t Y.ib.a� , spa t ,[�yi. W. ria+A� _.. `S`i i `` a A ,-L {(jfir' 'iS�• }II t 6 �� _ v>><< `It ie ( �' Flow2 pH MG i Annually Standard i Annually _ mg/L , Annually i i _ Grab Grab __ i SDO _ SDO SDOT Oil and Grease Total Suspended Solids mg/L i Annually Grab SDO BOD. 5-day. 20°C mg/L . Annuallynn- Grab SDO Total Nitrogen Total Phosphorus _.._._._..._._._.__ TTO , mg/L i Annually _ Grab i 1 SDO SDO SDO Grab Grab Sample Locations: SDO — Stormwater Discharge Outfall 2 Total flow shall be measured continuously or calculated based on the amount of area draining to the outfall. the amount of built -upon area. and the total amount of rainfall or estimated by the measurement of flow at 20 minute intervals during the rainfall event. Total precipitation and duration of the event measured shall be a representative storm event. Storm Event Characteristic Units Monitoring Requirements Total Event Precipitation inches Annually Event Duration hours Annually For facilities that develop a solvent management plant to be incorporated into the stormwater pollution prevention plan may make a request to DWQ that monitoring of total toxic organics be waived. The solvent management plan shall include. as a minimum. lists of the total toxic organic compounds used; the method of disposal used instead of dumping such as reclamation. contract hauling, or incineration: and the procedures for assuring that toxic organics do not routinely spill or leak into the stormwater. For those facilities allowed such a waiver. the discharger shall include a signed certification statement on the discharge monitoring reports. Stormwater discharges from any vehicle maintenance activity occurring on -site which uses more than 55 gallons of new motor oil per month when averaged over the calendar year shall be monitored by the permittee as specified below: e cinitortn Requilei ' easurentent regency, 2 5 4 5 Total Flows MG Oil and Grease 3/Term mg/L ' 3/Term Grab . Lead, Total Recoverable4 L 3/Term Grab Detergents (MBAS)s r mg/L 3/Term Grab pH Standard 3/Term Grab I SDO New motor oil usage I Gal/month 3/Term I Estimate SDO SDO SDO SDO Measurement Frequency — 3/Term shall mean stormwater runoff associated with vehicle maintenance activity on -site. Existing facilities shall be sampled once within six months of the effective date of the permit and, where possible. prior to implementing BMPs and development of the BMP plan at existing operations. Thereafter. sampling shall be conducted two times during the remaining permit term at intervals of greater than eighteen months apart and collected during the months of April through November. Sample Locations: SDO — Stormwater Discharge Outfall Total flow shall be measured continuously or calculated based on the amount of area draining to the outfall, the amount of built -upon area, and the total amount of rainfall or estimated by the measurement of flow at 20 minute intervals during the rainfall event. Total precipitation and duration of the event measured shall be a representative storm event. Applies only for facilities at which fueling occurs. Detergent monitoring is required only at facilities which conduct vehicle cleaning. Storm Event Characteristic Unit Monitoring Requirements Total Event Precipitation inches Annually Event Duration hours Annually A.(6) STORMWATER DEFINITIONS 1. Best Management Practices (BMPs) Schedules of activities. prohibitions of practices. maintenance procedures. and other management practices to prevent or reduce the pollution of waters of the United States. BMPs also include treatment requirements, operation procedures, and practices to control plant site runoff, spillage or leaks, sludge or waste disposal, or drainage from raw material storage. 2. Bulk Storage of Liquid Products Liquid raw materials, manufactured products, waste materials or by-products with a single above ground storage container having a capacity of greater than 660 gallons or with multiple above ground storage containers having a total storage capacity of greater than 1,320 gallons. 3. Point Source Discharge Any discernible, confined and discrete conveyance. including but specifically not limited to, any pipe, ditch. channel, tunnel, conduit. well, discrete fissure. container, rolling stock. or concentrated animal feeding operation from which pollutants are or may be discharged to waters of the state. 4. Runoff Coefficient The fraction of total rainfall that is not infiltrated into or otherwise retained by the soil. concrete. asphalt or other surface upon which it falls that will appear at the conveyance as runoff. 5. Secondary Containment Spill containment for the contents of the single largest tank within the containment structure plus sufficient freeboard to allow for the 25-year, 24-hour storm event. 6. Section 313 Water Priority Chemical A chemical or chemical category which: a. Is listed in 40 CFR 372.65 pursuant to Section 313 of Title III of the Superfund Amendments and Reauthorization Act (SARA) of 1986, also titled the Emergency Planning and Community Right -to -Know Act of 1986; b. Is present at or above threshold levels at a facility subject to SARA title III. Section 313 reporting requirements; and c. That meet at least one of the following criteria: (1) Is listed in appendix D of 40 CFR part 122 on either Table II (organic priority pollutants). Table III (certain metals, cyanides, and phenols) or Table IV (certain toxic pollutants and hazardous substances); (2) Is listed as a hazardous substance pursuant to section 311(b)(2)(A) of the CWA at 40 CFR 116.4; or (5) Is a pollutant for which EPA has published acute or chronic water quality criteria. 7. Sittnificant Materials Includes, but is not limited to: raw materials; fuels; materials such as solvents, detergents, and plastic pellets; finished materials such as metallic products; raw materials used in food processing or production; hazardous substances designated under section 101(14) of CERCLA; any chemical the facility is required to report pursuant to section 313 of Tide III of SARA; fertilizers; pesticides; and waste products such as ashes, slag and sludge that have the potential to be released with stormwater discharges. 8. Sisnificant Spills Includes, but is not limited to: releases of oil or hazardous substances in excess of reportable quantities under section 311 of the Clean Water Act (Ref: 40 CFR 110.10 and CFR 117.21) or section 102 of CERCLA (Ref: 40 CFR 302.4). 9. Stormwater Runoff The flow of water which results from precipitation and which occurs immediately following rainfall or as a result of snowmelt. 10. Total Flow The flow corresponding to the time period over which the sample collection occurs. The total flow calculated based on the size of the area draining to the outfall. the amount of the built -upon (impervious) surfaces within the drainage area, and the total amount of rainfall occurring during the sampling period. 1 1. Visible Sedimentation Solid particulate matter, both mineral and organic, that has been or is being transported by water. air, gravity, or ice from its site of origin which can be seen with the unaided eye. October 20 19 99 NCD.NR/DWQ/Budget Office P.O.Box 29535, Raleigh, NC 27626-0535 �,o 20 E C a, oa O` d O cc G- y 25 Lr,ZO7'Oaj C.�CN-En CTO Fn z �o�o.-c a, �yma oa �'o�oO-mmo Z ,5,11 E rcZ x-ZaEo�•_�UmavoL=c mZ3o> asD—C¢=mo3 uZQE. 'di 3' cNw tn , 7 o u) o w - Q•O o - N O Z U m N ?.-. 01 N v�moaoonQ�`?oc_�omcy 3~dry o co,2 �N'�orova� m->a Z v>Z�cvc��-3�ciro�rYc`E�aciar #f44835 1x NORTH CAROLINA ROWAN COUNTY } Salisburyillbst P.O. Box 4639 Salisbury, NC 28145 (704) 633-8950 FAX (704) 633-7373 AFFIDAVIT OF PUBLICATION $20 Before the undersigned, a Notary Public of said County and State, duly commissioned, qualified, and authorized by law to administer oaths, personally appeared STEVE JOHNSON, who being first duly swom, deposes and says that he is Advertising Director of POST PUBLISHING COMPANY, INC., engaged in the publication of a newspaper known as THE POST, published, issued and entered as second class mail in the City of Salisbury. in said County and State, that he is authorized to make this affidavit and swom statement, that the notice or other legal advertisement a true copy of which is attached hereto, was published in THE POST, on the following dates: October 18, 1999 and that the said newspaper is which such notice. paper document or legal advertisement was published was, at the time of each and every such publication, a newspaper meeting all of the requirements and qualifications of Section 1-597 of the General Statutes of North Carolina and was a qualified newspaper within the meaning of Section 1-597 of the General Statutes of North Carolina. This 20th day of October 19 99 Swom and subscribed before me this 20th day of October 19 99 1 • 1 NOTARY PUBLIC My commission expires ;q ' Doo T 63 Koh December 3, 1999 Mr. Mark McIntire Division of Water Quality P.O. Box 29535 512 N. Salisbury Street Raleigh, NC 27626 Phone (919) 733-5083 Fax (919) 733-0719 Subject: Arteva Specialties S.a.r.l. d/b/a Kosa (formerly HNA Holdings, Inc.) Salisbury, North Carolina NPDES Draft Permit Comments (Permit Number NC0004944) Dear Mr. McIntire: Arteva Specialties S.a.r.l. d/b/a Kosa (Kosa), formerly HNA Holdings, Inc. received a draft NPDES permit on October 26,1999. As discussed with Kristen Jenkins/CH2M HILL, a meeting had been scheduled with you on December 3, 1999, to discuss the draft permit, and comments were going to be submitted within a week of that meeting. Since the meeting has been postponed, Kosa is providing comments on the draft permit in this letter. Name Change The facility has changed names since the permit application was submitted. The facility name should be Arteva Specialties S.a.r.l. d/b/a Kosa. An official name change request was submitted one year ago and the agency told us that the company name would be changed when the permit was issued. pH The facility has maintained compliance with effluent pH limitations for the previous three years. However, pH values increase to the upper limit of 9 during the summer months. The polishing ponds typically have algae blooms during the summer which are causing the elevated pH values. KOSA would like permission to monitor for pH at both the clarifier overflow and polishing pond effluent. If the polishing pond effluent pH exceeds the upper permit limit of 9, the clarifier overflow pH values for the previous 30 days would be reviewed, and if no values exceed the upper limit of 9, then clarifier effluent pH values would be used for compliance purposes. The retention time in the polishing pond system is approximately 30 days assuming polishing pond volumes of 5.6,18.2, and 20 million gallons for Ponds 2, 3, and 4, and an average flow rate of 1.5 MGD. KOSA is aware of at least one other facility in North Carolina with the pH monitoring conditions discussed above. P.O. Box 4 7401 Statesville Ave. (704) 636-6000 Salisbury, NC 28145-0004 Salisbury, NC 28147 www.kosa.com /'S' PAA TSS r ;a ¢o TSS Based on the DWQ fact sheet, TSS limitations for the draft permit were calculated based on Organic Chemicals, Plastics, and Synthetic Fibers (OCPSF) guidelines and secondary treatment regulation. There was no TSS allocation for wastewater from boilers and chillers, water treatment plant blowdown, and process storm water. For the TSS limit in the current r ( v permit, an allocation was given to these sources based on intake water quality (NPDES S I' "v' `�� ' Renewal Correspondence, Davis and Floyd, Inc. to Division of Environmental Management rt c ° dated February 15, 1991). As a result, the TSS limit in the draft permit is significantly lower than the current permit. Therefore, Kosa is requesting that the basis for the TSS limit remain the same with the revised permit and a TSS allocation based on intake water quality be given to wastewater from boilers and chillers, water treatment plant blowdown, and ' process storm water. Using the same intake water quality with a monthly average and daily �� maximum TSS value of 53 mg/L and 79.5 mg/L, respectively, Kosa has estimated a TSS monthly average and daily maximum limit of 454 lb/d and 1369 lb/d, respectively. Ammonia Nitrogen The facility is currently required to monitor for ammonia nitrogen three times per week with limits of 23 lb/d monthly average and 461b/day daily maximum. The frequency is the same in the draft permit. Since the facility has relatively low levels of ammonia nitrogen in the effluent (average of 5 lb/day for the previous three years), a monitoring frequency of once per week is requested. Metals Metals monitoring is annual in the draft permit for all metals except copper and zinc. Zinc has only been detected four times since the beginning of 1998 as presented in Attachment A. Therefore, Kosa is requesting annual monitoring for zinc. OCPSF Priority Pollutants As discussed in the permit application, the facility researched the presence of bis (2- ethylhexyl) phthalate (BEHP) in the effluent and discovered that the source was the submersible composite sampling pump. This pump was replaced with a typical composite sampler with a peristaltic pump in April 1998. Since the pump was replaced, BEHP has not been detected in the effluent as presented in Attachment A. Therefore, Kosa is requesting annual monitoring for BEHP. s not been detected in the effluent since January 1998. Therefore, Kosa is re . . - • g annual monitoring for benzene'e sed limits for nine OCPSF ammeters in the draft permit. We are not aware of an OCPSF or Q require . - tfor concentration limits for these parameters. Therefore, we would like °vt-S k to h - - concentration limits removed and have only mass based limits for the OCPSF pollutis which are based on the actual process flow rate. t ,r�''`0 pLf 5 Storm Water Discharges The facility received DWQ approval in a letter dated November 22,1996, to collect grab U� storm water samples samples instead of composite due to the number of outfalls. Therefore, P P we are requesting that the permit state that storm water sampling be conducted with grab samples. h Additional Permit Verbiage The current NPDES permit includes limits for several pollutants which are below acceptable detection levels. Therefore, the facility is requesting that the following verbiage is included et- ( g� in the renewed permit: 4s ti mil, el Analytical data which is less than the detection level shall be reported and averaged as zero for reporting of both concentration and mass s.ainment. Marked up Permit A marked up copy of the draft NPDES permit is attached. This should help in communicating the areas discussed in this memo. Please feel free to contact me at (704) 636 — 6000 (extension 4862) or our consultant, Kristen Jenkins, CH2M HILL, at (770) 604 — 9182, extension 546 if you have any questions or require additional information. Sincerely, Kosa Stephen C. Lamb Senior Environmental Engineer Enclosures: Marked -up Draft Permit C: Kristen Jenkins/CH2M HILL Bill Kreutzberger/CH2M HILL Bryson Woodlief/KoSaDavid Casner/KoSa TABLE A-1 Summary of Select Effluent Data Benzene Bis(2-ethylhexyl) phthalate Total Zinc (Ib/d) (ug/L) (mg/L) Daily limit (past) 39.83 ug/l 60.2 ug/l none Jan-98 <.065 45.6 <.02 <.067 147 <.02 Feb-98 <.077 74.7 <.02 <.02 Mar-98 <.055 51.6 <.02 <.02 Apr-98 <.06 <10.0 0.027 <.02 May-98 <.062 <10.0 <.02 0.021 Jun-98 <.060 <10.0 <.02 <.02 JuI-98 <.060 <10.0 <.02 <.02 Aug-98 <.060 <10.0 0.07 <.02 Sep-98 <.061 <10.0 <.02 <.02 Oct-98 <.51 <10.0 <.02 <.02 Nov-98 <.48 <10.0 <.02 <.02 Dec-98 <.048 <10.0 <.02 <.02 Jan-99 <.055 <10.0 0.021 <.02 Feb-99 <.042 <10.0 <.02 <.02 Mar-99 <.045 <10.0 <.02 <.02 TABLE A-1 Summary of Select Effluent Data Benzene Bis(2-ethylhexyl) phthalate Total Zinc (Ib/d) (ug/L) (mglL) Apr-99 <.052 <10.0 <.02 <.02 May-99 <.057 <10.0 <.02 <.02 Jun-99 <.044 <10.0 <.02 <.02 JuI-99 <.055 <10.0 <.02 <.02 Aug-99 <.054 <10.0 <.02 <.02 Sep-99 <.058 <10.0 <.02 <.02 Permit No. NC0004944 STATE OF NORTH CAROLINA DEPARTMENT OF ENVIRONMENT AND NATURAL RESOURCES DIVISION OF WATER QUALITY PERMIT TO DISCHARGE WASTEWATER UNDER THE NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM In compliance with the provision of North Carolina General Statute 143-215.1, other lawful standards and regulations promulgated and adopted by the North Carolina Environmental Management Commission, and the Federal Water Pollution Control Act. as amended, HNA Holdings, Izcer rated f/k/a Hoe st-Cinese Corporation is hereby authorized to discharge wastewater from a facility located at xoSA - Salisbury Facility Highway 70 at Highway 801 West of Salisbury Rowan County ARrEvA SPEC. /AL r, E$ C, a . r. , d /RosA to receiving waters designated as North Second Creek in the Yadkin -Pee Dee River Basin in accordance with effluent limitations, monitoring requirements. and other conditions set forth in Parts I, II, III and IV hereof. This permit shall become effective This permit and authorization to discharge shall expire at midnight on March 31, 2004 Signed this day DRAFT Kerr T. Stevens, Director Division of Water Quality liy Authority of the Environmental Management Commission is hereby authorized to: 1. Permit No. NC0004944 SUPPLEMENT TO PERMIT COVER SHEET Incted As R TF✓v SPr c, 1 � s sum 1. C%b% Continue to operate an existing2.305 MGD activated sludge wastewater consisting of a bar screen and grit chamber. gr rap, equalization aeration basins, anaerobic groundwater treatment unit secondary clarifiers, t polishing ponds with portable aerators and chemica sludge dewatering, sludge holding, and instrumente Salisbury facility at the intersection of Highway 70 Rowan County (See Part 1I1, A of this permit); 7ANxs atment facility mechanical ree (3) aerated addition facilities, aerobic digestion, flow measurement located a and Highway 801, west of Salisbury in TiSFRT Le I//Pc"RoxpL 2. Discharge from said treatment works at the location specified on the attached map into North Second Creek, a class C water in the Yadkin -Pee Dee River Basin; and 3. Continue to discharge stormwater associated with industrial activity through the five outfalls. (outfalls A. B, C, D, and 5) as shown on the attached map. Modifications to the stormwater conveyance system are authorized by this permit in accordance with documentation to be included in the facility's Stormwater Pollution Prevention Plan (construction activities must be authorized under General Permit No. NCG010000). Jam_ DNA LYT(G/6,L PATA wr-jiGH /3 L e VET sitfrt-L- 8E g«PoiTED ,kr.iD Ko .CA RodsS c r= -Ten-Ai rite DCTecTioit/ ✓Fg EP s Z E7 O 1 or2 leEPoRi7' ' of BoT' GONLENTKPrVod✓ Ail() MASS , 77tE PFTEcr(ord Noic:p ,S-S A c,,elfr Latitude: Lon¢itude: Quad #: Stream Class: Receiving Stream: Permitted Flow: SCALE 1:24000 35°42'34" Sub -Basin: 03-0706 80°34'31" E16NE C North Second Creek 2.305 MGD A (1). EFFLUENT LIMITATIONS AND MONITORING REQUIREMENTS - FINAL Permit No. NC0004944 During the period beginning on the effective date of the permit and lasting until expiration. the Permittee is authorized to discharge from outfall(s) serial number 001- Wastewater Treatment Plant Effluent. Such discharges shall be limited and monitored by the Permittee as specified below: CHARACTERISTICS DISCHARGE LIMITATIONS MONITORING REQUIREMENTS EFFLUENT Monthly Average Daily Maximum Measurement Frequency Sample Type Sample Location' Flow (MGD) 2.305 Continuous Recording I: BOD, 5-day, 20°C (April 1 — October 31) 150.0 Ibs/day 300.0 lbs/day Daily Composite I. BO , "' ° ‘,, ovember 1 — MarcE 1) i= /day 600.0 Ibs/da ; ; , Daily 1.:-.posite -� `� NH3 a r '`' 23.0 46.0 Ibs/d'r . 3/Week Co osite E \ Total nisi • nded Residue 333.0 is/da 58.0 bs/ av Daily e. Composite E Fecal Cold trm (geometric m an) 200 / 100 400 / 10 till Weekly ^�� Grab E Dissolved I xygen2 Daily Grab E Dissolved I xygenl I Grab U, D - Total Cop $ • r / onthly Composite E Tota r i �p�hly Composite E Iron �,�� Monthly Composite E Manganese Monthly Composite E Conductivity I 1 Grab U, D Temperature S, I Grab U, 1) Chronic Toxicity; \ Quarterly Composite E NOTES: 2 /36y LiS/DAr Sample Locations: E — Effluent. U — Upstream at least 100 feet above the outfall. D — Downstream approximately eight miles from the outfall or at Highway 601. Upstream and downstream samples shall be grab samples. Stream samples shall be collected three times per week during June. July, August and September and once per week during the remaining months of the year. lnstream sampling requirements are provisionally waived in light of the permittee's participation in the Yadkin -Pee Dee River Basin Association. All instream sampling requirements are immediately reinstated should the permittee cease participation in the Association. The daily average dissolved oxygen effluent concentration shall not be Tess than 5.0 mg/L. Chronic Toxicity (Ceriodaphnia) P/F @ 34%: February. May. August. November: See condition A(3) of the Supplement to Effluent Limitations and Monitoring page. 3/141 EEIC 4 The pH shall not be Tess than 6.0 standard units nor greater than 9.0 standard units and shall be monitore daily at the effluent by grab sample. .EF TOE poc-ISH pc -'P E:'GCL!EN? p 14 ExcerEP5 %t1EU/'PX PQZNs.T WMtTePT.O I % HeCt"PriP Ofe7FLo4l p$ t/f4Lt4ES Fag 77j exC-/40c4S 30 Dn .s TI ILRE SHALL BE NO l IILSCHARG€-on LoA-TING s S OR Vrs1stcTOAMiN-OTHEtUrHAN TRACE AMOUNTS. tl/Du tr D 13 E ge—Vi Ets/EDJ /rriP i F po t/Psc. u ES Ex c-FED %N"E 5 CoN'i9oSrre Shrf12"71 itle-ArWS .Rt 2`f Houti conrPesrl-C- 06.4/h .Tr, .9�; tlppel2 wns T of 9,oJ %!tcN cldr►trPre-/. EFrLtsFivr /3 vA1,Ke5 i'h'wLP BC USED Fort Coyrspt,m,-'GE- puApaScs. 14tS 5 co,✓Oroti p, "lout-7 e,✓ /S 7b r3c C1sEP [vrtc,✓ P14GPre $c00,45 /t t ac CA-444EP et..E✓A-rev p H. A(2). EFFLUENT LIMITATIONS AND MONITORING REQUIREMENTS - FINAL NC0004944 During the period beginning on the effective date of the permit and lasting until expiration. the Permittee is authorized to discharge OCPSF related process wastewater from outfall serial number 001. Such discharges shall be limited and monitored by the Permittee as specified below: Effluent Characteristic Daily Maximum lbs/day Monthly Average lbs/day Daily Maximum ug/I- Measurement Frequency Sample Type Sample Location' Acenaphthene Acenaphthylene Acrylonitrile Anthracene Benzene Benzo(a)anthracene 3,4-Benzofluoranthene Benzo(k)fluoranthene Benzo(a)pyrene Bis(2-ethylhexyl) phthalate Carbon Tetrachloride Chlorobenzene Chloroethane Chloroform 2-Chlorophenol Chrysene Di-n-butyl phthalate 1,2-Dichlorobenzene 1.3-Dichlorobenzene 1.4-Dichlorobenzene 1,1-Dichloroethane 1.2-Dichloroethane 1.1-Dichloroethylene 1,2-trans-Dichloroethylene 2,4-Dichlorophenol 1.2-Dichloropropane 1.3-Dichloropropylene Diethyl phthalate 2.4-Dimethylphenol Dimethyl phthalate 4,6-Dinitro-o-cresol 2,4-Dinitrophenol 2.4-Dinitrotoluene 2.6-Dinitrotoluene Ethylbenzene Fluoranthene Fluorene Hexachlorobenzene Hexachlorobutadiene Hexachloroethane Methyl Chloride Methylene Chloride Naphthalene Nitrobenzene 2-Nitrophenol 4-Nitrophenol Phenanthrene 0.482 0.482 0.482 1.110 0.498 0.180 0.180 0.180 0.302 0.188 0.147 0.229 0.122 2.188 0.849 0.375 0.171 0.800 0.253 0.465 0.220 1.331 0.629 0.359 0.253 0.229 0.122 0.482 0.180 1.722 0.555 0.131 0.441 0.171 0.914 0.318 1.877 1.249 0.359 0.237 1.657 0.661 0.294 0.147 0.384 0.155 2.261 0.637 1.004 0.580 5.232 2.082 0.882 0.261 0.555 0.204 0.482 0.180 0.400 0.163 0.441 0.171 1.551 0.702 0.727 0.327 0.482 0.180 0.555 0.220 0.563 0.335 1.012 0.588 0.482 0.180 2 0.09 0.09 0.09 17 13 0.09 A,jNuAL-L-t 9 27 0.0023 Annually Annually Annually nnually Quarterly y Annually Annually ally Quarterly nua y Annually Annually Annually Annually Annually Annually Annually Annually Annually Annually Annually Annually Annually Annually Annually Annually Annually Annually Annually Annually Annually Annually Annually Annually Annually Annually Annually Annually Annually Annually Annually Annually Annually Annually Annually Annually Composite Composite Composite Composite Composite Composite Composite Composite Composite Composite Composite Composite Composite Composite Composite Composite Composite Composite Composite Composite Composite Composite Composite Composite Composite Composite Composite Composite Composite Composite Composite Composite Composite Composite Composite Composite Composite Composite Composite Composite Composite Composite Composite Composite Composite Composite Composite A(2). EFFLUENT LIMITATIONS AND MONITORING REQUIREMENTS - FINAL NC0004944 Effluent Characteristic Daily Maximum lbs/day Monthly Average Ibs/day Daily Maximum µa- Measurement Frequency Sample Type Sample Locations Phenol Pyrene Tetrachloroe thylene Toluene Total Chromium Total Copper Total Cyanide Total Lead Total Nickel Total Zinc 1,2.4-Trichlorobenzene 1,1,1-Trichloroethane 1.12-Trichloroethane Trichloroethylene Vinyl Chloride 0.212 0.547 0.457 1.143 0.441 0.441 0.441 2.188 0.192 0.204 0.180 0.212 0.555 0.171 0.171 0.171 0.849 32 psr/Nu��-t'r Annually Annually Annually Annually Annual) Annua y Annually Annuall Monthly nua y Annually Annually Annually Annually Composite Composi te Composite Composite Composite Composite Composite Composite Composite Composite Composite Composite Composite Composite Composite E E E E E E E E E E E E E E E b. IF the detention pond discharges only in response to a storm event exceeding a 10-year design storm, visual observations for color. foam. outfall staining, visible sheens, and dry weather flow are required, but analytical sampling shall not be required. c. If the detention pond discharges only in response to a storm event exceeding a 25-year. 24- hour storm. the pond shall be considered a non -discharging stormwater control system and not subject to NPDES requirements, unless the discharge causes a violation of water quality standards. 6. Samples analyzed in accordance with the terms of this permit shall be submitted on forms provided by the Director no later than January 31 following the year in which sampling was required. 7 Specific Monitoring Requirements a. Stormwater from HNA Holdings Inc. — Salisbury. Monitoring applies to all of the stormwater discharges. Monitoring is not required for stormwater which does not discharge to the surface waters of the state. 6t./NIk'n2C Stormwater Discharge Characteristics Units Monitoring Requirements Measurement Frequency Sample Type t Sample Location' Total Flow' MG Annually SDO pH Standard Annually Grab SDO Oil and Grease mg/L Annually Grab SDO Total Suspended Solids mg/L Annually omp� SDO BOD. 5-day, 20°C mg/L Annually : Composite SDO Total Nitrogen mg/L Annually Composite SDO Total Phosphorus mg/L Annually Composite SDO TTO mg/L i Annually Composite ,, SDO Composite sam les all be time -weighted composites 2 sample Locations: SDO — Stormwater isc arge 0utfall Total flow shall be measured continuously or calculated based on the amount of area draining to the outfall, the amount of built -upon area. and the total amount of rainfall or estimated by the measurement of flow at 20 minute intervals during the rainfall event. Total precipitation and duration of the event measured shall be a representative storm event. Storm Event Characteristic Units Total Event Precipitation inches Event Duration hours 6-XP3.8 Monitoring Requirements Annually Annually For facilities that develop a solvent management plant to be incorporated into the stormwater pollution prevention plan may make a request to DWQ that monitoring of total toxic organics be waived. The solvent management plan shall include, as a minimum, lists of the total toxic organic compounds used; the method of disposal used instead of dumping such as reclamation. contract hauling. or incineration: and the procedures for assuring that toxic organics do not routinely spill or leak into the stormwater. For those facilities allowed such a waiver, the discharger shall include a signed certification statement on the discharge monitoring reports. b. Stormwater discharges from any vehicle maintenance activity occurring on -site which uses more than 55 gallons of new motor oil per month when averaged over the calendar year shall be monitored by the permittee as specified below: Re: Hf'1A & Buck SS... Subject: Re: HNA & Buck SS... Date: Tue, 19 Oct 1999 10:34:28 -0400 From: Michael Parker <Michael.Parker@ncmail.net> Organization: NC DENR - Mooresville Regional Office To: Mark Mcintire <mark.mcintire@ncmail.net> The problem I have had with these drafts is getting these documents to all the people that need to see them and then giving them enough time to review them. Fortunately, I believe everyone has finally seen/reviewed them, and we have no additional comments to offer at this time. A signed copy of the Fact Sheet should be back to you soon. Sorry for the delay. Mark Mcintire wrote: > Did you get a chance to take a look at the HNA Salisbury draft? Also, I > think I sent you a copy of the Buck Steam Station draft a while back. I > seem to remember you calling about it, though I may be going crazy. Let > me know if you have comments on that one as well. EPA is barking at us > to issue as many majors as we can before the end of the year. > Thanks, > Mark > -- > Mark D. McIntire > Environmental Engineer > NPDES Unit - Division of Water Quality > 1617 Mail Service Center > Raleigh, NC 27699-1617 > (919) 733-5083, extension 553 > mailto:mark.mcintire@ncmail.net Michael Parker - Michael.Parker@ncmail.net Environmental Engineer II North Carolina Dept. of Environment & Natural Resources Division of Water Quality 919 N. Main Street Mooresville, NC 28115 Ph: 704.663.1699 Fax: 704.663.6040 Michael Parker <Michael.Parker@ncmail.net> Environmental Engineer II NC DENR - Mooresville Division of Water Quality 1 of 1 10/19/1999 10:58 AM DENR/DWQ FACT SHEET FOR NPDES PERMIT DEVELOPMENT NPDES No. NC0004944 Facility, Information Applicant/Facility Name: Arteva Specialties, S.a.r.l. d/b/a KOSA (f/k/a HNA Holdings) Applicant Address: P.O. Box 4, Salisbury, NC 28145-0004 Facility Address: At the intersection of Hwy 70 and Hwy 801 Permitted Flow 2.305 MGD Type of Waste: 97% industrial 3% domestic Facility/Permit Status: Existing renewal w/o expansion County: Rowan 't Stream Ch`aracteristi�cs. Receiving Stream North Second Creek Stream Classification C Subbasin 03-07-06 Drainage Area (mi2): 116 Summer 7Q10 (cfs) 6.9 Winter 7Q10 (cfs): 23 Average Flow (cfs): 116 IWC (%) @ 2.305 MGD: 34% 4 F sz, + -' Y. d 4. .•-/t. f_..: ._.._ .....'Y%.1. _ v E, .....:Y.. fx_ . `i. t..... . • Qa/�a *+ y'Q t 4I t .. it...... '.: iscellano�is..t u,!.i � .. _F �, I',' 3 � xefc%.. ... �, f . Regional Office: Mooresville USGS Topo Quad: E16NE Permit Writer: Mark McIntire Date: Updated January 12, 2000 Summary Arteva Specialties, S_a.r.l. d/b/a KOSA, formerly known as HNA Holdings, Inc., has applied for a renewal of the NPDES permit for its Salisbury facility. The facility manufactures polyester in chip and fiber form. As such, 40 CFR 414.30 and 414.40 (OCPSF federal guidelines) are applicable. Primary raw materials include terephthalic acid, ethylene glycol, and fiber finish oils. The facility was originally permitted in 1980 at a flow of 1.2 MGD. A modification request accompanied the permit renewal request received in 1992. At that time, Hoechst Celanese requested an increase in total flow from 1.2 MGD to 2.305 MGD to accommodate the discharge of remediated groundwater associated with a RCRA site stabilization plan. At the same time, new stream flows were requested from USGS. The flows provided by USGS were half what they had been when the permit was developed at 1.2 MGD. BOD5 was, and remains, water quality limited. Ammonia limitations are present as well to keep a check on NBOD. According to the NPDES permit application, approximately 1.6 MGD of wastewater is expected to be generated on any given day. Wastewater is broken down into the following components: Finish: 0.114 MGD Bandcaster: 0.08 MGD Cooling towers: 0.148 MGD Process: 0.082 MGD Groundwater: 0.616 MGD Domestic: 0.05 MGD Boilers d? Chillers: WTP Backwash: Process Stormwater: 0.116 MGD 0.09 MGD 0.304 MGD 1.6 MGD Total In accordance with EPA guidance, an actual average wasteflow was determined using data from January 1995 — August 1998. The actual average flow has been determined to be 1.5058 MGD. Of that 1.5058, approximately 0.979 MGD is considered process with an additional 300,000 gpd from process stormwater. Finish and Bandcaster wastewaters, making up approximately 19.8% of the process wastewater, are produced from fiber manufacturing and are regulated by 40 CFR 414. Subpart C. The remaining 80.2% of process wastewater comes from the contact cooling towers, resin processing, remediated groundwater, and process stormwater is regulated by 40 CFR 414, Subpart D. The attached spreadsheet summarizes the guideline calculations and actual average flow determination. The wastewater treatment facility is a biological process consisting of screening. equalization, aeration basins, clarification, polishing ponds, aerobic sludge digestion and sludge dewatering. Recovered groundwater is anaerobically pretreated prior to discharge to the equalization basin referenced above. The primary contaminant found in the groundwater is ethylene glycol, however 1,4-dioxane has also been detected. Groundwater pretreatment consists of ultraviolet treatment and addition of peroxide. As this is an end -of -pipe biological treatment system, 40 CFR 414, Subpart 1 applies. The second attached spreadsheet calculates Subpart I allocations. For water quality limited parameters, concentration -based limitations have been installed on permit page A(2) in accordance with state standards and/or EPA criteria. As there are no clearly defined metal -bearing or cyanide - bearing wastestreams, limits for total chromium, total copper, total cyanide, total lead, total nickel and total zinc do not apply. This permit also authorizes the discharge of stormwater. Stormwater requirements are outlined in Part I, A(4) and A(5). Proposed Changes • Permittee name: Per permittee request, the owner name of this facility has been changed from Hoechst Celanese Corporation to HNA Holdings, Incorporated. • BOD5 and TSS allocations: Allocations for BOD5 remain unchanged as they are water quality limited. Allocations for TSS were previously based on a process wasteflow of 1.2 MGD. These allocations have been revised using the past 3.5 years worth of daily flow data to compute an average. Allocations were computed in accordance with the attached spreadsheet. • Biocide Condition: The biocide condition, formerly condition F. has been deleted. This condition is not necessary as the biocide laden waste streams are subject to chronic toxicity testing at outfall 001. • Subpart I Monitoring: Subpart I requirements have been updated on page A(2) of the draft permit. These parameters have changed slightly since the permit was issued last. Additionally, the monitoring frequency for Subpart I requirements has been changed from quarterly to annually due to continued non -detection of these parameters. Total copper, iron, manganese and total zinc have been included on effluent page A(1) due to their common presence in the effluent from outfall 001. Monthly monitoring has been installed for these parameters. Of the other subpart I parameters, only benzene and bis(2-ethylhexyl) phthalate (an organic vacuum pump lubricant) have been detected during the previous 3.5 years, therefore monitoring for these parameters remains quarterly. Toxici : Type of Toxicity Test: Existing Limit: Recommended Limit: Monitoring Schedule: Chronic P/F 001: Chronic P/F @ 34% 001: Chronic P/F @ 34% February, May, August, November This facility has been in compliance with its toxicity testing requirement for at least the past 3 years. Metals: Total copper, total zinc, iron and manganese remain on effluent page A(1). All other metals are monitored annually in conjunction with subpart I requirements. Instream Monitoring: Conductivity, temperature, and dissolved oxygen are monitored upstream and downstream. The HNA discharge does not appear to be affecting dissolved oxygen but is having an impact on downstream conductivity and temperature. The HNA discharge appears to be elevating instream conductivity by about 10 µmhos/cm on average, with an average downstream value of about 100. The HNA discharge also appears to be elevating instream temperature by about 1°C. Proposed Schedule for Permit Issuance: Draft Permit to Public Notice: August 11, 1999 Permit Scheduled to Issue: September 27, 1999 State Contact: If you have any questions on any of the above information or on the attached draft permit, please contact Mark McIntire at (919) 735-5038 ext. 553. • Arfeva Specialites, S.a.r.1. d/b/a KOSA - Salisbury Plant NC0004944 Month I Flow Jan-95 0.987 Feb-95 1.067 Mar-95 1.519 Apr-95 1.425 May-95 1.428 Jun-95 1.916 Jul-95 1.494 Aug-95 1.495 Sep-95 1.568 Oct-95 1.535 Nov-95 1.542 Dec-95 1.542 Jan-96 1.514 Feb-96 1.478 Mar-96 1.519 Apr-96 1.465 May-96 1.517 Jun-96 1.532 Jul-96 1.508 Aug-96 1.577 Sep-96 1.63 Oct-96 1.574 Nov-96 1.589 Dec-96 1.571 Jan-97 1.601 Feb-97 1.655 Mar-97 1.696 Apr-97 1.643 May-97 1.544 Jun-97 1.531 Jul-97 1.62 Aug-97 1.445 Sep-97 1.446 Oct-97 1.594 Nov-97 1.508 Dec-97 1.538 Jan-98 1.601 Feb-98 1.525 Mar-98 1.464 Apr-98 1.518 May-98 1.392 Jun-98 1.485 Jul-98 1.252 Aug-98 1.205 Average Flow from 1/95 - 8/98: 1.5058 MGD Information provided by KOSA with this permit renewal indicates that outfall 001 is designed to discharge 1.6 MGD. Of that, approximately 65% can be considered process wastewater on any given day. Applying this 65% to the average flow computed above yields an actual average process flow for the investigation period of: 0.978767 MGD. Actual average process flow: 0.97877 MGD plus 0.304 MGD of process stormwater => The process wastewater flow at this facility is split between two 40 CFR 414 subparts, subparts C and D. Approximately 19.8% is subpart C process wastewater with the difference being subpart D process WW. The subparts are summarized below: 40 CFR 414.31 (Subpart C - All units are mg/L) Daily Maxi Mon. Avg. GODS TSS 48 115 18 36 40 CFR 414.41 (Subpart D - All units are mg/L) I Daily Maxi Mon. Avg. GODS TSS 64 130 24 40 Process Flow applicable to subpart C: 0.25399 MGD Process Flow applicable to subpart D: 1.02878 MGD Subpart C Allocation - lbs/day (Daily Maxi Mon. Avg. BODE TSS 101.67643 243.59977 38.12866 76.25732 Subpart D Allocation - lbs/day Daily Maxi Mon. Avg. BODS TSS 549.12117 1115.4024 205.92044 343.20073 Domestic Allocation (Q = 60,500 gpd) - Assuming secondary limits - lbs/day Daily Maxi Mon. Avg. SODS TSS 22.70565 22.70565 15.1371 15.1371 Total Allocation (Sum of C, D, and Domestic) - lbs/day I Daily Maxi Mon. Avg. BODS TSS 674 1382 259 435 BODS TSS Existing Allocation I Daily Max I Mon. Avg. 300 1349 150 505 1.28277 Mark McIntire 4 0.136 MGD HOECHST CELANESE CORPORATION SALISBURY, NORTH CAROLINA WATER FLOW SCHEMATIC SANITARY f GROUNDWATER .531 MGD EVAP 0.100 MGD 0 WASTE TREATMENT PLANT OUTFALL N. SECOND CREEK 1.601 MGD STORM WATER 0.304 MGD FINISH 0.136 MGD 0.214 MGD A 0 BOILERS AND CHILLERS 0 EVAP 0,284 MGD CO 0 0\ O EVAP COOLING TOWERS 0.50 MGD D BANCASTERS A 0.274 MGD to r cD c-3 cu co 0 co 0 0 PROCESS 0.394 MGD 0.090 MGD BLOWDOWN CITY WATER 0.350 MGD INTAKE N. SECOND CREEK 1.23 MGD WATER TREATMENT PLANT 0.070 MGD REACTION BYPRODUCT OCPSF Subpart I Calculations FACILITY => NPDES Permit # _> OCPSF now => 7Q10s => QP => Dilution => 11NA Holdings - Salisbury \C0004944 1.28 MGD 6.9 cfs 2.305 MGD 2.9312854 Parameter OCPSF Daily Maximum pg/L OCPSF Monthly Average ltg/L OCPSF Daily Maximum lbs/day OCPSF Monthly Average lbs/day Federal Criteria or State Standard Standard Aquatic Life Pg/L Human Health Standard µg/L Allowable Aquatic Life µg/L Allowable Human Health ltg/L Allowable Aquatic Life lbs/day Allowable Human Health Ibs/day Limit Based On: Monthly Daily Average Maximum Limit Limit lbs/day \,r„ , i1,1hvnc 59 22 0.630 0.235 PC Acenaphth*lenc 59 22 0.630 0.235 PC Acrylonitrile 242 96 2.583 1.025 PC Anthracene 59 22 0.630 0.235 PC Benzene 136 37 1.452 0.395 SS Benzo(a)anthracene 59 22 0.630 0.235 FC 3,4-Benzofluoranthene 61 23 0.651 0.246 FC Benzo(Idlluoranthene 59 22 0.630 0.235 FC Bcnzo(a)pyrene 61 23 0.651 0.246 PC Bis(2-ethylhexyl) phthalate 279 103 2.978 1.100 PC Carbon Tetrachloride 38 18 0.406 0.192 SS Chlorobenzene 28 15 0.299 0.160 PC Chloroethane 268 104 2.861 1.110 PC Chloroform 46 21 0.491 0.224 5S 2-Chlorophenol 98 31 1.046 0.331 PC Cltrysene 59 22 0.630 0.235 PC Dim -butyl phthalate 57 27 0.608 0.288 PC 1.2•Dichlorobenzene 163 77 1.740 0.822 PC 1,3-Dichlorobenzene 44 31 0.470 0.331 PC 1.4-Dichlorobenzenc 28 15 0.299 0.160 PC 1.1-Dichloroethane 59 22 0.630 0.235 FC 1.2-Dichloroethane 211 68 2.252 0.726 FC I.1-Dichloroethylene 25 16 0.267 0.171 PC 1.2-trans-Dichlorocthylenc 54 21 0.576 0.224 PC 2,4-Dichlorophenol 112 39 1.196 0.416 PC I,2•Dichloropropane 230 153 2.455 1.633 PC I,3-Dichloropropylene 44 29 0.470 0.310 PC Diethyl phthalate 203 81 2.167 0.865 PC 2.4-Dimethylphenol 36 18 0.384 0.192 PC Dimethyl phthalate 47 19 0.502 0.203 PC 4.6-Dinitro-o-cresol 277 78 2.957 0.833 PC 2,4-Dinitrophenol 123 71 1.313 0.758 PC 2,4-Dinitrotoluene 285 113 3.042 1.206 FC 2,6•Dinitrotoluene 641 255 6.843 2.722 PC Ethylbenzene 108 32 1.153 0.342. FC Fluoranthene 68 25 0.726 0.267 PC Fluorene 59 22 0.630 0.235 FC Iiexachlorobenzene 28 15 0.299 0.160 PC Iiexachlorobutadiene 49 20 0.523 0.214 SS Ilexachloroethane 54 21 0.576 0.224 PC Methyl Chloride 190 86 2.028 0.918 FC Methylene Chloride 89 40 0.950 0.427 FC none 2700 none 791-1.-17 none none none none none none none 0.66 none 1.93 none none 110000 none 322441.40 none none 71.4 none 209.29 none none 0.031 none 0.09 none none none none none none none 0.031 none 0.09 none none 0.031 none 0.09 none none 5.9 none 17.29 none none 4.42 none 12.96 none none 21000 none 61556.99 none none none none none none none 470 none 1377.70 none none 400 none 1172.51 none none 0.031 none 0.09 none none none none none none none 17000 none 49831.85 none none 2600 none 7621.34 none none 2600 none 7621.34 none none none none none none none 99 none 290.20 none none 3.2 none 9.38 none none none none none none none 790 none 2315.72 none none 39 none 114.32 none none 1700 none 4983.19 none none 120000 none 351754.25 none none 2300 none 6741.96 none none 2900000 none 8500727.73 none none none none none none none 14000 none 41038.00 none none 9.1 none 26.67 none none none none none none none 29000 none 85007.28 none none 370 none 1084.58 none none 14000 none 41038.00 none none 0.00077 none 0.00 none none 49.7 none 145.68 none none 8.9 none 26.09 none none none none none none none 1600 none 4600.06 none 152.15 OCPSF none OCPSF 0.04 CHRONIC 6198.52 OCPSF 4.02 OCPSF 0.00 CHRONIC none OCPSF 0.00 CHRONIC 0.00 CHRONIC 0.33 CHRONIC 0.25 CHRONIC 1183.35 OCPSP none OCPSF 26.48 OCPSF 22.54 OCPSF 0.00 CI IRONIC none OCPSP 957.95 OCPSF 146.51 OCPSF 146.51 OCPSF none OCPSF 5.58 OCPSF 0.18 CHRONIC none OCPSF 44.52 OCPSF 2.20 CHRONIC 95.80 OCPSF 6762.02 OCPSF 129.61 OCPSF 163415.44 OCPSP none OCPSF 788.90 OCPSF 0.51 CHRONIC none OCPSF 1634.15 OCPSF 20.85 OCPSF 788.90 OCPSF 0.00 CHRONIC 2.80 OCPSF 0.50 CHRONIC none OCPSF 90.16 OCPSF 0.630 lbs/day 0.235 0.630 lbs/day 0.235 1.935 ug/L 0.630 lbs/day 0.235 1.452 lbs/day 0.395 0.091 ug/L 0.651 lbs/day 0.246 0.091 ug/L 0.091 ug/L 17.295 ug/L 12.956 ug/L 0.192 0.299 Ibs/day 0.160 2.861 lbs/day 1.110 0.491 lbs/day 0.224 1.046 lbs/day 0.331 0.091 ug/L 0.608 lbs/day 0.288 1.740 lbs/day 0.822 0.470 lbs/day 0.331 0.299 lbs/day 0.180 0.630 lbs/day 0.235 2252 Ibs/day 0.726 9.380 ug/L 0.171 0.576 lbs/day 0.224 1.196 Ibs/day 0.416 114.320 ug/L 1.633 0.470 lbs/day 0.310 2.167 lbs/day 0.865 0.384 lbs/day 0.192 0.502 lbs/day 0.203 2.957 lbs/day 0.833 1.313 Ibs/day 0.758 26.675 ug/L 6.843 lbs/day 2.722 1.153 lbs/day 0.342 0.726 lbs/day 0.267 0.630 lbs/day 0.235 0.002 ug/L 0.523 lbs/day 0.214 26.088 ug/L 0.224 2.028 Ibs/day 0.918 0,950 lbs/day 0.427 01/12/2000 OCPSF Subpart I Calculations Parameter OCPSF Daily Maximum itg/L OCPSF Monthly Average ltg/L OCPSF Daily Maxiutum lbs/day OCPSF Monthly Average lbs/day Federal Criteria or State Standard Standard Aquatic Life pg/L Human Health Standard Ng/L Allowable Aquatic Life it6/L Allowable Human Health ug/L Allowable Aquatic Life lbs/day Allowable Human Health lbs/day Limit Based On: Daily Maximum Limit Monthly Average Limit lbs/day Naphthalene 59 22 0.650 0.235 PC none none none none none none OCPSF 0.630 lbs/day 0.235 Nitrobenzene 68 27 0.726 0.288 PC none 1900 none 5569.44 none 107.07 OCPSF 0.726 Ibs/day 0.288 2-Nit•ophenol 69 91 0.737 0.438 PC none none none none none none OCPSF 0.737 lbs/day 0.438 4.Nitrophenol 124 72 1.324 0.769 PC none none none none none none OCPSF 1.324 lbs/day 0.769 Phenanthrene 59 22 0.630 0.235 FC none none none none none none OCPSF 0.630 lbs/day 0.235 Phenol 26 15 0.278 0.160 PC none 4600000 none 13983912.95 none 259210.70 OCPSF 0.278 Ibs/day 0.160 Pyrene 67 25 0.715 0.267 PC none 11000 none 32294.19 none 619.85 OCPSF 0.715 lbs/day 0.267 Tetrachloroethylene 56 22 0.598 0.235 55 none 8.85 none 25.94 none 0.50 CI IRONIC 25.942 ug/L 0.235 Toluene 80 26 0.854 0.278 SS 11 200000 52.24 586257.08 0.62 11270.05 CHRONIC 32.244 ug/L 0.278 Total Chromium 2770 1 110 29.570 11.899 SS 50 none 196.56 none 2.82 none CI IRONIC 196.564 ug/L Total Copper 3380 1450 36.082 15.479 SS•AL 7 none 20.52 none 0.39 none CI IRONIC 20.519 ug/L Total Cyanide 1200 420 12.810 4.484 SS 5 220000 14.66 694882.79 0.28 12397.03 CHRONIC 14.656 ug/L Total Lead 690 320 7.366 3.416 55 25 none 73.28 none 1.41 none CHRONIC 73.282 ug/L Total Nickel 3980 1690 42.487 18.011 SS 88 4600 257.95 13483.91 4.96 259.21 CHRONIC 257.953 ug/L Total Zinc 2610 1050 27.862 11.209 SS•AL 50 50 196.56 146.56 2.82 2.82 CHRONIC 196.569 ug/L 1.2.4-Trichlorobenzene 140 68 1.495 0.726 PC none none none none none none OCPSF 1.495 lbs/day 0.726 I.I,I•Frichloroethane 54 21 0.576 0.224 PC none none none none none none OCPSF 0.576 lbs/day 0.224 1,1.2=1-richloroethane 54 21 0.576 0.224 FC none 42 none 123.11 none 2.37 OCPSF 0.576 lbs/day 0.224 Trichloroethylene 54 21 0.576 0.224 FC none 81 none 237.93 none 4.56 OCPSF 0.576 Ihs/day 0.224 Vinyl Chloride 268 104 2.861 1.110 SS none 525 none 1538.92 none 29.58 OCPSF 2.861 lbs/day 1.110 01/12/2000 HNA Holdings, Inc. Water Quality Limited OCPSF Data NC0004944 Jan-95 [ Feb-95 I Mar-95 I Apr-95 May-95j Jun-951 Jul-95 Aug-95I Sep-95 Oct-951 Nov-951 Dec-95 Acrylonitrile Benzene Carbon Tetrachloride Hexachlorobenzene 1,2-Dichloroe thane 1,1,2-Trichloroethane 1,1-Dichloroethylene 1,2-Dichloropropane 1,3-Dichloropropylene 2,4-Dinitrotoluene Hexachlorobutadiene Nitrobenzene 4,6-Dinitro-o-cresol Bis(2-ethylhexyl) phthalate Tetrachloroethylene toluene Vinyl Chloride < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < 30 15 32 120 43 24 < 99 9.8 18 5.8 60 < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < Jan-961 Feb-96I Mar-961 Apr-96I May--96I Jun-961 Jul-961 Aug-961 Sep-961 Oct-96j Nov 96I Dec-96 Acrylonitrile Benzene Carbon Tetrachloride Hexachlorobenzene 1,2-Dichloroethane 1,1,2-Trichloroethane 1,1-Dichloroethylene 1,2-Dichloropropane 1,3-Dichloropropylene 2.4-Dinitrotoluene Hexachlorobutad ie ne Nitrobenzene 4,6-D initro-o-cresol Bis(2-ethylhexyl) phthalate Tetrachloroethylene :toluene Vinyl Chloride < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < 23 < 36 82 86 < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < 94 55 12 10 38 9.6 < < < < < < < < < < < < < < < < < 10/20/98 HNA Holdings, Inc. Water Quality Limited OCPSF Data NC0004944 Acrylonitrile Benzene Carbon Tetrachloride Hexachlorobenzene 1,2-Dichloroethane ,1,2-Trichloroethane 1,1-Dichloroethylene 1,2-Dichloropropane 1 3-Dichlorop ropyle ne 2,4-Dinitrotoluene Hexachlorobutadiene Nitrobenzene 4,6-Dinitro-o-cresol Bis(2-ethylhexyl) phthalate Tetrachloroethylene toluene Vinyl Chloride Jan-971 Feb-97 Mar-971 Apr-971May-97 Jun-971 Jul-97 Aug-97I Sep-97 Oct-971 Nov-971 Dec-97 < < < < < < < < < < < < 0.072 < 0.077 0.063 < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < <. < < < < < < < < < < < < < < < < < < < < < < < < < < C < < < < < < < < < < < < < < < < < < < < < < < < < < < < < 10.8 < 19.5 19 < < 23.6 13.2 66.3 13 37.5 < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < Jan-981 Feb-981 Mar-981 Apr-981 May-981 Jun-981 Jul-98I Aug-98I Sep-981 Oct-981 Nov-981:Dec-98 Acrylonitrile Benzene ,Carbon :Tetrachloride iexachlorobenzene 12-Dchloroethane 11,2-Trichloroethane 1,1-Dichloroethylene 1,2-Dichloropropane 1,3-Dichloropropylene 2,4=Dinitrotoluene Hexachlorobutadiene Nitrobenzene 4,6-Dinitro=o-cresol Bis(2-ethylhexyl) phthalate Tetrachloroethylene toluene Vinyl Chloride < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < < 147 74.7 51.6 < < < < < < < < < < < < < < < < < < < < < < < < < < < < < 10/20/98 Hoechst Celanese October 23, 1998 North Carolina Division of Environmental Management Water Quality Section Permits and Engineering Unit P.O. Box 29535 Raleigh, NC 27626-0535 Reference: NPDES Permit No.: NC0004944 Notice of Ownership Change Dear Sir / Madam: Technical Fibers Group Hoechst Celanese Corporation Highway 70 West, PO Box 4 Salisbury, NC 28144 704 636 6000 HNA Holdings, Inc. (formerly known as Hoechst Celanese Corporation) has sold the assets of its polyester business to ARTEVA Specialties Sarl. This sale of assets includes the Salisbury facility and the business operations that are conducted there. The sale will be effective on November 23, 1998. HNA Holdings, Inc. request that the NPDES permit referenced above be transferred to the ARTEVA Specialties Sarl Corporation. The parties hereby request that the permit be transferred effective November 23, 1998 to the ARTEVA Specialties Sarl Corporation to reflect the change in ownership. Enclosed is a check for $100.00 to pay the fee for this change. We have also enclosed a copy of the "Permit Transfer Agreement" signed by both parties, a partial copy of the October 12, 1998 "Asset Transfer Agreement", and a copy of the "Permit Name/Ownership Change Form". If you have any questions, please call Stephen Lamb at 704-636-6000 (extension 4862) or Bryson Woodlief at 704-636-6000 (extension 4253). Sincerely, A. J. 3ranecky Plant Manager File: npdes.DOC :C Nd 9Z 130 8 to Hoechst El .ACTION COUPON v��MARKETING DEPARTMENT P.O. BOX 36502 CHARLOTTE, N.C. 28236-6502 RONVIEW SERVICES YOU NEED AND MAIL THIS COUPON TO US TODAY! ..ncI.n i rI SHA OTHER SERVICES AVAILABLE SAVINGS LOANS AT S ARONV1EW: — 0 MasterCard ■ Financial Counseling ■ Share (Savings) Account 0 TimeSaver Open Line of Credit ■ Travelers Cheques • ShareChek (Checking) Account 0 Relay Card ■ New Car/Truck Loan ■ Notary Public Services ❑ Christmas Club • Used Car/Truck Loan 0 Official Checks 0 RV, Motorcycle, Boat Loan ■ Wire Transfers • Vacation Club • IRA ■ First or Second Mortgage Loan 0 AIS New Car Guide ■ Certificate of Deposit ■ Home Equity Line of Credit ■ NADA Used Car Guide 0 Home Improvement Loan ■ Payroll Deduction • Money Market Account 0 Other Savings Account ■ Mobile Home Loan ■ Other • Direct Deposit 0 Share Secured Loan NAME MEMBER ACCOUNT NUMBER ADDFIESS CITY, STATE, ZIP CODE PLEASE DETACH BEFORE CASHING •Sharonview Federal Credit Union 13504-A SOUTH POINT BLVD. CHARLOTTE, NC 28273 PAY TO THE ORDER OF SEQ. NORTH CAROLINA DEPT. "41962 Li 31 OF ENVIROMENT & NATURAL 000206861 RESOURCES PERMIT# NC0004944 BRANCH BANKING & TRUST CHARLOTTE, N.C. III 20686LIN 1:053LOLL2LI: 5216433698n'� 0 /tiC )09/tj ACCOUNT 66-112 631 CHECK NO. 206_861 DATE AMOUNT ,�e • .� �*******100.00 j2 /9 $* PLEASE DETACH BEFORE CASHING 37136-03 311745000 10/21/98 ACCOUNT TYPE 100.00 CHECK AMOUNT $ 100.00 0019592 22 000206861 Department of Environment, Health and Natural Resources Division of Environmental Management James B. Hunt, Jr., Governor Jonathan B. Howes, Secretary A. Preston Howard, Jr., P.E., Director Ai-4X NI FR WATER QUALITY SECTION FER11T NAME/OWNERS131P CHANGE JOIM I. CURRENT PERMIT INFO) MATIQN: Permit Number: 1 N l G Iol o IQI q1 91# [91 1. Permit holder's name: /WA NoL.D/NiS /A%d. 2. Permit's signing official's name and title; AN mom' 5RANY (Person leggy responsible for permit) Sire- MMA/A6R (Tide) 3. Mailing address; %7 D. Box 7 City; SAL! s gag)/ State; N L Zip Code; a VHS Phone: f 70 V) 6 3 6 —good II. NEW OWNER/NAME INFORMATION 1. This request for a name change is a nrsult of: Change in ownership of property/company _b. Name change only _c. Other (please explain); 2. New owner's name (name to be put on permit): ART6vA SPEWeet-T1 E'S Se r/ 3. New owner's or signing official's name and title: AM7» oJI Y BRA4/E(XY (Person leggy responsible for permit) S �T� ,litwAGFR ('Pule) 4. Mailing address; f� o. Sox q may; S A `. f Rug f • State; 4/C• Tip Code; 2 V1 45 Phone: (70cf ‘36 —boo 0 OT BE ED BY THE DIVISION THIS APPLICATION PACKAGE WILL N UNLESS ALLCOFPTHE APPLICABLE I EMSOF ENVIRONMENTAL MANAGEMENT LISTED BELOW ARE INCLUDED WITH THE SUBMITTAL. REQUIRED ITEMS: 1. This completed application 2. passing fee of $ 100.00 (Checks to be made payable to DEHNR) 3. If an ownership change, legal documentation of the transfer of ownership (such as a contract, deed, articles of incorporation) CERTIFICATION MUST BE COMPLETED AND SIGNED BYE THE CURRENT PERMIT HOLDER AND THE NEW APPLICANTLY, COMPLETE AND EO F CHANGE OF OWNERSHIP. APPLICANT'S CERTIFICATION. CHANGE Current Permittee's Certification: changebeen NTF+o,NY BRAil ruc Y , attest that this application for name/ownership I and complete to the best of my knowledge. I understand that if all required Parts reviewed and is accurateinformation and attachments are not of this application are not completed and that if all required supporting included, this app cation package will be returned p i G ? I Date Signature- Applicant's Certification: change has been , 1 1c 74"/CZ(` � attest that this application for a name/ownership reviewed and d that all required is accurate and complete to the best of my knowledge. Iinfor�niation and auxhments arepnot of this application are not completed and that if all wcromm�le��g included, application package 'Ube returned l Signature. A Ai jFGK y Date' APPLICATION PACKAGE, INCLUDING ALL SUPPORTING INFORMATION THE MATERIAL SHOULD BE SENT TO THE FOLLOWING ADDRESS: AND MATERIALS, North Carolina Division of Environmental Management Water Quality Section Permits and Engineering Unit P.O. Box 29535 Raleigh, North Carolina 27626-0535 TeleFpax:hone:919)1733-0719083 uL.1 rG 7v 1U . ex rR num.n.71 UMW WR- MICMN OCT-22-1998 13:04 7004aleGn7 I u 71(1114b37d101 f Jt /, outN•- . ♦r t• •... v, -. ♦P.0• •41••I.A PO0.. 4 This Agreement is entered into this date by HNA► Holdings, Inc. and AR.TEVA Spicia}hies Sari in order to effect t transfer of permits issued by NCDENR and the responsblli'ty, coverage, and liability thereunder from RNA Holdings, Inc. to ARTEVA S•'- "yes Sari. tab . certifies that there will be no operational changes that . ARTEVA Speaaraes Sari warrant a permit modification. 1 On the date such transfer becomes effecdve, ARTEVA S Sari agrees to assume the responsibility, coverage, and liabTty of the permit and MA Holdings, Inc. agiiees to relinquish all rights which it may have under said permit. This fitment is entered into by both parties this 21st day of October 1998. Said Wilier is targeted to become effective on the 23rd day of Nove;nber 1998, HNA Holdings, Inc. P.O. Box 4915 Warren, N,J. 07060 908-231-4058 At2201444.01, Witness ARTEVA Specialities Sari BY: James B. Flint Attorney in Fact for ARTEVA International B.V. as &wang party for ARTEVA Specialipes Sari (under formation) W TOTAL P.03 i* TOTAL PAGE.02