HomeMy WebLinkAboutWI0400575_Material Safety Data Sheet_20220208REDOX TECH, LLC
"Providing Innovative In Situ Soil and Groundwater Treatment"
1. Identification
Product identifier
Other means of identification
Recommended use
Recommended restrictions
Material Safety Data Sheet — Oxygen BioChem
Oxygen Biochem (OBC)TM
Not available.
Oxygen Biochem (OBC)TM is used to promote chemical oxidation and aerobic bioremediation of
petroleum compounds in groundwater.
Use in accordance with supplier's recommendations.
Manufacturer/Importer/Supplier/Distributor information
Manufacturer/Supplier
Address
Telephone
E-mail
Contact person
Emergency Telephone
2. Hazard(s) identification
Physical hazards
Health hazards
OSHA defined hazards
Label elements
Signal word
Hazard statement
Precautionary statement
Prevention
Response
Redox Tech, LLC
200 Quade Drive Cary
NC 2751
+1 919-6780140
haselow@redox-tech.com
Dr. John Haselowi
For Hazardous Materials [or Dangerous Goods] Incidents ONLY
(spill, leak, fire, exposure or accident), call CHEMTREC at
CHEMTREC®, USA: 001 (800) 424-9300
CHEMTREC®, Mexico (Toll -Free - must be dialed from within country):
01-800-681-9531
CHEMTREC®, Other countries: 001 (703) 527-3887
Oxidizing solids Category 3
Acute toxicity, oral
Skin corrosion/irritation
Serious eye damage/eye irritation
Sensitization, respiratory
Sensitization, skin
Specific target organ toxicity, single exposure
Not classified.
Category 4
Category 2
Category 2
Category 1
Category 1
Category 3 respiratory tract irritation
Danger
May intensify fire; oxidizer. Harmful if swallowed. Causes skin irritation. Causes serious eye
irritation. May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause an
allergic skin reaction. May cause respiratory irritation.
Keep away from heat. Keep/Store away from clothing and other combustible materials. Take any
precaution to avoid mixing with combustibles. Wear protective gloves/eye protection/face
protection. Wash thoroughly after handling. Do not eat, drink or smoke when using this product.
Avoid breathing dust/fume. In case of inadequate ventilation wear respiratory protection.
Contaminated work clothing must not be allowed out of the workplace. Use only outdoors or in a
well -ventilated area.
In case of fire: Use foam, carbon dioxide, dry powder or water fog for extinction. If swallowed: Call
a poison center/doctor if you feel unwell. Rinse mouth. If on skin: Wash with plenty of water. If
skin irritation or rash occurs: Get medical advice/attention. Take off contaminated clothing and
wash before reuse. If in eyes: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical
advice/attention. If inhaled: If breathing is difficult, remove person to fresh air and keep
comfortable for breathing. If experiencing respiratory symptoms: Call a poison center/doctor.
Oxygen Biochem (OBC)TM
920293 Version #: 01 Revision date: - Issue date: 09-May-2014
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Storage
Disposal
Hazard(s) not otherwise
classified (HNOC)
Store in a well -ventilated place. Keep container tightly closed. Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.
None known.
3. Composition/information on ingredients
Mixtures
Chemical name CAS number
Sodium persulfate
7775-27-1 70 - 90
Calcium peroxide
1305-79-9 10 - 20
Composition comments
4. First -aid measures
Inhalation
Skin contact
Eye contact
Ingestion
Most important
symptoms/effects, acute and
delayed
Indication of immediate
medical attention and special
treatment needed
General information
5. Fire -fighting measures
Suitable extinguishing media
Unsuitable extinguishing
media
Specific hazards arising from
the chemical
Special protective equipment
and precautions for firefighters
Fire -fighting
equipment/instructions
General fire hazards
All concentrations are in percent by weight unless ingredient is a gas. Gas concentrations are in
percent by volume.
Move to fresh air. Do not use mouth-to-mouth method if victim inhaled the substance. For
breathing difficulties, oxygen may be necessary. Call a physician or poison control center
immediately.
Remove and isolate contaminated clothing and shoes. For minor skin contact, avoid spreading
material on unaffected skin. Wash clothing separately before reuse. If skin irritation or an allergic
skin reaction develops, get medical attention.
Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if
present and easy to do. Continue rinsing. Get medical attention if irritation develops and persists.
Rinse mouth. Do not induce vomiting without advice from poison control center. If vomiting occurs,
keep head low so that stomach content doesn't get into the lungs. Do not use mouth-to-mouth
method if victim ingested the substance. Induce artificial respiration with the aid of a pocket mask
equipped with a one-way valve or other proper respiratory medical device. Get medical attention if
any discomfort continues.
May cause redness and pain. Symptoms may include coughing, difficulty breathing and shortness
of breath.
Provide general supportive measures and treat symptomatically.
Ensure that medical personnel are aware of the material(s) involved, and take precautions to
protect themselves.
Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2).
None known.
Contact with combustible material may cause fire.
Self-contained breathing apparatus and full protective clothing must be worn in case of fire.
In the event of fire, cool tanks with water spray.
May intensify fire; oxidizer.
6. Accidental release measures
Personal precautions,
protective equipment and
emergency procedures
Methods and materials for
containment and cleaning up
Environmental precautions
Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Wear
appropriate protective equipment and clothing during clean-up. Do not touch damaged containers
or spilled material unless wearing appropriate protective clothing. Avoid skin contact and inhalation
of vapors during disposal of spills. Ventilate closed spaces before entering them. Local authorities
should be advised if significant spillages cannot be contained. For personal protection, see Section
8 of the SDS.
Stop the flow of material, if this is without risk. Prevent entry into waterways, sewer, basements or
confined areas. Following product recovery, flush area with water. For waste disposal, see Section
13 of the SDS.
Avoid discharge into drains, water courses or onto the ground.
Oxygen Biochem (OBC)TM
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7. Handling and storage
Precautions for safe handling
Conditions for safe storage,
including any incompatibilities
Avoid inhalation of vapors/dust and contact with skin and eyes. Wash thoroughly after handling.
Keep away from clothing and other combustible materials. Use only with adequate ventilation. Do
not taste or swallow. Wear appropriate personal protective equipment (See Section 8). Observe
good industrial hygiene practices.
Store in original tightly closed container. Store away from incompatible materials (See Section 10).
Keep locked up.
8. Exposure controls/personal protection
Occupational exposure limits
US. ACGIH Threshold Limit Values
Components
Type Value
Sodium persulfate (CAS TWA 0.1 mg/m3
7775-27-1)
Biological limit values No biological exposure limits noted for the ingredient(s).
Appropriate engineering Observe occupational exposure limits and minimize the risk of exposure. Ensure adequate
controls ventilation, especially in confined areas.
Individual protection measures, such as personal protective equipment
Eye/face protection
Skin protection
Hand protection
Other
Respiratory protection
Thermal hazards
General hygiene
considerations
9. Physical and chemical
Appearance
Physical state
Form
Color
Odor
Odor threshold
pH
Melting point/freezing point
Initial boiling point and boiling
range
Flash point
Evaporation rate
Flammability (solid, gas)
Wear safety glasses with side shields (or goggles).
Wear protective gloves.
Neoprene or rubber gloves are recommended. Apron and long sleeves are recommended.
In the case of respirable dust, use self-contained breathing apparatus. Wear positive pressure
self-contained breathing apparatus (SCBA).
Wear appropriate thermal protective clothing, when necessary.
Always observe good personal hygiene measures, such as washing after handling the material
and before eating, drinking, and/or smoking. Routinely wash work clothing and protective
equipment to remove contaminants.
properties
Off-white, granular solid.
Solid.
Solid.
Off-white.
Odorless.
Not available.
11.7±0.4 (1-40% solution, slurry)
Not available.
Not applicable.
Not available.
Not available.
Not available.
Upper/lower flammability or explosive limits
Flammability limit - lower
(%)
Flammability limit - upper
(%)
Explosive limit - lower (%)
Explosive limit - upper (%)
Vapor pressure
Vapor density
Relative density
Not available.
Not available.
Not available.
Not available.
Not applicable.
Not applicable.
2.76±0.16 (25°C)
Oxygen Biochem (OBC)TM
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Solubility(ies)
Solubility (water)
Partition coefficient
(n-octanol/water)
Auto -ignition temperature
Decomposition temperature
Viscosity
Other information
Oxidizing properties
10. Stability and reactivity
Reactivity
Chemical stability
Possibility of hazardous
reactions
Conditions to avoid
Incompatible materials
Hazardous decomposition
products
Soluble in water.
Not available.
Not available.
Not available.
Not available.
Oxidizing.
The product is stable and non -reactive under normal conditions of use, storage and transport.
Material is stable under normal conditions.
No dangerous reaction known under conditions of normal use.
Contact with combustibles.
Combustible material. Oxidizing material. Reducing agents.
No hazardous decomposition products are known.
11. Toxicological information
Information on likely routes of exposure
Ingestion
Inhalation
Skin contact
Eye contact
Symptoms related to the
physical, chemical and
toxicological characteristics
Information on toxicological effects
Acute toxicity
Skin corrosion/irritation
Serious eye damage/eye
irritation
Respiratory or skin sensitization
Respiratory sensitization
Skin sensitization
Germ cell mutagenicity
Carcinogenicity
Reproductive toxicity
Specific target organ toxicity -
single exposure
Specific target organ toxicity -
repeated exposure
Aspiration hazard
Chronic effects
Further information
12. Ecological information
Ecotoxicity
Persistence and degradability
Bioaccumulative potential
Harmful if swallowed.
May cause irritation to the respiratory system.
Causes skin irritation.
Causes serious eye irritation.
May cause redness and pain. Exposed individuals may experience eye tearing, redness, and
discomfort. Symptoms may include coughing, difficulty breathing and shortness of breath.
Harmful if swallowed.
Causes skin irritation.
Causes serious eye irritation.
May cause allergy or asthma symptoms or breathing difficulties if inhaled.
May cause an allergic skin reaction.
No data available.
This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA.
No data available.
May cause respiratory irritation.
No data available.
Not applicable.
Prolonged exposure may cause chronic effects.
No data available.
This product's components are not classified as environmentally hazardous. However, this does
not exclude the possibility that large or frequent spills can have a harmful or damaging effect on
the environment.
No data is available on the degradability of this product.
No data available for this product.
Oxygen Biochem (OBC)TM
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Mobility in soil
Other adverse effects
Not available.
No data available.
13. Disposal considerations
Disposal instructions
Hazardous waste code
Waste from residues / unused
products
Contaminated packaging Empty containers should be taken to an approved waste handling site for recycling or disposal.
Consult authorities before disposal. Dispose in accordance with all applicable regulations.
The Waste code should be assigned in discussion between the user, the producer and the waste
disposal company.
Dispose of in accordance with local regulations.
14. Transport information
DOT
UN number UN1479
UN proper shipping name Oxidizing solid, n.o.s. (Sodium persulfate)
Transport hazard class(es)
Class 5.1
Subsidiary risk
Packing group II
Environmental hazards
Marine pollutant No
Special precautions for user Read safety instructions, SDS and emergency procedures before handling.
Special provisions 62, IB5, IP1
Packaging exceptions None
Packaging non bulk 211
Packaging bulk 242
IATA
UN number UN1479
UN proper shipping name Oxidizing solid, n.o.s. (Sodium persulfate, Calcium peroxide)
Transport hazard class(es)
Class 5.1
Subsidiary risk
Label(s) 5.1
Packing group II
Environmental hazards No
ERG Code 5L
Special precautions for user Read safety instructions, SDS and emergency procedures before handling.
IMDG
UN number UN1479
UN proper shipping name OXIDIZING SOLID, N.O.S. (Sodium persulfate, Calcium peroxide)
Transport hazard class(es)
Class 5.1
Subsidiary risk
Label(s) 5.1
Packing group II
Environmental hazards
Marine pollutant No
EmS F-A, S-Q
Special precautions for user Read safety instructions, SDS and emergency procedures before handling.
Transport in bulk according to This product is not intended to be transported in bulk.
Annex II of MARPOL 73/78 and
the IBC Code
15. Regulatory information
US federal regulations This product is a "Hazardous Chemical' as defined by the OSHA Hazard Communication
Standard, 29 CFR 1910.1200.
All components are on the U.S. EPA TSCA Inventory List.
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)
Not regulated.
Oxygen Biochem (OBC)TM
920293 Version #: 01 Revision date: - Issue date: 09-May-2014
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US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not listed.
CERCLA Hazardous Substance List (40 CFR 302.4)
Not listed.
Superfund Amendments and Reauthorization Act of 1986 (SARA)
Hazard categories Immediate Hazard - Yes
Delayed Hazard - Yes
Fire Hazard - Yes
Pressure Hazard - No
Reactivity Hazard - No
SARA 302 Extremely hazardous substance
Not listed.
SARA 311/312 Hazardous Yes
chemical
SARA 313 (TRI reporting)
Not regulated.
Other federal regulations
Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
Not regulated.
Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
Not regulated.
Safe Drinking Water Act Not regulated.
(SDWA)
US state regulations This product does not contain a chemical known to the State of California to cause cancer, birth
defects or other reproductive harm.
US. Massachusetts RTK - Substance List
Not regulated.
US. New Jersey Worker and Community Right -to -Know Act
Calcium peroxide (CAS 1305-79-9)
Sodium persulfate (CAS 7775-27-1)
US. Pennsylvania Worker and Community Right -to -Know Law
Not listed.
US. Rhode Island RTK
Not regulated.
US. California Proposition 65
US - California Proposition 65 - Carcinogens & Reproductive Toxicity (CRT): Listed substance
Not listed.
International Inventories
Country(s) or region Inventory name On inventory (yes/no)*
Australia Australian Inventory of Chemical Substances (AICS) Yes
Canada Domestic Substances List (DSL) Yes
Canada Non -Domestic Substances List (NDSL) No
China Inventory of Existing Chemical Substances in China (IECSC) Yes
Europe European Inventory of Existing Commercial Chemical Yes
Substances (EINECS)
Europe European List of Notified Chemical Substances (ELINCS) No
Japan Inventory of Existing and New Chemical Substances (ENCS) Yes
Korea Existing Chemicals List (ECL) Yes
New Zealand New Zealand Inventory Yes
Philippines Philippine Inventory of Chemicals and Chemical Substances Yes
(PICCS)
United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory Yes
*A "Yes" indicates this product complies with the inventory requirements administered by the governing country(s).
A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing
country(s).
Oxygen Biochem (OBC)TM
920293 Version #: 01 Revision date: - Issue date: 09-May-2014
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16. Other information, including date of preparation or last revision
Issue date
Revision date
Version #
Further information
NFPA Ratings
09-May-2014
01
HMIS® is a registered trade and service mark of the NPCA.
List of abbreviations NFPA: National Fire Protection Association.
References
Disclaimer
Registry of Toxic Effects of Chemical Substances (RTECS)
HSDB® - Hazardous Substances Data Bank
The information contained herein is accurate to the best of our knowledge. However, data, safety
standards and government regulations are subject to change and, therefore, holders and users
should satisfy themselves that they are aware of all current data and regulations relevant to their
particular use of product. CARUS CORPORATION DISCLAIMS ALL LIABILITY FOR RELIANCE
ON THE COMPLETENESS OR ACCURACY OR THE INFORMATION INCLUDED HEREIN.
CARUS CORPORATION MAKES NO WARRANTY, EITHER EXPRESS OR IMPLIED,
INCLUDING, BUT NOT LIMITED TO, ANY WARRANTIES OF MERCHANTIABILITY OR FITNESS
FOR PARTICULAR USE OR PURPOSE OF THE PRODUCT DESCRIBED HEREIN. All conditions
relating to storage, handling, and use of the product are beyond the control of Carus Corporation,
and shall be the sole responsibility of the holder or user of the product.
(Carus and design) is a registered service mark of Carus Corporation.
Oxygen Biochem (OBC)TM
920293 Version #: 01 Revision date: - Issue date: 09-May-2014
SDS US
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