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WI0100012_Complete File - Historical_20220307
1' LEGGETTE, BRASHEARS & GRAHAM, INC. PROFESSIONAL GROUND-WATER AND ENVIRONMENTAL ENGINEERING SERVICES M TAYLOR STATION COMMERCE CENTER D O �'j 950 TAYLOR STATION ROAD,SUITE K D GAHANNA.OH 43230 614-416-9100 FAX 614416-9101 FEB - 4 2003 www.lbgweb.com ASH OUNEO REGIONAL OFOF CE February 3, 2003 W. Mark Pritzl UIC Program Groundwater Section North Carolina DENR-DWQ 2728 Capital Blvd. Raleigh,NC 27604 RE: Proposed Amendment to Injection Well Permit BorgWarner Facility; Fletcher,North Carolina Dear Mr. Pritzl: In October 2002, Leggette, Brashears &Graham (LBG) submitted an injection well permit application for a proposed remediation pilot test at the BorgWamer Cooling Systems, Inc. facility in Fletcher, North Carolina. The proposed activities for the remediation pilot test involve the injection of Hydrogen Release CompoundTm (HRC). Following the application submittal,Mr. Qu Qi (the site coordinator with the NCDENR) suggested that the three monitoring wells proposed in the permit application be installed prior to final permit approval to verify conditions at the injection site. In December 2002, LBG installed three monitoring wells (MW-12,MW-13 &MW-14) at the proposed injection site, in accordance with the injection well permit, for the purpose of monitoring ground-water quality prior to and following HRC injection. Following installation, ground-water sampling was conducted to verify VOC concentrations in the proposed pilot test area. The results of the monitoring well installation and subsequent ground-water sampling were summarized in the January 22, 2003 letter report to Eaton from LBG. A copy of the letter report is provided herein for your files. As discussed in our January 13, 2003 telephone conversation,LBG wants to amend the pending permit application to include more injection points in the proposed pilot test area. In the current permit application, there are eight proposed borings drilled at 10-foot spacings in two rows with four borings in each row. LBG would like to increase the number to 21 borings drilled at 10-foot spacings in three rows with seven borings in each row. The locations of the proposed injection borings relative to the pilot test site are shown in Figure 1. MISSOURI ILLINOIS SOUTH DAKOTA PENNSYLVANIA FLORIDA NEW JERSEY MINNE.SOTA TEXAS .. MASSACHUSETTS WISCONSIN NEW YORK CONNECPICUT r^ If you have any questions or require additional clarification on the proposed amendment to the injection well permit, please feel free to contact us. Respectfully submitted, LEGGE=, BRASHEARS &GRAHAM, INC. Doug Hunter Senior Ground-Water Hydrologist cc: Steve Fesko, Eaton Corporation Anastasia Hamel, BorgWarner, Inc. Ray Raymond, BorgWamer Emissions/Thermal Systems Qu Qi,NCDENR LEGGETIEE, BRASHEARS & GRAHAM, INC. � i 1994iaa/ r 1994 1987 1994 i a^ ORIGINAL ADDITION _ ^° BUILDING 1978 ' ' a 1976 � R - 5,"4 4� � T� Sw r, 5V SV SV SV i S S CD a rn a {P-i➢-N�iF-R-iP�N- OFFICES a a 1978 i• i Mw?13 • RBAB M�,1 Mw-S. M`I'1,6a a/v _ 60' R/M N LEGEND t'=1oa' STORM SEWER ¢ SECURITY uGNr FIGURE 1 BURIED ELECTRIC w FIRE HYDRANT Leggette, Brashears & Graham, Inc. -.- BURIED GAS $- MONITORING WELL GAHANNA. ONTO FORMER EATON CORPORATION -•- FIRE PROTECTION .� PROPOSED MONITORING WELL BORGWARNER COOLING SYSTEMS, INC. .- WATER • INJECTION POINT PROPOSED HRC INJECTION POINT -.- BURIED SANITARI' -¢-PROPERTY BOUNDARY FLETCHER., NORTH CAROLINA DATE JANUARY 2003 FLET01' MEMORANDUM Date: November 25,2002 To: Mark Pritzl Underground Injection Control (UIC) Group Groundwater Section, Central Office Through: Landon Davidson, Regional Groundwater Supervisor Asheville Regional Office From: Qi Q u Asheville Re ional Office Subject: UIC Pre-Construction Inspection Former Eaton Facility Cane Creek Industrial Park, Fletcher Henderson County I have reviewed the subject UIC application and visited the site. The information in the application package is accurate and the issuance of the permit is recommended. If you have any questions about the site,please do not hesitate to call me at(828) 251-6208 ext. 228. Page 1 of 2 North Carolina Department of Environment and Natural Resources Division of Water Quality ; Groundwater Section PRECONSTRUCTION INJECTION FACILITY INSPECTION REPORT-FORM A INJECTION WELL PERMIT NO. WI DATE I// t Z o L- NAME OF OWNER ADDRESS OF OWNER 9'r,7C8tt Ce--6.er /7—y2 c' IeyeO _c( DN (Screed road or lot and subdivision,county,town) LOCATION OF PROPOSED INJECTION WELL (and source well(s), if applicable) 4,lear -f-Ge- l CE plan.re. r 4t +"L fv '4 MA 1c4 i n i' `.g 0T-� i -6 (Street road or lot and subdivision,county,tow n,ijdifferent than owner's address,plus description oflocation on site) Potential pollution source N"/Cn vL h, (—<ec Co,„,,, istance from well Potential pollution source Distance from well Potential pollution source Distance from well Minimum distance of proposed well from property boundary e'v r Quality of draina.ge at site c afe- Flooding potential of site (good,a equate,poor) (high,moderate,low) DRAW SKETCH OF SITE (Show property boundaries,buildings, wells,potential pollution sources,roads,approximate scale, and north arrow.) Fcr,ner d r+et, Pcel � nfo p�rcd :n J'ufi.W, h(L c� i V V U Vera/01 GW/UIC-1 PRECONSTRUCTION INJECTION FACILITY INSPECTION REPORT - FORM A (cont.) GPS Data: Latitude 3r 2 $-� j • Longitude: 2 3l;.ff ! COMMMENTS - 1 kx- p ryjoo r-a dv rGG'!'f rti F,Ze.i. r l L'o c LC� ,< 'rAz Ge.�t•2 r ra.Z TCCE pfta e . -f� an v (! do 4-c6, r wNr cl, .WGl .F;j(sd Wklen add - o., w:.s b:.i4f- i., /S7e (h.PIJ uf( : d wefDr— ';&LAr.L,. LIP/IS I+yY'W PZ.w i-Lr �nPu�td iN jLCfftY.� 10444 ,�, ..6a t-b r'r.!!.<:[gs Ar, AS ( HoPfJLrs Crezlc lim�IVIK wp„n.nsZ./ b CA" c,4 ) . `(ll-c C,,f A,l j'l A.�sv.c,.T.� drn;.. <I A.d -1-tc- INSPECTOR On, Office 429D WITNESS k4( vnot Address 3orJr GJtrner Co.,i;w SpSteh,s� Inc L q,nP Cr-wc Acdc Fl.z+cHer c 'UC L �73L WITNESS Address Ver.3/01 GW/UIC-1 is f of + Iv 'It4 gtu i�.J Fi t e, i� i t ra i �#ti k Ntdjit ia4 e a t Photo 1. Main building. To the north of the injection location. k Photo 2. Office building attached to the main building. West of the injection location. !7 . � �w +, • «. • $\ \ � . /���\ \ ��«» • g72 § , . z , . =� - %� •:. > « -- -- M) DIVISION OF WATER QUALITY GROUNDWATER SECTION February 25, 2003 MEMORANDUM To: Landon Davidson, L.G.,Regional Groundwater Supervisor Groundwater Section Asheville Regional Office From: Mark Pritzl 14P Mark.Pritzl@ncmail.net Hydrogeological Technician II UIC Group Groundwater Section Raleigh Central Office Re: issuance of injection well permit type 5I (in-situ Groundwater Remediation Well) Permit Number WI0100012 is for a pilot study to inject an HRC slurry to enhance reductive dechlorination of the dissolved chlorinated solvent contamination at Cane Creek Industrial Park, in the town of Fletcher. Please retain the application paper work and permit copy for the ARO-UIC files. The UIC Program wishes to thank Qu Qi with the review and inspection tasks. If you have any questions regarding this letter or the UIC program,please contact me at(919) 715-6166. rASHEVILL 7 2003 cc: CO-UIC Files Enclosures TER SECTION GIONAL OFFICE t DIVISION OF WATER QUALITY GROUNDWATER SECTION February 19, 2003 MEMORANDUM To: Debra Watts, Supervisor, Permits & Compliance Branch Through: Evan Kane,Hydrogeologist, UIC Program Manager( From: Mark Pritzl, Hydrogeological Technician,UIC Program (A JP 01 Re: Eaton Corporation's injection well application for a Pilot Study to inject HRC to enhance reductive dehalogenation of the dissolved chlorinated solvent contamination. • This site is located in Fletcher, North Carolina and is within the northeast-trending Brevard fault zone, a narrow belt of steeply dipping low-grade metamorphic rocks. These rocks are Cambrian Age prophyroclastic, mylonite and cataclastic schist. The consultant has identified four lithologic zones beneath this site and generally the site geology consist of unconsolidated fill, soil and alluvium, underlain by saprolite and fractured metamorphic rock. See map behind summary. Average depth to the surficial water-table is approximately 8.5 feet at the pilot test area. There is a significant water level(head) difference between deep wells and shallow wells indicating that the surficial aquifer is recharging the semi-confined bedrock aquifer. • cis-1,2-dichloroethene, trichloroethene and 1,1-dichloroethene are the main chlorinated solvent contamination that exist in the surficial aquifer and are the contaminants of interest for this pilot study. • The injection wells used in the injection of HRC will be temporary, utilizing direct push technology, or the GeoProbe, to a depth of 20 feet below ground surface (bls). Twenty one borings will be installed in three rows at intervals of ten feet with seven borings in each row. There has been three monitor wells installed at the proposed injection site, MW-12, MW-13 and MW-14 for the purpose of monitoring groundwater quality prior to and following HRC injection. See map behind summary. • Groundwater samples will be collected at monitor wells MW-12, MW-13 and MW-14 during this pilot study and all three wells are screened from 10-15 feet bls. Prior to HRC injection groundwater samples will be collected from the new monitoring wells. Following HRC injection, the new monitoring wells will be sampled every two months for a period of six months for VOCs and for the following biodegradation indicator parameters; dissolved iron, manganese, sulfide, nitrate, sulfate, chloride, alkalinity, total organic carbon, lactic acid, pyruvic acid, acetic acid, propionic acid and butyric acid. The following gases and other field parameters will also be monitored; carbon dioxide, methane, ethane, ethane, dissolved oxygen, ORP, pH, temperature and ferrous iron. After the first six months the sampling program will be reevaluated to assess the need for continued monitoring. • Groundwater samples will be collected using minimal drawdown sampling procedures that are consistent with the Groundwater Section's policy Memo on Recommended Well Purge ..Volumes from Arthur Mouberry dated February 21, 2001. The applicant has provided sampling results from biodegradation parameters which indicates reductive dechlorination is present in the surficial aquifer. This information is promising and indicates that HRC may increase natural attenuation or reductive dechlorination. This UIC application proposes a simple pilot study utilizing HRC with one up-gradient monitoring well, a monitoring well in the HRC injection grid and one monitoring well down- gradient of the injection grid. At this time the UIC Program recommends that a permit be issued to Eaton Corporation for a pilot study to inject HRC. �OF VATF9v Michael F.Easley,Governor William G.Ross Jr.,Secretary �O G North Carolina Department of Environment and Natural Resources �? r Alan W.Klimek,P.E.Director > 1 Division of Water Quality O -c February 25, 2003 Steve Fesko Eaton Corporation Eaton Center 111 Superior-Avenue Cleveland, OH 44114 Dear Mr. Fesko: In accordance with the application received on October 29, 2002 we are forwarding Permit No. WI0100012. This permit is for a pilot study to inject an HRC slurry to enhance reductive dechlorination of the dissolved chlorinated solvent contamination at Cane Creek Industrial Park,in Fletcher,North Carolina. This permit shall be effective from the date of issuance until February 28,2006,and shall be subject to the conditions and limitations stated therein, including the requirement to submit a final project evaluation as stated in PART VE-MONITORING AND REPORTING REQUIREMENTS. You will also need to notify this office by telephone 48 hours prior to initiation of injection at this facility. In order to continue uninterrupted legal use of this injectant for the stated purpose,you should submit an application to renew the permit three months prior to its expiration date. If you have any questions regarding your permit please contact me at(919)715-6166 or Evan Kane at(919) 715-6165. Sincerely, Mark Pritzl Hydrogeological Technician UIC Program cc: MUM Files ARO-UIC Files Enclosures M Customer Service Division of Water Quality / Groundwater Section 1 800 623-7748 1636 Mail Service Center Raleigh,NC 27699-1636 Phone: (919)733.3221 Fax: (919)715-0588 Internet: hdp://gw.ehnr.state.nc.us NORTH CAROLINA ENVIRONMENTAL MANAGEMENT COMMISSION DEPARTMENT OF ENVIRONMENT AND NATURAL RESOURCES RALEIGH,NORTH CAROLINA PERMIT FOR THE CONSTRUCTION AND OPERATION OF A WELL FOR INJECTION In accordance with the provisions of Article 7, Chapter 87; Article 21, Chapter 143, and other applicable Laws, Rules, and Regulations - PERMISSION IS HEREBY GRANTED TO Eaton Corporation FOR THE CONSTRUCTION AND OPERATION OF A TYPE 5I INJECTION WELL, defined in Title 15A North Carolina Administrative Code 2C .0209(e)(3)(C), to conduct a pilot study to inject a HRCTM slurry for reductive dechlorination of the dissolved chlorinated solvent contamination at this site. These injection wells will be located at Cane Creek Industrial Park, Fletcher,North Carolina, and will be operated in accordance with the application received on October 29, 2002 and in conformity with the specifications and supporting data received on February 4, 2003, all of which are filed with the Department of Environment and Natural Resources and are considered a part of this permit. This permit is for Construction and Operation only, and does not waive any provisions of the Water Use Act or any other applicable Laws, Rules, or Regulations. Operation and use of an injection well shall be in compliance with Title 15A North Carolina Administrative Code 2C .0100 and .0200, and any other Laws, Rules, and Regulations pertaining to well construction and use. This permit shall be effective, unless revoked, from the date of its issuance until February 28, 2006, and shall be subject to the specified conditions and limitations set forth in Parts I through X hereof. Permit issued this the a2C day of �f',G�_, 2003. Ted L. Bush, Jr., Assistant Chief Groundwater Section Division of Water Quality By Authority of the Environmental Management Commission. Permit No.WI0100012 PAGE 1 OF 6 ver.3/01 GWiUIC-5 PART I-WELL CONSTRUCTION GENERAL CONDITIONS 1. The Permittee must comply with all conditions of this permit and with the standards and criteria specified in Criteria and Standards Applicable to Injection Wells (15A NCAC 2C 0200). Any noncompliance with conditions of this permit constitutes a violation of the North Carolina Well Construction Act and is grounds for enforcement action as provided for in N.C.G.S. 87-94. 2. This permit shall become voidable unless the facility is constructed in accordance with the conditions of this permit, the approved plans and specifications, and other supporting data. 3. Each injection well shall not hydraulically connect separate aquifers. 4. Each injection well shall be constructed in such a manner that water from land surface cannot migrate into the gravel pack or well screen. 5. Each injection well shall be secured to reasonably insure against unauthorized access and use. Each well shall be permanently labeled with a warning that it is for injection purposes and the entrance to each well must be secured with a locking cap. 6. Each injection well shall be afforded reasonable protection against damage during construction and use. 7. Each injection well shall have permanently affixed an identification plate. 8. A completed Well Construction Record(Form GW-1) must be submitted for each injection well to, DENR-Division of Water Quality, Groundwater Section UIC-Staff, 1636 Mail Service Center, Raleigh,NC 27699-1636,within 30 days of completion of well construction. PART II- WELL CONSTRUCTION SPECIAL CONDITIONS 1. At least forty-eight (48) hours prior to constructing each injection well, the Permittee shall notify the Groundwater Section-Underground Injection Control (UIC), Central Office staff, telephone number(919) 715-6166. PART III- OPERATION AND USE GENERAL CONDITIONS 1. This permit is effective only with respect to the nature, volume of materials and rate of injection, as described in the application and other supporting data. 2. This permit is not transferable without prior notice to, and approval by, the Director of the Division of Water Quality(Director). In the event there is a desire for:the facility to change ownership, or there is a name change of the Permittee, a formal permit amendment request must be submitted to the Director, including any supporting materials as may be appropriate, at least 30 days prior to the date of the change. Permit No.WI0100012 PAGE 2 OF 6 ver.3/01 GW/UIC-5 • 0 3. -The issuance of this permit shall not relieve the Permittee of the responsibility of complying with any and all statutes,rules, regulations, or ordinances which may be imposed by other local, state, and federal agencies which have jurisdiction. Furthermore, the issuance of this permit does not imply that all regulatory requirements have been met. PART IV-PERFORMANCE STANDARDS 1. The injection facility shall be effectively maintained and operated at all times so that there is no contamination of groundwater which will render it unsatisfactory for normal use. In the event that the facility fails to perform satisfactorily, including the creation of nuisance conditions or failure of the injection zone to adequately assimilate the injected fluid, the Permittee shall take immediate corrective"actions including those actions that may be required-by the Division of Water Quality such as the repair, modification, or abandonment of the injection facility. 2. The Permittee shall be required to comply with the terms and conditions of this permit even if compliance requires a reduction or elimination of the permitted activity. 3. The issuance of this permit shall not relieve the Permittee of the responsibility for damages to surface or groundwater resulting from the operation of this facility. PART V- OPERATION AND MAINTENANCE REQUIREMENTS 1. The injection facility shall be properly maintained and operated at all times. 2. The Permittee must notify the Division and receive prior written approval from the Director of any planned physical alterations or additions in the permitted facility or activity not specifically authorized by the permit. 3. At least forty-eight (48) hours prior to the initiation of the operation of the facility for injection, the Permittee must notify by telephone the Groundwater Section-Underground Injection Control (UIC), Central Office staff, telephone number(919) 715-6166. Notification is required so that Division staff can inspect or otherwise review the injection facility and determine if it is in compliance with permit conditions. PART VI - INSPECTIONS 1. Any duly authorized officer, employee, or representative of the Division of Water Quality may, upon presentation of credentials, enter and inspect any property, premises, or place on or related to the injection facility at any reasonable time for the purpose of determining compliance with this permit, may inspect or copy any records that must be maintained under the terms and conditions of this permit, and may obtain samples of groundwater, surface water, or injection fluids. Permit No. WI0100012 PAGE 3 OF 6 ver.3(01 GW/UIC-5 • e 2. Department representatives shall have reasonable access for purposes of inspection, observation, and sampling associated with injection and any related facilities as provided for in N.C.G.S. 87-90. 3. Provisions shall be made for collecting any necessary and appropriate samples associated with the injection facility activities. PART VII-MONITORING AND REPORTING REQUIREMENTS 1. The proposed monitor plan in the UIC Permit Application received on October 29, 2002, shall be followed and all sample results shall be submitted to the Groundwater Section's Asheville Regional Office and the Raleigh-Central Office. Any monitoring(including groundwater, surface water, or soil sampling) deemed necessary by the Division of Water Quality to insure surface and ground water protection,will be established and an acceptable sampling reporting schedule shall be followed. 2. The Permittee shall produce a final project evaluation within 9 months after completing all injection activity associated with your permit application. This document shall assess the injection projects findings in a written summary. The final project evaluation shall also contain: monitoring well sampling data, contaminant plume and potentiometric surface maps. 3. The final project evaluation shall be submitted to the Underground Injection Control Program, Groundwater Section,NC DENR-Division of Water Quality, 1636 Mail Service Center, Raleigh,NC 27699-1636 and to the Groundwater Section, Asheville Regional Office, Interchange Building, 59 Woodfin Place, Asheville, NC 28801. ,4. The Permittee shall report by telephone, within 48 hours of the occurrence or first knowledge of the occurrence, to the Asheville Regional Office, telephone number(828) 251-6208, any of the following: (A) Any occurrence at the injection facility which results in any unusual operating circumstances; (B) Any failure due to known or unknown reasons, that renders the facility incapable of proper injection operations, such as mechanical or electrical failures. 5. Where the Permittee becomes aware of an omission of any relevant facts in a permit application, or of any incorrect information submitted in said application or in any report to the Director, the relevant and correct facts or information shall be promptly submitted to the Director by the Permittee. 6. In the event that the permitted facility fails to perform satisfactorily, the Permittee shall take such immediate action as may be required by the Director. Permit No.WI0100012 PAGE 4 OF 6 ver.3/01 GIMIC-5 PART VIII- PERMIT RENEWAL The Permittee shall, at least three (3) months prior to the expiration of this permit, request an extension. PART IX- CHANGE OF WELL STATUS 1. The Permittee shall provide written notification within 15 days of any change of status of an injection well. Such a change would include the discontinued use of a well for injection. If a well is taken completely out of service temporarily, the Permittee must install a sanitary seal. If a well is not to be used for any purpose that well must be permanently abandoned according to 15A NCAC 2C .0213(h)(1), Well Construction Standards. ' 2. When operations have ceased at the facility and a well will no longer be used for any purpose, the Permittee shall abandon that injection well in accordance with the procedures specified in 15A NCAC 2C .0214, including but not limited to the following: (A) All casing and materials may be removed prior to initiation of abandonment procedures if the Director finds such removal will not be responsible for, or contribute to, the contamination of an underground source of drinking water. (B) The entire depth of each well shall be sounded before it is sealed to insure freedom from obstructions that may interfere with sealing operations. (C) The well shall be thoroughly disinfected, prior to sealing, if the Director determines that failure to do so could lead to the contamination of an underground source of drinking water. (D) Drilled wells shall be completely filled with cement grout, which shall be introduced into the well through a pipe which extends to the bottom of the well and is raised as the well is filled. (E) In the case of gravel-packed wells in which the casing and screens have not been removed, neat-cement shall be injected into the well completely filling it from the bottom of the casing to the top. (F) In those cases when, as a result of the injection operations, a subsurface cavity has been created, each well shall be abandoned in such a manner that will prevent the movement of fluids into or between underground sources of drinking water and in accordance with the terms and conditions of the permit. (G) The Permittee shall submit a Well Abandonment Record(Form GW-30) as specified in 15A NCAC 2C .0213(h)(1)within 30 days of completion of abandonment. Peanut No.WI0100012 PAGE 5 OF 6 ver.3/01 GW/UIC-5 3. The written documentation required in Part IX (1) and(2) (G) shall be submitted to: Groundwater Section-UIC Staff DENR-Division of Water Quality 1636 Mail Service Center Raleigh,NC 27699-1636 PART X—WORKER PRECAUTIONS DURING APPLICATION 1. Some effects reported to be associated with the product proposed to be used are as follows: eye, skin, nose, throat and lung irritation. If the product is released into the environment in a way that could result in a suspension of fine solid or liquid particles (e.g., grinding, blending_, vigorous shaking or mixing), then proper personal protective equipment should be used. The application process should be reviewed by an industrial hygienist to ensure that the most appropriate personal protective equipment is used. 2. Persons working with these products should wear goggles or a face shield, gloves, and protective clothing. Face and body protection should be used for anticipated splashes or sprays. 3. Eating, drinking, smoking, handling contact lenses, and applying cosmetics should not be permitted in the application area during or immediately following application. 4. Safety controls should be in place to ensure that the check valve and the pressure delivery systems are working properly. 5. The Material Safety Data Sheets should be followed to prevent incompatible or adverse reactions and injuries. Permit No.WI0100012 PAGE 6 OF 6 ver.3/01 GW/UIC-5 t' DIVISION OF WATER QUALITY D GROUNDWATER SECTION NOY — 1 2002 October 31, 2002 GROUNDWATER SECTION ASHEVILLE REGIONAL OFFICE MEMORANDUM To: Landon Davidson, L.G., Regional Groundwater Supervisor Groundwater Section Asheville Regional Office n From: Mark Pritzl It'1�. Mark.Pritzl@ncmail.net Hydrogeological Technician 11 Underground Injection Control (UIC) Group Central Office(CO) Re: Request for review of an injection well application, type 5I injection well (in-situ remediation), submitted by Eaton Corporation,to construct and use injection wells for the injection of an HRC' slung to enhance reductive dechlorination of the dissolved chlorinated organic contamination at the Borg Warner Cooling Systems on Cane Creek Industrial Park, in Fletcher,North Carolina. 1. Please review the application and submit comments to CO-UIC group. Retain the application for your UIC file. 2. Please inspect the injection well site to verify that the location and construction plans submitted in the application are accurate and that the NCAC Title 15A 2C.0200 standards are being complied with, using the enclosed Preconstruction Injection Facility Inspection Report(Form A) as appropriate. 3. You are requested to return The Review Comments and the completed Preconstruction Injection Facility Inspection Report(Form A) to the CO-UIC by November 15, 2002. If the inspection and review can not be accomplished by this date,please inform the CO- UIC. The UIC group greatly appreciates your assistance with this review. If you have any questions regarding this review or the UIC program, please contact me at(919) 715-6166. cc: CO-UIC Files Enclosures WAIF Michael F.Easley,Governor IQ 9 William G.Ross Jr.,Secretary [� Q North Carolina Department of Environment and Natural Resources r ; Alan W.Klimek,P.E.Director -i Division of Water Quality O -c October 31, 2002 Steve Fesko Eaton Corporation Eaton Center 111 Superior Avenue Cleveland, OH 44114 Dear Mr. Fesko: Your application for a permit to construct and/or use injection wells for injecting an HRC slurry for reductive dechlorination of the dissolved chlorinated solvent contamination at Cane Creek Industrial Park, in Fletcher,North Carolina has been received and is currently under review. A member of the Groundwater Section's Asheville Regional Office staff will be contacting you to arrange an inspection of the injection site as part of the review. If you have any questions regarding the permit or injection well rules please contact me at (919) 715-6166. Sincerely, p Mark Pritzl Hydrogeological Technician UIC Program cc: CO-UIC Files ARO-UIC Files AGA WDENR Customer Service Division of Water Quality / Groundwater Section 1 800 623-7748 1636 Mail Service Center Raleigh,NC 27699-1636 Phone: (919)733-3221 Fax: (919)715-0588 Internet: http://gw.ehnr.state.nc.us NORTH CAROLINA DEPARTMENT OF ENVIRONMENT AND NATURAL RESOURCES APPLICATION FOR PERMIT TO CONSTRUCT AND/OR USE A WELL(S)FO z INJECTION ` Class 5I Wells w In Accordance with the provisions of NCAC Title 15A: 02C.0200 Complete application and mail to address on the back page. — < C=) TO: DIRECTOR,NORTH CAROLINA DIVISION OF WATER QUALITY , DATE: October 28 204� ,_ A. PERMIT APPLICANT Name: Eaton Corporation Address: Eaton Center - 1111 Superior Avenue City: Cleveland State: OH 4 Zip Code:44114 County: Cuyahoga Telephone: (216) 523-5000 B. PROPERTY OWNER(if different from applicant) Name: Borg Warner Cooling Systems, Inc. Address: Cane Creek Industrial Park City: Fletcher State: NC Zip Code: 28732 County: Henderson Telephone: (832) 684-3501 C. STATUS OF APPLICANT Private: % Commercial: Federal: State: County: Municipal: Native American Lands: _ D. FACILITY(SITE)DATA (Fill out ONLY if the Status is Federal, State, County, Municipal or Commercial). Name of Business or Facility: Address: City: Zip Code: County: Telephone: Contact Person: E. INJECTION PROCEDURE Provide a detailed description of all planned activities relating to the proposed injection facility including but not limited to: (1) construction plans and materials; Provided in Attachment E (2) operation procedures; and (3) a planned injection schedule. GW-57 REM (Jan,2000) Pagel of 5 F. DESCRIPTION OF SITE Provide a brief description of the contamination incident and the incident number assigned by the Division of Water Quality staff in the Department's Regional Office: The NCDENR Incident Number is 21521 See Attachment F for site description J G. HYDROGEOLOGIC DESCRIPTION Provided in Attachment G SECTION (G)MUST BE ORIGINALLY SEALED AND SIGNED BY A LICENSED GEOLOGIST Provide a hydrogeologic description, soils description, and cross section of the subsurface to a depth that included the known or projected depth of contamination. The number of borings shall be sufficient to determine the following: j (1) the regional geologic setting; .. (2) significant changes in lithology; (3) the hydraulic conductivity of the saturated zone; (4) the depth to the mean seasonal high water table; and (5) a determination of transmissivity and specific yield of the aquifer to be used for injection(showing calculations). — H. MONITORING PROCEDURE Provided in Attachment H Provide plans for proposed location and construction details of groundwater monitoring well network, including a schedule for sampling and analytical methods. Include any modeling/testing performed to investigate injectant's potential or susceptibility to change (biological, chemical or physical)in the subsurface. I. WELL USE Will the injection well(s) also be used as the supply well(s) for the following? y (1) The injection operation? YES NO X (2) Personal consumption? YES NO X J. CONSTRUCTION DATA(check one) EXISTING WELL being proposed for use as an injection well. Provide the data in (1) through (7) below to the best of your knowledge. Attach a copy of Form GW-I (Well Construction Record) if available. X PROPOSED WELL to be constructed for use as an injection well. Provide the data in (1) through (7) below as PROPOSED construction specifications. Submit Form GW-1 after construction. (1) Well Drilling Contractor's Name: Probe Technology Inc. NC Contractor Certification number: 2724 I (2) Date to be constructed: December 2002* Number of borings: 8 Approximate depth of each boring(feet): 20 J *Pending NCDENR approval GW-57 REM (Jan,2000) Page 2 of 5 e (3) Well casing: None Type: Galvanized steel_Black steel_Plastic_Other(specify) Casing depth: From to ft. (reference to land surface) _ Casing extends above ground inches (4) Grout: Grout type: Cement_ Bentonite X Other(specify) Grouted surface and grout depth(reference to land surface): around closed loop piping; from to (feet). around well casing; from to (feet). (5) Screens None Depth: From to feet below ground surface. (6) N.C. State Regulations (Title 15A NCAC 2C .0200) require the permittee to make provisions for monitoring wellhead processes. A faucet on both influent (recovered groundwater) and effluent (fluid being injected into the well) lines is generally required. Will there be a faucet on the influent line? yes no X Will there be a faucet on the effluent line? yes nc X (7) SOURCE WELL CONSTRUCTION INFORMATION (if different from injection well). Attach a copy of Form GW-1 (Well Construction Record). If Form GW-1 is not available, provide the data in part G of this application form to the best of your knowledge. NOTE: THE WELL DRILLING CONTRACTOR CAN SUPPLY THE DATA FOR EITHER EXISTING OR PROPOSED WELLS IF THIS INFORMATION IS UNAVAILABLE BY OTHER MEANS. K. OTHER WELL DATA Provided in Attachment K Provide a tabulation of data on all wells within '/4 mile of the injection well(s), excepting water supply wells serving a single-family residence, which penetrate the proposed injection zone. Such data shall include a description of each well's type, depth, record of abandonment or completion, and additional information the Director may require. L. PROPOSED OPERATING DATA (1) Injection rate: Average (daily) NA eallons per minute(gpm) (2) Injection volume: Average(daily) 43 gallons per day(gpd) (3) Injection pressure: Average(daily) NA pounds/square inch(psi) (4) Injection temperature:Average(January) 45 ° F, Average (July) 85 *F (5) Hydraulic capacity of the well: NA (Temporary �eoprobe boring) (6) Expected lifetime of the injection facilityless than lyears (7) Give a description of how the above data will be measured and controlled: A predetermined volume of HRC will be mixed in a hopper, then pumped _ into each geoprobe boring. GW-57 REM (Jan,2000) Page 3 of 5 ! A M. INJECTION-RELATED EQUIPMENT See Attachment M J Attach a diagram showing the detailed plans and specifications of the surface and subsurface construction details of the system. N. LOCATION OF WELLS) Provided in Attachment N Attach a scaled, site-specific map(s) showing the location(s)of the following: (1) the proposed injection well(s); (2) all property boundaries; (3) contour intervals not exceeding two feet; (4) the direction and distance from the injection well or well system to two nearby, permanent reference points(such as roads, streams, and highway intersections); (5) all buildings within the property boundary; (6) any other existing or abandoned wells, including water supply and monitoring wells, within the area of review of the injection well or wells system; -' (7) potentiometric surface showing direction of groundwater movement; (9) the horizontal and vertical extent of the contaminant plume (including isoconcentration lines and plume cross sections); (9) any existing sources of potential or known groundwater contamination, including waste storage, treatment or disposal systems within the area of review of the injection well or well system; and (10) all surface water bodies within 1000 feet of the injection well or well system. O. INJECTION FLUID DATA (1) Fluid source, if underground, from what depth, formation and type of rock/sediment unit will the fluid be drawn(e.g., granite,limestone, sand, etc.). Not applicable. Depth: Formation: Rock/sediment unit: (2) Provide the chemical, physical, biological and radiological characteristics of the fluid to be injected. The Material Safety Data Sheets for the HRC compound are provided in Attachment 0. P. PERMIT LIST _ Attach a list of all permits or construction approvals that are related to the site, including but not limited to: (1) Hazardous Waste Management program permits under RCRA 1 (2) NC Division of Water Quality Non-Discharge permits (3) Sewage Treatment and Disposal Permits (4) Other environmental permits required by state or federal law. GW-57 REM (Jan,2000) Page 4 of 5 r Q. CERTIFICATION "I hereby certify, under penalty of law, duet I have personally examined and am familiar with the information submitted in this document and all attachments thereto and that, based on my inquiry of those individuals immediately responsible for obtaining said information, I believe that the information is tt=, accurate and complete. I am aware that there are significant penalties, including the possibility of fines and imprisonment, for submitting false information. I agree to construct, operate, maintain, repair, and if applicable, abandon the injection well and all related appurtenances in accordance with the approved specifications and conditions of the Permit." Eaton Corporation By: T (cam/_, (Signature of Well Owner or Authorized Agent) Vice President & Secretary If authorized agent it acting on behalf of the well owner, please supply a letter signed by the owner authorizing the above agent. R. CONSENT OF PROPERTY OWNER (Owner means any person who holds the fee or other property rights in the well being constructed. A well is real property and its construction on land rests ownership in the landowner in the absence of contrary agreement in writing.) If the property is owned by someone other than the applicant, the property owner hereby consents to allow the applicant to construct each injection well as outlined in this application and that it shall be the responsibility of the applicant to ensure that the injection well(s) conforms to the Well Constriction Standards (Title 15A NCAC 2C .0200) i f Property Owner If Differ en "rohn Applicant) Please return two copies of the completed Application package to: UIC Program Groundwater Section North Carolina DENR-DWQ 1636 Mail Service Center Raleigh, NC 27699-1636 Telephone (919) 715-6165 GW-57 REM (Jan,2000) Page 5 of 5 i < f ! 1 ATTACHMENT E INJECTION PROCEDURE i i i 1 J E. INJECTION PROCEDURE I The proposed injection activities at the BorgWamer Cooling System, Inc. facility in Fletcher, North Carolina involve the injection of Hydrogen Release Compound (HRCT°') into the subsurface utilizing Geoprobe® direct-push methods. HRC is a proprietary product developed and distributed by Regenesis, Inc., of San Clemente, California. The purpose of the proposed injection is to evaluate the efficacy of using HRC for the in-situ treatment of contaminated ground water at the site. 1) Construction Plans and Materials A total of eight Geoprobe borings will be drilled in a 40 x 10 foot test treatment area for the purpose of injecting HRC. The borings will be drilled at ten foot spacings in two rows with four borings in each row. The borings will be installed within the shallow ground-water zone at depths between 15 to 20 feet below grade. After reaching the target depth, HRC will be injected directly through the Geoprobe rods into the formation. Following injection, the Geoprobe rods will be pulled and the boring sealed with bentonite grout. Consequently, no permanent/temporary injection wells will be constructed. HRC is a proprietary, food-grade polylactate ester specially formulated for slow release of lactic acid upon hydration. The compound is a high viscosity, flowable liquid with the consistency of viscous honey. Upon injection, HRC slowly dissolves and degrades to lactic acid, which in turn is metabolized by indigenous anaerobic microbes to produce hydrogen. The hydrogen is then used by reductive dechlorinating microbes to degrade chlorinated solvents and their derivatives. 2) Operation Procedures The Geoprobe rod assembly will be pushed to the desired depth and the predetermined volume of HRC compound will be pressure injected through the rods into the subsurface. Prior to injection, the HRC will be pre-heated, poured into a pump hopper and mixed to a uniform consistency. During injection, the Geoprobe rods will be slowly withdrawn to deliver the HRC across the treatment interval. HRC will be applied to the boring at a rate of five (5) pounds per vertical foot of saturation. Following the HRC injection, the Geoprobe rods will be pulled, and the boring filled with bentonite to secure the HRC in place and to prevent contaminant migration from the surface. 3) Planned Injection Schedule For the purposes of this pilot test, the schedule consists of a single HRC injection I into each borehole. It is anticipated that the drilling/injection process will take one to two days to complete. I J I ATTACHMENT F SITE DESCRIPTION I i I I r f F DESCRIPTION OF SITE In the course of multiple assessment investigations at the Facility, impact to ground- water (levels above State standards) was detected. The NCDENR incident number is 21521. The detailed results from the site investigations are documented in the July 2001 Comprehensive Site Assessment (CSA) Report and the August 2002 Addendum to the CSA. The type, source and amount of ground-water impact are summarized below. ❑ Type of Contaminants: The type of impact consists of chlorinated volatile organic compounds. Trichloroethylene, tetrachloroethylene, cis-1,2- dichloroethene and vinyl chloride have been reported above State standards in ground-water samples from the site. ❑ Source of the Release: After significant investigation, Eaton has been unable to determine the historic source of ground-water impact. Chlorinated solvents are no longer used or present at the Facility. The impact is not related to leaks from above or below ground storage tanks, surface spills, or pipelines, etc. The impact may be related to unknown historic activities at the site when the site was part of the former airport. Historical aerial photographs, during the time of former airport operations, show an area of surface disturbance in the current position of the Facility building. The area of historical surface disturbance coincides with the J area where ground-water impact was identified. ❑ Amount of Release: Because the exact source of the ground-water impact is not known, the amount (volume) of VOCs in the ground water cannot be quantified. I J I J i r I' ATTACHMENT G HYDROGEOLOGIC DESCRIPTION J I 1 1 G HYDROGEOLOGIC DESCRIPTION 1) Regional Geologic Setting Information regarding the geologic and hydrogeologic setting for the area in and around the Facility is based on the Geologic Map and Mineral Resources Summary of the Fruitland Quadrangle, North Carolina (Lemmon and Dunn, 1973) and the Mineral Resources Summary of the Fruitland Quadrangle North Carolina (Lemmon, 1973). The regional geology consists of four general stratigraphic units: unconsolidated alluvium, residuum and saprolite and consolidated metamorphic bedrock. The alluvium consists of clay, silt, sand, and gravel deposited by streams and rivers. The unit, where found, is generally present at ground surface and ranges in thickness from a few feet to greater than 50 feet. Where the alluvium is absent, residuum is usually encountered at ground surface. Residuum is soil that has undergone sufficient weathering to destroy all relict rock structure. This unit varies from thin (less than 10 feet) upwards to 30 feet in thickness. Typically, the residuum grades into saprolite at depth. Saprolite is thoroughly decomposed bedrock that retains relict rock structure. Thickness of this unit is highly variable, from thin (less than 10 feet) up to 100 feet across the region. The region is within the northeast-trending Brevard fault zone, a narrow belt of steeply dipping low- grade metamorphic rocks. The rocks within the fault zone are generally Cambrian Age porphyroclastic mylonite and cataclastic schist(Lemmon and Dunn, 1973). 2) Significant Changes in Lithology The lithologic descriptions of the subsurface soils and geology at the Facility are based on drilling results of the Geoprobe borings and monitoring wells. Generally, the site geology consists of unconsolidated fill, soil and alluvium, underlain by saprolite and fractured metamorphic rock. The units encountered at the Facility in order of increasing depth are: o Unconsolidated fill and soil o Alluvium o Saprolite F o Bedrock The relationship of these units is depicted on the geologic cross-sections on Figures G-1 and G-2. Cross-Section A—A' (Figure G-1) is oriented east-west along the southern boundary of the Facility and Cross-Section B—B' (Figure G-2) is oriented north-south along the eastern boundary of the Facility. i 1 I The unconsolidated fill/soil consists of clay and silt with interbedded sand seams. The material ranges in thickness from 3 to 17 feet and appears to thin to the east- northeast at wells MW-3 and MW-4 to thicken to the southwest at wells MW-6D and MW-10. Below the surficial soil is the alluvium, a variable unit ranging from silty clay to - sand and gravel. The total thickness of the alluvium ranges from 0 to 15 feet except in the southwestern corner of the Facility at well MW-6D, where the thickness is almost 40 feet. The alluvium consists of interlayered silt, clay and sand except in the area near where the surface ditch flows under Mills Gap Road. In this area (wells MW-8 and MW- 9, as shown on Drawing G-1), the alluvium is primarily coarser-grained sand and gravel. At well MW-6D, the upper 10 feet is coarser-grained sand and gravel and the lower 30 feet is fine-grained silt and clay. Below the alluvium is the saprolite unit, a clay, silt and sand that demonstrates relict bedrock texture. This unit, which occurs at depths from 5 to 50 feet, ranges in thickness from 14 to 20 feet, with the thickest area near well MW-5D (20 feet). The bedrock beneath the facility is highly fractured metamorphic rock, ranging from schist at MW-3D, MW-51), and MW-71) to quartzite and slate at MW-6D. The top of the competent (unweathered) bedrock occurs at depths of 20 to 60 feet below grade. 3) Hydraulic Conductivity Representative hydraulic conductivities for the shallow ground-water zone were determined based on values reported in the September 1994 CSA Report for the Wilsonart facility. The shallow ground-water zone evaluated at the Wilsonart facility is stratigraphically equivalent to the proposed injection zone at the BorgWarner facility. Based on slug tests, the hydraulic conductivity of the alluvium/saprolite ranged from 0.17 to 2.83 feet per day (ft/day), with an average of 1.16 ft/day. 4) Depth to Mean Seasonal High Water Table Based on the available water level data for the shallow ground-water zone, the depth to the seasonal high water table varies from 14.5 to 3.7 feet below grade across the site. In the proposed area of the injection well pilot test, the depth to the seasonal high water table is approximately 8.5 feet. Historical water-level data for the site is provided in Table G-1. 5) Aquifer Transmissivity and Specific Yield The transmissivity of the shallow ground-water zone in the area of the proposed injection site was calculated based on the reported hydraulic conductivities from the 1994 Wilsonart pumping test and the estimated saturated aquifer thickness. Based on a depth to water of 8.5 feet and total depth of 20 feet, the saturated thickness of the shallow ground-water zone is approximately 11.5 feet. Assuming hydraulic conductivities between 0.17 and 2.83 ft/day, the calculated transmissivity of the shallow ground-water zone is between 2 and 33 ftZ/day. The best available specific yield estimates for the shallow ground-water zone are those reported for the 1994 Wilsonart pumping test and range between 0.001 and 0.007 (Rust, 1994). North Carolina Licensed Geologist d7' V M4S Frank J. gtzchell References —' Lemmon, Robert E., 1973, Mineral Resources Summary of the Fruitland Quadrangle, North Carolina, North Carolina Department of Natural and Economic Resources, j Office of Earth Resources Report MRS 202-NW. Lemmon, Robert E. and David E. Dunn, 1973, Geologic Map of the Fruitland Quadrangle, North Carolina, North Carolina Department of Natural and Economic Resources, Office of Earth Resources Map GM 202-NW. RUST Environment &Infrastructure, September 1994, Comprehensive Site Assessment/ Corrective Action Plan, prepared for Ralph Wilson Plastics Company, Fletcher, North Carolina. I i 00 0 + 6 6 & J m N W (n A W N S _ n r Elevagation(feetgMang g ®® 0 O o fp—� ,�O N O f O� p O N N G Qy 6 9 @ ® & F 0 N N m t0 m N �p �Op OW tD to0 tN0 too Oho m C % m W p W� W N t,V m N O N V N N J p'mI C0 p N m N m tA0 N fn V m N A OAi N A A +l i O y W O 'y ONi N J m A Ta Q 1 0 m y I N N N N N Co tootOtm�p to+O m Coom < m 3 S N co p N 0 Q O_ m N A N V J A J4 q S P tl N � J � pOpop pmp�� lJp N < w S � p ioy � � � mm � g m g c m $ m 00co 'Iao ® gym Q w Cove' 'l— C" MCn m D of ! m m g V N N N W m N m tD T m N w ONo 0 N W m j m N C OF fmi —� w $ CDm m r m m m m m < m y o r m g vi � m mmrn t9) m < e N p 3 Oo J p tp0� O+ Npp Omo N N w t! S m O t.JO pAp tpmpO�� pWp�� Cn m d W OJD N m m+ W m m m ? 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N N 3000 2095 A MW-6D WEST 2090 MW-10 2085 UNCONSOLIDATED FILL. 2080 (10) 2079,39 - 2075 2070 2065 2060 2055 2050 2045 -- - - - - - - - - - - - - - 2040 2035 2030 (10I) 2025 2020 2015 (lOD) 2010 2005 A' EAST MW-7D Q u0 MW-9 MW-8 ® CLAY SILT ® SILT/CLAY L ",r —,:' Q j 0 _' SAND ALLUVIUM , SAPROLTTE 71 ':=:= 207976 R e T., CRYSTALLINE BEDROCK +`< SLATE �<<+ SCREENED INTERVAL c < + < POTENTIOMETRIC SURFACE BEDROCK I WATER TABLE y POTENTIOMETRIC SURFACE INTERFACE SAPROLITE / GROUND WATER LEVEL ELEVATION MEASUREMENTS TAKEN 8/8/01 s r � a . r BEDROCK -- FORMER EATON CORPORATION BORGWARNER COOLING SYSTEMS, INC. FLETCHER, NORTH CAROLINA PLANT o DATE:ocrOBER 2002 APPROVED BY: DWN BY:KwG SCALE: As SHOWN Vf5 CHKD. BV:off VERTICAL: 1" = 10' SHEET 1 OF1 HORIZONTAL: 1" = 100' � GEOLOGIC CROSS SECTION DRAWING NUMBER A—A' FIGURE G-1 B NORTH MW-3/3D MW-4 MW-5/5D 3000 2095 2090 2085 ALLUVIUM - (3) C5) 2080 2075 2070 SAPROLITE 2065 i 2060 w 2055 (5D) w w 2050 BEDROCK a J 2045 (3D) w 2040 2035 LEGEND B' CLAY SOUTH ® M 7D SILT ® SILT/CLAY 4r j1. ��- SAND ®47 2084.05 SAPROLITE 4 CRYSTALLINE BEDROCK 41 ® SLATE SCREENED INTERVAL y POTENTIOMETRIC SURFACE BEDROCK WATER TABLE ALLUVIUM/SAPROUTE GROUND WATER LEVEL ELEVATION H MEASUREMENTS TAKEN 6/8/01 O w VERTICAL: 1' = 10' _. HORIZONTAL: 1" - 100' 'r FORMER EATON CORPORATION as BORGWARNER COOLING SYSTEMS, INC. FLETCHER, NORTH CAROLINA PLANT DATE:OCTOBER 2002 APPROVED BY: DYM BY:awC r r SCALE: AS SHOWN I 0I5 CHKD. BY:DH SHEET 1 OF1 GEOLOGIC CROSS SECTION DRAWING NUMBER RGURE G-2 I 1 i ATTACHMENT H MONITORING PROCEDURE J _! H MONITORING PROCEDURE Three monitoring wells, one upgradient, one inside the treatment area and one downgradient of the injection site, will be installed in the shallow ground-water zone for purposes of monitoring ground-water quality prior to and following HRC injection. The proposed monitoring well locations are shown in Figure N-1 (Attachment N). Monitoring wells will be drilled using 4 '/a inch ID hollow stem augers (HSA) by advancing the augers to the completion depth and constructing the well within the augers. Monitoring wells will be completed using 2-inch ID schedule-40 PVC casing and 0.010- inch slot PVC screen. A washed silica sand filter pack will be placed in the annulus around the screen to a depth of approximately 2 feet above the top of the screen. The filter pack will secured with a 2-foot bentonite pellet seal and the remaining annular space will backfilled with bentonite slurry to within approximately 3 feet below the ground surface. Each monitoring well will be completed with a locking, steel protective casing set in a sloping concrete pad. Following construction, the monitoring wells will be developed by surging and pumping with a submersible pump. Each well will be developed until _ approximately 10 well volumes were removed, the discharge water appeared clear, or the well had been completely evacuated four times. Following development and prior to HRC injection, ground-water samples from the new monitoring wells will be submitted for analysis of VOCs and the following biodegradation indicator parameters: o Inorganic parameters consisting of dissolved iron and manganese, sulfide, nitrate, sulfate, chloride, alkalinity, and total organic carbon. o Metabolic acids consisting of lactic, pyruvic, acetic, propionic, and butyric. o Dissolved gases consisting of carbon dioxide, methane, ethane, and ethene. o Field parameters including dissolved oxygen, oxygen reduction potential, pH, temperature, and ferrous iron. The resultant data will be used to establish pre-treatment baseline conditions. Following HRC injection, the new monitoring wells will be sampled every two months for a period of six months for VOCs and the listed biodegradation indicator parameters. The resultant data will be used to evaluate the efficacy of the HRC injection for reducing VOC concentrations. After the initial six months, the sampling program will be reevaluated to r assess the need for continued monitoring. Ground-water samples will be collected using minimal drawdown sampling procedures. In this approach, the wells will be purged with a peristaltic pump at a rate that produces no net drawdown of the water-level surface within the well. The water temperature, pH, specific conductance, dissolved oxygen, and oxidation reduction potential will be monitored continuously throughout the purging process via a constant J reading flow-through cell. The ground-water samples will be collected following stabilization of the field parameters. Ground-water samples will be placed into approved containers provided by the laboratory. Sample preservatives will be added to the sample _ bottles prior to or immediately following sample collection. Following collection, the sample bottles will be labeled and placed in a cooler with ice for delivery to Prism Laboratories for analysis of VOCs and biodegradation indicator parameters. On October 1, 2001, shallow zone monitoring wells MW-1, MW-2, MW-3, MW- -� 4, MW-5, MW-8, and MW-9 were sampled for VOCs and to characterize the concentrations of the biodegradation indicator parameters listed above. The laboratory analytical results for the biodegradation indicator parameters in ground water from the shallow zone monitoring wells are summarized in Table H-1. In general: ❑ Dissolved iron and sulfide were not detected in any of the shallow ground- water samples. ❑ Dissolved manganese concentrations ranged from non-detect (MW-I) to 0.25 mg/L GvIW-2). ❑ Nitrate concentrations ranged from non-detect (MW-2, MW-4, and MW-9) to 0.26 mg/L(MW-1). r ❑ Sulfate concentrations ranged from non-detect (MW-2 and MW-5) to 4.5 mg/L(MW-1). ❑ Chloride concentrations ranged from 1.1 (MW-5) to 8.7 mg/L (MW-9). ❑ Alkalinity concentrations ranged from 11 (MW-2) to 52 mg/L (MW-1). I j ❑ Total Organic Carbon was only detected in the ground-water sample from MW-4 at a concentration of 4.7 mg/L. Metabolic acids were not detected in any of the shallow ground-water samples and the dissolved gas analytical results are listed below. ❑ Carbon Dioxide concentrations ranged from 79,000 (MW-5) to 140,000 µg/L (MW-4). ❑ Methane concentrations ranged from 0.31 (MW-1) to 1,900 µg/1 (MW-4). ❑ Ethane concentrations ranged from 0.0076 (MW-1 and MW-3) to 0.052 µg/L (MW-5). ❑ Ethene concentrations ranged from 0.026 (MW-4) to 0.14 µg/l (MW-5). The laboratory analytical results for the biodegradation indicator parameters were submitted along with the VOC data to Regenesis (San Juan Capistrano, California) to evaluate the natural attenuation potential within the shallow ground-water zone. Based on the available data, Regenesis concluded that the following conditions indicate that natural attenuation is on-going at the Fletcher facility: o Presence of dissolved manganese—indicates reducing conditions o Low sulfate—indicates sulfate lowered by sulfate reducers o Sulfides not detected—indicates reducing conditions o Elevated carbon dioxide—indicates biologic activity in aquifer i o Presence of methane—indicates reducing conditions o Presence of ethane—indicates naturally occurring reductive dechlorination o Low to no TOC—low TOC associated with reductive dechlorination o Low to no nitrate Based on these results, it is concluded that conditions in the shallow ground-water zone are favorable for enhanced/accelerated natural attenuation (biodegradation). f d � 1 � � 0 2 § g § 2Qe2 2gg22 00 . § c �co cq / 0RR /k d - m � 2CD 0 § 2 \ 6gmz 2ggzz oo � E o7 = m = � = 0 0 = = c = c / Ci z2zQzz � z zzzzz /§ § j \ . . CD d - Cl co� � 0 CD N 2 ) 222G = ) 2gg22 L ! § � = ~ = a - 5\ j = _ _ _ _ m £ d = - m � z \ z0w � � z zzzzz CL - j \ / d NrLo g \ 22g2 = g 2gg22 = oo 0 Ec WCD N � 0 d o � � � ° R � mo = o = oc zzz2gmmz zzzzz . � E 00 ) � ) \ CD 0 0 � m � m � - - o00 = \ . E E 0) / 0 kCD k ■ J WE ca 0 ) § . 0 5/ � ) / \ § a ! cc a) - - - - - - k k ` 0 CL a) CD k � o k 0 > \ k § 2 ca it ) 50CL \ k ) ) k \ k \ =0 « ) &) E2 a / £ g % kg 22 ATTACHMENT K OTHER WELL DATA J J J K OTHER WELL DATA The available information on all wells within '/a mile of the proposed injection well site that penetrate the shallow ground-water zone (excepting water supply wells i serving single-family residences) is provided in Table K-1. A total of 29 wells were identified: ❑ Seven monitoring wells and one site production well are reported at the Wilsonart facility; ❑ Four monitoring wells are reported at the Steelcase facility; ❑ Fifteen monitoring wells are at the BorgWarner facility (former Eaton); and ❑ One monitoring well is reported at the ABF facility. I I J J i J J TABLE K-1 WATER WELL SEARCH Former Eaton Facility-Fletcher,North Carolina Number Well Casing Screened Current OwnerNser Name of Total Depth Depth(feet Interval Address Wells Well Type (feet bgs) bgs) (feet bgs) Comments BorgWamer Cooling Systems, Inc. Cane Creek Industrial Park 1 Monitoring 17 7 7-17 MW-1 BorgWamer Cooling Systems, Inc. Cane Creek Industrial Park 1 Monitoring 17 7 7-17 MW-2 BorgWamer Cooling Systems, Inc. Cane Creek Industrial Park 1 Monitoring 16 6 6-16 MW-3 BorgWamer Cooling Systems, Inc. Cane Creek Industrial Park 1 Monitoring 55 45 45-55 MW-3D BorgWamer Cooling Systems, Inc. Cane Creek Industrial Park 1 Monitoring 14 4 4-14 MW-4 BorgWamer Cooling Systems, Inc. Cane Creek Industrial Park 1 Monitoring 16 6 6-16 MW-5 BorgWamer Cooling Systems, Inc. Cane Creek Industrial Park 1 Monitoring 26 21 21-26 MW-51 BorgWamer Cooling Systems, Inc. Cane Creek Industrial Park 1 Monitoring 42 32 32-42 MW-513 BorgWamer Cooling Systems, Inc. Cane Creek Industrial Park 1 Monitoring 75 65 65-75 MW-61D BorgWamer Cooling Systems, Inc. Cane Creek Industrial Park 1 Monitoring 35 25 25-35 MW-713 BorgWamer Cooling Systems, Inc. Cane Creek Industrial Park 1 Monitoring 14 9 9.14 MW-8 BorgWamer Cooling Systems, Inc. Cane Creek Industrial Park 1 Monitoring 19 9 9-19 MW-9 BorgWamer Cooling Systems, Inc. Cane Creek Industrial Park 1 Monitoring 15 5 5-15 MW-10 BorgWamer Cooling Systems, Inc. Cane Creek Industrial - Park 1 Monitoring 65 60 60-65 MW-101 BorgWamer Cooling Systems, Inc. Cane Creek Industrial Park 1 Monitoring 85 75 75-85 MW-10D BKT Enterprises 7 Monitoring 20 5 15 ABF Transportation Ralph Wilson Plastics Co. Industrial 1469 Cane Creek 1 Supply 401 41 NA RWP Production well Ralph Wilson Plastics Co. 1469 Cane Creek 1 Monitoring 23 13 13-23 Leggette,Brashears&Graham,Inc. October 2002 Columbus,Ohio 1 of 2 Injection Well Permit Application TABLE K-1 WATER WELL SEARCH -- Former Eaton Facility-Fletcher,North Carolina Number Well Casing Screened i Current Owner/User Name of Total Depth Depth(feet Interval Address Wells Well Type (feet bgs) bgs) (feet bgs) i Comments Ralph Wilson Plastics Co. _ 1469 Cane Creek 1 Monitoring 29 19 19-29 Ralph Wilson Plastics Co. 1469 Cane Creek 1 Monitoring unk Ralph Wilson Plastics Co. 1469 Cane Creek 1 Monitoring unk Ralph Wilson Plastics Co. - 1469 Cane Creek 1 Monitoring unk I Ralph Wilson Plastics Co. —' 1469 Cane Creek 1 Monitoring unk Ralph Wilson Plastics Co. 1469 Cane Creek 1 Monitoring unk Ralph Wilson Plastics Co. 1469 Cane Creek 1 Monitoring unk _ Steelcase,Inc Hoopers Creek Rd. 04-694.2241 1 Monitoring unk Steelcass, Inc Hoopers Creek Rd. 04-6a4-2241 1 Monitoring unk (1) Steelcase,Inc Hoopers Creek Rd. 04-684-2241 2 Monitoring unk (1) J Leggette,Brashears&Graham,Inc. October 2002 Columbus,Ohio 2 of 2 Injection Well Permit Application ATTACHMENT M INJECTION-RELATED EQUIPMENT J I J J J J J i i M INJECTION-RELATED EQUIPMENT The HRC will be pressure injected into the target formation through Geoprobe® drilling rods. Prior to injection, the HRC will be pre-heated, poured into a pump hopper and mixed to a uniform consistency. Following injection, the Geoprobe®rods will be pulled and the boring will be sealed with bentonite. Because there will be no permanent injection wells or injection equipment at the facility, equipment plans or specifications will not be prepared. i f l ATTACHMENT N - LOCATION OF WELL(S) -J _ I _ �G G G 6 G1 ,�G G G Y Y a . 1 1994 997 ¢ it 1994 1987 a E APLOYEE I� ARKING a a� ORIGINAL ADC BUILDING 11 a 1976 a rn a OFFICES � � a 1978 PROPOSE[ a a INJECTION ISITOR ARKING I \ a eow,� ���8�— W wv I REVISION RECORD DAIS DESGDPIIDN RE.Vf iflEVf_DESC RE RE DEM REMI VJ RE/iDESC REVa 1 REVa_DESD REM I RM-DM �s LEGEND STORM SEWER BURIED ELECTRIC -�- BURIED GAS \ -n- FIRE PROTECTION -.- WATER n \ BURIED SANITARY PROPERTY BOUNDARY -0 SECURITY LIGHT -n1 M FIRE HYDRANT MONITORING WELL 1994 III PROPOSED MONITORING WELL J • INJECTION WELL v a a a aII `VAS St`ei R IN FEET 5� —'wv /°r FORMER EATON CORPORATION COOLING BORGWARNER COOLING SYSTEMS, INC. ' FLEfCHER, NORTH CAROLINA PLANT DA1E:oCTORI7t zaD2 APPROVED BY: OWN BY:I<MAC SCALE: AS SHOWN J1S CHKD. BY:DH SHEET 1 OF1 0 SITE PLAN DRAWING NUMBER FIGURE N-1 BOMR WA NER SITE LOCATION MAP FLETCHER., NORTH CAROUNA 6 6 3 1997 � ..,.' 1994 II 1994 19, a EMPLOYEE PARKING a� IGINAL ADDI ev n—,7 ^v n-Rr-^-Vn-no- B DING 19 i—:—. �-- 19 6 a a a a p-n-R O9713 ES a a a a VISITOR PARKING a M`N 201 9I-LES GAP — ROAD g2 �1 MO 9 56 6w wv M 0ea o REVISION RECORD AM I DESCRIPTION REVt 1REY1_OE9C Rm REVZDESC REV] IREVS_DESC M4 1 REV4_1E REVS REVS_OESC 4ADDITION \ 1997 LEGEND dog MONITORING WELL 1994 II A FORPORARY STREAMBENCH ELEVATION MARK, MEASUREMENT —'— BURIED ELECTRIC a- —'— BURIED GAS FIRE PROTECTION a — — WATER a —•— SANITARY �MW,A MONITORING WELL & STREAM ELEVATIONS MEASURED 9/21/00 Ia - -n—nJ —2090— EQUIPOTENTIAL CONTOUR GROUND WATER FLOW DIRECTION GRADIENT: A—A'a 2090 —680 2080 p 0.015 -'1' 2p85 9 D n Im j5 37 —' ^w /°N FORMER EATON CORPORATION COOLING BORGWARNER COOLING SYSTEMS, INC. FLETCHER, NORTH CAROLINA PLANT OilDATE.F 08EE 2002 APPROVED BY: DM BY:KMAC SCALE: As sHowN As CHKD. BY:DH SHALLOW ZONE SHEET 1 OF1 o POTENTIOMETRIC SURFACE MAP DRAWNG NUMBER (1/22/02) FIGURE N-3 N 25� Kg 22 8 21 250• Gp' �s 6 6 f 6 • � f f—i —L Kg i 1997 Ke 9 1994 al 1994 1987 • 0 4 EMPLOYEE I" K9' KB'2 PARKING a I KB • " ORIGINAL a ADDI BUILDING 19 1976 1 � yl '2 a K _• / /�D Oaf SC�'V✓/� J '�#a Gnp_" V' �1 1 M,N�1p0 �22/G P o ® OFFICES / ((;; 19 a GP�20 1 h O l 1978 / � Op ® 28 i KGP-18 �v' NO Gp, � 15 �4 GP'1'1 O- GP NQ VISITOR a PARKING O/ ,�O Z 55 6 �Q / NO Gp�Q P'229 GP 2� , / Gp'NG i GP23 Gp,a Gpbc 7 REVISION RECORD DALE DESWPTfRI Roil IW REYt_06C EV2 PEV20ESC REV] I REVJ_D REVt 1 REVt_DESC REPS I REV5_DEX t\ nADDLEGEND • OCTOBER 1999 GEOPROBE BORING, BY KERAMIDA APRIL 2000, CEC GEOPROBE SAMPLE POINT 1994 • K I I MONITORING WELL TEMPORARY BENCH MARK, AL FOR STREAM ELEVATION MEASUREMENT —�— BURIED ELECTRIC o1 2�, LKg 1�0 p5 —.— BURIED GAS J a • I —w— FIRE PROTECTION �Cg' /• h a BURIED SANITARY BURIED WATER 3 • p2 �' 28 TOTAL VOC CONCENTRATION (ug/Q 55, I 1 MW,2 GP O ' i IN FEkf I/50 O'D l FORMER EATON CORPORATION BORGWARNER COOLING SYSTEMS, INC. y FLETCHER, NORTH CAROLINA PLANT S DATE:OCTOBER 20112 APPROVED BY: OWN BY:KMAC SCALE: AS SHOWN .Rs CHKO. BY:DH M•N' SHALLOW ZONE SHEET 1 OF 1 TOTAL VOCs ISOCONCENTRATION DRAWNG NUMBER MAP (09/1) FIGURE N-4 1 r ATTACHMENT O INJECTION FLUID DATA J ' l 1� HRC MSDS ; Page 1 of 6 REGENIESIS r 4mma� MATERIAL SAFETY DATA SHEET tit�.v Last Revised: March 1, 2001 -_ �d�ill6ssf't_c�tJne=ylS.,� . ai±sr, 'fm2r1 �., Section 1 -Material Identification Supplier: Regenesis Bioremediation Products Yam' 1011 Calle Sombra San Clemente, CA 92673 Telephone: (949)366-8000 �;t ' Facsimile: (949) 366-8090 Chemical Name: Propanoic acid, 2-[2-[2-(2-hydroxy-l-oxopropoxy)-1-oxopropoxy] -1-oxopropoxy]-1,2,3-propanetriyl ester Chemical Family: Organic Chemical i Trade Name: Glycerol tripolylactate r Product Name: Hydrogen Release Compound (HRCO) Section 2-Hazardous Ingredients i j CAS #: 201167-72-8 One should anticipate the potential for eye irritation and skin 'irritation with large scale exposure or in sensitive individuals. i i Section 3 -Physical Data http://www.regenesis.com/HRC/hrcrosds.htm 8/22/2002 HRC MSDS Page 2 of 6 Melting Point: NA Boiling Point: ND Flash Point: ND Density: 1.347 Solubility: Acetone and DMSO Appearance: Amber semi-solid Odor: Not detectable Vapor Pressure: None Section 4-Fire and Explosion Hazard Data Extinguishing Media: Carbon Dioxide,Dry Chemical Powder or Appropriate Foam. Water may be used to keep exposed containers cool. For large quantities involved in a fire, one should wear full protective clothing and a NIOSH approved self contained breathing apparatus with full face piece operated in the pressure demand or positive pressure mode as for a situation where lack of oxygen and excess heat are present. Section 5 -Toxicological Information Acute Effects: May be harmful by inhalation, ingestion, or skin absorption. May cause irritation. To the best of our knowledge, the chemical, physical, and toxicological properties of the glycerol tripolylactate have not been investigated. Listed below are the toxicological information for glycerol and lactic acid. RTECS#: NIA8050000 http://www.regenesis.com/BRC/hrcrosds.htm 8/22/2002 HRC MSDS Page 3 of 6 Glycerol Irritation data: SKN-RBT 500 MG/24H MLD 85JCAE-,207,1986 EYE-RBT 126 MG MLD BIOFX* 9-4/1970 EYE-RBT 500 MG/24H MLD 85JCAE-,207,1986 Toxicity data: ORL-MUS LD50:4090 MG/KG FRZKAP (6),56,1977 SCU-RBT LD50:100 MG/KG NIIRDN 6,215,1982 ORL-RAT LD50:12600 MG/KG FEPRA7 4,142,1945 H-M-RAT LC50: >570 MG/M3/1H BIOFX* 9-4/1970 IPR-RAT LD50: 4420 MG/KG RCOCB8 56,125,1987 IVN-RAT LD50:5566 MG/KG ARZNAD 26,1581,1976 IPR-NMS I.D50: 8700 MG/KG ARZNAD 26,1579,1978 SCU-MUS LD50:91 MG/KG N=N 6,215,1982 IVN-MUS LD50: 4250 MG/KG JAPMA8 39,583,1950 ORL-RBT LD50: 27 GM/KG DMDJAP 31,276,1959 SKN-RBT LD50:>10GM/KG BIOFX* 9-4/1970 IVN-RBT LD50: 53 GM/KG N=N 6,215,1982 ORL-GPG LD50: 7750 MG/KG JIHTAB 23,259,1941 Target Organ data: Behavioral (headache), gastrointestinal (nausea or vomiting), Paternal effects (spermatogenesis, testes, epididymis, sperm duct), effects of fertility (male fertility index,post-implantation mortality). RTECS#: OD2800000 Lactic acid Irritation data: SKN-RBT 5MG/24H SEV 85JCAE-,656,86 EYE-RBT 750 UG SEV AJOPAA 29,1363,46 Toxicity data: ORL-RAT LD50:3543 MG/KG FMCHA2-,C252,91 SKN-RBT LD50:>2 GM/KG FMCHA2-,C252,91 http://www.regenesis.com/HRC/hrcrosds.htm 8/22/2002 IMC MSDS Page 4 of 6 ORL-MUS I.D50: 4875 MG/KG FAONAU 40,144,67 ORL-GPG LD50: 1810 MG/KG=AB 23,259,41 ORL-QAL LD50: >2250 MG/KG FMCHA2-,C252,91 -. Only selected registry of toxic effects of chemical substances anECS) data is presented here. See actual entry in RTECS for complete information on lactic acid and glycerol. Section 6 - Health Hazard Data Handling: Avoid continued contact with skin. Avoid contact with eyes. In any case of any exposure which elicits a response, a physician should be consulted immediately. _- First Aid Procedures: Inhalation: Remove to fresh air. If not breathing give artificial respiration. In case of labored breathing give oxygen. Call a physician. Ingestion: No effects expected.Do not give anything to an unconscious person. Call i physician immediately. Skin Contact: Flush with plenty of water. Contaminated clothing may be washed or dry cleaned normally. Eye contact: Wash eyes with plenty of water for at least 15 minutes lifting both uppe and lower lids. Call a physician. Section 7 -Reactivity Data http://www.regenesis.com/ERC/hrcrosds.htm 8/22/2002 iKu M.ND6 rage:) or o Conditions to Avoid: Strong oxidizing agents, bases and acids Hazardous Polymerization: None known _ Further Information: Hydrolyses in water to form Lactic Acid and Glycerol. Section 8 - Spill, Leak or Accident Procedures After Spillage or Leakage: Neutralization is not required.This combustible material may be burned in a chemical incinerator equipped with an afterburner and scrubber. Disposal: Laws and regulations for disposal vary widely by locality. Observe all - applicable regulations and laws. This material, may be disposed of in solid waste. Material is readily degradable and hydrolyses in several hours. No requirement for a reportable quantity (CERCLA) of a spill is known. Section 9 - Special Protection or Handling Should be stored in plastic lined steel, plastic, glass, aluminum, stainless steel, or reinforced fiberglass containers. Protective Gloves: Vinyl or Rubber Eyes: Splash Goggles or Full Face Shield Area should have approved means of washing eyes. Ventilation: General exhaust. Storage: Store in cool, dry, ventilated area. Protect from imcompatible materials. ***************************************************************** http://www.regenesis.com/HRC/hrcrosds.htm 8/22/2002 *HRC MSDS Page 6 of 6 Section 10 - Other Information This material will degrade in the environment by hydrolysis to lactic acid and glycerol. Materials containing reactive chemicals should be used only by personnel with appropriate chemical training. The information contained in this document is the best available to the supplier as of the time of writing. Some possible hazards have been determined by analogy to similar classes of material. No separate tests have been performed on the toxicity of this material.The items in this document are subject to change and clarification as more information becomes available. [Hnnm][tip ] Copyright©Regenesis Bioremediation Products. 1996-2002.All Rights Reserved. O Registered Trademark of Regenesis Bioremediation Products, Inc. http://www.regenesis.com/HRCthrcrosds.htin 8/22/2002 D WE LEGGETTE BRASBEARS & GRAHAM OCi 3 0 2002 D PROFESSIONAL GROUND-WATER AND ENVIRONMENTAL ENGINEERING SERVICES GROUNDWATER SECTION ASHBILLE REGIONAL OFFICE TAYLOR STATION COMMERCE CENTER 950 TAYLOR STATION ROAD.SUITE K GAHANNA,OH 43230 614416-9100 PAX 614416-9101 www.Ibgweb.e October 28, 2002 Mr. Evan Kane UIC Program Manager UIC Program Groundwater Section North Carolina DENR-DWQ 2728 Capital Blvd. Raleigh,NC 27604 RE: Injection Well Permit Application BorgWamer Facility; Fletcher, North Carolina Dear Mr. Kane: Enclosed please find two signed injection well permit applications for the proposed remediation pilot test at the BorgWamer Cooling Systems, Inc. facility in Fletcher, North Carolina. The proposed activities for the remediation pilot test involve the injection of Hydrogen Release Compound (HRCTm) into the subsurface utilizing Geoprobe® direct-push methods. HRC is a proprietary product developed and distributed by Regenesis, Inc., of San Clemente, California. The purpose of the proposed injection is to evaluate the efficacy of using HRC for the in-situ treatment of contaminated ground water at the site. If you have any questions or concerns regarding the permit application, please feel free to contact us at (614)416-9100. Thank you for your assistance in this matter. Very truly yours, LEGGETTE, B HEARS & GRAHAM, INC. 90tA Doug unter Senior Ground-Water Hydrologist DRH/drh cc: Steve Fesko, Eaton Anastasia Hamel, Borg-Warner Ray Raymond, Borg-Warner MISSOURI ILLINOIS SOUTH DAKOTA PENNSYLVANIA FLORIDA NEW JERSEY MINNESOTA TEXAS MASSACHUSETTS WISCONSIN NEW YORK CONNECTICUT NORTH CAROLINA DEPARTMENT OF ENVIRONMENT AND NATURAL RESOURCES APPLICATION FOR PERMIT TO CONSTRUCT AND/OR USE A WELL(S) FOR INJECTION Class 51 Wells In Accordance with the provisions of NCAC Title I SA: 02C.0200 Complete application and mail to address on the back page. TO: DIRECTOR,NORTH CAROLINA DIVISION OF WATER QUALITY DATE: October 28 20 02 A. PERMIT APPLICANT Name: Eaton Corporation Address: Eaton Center - 1111 Superior Avenue City: Cleveland State: OH ' Zip Code:44114 County: Cuyahoga Telephone: (216) 523-5000 B. PROPERTY OWNER(if different from applicant) Name: Borg Warner Cooling Systems, Inc. Address: Cane Creek Industrial Park City: Fletcher State: NC Zip Code: 28732 County: Henderson Telephone: (832) 684-3501 C. STATUS OF APPLICANT Private: % Commercial: Federal: State: County: Municipal: Native American Lands:_ D. FACIL=(SITE)DATA (Fill out ONLY if the Status is Federal, State, County,Municipal or Commercial). Name of Business or Facility: Address: City: Zip Code: County: Telephone: Contact Person: E. INJECTION PROCEDURE Provide a detailed description of all planned activities relating to the proposed injection facility including but not limited to: (1) construction plans and materials; Provided in Attachment E (2) operation procedures; and ki (ra pp f� (3) a planned injection schedule. l� U LS D OC�S 3 0 2002 OW-57 REM (Jan,2000> GROUNDWATER SECTION ASHEVILLE REGIONAL OFFICE i'A 1 F. DESCRIPTION OF SITE Provide a brief description of the contamination incident and the incident number assigned by the Division of Water Quality staff in the Department's Regional Office: The NCDENR Incident Number is 21521, See Attachment F for site description G. HYDROGEOLOGIC DESCRIPTION Provided in Attachment G SECTION(G)MUST BE ORIGINALLY SEALED AND SIGNED BY A LICENSED GEOLOGIST Provide a hydrogeologic description, soils description, and cross section of the subsurface to a depth that included the known or projected depth of contamination. The number of borings shall be sufficient to determine the following: (1) the regional geologic setting; (2) significant changes in lithology; (3) the hydraulic conductivity of the saturated zone; (4) the depth to the mean seasonal high water table; and (5) a determination of trarismissivity and specific yield of the aquifer to be used for injection(showing calculations). H. MONITORING PROCEDURE Provided in Attachment H Provide plans for proposed location and construction details of groundwater monitoring well } network, including a schedule for sampling and analytical methods. Include any modeling/testing performed to investigate injectant's potential or susceptibility to change (biological, chemical or physical) in the subsurface. I. WELL USE Will the injection well(s) also be used as the supply well(s) for the following? (1) The injection operation? YES NO - X (2) Personal consumption? YES NO X J. CONSTRUCTION DATA (check one) EXISTING WELL being proposed for use as an injection well. Provide the data in (1) through (7) below to the best of your knowledge. Attach a copy of Form GW-1 (Well Construction Record) if available. X PROPOSED WELL to be constructed for use as an injection well. Provide the data in (1) through (7) below as PROPOSED construction specifications. Submit Form GW-1 after construction. - (1) Well Drilling Contractor's Name: Probe Technology Inc. NC Contractor Certification number: 2724 _r (2) Date to be constructed: December 2002* Number of borings: 8 Approximate depth of each boring(feet): 20 *Pending NCDENR approval _ Page 2 of-5 REM (Jan,2000) 4 { (3) Well casing: None J Type: Galvanized steel—Black steel—Plastic—Other(specify) Casing depth: From to ft. (reference to land surface) Casing extends above ground inches (4) Grout: Grout type: Cement— Bentonite X Other(specify) Grouted surface and grout depth(reference to land surface): _ —around closed loop piping; from to (feet). i around well casing; from to (feet). (5) Screens None Depth: From to feet below ground surface. (6) N.C. State Regulations (Title 15A NCAC 2C .0200) require the permittee to make provisions for monitoring wellhead processes. A faucet on both influent (recovered groundwater) and effluent (fluid being injected into the well) lines is generally required. Will there be a faucet on the influent line? yes no X Will there be a faucet on the effluent line? yes ncL X (7) SOURCE WELL CONSTRUCTION INFORMATION (if different from injection well). Attach a copy of Form GW-1 (Well Construction Record). If Form GW-1 is not available, provide the data in part G of this application form to the best of your knowledge. NOTE: THE WELL DRILLING CONTRACTOR CAN SUPPLY THE DATA FOR EITHER EXISTING OR PROPOSED WELLS IF THIS INFORMATION IS UNAVAILABLE BY OTHER MEANS. K. OTHER WELL DATA Provided in Attachment K Provide a tabulation of data on all wells within I/4 mile of the injection well(s), excepting water supply wells serving a single-family residence, which penetrate the proposed injection zone. Such data shall include a description of each well's type, depth, record of abandonment or completion, and additional information the Director may require. L. PROPOSED OPERATING DATA (1) Injection rate: Average(daily) NA gallons per minute(gpm) (2) Injection volume: Average(daily) 43 gallons per day (gpd) I (3) Injection pressure: Average (daily) NA pounds/square inch(psi) (4) Injection temperature:Average(January) 45 °F, Average (July) 85 ° F (5) Hydraulic capacity of the well: NA (Temporary geoprobe boring) (6) Expected lifetime of the injection facilityless than lyears (7) Give a description of how the above data will be measured andicontrolled: -I A predetermined volume of HRC will be mixed in a ,hovner. then numved into each geoprobe boring. GW-57 REM (Jan,2000) ! Page 3 of 5 YJ M. INJECTION-RELATED EOUIPMENT See Attachment M -� Attach a diagram showing the detailed plans and specifications of the surface and subsurface construction details of the system. N. LOCATION OF WELLS) Provided in Attachment N Attach a scaled, site-specific map(s) showing the location(s) of the following: (1) the proposed injection well(s); (2) all property boundaries; J (3) contour intervals not exceeding two feet; (4) the direction and distance from the injection well or, well system to two nearby, permanent reference points (such as roads, streams, and highway intersections); (5) all buildings within the property boundary; (6) any other existing or abandoned wells, including water supply and monitoring wells, within the area of review of the injection well or wells system; (7) potentiometric surface showing direction of groundwater movement; (8) the horizontal and vertical extent of the contaminant plume (including isoconcentration lines and plume cross sections); (9) any existing sources of potential or known groundwater contamination, including waste storage, treatment or disposal systems within the area of review of the injection well or well system; and (10) all surface water bodies within 1000 feet of the injection well or well system. O. INJECTION FLUID DATA (1) Fluid source, if underground, from what depth, formation and type of rock/sediment unit will the fluid be drawn(e.g., granite, limestone, sand, etc.). Not applicable. Depth: _ Formation: Rock/sediment unit: -JI (2) Provide the chemical, physical, biological and radiological characteristics of the fluid to be,injected. The Material Safety Data Sheets for the HRC compound are provided in Attachment 0. P. PERMIT LIST Attach a list of all permits or construction approvals that are related to the site, including but J not limited to: (1) Hazardous Waste Management program permits under RCRA J (2) NC Division of Water Quality Non-Discharge permits (3) Sewage Treatment and Disposal Permits (4) Other environmental permits required by state or federal law. JGW-57 REM.(Jan,2000) Page 4 of 5 i I - i I. Q. CERTIFICATION "I hereby certify, ender penalty of law, that I have personally examined and am familiar with the information submitted in this document and all attachments thereto and that, based on my inquiry of those individuals immediately responsible for obtaining said information, I believe that the information is true, accurate and complete. I am aware that there are significant penalties, including the possibility of fines and imprisonment, for submitting false infoffiation. I agree to construct, operate, maintain repair, and if applicable, abandon the injection well and all related appurtenances in accordance with the approved specifications and conditions of the Permit" Eaton Corporation (Signature ofWell Owner or Authorized Agent) I Vice President & Secretary JIf authorized agent is acting on behalf of the well owner, please supply a letter signed by the owner authorizing the above agent. I R. CONSENT OF PROPERTY OWNER (Owner means any person who holds the fee or other property rights in the well being constructed. A well is real property and its construction on land rests ownership in the landowner in the absence of contrary agreement in writing.) If the property is owned by someone other than the applicant, the property owner hereby consents to allow the applicant to construct each injection well as outlined in this application and that it shall be the responsibility of the applicant to ensure that the injection well(s) conforms to the Well Construction Standards (Title 15A NCAC 2C .0200) f Property Owner If Di$eren rom Applicant) f Please return two copies of the completed Application package to: UIC Program _ Groundwater Section North Carolina DFNR-DWQ 1636 Mail Service Center Raleigh, NC 27699-1636 Telephone (919) 715-6165 J GW-57 REM (Jan,2000) Page 5 of 5 ' � r I J ATTACHMENT E i INJECTION PROCEDURE I J J J f I E. INJECTION PROCEDURE The proposed injection activities at the BorgWamer Cooling System, Inc. facility in Fletcher, North Carolina involve the injection of Hydrogen Release Compound (HRCm) into the subsurface utilizing Geoprobe® direct-push methods. HRC is a proprietary product developed and distributed by Regenesis, Inc., of San Clemente, California. The purpose of the proposed injection is to evaluate the efficacy of using HRC for the in-situ treatment of contaminated ground water at the site. 1) Construction Plans and Materials A total of eight Geoprobe borings will be drilled in a 40 x 10 foot test treatment area for the purpose of injecting HRC. The borings will be drilled at ten foot spacings in two rows with four borings in each row. The borings will be installed within the shallow ground-water zone at depths between 15 to 20 feet below grade. After reaching the target depth, HRC will be injected directly through the Geoprobe rods into the formation. Following injection, the Geoprobe rods will be pulled and the boring sealed with bentonite grout. Consequently, no permanent/temporary injection wells will be constructed. HRC is a proprietary, food-grade polylactate ester specially formulated for slow release of lactic acid upon hydration. The compound is a high viscosity, flowable liquid with the consistency-of viscous honey. Upon injection, HRC slowly dissolves and degrades to lactic acid, which in turn is metabolized by indigenous anaerobic microbes to produce hydrogen. The hydrogen is then used by reductive dechlorinating microbes to degrade chlorinated solvents and their derivatives. 2) Operation Procedures The Geoprobe rod assembly will be pushed to the desired depth and the predetermined volume of HRC compound will be pressure injected through the rods into the subsurface. Prior to injection, the HRC will be pre-heated, poured into a pump hopper and mixed to a uniform consistency. During injection, the Geoprobe rods will be slowly withdrawn to deliver the HRC across the treatment interval. HRC will be applied to the boring at a rate of five (5) pounds per vertical foot of saturation. Following the HRC injection, the Geoprobe rods will be pulled, and the boring filled with bentonite to secure the HRC in place and to prevent contaminant migration from the surface. 3) Planned Injection Schedule For the purposes of this pilot test, the schedule consists of a single HRC injection into each borehole. It is anticipated that the drillinglinjection process will take one to two days to complete. J ATTACHMENT F i SITE DESCRIPTION F DESCRIPTION OF SITE In the course of multiple assessment investigations at the Facility, impact to ground- water (levels above State standards) was detected. The NCDENR incident number is 21521. The detailed results from the site investigations are documented in the July 2001 Comprehensive Site Assessment (CSA) Report and the August 2002 Addendum to the J CSA. The type, source and amount of ground-water impact are summarized below. ❑ Tvpe of Contaminants: The type .of impact consists of chlorinated volatile organic compounds. Trichloroethylene, tetrachloroethylene, cis-1,2- dichloroethene and vinyl chloride have been reported above State standards in ground-water samples from the site. ❑ Source of the Release: After significant investigation, Eaton has been unable to determine the historic source of ground-water impact. Chlorinated solvents are no longer used or present at the Facility. The impact is not related to leaks from above or below ground storage tanks, surface spills, or pipelines, etc. The impact may be related to unknown historic activities at the site when the site was part of the former airport. Historical aerial photographs, during the time of former airport operations, show an area of surface disturbance in the current position of the Facility building. The area of historical surface disturbance coincides with the area where ground-water impact was identified. ❑ Amount of Release: Because the exact source of the ground-water impact is not known, the amount (volume) of VOCs in the ground water cannot be quantified. J i i J . J V 1 ATTACHMENT G HYDROGEOLOGIC DESCRIPTION G EIYDROGEOLOGIC DESCRIPTION 1) Regional Geologic Setting Information regarding the geologic and hydrogeologic setting for the area in and around the Facility is based on the Geologic Map and Mineral Resources Summary of the Fruitland Quadrangle, North Carolina (L.emmon and Dunn, 1973) and the Mineral Resources Summary of the Fruitland Quadrangle North Carolina (L.emmon, 1973). The regional geology consists of four general stratigraphic units: unconsolidated alluvium, residuum and saprolite-and consolidated metamorphic bedrock. The alluvium consists of clay, silt, sand, and gravel deposited by streams and rivers. The unit, where found, is generally present at ground surface and ranges in thickness from a few feet to greater than 50 feet. Where the alluvium is absent, residuum is usually encountered at ground surface. Residuum is soil that has undergone,sufficient weathering to destroy all relict rock structure. This unit varies from thin (less than 10 feet) upwards to 30 feet in thickness. Typically, the residuum grades into saprolite at depth. Saprolite is thoroughly decomposed bedrock that retains relict rock structure. Thickness of this unit is highly variable, from thin (less than 10 feet) up to 100 feet across the region. The region is within the northeast-trending Brevard fault zone, a narrow belt of steeply dipping low- grade metamorphic rocks. The rocks within the fault zone are generally Cambrian Age porphyroclastic mylonite and cataclastic schist (Lemmon and Dunn, 1973). 2) Significant Changes in Lithology The lithologic descriptions of the subsurface soils and geology at the Facility are based on drilling results of the Geoprobe borings and monitoring wells. Generally, the site geology consists of unconsolidated fill, soil and alluvium, underlain by saprolite and fractured metamorphic rock. The units encountered at the Facility in order of increasing depth are: o Unconsolidated fill and soil o Alluvium o Saprolite o Bedrock The relationship of these units is depicted on the geologic cross-sections on Figures G-1 and G-2. Cross-Section A—A' (Figure G-1) is oriented east-west along the southern boundary of the Facility and Cross-Section B—B' (Figure G-2) is oriented north-south along the eastern boundary of the Facility. I The unconsolidated fill/soil consists of clay and silt with interbedded sand seams.The material ranges in thickness from 3 to 17 feet and appears to thin to the east- northeast at wells MW-3 and MW-4 to thicken to the southwest at wells NM-6D and MW-10. Below the surficial soil is the alluvium, a variable unit ranging from silty clay to sand and gravel. The total thickness of the alluvium ranges from 0 to 15 feet except in the southwestern corner of the Facility at well MW-6D, where the thickness is almost 40 feet. The alluvium consists of interlayered silt, clay and sand except in the area near where the surface ditch-flows under Mills Gap Road. In this area (wells MW-8 and MW- 9, as shown on Drawing G-1), the alluvium is primarily coarser-grained sand and gravel. At well MW-6D, the upper 10 feet is coarser-grained sand and gravel and the lower 30 feet is fine-grained silt and clay. Below the alluvium is the saprolite unit, a clay, silt and sand that demonstrates relict bedrock texture. This unit, which occurs at depths from 5 to 50 feet, ranges in thickness from 14 to 20 feet, with the thickest area near well MW-5D (20 feet). The bedrock beneath the facility is highly fractured metamorphic rock, ranging from schist at MW-3D, MW-5D, and MW-7D to quartzite and slate at MW-6D. The top of the competent(unweathered) bedrock occurs at depths of 20 to 60 feet below grade. 3) Hydraulic Conductivity Representative hydraulic conductivities for the shallow ground-water zone were determined based on values reported in the September 1994 CSA Report for the _ Wilsonart facility. The shallow ground-water zone evaluated at the Wilsonart facility is stratigraphically equivalent to the proposed injection zone at the BorgWamer facility. Based on slug tests, the hydraulic conductivity of the alluvium/saprolite ranged from 0.17 to 2.83 feet per day (ft/day), with an average of 1.16 ft/day. 4) Depth to Mean Seasonal High Water Table Based on the available water level data for the shallow ground-water zone, the depth to the seasonal high water table varies from 14.5 to 3.7 feet below grade across the site. In the proposed area of the injection well pilot test, the depth to the seasonal high water table is approximately 8.5 feet. Historical water-level data for the site is provided in Table G-1. 5) Aquifer Transmissivity and Specific Yield The transmissivity of the shallow ground-water zone in the area of the proposed injection site was calculated based on the reported hydraulic conductivities from the 1994 Wilsonart pumping test and the estimated saturated aquifer thickness. Based on a depth to water of 8.5 feet and total depth of 20 feet, the saturated thickness of the shallow ground-water zone is approximately 11.5 feet. Assuming hydraulic conductivities between 0.17 and 2.83 ft/day, the calculated transmissivity of the shallow ground-water zone is between 2 and 33 ft2/day. The best available specific yield estimates for the shallow ground-water zone are those reported for the 1994 Wilsonart pumping test and range between 0.001 and 0.007 (Rust, 1994). North Carolina Licensed Geologist 2 J Frank J. tchell i References Lemmon, Robert E., 1973, Mineral Resources Summary of the Fruitland Quadrangle, - North Carolina, North Carolina Department of Natural and Economic Resources, Office of Earth Resources Report MRS 202-NW. Lemmon, Robert E. and David E. Dunn, 1973, Geologic Map of the Fruitland Quadrangle, North Carolina, North Carolina Department of Natural and I' Economic Resources, Office of Earth Resources Map GM 202-NW. RUST Environment&Infrastructure, September 1994, Comprehensive Site Assessment/ j Corrective Action Plan, prepared for Ralph Wilson Plastics Company, Fletcher, North Carolina. 1 f I J i ` I O r ENvatbn(teat mall p N oD 0 0o 30 o N0Np O o 0 0�pp 0 0 00 0 o o C N K W O In QJ (J N N N o V too tAp A N A A m O d � m o � _ ry (D ttAJJ m p O� b y � ONi N J 0 A N 0 rS N � � 1 N N N N N N m r k d (A O V O d b ao ppion "' m_ n O J O) W 0) go _R O A � N f\1 tl r� oN N N N m O J � o 00 < R d O pe tl C tJ0 J �jj N fAJ W m O� IC � S V b � "' 00p� 00000o m r � $ 3 �OyOS cM J � op8pJ m mo oW o8 < m f '� r m N N 0D 0 fT �Wp � t0 b < d f1 N �u O p 2 3 VQ 0 A ro y pOp N y 6 S M Ow �0 Nod O 88 p Omp 0 O O O OmP 0 0 O O ry r j d tV0 tVD A N �4 A .t2O W m O — O) N fT A N J P N t�0 IU W R O N N 00 pom O0 00 o N N N N N N N m O I o 00p � p0� A r ,5 f � .tVO 0 m V O+ T fJ ORpD� J O 5 � � �!� 0 0000000 W00pNp W000p p0� p0� o m rfo \: OpVpD N N 0VC (VO mmW W(� O (T N m V ro W V V - A C. N W f0 tOO A 3nn I77I 1771 I} 1T "o V m I + r I I I I I A A W O V O W N O A A J N O m N N m N �tppOO O N O ' m ' N tWp t0 !O W fW0 r W m ' j — 3000 2095 A MW-6D WEST 2090 MW-10 2085 UNCONSOLIDATED FILL/ (10) 207939 2080 2075 2070 2065 2060 2055 2050 2045 2040 2035 2030 C10D 2025 2020 2015 (10D) 2010 2005 I A' EAST MW-7D LEGEND MW-9 MW1-8 ® CLAY SILT y ® SILT/CLAY IIL 2084.057 SAND ALLUVIUM SAPROLRE 27 2079,76 CRYSTALLINE BEDROCK SLATE SCREENED INTERVAL y POTENTIOMETRIC SURFACE BEDROCK S WATER TABLE / 7 POTENTIOMETRIC SURFACE INTERFACE SAPROLITE GROUND WATER LEVEL ELEVATION MEASUREMENTS TAKEN 6/6/01 v Y BEDROCK - - FORMER EATON CORPORATION BORGWARNER COOLING SYSTEMS, INC. FLETCHER, NORTH CAROLINA PLANT DATE:70BM 2002 APPROVED BY: DWN BY:KMAC SCALE: AS SHOWN its CHKD. BY:D1 VERTICAL 1" = 10' SHEET 1 OFT HORIZONTAL: 1' = 100' o GEOLOGIC CROSS SECTION DRAWING NUMBER A-A' FIGURE G-1 B NORTH MW-3/3D MW-4 MW-5/5D 3000 l 1 2095 2090 �0�3E3,( - • 2085 ALLUVIUM (3) = `< r: (5) 2080 _ 2075 2070 OLITE 2065 [7SAPR 2060 E w 2055 (5D) w w z 0 2050 BEDROCK a w2045 (3D) 2040 2035 LEGEND B' SOUTH ® CLAY MW-7D ® SILT ® SILT/CLAY 41 SAND ®2084,05 SAPROLITE - CRYSTALLINE BEDROCK ® SLATE / SCREENED INTERVAL q POTENTIOMETRIC SURFACE BEDROCK WATER TABLE ALLUVIUM/SAPROLITE GROUND WATER LEVEL ELEVATION N MEASUREMENTS TAKEN 6/8/01 O VERTICAL: 1" = 10' HORIZONTAL: 1" 100' cr :, / FORMER EATON CORPORATION = BORGWARNER COOLING SYSTEMS, INC. A '� / FLETCHER, NORTH CAROLINA PLANT -- B DATE:OCTW 2002 APPROVED BY: DM BY:KMAC r r SCALE: AS sgw11 iTs CHKD. BY:oH SHEET 1 OF1 GEOLOGIC CROSS SECTION DRAWING NUMBER RGURE G-2 - i _I 1 r. ATTACHMENT H MONITORING PROCEDURE i ` H MONITORING PROCEDURE Three monitoring wells, one upgradient, one inside the treatment area and one downgradient of the injection site, will be installed in the shallow ground-water zone for purposes of monitoring ground-water quality prior to and following HRC injection. The proposed monitoring well locations are shown in Figure N-1 (Attachment N). Monitoring wells will be drilled using 4 1/4 inch ID hollow stem augers (HSA) 'by advancing the augers to the completion depth and constructing the well within the augers. Monitoring wells will be completed using 2-inch ID schedule-40 PVC casing and 0.010- inch slot PVC screen.- A washed silica sand filter pack will be placed in the annulus around the screen to a depth of approximately 2 feet above the top of the screen. The filter pack will secured with a 2-foot bentonite pellet seal and the remaining annular space will backfilled with bentonite slurry to within approximately 3 feet below the ground surface. Each monitoring well will be completed with a locking, steel protective casing set in a sloping concrete pad. Following construction, the monitoring wells will be developed by surging and pumping with a submersible pump. Each well will be developed until approximately 10 well volumes were removed, the discharge water appeared clear, or the well had been completely evacuated four times. I Following development and prior to HRC injection, ground-water samples from the new monitoring wells will be submitted for analysis of VOCs and the following biodegradation indicator parameters: - o Inorganic parameters consisting of dissolved iron and manganese, sulfide, nitrate, sulfate, chloride, alkalinity, and total organic carbon. o Metabolic acids consisting of lactic, pyruvic, acetic, propionic, and butyric. 1 o Dissolved gases consisting of carbon dioxide, methane, ethane, and ethene. ' o Field parameters including dissolved oxygen, oxygen reduction potential, pH, — temperature, and ferrous iron. The resultant data will be used to establish pre-treatmentfbaseline conditions. Following HRC injection, the new monitoring wells will be sampled every two months for a period of six months for VOCs and the listed biodegradation indicator parameters. The resultant data will be used to evaluate the efficacy of the HRC injection for'reducing VOC concentrations. After the initial six months, the sampling program will be reevaluated to assess the need for continued monitoring. Ground-water samples will be collected using minimal drawdown sampling procedures. In this approach, the wells will be purged with a peristaltic pump at a rate that produces no net drawdown of the water-level surface within the well. The water temperature, pH, specific conductance, dissolved oxygen, and oxidation reduction potential will be monitored continuously throughout the purging process via a constant reading flow-through cell. The ground-water 'samples will be collected following stabilization of the field parameters. Ground-water samples will be placed into approved J containers provided by the laboratory. Sample preservatives will be added to the sample bottles prior to or immediately following sample collection. Following collection, the sample bottles will be labeled and placed in a cooler with ice for delivery to Prism Laboratories for analysis of VOCs and biodegradation indicator parameters. On October 1, 2001, shallow zone monitoring wells MW-1, MW-2, MW-3, MW- 4, MW-5, MW-8, and MW-9 were sampled for VOCs and to characterize the concentrations of the biodegradation indicator parameters listed above.' The laboratory analytical results for the biodegradation indicator parameters in ground water from the shallow zone monitoring wells are summarized in Table H-1. In general:. ❑ Dissolved iron and sulfide were not detected in any of the shallow ground- water samples. ❑ Dissolved manganese concentrations ranged from non-detect (MW-1) to 0.25 mg/L (MW-2). - ❑ Nitrate concentrations ranged from non-detect (MW-2, MW-4, and MW-9) to 0.26 mg/L(MW-1). ❑ . Sulfate concentrations ranged from non-detect (NW-2 and MW-5) to 4.5 mg/L.(MW-1). ❑ Chloride concentrations ranged from 1.1 (MW-5) to 8.7 mg/L (MW-9). ❑ Alkalinity concentrations ranged from 11 (MW-2) to 52 mg/L (MW-1). ❑ Total Organic Carbon was only detected in the ground-water sample from MW-4 at a concentration of 4.7 mg/L. Metabolic acids were not detected in any of the shallow ground-water samples and the dissolved gas analytical results are listed below. ❑ Carbon Dioxide concentrations ranged from 79,000 (MW-5) to 140,000 µg/L (MW-4). ❑ Methane concentrations ranged from 0.31 (MW-1) to 1,900 µg/1 (MW-4). ❑ Ethane concentrations ranged from 0.0076 (MW-1 and MW-3) to 0.052 µg/L (MW-5). ❑ Ethene concentrations ranged from 0.026 (MW-4) to 0.14 µg/l (MW-5). The laboratory analytical results for the biodegradation indicator parameters were submitted along with the VOC data to Regenesis (San Juan Capistrano, California) to evaluate the natural attenuation potential within the shallow ground-water zone. Based on the available data, Regenesis concluded that the following conditions indicate that natural attenuation is on-going at the Fletcher facility: 1 o Presence of dissolved manganese—indicates reducing conditions o Low sulfate—indicates sulfate lowered by sulfate reducers o Sulfides not detected—indicates reducing conditions o Elevated carbon dioxide—indicates biologic activity in aquifer o Presence of methane—indicates reducing conditions o Presence of ethane—indicates naturally occurring reductive dechlorination o Low to no TOC—low TOC associated with reductive dechlorination o Low to no nitrate I Based on these results, it is concluded that conditions in the shallow ground-water zone are favorable for enhanced/accelerated natural attenuation (biodegradation). E I J I i i TABLE H-1 NATURAL ATTENUATION PARAMETERS Former Eaton Facility,Fletcher,North Carolina Detection { Limit MW-1 MW-2 MW-3 MW-4 MW-5 MW-8 MW-9 Field Parameters Dissolved Oxygen (g/L) 0.87 4.41 5.54 0 1.31 n/a n/a ORP n/a n/a n/a n/a n/a n/a n/a pH 6.08 5.10 5.45 5.31 5.66 5.59 5.16 temperature (C) 18.0 14.3 19.0 18.9 15.4 17.9 17.2 ferrous iron (mg/L) 0 0 0 0.2 0 0 0.2 Inorganic Parameters(mg/L) dissolved iron 0.5 ND ND ND ND ND NO ND dissolved manganese 0.01 ND 0.25 0.017 1.6 0.034 0.049 0.018 sulfide 0.5 ND ND ND ND ND ND ND nitrate 0.1 0.26 ND 0.12 ND 0.16 0.11 ND sulfate 1 4.5 ND 3.1 2.8 ND 3.6 2.0 chloride 1 2.4 1.3 1.7 6.1 1.1 4.1 8.7 alkalinity 5 52 11 15 19 28 33 48 TOC 1 ND ND ND 4.7 ND ND ND J Metabolic Acids(mg/L) lactic acid 25 ND ND ND ND ND ND ND pyruvic acid 10 ND ND ND ND ND ND ND acetic acid 1 ND ND ND ND ND ND ND propjonic acid 1 ND ND ND ND ND NO ND butyric acid 1 ND ND ND ND ND ND ND Dissolved Gases(ug/L) _1 carbon dioxide 600 110,000 81,000 100,000 140,000 79,000 120,000 110,000 methane 0.02 0.31 1.8 0.35 1,900 0.59 0.73 0.78 ethane 0.01 0.0076 0.013 0.0076 0.0077 0.052 0.026 0.011 ethene 0.01 0.033 0.039 0.13 0.026 0.14 0.074 0.031 n/a field instrument malfunctioned ND parameter concentration below the method detection limit J I J Leggette,Brashears&Graham,Inc. October 2002 Columbus,Ohio t of 1 Injection Well Permit Application i ATTACHMENT K I OTHER WELL DATA J t I J J K OTHER WELL DATA The available information on all wells within 114 mile of the proposed injection well site that penetrate the shallow ground-water zone (excepting water supply wells serving single-family residences) is provided in Table K-1. A total of 29 wells were identified: ❑ Seven monitoring wells and one site production well are reported at the Wilsonart facility; ❑ Four monitoring wells are reported at the Steelcase facility; ❑ Fifteen monitoring wells are at the BorgWarner facility(former Eaton); and ❑ One monitoring well is reported at the ABF facility. Ji i i J J_ TABLE K-1 WATER WELL SEARCH Former Eaton Facility-Fletcher,North Carolina Number Well Casing Screened Current Owner/User Name of Total Depth Depth(feet Interval Address Wells Well Type I (feet bgs) bgs) (feet bgs) . Comments 1 BorgWamer Cooling Systems, Inc. Cane Creek Industrial Park 1 Monitoring 17 7 7-17 MW-1 BorgWamer Cooling Systems, Inc. Cane Creek Industrial Park 1 Monitoring 17 7 7-17 MW-2 _ BorgWamer Cooling Systems, Inc. Cane Creek Industrial Park 1 Monitoring 16 6 6-16 MW-3 BorgWamer Cooling Systems, Inc. Cane Creek Industrial Park 1 Monitoring 55 45 45-55 MW3D -' BorgWamer Cooling Systems, Inc. Cane Creek Industrial Park 1 Monitoring 14 4 4-.14 MW-4 ( BorgWamer Cooling Systems, Inc. Cane Creek Industrial Park 1 Monitoring 16 6 6-16 MW-5 BorgWamer Cooling Systems, J Inc. Cane Creek Industrial Park 1 Monitoring 26 21 21-26 MW-51 BorgWamer Cooling Systems, Inc. Cane Creek Industrial Park 1 Monitoring 42 32 32-42 MW-5D _ BorgWamer Cooling Systems, i Inc. Cane Creek Industrial Park 1 Monitoring 75 65 65-75 MW613 BorgWamer Cooling Systems, Inc. Cane Creek Industrial Park 1 Monitoring 35 25 25-35 MW-7D BorgWamer Cooling Systems, Inc. Cane Creek Industrial -� Park 1 Monitoring 14 9 9.14 MW-8 BorgWamer Cooling Systems, Inc. Cane Creek Industrial Park 1 Monitoring 19 9 9-19 MW-9 BorgWamer Cooling Systems, Inc. Cane Creek Industrial Park 1 Monitoring 15 5 1 5-15 MW-10 BorgWamer Cooling Systems, Inc. Cane Creek Industrial Park 1 Monitoring 65 60 60-65 MW-101 BorgWamer Cooling Systems, Inc. Cane Creek Industrial Park 1 Monitoring 85 75 75-85 MW-10D BKT Enterprises 1 Monitoring 20 5 15 ABF Transportation Ralph Wilson Plastics Co. Industrial 1469 Cane Creek 1 Supply 401 41 NA RW P Production well Ralph Wilson Plastics Co. 1469 Cane Creek 1 Monitoring 23 13 13-23 i Leggette,Brashears&Graham,Inc. October 2002 Columbus,Ohio 1 of 2 Injection Well Permit Application TABLE K-1 WATER WELL SEARCH Former Eaton Facility-Fletcher,North Carolina Number Well Casing Screened -- Current Owner/User Name of Total Depth Depth(feet Interval Address Wells Well Type (feet bgs) bgs) (feet bgs) Comments J� Ralph Wilson Plastics Co. 1469 Cane Creek 1 Monitoring 29 19 19-29 Ralph Wilson Plastics Co. , 1469 Cane Creek 1 Monitoring unk Ralph Wilson Plastics Co. _ 1469 Cane Creek 1 Monitoring unk Ralph Wilson Plastics Co. 1469 Cane Creek 1 Monitoring unk Ralph Wilson Plastics Co. 1469 Cane Creek 1 Monitoring unk Ralph Wilson Plastics Co. 1469 Cane Creek 1 Monitoring unk Ralph Wilson Plastics Co. -- 1469 Cane Creek 1 Monitoring unk _ Steelcase,Inc ! Hoopers Creek Rd. i 04-684-2241 1 1 Monitoring unk (1) Steelcase,Inc Hoopers Creek Rd. { 04-684-2241 1 Monitoring unk (1) Steelcase,Inc Hoopers Creek Rd. 04-684-2241 2 Monitoring unk (1) t I i Leggette,Brashears&Graham,Inc. October 2002 iColumbus,Ohio 2 of 2 Injection Well Permit Application J ATTACHMENT M INJECTION-RELATED EQUIPMENT J I VI J . J i M INJECTION-RELATED EQUIPMENT The HRC will be pressure injected into the target formation through Geoprobe® drilling rods. Prior to injection, the HRC will be pre-heated, poured into a pump hopper i and mixed to a uniform consistency. Following injection, the Geoprobe® rods will be pulled and the boring will be sealed with bentonite. Because there will be no permanent injection wells or injection equipment at the facility, equipment plans or specifications _J will not be prepared. G J -r J ATTACHMENT N LOCATION OF WELL(S) 6 G f� a w 1997 J � 1994 ¢ II 1994 1987 a E PLOYEE ARKING a a� ORIGINAL AE BUILDING a 1976 i a M � 0 00 a rn as OFFICES a 1978 a PROPOSE a a INJECTIO RKING a MW,6aMW'� MW�S RM - - -- RIV MW-g MW sa wv REN9DN RECORD DATE IDE541tIPaDN REV, REVI.�ESC REYt REVLDESC RE`/3 Hf/3_DFSf. REVI PEV�..DFSC uvs RFvs_oEsc `w,3o LEGEND STORM SEWER — BURIED ELECTRIC —E— BURIED GAS \ —n— FIRE PROTECTION WATER ADDITION \ BURIED SANITARY 1997 PROPERTY BOUNDARY + SECURITY LIGHT m FIRE HYDRANT MONITORING WELL 1994 I I PROPOSED MONITORING WELL _ V • INJECTION WELL a V a �0*'A T� a C MN�2 E . 4,5D vog FORMER, EATON CORPORATION COOLING BORGWARNER COOLING SYSTEMS, INC. FLETCHER, NORTH CAROLINA PLANT gDATE:OCTOBER 2002 APPROVED BY: DWN BY:KNAc SCALE: AS SHOWN ars CHKD. BY:DH m SHEET 1 OF1 0 SITE PLAN DRAWING NUMBER FIGURE N-1 1111011111 F I drA Brashears Grohom, GAHANNA. CHO FORMER EATON CORPORATION BORGWARNER COOLING SYSTEMS, INC. SITE LOCATION MAP FLETCHER., NORTH CAROLINA N a4 --i 6` _ `u II. 1997 1994 a" ¢ ¢ I 1994 1987 ¢ ¢ a EMPLOYEE PARKING I toe s a� IGINAL XADS B DING 1 a a m Qo I OFFICES a 1978 a a VISITOR PARKING a Mw� � 2��9 62 _ 6AP ROAD �1 Mo 9 56 m wv M o$o o REVISION RECORD DALE I DESCdSR1 REV1 i Eli REV2 RlV1_OESC REY.I REV]_DESC REV{ RF/{_pE% REVS I REVS_DESC ADDITION \ 1997 LEGEND �090 —R-T ip MONITORING WELL TEM 1994 I ♦ FOR REAM ELEVATION BENCH O MARK,OR MEASUREMENT —�— BURIED ELECTRIC —E— BURIED GAS —�— FIRE PROTECTION —•— WATER ' — — SANITARY �Mw A MONITORING WELL & STREAM ELEVATIONS MEASURED 9/21/00 J —2090— EQUIPOTENTIAL CONTOUR GROUND WATER FLOW DIRECTION GRADIENT: A-A'r-- 2090 -680 2080 a 0.015 vb 99 �N 15 32 i a� FORMER EATON CORPORATION COOLING BORGWARNER COOLING SYSTEMS, INC. ' FLETCHER, NORTH CAROLINA PLANT DATE:OCTORER 2002 APPROVED BY: DYNJ BY:KEWC §� SCALE: AS SHOWN JTS CHKO. BY:DN SHALLOW ZONE SHEET 1 OFI POTENTIOMEMIC SURFACE MAP DRANANG NUMBER (1/22/02) FIGURE N-3 2ge Kg 22 B 21 ram` r r` • I r GP,260 i i i � � y • •K8,10 KB 'I ' 1997 1994 9 a^ ¢ 1994 1987 • EMPLOYEE I^ KgN`, K8�2 �KB13 PARKING a Kg • a^ ORIGINAL I ry—n—pn—n�- BUILDING ADD —,—a—{-.� 19 1976 a K1 � K 2 a I , , • � � °a\ s G3 � � � i a wP 4n d Gpd� p0 od ® \ OFFICES Gp!�y19 i Gp�2 a® \1978Y. (4 pCS o 10• p , i P�15 a ,2A GP50 P- Gp J N° VISITOR I n G / PARKING 5q$ 1� 7 50° Z Ss 9 Wa- u / MW 60 i 1g\ 35 o Gp�1° P�27-9 Gp ,' GP�N° Gp2 Gp 5� GI?g( PIV MW,9�6 sr lVW MW— G9 REASON RECORD DATEOESCICPllp1 REVt REVt_DESC REY] WEVZOESC IffVJ ,RVJ_DESC REVS REVI_DESC REVS REYS_DESC ADDITION 1997 \ LEGEND . OCTOBER 1999 GEOPROBE BORING, BY KERAMIDA "'-1 •p APRIL 2000, CEC GEOPROBE y�g i�3 SAMPLE POINT Nn a MONITORING WELL 1994 2D I � TEMPORARY BENCH MARK, FOR STREAM ELEVATION I MEASUREMENT BURIED ELECTRIC d O I•Y15 S� D5 a BURIED GAS FIRE PROTECTION BURIED SANITARY BURIED WATER • a 5® p2 1 TOTAL VOC CONCENTRATION (ug/1) OF 0 E NO / OO Gp�23 VS ,5D FORMER EATON CORPORATION BORGWARNER COOLING SYSTEMS, INC. FLETCHER, NORTH CAROLINA PLANT Nx DATE:OCTOBER 2002 APPROVED BY: DWN BY:KWC -ID SCALE: AS SHOWN ,RS CHKD. BY:DH 5 SHALLOW ZONE SHEET 1 OF 1 TOTAL VOCa ISOCONCENTRATION DRAWING NUMBER MAP ("9/1) FIGURE N-4 i -I ATTACHMENT O . INJECTION FLUID DATA _l HRC MSDS Page 1 of 6 FOR w J REGENESIS MATERIAL SAFETY DATA SHEET Mom' Last Revised: March 1, 2001 Section 1 -Material Identification ' beiifJncmramnnRp.ie'�ri- . f— Supplier. Regenesis Bioremediation Products 1011 Calle Sombra _ = San Clemente, CA 92673 Telephone: (949) 366-8000 m ��9 Facsimile: (949) 366-8090 Chemical Name: Propanoic acid, 2-[2-[2-(2-hydroxy-l-oxopropoxy)-l-oxopropoxy] -1-oxopropoxy]-1,2,3-propanetdyi ester Chemical Family: Organic Chemical Trade Name: Glycerol tripolylactate I Product Name: Hydrogen Release Compound® (HRC®) Section 2 -Hazardous Ingredients I CAS #: 201167-72-8 One should anticipate the potential for eye irritation and skin irritation with large scale exposure or in sensitive individuals. l I Section 3 -Physical Data http://www.regenesis.conifBRC/hrcrosds:htm 8/22/2002 HRC MSDS Page 2 of 6 Melting Point: NA Boiling Point: ND Flash Point: ND Density: 1.347 Solubility: Acetone and DMSO Appearance: Amber semi-solid Odor.Not detectable Vapor Pressure:None _I Section 4-Fire and Explosion Hazard Data Extinguishing Media: Carbon Dioxide, Dry Chemical Powder or Appropriate Foam. Water may be used to keep exposed containers cool. - For large quantities involved in a fire, one should wear full protective clothing and a NIOSH approved self contained breathing apparatus with full face piece operated in the pressure demand or positive pressure mode as for a situation where lack of oxygen and excess heat are present. i 1 Section 5 -Toxicological Information Acute Effects: May be harmful by inhalation, ingestion, or skin absorption. May cause irritation. To the best of our knowledge, the chemical,physical, and toxicological properties of the glycerol tripolylactate have not been investigated. Listed below are the toxicological information for glycerol and lactic acid. RTECS#: NIA8050000 http://www.regenesis.com/HRC/hrcrosds.htm 8/22/2002 HRC MSDS Page 3 of 6 Glycerol Irritation data: SKN-RBT 500 MG/24H MLD 85JCAE-,207,1986 EYE-RBT 126 MG MLD BIOFX* 9-4/1970 EYE-RBT 500 MG/24H MLD 85JCAE-,207,1986 Toxicity data: ORL-MUS LD50:4090 MG/KG FRZKAP (6),56,1977 SCU-RBT-LD50:100 MG/KG NMZDN 6,215,1982 ORL-RAT LD50:12600 MG/KG FEPRA7 4,142,1945 1EM-RAT LC50: >570 MG/M3/1H BIOFX* 9-4/1970 IPR-RAT LD50: 4420 MG/KG RCOCB8 56,125,1987 IVN-RAT LD50:5566 MG/KG ARZNAD 26,1581,1976 IPR-MUS LD50: 8700 MG/KG ARZNAD 26,1579,1978 SCU-MUS LD50:91 MG/KG N=N 6,215,1982 IVN-MUS I-D50: 4250 MG/KG JAPMA8 39,583,1950 ORL-RBT LD50: 27 GM/KG DMDJAP 31,276,1959 SKN-RBT LD50:>10GM/KG BIOFX* 9-4/1970 IVN-RBT LD50: 53 GM/KG NIIRDN 6,215,1982 I ORL-GPG LD50: 7750 MG/KG=AB 23,259,1941 Target Organ data: Behavioral (headache), gastrointestinal (nausea or vomiting), Paternal effects (spermatogenesis, testes, epididymis, sperm duct), effects of fertility (male fertility index,post-implantation mortality). RTECS#: OD2800000 Lactic acid Irritation data: SKN-RBT 5MG/24H SEV 85JCAE-,656,86 EYE-RBT 750 UG SEV AJOPAA 29,1363,46 Toxicity data: ORL-RAT LD50:3543 MG/KG FMCHA2-,C252,91 SKN-RBT LD50:>2 GM/KG FMCHA2-,C252,91 http://www.regenesis.com/ERC/hrcrosds.htin 8/22/2002 HRC MSDS Page 4 of 6 ORL-MUS LD50: 4875 MG/KG FAONAU 40,144,67 . ORL-GPG LD50: 1810 MG/KG=AB 23,259,41 ORL-QAL LD50: >2250 MG/KG FMCHA2-,C252,91 Only selected registry of toxic effects of chemical substances.(RTECS) data is presented here. See actual entry in RTECS for complete information on lactic acid and glycerol. Section 6 -Health Hazard Data Handling: Avoid continued contact with skin. Avoid contact with eyes. In any case of any exposure which elicits a response, a physician should be consulted immediately. I First Aid Procedures: Inhalation: Remove to fresh air. If not breathing give artificial respiration. In case of labored breathing give oxygen. Call a physician. Ingestion: No effects expected. Do not give anything to an unconscious person. Call physician immediately. J Skin Contact: Flush with plenty of water. Contaminated clothing may be washed or dry cleaned normally. Eye contact: Wash eyes with plenty of water for at least 15 minutes lifting both uppej and lower lids. Call a physician. Section 7 -Reactivity Data http://www.regenesis.conVBRC/hrcrosds.htm 8/22/2002 y1L\l.lY1VLJ L 4dV J V1 v <• s Conditions to Avoid: Strong oxidizing agents, bases and acids Hazardous Polymerization: None known Further Information: Hydrolyses in water to form Lactic Acid and Glycerol. Section 8 - Spill, Leak or Accident Procedures After Spillage or Leakage: Neutralization is not required. This combustible material may be burned in a chemical incinerator equipped with an afterburner and scrubber. J Disposal: Laws and regulations for disposal vary widely by locality. Observe all applicable regulations and laws. This material, may be disposed of in solid waste. Material is readily degradable and hydrolyses in several hours. No requirement for a reportable quantity (CERCLA) of a spill is known. Section 9 - Special Protection or Handling Should be stored in plastic lined steel, plastic, glass, aluminum, stainless steel, or reinforced fiberglass containers. Protective Gloves: Vinyl or Rubber Eyes: Splash Goggles or Full Face Shield Area should have approved means of washing eyes. Ventilation: General exhaust. Storage: Store in cool, dry, ventilated area. Protect from imcompatible materials. http://www.regenesis.com/HPC/hrcrosds.htm 8/22/2002 HRC MSDS Page 6 of 6 Section 10- Other Information ; This material will degrade in the environment by hydrolysis to lactic acid and - glycerol. Materials containing reactive chemicals should be used only by personnel with -J appropriate chemical training. The information contained in this document is the best available to the supplier as of — the time of writing. Some possible hazards have been determined by analogy to similar classes of material.No separate tests have been performed on the toxicity of this material. The items in this document are subject to change and clarification as more information becomes available. Hninc][UP Copyright©Regenesis Bioremediation Products. I996-2002.All Rights Reserved I ®Registered Trademark ofRegenests Bioremediation Products, Inc. J� �I I J I http://www.regenesis.com/BRC/hmmsds.htm 8/22/2002