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HomeMy WebLinkAboutWI0100015_Complete File - Historical_20220307 V2 AR CA D 1 S ARCADIS G&M of North Carolina,Inc. Infrastructure, buildings, environment communications 801 Corporate Center Drive Suite 300 Raleigh, Mr. Evan Kane North Carolina 27607-5073 LTIC Program Tel 919 854 1282 Groundwater Section Fax 919 854 5448 North Carolina DENR-DWQ w .arcaclis-us.conn 1636 Mail Service Center Raleigh,NC 27699-1636 ENVIRONMENTAL Subject UIC Permit Application for Coats American Sylvan Facility,Rosman,North Carolina,Incident Number 5337. Date: Dear Mr.Kane: 11 June 2003 ARCADIS is pleased to submit three copies of the underground injection permit Contact: application for the above referenced site. This permit is for the injection of oxygen Alan Pinnix release compound to address the presence of vinyl chloride in groundwater. Extension: 247 Should you have any questions,please contact the undersigned. E-mall: apinnix@arcadis-us.com Sincerely, ARCADIS G&M of North Carolina,Inc. our ref: )Alan NC103013.0001 Pinnix, L.G. Project Scientist copies: Mr. Mike Bell Ms. Laura K. Dechant p E C E o W E JUN 16 2003 D GROUNDWATER SECTION ASHEVILLE REGIONAL OEfICE Part of a bigger picture l UNDERGROUND INJECTION CONTROL PERMIT APPLICATION Coats American Sylvan Plant Rosman, North Carolina Groundwater Incident No. 5337 JUN 16 2003 U SECTION E RFiiiOA'AL OFFICE May 2003 VaARCADIS Infrastructure, buildings, environment, communications PREPARED FOR Coats American, Inc. ARCADIS JUN 16 2003 GROUND—WATER SECTION ASHEVILLE REGIONAL OFFiuE UNDERGROUND INJECTION CONTROL PERMIT APPLICATION Coats American Sylvan Facility Rosman, North Carolina Groundwater Incident No. 5337 Prepared for Coats American,Inc. Prepared by ARCADIS Geraghty&Miller of North Carolina,Inc. 801 Corporate Center Drive Suite 300 North Carolina 27607 Tel 919 854-1282 Fax 919 854-SW Ow Ref.: NC103013.0001 Dab: May 2003 This document is intended only for the use of the indWual or entity for which it was prepared and may contain information that is privileged,confidentOL and exempt from disclosure under applxable law.Any dissemination,distribution,or copying of this document is strx*prohibited. ARCADIS GENERAL APPLICATION FOR PERMIT TO CONSTRUCT AND/OR USE A WELL(S)FOR INJECTION COATS AMERICAN SYLVAN PLANT ROSMAN,NORTH CAROLINA GROUNDWATER INCIDENT NO.5337 May 2003 Provided byARCADIS G&MofNorrh Carolina,Inc. Michelle R. ,P.E. Project ltoeer �.•P�N CaRp rr.,, ��•o ,...,,,*% J. Alan Pinnix,L.G. _ aL 1260 Project Scientist L % �y giemYn,b,menu^Winn OI,mWI[RmiMuk. g^_W9tlec NORTH CAROLINA DEPARTMENT OF ENVIRONMENT AND NATURAL RESOURCES TO: DIRECTOR,NORTH CAROLINA DIVISION OF WATER QUALITY DATE: May 30,2003. A. PERMIT APPLICANT — Name: Mr.Mike Bell.Environmental and Safety Coordinator Address: Coats North America Post Office Box 670 City: Toccoa State: GA Zip Code: 30577 County: Stephens Telephone: 1-706-986-2141 Ext.2248 B. PROPERTY OWNER(same as applicant) C. STATUS OF APPLICANT Private: Commercial: X Federal: State: County: Municipal: Native American Lands: I , D. FACILITY(SITE) DATA Name of Facility: Coats American Sylvan Plant Address:Highway 178 City: Rosman Zip Code: 28772 County: Transylvania Telephone: 1-828-862-4215 Ext. 17 Contact Person: Eddie Briscoe E. INJECTION PROCEDURE Provide a detailed description of all planned activities relating to the proposed injection facility including but not limited to: (1) Construction Plans and Materials: ARCADIS G&M of North Carolina,Inc. (ARCADIS) will subcontract with Regional Probing Services,Inc. (Regional Probing)to inject Oxygen Release Compound(ORC)into 9 temporary well points at the Coats Sylvan Manufacturing Facility(the Site)shown on Figures 1, 2, and 3. The ORC material V properties are described in the Material Safety Data Sheet(MSDS)provided as Attachment 1. ARCADIS and Regional Probing will follow the procedures described by L GW-57 REM (Novembu 1999) Page 1 of 9 REGENESIS Bioremediation Products in Attachment 2: ORC® Slurry Installation Instructions, Geoprobe®Injection into the Soil Matrix. During the initial application,the 9 injection points in the source area will be treated with a slurry solution of 60 pounds of ORC and 17 gallons of water per point for a total of 540 pounds of ORC and 153 gallons of water. The calculations used to design the injection program are included in Attachment 3. -- (2) Operation Procedures: Refer to Attachment 2. (3) Planned Iniection Schedule: The proposed scheduled is to complete the injection within a two day period to commence within 4 weeks of UIC permit application approval in . 2003. The proposed injection of ORC will be used to reduce the concentrations of contaminant constituents present in the surficial aquifer at the Site. A second,and possibly a third injection of ORC may be required to achieve the desired contaminant reduction. An injection schedule for the additional injections is unavailable at this time, due to the length of time for monitoring the first injection. It is anticipated that the additional injection events will be performed in less than two days. Additional injections may not be necessary depending on the success of the initial ORC injection. Written notification to NCDENR will be made at least thirty days prior to any subsequent injections. F. DESCRIPTION OF SITE Provide a brief description of the contamination incident and the incident number assigned by the Division of Water Quality staff in the Department's Regional Office: The Coats American- Sylvan Facility is in a rural area of Transylvania County on State Highway 64 near Rosman,North Carolina(Figure 1). The facility,which lies outside the corporate limits of Rosman,is a spinning plant for textile threads used in industrial sewing. The plant was constructed in the mid-1960's and was owned and operated by American Thread until 1991 when American Thread and Coats merged to form Coats American.The 50-acre plant property is bounded on the north, south and east by pasture land. State Highway 64 borders the plant on the western side. The land on the opposite side of Highway 64 is primarily pasture with two parcels containing vacant houses. Topographically,the site lies on the fluvial plain of the French Broad River.The site slopes gently to the southeast, at a horizontal gradient of approximately 0.01 feet/foot,toward the French Broad River,which is approximately 2,000 feet from the site. The surrounding area is characterized by the hills and valleys of the southern Blue Ridge physiographic province. Galloway Creek, a tributary of the French Broad,borders the facility on the west and south sides. When the Sylvan plant began operations in the mid-1960's, floor scrubber and frame cleaning water was placed into a storm-water drain which flowed into the French Broad River. In the early 1970s a small(8 feet x 8 feet x 5 feet deep)pit was dug on the Company property for deposition of the scrubber and frame cleaning water. In 1984 or 1985,the first pit was covered by filling with soil and a second pit was dug. The second pit was used until January 1989 and was covered/filled with soil in August 1989. The floor scrubber and washer water has since been placed into the on-site wastewater treatment plant. GW-57 REM (November 1999) Page 2 of 9 A written Notice of Violation(NOV)was issued April 12, 1990,based upon the results of a groundwater sample collected from the disposal pit groundwater.A Phase I environmental site assessment was performed in August and September 1990. A Phase H environmental site assessment was performed in November and December 1990. Based on the investigations, a Phase I soil/source removal was performed in May 1992.Approximately 500 tons of soil were removed from the pits and transported off-site for disposal by thermal incineration.Phase II and Phase III soil/source removal actions were performed in October 1992. During the Phase II -- excavation event an additional 477 tons of soil were removed from the pits and sent for disposal. Confirmatory samples indicated that one sample contained low concentrations of heavy oils. Based upon the presence of heavy oils at the one location,a third excavation/sampling event was performed and an additional 100 tons of soil were removed and treated off site. On November 4, 1992,the NCDEHNR granted closure certification of the pit areas relative to the source removal.In July 1993 groundwater recovery and treatment was initiated to remediate a small plume containing low concentrations of VOCs and SVOCs. Quarterly monitoring from 1993 to 1995 showed a marked decrease in constituent concentrations. In December 1995, Coats American submitted a Corrective Action Plan(CAP)under 15A NCAC 2L.0106(1). The CAP demonstrated that natural attenuation and natural biodegradation of constituents would remediate groundwater without impacting current or foreseeable receptors. On March 28, 1996,the NCDENR approved the CAP and established a groundwater sampling frequency to monitor degradation of constituents of concern. The approved CAP allowed a reduction of monitoring frequency from quarterly to semiannually for the first year,followed by annual monitoring. Semi-annual monitoring was conducted during the first year(1996). Sampling was then converted to annual monitoring, and the first event was scheduled to be conducted in 1997. However, the initial annual monitoring was not performed until October 1998. The fifth annual sampling event was conducted in September 2002. The following conclusions were based on the September 2002 sampling event: Although eight VOCs were detected in the former recovery well GM-4 during the September 2002 sampling event, only one VOC(vinyl chloride,9.7 µg/L)was reported at a concentration above the established state 2L groundwater standards (Table 1). No constituents were detected in samples collected from wells GM-10,RW-1 and RW-2. Since groundwater monitoring began at the site in the summer of 1993,recovery well GM-4 is the only well to have constituents above regulatory limits. Based on historical data from numerous sampling events conducted over 6 years, it is evident that the area of impacted groundwater at this facility is very small and that only limited migration has occurred due to natural attenuation. The concentration of vinyl chloride in well GM-4 is relatively similar to that observed over the last four sampling events. The site incident number is 5337. G. HYDROGEOLOGIC DESCRIPTION j SECTION(G)MUST BE ORIGINALLY SEALED AND SIGNED BY A LICENSED GEOLOGIST Provide a hydrogeologic description, soils description, and cross section of the subsurface to a depth that included the known or projected depth of contamination. The number of borings shall be sufficient to determine the following: GW-57 REM (November 1999) Page 3 of 9 111111 10, j CAFirp<� �. `aO:�G6NSF •49 ": (1) the regional geologic setting; SEAL o (2) significant changes in lithology; (3) the hydraulic conductivity of the saturated zone; �•n, 5 (4) the depth to the mean seasonal high water table; and ,�•'FQ.. .•�����` (5) a determination of transmissivity and specific yield of the aquifer to l ,y � e n (showing calculations). "s`Jill Regional Geologic Setting The area of Rosman,North Carolina is situated within the Blue Ridge Province. More specifically,Rosman is located to the east of the Brevard Fault Zone within the Chauga Geologic Belt.The entire area of Rosman is underlain by the Henderson Gneiss,which consists of biotite gneiss(Horton and McConnell, 1991). Lithology The site is underlain by silts and clays interbedded with fine sands to a depth of approximately 90 ft bls where bedrock is present. Two lithologic cross sections were constructed using information obtained from soil borings drilled during the Phase 11 investigation. Cross-section A -A',illustrated in Figure 4,presents site lithology from upgradient of the pits at well GM-1 through the pits and downgradient to well GM-7 parallel to the general groundwater flow direction. Cross-section B -B', illustrated in Figure 5,presents site lithology perpendicular to the general groundwater flow direction. The cross-sections indicate that silts and clays are i predominant in the upper portion of the lithologic section. These fine sediments generally coarsen downward to a silty sand at variable depths. However, a clayey-silty sand is present in the upper section of GM-5 and extends to the middle of section of boring BH-3 southwest of the pits. These areas of sandy material illustrate the variable nature of the sediments in the area. However,low permeable silts and clays are generally present in the upper 10 to 15 feet of the lithologic section, especially near the pits where they are present to a depth of at least 10 ft bls. Groundwater Flow and Direction Historical groundwater elevation data were collected at various times prior to and following remedial system operation. A comparison of historical water level data is presented on Table 2 for the June 15, 1993;August 28, 1996; October 20, 1998; October 18, 1999;November 16, 2000; August 2,2001 and September 18,2002 sampling events. All data were collected during times when the recovery system was shutdown and are indicative of natural groundwater flow direction. All water-level data indicate that the natural groundwater flow direction is generally to the southeast and is consistent over time. Based upon the natural groundwater flow direction, the monitoring well network is properly positioned to detect the potential migration of constituents from the former source area near well GM-4. Depth to the mean seasonal high water table is approximately 4.5 feet as measured in GM-4. The hydraulic conductivity(K),which is the capacity of a medium to transmit water, was determined from slug tests in on-site monitor wells. The calculated K values for the wells are _ included in Table 3. The site groundwater flow velocity was calculated using the K values derived from the slug tests, a hydraulic gradient of 0.03 based upon the generated water-level contour maps and an effective 4 GW-57 REM (November 1999) Page 4 of 9 porosity of 0.010 based upon site lithologic data. Using the above assumptions, an average groundwater flow rate of 59 feet per year(ft/yr)was calculated. It is important to note that.this is an average velocity for the site. Using the K values from individual wells,the calculated groundwater flow velocity ranged from a high of 184 ft/yr at well GM-9 to a low of 27 ft/yr at well GM-4. Transmissivity can be calculated from hydraulic conductivity and aquifer thickness. Using a value of 0.2480 ft/day for K and aquifer thickness of 20 feet,the T would be 4.96 fl/day.For the purpose of this calculation,the surficial aquifer is assumed to be present from 5 to 25 feet below land surface in the vicinity of GM-4. The specific yield for the sediments at this site can be obtained from a literature reference. In the vicinity of GM-4,the lithology is predominantly silts and clays. The corresponding specific yield would therefore be approximately 10 percent by volume(Heath, 1989). H. MONITORING PROCEDURE Provide plans for proposed location and construction details of groundwater monitoring well network,including a schedule for sampling and analytical methods. Include any modeling/testing performed to investigate injectant's potential or susceptibility to change - (biological, chemical or physical)in the subsurface. After the injection points are completed, existing site monitor wells GM-4, GM-10,RW-1,and RW-2 will be used to assess the performance of the ORC(Figure 3). Three months after the initial ORC application, a groundwater sampling event will be conducted to measure natural attenuation-parameters and monitor the presence of vinyl chloride(the primary COC) and other volatile organic compounds (VOCs). Geochemical parameters pH,redox,DO,turbidity, temperature, and specific conductivity will be measured and recorded during well purging using a flow through cell. Groundwater samples collected from the four wells will be submitted for laboratory analysis of VOCs using USEPA Method 8260. If analytical results dictate, subsequent ORC applications may be performed. I. WELL USE Will the injection well(s) also be used as the supply well(s) for the following? (1) The injection operation? YES NO X (2) Personal consumption? YES NO X J. CONSTRUCTION DATA(check one) EXISTING WELL being proposed for use as an injection well. Provide the data in(1)through(7)below to the best of your knowledge. Attach a copy of Form GW-1 (Well Construction Record)if available. X PROPOSED WELL to be constructed for use as an injection well. Provide the data in(1)through(7)below as PROPOSED construction specifications. { Submit Form GW-1 after construction. cw-57 REM (November 1999) Page 5 of 9 i (1) Well Drilling Contractor's Name: Regional Probing Services, Inc. NC Driller Registration number: 1625 (2) Date to be constructed: 2003 (to be determined based on UIC permit approval date. Number of borings: 9 Approximate depth of each boring(feet): 25 (3) Well casing and screens: As described in Attachment 2,there are no screened intervals, and the injection zone will be from approximately 25 feet below land surface(ft bls)to approximately 5 ft bls. (4) Grout type shall be Portland Cement Type I. The boreholes will be grouted to land surface upon completion of the injection activities (5) N.C. State Regulations (Title 15A NCAC 2C .0200)require the permittee to make provisions for monitoring wellhead processes. A faucet on both influent(recovered groundwater) and effluent(fluid being injected into the well) lines is generally required. This is not applicable due to the one time nature of the ORC application,and the fact that there are no well casings or screened intervals for either injection or groundwater extraction. Will there be a faucet on the influent line? yes_no X . Will there be a faucet on the effluent line? yes no X . (6) SOURCE WELL CONSTRUCTION INFORMATION: Not Applicable. NOTE: THE WELL DRILLING CONTRACTOR CAN SUPPLY THE DATA FOR EITHER EXISTING OR PROPOSED WELLS IF THIS INFORMATION IS — UNAVAILABLE BY OTHER MEANS. K. OTHER WELL DATA Provide a tabulation of data on all wells within '/<mile of the injection well(s), excepting water supply wells serving a single-family residence,which penetrate the proposed injection zone. _ Such data shall include a description of each well's type, depth,record of abandonment or completion, and additional information the Director may require. During the Corrective Action Plan phase of work,a potable well survey was conducted during for properties within a 1,500-foot radius of the impacted monitor well (GM-4). Wells excepting single-family residence wells include a water supply well on the NCDOT Maintenance Building property,and three water supply wells,two groundwater recovery wells,and 11 groundwater monitor wells present on the Coats American property. Water-supply wells in the area typically pump water from the bedrock,which is present approximately 90 ft bls at the site. Well data are { tabulated below. GW-57 REM (November 1999) Page 6 of 9 i Relative Top Well Date of Casing Screened Interval Site Well ID Typ e Installed Elevation (Feet BLS (NCDOT TRA-25- NA NA NA NA Maintenance 2-21 Buildings) _ Coats GM-1 8/6/90 184.84 11-21 American GM-2 8/7/90 181.32 4-14 Sylvan Facility GM-3 8/9/90 180.26 13-23 GM-4 8/7/90 179:53 5-15 GM-5 11/28/90 178.55 10-20 GM-6 11/29/90 177.13 9-19 GM-7 11/29/90 176.17 5-15 GM-8 11/27/90 178.16 10.5-20.5 GM-9 12/19/90 176.07 8-18 GM-10 9/16/91 178.29 65-75 GM-11 9/17/91 175.40 79-89 RW-1 6/5/92 177.03 5-50 RW-2 6/4/92 177.03 5-50 PW-1 NA NA 400 feet total depth PW-2 NA NA 400 feet total depth PW-3 NA I NA 1 212 feet total depth L. PROPOSED OPERATING DATA (1)- Injection rate: Average(daily) 1_6 gallons per minute(gpm) (2) Injection volume: Average(daily) 76.5 gallons per day(gpd) (3) Injection pressure: Average(daily) 100 pounds/square inch(psi) (4) Injection temperature: Average(January) N/A°F,Average(July)N/A°F (5) Hydraulic capacity of the well: Not Applicable (6) Expected lifetime of the injection facility: 0.005 year (7) Give a description of how the above data will be measured and controlled: The injection rates/volume are monitored during the injection process by pre-measuring the amount of ORC slurry to be injected per point as specified in the work plan. The entire volume is then injected for that point, during which time the injection pressure is monitored with an in-line standard pressure gauge. The temperature of the injected slurry will approximate the ambient atmospheric temperature at the time of injection. The hydraulic capacity is not applicable because there is no well casing or screened interval with this process. The expected lifetime of the injection process is one to two days per event. M. INJECTION-RELATED EQUIPMENT See Attachment 2. N. LOCATION OF WELUSl -- Attach a scaled, site-specific map(s) showing the location(s) of the following: GW-57 REM (November 1999) Page 7 of 9 (1) the proposed injection well(s) (See Figure 3); (2) all property boundaries (See Figure 2); (3) contour intervals not exceeding two feet(See Figure 1); (4) the direction and distance from the injection well or well system to two nearby, permanent reference points (such as roads, streams, and highway intersections) (See Figure 2); (5) all buildings within the property boundary(See Figure 2); (6) any other existing or abandoned wells, including water supply and monitoring wells, within the area of review of the injection well or wells system(See Figure 8); (7) potentiometric surface showing direction of groundwater movement(see Figure 6); (8) the horizontal and vertical extent of the contaminant plume(including isoconcentration lines and plume cross sections) (see Figure 7; due to limited extent of impact above NCAC 2L standards,i.e.vinyl chloride in only one well, a plume cross section was not developed); (9) any existing sources of potential or known groundwater contamination,including waste storage,treatment or disposal systems within the area of review of the injection well or well system(None); and (10) all surface water bodies within 1000 feet of the injection well or well system (see Figures 1,2). O. INJECTION FLUID DATA (1) Fluid source,if underground, from what depth, formation and type of rock/sediment unit will the fluid be drawn(e.g.,granite, limestone,sand,etc.). Not Applicable-potable water will be used for ORC slurry. (2) Provide the chemical,physical,biological and radiological characteristics of the fluid to be injected. See Attachment 2. P. PERMIT LIST Attach a list of all permits or construction approvals that are related to the site,including but not limited to: (1) Hazardous Waste Management program permits under RCRA (2) NC Division of Water Quality Non-Discharge permits (3) Sewage Treatment and Disposal Permits 4 (4) Other environmental permits required by state or federal law. L All permits and construction approvals relating to the site are on file with the Environmental Compliance Division and are available upon request. Q. CERTIFICATION "I hereby certify,under penalty of law,that I have personally examined and am familiar with the information submitted in this document and all attachments thereto and that,based on my GW-57 REM (November 1999) Page 8 of 9 All permits and construction approvals relating to the site are on file with the Environmental Compliance Division and are available upon request. Q. CERTIFICATION 1 hereby certify, under penalty of law,that I have personally examined and am familiar with the information submitted in this document and all attachments thereto and that, based on my inquiry of those individuals immediately responsible for obtaining said information,I believe that the information is true, accurate and complete. I am aware that there are significant penalties, including the possibility of fines and imprisonment, for submitting false information. I agree to construct, operate, maintain,repair, and if applicable,abandon the injection well and all related appurtenances in accordance with the approved specifications and conditions of the Permit." (Signature of Well Owner or Authorized Agent) Ifauthorized agent is acting on behalf of the well owner, please supply a letter signed by the owner authorizing the above agent. R. CONSENT OF PROPERTY OWNER (Owner means any person who holds the fee or other property rights in the well being constructed. A well is real property and its construction on land rests ownership in the landowner in the absence of contrary agreement in writing.) If the property is owned by someone other than the applicant,the property owner hereby consents to allow the applicant to construct each injection well as outlined in this application and that it shall be the responsibility of the applicant to ensure that the injection well(s) conforms to the Well Construction Standards (Title 15A NCAC 2C .0200) (Signature Of Property Owner If Different From Applicant) cw-57 Ram (November 1999) Page 10 of I 1 C , UIC Permit Application FIGURES Cherryfield • .Y r•1 _ ' Gran -d • 2 Hiii n 2 2?�d llbi At Moriah . G;r sr1 vx:soN• SITE 1, C'ul ccn LOCATION 4. SFG'r:3 STn TIC" .. Rosman r,on 1/2 0 1 uiLE 1" 0 1000 2000 3000 4000 5000 6000 7000 SCALE 1:24000 N County Contour Interval 40—ft Datum is Mean Sea Level Location U.S.G.S. 7.5 Minute Series Rosman, NC Topographic Quadrangle. PUTIX Dcae9 rr. FIGURE N0. ARCADIS P.Pfii„1N D T a.. w&wiN NCTOPO SITE �s �U a„� Cam., �. LOCATION 801 Cor to center 01ae. 9 to 300 KJT ND NC101043.0001 „ e h, NC 2)601 COATS AMERICAN — SYLVAN FACILITY Txj 919-M4-1282 Fox: 919-854-5448 0y0 WE' wiKTEA wv.arcaale-ue.wm 120CT01 n NORTO„ ROSMAN, NORTH CAROLINA eo 64 Cws AHERICAN 11 ,c -- ROSMAN PASTURE ,x — l70 PROPERTY LINE VICINITY MAP NTS ' GRAS: GM-9 ,GM-11 ,4 GM-8 RW-2 AGM-7 EXCAVATED X GM-1 PfT AREA No.1 ' *-GM-6 GM-2y -4 RW-1 EXCAVATED N GAF PIT AREA No.2/ M- v GM-1 PASTURE 1--� ray ?, j — ----------------------� m COATS A oRICAN GRASS /�� .x, NUFA( T—BUILI 01 GRASS I ``\ O GRASS ,x t7 P A R K I N ,v GRASS — REFERENCED DRAWINGS — ax.+wm OESaI°VMx xa. A-1 LOCKWOOD GREEN SITE '°;.° A-2 LOCKWOOD GREEN GRADE 63108 PROPERTY PLAT SY-124 SYLVAN PLANT _ ARCADIS PRJT MANAGER- CHECKED BY+ DRAFTER- PROJECT A PINNI% K PAHR A. NORTON NOTES: DRAWING ARCADIS ChM of North Carolina, Inc. SITEI Cl 801 Corporate Center Drive, Suite 300 Raleigh, NC 27607 DATE- Tel: 919-854-1282 Fax: 919-854-5448 .arcadis—us.conn I4HAY03 w m n Y[ � a4 a4 �� 15' WIDE EASEMENT ACCESS ROAD TO m PASTURE PUMP STATION mQ \ H BROAD DIS TANCE TO FRENC j��Es I\ R42R i4 SHORTEST Pw-s--\ W-2 i4 . 19 GPM 9212' PM @400' PW_1 125 GPM 0400' FENCE .Y< a4 ��\ ..PROPERTY LINE a4 Oo 0 SEWAGE DISPOSAL PLANT t YLVAN PLANT o 4 r w ING � 3 [4 [ r a4 a[ [ °4r a4 Y< 4 1 a4 a4 GRASS a4 LEGEND GRASS a4 a4 a4 [ Y[ I BUILDING/STRUCTURE s Y< G4LLOYAY CREEK — + — FENCE LINE PROPERTY LINE a4 a4 , "[ a4 GRASS - a4 PAVEMENT M h Yc ____ — _ __—__y�__ Oe ab ,4 GRASS STATE HIGHWAY #64 MONITOR WELLS A RECOVERY WELLS ■ PRODUCTION WELLS SCALE IN FEET 0 250 500 R. NC103013.0001 FIGURE: AMERICA — SYLVAN FACILITY SITE OSMAN, NORTH CAROLINA LAYOUT 2 I \+ LEGEND I \+ —•—•— FENCE • MONITOR WELL + A RECOVERY WELL IPROPOSED ORC x N \+\ INJECTION POINT I +\ SCALE IN FEET i +\jPROPERTY o 30 BOUNDARY i EXCAVATED + PIT AREA 2 \ I +\GM-2 GM-8 • I +\ I +\ x GM-3 • I � + + GM-9 GM-4 •RW-2 \+\ I EXCAVATED • GM-10 PIT AREA 1 4-\ x I +\ + x + +�i RW-1 • GM-7 • _ +\ • GM-5 I •GM-11 x PRJT 1aNaGER- CHECKED BY. FIGURE. A��/�A���+ a PIHmx H PAHR MONITOR WELL AND RECOVERY WELL LOCATIONS J BRAVING,COATS-SITE-03D AND PROPOSED ORC INJECTION POINTS 3 ARCADIS GA:M of North CmoDRo, Inc. NC103013.0001 801 CoMo.ate Center DAre, Suite 300 PRJT ND COATS AMERICAN—SYLVAN FACILITY Role. h, NC 27607 rel: $19-854—IZ82 Fax: 919-854-5448 DVG DATE. DWYER. ROSMAN, NORTH CAROLINA www.OrcaEie—ue.com 13MY03 A. NORTON A p■ 105 GM-1 8H-1 GI GM-3 GM-4 GM-10 GM-7 185 180 I I I I 180 A1� 175 6. . . 4 k 175 I \•\, w-B ,. 1`YSllfy'ySandJ II uixx \\ x170 -P 170 - T a �= elnc I cu-m A. 165 s"fA7 +. H t- ,y,, ..; • 165 I Du-a Ae oa-11 GM-6 160 �4'a 160 T I c � 155 nr } 155 150 F' 5 � ' y- + x�"r� A pf A t _ Fiy fi ,.f{�3y,1 6r . 150 145 'Ati"'r� ,a�8 ' de"� '� .0 t¢ 145 �,,yytk rrt-t`.+s`1ft,R,,`s qr. ,i' &]fir �' tr'1 Y . 1i, + � T ,Y�•' '' h _ 3-'^'i .� ti'ur LEGEND wo 140 , , , Organic Clays and Organic Silty Clay 135 -r�, 1s „ I • 135 Inorganic Clays and Gravelly, Sandy. or Silty Clay 130 130 T Sc Silty Sands, Poorly Graded • .{125 3 r ,I!._ Sand-Silt Mixture � �3 I I �i� jtx '` I ! s hu 1T,d+ 125 z • } `" �' "r ,,� '' Inorganic Silts, Fine or Silty s g ' -$' r '-'r1 tl '''`. 120 Soils d ® Inorganic Clays 115 115 Land Surface 110 w� { R ' ,`'`'',ret�y �� ,£'v Well Casing vERncAL'SCAtE.IN FEET -..�.---- - - - 105 105 0 15 30 100 II' S Q�r .r`W`h 4 Id iillti 11: k3N 1 Y .' + rk 'rri>Fi'+ `J h4. g P't 7fi. 00 HORIZONTAL SCALE IN FEET O 60 120 ' 95 95 PRJT MANAGER. CHECKED BY, - FIGURE.U vING,%A-A N PANR GENERALIZED SUBSURFACE CROSS-SECTION A-A' ARCADIS MIJ RT N•Ah Caralina, Iac:2760) A Rv 801 CerPemmal caer OAve. Suite 300 PRJT Na a NC103013,0001 COATS AMERICAN SYLVAN FACILITY laigqh, NC Tel: 918-854-12e2 Far. 919-854-5448 DWG DATE. DRArTM ROSMAN, NORTH CAROLINA .orcaala—ue.c•m 16MAY03 A. NORTON mp I B' By wia I Q �. cx-B I �.Lnr-x gig I 1 oR-10 GM-5 BFi-3 ' GM-4 GM-8 � ' B cu-e 160 160 I i cuwnn ,m 175 tf + - t g18' 175 - '.$'iv max• ", r r ,+ y LEGEND .. 170 -ry'Y; i..:3tf C} Clayey Silty Sand* R'` .4'. -tr 170 Clayey Silty Sand, Poorly 1 Graded Sand-Silt-Clayey Mixture Ck �y. �3�Y 4'SGa x�l � 4 i '. � � •�'. n T`i s. ° . Inorganic Clays and Gravelly, 165 .,�;€x�a'� .� 165 Sandy, or Silty Clay -- ;17 Silty Sands, Poorly Graded 160 1fi0 Sand-Silt Mixture �`.,� I .� �� , Inorganic Silts, Fine Sandy 'I' _' '� '+-P • 'i or Silty Soils 155 155 Inorganic Silts & Fine Sands, ® Silty or Clayey Fine Sand ° ® Inorganic Clays 150 150 Land- Surface Well Casing VERTICAL SCALE IN-FEET 0 10 20 HORIZONTAL SCALE IN FEET 0 40 RO PRJT MANAGER- EMEE'HED BY• nOUflE: ARCAD_ 1S A PINNI% M PAHR BRAVING e_B GENERALIZED SUBSURFACE CROSS-SECTION B-B' set C. c31u C M.r dC.. BC. Inc. NC103013.0001 5 e01 IS G&b f Mort OCar Carolina, c. PRJT N6 Raleigh, NC 27607 COATS AMERICAN SYLVAN FACILITY ' TAR: B1B-es4-1282 FR.: 919-ee4-s44s DWG DATE. DRAFTER ROSMAN, NORTH CAROLINA ww,orcadI.....com 16MAYD3 A. NORTON 00 w � GM-1 174.80 r\ PROPERTY i BOUNDARY r +\ b EXCAVATED \r PIT AREA 2\O \ O I \r �GM-8 GM-2 \, 172.17 ASSUME 184.0' ELEVATION i 174.48� \ / AT LOADING DOCK ENTRANCE GM-3 G • 172.72 GM-9 • RW-2 168.65 172*72 EEXPITCAVA PIT 1 GM-10 \r ' \« / BUILDING I� � � \r j PAVED I • GM-5 RW-1• 168.39• \r\ 170.46 • GM-11 / II • GM-6 168.81 LEGEND —•— FENCE NOTE 1: ALL ELEVATIONS ARE RELATIVE TO I • MONITOR WELL THE LOADING DOCKENTRANCE. i A RECOVERY WELL NOTE 2: GROUNDWATER ELEVATION DATA 172.72 WATER LEVEL ELEVATION (FT,MSL) FROM WELLS GM-10, GM-11, i —170— POTENTIOMETRIC CONTOUR 2-FT RW-1 & RW-2 WERE NOT USED ( ) IN DETERMINING GROUNDWATER 3 GROUNDWATER FLOW DIRECTION CONTOURS DUE TO SCREENING SCALE IN FEET DEPTHS BELOW SHALLOW AQUIFER. 0 60 PRJT PANI H. PAHR BY, GENERALIZED - FIGURE: Va ARCADIS PINNIX H. PANR 9RAv1xd COATS-SITE-03 GROUNDWATER FLOW DIRECTION 801AD;S G&Meof Net o`Carolina, Inc. PUT Nd SEPTEMBER 18, 2002 6 Raley", INC 2760T NC103013.0001 Tel: 919-854-1282 Pox. 919-854-5448 DvG COATS AMERICAN—SYLVAN FACILITY ewr.a,caele-ae.com 13HAY03E A NCR;N ROSMAN, NORTH CAROLINA GM-1 174.80 I r PROPERTY i \ BOUNDARY r\r 1`T r\ _ r EXCAVATED \+ PIT AREA 2\ \ GM-2 �• \+ NS ASSUME 184.0' ELEVATION I UZI \r AT LOADING DOCK ENTRANCE GM-3 *, GM-4 \+ • ...t.' • RW-2\ rW EXCAVATED GM-10 <1.0 r\ PIT AREA 1 <1.0 +\ / BUILDING I +\r j PAVED RW_1 O NS \♦\•• G© <1.0 • GM—lL NS • GM-6 LEGEND I NS —•— FENCE • MONITOR WELL RECOVERY WELL i 90. VINYL CHLORIDE CONCENTRATION (Ng/L) FN_Sj NOT SAMPLED APPROXIMATE HORIZONTAL EXTENT l OF GROUNDWATER IMPACT ABOVE SCALE IN iEEf GGG....0 NC 2L STANDARDS o 60 PRJT MANAGER. CHECKER 9Y. VINYL CHLORIDE - ^°ORE: ARCADIS A N PARR (N9/L) DRAWING. viNU COATS-SITE-03 CONCENTRATIONS 801 CI°rpomto Center ofna 7m a°ia0 PRJT NEB SEPTEMBER 18, 2002 7 Tel:91, NC 4-128 NC I03013.0001 Tel: 9 , NC 2-1382 Fat: 919-850-5449 COATS AMERICAN—SYLVAN FACILITY '"•araa019—° °°m ISMAYOTE A. NORTON ROSMAN, NORTH CAROLINA 1 I 32 1 25E� 26 21A 97 _ 21 6� 8 I 18 92B 20 \ / , _I 17 r \ FORMER S J f___-- ----- �--- I I COATS AMERICAI 1 16 93 15 13H 1 1 --- -T -- -f i39 1 13A 13B L �'/' 13 1 13E� ♦ , —T--- � _ 13J_ A 14 ~') 12D - -_12A � 92D -L 12C 1 12B ` � - ,12E -�- L 12 12E\ SCALE IN FEET 0 400 800 - -�_L A.PUT MANAGER CHECKED BY, DRAFTERS PROJECT ARCADI L NOTES: M. PAHR DDRAWINGN ARCADIS C&M of North Carolina, Inc. TRANS-1 801 Corporate Center Drive, Suite 300 Raleigh, NC 27607 DATE, Tel: 919-854-1282 Faz: 919-854-5448 www,arcadis—us.com l6MAY03 i 1 i I 1 \ I 89 ` 92G go MoU 91 \` o 9 \ � 92 LEGEND 1500-FT = PROPERTY LINE RADIUS — 1500-FT RADIUS FROM SOURCE / INTERMITTENT STREAM \ �I( WATER SUPPLY WELL NOTE: SEE TABLE FOR ,PROPERTY DESCRIPTIONS.. ER' NC103013.0001 FlGURE: f AMERICAN - SYLVAN FECILITY WATER-SUPPLY WELLS WITHIN 1,500=FEET ?OSMAN, NORTH CAROLINA OF THE SOURCE AREA 8 i UIC Permit Application ARCADIS TABLES Table 1. Groundwater Quality Detection Summary,September 2002 Sampling Event,Coats American-Sylvan Plant,Rosman,North Carolina. Constituent NC GWI/ GM4 DUP-1* GM-10 RW-1 RW-2 Date Sampled 9/18/2002 9/18/2002 9/18/2002 9/18/2002 9/18/2002 Pnrgeable Halnearbons (USEPA Method 601)µg/L 1,1-Dichloroethane 700 8.1 9.0 <1.0 <1.0 <1.0 1,1-Dichloroethene 7 <5.0 <5.0 <1.0 <1.0 <1.0 1,1,1-Txichloroethane 200 5.0 <5.0 <1.0 <1.0 <1.0 Trichlorofluoromethane 2100 15 16 <1.0 <1.0 <1.0 Vinyl Chloride 0.015 9.7 9.2 <1.0 <1.0 <1.0 Pnrgeable Aromatics (USEPA Method 602)µg/L Toluene 1000 110 100 <I.0 <I.0 <1.0 Ethylbenzene 29 14 14 <1.0 <1.0 <1.0 Total xylenes 530 84 75 <2.0. <2.0 <2.0 Semi-Volatile Orga_ni .a (USEPA Method 8270)µg/L - ND ND ND ND ND Total TICsv 116.6 145.3 141 32 103.7 µg/L Micrograms per liter. I/ North Carolina Subchapter 2L Groundwater Standards. v Tentatively identified Compounds(TICS)(estimated concentrations). J Sample data are qualified as estimated. < Not detected above the quantitation limit. * Blind field replicate of primary groundwater sample GM-4. OConstituent concentration is above groundwater standard. ND Compounds were not detected in sample. GAEnv\CantsAmeri=\Sylvan 1`1=62002 S=pling\Tables\tablel.xls Table 2. Groundwater Elevations, Coats American-Sylvan Plant,Rosman,North Carolina. Pre-Pumping Non-Pumping Non-Pumping Measuring 6/15/1993 8/28/1996 10/20/1998 Well Point Depth to Water-Level Depth to Water-Level Depth to Water-Level Elevation* Water** Elevation Water** Elevation Water** Elevation ~ GM-1 184.84 11.72 173.12 9.22 175.62 11.10 173.74 GM-2 181.32 9.30 172.02 4.85 176.47 7.37 173.95 J GM-3 180.26 9.25 171.01 7.09 173.17 8.12 172.14 GM-4 179.53 8.80 170.73 4.50 175.03 5.38 174.15 GM-5 178.55 11.15 167.40 8.26 170.29 9.20 169.35 GM-6 177.13 14.32 162.81 8.77 168.36 11.09 166.04 GM-7 176.17 11.64 164.53 8.31 167.86 9.21 166.96 GM-8 178.76 8.46 170.30 7.92 170.84 7.21 171.55 GM-9 176.07 11.05 165.02 9.03 167.04 8.79 167.28 GM-10 178.29 11.78 166.51 8.67 169.62 9.55 168.74 GM-11 175.40 15.94 159.46 11.37 164.03 12.40 163.00 RW-1 177.03 13.75 163.28 9.89 167.14 9.81 167.22 RW-2 177.37 12.14 165.23 8.90 168.47 9.83 167.54 Non-Pumping Non-Pumping Non-Pumping Measuring 11/16/2000 8/2/2001 9/18/2002 Well Point Depth to Water-Level Depthto Water-Level Depthto Water-Level Elevation* Water** Elevation Water** Elevation Water** Elevation GM-1 184.84 9.70 175.14 10.09 174.75 10.04 174.80 GM-2 181.32 6.00 175.32 4.95 176.37 6.84 174.48 GM-3 180.26 6.72 173.54 ND ND 7.54 172.72 GM-4 179.53 4.35 175.18 4.41 175.12 5.50 174.03 GM-5 178.55 6.79 171.76 7.77 170.78 8.09 170.46 GM-6 177.13 7.61 169.52 7.90 169.23 8.32 168.81 GM-7 176.17 6.83 169.34 7.36 168.81 7.78 168.39 GM-8 178.76 5.94 172.82 6.36 172.40 6.59 172.17 GM-9 176.07 6.57 169.50 7.09 168.98 7.42 168.65 GM-10 178.29 6.66 171.63 7.50 170.79 7.72 170.57 GM-11 175.40 5.56 169.84 7.15 168.25 7.58 167.82 " RW-1 177.03 7.92 169.11 8.13 168.90 8.44 168.59 RW-2 177.37 6.95 170.42 7.63 169.74 7.92 169.45 * Measuring point is the top of PVC casing;all elevations are relative. ** Depth below top of PVC casing. ND No Data G:\Env\Coats Amexi=\Sylvaa P1an62002 Annual Monitoring\Tables Table 3. Hydraulic Conductivity Values from Slug Tests, Coats American Sylvan Plant, Rosman,North Carolina. Well Hydraulic Conductivity(K) cm/sec GM-1 2.68 x 10-4 GM-3 1.10 x 10-4 GM-4 8.75 x 10"5 GM-5 1.17 x 10-4 GM-6 1.22 x 104 GM-7 7.47 x 10-5 GM-8 1.63 x 104 GM-9 5.93 x 10-4 cm/sec Centimeters per second. g:lmWeoan�ai�\%➢han plmtWic pemitUable 3.d«\ UIC Permit Application ARCADIS ATTACHMENT t ORC MATERIAL SAFETY DATA SHEET L-. OXYGEN RELEASE COMPOUND (ORC®) MATERIAL SAFETY DATA SHEET (MSDS) Lr Last Revised:March 27,2003 L~ SECTION 1 -MATERIAL IDENTIFICATION *####k########***************kk##******#k########*#k#####************######**# SUPPLIER: REGENESIS 1011 Calle Sombra San Clemente, CA 92673 949-366-8000 phone 949-366-8090 fax info@regenesis.com e-mail CHEMICAL DESCRIPTION: A mixture of Magnesium Peroxide [M902],Magnesium Oxide [MgO], and Magnesium Hydroxide [Mg(OH)2] CHEMICAL FAMILY: Inorganic Chemicals r , PRODUCT NAME: j Oxygen Release Compound(ORC"') PRODUCT USE: Used for environmental remediation of contaminated soil and groundwater SECTION 2-CHEMICAL IDENTIFICATION CHEMICAL CHARACTERIZATION Magnesium Peroxide [MgO2]: CAS Reg.No. 14452-57-4 Magnesium Oxide [MgO]: CAS Reg.No. 1309484 Magnesium Hydroxide((Mg(OH)2): CAS Reg.No. 1309-42-8 ` FORM : powder - COLOR:white ODOR: odorless j I ASSAY:25 -35%Magnesium Peroxide(MgO2) ****************************************************************************** SECTION 3 -PHYSICAL AND TECHNICAL SAFETY DATA ****************************************************************************** MELTING POINT:Not Determined BOILING POINT:Not Determined DENSITY: 0.6-0.8 g/cc BULK DENSITY: --- VAPOR PRESSURE: Data not available VISCOSITY: -- SOLUBILITY: Reacts with water. Soluble in acid pH VALUE: Approx. 10 in saturated solution FLASH POINT:Not applicable SELF-IGNITION TEMPERATURE:Not applicable EXPLOSION LIMITS %BY VOLUME: — THERMAL DECOMPOSITION: Spontaneous decomposition possible about 150' C ` HAZARDOUS DECOMPOSITION PRODUCTS:Not known HAZARDOUS REACTIONS: Hazardous polymerization will not occur FURTHER INFORMATION:Non-combustible,but will support combustion SECTION 4-REACTIVITY DATA STABILITY: Product is stable unless heated above 150°C.Magnesium Peroxide reacts with water to slowly release oxygen.React by product is magnesium hydroxide 1 CONDITIONS TO AVOID: Heat above 150°C. Open flames INCOMPATIBILITY: Strong Acids. Strong chemical agents HAZARDOUS POLYMERIZATION:None known I 1 ############################################################################## SECTION 5-REGULATIONS ############################################################################## PERMISSIBLE EXPOSURE LIMITS IN AIR:Not established. Should be treated as a nuisance dust. SECTION 6-PROTECTIVE MEASURES,STORAGE,AND HANDLING TECHNICAL PROTECTIVE MEASURES STORAGE: Keep container tightly closed.Keep away from combustible material HANDLING: Use only in well-ventilated areas PERSONAL PROTECTIVE EQUIPMENT _ RESPIRATORY PROTECTION: Recommended(HEPA Filters) HAND PROTECTION: Wear suitable gloves EYE PROTECTION: Use chemical safety goggles OTHER: --- INDUSTRIAL HYGIENE: Avoid contact with skin and eyes PROTECTION AGAINST FIRE AND EXPLOSION: --- DISPOSAL: Dispose via sanitary landfill per state/local authority f _ FURTHER INFORMATION:Not flammable,but may intensify fire ############################################################################## SECTION 7-MEASURES IN CASE OF ACCIDENTS AND FIRE AFTER SPILLAGE/LEAKAGE/GAS LEAKAGE: Collect in suitable containers.Wash remainder with copious quantities of water. J EXTINGUISHING MEDIA it SUITABLE: Carbon dioxide, dry chemicals, foam I� NOT TO BE USED: --- FURTHER INFORMATION: Self contained breathing apparatus or approved gas mask should f I be wom due to small particle size. Use extinguishing media appropriate for surrounding fire. 1 FIRST AID:After contact with skin,wash immediately with plenty of water and soap. In case of contact with eyes,rinse immediately with plenty of water and seek medical attention. FURTHER INFORMATION: --- **MMMMMMMMMMM#MMMM***MM*MM###*##*MMMM#**MMMMM#######**#*##########**#*MM##**** SECTION 8-INFORMATION ON TOXICOLOGY *MMMM##*#########M#M##MM###****MM###**MMM##**#***#*****MM**MM*MMMMMM###***MMM# TOXICITY DATA:Data not available *****MMMMMMMM*M*#***MM#*MMMMM###**MM#****MMMM##*#***************#*MMMMM###**** SECTION 9-INFORMATION ON ECOLOGY WATER POLLUTION HAZARD RATING(WGK): 0 ****MM#MMM#MMMMMMM#MMM#MMMM###**MMMM#*#**MMM#########**####*######**#*#MMM#### SECTION 10-FURTHER INFORMATION After the reaction of magnesium peroxide to form oxygen the resulting material,magnesium hydroxide is mildly basic. The amounts of magnesium oxide (magnesia) and magnesium hydroxide in the initial product have an effect similar to lime,but with lower alkalinity. The information contained in this document is the best available to the supplier at the time of writing,but is provided without warranty of any kind. Some possible hazards have been determined by analogy to similar classes of material. The items in this document are subject to change and clarification as more information becomes available. C l I � I i �L UIC Permit Application ARCADIS ATTACHMENT 2 ORC SLURRY INSTALLATION INSTRUCTIONS I I I 1 z' REGENESIS Oxygen Release Compound (ORC(5) Installation Instructions (Direct-Injection Slurry Application) SAFETY: Pure ORC is shipped to you as a fine powder rated at-325 mesh (passes through a 44 micron screen). It is considered to be a mild oxidizer and as such should be handled with care while in the field. Field personnel should take precautions while applying the pure ORC. Typically, the operator should work upwind of the product as well as use appropriate safety equipment. These would include eye and respiratory protection, and gloves as deemed appropriate by exposure duration and field conditions. Personnel operating the field equipment utilized during the installation process should have appropriate training, supervision and experience. GENERAL GUIDELINES: _! ORC may be installed in the contaminated saturated zone in the ground utilizing hand augered holes, Geoprobe°type hydraulic punch equipment, or hollow stem augers. This set of instructions is specific for Geoprobe equipment. Alternate instructions may be obtained from the Regenesis Technical Support Department. For optimum results the ORC slurry installation should span the entire vertical contaminated saturated thickness, including the capillary fringe and "smear zone". f Two general installation approaches are available. The first is to backfill only the probe hole with slurry. This is a simple approach, in that it is easy, straightforward, and the location of the ORC slurry is-precisely known after installation. However, this method requires significantly more probe holes than the alternative, and may take more time for the completion of the remediation process. A separate set of instructions for this method utilizing Geoprobe equipment is available from Regenesis. The second method is to inject the slurry through the probe holes into the contaminated saturated zone. This method requires fewer probe holes, is less disruptive to the site, and aids the spread of oxygen by spreading the ORC source material. However, it may be difficult to know the exact, final disposition of the ORC installed with this method. This is the method described in these instructions. Note: It is important that the installation method and specific ORC slurry point location — be established prior to field installation. It is also important that the ORC slurry volume and solids content for each drive point be predetermined. The Regenesis Technical h Service Department is available to discuss these issues, and Helpful Hints at the end of these instructions offers relevant information. Regenesis also has available Technical Bulletins covering source treatments with ORC. 1 J I` SPECIFIC INSTALLATION PROCEDURES 1. Identify the location of all underground structures, including utilities, tanks, distribution piping, sewers, drains, and landscape irrigation systems. 2. Identify surface and aerial impediments. 3. Adjust planned installation locations for all impediments and obstacles. 4. Pre-mark the installation grid point locations, noting any that have special depth requirements. 5. Set up the Geoprobe unit over each specific'point, following manufacturer recommended procedures. Care should be taken to assure approximate vertical probe holes. 6. Penetrate surface pavement, if necessary, following standard Geoprobe procedures. 7. Drive the 1 112" (one-and-one-half inch) pre-probe (part#AT-148B) with the expendable tip (part#AT142B) to the desired maximum depth. Standard 1" (one.inch) drive rods (part AT104B) should be used, after the pre-probe, (Hint: -- Pre-counted drive rods should be positioned prior to the installation driving procedure to assure the desired depth is reached.) 8. Disconnect the drive rods from the expendable tip, following standard Geoprobe procedures. 9. Mix the appropriate quantity of ORC slurry for the current drive point. (See separate "Directions for ORe Slurry Mixing" and Helpful Hints). Note: Do not _ mix more slurry than will be used within a 30 minute period. 10.Set up and operate an appropriate slurry pump according to manufacturer's directions. Based on our experience, a Geoprobe model GS-1000 pump is recommended. Connect the pump to the probe grout pull cap (GS-1054) via a 1 inch diameter delivery hose. The hose is then attached to the 1" drive rod with its quick connector fitting. Upon confirmation of all connections add the ORC slurry to the pump hopper/tank. 11.Withdraw the pre-probe and drive stem 4' (four feet). (Also note Helpful Hints - Operations at end of instructions.) 12.Optional pretreatment step. (See Helpful Hints - Operations at end of instructions). Pump one to two gallons of tap water into the aquifer to enhance dispersion pathways from the probe hole. 13.Pump the predetermined quantity of ORC slurry for the depth interval being injected. Observe pump pressure levels for indications of slurry dispersion or refusal into the aquifer. (Increasing pressure indicates reduced acceptance of material by the aquifer). 14.Remove one 4' section of the 1" drive rod. The drive rod will contain slurry. This slurry should be returned to the ORC bucket for reuse. 15.Repeat steps 11, 13, and 14 until treatment of the entire affected thickness has been achieved. It is generally recommended that the procedure extend to the top of the capillary fringe/smear zone. 16.Install an appropriate seal, such as bentonite, above the ORC slurry through the -- entire vadose zone. This helps assure that the slurry stays in place and prevents contaminant migration from the surface. Depending on soil conditions and local regulations, a•bentonite seal can be pumped through the slurry pump or added via chips or pellets after probe removal. 17.Remove and decontaminate the drive rods and pre-probe. 2 18.Finish the probe hole at surface as appropriate (concrete or asphalt cap, if necessary). is. Move to the next probe point, repeating steps 5 through 18. HELPFUL HINTS: A. Physical characteristics Al. Slurry The ORC slurry is made using the dry ORC powder(rated at-325 mesh). It makes a smooth slurry, with a consistency that depends on the amount of water used. A thick, but pumpable, slurry that approaches a paste can be made by using 65-67% solids. This material would normally be used for back-filling a bore or probe hole. It is especially useful where maximum density is desired such as where ground water is present in the hole or there are heaving sands. Thinner slurries can be made by using more water. Typical solids for the thinner slurries content will range from 35% to 62%. Such slurries are useful for injecting through a probe or bore hole into.the saturated aquifer. As a rule, it is best to mix the first batch of slurry at the maximum solids content one would expect to use. It can then be thinned by adding additional water in small increments. By monitoring this process, the appropriate quantities of water for subsequent batches can be determined. The slurry should be mixed at about the time it is expected to be used. It is best to not hold it for more than 30 minutes. Thinner slurries, especially, can experience a separation upon standing. All ORC slurries have a tendency to form cements when left standing. If a slurry begins to thicken too much, it should be mixed again and additional water added if necessary. Care should be taken with slurry that may be left standing in a grout pump or hose. _ Problems can generally be avoided by periodically re-circulating the slurry through the pump and hose back into the pump's mixing or holding tank. A2. Equipment Most geotechnical grout pumping equipment has a holding tank with a capacity sufficient for injection. When applying measured volumes of ORC slurry to probe holes, it is sometimes useful to know the volumes and content of the delivery system lines. The following information may be useful in this regard. Geoprobe pump: At the end of a pump stroke virtually no deliverable slurry remains in the pump. 5/8" O.D. connecting hose(10 feet long): 0.2 gallons (26 fluid ounces). Four foot(4')length of 1"drive rod: .04 gallons(5 fluid ounces). Three foot(3') length of 1 1/2"pre-probe: .03 gallons(4 fluid ounces). 3 Cleaning and maintenance: Pumping equipment and drive rods can be lightly cleaned by circulating clear water through them. Further cleaning and decontamination (if necessary due to subsurface conditions) should be performed according to the equipment supplier's standard procedures and local regulatory requirements. B. Operating characteristics 131. Operations - General Judgment will be needed in the field when injecting ORC slurries. In general, it is relatively easy to inject ORC slurries into sandy soils, and this can usually be accomplished at very moderate pressures. Silts and clays require more pressure, and may accept less slurry. Careful observation of pressure during slurry pumping is the best indication of the effectiveness of the slurry injection. To test the soil's ability to accept the slurry and to "precondition" the injection point for the slurry, it is sometimes useful to inject a small volume of plain water prior to the slurry. Normally, one-half(0.5) gallons to two (2) gallons would be appropriate. During injection, increasing pressure and decreasing flow rate are signs of refusal by the soil matrix to accept the slurry. The site geologist should determine whether to increase pressure, and possibly fracture ("frac') the soil matrix to achieve ORC slurry installation in a tight site that has refused the slurry at lower pressures. B2. Fill Volumes Probe hole back-filling Probe hole capacities: Per 10'(Ten Foot)Length Theoretical Operating Volume (Gallons/Fluid Ounces/Cubic Inches) (Gallons/Fluid Ounces) Sand, Silts&Clay Sand Silts &Clay 1" Diameter .41 gal/52 fl. oz./94.2 cu. in. 11.61 gal/78 fl. oz. 51 gal/65 fl.oz. 1 1/2" Diameter .92 gal/117 fl. oz./212.0 cu. in. 111.38 gal/176 fl. oz. 1.15 gal/146 fl. oz. T Diameter 11.63 gal/209 fl.oz./376.8 cu. in. 112.44 gaU313 fl. oz. 2.04 gal/261 fl.oz. 2 1/4" Diameter 2.06 gaU264 fl. oz./476.9 cu. in 113.09 gal/396 fl. oz. 2.57 gaU330 fl. oz. Note that the operating volumes include a 50% excess above the theoretical volume in sands and 25% in clays and silts. This is important to successful treatment. The additional material allows for a small degree of infiltration of the slurry into the surrounding soil and fractures, as well as hole diameter variability. It is important to assure that the entire contaminated saturated zone is treated (including the capillary fringe), since this is often the area of highest pollution concentration. Failure to treat this area due to improper installation can undermine an otherwise successful remediation effort. 4 For direct assistance or answers to any questions you may have regarding these instructions, contact Regenesis Technical Services at 949-366-8000. REGENESIS, 2002 - www.regenesis.com 5 UIC Permit Application ARCADIS ATTACHMENT 3 DESIGN CALCULATIONS _ -ORC Design Software for Grid Applications Using Slurry Injection ` USverdon 3.1 Re9ales5 Teihnial Support:USA(949)3668000,xwu2Eegaless.min - t _ I �i � su.R mr Rnmmnp pb t* l;- -:, airro Icmlbn:Raamon NC - CamlIDent Nradm GEM gLOPPN}It}01 � � • - �� fund Con¢pNY NeOe.YEiYN of Plum.RequlMp Ramedlatlan YAdm ofpam(atimodlrgprflaaaeaaaim) - 204 - Ienplhafdurroomm ,bBwlbedamdml- - -.mR - apo aRJL Di to mNam ra m mna 5 R .hNdga pamNa lee salumlodzam. z0B Nominal aqurt C(pmval mrb Ilty m Ip, leyl of mrim a(rul mprald e l rim Vs Eabe) 1'=' __ .TdelPmoulY I 033 Efl pamal,, Hyaradc mmudmy 6'� ' OS NdeY v _ 1 BEN mJ a ' Kydaracgm ll a11a 1M Seapepo veh]ly - -48.7 Nyr a.tl9 Ndry , 2 Tire mucl Tm Pam Vauma '. 2.BM Ilr 2a,SCT pW IDmaaha.d? of a - - _. • R.MaMI" ORc(b) ndWdui ho ra Card(milli Mau(b) wartem:: (10%Oil Waki - - i 0.001 0.0 - .3.1 ^E mlwne OW 6, am 3.1 0 Nhyllcive - 0.0 3.2 0, MIRE. +,,., :. --am OA 2] - 0 ♦ .' ' dlullaael.ila - - .. Om OD - 0.7 0 Mmi and In - - ` Om aD - 1.3 VOLSsaWnc { - - Oa0 awl a --30 2 oxrmdel;.m ede2)fard (.2)aemem: - low -1.a a.0 reaumairemr.Fu 1.21Mn1.2) - - '. 1D.w - -t.r Mini maarm M mlolen Xmm ea - a1a 2 f 'Trial PaOtlaum HyllmmNone. 1 owl oil 3.1 - D yg m Blomgial Osm Daena(ROD) - i ➢ 1 0 Chvmlml Oryym Dammd(LOD) �, dual 0.0. 1 D .. E.uam s_rb.nvwao.Yg Dm.na: _ - sm o-rkdlkamwry -. . .19 yam =_-- 1121Na FretlbndagankmTo¢rm o01 rg OmODt .. t (Eadmamd camp Saff Coi-WKf Cpw) - {AaluatRmmmac.mpmldereNeC n - -Km,,- .,Canlemm t '1 Sbmh • -ORC#o elwual eDeCn out mpm•em osvoen dunamr Vm) Cam.("do) Mark(1b) Wmarm . (1e%Oil barmard Wild.. = MDX 0.0- 3.1 0 - '.tolbmmane - 0.0 32 0 -, rylanas -. 0.0 3.2 0 0.0 2.7 - 0 [ dWbmeNarb 0.0 a.T a 'N,ryI tlIWMe. 0.0 12 0 NOC'sandtlL'a - 0.7 - -311 2] ' moradeod,elm edE tlelcbbmeWc aemena. - M- .mi dmlxlurvaon d.mmin - - - _ I•T i zy .To1nl Powmum Hydrocarbonlle 0.00 - 0.0 ].1 D {r Bbbpbal Oaypen Comand(BOO) Um emuWpia atllsmtM pbsseo l.W� - - I Doi a a Cbem1cAOryjan Demmd(COD)i-„ 1.1eeamull1pleaifood" we->fm .- - an t a - ORC fair Dinahotl ORCforSnEed Md Damli'-OROT."/ ORC Carl a4 !Summaryof6avbd ORCRmulnments Phase Obs) Pnaeo be 1btCa ma Oam Fm1ar S low InaMEuM SpeCam Toni 6TEY;MTBE _ 4 Y! 5 -135 3 L3511 mil. Taal Pewbum Nydroda. BdMicid 0gg8n DomaM IBOD) Ch mlml Oman uunem(COD) s Gbeaa ma.:un @uttnnit w IN rpulme GRL ab•wtY(in 301b1 crem.nla•1 '.; - -"' 150 Pounda ORC .aalbary Dnlpn for ORC Sluery sPou'llontlinnarsoft) BOws - Sb"Aloalnp Velmnerorin)ama" r solaria". a 5pumns,. PounaaperbraWn' - poem Smmq beMeml mwa(El - -6.Oft - Buclamperbmtlon = . >amwa - 3mvs Daa9n eaWammm�l(20-00%bywL bryeaima)" Elk "Advetllvew two bat iowa(aeye) 60 days `V M arimr ree Ire]pe hale(pM) - pa+v: Numbarol WbmmpM'_ S o +` 9pdM 'ATaa mrfdrmbn9 ell hbl (pall `-• - saa Raquhod ORCpr1m1 - ' Minimum Dom OY_rtMN ]0aadd 1 . 'Sai ORC O.Wenp min Fob am.for 97%Wary sae-� 'Tabu Mmmum Dos.Ormi 540 baaDRL '- FaumOrymrslulry m)palad In aam:ai upm l5 bm[APm•dsumm• Feexma%mrtlulry mlrllanInela:eluplo5m11 ORC bue mateXa wtlmrybyadlonpm) •. fiW - . _ _ NumberafCC to Me tuckeb - - . IEC ' - - F ORC bulk rawmad mat E .. - 10.m Cpsl brbuR ORL material S '-6,am aNppinp end T%UC ales In es a ll i Saba Tal ad 6% Total Mal.Coal 35,}]4 ' t Shi b WIlr e,mrN s E_ 'fID Total Rai Mail Coal ' Slv In to ollsLlf rb a Co• ellmata - - FmmpemreaNbf.pant=uncmmmlmmd•MRC IM.btamllrt) - 25 'Daalpl -e S ., Tabulargmfardbadpusllbrprejeclle) ' '235 _, pulmqulgem repoXtrq S.-s� „ EOmMm ea[ma; dlibn rem(E pe tlaydCU lw PadpuahbraXPmp) 200 Loa G pammt _S.. " Ee4mamtl pomb per day(151o3O1ap elbb lDrtlima push) "�.0.0 Gm m I rm ibMp mw Re olree Xumbaroltla !y - 2 ON h.,, Moblderobm9lmb)etlionabmnwMri- ^,�Sy 11.GCd Other` c S. DeJymlelpr lnj.5vb.lS1-2K br Wab 33-0Kbrall(Ip) S e- '1$CO Cover TomllnerSon auamnwimcosllne Ilmibn '. 5-- 4.0LO Omar T"- -S. in ToullnstaRC st mibaN mnsUlmnl.mb.ofc f "i - _ road i Cael f 9BY G D I JUN 19 2003 D UNDERGROUND INJECTION GROUNDWATER SECTION CONTROL PERMIT ASHEVILLE REGIONAL OFFICE APPLICATION Coats American Sylvan Plant Rosman, North Carolina Groundwater Incident No. 5337 o C- � - C `T rn fV u'z CJ1 -� w c May 2003 0ARCADIS Infrastructure, buildings, environment, communications PREPARED FOR Coats American, Inc. ARCADIS UNDERGROUND INJECTION CONTROL PERMIT APPLICATION Coats American Sylvan Facility Rosman, North Carolina Groundwater Incident No. 5337 Prepared for Coats American,Inc. Prepared by ARCADIS Geraghty&Miller of North Carolina,Inc 801 Corporate Center Drive Suite 300 North Carolina 27607 Tel 919 8541282 Fax 919 854-5448 Our Ref.: NC103013.0001 Dab: May 2003 This document is intended only for the use of the individual or entity for which it was prepared and may contain information that is privileged,confidential,and exempt from disclosure under applicable law.Any d&eminatxln,dstdbution,or copying of the document B strictly prohibited. ARCADIS GENERAL APPLICATION FOR PERMIT TO CONSTRUCT AND/OR USE A WELL(S)FOR INJECTION COATS AMERICAN SYLVAN PLANT ROSMAN,NORTH CAROLINA GROUNDWATER INCIDENT NO.5337 May 2003 Provided byARCADIS G&MofNorth Carolina,Inc. Michelle R.yq,P.E. Project eer `,,,garrrtrNrr�r qN GARO �` O .•GONS�c .,9 •4 Al J.Alan Pinnix,L.G. 1260 Project Scientist 4�' ? c O o W L c > O %+i Ql O i- �r :>C me _ Sri N vex r ti Z g!mtnN+mmunY,Mn VTuk VvmTuk-tl9^S+Ttloc NORTH CAROLINA DEPARTMENT OF ENVIRONMENT AND NATURAL RESOURCES TO: DIRECTOR,NORTH CAROLINA DIVISION OF WATER QUALITY DATE: May 30,2003. A. PERMIT APPLICANT ` Name: Mr.Mike Bell. Environmental and Safety Coordinator Address: Coats North America Post Office Box 670 City: Toccoa State: GA Zip Code: 30577 County: Stephens Telephone: 1-706-886-2141 Ext.2248 B. PROPERTY OWNER(same as applicant) C. STATUS OF APPLICANT Private: Commercial: X Federal: State: County: Municipal: Native American Lands: D. FACILITY(SITE)DATA Name of Facility: Coats American Sylvan Plant Address:Highway 178 City: Rosman Zip Code: 28772 County: Transylvania Telephone: 1-828-862-4215 Ext. 17 Contact Person: Eddie Briscoe E. INJECTION PROCEDURE Provide a detailed description of all planned activities relating to the proposed injection facility including but not limited to: (1) Construction Plans and Materials: ARCADIS G&M of North Carolina,Inc. (ARCADIS) will subcontract with Regional Probing Services,Inc. (Regional Probing)to inject Oxygen Release Compound(ORC)into 9 temporary well points at the Coats Sylvan Manufacturing Facility(the Site)shown on Figures 1,2,and 3. The ORC material properties are described in the Material Safety Data Sheet(MSDS)provided as Attachment 1. ARCADIS and Regional Probing will follow the procedures described by OW-57 REM (November 1999) Page 1 of 9 REGENESIS Bioremediation Products in Attachment 2: ORC®Slurry Installation Instructions, Geoprobe®Injection into the Soil Matrix. During the initial application,the 9 injection points in the source area will be treated with a slurry solution of 60 pounds of ORC and 17 gallons of water per point for a total of 540 pounds of ORC and 153 gallons of water. The calculations used to design the injection program are included in Attachment 3. - (2) Operation Procedures:Refer to Attachment 2. (3) Planned Injection Schedule: The proposed scheduled is to complete the injection within a two day period to commence within 4 weeks of UIC permit application approval in 2003.The proposed injection of ORC will be used to reduce the concentrations of contaminant constituents present in the surficial aquifer at the Site. A second,and possibly a third injection of ORC may be required to achieve the desired contaminant reduction. An injection schedule for the additional injections is unavailable at this time, due to the length of time for monitoring the first injection. It is anticipated that the additional injection events will be performed in less than two days. Additional injections may not be necessary depending on the success of the initial ORC injection. Written notification to NCDENR will be made at least thirty days prior to any subsequent injections. F. DESCRIPTION OF SITE Provide a brief description of the contamination incident and the incident number assigned by the Division of Water Quality staff in the Department's Regional Office: The Coats American- Sylvan Facility is in a rural area of Transylvania County on State Highway 64 near Rosman,North Carolina(Figure 1). The facility,which lies outside the corporate limits of Rosman, is a spinning plant for textile threads used in industrial sewing. The plant was constructed in the mid-1960's and was owned and operated by American Thread until 1991 when American Thread and Coats merged to form Coats American.The 50-acre plant property is bounded on the north,south and east by pasture land. State Highway 64 borders the plant on the western side. The land on the opposite side of Highway 64 is primarily pasture with two parcels containing vacant houses. Topographically,the site lies on the fluvial plain of the French Broad River.The site slopes gently to the southeast, at a horizontal gradient of approximately 0.01 feet/foot,toward the French Broad River,which is approximately 2,000 feet from the site. The surrounding area is characterized by the hills and valleys of the southern Blue Ridge physiographjc province. Galloway Creek, a tributary of the French Broad,borders the facility on the west and south sides. When the Sylvan plant began operations in the mid-1960's, floor scrubber and frame cleaning water was placed into a storm-water drain which flowed into the French Broad River. In the early 1970s a small(8 feet x 8 feet x 5 feet deep)pit was dug on the Company property for deposition of the scrubber and frame cleaning water. In 1984 or 1985,the first pit was covered by filling with soil and a second pit was dug: The second pit was used until January 1989 and was covered/filled with soil in August 1989. The floor scrubber and washer water has since been placed into the on-site wastewater treatment plant. GW-57 REM (November 1999) Page 2 of 9 A written Notice of Violation(NOV)was issued April 12, 1990,based upon the results of a groundwater sample collected from the disposal pit groundwater.A Phase I environmental site assessment was performed in August and September 1990. A Phase II environmental site assessment was performed in November and December 1990. Based on the investigations, a Phase I soil/source removal was performed in May 1992.Approximately 500 tons of soil were removed from the pits and transported off-site for disposal by thermal incineration.Phase II and Phase III soil/source removal actions were performed in October 1992. During the Phase II excavation event an additional 477 tons of soil were removed from the pits and sent for disposal. Confirmatory samples indicated that one sample contained low concentrations of heavy oils. Based upon the presence of heavy oils at the one location, a third excavation/sampling event was performed and an additional 100 tons of soil were removed and treated off site. On November 4, 1992,the NCDEHNR granted closure certification of the pit areas relative to the source removal.In July 1993 groundwater recovery and treatment was initiated to remediate a small plume containing low concentrations of VOCs and SVOCs. Quarterly monitoring from 1993 to 1995 showed a marked decrease in constituent concentrations. In December 1995, Coats American submitted a Corrective Action Plan(CAP)under 15A NCAC 2L.0106(1). The CAP demonstrated that natural attenuation and natural biodegradation of constituents would remediate groundwater without impacting current or foreseeable receptors. On March 28, 1996,the NCDENR approved the CAP and established a groundwater sampling frequency to monitor degradation of constituents of concern. The approved CAP allowed a reduction of monitoring frequency from quarterly to semiannually for the first year, followed by annual monitoring. Semi-annual monitoring was conducted during the first year(1996). Sampling was then converted to annual monitoring, and the first event was scheduled to be conducted in 1997. However,the initial annual monitoring was not performed until October 1998. The fifth annual sampling event was conducted in September 2002. The following conclusions were based on the September 2002 sampling event: Although eight VOCs were detected in the former recovery well GM-4 during the September 2002 sampling event,only one VOC (vinyl chloride, 9.7 µg/L) was reported at a concentration above the established state 2L groundwater standards (Table 1). No constituents were detected in samples collected from wells GM-10,RW-1 and RW-2. Since groundwater monitoring began at the site in the summer of 1993,recovery well GM-4 is the only well to have constituents above regulatory limits. Based on historical data from numerous sampling events conducted over 6 years, it is evident that the area of impacted groundwater at this facility is very small and that only limited migration has occurred due to natural attenuation. The concentration of vinyl chloride in well GM4 is relatively similar to that observed over the last four sampling events. The site incident number is 5337. G. HYDROGEOLOGIC DESCRIPTION SECTION(G)MUST BE ORIGINALLY SEALED AND SIGNED BY A LICENSED GEOLOGIST Provide a hydrogeologic description, soils description, and cross section of the subsurface to a depth that included the known or projected depth of contamination. The number of borings shall be sufficient to determine the following: - - GW-57 REM (Novmnba 1999) Page 3 of 9 Opp 111111Jfff#I %,�` ;CR �'. A y?Z: (1) the regional geologic setting; SEAL (2) significant changes in lithology; 12� (3) the hydraulic conductivity of the saturated zone; ' (4) the depth to the mean seasonal high water table; and '•�� '�QLO��•��.���` (5) a determination of transmissivity and specific yield of the aquifer to 152, �kdl FI)fh���1�on (showing calculations). '*fit 11111% Regional Geologic Setting The area of Rosman,North Carolina is situated within the Blue Ridge Province. More specifically,Rosman is located to the east of the Brevard Fault Zone within the Chauga Geologic -- Belt.The entire area of Rosman is underlain by the Henderson Gneiss,which consists of biotite gneiss (Horton and McConnell, 1991). . Lithology The site is underlain by silts and clays interbedded with fine sands to a depth of approximately 90 ft bls where bedrock is present. Two lithologic cross sections were constructed using information obtained from soil borings drilled during the Phase H investigation. Cross-section A A',illustrated in Figure 4,presents site lithology from upgradient of the pits at well GM-1 through the pits and downgradient to well GM-7 parallel to the general groundwater flow direction. Cross-section B -B', illustrated in Figure 5,presents site lithology perpendicular to the general groundwater flow direction. The cross-sections indicate that silts and clays are predominant in the upper portion of the lithologic section. These fine sediments generally coarsen downward to a silty sand at variable depths. However, a clayey-silty sand is present in the upper section of GM-5 and extends to the middle of section of boring BH-3 southwest of the pits. These areas of sandy material illustrate the variable nature of the sediments in the area. However,low permeable silts and clays are generally present in the upper 10 to 15 feet of the lithologic section,especially near the pits where they are present to a depth of at least 10 ft bls. Groundwater Flow and Direction Historical groundwater elevation data were collected at various times prior to and following remedial system operation. A comparison of historical water level data is presented on Table 2 for the June 15, 1993; August 28, 1996; October 20, 1998; October 18, 1999;November 16, 2000; August 2,2001 and September 18,2002 sampling events. All data were collected during times when the recovery system was shut down and are indicative of natural groundwater flow direction. All water-level data indicate that the natural groundwater flow direction is generally to the southeast and is consistent over time. Based upon the natural groundwater flow direction, the monitoring well network is properly positioned to detect the potential migration of constituents from the former source area near well GM-4. Depth to the mean seasonal high water table is approximately 4.5 feet as measured in GM-4. The hydraulic conductivity(K),which is the capacity of a medium to transmit water,was determined from slug tests in on-site monitor wells. The calculated K values for the wells are included in Table 3. The site groundwater flow velocity was calculated using the K values derived from the slug tests, a hydraulic gradient of 0.03 based upon the generated water-level contour maps and an effective GW-57 REM (November 1999) Page 4 of 9 porosity of 0.010 based upon site lithologic data. Using the above assumptions,an average groundwater flow rate of 59 feet per year(ft/yr)was calculated It is important to note that.this is an average velocity for the site. Using the K values from individual wells,the calculated groundwater flow velocity ranged from a high of 184 ft/yr at well GM-9 to a low of 27 ft/yr at well GM-4. Transmissivity can be calculated from hydraulic conductivity and aquifer thickness. Using a value of 0.2480 ft/day for K and aquifer thickness of 20 feet,the T would be 4.96 ft/day.For the purpose of this calculation, the surficial aquifer is assumed to be present from 5 to 25 feet below land surface in the vicinity of GM4. The specific yield for the sediments at this site can be obtained from a literature reference. In the vicinity of GM-4,the lithology is predominantly silts and clays. The corresponding specific yield would therefore be approximately 10 percent by volume(Heath, 1989). H. MONITORING PROCEDURE Provide plans for proposed location and construction details of groundwater monitoring well network,including a schedule for sampling and analytical methods. Include any modeling/testing performed to investigate injectant's potential or susceptibility to change (biological, chemical or physical)in the subsurface. After the injection points are completed, existing site monitor wells GM-4,GM-10,RW-1,and RW-2 will be used to assess the performance of the ORC(Figure 3). Three months after the initial ORC application, a groundwater sampling event will be conducted to measure natural attenuation parameters and monitor the presence of vinyl chloride(the primary COC) and other volatile organic compounds(VOCs). Geochemical parameters pH, redox,DO,turbidity, temperature, and specific conductivity will be measured and recorded during well purging using a flow through cell. Groundwater samples collected from the four wells will be submitted for laboratory analysis of VOCs using USEPA Method 8260. If analytical results dictate, subsequent ORC applications may be performed. I. WELL USE Will the injection well(s)also be used as the supply well(s) for the following? (1) The injection operation? YES NO X (2) Personal consumption? YES NO X J. CONSTRUCTION DATA(check one) EXISTING WELL being proposed for use as an injection well. Provide the data in(1)through(7)below to the best of your knowledge. Attach a copy of Form GW-1 (Well Construction Record) if available. X PROPOSED WELL to be constructed for use as an injection well. Provide the data in(1)through(7)below as PROPOSED construction specifications. Submit Form GW-1 after construction. Gw-57 REM (November 1999) Page 5 of 9 (1) Well Drilling Contractor's Name: Regional Probing Services, Inc. NC Driller Registration number: 1625 (2) Date to be constructed: 2003 (to be determined based on UIC permit approval date. Number of borings: 9 Approximate depth of each boring(feet): 25 (3) Well casing and screens: As described in Attachment 2, there are no screened intervals, and the injection zone will be from approximately 25 feet below land surface (ft bls)to approximately 5 ft bls. —' (4) Grout type shall be Portland Cement Type I. The boreholes will be grouted to land surface upon completion of the injection activities (5) N.C. State Regulations(Title 15A NCAC 2C .0200)require the permittee to make provisions for monitoring wellhead processes. A faucet on both influent(recovered groundwater) and effluent(fluid being injected into the well)lines is generally required. This is not applicable due to the one time nature of the ORC application, and the fact that there are no well casings or screened intervals for either injection or groundwater extraction. Will there be a faucet on the influent line? yes_no X Will there be a faucet on the effluent line? yes no X _ (6) SOURCE WELL CONSTRUCTION INFORMATION: Not Applicable. NOTE: THE WELL DRILLING CONTRACTOR CAN SUPPLY THE DATA FOR EITHER EXISTING OR PROPOSED WELLS IF THIS INFORMATION IS UNAVAILABLE BY OTHER MEANS. K. OTHER WELL DATA Provide a tabulation of data on all wells within '/< mile of the injection well(s), excepting water supply wells serving a single-family residence, which penetrate the proposed injection zone. Such data shall include a description of each well's type, depth,record of abandonment or completion,and additional information the Director may require. During the Corrective Action Plan phase of work, a potable well survey was conducted during for properties within a 1,500-foot radius of the impacted monitor well(GM-4). Wells excepting single-family residence wells include a water supply well on the NCDOT Maintenance Building property,and three water supply wells,two groundwater recovery wells,and 11 groundwater monitor wells present on the Coats American property. Water-supply wells in the area typically pump water from the bedrock,which is present approximately 90 ft bls at the site. Well data are tabulated below. GW-57 REM (November 1999) Page 6 of 9 Relative Top Well Date of Casing Screened Interval Site Well ID Type Installed Elevation (Feet BLS (NCDOT TRA-25- NA NA NA NA Maintenance 2-21 Buildings) Coats GM-1 8/6/90 184.84 11-21 American GM-2 8/7/90 181.32 4-14 Sylvan Facility GM-3 8/9/90 180.26 13-23 GM-4 8/7/90 179.53 5-15 GM-5 11/28/90 178.55 10-20 GM-6 11/29/90 177.13 9-19 GM-7 11/29/90 176.17 5-15 GM-8 11/27/90 178.16 10.5-20.5 GM-9 12/19/90 176.07 8-18 GM-10 9/16/91 178.29 65-75 GM-11 9/17/91 175.40 79-89 RW-1 6/5/92 177.03 5-50 RW-2 6/4/92 177.03 5-50 PW-1 NA NA 400 feet total depth PW-2 NA NA 400 feet total depth PW-3 NA NA 1 212 feet total depth L. PROPOSED OPERATING DATA (1) Injection rate: Average(daily) 1_6 gallons per minute(gpm) (2) Injection volume: Average(daily)76.5 gallons per day(gpd) (3) Injection pressure: Average(daily) 100 pounds/square inch(psi) (4) Injection temperature: Average(January) N/A°F,Average (July)N/A°F (5) Hydraulic capacity of the well: Not Applicable (6) Expected lifetime of the injection facility: 0.005 vear (7) Give a description of how the above data will be measured and controlled: The injection rates/volume are monitored during the injection process by pre-measuring the amount of ORC slurry to be injected per point as specified in the work plan. The entire volume is then injected for that point, during which time the injection pressure is monitored with an in-line standard pressure gauge. The temperature of the injected slurry will approximate the ambient atmospheric temperature at the time of injection. The hydraulic capacity is not applicable because there is no well casing or screened interval with this process. The expected lifetime of the injection process is one to two days per event. M. INJECTION-RELATED EQUIPMENT See Attachment 2. N. LOCATION OF WELUSl Attach a scaled, site-specific map(s) showing the location(s)of the following: GW-57 REM (November 1999) Page 7 of 9 (1) the proposed injection well(s) (See Figure 3); (2) all property boundaries (See Figure 2); (3) contour intervals not exceeding two feet(See Figure 1); (4) the direction and distance from the injection well or well system to two nearby, permanent reference points (such as roads, streams, and highway intersections) (See Figure 2); (5) all buildings within the property boundary(See Figure 2); (6) any other existing or abandoned wells, including water supply and monitoring wells, - within the area of review of the injection well or wells system(See Figure 8); (7) potentiometric surface showing direction of groundwater movement(see Figure 6); (8) the horizontal and vertical extent of the contaminant plume (including isoconcentration lines and plume cross sections) (see Figure 7; due to limited extent of impact above NCAC 2L standards,i.e.vinyl chloride in only one well, a plume cross section was not developed); (9) any existing sources of potential or known groundwater contamination, including waste storage,treatment or disposal systems within the area of review of the injection well or well system (None); and (10) all surface water bodies within 1000 feet of the injection well or well system (see Figures 1,2). O. INJECTION FLUID DATA (1) Fluid source,if underground,from what depth,formation and type of rock/sediment unit will the fluid be drawn(e.g.,granite,limestone,sand, etc.). Not Applicable-potable water will be used for ORC slurry. (2) Provide the chemical,physical,biological and radiological characteristics of the fluid to be injected. See Attachment 2. - P. PERMIT LIST Attach a list of all permits or construction approvals that are related to the site,including but not limited to: (1) Hazardous Waste Management program permits under RCRA (2) NC Division of Water Quality Non-Discharge permits (3) Sewage Treatment and Disposal Permits (4) Other environmental permits required by state or federal law. All permits and construction approvals relating to the site are on file with the Environmental Compliance Division and are available upon request. Q. CERTIFICATION "I hereby certify,under penalty of law,that I.have personally examined and am familiar with the information submitted in this document and all attachments thereto and that,based on my _ _ cw-57 REM (November 1999) Page 8 of 9 All permits and construction approvals relating to the site are on file with the Environmental Compliance Division and are available upon request. Q. CERTIFICATION "I hereby certify, under penalty of law,that I have personally examined and am familiar with the information submitted in this document and all attachments thereto and that, based on my inquiry of those individuals immediately responsible for obtaining said information, I believe that the information is true,accurate and complete. I am aware that there are significant penalties, including the possibility of fines and imprisonment, for submitting false information. I agree to construct, operate, maintain,repair, and if applicable, abandon the injection well and all related appurtenances in accordance with the approved specifications and conditions of the Permit." (Signature of Well Owner or Authorized Agent) If authorized agent is acting on behalf of the well owner, please supply a letter signed by the owner authorizing the above agent. R. CONSENT OF PROPERTY OWNER (Owner means any person who holds the fee or other property rights in the well being constructed. A well is real property and its construction on land rests ownership in the landowner in the absence of contrary agreement in writing.) If the property is owned by someone other than the applicant,the property owner hereby consents to allow the applicant to construct each injection well as outlined in this application and that it shall be the responsibility of the applicant to ensure that the injection well(s)conforms to the Well Construction Standards (Title 15A NCAC 2C .0200) — (Signature Of Property Owner If Different From Applicant) - GW-57 REM (November 1999) Page 10 of 11 UIC Permit Application ARCADIS FIGURES .y • ii GrAveyard v Y i• Hill. SITE LOCATION 000 Rosniali brnr On Mile 215 1 1/2 0 1 MILE 1000 0 1000 2000 0000 •000 s000 1 700o SCALE 1:24000 (v County Contour Interval 40—ft Datum is Mean Sea Level Location U.S.C.S. 7.5 Minute Series Rosman, NC Topographic Quadrangle. PRJT N IGM aEC120 BY, FIGURE N0. ARCADIS AAWi ' aT p„nvINO NCTOPO SITE �s�M a Na Carolina, Inc. LOCATION 801 Corporate Center Dry ,suite 700 PRJT Ne NC101043.0001 Rdei9h, NC 21C0) COATS AMERICAN — SYLVAN FACILITY Tal: IF..: 918-es4-sua III wTE, 1a 1Ew 12DCT01 A N TIW ROSMAN, NORTH CARODNA rw.arcaaia-ua.wm ggg COATS ANERKAN 64 g `j +k lLL ROSNAN ^ PASTURE y, k IR PROPERTY LINE 'ram VICINITY MAP NTS LL �' IRAs '� ak GM: GM-11 '9L ,k GM-B RW-2 AGM-7 EXCAVATED '11111 X GM-1 PIT AREA No.1 rGM-6 m,. GM-2 A_4 RW-1 EXCAVATED-y GAF PITAREANo.2/ ,k M- - ak k 0M-5 GM-1 PASTURE k ,u1�J�❑— ' r ---------------------------� ak P ak LL LL 6 COATSA —vRICA� ` k Z 0 GRASS /�0 .k G1 NUFAI V<f/ r BUIL LL PT r k a4 0 , ak G <_ ak GRASS �y Y GRASS 0. - `� ,k ,• ,k J ,LL P A R K I N ,LL y. k GRASS — REFERENCED DRAWINGS — or mo oExOnwx Ho. A-1 LOCKWOOD GREEN SITE m_ s A-2 LOCKWOOD GREEN GRADE 63108 1 PROPERTY PLAT SY-124 1 SYLVAN PLANT ARC A. PI MANAGER+ KPAHCHECKED BY. GRAFTER PROJECT A P1NMAN PAHR A.DRAFTER- DRAWING, ARCADIS G&N of North Carolina, Inc. SITEI C 801 Corporate Center Drive, Suite 300 - Raleigh, NC 27607 - DATE- Tel: 919-854-1282 Fax: 919-854-5448 14NAY03 wwx,.orccdi.—us.ccm Za n 15' WIDE EASEMENT + ACCESS ROAD TO m PASTURE PUMP STATION mQ BROAD RIVER 1,907-ft. FRENCH SHORTEST D (STAKE TD ZRF�S VJ-2 19 GPM 0212' 1 pW_1 ..\ `1 125 GPM @400' FENCE +� 1 � �`\ PROPERTY�LINE J O 00 SEWAGE DISPOSAL PLANT w � YLVAN PLANT o r w ING � r 3 � , �a - •� �� GRASS L E G E N D GRASS J I BUILDING/STRUCTURE s �a 1, a4ZIOP'AY REEK • — FENCE LINE PROPERTY LINE GRASS -� PAVEMENT --- - GRASS STATE HIGHWAY #64 • MONITOR WELLS • RECOVERY WELLS ■ PRODUCTION WELLS SG IN FEET 0 250 500 .R NC103013.0001 FIGURE: i AMERICA — SYLVAN FACILITY SITE 'OSMAN. NORTH CAROLINA LAYOUT 2 LEGEND I — FENCE +\ • MONITOR WELL x +\ A RECOVERY WELL I PROPOSED ORC x N +\ INJECTION POINT +\ SCALE IN FEET PROPERTY o 30 BOUNDARY G� +\ i EXCAVATED + PIT AREA 2 \ x \ • +\ GM-8 GM-2• +\ iGM-3 • �+ GM-9 • x GM 4 • RW-2 + EXCAVATED GM-10 PIT AREA 1 +\ x + I \+ + • GM-5 \ I GM-11 x I PUT NANAGEM CNEIX D 9Y, ARCADIS a PINNIX K PANR MONITOR WELL AND RECOVERY WELL LOCATIONS FlGUflE DRAWING,COATS—SITE-030 AND PROPOSED ORC INJECTION POINTS ARCMIS GAM of North Corou... Inc. 801 Co,orute Camar orm,, S.R. 300 PRAT rm,NCI030I3.0001 R.I.tgh, NC 2760] COATS AMERICAN—SYLVAN FACILITY Tel: 919-854-1282 FRA: 919-854-5448 DVG DATE, DRAFTER, ROSMAN, NORTH CAROLINA nwe.arcoEie-ua.com 13NAY93 A. NDRTON 185 GM-1 BH-1 GM-2 GM-3 GM-4 GM-10 GM-7 185 180 I A \ 1eo 175 5dra:6' S & 170 -Yi 9 x $!(fy Send i ,"" 4My-3 170 v?} 155 d , 155 r''=1;� .��. I r. 150 ems} ��;' i ar<-J � �«��,�. 150 145 - I e� 1 r tas LEGEND 140 — 1 k 5 140 Organic Clays and Organic r t � t III Silty Clay 135 °Y i k ` �t", < $ u r<+y e t } s ° 135 ® Inorganic Clays and Gravelly. 730 � "5'� + � � e`�;t � ,�( "'' ' Slily Send - Sandy, or Silty Clay "`. � t� of ' 1*'�T �xa Tx �c,F^a '�''r`. ' � 130 Silty Sands, Poorly Graded 125 d, ,,�`� 3 d h5 , ' ` ' � 41 125 Sand—Silt Mixture Inorganic Silts, Fine or Silty r", Y ,r s k a ' -' lI�F 120 G�{a d # c1'zr .1. :,1rz4J k ?' , '� 120 Soils Inorganic Clays 115C'1 i 115 Land Surface .,;' 110 -€^ " '�.ws �&�' k �3't no Well Casing {kI 105 vmnm sail!IM FEEr - �--—- ir'.7 TJ J �` 5 rl 4 v e r r..+[[ry Y x,,, �r ,�yy"" • 4,C,' 105 0 1s 30 k'wY9G � .qM,IN iY Yv'9 11:.. "' G. 1',,✓ 1 ' !Sy Y�a�'`y 'l.J. "+' p,T' arr, rA., 100 Jr,'trn�'d' � � P. . i$`-�r.IPltil , f rite ' .fie E l: 4 S c'+ '�,� \ cA' '2� `,5."X Ila > F P "N `"'S 11 l a r kv ,p v 100 HORIZONTAL SCALE W FEET �1 r .� t a :a",a'+^I'� o 60 1zo 95 I LLr. „Nfi a�,^' i .tt u"f 95 PRJT HAHADERI CHECKED BY- A. - -HR FlCIIRE: ARCADISVIN&A A PA8 GENERALIZED SUBSURFACE.CROSS-SECTION A-A' ARCADIS ChM RI Nar aaralina, Ina. 4 801 caraorala Canter Drive, Suite 300 PRJT N NC103013.0001 RalaigA, H0 27607 COATS AMERICAN SYLVAN FACILITY Tel: 919-854-1282 Fax: 919-854-5448 Ova DATE, DRUTER� ROSMAN, NORTH CAROLINA www.arcadia-ue.cam 16MAY03 A. MORT6M wl_1 T. B I \\ Be B• I a cu-e I EW25 _2 W 0 BIDO I W-4 W-10 W-7- GM-5 BH-3 GM-4 GM-8 I W2, I c'M-a 180 180 I i marnm. o m 175 175 LEGEND 170 170 Clayey Silty Sand, Poorly ,<4 Graded Sand—Silt—Clayey Mixture � 165 ;?"-i1 r ® Inorganic Clays and Gravelly, 165 Sandy, or Silly Clay Silty Sands, Poorly Graded ,1 ,� I� Sand—Silt Mixture 160 Inorganic Silts, Fine Sandy Or Silty Soils 155 155 ® Inorganic Silts & Fine Sands, Silty or Clayey Fine Sand ® Inorganic Clays t5o 15a Land Surface Well Casing VERTICAL SCALE IN FEET _ 0 r0 20 HORIZONTAL SCALE IN fEEr a Q ea PRJT HANA6ER- CHECKED BY. RGORE: ARCADIS PINNI% L PA HI;! W2 DRAWING. e_B GENERALIZED SUBSURFACE CROSS-SECTION B-B' ARCADIS G&M of North Cwoll'na. Inc. 801 Comomle Center Drive. Suite 0DO PR.1T xa NC103013.0001 Raleigh, NO 27607 COATS AMERICAN SYLVAN FACILITY Tel: 919-854-1282 Fax: 919-85e-5448 Bvo DATE, ORAFTER� ROSMAN, NORTH CAROLINA w^.arcoriie-ua.com I6NATU3 A. NORTON GM-1 174.80 �r\ PROPERTY r r\r� jp N k, r EXCAVATED \r / I PIT AREA 2\O � ^o GM-2 \r\r ~172.17 ASSUME 184.0' ELEVATION i 174.48� AT LOADING DOCK ENTRANCE GM-3 G r � • 172.72 vo • �r GM-9 • Rtd-2 168.65 EXCAVA GM-10 r\ PIT 1 *� / BUILDING I r\r j PAVEDGM 7 • GM-5 RW-1 • 168.39• r\ 170.46 • GM—Il / I • GM-6 168.81 LEGEND —•— FENCE NOTE 1: ALL ELEVATIONS ARE RELATIVE TO • MONITOR WELL - THE LOADING DOCK ENTRANCE. i A RECOVERY WELL NOTE 2: GROUNDWATER ELEVATION DATA 172.72 WATER LEVEL ELEVATION (FT,MSL) FROM WELLS GM-10, GM-11, i —170— POTENTIOMETRIC CONTOUR 2—FT RW-1 & RW-2 WERE NOT USED ( ) IN DETERMINING GROUNDWATER GROUNDWATER FLOW DIRECTION CONTOURS DUE TO SCREENING SCALE IN FEET DEPTHS BELOW SHALLOW AQUIFER. 0 60 PRJT MANAGER- CHECKED BY, GENERALIZED BRAVING, FIGURE ARCADIS H. PAMR vI"G'COATS—SITE-03 GROUNDWATER FLOW DIRECTION ARCADIS G&M of North Carolina, Inc. SEPTEMBER 18 6 eat Corporate Center Dave, suite 300 PRJT NO'NCI03013.0001 ' 2��2 Raleigh. NC PRD) COATS AMERICAN-SYLVAN FACILITY Tel: 919-664-1362 To.; 91R-65<-3448 3vG OATEN DRAFTER. ^w.arcaale—ae.aam 13MAY03 A. NORTON ROSMAN, NORTH CAROLINA GM-1 174.00 PROPERTY/ BOUNDARY r \r N I r\ r\ EXCAVATED r\r PIT AREA 2 r \ r \r �GM-8 ASSUME 184.0' ELEVATION AT LOADING DOCK ENTRANCE GM-3r 9.7 \r\ GM-9 ® %1 • •RW 2\r EXCAVATED GM-10 Kill \ PIT AREA 1 <1.0 r\ / BUILDING I r\r j PAVED I RW-I •i G© Offs] • \r\• G <1.D N • GM-]I / II • GM-6 LEGEND I ®S —•— FENCE • MONITOR WELL A RECOVERY WELL i EZI VINYL CHLORIDE CONCENTRATION (Hg/L) NS NOT SAMPLED APPROXIMATE HORIZONTAL EXTENT OF GROUNDWATER IMPACT ABOVE SCALE IN FEET L=1•=•=I NC 2L STANDARDS 0 60 PUT 14WAGER, CNECKEB 9Y, VINYL CHLORIDE FIGURE: ARCADIS VIN.PINI H PANR \r9 oRAwuc'COATS—SITE-03 CONCENTRATIONS /L ARCAUIS G&M NPAN C 1Ae. SEPTEMBER 18 7 em como.°t. ce°mr 0d.°. SeRe 300 PRJT N0,NC103013.0001 ' 2��2 R°lelgh, NC Z)BW COATS AMERICAN—SYLVAN FACILITY Tel: 919-854-1282 Fe.: 919-854-5445 9VG SATE- ER AFI" "••°�°°a"—° °°'^ 151AYo3 A. 10R6 ROSMAN, NORTH CAROLINA I. 32 25E,� 26 5 I '21A 1 I 97 21 .6� —88 y 1 18 92B 20 I 1 •. / FORMER 1 PITS ICOATS AMERICAI 16 I. 93 15\ _ '13 13H 1 1 --- � 13A 13B I, /�-/' 13\\F\ 13J-� 14 12D 12A __ 92D 12c--- 12B 2 -�- 12 ,12F .SCALE IN FEET — / 12E� 0 400 am _L PUT MANAGER, CHECKED BY, DRAFTER, PROJECT ARCAD I S NOTES:A. NNIX N. PAHR A. NORTO DRAW NGN ARCADIS G&M of North Carolina. Inc. TRANS-1 C 801 Corporate Center Drive. Suite 300 Raleigh, NC 27507 DATE- Tel: 919-854-1282 Fax: 919-854-5448 16MAY03 www.arcadis—us.conn I r r � i r 90 M 0 u ! 91 N \ ` Tq \ 2 0 9 , �v 92 1 / LEGEND 1500-FT =- = PROPERTY LINE RADIUS - 1 500-FT RADIUS FROM SOURCE / INTERMITTENT STREAM 3}F WATER SUPPLY WELL NOTE: SEE TABLE FOR PROPERTY DESCRIPTIONS. .R NC103013.0001 FIGURE: AMERICAN - SYLVAN FECILITY WATER-SUPPLY WELLS WITHIN 1,500-FEET !OSMAN, NORTH CAROLINA OF THE SOURCE AREA 8 UIC Permit Application ARCADIS TABLES Table 1. Groundwater Quality Detection Summary,September 2002 Sampling Event,Coats American-Sylvan Plant,Rosman,North Carolina. Constituent NCGWI/ GM4 DUP-1* GM-10 RW-1 RW-2 Date Sampled 9/18/2002 9/18/2002 9/18/2002 9/18/2002 9/18/2002 Pnrgeable Halocarbons (USEPA Method 601)µg/L 1,1-Dichloroethane 700 8.1 9.0 <1.0 <I.0 <1.0 1,1-Dichloroethene 7 <5.0 <5.0 <1.0 <1.0 <1.0 1,1,1-Trichloroethane 200 5.0 <5.0 <1.0 <I.0 <1.0 Trichlorofluoromethane 2100 15 16 <I.0 <1.0 <1.0 Vinyl Chloride 0.015 9.7 9.2 . <1.0 <1.0 <1.0 Purgeable Aromati c (USEPA Method 602)µg/L Toluene 1000 110 100 <1.0 <1.0 <1.0 Ethylbenzene 29 14 14 <1.0 <1.0 <1.0 Total xylenes 530 84 75 <2.0 <2.0 <2.0 Semi-Volatile Organics (USEPA Method 8270)µg/L - ND ND ND ND ND TotalTICsv 116.6 145.3 141 32 103.7 µg/L Micrograms per liter. 1/ North Carolina Subchapter 2L Groundwater Standards, v Tentatively identified Compounds(TICS)(estimated concentrations). J Sample data are qualified as estimated. < Not detected above the quantitation limit. * Blind field replicate of primary groundwater sample GM4. OConstituent concentration is above groundwater standard. ND Compounds were not detected in sample. (3AFm%CualsAmericantSylvan Plantt2002 SamplinglTablesttabIcI.xls Table 2. Groundwater Elevations, Coats American-Sylvan Plant, Rosman,North Carolina. Pre-Pumping Non-Pumping Non-Pumping Measuring 6/15/1993 8/28/1996 10/20/1998 - Well Point Depth to Water-Level Depth to Water-Level Depth to Water-Level Elevation* Water** Elevation Water** Elevation Water** Elevation Y GM-1 184.84 11.72 173.12 9.22 175.62 11.10 173.74 GM-2 181.32 9.30 172.02 4.85 176.47 7.37 173.95 GM-3 180.26 9.25 171.01 7.09 173.17 8.12 172.14 GM-4 179.53 8.80 170.73 4.50 175.03 5.38 174.15 GM-5 178.55 11.15 167.40 8.26 170.29 9.20 169.35 GM-6 .177.13 14.32 162.81 8.77 168.36 11.09 166.04 GM-7 176.17 11.64 164.53 8.31 167.86 9.21 166.96 GM-8 178.76 8.46 170.30 7.92 170.84 7.21 171.55 GM-9 176.07 11.05 165.02 9.03 167.04 8.79 167.28 GM-10 178.29 11.78 166.51 8.67 169.62 9.55 168.74 GM-11 175.40 15.94 159.46 11.37 164.03 12.40 163.00 RW-1 177.03 13.75 163.28 9.89 167.14 9.81 167.22 RW-2 177.37 12.14 165.23 8.90 168.47 9.83 167.54 Non-Pumping Non-Pumping Non-Pumping Measuring 11/16/2000 8/2/2001 9/18/2002 Well Point Depth to Water-Level Depth to Water-Level Depth to Water-Level Elevation* Water** Elevation Water** Elevation Water** Elevation GM-1 184.84 9.70 175.14 10.09 174.75 10.04 174.80 GM-2 181.32 6.00 175.32 4.95 176.37 6.84 174.48 GM-3 180.26 6.72 173.54 ND ND 7.54 172.72 GM-4 179.53 4.35 175.18 4.41 175.12 5.50 174.03 GM-5 178.55 6.79 171.76 7.77 170.78 8.09 170.46 GM-6 177.13 7.61 169.52 7.90 169.23 8.32 168.81 GM-7 176.17 6.83 169.34 7.36 168.81 7.78 168.39 GM-8 178.76 5.94 172.82 6.36 172.40 6.59 172.17 GM-9 176.07 6.57 169.50 7.09 168.98 7.42 168.65 GM-10 178.29 6.66 171.63 7.50 170.79 7.72 170.57 GM-11 175.40 5.56 169.84 7.15 168.25 7.58 167.82 RW-1 177.03 7.92 169.11 8.13 168.90 8.44 168.59 RW-2 177.37 6.95 170.42 7.63 169.74 7.92 169.45 * Measuring point is the top of PVC casing;all elevations are relative. ** Depth below top of PVC casing. ND No Data Q:\Env\Coats American\Sylvan Plant\2002 Annual Monitoring\Tables Table 3. Hydraulic Conductivity Values from Slug Tests, Coats American Sylvan Plant, Rosman, North Carolina. Well Hydraulic Conductivity (K) cm/sec GM-1 2.68 x 104 GM-3 1.10 x 104 GM-4 8.75 x 10-5 GM-5 1.17 x 104 GM-6 1.22 x 10-4 GM-7 7.47 x 10-' GM-8 1.63 x 104 GM-9 5.93 x 104 cm/sec Centimeters per second. g.'mnvk en==i=%yly pl=6wc p=iNable Mod UIC Permit Application ARCADIS ATTACHMENT 1 ORC MATERIAL SAFETY DATA SHEET OXYGEN RELEASE COMPOUND (ORC®) MATERIAL SAFETY DATA SHEET(MSDS) Last Revised: March 27,2003 SECTION 1-MATERIAL IDENTIFICATION ****************************************************************************** SUPPLIER: REGENESIS 1011 Calle Sombra San Clemente, CA 92673 _ 949-366-8000 phbne 949-366-8090 fax info@regenesis.com e-mail CHEMICAL DESCRIPTION: A mixture of Magnesium Peroxide [MgO2],Magnesium Oxide [MgO], and Magnesium Hydroxide [Mg(OH)2] CHEMICAL FAMILY: Inorganic Chemicals PRODUCT NAME: Oxygen Release Compound (ORe) PRODUCT USE: Used for environmental remediation of contaminated soil and groundwater SECTION 2-CHEMICAL IDENTIFICATION CHEMICAL CHARACTERIZATION Magnesium Peroxide [M902]: CAS Reg.No. 14452-57-4 Magnesium Oxide [MgO]: CAS Reg.No. 1309-48-4 Magnesium Hydroxide((Mg(OH)2): CAS Reg.No. 1309-42-8 FORM : powder COLOR:white ODOR: odorless ASSAY: 25 -35%Magnesium Peroxide(MgO2) SECTION 3 -PHYSICAL AND TECHNICAL SAFETY DATA MELTING POINT:Not Determined BOILING POINT:Not Determined DENSITY: 0.6-0.8 g/cc BULK DENSITY: -- VAPOR PRESSURE: Data not available VISCOSITY: --- SOLUBILITY: Reacts with water. Soluble in acid pH VALUE: Approx. 10 in saturated solution FLASH POINT:Not applicable SELF-IGNITION TEMPERATURE:Not applicable EXPLOSION LIMITS %BY VOLUME: --- THERMAL DECOMPOSITION: Spontaneous decomposition possible about 150' C HAZARDOUS DECOMPOSITION PRODUCTS:Not known HAZARDOUS REACTIONS: Hazardous polymerization will not occur FURTHER INFORMATION:Non-combustible,but will support combustion ****************************************************************************** SECTION 4-REACTIVITY DATA ****************************************************************************** STABILITY:Product is stable unless heated above 150°C. Magnesium Peroxide reacts with water to slowly release oxygen. React by product is magnesium hydroxide CONDITIONS TO AVOID: Heat above 150°C. Open flames INCOMPATIBILITY: Strong Acids. Strong chemical agents HAZARDOUS POLYMERIZATION:None known SECTION 5-REGULATIONS PERMISSIBLE EXPOSURE LIMITS IN AIR:Not established. Should be treated as a nuisance dust. SECTION 6-PROTECTIVE MEASURES, STORAGE,AND HANDLING TECHNICAL PROTECTIVE MEASURES STORAGE: Keep container tightly closed. Keep away from combustible material HANDLING: Use only in well-ventilated areas PERSONAL PROTECTIVE EQUIPMENT RESPIRATORY PROTECTION: Recommended(HEPA Filters) HAND PROTECTION: Wear suitable gloves EYE PROTECTION:Use chemical safety goggles OTHER: --- INDUSTRIAL HYGIENE: Avoid contact with skin and eyes PROTECTION AGAINST FIRE AND EXPLOSION: --- DISPOSAL: Dispose via sanitary landfill per state/local authority FURTHER INFORMATION:Not flammable,but may intensify fire ****************************************************************************** SECTION 7-MEASURES IN CASE OF ACCIDENTS AND FIRE ****************************************************************************** AFTER SPILLAGE/LEAKAGE/GAS LEAKAGE: Collect in suitable containers.Wash remainder with copious quantities of water. EXTINGUISHING MEDIA SUITABLE: Carbon dioxide, dry chemicals, foam NOT TO BE USED: --- FURTHER INFORMATION: Self contained breathing apparatus or approved gas mask should be worn due to small particle size. Use extinguishing media appropriate for surrounding fire. FIRST AID: After contact with skin, wash immediately with plenty of water and soap. In case of contact with eyes,rinse immediately with plenty of water and seek medical attention. FURTHER INFORMATION: --- SECTION 8 -INFORMATION ON TOXICOLOGY TOXICITY DATA:Data not available ****************************************************************************** SECTION 9-INFORMATION ON ECOLOGY WATER POLLUTION HAZARD RATING(WGK): 0 SECTION 10-FURTHER INFORMATION ****************************************************************************** - After the reaction of magnesium peroxide to form oxygen the resulting material,magnesium hydroxide is mildly basic. The amounts of magnesium oxide (magnesia) and magnesium hydroxide in the initial product have an effect similar to lime,but with lower alkalinity. The information contained in this document is the best available to the supplier at the time of writing,but is provided without warranty of any kind. Some possible hazards have been determined by analogy to similar classes of material. The items in this document are subject to change and clarification as more information becomes available. UIC Permit Application ARCADIS ATTACHMENT 2 ORC SLURRY INSTALLATION INSTRUCTIONS REGENESIS Oxygen Release Compound (ORC°) Installation Instructions (Direct-Injection Slurry Application) SAFETY: Pure ORC is shipped to you as a fine powder rated at-325 mesh (passes through a 44 micron screen). It is considered to be a mild oxidizer and as such should be handled with care while in the field. Field personnel should take precautions while applying the pure ORC. Typically, the operator should work upwind of the product as well as use appropriate safety equipment. These would include,eye and respiratory protection, and gloves as deemed appropriate by exposure duration and field conditions. Personnel operating the field equipment utilized during the installation process should have appropriate training, supervision and experience. GENERAL GUIDELINES: ORC may be installed in the contaminated saturated zone in the ground utilizing hand augered holes, Geoprobe®type hydraulic punch equipment, or hollow stem augers. This set of instructions is'specific for Geoprobe equipment. Alternate instructions may- be obtained from the Regenesis Technical Support Department. For optimum results the ORC slurry installation should span the entire vertical contaminated saturated thickness, including the capillary fringe and "smear zone". Two general installation approaches are available. The first is to backfill only the probe hole with slurry. This is a simple approach, in that it is easy, straightforward, and the location of the ORC slurry is precisely known after installation. However, this method requires significantly more probe holes than the alternative, and may take more time for the completion of the remediation process. A separate set of instructions for this method utilizing Geoprobe equipment is available from Regenesis. The second method is to inject the slurry through the probe holes into the - contaminated saturated zone. This method requires fewer probe holes, is less disruptive to the site, and aids the spread of oxygen by spreading the ORC source material. However, it may,be difficult to know the exact, final disposition of the ORC installed with this method. This is the method described in these instructions. Note: It is important that the installation method and specific ORC slurry point location be established prior to field installation. It is also important that the ORC slurry volume and solids content for each drive point be predetermined. The Regenesis Technical Service Department is available to discuss these issues, and Helpful Hints at the end. of these instructions offers relevant information. Regenesis also has available Technical Bulletins covering source treatments with ORC. S SPECIFIC INSTALLATION PROCEDURES 1. Identify the location of all underground structures, including utilities, tanks, distribution piping, sewers, drains, and landscape irrigation systems. 2. Identify surface and aerial impediments. 3. Adjust planned installation locations for all impediments and obstacles. _ 4. Pre-mark the installation grid point locations, noting any that have special depth requirements. ,- 5. Set up the Geoprobe unit over each specific point, following manufacturer recommended procedures. Care should be taken to assure approximate vertical probe holes. 6. Penetrate surface pavement, if necessary, following standard Geoprobe procedures. 7. Drive the 1 1/2 (one-and-one-half inch) pre-probe (part#AT-148B) with the expendable tip (part#AT142B) to the desired maximum depth. Standard 1" (one inch) drive rods (part AT104B) should be used, after the pre-probe. (Hint: Pre-counted drive rods should be positioned prior to the installation driving procedure to assure the desired depth is reached.) 8. Disconnect the drive rods from the expendable tip, following standard Geoprobe procedures. 9. Mix the appropriate quantity of ORC slurry for the current drive point. (See separate "Directions for OR&Slurry Mixing" and Helpful Hints). Note: Do not mix more,slurry than will be used within a 30 minute period. 10.Set up and operate an appropriate slurry pump according to manufacturer's directions. Based on our experience, a Geoprobe model GS-1000 pump is recommended. Connect the pump to the probe grout pull cap (GS-1054)via a 1 inch diameter delivery hose. The hose is then attached to the 1" drive rod with its quick connector fitting. Upon confirmation of all connections add the ORC slurry to the pump hopper/tank. 11.Withdraw the pre-probe and drive stem 4' (four feet). (Also note Helpful Hints - Operations at end of instructions.) 12.Optional pretreatment step. (See Helpful Hints - Operations at end of instructions). Pump one to two gallons of tap water into the aquifer to enhance dispersion pathways from the probe hole. 13.Pump the predetermined quantity of ORC slurry for the depth interval being injected. Observe pump pressure levels for indications of slurry;dispersion or refusal into the aquifer. (Increasing pressure indicates reduced acceptance of material by the aquifer). 14.Remove one 4' section of the 1" drive rod. The drive rod will contain slurry. This slurry should be returned to the ORC bucket for reuse. 15.Repeat steps 11, 13, and 14 until treatment of the entire affected thickness has been achieved. It is generally recommended that the procedure extend to the top of the capillary fringe/smear zone. 16.Install an appropriate seal, such as bentonite, above the ORC slurry through the - entire'vadose zone. This helps assure that the slurry stays in place and prevents contaminant migration from the surface. Depending on soil conditions and local regulations, a bentonite seal can be pumped through the slurry pump or added via chips or pellets after probe removal. 17.Remove and decontaminate the drive rods and pre-probe. 2 i _ I t 18.Finish the probe hole at surface as appropriate (concrete or asphalt cap, if necessary). 19. Move to the next probe point, repeating steps 5 through 18. HELPFUL HINTS: A. Physical characteristics Al. Slurry The ORC slurry is made using the dry ORC powder (rated at-325 mesh). It makes a smooth slurry, with a consistency that depends on the amount of water used. A thick, but pumpable, slurry that approaches a paste can be made by using 65-67% solids. This material would normally be used for back-filling a bore or probe hole. It is especially useful where maximum density is desired such as where ground water is present in the hole or there are heaving sands. Thinner slurries can be made by using more water. Typical solids for the thinner slurries content will range from 35% to 62%. Such slurries are useful for injecting _ through a probe or bore hole into the saturated aquifer. As a rule, it is best to mix the first batch of slurry at the maximum solids content one would expect to.use. It can then be thinned by adding additional water in small increments. By monitoring this process, the appropriate quantities of water for subsequent batches can be determined. The slurry should be mixed at about the time it is expected to be used. It is best to not hold it for more than 30 minutes. Thinner slurries, especially, can experience a separation upon standing. All ORC slurries have a tendency to form cements when - left standing. If a slurry begins to thicken too much, it should be mixed again and additional water added if necessary. Care should be taken with slurry that may be left standing in a grout pump or hose. Problems can generally be avoided by periodically re-circulating the slurry through the pump and hose back into the pump's mixing or holding tank. A2. Equipment Most geotechnical grout pumping equipment has a holding tank with a capacity sufficient for injection. When applying measured volumes of ORC slurry to probe holes, it is sometimes useful to know the volumes and content of the delivery system lines. The following information may be useful in this regard. Geoprobe pump: At the end of a pump stroke virtually no deliverable slurry remains in the pump. 5/8" O.D. connecting hose(10 feet long): 0.2 gallons (26 fluid ounces). Four foot(4')length of 1"drive rod: .04 gallons (5 fluid ounces). Three foot(3') length of 1 1/2"pre-probe: 11 .03 gallons (4 fluid ounces). 3 Cleaning and maintenance: Pumping equipment and drive rods can be lightly cleaned by circulating clear water through them. Further cleaning and decontamination (if necessary due to subsurface conditions) should be performed according to the equipment supplier's standard procedures and local regulatory requirements. B. Operating characteristics ' 131. Operations- General Judgment will be needed in the field when injecting ORC slurries. In general, it is relatively easy to inject ORC slurries into sandy soils, and this can usually be accomplished at very moderate pressures. Silts and clays require more pressure, and - may accept less slurry. Careful_observation of pressure during slurry pumping is the best indication of the effectiveness of the slurry injection. To test the soil's ability to accept the slurry and to "precondition" the injection point for the slurry, it is sometimes useful to inject a small volume of plain water prior to the slurry. Normally, one-half(0.5) gallons to two (2) T gallons would be appropriate. During injection, increasing pressure and decreasing flow rate are signs of refusal by the soil matrix to accept the slurry. The site geologist should determine whether to increase pressure, and possibly fracture ("frac") the soil matrix to achieve ORC slurry installation in a tight site that has refused the slurry at lower pressures. B2. Fill Volumes Probe hole back-filling Probe hole capacities: Per 10'(Ten Foot) Length Theoretical Operating Volume (Gallons/Fluid Ounces/Cubic Inches) (Gallons/Fluid Ounces) Sand,Silts &Clay Sand ISilts &Clay 1"Diameter .41 gal/52 fl: oz./94.2 cu. in. 61 gal/78 fl.oz. 51 gal/65 fl.oz. 1 1/2" Diameter 1.92 gal/117 fl. oz./212.0 cu. in. 1.38 gal/176 fl. oz. 1.15 gaV146 fl. oz. 2" Diameter 11.63 gal/209 fl.oz./376.8 cu. in. 112.44 gal/313 fl. oz. 2.04 gal/261 fl. oz. - 2 1/4" Diameter 2.06 gal/264 fl, oz./476.9 cu. in 3.09 gal/396 fl. oz. 2.57 gal/330 fl, oz. Note that the operating volumes include a 50% excess above the theoretical volume in sands and 25% in clays and silts. This is important to successful treatment. The additional material allows for a small degree of infiltration of the slurry into the surrounding soil and fractures, as well as hole diameter variability. It is important to assure that the entire contaminated saturated zone is treated (including the capillary fringe), since this is often the area of highest pollution concentration. Failure to treat this area due to improper installation can undermine an otherwise successful remediation effort. 4 _ r For direct assistance or answers to any questions you may have regarding these instructions, contact Regenesis Technical Services at 949-366-8000. f REGENESIS, 2002 — www.regenesis.com 5 UIC Permit Application ARCADIS ATTACH ME NT 3 DESIGN CALCULATIONS ORC Design:Software for- rid Applications Using Slurry Injection 1•usVerson Bl Regenes67edlniml Sup G port:USA www•3egenemil '�Slft Nunn:FIn6M1blO plant, Locaw:Ruemon NO 3 $- 'C.nsukant Ncedb G3MS41DP020y11]o) - - - "•.� -Slte ConcpluuM.eUu,V bnl Ol Plum....uunn,. ... WMth of oases,Satual flona d1 Don)+ 29R ffun6taMplmm(pareealt.gfl d'ropnOn)' - - Zen •eve sR.n. ., y s fr Depth to oc bmwual no 5 it RIctneasM contandraledaalurated son. - 1 20 R N i '� y 1 •55) 'nN when,ma(5nval sand.silty Ind R,cbry) be rdlas'-(rot lak;"9 t NM1 Or Ve.daunt t - M, .S - iToblpdOsay }�"` - 025 ER P dslly O.t5 4 Hydnedie eenduNMy O5 Nest I.5Ed4 cM a iNnnuf Ipaebat _ - =OBf NR 9 eP.9e V.lOtlry = t F m -=.48.]IVyr 0.133 NaaY T .Mani Zee Pea Volume .A I - "3.fi00 1[' 20.9a7 9NI x Yi fa 01 .IvedPn. Oman D.nf a aCanWV t '43bIN(wlMll" ORC(b) •e IMMeua h. ea nal reoreze 1 .wen tlemend - ni Conc(NpILj me (bl" Oil th '(10%Oa) >Vd OAO. OA 3.1 toluene MM1Ylbavere „ - ,:"Y OAO 0.0 32 - rylenea • A" 010 - -0.0 r 3.2 0 �( -O.co -0.0 2] 0,i dahlwo.Un ,i 0.00 0.0 0] 0 c b iNityl NbrlEe'- - - SAID 0.0 •' 1.3 0 -i VOC§ME TIC. Y 040 0.1 3.2 2 Uaeretlded bo tad MiWOmedetl nd '0.00 - '0.0 0.0 0 .v +I ._ _ T au®emabl F H21NId Mnl zit ,` • IOAO -1.7 - ,0.10 2 M soresdisto ndomand TMaIPeOMa ti' IEone B oltylnl Oaygen Demand(000) CM1emlml0ay0en Demand(LDO) -x l Y.F y, -- - UAul .0 G ENlm issf 6 rb.d Pfl Ory0 nD ne Soil bulk Edrmlly "1.0 pl 112 b1d j Fddlon.fog �bwif Oml n0 0b001' 3 (E tl Iad a Me Sell Wet IKac tapwNe II0 q - Kea MAE -ORO Ob) 4 I dil[d,a?meals,that n.m eN nInl.n demand.- (mm I ° Conn(mOht) MseaVOY Oa) _ bdlvn I'm 0.0 3.1 e- .* 022 �e1hN0emnne. - 95 0.00 0.0 - 32. 0 - rylen.._ 1 - 24D - O00 0.0 32 0 ,. MTfiE '`�' ti y 12".. 000 0.0 - 2.] 'dlMbwoNo ' y SO - - OAO 0.0' 0.] 0, - vv chbMe •. to- n ," 25 0So • 'D.0 1.3 0 _```� ' '•:_. •VOCYendnCt 2MS OBO 0.7 -'32 23 �Ueeledcad else add alelNe.meblC demand + 00 - e00 - 0.0 0.0 0 Meaeurea 0fl.blmiwendemen0 l " .T.Ial Pe00leum HytlmOlCona. ~' -' 118 O00 0.O 3.110 Y �( Bblilp.l OuM nDual(SOD) I L e ouNpb of d..WW ph... 100 0.0 - 1 0 Chumlad Os,,oh Demand(COD) ,_. Use a muNple M dlswlead phen 1.00 y - 0.0 1 0 ORC for Distal d ORC for Slated Add Da Fadol;,:'ORC ToblW OROCosI 1 _ .5mmery of EatknatadoRCReRI ad'- �"' Pnaae lha 'Phase ha 11otOx"e paid Cella FedorS 1000 - InaNbual Species,Total 811 MTBE 4 - 23 5 - 135 $ 1150 F Total P¢hob mra NYdlbonal •y• 2 .. $ li i i6l.kglral OryOen Dunned(SOD) -. -, -r 2 - E •,. ': Cn iml Oxman Demand(CODI _a ,; ' - 1 " - $ Sliest abow measure butualtospecify Ys Ind ORC quanO In 3o lb In " ( requited bl nrl_-,a _ _. .... fsR P.a"ORC ,Dsllvery Odalvnf.r ORCSluery ,At _Spadn9wlM.ahae + BO ee/ + SI rty Yl tn9V.lu f loopvl p pabd per law * _ - 3{omanw , Pounds per l0.ell.n - 60poses L Sp3eing baboah n l0nt lfl7_ -x =30 n a Burk¢1a Pa[Leatlan ^- J 2.0. X.fra. 3 Daa'gnsWda eeNeN(20-00%bywt/aril d.nsl`- 30%t' AdvetlthnsU, uma beL mwe(e n) _ - - so tlga,+ Volturno afwebr poorest per late(6ep. 1]p'as !Number.}pobtata0he 9pwh •'Totatwetar for sake,0holes(gal) 1510. f Required ORC per feet - '" Mnmum Dow WeRdN 30toaby¢ ", Simple ORO Backspin,thin halo ale.fw R]%slurry -2R t4 " T.tWORc `� MlNmum Daso Ownido-+ . 5w lbs Ot ORL,: FemlbOitydnlurry b)eNlonlnwnd:aupblSbM - Fe=jVi farsl Ok ry urry lRfodlonln slR:.k upbtOlMfl - k s Pal Suna - c F wlbarybralun5'bl a0 cbY ak uPb51NT k ORC bulkmetenal for slmryinjualon(11.) SW •x � Nuaidoraf2l91b ORC sockeb' _ '• + 16.0 ,Y i ORCbuhm t sal Nai.;f. _ $ -10.00 COlforbuRORCmateRal- E 1 -6.400 [ q Shlppinp and i Esil ads In US D II :3 j SM.Tm d 6% S y324 ToNIMeLLCast - _ -Er 25,T14 e ry 1+' Shipping(-wnmramwm. - "._''u,. "•s --tee "• - T.dlRaan¢slaMaledelCsl 'f" 5244 F.: - L ORC Sltt aleation tea s Ihl an n Cass s0m 1 - Faoddefareadlbj.poNl=unto peel ted�NRC bj.Mtaml(R) ;P ,_n •010 Tadl lergN(ddddpush br Plot d(fll • e: �` .•225 .: P Rlt9 nd 1pal $ + Esemelnd eaOYlrmWlaOon nd(fl pe tlry:406 for path 150d d 0 OP", h '+2W ;. Ca 1 d re9emeN S .'s ?...•( Eath..dtl lnlnd par e1(15 to 30 Is....Ibis for dndpush) "G nd lermO ibeng ndrga Re vhednumbardee - - 2 War. - ' $ 10 ObetMbMeleebwstWend wbw lndOP IS OuY Iv(dW Sub > E-,..'- Othe T..11,.a[an.uemnbeterinsl for. nralbn 5 - "aa00 , Other E Total install Loel rot including wnwlUnl.lad.etc $ 9,ell -„Total Pooled Cost $ 9.Ob '- _� RECEIVED MAPS 1 G "��Qfi DIVISION OF WATER QUALITY II Asheville Regional Office AQUIFER PROTECTION SECTION I A uiter Protection March 14, 2006 MEMORANDUM To: Landon Davidson Asheville Regional Office From: Jesse Wiseman J ln1 Central Office UIC Program Re: Notice of Expiration UIC Permit No. WI0100015 Coats North America Transylvania County UIC Permit No. WI0100015 (Injection hi situ Groundwater Remediation Well(51)) issued to Coats North America is due to expire on July 31, 2006. A Notice of Expiration regarding this permit was sent by this office to Mike Bell of Coats North America on March 14, 2006. This letter is attached for your records. Attachment cc: CO-UIC Files � t�oifiiU le; ' rtoi�ss�d �U:�u��+r;,,l� __. `Iili ld t_�1 f WATF f ��� 9pG Michael F.Easley,Governor O Cl) y William G.Ross Jr.,Secretary t— North Carolina Department of Environment and Natural Resources O Y Alan W.Klimek,P.E.Director Division of Water Quality March 14, 2006 Mike Bell Coats North America P.O. Box 670 Toccoa, GA 30577 CERTIFIED MAIL RETURN RECEIPT REQUESTED 7002 2410 0003 0273 3853 Subject: Notice of Expiration North Carolina Well Construction Standards Applicable to Injection Wells - Subchapter 2C UIC Permit No. WI0100015 Issued to Coats North America Transylvania County Dear Mr. Bell: _ The Underground Injection Control (UIC) Program of the North Carolina Division of Water Quality is responsible for regulating injection well construction and operation activities within the state. Our records show that the injection well permit referenced above will expire on July 31, 2006. This permit was issued for the injection system located at Highway 178 in Rosman, North Carolina. Please submit the enclosed form;STATUS OFINJECTION WELL SYSTEM(form GW/UIC-68)to indicate the current status of your injection well system within 30 calendar days of the receipt of this letter. If you intend to conduct additional injections or pursue any injection-related activities that are beyond the scope of the permit referenced above,you must submit a letter requesting a renewal and/or amendment of the permit that describes in detail the procedure, locations, volume, and frequency of injected material, and any other pertinent information regarding the proposed activity. In addition, our records indicate that a final project evaluation is due within 9 months after completion of the injection operation. To date we have not received this report. If the injection project has been completed,please submit the required final project evaluation as indicated in your permit in PART VII—MONITORING AND REPORTING REQUIREMENTS. If any injection well is no longer being used for any purpose, it must be permanently abandoned according to the regulatory requirements specified in the North Carolina Administrative Code Npow�t}tCarolina - ,/VllfuCQ�l� Aquifer Protection Section 1636 Mail Service Center Raleigh,NC 27699-1636 Telephone: (919)733-3221 Internet:vnnv.ncwaterauality ore Location: 2728 Capital Boulevard Raleigh,NC 27604 Fax 1: (919)715-0588 Fax 2: (919)715-6048 An Equal Opportunily/Affirmative Action Employer—50%Recycled110%Post Consumer Paper Customer Service: (877)623-6749 Mike Bell March 14,2006 Page 2 of 2 Title 15A Subchapter 2C Section .0214. If any injection well is to be permanently abandoned, well abandonment records must be submitted to our office to ensure proper abandonment. Please contact Thomas Slusser at(919) 715-6166 or Evan Kane at(919) 715-6182 if you have any questions regarding this correspondence,your permit, or injection well rules and regulations. Sincerely, Jesse Wiseman Processing Assistant UIC Program Enclosure cc: J.Alan Pinnix,L.G.-ARCADIS APS Asheville Regional Office w/o enclosure CO-UIC Files w/o enclosure RECEIVED DIVISION OF WATER QUALM APR 2 0 2906 AQUIFER PROTECTION SECTION Asheville Regional Office April 18, 2006 A uifer Protection MEMORANDUM To: Landon Davidson Asheville Regional Office From: Jesse Wiseman J vJ Central Office LTIC Program Re: Notice of Regulatory Requirement UIC Permit No. WI0100015 Coats North America Transylvania County UIC Permit No. WI0100015 (Injection In situ Groundwater Remediation Well (51))issued to Coats North America is due to expire on July 31, 2006. A Notice of Regulatory Requirement regarding this permit was sent by this office to Mike Bell of Coats North America on April 18, 2006. This letter is attached for your records. Attachment cc: CO-UIC Files �. F WAIF Michael F.Easley,Governor 0 y William G.Ross Jr.,Secretary CO> [ North Carolina Department of Environment and Natural Resources 1 0 Y Alan W.Klimek,P.E.Director Division of Water Quality t April 18, 2006 Mike Bell Coats North America P.O. Box 670 Toccoa, GA 30577 CERTIFIED MAIL RETURN RECEIPT REQUESTED 7002 2410 0003 0273 4249 Subject: Notice of Regulatory Requirement North Carolina Well Construction Standards Applicable to Injection Wells - Subchapter 2C UIC Permit No. WI0100015 Issued to Coats North America Transylvania County Dear Mr. Bell: The Underground Injection Control (UIC) Program of the North Carolina Division of Water Quality is responsible for regulating injection well construction and operation activities within the state. Our records show that the injection well permit referenced above will expire on July 31, 2006. This permit was issued on July 30, 2003 for the injection system located off of Highway 178 in Rosman,North Carolina. This office attempted to bring your injection well system into compliance by sending you a Notice of Expiration and an injection well status form on March 14, 2006. To date the UIC Program has not received the requested status form. The pumose of this letter is to inform Coats North America of its responsibilities pertaining to injection well rules Please submit the enclosed form, STATUS OFINJECTION WELL SYSTEM(form GW/UIC-68) to indicate the current status of your injection well system within 15 calendar days of hie,] of this letter. If you intend to conduct additional injections or pursue any inj ection-related activities that are beyond the scope of the permit referenced above, you must submit a letter requesting renewal and/or amendment of the permit that describes in detail the procedure; locations, volume, and frequency of injected material, and any other pertinent information regarding the proposed activity. In addition, our records indicate that a final project evaluation is due within 9 months after completion of the injection operation. To date we have not received this report. If the injection N°rthCaoulina J�atura/!7 Aquifer Protection Section 1636 Mail Service Center Raleigh,NC 27699-1636 Telephone: (919)733-3221 Internet:w v.ncvvaterqualitv.ore Location: 2728 Capital Boulevard Raleigh,NC 27604 Fax 1: (919)715-0588 Fax 2: (919)715-6048 An Equal OpportunitylAfSrmaliveAclion Employer—50%Recycled/10%Post Consumer Paper Customer Service: (877)623-6748 Mike Bell ✓ .April 18,2006 Page 2 of 2 project has been completed,please submit the required final project evaluation as indicated in your permit in PART VH—MONITORING AND REPORTING REQUIREMENTS. If any injection well is no longer being used for any purpose,it must be permanently abandoned according to the regulatory requirements specified in the North Carolina Administrative Code Title 15A Subchapter 2C Section .0214. If any injection well is to be permanently abandoned, well abandonment records must be submitted to our office to ensure proper abandonment. Again, we have provided you with the appropriate information to update your UIC permit. You must respond within 15 calendar days of the receipt of this letter, or a Notice of Violation will be issued to you, which carries the possibility for an assessment of fines or cessation of operation of the injection well system. Please call Mike Ranck at (919) 715-6164 or email him at Michael.Ranck(a)ncmail.net if you have any questions about this correspondence, the UIC Program, or the enclosed form. Sincerely, 9. J, Debra J. Watts, Supervisor Groundwater Protection Unit Enclosure cc: J.Alan Pira ix, L.G. -ARCADIS APS Asheville Regional Office w/o enclosure CO-UIC Files w/o enclosure 01/26/2004 15:42 919-71- 58 , „ NCDE&N /WATER C''-' PAGE 01 L► R CA �/� Post-Ir Fax Note 7677 Date �� pa°pes� / To From ARCADIS C&M of North infrastructtuu 11 re, buildinc ColDept co w -CZ L, igre, Carolina,Inc. Phorlee Phone 4/p ,� / !� 801 Corporate Center Drive 0 1G suite 300 Mr.Mark Fritz] Raleigh, LUC,Program North Carolina 27607-5073 Tel 919 8S4 1282 Groundwater Section Fax 919 854 S448 North Carolina DENR-DWQ w .arcadis-umom 1636 Mail Service Center Raleigh,NC 27699-1636 ENVIRONMENTAL Subject: UIC Permit Application,Coats American Svlvan Plant,Rosman,North Carolina, Groundwater Incident#5337. Date; Dear Mr.laritzl: July 25,2003 Contact As per our telephone conversation on July 24,2003 we are pleased to follow up with J.Alan Pinnix L.G. clarification on the monitoring frequency for the proposed injection of oxygen release compound(ORC)at the above referenced site. This letter is to confirm that Extension; the planned monitoring will be on a quarterly basis for a period of one year. As 247 outlined in the permit application,the first event will be approximately 3 months after ORC injection. EmaB: apmnixda arcadis- Thank you for your assistance in reviewing this permit application and should you us.com have additional questions,please do not hesitate to contact the undersigned, our ref: NC103015.0001 Sincerely, ARCADIS G&M of North Carolina,Inc. PAlan Pinnix, L.G. Project Scientist Covias Mr.Mike Bell c w a L r— Co CC Co V .f*iq � n w � O z Part of a bigger picture R E C E o y E AUG 4 2003 D DIVISION OF WATER QUALITY GROUNDWATER SECTION GROUNDWATER SECTION ASHEVILLE REGIONAL OFFICE July 31, 2003 MEMORANDUM To: Landon Davidson, L.G.,Regional Groundwater Supervisor Groundwater Section Asheville Regional Office From: Mark Pritzl Mark.Pritzl@ncmail.net Hydrogeological Technician II UIC Group Groundwater Section Raleigh Central Office Re: Issuance of injection well permit type 5I (in-situ Groundwater Remediation Well) Permit Number WIOI 00015 for the injection of an ORC to enhance aerobic biodegradation of the dissolved vinyl chloride contamination at the Coats America Sylvan Plant, in Rosman,North Carolina. The UIC group greatly appreciates Kay Dechant's assistance with this review. Please retain the application paper work and permit copy for the ARO-UIC files. If you have any questions regarding this Memo or the UIC program, please contact me at (919) 715-6166. cc: CO-UIC Files Enclosures GROUNDWATER SECTION July 29, 2003 MEMORANDUM To: Debra Watts, Supervisor,Permits &Compliance Branch Through: Evan Kane, Hydrogeologist,UIC Program Manager 7/�_ From: Mark Pritzl, Hydrogeological Technician,UIC Program 4 Re: Coats' injection well application for the injection of an Oxygen Releasing Compound (ORC) slurry to enhance aerobic biodegradation of the dissolved vinyl chloride contamination in groundwater at this site. • This site is located within the Blue Ridge physiographic province of North Carolina and is located just east of the Brevard Fault in the Chauga Geologic Belt. The site is underlain by silts and clays inter-bedded with fine sands to a depth of 90 feet below land surface (bls), where bedrock begins. These fine sediments generally coarsen downward to a silty sand just before encountering bedrock. Bedrock under the site has been identified as the Henderson Gneiss which consists of a biotite gneiss. • Shallow local groundwater movement at the entire site generally moves toward the south-cast and depth to groundwater is less than 5 feet(bls) around the injection area. Head data from GM-4 and GM-10 indicate that the shallow sediments are recharging the deeper sediments, or that the injection area is in a recharging zone. (See X-sections in application) • Chlorinated solvent contamination exists in the surficial aquifer with vinyl chloride as the main dissolved contaminant of concern for this remedial activity. Groundwater contamination is the result of depositing floor scrubber and frame cleaning water into two pits that existed from the early 1970s to 1989. Since 1990, the site has been the subject of a great number of remedial activities such as the excavation of over 1,000 tons of soil from both pits in 1992. The proposed injection process is to address the last or residual contamination around GM-4.) p Within the proposed injection process, the injection of an ORC slurry is proposed to enhance the aerobic bacteria breakdown of vinyl chloride to heat, CO2, H2O and Cl-. I have provided a r technical written summary illustrating this direct substrate biodegradation process, in which f, the author also explains that aerobic co-metabolic processes may also occur to break down the dissolved vinyl chloride contamination. • Nine injection points are proposed that will utilize the GeoProbe or push rod technology. The nine injection points will be placed in three rows with 8 feet between each row, and three injection points will be placed in each row with 8 feet between each injection point. Each injection point will deliver 3 lbs/vertical foot of ORC or 60 lbs per hole, and the injection interval is from 5 feet bls to 25 feet bls. The entire injection grid is located hydraulically up gradient of GM-4 or inside the"Excavated Pit Area L" As mentioned before, this area is the only area identified by the consultant where groundwater is contaminated above the 2L standards. A second and possibly a third injection event of ORC may be required to achieve the desired contaminant reduction. • All groundwater samples will be analyzed for VOCs, DO, ORP,pH, turbidity, temperature and specific conductivity. Groundwater samples will be collected from GM-4, GM-10, RW- 1, RW-2, and MW-4D. A pre-injection sampling event will take place, and post-injection sampling from the monitoring wells mentioned above will begin three months after injection and continue every three months for one year. • The main limiting factor for ORC injection at this site is the existence of significant dissolved iron(ferrous) in shallow groundwater,which could scavenge the delivered oxygen, making it unavailable for bacterial utilization. This limited availability of delivered oxygen could, in turn, limit the radius of influence of the injected oxygen so as not to be effective. • At this time, I recommend that a permit be issued to Coats for the injection of an ORC slurry to enhance aerobic biodegradation of vinyl chloride dissolved in groundwater at this site. '17 .8G4.8 ' 0 ' PROPERTY \ BOUNDARY r r\r N \r r II AR EA EXCAVATED \r\ \`O r \r �GM-8 / I GM-2 1 \r\ NS ASSUME 184.0' ELEVATION ® r AT LOADING DOCK ENTRANCE I GM-3 ,F GM-4 \r • 9.7 • \r GM-9 ' • RW-2\ EXCAVATED GM-10 PIT AREA i <1.0 r\ r BUILDING I \r PAVED I RW—i • GM-7 • \r\ j • GM-5 <1.0 NS • NS GM-11 NS • GM-6 LEGEND I 0 —•— FENCE • MONITOR WELL RECOVERY WELL i 179-71 VINYL CHLORIDE CONCENTRATION (Vg/L) NS NOT SAMPLED a APPROXIMATE HORIZONTAL EXTENT a"3"1'"' OF GROUNDWATER IMPACT ABOVE o ScnLE IN FEET OF NC.2L STANDARDS 6 PRJT MANAGER, CHECKED BYE VINYL CHLORIDE AGURE: A. PINNIX N PANR ARCADIS BRAVING COATS—SITE-03 CONCENTRATIONS (dig/L) AflCAD1S Na"" Cara° "a' NclD3D13.0001 SEPTEMBER 18 2002 7 .. 801 Carycrata Cantor ogre. Salta 3W PRJT Na r ' Raleigh, INC 27607 COATS AMERICAN—SYLVAN FACILITY, Tel: 919-854-1282 Fax: 919-854-5448 8VG BATE. A.nR-TERM ROSMAN, NORTH CAROLINA .w.arcoaia—ua.<am 15MAY02 NURTUN 17 .8G4.8 0 r PROPERTY i \ / BOUNDARY r EXCAVATED PIT AREA 2/ \O II GM-2 \+\r �172.17 ASSUME 184.0' ELEVATION 174.48� \ AT LOADING DOCK ENTRANCE GM-3 c3m / 172,72 k • \+ GM-9 • RW-2 168.65 EXCAVA GM-10 PIT 1 \+\ / BUILDING I +\r j PAVED I • GM-5 RW-1 • 168.39• \+\ 170.46 • GM-11 . I / / • GM-6 LEGEND I 168.81 —•— FENCE NOTE 1: ALL ELEVATIONS ARE RELATIVE TO I • MONITOR WELL THE LOADING DOCK ENTRANCE. i A RECOVERY WELL NOTE 2: GROUNDWATER ELEVATION DATA 172.72 WATER LEVEL ELEVATION (FT,MSL) FROM WELLS GM-10, GM-11, i —170— POTENTIOMETRIC CONTOUR 2—FT RW-1 & RW-2 WERE NOT USED ( ) IN DETERMINING GROUNDWATER �D GROUNDWATER FLOW DIRECTION CONTOURS DUE TO SCREENING SCALE IN FEET DEPTHS BELOW SHALLOW AQUIFER. 0 60 PRJT HANAGERJ CHECKED BY. GENERALIZED FIGURE: ARCADIS PINNI% H PAHR Danvwu CDA7S—SITE-03 GROUNDWATER FLOW DIRECTION ARCADES C&M a1 NartN caraaaa, Ioa. SEPTEMBER 18 6 NC103013.0001 2��2 eDt Coryo.ote Cuter Drive. 5uaa 300 PRJT N0' r . Rolel9n. NC 99507 COATS AMERICAN—SYLVAN FACILITY Tel: 919-854-1232 For: 919-85e-5448 DVG DATE, DRAFTER. a,e.orcaaro—ue.core 13HAY03 A. NORTON ROSMAN, .NORTH CAROLINA I \+ LEGEND I —•—•— FENCE + • MONITOR WELL eC \+ A RECOVERY WELL I N +\ PROPOSED ORC INJECTION POINT x PROPERTY a I +\ SCALE IN FEET 30 x +\ BOUNDARY x EXCAVATED + PIT AREA 2 x \ • ' + GM-8 GM-2• \T\ +\ x GM-3 • � + I w +\ GM* -9 • x RW-2 \+\ EXCAVATED CM-4 • PIT AREA 1 GM-10 +\ x + I �+ x \ I + x RW-1 • GM-7 • \+ I • GM-5 \ x •GM-11 I x 1 A. P NAIX CN PMR 9T MONITOR WELL AND.RECOVERY WELL LOCATIONS f1CURE ARCADIS Vi N1% N PANR R9Av1NG COATS-SITE-030 AND PROPOSED ORC INJECTION POINTS . 3 01CaryamIS �e Caaler Dr of North ..,.. S.R.�300 PRAT �NC103013.0001 Raleigh, INC 27607 COATS AMERICAN—SYLVAN FACILITY Tel: 919-654-1]62 Fax: 919-654-5446 Rvc RATc, RR'NTCRI ROSMAN• *NORTH CAROLINA • nnn.arcoCi.-4. Co. 13NAY03 0. OR TON tb2223 r``h Page 1 of 3 { Remediation of Vinyl Chloride Vinyl Chloride and ORC Vinyl chloride(VC)is a common groundwater contaminant usually associated with higher order chlorinated aliphatic hydrocarbons(CAHs)such as perchloroethylede(PCE),tichloroethylene(TCE),and dichloroethylene(DCE). The presence of oxygen stimulates the degradation of vinyl chloride and is the basis upon which ORC has been shown to effectively treat this contaminant. Aerobic M tahnlicm of Vinyl Chloride The metabolism of vinyl chloride in the presence of oxygen may proceed via two possible mechanisms.In one pathway,VC serves as a primary substrate for oxygen-dependent microbial growth and is degraded completely to carbon dioxide and water (Davis and Carpenter,1990).This process occurs intracellularly and unlike co-metabolic(aerobic)remediation,no oxygenase-inducing compounds,such as methane are required for VC metabolism in this oxidative pathway.The use of ORC can thus stimulate vinyl chloride degradation without any additional treatment amendments or technologies. The direct,intracellular metabolism of vinyl chloride proceeds via oxidation to an intermediate compound(chlorooxirane) which ultimately degrades to carbon dioxide and water(Harhnans and DeBont, 1992).The chlorooxirane,an unstable epoxide intermediate,degrades further into various fragments(such as formic acid and oxyglycolic acid)which,in tutu,are transformed to CO2 and H2O.This results in a net energy benefit to the microbe.The proposed.mechanism of intracellular aerobic metabolism of VC is illustrated in Figure 1: H C1 02 H2O H O C1 ) C = C C ........0 —I — ► various intermediates (HCOOH,HOCCOOH) NADH NAD' H H 02 incorporated into cell mass Energy+ CO2+H2O+ Cl ,Figure 16 VC intracell"lar degradation pathway Net energy benefit to degrading organism. Others have suggested a,second possible pathway that involves methanotrophs capable of destroying vinyl chloride extracellularly through co-metabolism(McCarty, 1994).In co-metabolism,the formation of the chlorooxirane intermediate requires an enzyme-inducing substrate(in this case methane)that is apparently not required in intracellular aerobic VC metabolism.When co-metabolic VC degradation occurs,methanotrophs produce oxygenases,for example methane monooxygenase(MMO),that leak out of the cell and fortuitously degrade VC extracellularly with no net energetic benefit to the microbe.This co-metabolic degradation pathway may proceed according to the reactions shown in Figure 2: http://w�vw.regenesis.com/ORCtech/Tb2223.htm 3/21/2003 tb2223 Page 2 of 3 intracellular various intermediates , CH, CH30H incorporated -L+ CO2 +H=O into cell mass NADH, OZ NAD+ ,', extracellular'; O H 0 M H :' CI various intermediates C=C """"'C� incorporated by non- H H ' I N . H/ �H.�D+ methanonophs and/or NADH, OZ mineralized to CO,Cl ,H=O Figure 2: VC extracellular.co-metabolic dMradatlon pathway: No net energy benefit to MMO producing methanotroph. Both of the proposed mechanisms of VC biodegradation are oxygen-demanding processes that will benefit from ORC treatment. In addition to the requirements of aerobic respiration,oxygen plays an integral role in both intracellular and extracellular enzymatic reactions.The application of ORC can thus aid in the sustenance of the relevant microbial populations and enhance the rate of aerobic dechlorination of vinyl chloride. ORC Treatment of Yin idt Results from controlled laboratory studies and field applications support the ability of OKC to effectively enhance the biodegradation of vinyl chloride. 1.In a recent study conducted on groundwater and soils from an industrial site,VC was shown to degrade very rapidly(Tin =5 days)with ORC addition as the only applied treatment technology(Bell,P.et.al, 1997). 2.In another field demonstration of ORC conducted on a New York State Superfund site,ORC treatment resulted in significant degradation of vinyl chloride(Martinovich and Putscher, 1997;see also TB 3.1.1).Concurrent laboratory studies corroborated the field results using materials from the site. 3.At an industrial site in Massachusetts,project engineers sought to remediate chlorinated compound contamination in the property's groundwater.Treatment options were confined to the following limitations:the treatment was to be non-invasive and operate within limited available space;facility operations were to remain undisturbed; all possible air and water(both surface and subsurface)health hazards were to be considered and monitored for exposure to contamination.The particular remediation objectives of this site prompted project engineers to design an inventive dual phase strategy to remediate chlorinated compounds in sites The strategy is engineered as follows: 6 A groundwater recirculation system extracts water from three wells and re-injects the water into three injection wells upgradient A Phase one: addition of organic acids stimulates anaerobic conditions in the recirculation system,allowing microbial dechlorination of highly chlorinated compounds,(PCE,TCE,DCE). 6 Phase two:ORC socks are placed in an injection well to generate aerobic conditions and bacteria begin to degrade the vinyl chloride that accumulates in phase one. 6 Preliminary results indicate that vinyl chloride concentrations decreased as dissolved oxygen levels increased. 6 During the aerobic phase,the co-metabolic substrate methane was also introduced into the system.Addition of methane further accelerated degradation of vinyl chloride. http://www.regenesis.com/ORCtech/Tb2223.htm 3/21/2003 tb2223 �` ``t Page 3 of 3 These results suggest that both of the possible metabolic processes for aerobic vinyl chloride degradation may be occurring simultaneously within this system. As of early 1997,ORC has been applied to degrade VC at several sites across the U.S.This passive approach to remediation of chlorinated compounds presents a cost-effective method of treating both leachate contaminated landfills and industrial solvent contaminated sites.Investigations to further establish the role of ORC in vinyl chloride biodegradation are currently underway. ORC Installation Design Parameters The theoretical mass ratio of oxygen to vinyl chloride required for the aerobic metabolism of VC is relatively low at 1.3:1. Thus,for every pound of vinyl chloride to be degraded,at least 1.3 pounds of oxygen are required. The sorption coefficient(Koc)for vinyl chloride is 57(mUg),indicating that its tendency to sorb to the aquifer matrix is approximately equal to that of benzene(Koc=83 mUg).Therefore,in ORC application designs,when using dissolved vinyl chloride data from groundwater samples one can use additional demand factors usually associated with BTEX remediation projects as an acceptable approximation. References Bell, P.,K Casper and P.McIntire. 1997.Treatability Evaluation of In-Situ Biodegradation of Chlorinated Solvents in Groundwater. Proceedings from Air&Waste Management Association 90ffi Annual Meeting &Exhibition. Toronto, Canada. Davis,J. and C. L. Carpenter. 1990. Aerobic Biodegradation of Vinyl Chloride in Groundwater Samples.Appl. Environ.Microbiol. 56: 3878-3880. Hartmans, S. and J. A. M.DeBont. 1992. Aerobic Vinyl Chloride Metabolism in Mycobacterium aurum Ll. Appl. Environ. Microbiol. 58:1220-1226. Martinovich,B. and A. Putscher. 1997. Aerobic Biodegradation of Vinyl Chloride in Groundwater. In Situ and On-Site Bioremediation (5): 469.Alleman and Leeson eds. Battelle Press, Columbus, Ohio. McCarty,P. and L. Semprini. 1994. Groundwater Treatment for Chlorinated Solvents. Handbook of Bioremediation, Chapter 5. Matthews, T.E. ed. Lewis Publishers,Boca Raton,Florida. 257 pp. Technical Bulletin Indexl ftgenesis Home Page http://www.regenesis.com/ORCtech/Tb2223.htm 3/21/2003 �0�WAf��0 / Michael F.Easley,Governor William G.Ross Jr.,Secretary 0 (� North Carolina Department of Environment and Natural Resources 0 r Alan W.Klimek P.E.Director —i I Division of Water Quality O Y Coleen H.Sullins,Deputy Director Division of Water Quality July 31, 2003 Mr. Mike Bell, Environmental Safety Coordinator Coats North America Post Office Box 670 Toccoa, GA 30577 Dear Mr. Bell: In accordance with the application received on June 16, 2003, we are forwarding Permit Number WI0100015 for the injection of an ORC slurry to enhance aerobic biodegradation of the dissolved vinyl chloride contamination at the Coats America Sylvan Plant, in Rosman,North Carolina. This permit shall be effective from the date of issuance until July 31, 2006, and shall be subject to the conditions and limitations stated therein, including the requirement to submit a final project evaluation as stated in PART VII-MONITORING AND REPORTING REQUIREMENTS. You will also need to notify this office by telephone 48 hours prior to initiation of injection at this facility. In order to continue uninterrupted legal use of this inj ectant for the stated purpose,you should submit an application to renew the permit three months prior to its expiration date.' If you have any questions regarding your permit please contact me at(919)715-6166 or Evan Kane at(919) 715-6165. Sincerely, 0j, Mark Pritzl Hydrogeological Technician UIC Program cc: J.Alan Pinnix,ARCAD IS,fax copy CO-UIC Files ARO-UIC Files Enclosures AMA NLDENR N.C.Division of Water Quality /Groundwater Section 1636 Mail Service Center,Raleigh,N.C. 27699-1636 ,Customer Service Phone: (919)733-3221 Fax: (919)715-0588 Internet: httpl/gw.ehncstate.nc.us I-877-623'6748 NORTH CAROLINA ENVIRONMENTAL MANAGEMENT COMMISSION DEPARTMENT OF ENVIRONMENT AND NATURAL RESOURCES RALEIGH,NORTH CAROLINA PERMIT FOR THE CONSTRUCTION AND OPERATION OF A WELL FOR INJECTION In accordance with the provisions of Article 7, Chapter 87; Article 21, Chapter 143, and other applicable Laws, Rules, and Regulations PERMISSION IS HEREBY GRANTED TO Coats North America FOR THE CONSTRUCTION AND OPERATION OF A TYPE 5I INJECTION WELL, defined in Title 15A North Carolina Administrative Code 2C .0209(e)(3)(C), for the injection of an ORC slurry to augment biodegradation of vinyl chloride dissolved in groundwater at this site. These injection wells will be located at Highway 178, in Rosman,North Carolina, and will be operated in accordance with the application received on June 16, 2003, and in conformity with the specifications and supporting data submitted, all of which are filed with the Department of Environment and Natural Resources and are considered a part of this permit. This permit is for Construction and Operation only, and does not waive any provisions of the Water Use Act or any other applicable Laws, Rules, or Regulations. Operation and use of an injection well shall be in compliance with Title 15A North Carolina Administrative Code 2C .0100 and .0200, and any other Laws,Rules, and Regulations pertaining to well construction and use. This permit shall be effective, unless revoked, from the date of its issuance until July 31, 2006, and shall be subject to the specified conditions and limitations set forth in Parts I through X hereof. Permit issued this the 36 day of 2003. Ted L. Bush, Jr., Assistant Chief Groundwater Section Division of Water Quality By Authority of the Environmental Management Commission. Permit No.WI0100015 PAGE 1 OF 6 ver.3101 GW/UIC-5 PART I-WELL CONSTRUCTION GENERAL CONDITIONS 1. The Permittee must comply with all conditions of this permit and with the standards and criteria specified in Criteria and Standards Applicable to Injection Wells (15A NCAC 2C .0200). Any noncompliance with conditions of this permit constitutes a violation of the North Carolina Well Construction Act and is grounds for enforcement action as provided for in N.C.G.S. 87-94. 2. This permit shall become voidable unless the facility is constructed in accordance with the conditions of this permit, the approved plans and specifications, and other supporting data. 3. Each injection well shall not hydraulically connect separate aquifers. 4. Each injection well shall be constructed in such a manner that water from land surface cannot migrate into the gravel pack or well screen. 5. Each injection well shall be secured to reasonably insure against unauthorized access and use. Each well shall be permanently labeled with a warning that it is for injection purposes and the entrance to each well must be secured with a locking cap. 6. Each injection well shall be afforded reasonable protection against damage during construction and use. 7. Each injection well shall have permanently affixed an identification plate. 8. A completed Well Construction Record(Form GW-1) must be submitted for each injection well to, DENR-Division of Water Quality, Groundwater Section UIC-Staff, 1636 Mail Service Center,Raleigh,NC 27699-1636,within 30 days of completion of well construction. PART H-WELL CONSTRUCTION SPECIAL CONDITIONS 1. At least forty-eight(48) hours prior to constructing each injection well, the Permittee shall notify the Groundwater Section-Underground Injection Control (UIC), Central Office staff, telephone number(919) 715-6166. PART III- OPERATION AND USE GENERAL CONDITIONS 1. This permit is effective only with respect to the nature, volume of materials and rate of injection, as described in the application and other supporting data. 2. This permit is not transferable without prior notice to, and approval by, the Director of the Division of Water Quality (Director). In the event there is a desire for the facility to change ownership, or there is a name change of the Permittee, a formal permit amendment request must be submitted to the Director, including any supporting:materials as may be appropriate, at least 30 days prior to the date of the change. i Permit No.WI0100015 PAGE 2 OF 6 ver.3/01 GW/UIC-5 3. The issuance of this permit shall not relieve the Permittee of the responsibility of complying with any and all statutes,rules, regulations, or ordinances which may be imposed by other local, state, and federal agencies which have jurisdiction. Furthermore, the issuance of this peimit does not imply that all regulatory requirements have been met. PART IV-PERFORMANCE STANDARDS 1. The injection facility shall be effectively maintained and operated at all times so that there is no contamination of groundwater which will render it unsatisfactory for normal use. In the event that the facility fails to perform satisfactorily, including the creation of nuisance conditions or failure of the injection zone to adequately assimilate the injected fluid,the Permittee shall take immediate corrective actions including those actions that may be required by the Division of Water Quality such as the repair, modification, or abandonment of the injection facility. 2. The Permittee shall be required to comply with the terms and conditions of this permit even if compliance requires a reduction or elimination of the permitted activity. 3. The issuance of this permit shall not relieve the Permittee of the responsibility for damages to surface or groundwater resulting from the operation of this facility. PART V- OPERATION AND MAINTENANCE REQUIREMENTS 1. The injection facility shall be properly maintained and operated at all times. 2. The Permittee must notify the Division and receive prior written approval from the Director of any planned physical alterations or additions in the permitted facility or activity not specifically authorized by the permit. 3. At least forty-eight(48) hours prior to the initiation of the operation of the facility for injection, the Permittee must notify by telephone the Groundwater Section-Underground Injection Control (UIC), Central Office staff, telephone number(919) 715-6166. Notification is required so.that Division staff can inspect or otherwise review the injection facility and determine if it is in compliance with permit conditions. PART VI-INSPECTIONS 1. Any duly authorized officer, employee, or representative of the Division of Water Quality may,upon presentation of credentials, enter and inspect any property, premises, or place on or related to the injection facility at any reasonable time for the purpose of determining compliance with this permit, may inspect or copy any records that must be maintained under the terms and conditions of this permit, and may obtain samples of groundwater, surface water, or injection fluids. Permit No.WI0100015 PAGE 3 OF 6 ver.3/01 GW/UIC-5 2. Department representatives shall have reasonable access for purposes of inspection, observation, and sampling associated with injection and any related facilities as provided for in N.C.G.S. 87-90. 3. Provisions shall be made for collecting any necessary and appropriate samples associated with the injection facility activities. PART VII -MONITORING AND REPORTING REQUIREMENTS 1. The proposed monitor plan included in the application received on June 16, 2003, and amended letter received on July 28, 2003, shall be followed and all sample results shall be submitted to the Groundwater Section's Asheville Regional Office and the Raleigh Central Office. Any monitoring(including groundwater, surface water, or soil sampling) deemed necessary by the Division of Water Quality to insure surface and ground water protection, will be established and an acceptable sampling reporting schedule shall be followed. 2. The Permittee shall produce a final project evaluation within 9 months after completing all injection-related activities associated with the permit application. This document shall assess the injection projects findings in a written summary. The final project evaluation shall also include all monitoring well sampling data, the contaminant plume maps and the potentiometric surface maps. 3. The final project evaluation shall be submitted to the Underground Injection Control Program, Groundwater Section,NC DENR-Division of Water Quality, 1636 Mail Service Center, Raleigh,NC 27699-1636 and to the Groundwater Section, Asheville Regional Office, Interchange Building, 59 Woodfrn Place, Asheville,NC 28801. 4. The Permittee shall report by telephone, within 48 hours of the occurrence or first knowledge of the occurrence,to the Asheville Regional Office, telephone number(828) 251-6208, any of the following: (A) Any occurrence at the injection facility which results in any unusual operating circumstances; (B) Any failure due to known or unknown reasons, that renders the facility incapable of proper injection operations, such as mechanical or electrical failures. 5. Where the Permittee becomes aware of an omission of any relevant facts in a permit application, or of any incorrect information submitted in said application or in any report to the Director,the relevant and correct facts or information shall be promptly submitted to the Director by the Permittee. 6. In the event that the permitted facility fails to perform satisfactorily,the Permittee shall take such immediate action as may be required by the Director. Permit No.WI0100015 PAGE 4 OF 6 vec3/01 GW/UIC-5 PART VIH-PERMIT RENEWAL The Permittee shall, at least three (3) months prior to the expiration of this permit, request an extension.' PART IX- CHANGE OF WELL STATUS 1. The Permittee shall provide written notification within 15 days of any change of status of an injection well. Such a change would include the discontinued use of a well for injection. If a well is taken completely out of service temporarily, the Permittee must install a sanitary seal. If a well is not to be used for any purpose that well must be permanently abandoned according to 15A NCAC 2C .0213(h)(1), Well Construction Standards. 2. When operations have ceased at the facility and a well will no longer be used for any purpose, the Permittec shall abandon that injection well in accordance with the procedures specified in 15A NCAC 2C .0214, including but not limited to the following: (A) All casing and materials may be removed prior to initiation of abandonment procedures if the Director finds such removal will not be responsible for, or contribute to, the contamination of an underground source of drinking water. (B) The entire depth of each well shall be sounded before it is sealed to insure freedom from obstructions that may interfere with sealing operations. (C) The well shall be thoroughly disinfected,prior to sealing, if the Director determines that failure to do so could lead to the contamination of an underground source of drinking water. (D) Drilled wells shall be completely filled with cement grout,which shall be introduced into the well through a pipe which extends to the bottom of the well and is raised as the well is filled. (E) In the case of gravel-packed wells in which the casing and screens have not been removed,neat-cement shall be injected into the well completely filling it from the bottom of the casing to the top. (F) In those cases when, as a result of the injection operations, a subsurface cavity has been created, each well shall be abandoried in such a manner that will prevent the movement of fluids into or between underground sources of drinking water and in accordance with the terms and conditions of the permit. (G) The Permittee shall submit a Well Abandonment Record (Form GW-30) as specified in 15A NCAC 2C .0213(h)(1) within j0 days of completion of abandonment. Permit No.WI0100015 PAGE 5 OF 6 ver.3/01 GW/UIC-5 3. The written documentation required in Part IX(1) and(2) (G) shall be submitted to: Groundwater Section-UIC Staff DENR-Division of Water Quality 1636 Mail Service Center Raleigh,NC 27699-1636 PART X—WORKER PRECAUTIONS DURING APPLICATION 1. Some effects reported to be associated with the product proposed to be used are as follows: eye, skin,nose, throat and lung irritation. If the product is released into the environment in a way that could result in a suspension of fine solid or liquid particles (e.g., grinding, blending, vigorous shaking or mixing), then proper personal protective equipment should be used. The application process should be reviewed by an industrial hygienist to ensure that the most appropriate personal protective equipment is used. 2. Persons working with these products should wear goggles or a face shield, gloves, and protective clothing. Face and body protection should be used for anticipated splashes or sprays. 3. Eating, drinking, smoking, handling contact lenses, and applying cosmetics should not be permitted in the application area during or immediately following application. 4. Safety controls should be in place to ensure that the check valve and the pressure delivery systems are.working properly. 5. The Material Safety Data Sheets should be followed to prevent incompatible or adverse reactions and injuries. i { I Permit No.WI0100015 PAGE 6 OF 6 ver.3101 GW/UIC-5 FILE COTY DIVISION OF WATER QUALITY GROUNDWATER SECTION ASHEVILLE REGIONAL OFFICE MEMORANDUM: TO: Mark Pritzl Central Office THROUGH: Landon David FROM: Kay Dechant 1�e SUBJECT: UIC Pre-Construction Inspection Coats American Sylvan Plant Groundwater Incident 5537 DATE: July 15, 2003 This office has reviewed the subject UIC permit application and completed the Preconstruction Injection Facility Inspection. Attached is Report Form-A. Issuance of the permit is recommended. If you have any comments or questions, please contact me at(828) 251-6208. — t Page I of 2 North Caruhiiia Department of Environment anti iY`utural Resources Division of Water Quality ! Groundwater Section I c PRECONSTRUCTION INJECTION FACILITY INSPECTION REPORT-FORM A INJECTION WELL PERMIT NO. WI DATE NAME OF OWNER /yl,�� p�/�• (_dq/S 1604 ADDRESS OF O-vN-.NER A /o,< 4M Teccam Gfit 30 ,� (Streed road or lot and subdivision,county,town) LOCATION OF PROPOSED INJECTION WELL (and source well(s), if applicable) tffe a 6 � (Streed road or 16t and subdivision, county,town, iirdierent than owner's address,plus description ojlocation on site) Potential pollution source / Distance from well V'4 Potential pollution source Distance from-well Al-4- Potential pollution source Distance from well Minimum distance of proposed well from property boundary %S Quality of drainage at site, f� Flooding potential of site Igood.u, yuate.po"p (bigh.macerate.lowt s DRAW SKETCH OF SITE (Shaw property boundaries. buildings. .,ells.po%ential poifaior sources. reads,approrinla:e sce/r. and norfh arrow.) ^ /tntli= Wr sit-€ / cn \ UN al661� a 0 RU \ I V Ver.3/01 G W-'UIC-1 Page 2 of 2 PRECONSTRUCTION INJECTION FACILITY INSPECTION REPORT - FORM A (cont.) GPS Data: Latitude: 33 (z��,� � , r! Longitude: sj,26 4e 42j�1rR/� COMMENTS INSPECTOR Office WITNESS Address WITNESS ✓ tom Address I Ver.J!O I GWr2IIC-I i DIVISION OF WATER QUALITY , GROUNDWATER SECTION ASHEVILLE REGIONAL OFFICE MEMORANDUM: TO: Mark Pritzl Central Office THROUGH: Landon Davidson FROM: Kay Dechant SUBJECT: UIC Pre-Construction Inspection Coats American Sylvan Plant Groundwater Incident 5537 DATE: July 15, 2003 This office has reviewed the subject UIC permit application and completed the Preconstruction Injection Facility Inspection. Attached is Report Form-A. Issuance of the permit is recommended. If you have any comments or questions,please contact me at (828) 251-6208. i I .- I / Page 1 of 2 — t North Carolina Department of Environment and Natural Resources. Division of Water Quality i Groundwater Section PRECONSTRUCTION INJECTION FACILITY INSPECTION REPORT-FORM A INJECTION WELL PER-MIT G/ NO. Wl DATE / NA.-*IE OF OWNER /yJ,ri� Al ts /(/w, L,do Ar,6C4 ADDRESS OF OWNER & Add �D Toccoa. , 6 ,3oS,�7 (Street/road or lot and subdivision, county, town) LOCATION,,cOF PROPOSED INJECTION WELL (and source well(s), if applicable) laf�SiH�w tSireeri road o r, t and subdivision , county, tmtw,iifdifj-erent than owner's address,plus description of location on site) °clential poih:cion scn- _ Z d Distance moo^ T' potential r)oliu or. Q/ Q � D15m^.Ce Ir0': rf off Potential pollution source Distance from %cell i Minimum distance of proposed well from property boundary /S Quality of drainage ai site Flooding potential of site DRAW SKETCH OF SITE • e A"-y a - ,Mav i i e.._ . . G1d' 1:i i i 3r'1'n 4 Page 2 of 2 a , PRECONSTRUCTION INJECTION FACILITY INSPECTION REPORT -' FORM A (conL) GPS Data: 6 Latitude:_ Longitude: 6 /r COi UMENTS INSPECTOR Office WITNESS :address WIT\-ESS kddr s; — U GV L iC i �OF W ATF90 _ I Michael F.Easley,Governor William G.Ross Jr.,Secretary \� G North Carolina Department of Environment and Natural Resources rAlan W.Klimek,P.E.Director -� Division of Water Quality O C Coleen H.Sullins,Deputy Director Division of Water Quality I June 17, 2003 Mr. Mike Bell, Environmental Safety Coordinator Coats North America Post Office Box 670 Toccoa, GA 30577 Dear Mr. Bell: Your application for a permit to construct and/or use injection wells for the injection of an ORC slurry to enhance aerobic biodegradation of the dissolved vinyl chloride contamination in groundwater at Coats American Sylvan Plant, on.Highway 178 in Rosman,North Carolina has been received and is currently under review. A member of the Groundwater Section's Asheville Regional Office staff will be contacting you to arrange an inspection of the injection site as part of the review. If you have any questions regarding the permit or injection well rules please contact me at (919) 715-6166. Sincerely, Mark Pritzl Hydrogeological Technician UIC Program cc: CO-UIC Files ARO-UIC Files E,4 N.C.Division of Water Quality /Groundwater Section 1 1636 Mail Service Center Raleigh,N.C. 27699.1636 FIU58'77-623-6748 omer Service Phone: (919)733-3221 Fax: (919)715-0588 Internet: hupl/gw.ehncstate.nc.us