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HomeMy WebLinkAboutWQ0011431_Residual Annual Report 2021_20220301 Non-Discharge Branch Upload/Submittal Form NORTH CAROLINA Enriry mmful Quoity Version 2-Revised June 23,2020 Initial Review Reviewer Thornburg,Nathaniel D Is this submittal an application?(Excluding additional information.)* Yes No If not an application what is the submittal type?* Annual Report Residual Annual Report Additional Information Other Annual Report Year* 2021 Permit Number(IR)* WQ0011431 Applicant/Permittee Town of Cleveland Email Notifications Does this need review by the hydrogeologist?* ( Yes • No Regional Office Mooresville CO Reviewer Admin Reviewer Submittal Form Project Contact Information Please provide information on the person to be contacted by NDB Staff regarding electronic submittal,confirmation of receipt,and other correspondence. ............................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................ Name* Denise Harrison Email Address* Phone Number* biogreensvc@aol.com 336-978-0042 Project Information Application/Document Type* New(Fee Required) Modification-Minor Modification-Major(Fee Required) Renewal Renewal with Major Modification(Fee GW-59, NDMR,NDMLR, NDAR-1, Required) NDAR-2 Annual Report Residual Annual Report Additional Information Change of Ownership Other We no longer accept these monitoring reports through this portal. Please click on the link below and it will take you to the correct form. https://edocs.deq.nc.gov/Forms/NonDischarge_Monitoring_Report Permit Type:* Wastewater Irrigation High-Rate Infiltration Other Wastewater Reclaimed Water Closed-Loop Recycle Residuals Single-Family Residence Wastewater Other Irrigation Permit Number:* WQ0011431 Has Current Existing permit number Applicant/Permittee Address* Post Office Box 429;Cleveland,NC 27013 Facility Name* Town of Cleveland Class B Residuals Program Please provide comments/notes on your current submittal below. Town of Cleveland 2021 Class B Annual Report At this time,paper copies are no longer required.If you have any questions about what is required,please contact Nathaniel Thornburg at nathaniel.thornburg@ncdenr.gov. Please attach all information required or requested for this submittal to be reviewed here.* (Application Form,Engineering Plans,Specifications,Calculations,Etc.) 2021 Class B Annual Report-WQ0011431-Town of 4.63MB Cleveland.pdf Upload only 1 PDF document(less than 250 MB).Multiple documents must be combined into one PDF file unless file is larger than upload limit. * By checking this box, I acknowledge that I understand the application will not be accepted for pre-review until the fee(if required)has been received by the Non- Discharge Branch.Application fees must be submitted by check or money order and made payable to the North Carolina Department of Environmental Quality(NCDEQ). I also confirm that the uploaded document is a single PDF with all parts of the application in correct order(as specified by the application). Mail payment to: NCDEQ—Division of Water Resources Attn:Non-Discharge Branch 1617 Mail Service Center Raleigh,NC 27699-1617 Signature his Submission Date 3/1/2022 2021 ANNUAL REPORT LAND APPLICATION PROGRAM TOWN OF CLEVELAND PERMIT #WQ0011431 Compiled By: Bio-Green Services, Inc. 383 Potts Road Advance, NC 27006 January 2022 Bio-green Services,Inc. 377 Potts Road Advance,NC 27006 336-940-4544 NC PERMIT#WQ0011431 LAND APPLIERS: Bio-Green Services,Inc. 383 Potts Road Advance,North Carolina 27006 2021 Town of Cleveland Total Dry Tons 10.16 2021 Town of Cleveland Total Metric Tons 9.21512 January 1, 2022 NCDENR-DWR 512 N Salisbury St 9th Floor, Office #942X Raleigh, NC 27604 Attention: Information Processing Unit Reference: 2021 LAND APPLICATION ANNUAL REPORT Town of Cleveland Permit No. WQ0011431 Non-Discharge Compliance Unit: Bio-Green Services, Inc. (Bio-Green) is submitting all monitoring and reporting requirements as specified in the above referenced permit. Bio-Green compiled this report using data gathered during the compliance year by Bio-Green and The Town of Cleveland. This data includes: I Annual Land Application Certification Form Form ACF II Annual Residual Sampling Summary Form Form RSSF III Annual Land Application Field Summary Form Form FSF IV Metals Field Loading Summary Form V Lab Sheets (Analytical Data) VI Annual Pathogen and Vector Reduction Forms VII Soil Analysis If there is any further information required or questions regarding this annual report, please do not hesitate to contact Bio-Green for further assistance. Sincerely, Ade Ray Gambill NC Land Application/Residuals Operator TABLE OF CONTENTS SECTION NO. TITLE I Annual Land Application Certification Form Form ACF II Annual Residual Sampling Summary Form Form RSSF III Annual Land Application Field Summary Form Form FSF IV Metals Field Loading Summary Form V Lab Sheets (Analytical Data) VI Annual Pathogen and Vector Reduction Forms VII Soil Analysis ANNUAL LAND APPLICATION CERTIFICATION FORM ANNUAL LAND APPLICATION CERTIFICATION FORM WQ Permit#: WQ0011431 County: Rowan v Year: 2021 Facility Name(as shown on permit): Town of Cleveland Land Application Operator: Bio-Green Services,Inc. Phone: 336-813-8063 Land application of residuals as allowed by the permit occurred during the past calendar year? CI Yes ❑ No -If No,skip Part A,and Part B and proceed to Part C. Also,If residuals were generated but not land applied,please attach an explanation on how the residuals were handled. Part A-Residuals Application Summary: Total number of application fields in the permit: 1 Total number of fields utilized for land application during the year: Total amount of dry tons applied during the year for all application sites: 10.17 Total number of acres utilizes for land application during the year: 10 Part B-Annual Compiance Statement: Facility was compliant during calendar year 2021 with all conditions of the land application permit (including but not limited to items 1-13 below)issued by the Division of Water Resources. El Yes ❑ No If no please,provide a written description why the facility was not compliant,the dates,and explain corrective action taken. 1) Only residuals approved for this permit were applied to the permitted sites. 2) Soil pH was adjusted as specified in the permit and lime was applied(if needed)to achieve a soil pH of at least 6.0 or the limit specified in the permit. 3) Annual soils analysis were performed on each site receiving residuals during the past calendar year and three(3)copies of laboratory results are attached. 4) Annual TCLP analysis(if required)was performed and three(3)copies of certified laboratory results are attached. 5) All other monitoring was performed in accordance with the permit and reported during the year as required and three (3)copies of certified laboratory results are attached. 6) The facility did not exceed any of the Pollutant Concentration Limits in 15A NCAC 02T.1105(a)or the Pollutant Loading Rates in 15A NCAC 02T .1105(b)(applicable to 40 CFR Part 503 regulated facilities).. 7) All general requirements in as specified in the Land Application Permit were complied with(applicable to 40 CFR Part 503 regulated facilities). 8) All monitoring and reporting requirements in 15A NCAC 02T.1111 were complied with(applicable to 40 CFR Part 503 regulated facilities). 9) All operations and maintenance requirements in the permit were complied with or, in the case of a deviation, prior authorization was received from the Division of Water Resources. 10) No contravention of Ground Water Quality Standards occurred at a monitoring well or explanations of violations are attached to include appropriate actions and remediations. 11) Vegetative cover was maintained and proper crop management was performed on each site receing residuals,as specified in the permit. 12) No runoff of residuals from the application sites onto adjacent property or nearby surface waters has occurred. 13) All buffer requirements as specified on the permit were maintained during each application of residuals. Part C-Certification: "I certify,under penalty of law,that the above information is, to the best of my knowledge and belief,true,accurate, and complete.I am aware that there are significant penalties for submitting false information,including the possibility of fines and imprisonment for knowing violations." Patrick Phifer, Mayor 2/18/22 Permittee Name and Title(type or print) Signature of Pe ittee Date 4 ,., 3/1/22 Signature of Preparer* Date Signature of Land Applier Date (if different from Permittee) (if different from Permittee and Preparer) * Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 02T.1102(26) DENR FORM ACF (12/2006) ANNUAL RESIDUAL SAMPLING SUMMARY FORM ANNUAL RESIDUAL SAMPLING SUMMARY FORM Please note that your permit may contain additional parameters to be analyzed. The parameters can be reported in FORM RSSF - B WQ Permit Number: WQ0011431 Laboratory: 1) Environmental Chemists Inc. Facility Name: Town of Cleveland 2) Residual Source�WQ # oru NC0049867 3) N�3DES #: 4) WWTP Name: Cleveland WWTP 5) Residual Analysis Data Conc. Sample or Composite Date Parameter Limit (mg/kg) (mg/kg)`' 4/6/21 Percent Solids (%) NA 1 .47 r ' " Arsenic 75 16.9 Cadmium 85 16.9 Copper 4,300 504 1 Chromium NA 28.9 Lead 840 16.9 Mercury 57 1 .03 - Molybdenum 75 16.9 Nickel 420 19.5 Selenium 100 16.9 Zinc 7.500 898 Total Phosphorus NA 40100 r TKN NA 71600 Am I monia-Nitrogen NA 982 Nitrate and Nitrite NA 5.34 a For surface disposal facilities the ceiling concentration limits listed in this form are not applicable. Reference the individual permit for metals limits. "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties foci su mitt false information, including the possibility of fines and imprisonment for knowing violations." r 4�� 7- " 0 //"E /20-22 Signature of Preparer * Date *Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26) nF? 1P FnRM Rc�r= pa)r')nr:r\ ANNUAL RESIDUAL SAMPLING SUMMARY FORM - B Report all sampling analysis results for parameters not listed in FORM RSSF that are part of the WQ permit or were analyzed for over the past calendar year. Use additional forms as needed. WQ Permit Number: WQ0011431 Laboratory: 1) Environmental Chemists Inc. Facility Name: Town of Cleveland 2) Residual Source NC0049867 3) NPDES # or WQ#: 4) WWTP Name: Cleveland WWTP 5) Residual Analysis Data Sample or Composite Date Parameter (mg/kg) 3/9/2 I Aluminum 26900 Calcium 28200 T Magnesium 2660 pH 6.54 Potassium 4030 Sodium 12700 SAR 2.34 PAN 43.3635 • -. _...._ h- I "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." Signature of Preparer * Date *Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T . 1102 (26) DENR FORM RSSF - B (12/2006) ANNUAL LAND APPLICATION SUMMARY FORM ANNUAL LAND APPLICATION FIELD SUMMARY FORM PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE. Facility Name: Town of Cleveland WQ Permit #: WQ0011431 Field #: 1 Acres Utilized: 10 Land Owner: Town of Cleveland Annual Dry Tons Applied: 10. 1669 Site #: NC-RA-01 Acres Permitted: 10 Operator: Same _ Predominant Soil Series: Enon Cation Exchange Capacity (non 503): Crop I Name: Fescue Crop 1 Max. PAN: 188 Crop 2 Name: Fescue Crop 2 Max. PAN: ' r Soil Volume applied Volume Residual Sources Precip. > o z Nitrate Name of Crop Type ° (enterone) % Appliedper Cond. ;a m w PAN Applied ° Solids/ pp (NPDES # WQ# Past 24 ••D .. pp w TKN o and Receiving Residual ° Liquid Solids Acre Fert. Animal lDry' firs. o Ev' °° Ibs/acre n Wet, r�. �. . w * �, Nitrite ( ) Application Cu. Yds Gallons Waste, etc) Moist) °� mg/kgmg/kg mg/kg Crop1 Crop2 CropI Crop2 (Dry �onsJAc) inches a o 9 9 9 9 0.000 i 0.000 0.000 - 0.000 0.000 0.000 0.000 Mill 0.000 0.000 0.000 0.000 0.000 May 76500 1.47 0.469 7'OC Dry 0 S 0.5 1.3 71600 982 5.34 20.335 NA Fescue 0.000 0.000 0.000 0.000 0.000 0.000 0.000 I 0.000 0.000 Sep 45000 1.47 0.276 TOC Dry 0 S 0.5 0.3 71600 982 5.34 11.962 NA Fescue Oct 40500 1.47 0.248 TOC Dry 0 S 0.5 t • : Fescue 0.000 1 tttt ttt w 0.000 0.000 0.000 Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp to this form): TOTALS: 01 162000 As Cd Cu Cr Pb I Hg I Mo Ni Se Zn ( P 43.062 0.000 Lime Applied Annual lbs/acre 0.034 0.034 1.001 0.057 0.034 0.002 0.034 0.039 0.034 1.783 j 79.639 Date 1 lbs/ac Prior Years Cumulative lbs/ac 0.018 5.491 22. 15 0.023 0.026 0.525 0.606 0.011 51.663 Current Cumulative Ibs/ac 0.052 5.525 23.151 0.057 0.057 0.028 0.559 0.645 0.045 53.446 Permitted C. P. L. R.**** 36 34 1338 na 267 15 na 374 89 2498 Permit PAN Limit 1st/2nd Crop I 188 I l "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." A 09 47-r,%-e-w *Application Method: S - Surface, IN - Injection, INC - Incorporation 2/2//22 **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0 Signature of Land Applier Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2, aerobically digested -0.3, raw sludge -0.4 ****C.P.L.R.: Cumulative Pollutant Loading Rate DENR FORM FSF (12/2006) ANNUAL METALS FIELD LOADING SUMMARY FORM ANNUAL METALS FIELD LOADING SUMMARY FORM* Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Facility Name: Town of Cleveland Total Dry Tons Applied(Annual): 10.16 Permit#: WQ0011431 Cation Exchange Capacity(non 503 only): Operator: Bio-Green Services,Inc. Owner: Town of Cleveland Predominant Soil Series: Enon Acres Used: 10 Acres Permitted: 10 Site#: NC-RA-01 Field#: I Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg,%Solids use Raw Percent#): Sample or,.1 I 2•. 3; 4 i 5 1 6 j 7 8. 91 hO 1 11 12. Com- posite Date 4/6/21 4/6/21 4/6/21 %Solids 1.47 1.47 1.47 Arsenic 16.9 16.9 16.9 Cadmium 16.9 16.9 16.9 Copper 504 504 504 Chromium 28.9 28.9 28.9 Lead 16.9 16.9 16.9 Mercury 1.03 1.03 1.03 Molyb- denum 16.9 16.9 16.9 Nickel 19.5 19.5 19.5 Selenium 16.9 16.9 16.9 Zinc 898 898 898 Total Phos- 40100 40100 40100 phorus Annual Heavy Metal Field Loadings(Calculated in lbs/acre): Total 1 ; 2 -3; 4 5 6 7j 8; J 10 11 12 DT/AcJ App. Event 0.47 0.28 0.25 Arsenic 0.000 0.000 0.000 0.000 0.016 0.000 0.000 0.000 0.009 0.008 0.000 0.000 0.034 Cadmium 0.000 0.000 0.000 0.000 0.016 0.000 0.000 0.000 0.009 0.008 0.000 0.000 0.034 Copper 0.000 0.000 0.000 0.000 0.473 0.000 0.000 0.000 0.278 0.250 0.000 0.000 1.001 Chromium 0.000 0.000 0.000 0.000 0.027 0.000 0.000 0.000 0.016 0.014 0.000 0.000 0.057 Lead 0.000 0.000 0.000 0.000 0.016 0.000 0.000 0.000 0.009 0.008 0.000 0.000 0.034 Mercury 0.000 0.000 0.000 0.000 0.001 0.000 0.000 0.000 0.001 0.001 0.000 0.000 0.002 Molyb 0.000 0.000 0.000 0.000 0.016 0.000 0.000 0.000 0.009 0.008 0.000 0.000 0.034 denum Nickel 0.000 0.000 0.000 0.000 0.018 0.000 0.000 0.000 0.011 0.010 - 0.000 0.000 0.039 Selenium 0.000 0.000 0.000 0.000 0.016 0.000 0.000 0.000 0.009 0.008 0.000 0.000 0.034 Zinc 0.000 0.000 0.000 0.000 0.842 0.000 0.000 0.000 0.496 0.445 0.000 0.000 1.783 Total Phos- 0.000 0.000 0.000 0.000 37.614 0.000 0.000 0.000 22.135 19.890 0.000 0.000 79.639 phorus "I certify,under penalty of law,that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information,including the possibility of fines and imprisonment for knowing violations". iket9zirj (- Signature of Land Applier Date DENR FORM MFLSF(12/2006) LAB SHEETS CLEVELAND WWTP LAND APPLICATION PROGRAM RESIDUALS ANALYSIS Residual Type: Wastewater Treatment Plant Date Sampled: March 9,2021 Date Reported: April 6,2021 Cleveland WWTP Permit No.WQ0011431 Mineralization Rate 0.3 1.47 %Solids 6.54 pH Parameter % Mg/Kg Dry Weight Pounds/Dry Ton (%x 10,000) (Mg/Kg x 0.002) Nitrogen(TKN) 7.160 71,600.000 143.200 Phosphorus 4.010 40,100.000 80.200 Potassium 0.403 4,030.000 8.060 PAN(injected)* 2.217 22,172.740 44.345 PAN(surface)* 2.168 21,681.740 43.363 Ammonia Nitrogen 0.098 982.000 1.964 Calcium 2.820 28,200.000 56.400 Calcium Carbonate Eq. --- --- --- Magnesium --- 2,660.000 5.320 Sodium --- 12,700.000 25.400 Sulfur --- --- Nitrate N/Nitrite N --- 5.340 0.011 Barium --- --- --- SAR Chloride --- --- --- _ 2.34 Iron --- --- --- Ceiling Concen. Aluminum --- 26,900.00 53.800 (Mg/Kg) Arsenic --- 16.900 --- 75 Cadmium --- 16.900 0.034 85 Chromium --- 28.900 --- -- Copper --- 504.00 1.008 4,300 Lead --- 16.900 0.034 840 Mercury --- 1.030 --- 57 Molybdenum --- 16.900 --- 75 Nickel --- 19,50 0.039 420 Selenium --- 16.900 --- 100 Zinc --- 898.00 1.796 7,500 Envirochem 2021-03907 *Determination of Plant Available Nitrogen(PAN): Injected Application: (Mineralization Rate)(TKN-Ammonia N)+Ammonia N+Nitrate N+Nitrite N=%PAN Surface Application: (Mineralization Rate)(TKN-Ammonia N)+(0.5)(Ammonia N)+Nitrate N+Nitrite N=%PAN Note: Constituents N.D.(Not Detected)or<detection limits arc listed as detection limits for calculation purposes. Town of Cleveland Non-Discharge Permit No. W00011431 2021 Sample Date Fecal Coliform Log MPN/gram dry weight 03/09/21 1,608 3.21 03/09/21 11,380 4.06 03/09/21 3,901 3.59 03/09/21 1,915 3.28 _ 03/09/21 2,868 3.46 03/09/21 5,604 3.75 03/09/21 7,591 3.88 Total 25.22 Average 3.60 Geometric Mean 4,010 Fecal Coliform-MPN/gram dry weight Geometric Mean of Less than 2,000,000 mets Class B -Alternative 1 Pathogen Reduction TOC 2021 Fecals Page 1 Environmental Chemists, Inc. envirochem 6602 Windmill Way,Wilmington,NC 28405 • 910.392.0223 Lab • 910.392.4424 Fax 710 Bowsertown Road,Manteo,NC 27954 • 252.473.5702 Lab/Fax 255-A Wilmington Highway,Jacksonville,NC 28540 • 910.347.5843 Lab/Fax ANALYTICAL&CONSULTING CHEMISTS info a environmentalchemis(s.com Bio-Green Services,Inc Date of Report: Apr 06, 2021 383 Potts Road Customer PO#: Advance NC 27006 Customer ID: 21030012 Attention: Ray Gambill Report#: 2021-03907 Project ID: Town of Cleveland Lab ID Sample ID: Collect Date/Time Matrix Sampled by 21-09532 Site: Sample 001 3/9/2021 6:00 AM Solid/Sludge Client Test Method Results Date Analyzed Totai Solids(%) SM 2540 B 2.80% 03/09/2021 Fecal Density SM 9221C E MPN 24 hr 503 1608 MPN/g 03/09/2021 Lab ID Sample ID: Collect Date/Time Matrix Sampled by 21-09533 Site: Sample 002 3/9/2021 6:00 AM Solid/Sludge Client Test Method Results Date Analyzed Total Solids(%) SM 2540 B 2.90% 03/09/2021 Fecal Density SM 0221C E MPN 24 hr 503 11380 M PN/g 03/09/2021 Lab ID Sample ID: Collect Date/Time Matrix Sampled by 21-09534 Site: Sample 003 3/9/2021 6:00 AM Solid/Sludge Client Test Method Results Date Analyzed Total Solids (%) SM 2540 B 2.82% 03/09/2021 Fecal Density SM 9221C E MPN 24 hr 503 3901 MPN/g 03/09/2021 Lab ID Sample ID: Collect Date/Time Matrix Sampled by 21-09535 Site: Sample 004 3/9/2021 6:00 AM Solid/Sludge Client Test Method Results Date Analyzed Total Solids (%) SM 2540 B 2.35% 03/09/2021 Fecal Density SM 9221C E MPN 24 hr 503 1915 MPN/g 03/09/2021 Lab ID Sample ID: Collect Date/Time Matrix Sampled by 21-09536 Site: Sample 005 3/9/2021 6:00 AM Solid/Sludge Client Test Method Results Date Analyzed Total Solids(%) SM 2540 B 2.72% 03/09/2021 Fecal Density SM 9221C E MPN 24 hr 503 2868 MPN/g 03/09/2021 Report#:: 2021-03907 Page 1 of 5 Environmental Chemists, Inc. envirochenl 6602 Windmill Way,Wilmington,NC 28405 • 910.392.0223 Lab • 910.392.4424 Fax 710 Bowsertown Road,Manteo,NC 27954 • 252.473.5702 Lab/Fax 255-A Wilmington Highway,Jacksonville,NC 28540 • 910.347.5843 Lab/Fax ANALYTICAL&CONSULTING CHEMISTS info@environmentalchemists.com Bio-Green Services, Inc Date of Report: Apr 06, 2021 383 Potts Road Customer PO#: Advance NC 27006 Customer ID: 21030012 Attention: Ray Gambill Report#: 2021-03907 Project ID: Town of Cleveland Lab ID Sample ID: Collect Date/Time Matrix Sampled by 21-09537 Site:Sample 006 3/9/2021 6:00 AM Solid/Sludge Client Test Method Results Date Analyzed Total Solids(%) SM 2540 B 2.32% 03/09/2021 Fecal Density SM 9221C E MPN 24 hr 503 5604 MPN/g 03/09/2021 Lab ID Sample ID: Collect Date/Time Matrix Sampled by 21-09538 Site: Sample 007 3/9/2021 6:00 AM Solid/Sludge Client Test Method Results Date Analyzed Total Solids (%) SM 2540 B 3.03% 03/09/2021 Fecal Density SM 9221C E MPN 24 hr 503 7591 MPN/g 03/09/2021 Report# 2021.03907 Page 2 of 5 Environmental Chemists, Inc. envirocheni 6602 Windmill Way,Wilmington,NC 28405 • 910.392.0223 Lab • 910.392.4424 Fax 710 Bowsertown Road,Manteo,NC 27954 • 252.473.5702 Lab/Fax sn 255-A Wilmington Highway,Jacksonville,NC 28540 • 910.347.5843 Lab/Fax ANALYTICAL&CONSULTING CHEMISTS info r@environnientalchetnists.com Bio-Green Services,Inc Date of Report: Apr 06, 2021 383 Potts Road Customer PO#: Advance NC 27006 Customer ID: 21030012 Attention: Ray Gambill Report#: 2021-03907 Project ID: Town of Cleveland Lab ID Sample ID: Collect DatelTime Matrix Sampled by 21-09794 Site: Sludge 3/9/2021 6:00 AM Solid/Sludge Client Test Method Results Date Analyzed Chlordane(TCLP) SW 846 Method 80131B/3510 <0.02 mg/L 03/22/2021 Endrin (TCLP) SW 848 Method 8081B/3510 <0.0005 mg/L 03/22/2021 Heptachlor(TCLP) SW 846 Method 8081B/3510 <0.0005 mg/L 03/22/2021 Heptachlor epoxide(TCLP) SW 848 Method 8081B/3510 <0.0005 mg/L 03/22/2021 Lindane(TCLP) SW 846 Method 8001B/3510 <0.0005 mg/L 03/22/2021 Methoxychlor(TCLP) SW 846 Method 8081B/3510 <0.0005 mg/L 03/22/2021 Toxaphene(TCLP) SW 846 Method 80816/3510 <0.05 mg/L 03/22/2021 1,4-Dichlorobenzene(TCLP) SW 848 method 8270/3510 <0.050 mg/L 03/19/2021 2,4,5-Trichlorophenol(TCLP) SW 846 method 8270/3510 <0.050 mg/L 03/19/2021 2,4,6-Trichlorophenol (TCLP) SW 846 method 8270/3510 <0.050 mg/L 03/19/2021 2,4-Dinitrotoluene(TCLP) SW 846 method 8270/3510 <0.050 mg/L 03/19/2021 Cresol(TCLP) SW 846 method B270/3510 0.113 mg/L 03/19/2021 Hexachloro-1,3-butadiene(TCLP) SW 846 method 8270/3510 <0.050 mg/L 03/19/2021 Hexachlorobenzene(TCLP) SW 846 method 8270/3510 <0.050 mg/L 03/19/2021 Hexachioroethane(TCLP) SW 846 method 8270/3510 <0.050 mg/L 03/19/2021 m +p-Cresol (TCLP) SW 846 method 8270/3510 0.113 mg/L 03/19/2021 Nitrobenzene(TCLP) SW 846 method 8270/3510 <0.050 mg/L 03/19/2021 o-Cresol(TCLP) SW 846 method 8270/3510 <0.050 mg/L 03/19/2021 Pentachlorophenol(TCLP) SW 846 method 8270/3510 <0.250 mg/L 03/19/2021 Pyridine (TCLP) SW 846 method 8270/3510 <0.050 mg/L 03/19/2021 2,4,5-TP (TCLP) SW846 Method 8151A <0.003 mg/L 03/18/2021 2,4-D(TCLP) SW846 Method 8151A <0.003 mg/L 03/18/2021 1,1-Dichloroethylene (TCLP) SW846 Method 8260/5030 <0.01 mg/L 03/19/2021 1,2-Dichloroethane(TCLP) SW846 Method 8260/5030 <0,01 mg/L 03/19/2021 Benzene(TCLP) SW846 Method 8280/5030 <0.01 mg/L 03/19/2021 Carbon Tetrachloride(TCLP) SW846 Method 8260/5030 <0.01 mg/L 03/19/2021 Report#. 2021-03907 Page 3 of 5 Environmental Chemists, Inc. envirochem 6602 Windmill Way,Wilmington,NC 28405 0 910.392.0223 Lab • 910.392.4424 Fax 710 Bowsertown Road,Manteo,NC 27954 • 252.473.5702 Lab/Fax 255-A Wilmington Highway,Jacksonville,NC 28540 • 910.347.5843 Lab/Fax ANALYTICAL&CONSULTING CHEMISTS info@environmentalchemists.com Bio-Green Services,Inc Date of Report: Apr 06, 2021 383 Potts Road Customer PO#: Advance NC 27006 Customer ID: 21030012 Attention: Ray Gambill Report#: 2021-03907 Project ID: Town of Cleveland Chlorobenzene (TCLP) SWB48 Method 8260/5030 <0.01 mg/L 03/19/2021 Chloroform(TCLP) SW846 Method 8260/5030 <0.01 mg/L 03/19/2021 Methyl ethyl ketone(TCLP) SW846 Method 8260/5030 <0.05 mg/L 03/19/2021 Tetrachloroethylene(TCLP) SW846 Method 8260/5030 <0.01 mg/L 03/19/2021 Trichloroethylene(TCLP) SW846 Method 8260/5030 <0.01 mg/L 03/19/2021 Vinyl Chloride(TCLP) SW846 Method 8260/5030 <0.01 mglL 03/19/2021 RCI Cyanide SM 4500 CND 1.10 mg/kg 03/11/2021 Sulfide SM 4500 S o 0.42 mg/kg 03/16/2021 Ignitability SW 846 method 1010 >175°F 03/22/2021 Sludge Residuals Aluminum EPA200.7 26900mg/kg 03/11/2021 Arsenic EPA 200.7 <16.9 mg/kg 03/11/2021 Cadmium EPA 200.7 <16.9 mg/kg 03/11/2021 Calcium EPA 200.7 28200 mg/kg 03/11/2021 Chromium EPA200.7 28.9mg/kg 03/11/2021 Copper EPA 200.7 504 mg/kg 03/11/2021 Lead EPA 200.7 <16.9 mg/kg 03/11/2021 Magnesium EPA 200.7 2660 mg/kg 03/11/2021 Molybdenum EPA 200.7 <16.9 mg/kg 03/16/2021 Nickel EPA 200.7 19.5 mg/kg 03/11/2021 Potassium EPA 200.7 4030 mg/kg 03/16/2021 Selenium EPA200.7 <16.9mg/kg 03/18/2021 Sodium EPA 200.7 12700 mg/kg 03/16/2021 Zinc EPA 200.7 898 mg/kg 03/11/2021 Nitrate+Nitrite-Nitrogen EPA 353.2 5.34 mg/kg 03/16/2021 Total Solids (%) SM 2540 B 1.47% 03/10/2021 pH SM 4500 H B 6.54 units 03/10/2021 Ammonia Nitrogen SM 4500 NH3 C 982 mg/kg 03/15/2021 Total Kjeldahl Nitrogen(TKN) SM45004rgB 71600mg/kg 03/12/2021 Report# 2021-03907 Page 4 of 5 Environmental Chemists, Inc. envirochem 6602 Windmill Way,Wilmington,NC 28405 • 910.392.0223 Lab a 910.392.4424 Fax 710 Bowsertown Road,Manteo,NC 27954 . 252.473.5702 Lab/Fax 5M 255-A Wilmington Highway,Jacksonville,NC 28540 • 910.347.5843 Lab/Fax ANALYTICAL&CONSULTING CHEMISTS info@environmentalchemists.com environmentalchemists.com Bio-Green Services,Inc Date of Report: Apr 06, 2021 383 Potts Road Customer PO#: Advance NC 27006 Customer ID: 21030012 Attention: Ray Gambill Report#: 2021-03907 Project ID: Town of Cleveland Total Phosphorus SM 4500 P F 40100 mg/kg 03/18/2021 Mercury SW846 7471E <1.03 mg/kg 03/12/2021 TCLP Metals Arsenic EPA 200.7 <1.0 mg/L 03/22/2021 Barium EPA 200.7 <1.0 mg/L 03/22/2021 Cadmium EPA 200.7 <1.0 mg/L 03/22/2021 Chromium EPA 200.7 <1.0 mg/L 03/22/2021 Lead EPA 200.7 <1.0 mg/L 03/22/2021 Selenium EPA 200.7 <1.0 mg/L 03/22/2021 Silver EPA 200.7 <1.0 mg/L 03/22/2021 Mercury EPA 245.1 <0.0002 mg/L 03/19/2021 Comment: Sludge results, except pH, reported on a dry weight basis. pH reported on an as received basis. Reviewed by: tO,j , idailL Report#:: 2021-03907 Page 5 of 5 Environmental Chemist, Inc., Wilmington, NC Lab #94 6602 Windmill Way Wilmington, NC 28405 910.392.0223 Sample Receipt Checklist Client:T3\0 6,E,Sat alb Date:3 9 i a_i Report Number: 1 ---- (;390 1 ' 7 Receipt of sample: ECHEM Pickup 0 Client Deliver* 'UPS 0 FedEx 0 Other 0 ❑ YES +❑ NO ItA_ N/A 1. Were custody seals present on the cooler? ❑ YES 0 NO N/A 2. If custody seals were present, were they intact/unbroken? Original temperature upon receipt V °C Corrected temperature upon receipt °C How temperature taken: 0 Temperature Blank IX Against Bottles IR Gun ID: Thomas Traceable S/N 192511657 IR Gun Correction Factor°C: 0.0 ❑ YES 0 NO 3. If temperature of cooler exceeded 6°C, was Project Mgr./QA notified? +'i YES 0 NO 4. Were proper custody procedures (relinquished/received) followed? 0. YES 0 ND 5. Were sample ID's listed on the COC? Ni YES 0 NO 6. Were samples ID's listed on sample containers? YES 0 NO 7. Were collection date and time listed on the COC? . ' YES 0 NO 8. Were tests to be performed listed on the COC? YES 0 NO 9. Did samples arrive in proper containers for each test? IV YES 0 NO 10. Did samples arrive in good condition for each test? IV YES 0 NO 11. Was adequate sample volume available?' 01 YES 0 NO 12. Were samples received within proper holding time for requested tests? ❑ YES 0 NO 13. Were acid preserved samples received at a pH of<2? * ❑ YES 0 NO 14. Were cyanide samples received at a pH>12? ❑ YES 0 NO 15. Were sulfide samples received at a pH>9? _ ❑ YES 0 NO 16. Were NH3/TKN/Phenol received at a chlorine residual of<0.5 m/L? ** ❑ YES 0 NO 17. Were Sulfide/Cyanide received at a chlorine residual of<0.5 m/L? ❑ YES 0 NO 18. Were orthophosphate samples filtered in the field within 15 minutes? * TOC/Volatiles are pH checked at time of analysis and recorded on the benchsheet. ** Bacteria samples are checked for Chlorine at time of analysis and recorded on the benchsheet. Sample Preservation: (Must be completed for any sample(s) incorrectly preserved or with headspace) Sample(s) were received incorrectly preserved and were adjusted accordingly by adding (circle one): H2SO4 HNO3 HCI NaOH Time of preservation: If more than one preservative is needed, notate in comments below Note:Notify customer service immediately for incorrectly preserved samples.Obtain a new sample or notify the state lab if directed to analyzed by the customer.Who was notified,date and rime: Volatiles Sample(s) were received with headspace COMMENTS: DOC. QA.002 Rev 1 envirochem ENVIRONMENTAL CHEMISTS EMISTS I N C 6602 Windmill Way Wilmington, NC 28405 Analytical & Consulting Chemists NCDI=NR; DWQ CERTIFICATION # 94 NCDHHS: DLS CERTIFICATION # 37729 iOnfo@env FFICE: 1O-3g2 223 FAX 910-392-4424 COLLECTION AND CHAIN OF CUSTODY talchemists.com Client: ? ` 0 _ r �-` col c.c, --1--- PROJECT NAME. (9::, ADDRESS: �� I �J �C) REPORT NO: -- 0 � '" CONTACT NAME: , ;-ytlfq ( 1 (-Q.- YlC ��C�U REPORT TO: � PO NO: COPY TO: A. P /FAX: 3 -- gd 3 Sampled B email: } ( f ems, . �1e. 0�Cc' SAMPLE TYPE: I = Influent, E = Effluent, W = Well, ST = Stream, SO = Soil, SL = Sludge, Other: Collection Sample Identification C, PRESERVATION aC7 :9 ` n en I LIJ re w ma.r v Date Time Temp U, ° a z z o z N z a w T ANALYSIS REQUESTED � 3 � � P a z x x z � � o w a-. \ s C P G G , 3) MO II In ii 8 C P I 53_5 A ME p C P 96.37 G G Q s 111.11 C P �. G G C7-- --- -------- - G G Q1 7 , yam-� C P 6W0Gle. E . C P G G NOTICE - DECHLORINATION: Samples for Ammonia, TKN, Cyanide, Phenol and Bacteria must be dechlorinated (0.5 ppm or less in the fie ) Id at the time of collection. See reverse for Instructions Transfer Relinquished By: 1 Date/Time Received By: Date/Time 2. Temperature when R c 'ved °C: r L Accepted: -� Rejects Delivered By: Resample Requested: Comments: Received By: --� Date: 3 i Z Time: 1 L `l' P L 1 Dbcv)a./ TURNAROUND: ANNUAL PATHOGEN AND VECTOR FORMS ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM(503 Rules) Facility Name: Town of Cleveland WQ Permit Number: WQ0011431 WWTP Name: Cleveland WWTP NPDES Number: NC0049867 Monitoring Period: From 1/1/2021 To 12/31/2021 Pathogen Reduction (40 CFR 503.32)-Please indicate level achieved and alternative performed: Class A: Alternative I 0 Alternative 2 0 Alternative 3 ❑ Alternative 4 ❑ Alternative 5 ❑ Alternative 6 0 If applicable to alternative performed(Class A only)indicate"Process to Further Reduce Pathogens": Compost ❑ Heat Drying ❑ Heat Treatment 0 Thetmophilic 0 Beta Ray 0 Gamma Ray 0 Pasteurization ❑ Class B: Alternative 1 I] IAlternative 2 CI If applicable to alternative performed(Class B only)indicate"Process to Significantly Reduce Pathogens": Lime Stabilization p Air Drying❑ Composting 0 (Aerobic Digestion 0 Anaerobic Digestion ❑ If applicable to alternative performed(Class A or Class B)complete the following monitoring data: Number of Allowable Level Pathogen Density Frequency Sample Analytical Parameter Excee- in Sludge Minimutr Geo. Mean Maximum Units _dencec of Analysis Type Tech-nique z x 10 to the MPN 1,608 4,010 11,380 MPN/gram 0 Annual Grab SM 9221C E MPN bth power per gram of CFU Fecal Coliform total solids 1000 mpn per gram of total solid (dry weight) Salmonella bacteria 3 MPN per 4 grams (in lieu of fecal total solid(dry coliform) weight) Vector Attraction Reduction(40 CFR 503.33)-Please indicate option performed: Alt.1 (VS reduction) ❑ Alt.2(40-day bench) ❑ Alt.3(30-day bench) 0 Alt.4(Spec.02 uptake) ❑ Alt.5(14-Day Aerobic) ❑ Alt.6(Alk.Stabilization p Alt 7(Drying-Stable) ❑ Alt.8(Drying-Unstable) 0 Alt.9(Injection) ❑ Alt. 10(Incorporation) ❑ No vector attraction reduction alternatives were performed 0 CERTIFICATION STATEMENT(please check the appropriate statement) 0 "I certify,under penalty of law,that the pathogen requirements in 40 CFR 503.32 and the vector attraction reduction requirement in 40 CFR 503.33 have been met." El "I certify,under penalty of law,that the pathogen requirements in 40 CFR 503.32 and the vector attraction reduction requirement in 40 CFR 503.33 have not been met." (Please note if you check this statement attach an explanation why you have not met one or both of the requirements.) "This determination has been made under my direction and supervision in accordance with the system designed to ensure that qualified personnel properly gather and evaluate the information used to determine that the pathogen and vector attraction reduction requirements have been met. I am aware that there are significant penalties for false certification including fine and imprisonment." Ray Gambill, President Preparer Name and or print) Land Applier Name and Title(if applicable)(type or print) 2/42 Signature of Preparer* Date Signature of Land Applier(if applicable) Date *Preparer is defined in 40 CFR Part 503.9(r)and 15A NCAC 2T.1102(26) DENR FORM PVRF 503(12/2006) BRUNSWICK COUNTY ALKALINE STABILIZATION OF BIOSOLIDS Facility Name: r.) c./ ..i. u'I"" �.ct y A hC; ' Operator: u,� "' Lbs. or Gallons Used: / z 5 ( / t 1 Material Used For Stabilization: Lime Batch Size (gallons): �r!• S "���� Initial pH >i 2 pH 2 Hour pH 24 Hour pH Operator Date COrr. Corrected Corr_ Corrected COrf. Corrected Corr. Corrected Initials pH Temp C Time pH Temp C Time pH Temp C Time pH Temp C Time Factor + pH Factor + pH Factor + pH Factor + pH 5. 6. 7 z� . 03 11 �, o 12 ,. E , : 0 i Lz.i 1 /e� /2.14' U , 21 ; 2.7 I /ivy f�� S- Z / 1, Z ., r01 1Lc;? /U, rr.•..) ,•� . A I . i ' l _____ c �, Ir) (NI a) (9 c`) G N . •7 r— rl) tC. N 01 Cr) C) 1C) C) C) '.1 COV r- 0 C') O C) r`� I O O V' M Cr) M r7 N N N r0 O O •— •— N N IN r') in .^) I-) V .— r O O 0 O O O O Q C] O O O C O G O O sr v V 0 0 0 0 0 Q Q 0 0 o L o C 0 L; V N y) _ � ; ',J1 ? ; U A. V) V) V) V) V) V) V) Ce) 1.1 V) V) V) V) N V) 7 O 7 7 =. M .. .: — 0 > > > 7 7 7 c c c c c c a a cc `. $ cc c c U �- C- 0_ a. C_ 0_ 0_ Q. C. 0_ 0_ a_ a_ a_ a 0. r 4 li 0 Cr_ p CD CO I- CO rn V• M N z- O 0) CO I-- CO to r c) N T- O O) c0 I--- CO in '' cr) N N-- O E CI co co co CO co CO Co co co co N N N Cs., N N N N N N .- c- 1- c- ..- r r r c- h SOIL ANALYSIS REPORTS Page 1 of 1 Report Number: 21-015-0935 • *; ! . WAccount Number:46646alt ' - int r ¢ 7621 Whitepine Road, tticl;mond, VA 23237 �� Main 804-743-9401 ° Fax 804-271-6446 Send To: BIO-GREEN SERVICES INC ANALYTICAL www.waypointanatyticral.com 383 POTTS RD "Every acre...Every year. Grower: Town of Cleavland ADVANCE NC 27006 SOIL ANALYSIS REPORT Analytical Method(s): Mehlich 3 SMP Buffer pH Loss On Ignition Water pH Date Received: 01/15/2021 Date Of Analysis: 01/18/2021 Date Of Report: 01/18/2021 NC = North Carolina Fertility Index Value OM WN ENR Phosphorus Potassium Magnesium Calcium Sodium pH Acidity C.E.0 Sample ID Lab - % Soil M3 K Mg Ca Na Soil Buffer H Field ID Number Class lbs/A Rate ppm Rate ppm Rate ppm Rate ppm Rate ppm Rate ppm Rate ppm Rate PH Index meq/100g meq/100g BGCL1 1 22345 4.0 119 1 9 VL I 23 VL 248 VH 872 M 24 VL 5.9 6.79 1.4 1 8.0 M MIN NC = 7 LNc = 12I Percent Base Saturation Nitrate Sulfur Zinc Manganese Iron Copper Boron Soluble Salts SampleID K I Mg Ca Na l H — NO3N S Zn Mn Fe Cu B SS FieldieldID % Vo II o/a % % ppm Rate ppm Rate ppm Rate ppm Rate ppm Rate ppm Rate ppm Rate ms/cm Rate BGCL1 0.7 25.8 54.5 1.3 17.5 11 L 2.3 M 90 VH 63 VH 1.6 H 0.2 VL NC = 23 NC = 57.5 NC = 563 NC = 80.0 Values on this report represent the plant available nutrient;in the Explanation of symbols: % (percent). pprn(parts per million),lbs/A This report applies to samples)tested.Samples are retained a soil. Rating alter each value: VL(Very Low), L(t.ow). M(Medium). (pounds per acre), ins/cm (milli-mhos per centimeter), meq/100g maxitnian of thirty days alter testing. by. tutri r 11 r r.,aWa, H (High),VH(Very High). ENR -Estimated Nitrogen Release. (milli-equivalent per 100 grams). Conversions: ppm x 2=lbs/A. Soluble Analysis prepared by:Waypoint Analytical Virginia. Inc. C.E.C. -Cation Exchange Capacity. Salts insrcm x 640 = ppm. Pauric Mc Groary Ph.D., CPAg Date Received: 01/15/2021 Date Of Report: 01/18/2021 SOIL FERTILITY RECOMMENDATIONS Nitrogen Phosphate Potash Magnesium Sulfur Zinc Manganese Iron Copper Boron Sample ID Yield Goal Lime N P O K O MgS Zn Mn Fe Cu B Field ID Intended Crop Tons Tons/A z s lb/A lb/A lb/A lb/A Ib/A lb/A Ib/A lb/A Ib/A lb/A BGCL1 Fescue Hay 4 0.8 200 120 180 0 10 0 0 0 0 1.0 Comments: "The recommendations are based on research data and experience, but NO GUARANTEE or WARRANTY expressed or implied, concerning crop performance is made." 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