WQ0038580_Residual Annual Report 2021_20220228

Initial Review
Reviewer
EADS\ndthornburg
Is this submittal an application? (Excluding additional information.)*
Yes No
If not an application what is the submittal type?* Annual Report
Residual Annual Report
Additional Information
Other
Annual Report Year* 2021
Permit Number (IR) * WQ0038580
ApplicantlPermittee Town of Hillsborough
Email Notifications
Does this need review by the hydrogeologist?* Yes No
Regional Office Raleigh
CO Reviewer
Admin Reviewer

Submittal Form
Project Contact Information
Please provide information on the person to be contacted by NDB Staff regarding electronic submittal, confirmation of receipt, and other correspondence.
............................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................
Name* Brent Collins
Email Address*
[e-mail]
Project Information
Application/Document Type*
New (Fee Required)
Modification - Major (Fee Required)
Renewal with Major Modification (Fee
Required)
Annual Report
Additional Information
Other
Phone Number*
336-399-3646
Modification - Minor
Renewal
GW-59, NDMR, NDMLR, NDAR-1,
N DAR-2
Residual Annual Report
Change of Ownership
We no longer accept these monitoring reports through this portal. Please click on the link below and it will take you to the correct form.
hftps://edocs.deq.nc.gov/Forms/NonDischarge_Monitoring_Report
Perm it Type:*
Wastewater Irrigation
High -Rate Infiltration
Other Wastewater
Reclaimed Water
Closed -Loop Recycle
Residuals
Single -Family Residence Wastewater
Other
Irrigation
Permit Number: *
WQ0038580
Has Current Existing permit number
Applicant/Permittee Address*
PO Box 429, Hillsborough, NC 27278
Facility Name*
Town of Hillsborough Class A Residuals Program
Please provide comments/notes on your current submittal below.
At this time, paper copies are no longer required. If you have any questions about what is required, please contact Nathaniel Thornburg
at [e-mail].
Please attach all information required or requested for this submittal to be reviewed here.
(Application Form, Engineering Plans, Specifications, Calculations, Etc.)
2021 Hillsborough Annual Report - W00038580.pdf 8.72MB
Upload only 1 PDF document (less than 250 MB). Multiple documents must be combined into one PDF file unless file is larger
than upload limit.
* By checking this box, I acknowledge that I understand the application will not be
accepted for pre -review until the fee (if required) has been received by the Non -
Discharge Branch. Application fees must be submitted by check or money order and
made payable to the North Carolina Department of Environmental Quality (NCDEQ).
I also confirm that the uploaded document is a single PDF with all parts of the
application in correct order (as specified by the application).
Mail payment to:
NCDEQ — Division of Water Resources
Attn: Non -Discharge Branch
1617 Mail Service Center
Raleigh, NC 27699-1617
Signature
Submission Date 2/28/2022

MA
--Resources, Inc.
February 28, 2022
DENR/Water Quality Section
Non -Discharge Compliance Unit
1617 Mail Service Center
Raleigh, NC 27699-1617
Re: 2021 Annual Report — Town of Hillsborough WTP
Treatment and Land Application of Residuals
Permit No. WQ0038580
Dear Sir or Madam:
Enclosed is one copy of the 2021 Annual Report for the above referenced land
application permit.
During 2021, EMA Resources land applied 138.65 dry tons to 61.98 acres of private
farmland. Please contact Brent Collins - Director of Technical Services if you have any
further questions regarding this report.
Sincerely,
Brent Collins
Director of Technical Services
[e-mail]
Phone [phone] — Fax [phone]
755 Yadkinville Rd — Mocksville, NC 27028

---Resources, Inc.
Town of Hillsborough
2021 Annual Report
Residuals Land Application
Permit No. WQ0038580
Prepared By:
EMA Resources, Inc.
Phone [phone] — Fax [phone]
755 Yadkinville Rd — Mocksville, NC 27028

CLASS A ANNUAL DISTRIBUTION AND MARKETING/ SURFACE DISPOSAL CERTIFICATION AND SUMMARY FORM
WQ PERMIT #: WQ0038580 FACILITY NAME:
PHONE:
COUNTY:
Town of Hillsborough WTP
Orange
OPERATOR:
Town of Hillsborough WTP
FACILITY TYPE (please check one): ❑ Surface Disposal (complete Part A (Source(s) and "Residual In" Volume only) and Part C)
El Distribution and Marketing (complete Parts A, B, and C)
Was the facility in operation during the past calendar year?
Yes 0 No ❑ -* If No skip parts A, B, C and certify form below
Part A*:
Part B*:
Month
Sources(s) (include NPDES # if
applicable)
Volume (dry tons)
Recipient Information
Amendment/
Bulking Agent
Residual In
Product Out
Name(s)
Volume (dry tons)
Intended use(s)
January
February
March
April
May
June
July
August
September
October
November
December
Total from FORM DMSDF (sup)
0
0
138.65
138.65
Totals:
Annual (dry tons):
0
0
138.65
138.65
Amendment(s) used:
Bulking Agent(s) used:
DMSDF (Supp)
* If more space is required, attach additional information sheets (FORM DMSDF (supp)): Total Number of Form
0
Part C:
Facility was compliant during the past calendar year with all conditions of the land application permit
(including but not limited to items 1-3 below) issued by the Division of Water Quality:
O Yes
❑ No If No, Explain in Narritive
1. All monitoring was done in accordance with the permit and reported for the year as required and three (3) copies of certified laboratory results are attached.
2. All operation and maintenance requirements were compiled with or, in the case of a deviation, prior authorization was received from the Division of Water Quality.
3. No contravention of Ground Water Quality Standards occurred at a monitoring well.
"I certify, under penalty of law, that the above information is, to the best of my knowledge and belief, true, accurate and complete. I am aware that there are significant
penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations."
Marie Strandwitz (Feb 17, 202212:13 EST)
Signature of Permittee
Feb 17, 2022
Nathan Cat ss (Feb 17, 202210:02 EST)
Date Signature of Preparer**
(if different from Permittee)
**Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26)
Feb 17, 2022
Date
DENR FORM DMSDF (12/2006)

CLASS A ANNUAL DISTRIBUTION AND MARKETING/ SURFACE DISPOSAL CERTIFICATION AND SUMMARY FORM
Supplemental Information
WQ PERMIT #: WQ0038580 FACILITY NAME: Town of Hillsborough WTP
PHONE:
COUNTY:
Orange
OPERATOR: Town of Hillsborough WTP
FACILITY TYPE (please check one): ❑ Surface Disposal (complete Part A - "Month", "Source(s)" and "Residual In" columns only)
Distribution and Marketing (complete Parts A, and B)
Part A*:
Part B*:
Month
Sources(s) (include NPDES # if
applicable)
Volume (dry tons)
Recipient Information
Amendment/
Bulking Agent
Residual In
Product Out
Name(s)
Volume (dry
tons)
Intended use(s)
November
Town of Hillsborough WTP
138.65
Richard Vanhook
138.65
Soil Amendment
Totals:
Annual (dry tons):
0
0
138.65 138.65
Amendment(s) used:
Bulking Agent(s) used:
DMSDF (Supp)
* If more space is required, attach additional information sheets (FORM DMSDF (supp)): Total Number of Form
1
DENR FORM DMSDF (Supp) (12/2006)

ANNUAL RESIDUAL SAMPLING SUMMARY FORM
Please note that your permit may contain additional parameters to be analyzed. The parameters can be reported in FORM RSSF - B
WQ Permit Number:
Facility Name:
Residual Source WQ # or
NPDES #:
WWTP Name:
Residual Analysis Data
WQ0038580 Laboratory: 1) Waypoint Analytical
Town of Hillsborough WTP
PWS#0368015
Town of Hillsborough WTP
2)
3)
4)
5)
Parameter
(mg/kg)
Conc.
Limit
(mg/kg)a
Sample or Composite Date
10/26/21
Percent Solids (%)
NA
2.78
Arsenic
75
11.2
Cadmium
85
0.714
Copper
4,300
42.9
Chromium
NA
51.4
Lead
840
15
Mercury
57
0.232
Molybdenum
75
4.82
Nickel
420
9.39
Selenium
100
11.4
Zinc
7,500
114
Total Phosphorus
NA
1570
TKN
NA
3560
Ammonia -Nitrogen
NA
793
Nitrate and Nitrite
NA
342
a For surface disposal facilities the ceiling concentration limits listed in this form are not applicable. Reference the individual permit for metals limits.
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed
to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant
penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations."
ri
Nathan t s(Feb 17, 202210:02 EST)
Signature of Preparer *
Feb 17, 2022
Date
*Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26)
DENR FORM RSSF (12/2006)

ANNUAL RESIDUAL SAMPLING SUMMARY FORM - B
Report all sampling analysis results for parameters not listed in FORM RSSF that are part of the WQ permit or were analyzed for over the past
calendar year. Use additional forms as needed.
WQ Permit Number:
Facility Name:
Residual Source
NPDES # or WQ#:
WWTP Name:
WQ0038580 Laboratory: 1) Waypoint Analytical
Town of Hillsborough WTP
PWS#0368015
Town of Hillsborough WTP
Residual Analysis Data
2)
3)
4)
5)
Parameter
(mg/kg)
Sample or Composite Date
10/26/21
Aluminum
134000
Calcium
1850
Magnesium
1190
pH
4.9
Potassium
593
Sodium
539
PAN
1845
SAR
0.4
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system
designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are
significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations."
Nathan CatesFeb 17, 202210:02 EST)
Signature of Preparer *
*Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26)
Feb 17, 2022
Date
DENR FORM RSSF - B (12/2006)

ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name:
Permit #:
City of Hillsborough Total Dry Tons Applied (Annual):
WQ0038580
Cation Exchange Capacity (non 503 only):
59.54
Operator: Richard Varhook Owner: Richard Varhook Predominant Soil Series: GeB
Acres Used:
30.07 Acres Permitted:
30.07 Site #: OR03 Field #:
1
Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #):
Sample or
Corn-
posite
Date
I
?
3
10
11
12
10/26/21
% Solids
2.78
Arsenic
11.2
Cadmium
0.714
Copper
42.9
Chromium
51.4
Lead
15
Mercury
0.232
Molyb-
denum
4.82
Nickel
9.39
Selenium
11.4
Zinc
114
Total
Phos-
phorus
1570
Annual Heavy Metal Field Loadings (Calculated in lbs/acre):
Total
DT/Ac./
App.
Event
1
2I
3
4
5
6
7
II
9
10
12
Totals:
1.98
Arsenic
0.044
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.044
Cadmium
0.003
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.003
Copper
0.170
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.170
Chromium
0.204
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.204
Lead
0.059
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.059
Mercury
0.001
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.001
Molyb-
denum
0.019
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.019
Nickel
0.037
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.037
Selenium
0.045
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.045
Zinc
0.451
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.451
Total
Phos-
phorus
6.217
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
6.217
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
&‘
Signature of Land Applier
2/16/2022
Date
DENR FORM MFLSF (12/2006)

ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
Facility Name: City of Hillsborough WQ Permit #: WQ0038580 Field #: 1
Land Owner: Richard Varhook Annual Dry Tons Applied: 59.54 Site #: OR03
Operator: Richard Varhook
Crop 1 Name:
Fescue -Hay
Predominant Soil Series:
Acres Utilized:
Acres Permitted:
30.07
30.07
GeB Cation Exchange Capacity (non 503): 0
Crop 1 Max. PAN: 211
Crop 2 Name:
Crop 2 Max. PAN:
Date or
Month
Volume
enter one)Solids/
Liquid
Cu. Yds
applied
Gallons
%
Solids
Volume
Appliedper
pP
Acre
(Dry Tons/Ac)
Residual Sources
(NPDES #, WQ#,
Fert., Animal
Waste, etc)
Soil
Cond.
(Dry, Wet,
Moist)
Precip.
Past 24
Hrs.
inches
Application
Method*
Volatilization
Rate**
Mineralizatio
n Rate***
TKN
mg/kg
Ammonia 'Z
rn
Nitrogen
Nitrate
and
Nitrite
mg/kg
PAN Applied
(lbs/acre)
Name of Crop Type
ReceivingResidual
Application
Crop 1
Crop 2
Crop 1
Crop 2
11/4
78000
2.78
0.301
Hillsborough WTP
D
<.5"
S
0.5
0.4
3560
793
342
1.110
NA
Fescue
11/5
91000
2.78
0.351
Hillsborough WTP
D
<.5"
S
0.5
0.4
3560
793
342
1.295
NA
Fescue
11/8
162500
2.78
0.626
Hillsborough WTP
D
<.5"
S
0.5
0.4
3560
793
342
2.312
NA
Fescue
11/9
182000
2.78
0.702
Hillsborough WTP
D
<.5"
S
0.5
0.4
3560
793
342
2.589
NA
Fescue
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0
0
0.000
Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp to this form):
0.000
0.000
TOTALS:
0
513500
As
Cd
Cu
Cr
Pb
Hg
Mo
Ni
Se
Zn
P
7.306
0.000
Lime Applied
Annual lbs/acre
0.044
0.003
0.170
0.204
0.059
0.001
0.019
0.037
0.045
0.451
6.217
Date
lbs/ac
Prior Years Cumulative lbs/ac
0
0
0
0
0
0
0
0
0
0
Current Cumulative lbs/ac
0.044
0.003
0.170
0.204
0.059
0.001
0.019
0.037
0.045
0.451
Permitted C. P. L. R.****
36
34
1338
267
15
374
89
2498
Permit PAN Limit l st/2nd Crop
211
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false
information, including the possibility of fines and imprisonment for knowing violations."
Signature of Land Applier
*Application Method: S - Surface, IN - Injection, INC - Incorporation
2/16/2022 **Volatilization Rate: Surface - 0.5, Injection/Incorporation -1.0
Date **' Mineralization Rates: Compost -0.1, anaerobially digested -0.2,
aerobically digested -0.3, raw sludge -0.4
****C.P.L.R.: Cumulative Pollutant Loading Rate
DENR FORM FSF (12/2006)

ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name:
Permit #:
City of Hillsborough Total Dry Tons Applied (Annual):
WQ0038580
Cation Exchange Capacity (non 503 only):
23.36
Operator: Richard Varhook Owner: Richard Varhook Predominant Soil Series: CfB
Acres Used:
9.01 Acres Permitted:
9.01 Site #: OR03 Field #:
2
Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #):
Sample or
Corn -
posite
Date
I
2
3
9
`10
111
1.12
10/26/21
% Solids
2.78
Arsenic
11.2
Cadmium
0.714
Copper
42.9
Chromium
51.4
Lead
15
Mercury
0.232
Molyb-
denum
4.82
Nickel
9.39
Selenium
11.4
Zinc
114
Total
Phos-
phorus
1570
Annual Heavy Metal Field Loadings (Calculated in lbs/acre):
Total
DT/Ac./
App.
Event
1
2I
3
4
5
6
7
II
9
10
12
Totals:
2.59
Arsenic
0.058
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.058
Cadmium
0.004
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.004
Copper
0.222
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.222
Chromium
0.267
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.267
Lead
0.078
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.078
Mercury
0.001
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.001
Molyb-
denum
0.025
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.025
Nickel
0.049
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.049
Selenium
0.059
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.059
Zinc
0.591
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.591
Total
Phos-
phorus
8.142
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
8.142
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
&‘
Signature of Land Applier
2/16/2022
Date
DENR FORM MFLSF (12/2006)

ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
Facility Name: City of Hillsborough WQ Permit #: WQ0038580 Field #: 2
Land Owner: Richard Varhook Annual Dry Tons Applied: 23.36 Site #: OR03
Operator: Richard Varhook
Crop 1 Name:
Fescue -Hay
Predominant Soil Series:
Acres Utilized:
Acres Permitted:
9.01
9.01
CfB Cation Exchange Capacity (non 503): 0
Crop 1 Max. PAN: 216
Crop 2 Name:
Crop 2 Max. PAN:
Date or
Month
Volume
enter one)Solids/
Liquid
Cu. Yds
applied
Gallons
%
Solids
Volume
Appliedper
pP
Acre
(Dry Tons/Ac)
Residual Sources
(NPDES #, WQ#,
Fert., Animal
Waste, etc)
Soil
Cond.
(Dry, Wet,
Moist)
Precip.
Past 24
Hrs.
inches
Application
Method*
Volatilization
Rate**
Mineralizatio
n Rate***
TKN
mg/kg
Ammonia 'Z
rn
Nitrogen
Nitrate
and
Nitrite
mg/kg
PAN Applied
(lbs/acre)
Name of Crop Type
ReceivingResidual
Application
Crop 1
Crop 2
Crop 1
Crop 2
11/10
201500
2.78
2.593
Hillsborough WTP
D
<.5"
S
0.5
0.1
3560
793
342
5.264
NA
Fescue
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0
0
0.000
Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp to this form):
0.000
0.000
TOTALS:
0
201500
As
Cd
Cu
Cr
Pb
Hg
Mo
Ni
Se
Zn
P
5.264
0.000
Lime Applied
Annual lbs/acre
0.058
0.004
0.222
0.267
0.078
0.001
0.025
0.049
0.059
0.591
8.142
Date
lbs/ac
Prior Years Cumulative lbs/ac
0
0
0
0
0
0
0
0
0
0
Current Cumulative lbs/ac
0.058
0.004
0.222
0.267
0.078
0.001
0.025
0.049
0.059
0.591
Permitted C. P. L. R.****
36
34
1338
267
15
374
89
2498
Permit PAN Limit 1st/2nd Crop
216
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false
information, including the possibility of fines and imprisonment for knowing violations."
Signature of Land Applier
*Application Method: S - Surface, IN - Injection, INC - Incorporation
2/16/2022 **Volatilization Rate: Surface - 0.5, Injection/Incorporation -1.0
Date **' Mineralization Rates: Compost -0.1, anaerobially digested -0.2,
aerobically digested -0.3, raw sludge -0.4
****C.P.L.R.: Cumulative Pollutant Loading Rate
DENR FORM FSF (12/2006)

ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name:
Permit #:
City of Hillsborough Total Dry Tons Applied (Annual):
WQ0038580
Cation Exchange Capacity (non 503 only):
22.60
Operator: Richard Varhook Owner: Richard Varhook Predominant Soil Series: GeB
Acres Used:
6.8 Acres Permitted:
6.8 Site #: OR03 Field #:
3
Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #):
Sample or
Corn -
posite
Date
3
9
`10
111
1.12
10/26/21
% Solids
2.78
Arsenic
11.2
Cadmium
0.714
Copper
42.9
Chromium
51.4
Lead
15
Mercury
0.232
Molyb-
denum
4.82
Nickel
9.39
Selenium
11.4
Zinc
114
Total
Phos-
phorus
1570
Annual Heavy Metal Field Loadings (Calculated in lbs/acre):
Total
DT/Ac./
App.
Event
1
2I
3
4
5
6
7
II
9
10
12
Totals:
3.32
Arsenic
0.074
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.074
Cadmium
0.005
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.005
Copper
0.285
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.285
Chromium
0.342
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.342
Lead
0.100
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.100
Mercury
0.002
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.002
Molyb-
denum
0.032
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.032
Nickel
0.062
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.062
Selenium
0.076
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.076
Zinc
0.758
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.758
Total
Phos-
phorus
10.437
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
10.437
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
&‘
Signature of Land Applier
2/16/2022
Date
DENR FORM MFLSF (12/2006)

ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
Facility Name: City of Hillsborough WQ Permit #: WQ0038580 Field #: 3
Land Owner: Richard Varhook Annual Dry Tons Applied: 22.60 Site #: OR03
Operator: Richard Varhook
Crop 1 Name:
Fescue -Hay
Predominant Soil Series:
Acres Utilized:
Acres Permitted:
6.8
6.8
GeB Cation Exchange Capacity (non 503): 0
Crop 1 Max. PAN: 211
Crop 2 Name:
CfB
Crop 2 Max. PAN:
Date or
Month
Volume
enter one)Solids/
Liquid
Cu. Yds
applied
Gallons
%
Solids
Volume
Appliedper
pP
Acre
(Dry Tons/Ac)
Residual Sources
(NPDES #, WQ#,
Fert., Animal
Waste, etc)
Soil
Cond.
(Dry, Wet,
Moist)
Precip.
Past 24
Hrs.
inches
Application
Method*
Volatilization
Rate**
Mineralizatio
n Rate***
TKN
mg/kg
Ammonia 'Z
rn
Nitrogen
Nitrate
and
Nitrite
mg/kg
PAN Applied
(lbs/acre)
Name of Crop Type
ReceivingResidual
Application
Crop 1
Crop 2
Crop 1
Crop 2
11/11
195000
2.78
3.324
Hillsborough WTP
D
<.5"
S
0.5
0.1
3560
793
342
6.750
NA
Fescue
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0
0
0.000
Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp to this form):
0.000
0.000
TOTALS:
0
195000
As
Cd
Cu
Cr
Pb
Hg
Mo
Ni
Se
Zn
P
6.750
0.000
Lime Applied
Annual lbs/acre
0.074
0.005
0.285
0.342
0.100
0.002
0.032
0.062
0.076
0.758
10.437
Date
lbs/ac
Prior Years Cumulative lbs/ac
0
0
0
0
0
0
0
0
0
0
Current Cumulative lbs/ac
0.074
0.005
0.285
0.342
0.100
0.002
0.032
0.062
0.076
0.758
Permitted C. P. L. R.****
36
34
1338
267
15
374
89
2498
Permit PAN Limit l st/2nd Crop
211
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false
information, including the possibility of fines and imprisonment for knowing violations."
Signature of Land Applier
*Application Method: S - Surface, IN - Injection, INC - Incorporation
2/16/2022 **Volatilization Rate: Surface - 0.5, Injection/Incorporation -1.0
Date **' Mineralization Rates: Compost -0.1, anaerobially digested -0.2,
aerobically digested -0.3, raw sludge -0.4
****C.P.L.R.: Cumulative Pollutant Loading Rate
DENR FORM FSF (12/2006)

ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name:
Permit #:
City of Hillsborough Total Dry Tons Applied (Annual):
WQ0038580
Cation Exchange Capacity (non 503 only):
17.33
Operator: Richard Varhook Owner: Richard Varhook Predominant Soil Series: GeB
Acres Used:
10.78 Acres Permitted:
10.78 Site #: OR03 Field #:
4
Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #):
Sample or
Corn -
posite
Date
3
9
`10
111
112
10/26/21
% Solids
2.78
Arsenic
11.2
Cadmium
0.714
Copper
42.9
Chromium
51.4
Lead
15
Mercury
0.232
Molyb-
denum
4.82
Nickel
9.39
Selenium
11.4
Zinc
114
Total
Phos-
phorus
1570
Annual Heavy Metal Field Loadings (Calculated in lbs/acre):
Total
DT/Ac./
App.
Event
1
2I
3
4
5
6
7
II
9
10
12
Totals:
1.61
Arsenic
0.036
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.036
Cadmium
0.002
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.002
Copper
0.138
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.138
Chromium
0.165
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.165
Lead
0.048
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.048
Mercury
0.001
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.001
Molyb-
denum
0.016
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.016
Nickel
0.030
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.030
Selenium
0.037
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.037
Zinc
0.367
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.367
Total
Phos-
phorus
5.049
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
5.049
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
&‘
Signature of Land Applier
2/16/2022
Date
DENR FORM MFLSF (12/2006)

ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
Facility Name: City of Hillsborough WQ Permit #: WQ0038580 Field #: 4
Land Owner: Richard Varhook Annual Dry Tons Applied: 17.33 Site #: OR03
Operator: Richard Varhook
Crop 1 Name:
Fescue -Hay
Predominant Soil Series:
Acres Utilized:
Acres Permitted:
10.78
10.78
GeB Cation Exchange Capacity (non 503): 0
Crop 1 Max. PAN: 21 I
Crop 2 Name:
Crop 2 Max. PAN:
Date or
Month
Volume
enter one)Solids/
Liquid
Cu. Yds
applied
Gallons
%
Solids
Volume
Appliedper
pP
Acre
(Dry Tons/Ac)
Residual Sources
(NPDES #, WQ#,
Fert., Animal
Waste, etc)
Soil
Cond.
(Dry, Wet,
Moist)
Precip.
Past 24
Hrs.
inches
Application
Method*
Volatilization
Rate**
Mineralizatio
n Rate***
TKN
mg/kg
Ammonia 'Z
rn
Nitrogen
Nitrate
and
Nitrite
mg/kg
PAN Applied
(lbs/acre)
Name of Crop Type
ReceivingResidual
Application
Crop 1
Crop 2
Crop 1
Crop 2
11/15
149500
2.78
1.608
Hillsborough WTP
D
<.5"
S
0.5
0.1
3560
793
342
3.264
NA
Fescue
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0
0
0.000
Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp to this form):
0.000
0.000
TOTALS:
0
149500
As
Cd
Cu
Cr
Pb
Hg
Mo
Ni
Se
Zn
P
3.264
0.000
Lime Applied
Annual lbs/acre
0.036
0.002
0.138
0.165
0.048
0.001
0.016
0.030
0.037
0.367
5.049
Date
lbs/ac
Prior Years Cumulative lbs/ac
0
0
0
0
0
0
0
0
0
0
Current Cumulative lbs/ac
0.036
0.002
0.138
0.165
0.048
0.001
0.016
0.030
0.037
0.367
Permitted C. P. L. R.****
36
34
1338
267
15
374
89
2498
Permit PAN Limit l st/2nd Crop
211
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false
information, including the possibility of fines and imprisonment for knowing violations."
Signature of Land Applier
*Application Method: S - Surface, IN - Injection, INC - Incorporation
2/16/2022 **Volatilization Rate: Surface - 0.5, Injection/Incorporation -1.0
Date **' Mineralization Rates: Compost -0.1, anaerobially digested -0.2,
aerobically digested -0.3, raw sludge -0.4
****C.P.L.R.: Cumulative Pollutant Loading Rate
DENR FORM FSF (12/2006)

ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name:
Permit #:
City of Hillsborough Total Dry Tons Applied (Annual):
WQ0038580
Cation Exchange Capacity (non 503 only):
15.82
Operator: Richard Varhook Owner: Richard Varhook Predominant Soil Series: GeB
Acres Used:
5.32 Acres Permitted:
5.32 Site #: OR03 Field #:
5
Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #):
Sample or
Corn -
posite
Date
3
9
`10
111
1.12
10/26/21
% Solids
2.78
Arsenic
11.2
Cadmium
0.714
Copper
42.9
Chromium
51.4
Lead
15
Mercury
0.232
Molyb-
denum
4.82
Nickel
9.39
Selenium
11.4
Zinc
114
Total
Phos-
phorus
1570
Annual Heavy Metal Field Loadings (Calculated in lbs/acre):
Total
DT/Ac./
App.
Event
1
2I
3
4
5
6
7
II
9
10
12
Totals:
2.97
Arsenic
0.067
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.067
Cadmium
0.004
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.004
Copper
0.255
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.255
Chromium
0.306
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.306
Lead
0.089
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.089
Mercury
0.001
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.001
Molyb-
denum
0.029
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.029
Nickel
0.056
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.056
Selenium
0.068
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.068
Zinc
0.678
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.678
Total
Phos-
phorus
9.338
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
9.338
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
&‘
Signature of Land Applier
2/16/2022
Date
DENR FORM MFLSF (12/2006)

ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
Facility Name: City of Hillsborough WQ Permit #: WQ0038580 Field #: 5
Land Owner: Richard Varhook Annual Dry Tons Applied: 15.82 Site #: OR03
Operator: Richard Varhook
Crop 1 Name: Fescue -Pasture
Predominant Soil Series:
Acres Utilized:
Acres Permitted:
5.32
5.32
GeB Cation Exchange Capacity (non 503): 0
Crop 1 Max. PAN: 211
Crop 2 Name:
Crop 2 Max. PAN:
Date or
Month
Volume
enter one)Solids/
Liquid
Cu. Yds
applied
Gallons
%
Solids
Volume
Appliedper
pP
Acre
(Dry Tons/Ac)
Residual Sources
(NPDES #, WQ#,
Fert., Animal
Waste, etc)
Soil
Cond.
(Dry, Wet,
Moist)
Precip.
Past 24
Hrs.
inches
Application
Method*
Volatilization
Rate**
Mineralizatio
n Rate***
TKN
mg/kg
Ammonia 'Z
rn
Nitrogen
Nitrate
and
Nitrite
mg/kg
PAN Applied
(lbs/acre)
Name of Crop Type
ReceivingResidual
Application
Crop 1
Crop 2
Crop 1
Crop 2
11/16
136500
2.78
2.974
Hillsborough WTP
D
<.5"
S
0.5
0.1
3560
793
342
6.039
NA
Fescue
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0
0
0.000
Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp to this form):
0.000
0.000
TOTALS:
0
136500
As
Cd
Cu
Cr
Pb
Hg
Mo
Ni
Se
Zn
P
6.039
0.000
Lime Applied
Annual lbs/acre
0.067
0.004
0.255
0.306
0.089
0.001
0.029
0.056
0.068
0.678
9.338
Date
lbs/ac
Prior Years Cumulative lbs/ac
0
0
0
0
0
0
0
0
0
0
Current Cumulative lbs/ac
0.067
0.004
0.255
0.306
0.089
0.001
0.029
0.056
0.068
0.678
Permitted C. P. L. R.****
36
34
1338
267
15
374
89
2498
Permit PAN Limit l st/2nd Crop
211
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false
information, including the possibility of fines and imprisonment for knowing violations."
Signature of Land Applier
*Application Method: S - Surface, IN - Injection, INC - Incorporation
2/16/2022 **Volatilization Rate: Surface - 0.5, Injection/Incorporation -1.0
Date **' Mineralization Rates: Compost -0.1, anaerobially digested -0.2,
aerobically digested -0.3, raw sludge -0.4
****C.P.L.R.: Cumulative Pollutant Loading Rate
DENR FORM FSF (12/2006)

Waypoint
ANALYTICAL
11/9/2021
EMA Resources Inc
Mr. Brent Collins
755 Yadkinville Rd
Mocksville, NC, 27028
Ref: Analytical Testing
Lab Report Number: 21-300-0127
Client Project Description: Hillsborough, NC
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 ° fax [phone]
www.waypointanalytical.com
Dear Mr. Brent Collins:
Waypoint Analytical, LLC. received sample(s) on 10/27/2021 for the analyses presented in the following report.
The above referenced project has been analyzed per your instructions. The analyses were performed in
accordance with the applicable analytical method. Where the laboratory was not responsible for the sampling
stage (refer to the chain of custody) results apply to the sample as received.
The analytical data has been validated using standard quality control measures performed as required by the
analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all
parameters (NELAP and non-NELAP) were performed in accordance with guidelines established by the USEPA
(including 40 CFR 136 Method Update Rule May 2021) and NELAC unless otherwise indicated. Any parameter
for which the laboratory is not officially NELAP accredited is indicated by a symbol. These are not included in
the scope because NELAP accreditation is either not available or has not been applied for. Additional
certifications may be held/are available for parameters, where NELAP accreditation is not required or applicable.
A full list of certifications is available upon request.
Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of
sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time.
Refer to sample analysis time for confirmation of holding time compliance.
The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as -
received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to
the samples included in this report.
Please do not hesitate to contact me or client services if you have any questions or need additional information.
Sincerely,
Ca,
Danyale Love
Project Manager
Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the
analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis.
Page 1 of 7

Waypoint
ANALYTICAL
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 ° Fax [phone]
www.waypointa nalytical.com
Certification Summary
Laboratory ID: WP MTN: Waypoint Analytical, LLC., Memphis, TN
State Program Lab ID Expiration Date
Alabama State Program 40750 02/28/2022
Arkansas State Program 88-0650 02/07/2022
California State Program 2904 06/30/2022
Florida State Program - NELAP E871157 06/30/2022
Georgia State Program C044 02/18/2023
Georgia State Program 04015 06/30/2022
Illinois State Program - NELAP 200078 10/10/2022
Kentucky State Program 80215 06/30/2022
Kentucky State Program KY90047 12/31/2021
Louisiana State Program - NELAP LA037 12/31/2021
Louisiana State Program - NELAP 04015 06/30/2022
Mississippi State Program MS 02/11/2023
North Carolina State Program 415 12/31/2021
Pennsylvania State Program - NELAP 68-03195 05/31/2022
South Carolina State Program 84002 06/30/2022
South Carolina State Program 84002 06/30/2022
Tennessee State Program 02027 02/11/2023
Texas State Program - NELAP T104704180 09/30/2022
Virginia State Program 00106 06/30/2022
Virginia State Program - NELAP 460181 09/14/2022
Page 1 of 1 00001 /21-300-0127
Page 2 of 7

Waypoint
ANALYTICAL
Report Number: 21-300-0127
Client Project Description: Hillsborough, NC
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 ° Fax [phone]
www.waypointa nalytical. com
Sample Summary Table
Lab No Client Sample ID Matrix Date Collected Date Received
95454 Sludge Solids 10/26/2021 09:30 10/27/2021
Page 3 of 7

Waypoint.
ANALYTICAL
46245
EMA Resources Inc
Mr. Brent Collins
755 Yadkinville Rd
Mocksville , NC 27028
Report Number : 21-300-0127
Lab No : 95454
Sample ID : Sludge
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 ° Fax [phone]
www.waypointa nalytical. cam
Project Hillsborough, NC
Information :
REPORT OF ANALYSIS
Report Date : 11/09/2021
Received : 10/27/2021
49-Qc� (»-)9
Danyale Love
Project Manager
Matrix: Solids
Sampled: 10 / 26/ 2021 9:30
Test Results Units MDL MQL DF Date / Time By Analytical
Analyzed Method
Moisture 97.2 % 0.010 1 10/29/21 16:25 FMM SW-DRYWT
Ammonia Nitrogen 793j mg/Kg - dry 571 3570 1 11/03/21 10:00 JPJ 4500NH3C-2011
Nitrate+Nitrite-N 342 mg/Kg - dry 177 177 1 11/03/21 15:39 ZBD 4500NO3F-2011
Organic N <3571 mg/Kg - dry 3571 1 11/03/21 10:00 CALCULATION
pH 4.9 s.u. 1 11/02/21 15:09 DRS 9045D
Total Solids 2.78 % 0.010 0.010 1 10/29/21 16:25 FMM 2540G-2011
Total Volatile Solids 31.6 % 0.010 0.010 1 10/29/21 16:25 FMM 2540G-2011
Total Kjeldahl Nitrogen 3560 mg/Kg - dry 1790 1 11/04/21 15:31 CLP 4500NORGD-2011
Phosphorus 1570 mg/Kg - dry 98.6 179 1 11/09/21 04:31 TJS 6010D
Aluminum 134000 mg/Kg - dry 165 179 1 11/09/21 04:31 TJS 6010D
Arsenic 11.2] mg/Kg - dry 8.57 17.9 1 11/09/21 04:31 TJS 6010D
Cadmium <0.714 mg/Kg - dry 0.714 3.57 1 11/09/21 04:31 TJS 6010D
Calcium 1850 mg/Kg - dry 1380 1790 1 11/09/21 04:31 TJS 6010D
Chromium 51.4 mg/Kg - dry 8.43 8.93 1 11/09/21 04:31 TJS 6010D
Copper 42.9 mg/Kg - dry 11.1 17.9 1 11/09/21 04:31 TJS 6010D
Iron 52900 mg/Kg - dry 304 357 1 11/09/21 04:31 TJS 6010D
Lead 15.0 mg/Kg - dry 6.43 10.7 1 11/09/21 04:31 TJS 6010D
Magnesium 1190 mg/Kg - dry 92.1 179 1 11/09/21 04:31 TJS 6010D
Manganese 4640 mg/Kg - dry 11.6 17.9 1 11/09/21 04:31 TJS 6010D
Mercury <0.232 mg/Kg - dry 0.232 0.532 1 11/03/21 13:32 JW2 7471A
Molybdenum <4.82 mg/Kg - dry 4.82 8.93 1 11/09/21 04:31 TJS 6010D
Nickel 9.39 mg/Kg - dry 4.29 8.93 1 11/09/21 04:31 TJS 6010D
Potassium 593 mg/Kg - dry 221 357 1 11/09/21 04:31 TJS 6010D
Qualifiers/
Definitions
DF Dilution Factor J Estimated value
L Limit Exceeded MQL Method Quantitation Limit
Page 4 of 7

Waypoint.
ANALYTICAL
46245
EMA Resources Inc
Mr. Brent Collins
755 Yadkinville Rd
Mocksville , NC 27028
Report Number : 21-300-0127
Lab No : 95454
Sample ID : Sludge
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 ° Fax [phone]
www.waypointa nalytical. cam
Project Hillsborough, NC
Information :
REPORT OF ANALYSIS
Report Date : 11/09/2021
Received : 10/27/2021
49-Qc� (»-)9
Danyale Love
Project Manager
Matrix: Solids
Sampled: 10 / 26/ 2021 9:30
Test Results Units MDL MQL DF Date / Time By Analytical
Analyzed Method
Selenium <11.4 mg/Kg - dry 11.4 17.9 1 11/09/21 04:31 TJS 6010D
Sodium 539 ] mg/Kg - dry 464 893 1 11/09/21 04:31 TJS 6010D
Zinc 114 mg/Kg - dry 28.9 44.6 1 11/09/21 04:31 TJS 6010D
Sulfur 4140 mg/Kg - dry 185 357 1 11/09/21 04:31 TJS 6010D
Sodium Absorption Ratio 0.40] Ratio 0.01 0.01 1 11/09/21 04:31 CALCULATION
Qualifiers/
Definitions
DF Dilution Factor
J Estimated value
Page 5 of 7

Waypoi nt
ANALYTICAL
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 ° Fax [phone]
www.waypointanalytical.com
Shipment Receipt Form
Customer Number: 46245
Customer Name: EMA Resources Inc
Report Number: 21-300-0127
• Fed Ex
O UPS
Shipping Method
O US Postal 0 Lab
O Client 0 Courier
0 Other :
Thermometer ID: FT
—
Shipping container/cooler uncompromised? # Yes
O No
Number of coolers/boxes received [ 1
Custody seals intact on shipping container/cooler? Yes
O No
• Not Present
Custody seals intact on sample bottles? 0 Yes
O No
• Not Present
Chain of Custody (COC) present? # Yes
O No
COC agrees with sample label(s)? # Yes
O No
COC properly completed # Yes
O No
Samples in proper containers? # Yes
O No
Sample containers intact? # Yes
O No
Sufficient sample volume for indicated test(s)? # Yes
O No
All samples received within holding time? # Yes
O No
Cooler temperature in compliance? # Yes
O No
Cooler/Samples arrived at the laboratory on ice.
Samples were considered acceptable as cooling
process had begun.
Yes
O No
Water - Sample containers properly preserved
Water - VOA vials free of headspace
0 Yes
0 Yes
O No
O No
O N/A
O N/A
Trip Blanks received with VOAs
0 Yes
O No
O N/A
Soil VOA method 5035 — compliance criteria met 0 Yes
O No
O N/A
r High concentration container (48 hr) r Low concentration EnCore samplers (48 hr)
r High concentration pre -weighed (methanol -14 d) Low conc pre -weighed vials (Sod Bis -14 d)
Special precautions or instructions included? 0 Yes 0 No
Comments:
Signature:
Summer Harrison
Date & Time:
Page 6 of 7
10/28/2021 16:22:45

For Laboratory Use Only
Matrix Key
WW — Wastewater GW —Groundwater
DW — Drinking Water S — Soil /Solid 0—Oil
P - Product M Misc
W
01
H
�
A Cool c IOC Na25203 IMitrp Only)
B Cool <= 6C
C H2504 pHt2
None Required
E NaOH pH>10
F HNO3 pH[2
G HCLpH[2
H H3PO4 pH[2
Cool [= 6C NA25203
Comments/Notes
a
aS
U
U
-r1
0
03
U
VI
Q
Eri
TO0
SW
Mn,Mg,Mo,Hg, Ni,Se, Na,P,S, K,Zn
Client Remarks/Comments
Sludge Samples - Report Dry Weight
E
i=
a,
e
E
i=
N
a
n
t' ..
C]
H- Y
o.--,
Received by: (SIGNATURE)
Received by: (SIGNATURE(
ceived by: (SIGNAT RE)
I IIIl11IIIN IIII IIIIII I I I III.1 III! IIII 1 IIIII IIIII III 1 IIII I11
EMAResources Inc
Hillshorojnh. NC
Met od of Shipment
Fed Ea UPS EUSPS
Courier Client Drop Off
Other
Purchase Order Number
luired Analysis / Preservative
1
1
303
Date Time
�ctl� y-''
i
a,
8
Date Time
SA1
1
Hd
Sampled by (Name — Print)
Relingquu' ed by: SIGNATURE]
Relinquished by: (SIGNATURE)
Relinquished by: (SIGNATURE)
Billing information
Account #46245
Project/Site Location (City/State} RUSH — Additional charges apply
Special Detection Limit(s)
'/� p _ ,5 Date Results Needed
r. • to riJ[
I Project Manager Email
[e-mail]
sp!IoS Itiol
N oiue6Jo,e J !N
1
eiuoWWV/N>ll
I
r
I
!
WO L09) s€elaW1
.„...)
a3!sodwob) JO geJ(91
Client Project Manager/Contact
Brent Collins
Project Manager Phone #
336-399-3646
(AaH o; la;aj) xpaeyj
`3
n
sJaurBUM) ;a JaquanN
Unless noted, all containers
per Table II of 40 CFR Part
136.
Sample Identification
is
rFor Laboratory Use Only
c
E
E
O
V
N
Client Name/Address
EMA Resources Inc
755 Yadkinville Rd
Macksville, NC 27028
Project Description
Project Number
Waypoint0
ANALYTICAL
2790 Whitten Road
Memphis, TN 38133
Mt) Z13-2400
a . `fir !)
o @
E..,t{r4+I
7
a
H
U'
z
(2.,:i
��
yi
0
C 4-1
...___
Page 7 of 7

Sodium
Calcium
Magnesium
Percent Solids
10/26/2021
mg/kg mg/L Equiv Weight Milli Equiv
539 14.9842 23 0.651487
1850 51.43 20 2.5715
1190 33.082 12 2.756833
2.78
SAR =
SAR 0.40
Na
�2 (Ca2 i + Mgt )

ace Analytical®
A\ALYTICAL
REPO
December 15, 2021
RT
EMA Resources
Sample Delivery Group: L1432018
Samples Received: 11/16/2021
Project Number:
Description: Sludge
Report To:
Mr. Brent Collins
755 Yadkinville Road
Mocksville, NC 27028
Entire Report Reviewed By:
Justin Carr
Project Manager
Results relate only to the items tested or calibrated and are reported as rounded values. This test report shall not be
reproduced, except in full, without written approval of the laboratory. Where applicable, sampling conducted by Pace
Analytical National is performed per guidance provided in laboratory standard operating procedures ENV-SOP-MTJL-0067 and
ENV-SOP-MTJL-0068. Where sampling conducted by the customer, results relate to the accuracy of the information provided,
and as the samples are received.
Pace Analytical National
12065 Lebanon Rd Mount Juliet, TN 37122 615-758-5858 800-767-5859 www.pacenational.com
4
Cn
5
Sr
LQC]
GI
rAI1
9
SC
ACCOUNT:
EMA Resources
PROJECT:
SDG:
L1432018
DATE/TIME:
12/15/21 14:37
PAGE:
1of20

TABLE OF CONTENTS
Cp: Cover Page
Tc: Table of Contents
Ss: Sample Summary 3
Cn: Case Narrative 4
Sr: Sample Results 5
HILLSBOROUGH L1432018-01 5
Qc: Quality Control Summary 7
Wet Chemistry by Method 9012 B 7
Wet Chemistry by Method 9034-9030B 8
Wet Chemistry by Method 9045D 9
Wet Chemistry by Method D93/1010A 10
Mercury by Method 7470A 11
Metals (ICP) by Method 6010D 12
Volatile Organic Compounds (GC/MS) by Method 8260D 13
Chlorinated Acid Herbicides (GC) by Method 8151A 14
Pesticides (GC) by Method 8081B 15
Semi Volatile Organic Compounds (GC/MS) by Method 8270E 16
GI: Glossary of Terms 18
Al: Accreditations & Locations 19
Sc: Sample Chain of Custody 20
Cp
2
Tc
3
SS
4
Cn
5
Sr
LQC]
GI
s
Al
9
SC
ACCOUNT:
EMA Resources
PROJECT: SDG: DATE/TIME: PAGE:
L1432018 12/15/21 14:37 2 of 20

SAMPLE SUMMARY
HILLSBOROUGH L1432018-01 Waste
Collected by
Brent Collins
Collected date/time Received date/time
11/15/21 08:00 11/16/21 09:15
Method
Preparation by Method 1311
Preparation by Method 1311
Wet Chemistry by Method 9012 B
Wet Chemistry by Method 9034-9030B
Wet Chemistry by Method 9045D
Wet Chemistry by Method D93/1010A
Mercury by Method 7470A
Metals (ICP) by Method 6010D
Volatile Organic Compounds (GC/MS) by Method 8260D
Chlorinated Acid Herbicides (GC) by Method 8151A
Pesticides (GC) by Method 8081B
Semi Volatile Organic Compounds (GC/MS) by Method 8270E
Batch Dilution Preparation
date/time
W G 1779303 1 11/23/2116:45
W G1781099 1 11/30/2111:45
W G1776989 1 11/19/2114:43
W G 1778110 1 11 / 21 /2118: 2 2
W G1777759 1 11/20/2110:05
W G 1777 016 1 11/19/21 0 4:2 6
W G 178 89 98 1 12 /14 /2110:48
W G 1789073 1 12/14/2112:19
W G1780074 1 11/27/2117:21
W G 17849 2 9 1 12/02/21 07:59
WG1782025 1 12/01/21 20:30
W G 178 2 49 0 1 12/01/21 21:13
Analysis
date/time
11/23/2116:45
11/30/2111:45
11/20/21 03:35
11/23/21 03:11
11/20/2112:00
11/19/21 04:26
12/15/2110:32
12/15/21 00:02
11/27/2117:21
12/06/2114:29
12/02/2113:41
12/02/21 03:19
Analyst Location
APH
APH
SDL
CAT
SDE
CAT
ABL
CCE
BMB
HMH
AM M
AMG
Mt. Juliet, TN
Mt. Juliet, TN
Mt. Juliet, TN
Mt. Juliet, TN
Mt. Juliet, TN
Mt. Juliet, TN
Mt. Juliet, TN
Mt. Juliet, TN
Mt. Juliet, TN
Mt. Juliet, TN
Mt. Juliet, TN
Mt. Juliet, TN
i
Cp
z
Tc
3
Ss
4
Cn
5
Sr
LQC]
GI
8
AI
9
Sc
ACCOUNT:
EMA Resources
PROJECT: SDG:
L1432018
DATE/TIME:
12/15/21 14:37
PAGE:
3 of 20

CASE NARRATIVE
All sample aliquots were received at the correct temperature, in the proper containers, with the
appropriate preservatives, and within method specified holding times, unless qualified or notated within
the report. Where applicable, all MDL (LOD) and RDL (LOQ) values reported for environmental samples
have been corrected for the dilution factor used in the analysis. All Method and Batch Quality Control
are within established criteria except where addressed in this case narrative, a non-conformance form
or properly qualified within the sample results. By my digital signature below, I affirm to the best of my
knowledge, all problems/anomalies observed by the laboratory as having the potential to affect the
quality of the data have been identified by the laboratory, and no information or data have been
knowingly withheld that would affect the quality of the data.
Justin Carr
Project Manager
Project Narrative
All Reactive Cyanide results reported in the attached report were determined as totals using method 9012 B.
All Reactive Sulfide results reported in the attached report were determined as totals using method 9034-9030B.
Co
Tc
3
Ss
Cn
5
Sr
L0C]
GI
rAI1
9
SC
ACCOUNT:
EMA Resources
PROJECT: SDG: DATE/TIME: PAGE:
L1432018 12/15/21 14:37 4 of 20

HILLSBOROUGH SAMPLE RESULTS - 01
Collected date/time: 11/15/21 08:00 L1432018
Preparation by Method 1311
Result Qualifier Prep Batch
Analyte date / time
TCLP Extraction - 11/30/202111:45:22 AM WG1781099
TCLP 7HE Extraction - 11/23/2021 4:45:18 PM WG1779303
Fluid 1 11/30/202111:45:22 AM WG1781099
Initial pH 6.96 11/30/202111:45:22 AM WG1781099
Final pH 5.02 11/30/202111:45:22 AM WG1781099
Wet Chemistry by Method 9012 B
Analyte
Result Qualifier RDL Dilution Analysis
mg/kg mg/kg date / time
Batch
Reactive Cyanide ND 0.250 1 11/20/2021 03:35 WG1776989
Wet Chemistry by Method 9034-9030B
Analyte
Reactive Sulfide
Result Qualifier RDL Dilution Analysis Batch
mg/kg mg/kg date / time
31.3 25.0 1 11/23/2021 03:11 WG1778110
Wet Chemistry by Method 9045D
Result Qualifier Dilution Analysis
Analyte su date / time
Corrosivity by pH
Sample Narrative:
L1432018-01 W91777759: 6.69 at 19.8C
Batch
6.69 T8 1 11/20/202112:00 WG1777759
Wet Chemistry by Method D93/1010A
Result Qualifier Dilution Analysis Batch
Analyte Deg. F date /time
—
Ignitability DNI at 170 1 11/19/2021 04:26 WG1777016
Mercury by Method 7470A
Result Qualifier RDL Limit Dilution Analysis Batch
Analyte mg/I mg/I mg/ date/time
Meicury ND 0.0100 0.20 1 12/15/202110:32 WG1788998
Metals (ICP) by Method 6010D
Result Qualifier RDL Limit Dilution Analysis Batch
Analyte mg/I mg/I mg/ date/time
—
Arsenic ND 0.100 5 1 12/15/2021 00:02 WG1789073
Barium ND 0.100 100 1 12/15/2021 00:02 WG1789073
Cadmium ND 0.100 1 1 12/15/2021 00:02 WG1789073
Chromium ND 0.100 5 1 12/15/2021 00:02 WG1789073
Lead ND 0.100 5 1 12/15/2021 00:02 WG1789073
Selenium ND 0.100 1 1 12/15/2021 00:02 WG1789073
Silver ND 0.100 5 1 12/15/2021 00:02 WG1789073
Volatile Organic Compounds (GC/MS) by Method 8260D
Result Qualifier RDL Limit Dilution Analysis Batch
Analyte mg/I mg/I mg/ date/time
Benzene ND 0.0500 0.50 1 11/27/202117:21 WG1780074
Carbon tetrachloride ND 0.0500 0.50 1 11/27/2021 17:21 WG1780074
Chlorobenzene ND 0.0500 100 1 11/27/202117:21 WG1780074
Chloroform ND 0.250 6 1 11/27/202117:21 WG1780074
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
EMA Resources L1432018 12/15/2114:37 5 of 20

HILLSBOROUGH SAMPLE RESULTS - 01
Collected date/time: 11/15/21 08:00 L1432018
Volatile Organic Compounds (GC/MS) by Method 8260D
Result Qualifier RDL Limit Dilution Analysis Batch
Analyte mg/I mg/I mg/1 date/time
1,2-Dichloroethane ND 0.0500 0.50 1 11/27/202117:21 WG1780074
1,1-Dichloroethene ND 0.0500 0.70 1 11/27/202117:21 WG1780074
2-Butanone (MEK) ND 0.500 200 1 11/27/202117:21 WG1780074
Tetrachloroethene ND 0.0500 0.70 1 11/27/202117:21 WG1780074
Trichloroethene ND 0.0500 0.50 1 11/27/202117:21 WG1780074
Vinyl chloride ND J4 0.0500 0.20 1 11/27/202117:21 WG1780074
(S) Toluene-d8 101 80.0-120 11/27/202117:21 WG1780074
(S)4-Bromofluorobenzene 98.3 77.0-126 11/27/202117:21 WG1780074
(S)1,2-Dichloroethane-d4 88.2 70.0-130 11/27/202117:21 WG1780074
Chlorinated Acid Herbicides (GC) by Method 8151A
Result Qualifier RDL Limit Dilution Analysis Batch
Analyte mg/I mg/I mg/1 date/time
2,4,5-TP (Silvex) ND Q 0.00200 1 1 12/06/202114:29 WG1784929
2,4-D ND Q 0.00200 10 1 12/06/202114:29 WG1784929
(S) 2,4-Dichlorophenyl Acetic Acid 99.6 14.0-158 12/06/202114:29 WG1784929
Pesticides (GC) by Method 8081B
Result Qualifier RDL Limit Dilution Analysis Batch
Analyte mg/I mg/I mg/ date/time
Chlordane ND 0.00500 0.03 1 12/02/202113:41 WG1782025
Endrin ND 0.00500 0.02 1 12/02/202113:41 WG1782025
Heptachlor ND 0.00500 0.0080 1 12/02/202113:41 WG1782025
Heptachlor epoxide ND 0.00500 0.0080 1 12/02/202113:41 WG1782025
Lindane ND 0.00500 0.40 1 12/02/202113:41 WG1782025
Methoxychlor ND 0.00500 10 1 12/02/202113:41 WG1782025
Toxaphene ND 0.0100 0.50 1 12/02/202113:41 WG1782025
(S) Decachlorobiphenyl 82.1 10.0-128 12/02/202113:41 WG1782025
(S) Tetrochloro-m-xylene 79.5 10.0-127 12/02/202113:41 WG1782025
Semi Volatile Organic Compounds (GC/MS) by Method 8270E
Result Qualifier RDL Limit Dilution Analysis Batch
Analyte mg/I mg/I mg/ date/time
1,4-Dichlorobenzene ND 0.100 7.50 1 12/02/2021 03:19 WG1782490
2,4-Dinitrotoluene ND 0.100 0.13 1 12/02/2021 03:19 WG1782490
Hexachlarobenzene ND 0.100 0.13 1 12/02/2021 03:19 WG1782490
Hexachlaro-1,3-butadiene ND 0.100 0.50 1 12/02/2021 03:19 WG1782490
Hexachlaroethane ND 0.100 3 1 12/02/2021 03:19 WG1782490
Nitrobenzene ND 0.100 2 1 12/02/2021 03:19 WG1782490
Pyridine ND 0.100 5 1 12/02/2021 03:19 WG1782490
3&4-Methyl Phenol ND 0.100 400 1 12/02/2021 03:19 WG1782490
2-Methylphenol ND 0.100 200 1 12/02/2021 03:19 WG1782490
Pentachlorophenol ND 0.100 100 1 12/02/2021 03:19 WG1782490
2,4,5-Trichlorophenol ND 0.100 400 1 12/02/2021 03:19 WG1782490
2,4,6-Trichlorophenol ND 0.100 2 1 12/02/2021 03:19 WG1782490
(S) 2-Fluorophenol 36.0 10.0-120 12/02/2021 03:19 WG1782490
(S) Phenol-d5 24.8 10.0-120 12/02/2021 03:19 WG1782490
(S) Nitrobenzene-d5 61.2 10.0-127 12/02/2021 03:19 WG1782490
(S) 2-Fluorobiphenyl 70.5 10.0-130 12/02/2021 03:19 WG1782490
(S)2,4,6-Tribromophenol 63.5 10.0-155 12/02/2021 03:19 WG1782490
(S) p-Terphenyl-d14 63.0 10.0-128 12/02/2021 03:19 WG1782490
Cp
z
Tc
3
SS
4
Cn
5
Sr
5
Qc
GI
9
Sc
ACCOUNT:
EMA Resources
PROJECT: SDG: DATE/TIME: PAGE:
L1432018 12/15/2114:37 6 of 20

WG1776989
Wet Chemistry by Method 9012 B
Method Blank (MB)
(MB) R3731880-1 11/20/21 03:01
Reactive Cyanide
Laboratory Control Sample (LCS)
(LCS) R3731880-2 11/20/21 03:02
.0)
0
U
d
N
o
d)
L)
3
O
E
d
.n
0
03
E
03
O]
E
a)
7
CCV
9
Reactive Cyanide
DATE/TIME:
ACCOUNT:
12/152114:37
EMA Resources

WG1778110
Wet Chemistry by Method 9034-9030B
Method Blank (MB)
Reactive Sulfide
Laboratory Control Sample (LCS)
(LCS) R3732617-2 11/23/21 03:11
.0)
0
U
E
a)
0
O
o �
d
N
o
d)
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U
0
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d
E
O]
E
O
DATE/TIME:
ACCOUNT:
12/152114:37
EMA Resources

Q
U
v
H
(n
c
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(n
Lrl
0
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Q
v
(n
WG1777759
Wet Chemistry by Method 9045D
DUP Qualifier
CO
(!) o a
O
Corrosivity by pH
DUP: 6.71 at 19.7C
Laboratory Control Sample (LCS)
d
E
V)
o
•
0)
L)
0
0
Sample Narrative:
LCS: 10 at 18.6C
< 0
0,
DATE/TIME:
w
0
0
a
ACCOUNT:
12/15/21 14:37
a
0
a
w

Q
U
v
H
cn
c
U
C.
v
0
Lo
('D
00
QUALITY CONTROL SUMMARY
WG1777016
00
Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD)
(LCS) R3731430-1 11/19/21 04:26 • (LCSD) R3731430-2 11/19/21 04:26
E
a
o_
E
O
L)
U
4)
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U
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4)
N
U
J
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0
N
o �
0
Ll
a1
LL
a1
LL
a1
N
l0
0
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w N
<
a 0
a 0
DATE/TIME:
w
w
O
0
a
ACCOUNT:
12/15/21 14:37

Method Blank (MB)
(MB) R3740877-1 12/15/21 10:10
0 0
c o
o] 5,
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4)
0
Laboratory Control Sample (LCS)
(LCS) R3740877-2 12/15/21 10:12
.0)
0
U
E
a)
O
o
M
DATE/TIME:
ACCOUNT:
12/152114:37
EMA Resources

Q
U
Method Blank (MB)
(MB) R3740823-1 12/14/21 23:30
v
H
cn
c
U
cn
O O O O O O O
O O O O O O O
E O O O O O O O
CO CO CO CO CO CO CO
CO CO CO CO CO CO CO
0') 0') 0') 0') 0') 0') 0')O) O O O O O O O
E co co co co O O O
E E
>, E
c ro ro
Q Q o] U U to to
v
0
Laboratory Control Sample (LCS)
('D
(LCS) R3740823-2 12/14/21 23:33
Q
v
cn
O O O O O O O
N N N N N N N
O O O O O O O
O O O O O O O
o Op Op Op Op Op Op Op
CO CO M n O M
0 6) 6) a 6) a 6) 6)
75)
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LS) CO c
o 0 0 0 0 0
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O
0
= E
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c ro rn
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DATE/TIME:
ACCOUNT:
12/152114:37
EMA Resources

0
U
0
H
cn
c
U
cn
0
to
0
('D
Q
0
cn
WG1780074
Volatile Organic Compounds (GC/MS) by Method 8260D
Method Blank (MB)
J O 00 O
0 0 0 0 0 O O O N
o M
0 0 0 0 0 0 0 0 0 0
Ln LC) LtD LtD LtD LtD o LtD Lo Lo 0 o O
00 O) O O 0 N O O LtD O O O O O
E O O O O O O O O O O co N. N.
J
C. n n n M n n n n n
0 0 O W LID LID n LID LID LID
00 O) O O O 0 0 0 0 O O O
E O O O O O O O O O O
N
Q
00
0)
CD
CC
N — co — co
d- .0O O'i O'i Oj
Ln E o = = = 0 0 = = = o O7 O7 co
N
N
(0
L i) C 4? Y = Co
00 N E O 0 C O -6
m a) ° a 0 O 0 0 0` __
tv c c ▪ ro
▪ a) c0 O O L O
m (O C S O O p m E
C a? tO N d U c
- Q 0] 0 0 0 N H H
(S) 4-Bromofuorobenzene
(S)1,2-Dichloroethane-d4
Laboratory Control Sample (LCS)
(LCS) R3734365-1 11/27/2112:41
< 0
a 00
DATE/TIME:
81
.
0
U .EI01 w
0
_ ce
E 00 LO O CO 71-
0 N ('F CD 00 CDJ N (V Ri CV N N cO M 0,1M N M
0 0 0 0 0 0 0 0 0 0 0 0 0
0 o o^ 0 OD 03 o^ 0 03 ar\`' coo co n o^
d
O:
W O 4
J o O 6l cn O7 47 O7
d)
0= (X] O cO cO ( n O N r
N n c0 Lf) LC) n M LC) 00 CO
J E O I N N N N N N N N C'r)
OOOOOOOO
0
O
E
O ▪ O O O O O O
— Ln Ln Ln Ln Ln Ln
'n O] N N N N N N
V) E O O O O O O
Carbon tetrachloride
Chlorobenzene
E
0
0
0
0
1,2-Dichloroethane
1,1-Dichloroethene
LtD
N
O O O
O O O
Lt) Lt) Lt)
N N N
Trichloroethene
Vinyl chloride
ACCOUNT:
12/15/21 14:37
a)
O
O
0)
w

0
U
0
H
0
cn
c
U
cn
0
0
co
('D
WG1784929
Chlorinated Acid Herbicides (GC) by Method 8151A
Method Blank (MB)
O
E
0
m 00
E
N
0
07
O O
0 0
N N
O O
O O
0 0
n N-
u) l0
O O
0 0
0 0
0 0
00
0
0
00 00 rn
rz
▪ Ni
o n `a
N N Q
Laboratory Control Sample (LCS)
(LCS) R3737553-2 12/06/2114:14
0
U
0I
E o
O O
d) O O
• o f) n
d
o
4)
U
LS)
E
00
0) n
0) O] CD
N N-
0 0
O 0
0 0
O 0
0 0
Lr) Lr)
0 0
DATE/TIME:
ACCOUNT:
12/15/21 14:37

0
U
0
H
cn
c
U
cn
0
0
co
('D
Q
0
cn
0
m
0
LO
N
O^
N
Method Blank (MB)
(MB) R3737263-1 12/02/21 12:15
-I OD O O 0 0 0 OD
O 0 0 0 0 0 0 0
Li, Li, Li, Li, Li, Li,
0 0 0 0 0 0 INI NI
O O O
m O] O O O O O O O O
E O O O O O O o
J n ^ ^ ^ ^ h co
t0 t0 t0 t0 t0 t0 M
0 0 0 0 0 0 0
CO ai O O O O O O O
E O O O O O O O
a)
0
m
3
01
a)
O-] N
E o > > > > > > N. co
0
LL
0
lG
O_
CU
Heptachlor epoxide
(S) Decachlorobiphenyl
(S) Tetrachloro-m-xylene
Laboratory Control Sample (LCS)
(LCS) R3737263-2 12/02/2112:24
0
U
N O LO (0 I�
C M CO CO NI NI
O O O O
N Ln ^ ^ ^ O O
� o Ln Ln N Ln Ln
a)
LY
( Li, in
J o 6l 6l 6l co
6 6 0 0
L.)O O O
0 0 0 0
E o 0 0 0
c
0
0
E
O O O O O
a, 0 0 0 0 0
6. O] O O O O O
VI E O O O O O
O
0
0
0
O_
Heptachlor epoxide
0
X
O
(S) Decachlorobiphenyl
(S) Tetrachloro-m-xylene
DATE/TIME:
ACCOUNT:
12/15/21 14:37
EMA Resources

0
H
0
cn
c
U
cn
0
0
('D
Q
0
cn
WG1782490
Semi Volatile Organic Compounds (GC/MS) by Method 8270E
Method Blank (MB)
J n O 03 O O Ltd
O 0, 0, 0, L
CC O O O O O O O O O O O O
m 0, O O O O O O O O O O O O O O O O O O
E a a a a a a a a a a a a o o o o o o
J
0 CO CO CO CO CO CO Cr) Cr) M M M M
M M M M M M M M M M M M
M M M M M M M M M M M M
07 O) O O O O O O O O O O O O
E O O O O O O O O O O O O
4)
Q
m
3
01
0
m a) 03 v
E > > > > > > > > > > > > ,n CO co CO co N 0) M CO co
1,4-Dichlorobenzene
2,4-Dinitrotoluene
Hexachlorobenzene
Hexachloro-1,3-butadiene
Hexachloroethane
Nitrobenzene
c
0
0
a
0
(V
3&4-Methyl Phenol
Pentachlorophenol
2,4,5-Trichlorophenol
2,4,6-Trichlorophenol
(S) Nitrobenzene-d5
(S) 2-Fluorob1phenyl
0
ti
0
N
(S) 2,4, 6-Tribromophenol
Laboratory Control Sample (LCS)
(LCS) R3736397-1 12/01/21 23:46
p O p p O O O O O p O 0 O 03
N N ro N (0 N N N 0) N
O O p p O O O O O O O O O O
N c, M N O O O
a,
� (O CO cO m co N CO co m 71F cO Oa CO
J o LO O (0 (0 LO (0 OM O LO I0 O CO CO CO CO
d)
0�
U
0
0
E
0
0
0)
O)
E
CO CO CO OThO 03 6) N 00
M
N �'F cc) cc)N M N N M �'F M
0 0 0 0 0 0 0 0 0 0 0 0
O O O O O O O O O O O O
00 00 00 00 00 00 00 00 00 00 00 00
E 0 0 0 0 0 0 0 0 0 0 0 0
0
0
a)
0
0
0
m
Q �
2,4-Dinitrotoluene
Hexachlorobenzene
Hexachloro-1,3-butadiene
Hexachloroethane
0
0
0
Z
0
Q
0_ N
3&4-Methyl Phenol
Pentachlorophenol
0 0
0 0
__c
0_ 0_
0 0
0 0
I— 170 IA
�F �F
N N
(S) Nitrobenzene-d5
(S) 2-Fluorobrphenyl
(S) p-Terphenyl-d14
DATE/TIME:
ACCOUNT:
12/152114:37
EMA Resources

Q
U
v
H
cn
c
U
cn
v
0
co
('D
00
WG1782490
Semi Volatile Organic Compounds (GC/MS) by Method 8270E
Laboratory Control Sample (LCS)
(LCS) R3736397-1 12/01/21 23:46
U
d
V)
J o
N N_
O O O
O O O
Ni O
Uri W Co
N M O
(S) 2,4, 6-Tribromophertol
DATE/TIME:
12/15/21 14:37
0
CV
N 7
0
U
0
0
a
ACCOUNT:

GLOSSARY OF TERMS
Guide to Reading and Understanding Your Laboratory Report
The information below is designed to better explain the various terms used in your report of analytical results from the Laboratory. This is not
intended as a comprehensive explanation, and if you have additional questions please contact your project representative.
Results Disclaimer - Information that may be provided by the customer, and contained within this report, include Permit Limits, Project Name,
Sample ID, Sample Matrix, Sample Preservation, Field Blanks, Field Spikes, Field Duplicates, On -Site Data, Sampling Collection Dates/Times, and
Sampling Location. Results relate to the accuracy of this information provided, and as the samples are received.
Abbreviations and Definitions
MDL Method Detection Limit.
ND Not detected at the Reporting Limit (or MDL where applicable).
RDL Reported Detection Limit.
Rec. Recovery.
RPD Relative Percent Difference.
SDG Sample Delivery Group.
Surrogate (Surrogate Standard) - Analytes added to every blank, sample, Laboratory Control Sample/Duplicate and
(S) Matrix Spike/Duplicate; used to evaluate analytical efficiency by measuring recovery. Surrogates are not expected to be
detected in all environmental media.
U Not detected at the Reporting Limit (or MDL where applicable).
Analyte The name of the particular compound or analysis performed. Some Analyses and Methods will have multiple analytes
reported.
If the sample matrix contains an interfering material, the sample preparation volume or weight values differ from the
Dilution standard, or if concentrations of analytes in the sample are higher than the highest limit of concentration that the
laboratory can accurately report, the sample may be diluted for analysis. If a value different than 1 is used in this field, the
result reported has already been corrected for this factor.
These are the target % recovery ranges or % difference value that the laboratory has historically determined as normal
Limits for the method and analyte being reported. Successful QC Sample analysis will target all analytes recovered or
duplicated within these ranges.
Original Sample The non -spiked sample in the prep batch used to determine the Relative Percent Difference (RPD) from a quality control
sample. The Original Sample may not be included within the reported SDG.
This column provides a letter and/or number designation that corresponds to additional information concerning the result
Qualifier reported. If a Qualifier is present, a definition per Qualifier is provided within the Glossary and Definitions page and
potentially a discussion of possible implications of the Qualifier in the Case Narrative if applicable.
The actual analytical final result (corrected for any sample specific characteristics) reported for your sample. If there was
no measurable result returned for a specific analyte, the result in this column may state "ND" (Not Detected) or "BDL"
Result (Below Detectable Levels). The information in the results column should always be accompanied by either an MDL
(Method Detection Limit) or RDL (Reporting Detection Limit) that defines the lowest value that the laboratory could detect
or report for this analyte.
Uncertainty
(Radiochemistry)
Case Narrative (Cn)
Quality Control
Summary (Qc)
Sample Chain of
Custody (Sc)
Sample Results (Sr)
Sample Summary (Ss)
Confidence level of 2 sigma.
A brief discussion about the included sample results, including a discussion of any non -conformances to protocol
observed either at sample receipt by the laboratory from the field or during the analytical process. If present, there will
be a section in the Case Narrative to discuss the meaning of any data qualifiers used in the report.
This section of the report includes the results of the laboratory quality control analyses required by procedure or
analytical methods to assist in evaluating the validity of the results reported for your samples. These analyses are not
being performed on your samples typically, but on laboratory generated material.
This is the document created in the field when your samples were initially collected. This is used to verify the time and
date of collection, the person collecting the samples, and the analyses that the laboratory is requested to perform. This
chain of custody also documents all persons (excluding commercial shippers) that have had control or possession of the
samples from the time of collection until delivery to the laboratory for analysis.
This section of your report will provide the results of all testing performed on your samples. These results are provided
by sample ID and are separated by the analyses performed on each sample. The header line of each analysis section for
each sample will provide the name and method number for the analysis reported.
This section of the Analytical Report defines the specific analyses performed for each sample ID, including the dates and
times of preparation and/or analysis.
Qualifier Description
J4 The associated batch QC was outside the established quality control range for accuracy.
P RPD between the primary and confirmatory analysis exceeded 40%.
Sample was prepared and/or analyzed past holding time as defined in the method. Concentrations should be
considered minimum values.
T8 Sample(s) received past/too close to holding time expiration.
ACCOUNT:
EMA Resources
PROJECT: SDG: DATE/TIME: PAGE:
L1432018 12/15/21 14:37 18 of 20

ACCREDITATIONS & LOCATIONS
Pace Analytical National 12065 Lebanon Rd Mount Juliet, TN 37122
Alabama
40660
Alaska
17-026
Arizona A20612
Arkansas 88-0469
California 2932
Colorado _ TN00003
Connecticut PH-0197
Florida E87487
Georgia NELAP
Georgia 923
Idaho TN00003
Illinois 200008
Indiana C-TN-01
Iowa 364
Kansas E-10277
Kentucky1° KY90010
Kentucky2 16
Louisiana A130792
Louisiana LA018
Maine TN00003
Maryland 324
Massachusetts M-TN003
Michigan 9958
Minnesota 047-999-395
Mississippi TN00003
Missouri 340
Montana CERT0086
Nebraska NE-0S-15-05
Nevada TN000032021-1
New Hampshire 2975
New Jersey—NELAP TN002
New Mexico' TN00003
New York 11742
North Carolina Env375
North Carolina DW21704
North Carolina' 41
North Dakota R-140
Ohio—VAP CL0069
Oklahoma 9915
Oregon TN200002
Pennsylvania 68-02979
Rhode Island LA000356
South Carolina 84004002
South Dakota n/a
Tennessee'" 2006
Texas T104704245-20-18
Texas LAB0152
Utah TN000032021-11
Vermont VT2006
Virginia 110033
Washington C847
West Virginia 233
Wisconsin 998093910
Wyoming A2LA
A2LA — ISO 17025 1461.01 AIHA-LAP,LLC EMLAP 100789
A2LA— ISO 17025 5 1461.02 DOD 1461.01
Canada 1461.01 USDA P330-15-00234
EPA—Crypto TN00003
'Drinking Water 2 Underground Storage Tanks 3 Aquatic Toxicity ° Chemical/Microbiological 5 Mold 6 Wastewater n/a Accreditation not applicable
* Not all certifications held by the laboratory are applicable to the results reported in the attached report.
* Accreditation is only applicable to the test methods specified on each scope of accreditation held by Pace Analytical.
Co
Tc
3
SS
4
Cn
5
Sr
LQC]
GI
9
SC
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
EMA Resources L1432018 12/15/21 14:37 19 of 20

Company Name/Address:
Billing Information:
Analysis / Container / Preservative
Chain of Custody Page __ of
EMA Resources
Mr. Brent Collins
755 Yadkinville Road
Pres
Chk
Analytical
755 Yadkinville Road
Mocksville, NC 27028
Mocksville, NC 27028
CRSV IL-CIr-N©Pres
TCLP - full 1L-CIr-NoPres
ace
Report to',
Mr. Brent Collins
-
Email To:
[e-mail];roy.whitak
1206S lebandn Ad Movnl lukel. TN 37177
Submitting ' ,md`""°"lachai"°lea"°d
codatdudesackno„ded6meetaedavenia"eeoltAa
Pate terms tndtonddrane found at
PrOJPCt Description:
Sludge
City/State �
Collected: lei/CX�b(ev�4/A
/ ��[ -/
Please Circle:
PT MT CT ET
httµsHtnt°.ptcelabs..cwnfhabfs/ws-ttaad rd•
MIMS pa,
Phone: [phone]
Client Project
g
Lab Project 4
SDG JJ / l v /'%( g
F238
Coll t
Site/Facility ID
#
P.O. q
cted Viy ri/n�t�):
(MA c. t,s$
AcctnmM u: EARES
Collected by (signature):
Rush? (Lab
_Same Day
MUST Be
_Five Day
Notified)
Quote #
Tempiate:T11413
Prelogin: P856932
Immediately
Packed an Ice N Y
Next Day
Two Day
Three Day
5 Day
_ 10 Day
(Rad Only) Date Results
(Rad Only)
Needed
No
PM: 807 - Justin Carr
Pa: 10 (a ! LlF I
uj� ^ Lr�J
Of
•
Cntrs
Shipped Via: FedEt Groun
Sample ID
Comp/Grab
Matrix
I
Depth Date
Time
1
Remarks I Sample a (lab only)
'ifs.. coot,
_ C
ss
3'
//1/3e
$ oa
2
x
x
- -
�©1
"Matrix:
Remarks:
Sample Receipt Checkii/e'
SS - Soil AIR - Air F- Filter
PH Temp
COC Seal Present/intact: NP ` Yr— ?a,
GW - Groundwater 8 - Bioassay
WW Wastewater
Flow other
COC Signed/Accurate: y nl
Bottles arrive intact: to
Correct bottles used: *'
DW - Drinking Water
DT - Other
Samples returned via:
Tracking It
Sufficient volume sent: 6erliN
Applicable
UPS FedEx Courier
VOA Zero Headapace: Y N'
a
— _ _
Relinquished b : (Signature
Date
`, j/ I
/•// S
Time:
�,
Received by: {Signature)
Trip Blank Received: Yes /Otd
MeoH
Preservation Cor sect/Checked: a
RAD Screen <1J.5 mR/hr:_�:
TBRNCI.
TBR
Relinquished by : (Signature)
Date:
Time:
Received by: (signature)
Tem :'� /!{5 / Bottles Received.
If preservation required by Login: Date/Time
Relinquished by : (Signature)
Date
Time:
ec ve iab by (Signature)
l / Ti
(J 441 0 1�
?I
Hold:
Condition:
NCF / lf/.rry7

Page 1 of 1
Report Number: 21-355-0869
Account Number:46245
Send To: EMA Resources Inc
755 Yadkinville Road
Mocksville NC 27028
Date Received: 12/21/2021
Waypoint.
ANALYTICAL
Date Of Analysis: 12/22/2021
Farm: OR03
7621 Whitepine Road, Richmond, VA 23237
Main 804-743-9401 ° Fax [phone]
www.waypointanalytical.com
"Every acre...Every year. "m, Grower: Richard Vanhook
SOIL ANALYSIS REPORT
Date Of Report: 12/22/2021
Analytical Method(s): Mehlich 3 SMP Buffer pH Loss On Ignition Water pH
NC = North Carolina Fertility Index Value
Sample ID
Field ID
Lab
Number
HM
W/V
ENR
Phosphorus
Potassium
Magnesium
Calcium
Sodium
pH
Acidity
C.E.0
%
Soil
Class
Ibs/A
M3
ppm Rate
ppm Rate
ppm Rate
K
ppm Rate
Mg
ppm Rate
Ca
ppm Rate
Na
ppm Rate
Soil
pH
Buffer
Index
H
meq/100g
meq/100g
01
24471
1.6
117
123 VH
NC = 102
57 L
NC = 29
223 VH
641 M
16 VL
5.9
6.82
1.1
6.4
MIN
02
24472
1.8
128
55 H
NC = 46
91 M
NC = 47
160 H
659 M
13 VL
6.0
6.84
0.9
5.8
MIN
03
24473
2.1
144
48 M
NC = 40
99 M
NC = 51
231 H
970 M
18 VL
6.2
1.0
8.1
MIN
04
24474
1.2
95
264 VH
NC = 220
28 VL
NC = 14
139 H
1124 H
26 VL
6.6
0.4
7.4
MIN
05
24475
1.7
126
167 VH
NC = 139
102 H
NC = 52
113 H
388 L
15 VL
5.6
6.83
1.0
4.2
MIN
SampleID
Field IDD
Percent Base Saturation
Nitrate
Sulfur
Zinc
Manganese
Iron
Copper
Boron
Soluble Salts
K
%
Mg
%
Ca
%
Na
%
H
%
NO3 N
ppm Rate
S
ppm Rate
Zn
ppm Rate
Mn
ppm Rate
Fe
ppm Rate
Cu
ppm Rate
B
ppm Rate
SS
ms/cm Rate
01
2.3
29.0
50.1
1.1
17.2
26 H
NC = 54
16.7 VH
NC = 417.5
76 VH
NC = 475
3.6 VH
NC = 180.0
0.3 VL
02
4.0
23.0
56.8
1.0
15.5
14 L
NC=29
7.5 H
NC=187.5
141 VH
NC=881
1.9 H
NC=95.0
0.3 VL
03
3.1
23.8
59.9
1.0
12.3
17 M
NC = 35
7.2 H
NC = 180.0
117 VH
NC = 731
2.5 H
NC = 125.0
0.4 L
04
1.0
15.7
75.9
1.5
5.4
12 L
NC = 25
24.3 VH
NC = 607.5
18 M
NC = 113
11.0 VH
NC = 550.0
0.3 VL
05
6.2
22.4
46.2
1.6
23.8
23 M
NC = 48
18.0 VH
NC = 450.0
109 VH
NC = 681
3.0 H
NC = 150.0
0.2 VL
Values on this report represent the plant available nut ients in the
soil. Rating after each value: VL (Very Low), L (Low), M (Medium),
H (High), VH (Very High). ENR - Estimated Nitrogen Release.
C.E.C. - Cation Exchange Capacity.
Explanation of symbols: % (percent), ppm (parts per million), lbs/A
(pounds per acre), ms/cm (milli -mhos per centimeter), meq/100g
(milli -equivalent per 100 grams). Conversions: ppm x 2 = lbs/A, Soluble
Salts ms/cm x 640 = ppm.
This repor applies to sample(s) tested. Samples are retained a
maximum of thirty days after testing.
Analysis prepared by: Waypoint Analytical Virginia. Inc.
by: wiz mt Groaj,
Pauric Mc Groary Ph.D., CPAg

2021 Hillsborough Annual Report - WQ0038580
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2021 Hillsborough Annual Report - WQ0038580
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