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Home My WebLink AboutWQ0001026_Residual Annual Report 2021_20220228Initial Review Reviewer EADS\ndthornburg Is this submittal an application? (Excluding additional information.)* Yes No If not an application what is the submittal type?* Annual Report Residual Annual Report Additional Information Other Annual Report Year* 2021 Permit Number (IR) * WQ0001026 ApplicantlPermittee City of Washington Email Notifications Does this need review by the hydrogeologist?* Yes No Regional Office Washington CO Reviewer Admin Reviewer Submittal Form Project Contact Information Please provide information on the person to be contacted by NDB Staff regarding electronic submittal, confirmation of receipt, and other correspondence. ............................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................ Name* Brent Collins Email Address* brent.collins@emaresourcesinc.com Project Information Application/Document Type* New (Fee Required) Modification - Major (Fee Required) Renewal with Major Modification (Fee Required) Annual Report Additional Information Other Phone Number* 336-399-3646 Modification - Minor Renewal GW-59, NDMR, NDMLR, NDAR-1, N DAR-2 Residual Annual Report Change of Ownership We no longer accept these monitoring reports through this portal. Please click on the link below and it will take you to the correct form. hftps://edocs.deq.nc.gov/Forms/NonDischarge_Monitoring_Report Perm it Type:* Wastewater Irrigation High -Rate Infiltration Other Wastewater Reclaimed Water Closed -Loop Recycle Residuals Single -Family Residence Wastewater Other Irrigation Permit Number: * WQ0001026 Has Current Existing permit number Applicant/Permittee Address* PO Box 1988, Washington, NC 27889 Facility Name* City of Washington Class B Residuals Program Please provide comments/notes on your current submittal below. At this time, paper copies are no longer required. If you have any questions about what is required, please contact Nathaniel Thornburg at nathaniel.thornburg@ncdenr.gov. Please attach all information required or requested for this submittal to be reviewed here. (Application Form, Engineering Plans, Specifications, Calculations, Etc.) 2021 Washington Annual Report - W00001026.pdf 9.21 MB Upload only 1 PDF document (less than 250 MB). Multiple documents must be combined into one PDF file unless file is larger than upload limit. * By checking this box, I acknowledge that I understand the application will not be accepted for pre -review until the fee (if required) has been received by the Non - Discharge Branch. Application fees must be submitted by check or money order and made payable to the North Carolina Department of Environmental Quality (NCDEQ). I also confirm that the uploaded document is a single PDF with all parts of the application in correct order (as specified by the application). Mail payment to: NCDEQ — Division of Water Resources Attn: Non -Discharge Branch 1617 Mail Service Center Raleigh, NC 27699-1617 Signature Submission Date 2/28/2022 MA --Resources, Inc. February 28, 2022 DENR/Water Quality Section Non -Discharge Compliance Unit 1617 Mail Service Center Raleigh, NC 27699-1617 Re: 2021 Annual Report - Washington Treatment and Land Application of Residuals Permit No. WQ0001026 Dear Sir or Madam: Enclosed is one copy of the 2021 Annual Report for the above referenced land application permit. During 2021 EMA Resources, Inc. land applied 499.4 dry tons of wastewater residuals to 205 acres of private farmland. Please contact Brent Collins - Director of Technical Services if you have any further questions regarding this report. Sincerely, Brent Collins Director of Technical Services brent.collins@emaresourcesinc.com Phone 336.751.1441 — Fax 336.751.1442 755 Yadkinville Rd — Mocksville, NC 27028 ---Resources, Inc. City of Washington 2021 Annual Report Residuals Land Application Permit No. WQ0001026 Prepared By: EMA Resources, Inc. Phone 336.751.1441 — Fax 336.751.1442 755 Yadkinville Rd — Mocksville, NC 27028 ANNUAL LAND APPLICATION CERTIFICATION FORM WQ Permit#: WQ0001026 County: Facility Name (as shown on permit): Land Application Operator: Beaufort County, NC Year: City of Washington 2021 EMA Resources Inc. Phone: 336-751-1441 Land application of residuals as allowed by the permit occurred during the past calendar year? Yes ❑ No - If No, skip Part A, and Part B and proceed to Part C. Also, If residuals were generated but not land applied, please attach an explanation on how the residuals were handled. Part A - Residuals Application Summary: Total number of application fields in the permit: 54 Total number of fields utilized for land application during the year: 8 Total amount of dry tons applied during the year for all application sites: 499.4 Total number of acres utilizes for land application during the year: 205 Part B - Annual Compiance Statement: Facility was compliant during calendar year 2021 with all conditions of the land application permit (including but not limited to items 1-13 below) issued by the Division of Water Quality. In Yes ❑ No If no please, provide a written description why the facility was not compliant, the dates, and explain corrective action taken. 1) Only residuals approved for this permit were applied to the permitted sites. 2) Soil pH was adjusted as specified in the permit and lime was applied (if needed) to achieve a soil pH of at least 6.0 or the limit specified in the permit. 3) Annual soils analysis were performed on each site receiving residuals during the past calendar year and three (3) copies of laboratory results are attached. 4) Annual TCLP analysis (if required) was performed and three (3) copies of certified laboratory results are attached. 5) All other monitoring was performed in accordance with the permit and reported during the year as required and three (3) copies of certified laboratory results are attached. 6) The facility did not exceed any of the Pollutant Concentration Limits in 15A NCAC 02T .1105(a) or the Pollutant Loading Rates in 15A NCAC 02T .1105(b) (applicable to 40 CFR Part 503 regulated facilities). 7) All general requirements in as specified in the Land Application Permit were complied with (applicable to 40 CFR Part 503 regulated facilities). 8) All monitoring and reporting requirements in 15A NCAC 02T .1111 were complied with (applicable to 40 CFR Part 503 regulated facilities). 9) All operations and maintenance requirements in the permit were complied with or, in the case of a deviation, prior authorization was received from the Division of Water Quality. 10) No contravention of Ground Water Quality Standards occurred at a monitoring well or explanations of violations are attached to include appropriate actions and remediations. 11) Vegetative cover was maintained and proper crop management was performed on each site receing residuals, as specified in the permit. 12) No runoff of residuals from the application sites onto adjacent property or nearby surface waters has occurred. 13) All buffer requirements as specified on the permit were maintained during each application of residuals. Part C - Certification: "I certify, under penalty of law, that the above information is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." Adam Waters - Public Works Director Permittee Name and Title (type or print) f7Lo/ �7 VYDOGGt, Hop J. Woolard (Feb 3, 2022 07:45 EST) .Adam U/aived Feb 3, 2022 Signature of Permittee Date Feb 3, 2022 2/1/2022 Signature of Preparer* Date Signature of Land Applier Date (if different from Permittee) (if different from Permittee and Preparer) * Preparer is defined in 40 CFR Part 503.9 (r) and 15A NCAC 02T .1102 (26) DENR FORM ACF (12/2006) Signature Page - 2021 Washington Annual Report - WQ0001026 Final Audit Report 2022-02-03 Created: 2022-02-03 By: Brent Collins (brent.collins@emaresourcesinc.com) Status: Signed Transaction ID: CBJCHBCAABAAmfkSxdBYIXj4ScQDA-Swgz4LGBfJJ6Hv "Signature Page - 2021 Washington Annual Report - WQ000102 6" History Document created by Brent Collins (brent.collins@emaresourcesinc.com) 2022-02-03 - 3:56:42 PM GMT- IP address: 206.85.202.26 Document emailed to Adam Waters (awaters@washingtonnc.gov) for signature 2022-02-03 - 3:58:58 PM GMT Email viewed by Adam Waters (awaters@washingtonnc.gov) 2022-02-03 - 9:10:19 PM GMT- IP address: 54.147.246.36 Document e-signed by Adam Waters (awaters@washingtonnc.gov) Signature Date: 2022-02-03 - 9:11:23 PM GMT - Time Source: server- IP address: 208.180.158.162 Agreement completed. 2022-02-03 - 9:11:23 PM GMT Ea Adobe Sign Pages from 2021 Washington Annual Report - WQ0001026 Final Audit Report 2022-02-03 Created: 2022-02-01 By: Brent Collins (brent.collins@emaresourcesinc.com) Status: Signed Transaction ID: CBJCHBCAABAAIOTHGTBnabogEjg15Gh9m346M26vYnyP "Pages from 2021 Washington Annual Report - WQ0001026" Hi story ,n Document created by Brent Collins (brent.collins@emaresourcesinc.com) 2022-02-01 - 11:08:19 PM GMT- IP address: 206.85.202.26 ► Document emailed to Hope J. Woolard (hwoolard@washingtonnc.gov) for signature 2022-02-01 - 11:23:55 PM GMT In Email viewed by Hope J. Woolard (hwoolard@washingtonnc.gov) 2022-02-02 - 2:23:04 PM GMT- IP address: 3.237.199.191 Document e-signed by Hope J. Woolard (hwoolard@washingtonnc.gov) Signature Date: 2022-02-03 - 12:45:46 PM GMT - Time Source: server- IP address: 208.180.158.162 Agreement completed. 2022-02-03 - 12:45:46 PM GMT Ea Adobe Sign ANNUAL RESIDUAL SAMPLING SUMMARY FORM Please note that your permit may contain additional parameters to be analyzed. The parameters can be reported in FORM RSSF - B WQ Permit Number: Facility Name: Residual Source WQ # or NPDES #: WWTP Name: Residual Analysis Data WQ0001026 City of Washington NC0020648 Washington WWTP Laboratory: 1) Waypoint Analytical 2) 3) 4) 5) Parameter (mg/kg) Conc. Limit (mg/kg)a Sample or Composite Date 3/15/21 3/30/21 Spring Average 11/10/21 11/30/21 Fall Average Percent Solids (%) NA 4.97 4.94 4.96 4.48 4.24 4.36 Arsenic 75 8.64 6.65 7.6 7.84 11.9 9.87 Cadmium 85 0.784 0.784 0.8 0.884 2.38 1.63 Copper 4,300 246 269 257.5 287 300 293.50 Chromium NA 21.4 18.7 20.1 20.8 18.4 19.60 Lead 840 25.8 26.3 26.1 21.3 32.9 27.10 Mercury 57 1.39 1.31 1.4 1.2 1.39 1.30 Molybdenum 75 5 4.9 5.0 5.11 5.95 5.53 Nickel 420 13.3 14.6 14.0 16.1 15.8 15.95 Selenium 100 7.94 6.53 7.2 7.11 11.9 9.51 Zinc 7,500 634 696 665.0 807 852 829.50 Total Phosphorus NA 29600 31800 30700 32700 33300 33000 TKN NA 27800 35500 31650 46900 55200 51050 Ammonia -Nitrogen NA 9480 10600 10040.0 9220 11200 10210 Nitrate and Nitrite NA 0 94.3 47.2 106 1330 718 a For surface disposal facilities the ceiling concentration limits listed in this fo u are not applicable. Reference the individual peunit for metals limits. "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." h`oreo7. GdooGaicl�s Feb 3, 2022 Hop Signature of Preparer * Date *Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26) DENR FORM RSSF (12/2006) ANNUAL RESIDUAL SAMPLING SUMMARY FORM - B Report all sampling analysis results for parameters not listed in FORM RSSF that are part of the WQ permit or were analyzed for over the past calendar year. Use additional forms as needed. WQ Permit Number: Facility Name: Residual Source NPDES # or WQ#: WWTP Name: WQ0001026 Laboratory: 1) Waypoint Analytical City of Washington NC0020648 Washington WWTP Residual Analysis Data 2) 3) 4) 5) Parameter (mg/kg) Sample or Composite Date 3/15/21 3/30/21 Average 11/10/21 11/30/21 Fall Average Aluminum 35000 34900 34950 33300 33600 33450 Calcium 27600 30000 28800 27600 31900 29750 Magnesium 52200 54300 53250 2510 2520 2515 pH 8.2 8.2 8.2 7.2 7.8 7.5 Potassium 2420 2000 2210 1780 2020 1900 Sodium 2140 2180 2160 2510 2740 2625 PAN 10236 12864 11550 16020 20130 18075 SAR 0.42 0.38 0.82 0.82 "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." 17`re �7 Wx/a/ ( Hop EST) Signature of Preparer * *Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26) Feb 3, 2022 Date DENR FORM RSSF - B (12/2006) ANNUAL METALS FIELD LOADING SUMMARY FORM* Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Facility Name: Permit #: City of Washington Total Dry Tons Applied (Annual): WQ0001026 Cation Exchange Capacity (non 503 only): 73.94 Operator: Hunter Roost Farms Owner: Hunter Roost Farms Predominant Soil Series: GoA Acres Used: 26.81 Acres Permitted: 26.81 Site #: BF210 Field #: 2 Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #): Sample or Com- posite Date 1 Spring Avg 3 3 14 15 16 17 18 19 110 111 112 % Solids 4.96 Arsenic 7.65 Cadmium 0.78 Copper 258 Chromiumr 20.05 Lead 26.05 Mercury 1.35 Molyb- denum 4.95 Nickel 13.95 Selenium 7.24 Zinc 665 Total Phos- phorus 30700 Annual Heavy Metal Field Loadings (Calculated in lbs/acre): Total DT/Ac./ App. Event L L 3 Li L L 6 t L L 10 11 12 Totals: 2.76 Arsenic 0.042 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.042 Cadmium 0.004 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.004 Copper 1.423 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 1.423 Chromium 0.111 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.111 Lead 0.144 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.144 Mercury 0.007 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.007 Molyb denum 0.027 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.027 Nickel 0.077 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.077 Selenium 0.040 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.040 Zinc 3.668 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 3.668 Total Phos- phorus 169.341 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 169.341 "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations". Signature of Land Applier 2/1/2022 Date DENR FORM MFLSF (12/2006) Facility Name: Land Owner: ANNUAL LAND APPLICATION FIELD SUMMARY FORM PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE. WQ Permit #: WQ0001026 Field #: 2 Site #: BF210 City of Washington Hunter Roost Farms Operator: Hunter Roost Farms Crop 1 Name: Soybeans Annual Dry Tons Applied: 73.94 Predominant Soil Series: GoA Crop 1 Max. PAN: 176 Crop 2 Name: Acres Utilized: 26.81 Acres Permitted: 26.81 Cation Exchange Capacity (non 503): Crop 2 Max. PAN: 0 Date or Month Volume (enter one) Liquid 9 Cu. Yds applied Solids/ Gallons % Solids Volume Appliedper PP Acre (Dry Tons/Ac) Residual (NPDES Fert , Waste, Sources #, WQ#,7j Animal Soil Cond. (Dry, Wet, Moist) Precip. Past 24 Hrs. inches Application Method* o w w . N' 1,?-,' Mineralizatio n Rate* * * TKN mg/kg Ammonia Y rn Nitrogen E Nitrate and Nitrite mg/kg PAN Applied (lbs/acre) Name of Crop Type Receiving Residual Application PP etc) Crop 1 Crop 2 Crop 1 Crop 2 4/7 45500 4.96 0.351 Washington D <.5" S 0.5 0.3 31650 10040 47 8.109 NA Beans 4/8 273000 4.96 2.106 Washington D <.5" S 0.5 0.3 31650 10040 47 48.651 NA Beans 4/9 39000 4.96 0.301 Washington D <.5" S 0.5 0.3 31650 10040 47 6.950 NA Beans 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0 0 0.000 Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp to this form): 0.000 0.000 TOTALS: 0 357500 As Cd Cu Cr Pb Hg Mo Ni Se Zn P 63.710 0.000 Lime Applied Annual lbs/acre 0.042 0.004 1.423 0.111 0.144 0.007 0.027 0.077 0.040 3.668 169.341 Date lbs/ac Prior Years Cumulative lbs/ac 0.008 0.003 0.313 0.082 0.03 0.002 0.017 0.044 0.008 0.924 12/6 2000 Current Cumulative lbs/ac 0.050 0.007 1.736 0.193 0.174 0.009 0.044 0.121 0.048 4.592 Permitted C. P. L. R. * * * * 36 34 1338 267 15 374 89 2498 Permit PAN Limit 1 st/2nd Crop 176 "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." Signature of Land Applier *Application Method: S - Surface, IN - Injection, INC - Incorporation 2/1/2022 **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0 Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2, aerobically digested -0.3, raw sludge -0.4 ****C.P.L.R.: Cumulative Pollutant Loading Rate DENR FORM FSF (12/2006) ANNUAL METALS FIELD LOADING SUMMARY FORM* Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Facility Name: Permit #: City of Washington Total Dry Tons Applied (Annual): WQ0001026 Cation Exchange Capacity (non 503 only): 156.02 Operator: Hunter Roost Farms Owner: Hunter Roost Farms Predominant Soil Series: GoA Acres Used: 64.02 Acres Permitted: 64.02 Site #: BF210 Field #: 4 Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #): Sample or Com- posite Date 1 I Fall Average 2 3 1 4 1 5 1 6 1 7 1 8 1 9 110 111 112 % Solids 4.36 Arsenic 9.87 Cadmium 1.63 Copper 293.5 Chromiumr 19.6 Lead 27.1 Mercury 1.3 Molyb- denum 5.53 Nickel 15.95 Selenium 9.51 Zinc 829.5 Total Phos- phorus 33000 Annual Heavy Metal Field Loadings (Calculated in lbs/acre): Total DT/Ac./ App. Event L L 3 Li L L 6 t L L 10 11 12 Totals: 2.44 Arsenic 0.048 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.048 Cadmium 0.008 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.008 Copper 1.431 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 1.431 Chromium 0.096 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.096 Lead 0.132 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.132 Mercury 0.006 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.006 Molyb denum 0.027 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.027 Nickel 0.078 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.078 Selenium 0.046 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.046 Zinc 4.043 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 4.043 Total Phos- phorus 160.842 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 160.842 "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations". Signature of Land Applier 2/1/2022 Date DENR FORM MFLSF (12/2006) Facility Name: Land Owner: ANNUAL LAND APPLICATION FIELD SUMMARY FORM PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE. WQ Permit #: WQ0001026 Field #: 4 City of Washington Hunter Roost Farms Annual Dry Tons Applied: 156.02 Operator: Hunter Roost Farms Crop 1 Name: Wheat Predominant Soil Series: GoA Site #: BF210 Crop 1 Max. PAN: 135 Crop 2 Name: Acres Utilized: 64.02 Acres Permitted: 64.02 Cation Exchange Capacity (non 503): Crop 2 Max. PAN: 0 Date or Month Volume (enter one) Liquid 9 Cu. Yds applied Solids/ Gallons % Solids Volume Appliedper PP Acre (Dry Tons/Ac) Residual (NPDES Fert , Waste, Sources #, WQ#,7j Animal Soil Cond. (Dry, Wet, Moist) Precip. Past 24 Hrs. inches Application Method* o w w . N' 1,?-,' Mineralizatio n Rate* * * TKN mg/kg Ammonia Y rn Nitrogen E Nitrate and Nitrite mg/kg PAN Applied (lbs/acre) Name of Crop Type Receiving Residual Application PP etc) Crop 1 Crop 2 Crop 1 Crop 2 11/8 84500 4.36 0.240 Washington D <.5" S 0.5 0.3 51050 10210 718 8.675 NA Wheat 11/9 208000 4.36 0.591 Washington D <.5" S 0.5 0.3 51050 10210 718 21.354 NA Wheat 11/10 208000 4.36 0.591 Washington D <.5" S 0.5 0.3 51050 10210 718 21.354 NA Wheat 11/11 143000 4.36 0.406 Washington D <.5" S 0.5 0.3 51050 10210 718 14.681 NA Wheat 11/14 84500 4.36 0.240 Washington D <.5" S 0.5 0.3 51050 10210 718 8.675 NA Wheat 11/15 58500 4.36 0.166 Washington D <.5" S 0.5 0.3 51050 10210 718 6.006 NA Wheat 11/16 71500 4.36 0.203 Washington D <.5" S 0.5 0.3 51050 10210 718 7.340 NA Wheat 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0 0 0.000 Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp to this form): 0.000 0.000 TOTALS: 0 858000 As Cd Cu Cr Pb Hg Mo Ni Se Zn P 88.085 0.000 Lime Applied Annual lbs/acre 0.048 0.008 1.431 0.096 0.132 0.006 0.027 0.078 0.046 4.043 160.842 Date lbs/ac Prior Years Cumulative lbs/ac 0.215 0.062 7.527 1.077 0.917 0.041 0.2 0.628 0.185 19.204 12/6 2000 Current Cumulative lbs/ac 0.263 0.070 8.958 1.173 1.049 0.047 0.227 0.706 0.231 23.247 Permitted C. P. L. R. * * * * 36 34 1338 267 15 374 89 2498 Permit PAN Limit 1 st/2nd Crop 135 "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." Signature of Land Applier *Application Method: S - Surface, IN - Injection, INC - Incorporation 2/1/2022 **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0 Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2, aerobically digested -0.3, raw sludge -0.4 ****C.P.L.R.: Cumulative Pollutant Loading Rate DENR FORM FSF (12/2006) ANNUAL METALS FIELD LOADING SUMMARY FORM* Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Facility Name: Permit #: City of Washington Total Dry Tons Applied (Annual): WQ0001026 Cation Exchange Capacity (non 503 only): 53.78 Operator: Hunter Roost Farms Owner: Hunter Roost Farms Predominant Soil Series: Le Acres Used: 15.14 Acres Permitted: 15.14 Site #: BF210 Field #: 6 Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #): Sample or Com- posite Date 1 Spring Avg 3 3 14 15 16 17 18 19 110 111 112 % Solids 4.96 Arsenic 7.65 Cadmium 0.78 Copper 258 Chromiumr 20.05 Lead 26.05 Mercury 1.35 Molyb- denum 4.95 Nickel 13.95 Selenium 7.24 Zinc 665 Total Phos- phorus 30700 Annual Heavy Metal Field Loadings (Calculated in lbs/acre): Total DT/Ac./ App. Event L L 3 Li L L 6 t L L 10 11 12 Totals: 3.55 Arsenic 0.054 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.054 Cadmium 0.006 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.006 Copper 1.833 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 1.833 Chromium 0.142 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.142 Lead 0.185 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.185 Mercury 0.010 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.010 Molyb denum 0.035 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.035 Nickel 0.099 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.099 Selenium 0.051 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.051 Zinc 4.724 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 4.724 Total Phos- phorus 218.093 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 218.093 "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations". Signature of Land Applier 2/1/2022 Date DENR FORM MFLSF (12/2006) Facility Name: Land Owner: ANNUAL LAND APPLICATION FIELD SUMMARY FORM PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE. WQ Permit #: WQ0001026 Field #: 6 Site #: BF210 City of Washington Hunter Roost Farms Operator: Hunter Roost Farms Crop 1 Name: Soybeans Annual Dry Tons Applied: 53.78 Predominant Soil Series: Le Crop 1 Max. PAN: 146 Crop 2 Name: Acres Utilized: 15.14 Acres Permitted: 15.14 Cation Exchange Capacity (non 503): Crop 2 Max. PAN: 0 Date or Month Volume (enter one) Liquid 9 Cu. Yds applied Solids/ Gallons % Solids Volume Appliedper PP Acre (Dry Tons/Ac) Residual (NPDES Pert , Waste, Sources #, WQ#,7j Animal Soil Cond. (Dry, Wet, Moist) Precip. Past 24 Hrs. inches Application Method* o w w . N' 1,?-,' Mineralizatio n Rate* * * TKN mg/kg Ammonia Y rn Nitrogen E Nitrate and Nitrite mg/kg PAN Applied (lbs/acre) Name of Crop Type Receiving Residual Application PP etc) Crop 1 Crop 2 Crop 1 Crop 2 3/27 110500 4.96 1.510 Washington D <.5" S 0.5 0.3 31650 10040 47 34.871 NA Beans 4/5 104000 4.96 1.421 Washington D <.5" S 0.5 0.3 31650 10040 47 32.820 NA Beans 4/6 45500 4.96 0.622 Washington D <.5" S 0.5 0.3 31650 10040 47 14.359 NA Beans 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0 0 0.000 Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp to this form): 0.000 0.000 TOTALS: 0 260000 As Cd Cu Cr Pb Hg Mo Ni Se Zn P 82.050 0.000 Lime Applied Annual lbs/acre 0.054 0.006 1.833 0.142 0.185 0.010 0.035 0.099 0.051 4.724 218.093 Date lbs/ac Prior Years Cumulative lbs/ac 0.151 0.038 6.443 0.766 0.659 0.034 0.124 0.408 0.161 14.976 12/6 2000 Current Cumulative lbs/ac 0.205 0.044 8.276 0.908 0.844 0.044 0.159 0.507 0.212 19.700 Permitted C. P. L. R. * * * * 36 34 1338 267 15 374 89 2498 Permit PAN Limit 1 st/2nd Crop 146 "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." Signature of Land Applier *Application Method: S - Surface, IN - Injection, INC - Incorporation 2/1/2022 **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0 Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2, aerobically digested -0.3, raw sludge -0.4 ****C.P.L.R.: Cumulative Pollutant Loading Rate DENR FORM FSF (12/2006) ANNUAL METALS FIELD LOADING SUMMARY FORM* Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Facility Name: Permit #: City of Washington Total Dry Tons Applied (Annual): WQ0001026 Cation Exchange Capacity (non 503 only): 53.78 Operator: Hunter Roost Farms Owner: Hunter Roost Farms Predominant Soil Series: Le Acres Used: 11.82 Acres Permitted: 11.82 Site #: BF210 Field #: 7 Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #): Sample or Com- posite Date 1 Spring Avg 3 3 14 15 16 17 18 19 110 111 112 % Solids 4.96 Arsenic 7.65 Cadmium 0.78 Copper 258 Chromiumr 20.05 Lead 26.05 Mercury 1.35 Molyb- denum 4.95 Nickel 13.95 Selenium 7.24 Zinc 665 Total Phos- phorus 30700 Annual Heavy Metal Field Loadings (Calculated in lbs/acre): Total DT/Ac./ App. Event L L L 3 Li L L 6 t L L 10 11 12 Totals: 4.55 Arsenic 0.070 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.070 Cadmium 0.007 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.007 Copper 2.348 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 2.348 Chromium 0.182 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.182 Lead 0.237 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.237 Mercury 0.012 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.012 Molyb denum 0.045 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.045 Nickel 0.127 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.127 Selenium 0.066 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.066 Zinc 6.052 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 6.052 Total Phos- phorus 279.370 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 279.370 "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations". Signature of Land Applier 2/1/2022 Date DENR FORM MFLSF (12/2006) Facility Name: Land Owner: ANNUAL LAND APPLICATION FIELD SUMMARY FORM PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE. WQ Permit #: WQ0001026 Field #: 7 Site #: BF210 City of Washington Hunter Roost Farms Operator: Hunter Roost Farms Crop 1 Name: Soybeans Annual Dry Tons Applied: 53.78 Predominant Soil Series: Le Crop 1 Max. PAN: 146 Crop 2 Name: Acres Utilized: 11.82 Acres Permitted: 11.82 Cation Exchange Capacity (non 503): Crop 2 Max. PAN: 0 Date or Month Volume (enter one) Liquid 9 Cu. Yds applied Solids/ Gallons % Solids Volume Appliedper pp Acre (Dry Tons/Ac) Residual (NPDES Pert , Waste, Sources #, WQ#,7j Animal Soil Cond. (Dry, Wet, Moist) Precip. Past 24 Hrs. inches Application Method* o w w . N' 1,?-,' Mineralizatio n Rate* * * TKN mg/kg Ammonia Y rn Nitrogen E Nitrate and Nitrite mg/kg PAN Applied (lbs/acre) Name of Crop Type Receiving Residual Application PP etc) Crop 1 Crop 2 Crop 1 Crop 2 3/27 110500 4.96 1.934 Washington D <.5" S 0.5 0.3 31650 10040 47 44.666 NA Beans 4/5 104000 4.96 1.820 Washington D <.5" S 0.5 0.3 31650 10040 47 42.038 NA Beans 4/6 45500 4.96 0.796 Washington D <.5" S 0.5 0.3 31650 10040 47 18.392 NA Beans 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0 0 0.000 Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp to this form): 0.000 0.000 TOTALS: 0 260000 As Cd Cu Cr Pb Hg Mo Ni Se Zn P 105.096 0.000 Lime Applied Annual lbs/acre 0.070 0.007 2.348 0.182 0.237 0.012 0.045 0.127 0.066 6.052 279.370 Date lbs/ac Prior Years Cumulative lbs/ac 0.136 0.034 5.351 0.63 0.564 0.029 0.106 0.346 0.146 12.486 12/6 2000 Current Cumulative lbs/ac 0.206 0.041 7.699 0.812 0.801 0.041 0.151 0.473 0.212 18.538 Permitted C. P. L. R. * * * * 36 34 1338 267 15 374 89 2498 Permit PAN Limit 1 st/2nd Crop 146 "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." Signature of Land Applier *Application Method: S - Surface, IN - Injection, INC - Incorporation 2/1/2022 **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0 Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2, aerobically digested -0.3, raw sludge -0.4 ****C.P.L.R.: Cumulative Pollutant Loading Rate DENR FORM FSF (12/2006) ANNUAL METALS FIELD LOADING SUMMARY FORM* Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Facility Name: Permit #: City of Washington Total Dry Tons Applied (Annual): WQ0001026 Cation Exchange Capacity (non 503 only): 60.49 Operator: Hunter Roost Farms Owner: Hunter Roost Farms Predominant Soil Series: Le Acres Used: 19.21 Acres Permitted: 19.21 Site #: BF210 Field #: 8 Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #): Sample or Com- posite Date 1 Spring Avg 3 3 14 15 16 17 18 19 110 111 112 % Solids 4.96 Arsenic 7.65 Cadmium 0.78 Copper 258 Chromiumr 20.05 Lead 26.05 Mercury 1.35 Molyb- denum 4.95 Nickel 13.95 Selenium 7.24 Zinc 665 Total Phos- phorus 30700 Annual Heavy Metal Field Loadings (Calculated in lbs/acre): Total DT/Ac./ App. Event L L 3 Li L L 6 t L L 10 11 12 Totals: 3.15 Arsenic 0.048 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.048 Cadmium 0.005 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.005 Copper 1.625 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 1.625 Chromium 0.126 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.126 Lead 0.164 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.164 Mercury 0.009 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.009 Molyb denum 0.031 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.031 Nickel 0.088 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.088 Selenium 0.046 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.046 Zinc 4.188 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 4.188 Total Phos- phorus 193.349 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 193.349 "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations". Signature of Land Applier 2/1/2022 Date DENR FORM MFLSF (12/2006) Facility Name: Land Owner: ANNUAL LAND APPLICATION FIELD SUMMARY FORM PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE. WQ Permit #: WQ0001026 Field #: 8 Site #: BF210 City of Washington Hunter Roost Farms Operator: Hunter Roost Farms Crop 1 Name: Soybeans Annual Dry Tons Applied: 60.49 Predominant Soil Series: Le Crop 1 Max. PAN: 146 Crop 2 Name: Acres Utilized: 19.21 Acres Permitted: 19.21 Cation Exchange Capacity (non 503): Crop 2 Max. PAN: 0 Date or Month Volume (enter one) Liquid q Cu. Yds applied Solids/ Gallons % Solids Volume Appliedper PP Acre (Dry Tons/Ac) Residual (NPDES Fert , Waste, Sources #, WQ#,7j Animal Soil Cond. (Dry, Wet, Moist) Precip. Past 24 Hrs. inches Application Method* o w w . N' 1,?-,' Mineralizatio n Rate* * * TKN mg/kg Ammonia Y rn Nitrogen E Nitrate and Nitrite mg/kg PAN Applied (lbs/acre) Name of Crop Type Receiving Residual Application PP etc) Crop 1 Crop 2 Crop 1 Crop 2 4/6 104000 4.96 1.120 Washington D <.5" S 0.5 0.3 31650 10040 47 25.866 NA Beans 4/7 188500 4.96 2.030 Washington D <.5" S 0.5 0.3 31650 10040 47 46.883 NA Beans 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0 0 0.000 Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp to this form): 0.000 0.000 TOTALS: 0 292500 As Cd Cu Cr Pb Hg Mo Ni Se Zn P 72.749 0.000 Lime Applied Annual lbs/acre 0.048 0.005 1.625 0.126 0.164 0.009 0.031 0.088 0.046 4.188 193.349 Date lbs/ac Prior Years Cumulative lbs/ac 0.125 0.029 4.382 0.511 0.481 0.025 0.09 0.292 0.135 10.327 12/6 2000 Current Cumulative lbs/ac 0.173 0.034 6.007 0.637 0.645 0.034 0.121 0.380 0.181 14.515 Permitted C. P. L. R. * * * * 36 34 1338 267 15 374 89 2498 Permit PAN Limit 1 st/2nd Crop 146 "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." Signature of Land Applier *Application Method: S - Surface, IN - Injection, INC - Incorporation 2/1/2022 **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0 Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2, aerobically digested -0.3, raw sludge -0.4 ****C.P.L.R.: Cumulative Pollutant Loading Rate DENR FORM FSF (12/2006) ANNUAL METALS FIELD LOADING SUMMARY FORM* Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Facility Name: Permit #: City of Washington Total Dry Tons Applied (Annual): WQ0001026 Cation Exchange Capacity (non 503 only): 28.35 Operator: Hunter Roost Farms Owner: Hunter Roost Farms Predominant Soil Series: GoA Acres Used: 29.08 Acres Permitted: 29.08 Site #: BF210 Field #: 12 Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #): Sample or Com- posite Date 1 Fall Average 3 3 14 15 16 17 18 19 110 111 112 % Solids 4.36 Arsenic 9.87 Cadmium 1.63 Copper 293.5 Chromiumr 19.6 Lead 27.1 Mercury 1.3 Molyb- denum 5.53 Nickel 15.95 Selenium 9.51 Zinc 829.5 Total Phos- phorus 33000 Annual Heavy Metal Field Loadings (Calculated in lbs/acre): Total DT/Ac./ App. Event L L L 3 Li L L 6 t L L 10 11 12 Totals: 0.98 Arsenic 0.019 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.019 Cadmium 0.003 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.003 Copper 0.572 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.572 Chromium 0.038 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.038 Lead 0.053 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.053 Mercury 0.003 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.003 Molyb denum 0.011 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.011 Nickel 0.031 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.031 Selenium 0.019 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.019 Zinc 1.618 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 1.618 Total Phos- phorus 64.350 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 64.350 "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations". Signature of Land Applier 2/1/2022 Date DENR FORM MFLSF (12/2006) ANNUAL LAND APPLICATION FIELD SUMMARY FORM PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE. Facility Name: City of Washington WQ Permit #: WQ0001026 Field #: 12 Land Owner: Hunter Roost Farms Annual Dry Tons Applied: 28.35 Site #: BF210 Operator: Hunter Roost Farms Crop 1 Name: Wheat Predominant Soil Series: GoA Crop 1 Max. PAN: 136 Crop 2 Name: Acres Utilized: 29.08 Acres Permitted: 29.08 Cation Exchange Capacity (non 503): Crop 2 Max. PAN: 0 Date or Month Volume (enter one) Liquid 9 Cu. Yds applied Solids/ Gallons % Solids Volume Appliedper pp Acre (Dry Tons/Ac) Residual (NPDES Fert , Waste, Sources #, WQ#,7j Animal Soil Cond. (Dry, Wet, Moist) Precip. Past 24 Hrs. inches Application Method* o w w . N' 1,?-,' Mineralizatio n Rate* * * TKN mg/kg Ammonia Y rn Nitrogen E Nitrate and Nitrite mg/kg PAN Applied (lbs/acre) Name of Crop Type Receiving Residual Application PP etc) Crop 1 Crop 2 Crop 1 Crop 2 11/14 39000 4.36 0.244 Washington D <.5" S 0.5 0.3 51050 10210 718 8.815 NA Wheat 11/15 117000 4.36 0.731 Washington D <.5" S 0.5 0.3 51050 10210 718 26.444 NA Wheat 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0 0 0.000 Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp to this form): 0.000 0.000 TOTALS: 0 156000 As Cd Cu Cr Pb Hg Mo Ni Se Zn P 35.258 0.000 Lime Applied Annual lbs/acre 0.019 0.003 0.572 0.038 0.053 0.003 0.011 0.031 0.019 1.618 64.350 Date lbs/ac Prior Years Cumulative lbs/ac 0.068 0.017 2.839 0.364 0.296 0.013 0.055 0.197 0.081 6.865 12/6 2000 Current Cumulative lbs/ac 0.087 0.020 3.411 0.402 0.349 0.016 0.066 0.228 0.100 8.483 Permitted C. P. L. R. * * * * 36 34 1338 267 15 374 89 2498 Permit PAN Limit 1 st/2nd Crop 136 "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." Signature of Land Applier *Application Method: S - Surface, IN - Injection, INC - Incorporation 2/1/2022 **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0 Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2, aerobically digested -0.3, raw sludge -0.4 ****C.P.L.R.: Cumulative Pollutant Loading Rate DENR FORM FSF (12/2006) ANNUAL METALS FIELD LOADING SUMMARY FORM* Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Facility Name: Permit #: City of Washington Total Dry Tons Applied (Annual): WQ0001026 Cation Exchange Capacity (non 503 only): 26.00 Operator: Hunter Roost Farms Owner: Hunter Roost Farms Predominant Soil Series: Ly Acres Used: 13.48 Acres Permitted: 13.48 Site #: BF210 Field #: 15 Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #): Sample or Com- posite Date 1 I Fall Average 2 3 1 4 1 5 1 6 1 7 1 8 1 9 110 111 112 % Solids 4.36 Arsenic 9.87 Cadmium 1.63 Copper 293.5 Chromiumr 19.6 Lead 27.1 Mercury 1.3 Molyb- denum 5.53 Nickel 15.95 Selenium 9.51 Zinc 829.5 Total Phos- phorus 33000 Annual Heavy Metal Field Loadings (Calculated in lbs/acre): Total DT/Ac./ App. Event L L 3 Li L L 6 t L L 10 11 12 Totals: 1.93 Arsenic 0.038 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.038 Cadmium 0.006 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.006 Copper 1.132 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 1.132 Chromium 0.076 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.076 Lead 0.105 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.105 Mercury 0.005 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.005 Molyb denum 0.021 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.021 Nickel 0.062 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.062 Selenium 0.037 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.037 Zinc 3.200 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 3.200 Total Phos- phorus 127.314 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 127.314 "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations". Signature of Land Applier 2/1/2022 Date DENR FORM MFLSF (12/2006) Facility Name: Land Owner: ANNUAL LAND APPLICATION FIELD SUMMARY FORM PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE. WQ Permit #: WQ0001026 Field #: 15 City of Washington Hunter Roost Farms Annual Dry Tons Applied: 26.00 Site #: BF210 Operator: Hunter Roost Farms Crop 1 Name: Wheat Predominant Soil Series: Ly Crop 1 Max. PAN: 106 Crop 2 Name: Acres Utilized: 13.48 Acres Permitted: 13.48 Cation Exchange Capacity (non 503): Crop 2 Max. PAN: 0 Date or Month Volume (enter one) Liquid Cu. Yds applied Solids/ Gallons % Solids Volume Appliedper pp Acre (Dry Tons/Ac) Residual Sources (NPDES #, WQ#, Fert., Animal Waste, etc) Soil Cond. (Dry, Wet, Moist) Precip. Past 24 Hrs. inches Application Method* * *atn2I uOTTEZTTTWTOA Mineralizatio n Rate* * * TKN mg/kg Ammonia Y rn Nitrogen Nitrate and Nitrite mg/kg PAN Applied (lbs/acre) Name of Crop Type Receiving Residual Appl.cation Crop 1 Crop 2 Crop 1 Crop 2 11/13 143000 4.36 1.929 Washington D <.5" S 0.5 0.3 51050 10210 718 69.723 NA Wheat 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0 0 0.000 Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp to this form): 0.000 0.000 TOTALS: 0 143000 As Cd Cu Cr Pb Hg Mo Ni Se Zn P 69.723 0.000 Lime Applied Annual lbs/acre 0.038 0.006 1.132 0.076 0.105 0.005 0.021 0.062 0.037 3.200 127.314 Date lbs/ac Prior Years Cumulative lbs/ac 0 0 0 0 0 0 0 0 0 0 12/6 2000 Current Cumulative lbs/ac 0.038 0.006 1.132 0.076 0.105 0.005 0.021 0.062 0.037 3.200 Permitted C. P. L. R.**** 36 34 1338 267 15 374 89 2498 Permit PAN Limit 1 st/2nd Crop 106 "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." 1 /6/2020 Signature of Land Applier Date *Application Method: S - Surface, IN - Injection, INC - Incorporation **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0 *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2, aerobically digested -0.3, raw sludge -0.4 ****C.P.L.R.: Cumulative Pollutant Loading Rate DENR FORM FSF (12/2006) ANNUAL METALS FIELD LOADING SUMMARY FORM* Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Facility Name: Permit #: City of Washington Total Dry Tons Applied (Annual): WQ0001026 Cation Exchange Capacity (non 503 only): 100.82 Operator: Hunter Roost Farms Owner: Hunter Roost Farms Predominant Soil Series: CrA Acres Used: 25.44 Acres Permitted: 25.44 Site #: BF210 Field #: 16 Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #): Sample or Com- posite Date 1 I Spring Avg 2 3 1 4 1 5 1 6 1 7 1 8 1 9 110 111 112 % Solids 4.96 Arsenic 7.65 Cadmium 0.78 Copper 258 Chromiuir 20.05 Lead 26.05 Mercury 1.35 Molyb- denum 4.95 Nickel 13.95 Selenium 7.24 Zinc 665 Total Phos- phorus 30700 Annual Heavy Metal Field Loadings (Calculated in lbs/acre): Total DT/Ac./ App. Event L L 3 Li L L 6 t L L 10 11 12 Totals: 3.96 Arsenic 0.061 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.061 Cadmium 0.006 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.006 Copper 2.045 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 2.045 Chromium 0.159 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.159 Lead 0.206 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.206 Mercury 0.011 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.011 Molyb denum 0.039 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.039 Nickel 0.111 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.111 Selenium 0.057 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.057 Zinc 5.271 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 5.271 Total Phos- phorus 243.328 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 243.328 "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations". Signature of Land Applier 2/1/2022 Date DENR FORM MFLSF (12/2006) Facility Name: Land Owner: ANNUAL LAND APPLICATION FIELD SUMMARY FORM PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE. WQ Permit #: WQ0001026 Field #: 16 City of Washington Hunter Roost Farms Annual Dry Tons Applied: 100.82 Site #: BF210 Operator: Hunter Roost Farms Crop 1 Name: Soybeans Predominant Soil Series: CrA Crop 1 Max. PAN: 154 Crop 2 Name: Acres Utilized: 25.44 Acres Permitted: 25.44 Cation Exchange Capacity (non 503): Crop 2 Max. PAN: 0 Date or Month Volume (enter one) Liquid Cu. Yds applied Solids/ Gallons % Solids Volume Appliedper pp Acre (Dry Tons/Ac) Residual Sources (NPDES #, WQ#, Fert., Animal Waste, etc) Soil Cond. (Dry, Wet, Moist) Precip. Past 24 Hrs. inches Application Method* * *atn2l UOTWZTTTWTOA Mineralizatio n Rate* * * TKN mg/kg Ammonia Y rn Nitrogen Nitrate and Nitrite mg/kg PAN Applied (lbs/acre) Name of Crop Type Receiving Residual Appl.cation Crop 1 Crop 2 Crop 1 Crop 2 3/24 130000 4.96 1.057 Washington D <.5" S 0.5 0.3 31650 10040 47 24.415 NA Beans 3/25 175500 4.96 1.427 Washington D <.5" S 0.5 0.3 31650 10040 47 32.960 NA Beans 3/26 182000 4.96 1.480 Washington D <.5" S 0.5 0.3 31650 10040 47 34.181 NA Beans 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0 0 0.000 Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp to this form): 0.000 0.000 TOTALS: 0 487500 As Cd Cu Cr Pb Hg Mo Ni Se Zn P 91.556 0.000 Lime Applied Annual lbs/acre 0.061 0.006 2.045 0.159 0.206 0.011 0.039 0.111 0.057 5.271 243.328 Date lbs/ac Prior Years Cumulative lbs/ac 0.115 0.026 4.815 0.593 0.502 0.029 0.091 0.317 0.125 11.458 12/6 2000 Current Cumulative lbs/ac 0.176 0.032 6.860 0.752 0.708 0.040 0.130 0.428 0.182 16.729 Permitted C. P. L. R.**** 36 34 1338 267 15 374 89 2498 Permit PAN Limit 1 st/2nd Crop 154 "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." 2/1/2022 Signature of Land Applier Date *Application Method: S - Surface, IN - Injection, INC - Incorporation **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0 *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2, aerobically digested -0.3, raw sludge -0.4 ****C.P.L.R.: Cumulative Pollutant Loading Rate DENR FORM FSF (12/2006) Waypoint ANALYTICAL 3/24/2021 EMA Resources Inc Mr. Brent Collins 755 Yadkinville Rd Mocksville, NC, 27028 Ref: Analytical Testing Lab Report Number: 21-075-0035 Client Project Description: Washington/NC 2790 Whitten Road, Memphis, TN 38133 Main 901.213.2400 ° Fax 901.213.2440 www.waypointanalytical.com Dear Mr. Brent Collins: Waypoint Analytical, LLC. received sample(s) on 3/16/2021 for the analyses The above referenced project has been analyzed per your instructions. The accordance with the applicable analytical method. Where the laboratory was stage (refer to the chain of custody) results apply to the sample as received. presented in the following report. analyses were performed in not responsible for the sampling The analytical data has been validated using standard quality control measures performed as required by the analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all parameters (NELAP and non-NELAP) were performed in accordance with guidelines established by the USEPA (including 40 CFR 136 Method Update Rule August 2017) and NELAC unless otherwise indicated. Any parameter for which the laboratory is not officially NELAP accredited is indicated by a '—' symbol. These are not included in the scope because NELAP accreditation is either not available or has not been applied for. Additional certifications may be held/are available for parameters, where NELAP accreditation is not required or applicable. A full list of certifications is available upon request. Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time. Refer to sample analysis time for confirmation of holding time compliance. The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as - received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to the samples included in this report. Please do not hesitate to contact me or client services if you have any questions or need additional information. Sincerely, Cpa, Danyale Love Project Manager Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis. TN I fR Page 1 of 8 Waypoint ANALYTICAL 2790 Whitten Road, Memphis, TN 38133 Main 901.213.2400 ° Fax 901.213.2440 www.waypointa nalytical.com Certification Summary Laboratory ID: WP MTN: Waypoint Analytical, LLC., Memphis, TN State Program Lab ID Expiration Date Alabama State Program 40750 02/28/2022 Arkansas State Program 88-0650 02/07/2022 California State Program 2904 06/30/2021 Florida State Program - NELAP E871157 06/30/2021 Georgia State Program C044 02/18/2023 Georgia State Program 04015 06/30/2021 Illinois State Program - NELAP 200078 10/10/2021 Kentucky State Program 80215 06/30/2021 Kentucky State Program KY90047 12/31/2021 Louisiana State Program - NELAP LA037 12/31/2021 Louisiana State Program - NELAP 04015 06/30/2021 Mississippi State Program MS 02/11/2023 North Carolina State Program 415 12/31/2021 Oklahoma State Program 9311 08/31/2021 Pennsylvania State Program - NELAP 68-03195 05/31/2021 South Carolina State Program 84002 06/30/2021 South Carolina State Program 84002 06/30/2021 Tennessee State Program 02027 02/11/2023 Tennessee A2LA ISO 17025:2017 4313.01 10/31/2021 Texas State Program - NELAP T104704180 09/30/2021 Virginia State Program 00106 06/30/2021 Virginia State Program - NELAP 460181 09/14/2021 Page 1 of 1 00001/21-075-0035 Page 2 of 8 Waypoint, ANALYTICAL Report Number: 21-075-0035 Client Project Description: Washington/NC 2790 Whitten Road, Memphis, TN 38133 Main 901.213.2400 ° Fax 901.213.2440 www.waypointa nalytical. com Sample Summary Table Lab No Client Sample ID Matrix Date Collected Date Received 93200 Washington Solids 03/15/2021 10:30 03/16/2021 Page 3 of 8 Waypol nt.M ANALYTICAL 2790 Whitten Road, Memphis, TN 38133 Main 901.213.2400 ° fax 901.213.2440 www.waypointanalytical.com Client: EMA Resources Inc Project: Washington/NC Lab Report Number: 21-075-0035 Date: 3/24/2021 CASE NARRATIVE Metals Analysis Method 6010D QC Batch No: L542742/L542290 One or more Internal Standards are outside method acceptance criteria. Re -analysis and/or sample dilutions are required. QC Batch No: L542742/L542290 One or more Internal Standards are outside method acceptance criteria. Re -analysis and/or sample dilutions are required. Sample 93200 (Washington) Analyte: Magnesium QC Batch No: L542742/L542290 The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test was performed and passed quality control acceptance ranges. No matrix interference is suspected. Page 4 of 8 Waypoint, ANALYTICAL 46245 EMA Resources Inc Mr. Brent Collins 755 Yadkinville Rd Mocksville , NC 27028 2790 Whitten Road, Memphis, TN 38133 Main 901.213.2400 ° Fax 901.213.2440 www.waypointanalytical.com Project Washington/NC Information : Report Number :21-075-0035 REPORT OF ANALYSIS Report Date : 03/24/2021 Received : 03/16/2021 Danyale Love Project Manager Lab No : 93200 Matrix: Solids Sample ID : Washington Sampled: 3/15/2021 10:30 Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Method Moisture 95.0 % 0.010 1 03/18/21 16:29 FMM SW-DRYWT Ammonia Nitrogen 9480 mg/Kg - dry 320 2000 1 03/23/21 15:00 JPJ 4500NH3C-2011 Nitrate+Nitrite-N <0 mg/Kg - dry 0 92.0 1 03/19/21 14:54 ZBD 4500NO3F-2011 Organic N 18320 mg/Kg - dry 2000 1 03/23/21 15:00 CALCULATION pH 8.2 s.u. 1 03/22/21 16:00 ADM 9045D Total Solids 4.97 % 0.010 0.010 1 03/18/21 16:29 FMM 2540G-2011 Total Volatile Solids 54.9 % 0.010 0.010 1 03/18/21 16:29 FMM 2540G-2011 Total Kjeldahl Nitrogen 27800 mg/Kg - dry 1000 1 03/23/21 15:48 CLP 4500NORGD-2011 Phosphorus 29600 mg/Kg - dry 55.2 100 1 03/20/21 07:17 JTR 6010D Aluminum 35000 mg/Kg - dry 92.4 100 1 03/20/21 07:17 JTR 6010D Arsenic 8.64J mg/Kg - dry 4.80 10.0 1 03/23/21 21:21 JADS 6010D Cadmium 0.7843 mg/Kg - dry 0.400 2.00 1 03/20/21 07:17 JTR 6010D Calcium 27600 mg/Kg - dry 774 1000 1 03/20/21 07:17 JTR 6010D Chromium 21.4 mg/Kg - dry 4.72 5.00 1 03/23/21 21:21 JADS 6010D Copper 246 mg/Kg - dry 6.20 10.0 1 03/20/21 07:17 JTR 6010D Iron 17300 mg/Kg - dry 170 200 1 03/20/21 07:17 JTR 6010D Lead 25.8 mg/Kg - dry 3.60 6.00 1 03/20/21 07:17 JTR 6010D Magnesium 52200 mg/Kg - dry 51.6 100 1 03/20/21 07:17 JTR 6010D Manganese 584 mg/Kg - dry 6.50 10.0 1 03/20/21 07:17 JTR 6010D Mercury 1.39 mg/Kg - dry 0.132 0.302 1 03/18/21 12:07 DDB 7471A Molybdenum 5.00 mg/Kg - dry 2.70 5.00 1 03/20/21 07:17 JTR 6010D Nickel 13.3 mg/Kg - dry 2.40 5.00 1 03/20/21 07:17 JTR 6010D Potassium 2420 mg/Kg - dry 124 200 1 03/20/21 07:17 JADS 6010D Qualifiers/ Definitions DF Dilution Factor J Estimated value L Limit Exceeded MQL Method Quantitation Limit Page 5 of 8 Waypoint, ANALYTICAL 46245 EMA Resources Inc Mr. Brent Collins 755 Yadkinville Rd Mocksville , NC 27028 Report Number : 21-075-0035 2790 Whitten Road, Memphis, TN 38133 Main 901.213.2400 ° Fax 901.213.2440 www.waypointanalytical.com Project Washington/NC Information : REPORT OF ANALYSIS Report Date : 03/24/2021 Received : 03/16/2021 Danyale Love Project Manager Lab No : 93200 Matrix: Solids Sample ID : Washington Sampled: 3/15/2021 10:30 Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Method Selenium 7.943 mg/Kg - dry 6.40 10.0 1 03/23/21 21:21 JADS 6010D Sodium 2140 mg/Kg - dry 260 500 1 03/20/21 07:17 JTR 6010D Zinc 634 mg/Kg - dry 16.2 25.0 1 03/20/21 07:17 JTR 6010D Sulfur 8900 mg/Kg - dry 104 200 1 03/20/21 07:17 JTR 6010D Sodium Absorption Ratio 0.39 Ratio 0.01 0.01 1 03/20/21 07:17 CALCULATION Qualifiers/ Definitions DF Dilution Factor J Estimated value Page 6 of 8 Waypoint.. ANALYTICAL 2790 Whitten Road, Memphis, TN 38133 Main 901.213.2400 ° Fax 901.213.2440 www.waypointanalytica I.com Shipment Receipt Form Customer Number: 46245 Customer Name: EMA Resources Inc Report Number: 21-075-0035 Shipping Method ® Fed Ex O US Postal O Lab 0 Other : O UPS 0 Client 0 Courier Thermometer ID: I# Shipping container/cooler uncompromised? ® Yes 0 No Number of coolers/boxes received Custody seals intact on shipping container/cooler? () Yes Custody seals intact on sample bottles? 0 Yes O No O No ® Not Present ® Not Present Chain of Custody (COC) present? ® Yes 0 No COC agrees with sample label(s)? ® Yes 0 No COC properly completed ® Yes O No Samples in proper containers? ® Yes O No Sample containers intact? ® Yes O No Sufficient sample volume for indicated test(s)? ® Yes O No All samples received within holding time? ® Yes 0 No Cooler temperature in compliance? ® Yes O No Cooler/Samples arrived at the laboratory on ice. Samples were considered acceptable as cooling process had begun. ® Yes O No Water - Sample containers properly preserved Water - VOA vials free of headspace O Yes O Yes O No O No ® N/A ® N/A Trip Blanks received with VOAs 0 Yes O No ® N/A Soil VOA method 5035 — compliance criteria met 0 Yes O No ® N/A High concentration container (48 hr) High concentration pre -weighed (methanol -14 d) Low concentration EnCore samplers (48 hr) Low conc pre -weighed vials (Sod Bis -14 d) Special precautions or instructions included? 0 Yes Comments: ® No Signature: Tory Phillips Date & Time: Page 7 of 8 03/16/2021 10:47:28 ro LO m co 0 ✓ n co Client Name/Address EMA Resources Inc 755 Yadkinville Rd Mocksville, NC 27028 Client Project Manager/Contact Brent Collins Billing Information Account #46245 For Laboratory Use Only Project Description Project/Site Location (City/State) ( I+=154 1 Ad YV RUSH - Additional charges apply Special Detection Limit(sj Date Results Needed Method ' ry �au��eJJ�JCourier of Shi red Ex Other ment UPS In USPS Client Drop Off Matrix Key WW - Wastewater GW -Groundwater DW- Drinking Water S -Soil/Solid 0-Oil P -Product M - Mise Protect Number Project Manager Phone # 336-399-3646 Project Manager Email brent.colIins@emaresources COM Purchase Order Number r - Slteft acility ID N ��M�� p 2790 Whitten Memphis, TN (901) 213.2400 10 ANALYTICAL Road 38133 Unless noted, all containers per Table ii of 40 CFR Part 136, Humber of Containers Matrix (Refer to key) e e3 E a Metals (6010D) TKN/Ammonia Nitrate/Organic N Total Solids 2 V J CO - A Goof z 10C Na25203 (Micro OnIyl 8 cool c= 6C C HZ504pHcI p None E NaOHpH).10 F HNO3 pHc2 G HCL pHc2 H H3PO4 pHc2 I Coal ce 6C NA25203 - Required Analysis / Preservative Comments/Notes Date ' Time Sample Identification 31/5 io. w h,L. n i ` L/ i.,--- V L.„,..-- Metals:Al,As,Ca,Gd,Cr,Cu,Fe,Pb - - - - Mn, Mg, Mo, Hg, NI, Se, Na, P,S, K,Zn - 1 ii 11111111111111111111111111111 EMA Resou Inc -°"5 - - . r _ ces hasninaton,NG 10 46:58 - I For Laboratory Use Only Sampled by (Name -Print) fir ret,¢adrA,r.i Client Remarks/Comments Sludge Samples - Report Dry Weight ice / N Custody Seals y / N Lab Comments Relinquls by: (SIGNATURE) Date Time 3 /I S 3, apisn Received by: (SIGNATURE) Date Tlnie Relinquished by: (SIGNATURE) Date Time Received by: (SIGNATURE) Date Time Blank ACoolerTern 1( Relinquished by: (SIGNATURE) Date Time Rece by SI TURE) -• ��Er _..yam Da Ti e 3 I LP Z { Sodium Calcium Magnesium Percent Solids 3/15/2021 mg/kg mg/L Equiv Weight Milli Equiv 2140 106.358 23 4.624261 27600 1371.72 20 68.586 52200 2594.34 12 216.195 4.97 SAR= SAR 0.39 Na+ /2 (Ca2+ + Mg2+) Waypoint ANALYTICAL 4/8/2021 EMA Resources Inc Mr. Brent Collins 755 Yadkinville Road Mocksville, NC, 27028 Ref: Analytical Testing Lab Report Number: 21-090-0120 Client Project Description: Washington Dear Mr. Brent Collins: Waypoint Analytical, LLC. received sample(s) on The above referenced project has been analyzed accordance with the applicable analytical method stage (refer to the chain of custody) results apply 2790 Whitten Road, Memphis, TN 38133 Main 901.213.2400 ° Fax 901.213.2440 www.waypointanalytical.com 3/31/2021 for the analyses presented in the following report. per your instructions. The analyses were performed in . Where the laboratory was not responsible for the sampling to the sample as received. The analytical data has been validated using standard quality control measures performed as required by the analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all parameters (NELAP and non-NELAP) were performed in accordance with guidelines established by the USEPA (including 40 CFR 136 Method Update Rule August 2017) and NELAC unless otherwise indicated. Any parameter for which the laboratory is not officially NELAP accredited is indicated by a '—' symbol. These are not included in the scope because NELAP accreditation is either not available or has not been applied for. Additional certifications may be held/are available for parameters, where NELAP accreditation is not required or applicable. A full list of certifications is available upon request. Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time. Refer to sample analysis time for confirmation of holding time compliance. The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as - received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to the samples included in this report. Please do not hesitate to contact me or client services if you have any questions or need additional information. Sincerely, Cpa, Danyale Love Project Manager Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis. TN I fR Page 1 of 7 Waypoint ANALYTICAL 2790 Whitten Road, Memphis, TN 38133 Main 901.213.2400 ° Fax 901.213.2440 www.waypointa nalytical.com Certification Summary Laboratory ID: WP MTN: Waypoint Analytical, LLC., Memphis, TN State Program Lab ID Expiration Date Alabama State Program 40750 02/28/2022 Arkansas State Program 88-0650 02/07/2022 California State Program 2904 06/30/2021 Florida State Program - NELAP E871157 06/30/2021 Georgia State Program C044 02/18/2023 Georgia State Program 04015 06/30/2021 Illinois State Program - NELAP 200078 10/10/2021 Kentucky State Program 80215 06/30/2021 Kentucky State Program KY90047 12/31/2021 Louisiana State Program - NELAP LA037 12/31/2021 Louisiana State Program - NELAP 04015 06/30/2021 Mississippi State Program MS 02/11/2023 North Carolina State Program 415 12/31/2021 Oklahoma State Program 9311 08/31/2021 Pennsylvania State Program - NELAP 68-03195 05/31/2021 South Carolina State Program 84002 06/30/2021 South Carolina State Program 84002 06/30/2021 Tennessee State Program 02027 02/11/2023 Tennessee A2LA ISO 17025:2017 4313.01 10/31/2021 Texas State Program - NELAP T104704180 09/30/2021 Virginia State Program 00106 06/30/2021 Virginia State Program - NELAP 460181 09/14/2021 Page 1 of 1 00001/21-090-0120 Page 2 of 7 Waypoint, ANALYTICAL Report Number: 21-090-0120 Client Project Description: Washington 2790 Whitten Road, Memphis, TN 38133 Main 901.213.2400 ° Fax 901.213.2440 www.waypointa nalytical. com Sample Summary Table Lab No Client Sample ID Matrix Date Collected Date Received 85994 Washington Solids 03/30/2021 09:00 03/31/2021 Page 3 of 7 Waypoint, ANALYTICAL 46245 EMA Resources Inc Mr. Brent Collins 755 Yadkinville Road Mocksville , NC 27028 Report Number : 21-090-0120 2790 Whitten Road, Memphis, TN 38133 Main 901.213.2400 ° Fax 901.213.2440 www.waypointanalytical.com Project Washington Information : REPORT OF ANALYSIS Report Date : 04/08/2021 Received : 03/31/2021 Danyale Love Project Manager Lab No : 85994 Matrix: Solids Sample ID : Washington Sampled: 3/30/2021 9:00 Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Method Sodium Absorption Ratio 0.38 Ratio 0.01 0.01 1 04/07/21 02:29 CALCULATION Moisture 95.1 % 0.010 1 03/31/21 15:59 FMM SW-DRYWT Ammonia Nitrogen 10600 mg/Kg - dry 327 2040 1 04/06/21 15:30 JPJ 4500NH3C-2011 Nitrate+Nitrite-N <94.3 mg/Kg - dry 94.3 94.3 1 04/06/21 15:32 ZBD 4500NO3F-2011 Organic N 24960 mg/Kg - dry 2041 1 04/06/21 15:30 CALCULATION pH 8.2 s.u. 1 04/05/21 09:00 CxC 9045D Total Solids 4.94 % 0.010 0.010 1 03/31/21 15:59 FMM 2540G-2011 Total Volatile Solids 54.1 % 0.010 0.010 1 03/31/21 15:59 FMM 2540G-2011 Total Kjeldahl Nitrogen 35500 mg/Kg - dry 1020 1 04/07/21 14:40 CLP 4500NORGD-2011 Phosphorus 31800 mg/Kg - dry 56.3 102 1 04/07/21 02:29 JADS 6010D Aluminum 34900 mg/Kg - dry 94.3 102 1 04/07/21 21:53 JADS 6010D Arsenic 6.653 mg/Kg - dry 4.90 10.2 1 04/07/21 02:29 JADS 6010D Cadmium 0.7843 mg/Kg - dry 0.408 2.04 1 04/07/21 02:29 JADS 6010D Calcium 30000 mg/Kg - dry 790 1020 1 04/07/21 02:29 JADS 6010D Chromium 18.7 mg/Kg - dry 4.82 5.10 1 04/07/21 02:29 JADS 6010D Copper 269 mg/Kg - dry 6.33 10.2 1 04/07/21 02:29 JADS 6010D Iron 18700 mg/Kg - dry 174 204 1 04/07/21 02:29 TJS 6010D Lead 26.3 mg/Kg - dry 3.67 6.12 1 04/07/21 02:29 JADS 6010D Magnesium 54300 mg/Kg - dry 52.7 102 1 04/07/21 02:29 JADS 6010D Manganese 571 mg/Kg - dry 6.63 10.2 1 04/07/21 02:29 JADS 6010D Mercury 1.31 mg/Kg - dry 0.131 0.300 1 04/05/21 11:54 DDB 7471A Molybdenum 4.903 mg/Kg - dry 2.76 5.10 1 04/07/21 02:29 JADS 6010D Nickel 14.6 mg/Kg - dry 2.45 5.10 1 04/07/21 02:29 JADS 6010D Qualifiers/ Definitions DF Dilution Factor J Estimated value L Limit Exceeded MQL Method Quantitation Limit Page 4 of 7 Waypoint, ANALYTICAL 46245 EMA Resources Inc Mr. Brent Collins 755 Yadkinville Road Mocksville , NC 27028 Project Washington Information : 2790 Whitten Road, Memphis, TN 38133 Main 901.213.2400 ° Fax 901.213.2440 www.waypointanalytical.com Report Number :21-090-0120 REPORT OF ANALYSIS Report Date : 04/08/2021 Received : 03/31/2021 Danyale Love Project Manager Lab No : 85994 Matrix: Solids Sample ID : Washington Sampled: 3/30/2021 9:00 Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Method Potassium 2000 mg/Kg - dry 126 204 1 04/07/21 21:53 DADS 6010D Selenium <6.53 mg/Kg - dry 6.53 10.2 1 04/07/21 02:29 DADS 6010D Sodium 2180 mg/Kg - dry 265 510 1 04/07/21 02:29 DADS 6010D Zinc 696 mg/Kg - dry 16.5 25.5 1 04/07/21 02:29 DADS 6010D Sulfur 8920 mg/Kg - dry 106 204 1 04/07/21 02:29 DADS 6010D Qualifiers/ Definitions DF Dilution Factor J Estimated value Page 5 of 7 Waypoint.. ANALYTICAL 2790 Whitten Road, Memphis, TN 38133 Main 901.213.2400 ° Fax 901.213.2440 www.waypointanalytica I.com Shipment Receipt Form Customer Number: 46245 Customer Name: EMA Resources Inc Report Number: 21-090-0120 ® Fed Ex O UPS Shipping Method O US Postal O Lab O Client 0 Courier O Other : Thermometer ID: I#99 Shipping container/cooler uncompromised? ® Yes 0 No Number of coolers/boxes received Custody seals intact on shipping container/cooler? () Yes Custody seals intact on sample bottles? 0 Yes O No O No ® Not Present ® Not Present Chain of Custody (COC) present? ® Yes 0 No COC agrees with sample label(s)? ® Yes 0 No COC properly completed ® Yes 0 No Samples in proper containers? ® Yes 0 No Sample containers intact? ® Yes 0 No Sufficient sample volume for indicated test(s)? ® Yes 0 No All samples received within holding time? ® Yes 0 No Cooler temperature in compliance? ® Yes 0 No Cooler/Samples arrived at the laboratory on ice. Samples were considered acceptable as cooling process had begun. ® Yes 0 No Water - Sample containers properly preserved Water - VOA vials free of headspace ® Yes 0 Yes O No O No O N/A ® N/A Trip Blanks received with VOAs 0 Yes O No ® N/A Soil VOA method 5035 — compliance criteria met 0 Yes O No ® N/A High concentration container (48 hr) High concentration pre -weighed (methanol -14 d) Low concentration EnCore samplers (48 hr) Low conc pre -weighed vials (Sod Bis -14 d) Special precautions or instructions included? 0 Yes Comments: ® No Signature: Tory Phillips Date & Time: Page 6 of 7 03/31/2021 13:32:23 Client Name/Address EMA Resources Inc 755 Yadkinville Rd Mocksville, NC 27028 Client Project Manager/Contact Brent Collins Rifling Information Account #46245 For Laboratory Use Only Project Description I4OSin;^S ^ jlj� Project/Site Location (City/State) Vji}Sl•1S iiN H RUSH — Additional charges apply Special Detection Urn Ms] Date Results Needed A Meth ElCourier f Shi ed Ex Other ment UPS OUSP5 Client Drop Off Matrix Key WW — Wastewater GW —Groundwater DW — Drinking Water 5 — Soil /Solid 0 — Oil P - Product M - Misc Project Number Project Manager Phone # 336-399-3646 I J Project Manager Email brentoollins@emaresources.com Purchase Order Number Site/Facillty ID # y ■aypoin 2790OD Whitten Memphis. (901) 213-2400 • t O ANALYTICAL ROW TN 38133 - Unless noted, all containers per Table II of 40 CFR Part 135. Number of Containers IMatrix (Refer to Key) (G)rab or (C}omposite Metals (6010D) TKN/Ammonia Nitrate/Organic N I Total Solids ,/�r�� a 1 i 1 W r � V U . A Cool r DX Na252O3 (Mkro Onlyl 8 Cool < 6C a D H2504 phlc2 None Required E NaOH pHa10 F HNO3 pHr2 G HCY pHe2 H H3PO4 PHc2 I oz.!. 6C NA25203 Date Time Sample Identification Re, uired Analysis / Preservative Comments/Notes il3G 9• °Com ' nsl.,,,5- o,. j 5" L= 4.- i.- 4,7" ,.V- r! o i/ w Meta1s:AI,As,Ca,Cd,Cr,Cu,Fe, Pb I' / 1 - Mn,Mg,Ma,Hg,Ni,Se,Na,P,S,K,Zn I& i ► 11011 Mill IV I-2021 III1 III IIII IIIII it Ill III 121 0t20 I vvasninq[on - -ee. _I 1 i a - i - L - - - For laboratory Use Only Sampled by (Name — Print) r�� Lam'/ 75 Client Remarks/Comments Sludge Samples - Report Dry WeiWeight Ice N _ Custody y 4 Lab Comments Relinquis by: (SIGNATURE) Date Time 3/3v j. s ,,,, Received by: (SIGNATURE) — Date Time Blan Cooler Temp �) �7 re �l Relinquished by: (SIGNATURE) Date Time Recelv by: - GNATURE) Date Time Relinquished by: (SIGNATURE) Date Time Rec ed y; ( NATURE) eti Ti e liZI Ds Sodium Calcium Magnesium Percent Solids 3/30/2021 mg/kg mg/L Equiv Weight Milli Equiv 2180 107.692 23 4.682261 30000 1482 20 74.1 54300 2682.42 12 223.535 4.94 SAR= SAR 0.38 Na+ /2 (Ca2+ + Mg2+) Waypoint ANALYTICAL 11/19/2021 EMA Resources Inc Mr. Brent Collins 755 Yadkinville Rd Mocksville, NC, 27028 Ref: Analytical Testing Lab Report Number: 21-315-0179 Client Project Description: Washington, NC 2790 Whitten Road, Memphis, TN 38133 Main 901.213.2400 ° Fax 901.213.2440 www.waypointanalytical.com Dear Mr. Brent Collins: Waypoint Analytical, LLC. received sample(s) on 11/11/2021 for the analyses presented in the following report. The above referenced project has been analyzed per your instructions. The analyses were performed in accordance with the applicable analytical method. Where the laboratory was not responsible for the sampling stage (refer to the chain of custody) results apply to the sample as received. The analytical data has been validated using standard quality control measures performed as required by the analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all parameters (NELAP and non-NELAP) were performed in accordance with guidelines established by the USEPA (including 40 CFR 136 Method Update Rule May 2021) and NELAC unless otherwise indicated. Any parameter for which the laboratory is not officially NELAP accredited is indicated by a '—' symbol. These are not included in the scope because NELAP accreditation is either not available or has not been applied for. Additional certifications may be held/are available for parameters, where NELAP accreditation is not required or applicable. A full list of certifications is available upon request. Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time. Refer to sample analysis time for confirmation of holding time compliance. The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as - received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to the samples included in this report. Please do not hesitate to contact me or client services if you have any questions or need additional information. Sincerely, Cpa, Danyale Love Project Manager Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis. TN I fR Page 1 of 8 Waypoint ANALYTICAL 2790 Whitten Road, Memphis, TN 38133 Main 901.213.2400 ° Fax 901.213.2440 www.waypointa nalytical.com Certification Summary Laboratory ID: WP MTN: Waypoint Analytical, LLC., Memphis, TN State Program Lab ID Expiration Date Alabama State Program 40750 02/28/2022 Arkansas State Program 88-0650 02/07/2022 California State Program 2904 06/30/2022 Florida State Program - NELAP E871157 06/30/2022 Georgia State Program C044 02/18/2023 Georgia State Program 04015 06/30/2022 Illinois State Program - NELAP 200078 10/10/2022 Kentucky State Program 80215 06/30/2022 Kentucky State Program KY90047 12/31/2021 Louisiana State Program - NELAP LA037 12/31/2021 Louisiana State Program - NELAP 04015 06/30/2022 Mississippi State Program MS 02/11/2023 North Carolina State Program 415 12/31/2021 Pennsylvania State Program - NELAP 68-03195 05/31/2022 South Carolina State Program 84002 06/30/2022 South Carolina State Program 84002 06/30/2022 Tennessee State Program 02027 02/11/2023 Texas State Program - NELAP T104704180 09/30/2022 Virginia State Program 00106 06/30/2022 Virginia State Program - NELAP 460181 09/14/2022 Page 1 of 1 00001/21-315-0179 Page 2 of 8 Waypoint, ANALYTICAL Report Number: Client Project Description: 21-315-0179 Washington, NC 2790 Whitten Road, Memphis, TN 38133 Main 901.213.2400 ° Fax 901.213.2440 www.waypointa nalytical. com Sample Summary Table Lab No Client Sample ID Matrix Date Collected Date Received 97704 Washington Solids 11/10/2021 07:45 11/11/2021 Page 3 of 8 Waypol nt.M ANALYTICAL 2790 Whitten Road, Memphis, TN 38133 Main 901.213.2400 ° fax 901.213.2440 www.waypointanalytical.com Client: EMA Resources Inc Project: Washington, NC Lab Report Number: 21-315-0179 Date: 11/19/2021 CASE NARRATIVE Metals Analysis Method 6010D Sample 98731 Analyte: Iron QC Batch No: L585490/L585008 The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test was performed and passed quality control acceptance ranges. No matrix interference is suspected. Analyte: Magnesium QC Batch No: L585490/L585008 The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test was performed and passed quality control acceptance ranges. No matrix interference is suspected. Analyte: Manganese QC Batch No: L585490/L585008 The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test was performed and passed quality control acceptance ranges. No matrix interference is suspected. Analyte: Phosphorus QC Batch No: L585490/L585008 The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test was performed and passed quality control acceptance ranges. No matrix interference is suspected. Analyte: Lead QC Batch No: L585490/L585008 The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test was performed and passed quality control acceptance ranges. No matrix interference is suspected. Analyte: Sulfur QC Batch No: L585490/L585008 The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test was performed and passed quality control acceptance ranges. No matrix interference is suspected. Page 4 of 8 Waypoint, ANALYTICAL 46245 EMA Resources Inc Mr. Brent Collins 755 Yadkinville Rd Mocksville , NC 27028 2790 Whitten Road, Memphis, TN 38133 Main 901.213.2400 ° Fax 901.213.2440 www.waypointanalytical.com Project Washington, NC Information : Report Number :21-315-0179 REPORT OF ANALYSIS Report Date : 11/19/2021 Received : 11/11/2021 Danyale Love Project Manager Lab No : 97704 Matrix: Solids Sample ID : Washington Sampled: 11/10/2021 7:45 Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Method Moisture 95.5 % 0.010 1 11/12/21 16:14 FMM SW-DRYWT Ammonia Nitrogen 9220 mg/Kg - dry 356 2220 1 11/17/21 14:30 JPJ 4500NH3C-2011 Nitrate+Nitrite-N 106 mg/Kg - dry 104 104 1 11/17/21 14:15 ZBD 4500NO3F-2011 Organic N 37670 mg/Kg - dry 355.6 2222 1 11/17/21 10:00 DH CALCULATION pH 7.2 s.u. 1 11/18/21 14:00 ADM 9045D Total Solids 4.48 % 0.010 0.010 1 11/12/21 16:14 FMM 2540G-2011 Total Volatile Solids 53.6 % 0.010 0.010 1 11/12/21 16:14 FMM 2540G-2011 Total Kjeldahl Nitrogen 46900 mg/Kg - dry 222 5560 1 11/17/21 10:00 JPJ ;M-4500-NH3C-TKI` Phosphorus 32700 mg/Kg - dry 61.3 111 1 11/18/21 05:06 TJS 6010D Aluminum 33300 mg/Kg - dry 103 111 1 11/18/21 05:06 TJS 6010D Arsenic 7.843 mg/Kg - dry 5.33 11.1 1 11/18/21 05:06 TJS 6010D Cadmium 0.8843 mg/Kg - dry 0.444 2.22 1 11/18/21 05:06 TJS 6010D Calcium 27600 mg/Kg - dry 860 1110 1 11/18/21 05:06 TJS 6010D Chromium 20.8 mg/Kg - dry 5.24 5.56 1 11/18/21 05:06 TJS 6010D Copper 287 mg/Kg - dry 6.89 11.1 1 11/18/21 05:06 TJS 6010D Iron 22200 mg/Kg - dry 189 222 1 11/18/21 05:06 TJS 6010D Lead 51.3 mg/Kg - dry 4.00 6.67 1 11/19/21 13:47 TJS 6010D Magnesium 2510 mg/Kg - dry 57.3 111 1 11/18/21 05:06 TJS 6010D Manganese 633 mg/Kg - dry 7.22 11.1 1 11/18/21 05:06 TJS 6010D Mercury 1.20 mg/Kg - dry 0.148 0.340 1 11/17/21 15:27 JW2 7471A Molybdenum 5.113 mg/Kg - dry 3.00 5.56 1 11/18/21 05:06 TJS 6010D Nickel 16.1 mg/Kg - dry 2.67 5.56 1 11/18/21 05:06 TJS 6010D Potassium 1780 mg/Kg - dry 137 222 1 11/18/21 22:17 TJS 6010D Qualifiers/ Definitions DF Dilution Factor J Estimated value L Limit Exceeded MQL Method Quantitation Limit Page 5 of 8 Waypoint, ANALYTICAL 46245 EMA Resources Inc Mr. Brent Collins 755 Yadkinville Rd Mocksville , NC 27028 Report Number : 21-315-0179 2790 Whitten Road, Memphis, TN 38133 Main 901.213.2400 ° Fax 901.213.2440 www.waypointanalytical.com Project Washington, NC Information : REPORT OF ANALYSIS Report Date : 11/19/2021 Received : 11/11/2021 Danyale Love Project Manager Lab No : 97704 Matrix: Solids Sample ID : Washington Sampled: 11/10/2021 7:45 Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Method Selenium <7.11 mg/Kg - dry 7.11 11.1 1 11/18/21 05:06 TJS 6010D Sodium 2510 mg/Kg - dry 289 556 1 11/18/21 05:06 TJS 6010D Zinc 807 mg/Kg - dry 18.0 27.8 1 11/18/21 05:06 TJS 6010D Sulfur 11200 mg/Kg - dry 115 222 1 11/18/21 05:06 TJS 6010D Sodium Absorption Ratio 0.82 Ratio 0.01 0.01 1 11/18/21 05:06 CALCULATION Qualifiers/ Definitions DF Dilution Factor J Estimated value Page 6 of 8 Waypoint.. ANALYTICAL 2790 Whitten Road, Memphis, TN 38133 Main 901.213.2400 ° Fax 901.213.2440 www.waypointanalytica I.com Shipment Receipt Form Customer Number: 46245 Customer Name: EMA Resources Inc Report Number: 21-315-0179 0 Fed Ex 0 UPS Shipping Method O US Postal 0 Lab O Client 0 Courier 0Other : Thermometer ID: I#102 Shipping container/cooler uncompromised? 0Yes 0No Number of coolers/boxes received Custody seals intact on shipping container/cooler? U Yes Custody seals intact on sample bottles? O Yes O No O No 0 Not Present 0 Not Present Chain of Custody (COC) present? D Yes 0 No COC agrees with sample label(s)? D Yes 0 No COC properly completed D Yes 0 No Samples in proper containers? D Yes 0 No Sample containers intact? D Yes 0 No Sufficient sample volume for indicated test(s)? D Yes 0 No All samples received within holding time? D Yes 0 No Cooler temperature in compliance? D Yes 0 No Cooler/Samples arrived at the laboratory on ice. Samples were considered acceptable as cooling process had begun. D Yes 0 No Water - Sample containers properly preserved Water - VOA vials free of headspace 0 Yes 0 Yes O No O No 0 N/A 0 N/A Trip Blanks received with VOAs 0 Yes O No ON/A Soil VOA method 5035 — compliance criteria met 0 Yes O No ON/A High concentration container (48 hr) High concentration pre -weighed (methanol -14 d) Low concentration EnCore samplers (48 hr) Low conc pre -weighed vials (Sod Bis -14 d) Special precautions or instructions included? 0 Yes Comments: Di No Signature: Kristina A. McAdams Date & Time: Page 7 of 8 11 /11 /2021 16:08:27 Client Name/Address EMA Resources Inc 755 Yadkinville Rd Mocksville. NC 27028 Client Project Manager/Contact Brent Collins Billing Information Account #46245 For Laboratory Use Only Project Description r Project/Site Location (City/State) ``--— WaS'1Z- i$41 % X- RUSH - Additional charges apply Special Detection Limits) Date Results Needed Meth of Shipment Fed Ex CourierClient Other 9UPS DU5P5 Drop Off Matrix Key WW - Wastewater GW - Groundwater DW - Drinking Water S - Soil /Solid 0 - Oil P- Product M -Misc Project Number Project Manager Phone tt 336-399-3646 Project Manager Email brent.collins@emaresources.corn ~ Purchase Order Number Site/Facility ID p ��,%Y_ } '�CD ■ ■ ` ANALYTICAL 2790 Whitten Road Ntcmhis, TN 3g13i (9i11) 213-24(It1 _ Unless noted, all containers per Table II of 40 CFR Part 136. Number of Containers Matrix (Refer to Key) [)rab or (C}omposite --, ❑ C7 cn io LKNIAmm©nia Nitrate/Organic N U +� CO V J r ti C„�1 A Cool c 10C Na25203 (Micro Only) B Cool �_ 5C C H2504 pHr2 D None Required E NaDH pHa10 F HNO3 PH<2 G HCL pHc2 H H3PO4 psk2 1 Cool e= GC NAI52O3 Date r Time Sample Identification Required Analysis / Preservative Comments/Notes "IID 7:ySvi ir,)ast,: A ] S`a t G v v- "f t— rf Metals:Al.As,Ca.Cd,Cr,Cu,Fe,Pb Mn. Mg, Mo, Hg, N i,Se, Na, P,S, K,Zn 11111111111 II13111111Tell/ 1111 Hhl!1�l� 41 i r MA Resources Wash proton Inc . NC 6.08:00 For Laboratory Use only Sampled by (Name- Print) ,l rrrt"(„`f6' Client Remarks/Comments Sludge Samples - Report Dry Weight Ice 6"i / N CSetaIs ody 'if /rf i - Lab Comrnents Relinqui d by: (51 TURE) Date Time ,aIP A � ti Received by: (SIGNATURE) Date Time BIa Cooler Temp Relinquished by: (SIGNATURE) Date Time Received by: (SIGNATURE) Date Time {U Relinquished by: (SIGNATURE) Date Time k 'iv is 5 D i Ti e c Sodium Calcium Magnesium Percent Solids 11/10/2021 mg/kg mg/L Equiv Weight Milli Equiv 2510 112.448 23 4.889043 27600 1236.48 20 61.824 2510 112.448 12 9.370667 4.48 SAR= SAR 0.82 Na+ /2 (Ca2+ + Mg2+) Waypoint ANALYTICAL 12/8/2021 EMA Resources Inc Mr. Brent Collins 755 Yadkinville Road Mocksville, NC, 27028 Ref: Analytical Testing Lab Report Number: 21-335-0015 Client Project Description: Washington, NC 2790 Whitten Road, Memphis, TN 38133 Main 901.213.2400 ° Fax 901.213.2440 www.waypointanalytical.com Dear Mr. Brent Collins: Waypoint Analytical, LLC. received sample(s) on 12/1/2021 for the analyses The above referenced project has been analyzed per your instructions. The accordance with the applicable analytical method. Where the laboratory was stage (refer to the chain of custody) results apply to the sample as received. presented in the following report. analyses were performed in not responsible for the sampling The analytical data has been validated using standard quality control measures performed as required by the analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all parameters (NELAP and non-NELAP) were performed in accordance with guidelines established by the USEPA (including 40 CFR 136 Method Update Rule May 2021) and NELAC unless otherwise indicated. Any parameter for which the laboratory is not officially NELAP accredited is indicated by a '—' symbol. These are not included in the scope because NELAP accreditation is either not available or has not been applied for. Additional certifications may be held/are available for parameters, where NELAP accreditation is not required or applicable. A full list of certifications is available upon request. Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time. Refer to sample analysis time for confirmation of holding time compliance. The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as - received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to the samples included in this report. Please do not hesitate to contact me or client services if you have any questions or need additional information. Sincerely, Cpa, Danyale Love Project Manager Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis. TN I fR Page 1 of 8 Waypoint ANALYTICAL 2790 Whitten Road, Memphis, TN 38133 Main 901.213.2400 ° Fax 901.213.2440 www.waypointa nalytical.com Certification Summary Laboratory ID: WP MTN: Waypoint Analytical, LLC., Memphis, TN State Program Lab ID Expiration Date Alabama State Program 40750 02/28/2022 Arkansas State Program 88-0650 02/07/2022 California State Program 2904 06/30/2022 Florida State Program - NELAP E871157 06/30/2022 Georgia State Program C044 02/18/2023 Georgia State Program 04015 06/30/2022 Illinois State Program - NELAP 200078 10/10/2022 Kentucky State Program 80215 06/30/2022 Kentucky State Program KY90047 12/31/2021 Louisiana State Program - NELAP LA037 12/31/2021 Louisiana State Program - NELAP 04015 06/30/2022 Mississippi State Program MS 02/11/2023 North Carolina State Program 415 12/31/2021 Pennsylvania State Program - NELAP 68-03195 05/31/2022 South Carolina State Program 84002 06/30/2022 South Carolina State Program 84002 06/30/2022 Tennessee State Program 02027 02/11/2023 Texas State Program - NELAP T104704180 09/30/2022 Virginia State Program 00106 06/30/2022 Virginia State Program - NELAP 460181 09/14/2022 Page 1 of 1 00001/21-335-0015 Page 2 of 8 Waypoint, ANALYTICAL Report Number: Client Project Description: 21-335-0015 Washington, NC 2790 Whitten Road, Memphis, TN 38133 Main 901.213.2400 ° Fax 901.213.2440 www.waypointa nalytical. com Sample Summary Table Lab No Client Sample ID Matrix Date Collected Date Received 89410 Washington Solids 11/30/2021 08:45 12/01/2021 Page 3 of 8 Waypol nt.M ANALYTICAL 2790 Whitten Road, Memphis, TN 38133 Main 901.213.2400 ° fax 901.213.2440 www.waypointanalytical.com Client: EMA Resources Inc Project: Washington, NC Lab Report Number: 21-335-0015 Date: 12/8/2021 CASE NARRATIVE Metals Analysis Method 6010D Analyte: Aluminum QC Batch No: L588736/L587689 The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test was performed and passed quality control acceptance ranges. No matrix interference is suspected. Analyte: Arsenic QC Batch No: L588736/L587689 The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A post digestion spike was performed and passed quality control acceptance ranges. No matrix interference is suspected. Analyte: Calcium QC Batch No: L588736/L587689 The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test was performed and passed quality control acceptance ranges. No matrix interference is suspected. Analyte: Iron QC Batch No: L588736/L587689 The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test was performed and passed quality control acceptance ranges. No matrix interference is suspected. Analyte: Potassium QC Batch No: L588736/L587689 The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test was performed and passed quality control acceptance ranges. No matrix interference is suspected. Analyte: Magnesium QC Batch No: L588736/L587689 The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test was performed and passed quality control acceptance ranges. No matrix interference is suspected. Analyte: Manganese QC Batch No: L588736/L587689 The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test was performed and passed quality control acceptance ranges. No matrix interference is suspected. Analyte: Lead QC Batch No: L588736/L587689 The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A post digestion spike was performed and passed quality control acceptance ranges. No matrix interference is suspected. Page 4 of 8 Waypoint, ANALYTICAL 46245 EMA Resources Inc Mr. Brent Collins 755 Yadkinville Road Mocksville , NC 27028 2790 Whitten Road, Memphis, TN 38133 Main 901.213.2400 ° Fax 901.213.2440 www.waypointanalytical.com Project Washington, NC Information : Report Number :21-335-0015 REPORT OF ANALYSIS Report Date : 12/08/2021 Received : 12/01/2021 Danyale Love Project Manager Lab No : 89410 Matrix: Solids Sample ID : Washington Sampled: 11/30/2021 8:45 Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Method Moisture 95.8 % 0.010 1 12/02/21 15:52 FMM SW-DRYWT Ammonia Nitrogen 11200 mg/Kg - dry 381 2380 1 12/07/21 14:30 JPJ 4500NH3C-2011 Nitrate+Nitrite-N 1330 mg/Kg - dry 118 118 1 12/07/21 15:08 ZBD 4500NO3F-2011 Organic N 44020 mg/Kg - dry 381.0 2381 1 12/07/21 10:00 CALCULATION pH 7.8 s.u. 1 12/08/21 15:11 DRS 9045D Total Solids 4.24 % 0.010 0.010 1 12/02/21 15:52 FMM 2540G-2011 Total Volatile Solids 54.3 % 0.010 0.010 1 12/02/21 15:52 FMM 2540G-2011 Total Kjeldahl Nitrogen 55200 mg/Kg - dry 238 5950 1 12/07/21 10:00 JPJ ;M-4500-NH3C-TKI` Phosphorus 33300 mg/Kg - dry 65.7 119 1 12/06/21 22:20 JADS 6010D Aluminum 33600 mg/Kg - dry 110 119 1 12/06/21 22:20 JADS 6010D Arsenic <11.9 mg/Kg - dry 5.71 11.9 1 12/06/21 22:20 JADS 6010D Cadmium <2.38 mg/Kg - dry 0.476 2.38 1 12/06/21 22:20 JADS 6010D Calcium 31900 mg/Kg - dry 921 1190 1 12/06/21 22:20 JADS 6010D Chromium 18.4 mg/Kg - dry 5.62 5.95 1 12/06/21 22:20 JADS 6010D Copper 300 mg/Kg - dry 7.38 11.9 1 12/06/21 22:20 JADS 6010D Iron 22500 mg/Kg - dry 203 238 1 12/06/21 22:20 JADS 6010D Lead 32.9 mg/Kg - dry 4.29 7.14 1 12/06/21 22:20 JADS 6010D Magnesium 2520 mg/Kg - dry 61.4 119 1 12/06/21 22:20 JADS 6010D Manganese 660 mg/Kg - dry 7.74 11.9 1 12/06/21 22:20 JADS 6010D Mercury 1.39 mg/Kg - dry 0.155 0.355 1 12/06/21 13:45 TJS 7471A Molybdenum <5.95 mg/Kg - dry 3.21 5.95 1 12/06/21 22:20 JADS 6010D Nickel 15.8 mg/Kg - dry 2.86 5.95 1 12/06/21 22:20 JADS 6010D Potassium 2020 mg/Kg - dry 147 238 1 12/07/21 17:55 JADS 6010D Qualifiers/ Definitions DF Dilution Factor J Estimated value L Limit Exceeded MQL Method Quantitation Limit Page 5 of 8 Waypoint, ANALYTICAL 46245 EMA Resources Inc Mr. Brent Collins 755 Yadkinville Road Mocksville , NC 27028 2790 Whitten Road, Memphis, TN 38133 Main 901.213.2400 ° Fax 901.213.2440 www.waypointanalytical.com Project Washington, NC Information : Report Number :21-335-0015 REPORT OF ANALYSIS Report Date : 12/08/2021 Received : 12/01/2021 Danyale Love Project Manager Lab No : 89410 Matrix: Solids Sample ID : Washington Sampled: 11/30/2021 8:45 Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Method Selenium <11.9 mg/Kg - dry 7.62 11.9 1 12/06/21 22:20 DADS 6010D Sodium 2740 mg/Kg - dry 310 595 1 12/07/21 17:55 DADS 6010D Zinc 852 mg/Kg - dry 19.3 29.8 1 12/06/21 22:20 DADS 6010D Sulfur 11600 mg/Kg - dry 123 238 1 12/06/21 22:20 DADS 6010D Sodium Absorption Ratio 0.81 Ratio 0.01 0.01 1 12/06/21 22:20 CALCULATION Qualifiers/ Definitions DF Dilution Factor J Estimated value Page 6 of 8 Waypoint.. ANALYTICAL 2790 Whitten Road, Memphis, TN 38133 Main 901.213.2400 ° Fax 901.213.2440 www.waypointanalytica I.com Shipment Receipt Form Customer Number: 46245 Customer Name: EMA Resources Inc Report Number: 21-335-0015 0 Fed Ex 0 UPS Shipping Method O US Postal 0 Lab O Client 0 Courier 0Other : Thermometer ID: IT135 Shipping container/cooler uncompromised? 0Yes 0No Number of coolers/boxes received Custody seals intact on shipping container/cooler? U Yes Custody seals intact on sample bottles? O Yes O No O No 0 Not Present 0 Not Present Chain of Custody (COC) present? D Yes 0 No COC agrees with sample label(s)? D Yes 0 No COC properly completed D Yes 0 No Samples in proper containers? D Yes 0 No Sample containers intact? D Yes 0 No Sufficient sample volume for indicated test(s)? D Yes 0 No All samples received within holding time? D Yes 0 No Cooler temperature in compliance? D Yes 0 No Cooler/Samples arrived at the laboratory on ice. Samples were considered acceptable as cooling process had begun. D Yes 0 No Water - Sample containers properly preserved Water - VOA vials free of headspace 0 Yes 0 Yes O No O No 0 N/A 0 N/A Trip Blanks received with VOAs 0 Yes O No ON/A Soil VOA method 5035 — compliance criteria met 0 Yes O No ON/A High concentration container (48 hr) High concentration pre -weighed (methanol -14 d) Low concentration EnCore samplers (48 hr) Low conc pre -weighed vials (Sod Bis -14 d) Special precautions or instructions included? 0 Yes Comments: Oi No Signature: Emily M. Peterson Date & Time: Page 7 of 8 12/01/2021 09:35:44 Client Name/Address EMA Resources Inc I 755 Yadkinville Rd Mocksville, NC 27028 Client Project Manager/Contact Brent Collins Billing Information Account #46245 For Laboratory Use Only Project Description Project/Site Location (City/State) `` I r OS ,..45 .J N 7 RUSH — Additional charges apply Special Detection Limit(s) Date Results Needed Method of Shipment IFed Ex r"I Courier LJJ Other I. ■ UPS USPS Client Drop Off Matrix Key WW — Wastewater GW —Groundwater DW — Drinking Water S — Soil /Solid 0 — Oil P - Product M - Misc Project Number Project Manager Phone # 336-399-3646 Project Manager Email brent.collins@emaresources,com Purchase Order Number Site/Facility ID Si aypoint. 2790 Whitten Memphis, TN (901) 213-2� • ANALYTICAL Road 38133 Unless noted, all containers per Table II of 40 CFR Part 136. Number of Containers Matrix (Refer to Key) (G)rab or (C)omposite Metals (6010D) TKN/Ammonia Nitrate/Organic N Total Solids T J�— 0- V) ) I-1 •' / 0 I A Cool < 1OC Na2S2O3 (Nitro Drily) B Cool c= 6C C H2SO4PHc2 D None Required E NaOH pHa1O F HNO3 pH<2 G Htt pH<2 H H3PO4 pH<2 I Cool <= 5C NA2S2O3 Date Time y Sample Identification Required Analysis / Preservative Comments/Notes 5)I30 1"' 1i^ioss:nS 14el 1 5t'd G v L� v i..— L.....- l I.-- Metals:AI,As,Ca,Cd,Cr,Cu,Fe,Pb r Mn,Mg,Mo, Hg, N i,Se, Na, P,S, K,Zn 1 , 46245 12-0, 2021 I NE w _ - EMA Washington. Resources Inc 09-35.02 NC i - i i For Laboratory Use Only Sampled by !3{fnt (Name — Print} C704 '/..5 Client Remarks/Comments Sludge Samples - Report Dry Weight Ice OfN Custody 1 Seals YRNI , 1 l Lab Comments Relinqu ed by: (SIGNATURE) Date Time �I �30 3. .yr+r Received by: (SIGNATURE) Date Time - Blank/ Temp t ' a i - Relinquished by: (SIGNATURE) Date Time Received by: (SIGNATURE) Date Time RelinquishedTi by: (SIGNATURE] Date Time - rived by: (SIG TUREj Datf Time IP1e Mblifl -1111 12- Sodium Calcium Magnesium Percent Solids 11/30/2021 mg/kg mg/L Equiv Weight Milli Equiv 2740 116.176 23 5.05113 31900 1352.56 20 67.628 2520 106.848 12 8.904 4.24 SAR= SAR 0.82 Na+ /2 (Ca2+ + Mg2+) 1 ceAnalytical® A \ A L Y T I C A L REPORT Cp March 24, 2021 z Tc 3 Ss EMA Resources 4 Sample Delivery Group: L1327O35 Cn Samples Received: 03/16/2021 5Sr Project Number: 6 Description: Sludge Qc 7 GI Report To: Mr. Brent Collins 755 Yadkinville Road rAll Mocksville, NC 27028 II 9 Sc Entire Report Reviewed By: ,, dV- Justin Carr Project Manager Results relate only to the items tested or calibrated and are reported as rounded values.This test report shall not be Aim X. reproduced,except in full,without written approval of the laboratory.Where applicable,sampling conducted by Pace Analytical National is performed per guidance provided in laboratory standard operating procedures ENV-SOP-MTJL-0067 and ft ENV-SOP-MTJL-0068.Where sampling conducted by the customer,results relate to the accuracy of the information provided, and as the samples are received. dji. dr ) e°°. MI"- fiffilMlipm,ft. 1111111111_ 11.1%.111211.11C..fr lib. fili ) 11114(1: . 11111— ' j .., i )1 glii W. 11114 IIII Illie a Pace Analytical National 12065 Lebanon Rd Mount Juliet, TN 37122 615-758-5858 800-767-5859 www.pacenational.com ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: EMA Resources L1327035 03/24/2115:48 1 of 20 TABLE OF CONTENTS Cp: Cover Page Tc: Table of Contents 2 Ss: Sample Summary 3 Cn: Case Narrative 4 Sr: Sample Results 5 WASHINGTON L1327035-01 5 Qc: Quality Control Summary 7 Wet Chemistry by Method 9012 B 7 Wet Chemistry by Method 9034-9030B 8 Wet Chemistry by Method 9045D 9 Wet Chemistry by Method D93/1010A 10 Mercury by Method 7470A 11 Metals (ICP) by Method 6010D 12 Volatile Organic Compounds (GC/MS) by Method 8260D 13 Chlorinated Acid Herbicides (GC) by Method 8151A 14 Pesticides (GC) by Method 8081B 15 Semi Volatile Organic Compounds (GC/MS) by Method 8270E 16 GI: Glossary of Terms 18 Al: Accreditations & Locations 19 Sc: Sample Chain of Custody 20 Cp F 4 Cn 5 Sr [Qc] 7 GI 8 AI 9 SC ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: EMA Resources L1327035 03/24/2115:48 2 of 20 SAMPLE SUMMARY WASHINGTON L1327035-01 Waste Collected by Collected date/time Received date/time Brent Collins 03/15/2110:30 03/16/21 09:00 Method Batch Dilution Preparation Analysis Analyst Location date/time date/time Preparation by Method 1311 WG1635858 1 03/17/2110:38 03/17/2110:38 APH Mt. Juliet, TN Preparation by Method 1311 WG1638093 1 03/21/21 09:44 03/21/21 09:44 APH Mt. Juliet, TN Wet Chemistry by Method 9012 B WG1637283 1 03/19/21 08:57 03/20/21 02:53 SDL Mt. Juliet, TN Wet Chemistry by Method 9034-9030B WG1636150 1 03/17/21 22:00 03/17/21 22:00 LDT Mt. Juliet, TN Wet Chemistry by Method 9045D WG1635806 1 03/17/2110:40 03/17/2111:06 AMH Mt. Juliet, TN Wet Chemistry by Method D93/1010A WG1637776 1 03/20/2115:00 03/20/2115:00 LRP Mt. Juliet, TN Mercury by Method 7470A WG1636746 1 03/18/2111:54 03/19/21 09:00 ABL Mt. Juliet, TN Metals (ICP) by Method 6010D WG1637155 1 03/19/21 00:14 03/19/2114:35 KMG Mt. Juliet, TN Volatile Organic Compounds (GC/MS) by Method 8260D WG1638433 1 03/22/2114:33 03/22/2114:33 TPR Mt. Juliet, TN Chlorinated Acid Herbicides (GC) by Method 8151A WG1638364 1 03/22/2112:26 03/23/2116:53 AMM Mt. Juliet, TN Pesticides (GC) by Method 8081B WG1637816 1 03/21/21 03:32 03/21/2111:23 AMM Mt. Juliet, TN Semi Volatile Organic Compounds (GC/MS) by Method 8270E WG1636160 1 03/18/2116:43 03/21/21 23:02 AMG Mt. Juliet, TN t Cp 2 Tc ri 4 Cn 5 Sr L6QC] 7 GI 8 AI 9 SC ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: EMA Resources L1327035 03/24/2115:48 3 of 20 CASE NARRATIVE All sample aliquots were received at the correct temperature, in the proper containers, with the appropriate preservatives, and within method specified holding times, unless qualified or notated within the report. Where applicable, all MDL (LOD) and RDL (LOQ) values reported for environmental samples have been corrected for the dilution factor used in the analysis. All Method and Batch Quality Control are within established criteria except where addressed in this case narrative, a non-conformance form or properly qualified within the sample results. By my digital signature below, I affirm to the best of my knowledge, all problems/anomalies observed by the laboratory as having the potential to affect the quality of the data have been identified by the laboratory, and no information or data have been knowingly withheld that would affect the quality of the data. Justin Carr Project Manager Project Narrative All Reactive Cyanide results reported in the attached report were determined as totals using method 9012B. All Reactive Sulfide results reported in the attached report were determined as totals using method 9034/9030B. Cp 2 Tc 3 Ss 4 Cn 5 Sr L6QC] GI 8AI 9 SC ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: EMA Resources L1327035 03/24/2115:48 4 of 20 WASHINGTON SAMPLE RESULTS - 01 Collected date/time: 03/15/21 10:30 L1327035 Preparation by Method 1311 Analyte Result Qualifier Prep date / time Batch TCLP Extraction - 3/17/202110:38:57 AM WG1635858 TCLP ZHE Extraction - 3/21/2021 9:44:11 AM WG1638093 Fluid 1 3/17/202110:38:57 AM WG1635858 Initial pH 7.90 3/17/202110:38:57 AM WG1635858 Final pH 5.21 3/17/202110:38:57 AM WG1635858 Wet Chemistry by Method 9012 B Analyte Reactive Cyanide Result Qualifier RDL Dilution Analysis Batch mg/kg mg/kg date / time ND 0.250 1 03/20/2021 02:53 WG1637283 Wet Chemistry by Method 9034-9030B Result Qualifier RDL Dilution Analysis Batch Analyte mg/kg mg/kg date /time Reactive Sulfide ND 25.0 1 03/17/202122:00 WG1636150 Wet Chemistry by Method 9045D Analyte Corrosivity by pH Result Qualifier Dilution Analysis Batch su date/time 8.34 18 1 03/17/202111:06 WG1635806 Sample Narrative: L1327035-01 WG1635806: 8.34 at 21.8C Wet Chemistry by Method D93/1010A Analyte Ignitability Result Qualifier Dilution Analysis Batch Deg. F date/time DNI at170 1 03/20/202115:00 WG1637776 Mercury by Method 7470A Result Qualifier RDL Limit Dilution Analysis Batch Analyte mg/I mg/I mg/I date / time Mercury ND 0.0100 0.20 1 03/19/2021 09:00 WG1636746 Metals (ICP) by Method 6010D Result Qualifier RDL Limit Dilution Analysis Batch Analyte mg/I mg/I mg/I date / time Arsenic ND 0.100 5 1 03/19/202114:35 WG1637155 Barium ND 0.100 100 1 03/19/202114:35 WG1637155 Cadmium ND 0.100 1 1 03/19/202114:35 WG1637155 Chromium ND 0.100 5 1 03/19/202114:35 WG1637155 Lead ND 0.100 5 1 03/19/202114:35 WG1637155 Selenium ND 0.100 1 1 03/19/202114:35 WG1637155 Silver ND 0.100 5 1 03/19/202114:35 WG1637155 Volatile Organic Compounds (GC/MS) by Method 8260D Result Qualifier RDL Limit Dilution Analysis Batch Analyte mg/I mg/I mg/I date / time Benzene ND 0.0500 0.50 1 03/22/202114:33 WG1638433 Carbon tetrachloride ND 0.0500 0.50 1 03/22/202114:33 WG1638433 Chlorobenzene ND 0.0500 100 1 03/22/202114:33 WG1638433 Chloroform ND 0.250 6 1 03/22/202114:33 WG1638433 Cp 2 Tc SS 4 Cn Sr 6 Qc 7 GI 8 AI 9 Sc ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: EMA Resources L1327035 03/24/2115:48 5 of 20 WASHINGTON SAMPLE RESULTS - 01 Collected date/time: 03/15/21 10:30 L1327035 Volatile Organic Compounds (GC/MS) by Method 8260D Result Qualifier RDL Limit Dilution Analysis Batch Analyte mg/I mg/I mg/I date / time 1,2-Dichloroethane ND 0.0500 0.50 1 03/22/202114:33 WG1638433 1,1-Dichloroethene ND 0.0500 0.70 1 03/22/202114:33 WG1638433 2-Butanone (MEK) ND 0.500 200 1 03/22/202114:33 WG1638433 Tetrachloroethene ND 0.0500 0.70 1 03/22/202114:33 WG1638433 Trichloroethene ND 0.0500 0.50 1 03/22/202114:33 WG1638433 Vinyl chloride ND 0.0500 0.20 1 03/22/202114:33 WG1638433 (S) Toluene-d8 104 80.0-120 03/22/202114.33 WG1638433 (S) 4-Bromofluorobenzene 102 77.0-126 03/22/202114.33 WG1638433 (S) 1,2-Dichloroethane-d4 88.6 70.0-130 03/22/202114.33 WG1638433 Chlorinated Acid Herbicides (GC) by Method 8151A Result Qualifier RDL Limit Dilution Analysis Batch Analyte mg/I mg/I mg/I date / time 2,4,5-TP (Silvex) ND 0.00200 1 1 03/23/202116:53 WG1638364 2,4-D ND 0.00200 10 1 03/23/202116:53 WG1638364 (S) 2,4-Dichlorophenyl Acetic Acid 66.6 14.0-158 03/23/202116:53 WG1638364 Pesticides (GC) by Method 8081B Result Qualifier RDL Limit Dilution Analysis Batch Analyte mg/I mg/I mg/I date / time Chlordane ND 0.00500 0.03 1 03/21/202111:23 WG1637816 Endrin ND 0.00500 0.02 1 03/21/202111:23 WG1637816 Heptachlor ND 0.00500 0.0080 1 03/21/202111:23 WG1637816 Lindane ND 0.00500 0.40 1 03/21/202111:23 WG1637816 Methoxychlor ND 0.00500 10 1 03/21/202111:23 WG1637816 Toxaphene ND 0.0100 0.50 1 03/21/202111:23 WG1637816 (S) Decachlorobiphenyl 91.6 10.0-128 03/21/202111:23 WG1637816 (S) Tetrachloro-m-xylene 96.8 10.0-127 03/21/202111:23 WG1637816 Semi Volatile Organic Compounds (GC/MS) by Method 8270E Result Qualifier RDL Limit Dilution Analysis Batch Analyte mg/I mg/I mg/I date / time 1,4-Dichlorobenzene ND 0.100 7.50 1 03/21/2021 23:02 WG1636160 2,4-Dinitrotoluene ND 0.100 0.13 1 03/21/2021 23:02 WG1636160 Hexachlorobenzene ND 0.100 0.13 1 03/21/2021 23:02 WG1636160 Hexachloro-1,3-butadiene ND 0.100 0.50 1 03/21/2021 23:02 WG1636160 Hexachloroethane ND 0.100 3 1 03/21/2021 23:02 WG1636160 Nitrobenzene ND 0.100 2 1 03/21/2021 23:02 WG1636160 Pyridine ND J4 0.100 5 1 03/21/2021 23:02 WG1636160 3&4-Methyl Phenol 0.492 0.100 400 1 03/21/2021 23:02 WG1636160 2-Methylphenol ND 0.100 200 1 03/21/2021 23:02 WG1636160 Pentachlorophenol ND 0.100 100 1 03/21/2021 23:02 WG1636160 2,4,5-Trichlorophenol ND 0.100 400 1 03/21/2021 23:02 WG1636160 2,4,6-Trichlorophenol ND 0.100 2 1 03/21/2021 23:02 WG1636160 (S) 2-Fluorophenol 94.5 10.0-120 03/21/202123:02 WG1636160 (S) Phenol-d5 76.0 10.0-120 03/21/202123:02 WG1636160 (S) Nitrobenzene-d5 129 J1 10.0-127 03/21/202123:02 WG1636160 (S) 2-Fluorobiphenyl 128 10.0-130 03/21/202123:02 WG1636160 (S)2,4,6-Tribromophenol 140 10.0-155 03/21/202123:02 WG1636160 (S) p-Terphenyl-d14 138 J1 10.0-128 03/21/202123:02 WG1636160 Cp 2 Tc SS 4 Cn 5 Sr 6 Qc GI 8 AI 9 Sc ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: EMA Resources L1327035 03/24/2115:48 6 of 20 WG1637283 QUALITY CONTROL SUMMARY Wet Chemistry by Method 9012 B L1327035-01 Method Blank (MB) (MB) R3632858-1 03/20/21 02:36 MB Result MB Qualifier MB MDL MB RDL Analyte mg/kg mg/kg mg/kg Reactive Cyanide U 0.0390 0.250 L1326768-03 Original Sample (OS) • Duplicate (DUP) (OS) L1326768-03 03/20/21 02:43 • (DUP) R3632858-3 03/20/21 02:44 Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD Limits Analyte mg/kg mg/kg Reactive Cyanide ND ND 1 0.000 20 L1327992-03 Original Sample (OS) • Duplicate (DUP) (OS) L1327992-03 03/20/21 03:15 • (DUP) R3632858-8 03/20/21 03:16 Analyte Reactive Cyanide Original Result DUP Result Dilution DUP RPD DUP Qualifier mg/kg mg/kg ND ND 1 0.000 Laboratory Control Sample (LCS) DUP RPD Limits 20 (LCS) R3632858-2 03/20/21 02:37 Spike Amount LCS Result LCS Rec. Rec. Limits LCS Qualifier Analyte mg/kg mg/kg Reactive Cyanide 2.50 2.57 103 85.0-115 L1326772-02 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD) (OS) L1326772-02 03/20/21 02:49 • (MS) R3632858-4 03/20/21 02:50 • (MSD) R3632858-5 03/20/21 02:51 Spike Amount Original Result MS Result MSD Result MS Rec. MSD Rec. Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits Analyte mg/kg mg/kg mg/kg mg/kg Reactive Cyanide 1.67 ND 0.958 1.30 57.5 77.8 1 75.0-125 J6 J3 30.0 20 L1327214-01 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD) (OS) L1327214-01 03/20/21 02:54 • (MS) R3632858-6 03/20/21 02:55 • (MSD) R3632858-7 03/20/21 02:56 Spike Amount Original Result MS Result MSD Result MS Rec. MSD Rec. Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits Analyte mg/kg mg/kg mg/kg mg/kg Reactive Cyanide 1.67 0.253 0.704 0.748 27.1 29.7 1 75.0-125 J6 J6 5.98 20 ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: EMA Resources L1327035 03/24/2115:48 7 of 20 WG1636150 QUALITY CONTROL SUMMARY Wet Chemistry by Method 9034-9030B L1327035-01 Method Blank (MB) (MB) R3631965-1 03/17/21 22:00 MB Result MB Qualifier MB MDL MB RDL Analyte mg/kg mg/kg mg/kg Reactive Sulfide U 7.63 25.0 L1326531-04 Original Sample (OS) • Duplicate (DUP) (OS) L1326531-04 03/17/21 22:00 • (DUP) R3631965-5 03/17/21 22:00 Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD Limits Analyte mg/kg mg/kg Reactive Sulfide ND ND 1 0.000 20 L1326531-06 Original Sample (OS) • Duplicate (DUP) (OS) L1326531-06 03/17/21 22:00 • (DUP) R3631965-6 03/17/21 22:00 Analyte Reactive Sulfide Original Result DUP Result Dilution DUP RPD DUP Qualifier mg/kg mg/kg ND ND 1 0.000 Laboratory Control Sample (LCS) DUP RPD Limits 20 (LCS) R3631965-2 03/17/21 22:00 Spike Amount LCS Result LCS Rec. Rec. Limits LCS Qualifier Analyte mg/kg mg/kg Reactive Sulfide 100 96.2 96.2 70.0-130 L1326531-02 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD) (OS) L1326531-02 03/17/21 22:00 • (MS) R3631965-3 03/17/21 22:00 • (MSD) R3631965-4 03/17/21 22:00 Spike Amount Original Result MS Result MSD Result MS Rec. MSD Rec. Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits Analyte mg/kg mg/kg mg/kg mg/kg Reactive Sulfide 100 ND 91.9 91.7 91.9 91.7 1 70.0-130 0.209 20 ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: EMA Resources L1327035 03/24/2115:48 8 of 20 WG1635806 QUALITY CONTROL SUMMARY Wet Chemistry by Method 9045D L1327035-01 Laboratory Control Sample (LCS) (LCS) R3631627-1 03/17/2111:06 Spike Amount LCS Result LCS Rec. Rec. Limits LCS Qualifier Analyte su su Corrosivity by pH 10.0 10.1 101 99.0-101 Sample Narrative: LCS:10.07 at20.5C ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: EMA Resources L1327035 03/24/2115:48 9 of 20 WG1637776 QUALITY CONTROL SUMMARY Wet Chemistry by Method D93/1010A L1327035-01 Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD) (LCS) R3632980-1 03/20/21 15:00 • (LCSD) R3632980-2 03/20/2115:00 Spike Amount LCS Result LCSD Result LCS Rec. LCSD Rec. Rec. Limits LCS Qualifier LCSD Qualifier RPD RPD Limits Analyte Deg. F Deg. F Deg. F Ignitability 126 124 126 98.6 100 95.6-104 1.60 10 ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: EMA Resources L1327035 03/24/2115:48 10 of20 WG1636746 QUALITY CONTROL SUMMARY Mercury by Method 7470A L1327035-01 Method Blank (MB) (MB) R3632650-1 03/19/21 08:39 MB Result Analyte mg/I Mercury U MB Qualifier MB MDL MB RDL mg/I mg/I Laboratory Control Sample (LCS) 0.00330 0.0100 (LCS) R3632650-2 03/19/21 08:41 Spike Amount LCS Result LCS Rec. Rec. Limits LCS Qualifier Analyte mg/1 mg/I Mercury 0.0300 0.0306 102 80.0-120 ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: EMA Resources L1327035 03/24/2115:48 11 of 20 WG1637155 QUALITY CONTROL SUMMARY Metals (ICP) by Method 6010D L1327035-01 Method Blank (MB) (MB) R3632807-1 03/19/2114:03 MB Result MB Qualifier MB MDL MB RDL Analyte mg/I mg/I mg/I Arsenic U 0.0333 0.100 Barium U 0.0333 0.100 Cadmium U 0.0333 0.100 Chromium U 0.0333 0.100 Lead U 0.0333 0.100 Selenium U 0.0333 0.100 Silver U 0.0333 0.100 Laboratory Control Sample (LCS) (LCS) R3632807-2 03/19/2114:06 Spike Amount LCS Result LCS Rec. Rec. Limits LCS Qualifier Analyte mg/I mg/I Arsenic 10.0 9.62 96.2 80.0-120 Barium 10.0 9.78 97.8 80.0-120 Cadmium 10.0 9.62 96.2 80.0-120 Chromium 10.0 9.32 93.2 80.0-120 Lead 10.0 9.53 95.3 80.0-120 Selenium 10.0 10.2 102 80.0-120 Silver 2.00 1.90 95.0 80.0-120 ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: EMA Resources L1327035 03/24/2115:48 12 of 20 WG1638433 QUALITY CONTROL SUMMARY Volatile Organic Compounds (GC/MS) by Method 8260D L1327035-01 Method Blank (MB) (MB) R3633608-2 03/22/2113:31 MB Result Analyte mg/I MB Qualifier MB MDL MB RDL mg/I mg/I Benzene U 0.0167 0.0500 Carbon tetrachloride U 0.0167 0.0500 Chlorobenzene U 0.0167 0.0500 Chloroform U 0.0833 0.250 1,2-Dichloroethane U 0.0167 0.0500 1,1-Dichloroethene U 0.0167 0.0500 2-Butanone (MEK) U 0.167 0.500 Tetrachloroethene U 0.0167 0.0500 Trichloroethene U 0.0167 0.0500 Vinyl chloride U 0.0167 0.0500 (S) Toluene-d8 103 80.0-120 (S 4-Bromofluorobenzene 101 770-126 (S 1,2-Dichloroethane-d4 878 70.0-130 Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD) (LCS) R3633608-1 03/22/21 11:54 • (LCSD) R3633608-3 03/22/2113:51 Spike Amount LCS Result LCSD Result LCS Rec. LCSD Rec. Rec. Limits LCS Qualifier LCSD Qualifier RPD RPD Limits Analyte mg/I mg/I mg/I Benzene 0.250 0.279 0.256 112 102 70.0-123 8.60 20 Carbon tetrachloride 0.250 0.290 0.283 116 113 68.0-126 2.44 20 Chlorobenzene 0.250 0.246 0.240 98.4 96.0 80.0-121 2.47 20 Chloroform 0.250 0.275 0.261 110 104 73.0-120 5.22 20 1,2-Dichloroethane 0.250 0.241 0.228 96.4 91.2 70.0-128 5.54 20 1,1-Dichloroethene 0.250 0.307 0.272 123 109 71.0-124 12.1 20 2-Butanone (MEK) 1.25 0.995 0.992 79.6 79.4 44.0-160 0.302 20 Tetrachloroethene 0.250 0.274 0.257 110 103 72.0-132 6.40 20 Trichloroethene 0.250 0.284 0.269 114 108 78.0-124 5.42 20 Vinyl chloride 0.250 0.213 0.194 85.2 77.6 67.0-131 9.34 20 (S) Toluene-d8 99.9 102 80.0-120 (S) 4-Bromofluorobenzene 101 103 77.0-126 (S) 1,2-Dichloroethane-d4 90.0 87.6 70.0-130 ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: EMA Resources L1327035 03/24/2115:48 13 of 20 WG1638364 QUALITY CONTROL SUMMARY Chlorinated Acid Herbicides (GC) by Method 8151A L1327035-01 Method Blank (MB) (MB) R3633798-1 03/23/2113:21 MB Result MB Qualifier MB MDL MB RDL Analyte mg/I mg/I mg/I 2,4-D U 0.000667 0.00200 2,4,5-TP (Silvex) U 0.000667 0.00200 (S) 2,4-Dichlorophenyl Acetic 67.6 14.0-158 Acid Laboratory Control Sample (LCS) (LCS) R3633798-2 03/23/2113:35 Spike Amount LCS Result LCS Rec. Rec. Limits LCS Qualifier Analyte mg/I mg/I 2,4-D 0.0500 0.0402 80.4 50.0-120 2,4,5-TP (Silvex) 0.0500 0.0546 109 50.0-125 (S) 2,4-Dichlorophenyl Acetic 65.6 14.0-158 Acid L1327719-01 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD) (OS) L1327719-01 03/23/21 18:46 • (MS) R3633798-3 03/23/2119:00 • (MSD) R3633798-4 03/23/2119:14 Spike Amount Original Result MS Result MSD Result MS Rec. MSD Rec. Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits Analyte mg/1 mg/1 mg/I mg/I 2,4-D 0.0500 ND 0.0392 0.0395 78.4 79.0 1 50.0-120 0.762 20 2,4,5-TP (Silvex) 0.0500 ND 0.0510 0.0517 102 103 1 50.0-125 1.36 20 (S)2,4-DichlorophenylAcetic 69.8 71.6 14.0-158 Acid ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: EMA Resources L1327035 03/24/2115:48 14 of 20 WG1637816 QUALITY CONTROL SUMMARY Pesticides (GC) by Method 8081B L1327035-01 Method Blank (MB) (MB) R3633117-1 03/21/21 10:54 MB Result MB Qualifier MB MDL MB RDL Analyte mg/I mg/I mg/I Gamma BHC U 0.00167 0.00500 Endrin U 0.00167 0.00500 Heptachlor U 0.00167 0.00500 Methoxychlor U 0.00167 0.00500 Chlordane U 0.00167 0.00500 Toxaphene U 0.00333 0.0100 (S) Decachlorobiphenyl 97.4 10.0-128 (S) Tetrachloro-m-xylene 88.7 10.0-127 Laboratory Control Sample (LCS) (LCS) R3633117-2 03/21/21 11:08 Spike Amount LCS Result LCS Rec. Rec. Limits LCS Qualifier Analyte mg/I mg/I Gamma BHC 0.0100 0.0116 116 55.0-129 Endrin 0.0100 0.0130 130 57.0-134 Heptachlor 0.0100 0.0125 125 27.0-132 Methoxychlor 0.0100 0.0138 138 54.0-155 (S) Decachlorobiphenyl 105 10.0-128 (S) Tetrachloro-m-xylene 95.2 10.0-127 ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: EMA Resources L1327035 03/24/2115:48 15 of20 WG1636160 QUALITY CONTROL SUMMARY Semi Volatile Organic Compounds (GC/MS) by Method 8270E L1327035-01 Method Blank (MB) (MB) R3632717-2 03/19/21 07:04 MB Result Analyte mg/I MB Qualifier MB MDL MB RDL mg/I mg/I 1,4-Dichlorobenzene U 0.0333 0.100 2,4-Dinitrotoluene U 0.0333 0.100 Hexachlorobenzene U 0.0333 0.100 Hexachloro-1,3-butadiene U 0.0333 0.100 Hexachloroethane U 0.0333 0.100 Nitrobenzene U 0.0333 0.100 Pyridine U 0.0333 0.100 2-Methylphenol U 0.0333 0.100 3&4-Methyl Phenol U 0.0333 0.100 Pentachlorophenol U 0.0333 0.100 2,4,5-Trichlorophenol U 0.0333 0.100 2,4,6-Trichlorophenol U 0.0333 0.100 (S) Nitrobenzene-d5 64.5 10.0-127 (S) 2-Fluorobiphenyl 84.1 10.0-130 (S) p-Terphenyl-d14 92.1 10.0-128 (S) Phenol-d5 44.2 10.0-120 (S) 2-Fluorophenol 56.5 10.0-120 (S) 2,4, 6-Tribromophenol 81.0 10.0-155 Laboratory Control Sample (LCS) (LCS) R3632717-1 03/19/21 06:43 Spike Amount LCS Result LCS Rec. Rec. Limits LCS Qualifier Analyte mg/I mg/I 1,4-Dichlorobenzene 0.500 0.349 69.8 18.0-120 2,4-Dinitrotoluene 0.500 0.453 90.6 49.0-124 Hexachlorobenzene 0.500 0.430 86.0 44.0-120 Hexachloro-1,3-butadiene 0.500 0.345 69.0 19.0-120 Hexachloroethane 0.500 0.329 65.8 15.0-120 Nitrobenzene 0.500 0.336 67.2 27.0-120 Pyridine 0.500 0.0271 5.42 10.0-120 J4 2-Methylphenol 0.500 0.356 71.2 28.0-120 3&4-Methyl Phenol 0.500 0.379 75.8 31.0-120 Pentachlorophenol 0.500 0.433 86.6 23.0-120 2,4,5-Trichlorophenol 0.500 0.453 90.6 44.0-120 2,4,6-Trichlorophenol 0.500 0.426 85.2 42.0-120 (S) Nitrobenzene-d5 56.5 10.0-127 (S) 2-Fluorobiphenyl 80.3 10.0-130 (S) p-Terphenyl-d14 85.1 10.0-128 ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: EMA Resources L1327035 03/24/2115:48 16 of 20 WG1636160 QUALITY CONTROL SUMMARY Semi Volatile Organic Compounds (GC/MS) by Method 8270E L1327035-01 Laboratory Control Sample (LCS) (LCS) R3632717-1 03/19/21 06:43 Spike Amount LCS Result LCS Rec. Rec. Limits LCS Qualifier Analyte mg/I mg/I (S) Phenol-d5 44.8 10.0-120 (S) 2-Fluorophenol 56.5 10.0-120 (S) 2,4, 6-Tribromophenol 84.0 10.0-155 L1325656-02 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD) (OS) L1325656-02 03/19/21 08:40 • (MS) R3632717-3 03/19/21 09:01 • (MSD) R3632717-4 03/19/21 09:22 Spike Amount Original Result MS Result MSD Result MS Rec. MSD Rec. Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits Analyte mg/I mg/I mg/I mg/I 1,4-Dichlorobenzene 0.500 ND 0.342 0.331 68.4 66.2 1 17.0-120 3.27 40 2,4-Dinitrotoluene 0.500 ND 0.445 0.448 89.0 89.6 1 39.0-125 0.672 25 Hexachlorobenzene 0.500 ND 0.432 0.497 86.4 99.4 1 35.0-122 14.0 24 Hexachloro-1,3-butadiene 0.500 ND 0.344 0.333 68.8 66.6 1 12.0-120 3.25 34 Hexachloroethane 0.500 ND 0.325 0.313 65.0 62.6 1 10.0-120 3.76 40 Nitrobenzene 0.500 ND 0.345 0.340 69.0 68.0 1 12.0-120 1.46 30 Pyridine 0.500 ND ND ND 6.86 8.42 1 10.0-120 J6 J6 20.4 37 2-Methylphenol 0.500 ND 0.347 0.328 69.4 65.6 1 10.0-120 5.63 30 3&4-Methyl Phenol 0.500 ND 0.357 0.337 71.4 67.4 1 10.0-120 5.76 36 Pentachlorophenol 0.500 ND 0.443 0.484 88.6 96.8 1 10.0-128 8.85 37 2,4,5-Trichlorophenol 0.500 ND 0.443 0.449 88.6 89.8 1 33.0-120 1.35 31 2,4,6-Trichlorophenol 0.500 ND 0.419 0.427 83.8 85.4 1 26.0-120 1.89 31 (S) Nitrobenzene-d5 61.1 57.E 10.0-127 (S) 2-Fluorobiphenyl 81.3 79.3 10.0-130 (S) p-Terphenyl-d14 99.3 79.7 10.0-128 (S) Phenol-d5 43.1 40.0 10.0-120 (S) 2-Fluorophenol 54.5 50.0 10.0-120 (S) 2,4, 6-Tribromophenol 88.0 98.0 10.0-155 ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: EMA Resources L1327035 03/24/2115:48 17 of 20 GLOSSARY OF TERMS Guide to Reading and Understanding Your Laboratory Report The information below is designed to better explain the various terms used in your report of analytical results from the Laboratory. This is not intended as a comprehensive explanation, and if you have additional questions please contact your project representative. Results Disclaimer - Information that may be provided by the customer, and contained within this report, include Permit Limits, Project Name, Sample ID, Sample Matrix, Sample Preservation, Field Blanks, Field Spikes, Field Duplicates, On -Site Data, Sampling Collection Dates/Times, and Sampling Location. Results relate to the accuracy of this information provided, and as the samples are received. Abbreviations and Definitions MDL ND RDL Rec. RPD SDG (S) U Analyte Method Detection Limit. Not detected at the Reporting Limit (or MDL where applicable). Reported Detection Limit. Recovery. Relative Percent Difference. Sample Delivery Group. Surrogate (Surrogate Standard) - Analytes added to every blank, sample, Laboratory Control Sample/Duplicate and Matrix Spike/Duplicate; used to evaluate analytical efficiency by measuring recovery. Surrogates are not expected to be detected in all environmental media. Not detected at the Reporting Limit (or MDL where applicable). The name of the particular compound or analysis performed. Some Analyses and Methods will have multiple analytes reported. Dilution If the sample matrix contains an interfering material, the sample preparation volume or weight values differ from the standard, or if concentrations of analytes in the sample are higher than the highest limit of concentration that the laboratory can accurately report, the sample may be diluted for analysis. If a value different than 1 is used in this field, the result reported has already been corrected for this factor. Limits These are the target % recovery ranges or % difference value that the laboratory has historically determined as normal for the method and analyte being reported. Successful QC Sample analysis will target all analytes recovered or duplicated within these ranges. Original Sample The non -spiked sample in the prep batch used to determine the Relative Percent Difference (RPD) from a quality control sample. The Original Sample may not be included within the reported SDG. Qualifier This column provides a letter and/or number designation that corresponds to additional information concerning the result reported. If a Qualifier is present, a definition per Qualifier is provided within the Glossary and Definitions page and potentially a discussion of possible implications of the Qualifier in the Case Narrative if applicable. Result The actual analytical final result (corrected for any sample specific characteristics) reported for your sample. If there was no measurable result returned for a specific analyte, the result in this column may state "ND" (Not Detected) or "BDL" (Below Detectable Levels). The information in the results column should always be accompanied by either an MDL (Method Detection Limit) or RDL (Reporting Detection Limit) that defines the lowest value that the laboratory could detect or report for this analyte. Uncertainty (Radiochemistry) Confidence level of 2 sigma. Case Narrative (Cn) A brief discussion about the included sample results, including a discussion of any non -conformances to protocol observed either at sample receipt by the laboratory from the field or during the analytical process. If present, there will be a section in the Case Narrative to discuss the meaning of any data qualifiers used in the report. Quality Control Summary (Qc) This section of the report includes the results of the laboratory quality control analyses required by procedure or analytical methods to assist in evaluating the validity of the results reported for your samples. These analyses are not being performed on your samples typically, but on laboratory generated material. Sample Chain of Custody (Sc) This is the document created in the field when your samples were initially collected. This is used to verify the time and date of collection, the person collecting the samples, and the analyses that the laboratory is requested to perform. This chain of custody also documents all persons (excluding commercial shippers) that have had control or possession of the samples from the time of collection until delivery to the laboratory for analysis. Sample Results (Sr) This section of your report will provide the results of all testing performed on your samples. These results are provided by sample ID and are separated by the analyses performed on each sample. The header line of each analysis section for each sample will provide the name and method number for the analysis reported. Sample Summary(Ss) This section of the Analytical Report defines the specific analyses performed for each sample ID, including the dates and times of preparation and/or analysis. Qualifier Description J1 J3 J4 J6 T8 Surrogate recovery limits have been exceeded; values are outside upper control limits. The associated batch QC was outside the established quality control range for precision. The associated batch QC was outside the established quality control range for accuracy. The sample matrix interfered with the ability to make any accurate determination; spike value is low. Sample(s) received past/too close to holding time expiration. Cp 2 Tc SS 4 Cn 5 Sr 6 Qc 7 GI 8 AI 9 SC ACCOUNT: EMA Resources PROJECT: SDG: L1327035 DATE/TIME: 03/24/2115:48 PAGE: 18 of 20 ACCREDITATIONS & LOCATIONS Pace Analytical National 12065 Lebanon Rd Mount Juliet, TN 37122 Alabama 40660 Nebraska NE-OS-15-05 Alaska 17-026 Nevada TN000032021-1 Arizona AZ0612 New Hampshire 2975 Arkansas 88-0469 New Jersey—NELAP TN002 California 2932 New Mexico' TN00003 Colorado TN00003 New York 11742 Connecticut PH-0197 North Carolina Env375 Florida E87487 North Carolina 1 DW21704 Georgia NELAP North Carolina 3 41 Georgia' 923 North Dakota R-140 Idaho TN00003 Ohio—VAP CL0069 Illinois 200008 Oklahoma 9915 Indiana C-TN-01 Oregon TN200002 Iowa 364 Pennsylvania 68-02979 Kansas E-10277 Rhode Island LA000356 Kentucky 6 KY90010 South Carolina 84004002 Kentucky 2 16 South Dakota n/a Louisiana A130792 Tennessee' 4 2006 Louisiana LA018 Texas T104704245-20-18 Maine TN00003 Texas LAB0152 Maryland 324 Utah TN000032021-11 Massachusetts M-TN003 Vermont VT2006 Michigan 9958 Virginia 110033 Minnesota 047-999-395 Washington C847 Mississippi TN00003 West Virginia 233 Missouri 340 Wisconsin 998093910 Montana CERT0086 Wyoming A2LA A2LA — ISO 17025 1461.01 AIHA-LAP,LLC EMLAP 100789 A2LA — ISO 17025 5 1461.02 DOD 1461.01 Canada 1461.01 USDA P330-15-00234 EPA—Crypto TN00003 Drinking Water 2 Underground Storage Tanks 3 Aquatic Toxicity "Chemical/Microbiological 5 Mold 6 Wastewater n/a Accreditation not applicable * Not all certifications held by the laboratory are applicable to the results reported in the attached report. * Accreditation is only applicable to the test methods specified on each scope of accreditation held by Pace Analytical. Cp 2 Tc SS 4 Cn 5 Sr L6QC] GI 9 SC ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: EMA Resources L1327035 03/24/2115:48 19 of 20 Billing Information: T: Analvsis J Container f Pre ervativ :hain of Custody Page_of_ EMA Resources Mr. Brent Collins ores Chk ace Analytical' 755 Yadkinville Road 755 Yadkinville Road Mocksville, NC 27028f ""`°"�'" r° '� ; "°"°" Mocksville,NC 27028 f Report to: Email To:brent.collins@emaresourcesinc.com 12065 Lebanon Rd ❑r t"❑i Mr. Brent Collins , Monntluret,rrr 37t22 Phone:615-755-5858 �ry _4:' Project Description: City/State ss L / Please Circle: Phone:8o0-767-5559 � Sludge Collected: 4 /IAI5 / Fay:615-756-5859 ■iC PT MT CT ET r Phone:336-751-1441 Client Project 4 Lab Project# -1 5DG 4 61 / V 2 �3$ Ti D 148 CoilVed by(print): Site/Facility ID# P.O.# �n 1- a o Acctnum:EMARES Collected by(signature): v7 Z �� Rush? (Lab MUST Be Notified) Quote# ` 1- Template:T11413 Same Day Five Day a Prelogin:P820651 O _Li Nett Day _5 Day(Rad Only) Date Results Needed Z r, PM:B07-Justin Carr Immediately Two Day __10 Day(Rad Only) No. i — Packed on Ice N ` Y Three Daypg. , ofj Cntrs 'i a J Shipped Via:FedEX Ground Sample lD Comp/Grab Matrix* Depth Date Time a L Remarks , Sample a(lab only) _M541... 55 _ f 3/I /2( .-.?k,,,. 2 X X 0 J 1 _ ( —.—..._. _._ I *Matrix: Remarks: - r____, Samnie Receipt Check,) e t. 55 Soil AIR-Air F-Filter pH Temp COC Seal Present/Intact: Y .,..._N GW-Groundwater 8-Bioassay Coc Signed/Accurate: --k N WW-WasteWater Flow Other Bottles arrive intact: /Y NF DIN-Drinking Water Correct bottles used: !? N OT-Other -• .• ' Sampfesteturnedvia: (� Sufficient volume sent: !4 N _UPS _FedEx Courier Tracking# 7 �� } X If Applicable Relinquished by;(Signature) Date, Time: Received by:(Signature) D� U Ica Zero Headspace: Y _ N ( B ] Trip Blank Received: Yes/ o Preservation Correct/Checked: yY• �N RAD Screen <0.5 mR/hr: L` _N y �r T..0prs� HCL off Relin wished b TBR - l q y:(Signature) Date: Time: Received by:(Signature) T.t,.8 �' oc Bottles Received:e7 If preservation required by Login:Date/Time •�+ eo Relinquished by;(Signature) Date: Time: Receive f• ab• :( gnature QR I Dade , Time: Hold: Conditio 10P3 . NCF / �K ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (02T Rules) Facility Name: City of Washington WQ Permit Number: 2021 WWTP Name: Washington WWTP NPDES Number: NC0020648 Monitoring Period: From 3/16/2021 To 3/16/2021 Pathogen Reduction (15A NCAC 02T .1106)- Please indicate level achieved and alternative performed: Class A: Alt. A (time/temp) ❑ Alt B (Alk Treatment)❑ Alt. C (Prior Testing)❑ AIt.D (No Prior Test) ❑ Process to Further Reduce Pathogengs ❑ If applicable to alternative performed(Class A only)indicate"Process to Further Reduce Pathogens": Compost ❑ Heat Drying ❑ Heat Treatment ❑ Thermophilic Beta Ray ❑ Gamma Ray ❑ Pasteurization CI Class B: Alt. (1)Fecal Density p Alt. (2)Process to Significantly Reduce Pathogens ❑ If applicable to alternative performed(Class B only)indicate"Process to Significantly Reduce Pathogens": Lime Stabilization ❑ Air Drying ❑ Composting ❑ Aerobic Digestion ❑ Anaerobic Digestion ❑ If applicable to alternative performed (Class A or Class B) complete the following monitoring data: Allowable Level Pathogen DensityNumber of Parameter gExcee- in Frequency Sample Analytical Sludge Minimum Geo. Mean Maximum Units deuces of Analysis Type Tech-nique 2 x 10 to the MPN 3600 14923 34000 MPN/g 0 Quarterly G SM92210E 6th power per gram of Fecal Coliform total solids CFU 1000 mpn per gram of total solid (dry weight) Salmonella bacteria 3 MPN per 4 grams (in lieu of fecal total solid(thy coliform) weight) Vector Attraction Reduction (15A NCAC 02T.1107) -Please indicate alternative performed: Alt.1 (VS reduction) o Alt. 2 (40-day bench) ❑ Alt. 3 (30-day bench) ❑ Alt. 4 (Spec. 02 uptake) ❑ Alt. 5 (14-Day Aerobic) ❑ Alt. 6 (Alk. Stabilization ❑ Alt 7(Drying-Stable) ❑ Alt. 8 (Drying-Unstable) ❑ Alt. 9 (Injection) ❑ Alt. 10 (Incorporation) ❑ No vector attraction reduction alternatives were performed ❑ CERTIFICATION STATEMENT (please check the appropriate statement) O "I certify,under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the vector attraction reduction requirement in 15A NCAC 02T .1107 have been met." ❑ "I certify,under penalty of law,that the pathogen requirements in 15A NCAC 02T .1106 and the vector attraction reduction requirement in 15A NCAC 02T .1107 have not been met." (Please note if you check this statement attach an explanation why you have not met one or both of the requirements.) "This determination has been made under my direction and supervision in accordance with the system designed to ensure that qualified personnel properly gather and evaluate the information used to determine that the pathogen and vector attraction reduction requirements have been met. I am aware that there are significant penalties for false certification including fine and imprisonment." Hope Woolard-Water Resources Superintendent Brent Collins; Director of Technical Services Preparer Name and Title (type or print) Land Applier Name and Title (if applicable)(type or print) D ��Z hizZa G( Feb 3,2022zit/xi 2/1/2022 Hop J.Woolard(Feb 3,202207:45 EST) Signature of Preparer* Date Signature of Land Applier(if applicable) Date *Preparer is defined in 40 CFR Part 503.9(r)and 15A NCAC 2T .1102 (26) DENR FORM PVRF 02T (12/2006) Summary Sheet Fecal Coliforms Pathogen Reduction Date: 3/16/2021 Location # MPN/g Log 1 34000 4.5315 2 32500 4.5119 3 9000 3.9542 4 27500 4.4393 5 18600 4.2695 6 9000 3.9542 7 3600 3.5563 14923 Geometric Means/g Total Dry Solids Signature 3,4. Temp 357P °C NAME DATE/TIME y,{,(e, °C Sampled By 4.,k,:o_upy„V 3-i(r2t , .3a-} Sample Location y S1udQe # Received By ' ae.i 3-1i,-21 , gs5O 24 hr.Check $It1t11 1019. Sample Type: Grab x Composite Analyzed By c Z � 3(lt•jI 48 hr.Check 3kl!rI yt I%, l9.`S Preservation: NONE _.. Calculated By QQl L % ,312$121 92q 72 hr.Check 31 RI.a1 10`tl Tua Checked By k y ,0 t c ,3 L 5-- (, i LI-4- C_ FECAL COLIFORM TEST Standard Methods 9221 C E-2006(MPN)(Aqueous) 5 a, Presumptive Test o mL Sample 0.001 0.0001 0.00001 0.000001 0.0000001 0.00000001 1115PAI- _ 24 hours r --- 1 r f f t t "i-- 1-, — — ' 1—- — — — — — — 48 hours 1- — L �- _ _ — y-Ct 9) 9 I c Fecal Coliform Test mL Sample 0.001 0.0001 0.00001 0.000001 0.0000001 0.00000001 J.:31UL_ 24 hours -f]�- I — + � + t ` — — — I — _ � I_— . I -I _ I 11 ) MPN Fecal Coliform/g= 10 x MPN index/100 ml MPN/g= 10 x /I' = _ 140 j 3/1 D 00 Mby largest volume X%dry solids tested 0.00/ )C 5 0.0©J 0 Sterility Control Quality Control Tubes 10 mL A Double Strength(DS)Control Single Strength(SS)Control . O- --' EC Broth Control Revised 5-23-16 34.1 Temp 3 °C NAME (�1DATE/TIME y.{,(I, °C Sampled By4411 :: Q`r,/� ,�/ 3-f f : gv�'/ Sample Location Sludge # �� Received By .0 _ ` 3-14-Z1 , %s50 24 hr.Check 311-LIDA I DP Sample Type:Grab x Composite p,3Av Analyzed By _ A l� 1 11000 48 hr.Check 3I llr I ii I L 1-4 Preservation: NONE Calculated By Pallet: '.it,�, 3/25/2/ 130 72 hr.Check 311gta-I Io`{,'i r- fb Checked By 3 a 5,D-I f 14-q-a. FECAL COLIFORM TEST Standard Methods 9221 C E-2006(MPN)(Aqueous) 5 a Presumptive Test 0 mL Sample 0.001 0.0001 0.00001 0.000001 0.0000001 0.00000001 MPN ` 24 hours t 'I` i fi ' I- , ..�-1 r Jr .- , t r_ _I— , _ f t 48 hours — cico ) Fecal Coliform Test • mL Sample 0.001 0.0001 ' i I 0.00001 0.000001 _ 0.0000001 0.00000001 .. ??PN 24 hours -I- — ' 1 t — -- I --- _I — J 1 I _ I I ' I 1 I I `t'5 - MPN Fecal Coliform/g= 10 x MPN index/100 ml MPN/g= 10 x 14,5 = 45 ` ?coo 404 largest volume X%dry solids tested 0.00/X 5 o,OO.5 Sterility Control L Quality Control Tubes 10 mL Double Strength(OS)Control VL4� Single Strength(SS)Control 1�`C-- EC Broth Control Revised 5-23-16 Sampled By Received By Analyzed By Calculated By Checked By NAME 3 DATE / TIME , �5 3-1le-D , :& - 2ii 31a5121 931 PHI Temp 35,0 °C 't•I (e. °C Sample Location Sludge # 24 hr. Check 3I11IZ1 ‘D>1 ?$ Sample Type: Grab x Composite 48 hr. Check 3llrrI t Lozla 3' Preservation: NONE 72 hr. Check 311cLI FECAL COLIFORM TEST Standard Methods 9221 C E-2006(MPN)(Aqueous) Presumutive Test mL Sample 0.001 0.0001 0.00001 0.000001 0.0000001 0.00000001 MPN 24 hours -I— -i A- fi i- — - .I- .t- + a— _ f' 'i '_ — — 1 48 hours — +r- — P- _(D1 14 o Fecal Coliform Test mL Sample 0.001 0.0001 0.000011I 0.000001 0.0000001 0.00000001 VV 24 hours �' I. r -I-f ii II 1 1 l` I 1 1 I _ � J( 'S MPN Fecal Coliform/g = 10 x MPN index / 100 ml largest volume X % dry solids tested Sterility Control Quality Control Tubes 10 mL Double Strength (DS) Control Kire Single Strength (SS) Control �Tr--- EC Broth Control Revised 5-23-16 MPN/g= 10x 13 0 -OO/x /i aoolq = 130 _ 325oo mfAilsv Sampled By Received By Analyzed By Calculated By Checked By NAME 01/ DATE / TIME %5Q 24 hr. Check 31 !1 b-% } vl PAP' M L3111.1.)111D1 48hr. Check 3lC L'Lt j v-S Preservation: NONE 31031 4,32 141F4 72 hr. Check Ict( -f /06D 94-431 Sample Location Sludge # Sample Type: Grab x Composite FECAL COLIFORM TEST Standard Methods 9221 C E-2006(MPN)(Aqueous) Presumptive Test to r7 Temp 35 °C 4�.1P °C mL Sample 0.001 0.0001 0.00001 0.000001 0.0000001 0.00000001 MPN 24 hours '( �' �- �. k- ' 'i t �- - - - - -- ." _ (49p 48 hours 1 t ' _ — — — — — Fecal Coliform Test mL Sample 24 hours 0.001 It1 0.0001 0 00001 0.000001 0.0000001 0.00000001 MPN Fecal Coliform/g = 10 x MPN index / 100 ml largest volume X % dry solids tested Sterility Control Quality Control Tubes 10 mL Double Strength (DS) Control aCroJ Single Strength (SS) Control 'C-' EC Broth Control Revised 5-23-16 MPN/g = 10 x 4.5 O•OOJ� - �N- 4. g0nO /4PAJ/ 0.006 NAME' DATE / TIME Sampled By Q `4ie f / 3- i /r 1[ , �-- Received By `��,, /J� 314.-] 1 , 455'0 Analyzed By pp A 1141 Calculated By it.P,leA; p:312°5121 q33 Checked By -i a� 3-,au"--(, 1 5- 24 hr. Check 31rib t (t -i1 48 hr. Check 3E1grl -t 6 72 hr. Check 311gl D( IDSr fok Sample Location Sludge # if Sample Type: Grab x Composite Preservation: NONE FECAL COLIFORM TEST Standard Methods 9221 C E-2006(MPN)(Aqueous) 5 3 Presumptive Test b 3'� •� Temp 35 °C y+f.� °C mL Sample 0.001 0.0001 0.00001 0.000001 0.0000001 0.00000001 MPN 24 hours fi t -i— i— `t-' i— 'r .i— I— -- ^ 4— t _ �� 1 rtqC) 48 hours I + I L 3 Fecal Coliform Test mL Sample 0.001 0.0001 0.00001 0.000001 0.0000001 0.00000001 24hours t —I--1 t-I— `1"—I— —I—I -- I _ 1 - I_._ 1 _ ii �, MPN Fecal Coliform/g = 10 x MPN index / 100 ml largest volume X % dry solids tested Sterility Control Quality Control Tubes 10 mL Double Strength (DS) Control Single Strength (SS) Control tksloture EC Broth Control Revised 5-23-16 MPN/g = 10 x it Door ?<�/ = _ #21500 /4 /Vs, © oo Sampled By Received By Analyzed By Calculated By Checked By NAME DATE / TIME 01i 3-i..u, 6'10 $s5O 24 hr. Check 3Ints1 fit; 1 ‘4?11 5 Sample Type: Grab x Composite p,�shr 7 it. ,) & 48 hr. Check 3l Isr 1 -t I i w' Preservation: NONE 3/z / i 93ti 72 hr. Check a{ Icfia f2u43 3-?s--21 , 1G Sample Location S1udEe # 5 FECAL COLIFORM TEST Standard Methods 9221 C E-2006(MPN)(Aqueous) Presumptive Test e7? Temp 35 0O °C 't+f°C mL Sample 0.001 0.0001 0.00001 0.000001 0.0000001 0.00000001 MPN 24 hours 1-. I-- 1- 41 — fi '1"-'.i- 1.--i` t — e — , — - - r+ 1. iqo _ 48 hours t , .r -�- — — r d , ( 0 Fecal Coliform Test mL Sample • 0.0001 0.00001 0.000001 0.0000001 0.00000001 M 24 hours i0.001 .— t 1— —, i- t 1- -] t I_- I - 1 1 I _ 1 I C- qz MPN Fecal Coliform/g = 10 x MPN index / 100 ml largest volume X % dry solids tested Sterility Control Quality Control Tubes 10 mL Double Strength (DS) Control KR0 wI Single Strength (SS) Control vJ7C., EC Broth Control Revised 5-23-16 MPN/g = 10 x 7.3 = 93 i4l� no /441/, O . cos Sampled By Received By Analyzed By Calculated By Checked By NAME DATE / TIME 3-) —J_1 $s5O 24 hr. Check 311�1111) sh 3 f25/21 93(P 3 a5a�{ )tf�F-f 48 hr. Check 31r1sL i 72 hr. Check 3i1g1� 1t53r.X3 Sample Location Sludge # ' Sample Type: Grab x Composite Preservation: NONE FECAL COLIFORM TEST Standard Methods 9221 C E-2006(MPN)(Aqueous) c> Presumptive Test Temp 33 5 00 °C 9.4, °C mL Sample 0.0001 0.00001 0.000001 0.0000001 0.00000001 MPN 24 hours f .' + -k' •— •— -- -- r ^ --' r O O 48 hours --- r- ., , .-- r a Fecal Coliform Test mL Sample 0.001 0.0001 0.00001 0.000001 0.0000001 0.00000001 IVIPN� 24 hours i- f '— --" -1" - � -- � 1 I _ � � I l ( '�: MPN Fecal Coliform/g = 10 x MPN index / 100 ml largest volume X % dry solids tested Sterility Control Quality Control Tubes 10 mL Double Strength (DS) Control VRLyna1e }JL_QT� Single Strength (SS) Control EC Broth Control Revised 5-23-16 MPN/g = 10 x 4.5 000/x5 goo° N/14 0•006 NAME Sampled By Received By Analyzed By Calculated By Checked By DATE / TIME 3- , %5-O 24 hr. 311t bI 05048 hr. 3J.Z,_5/21 Q31- 72 hr. 3-a5al, Check 311.1111 Cs l Sample Location S1udEe # Temp 33 5 O0 °C 7 Sample Type: Grab x Composite Check at lrr l -t . ) P Preservation: NONE Check 3i 1q1 a( JD53 FECAL COLIFORM TEST Standard Methods 9221 C E-2006(MPN)(Aqueous) Presumptive Test mL Sample 0.001 0.0001 0.00001 0.000001 0.0000001 0.00000001 MPN 24 hours CR 10 — 48 hours j' 1 r r .- - r Fecal Coliform Test mL Sample 0.001 0.0001 0.00001 0.000001 0.0000001 r 0.00000001 24 hours _ —T - I I 1 I 1 I I I_1 I I .4._1 ^ s MPN Fecal Coliform/g = 10 x MPN index / 100 ml largest volume X % dry solids tested Sterility Control Quality Control Tubes 10 mL Double Strength (DS) Control VRQff-kIe Single Strength (SS) Control yak L EC Broth Control Revised 5-23-16 MPN/g = 10 x / • c� O•00/ )C5 = 1' 36 OO l 0. 005 C� ' Sampled By Received By Analyzed By Calculated By Checked By CITY OF IA/. _..›HINGTON SLUDGE Standard Methods 2540 G-2011(Aqueous) Name Date/Time Q 2/fO,,(,�/ 2-1 c,-a-t $ A/ 25-o 1 0-4Labz, /.L•k.J-1 / 3 ►5 I lit 4 Time on water bath Time in oven Time out of oven Time weighed 1st 2nd 1L''1 (4;'1 q5-7 /IOC q Sample # I Evaporating Dish # 5 Sample # 1 CL - Evaporating Dish # l P el 7 ` IF . —, Wet Weight + Dish Weight 131 0 0 2 . T Wet Weight + Dish Weight Dish Weight 4' c Ce i G , Dish Weight 6 7 % a O . 3 Wet Weight 5 O 1 4 S. Li Wet Weight if q 9 O).. I 1st Dry Weight + Dish Weight .- D g g 1st Dry Weight + Dish Weight -7k D a , Q 2nd Dry Weight + Dish Weight q, 9 co s Q , 2nd Dry Weight + Dish Weight (;,3 Difference in 1st & 2nd Dry Weight + Dish We ht (2nd - 1st) ©, ^ Difference in 1st & 2nd Dry Weight + Dish Weight (2nd - 1st) Dry Weight (2nd Dry Weight + Dish Weight - Dish Weight) a i4- I a, Dry Weight (2nd Dry Weight + Dish Weight - Dish Weight) a 5 % % % Dry Solids ((Dry Weight / Wet Weight) x 100) q LA $ a a = Zj /_, % Dry Solids ((Dry Weight / Wet Weight) x 100) 55 • I D -1 = 5), *Note -Differences should agree within 4% or 0.5 mg, which ever is Tess Revised 9/26/19 JDW Sampled By Received By Analyzed By Calculated By Checked By Name CITY OF W ASHINGTON SLUDGE Standard Methods 2540 G-2011(Aqueous) Date/Time ?3( foD5- 3-rs a� iLE3-T 1st 2nd Time on water bath Time in oven Time out of oven Time weighed t33� q51 /436 l t oO Sample # 610,4(-- Evaporating Dish # 1 1 Sample # Evaporating Dish # Wet Weight + Dish Weight Wet Weight + Dish Weight / 1 q (Q 36, Dish Weight a. 5- 3, Dish Weight Ce q 4, 9' 7. f Wet Weight Wet Weight ii" 9 9' [ , 1st Dry Weight + Dish Weight (1.--4. a 5 Al- 0 1st Dry Weight + Dish Weight , 1 O 4 2nd Dry Weight + Dish Weight S. - 5 It, 0 2nd Dry Weight + Dish Weight 7 j % D 4 , 3 Difference in 1st & 2nd Dry Weight + Dish Weight (2nd - 1st) i✓ , 0 Difference in 1st & 2nd Dry Weight + Dish Weight (2nd - 1st) 0 . I I Dry Weight (2nd Dry Weight + Dish Weight - Dish Weight) O , Dry Weight (2nd Dry Weight + Dish Weight - Dish Weight) a)062,9 J ' % Dry Solids ((Dry Weight l Wet Weight) x 100) % Dry Solids ((Dry Weight l Wet Weight) x 100) a, 4.(;'a 1 2 4' % *Note -Differences should agree within 4% or 0.5 mg, which ever is less Revised 9/26/19 JDW Name Sampled By Received By Analyzed By Calculated By Checked By CITY OF Vv...3HINGTON SLUDGE Standard Methods 2540 G-2011(Aqueous) Date/Time 0, 2/14/ , .D Gt�u , 3-11,-.2l f 5Q 3 l a-t / I."23� 0 1 / 3-) 14 "19 1 -(Jf Time on water bath rime in oven Time out of oven Time weighe 1st d 2nd ,Qs-; (24;) 7'tl4 (41A 4s7 , g' /tQJ 6/53 Sample # 1 3 Evaporating Dish # 4 Sample # Evaporating Dish # Wet Weight + Dish Weight Wet Weight + Dish Weight j ] rj ) L 9 , 2. Dish Weight 9 15 , S Dish Weight Wet Weight 4f 9 9 9 te, 7 Wet Weight 1st Dry Weight + Dish Weight Ilo(..7 a - a' 1st Dry Weight + Dish Weight 2nd Dry Weight + Dish Weight 7 t (p (F 4, % 2nd Dry Weight + Dish Weight Difference in 1st & 2nd Dry Weight + Dish Weight (2nd - 1st) O , 4 Difference in 1st & 2nd Dry Weight + Dish Weight (2nd - 1st) _ Dry Weight (2nd Dry Weight + Dish Weight - Dish Weight) AS i a . 3 Dry Weight (2nd Dry Weight + Dish Weight - Dish Weight) % Dry Solids ((Dry Weight / Wet Weight) x 100) c� 5 park = 5/0 % Dry Solids ((Dry Weight / Wet Weight) x 100) *Note -Differences should agree within 4% or 0.5 mg, which ever is Tess Revised 9/26/19 JDW Name Sampled By Received By Analyzed By Calculated By Checked By CITY OF Vb....HINGTON SLUDGE Standard Methods 2540 G-2011(Aqueous) DatelTime O U% 4/ J- h -2-I , •3 3 s 3 -t�-� I 2 so .n 3-)1 /zact fi , 3-1 g YI r 5- - ;Z/ =142 Time on water bath Time in oven Time out of oven Time weigh 1st ed 2nd . ia37 -s ( i7) 7-A1 - ( _ 9s? q 44, 1.101 (IS3 Sample # Evaporating Dish # I Cr' Sample # Evaporating Dish # Wet Weight + Dish Weight 1 2 a_ cp 1 ' 3 Wet Weight + Dish Weight Dish Weight 3 o.. , 3 Dish Weight Wet Weight 1 �P ci 3 . , 0 _ Wet Weight 1st Dry Weight + Dish Weight .� 1st Dry Weight + Dish Weight 2nd Dry Weight + Dish Weight ¥ 4- 5 1- I. i 2nd Dry Weight + Dish Weight Difference in 1st & 2nd Dry Weight + Dish Weight (2nd - 1st) (' , 4 Difference in 1st & 2nd Dry Weight + Dish Weight (2nd - 1st) Dry Weight (2nd Dry Weight + Dish Weight - Dish Weight) 4 3 3 Dry Weight (2nd Dry Weight + Dish Weight - Dish Weight) % Dry Solids ((Dry Weight! Wet Weight) x 100) � q 1-1 a (4 cl.. = —T /,:a % Dry Solids ((Dry Weight / Wet Weight) x 100) *Note -Differences should agree within 4% or 0.5 mg, which ever is less Revised 9/26/19 JDW Sampled By Received By Analyzed By Calculated By Checked By Name CITY OF VIA..HINGTON SLUDGE Standard Methods 2540 G-2011(Aqueous) Date/Time Q `li/t{04/, 240 3 ?- I { $56 r Time on water bath Time in oven Time out of oven Time weigh 1st 2nd Eqa714 ra cj 1sa Sample # 5 Evaporating Dish # 3 L 1 Sample # y Evaporating Dish # Wet Weight + Dish Weight / a ? / z • 3 Wet Weight + Dish Weight Dish Weight 1' 0 a (e . j Dish Weight Wet Weight Lfq q 2'4, - ?../ Wet Weight 1st Dry Weight + Dish Weight 4-4 1st Dry Weight + Dish Weight 2nd Dry Weight + Dish Weight dip 3 1+ S , Q 2nd Dry Weight + Dish Weight Difference in 1st & 2nd Dry Weight + Dish Weight (2nd - 1st) 0 • Difference in 1st & 2nd Dry Weight + Dish Weight (2nd - 1st) Dry Weight (2nd Dry Weight + Dish Weight - Dish Weight) a 3 l % ,9 -t Dry Weight (2nd Dry Weight + Dish Weight - Dish Weight) % Dry Solids ((Dry Weight / Wet Weight) x 100) 4-, ' q = 5 ga % Dry Solids ((Dry Weight / Wet Weight) x 100) *Note -Differences should agree within 4% or 0.5 mg, which ever is less Revised 9/26/19 JDW Name Sampled By Received By Analyzed By Calculated By Checked By CITY OF W.:3HINGTON SLUDGE Standard Methods 2540 G-2011(Aqueous) Date/Time 2" ito-a_1 1 3 3, 856 3-tS-al, /448 ? Iy' 2/. 445 Time on water bath Time in oven Time out of oven Time weigh 1st 2nd /..- 8' s5s (4/►1-', 1 i Vi8 Q5? g 1►a:2_ 95? Sample # Evaporating Dish # 3 Sample # Evaporating Dish # Wet Weight + Dish Weight /'A i O q p , 7 Wet Weight + Dish Weight Dish Weight 7 S 0 7 5; if Dish Weight Wet Weight 5— 0 0 / !---7" Wet Weight lst Dry Weight + Dish Weight® 1st Dry Weight + Dish Weight 2nd Dry Weight + Dish Weight q 0 4-0 4 , 4 2nd Dry Weight + Dish Weight Difference in 1st & 2nd Dry Weight + Dish Weight (2nd - 1st) 0.3 Difference in 1st & 2nd Dry Weight + Dish Weight (2nd - 1st) Dry Weight (2nd Dry Weight + Dish Weight - Dish Weight) a 4:' 3 I ,1 Dry Weight (2nd Dry Weight + Dish Weight - Dish Weight) % Dry Solids ((Dry Weight / Wet Weight) x 100) 5, 2-4 i 5 % Dry Solids ((Dry Weight / Wet Weight) x 100) *Note -Differences should agree within 4% or 0.5 mg, which ever is less Revised 9/26/19 JDW Sampled By Received By Analyzed By Calculated By Checked By Name CITY OF W1/..SHINGTON SLUDGE Standard Methods 2540 G-2011(Aqueous) Date/Time 3-/g-.11 / /45/ 70/ Time on water bath g 3 1st Time in oven ta{3j} Time out of oven 1 3`3 Time weighed 14+4 2nd 1i1� ►31c1 Sample # j 7 Evaporating Dish # Op Sample # f, l ctvt)- Evaporating Dish # ID Wet Weight + Dish Weight j i 1 9 Q 51, 1' Wet Weight + Dish Weight Dish Weight g a' 3 Dish Weight 2.0 Z 5 k. Wet Weight 4f q of r q Wet Weight lst Dry Weight + Dish Weight _ ]�f 1st Dry Weight + Dish Weight Sv 25 *. - 2nd Dry Weight + Dish Weight 7 1 5 % (p , 4- 2nd Dry Weight + Dish Weight 25 0 5 4~, 3 Difference in 1st & 2nd Dry Weight + Dish Weight (2nd - 1st) 0 . 0 Difference in 1st & 2nd Dry Weight + Dish Weight (2nd - 1st) 0 , Dry Weight (2nd Dry Weight + Dish Weight - Dish Weight) a 5 1 Lf I Dry Weight (2nd Dry Weight + Dish Weight - Dish Weight) I ok Dry Solids ((Dry Weight / Wet Weight) x 100) 5, p D--Cl c S-'p % Dry Solids ((Dry Weight / Wet Weight) x 100) *Note -Differences should agree within 4% or 0.5 mg, which ever is less Revised 9/26/19 JDW ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (02T Rules) Facility Name: WWTP Name: City of Washington Washington WWTP Monitoring Period: From 4/12/2021 To WQ Permit Number: NPDES Number: 4/12/2021 2021 NC0020648 Pathogen Reduction (15A NCAC 02T .1106) - Please indicate level achieved and alternative performed: Class A: Alt. A (time/temp) • Alt B (Alk Treatment) ■ Alt. C (Prior Testing)❑ AIt.D (No Prior Test) • Process to Further Reduce Pathogengs ■ If applicable to alternative performed (Class A only) indicate "Process to Further Reduce Pathogens": Compost ■ Heat Drying • Heat Treatment ■ Thermophilic r-R Beta Ray • Gamma Ray • Pasteurization • Class B: Alt. (1) Fecal Density Alt. (2) Process to Significantly Reduce Pathogens I o • If applicable to alternative performed (Class B only) indicate "Process to Significantly Reduce Pathogens": Lime Stabilization • Air Drying • Composting • Aerobic Digestion • Anaerobic Digestion • If applicable to alternative performed (Class A or Class B) complete the following monitoring data: Parameter Allowable Level in Sludge Pathogen Density g Number of Excee- dences Frequency of Analysis Sample Type Analytical Tech-nique Minimum Geo. Mean Maximum Units Fecal Coliform 2 x 10 to the 6th power per gram of total solids MPN 3600 5485 9000 MPN/g 0 Quarterly G SM92210E CFU 1000 mpn per gram of total solid (dry weight) Salmonella bacteria (in lieu of fecal coliform) 3 MPN per 4 grams total solid (dry weight) Vector Attraction Reduction (15A NCAC 02T .1107) - Please indicate alternative performed: Alt. 1 (VS reduction) n Alt. 2 (40-day bench) • Alt. 3 (30-day bench) • Alt. 4 (Spec. 02 uptake) • Alt. 5 (14-Day Aerobic) • Alt. 6 (Alk. Stabilization • Alt 7 (Drying - Stable) • Alt. 8 (Drying - Unstable) • Alt. 9 (Injection) • Alt. 10 (Incorporation) • No vector attraction reduction alternatives were performed • CERTIFICATION STATEMENT (please check the appropriate statement) O "I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the vector attraction reduction requirement in 15A NCAC 02T .1107 have been met." • "I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the vector attraction reduction requirement in 15A NCAC 02T .1107 have not been met." (Please note if you check this statement attach an explanation why you have not met one or both of the requirements.) "This determination has been made under my direction and supervision in accordance with the system designed to ensure that qualified personnel properly gather and evaluate the information used to determine that the pathogen and vector attraction reduction requirements have been met. I am aware that there are significant penalties for false certification including fine and imprisonment." Hope Woolard - Water Resources Superintendent Brent Collins; Director of Technical Services Preparer Name and Title (type or print) /De c7 hizZa G( Feb 3, 2022 Ho p4 J. Nicolard (Feb 3, 2022 07:45 EST) Land Applier Name and Title (if applicable)(type or print) Signature of Preparer* Date Signature of Land Applier (if applicable) *Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26) 2/1/2022 Date DENR FORM PVRF 02T (12/2006) Date: 4/12/2021 Location # 1 2 3 4 5 6 7 Summary Sheet Fecal Coliforms Pathogen Reduction MPN/g Log 8000 3.9031 9000 3.9542 4000 3.6021 8000 3.9031 4500 3.6532 4000 3.6021 3600 3.5563 5485 Geometric Means/g Total Dry Solids Signature NA E DATE / TIME Sampled By 3 aq-�� 51 Sample Location Sludge # 1 � Temp 35•a °C 1,* °C Received By 3-a1:10.l 4 917 24 hr. Check .3l301L\ iq 9 ? Sample Type: Grab x Composite Analyzed By (,� 32°r- z4, 953 48 hr. Check �13►]�l i 0y0,?' Preservation: NONE Cx leck Calculated By ` , ✓ ]i�fi�Qi �. Ji- 5 2, 61 72 hr. Check l a 1 Checked By , _Q .d-e_ L/ r, 2 FECAL COLIFORM TEST Standard Methods 9221 C E-2006(MPN)(Aqueous) 0 Presumptive Test o mL Sample' 0.001 0.0001 0.00001 0.000001 0.0000001 0.00000001 MPN 24 hours 4 ¥ -i- -1-- i- k i— l" -- ►- .- -' — — -- —_ — — - - Fecal Coliform Test +1.D mL Sample 0.001 0.0001 0.00001 0.000001 0.0000001 0.00000001 -- MPN 24 hours - - - 1 ,.. + = ! , — [... , ., .� 1 � � r 1 1 .. 1 z' q MPN Fecal Coliform/g = 10 x MPN index / 100 ml largest volume X % dry solids tested Sterility Control Quality Control Tubes Double Strength (DS) Control Single Strength (SS) Control EC Broth Control Revised 5-23-16 10 mL MPN/g = 10 x h.0 o•oo/x 5 (5 0 OD gpiti NA E DATE / TIME Sampled By aq-fit 1 Received By Analyzed By Calculated By Checked By mL Sample 24 hours 48 hours mL Sample 24 hours _ 3- ci al l'17 c 55c P :7). i5-2/,98 � 0 4-(0 1 , rs24 lA. 0.001 3 0.001 fi 3 0.0001 1- 3 Temp 35.c) °C + lGv °C Sample Location S1udee # L CLip 24 hr. Check 313c\a► Iet5'`Pd3 Sample Type: Grab x Composite 04 48 hr. Check 313►1 .1 1110TO Preservation: Cookc\ 72 hr. Check 'y1 1 lolrt5,94122 FECAL COLIFORM TEST Standard Methods 9221 C E-2006(MPN)(Aqueous) v Presumptive Test 1 VON 0 0.0001 MPN Fecal Coliform/g = 10 x MPN index / 100 ml largest volume X % dry solids tested Sterility Control 0.00001 0.000001 Fecal Coliform Test 0.00001 1 Quality Control Tubes 10 mL Double Strength (DS) Control Ni c2 tu.1e, _, Single Strength (SS) Control 1\-1-b rrttA) P EC Broth Control d IM—Ose.,1Q}e, Revised 5-23-16 -r 0.000001 MPN/g = 10 x' •`` O, 00/A . tkP. 0.0000001 0.0000001 0, ooli 0.00000001 0.00000001 IVD MPN Ito 19500 kouls NA E DATE/TIME Sampled By 1�`"3 a4-a i i F Tr Received By 3- .q a 1 i c/i7 24 hr. Check 3 l 30‘.1.1 19 Sq, 05 Analyzed By ..2c 4/)013 48 hr. Check 3�3►j j 1110S. Calculated By �i2�Jv4 7d k- 1) q3 f 72 hr. Check 4 l i r. Ly 1 D n P Checked By 0 ` -6, --)-1. 11 S 2'.) 5 Temp 35•1) °C °C Sample Location Sludge # Sample Type: Grab x Composite iu 0 3 (Da tcH , Preservation: NONE Cq� I��1 `% C. FECAL COLIFORM TEST Standard Methods 9221 C E-2006(MPN)(Aqueous) 3 Presumptive Test mL Sample 0.001 0.0001 0.00001 0.000001 0.0000001 0.00000001 ' MPN 24 hours T 1---1— .1.- 1-- — ‘-- -- - - - — — ._ — 'jqo 48 hours r. 't' t — - 1 v. t - - , a 0 Fecal Coliform Test mL Sample 0.001 0.0001 0.00001 0.000001 0.0000001 0.00000001 MPN 24 hours _I -I� 1 MPN Fecal Coliform/g = 10 x MPN index / 100 ml largest volume X % dry solids tested Sterility Control Quality Control Tubes 10 mL Double Strength (DS) Control 113-:'Gu.►e.. Single Strength (SS) Control W.A. cyctikr ti EC Broth Control Te,_ J Revised 5-23-16 Li MPN/g= 10x'�� ®.d©/ X5 _6, od c gOOO yf10/k Sampled By Received By Analyzed By Calculated By Checked By NAME 5 DATE / TIME `13 aq-ai , clot 1013 k-6zV 933 i{-►4-.2.1 2 a3 24 hr. Check 3130:W ,q61,f1-15 hr. Check 313► l y 11W 72 hr. Check 41 ►I).1 ' 10300 Sample Location Temp3 °C Le °C Sludge # 3 Sample Type: Grab x Composite s..A 3pala Preservation: NONE f lc 1v`4` C. FECAL COLIFORM TEST Standard Methods 9221 C E-2006(MPN)(Aqueous) a . Presumptive Test mL Sample 0.001 0.0001 0.00001 0.000001 0.0000001 0.00000001 MPN 24 hours f- I fi- t- — }- -- — — r .r; . 1 48 hours •0 _ _ 1- k. r - �' =1 — _ - v v Fecal Coliform Test .0 mL Sample 0.001 0.0001 0.00001 0.000001 0.0000001 0.00000001 MPN 24 hours .— AI -- J — 1 — I �, �. o,- 1 I 1 1 ; " .0 ` MPN Fecal Coliform/g = 10 x MPN index / 100 ml largest volume X % dry solids tested Sterility Control .-- Quality Control Tubes 10 mL Double Strength (DS) Control 1 NtQ ir re , Single Strength (SS) Control y� EC Broth Control it, Revised 5-23-16 MPN/g = 10 x 2 V _ 020 oat 2c 5 0.095 k00 0 m P?cl/s Sampled By Received By Analyzed By Calculated By Checked By NAME / DATE / TIME 3 aq-J-1 010'4 fay 7,i. _b' 01 dt 4-/s-21, 8.q-0 5 3 24 hr. Check 31342.1 4100,P 48 hr. Check 3131W ,11 DS." 72 hr. Check 'y‘ 4 L% ION Sample Location Sludge # 4 Sample Type: Grab x Composite Preservation: -NONE wokc-o-k FECAL COLIFORM TEST Standard Methods 9221 C E-2006(MPN)(Aqueous) 0 Presumptive Test o 3 Temp 35'° °C 4*LQ °C mL Sample 0.001 0.0001 0.00001 0.000001 0.0000001 0.00000001 MPN I 24 hours 4- 4- ¢-t- t 1- - t . - - - - - - -- - - - 11 48 hours , t- — — — — — — — — - mL Sample 24 hours 0.001 -i-- 1 3i3� r I MPN Fecal Coliform/g = 10 x MPN index / 100 ml largest volume X % dry solids tested Sterility Control z Fecal Coliform Test 0.00001 Quality Control Tubes 10 mL Double Strength (DS) Control j_Q.sy"tl`!e Single Strength (SS) Control Ik•-k EC Broth Control Revised 5-23-16 0.000001 0.0000001 0.00000001 MPN MPN/g = 10 x G At ® _ ° = 1,22Q ©f t IAJ o•dot 5 0, oc�� p 8000 Plyd`� < Sampled By Received By Analyzed By Calculated By Checked By NA cp E r DATE / TIME 7`'3a4-a-t, 90? CO 3z01-,2-I, 1€ .9 5 / 2/,91i1 Lt--ref 21 I S a' 24 hr. Check 313o\\.►,?oil,9b 48 hr. Check 313►\.1 I y 05 72 hr. Check 'yl ►L?-► 1p5 Temp 35•° °C Sample Location Sludge # S Sample Type: Grab x Composite TA304% Preservation: NONE? COc)ltctkOiC, FECAL COLIFORM TEST Standard Methods 9221 C E-2006(MPN)(Aqueous) Presumptive Test b u mL Sample 0.001 0.0001 0.00001 0.000001 0.0000001 0.00000001 MPN 24 hours k- — r :l' - - TA- + — _ — LG 1 i 48 hours .1--— — r — — 0 J Fecal Coliform Test <j•$ mL Sample 0.001 0.0001 0.00001 0.000001 0.0000001 0.00000001 ,..MPN- 24 hours — •r- I — — — � I I _ 1 1 41 SS MPN Fecal Coliform/g = 10 x MPN index / 100 ml largest volume X % dry solids tested Sterility Control Quality Control Tubes 10 mL Double Strength (DS) Control Q 4)..L. e Single Strength (SS) Control KA, 0.y.,Ctuut Vt.UV_LiTf•-• EC Broth Control Revised 5-23-16 MPN/g = 10 x g 0. OO / if fMD u15/21 = l� ` 45oo kiJV/ Sampled By Received By Analyzed By Calculated By Checked By E r DATE / TIME `'3a,'109 3rz°[-a I O`iS k-�al,9'iz 24 hr. Check 3130 1pt"113 48 hr. Check 3)S49.1 t1110 72 hr. Check 4 ! l a l r 10'da Sample Location SludEe # 3 Temp 35•D °C ,,i,,I; (v °C Sample Type: Grab x Composite Preservation: -NONE' c .C- F FECAL COLIFORM TEST Standard Methods 9221 C E-2006(MPN)(Aqueous) Presumptive Test mL Sample 0.001 0.0001 0.00001 0.000001 0.0000001 0.00000001 MPN 24 hours k- —� .- _ ._ 5 48 hours — — — _ r �- .- _ _ .- •— — .— — — { 0 0 Fecal Coliform Test mL Sample 0.001r 0.0001 0.00001 0.000001 0.0000001 0.00000001: 24 hours I 1 rr ff 1 _I1 I I 1,,,,MPN-.\ -0 MPN Fecal Coliform/g = 10 x MPN index / 100 ml largest volume X % dry solids tested Sterility Control Quality Control Tubes 10 mL Double Strength (DS) Control _ }'\ts FIA.t re, Single Strength (SS) Control 0 A EC Broth Control Revised 5-23-16 MPN/g= 10x .A9.0 o ,,00 / is 5 _ z k000 ilti14 0.005 Sampled By Received By Analyzed By Calculated By Checked By NA a E DATE / TIME 7`13aa_ii, c "zraRca! °ll` 3 2Pt-a-r, INS ? -Sa , 4k3 24 hr. Check 3130 1, Iot1�P 48 hr. Check 313Aa.1 CS44, 72 hr. Check 41'1 -► Sample Location Sludge # l Sample Type: Grab x Composite {•3,T0a14t Preservation: NONE' FECAL COLIFORM TEST Standard Methods 9221 C E-2006(MPN)(Aqueous) 0 Presumptive Test Temp 35•1" °C 44 Le °C mL Sample 0.001 il 0.0001 0.00001 0.000001 0.0000001 0.00000001 24 hours _ - - - .- - - -- �- �- .- r ` rt_1, CS 48 hours -- - - - - - 1 - _ - mL Sample 24 hours 0.001 0.0001 MPN Fecal Coliform/g = 10 x MPN index / 100 ml largest volume X % dry solids tested Sterility Control Fecal Coliform Test 0.00001 Quality Control Tubes 10 mL Double Strength (DS) Control t tJjt . Single Strength (SS) Control r� �� re - EC Broth Control Revised 5-23-16 0.000001 MPN/g = 10 x i • g 0 000c 5 0.0000001 l 0.00000001 = -67,000 = 3600 lmN Sampled By Received By Analyzed By Calculated By Checked By CITY OF V., .SHINGTON SLUDGE Standard Methods 2540 G-2011(Aqueous) Name Date/Time is5-65-G-DaliD 3 al , - 9 5 3-30 - /30 3-,3/2/, ,,04 Time on water bath Time in oven Time out of oven Time weigh 1st 2nd 957 k1. -t7-q-$ 1000 .f-? -7 S4 5 r/03 9e 1D--04 JUw 3/30a-1 Sample # 1 Evaporating Dish # Sample # i Evaporating Dish # 5 5 Wet Weight + Dish Weight 11 j 6, 5 1, (P Wet Weight + Dish Weight / / Cf (r 9 , Dish Weight (v 5 Co , I Dish Weight (v 9 (9L l , Co Wet Weight i(- q Q/ S- $ . 7 Wet Weight `j ©C) 2- $ .1 1st Dry Weight + Dish Weight 1st Dry Weight + Dish Weight / / , 2nd Dry Weight + Dish Weight 3 / QJ 5 0 . 7 2nd Dry Weight + Dish Weight f( g / � ,--1- Difference in 1st & 2nd Dry Weight + Dish Weight (2nd - 1st) Q , di-. Difference in 1st & 2nd Dry Weight + Dish Weight (2nd - 1st) D • 0 Dry Weight (2nd Dry Weight + Dish Weight - Dish Weight) 2 a - i Dry Weight (2nd Dry Weight + Dish Weight - Dish Weight) 2 D 1 % Dry Solids ((Dry Weight / Wet Weight) x 100) So ei , Q.__ % Dry Solids ((Dry Weight / Wet Weight) x 100) 24- 4-0 4 *Note -Differences should agree within 4% or 0.5 mg, which ever is Tess Revised 9/26/19 JDW Sampled By Received By Analyzed By Calculated By Checked By Name Pawll4 00-ki CITY OF 11. .SHINGTON SLUDGE Standard Methods 2540 G-2011(Aqueous) Date/Time S� 331 ,, (Ill Time on water bath Time in oven Time out of oven Time weighed 1st 2nd 1000 _ !io& 955 i�o{ :�+ 3-30-a.1 Sample # vZ Evaporating Dish # i ,a Sample # PJlar► Evaporating Dish # Wet Weight + Dish Weight / 3 D 9 At ,2 . 2 Wet Weight + Dish Weight Dish Weight $ 0 a G 3 , 9 Dish Weight %I a 5 4. 0 Wet Weight S © 0 Q 45 - Wet Weight 1st Dry Weight + Dish Weight °6 3 1 2,Ai,,ri 1st Dry Weight + Dish Weight CZ-1 as' 3,$ 2nd Dry Weight + Dish Weight 'S l ) 4 , (0 2nd Dry Weight + Dish Weight s r-, Ai , O Difference in 1st & 2nd Dry Weight + Dish Weight (2nd - 1st) 0 . a Difference in 1st & 2nd Dry Weight + Dish Weight (2nd - 1st) ©, a Dry Weight (2nd Dry Weight + Dish Weight - Dish Weight) a o . -I Dry Weight (2nd Dry Weight + Dish Weight - Dish Weight) b 0 % Dry Solids ((Dry Weight / Wet Weight) x 100) L , 53 • 6- '7) % Dry Solids ((Dry Weight / Wet Weight) x 100) *Note -Differences should agree within 4% or 0.5 mg, which ever is Tess Revised 9/26/19 JDW Sampled By Received By Analyzed By Calculated By Checked By Name CITY OF Id- SHINGTON SLUDGE Standard Methods 2540 G-2011(Aqueous) Date/Time P66141-4-/3-7(-) 3-29; 1/ q01 l r. 4 3 2-i , / 7-- J1 1..)-0e.. 3,- Time on water bath Time in oven Time out of oven Time weigh 1st 2nd ti3 /1a I { qs �k I/ 300, 102 iv -la ►au3 Sample # _ 3 Evaporating Dish # Sample # 1 Evaporating Dish # Wet Weight + Dish Weight ( 2 7 (,, Co 2-. Wet Weight + Dish Weight Dish Weight 7 7 5 (. d . r Dish Weight Wet Weight C 0 J p .� , L Wet Weight 1st Dry Weight + Dish Weight a1st Dry Weight + Dish Weight 2nd Dry Weight + Dish Weight 19' t q , i 2nd Dry Weight + Dish Weight Difference in 1st & 2nd Dry Weight + Dish Weight (2nd - 1st) 0 1 I Difference in 1st & 2nd Dry Weight + Dish Weight (2nd - 1st) Dry Weight (2nd Dry Weight + Dish Weight - Dish Weight) - -I I , O Dry Weight (2nd Dry Weight + Dish Weight - Dish Weight) % Dry Solids ((Dry Weight / Wet Weight) x 100) , 24 , 1 s q /a % Dry Solids ((Dry Weight / Wet Weight) x 100) *Note -Differences should agree within 4% or 0.5 mg, which ever is less Revised 9/26/19 JDW Sampled By Received By Analyzed By Calculated By Checked By Name fau/L/4-/Ttu kfigejte CITY OF 1, £HINGTON SLUDGE Standard Methods 2540 G-2011(Aqueous) Date/Time �041 3a9, R1 115-2- 3 - 1---! i 7- 9-- 3-31-01 , /1/3 Time on water bath Time in oven Time out of oven Time weighed 1st 2nd I/SZe (3I3c _ 1323 ,t103 to03 /al.14 1304 _l5 '/- Sample # Evaporating Dish # 0 Sample # Evaporating Dish # p 9 Wet Weight + Dish Weight I I 9 0 It -Li 1 Wet Weight + Dish Weight Dish Weight C9R07-0•7I Dish Weight Wet Weight g q 9 7-4 , 0 Wet Weight 1st Dry Weight + Dish Weight 1st Dry Weight + Dish Weight 2nd Dry Weight + Dish Weight 3-1 3 'f to , 2nd Dry Weight + Dish Weight Difference in 1st & 2nd Dry Weight + Dish Weight (2nd - 1st) 0 • 3 Difference in 1st & 2nd Dry Weight + Dish Weight (2nd - 1st) Dry Weight (2nd Dry Weight + Dish Weight - Dish Weight) A a 4 .0 Dry Weight (2nd Dry Weight + Dish Weight - Dish Weight) % Dry Solids ((Dry Weight / Wet — Weight) x 100) _ IS— % % Dry Solids ((Dry Weight / Wet Weight) x 100) *Note -Differences should agree within 4% or 0.5 mg, which ever is Tess Revised 9/26/19 JDW Sampled By Received By Analyzed By Calculated By Checked By CITY OF \,. £HINGTON SLUDGE Standard Methods 2540 G-2011(Aqueous) Name Date/Time lea vi4-, 3-23:211 90cd 1 3 a9 : , 6t / -- n i e' 3•-2$- 4 /!5 f , JJ G r 3-30Lt, 1' 1 12' &AL. i ��3f.2l, //// Time on water bath Time in oven Time out of oven Time weighed 1st 2nd //5-9 841 (3/3°7 ! r o 3 /o4-5- ! Sot., Sample # S Evaporating Dish # q Sample # i Evaporating Dish # Wet Weight + Dish Weight / 2 / U ' / 0 . C Wet Weight + Dish Weight Dish Weight 7 2i D. -, 5 Dish Weight Wet Weight 5 p (p q- , O Wet Weight 1st Dry Weight + Dish Weight 4 a 5 8S 1st Dry Weight + Dish Weight 2nd Dry Weight + Dish Weight .- Co a- 6— q , a 2nd Dry Weight + Dish Weight Difference in 1st & 2nd Dry Weight + Dish Weight (2nd - 1st) 0 • 3 Difference in 1st & 2nd Dry Weight + Dish Weight (2nd - 1st) Dry Weight (2nd Dry Weight + Dish Weight - Dish Weight) a --), - O •--f Dry Weight (2nd Dry Weight + Dish Weight - Dish Weight) % Dry Solids ((Dry Weight / Wet Weight) x 100) o., `f L fI— -.T..-' j / % Dry Solids ((Dry Weight / Wet Weight) x 100) *Note -Differences should agree within 4% or 0.5 mg, which ever is Tess Revised 9/26/19 JDW Sampled By Received By Analyzed By Calculated By Checked By Name /T-4 kv2e457 CITY OF 4 .SHINGTON SLUDGE Standard Methods 2540 G-2011(Aqueous) Date/Time 3 :2-I a/ 0 7 3 a- . , t17- p .2J Kerit r it� ;5 s 3-3! ), J115 Time on water bath Time in oven Time out of oven Time weighed 1st 2nd /a 0 `J %4_I (/aa) i323 io45 ica.L' Sample # Evaporating Dish # a Sample # 1 Evaporating Dish # Wet Weight + Dish Weight 1 a 0 9 3 1 , J— Wet Weight + Dish Weight Dish Weight 1 D ! P 0 , / Dish Weight Wet Weight L/- 9 t 7 1, 4 Wet Weight 1st Dry Weight + Dish Weight 732_94.2, 1st Dry Weight + Dish Weight 2nd Dry Weight + Dish Weight 7-3 2r'V 1.4 . 2, 2nd Dry Weight + Dish Weight Difference in 1st & 2nd Dry Weight + Dish Weight (2nd - 1st) V , 0 Difference in 1st & 2nd Dry Weight + Dish Weight (2nd - 1st) Dry Weight (2nd Dry Weight + Dish Weight - Dish Weight) .2 1 3 4- , 1 Dry Weight (2nd Dry Weight + Dish Weight - Dish Weight) % Dry Solids ((Dry Weight / Wet Weight) x 100) "L i 7 _ c 5 _ % Dry Solids ((Dry Weight 1 Wet 1 Weight) x 100) *Note -Differences should agree within 4% or 0.5 mg, which ever is less Revised 9/26/19 JDW Sampled By Received By Analyzed By Calculated By Checked By Name CITY OF b . ,SHINGTON SLUDGE Standard Methods 2540 G-2011(Aqueous) Date/Time Paid-41374J h4::ie 32921, et/7-- A l.)f. / 19Tv 3-A`P-2i 3-:3/- 2/ /// Time on water bath Time in oven Time out of oven Time weighed 1st 2nd i330 f 10 (3/30'4 13,23 12c3 i Al a,-/- 30(0 /5-.2-44 Sample # 7- Evaporating Dish # Sample # Evaporating Dish # Wet Weight + Dish Weight 1 7 / I j , % Wet Weight + Dish Weight Dish Weight 9.1- to a. 3 Dish Weight Wet Weight 5o O 1 & , 2 Wet Weight f 1st Dry Weight + Dish Weight gc 9 ' 7- g' 1st Dry Weight + Dish Weight 2nd Dry Weight + Dish Weight g q ,-F i 7 . (0 2nd Dry Weight + Dish Weight Difference in 1st & 2nd Dry Weight + Dish Weight (2nd - 1st) 0 . Difference in 1st & 2nd Dry Weight + Dish Weight (2nd - 1st) Dry Weight (2nd Dry Weight + Dish Weight - Dish Weight) 2 3 S 5--, 3 Dry Weight (2nd Dry Weight + Dish Weight - Dish Weight) % Dry Solids ((Dry Weight / Wet Weight) x 100) a. 4- C 5- 9- c• % Dry Solids ((Dry Weight / Wet Weight) x 100) *Note -Differences should agree within 4% or 0.5 mg, which ever is Tess Revised 9/26/19 JDW ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (02T Rules) Facility Name: City of Washington WQ Permit Number: 2021 WWTP Name: Washington WWTP NPDES Number: NC0020648 Monitoring Period: From 12/2/2021 To 12/2/2021 Pathogen Reduction (15A NCAC 02T .1106)- Please indicate level achieved and alternative performed: Class A: Alt. A (time/temp) ❑ Alt B (Alk Treatment)❑ Alt. C (Prior Testing)❑ AIt.D (No Prior Test) ❑ Process to Further Reduce Pathogengs ❑ If applicable to alternative performed(Class A only)indicate"Process to Further Reduce Pathogens": Compost ❑ Heat Drying ❑ Heat Treatment ❑ Thermophilic Beta Ray ❑ Gamma Ray ❑ Pasteurization CI Class B: Alt. (1)Fecal Density p Alt. (2)Process to Significantly Reduce Pathogens ❑ If applicable to alternative performed(Class B only)indicate"Process to Significantly Reduce Pathogens": Lime Stabilization ❑ Air Drying ❑ Composting ❑ Aerobic Digestion ❑ Anaerobic Digestion ❑ If applicable to alternative performed (Class A or Class B) complete the following monitoring data: Allowable Level Pathogen DensityNumber of Parameter gExcee- in Frequency Sample Analytical Sludge Minimum Geo. Mean Maximum Units deuces of Analysis Type Tech-nique 2 x 10 to the MPN 2571 3393 4000 MPN/g 0 Quarterly G SM92210E 6th power per gram of Fecal Coliform total solids CFU 1000 mpn per gram of total solid (dry weight) Salmonella bacteria 3 MPN per 4 grams (in lieu of fecal total solid(thy coliform) weight) Vector Attraction Reduction (15A NCAC 02T.1107) -Please indicate alternative performed: Alt.1 (VS reduction) o Alt. 2 (40-day bench) ❑ Alt. 3 (30-day bench) ❑ Alt. 4 (Spec. 02 uptake) ❑ Alt. 5 (14-Day Aerobic) ❑ Alt. 6 (Alk. Stabilization ❑ Alt 7(Drying-Stable) ❑ Alt. 8 (Drying-Unstable) ❑ Alt. 9 (Injection) ❑ Alt. 10 (Incorporation) ❑ No vector attraction reduction alternatives were performed ❑ CERTIFICATION STATEMENT (please check the appropriate statement) O "I certify,under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the vector attraction reduction requirement in 15A NCAC 02T .1107 have been met." ❑ "I certify,under penalty of law,that the pathogen requirements in 15A NCAC 02T .1106 and the vector attraction reduction requirement in 15A NCAC 02T .1107 have not been met." (Please note if you check this statement attach an explanation why you have not met one or both of the requirements.) "This determination has been made under my direction and supervision in accordance with the system designed to ensure that qualified personnel properly gather and evaluate the information used to determine that the pathogen and vector attraction reduction requirements have been met. I am aware that there are significant penalties for false certification including fine and imprisonment." Hope Woolard-Water Resources Superintendent Brent Collins; Director of Technical Services Preparer Name and Title (type or print) Land Applier Name and Title (if applicable)(type or print) c7 GUDOG2G( Feb 3,2022 2/1/2022 Hop op J IIN.N/oolard(Feb 3,202207:45 EST) Signature of Preparer* Date Signature of Land Applier(if applicable) Date *Preparer is defined in 40 CFR Part 503.9(r)and 15A NCAC 2T .1102 (26) DENR FORM PVRF 02T (12/2006) Summary Sheet Fecal Coliforms Pathogen Reduction Date: 12/2/2021 Location # MPN/g Log 1 4500 3.6532 2 3 4 5 6 7 4500 3.6532 11250 4.0512 4500 3.6532 4500 3.6532 4500 3.6532 4500 3.6532 5129 Geometric Means/g Total Dry Solids PamA Signature Sampled By Received By Analyzed By Calculated By Checked By NAME 5 DATE / TIME 11-15- •1, /o2q I040 ill)5131 111.24R1 132. XI laAl } I a2'T 24 hr. Check�iiij..�al 4P) 48 hr. Check it), i 1 i ,1'1=3 r 72 hr. Check it bcr at 3y Temp 34.1 °C 4y.tp° C Sample Location Sludge # I Sample Type: Grab x Composite Preservation: NONE FECAL COLIFORM TEST Standard Methods 9221 C E-2006(MPN)(Biosolids) 0 Presumptive Test mL Sample 0.001 0.0001 0.00001 0.000001 0.0000001 0.00000001 MPN 24 hours 48 hours r - 1— T Fecal Coliform Test 41, mL Sample 0.001 0.0001 0.00001 0.000001 ` 0.0000001 0.00000001y Ml 24 hours — — I — ,-- 1 I 1 1. Ir l ( - 8 MPN Fecal Coliform/g = 10 x MPN index / 100 ml largest volume X % dry solids tested Sterility Control Quality Control Tubes 10 mL Double Strength (DS) Control S yt p Q1k-e Single Strength (SS) Control �A y),., EC Broth Control ou Revised 5-23-16 MPN/g= lOx I•g 0.00/X�1 hr C IhR.CIZ- i��i1o1�1 l"i = 18 Sampled By Received By Analyzed By Calculated By Checked By NAME Pam DATE / TIME ,I-,5-a4, /021 11-1s-3►, /040 11115131 1) 0"0 ///2' 7/2/ /350 ,1-a.9-a l i 147A 24 hr. Check i►bula1 + 1 ?al 48 hr. Check ii),-i 1 in Ss- 72 hr. Check 11110zi Sample Location Temp •1 °C Sludge # 1 Sample Type: Grab x Composite Preservation: NONE FECAL COLIFORM TEST Standard Methods 9221 C E-2006(MPN)(Biosolids) Presumptive Test Lk" mL Sample 0.001 0.0001 0.00001 0.000001 0.0000001 0.00000001 MPN 24 hours - ¥ 1- $ 1- — ^ — - — .-- - - -- — - Ltt ' 48 hours " }- - - - _ - - r - - mL Sample 24 hours 0.001 O 0.0001 MPN Fecal Coliform/g = 10 x MPN index / 100 ml largest volume X % dry solids tested Sterility Control 0 Fecal Coliform Test 0.00001 Quality Control Tubes 10 mL Double Strength (DS) Control Single Strength (SS) Control Yl�c .urC EC Broth Control Revised 5-23-16 0.000001 MPN/g = 10 x • o,ddfn y 0.0000001 = �� 0.00000001 AL I Sampled By Received By Analyzed By Calculated By Checked By NAME DATE / TIME I ! S--) I 1 /030 I1-1 5 -D-1, /04D 1111513-, 11> /1/022/21 /3,`5/ rr-a�-ate la3a 24 hr. Check i►fllujl IVY? 48hr. Checkhl,1 hy IISi/ 72 hr. Check 1+11Kc]-a-1 IN-5 3y Temp•1 °C 411-1.1.0° C Sample Location S1udQe # £.' Sample Type: Grab x Composite Preservation: NONE FECAL COLIFORM TEST Standard Methods 9221 C E-2006(MPN)(Biosolids) Presumptive Test mL Sample 0.001 0.0001 0.00001 0.000001 r 0.0000001 0.00000001 MPN 24 hours 4 " k -1*- ) j- — — — _ — — — — — -- — — — — T 1 1 48 hours j^ - - J - - r ._ _ — r J — ^33 Fecal Coliform Test 4°1 mL Sample 0.001 0.0001 0.00001 0.000001 0.0000001 MP1Y 24 hours ,-- 1 .-- ._ — — 1 1 1I0.00000001 1 `' \+ . MPN Fecal Coliform/g = 10 x MPN index / 100 ml largest volume X % dry solids tested Sterility Control Quality Control Tubes 10 mL Double Strength (DS) Control Single Strength (SS) Control (`ll iic.tu C- EC Broth Control Revised 5-23-16 ek 0 RC±LA re. MPN/g= 10x •g 0.00(( . 0,001/ 8' Sampled By Received By Analyzed By Calculated By Checked By 5 DATE / TIME i i ., --.1, 7031 )t - ► s-DAI /040 i1]Is131 11.-1 ///e2 2/2/ it-iq-�j Ia33 24 hr. Check i ►Dial q 1 ').7 48 hr. Check 72hr. Check t+j,e�atr 1� Temp•? °C My.lo°C Sample Location _ Sludge # , Sample Type: Grab x Composite (1 Preservation: NONE FECAL COLIFORM TEST Standard Methods 9221 C E-2006(MPN)(Biosolids) Presumptive Test mL Sample 0.001 0.0001 0.00001 0.000001 0.0000001 0.00000001 ' MPN 24 hours — - k k k- 1- -1. - - - — (Lt-C 48 hours ^ � — — �. — — _ — _i 0 0 Fecal Coliform Test mL Sample 0.001 0.0001 0.00001 0.000001 0.0000001 0.00000001 MR 24 hours i� f' , — -f" 1 y I_ _ r f I LLS MPN Fecal Coliform/g = 10 x MPN index / 100 ml largest volume X % dry solids tested Sterility Control Quality Control Tubes 10 mL Double Strength (DS) Control yU p ce° U re — "y�" i Single Strength (SS) Control �t EC Broth Control tS Revised 5-23-16 MPN/g = 10 x /4.5 0, OOP/ 1(250 ittlx/, Sampled By Received By Analyzed By Calculated By Checked By 5 DATE / TIME il-«-,) /0321 11- I S"-D- /04D it�lsj� 1 1131 11/22/ai, /353 24 hr. Check 1 )'''t> 48 hr. Check ItIola a i 1 ti c, 72 hr. Check 11110a-►1 Sample Location Sludge # Sample Type: Grab x Preservation: NONE FECAL COLIFORM TEST Standard Methods 9221 C E-2006(MPN)(Biosolids) Presumptive Test Temp SA.1 °C 9y.lo°C Composite mL Sample 0.001 0.0001 0.00001 0.000001 0.0000001 0.00000001 MPN 24 hours -1' -- j-- — — — — _ — — Ci3 , 48 hours , .�- -t r - - - t '- '- - , - , - - _ T-It1114 V Fecal Coliform Test mL Sample 0.001 0.0001 ' 0.00001 0.000001 0.0000001 0.00000001 1 MP.1 24 hours -- — ' — — — I J �I .SS MPN Fecal Coliform/g = 10 x MPN index / 100 ml largest volume X % dry solids tested Sterility Control Quality Control Tubes 10 mL Double Strength (DS) Control Single Strength (SS) Control EC Broth Control Revised 5-23-16 12_jrztti re, MPN/g = lO x 8 c ,coo/X 1f Sampled By Received By Analyzed By Calculated By Checked By NAME DATE / TIME 11-15.I, (G33 )1-I 5 31, /0hp 11115)31 111,1 ,/ /z/ /32 j /11-3.a. 24 hr. Check > 1 48 hr. Checkit),i!)5S; 72 hr. Check I1v Iai !')f 7 Temp •1 °C �4•�°C Sample Location Sludge # .'' Sample Type: Grab x Composite Preservation: NONE FECAL COLIFORM TEST Standard Methods 9221 C E-2006(MPN)(Biosolids) Presumptive Test v 41,0 mL Sample 0.001 0.0001 0.00001 0.000001 0.0000001 0.00000001 MPN 24 hours 1- .r - } k - -- -- - ... -- -- - I- - - - - - ,_.. --,,, (y to ? 48 hours "r — t ,— _ _ .— — _ - — — — 1 — — 0 c) 0 Fecal Coliform Test mL Sample 0.001 0.0001 0.00001 0.000001 0.0000001 MPN 24 hours — — -� 1 — — I — I 10.00000001 II ! 1 ) MPN Fecal Coliform/g = 10 x MPN index / 100 ml largest volume X % dry solids tested Sterility Control Quality Control Tubes 10 mL Double Strength (DS) Control Single Strength (SS) Control EC Broth Control Revised 5-23-16 MPN/g = 10 x /• 0•00/X 4 = ig ,//500 #-PAi Sampled By Received By Analyzed By Calculated By Checked By NAME P k4.1„ ti,r4t? 11- DATE / TIME 11-1 s-D-1, /0*0 it i5)31 :11SD--- yf2/21, /355 rr ,af Pat,' 24 hr. Check 11t 1, 1 , } 48 hr. Check it),, la 1 ) :,P 72 hr. Check 3111cci1 )2, ' Sample Location S1udEe # 6 Sample Type: Grab x 3y Temp SA•1 °C M'-1. 1.:° C Composite Preservation: NONE FECAL COLIFORM TEST Standard Methods 9221 C E-2006(MPN)(Biosolids) C> Presumptive Test mL Sample 0.001 0.0001 0.00001 0.000001 0.0000001 0.00000001 ` MPN hours t1- ' Y {' -� .- - - - - - � r- , - - - ......,t24 I( -t---c-i 48 hours t -- - 1- f" "' _ r - - - - -- -" L7 Fecal Coliform Test mL Sample 24 hours 0.001 0.0001 1 MPN Fecal Coliform/g = 10 x MPN index / 100 ml largest volume X % dry solids tested Sterility Control 0.00001 Quality Control Tubes 10 mL Double Strength (DS) Control Single Strength (SS) Control EC Broth Control Revised 5-23-16 0.000001 MPN/g = 10 x oo0tX�l 0.0000 001 0.00000001 MP I c tY IV) ///2-Z/a2/ 0 • Go4I ifs 00 Pll:k Sampled By Received By Analyzed By Calculated By Checked By DATE / TIME II-,S-)1, /035 1010 i111513 IC 7)- / 2.2/021f /35.5 /I-1f-a i (i - 31c 3y Temp °C +-0-1- L° C Sample Location Sludge # 24 hr. Check ii►..ja1 Sample Type: Grab x Composite 48 hr. Check ��,^1�� '1 � >p7)PreservatiOn: NONE j 72 hr. Check litIm i 91-17 FECAL COLIFORM TEST Standard Methods 9221 C E-2006(MPN)(Biosolids) p Presumptive Test mL Sample 0.001 0.0001 0.00001 0.000001 0.0000001 0.00000001 MPN 24 hours I' �' - 1- 4' - - - - - - - r_ - _ 33 48 hours •j- •� - - - - _ _ r- - - r: Fecal Coliform Test mL Sample 0.001 0.0001 0.00001 0.000001 0.0000001 0.00000001 Ml 24 hours _ •- — - - ' I I _ I I I I .41 a%, jr MPN Fecal Coliform/g = 10 x MPN index / 100 ml largest volume X % dry solids tested Sterility Control Quality Control Tubes 10 mL Double Strength (DS) Control Single Strength (SS) Control EC Broth Control Revised 5-23-16 V1.4 Lire LSkX r�9 G ure. MPN/g = 10 x I d /15oo /-11A)/k. Sampled By Received By Analyzed By Calculated By Checked By Name deL .A i 7)12601/41, CITY OF WASHINGTON SLUDGE Standard Methods 2540 G-2011(Aqueous) Date/Time /4.2`r i0P0 i ii-i6 aJ, 15?q 1,/gz/al 3z Time on water bath Time in oven Time out of oven Time weigh 1st ed 2nd 10 5' ' , 9,),-i (n-i(;) 1,132 1oas, Ia.4t, t t3o , 135 Co Sample # I Evaporating Dish # 3 Sample # I eitkp 1, Evaporating Dish # 3E Wet Weight + Dish Weight t a S o 3 °I , 5 Wet Weight + Dish Weight 1 ". Le 17 R a . 3 Dish Weight n 0 4 L. p Dish Weight g 4, 3 Lf te, 3 Wet Weight 9 ci ,-, ,'; Wet Weight '- p i y (0 , 0 1st Dry Weight + Dish Weight 01 1 �� S 1st Dry Weight + Dish WeightTr 2 2nd Dry Weight + Dish Weight 2 0 / 1 5. 1 2nd Dry Weight + Dish Weight e s a. ' 3 , (. Difference in 1st & 2nd Dry Weight + Dish Weight (2nd - 1st) p , 4 Difference in 1st & 2nd Dry Weight + Dish Weight (2nd - 1st) 1- , 3 Dry Weight (2nd Dry Weight + Dish Weight - Dish Weight) n :� q , I Dry Weight (2nd Dry Weight + Dish Weight - Dish Weight) I e g 1 , 3 % Dry Solids ((Dry Weight / Wet Weight) x 100) , D g , Li 5 % Dry Solids ((Dry Weight / Wet Weight) x 100) 3, 2 = /-1- % *Note -Differences should agree within 4% or 0.5 mg, which ever is Tess Revised 9/26/19 JDW Sampled By Received By Analyzed By Calculated By Checked By CITY OF WASHINGTON SLUDGE Standard Methods 2540 G-2011(Aqueous) Name Date/Time 11-/5-2.1) i630 1 r- / 5-�-� /0/10 1r-rs �I,JO ►r-17-.21,rX // /2 2 j2/ 433 Time on water bath Time in oven Time out of oven Time weighed 1st 2nd 1 ICA _) I -7, cis mow- G /3a _ 1-2, Sample # 66,,,ti Qt, Evaporating Dish # -, Sample # ., Evaporating Dish # .) Wet Weight + Dish Weight Wet Weight + Dish Weight t i of 31 1. 5 Dish Weight v, a5 .5 Dish Weight G c1 15 3 .0 Wet Weight Wet Weight 5 p l 5 Ts, z� 1st Dry Weight + Dish Weight Ia53.1 1st Dry Weight + Dish Weight 7r1y5.I 2nd Dry Weight + Dish Weight S1 '1 a S 3 , -4 2nd Dry Weight + Dish Weight -7 / r y. , I Difference in 1st & 2nd Dry Weight + Dish Weight (2nd - 1st) D . 3 Difference in 1st & 2nd Dry Weight + Dish Weight (2nd - 1st) 0 • 0 Dry Weight (2nd Dry Weight + Dish Weight - Dish Weight) 0 I Dry Weight (2nd Dry Weight + Dish Weight - Dish Weight) I ci 01 i % Dry Solids ((Dry Weight / Wet Weight) x 100) % Dry Solids ((Dry Weight / Wet Weight) x 100) 3 rt r Lt a *Note -Differences should agree within 4% or 0.5 mg, which ever is less Revised 9/26/19 JDW Sampled By Received By Analyzed By Calculated By Checked By PoieLl i CITY OF WASHINGTON SLUDGE Standard Methods 2540 G-2011(Aqueous) Date/Time 11-15-al /c 3 / 11-15--.)--1 /0/10 II'i )>< 1000 l- 11517 ///2.?/) l a/) Time on water bath Time in oven Time out of oven Time weighed 1st 2nd 1'D•.9-1 //3 (r)_i:1) J''.F+ `E:.;-I Sample # 3 Evaporating Dish # _ .),., Sample # Evaporating Dish # Wet Weight + Dish Weight / a a q 5 4 , Wet Weight + Dish Weight Dish Weight 7 0 95 1, (r Dish Weight Wet Weight I1 el g q 7 . Wet Weight 1st Dry Weight + Dish Weight --30SD,, 1st Dry Weight + Dish Weight 2nd Dry Weight + Dish Weight 7 S 0 q 3,.2.. 2nd Dry Weight + Dish Weight Difference in 1st & 2nd Dry Weight + Dish Weight (2nd - 1st)- 6 "} Difference in 1st & 2nd Dry Weight + Dish Weight (2nd - 1st) Dry Weight (2nd Dry Weight + Dish Weight - Dish Weight) LA i)5 , La Dry Weight (2nd Dry Weight + Dish Weight - Dish Weight) % Dry Solids ((Dry Weight / Wet Weight) x 100) c� • /o % Dry Solids ((Dry Weight / Wet Weight) x 100) *Note -Differences should agree within 4% or 0.5 mg, which ever is less Revised 9/26/19 JDW Sampled By Received By Analyzed By Calculated By Checked By CITY OF WASHINGTON SLUDGE Standard Methods 2540 G-2011(Aqueous) Name Date/Time 044 Di ll-15 .l, /t 32. 10//0 ii-4,-,211 for d 1, ,//22fR/ t34' Time on water bath Time in oven Time out of ove Time weigh 1st n 2nd _, ►,..S qF 7/3 6La /3S - ept Sample # `t Evaporating Dish # , T Sample # Evaporating Dish # Wet Weight + Dish Weight I I q % ,� Wet Weight + Dish Weight Dish Weight (y, eiV g .5- Dish Weight Wet Weight 5 0 j S 0, 0 Wet Weight 1st Dry Weight + Dish Weight 1st Dry Weight + Dish Weight 2nd Dry Weight + Dish Weight -5- i ' D 1 . S 2nd Dry Weight + Dish Weight Difference in 1st & 2nd Dry Weight + Dish Weight (2nd - 1st) [✓ , 3 Difference in 1st & 2nd Dry Weight + Dish Weight (2nd - 1st) Dry Weight (2nd Dry Weight + Dish Weight - Dish Weight) .2 o 0 0 Dry Weight (2nd Dry Weight + Dish Weight - Dish Weight) % Dry Solids ((Dry Weight / Wet Weight) x 100) S.94) _ Li- 5c. % Dry Solids ((Dry Weight / Wet Weight) x 100) *Note -Differences should agree within 4% or 0.5 mg, which ever is less Revised 9/26/19 JDW Name Sampled By Received By Analyzed By Calculated By Checked By D 141-AL CITY OF WASHINGTON SLUDGE Standard Methods 2540 G-2011(Aqueous) Date/Time I,/ 33 IQ//O 11-111.7-La.I010)0 1i-1 94_ / -, 0- c)-1 L1 a( lif �ja1'1kO 1st 2nd Time on water bath Time in oven Time out of oven Time weighed / r. / q 7 / (///17-. 14- 9_1 to aS /G Sample # Evaporating Dish # Sample # Evaporating Dish # Wet Weight + Dish Weight i I'j O Ts i , 5 Wet Weight + Dish Weight Dish Weight % 9 0 69 9', q Dish Weight Wet Weight 6-0 O I 1 , (o Wet Weight 1st Dry Weight + Dish Weight 1st Dry Weight + Dish Weight 2nd Dry Weight + Dish Weight / o 9 9 , B' 2nd Dry Weight + Dish Weight Difference in 1st & 2nd Dry Weight + Dish Weight (2nd - 1st) ti . ,;._ Difference in 1st & 2nd Dry Weight + Dish Weight (2nd - 1st) Dry Weight (2nd Dry Weight + Dish Weight - Dish Weight) aoa ci ,9 Dry Weight (2nd Dry Weight + Dish Weight - Dish Weight) % Dry Solids ((Dry Weight / Wet Weight) x 100) /.- , o 5 = Li , % Dry Solids ((Dry Weight / Wet Weight) x 100) *Note -Differences should agree within 4% or 0.5 mg, which ever is Tess Revised 9/26/19 JDW Sampled By Received By Analyzed By Calculated By Checked By Name CITY OF WASHINGTON SLUDGE Standard Methods 2540 G-2011(Aqueous) Date/Time 11-15�f J ic34 ►�-1► ar 1:��5 11-1 cj-,QI / 7a9 11f�21�l�i.Z. Time on water bath Time in oven Time out of oven Time weighed 1st 2nd • (135 f03S Sample # Evaporating Dish # 1 Sample # Evaporating Dish # Wet Weight + Dish Weight / 1 "7 `f 8' . (p Wet Weight + Dish Weight Dish Weight 7 7- S- S- L, Dish Weight Wet Weight p i q 0 . O Wet Weight 1st Dry Weight + Dish Weight _ 1st Dry Weight + Dish Weight jot, t"-fs-�-r 2nd Dry Weight + Dish Weight 4 .- 9 7 a- 4.'2' 2nd Dry Weight + Dish Weight Difference in 1st & 2nd Dry Weight + Dish Weight (2nd - 1st) 0 . 3 Difference in 1st & 2nd Dry Weight + l Dish Weight (2nd - 1st) Dry Weight (2nd Dry Weight + Dish Weight - Dish Weight) ,2 1 Dry Weight (2nd Dry Weight + Dish Weight - Dish Weight) % Dry Solids ((Dry Weight / Wet Weight) x 100) il , 31 '" ,( % Dry Solids ((Dry Weight / Wet Weight) x 100) *Note -Differences should agree within 4% or 0.5 mg, which ever is Tess Revised 9/26/19 JDW Name Sampled By Received By Analyzed By Calculated By Checked By 014 CITY OF WASHINGTON SLUDGE Standard Methods 2540 G-2011(Aqueous) Date/Time Time on water bath Time in oven Time out of ove Time weigh 1st n 2nd ►- 4 7/2(+r,--t, q2h 0.6„_,1 )03S' 1 cii7 ii1tq Sample # 7 Evaporating Dish # (. - Sample # Evaporating Dish # Wet Weight + Dish Weight 1 a 3 0 4,1 Wet Weight + Dish Weight Dish Weight .7 i) 2 a 7, 3 Dish Weight Wet Weight if i g 7- le ,' Wet Weight 1st Dry Weight + Dish Weight 3 / S / 1st Dry Weight + Dish Weight 2nd Dry Weight + Dish Weight 3 Lt 3 15. 0 2nd Dry Weight + Dish Weight Difference in 1st & 2nd Dry Weight + Dish Weight (2nd - 1st) 0 , j Difference in 1st & 2nd Dry Weight + Dish Weight (2nd - 1st) Dry Weight (2nd Dry Weight + Dish Weight - Dish Weight) 1 C g I Dry Weight (2nd Dry Weight + Dish Weight - Dish Weight) % Dry Solids ((Dry Weight / Wet Weight) x 100) ci 3 - 14 ? r. % Dry Solids ((Dry Weight / Wet Weight) x 100) *Note -Differences should agree within 4% or 0.5 mg, which ever is less Revised 9/26/19 JDW ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (02T Rules) Facility Name: City of Washington WQ Permit Number: 2021 WWTP Name: Washington WWTP NPDES Number: NC0020648 Monitoring Period: From 12/2/2021 To 12/2/2021 Pathogen Reduction (15A NCAC 02T .1106)- Please indicate level achieved and alternative performed: Class A: Alt. A (time/temp) ❑ Alt B (Alk Treatment)❑ Alt. C (Prior Testing)❑ AIt.D (No Prior Test) ❑ Process to Further Reduce Pathogengs ❑ If applicable to alternative performed(Class A only)indicate"Process to Further Reduce Pathogens": Compost ❑ Heat Drying ❑ Heat Treatment ❑ Thermophilic Beta Ray ❑ Gamma Ray ❑ Pasteurization CI Class B: Alt. (1)Fecal Density p Alt. (2)Process to Significantly Reduce Pathogens ❑ If applicable to alternative performed(Class B only)indicate"Process to Significantly Reduce Pathogens": Lime Stabilization ❑ Air Drying ❑ Composting ❑ Aerobic Digestion ❑ Anaerobic Digestion ❑ If applicable to alternative performed (Class A or CL 2021 Allowable Level Pathogen DensityNumber of Parameter gExcee- in Frequency Sample Analytical Sludge Minimum Geo. Mean Maximum Units deuces of Analysis Type Tech-nique 2 x 10 to the MPN 4500 5129 11250 MPN/g 0 Quarterly G SM92210E 6th power per gram of Fecal Coliform total solids CFU 1000 mpn per gram of total solid (dry weight) Salmonella bacteria 3 MPN per 4 grams (in lieu of fecal total solid(thy coliform) weight) Vector Attraction Reduction (15A NCAC 02T.1107) -Please indicate alternative performed: Alt.1 (VS reduction) o Alt. 2 (40-day bench) ❑ Alt. 3 (30-day bench) ❑ Alt. 4 (Spec. 02 uptake) ❑ Alt. 5 (14-Day Aerobic) ❑ Alt. 6 (Alk. Stabilization ❑ Alt 7(Drying-Stable) ❑ Alt. 8 (Drying-Unstable) ❑ Alt. 9 (Injection) ❑ Alt. 10 (Incorporation) ❑ No vector attraction reduction alternatives were performed ❑ CERTIFICATION STATEMENT (please check the appropriate statement) O "I certify,under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the vector attraction reduction requirement in 15A NCAC 02T .1107 have been met." ❑ "I certify,under penalty of law,that the pathogen requirements in 15A NCAC 02T .1106 and the vector attraction reduction requirement in 15A NCAC 02T .1107 have not been met." (Please note if you check this statement attach an explanation why you have not met one or both of the requirements.) "This determination has been made under my direction and supervision in accordance with the system designed to ensure that qualified personnel properly gather and evaluate the information used to determine that the pathogen and vector attraction reduction requirements have been met. I am aware that there are significant penalties for false certification including fine and imprisonment." Hope Woolard-Water Resources Superintendent Brent Collins; Director of Technical Services Preparer Name and Title (type or print) Land Applier Name and Title (if applicable)(type or print) c7 GUDOG2G( Feb 3,2022 2/1/2022 Hop op J IIN.N/oolard(Feb 3,202207:45 EST) Signature of Preparer* Date Signature of Land Applier(if applicable) Date *Preparer is defined in 40 CFR Part 503.9(r)and 15A NCAC 2T .1102 (26) DENR FORM PVRF 02T (12/2006) Summary Sheet Fecal Coliforms Pathogen Reduction Date: 12/2/2021 Location # MPN/g Log 1 3600 3.5563 2 3 4 5 6 7 4000 3.6021 2571 3.4101 3000 3.4771 3600 3.5563 3600 3.5563 3600 3.5563 3393 Geometric Means/g Total Dry Solids Signature - Sampled By Received By Analyzed By Calculated By Checked By mL Sample 24 hours 48 hours mL Sample NAME „ tuL&I_i_. faekOzgAid - 24 hours 0.001 10, t DATE / TIME /J-t- 2I) gAi& ii-! 2l /0006 11l+j ai 1031 ll/az/a/ /3©3 l(-ag-mot, /y5� 0.0001 24 hr. Check ► t I4-1:4-1 0-E°i 48 hr. Check 111 a-) 104 ' Preservation: NONE 72 hr. Check + + 141 i l 0')/?., f �' FECAL COLIFORM TEST Standard Methods 9221 C E-2006(MPN)(Aqueous) Presumptive Test 0.00001 T 0.000001 0.0000001 Sample Location Sludge # / 3 Temp 35,0 °C 44.(e °C Sample Type: Grab x Composite 0.00000001 ° Fecal Coliform Test ®0��0-�---1MINI 001 0.001 0.0001 MPN Fecal Coliform/g = 10 x MPN index / 100 ml largest volume X % dry solids tested Sterility Control Quality Control Tubes Double Strength (DS) Control Single Strength (SS) Control EC Broth Control Revised 5-23-16 10 mL K.A_ c:)se ] 0.000001 MPN/g = lO x " g O.loom .5 0.0000001 C 0.00000001 = lg G3 , o0 iy/`"'/ Sampled By Received By Analyzed By Calculated By Checked By mL Sample NAME DATE / TIME 1 feweL ' ` rl/a al oa _l,3o' 4 3 i 1�'a3'a-( 1 lq S4f 0.001 .0001 C.2 C) 0.001 0.0001 MPN Fecal Coliform/g = lOxMPN index /100ml largest volume X % dry solids tested Sample Location Slud e # / 1 24 hr. Check ► i �;} 1oy�`7 --��( _ � Sample Type: Grab x Composite 48 hr. Check 1 n C -, Preservation: NONE 72 hr. Check i t 14j f IDS%' FECAL COLIFORM TEST Standard Methods 9221 C E-2006(MPN)(Aqueous) 0 Presumptive Test 0.00001 Sterility Control Quality Control Tubes Double Stren h S) Control EC Broth Control Revised 5-23-16 Fecal Coliform Test 0.00001 0.000001 0.0000001 0.00000001 Temp 35, o °c 44. (Q °C 9 MPN MPN/g= 10x _ 0 OO/X 5 0 0 t3�d© �� /c1" - Sampled By Received By Analyzed By Calculated By Checked By mL Sample 24 hours 48 hours mL Sample 24 hours NAME g 0.001 0.001 DATE / TIME 1 iLr 2 Jp O ip 11 0.0001 24 hr. Check I 1 I 48 hr. Check 1 i (� 72 hr. Check 1 % IS FECAL COLIFORM TEST Standard Methods 9221 C E-2006(MPN)(Aqueous) v Presumptive Test Temp Sample Location Sludge # ,� °C Sample Type: Grab x J Composite Preservation: NONE 0.00001 Fecal Coliform Test 0.000001 0.0000001 a3 0.00000001 MPN 0.00001 0.000001 0.0000001 0.00000001 a MPN Fecal Coliform/g = 10 x MPN index / 100 ml largest volume X % dry solids tested 0.0001 Sterility Control Quality ontrol Tubes EC Broth Control Revised 5-23-16 MPN/g = 10 x 00- (i ©.001X 5 = 4,0soo iy/14. 0.00.5 NAME Sampled By Received By 3 f�� Analyzed By Calculated By Checked By ✓' mL Sample 24 hours 48 hours mL Sample 0.001 24 hours L �1 I DATE / TIME 953 )1-J 21, I0C'6 sao 0.0001 Sample Location Slud e # 24 hr. Check 1+I;}..] O�{ Sample Type: Grab x Composite 48 hr. Check 1I1 31ar -I IO9 ,>p.27Preservation: NONE 72hr.Check i114f-Ifil? FECAL COLIFORM TEST Standard Methods 9221 C E-2006(MPN)(Aqueous) O Presumptive Test 0.00001 © d Fecal Coliform Test 0.0001 MPN Fecal Coliform/g = 10 x MPN index / 100 ml largest volume X % dry solids tested Sterility Control Quality Control Tubes Double Stren th 1 S Control Sin le Stren th (SS) Control EC Broth Control Revised 5-23-16 0.000001 0.0000001 0.00000001 0.00001 0.000001 0.0000001 0.00000001 3 Temp 35, V °C 44.(.°C MPN/g = 10 x • g = g O.40/x 4- p•O© 3— NAME DATE / TIME Temp 35, D °C Sampled By , 9� 44. ce °C Received By c k _ 7 Sample Location Sludge # ►1-i- loC6 24 hr. Check 11'.� Analyzed By b�[a Sample Type: Grab x Composite _tlfy. ''a` i 11) r S 110 a. 48 hr. Check 11 preservation: NONE Calculated By P J `%: 11 Checked Bylzz1a i • 1`�� 72 hr. Check 1,14H i i ) tic ti .�) � 11 .3-,� ( /S43 mL Sample 24 hours 48 hours mL Sample 24 hours S 0.0001 0.0001 FECAL COLIFORM TEST Standard Methods 9221 C E-2006(MPN)(Aqueous) Presumptive Test 0 00001 Fecal Coliform Test 0.000001 0.0000001 0.00000001 0.00001 0.000001 �md0mv��-m onmonsoroman mr 000001 0.00000001 MPN Fecal Coliform/g = 10 x MPN index / 100 ml largest volume X % dry solids tested Sterility Control Quality Control Tubes Double Stren th (DS) Control EC Broth Control Revised 5-23-16 MPN/g = 10 x • g = l� ©•nollr 0,006 30oo Sampled By Received By Analyzed By Calculated By Checked By mL Sample 24 hours 48 hours tritelt,Q Lof r, 0.001 mL Sample 24 hours 0.001 t- DATE / TIME /OO6 (tag 42ziof /336 //•)-.).r_ //sa l 0 0.0001 48 hr. Check 1113I.)-1 )per>,7 Preservation: NONE 72 hr. Check + + 1 y i Di OD FECAL COLIFORM TEST Standard Methods 9221 C E-2006(MPN)(Aqueous) ( Presumptive Test 0.00001 0.000001 0.0000001 V ( 0.0001 0 Fecal Coliform Test 0.00001 0.000001 i MPN Fecal Coliform/g = _ 10 x MPN index / 100 ml largest volume X % dry solids tested Sterility Control Quality Control Tubes Double Strength (DS) Control Single Strength (SS) Control EC Broth Control Revised 5-23-16 lO mL _i_ lkic-Cle..,.re KA_ c .L. rf._. 0.0000001 Sample Location S1ud2e # 5 24 hr. Check ► l 1 1:)--J iL,y � Sample Type: Grab x Composite 0.00000001 3 — Temp 35, °C tf+{.(e °C J MPN CI.9' 7 %g MPN/g= lOx �� _ 0.00000001 Sampled By Received By Analyzed By Calculated By Checked By mL Sample 24 hours 48 hours mL Sample 24 hours NAME 0.001 DATE / TIME 11-) /o 0 (p 24 hr. Check 1 * 1 14-1 I�y{cl o' 48 hr. Check 111 3}4-1 r letiCs 17 22 r3 72 hr. Check > > y s - 0.0001 FECAL COLIFORM TEST Standard Methods 9221 C E-2006(MPN)(Aqueous) Presumptive Test Sample Location Temp °C 44. (e °c Sample Type: Grab x Composite Preservation: NONE 0 00001 0.000001 0.0000001 0.00000001 MPN Fecal Conform Test `) ©��0��-�0.00001 0��-�� 0.0000001 0.00000001 0.001 MPN Fecal Coliform/g = 0.0001 10xMPN index /100m1 largest volume X % dry solids tested Sterility Control Quality Control Tubes Double Stren th DS) Control Revised 5-23-16 MPN/g = 10 x = 1e ©' do/x - ©.oa5 3600 P/N/1._, Sampled By Received By Analyzed By Calculated By Checked By mL Sample 24 hours 48 hours NAME Sample Location Siva e # • //7L- D©A 24hr.Check �� j;�! �p�ir7 �� i� — ��nj Sample Type: Grab x Composite yp e -- L, 48 hr. Check 1� —� �' ��`{& P-P Preservation: NONE a a 72 hr. Check + + 4"-`k 6 442119 3 0.001 0.001 DATE / TIME 11-1- 2I /0p%' -/ 3a r15_?3__ 0.0001 FECAL COLIFORM TEST Standard Methods 9221 C E-2006(MPN)(Aqueous) —0 Presumptive Test 0 00001 0.000001 0.0000001 0.00000001 Temp °C °C MP 0.00001 4_ 1,ee mvvdr ��m� ��r��r o.000000l 0.00000001 , PN MPN Fecal Coliform/g = 0.0001 10xMPN index /100m1 largest volume X % dry solids tested Sterility Control Quality Control Tubes Double Stren h (pS) Control EC Broth Control Revised 5-23-16 Fecal Coliform Test MPN/g = 10 x = ©•0c�lX ®•oo ��6o0 Ji{/i7 Sampled By Received By Analyzed By Calculated By Checked By Sample # Name L1 Lu-LIC leallek. 3418 aJ d / Wet Weight + Dish Weight Dish Weight Wet Weight 1st Dry Weight + Dish Weight 2nd Dry Weight + Dish Weight Difference in 1st & 2nd Dry Weight + Dish Weight (2nd - 1st) Dry Weight (2nd Dry Weight + Dish Weight - Dish Weight) % Dry Solids ((Dry Weight / Wet Weight) x 100) CITY OF W ,HINGTON SLUDGE Standard Methods 2540 G-2011(Aqueous) Date/Time ii-,- .,1 944p i t-1-DI fOver /1-/-.1-_t1 /o/'e // --//I3�4 r'l1 /6/2/, /fD5/ Evaporating Dish # ,j i I Qi cls L. „D., 7 20 8 3.0 a3g4.z. *Note -Differences should agree within 4% or 0.5 mg, which ever is Tess Revised 9/26/19 JDW Time on water bath b0.3i a -mot 0-3-lime in oven Time out of oven Time weighed Sample # fI»pD. Wet Weight + Dish Weight Dish Weight Wet Weight. 1st Dry Weight + Dish Weight 2nd Dry Weight + Dish Weight Difference in 1st & 2nd Dry Weight + Dish Weight (2nd - 1st) Dry Weight (2nd Dry Weight + Dish Weight - Dish Weight) % Dry Solids ((Dry Weight / Wet Weight) x 100) 1st 2nd Evaporating Dish # (/ c�upL (p 'f 6, l o , 9 Sn n, ..CD , j 4 7,2 = �� Sampled By Received By Analyzed By Calculated By Checked By Sample # Name CITY OF W. HINGTON SLUDGE Standard Methods 2540 G-2011(Aqueous) Date/Time q51 i i-i-J.i , /0 0 fr.,44A.1. /, - /47 A L y ►, �-2 1 U 1 Pa ,724 ;.? 116 al110 z P-1, [rJ C l Y I `-c, Wet Weight + Dish Weight Dish Weight Wet Weight 1st Dry Weight + Dish Weight 2nd Dry Weight + Dish Weight Difference in 1st & 2nd Dry Weight + Dish Weight (2nd - 1st) Dry Weight (2nd Dry Weight + Dish Weight - Dish Weight) % Dry Solids ((Dry Weight / Wet Weight) x 100) Evaporating Dish # (2,3 *Note -Differences should agree within 4% or 0.5 mg, which ever is less Revised 9/26/19 JDW Time on water bath Time in oven Time out of oven Time weighed Sample # Wet Weight + Dish Weight Dish Weight Wet Weight 1st Dry Weight + Dish Weight 2nd Dry Weight + Dish Weight Difference in 1st & 2nd Dry Weight + Dish Weight (2nd - 1st) Dry Weight (2nd Dry Weight + Dish Weight - Dish Weight) % Dry Solids ((Dry Weight / Wet Weight) x 100) 1st 2nd IC4-n 11:1aii a-Zt kAS— ichty a, ,i13 Evaporating Dish # S1' - Name Sampled By Received By Analyzed By Calculated By Checked By CITY OF V). ,HINGTON SLUDGE Standard Methods 2540 G-2011(Aqueous) Date/Time PIP z n Sample # Evaporating Dish # Wet Weight + Dish Weight Dish Weight Wet Weight 1st Dry Weight + Dish Weight 2nd Dry Weight + Dish Weight Difference in 1st & 2nd Dry Weight + Dish Wei. ht (2nd - 1st) Dry Weight (2nd Dry Weight + Dish Weight - Dish Weight) % Dry Solids ((Dry Weight / Wet Weight) x 100) "Note -Differences should agree within 4% or 0.5 mg, which ever is less Revised 9/26/19 JDW Time on water bath Time in oven Time out of oven Time weighed Sample # 3 Wet Weight + Dish Weight Dish Weight Wet Weight 1st Dry Weight + Dish Weight 2nd Dry Weight + Dish Weight Difference in 1st & 2nd Dry Weight + Dish Weight (2nd - 1st) Dry Weight (2nd Dry Weight + Dish Weight - Dish Weight) % Dry Solids ((Dry Weight / Wet Weight) x 100) 1003 jY\ 2nd 1 ao Evaporating Dish # cs £. 2 0.3 c Sampled By Received By Analyzed By Calculated By Checked By Sample # Wet Weight + Dish Weight Dish Weight Wet Weight 1st Dry Weight + Dish Weight 2nd Dry Weight + Dish Weight Difference in 1st & 2nd Dry Weight + Dish Wei • ht (2nd - 1st) Dry Weight (2nd Dry Weight + Dish Weight - Dish Weight) % Dry Solids ((Dry Weight / Wet Weight) x 100) CITY OF V4. ,HINGTON SLUDGE Standard Methods 2540 G-2011(Aqueous) Date/Time Ii-1- - 45 Evaporating Dish # is 3 4- Li' ° 7 32 *Note -Differences should agree within 4% or 0.5 mg, which ever is Tess Revised 9/26/19 JDW Time on water bath Time in oven Time out of oven Time weighed Sample # Wet Weight + Dish Weight Dish Weight Wet Weight 1st Dry Weight + Dish Weight 2nd Dry Weight + Dish Weight Difference in 1st & 2nd Dry Weight + Dish Wei. ht (2nd - 1st) Dry Weight (2nd Dry Weight + Dish Weight - Dish Weight) % Dry Solids ((Dry Weight / Wet Weight) x 100) 1st 9ai (0 lvn3 ( a) illy Iso(o 2nd mils i31$ /2,XC Evaporating Dish # Sampled By Received By Analyzed By Calculated By Checked By Sample # Name Palk; 5- Wet Weight + Dish Weight Dish Weight Wet Weight 1st Dry Weight + Dish Weight 2nd Dry Weight + Dish Weight Difference in 1st & 2nd Dry Weight + Dish Wei ht (2nd - 1st) Dry Weight (2nd Dry Weight + Dish Weight - Dish Weight) % Dry Solids ((Dry Weight / Wet Weight) x 100) CITY OF VII. ,,HINGTON SLUDGE Standard Methods 2540 G-2011(Aqueous) Date/Time q C)C�Ce f 'c Evaporating Dish # d�a130, o Time on water bath Time in oven Time out of oven Time weighed Sample # Wet Weight + Dish Weight Dish Weight 2ti " 02, 5— Wet Weight 1st Dry Weight + Dish Weight *Note -Differences should agree within 4% or 0.5 mg, which ever is less Revised 9/26/19 JDW 2nd Dry Weight + Dish Weight Difference in 1st & 2nd Dry Weight + Dish Wei ht (2nd - 1st) Dry Weight (2nd Dry Weight + Dish Weight - Dish Weight) % Dry Solids ((Dry Weight / Wet Weight) x 100) 1st 2nd 0 C'�z 3 7(U icn> i �G(. Evaporating Dish # Name Sampled By Received By Analyzed By Calculated By Checked By Sample # Wet Weight + Dish Weight Dish Weight Wet Weight 1st Dry Weight + Dish Weight 2nd Dry Weight + Dish Weight Difference in 1st & 2nd Dry Weight + Dish Wei ht (2nd - 1st) Dry Weight (2nd Dry Weight + Dish Weight - Dish Weight) % Dry Solids ((Dry Weight / Wet Weight) x 100) CITY OF W. ,HINGTON SLUDGE Standard Methods 2540 G-2011(Aqueous) Date/Time 11-r-ai 9s Evaporating Dish # / 2 7 5-00. a?3`,3.CP 03/ Time on water bath Time in oven Time out of oven Time weighed Sample # Wet Weight + Dish Weight Dish Weight Wet Weight 1st Dry Weight + Dish Weight SS 2nd Dry Weight + Dish Weight *Note -Differences should agree within 4% or 0.5 mg, which ever is Tess Revised 9/26/19 JDW Difference in 1st & 2nd Dry Weight + Dish Wei ht (2nd - 1st) Dry Weight (2nd Dry Weight + Dish Weight - Dish Weight) % Dry Solids ((Dry Weight / Wet Weight) x 100) 1st 2nd /l3q�y+ co y o I,1 SS 1.3/3 MAO Evaporating Dish # Sampled By Received By Analyzed By Calculated By Checked By Sample # 1 Name ®i :--1) f iFc CITY OF Vb. .)HINGTON SLUDGE Standard Methods 2540 G-2011(Aqueous) Date/Time 035— 11-'5 21, 1134 ///r�� / /.20(a 1st 2nd Time on water bath //39 ( Time in oven I O0 3 ('i) ! 13- i $ Time out of oven ,/c 1. 31g Time weighed / ot; 1 1-i AO Wet Weight + Dish Weight Dish Weight Wet Weight 1st Dry Weight + Dish Weight 2nd Dry Weight + Dish Weight Difference in 1st & 2nd Dry Weight + Dish Weight (2nd - 1st) Dry Weight (2nd Dry Weight + Dish Weight - Dish Weight) % Dry Solids ((Dry Weight / Wet Weight) x 100) Evaporating Dish # /37 /L{-1. E /01,7 o o 3 9 Ito Li,Jo, 5, *Note-Differences should agree within 4% or 0.5 mg, which ever is Tess Revised 9/26/19 JDW Sample # Wet Weight + Dish Weight Dish Weight Wet Weight 1st Dry Weight + Dish Weight 2nd Dry Weight + Dish Weight Difference in 1st & 2nd Dry Weight + Dish Weight (2nd - 1st) Dry Weight (2nd Dry Weight + Dish Weight - Dish Weight) % Dry Solids ((Dry Weight / Wet Weight) x 100) Evaporating Dish # Average Percent Volume of Sludge Weight Volatile/Weight Dry x 100 January 2021 Average R.S. 1 & 2 R.S. 3 R.S. 4 72.03% 73.63% 74.30% February 2021 Average R.S. 1 & 2 R.S. 3 R.S. 4 75.69% 73.84% 75.83% March 2021 Average R.S. 1 & 2 R.S. 3 R.S. 4 71.36% 72.23% 72.58% April 2021 Average R.S. 1 & 2 R.S. 3 R.S. 4 71.97% 72.34% 70.61 May 2021 Average R.S. 1 & 2 R.S. 3 R.S. 4 72.07% 73.08 69.08% June 2021 Average R.S. 1 & 2 R.S. 3 R.S. 4 68.67% 66.07% 69.22% July 2021 Average R.S. 1 & 2 R.S. 3 R.S. 4 65.75% 65.53% 64.81% August 2021 Average R.S. 1 & 2 R.S. 3 R.S. 4 67.22% 66.57% 64.68% September 2021 Average R.S. 1 & 2 R.S. 3 R.S. 4 68.62% 68.05% 66.92% October 2021 Average R.S. 1 & 2 R.S. 3 R.S. 4 69.13% 69.39% 63.30% November 2021 Average R.S. 1 & 2 R.S. 3 R.S. 4 71.31% 71.16% 65.38% December 2021 Average R.S. 1 & 2 R.S. 3 R.S. 4 72.83% 72.27% 66.09% January 2021 Average R.S. 1 & 2 R.S. 3 R.S. 4 72.03% 73.63% 74.30% February 2021 Average R.S. 1 & 2 R.S. 3 R.S. 4 75.69% 73.84% 75.83% March 2021 Average R.S. 1 & 2 R.S. 3 R.S. 4 71.36% 72.23% 72.58% April 2021 Average R.S. 1 & 2 R.S. 3 R.S. 4 71.97% 72.34% 70.61% May 2021 Average R.S. 1 & 2 R.S. 3 R.S. 4 72.07% 73.08% 69.08% June 2021 Average R.S. 1 & 2 R.S. 3 R.S. 4 68.67% 66.07% 69.22% July 2021 Average R.S. 1 & 2 R.S. 3 R.S. 4 65.75% 65.53% 64.81% August 2021 Average R.S. 1 & 2 R.S. 3 R.S. 4 67.22% 66.57% 64.68% September 2021 Average R.S. 1 & 2 R.S. 3 R.S. 4 68.62% 68.05% 66.92% October 2021 Average R.S. 1 & 2 R.S. 3 R.S. 4 69.13% 69.39% 63.30% November 2021 Average R.S. 1 & 2 R.S. 3 R.S. 4 71.31% 71.16% 65.38% December 2021 Average R.S. 1 & 2 R.S. 3 R.S. 4 72.83% 72.27% 66.09% AVG. 2021 Average 69.82% 73.32% 75.12% 72.06% 71.64% 71.41% 67.99% 65.36% 66.16% 67.86% 67.27% 69.28% 70.40% 3/15/21 Sample VS in 0.6982 VS out 0.549 VSFR= 47.38 3/30/21 Sample VS in 0.6982 VS out 0.541 VSFR= 49.05 11/10/21 Sample VS in 0.6982 VS out 0.536 VSFR= 50.07 11/30/21 Sample VS in 0.6982 VS out 0.543 VSFR= 48.64 NCDA&CS Agronomic Division Phone: (919) 733-2655 Website: www.ncagr.gov/agronomi/ Report No. FY21-SL032269 k5 i I"14 --- • . v. Predictive °± f' _ Soil Report Mehlich-3 Extraction )'y,iF.r' Links to Helpful Information Client: Client ID: Harvey Williamson Hunters Roost Farm Septic Service 5365 US Hwy 17 N Washington, NC 27889 Sampled County : Beaufort 282102 Advisor: Brent Collins EMA Resources Inc 755 Yadkinville Rd Mocksville, NC 27028 Advisor ID: 405413 Sampled: Received: 05/12/2021 Completed: 05/24/2021 Farm: BF210 Sample ID: 00002 Lime History: Recommendations: Lime Nutrients (lb/acre) More Information Note: 3 Crop (tons/acre) N P2O5 1 -Soybean 0.0 0 0 2 - 0.0 K2O 30 Mg S Mn Zn 0 0 0 0 Cu 0 B 0 Test Results [units - WN in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]: HM% W/V CEC BS% Ac pH P-I K-I Ca% Mg% 1.08 1.13 6.2 81 1.2 6.0 157 60 58 18 S-I 28 Mn-I 33 Soil Class: Mineral Mn-AI1 Mn-Al2 Zn-I Zn-AI 29 140 140 Cu-I 154 Na ESP SS -I NO3-N 0.1 2 Sample ID: 00006 Lime History: Recommendations: Lime Nutrients (lb/acre) More Information Note: 3 Crop (tons/acre) N P2O5 1 -Soybean 0.4 0 0 2 - 0.0 K2O 40 Mg S Mn Zn 0 0 0 0 Cu 0 B 0 Test Results [units - WN in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]: HM% W/V CEC BS% Ac pH P-I K-I Ca% Mg% 1.94 1.06 8.4 80 1.6 5.8 226 51 59 18 S-I 35 Mn-I 35 Soil Class: Mineral Mn-AI1 Mn-Al2 Zn-I Zn-AI 31 184 184 Cu-I 136 Na ESP SS -I NO3-N 0.1 1 Sample ID: 00007 Lime History: Recommendations: Lime Nutrients (lb/acre) More Information Note: 3 Crop (tons/acre) N P2O5 1 -Soybean 0.5 0 0 2 - 0.0 K2O 50 Mg S Mn Zn 0 0 0 0 Cu 0 B 0 Test Results [units - WN in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]: HM% W/V CEC BS% Ac pH P-I K-I Ca% Mg% 1.67 1.06 6.5 75 1.6 5.7 207 43 55 17 S-I 36 Mn-I 33 Soil Class: Mineral Mn-AI1 Mn-Al2 Zn-I Zn-AI 30 115 115 Cu-I 94 Na ESP SS -I NO3-N 0.1 2 North Carolina Reprogramming of the laboratory -information -management system that makes this report possible is being funded through a grant from the North Carolina Tobacco Trust Fund Commission. Thank you for using agronomic services to manage nutrients and safeguard environmental quality. - Steve Troxler, Commissioner of Agriculture Tatbariw Truk fund Coininissksn NCDA&CS Agronomic Division Phone: (919) 733-2655 Website: www.ncagr.gov/agronomi/ Report No. FY21-SL032269 Harvey Williamson Page 2 of 3 Sample ID: 00008 Lime History: Recommendations: Lime Nutrients (lb/acre) More Information Note: 3 Crop (tons/acre) N P2O5 1 -Soybean 0.5 0 0 2 - 0.0 K2O 60 Mg S 0 0 Mn Zn 0 0 Cu 0 B 0 Test Results [units - WN in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]: HM% W/V CEC BS% Ac pH P-I K-I Ca% Mg% 1.67 1.07 6.3 77 1.4 5.7 171 39 58 16 S-I 33 Mn-I 38 Soil Class: Mn-AI1 Mn-Al2 33 Mineral Zn-I Zn-AI 139 139 Cu-I 133 Na 0.1 ESP 2 SS -I NO3-N Page 1 of 1 Report No: 22-025-0821 Account No: 46245 Advisor: EMA Resources Inc 755 Yadkinville Road Mocksville NC 27028 Waypol nt.m ANALYTICAL Client: Hunters Roost Farms 7621 Whitepine Road, Richmond, VA 23237 Main 804-743-9401 ° Fax 804-271-6446 www.waypointanalytical.com Farm: BF210 Date Received: 01/25/2022 Date of Report: 01/26/2022 Lab No Field ID Sample ID Soil Class HM% W/V pH Ac P-I K-I S-I Mn-I Mn-All Mn-Al2 Zn-I Zn-Al Cu-! CEC BS% Ca% Mg% ESP Na 23545 04 MIN 1.1 5.4 1.4 48 12 31 175 0 0 108 108 70 5.0 73 61 10 1.1 0.1 23546 12 MIN 1.2 7.0 0.0 47 14 42 400 0 0 103 103 55 10.0 100 94 4 0.7 0.1 23547 15 MIN 1.3 7.6 0.0 39 15 46 481 0 0 100 100 60 20.5 100 98 2 0.4 0.1 Comment: Test result units = CEC and Na in meq/100cm3; NO3 N in mg/dm3; WA/ in g/cm3 North Carolina Division of Water Quality Certification #257, Analysis and fertility recommendations shown on this report are performed in accordance within NCDA guidelines, Analysis prepared by: Waypoint Analytical Virginia, Inc. NCDA&CS Agronomic Division Phone: (919) 733-2655 Website: www.ncagr.gov/agronomi/ Report No. FY21-SL034365 k5 i I"14 --- . va Predictive °± f' Soil Report Mehlich-3 Extraction '*'y,iF.r' Links to Helpful Information Client: Harvey Williamson Hunters Roost Farm Septic Service 5365 US Hwy 17 N Washington, NC 27889 Sampled County : Beaufort Client ID: 282102 Advisor: Brent Collins EMA Resources Inc 755 Yadkinville Rd Mocksville, NC 27028 Advisor ID: 405413 Sampled: Received: 06/21/2021 Completed: 06/28/2021 Farm: BF210 Sample ID: 00016 Lime History: Recommendations: Lime Nutrients (lb/acre) More Information Note: 3 Crop (tons/acre) N P2O5 1 -Soybean 0.0 0 0 2 - 0.0 K2O Mg S Mn Zn 40 0 0 0 0 Cu B 0 0 Test Results [units - W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]: HM% W/V CEC BS% Ac pH P-I K-I Ca% Mg% 0.66 1.14 7.8 86 1.1 6.1 424 50 67 16 S-I 45 Soil Class: Mineral Mn-I Mn-AI1 Mn-Al2 Zn-I Zn-Al 69 51 166 166 Cu-I Na ESP SS -I NO3-N 168 0.1 1 North Carolina Reprogramming of the laboratory -information -management system that makes this report possible is being funded through a grant from the North Carolina Tobacco Trust Fund Commission. Thank you for using agronomic services to manage nutrients and safeguard environmental quality. - Steve Troxler, Commissioner of Agriculture Tatbariw Truk fund Cixnmlbskm