WQ0012404_2021 Annual Report_20220228

Non -Discharge Branch Upload/Submittal Form
NORTH CAROLINA
EnWrvnmemfal Qualify
Version 2 - Revised June 23, 2020
Initial Review
Reviewer
EADS\ndthornburg
Is this submittal an application? (Excluding additional information.)*
Yes No
If not an application what is the submittal type?*
Annual Report
Residual Annual Report
Additional Information
Other
Annual Report Year* 2021
Permit Number (IR) * WQ0012404
Applicant/Permittee CF Nitrogen, Inc.
Email Notifications
Does this need review by the hydrogeologist?* Yes No
Regional Office
CO Reviewer
Admin Reviewer
Washington

Submittal Form
Project Contact Information
Please provide information on the person to be contacted by NDB Staff regarding electronic submittal, confirmation of receipt, and other correspondence.
Name*
Edmund Henriques
Email Address* Phone Number*
[e-mail] 336-288-7180
Project Information
Application/Document Type *
New (Fee Required)
Modification - Major (Fee Required)
Renewal with Major Modification (Fee
Required)
Annual Report
Additional Information
Other
Modification - Minor
Renewal
GW-59, NDMR, NDMLR, NDAR-1,
NDAR-2
Residual Annual Report
Change of Ownership
We no longer accept these monitoring reports through this portal. Please click on the link below and it will take you to the correct form.
https://edocs.deq.nc.gov/Forms/NonDischarge_Monitoring_Report
Permit Type: *
Permit Number:*
Applicant/Permittee Address*
Wastewater Irrigation
Other Wastewater
Closed -Loop Recycle
Single -Family Residence Wastewater
Irrigation
WQ0012404
Has Current Existing permit number
4 Parkway North, Suite 400, Deerfield, IL 60015
Facility Name* CF Nitrogen Site
High -Rate Infiltration
Reclaimed Water
Residuals
Other
Groundwater Remediation
Please provide comments/notes on your current submittal below.
Annual Report for Non -Discharge Injection Permit for land application of nitrogen -enriched
groundwater. Report includes annual groundwater data.
At this time, paper copies are no longer required. If you have any questions about what is required, please contact Nathaniel Thornburg
at [e-mail].
Please attach all information required or requested for this submittal to be reviewed here. *
(Application Form, Engineering Plans, Specifications, Calculations, Etc.)
Land App Annual Report CF Nitrogen 2021_With
Grou ndwater_20220228. pdf
Upload only 1 PDF document (less than 250 MB). Multiple documents must be combined into one PDF file unless file is larger
than upload limit.
19.08MB
By checking this box, I acknowledge that I understand the application will not be
accepted for pre -review until the fee (if required) has been received by the Non -
Discharge Branch. Application fees must be submitted by check or money order and
made payable to the North Carolina Department of Environmental Quality (NCDEQ).
I also confirm that the uploaded document is a single PDF with all parts of the
application in correct order (as specified by the application).
Mail payment to:
NCDEQ — Division of Water Resources
Attn: Non -Discharge Branch
1617 Mail Service Center
Raleigh, NC 27699-1617
Signature
Scei-Nuotee141;#4,6irteessf

Submission Date 2/28/2022

s
s
III
2021 Annual Report
Land Application Program
CF Nitrogen, Inc.
Permit No. WQ0012404
PREPARED FOR
CF Industries Holdings, Inc.
4 Parkway North Suite 400
Deerfield, IL 60015-2590
S&ME, Inc.
3201 Spring Forest Road
Raleigh, NC 27616
February 18, 2022

I I
February 18,2022
North Carolina Department of Environmental Quality
Division of Water Resources—UIC Program
1636 Mail Service Center
Raleigh, NC 27699-1636
Attention: Non-Discharge Permitting Unit
Reference: 2021 Annual Report
Land Application Program
CF Nitrogen, Inc.
Permit No.WQ0012404
S&ME Project No. 1040-98-044U
Non-Discharge Compliance Unit:
S&ME, Inc. (S&ME) is submitting all monitoring and reporting requirements as specified in the above referenced permit for CF
Nitrogen, Inc.S&ME compiled this report using data gathered during the compliance year.This data includes: 1) Certification
Form,2) Residual Sampling Summary Form,3)2020 Application Summary and Field Loading Rate Reports,4) Field Application
Summaries, 5) Updated Attachment B, 6) Landowner Agreement Attachments& Lessee Agreement Attachments,and 7)
Groundwater Report.
CF Nitrogen, Inc. conducted land application events on current permitted fields in Hertford and Northampton counties within
the year of 2021.A total of 14,4795,000 gallons of nitrogen-enriched groundwater were land applied.
TCLP, Pathogen and Vector Monitoring, and Soil Analysis are not included in the report as these requirements are not
required by Permit based on the permitted operation of a groundwater recovery system only.
If there is any further information required or questions regarding this land application program, please do not hesitate to
contact us for further assistance.
Sincerely,
S&ME, Inc.
erj ." . T
Edmund Q.B. Henriques, L.G. Tom Raymond, PE, PMP, RSM
Senior Geologist/Project Manager Principal Environmental Engineer/Vice President
[e-mail] [e-mail]
cc: Ms. Diane Diks, CHMM, CPEA(CF Nitrogen, Inc.)
Mr.Jay Bryant(Granville Farms)
S&ME, Inc.13201 Spring Forest Road I Raleigh, NC 27616 I p 919.872.2660 I www.smeinc.com

2021 Annual Report
&
Land Application Program
CF Nitrogen, Inc. III
S&ME Project No. Permit No.WQ0012404
TABLE OF CONTENTS:
SECTION NO. TITLE
I Annual Land Application Certification Form
II Residuals Sampling Summary and Analysis
III 2021 Application Summary and Field Loading Rate Reports
IV Field Application Summaries
V Updated Attachment B
VI Landowner Agreement Attachments&Lessee Agreement
Attachments
VII Groundwater Data
February 18, 2022 ii

2021 Annual Report
&
Land Application Program
CF Nitrogen, Inc. IIIrir
S&ME Project No. Permit No.WQ0012404
CF Nitrogen, Inc.
Ms. Diane Diks
4 Parkway North, Suite 400
Deerfield, IL 60015-2590
847-405-2400
NC PERMIT#WQ0012404
Mr.Jay Bryant
Granville Farms, Inc.
100 Farmers Chemical Road
Cofield, NC 27922
252-358-2129
LAND APPLIERS:
Granville Farms, Inc.
8229 Highway 96 North
Oxford, North Carolina 27565
919-690-8000
February 18, 2022 iii

Attachments

Annual Land Application Certification Form

ANNUAL LAND APPLICATION CERTIFICATION FORM
WQ Permit#: WQ0012404 County: Hertford Year: 2021
Facility Name(as shown on permit): CF Nitrogen,Inc.
Land Application Operator: Granville Farms,Inc. Phone: [phone]
Land application of residuals as allowed by the permit occurred during the past calendar year?
p Yes i] No -If No,skip Part A,and Part B and proceed to Part C. Also,If residuals were
generated but not land applied,please attach an explanation on how the residuals were handled.
Par3A-Residuals A+ut *.
Total number of application fields in the permit: 395
Total number of fields utilized for land application durinf the year: 19
Total amount of dry tons applied durity the year for all application sites: N/A Groundwater Recovery System
Total number of acres utilized for land application during the year: 643.0
Part 0-Annual Comuiance Statement:
Facility was compliant during calendar year 2021 with all conditions of the land application permit
(including but not limited to items 1-13 below)issued by the Division of Water Quality. (J Yes Li No
If no please,provide a written description why the facility was not compliant,the dates,and explain corrective
action taken.
1) Only residuals approved for this permit were applied to the permitted sites.
2) Soil pH was adjusted as specified in the permit and lime was applied(if needed)to achieve a soil p1-1 of at least 6.0 or
the limit specified in the permit.
3) Annual soils analysis were performed on each site receiving residuals during the past calendar year and three(3)copies
of laboratory results are attached.
4) Annual TCI.P analysis(if required)was performed and three(3)copies of certified laboratory results are attached.
5) All other monitoring was performed in accordance with the permit and reported during the year as required and three(3)
copies of certified laboratory results are attached.
6)The facility did not exceed any of the Pollutant Concentration Limits in 15A NCAC 02T.1105(a)or the Pollutant
Loading Rates in 15A NCAC 02T.1105(b)(applicable to 40 CFR Part 503 regulated facilities).
7)All general requirements in as specified in the Land Application Permit were complied with(applicable to 40 CFR Part
503 regulated facilities).
8)All monitoring and reporting requirements in 15A NCAC 02'1'.1111 were complied with(applicable to 40 CFR Part
503 regulated facilities).
9)All operations and maintenance requirements in the permit were complied with or,in the case of a deviation, prior
authorization was received from the Division of Water Quality.
10) No contravention of Ground Water Quality Standards occurred at a monitoring well or explanations of violations are
attached to include appropriate actions and remediations.
11) Vegetative cover was maintained and proper crop management was performed on each site receiving residuals,as
specified in the permit.
12) No runoff of residuals from the application sites onto adjacent property or nearby surface waters has occurred.
13) All buffer requirements as specified on the permit were maintained during each application of residuals.
Part C-Certificatiogi;,
"I certify,under penalty of law,that the above information is,to the best of my knowledge and belief,true,accurate,
and complete.I am aware that there are significant penalties for submitting false information,including the
possibility of fines and imprisonment for knowing violations."
Ashraf Malik,Sr,VP,Manufacturing&Distribution P"O - Z/25 22 Z
Permittee Name and Title(type or print) Signature of Permittee Date
�.✓�..�.�Q m. ..=6\47,-.-7-r-- 2/ /Lo 2_"2_
2/19./2O22
Signature of Preparer* Date Signa ure Lan pplier Date
Edmund Henriques,S&ME,Inc. Jay Bryant,Granville Farms,Inc.
*Preparer is defined in 40 CFR Part 503.9(r)and 1 SA NCAC 02T.1102(26)
DENR FORM ACF(12/2006)

ANNUAL RESIDUAL SAMPLING SUMMARY FORM-B
Report all sampling analysis results for parameters not listed in FORM RSSF that are part of the WQ permit or were analyzed for over the past calendar year. Use additional forms as needed.
WQ Permit Number: WQ0012404 Laboratory: 1)Waypoint Analytical(January 2021)
Facility Name: CF Nitrogen,Inc. 2)Pace Analytical(April,July,October 2021)
NPDES#or WQ#:NA 3)
Name Nitrogen-Enriched Groundwater Recovery System
RESIDUAL ANALYSIS DATA
Date Sampled(grab)or Date 1/21/2021 4/29/2021 7/15/2021 10/25/2021
Composited
Percent Solids NA N/A N/A N/A
PARAMETERS(mg/L dry weight)
TKN 244 263 186 259
Ammonia-Nitrogen 244 260 174 244
Nitrate-Nitrogen 275 254 186 244
Total Phosphorus 2.66 2.44 2.3 3.1
Aluminum 0.863 0.600 0.475 0.330
Calcium 59.6 58.9 47.8 50.8
Magnesium 17.6 17.3 15.8 15.6
Potassium 32.0 34.0 32.6 33.3
pH 7.1 7.1 6.7 6.8
Sodium 34.3 32.8 30.1 30.1
X 2/19/2022
Signature of Preparer Date
"I certify,under penalty of law,that this document was prepared under my direction or supervision in accordance
with a system designed to assure that qualified personnel properly gathered and evaluated the information
submitted. I am aware that there are significant penalties for submitting false information,including the possibility
of fines and imprisonment for knowing violations."

Residuals Sampling Summary and Analysis

VS/aypoint - 7621 Whitepine Road,Richmond,VA 23237
Main 804-743-9401 o Fax [phone]
ANALYTICAL www.waypointanalyticalcom
Sample Summary Table
Report Number: 21-022-0005
Client Project Description: CF Nitrogen Inc.
Lab No Client Sample ID Matrix Date Collected Date Received Method Lab ID
74763 097494 Aqueous 01/21/2021 10:00 01/22/2021
74763 097494 Aqueous 01/21/2021 10:00 01/22/2021 6010D WP MTN
WP MTN-Memphis,TN: Waypoint Analytical-TN,Memphis,TN
Page 1 of 3

Report Number W°
•
21-022-0005
Waypoint^ 7621 Whitepine Road,Richmond,VA 23237
Account Number Main 804-743-9401°Fax [phone]
46260 ANALYTICAL www.waypointanalytical.com
Send To: CF Industries
Diane Diks
100 Farmers Chemical Rd
Suite 400
Cofield, NC 27922
Purchase Order: B63722
Project:CF Nitrogen Inc. Revised Report Date : 03/03/2021
Date Received: 01/22/2021
REPORT OF ANALYSIS
Date Sampled: 01/21/2021
Lab Number: 74763
Sample ID: 097494
Quantitation Date and Time
Analysis Result Limit Method Test Started Analyst
Total Solids , mg/L 330 10 SM-2540B 02/02/2021 12:00 JCM
Total Kjeldahl Nitrogen , mg/L 244 10.0 SM-4500-NH3C-TKN 02/01/2021 11:10 JCM
Phosphorus, mg/L 2.66 0.100 6010D 01/29/2021 02:38 JADS
Potassium , mg/L 32.0 1.00 6010D 01/29/2021 18:04 TJS
Sulfur, mg/L 177 0.100 6010D 01/29/2021 02:38 JADS
Calcium , mg/L 59.6 0.500 6010D 01/29/2021 02:38 JADS
Magnesium , mg/L 17.6 0.100 6010D 01/29/2021 02:38 JADS
Sodium, mg/L 34.3 0.500 6010D 01/29/2021 02:38 JADS
Iron, mg/L <0.100 0.100 6010D 01/29/2021 02:38 JADS
Aluminum, mg/L 0.863 0.100 6010D 01/29/2021 02:38 JADS
Manganese, mg/L 1.32 0.010 6010D 01/29/2021 02:38 JADS
Zinc, mg/L 0.103 0.020 6010D 01/29/2021 02:38 JADS
Ammonia Nitrogen, mg/L 244 2.00 SM-4500-NH3C 02/01/2021 11:00 JCM
Nitrate+Nitrite-N , mg/L 275 100 4500NO3F-2011 02/02/2021 12:45 BW1
1plq/i r Pit 6Yoar
Pauric Mc Groary Ph.D., CPAg
Page 2 of 3

Report Number W°
21-022-0005
Waypoint^ 7621 Whitepine Road,Richmond,VA 23237
Account Number Main 804-743-9401°Fax [phone]
46260 ANALYTICAL www.waypointanalytical.com
Send To: CF Industries
Diane Diks
100 Farmers Chemical Rd
Suite 400
Cofield, NC 27922
Purchase Order: B63722
Project:CF Nitrogen Inc. Revised Report Date : 03/03/2021
Date Received: 01/22/2021
REPORT OF ANALYSIS
Date Sampled: 01/21/2021
Lab Number: 74763
Sample ID: 097494
Quantitation Date and Time
Analysis Result Limit Method Test Started Analyst
pH, s.u. 7.1 9045D 02/01/2021 14:00 JCM
Method Reference:
Methods for Chemical Analysis of Water and Wastes, EPA-600/4-79-020, March 1983
Standard Methods for the Analysis of Water and Wastewater, 1997
Standard Methods for the Analysis of Water and Wastewater, 20th Ed. 1998
USEPA, SW-846, Test Methods for Evaluating Solid Wastes, Physical/Chemical Methods, 3rd Ed. Current Revision
Comments:
�plq/i r Pit 6Yoar
Pauric Mc Groary Ph.D., CPAg
Page 3 of 3

1
ace Analytical® A \ ALYTI CAL REPORT 1 �p
May 18, 2021
z
Tc
3
Ss
CF Industries
4
Sample Delivery Group: L1346852 Cn
Samples Received: 05/01/2021 5Sr
Project Number:
6
Description: CFI Qc
Site: 211218
7
GI
Report To: Diane Diks
100 Farmers Chemical Rd rAll
Suite 400
9
Cofield, NC 27922 Sc
Entire Report Reviewed By: ,, dV-
Justin Carr
Project Manager
Results relate only to the items tested or calibrated and are reported as rounded values.This test report shall not be Alb
X. reproduced,except in full,without written approval of the laboratory.Where applicable,sampling conducted by Pace
Analytical National is performed per guidance provided in laboratory standard operating procedures ENV-SOP-MTJL-0067 and lit
ENV-SOP-MTJL-0068.Where sampling conducted by the customer,results relate to the accuracy of the information provided,
and as the samples are received.
NW 11114
) el.. ". 11..M111111.1111‘. . ..6•-• 411.1.11111111111"' ilila
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114914 IIII 14.1 .121.1raimw dji. dr Illie
a
Pace Analytical National
12065 Lebanon Rd Mount Juliet, TN 37122 615-758-5858 800-767-5859 www.pacenational.com
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
CF Industries L1346852 05/18/2110:52 1 of 15

TABLE OF CONTENTS
Cp: Cover Page 1
Cp
Tc: Table of Contents 2
Ss:Sample Summary 3 'Tc
Cn:Case Narrative 4
Sr:Sample Results 5 3Ss
101693 L1346852-01 5 4
Cn
Qc: Quality Control Summary 6
Wet Chemistry by Method 350.1 6 5Sr
Wet Chemistry by Method 351.2 8
Wet Chemistry by Method 353.2 9 L Qc]
Wet Chemistry by Method 365.4 10 7
GI
Wet Chemistry by Method 4500H+ B-2011 11
Metals(ICP) by Method 200.7 12 8AI
GI: Glossary of Terms 13
9
AI:Accreditations&Locations 14 Sc
Sc:Sample Chain of Custody 15
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CF Industries L1346852 05/18/2110:52 2 of 15

At IA
SAMPLE SUMMARY
Collected by Collected date/time Received date/time
101693 L1346852-01 WW Jay B 04/29/2112:10 05/01/2110:00 1 Cp
Method Batch Dilution Preparation Analysis Analyst Location
date/time date/time 2
— Tc
Calculated Results WG1667698 1 05/14/2117:14 05/14/2117:14 JER Mt.Juliet,TN
Wet Chemistry by Method 350.1 WG1665750 50 05/10/2114:06 05/10/2114:06 SL Mt.Juliet,TN
Wet Chemistry by Method 351.2 WG1665277 50 05/05/2114:38 05/06/2113:29 JER Mt.Juliet,TN
Wet Chemistry by Method 353.2 WG1667698 100 05/14/2117:14 05/14/2117:14 JER Mt.Juliet,TN
Wet Chemistry by Method 365.4 WG1664889 1 05/05/2114:38 05/06/21 05:09 SDL Mt.Juliet,TN 4
Cn
Wet Chemistry by Method 4500H+B-2011 WG1665903 1 05/07/21 02:29 05/07/21 02:29 WOS Mt.Juliet,TN
Metals(ICP)by Method 200.7 WG1665009 1 05/08/21 00:22 05/10/21 22:52 EL Mt.Juliet,TN 5
Sr
L6QC]
GI
8
Al
9
SC
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
CF Industries L1346852 05/18/2110:52 3 of 15

CASE NARRATIVE
Cp
All sample aliquots were received at the correct temperature, in the proper containers,with the
appropriate preservatives, and within method specified holding times, unless qualified or notated within 2
the report. Where applicable, all MDL(LOD) and RDL(LOQ)values reported for environmental samples Tc
have been corrected for the dilution factor used in the analysis. All Method and Batch Quality Control
are within established criteria except where addressed in this case narrative, a non-conformance form 3
or properly qualified within the sample results. By my digital signature below, I affirm to the best of my Ss
knowledge, all problems/anomalies observed by the laboratory as having the potential to affect the
quality of the data have been identified by the laboratory, and no information or data have been 4
knowingly withheld that would affect the quality of the data. Cn
Sr
5
L5QC]
GI
Justin Carr 8A1
Project Manager
9
SC
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
CF Industries L1346852 05/18/2110:52 4 of 15

101693 SAMPLE RESULTS - 01
Collected date/time: 04/29/21 12:10 L1346852
Calculated Results
Result Qualifier RDL Dilution Analysis Batch Cp
Analyte mg/I mg/I date/time
2
Total Nitrogen 517 10.0 1 05/14/202117:14 WG1667698 Tc
Wet Chemistry by Method 350.1 3Ss
Result Qualifier RDL Dilution Analysis Batch
Analyte mg/I mg/I date/time 4Cn
Ammonia Nitrogen 260 12.5 50 05/10/202114:06 WG1665750
5
Wet Chemistry by Method 351.2 Sr
Result Qualifier RDL Dilution Analysis Batch [QC]
Analyte mg/I mg/I date/time
Kjeldahl Nitrogen,TKN 263 12.5 50 05/06/202113:29 WG1665277
GI
Wet Chemistry by Method 353.2
Result Qualifier RDL Dilution Analysis Batch 8Al
Analyte mg/I mg/I date/time
Nitrate-Nitrite 254 10.0 100 05/14/202117:14 WG1667698 9
Sc
Wet Chemistry by Method 365.4
Result Qualifier RDL Dilution Analysis Batch
Analyte mg/I mg/I date/time
Phosphorus,Total 2.44 0.100 1 05/06/2021 05:09 WG1664889
Wet Chemistry by Method 4500H+ B-2011
Result Qualifier Dilution Analysis Batch
Analyte su date/time
pH 7.12 18 1 05/07/202102:29 WG1665903
Sample Narrative:
L1346852-01 WG1665903:7.12 at 20.8C
Metals (ICP) by Method 200.7
Result Qualifier RDL Dilution Analysis Batch
Analyte mg/I mg/I date/time
Aluminum 0.600 0.200 1 05/10/202122:52 WG1665009
Calcium 58.9 1.00 1 05/10/202122:52 WG1665009
Magnesium 17.3 1.00 1 05/10/202122:52 WG1665009
Potassium 34.0 1.00 1 05/10/202122:52 WG1665009
Sodium 32.8 1.00 1 05/10/202122:52 WG1665009
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CF Industries L1346852 05/18/21 10:52 5 of 15

WG1665750 QUALITY CONTROL SUMMARY
Wet Chemistry by Method 350.1 L1346852-01
Method Blank (MB) 1 Cp
R3652537-1 05/10/2112:21
MB Result MB Qualifier MB MDL MB RDL 2
Analyte mg/I mg/I mg/I Tc
Ammonia Nitrogen U 0.117 0.250
3
Ss
L1346500-01 Original Sample (OS) • Duplicate (DUP) 4
(OS)L1346500-01 05/10/2112:31•(DUP)R3652537-6 05/10/2112:33 Cn
Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD 5
Limits
Sr
Analyte mg/I mg/I
Ammonia Nitrogen ND ND 1 0.000 10 6
Qc
Sample Narrative:
OS:Sample stored at improper temp.for prored at improper temp.for prolonged period of time. GI
8
L1346851-02 Original Sample (OS) • Duplicate (DUP) Al
(OS)L1346851-02 05/10/2113:41•(DUP)R3652537-10 05/10/2113:43
9
Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD SC
Limits
Analyte mg/I mg/I
Ammonia Nitrogen ND ND 1 0.000 10
Laboratory Control Sample (LCS)
(LCS)R3652537-2 05/10/2112:23
Spike Amount LCS Result LCS Rec. Rec.Limits LCS Qualifier
Analyte mg/I mg/I
Ammonia Nitrogen 7.50 7.30 97.4 90.0-110
L1344035-01 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS)L1344035-01 05/10/2112:26•(MS)R3652537-3 05/10/2112:28•(MSD)R3652537-4 05/10/2112:30
Spike Amount Original Result MS Result MSD Result MS Rec. MSD Rec. Dilution Rec.Limits MS Qualifier MSD Qualifier RPD RPD Limits
Analyte mg/I mg/I mg/I mg/I
Ammonia Nitrogen 5.00 ND 4.70 4.92 94.0 98.4 1 90.0-110 4.61 10
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WG1665750 QUALITY CONTROL SUMMARY
Wet Chemistry by Method 350.1 L1346852-01
L1346851-01 Original Sample (OS) • Matrix Spike (MS) 1 Cp
L1346851-01 05/10/21 12:58•(MS)R3652537-9 05/10/2113:39
Spike Amount Original Result MS Result MS Rec. Dilution Rec.Limits MS Qualifier 2
Analyte mg/I mg/I mg/I % % Tc
Ammonia Nitrogen 5.00 ND 4.80 95.9 1 90.0-110
3
SS
4
Cn
5
Sr
6
QC
7
GI
8
Al
9
SC
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
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WG1665277 QUALITY CONTROL SUMMARY
Wet Chemistry by Method 351.2 L1346852-01
Method Blank (MB) 1 Cp
R3651390-1 05/06/2110:45
MB Result MB Qualifier MB MDL MB RDL 2
Analyte mg/I mg/I mg/I Tc
Kjeldahl Nitrogen,TKN U 0.140 0.250
3
Ss
L1345563-01 Original Sample (OS) • Duplicate (DUP) 4
(OS)L1345563-01 05/06/2110:58•(DUP)R3651390-4 05/06/2111:02 Cn
Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD 5
Limits
Sr
Analyte mg/I mg/I
Kjeldahl Nitrogen,TKN 1.96 2.06 1 4.98 20 6
Qc
L1345566-01 Original Sample (OS) • Duplicate (DUP) 7GI
(OS)L1345566-01 05/06/2111:03•(DUP)R3651390-5 05/06/2111:04
Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD 8
Limits Al
Analyte mg/I mg/I
Kjeldahl Nitrogen,TKN 0.271 0.892 1 107 P1 20 9
— Sc
Laboratory Control Sample (LCS)
(LCS)R3651390-2 05/06/2110:47
Spike Amount LCS Result LCS Rec. Rec.Limits LCS Qualifier
Analyte mg/I mg/I
Kjeldahl Nitrogen,TKN 15.2 15.2 100 75.2-121
L1345520-01 Original Sample (OS) • Matrix Spike (MS)
(OS)L1345520-01 05/06/2113:22•(MS)R3651390-3 05/06/2110:56
Spike Amount Original Result MS Result MS Rec. Dilution Rec.Limits MS Qualifier
Analyte mg/I mg/I mg/I
Kjeldahl Nitrogen,TKN 5.00 6.07 11.7 113 1 90.0-110 J5
L1345566-01 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS)L1345566-01 05/06/2111:03•(MS)R3651390-6 05/06/2111:06•(MSD)R3651390-7 05/06/2111:07
Spike Amount Original Result MS Result MSD Result MS Rec. MSD Rec. Dilution Rec.Limits MS Qualifier MSD Qualifier RPD RPD Limits
Analyte mg/I mg/I mg/I mg/I
Kjeldahl Nitrogen,TKN 5.00 0.271 5.06 6.07 95.8 116 1 90.0-110 J5 18.1 20
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
CF Industries L1346852 05/18/2110:52 8 of 15

WG1667698 QUALITY CONTROL SUMMARY
Wet Chemistry by Method 353.2 L1346852-01
Method Blank (MB) 1 Cp
R3654715-1 05/14/2116:54
MB Result MB Qualifier MB MDL MB RDL 2
Analyte mg/I mg/I mg/I Tc
Nitrate-Nitrite U 0.0500 0.100
3
Ss
L1346469-01 Original Sample (OS) • Duplicate (DUP) 4
(OS)L1346469-01 05/14/2116:59•(DUP)R3654715-3 05/14/2117:00 Cn
Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD 5
Limits
Sr
Analyte mg/I mg/I
Nitrate-Nitrite 0.474 0.496 1 4.54 20 6
Qc
L1347145-02 Original Sample (OS) • Duplicate (DUP) 7GI
(OS)L1347145-02 05/14/2117:18•(DUP)R3654715-6 05/14/2117:20
Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD 8
Limits Al
Analyte mg/I mg/I
Nitrate-Nitrite 1.16 1.17 1 0.858 20 9
Sc
Laboratory Control Sample (LCS)
(LCS)R3654715-2 05/14/2116:55
Spike Amount LCS Result LCS Rec. Rec.Limits LCS Qualifier
Analyte mg/I mg/I
Nitrate-Nitrite 2.50 2.67 107 90.0-110
L1346469-02 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS)L1346469-02 05/14/2117:02•(MS)R3654715-4 05/14/21 17:03•(MSD)R3654715-5 05/14/2117:04
Spike Amount Original Result MS Result MSD Result MS Rec. MSD Rec. Dilution Rec.Limits MS Qualifier MSD Qualifier RPD RPD Limits
Analyte mg/I mg/I mg/I mg/I
Nitrate-Nitrite 2.50 0.101 2.41 2.22 92.4 84.8 1 90.0-110 J6 8.21 20
L1347348-01 Original Sample (OS) • Matrix Spike (MS)
(OS)L1347348-01 05/14/2117:26•(MS)R3654715-7 05/14/2117:27
Spike Amount Original Result MS Result MS Rec. Dilution Rec.Limits MS Qualifier
Analyte mg/I mg/I mg/I
Nitrate-Nitrite 2.50 0.380 2.60 88.8 1 90.0-110 J6
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
CF Industries L1346852 05/18/21 10:52 9 of 15

WG1664889 QUALITY CONTROL SUMMARY
Wet Chemistry by Method 365.4 L1346852-01
Method Blank (MB) 1 Cp
R3650901-1 05/06/21 04:29
MB Result MB Qualifier MB MDL MB RDL 2
Analyte mg/I mg/I mg/I Tc
Phosphorus,Total U 0.0350 0.100
3
Ss
L1345563-01 Original Sample (OS) • Duplicate (DUP) 4
(OS)L1345563-01 05/06/21 04:45•(DUP)R3650901-3 05/06/21 04:46 Cn
Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD 5
Limits
Sr
Analyte mg/I mg/I
Phosphorus,Total 0.525 0.533 1 1.51 20 6
Qc
L1345566-01 Original Sample (OS) • Duplicate (DUP) 7GI
(OS)L1345566-01 05/06/21 04:49•(DUP)R3650901-4 05/06/21 04:50
Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD 8
Limits Al
Analyte mg/I mg/I
Phosphorus,Total 0.213 0.195 1 8.82 20 9
Sc
Laboratory Control Sample (LCS)
(LCS)R3650901-2 05/06/21 04:30
Spike Amount LCS Result LCS Rec. Rec.Limits LCS Qualifier
Analyte mg/I mg/I
Phosphorus,Total 3.16 2.93 92.9 81.2-118
L1345566-01 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS)L1345566-01 05/06/21 04:49•(MS)R3650901-5 05/06/21 04:52•(MSD)R3650901-6 05/06/21 04:53
Spike Amount Original Result MS Result MSD Result MS Rec. MSD Rec. Dilution Rec.Limits MS Qualifier MSD Qualifier RPD RPD Limits
Analyte mg/I mg/I mg/I mg/I
Phosphorus,Total 2.50 0.213 2.46 2.51 89.9 91.9 1 90.0-110 J6 2.01 20
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
CF Industries L1346852 05/18/21 10:52 10 of 15

WG1665903 QUALITY CONTROL SUMMARY
Wet Chemistry by Method 4500H+ B-2011 L1346852-01
L1343245-01 Original Sample (OS) • Duplicate (DUP) 1 Cp
L1343245-01 05/07/21 02:29•(DUP)R3651410-2 05/07/21 02:29
Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD 2
Limits
Tc
Analyte su su
pH 7.05 7.07 1 0.283 1 3
Ss
Sample Narrative:
4
OS:7.05 at20.7C Cn
DUP:7.07 at 20.6C
5
Sr
L1345977-01 Original Sample (OS) • Duplicate (DUP)
6
(OS)L1345977-01 05/07/21 02:29•(DUP)R3651410-3 05/07/21 02:29 Qc
Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD
Limits
7
Analyte su su % % GI
pH 7.39 7.42 1 0.405 1
8
Al
Sample Narrative:
OS:7.39 at20.6C 9
DUP:7.42 at 20.5C Sc
Laboratory Control Sample (LCS)
(LCS)R3651410-1 05/07/21 02:29
Spike Amount LCS Result LCS Rec. Rec.Limits LCS Qualifier
Analyte su su
pH 10.0 10.0 100 99.0-101
Sample Narrative:
LCS:10.04 at 20.2C
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
CF Industries L1346852 05/18/2110:52 11 of 15

WG1665009 QUALITY CONTROL SUMMARY
Metals (ICP) by Method 200.7 L1346852-01
Method Blank (MB) 1 Cp
R3652722-1 05/10/21 21:48
MB Result MB Qualifier MB MDL MB RDL 2
Analyte mg/I mg/I mg/I Tc
Aluminum U 0.0592 0.200
Calcium U 0.0473 1.00 3
SS
Magnesium U 0.115 1.00
Potassium U 0.313 1.00 4
Sodium U 0.444 1.00 Cn
5
Laboratory Control Sample (LCS) Sr
(LCS)R3652722-2 05/10/21 21:51 6
Spike Amount LCS Result LCS Rec. Rec.Limits LCS Qualifier Qc
Analyte mg/I mg/I
7
Aluminum 10.0 9.89 98.9 85.0-115 GI
Calcium 10.0 9.85 98.5 85.0-115
Magnesium 10.0 9.93 99.3 85.0-115 8Al
Potassium 10.0 9.58 95.8 85.0-115
Sodium 10.0 9.76 97.6 85.0-115
9
Sc
L1346441-02 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS)L1346441-02 05/10/21 21:53•(MS)R3652722-4 05/10/21 21:58•(MSD)R3652722-5 05/10/21 22:01
Spike Amount Original Result MS Result MSD Result MS Rec. MSD Rec. Dilution Rec.Limits MS Qualifier MSD Qualifier RPD RPD Limits
Analyte mg/I mg/I mg/I mg/I
Aluminum 10.0 ND 10.3 10.1 101 100 1 70.0-130 1.30 20
Calcium 10.0 40.1 50.2 49.9 101 97.7 1 70.0-130 0.656 20
Magnesium 10.0 3.40 13.4 13.2 101 98.2 1 70.0-130 1.71 20
Potassium 10.0 2.08 12.0 11.8 99.0 97.1 1 70.0-130 1.61 20
Sodium 10.0 33.6 43.3 43.0 97.2 93.6 1 70.0-130 0.823 20
L1346892-07 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS)L1346892-07 05/10/21 22:04•(MS)R3652722-6 05/10/21 22:06•(MSD)R3652722-7 05/10/21 22:08
Spike Amount Original Result MS Result MSD Result MS Rec. MSD Rec. Dilution Rec.Limits MS Qualifier MSD Qualifier RPD RPD Limits
Analyte mg/I mg/I mg/I mg/I
Aluminum 10.0 1.90 12.1 12.1 102 102 1 70.0-130 0.0349 20
Calcium 10.0 22.0 32.7 32.8 107 107 1 70.0-130 0.168 20
Magnesium 10.0 1.38 11.4 11.4 99.7 100 1 70.0-130 0.246 20
Potassium 10.0 3.08 12.9 12.9 98.1 98.5 1 70.0-130 0.306 20
Sodium 10.0 12.3 22.9 23.0 106 107 1 70.0-130 0.320 20
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
CF Industries L1346852 05/18/2110:52 12 of 15

GLOSSARY OF TERMS
Guide to Reading and Understanding Your Laboratory Report
The information below is designed to better explain the various terms used in your report of analytical results from the Laboratory. This is not Cp
intended as a comprehensive explanation,and if you have additional questions please contact your project representative.
2
Results Disclaimer-Information that may be provided by the customer,and contained within this report,include Permit Limits,Project Name, Tc
Sample ID,Sample Matrix,Sample Preservation,Field Blanks,Field Spikes,Field Duplicates,On-Site Data,Sampling Collection Dates/Times,and
Sampling Location.Results relate to the accuracy of this information provided,and as the samples are received.
Abbreviations and Definitions 3Ss
MDL Method Detection Limit.
4
ND Not detected at the Reporting Limit(or MDL where applicable). Cn
RDL Reported Detection Limit.
Rec. Recovery. 5
RPD Relative Percent Difference. Sr
SDG Sample Delivery Group.
6
U Not detected at the Reporting Limit(or MDL where applicable). Qc
Analyte The name of the particular compound or analysis performed.Some Analyses and Methods will have multiple analytes
reported.
7
If the sample matrix contains an interfering material,the sample preparation volume or weight values differ from the GI
Dilution standard,or if concentrations of analytes in the sample are higher than the highest limit of concentration that the
laboratory can accurately report,the sample may be diluted for analysis.If a value different than 1 is used in this field,the
result reported has already been corrected for this factor. 8AI
These are the target%recovery ranges or%difference value that the laboratory has historically determined as normal
Limits for the method and analyte being reported.Successful QC Sample analysis will target all analytes recovered or
duplicated within these ranges. 9
The non-spiked sample in the prep batch used to determine the Relative Percent Difference(RPD)from a quality control SC
Original Sample sample.The Original Sample may not be included within the reported SDG.
This column provides a letter and/or number designation that corresponds to additional information concerning the result
Qualifier reported.If a Qualifier is present,a definition per Qualifier is provided within the Glossary and Definitions page and
potentially a discussion of possible implications of the Qualifier in the Case Narrative if applicable.
The actual analytical final result(corrected for any sample specific characteristics)reported for your sample.If there was
no measurable result returned for a specific analyte,the result in this column may state"ND"(Not Detected)or"BDL"
Result (Below Detectable Levels).The information in the results column should always be accompanied by either an MDL
(Method Detection Limit)or RDL(Reporting Detection Limit)that defines the lowest value that the laboratory could detect
or report for this analyte.
Uncertainty Confidence level of 2 sigma.
(Radiochemistry)
A brief discussion about the included sample results,including a discussion of any non-conformances to protocol
Case Narrative(Cn) observed either at sample receipt by the laboratory from the field or during the analytical process.If present,there will
be a section in the Case Narrative to discuss the meaning of any data qualifiers used in the report.
Quality Control This section of the report includes the results of the laboratory quality control analyses required by procedure or
Summary(Qc) analytical methods to assist in evaluating the validity of the results reported for your samples.These analyses are not
being performed on your samples typically,but on laboratory generated material.
This is the document created in the field when your samples were initially collected.This is used to verify the time and
Sample Chain of date of collection,the person collecting the samples,and the analyses that the laboratory is requested to perform.This
Custody(Sc) chain of custody also documents all persons(excluding commercial shippers)that have had control or possession of the
samples from the time of collection until delivery to the laboratory for analysis.
This section of your report will provide the results of all testing performed on your samples.These results are provided
Sample Results(Sr) by sample ID and are separated by the analyses performed on each sample.The header line of each analysis section for
each sample will provide the name and method number for the analysis reported.
Sample Summary(Ss) This section of the Analytical Report defines the specific analyses performed for each sample ID,including the dates and
times of preparation and/or analysis.
Qualifier Description
J5 The sample matrix interfered with the ability to make any accurate determination;spike value is high.
J6 The sample matrix interfered with the ability to make any accurate determination;spike value is low.
P1 RPD value not applicable for sample concentrations less than 5 times the reporting limit.
T8 Sample(s)received past/too close to holding time expiration.
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
CF Industries L1346852 05/18/2110:52 13 of 15

A
ACCREDITATIONS & LOCATIONS
1
Pace Analytical National 12065 Lebanon Rd Mount Juliet, TN 37122 Cp
Alabama 40660 Nebraska N E-OS-15-05
Alaska 17-026 Nevada TN000032021-1 2
—
Arizona AZ0612 New Hampshire 2975 TC
Arkansas 88-0469 New Jersey—NELAP TN002
California 2932 New Mexico' TN00003 3
Colorado TN00003 New York 11742 Ss
Connecticut PH-0197 North Carolina Env375
Florida E87487 North Carolina' DW21704 4
Georgia NELAP North Carolina 3 41 Cn
Georgia' 923 North Dakota R-140
Idaho TN00003 Ohio—VAP CL0069 5
Illinois 200008 Oklahoma 9915 Sr
Indiana C-TN-01 Oregon TN200002
Iowa 364 Pennsylvania 68-02979 II6
Kansas E-10277 Rhode Island LA000356 L QCJ
Kentucky'6 KY90010 South Carolina 84004002
Kentucky 2 16 South Dakota n/a 7
Louisiana A130792 Tennessee'4 2006 GI
Louisiana LA018 Texas T104704245-20-18
Maine TN00003 Texas LAB0152
Maryland 324 Utah TN000032021-11
Massachusetts M-TN003 Vermont VT2006
Michigan 9958 Virginia 110033 9
Minnesota 047-999-395 Washington C847 SC
Mississippi TN00003 West Virginia 233
Missouri 340 Wisconsin 998093910
Montana CERT0086 Wyoming A2LA
A2LA—ISO 17025 1461.01 AIHA-LAP,LLC EMLAP 100789
A2LA—ISO 17025 5 1461.02 DOD 1461.01
Canada 1461.01 USDA P330-15-00234
EPA—Crypto TN00003
'Drinking Water 2 Underground Storage Tanks 3 Aquatic Toxicity "Chemical/Microbiological 5 Mold 6 Wastewater n/a Accreditation not applicable
*Not all certifications held by the laboratory are applicable to the results reported in the attached report.
*Accreditation is only applicable to the test methods specified on each scope of accreditation held by Pace Analytical.
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
CF Industries L1346852 05/18/2110:52 14 of 15

A
Company Narce/Address
Billing Information: I AnaIvEis/Container/Preservative ;Chain of Custody Page 1 of I_
E CF Industries
Diane Diks 1 Pres
100 Farmers Chemical Rd I Chk
1100 Farmers Chemical Rd -- i aceAnalytica!
S Suite 400
!
uite 40Q
Cnfield.NC 27922 Cofield,NC 27922
Report to: Email T
su17c0em5n.,nrn0
a00 a mRGp leM uu nht,hleai na 1c1w22
yDiane Diks
ee1 r► }Q 5 Yrie i nG.otlt'"1 ansnw es a[Mnawirdamrnt.nti a¢epianee of the
Project Desenption: O •r.a Tenn,ai canampn,mina ae.
^T City/State r Please Circle: to I n[1p,.rnnio.p.eri.m.cum/nubfip,.,:.neara-
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1./ _ termspdr Client r r�
Phone:[phone] Project N Lab Project N v y/�e
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CCuilected by(print): Site/Facility ID# P.O q Z 0 I._ [n __�
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w r r1 Acctnum:CFINDCNC
Collected by(signature): , k d Z O
Rush? (Lab MUST Be Notified) Quote p 0 W Y Z Tempiate:T186b05
_Same Day Five Day — p d Prelogin:P8444I1
1 _Next Day `5 Day;Rad Orly) Date Results Needed - . = PM:807-Justin Carr
Immediately _Two Day ,10 Day(Rad Only)
Packed on Ice N— Y- _Three Day No' r a 0 rr1 PB.
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Sample ID Comp/Grab 1 Matrix' Depth I Date [ rime ntrs ,•r4 N 1 Shipped Via:FedEX Ground
1 i 0 = Remeks I Sample a liab onilq
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sS-Soil AIR-Air F Filter Q- �a5 niVrlIAv'mN %C atC1Vrn r N1a r,e51u
-iv. , Sammie Receipt Checkkist
1 pH Temp roc seal Present/Intact: vNP Y N
GW-Groundwater B-Bioassay Po j+s I v M 1 50c l u h+ ph e.S ip1.OP O US COC Signed/Accurate, r .2
WW Waste Water Flow Other Bottles arrive intact: /4 N
DW-Drinking Water Correct bottles used: %4 --N
07-Other Samples returned via: + �j 2�� Sufficient volume sent: /r1 _H
Tracking p 47 N1 Q [ z IF A l stable
w UPS Fened _Courier r O pp
Resin uis ed b VOA Zero Headepace: Y
Q y:(Signature) Date: Time: Received b . Preservation Correct/Checked: C4/ N
�f - -- Trip Blank Received: Yesf No RAO screen •:a.S mR/hr: ,>j N
1 f a.C°""1 12 0 6 HC eoH
Relin r I i -7 / /M :3r7- 7BR
r_ .Date: Time: Received by:(Signature) Gj////%'( Te p "C Bottles Received: If preservation required by Login:Date/Time +
Y&-?// /3 ( O , We i H� ,4 )1 ,90 ; 1 4 �JReli 4 Is e : Signatu Date: Te: Received for lab by: natur Date: Time: Hold: Conditio i
?ALE F ED E:x �(36f>( 1- c izi i6OD NCF / OK
f

Pace Analytical Services,LLC
i ® 9800 Kincey Ave. Suite 100
aceAnalytcal
Huntersville,NC 28078
www.pacelabs.cam [phone]
July 27, 2021
Mr. Ed Henriques
S&ME, Inc.
8646 West Market Street
Suite 105
Greensboro, NC 27409
RE: Project: CF INDUSTRIES
Pace Project No.: 92550148
Dear Mr. Henriques:
Enclosed are the analytical results for sample(s) received by the laboratory on July 16, 2021. The results relate only to the
samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual,where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace Analytical Services-Asheville
A revised report is being submitted on 7/27/21 to include TKN results, per client request.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Angela Baioni
[e-mail]
[phone]
Project Manager
Enclosures
�8 ACCRFO
=�`/ o, REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
jeL_,.,
without the written consent of Pace Analytical Services,LLC. Page 1 of 22

Pace Analytical Services,LLC
i et, 9800 Kincey Ave. Suite 100
aceAnalytcal
Huntersville,NC 28078
www.paeelabs.enm [phone]
CERTIFICATIONS
Project: CF INDUSTRIES
Pace Project No.: 92550148
Pace Analytical Services Asheville
2225 Riverside Drive,Asheville, NC 28804 North Carolina Wastewater Certification#:40
Florida/NELAP Certification#: E87648 South Carolina Certification#: 99030001
North Carolina Drinking Water Certification#: 37712 VirginiaNELAP Certification#:460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
without the written consent of Pace Analytical Services,LLC. Page 2 of 22

Pace Analytical Services,LLC
et, 9800 Kincey Ave. Suite 100
aceArraiytical
Huntersville,NC 28078
www.paeelabs.enm [phone]
SAMPLE SUMMARY
Project: CF INDUSTRIES
Pace Project No.: 92550148
Lab ID Sample ID Matrix Date Collected Date Received
92550148001 103767 Water 07/15/21 12:30 07/16/21 10:34
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
without the written consent of Pace Analytical Services,LLC. Page 3 of 22

Pace Analytical Services,LLC
et, 9800 Kincey Ave. Suite 100
aceAnalytical
Huntersville,NC 28078
www.paeelabs.enm [phone]
SAMPLE ANALYTE COUNT
Project: CF INDUSTRIES
Pace Project No.: 92550148
Analytes
Lab ID Sample ID Method Analysts Reported Laboratory
92550148001 103767 EPA6010D SH1 5 PASI-A
EPA 9040C SMK 1 PASI-A
EPA 350.1 Rev 2.0 1993 NGP 1 PASI-A
EPA 351.2 Rev 2.0 1993 MFO 1 PASI-A
EPA 353.2 Rev 2.0 1993 HMH 1 PASI-A
EPA 365.1 Rev 2.0 1993 KDF1 1 PASI-A
PASI-A= Pace Analytical Services-Asheville
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
without the written consent of Pace Analytical Services,LLC. Page 4 of 22

Pace Analytical Services,LLC
i et, 9800 Kincey Ave. Suite 100
aceAnalytcal
Huntersville,NC 28078
www.paeelabs.enm [phone]
PROJECT NARRATIVE
Project: CF INDUSTRIES
Pace Project No.: 92550148
Method: EPA 6010D
Description: 6010 MET ICP
Client: S&ME-Greensboro
Date: July 27,2021
General Information:
1 sample was analyzed for EPA 6010D by Pace Analytical Services Asheville. All samples were received in acceptable condition with
any exceptions noted below or on the chain-of custody and/or the sample condition upon receipt form(SCUR)attached at the end of
this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Sample Preparation:
The samples were prepared in accordance with EPA 3010A with any exceptions noted below.
Initial Calibrations(including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank,where applicable,with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences(RPDs)were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
without the written consent of Pace Analytical Services,LLC. Page 5 of 22

Pace Analytical Services,LLC
i et, 9800 Kincey Ave. Suite 100
aceAnalytcal
Huntersville,NC 28078
www.paeelabs.enm [phone]
PROJECT NARRATIVE
Project: CF INDUSTRIES
Pace Project No.: 92550148
Method: EPA 9040C
Description: 9040 pH
Client: S&ME-Greensboro
Date: July 27,2021
General Information:
1 sample was analyzed for EPA 9040C by Pace Analytical Services Asheville. All samples were received in acceptable condition with
any exceptions noted below or on the chain-of custody and/or the sample condition upon receipt form(SCUR)attached at the end of
this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
H3:Sample was received or analysis requested beyond the recognized method holding time.
• 103767 (Lab ID:92550148001)
Method Blank:
All analytes were below the report limit in the method blank,where applicable,with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences(RPDs)were within acceptance criteria with any exceptions noted below.
Duplicate Sample:
All duplicate sample results were within method acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
without the written consent of Pace Analytical Services,LLC. Page 6 of 22

Pace Analytical Services,LLC
i et, 9800 Kincey Ave. Suite 100
aceAnalytcal
Huntersville,NC 28078
www.paeelabs.enm [phone]
PROJECT NARRATIVE
Project: CF INDUSTRIES
Pace Project No.: 92550148
Method: EPA 350.1 Rev 2.0 1993
Description: 350.1 Ammonia
Client: S&ME-Greensboro
Date: July 27,2021
General Information:
1 sample was analyzed for EPA 350.1 Rev 2.0 1993 by Pace Analytical Services Asheville. All samples were received in acceptable
condition with any exceptions noted below or on the chain-of custody and/or the sample condition upon receipt form(SCUR)attached
at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank,where applicable,with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences(RPDs)were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
without the written consent of Pace Analytical Services,LLC. Page 7 of 22

Pace Analytical Services,LLC
i et, 9800 Kincey Ave. Suite 100
aceAnalytcal
Huntersville,NC 28078
www.paeelabs.enm [phone]
PROJECT NARRATIVE
Project: CF INDUSTRIES
Pace Project No.: 92550148
Method: EPA 351.2 Rev 2.0 1993
Description: 351.2 Total Kjeldahl Nitrogen
Client: S&ME-Greensboro
Date: July 27,2021
General Information:
1 sample was analyzed for EPA 351.2 Rev 2.0 1993 by Pace Analytical Services Asheville. All samples were received in acceptable
condition with any exceptions noted below or on the chain-of custody and/or the sample condition upon receipt form(SCUR)attached
at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Sample Preparation:
The samples were prepared in accordance with EPA 351.2 Rev 2.0 1993 with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank,where applicable,with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences(RPDs)were within acceptance criteria with any exceptions noted below.
QC Batch:635898
A matrix spike and/or matrix spike duplicate(MS/MSD)were performed on the following sample(s): 92549749005,92550226003
M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample(LCS)recovery.
•MS (Lab ID:3339073)
•Nitrogen, Kjeldahl,Total
•MS (Lab ID:3339075)
•Nitrogen, Kjeldahl,Total
•MSD (Lab ID:3339074)
•Nitrogen, Kjeldahl,Total
•MSD (Lab ID:3339076)
•Nitrogen, Kjeldahl,Total
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
without the written consent of Pace Analytical Services,LLC. Page 8 of 22

Pace Analytical Services,LLC
i et, 9800 Kincey Ave. Suite 100
aceAnalytcal
Huntersville,NC 28078
www.paeelabs.enm [phone]
PROJECT NARRATIVE
Project: CF INDUSTRIES
Pace Project No.: 92550148
Method: EPA 353.2 Rev 2.0 1993
Description: 353.2 Nitrogen, NO2/NO3 pres.
Client: S&ME-Greensboro
Date: July 27,2021
General Information:
1 sample was analyzed for EPA 353.2 Rev 2.0 1993 by Pace Analytical Services Asheville. All samples were received in acceptable
condition with any exceptions noted below or on the chain-of custody and/or the sample condition upon receipt form(SCUR)attached
at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank,where applicable,with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences(RPDs)were within acceptance criteria with any exceptions noted below.
QC Batch:634791
A matrix spike and/or matrix spike duplicate(MS/MSD)were performed on the following sample(s): 92549180004,92549417003
M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample(LCS)recovery.
•MS (Lab ID:3333501)
•Nitrogen, NO2 plus NO3
•MSD (Lab ID:3333502)
•Nitrogen, NO2 plus NO3
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
without the written consent of Pace Analytical Services,LLC. Page 9 of 22

Pace Analytical Services,LLC
i et, 9800 Kincey Ave. Suite 100
aceAnalytcal
Huntersville,NC 28078
www.paeelabs.enm [phone]
PROJECT NARRATIVE
Project: CF INDUSTRIES
Pace Project No.: 92550148
Method: EPA 365.1 Rev 2.0 1993
Description: 365.1 Phosphorus,Total
Client: S&ME-Greensboro
Date: July 27,2021
General Information:
1 sample was analyzed for EPA 365.1 Rev 2.0 1993 by Pace Analytical Services Asheville. All samples were received in acceptable
condition with any exceptions noted below or on the chain-of custody and/or the sample condition upon receipt form(SCUR)attached
at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Sample Preparation:
The samples were prepared in accordance with EPA 365.1 Rev 2.0 1993 with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank,where applicable,with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences(RPDs)were within acceptance criteria with any exceptions noted below.
Additional Comments:
This data package has been reviewed for quality and completeness and is approved for release.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
without the written consent of Pace Analytical Services,LLC. Page 10 of 22

Pace Analytical Services,LLC
aceAnalytical et, 9800 Kincey Ave. Suite 100
Huntersville,NC 28078
www.paeelabs.enm [phone]
ANALYTICAL RESULTS
Project: CF INDUSTRIES
Pace Project No.: 92550148
Sample: 103767 Lab ID: 92550148001 Collected: 07/15/21 12:30 Received: 07/16/21 10:34 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6010 MET ICP Analytical Method: EPA6010D Preparation Method: EPA 3010A
Pace Analytical Services-Asheville
Aluminum 475 ug/L 100 72.0 1 07/18/21 17:32 07/20/21 22:31 7429-90-5
Calcium 47800 ug/L 100 94.2 1 07/18/21 17:32 07/20/21 22:31 7440-70-2
Magnesium 15800 ug/L 100 67.8 1 07/18/21 17:32 07/20/21 22:31 7439-95-4
Potassium 32600 ug/L 5000 3040 1 07/18/21 17:32 07/20/21 22:31 7440-09-7
Sodium 30100 ug/L 5000 611 1 07/18/21 17:32 07/20/21 22:31 7440-23-5
9040 pH Analytical Method: EPA 9040C
Pace Analytical Services-Asheville
pH at 25 Degrees C 6.7 Std. Units 0.10 0.10 1 07/19/21 15:50 H3
350.1 Ammonia Analytical Method: EPA 350.1 Rev 2.0 1993
Pace Analytical Services-Asheville
Nitrogen,Ammonia 174 mg/L 2.5 0.78 25 07/21/21 11:26 7664-41-7
351.2 Total Kjeldahl Nitrogen Analytical Method: EPA 351.2 Rev 2.0 1993 Preparation Method: EPA 351.2 Rev 2.0 1993
Pace Analytical Services-Asheville
Nitrogen, Kjeldahl,Total 186 mg/L 5.0 2.5 10 07/26/21 17:54 07/27/21 05:44 7727-37-9
353.2 Nitrogen,NO2/NO3 pres. Analytical Method: EPA 353.2 Rev 2.0 1993
Pace Analytical Services-Asheville
Nitrogen, NO2 plus NO3 186 mg/L 2.0 0.86 50 07/21/21 15:55
365.1 Phosphorus,Total Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation Method: EPA 365.1 Rev 2.0 1993
Pace Analytical Services-Asheville
Phosphorus 2.3 mg/L 0.050 0.025 1 07/22/21 10:05 07/22/21 12:05 7723-14-0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date: 07/27/2021 10:14 AM without the written consent of Pace Analytical Services,LLC. Page 11 of 22

Pace Analytical Services,LLC
aceAnalytical® 9800 Kincey Ave. Suite 100
Huntersville,NC 28078
www.pacelabs.com [phone]
QUALITY CONTROL DATA
Project: CF INDUSTRIES
Pace Project No.: 92550148
QC Batch: 634140 Analysis Method: EPA 6010D
QC Batch Method: EPA 3010A Analysis Description: 6010 MET
Laboratory: Pace Analytical Services-Asheville
Associated Lab Samples: 92550148001
METHOD BLANK: 3321932 Matrix: Water
Associated Lab Samples: 92550148001
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
Aluminum ug/L <100 100 72.0 07/20/21 21:32
Calcium ug/L <100 100 94.2 07/20/21 21:32
Magnesium ug/L <100 100 67.8 07/20/21 21:32
Potassium ug/L <5000 5000 3040 07/20/21 21:32
Sodium ug/L <5000 5000 611 07/20/21 21:32
LABORATORY CONTROL SAMPLE: 3321933
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Aluminum ug/L 5000 5110 102 80-120
Calcium ug/L 5000 5010 100 80-120
Magnesium ug/L 5000 5300 106 80-120
Potassium ug/L 5000 5240 105 80-120
Sodium ug/L 5000 5190 104 80-120
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 3330612 3330613
MS MSD
92548812001 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Aluminum ug/L ND 5000 5000 5270 5270 104 104 75-125 0 20
Calcium ug/L 3620 5000 5000 8810 8790 104 103 75-125 0 20
Magnesium ug/L 368 5000 5000 5820 5780 109 108 75-125 1 20
Potassium ug/L ND 5000 5000 6210 6190 107 107 75-125 0 20
Sodium ug/L ND 5000 5000 7950 7920 107 107 75-125 0 20
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date: 07/27/2021 10:14 AM without the written consent of Pace Analytical Services,LLC. Page 12 of 22

Pace Analytical Services,LLC
aceAnalytical® 9800 Kincey Ave. Suite 100
Huntersville,NC 28078
www.pacelabs.com [phone]
QUALITY CONTROL DATA
Project: CF INDUSTRIES
Pace Project No.: 92550148
QC Batch: 634132 Analysis Method: EPA 9040C
QC Batch Method: EPA 9040C Analysis Description: 9040 pH
Laboratory: Pace Analytical Services-Asheville
Associated Lab Samples: 92550148001
SAMPLE DUPLICATE: 3330590
92548854001 Dup Max
Parameter Units Result Result RPD RPD Qualifiers
pH at 25 Degrees C Std. Units 7.4 7.3 1 10 H3
SAMPLE DUPLICATE: 3330591
92548961001 Dup Max
Parameter Units Result Result RPD RPD Qualifiers
pH at 25 Degrees C Std. Units 6.5 6.5 0 10 H3
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date: 07/27/2021 10:14 AM without the written consent of Pace Analytical Services,LLC. Page 13 of 22

Pace Analytical Services,LLC
aceAnalytical® 9800 Kincey Ave. Suite 100
Huntersville,NC 28078
www.pacelabs.com [phone]
QUALITY CONTROL DATA
Project: CF INDUSTRIES
Pace Project No.: 92550148
QC Batch: 634656 Analysis Method: EPA 350.1 Rev 2.0 1993
QC Batch Method: EPA 350.1 Rev 2.0 1993 Analysis Description: 350.1 Ammonia
Laboratory: Pace Analytical Services-Asheville
Associated Lab Samples: 92550148001
METHOD BLANK: 3333043 Matrix: Water
Associated Lab Samples: 92550148001
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
Nitrogen,Ammonia mg/L <0.10 0.10 0.031 07/21/21 10:35
LABORATORY CONTROL SAMPLE: 3333044
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Nitrogen,Ammonia mg/L 5 5.0 99 90-110
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 3333047 3333048
MS MSD
92549481001 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Nitrogen,Ammonia mg/L 14.4 5 5 19.0 19.4 93 100 90-110 2 10
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 3333665 3333666
MS MSD
92549535001 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Nitrogen,Ammonia mg/L 0.19 5 5 4.7 4.7 90 90 90-110 0 10
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date: 07/27/2021 10:14 AM without the written consent of Pace Analytical Services,LLC. Page 14 of 22

Pace Analytical Services,LLC
et, 9800 Kincey Ave. Suite 100
aceAnalytical
Huntersville,NC 28078
www.pacelabs.com [phone]
QUALITY CONTROL DATA
Project: CF INDUSTRIES
Pace Project No.: 92550148
QC Batch: 635898 Analysis Method: EPA 351.2 Rev 2.0 1993
QC Batch Method: EPA 351.2 Rev 2.0 1993 Analysis Description: 351.2 TKN
Laboratory: Pace Analytical Services-Asheville
Associated Lab Samples: 92550148001
METHOD BLANK: 3339071 Matrix: Water
Associated Lab Samples: 92550148001
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
Nitrogen, Kjeldahl,Total mg/L <0.50 0.50 0.25 07/27/21 04:18
LABORATORY CONTROL SAMPLE: 3339072
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Nitrogen, Kjeldahl,Total mg/L 10 9.6 96 90-110
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 3339073 3339074
MS MSD
92549749005 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Nitrogen, Kjeldahl,Total mg/L 93.6 10 10 111 120 176 266 90-110 8 10 M1
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 3339075 3339076
MS MSD
92550226003 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Nitrogen, Kjeldahl,Total mg/L 1.3 10 10 8.1 8.5 67 71 90-110 5 10 M1
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date: 07/27/2021 10:14 AM without the written consent of Pace Analytical Services,LLC. Page 15 of 22

Pace Analytical Services,LLC
et, 9800 Kincey Ave. Suite 100
aceAnalytical
Huntersville,NC 28078
www.pacelabs.com [phone]
QUALITY CONTROL DATA
Project: CF INDUSTRIES
Pace Project No.: 92550148
QC Batch: 634791 Analysis Method: EPA 353.2 Rev 2.0 1993
QC Batch Method: EPA 353.2 Rev 2.0 1993 Analysis Description: 353.2 Nitrate+ Nitrite,preserved
Laboratory: Pace Analytical Services-Asheville
Associated Lab Samples: 92550148001
METHOD BLANK: 3333497 Matrix: Water
Associated Lab Samples: 92550148001
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
Nitrogen, NO2 plus NO3 mg/L <0.040 0.040 0.017 07/21/21 15:05
LABORATORY CONTROL SAMPLE: 3333498
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Nitrogen, NO2 plus NO3 mg/L 2.5 2.5 100 90-110
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 3333499 3333500
MS MSD
92549180004 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Nitrogen, NO2 plus NO3 mg/L 0.25 2.5 2.5 2.5 2.5 90 91 90-110 1 10
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 3333501 3333502
MS MSD
92549417003 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Nitrogen, NO2 plus NO3 mg/L 28.3 2.5 2.5 31.3 30.0 120 70 90-110 4 10 M1
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date: 07/27/2021 10:14 AM without the written consent of Pace Analytical Services,LLC. Page 16 of 22

Pace Analytical Services,LLC
aceAnalytical® 9800 Kincey Ave. Suite 100
Huntersville,NC 28078
www.pacelabs.com [phone]
QUALITY CONTROL DATA
Project: CF INDUSTRIES
Pace Project No.: 92550148
QC Batch: 635157 Analysis Method: EPA 365.1 Rev 2.0 1993
QC Batch Method: EPA 365.1 Rev 2.0 1993 Analysis Description: 365.1 Phosphorus,Total
Laboratory: Pace Analytical Services-Asheville
Associated Lab Samples: 92550148001
METHOD BLANK: 3335082 Matrix: Water
Associated Lab Samples: 92550148001
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
Phosphorus mg/L <0.050 0.050 0.025 07/22/21 11:55
LABORATORY CONTROL SAMPLE: 3335083
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Phosphorus mg/L 2.5 2.5 101 90-110
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 3335084 3335085
MS MSD
92549409001 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Phosphorus mg/L 4.1 2.5 2.5 6.5 6.7 97 104 90-110 2 10
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 3335086 3335087
MS MSD
92549423001 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Phosphorus mg/L 0.93 2.5 2.5 3.5 3.5 102 104 90-110 1 10
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date: 07/27/2021 10:14 AM without the written consent of Pace Analytical Services,LLC. Page 17 of 22

Pace Analytical Services,LLC
i et, 9800 Kincey Ave. Suite 100
aceAnalytcal
Huntersville,NC 28078
www.paeelabs.enm [phone]
QUALIFIERS
Project: CF INDUSTRIES
Pace Project No.: 92550148
DEFINITIONS
DF-Dilution Factor, if reported,represents the factor applied to the reported data due to dilution of the sample aliquot.
ND-Not Detected at or above adjusted reporting limit.
TNTC-Too Numerous To Count
J-Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL-Adjusted Method Detection Limit.
PQL-Practical Quantitation Limit.
RL-Reporting Limit-The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S-Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270.The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate%recovery and RPD values.
LCS(D)-Laboratory Control Sample(Duplicate)
MS(D)-Matrix Spike(Duplicate)
DUP-Sample Duplicate
RPD-Relative Percent Difference
NC-Not Calculable.
SG-Silica Gel-Clean-Up
U-Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis ofAcrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited.Contact your Pace PM for the current list of accredited analytes.
TNI-The NELAC Institute.
ANALYTE QUALIFIERS
H3 Sample was received or analysis requested beyond the recognized method holding time.
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample(LCS)recovery.
REPORT OF LABORATORY ANALYSIS
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Date: 07/27/2021 10:14 AM without the written consent of Pace Analytical Services,LLC. Page 18 of 22

Pace Analytical Services,LLC
et, 9800 Kincey Ave. Suite 100
aceAnalytical
Huntersville,NC 28078
www.paeelabs.enm [phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: CF INDUSTRIES
Pace Project No.: 92550148
Analytical
Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch
92550148001 103767 EPA 3010A 634140 EPA 6010D 634159
92550148001 103767 EPA 9040C 634132
92550148001 103767 EPA 350.1 Rev 2.0 1993 634656
92550148001 103767 EPA 351.2 Rev 2.0 1993 635898 EPA 351.2 Rev 2.0 1993 636037
92550148001 103767 EPA 353.2 Rev 2.0 1993 634791
92550148001 103767 EPA 365.1 Rev 2.0 1993 635157 EPA 365.1 Rev 2.0 1993 635228
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date: 07/27/2021 10:14 AM without the written consent of Pace Analytical Services,LLC. Page 19 of 22

Document Name: Document Revised:October 28,2020
Page 1 of 2
Sample Condition Upon Receipt(SCUR)+rca Issuing Authority.
�� a�Fr� Document No.:
5° F-CAR-05-033-Rev,07 Pace Carolinas C1ua4ity Office
•
' MechanicsviNe❑ Atlanta❑ Kernersviile❑
Laboratory receiving samples: Huntersville Raleigh❑
Asheville ❑ Eden❑ Greenwood ❑
Sample Condition Client Name: ��y project�: WO : 92550 148
Upon Receipt - -+ j`i 4-s 1✓i. - --- ._.. -- fl '
Other: Mini I 11111111111
0 Commercial Pace 92550148
Custody Seal Present? ❑Yes
No Seals Intact? ❑Yes Ilfio
patefanitialsPersan•ExaminingGontent __1
{{{{����....���� 0 Other Biological Tissue Frozen?
Bubble Bags l�(INoneYes ❑No �Fro
Bubble Wrap 77"`
Packing Material: ❑None
wet ❑Blue
ThermometI 92T064Type of Ice:
4R Gun ID:
L p j Correction Factor: Temp should be above freezing to 6°C
`1 Add/Subtract(°C) shoulds out of temp criteria.eing Samples on ice,cooling process
Cooler Temp: �"
has begun
Cooler Temp Corrected(' 1
USDA Regulated Soil( Ira water sample)
No
including Hawaii and Puerto Rico)?Des originate in quarantine zone within the United States:CA,NY,or SC(check maps)? Did samples originate from a foreign sourceaiinternationa y,
Did samples Comments/ p
Yes ❑No
IV Yes ❑No EN/A
Chain of Custody Present? ❑
VYes II Na N/A
❑Yes No N Samples Arrived within Hold Time? /A
Short Hold lime Analysis(<72 hr.)? Dyes \No EN/A 4.
Rush Turn Around Time Requested?
Yes ENO EN/A
Sufficient Volume? �� es ❑No [jN/A
Correct Containers Used? d�,Yes ❑No ON/A
•Pace Containers Used?
Kt Yes •No ❑N/A
Containers Intact? rues .�1No ON/A
Dissolved analysis:Samples Field Filtered? MI Yes ❑No ON/A
Sample Labels Match COC7 ( J
—
-Includes Date/Time/ID/Analysis Matrix: V V
EYes ONO N /A 14.
Headspace in VOA Vials(>5-6mm)? Eyes ❑No Ts N/A
Trip Blank Present?
Des ❑No ISIN/A
Trip Blank Custody Seals Present? Field Data Required? DYes ❑No
COMMENTS/SAMPLE DISCREPANCY
CLIENT NOTIFICATION/RESOLUTION
Date/Time:
Person contacted:
Date:
Project Manager SCURF Review:
Date:
Project Manager SRF Review: Page 20 of 22

Document Name: Document Revised.October 28,2020
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Project# Due pate 0�/23/21
PM:verified and within the acceptance range for preservation CLI>~��
samples.
**Ei_otto VOA,Coliform,
IOC,Oil and Grease,DR0/8015(water)DOC,LL g
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there is a discrepancy affecting North Carolina comP4iance samples,a copy of this o
Note: incorrect containers.
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Page 21 of 22

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Page 22 of 22

Pace Analytical Services,LLC
aceAnalytical® 9800 Kincey Ave. Suite 100
Huntersville,NC 28078
www.paeelabs.enm [phone]
November 18, 2021
Ed Henriques
S&ME, Inc.
8646 West Market Street
Suite 105
Greensboro, NC 27409
RE: Project: CF Nitrogen 21-1218, Phase P1
Pace Project No.: 92568626
Dear Ed Henriques:
Enclosed are the analytical results for sample(s)received by the laboratory on October 25, 2021. The results relate only to
the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual,where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace Analytical Services-Asheville
• Pace Analytical Services-Eden
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
amok,
Angela Baioni
[e-mail]
[phone]
Project Manager
Enclosures
cc: Diane Diks, CF Industries
7pQ p,C •FO
WOW, REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
without the written consent of Pace Analytical Services,LLC. Page 1 of 15

Pace Analytical Services,LLC
i et, 9800 Kincey Ave. Suite 100
aceAnalytcal
Huntersville,NC 28078
www.paeelabs.enm [phone]
CERTIFICATIONS
Project: CF Nitrogen 21-1218, Phase P1
Pace Project No.: 92568626
Pace Analytical Services Asheville
2225 Riverside Drive,Asheville, NC 28804 South Carolina Laboratory ID:99030
Florida/NELAP Certification#: E87648 South Carolina Certification#: 99030001
North Carolina Drinking Water Certification#: 37712 VirginiaNELAP Certification#:460222
North Carolina Wastewater Certification#:40
Pace Analytical Services Eden
205 East Meadow Road Suite A, Eden, NC 27288 North Carolina Wastewater Certification#:633
North Carolina Drinking Water Certification#: 37738 VirginiaNELAP Certification#:460025
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
without the written consent of Pace Analytical Services,LLC. Page 2 of 15

Pace Analytical Services,LLC
et, 9800 Kincey Ave. Suite 100
aceAnalytical
Huntersville,NC 28078
www.paeelabs.enm [phone]
SAMPLE ANALYTE COUNT
Project: CF Nitrogen 21-1218, Phase P1
Pace Project No.: 92568626
Analytes
Lab ID Sample ID Method Analysts Reported Laboratory
92568626001 CF Nitrogen EPA 350.1 Rev 2.0 1993 SRS 1 PASI-E
EPA 6010D RDT 5 PASI-A
EPA 9040C SMK 1 PASI-A
TKN+NO3+NO2 Calculation DMN 1 PASI-A
EPA 351.2 Rev 2.0 1993 MFO 1 PASI-A
EPA 353.2 Rev 2.0 1993 KDF1 1 PASI-A
EPA 365.1 Rev 2.0 1993 MDW 1 PASI-A
PASI-A= Pace Analytical Services-Asheville
PASI-E= Pace Analytical Services-Eden
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
without the written consent of Pace Analytical Services,LLC. Page 3 of 15

Pace Analytical Services,LLC
et, 9800 Kincey Ave. Suite 100
aceAnalytical
Huntersville,NC 28078
www.paeelabs.enm [phone]
ANALYTICAL RESULTS
Project: CF Nitrogen 21-1218, Phase P1
Pace Project No.: 92568626
Sample: CF Nitrogen Lab ID: 92568626001 Collected: 10/25/21 11:30 Received: 10/25/21 16:37 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
350.1 Ammonia EDN Analytical Method: EPA 350.1 Rev 2.0 1993
Pace Analytical Services-Eden
Nitrogen,Ammonia 244 mg/L 5.0 50 10/26/21 15:41 7664-41-7
6010 MET ICP Analytical Method: EPA6010D Preparation Method: EPA 3010A
Pace Analytical Services-Asheville
Aluminum 330 ug/L 100 1 10/28/21 10:05 11/02/21 18:20 7429-90-5
Calcium 50800 ug/L 100 1 10/28/21 10:05 11/02/21 18:20 7440-70-2
Magnesium 15600 ug/L 100 1 10/28/21 10:05 11/02/21 18:20 7439-95-4
Potassium 33300 ug/L 5000 1 10/28/21 10:05 11/02/21 18:20 7440-09-7
Sodium 30100 ug/L 5000 1 10/28/21 10:05 11/02/21 18:20 7440-23-5
9040 pH Analytical Method: EPA 9040C
Pace Analytical Services-Asheville
pH at 25 Degrees C 6.8 Std. Units 0.10 1 11/07/21 16:48 H3
Total Nitrogen Calculation Analytical Method:TKN+NO3+NO2 Calculation
Pace Analytical Services-Asheville
Total Nitrogen 502 mg/L 0.52 1 11/18/21 13:40
351.2 Total Kjeldahl Nitrogen Analytical Method: EPA 351.2 Rev 2.0 1993 Preparation Method: EPA 351.2 Rev 2.0 1993
Pace Analytical Services-Asheville
Nitrogen, Kjeldahl,Total 259 mg/L 25.0 50 11/16/21 19:20 11/17/21 10:25 7727-37-9
353.2 Nitrogen,NO2/NO3 pres. Analytical Method: EPA 353.2 Rev 2.0 1993
Pace Analytical Services-Asheville
Nitrogen, NO2 plus NO3 244 mg/L 4.0 100 11/01/21 14:04
365.1 Phosphorus,Total Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation Method: EPA 365.1 Rev 2.0 1993
Pace Analytical Services-Asheville
Phosphorus 3.1 mg/L 0.050 1 11/04/21 21:51 11/05/21 19:21 7723-14-0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date: 11/18/2021 02:02 PM without the written consent of Pace Analytical Services,LLC. Page 4 of 15

Pace Analytical Services,LLC
aceAnalytical® 9800 Kincey Ave. Suite 100
Huntersville,NC 28078
www.pacelabs.com [phone]
QUALITY CONTROL DATA
Project: CF Nitrogen 21-1218, Phase P1
Pace Project No.: 92568626
QC Batch: 655316 Analysis Method: EPA 350.1 Rev 2.0 1993
QC Batch Method: EPA 350.1 Rev 2.0 1993 Analysis Description: 350.1 Ammonia, EDN
Laboratory: Pace Analytical Services-Eden
Associated Lab Samples: 92568626001
METHOD BLANK: 3435883 Matrix: Water
Associated Lab Samples: 92568626001
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Nitrogen,Ammonia mg/L ND 0.10 10/26/21 14:57
LABORATORY CONTROL SAMPLE: 3435884
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Nitrogen,Ammonia mg/L 5 4.8 96 90-110
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 3435885 3435886
MS MSD
92566118002 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Nitrogen,Ammonia mg/L 16.4 5 5 14.5 14.5 -38 -37 90-110 0 M1
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 3435887 3435888
MS MSD
92566822001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Nitrogen,Ammonia mg/L 7.2 5 5 12.3 12.4 103 104 90-110 0
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date: 11/18/2021 02:02 PM without the written consent of Pace Analytical Services,LLC. Page 5 of 15

Pace Analytical Services,LLC
aceAnalytical® 9800 Kincey Ave. Suite 100
Huntersville,NC 28078
www.pacelabs.com [phone]
QUALITY CONTROL DATA
Project: CF Nitrogen 21-1218, Phase P1
Pace Project No.: 92568626
QC Batch: 655829 Analysis Method: EPA 6010D
QC Batch Method: EPA 3010A Analysis Description: 6010 MET
Laboratory: Pace Analytical Services-Asheville
Associated Lab Samples: 92568626001
METHOD BLANK: 3438155 Matrix: Water
Associated Lab Samples: 92568626001
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Aluminum ug/L ND 100 11/02/21 17:00
Calcium ug/L ND 100 11/02/21 17:00
Magnesium ug/L ND 100 11/02/21 17:00
Potassium ug/L ND 5000 11/02/21 17:00
Sodium ug/L ND 5000 11/02/21 17:00
LABORATORY CONTROL SAMPLE: 3438156
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Aluminum ug/L 5000 4890 98 80-120
Calcium ug/L 5000 4970 99 80-120
Magnesium ug/L 5000 4980 100 80-120
Potassium ug/L 5000 4890J 98 80-120
Sodium ug/L 5000 5430 109 80-120
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 3438157 3438158
MS MSD
92568782001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Aluminum ug/L ND 5000 5000 4920 5000 98 100 75-125 2
Calcium ug/L 14600 5000 5000 20100 20200 110 112 75-125 1
Magnesium ug/L 7020 5000 5000 12300 12400 106 108 75-125 1
Potassium ug/L ND 5000 5000 7130 7210 103 105 75-125 1
Sodium ug/L 6170 5000 5000 11600 11600 108 109 75-125 1
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date: 11/18/2021 02:02 PM without the written consent of Pace Analytical Services,LLC. Page 6 of 15

Pace Analytical Services,LLC
aceAnalytical® 9800 Kincey Ave. Suite 100
Huntersville,NC 28078
www.pacelabs.com [phone]
QUALITY CONTROL DATA
Project: CF Nitrogen 21-1218, Phase P1
Pace Project No.: 92568626
QC Batch: 658100 Analysis Method: EPA 9040C
QC Batch Method: EPA 9040C Analysis Description: 9040 pH
Laboratory: Pace Analytical Services-Asheville
Associated Lab Samples: 92568626001
SAMPLE DUPLICATE: 3449535
92569636001 Dup
Parameter Units Result Result RPD Qualifiers
pH at 25 Degrees C Std. Units 5.8 5.2 12 D6,H3
SAMPLE DUPLICATE: 3449536
92569375001 Dup
Parameter Units Result Result RPD Qualifiers
pH at 25 Degrees C Std. Units 4.0 4.0 0 H3
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date: 11/18/2021 02:02 PM without the written consent of Pace Analytical Services,LLC. Page 7 of 15

Pace Analytical Services,LLC
aceAnalytical® 9800 Kincey Ave. Suite 100
Huntersville,NC 28078
www.pacelabs.com [phone]
QUALITY CONTROL DATA
Project: CF Nitrogen 21-1218, Phase P1
Pace Project No.: 92568626
QC Batch: 660219 Analysis Method: EPA 351.2 Rev 2.0 1993
QC Batch Method: EPA 351.2 Rev 2.0 1993 Analysis Description: 351.2 TKN
Laboratory: Pace Analytical Services-Asheville
Associated Lab Samples: 92568626001
METHOD BLANK: 3459479 Matrix: Water
Associated Lab Samples: 92568626001
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Nitrogen, Kjeldahl,Total mg/L ND 0.50 11/17/21 09:08
LABORATORY CONTROL SAMPLE: 3459480
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Nitrogen, Kjeldahl,Total mg/L 10 9.7 97 90-110
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 3459481 3459482
MS MSD
92572407002 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Nitrogen, Kjeldahl,Total mg/L 45.5 10 10 58.7 62.4 132 169 90-110 6 M1
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 3459483 3459484
MS MSD
92572407005 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Nitrogen, Kjeldahl,Total mg/L 1.9 10 10 12.0 12.1 100 102 90-110 1
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date: 11/18/2021 02:02 PM without the written consent of Pace Analytical Services,LLC. Page 8 of 15

Pace Analytical Services,LLC
aceAnalytical® 9800 Kincey Ave. Suite 100
Huntersville,NC 28078
www.pacelabs.com [phone]
QUALITY CONTROL DATA
Project: CF Nitrogen 21-1218, Phase P1
Pace Project No.: 92568626
QC Batch: 656475 Analysis Method: EPA 353.2 Rev 2.0 1993
QC Batch Method: EPA 353.2 Rev 2.0 1993 Analysis Description: 353.2 Nitrate+ Nitrite,preserved
Laboratory: Pace Analytical Services-Asheville
Associated Lab Samples: 92568626001
METHOD BLANK: 3441355 Matrix: Water
Associated Lab Samples: 92568626001
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Nitrogen, NO2 plus NO3 mg/L ND 0.040 11/01/21 12:44
LABORATORY CONTROL SAMPLE: 3441356
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Nitrogen, NO2 plus NO3 mg/L 2.5 2.5 101 90-110
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 3441357 3441358
MS MSD
92568543002 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Nitrogen, NO2 plus NO3 mg/L 75.8 2.5 2.5 82.4 78.4 261 100 90-110 5 M1
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 3441359 3441360
MS MSD
92568547002 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Nitrogen, NO2 plus NO3 mg/L 0.58 2.5 2.5 3.0 3.0 95 95 90-110 0
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date: 11/18/2021 02:02 PM without the written consent of Pace Analytical Services,LLC. Page 9 of 15

Pace Analytical Services,LLC
aceAnalytical® 9800 Kincey Ave. Suite 100
Huntersville,NC 28078
www.pacelabs.com [phone]
QUALITY CONTROL DATA
Project: CF Nitrogen 21-1218, Phase P1
Pace Project No.: 92568626
QC Batch: 657623 Analysis Method: EPA 365.1 Rev 2.0 1993
QC Batch Method: EPA 365.1 Rev 2.0 1993 Analysis Description: 365.1 Phosphorus,Total
Laboratory: Pace Analytical Services-Asheville
Associated Lab Samples: 92568626001
METHOD BLANK: 3447301 Matrix: Water
Associated Lab Samples: 92568626001
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Phosphorus mg/L ND 0.050 11/05/21 19:15
LABORATORY CONTROL SAMPLE: 3447302
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Phosphorus mg/L 2.5 2.6 103 90-110
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 3447303 3447304
MS MSD
92568546001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Phosphorus mg/L 7.9 2.5 2.5 10.3 10.5 97 107 90-110 2
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 3447305 3447306
MS MSD
92568626001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Phosphorus mg/L 3.1 2.5 2.5 5.7 5.8 105 106 90-110 1
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date: 11/18/2021 02:02 PM without the written consent of Pace Analytical Services,LLC. Page 10 of 15

Pace Analytical Services,LLC
i et, 9800 Kincey Ave. Suite 100
aceAnalytcal
Huntersville,NC 28078
www.paeelabs.enm [phone]
QUALIFIERS
Project: CF Nitrogen 21-1218, Phase P1
Pace Project No.: 92568626
DEFINITIONS
DF-Dilution Factor, if reported,represents the factor applied to the reported data due to dilution of the sample aliquot.
ND-Not Detected at or above adjusted reporting limit.
TNTC-Too Numerous To Count
J-Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL-Adjusted Method Detection Limit.
PQL-Practical Quantitation Limit.
RL-Reporting Limit-The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S-Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270.The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate%recovery and RPD values.
LCS(D)-Laboratory Control Sample(Duplicate)
MS(D)-Matrix Spike(Duplicate)
DUP-Sample Duplicate
RPD-Relative Percent Difference
NC-Not Calculable.
SG-Silica Gel-Clean-Up
U-Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis ofAcrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Reported results are not rounded until the final step prior to reporting.Therefore,calculated parameters that are typically reported as
"Total"may vary slightly from the sum of the reported component parameters.
Pace Analytical is TNI accredited.Contact your Pace PM for the current list of accredited analytes.
TNI-The NELAC Institute.
ANALYTE QUALIFIERS
D6 The precision between the sample and sample duplicate exceeded laboratory control limits.
H3 Sample was received or analysis requested beyond the recognized method holding time.
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample(LCS)recovery.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date: 11/18/2021 02:02 PM without the written consent of Pace Analytical Services,LLC. Page 11 of 15

Pace Analytical Services,LLC
et, 9800 Kincey Ave. Suite 100
aceAnalytical
Huntersville,NC 28078
www.paeelabs.enm [phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: CF Nitrogen 21-1218, Phase P1
Pace Project No.: 92568626
Analytical
Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch
92568626001 CF Nitrogen EPA 350.1 Rev 2.0 1993 655316
92568626001 CF Nitrogen EPA 3010A 655829 EPA 6010D 655964
92568626001 CF Nitrogen EPA 9040C 658100
92568626001 CF Nitrogen TKN+NO3+NO2 660868
Calculation
92568626001 CF Nitrogen EPA 351.2 Rev 2.0 1993 660219 EPA 351.2 Rev 2.0 1993 660365
92568626001 CF Nitrogen EPA 353.2 Rev 2.0 1993 656475
92568626001 CF Nitrogen EPA 365.1 Rev 2.0 1993 657623 EPA 365.1 Rev 2.0 1993 657998
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date: 11/18/2021 02:02 PM without the written consent of Pace Analytical Services,LLC. Page 12 of 15

Document Name: Document Revised:October 23,2010
°
Sample Condition Upon Receipt(SCUR) Page 1 cf 2
_� aceAnal' tical Document No,:
Issuing Authority:
I F•CAR•CS-033-Rev.07 Pace Carolinas Quality Office
Laboratory receiving samples:
Asheville ❑ Eden Greenwood D Huntersville ❑ Raleigh Mechanicsviliefl AtlantaO Kernersville[r
W.Satiiptepi4ticiii-- Client a W
rE O# : 92568626
rl rirticerpM Project#:
Courier: EFed Ex ❑UPS ❑LISPS a-Client III I 1111 III
❑ Commercial ❑Pace ❑other:
92568626
Custody Seal Present? DYes pl., Seals Intact? Dyes ORIo
Date/Initials Person Examining Contents:
Packing Material: Diable Wrap ❑Bubble Bags ONone Zr Other Biolog�ic-a,�l issue Frozen?
Thermometer: Dyes l o ON/A
❑IR Gun ID: Wet ❑Blue [None
Type of Ice:
r� Correction Factor:
Cooler Temp: p`-a Add/Subtract('C) Os Tempe'ould be above freezing to 6°C
Cooler Temp Corrected VC): o
Samples ou p tem criteria,Sam es on ice,cooling process
has begun 0011 in e.
USDA Regulated soil(Zi N/A,water sample)
Did samples on ate in a quarantine zone within the United States:CA,NY,or SC(check maps)? Did samples originate from a foreign source(inte tionally,
❑Yes ENo including Hawaii and Puerto Rico)?❑Yes al o
Comments/Discrepancy:
Chain of Custody Present? [Dies ❑Na ON/A 1.
Samples Arrived within Hold Time? yes ❑Na ON/A 2.
Short Hold lime Analysis(<72 hr.)? Dyes 04 ❑N/A 3.
Rush Turn Around Time Requested? Oyes IP a ON/A 4.
Sufficient Volume? ]yes ❑Na ON/A 5.
Correct Containers Used? [Dyes ❑No ON/A 6.
-Pace Containers Used? Y s No ON/A
I." _
Containers Intact? es o ON/A 7,
Dissolved analysis:Samples Field Filtered? jr]Y No DNA _ S. •
Sample Labels Match COC? Dfes ❑No ON/A 9,
-Includes Date/Time/ID/Anal sis Matrix:
Headspace in VOA Vials(>5-6mm)? ❑Yes ❑No IA _ 10.
Trip Blank Present? Dyes zrib ❑N/A 11. —
- Trip Blank Custody Seals Present? Oyes ffft ❑N/A
COMMENTS/SAMPLE DISCREPANCY Field Data Required? ❑Yes ❑No
QD ° ; a On CDC f r SO. Col •am but- 1�• Sc ' 1 l l %30.
JS 161
Lot ID of split containers:
CLI ENT NOTIFICATION/RESOLUTION
Person contacted: Date/Time:
Project Manager SCURF Review: Date:
•
•
Project Manager SRF Review: Date:
Page 13 of 15

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I F-CAR -C33-Rev.C; F= :_- __; C-
Ze
`CI-.: rr37k tip ha i cf box is pH and/or de:11ICr i.-3;;cn r5 Fr*:t +
verifi2�ant tit:itin t;i'_ a:cep:an:a range far presar`:a:icr `4 r WV# . 9Z5 fi862fi samples. ,
Ex:e;.:ions:Y_,=,Co:ifzrns,"FCC,CO a C:=3;2,[.3,==-S(. ati l:cc,LL::; :1:1!
�LI! Date: 11/01/2i
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-5 C a_ C. - a. 0 a_ C. y` [7 e: t: lcta L' 1] �: L 1.:: ~' - VZ M m E., ~ c,
? C C C K 6 < c 7 } G i .3 H ii c ko l7
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pH Adjustment Log for Preserved Samples
ampfeID I Tipe of Presarla[lids pH upon receipt J Ca:z preservation adjusted Tme preservation Amount a Areszrra;ive
adjusted added Lot il
1 I I I
JI 1
a: INh2n2Tr tn2r2 is a discr'ponc7 e_:,r.;mart.,C3rar. ccmp!iarce;am a �'(of this form w+ll ?
i Ee;, co5" Fsent to the P,Cr;h Carolina CC'r1.NP C2rli1[a a0n
Oncc!d,in[nrrect preSarr]tive,Out of temp,incorrect containers. Orl[fl(i.e. .
Page 14 of 15

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Page 15 of 15

2021 Application Summary and Field Loading Rate Reports

2021 APPLICATION SUMMARY
CF NITROGEN,INC.
NITROGEN ENRICHED GROUNDWATER
PERMIT No. WQ0012404
NITROGEN ENRICHED GROUNDWATER SUMMARY
FARM FIELD APPL. ACRES TOTAL GAL'S./ PAN
NAME Alja` DATE UTILIZED GALLONS - ACRE (lbs/ac)
1 02 21 40.4 286,000.00 7,079.21 0.26 22.74
03-21 1,026,000.00 25,396.04 0.94 81.57
02-21 289,000.00 4,300.60 0.16 13.81
C.F.NITROGEN 2 03-21 67.2 1,440,000.00 21,428.57 1.12 97.51
Site 11
04-21 73,000.00 1,086.31 0.04 3.49
02-21 213,000.00 5,144.93 0.19 16.53
3 41.4
03-21 1,096,000.00 26,473.43 0.97 85.04
32 04-21 26.0 356,000.00 13,692.31 0.35 22.20
33 04-21 9.9 312,000.00 31,515.15 1.16 101.23
34 04-21 17.6 401,000.00 22,784.09 0.84 73.18
35 04-21 9.1 362,000.00 39,780.22 1.46 127.78
01-21 598,000.00 6,395.72 0.24 18.27
42 93.5
04-21 1,378,000.00 14,737.97 0.54 34.02
43 01-21 17.7 414,000.00 23,389.83 0.86 66.82
04-21 175,000.00 9,887.01 0.36 22.82
01-21 646,000.00 22,123.29 0.81 63.20
44 29.2
04-21 377,000.00 12,910.96 0.48 29.80
STEVEN BURGESS
Site 27 45 01-21 17 5 428,000.00 24,457.14 0.90 69.86
04-21 173,000.00 9,885.71 0.36 22.82
46 01-21 13.9 202,000.00 14,532.37 0.54 41.51
04-21 163,000.00 11,726.62 0.35 22.09
01-21 454,000.00 21,826.92 0.80 62.35
47 20.8
04-21 185,000.00 8,894.23 0.33 23.81
67 04-21 33.7 485,000.00 14,391.69 0.53 33.22
71 02-21 61.8 899,000.00 14,546.93 0.54 48.20
72 02-21 39.7 560,000.00 14,105.79 0.52 46.43
01-21 401,000.00 5,353.81 0.20 15.29
73 74.9
02-21 631,000.00 8,424.57 0.31 27.91
WILLIAM WARD,JR. 3 Q2-21 15.1 449,000.00 29,735.10 1.10 95.51
Site 33 4 02-21 13.6 323,000.00 23,750.00 0.81 70.62
TOTALS 643.0 14,795,000
LAND APPLICATIONS 2021
First Quarter 3,143,000
Second Quarter 3,650,000
Third Quarter 3,562,000
Fourth Quarter 4,440,000
Total Gallons Applied= 14,795,000
GROUNDWATER RECOVERED 2021 TO HOLDING LAGOON
First Quarter 3,020,600
Second Quarter 4,048,600
Third Quarter 3,434,700
Fourth Quarter 5,050,700
Total Gallons Recovered= 15,554,600
2/19/2022

CF INDUSTRIES, INC. - TUNIS,NORTH CAROLINA
VMSS, PLLC
Field Loading Rate Report-Nitrogen Enriched Groundwater
PERMIT# WQ0012404
OWNER: Cl'Industries
OPERATOR: Granville Farms,Inc.
RESIDUAL SOURCE: Nitrogen Enriched Groundwater
Permitted Acres: 40.40 Crop: Fescue Predominant Soil: Cr A
?i1141i' . ! 081P,M'16.WlitP5g 01!r41M-g M ')hii-N914)1SSiMMiiiig•niiM1s1'.0141Q1400)1ia
:1174.;itt.:Or Li4A.t4..00,$'m ;4;.$P,-ri8P,!.M 6i4'n:/6 ae8N. il. inliY
' 1 2Qt-21 40.40 . 286,000 7,079 0.26 22,74 0.14 2.01
Site No. 111E1EM4tIM 1,026,000 25,396 0,94 58.62 0.49 6.91
11 1111111.11111111111111
= .
111111111.1111111111111
, NMI
1111111111111111111111 MIN ,
' 111NMIIIIIMIIIIIIIIIIIMIIIIMallm
Annual'Totals 1,312,000 . 32,475 1,20 . 81.36 ', 0.63 8,92
. .. .... . ,.. . .„.
147 RYE Limit
(ths../acreiyear)
4---
scS411-
(Sig c r of Land Applier) 21DtaYL-
"i certify,under penalty of law,that this document was prepared under my direction or supervision in accordance with a system
designed to assure that qualified personnel properly gathered and evaluatert the information submitted.I am aware that there are
significant permitics for submitting talse information,including the possibility dillies and imprisonment for knowing violations."
2/16/2022

CF INDUSTRIES, INC. - TUNIS,NORTH CAROLINA
WMSS, PLLC
Field Loading Rate Report- Nitrogen Enriched Groundwater
PERMIT# WQ0012404
OWNER: CF industries
OPERATOR: Granville Farms, Inc.
RESIDUAL SOURCE Nitrogen Enriched Groundwater
Permitted Acres: 67.20 Crop: Fescue Predominant Soil: CM
0k10), I-0',01i.,W Z'NPOE',$'-' ''!! !. it....qP44a.; ar4.4CIPNism !.mAcre im mi. :004iit.C.Ojii*0,Y ,g.
,:.01/xitti:::,,,,,,6m:40"51,,,A::::: ,,,,f-iiRA:c,14 i.:,,,,,,,,,,,i,,,..,,,,**A.,A14,1,:.,:*:*,:p:,,,,,, ,,,,,,,,t(H,-:;
:i.:;..,.,-. :,.:. :,:iiii,..,..::,:,..:.:,i -; :. ....,,. :,::.:;H, ,,, ,,:i - : W .2, ! ', .,i': ::.,. ..
. . ... . -Le....-....-. —
2 - 2Qt-21_ 67,20 289,000 4,301 , 0.16 13,81 0.09 1,22
Site No. ' 3Qt-21 67,20 1,440,000 21,429 0,79 49.46 0.41 5.33
.__..
11 4Qt-21 67.20 73,000 1,086 0,04 3.36 0,03 030
. . . , . .
.._..
Annual Totals.. 1,802,000 26,815 _- 0.99 66,64 0,53 . 7.35
147 RYE Limit
(lbs./acre/year)
:Liz-7_1/11_
(Sign re of Land Applier) Date
"I certify,under penalty of law,that this document was prepared under my direction or supervision in accordance with a system
designed to assure that qualified personnel properly gathered and evaluated the information submitted,I am aware that there are
significant penalties for submitting false information,including the possibility of fines and inimisoninent for knowing violations,"
2/16/2022

CF INDUSTRIES,INC. - TUNIS,NORTH CAROLINA
WMSS,PLLC
Field Loading Rate Report-Nitrogen Enriched Groundwater
PERMIT# WQ0012404
OWNER: CF Industries
OPERATOR: Granville Farms, Inc.
RESIDUAL SOURCE: Nitrogen Enriched Groundwater
Permitted Acres: 41.40 Crop: !Fescue Predominant Soil: CrA
.
17'110_0 :': H1-,41Ii- i ., $ :NOJ.'13i,WoA*k,0Ns,. , AoiTm,. !N,,iiiiii6,ii:iowiiewl., i,
.,,,, .._H-,...,,,, ...,-.,,,. . _.,.__ ..._ ,...,,.:._..• .:i:H*„;:.,•,;:H: .;,.,.•,,,:- :,•.-::,:,:,:',
14Tua.4]m - ,it.i.ALLor.4 :, P.KRA ;',1-4',:,:. i: iiW , ,: P•tkiNf': H, 1 , *]:A1/4''' H
_ ,..„...... .
3 2Qt-21 41.,40 213,000 5,145 ft 19 .16-53 . 0.10 1,46
. , _ ... „
Site No, 3Qt-21 41,40 1,096,000 26,473 0.97 61.11 0.51 7.20
.
, .
1 ,
1 1
1
Annual rrotals 1,309,000 31„618 1.16 . 77.63 0.61 866
147 RYE Limit
(lbs./acre/year)
(Sigma ure of Land Applier) Date
"I certify,under penalty of law,that this document was prepared under my direction or supervision in accordance with a system
designed to assure that qualified personnel properly gathered and evaluated the information submitted.I am aware that there fire
significant penalties for submitting false information,including the possibility of fines and imprisonment for knowing violations,"
2/16/2022

CF:INDUSTRIES,INC. - TUNIS,NORTH CAROLINA
WMSS PLLC
Field Loading Rate Report-Nitrogen Enriched Groundwater
PERMIT WQ0012404
OWNER: Eloise T. Ward
OPERATO.R: Steven Burgess
RESIDUAL SOURCE: Nitrogen Enriched Groundwater
Permitted Acres: 26.00 Crop: Wheat Predominant Soil: BoB
MiRP81"Rgi iR.IO;;EU4O*44cOR.MMW: N411:000.40*40-0M.
Ajtiti4w W!*q
32 4Q1-21 26.00 356,000 11103133. 0.50 42,34 0.35 3.81
Site No.
27 1.1111111.11.1111111111=1111.111
4
1111.111111111
1111111111111
--
Melli
Annual Totals 356,000 .1111.1111.111111111.11= 0.35 3.81
- -
91 -RYE Limit
bs.lacre/year)
—SSA' 2.--/2-Zia-a—
(Sign re of Land Applier) Date
"1 certify,under penalty of law,that this document was prepared under my direction or supervision in accordance with a system
designed to assure that qualified personnel properly gathered and evaluated the information submitted,I am aware that there are
significant penalties for submitting false information,including the possibility of fines and imprisonment for knowing violations."
2/16/20'72

CF INDUSTRIES, INC. - TUNIS,NORTH CAROLINA
WMSS, PLLC
Field Loading Rate Report- Nitrogen Enriched Groundwater
PERMIT #WQ0012404
OWNER: Eloise T. Ward
OPERATOR: Steven Burgess
RESIDUAL SOURCE: Nitrogen Enriched Groundwater
Permitted Acres: 9.90 Crop: Wheat Predominant Soil: NoA
1IEC1)Y; NO-k.1*,M
444-/*.kPAN P
33 4Qt2l 9.90 312,000 31,515 1.16 97.44 0,82 8.76
Site No.
27
_ - - • -"-
Annual Totals 312,000 31,515 ; 97.44 0.82 ' 8.76
Sr
125 RYE Limit
(lbs./acre/year)
a46-
(Sign of Land Appl ter) Date
"I certify,under penalty of law,that this document was prepared under my direction or supervision in accordance with a system
designed to assure that qualified personnel properly gathered and evaluated the information submitted I am aware that there are
significant penalties for submitting:false information,including the possibility of fines and imprisonment for knowing violations,'
2/1 6/2022

CT INDUSTRIES, INC. - 'TUNIS, NORTH CAR( LINA
VMS ,PL.LC
Field Loading Rate Report-Nitrogen Enriched Groundwater
PERMIT 4 WQ0012444
OWNER: Eloise T. Ward
OPERATOR: Steven Burgess
RESIDUAL SOURCE: Nitrogen Enriched Groundwater
Permitted Acres: 17.60 Crop: Wheat Predominant Soil: Bel)
1ACO MONO: ;14g!..W*gi10)'WM;:;*0*(440,;5R.%**Hii Mit,A0044000.01iN
000tiid:0,:*40::$*iiii N10,0(AktaNitiOili!!H WeNN ''!Mf.dig,g*ii
34 . 4Qt-21 17,60 401,000 i 22,784 MN 70,45 0.59 6,33
Site No IIIIIIIIIIMMIMMMIIIIIIMIIIMIMMMIIII
27_. 11111111111111111.111111110111.11.1111.110111111
MIIIIIIIIMIIIIMIIIIMIIIIIIIIIUIIIIIIMI 11111111
IMIIIIIIIIMIIMIMIMIUINIIII ' NM
11111111111111MINIM
1111111.1.1 nillini
immiminimmINMININIIIIIIIIMIllIMIIIN NM
-.-
,..
Annual Totals' 40 00 1 0 MI11111.11111111 70 45 ' 0 59
'''. ' . - Igia
___ ..,_
. 91 RYE Limit
(lbs,/aerelyear)
24 2-7_1 2_ 7-
(Signatu r Land Applier) Date
"I codify,under penalty of law,that this document was prepared under my direction or supervision in accordance with a system
designed to assure that qualified personnel properly gathered and evaluated the information submitted.I am aware that there are
significant penalties thr submitting false information,including the possibility of tines and imprisonment for!mowing violations.'
2/16/2022

CF INDUSTRIES,INC. - TUNIS, NORTH CAROLINA
WIVISS, PLLC
Field Loading Rate Report- Nitrogen Enriched Groundwater
PERMIT# WQ0012404
OWNER: Eloise T. Ward
OPERATOR: Steven Burgess
RESIDUAL SOURCE: Nitrogen Enriched Groundwater
Permitted Acres: 9A0 Crop Wheat Predominant Soil: GoA
01E. ii: 0,*rri ;..g'so! $ 1! ii' ')?:01,,WI!.i,!i]. 00,Apr$SA ,J80i*!;]!gigqi'S°:4000041.t000Mr
WQ!SH' O.Iiii4i00. , 0!,0t,•4!MMHO:CO':A001li ijiii'i,kiyi V!. NifV.,g; ,! -g:,HIC
;
35 4Q1-21 9..10 362,000 39,780 1 46 _, 123.00 1.03 HOD
Site No. , ..
-)7 . .
1
- ,Annual Totals 362,000 39780 •- 123 00 1 01 11 05
-‘-
136 RYE Limit 7
(lbs./acre/year) 1
- OrT__4:5
(Signatur "Land Applier) Date
"1 certify,under penalty of law,that this document was prepared under my direction or supervision in accordance with a system
designed to assure that qualified personnel properly gathered and evaluated the information submitted.I am aware that there are
significant penalties for submitting false information,including the possibility of fines and imprisonment kir knowing violations,"
2/16/2022

CF INDUSTRIES, INC. - TUNIS, NORTH CAROLINA
WMSS, PLLC
Field Loading Rate Report - Nitrogen Enriched Groundwater
PERMIT#WQ0012404
OWNER: Neil Burgess
OPERATOR: Steven Burgess
RESIDUAL SOURCE: Nitrogen Enriched Groundwater
Permitted Acres: 93.50 Crop: Wheat Predominant Soil: Boll
42 1Qt-21 93.50 598,000 6,396 0 24 21 19 0.14 1,71
,
Site No. 4Qt-21 93.50 1,378,000 0,738 0.54 45.57 0,38 4.10
27
. _
Annual Totals 1,976,000 21,134 --- 66..76 0,52 . 5,80 102/50 RYE Limit
(lbs,./acre/year)
"sgAr— 2—
(Sig of Land Applier) Date
certify,under penalty of law,that this document was prepared under my direction or supervision in accordance with a system
designed to assure that qualified personnel properly gathered and evaluated the information submitted. am Aware that there are
significant penalties for submitting false information,including he possibility of fines and imprisonment for knowing violations."
2/16/2022

CF INDUSTRIES, INC. - TUNIS, NORTH CAROLINA
WMSS, PLLC
Field Loading Rate Report-Nitrogen Enriched Groundwater
PERMIT# WQ0912404
OWNER: Neil Burgess
OPERATOR: Steven Burgess
RESIDUAL SOURCE: Nitrogen Enriched Groundwater
Permitted Acres: 17.70 Crop: Wheat Predominant Soil: NoB
Oqii!g ftaP*]
43 I Qt-21 1770 414,000 23,390 0.86 77,49 0.52 6.25
Site No, 4Qt-21 17.70 175000 9887 0,36 30.57 0.26 , 2.75
,
27
Annual Totals 589,000 33,277 --- 108.06 0.77 8.99
'122/50 RYE Limit
(lbs./acre/year)
(Sig • - of Land Applier) Date
"I certify,under penalty of law,that this document was prepared under ny direction or supervision i9 accordance with a system
designed to assure ihat qualified personnel properly gathered and evaluated the information submitted.I am aware that there are
significant penalties for submitting false information,including the possibility of fines and imprisonment for knowing violations.'
2116/2022

CF INDUSTRIES,INC. - '.11INIS, NORTH CAROLINA
WMSS, PLLC
Field Loading Rate Report - Nitrogen Enriched Groundwater
PERMIT# WQ0012404
OWNER: Neil Burgess
OPERATOR: Steven Burgess
RESIDUAL SOURCE: Nitrogen Enriched Groundwater
Permitted Acres: 29.20 . _ Crop: Wheat Predominant Soil: Bolt
. ,. . ,. „ . . ......_.... „ . , .-... .-
1.0.WMPI;Ogn nI8V-iOSa n]l'IVITA)-M•1! :0:80MW. 0 :i]iiMNOi,i:Oii4,,-(*(A:0,) iV
. .jMM,'.0Min'ITP11104$.:0 ':'040$njg!! M-OC: Hqi?.)r*gptWiL:%I!':VMKAI
. 44 1Qt-21 29.20 i 646,000 22,l 23 0,81 73.30 0.49 , 5.91 ,
' Site No. 4Qt-21 29,20 .. 377,000 12,911 . 0.48 39,92 0.33 . 359
27 UIIIIIIIIIIIIIIIIIIIIIIIMIIII. 1 MO
nlIllIllNMIIIIIIII 1111111111111.
.111111111111=
1111111111.1 11111111111111111111111111
111111111111.11111.11 NM
IIIIIIIIIIIIM
all
1 .
Annual Totals 1,023,000 : 35,034 ' ---- ' 113,22 0.83 : 9.50
102/50 RYE Limit
(lbs.)acre/year)
(Signature of Land Applier) Dale
"I certify,under penalty of law,that his document was prepared under lily direction or supervision in accordance with a system
designed to assure that qualified personnel properly gathered and evaluated the information submitted,1 sin aware that there are
significant penalties for submitting false information,including the possibility of fines and imprisonment for knowing violations."
2/16/2022

CF INDUSTRIES, INC. - TUNIS, NORTH CAROLINA
WMSS, PLLC
Field Loading Rate Report - Nitrogen Enriched Groundwater
PERMIT# WQ0012404
OWNER: Neil Burgess
OPERATOR: Steven Burgess
RESIDUAL SOURCE: Nitrogen Enriched Groundwater
Permitted Acres: 17.50 Crop: Wheat Predominant Soil: No6
FJUTPOY,W
OnmiU11L1LD Q&LLOS n.004k8t.400 -**HR
45 1Qt-21 47.50 428,000 24,4.57 0.90 81.03 ; 0.54 6.53
Site No. 4Qt-21 . 17.50 173 000
9 886
0.36 30,57 0.26 2.75
27
- -------
Annual Totals 601 000 34 143 J ----- 111,59 , 0.80 9.28
122/50 RYE Limit
(lbs./acre/year)
24 2-74
(Sign e of Land Applier) Date
"1 certify,under penally of law,that this document was prepared under my direction or supervision in accordance with a system
designed to assure that qualified personnel properly gathered and evaluated the information submitted.I am aware that there are
significant penalties for submitting false information,including the possibility of tines and imprisonment for knowing violations,"
2/16/2022

CF INDUSTRIES, INC: - TUNIS, NORTH CAROLINA
WMSS,PLLC
Field Loading Rate Report-Nitrogen Enriched Groundwater
PERMIT# WQ0012404
OWNER: Neil Burgess
OPERATOR: Steven Burgess
RESIDUAL SOURCE: Nitrogen Enriched Groundwater
Permitted Acres: t 3.90 Crop: Wheat Predominant Soil: BoB
.1Wat!'3MWM iw4T77:77.
46 1Qt-21 , 13,90 202,000 14,532 0,54 48,15 0,32 3..88
Site No, 4Qt-21 13,90 163,000 11,727 0.43 36,26 0,30 3,26
• ,
Annual Totals 365,000 26,259 ----- 84,40 0,63 7,14
102/50 RYE Limit
(lbslacre/year)
(Si of Land Applier) Date
certify,under penalty of law,that this document was prepared under my direction or supervision in accordance with a system
designed io assure ihat qualified personnel properly gathered and evaluated the information submitted, am aware that there are
significant penalties for submitting false information.including the possibility of fines and imprisonment fix knowing violations,"
21160022

CF INDUSTRIES, INC. - TUNIS,NORTH CAROLINA
WMSS, PLLC
Field Loading Rate Report-Nitrogen Enriched Groundwater
PERMIT# WQ0012404
OWNER: Neil Burgess
OPERATOR: Steven Burgess
RESIDUAL SOURCE: Nitrogen Enriched Groundwater
Permitted Acres: 20.80 Crop: Wheat Predominant Soil: BoB
i0..?047ktXSW HAcreM
!1;!P100-4,040M MVAN.NS!i0
47 IQt-21 " 20.80 454,000 : 2 I.,827 0.80 72_31 0.48 5,83
Site No, 4Qt-21 ' 2080. 185,000 8,894 0.33 27,50 0,23 2,47
27 , .1111.111.111111111111
1111111111.1111111111111111111111111111111111
1.11111111.11
111111111
" 11.1111111111111.1111111111111111111111111111111111111111.11111.11111
Annual 3 Totals 69 30 VI 8 30•000 • 1=11/11 '102 I 50 RYE Limit
(lbsiacrelyear)
'7--
(Sig tre of Land Applies) Date
"I certify,under penalty of law,that this document was prepared under my direction or supervision in accordance with a system
designed to assure that qualified personnel properly gathered and evaluated the information submitted.I am aware that there are
significant penalties for submitting false infoimation,including the,possibility of fines and imprisonment for knowing violations."
2116/2022

CF INDUSTRIES, INC. - TUNIS, NORTH CAROLINA
WMSS, PLLC
Field Loading Rate Report - Nitrogen Enriched Groundwater
PERMIT.4 WQ0012404
OWNER: Maria Jones
OPERATOR: Steve Burgess
RESIDUAL SOURCE: Nitrogen Enriched Groundwater
Permitted Acres: 33»70 Crop; Wheat Predominant Soil: BoB
g09.4,0p,oi.*!..VA4OM
V[ZLZDMi0,80-40:*1A r:10440F)o;
67 4Qt-21 33,70 485,000 14,392 0.53 44.50 0.37 4,00
Site No.
27
" .
— .
_
Annual Totals 485,000 I 14,392 44.50 0.37 4.00
102 RYE Limit
(lbs./acre/year)
?_--2-72--
(Sign,,ore of Land Applier) Date
"1 certify,under penalty of law,that this document was prepared under my direction or supervision in accordance with a system
designed to assure that qualified personnel properly gathered and evaluated the information submitted,1 am aware that there are
significant penalties for submitting false information,including the possibility of lines and imprisonment for knowing violations,"
2/16/2022

CF INDUSTRIES, INC. - TUNIS,NORTH CAROLINA
PLLC
Field Loading Rate Report- Nitrogen Enriched Groundwater
PERMIT# WQ0012404
OWNER: William Davis
OPERATOR: Steve Burgess
RESIDUAL SOURCE: Nitrogen Enriched Groundwater
Permitted Acres: 61.80 Crop: Wheat Predominant Soil: BoB
0014)4 1] .1011•WO
ftyploAco.vM tiOijOHPAN " P
71 2Qt-21 61,80 ' 899,000 14,547 0,54 46.73 0,30 4,13
Site No,
27
. _
- 1
Annual Totals 899,000 14,547 -- 46,73 0,30 4,13
102 RYE Limit
(lbs./acre/year)
(Signatur of Land Applier) Date
'1 certify,under penalty of law,that this document was prepared under my direction or supervision in accordance with a system
designed to assure that qualified personnel properly gathered and evaluated the information submitted.I am aware that there are
significant penalties for submitting false information,including the possibility of tines and imprisonment for knowing violations,"
2/16/2022

CF INDUSTRIES, INC. - TUNIS,NORTH CAROLINA
WMSS, PLLC
Field Loading Rate Report-Nitrogen Enriched Groundwater
PERMIT if WQ0012404
OWNER: William Davis
OPERATOR: Steve Burgess
RESIDUAL SOURCE: Nitrogen Enriched Groundwater
Permitted Acres: 39.70 Crop: Wheat Predominant Soil; BoB
':1t111414)11 '4' 10A11t1ZqW4'01-14$.111A111111.111.10.TA(Mrwi (AIXO$$Hi
72 2Qt-21 39.70 560,000 14,106 0.52 45.31 0.29 4,00
Site No,
27
. .
Annual Totals 560.000 14,106 ---- 45,31 029 4.00
. ,
102 RYE Limit
Obslacre/yeat)
(Sign c of Land Applier) Date
"I certify,under penalty of law,that this document was prepared under my direction or supervision in accordance with a system
designed to assure that qualified personnel properly gathered and evaluated the information submitted.I am aware that there are
significant penalties for submitting false information,including the possibility of fines and imprisonment for knowing violations,"
2/16/2022

CF INDUSTRIES,INC - TUNIS, NORTH CAROLINA
WMSS,PLLC
Field Loading Rate Report-Nitrogen Enriched Groundwater
PERMIT#WQ0012404
OWNER: William Davis
OPERATOR: Steve Burgess
RESMUAL SOURCE: Nitrogen Enriched Groundwater
Permitted Acres: 74.90 Crop: Wheat Predominant Soil: NoA
001!), j' ii;P-AA•Mia'4tOittSn MTOTAL N ii.0004;1100ii ';PAO 'ap!MN0oi:0.0).00,m.;
VEI.Pr,WA)). ;ii;(,,,;.014;t0N$MinPAOrNCAt4 iO4!!!'4•0. !. i ;pArci ml,igrox,&
• 73 1QE-21 74,90 401,000 5,354 0,20 17,74 0.1E2 ; 1,43
Site No. 2Qt-21 , 74.90 631,000 8,425 ; 0 31 27.06 0,17 2.39
17
. _
, 11.11111 611.111
. ...... , ,
111111
Annual Totals, 1,032,000 : 13,778 ; -----; : 44.80 0.29 3,82
125 RYE Limit
(lbs./acre/year)
(Sign(ature of Land Applier) Date
"I certify,under penalty of law,that this document was prepared under my direction or supervision in accordance with a system
designed to assure that qualified personnel properly gathered and evaluated the information submitted,I am aware that there are
significant penalties for submitting false information,including the possibility of tines and imprisonment for knowing violations,"
2116/2022

CF INDUSTRIES, INC. - TUNES, NORTH CAROLINA
WMSS,PLLC
Field Loading Rate Report-Nitrogen Enriched Groundwater
PERMIT#WQ00124041
OWNER William & Nellie Ward
OPERATOR William Ward
RESIDUAL SOURCE: Nitrogen Enriched Groundwater
Permitted Acres: 15.10 Crop: Soybeans Predominant Soil: Noll
kp:8490Siin
3 2Qt-21 15.10 449,000 29,735 1,10 95.51 0.61 8.44
Site No.
33
_ . • . . .
Annual Totals 449,000 29,735 , --- 95,51 0,.61 ••• 8.44
161 RYE Limit
(lbs./acre/year)
(Signature of Land Applier) Date
"I certify,under penalty of law,that this document was prepared under my direction or supervision in accordance with a system
designed to assure that qualified personnel properly gathered and evaluated the information submitted I am aware that there are
significant penalties for submitting false information,including the possibility of fines and imprisonment for knowing violations,"
2/16/2022

Cll.INDUSTRIES, INC, - TUNIS, NORTII CAROLINA
PLLC
Field Loading Rate Report-Nitrogen Enriched Groundwater
PERMIT#W00012, 04
OWNER: & Nellie Ward
OPER,ATO.R: William Ward
RESIDUAL SOURCE: Nitrogen Enriched Groundwater
Permitted Acres: 13.60 Crop Soybeans Predominant Sod: NO
A..111:14;.1H
0A1M.
Wan 2Qt-2.1 13.60 323,000 11116,11M 0.87 : 76,29 0.48
Site No. 1111111111 111111111111111111111111111-11111111111.111111.
33
_ =NM
111=1111111111.1
MENA
111111111111101111.1111111111111111111.111
11111MIE
MUM
. _
Annual Totals' 323,000 • 23,750 :: ; 76,29 0,48 •; 6.74
. . . . . . .
161 RYE Limit
(lbs7/aere/year)
(sign, of Land Applies)
r;Z:i 1212—
"I certify,under penalty of law,that this document was prepared under my direction or supervision in accordance with a system
designed to assure that qualified personnel properly gathered and evaluated the information submitted.I am aware that there are
significant penalties for submitting false information,including the possibility of fines and imprisonment for knowing violations.'"
7/1612022

Field Application Summaries

GRANVILLE FARMS,INC. CLIENT: CF NITROGEN,INC.
FIELD APPLICATION SUMMARY PERMIT#WQ0012404
2021 APPLICATION YEAR APPLICATION METHOD:Surface
Granville Farms Site:11 Site 11 Total= 4,423,000 gallons
Acres Used= 149.0 acres
FIELD 1 2 3
'ACRES 40.4 67.2 41.4
' Crop ' fescue fescue fescue
5/26/2021 69,000 - -
5/27/2021 93,000 - -
6/1/2021 - - 6,000
6/2/2021 - 105,000 -
6/9/2021 - 71,000 -
6/10/2021 - 113,000 -
6/11/2021 - - 106,000
6/14/2021 - - 101,000
6/15/2021 72,000 - -
6/18/2021 52,000 - -
7/6/2021 - - 43,000
7/7/2021 - - 61,000
7/8/2021 - - 26,000
7/13/2021 - - 26,000
7/14/2021 - 61,000 -
7/15/2021 103,000 - -
7/16/2021 104,000 - -
7/22/2021 - 80,000 -
7/23/2021 - 82,000 -
7/26/2021 - 44,000 -
7/28/2021 - - 98,000
7/29/2021 100,000 - -
7/30/2021 - 113,000 -
7/31/2021 - - 59,000
8/2/2021 33,000 - -
8/3/2021 10,000 - -
8/12/2021 108,000 - -
8/13/2021 - 133,000 -
8/14/2021 - - 73,000
8/18/2021 - - 108,000
8/19/2021 113,000 - -
8/20/2021 - 102,000 -
8/23/2021 - 79,000 -
8/24/2021 - 8,000 -
8/25/2021 - - 75,000
8/26/2021 - - 107,000
8/27/2021 110,000 - -
8/30/2021 - 65,000 -
8/31/2021 - 116,000 -
9/1/2021 - - 101,000
9/2/2021 129,000 - -
9/3/2021 80,000 - -
9/7/2021 64,000 - -
9/8/2021 125,000 -
9/9/2021 - 69,000 -
9/10/2021 - 81,000 -
9/13/2021 - 118,000 -
9/14/2021 - - 113,000
9/15/2021 - - 110,000
9/16/2021 - - 96,000
9/28/2021 72,000 - -
9/29/2021 - 86,000 -
9/30/2021 - 78,000 -
10/1/2021 - 73,000 -
Field Totals 1,312,000 1,802,000 1,309,000
Q1-2021 _ _ _
Q2-2021 286,000 289,000 213,000
Q3-2021 1,026,000 1,440,000 1,096,000
Q4-2021 - 73,000 -

GRANVILLE FARMS,INC. CLIENT: CF NITROGEN,INC.
FIELD APPLICATION SUMMARY PERMIT#WQ0012404
2020 APPLICATION YEAR APPLICATION METHOD:Surface
Steven Burgess Site:27 Site Total= 9,600,000 gallons
Acres Used= 465.3 acres
FIELD 32 33 34 35 42 43 44 45 46 47 67 71 72 73
ACRES 26 9.9 17.6 9.1 93.5 17.7 29.2 17.5 13.9 20.8 33.7 61.8 39.7 74.9
CROP wheat wheat wheat wheat wheat wheat wheat wheat wheat wheat wheat wheat wheat wheat
1/6/2021 47,000
1/7/2021 40,000
1/13/2021 115,000
1/14/2021 104,000
1/15/2012 97,000
1/18/2021 96,000
1/19/2021 117,000
1/20/2021 130,000
1/21/2021 106,000
1/22/2021 117,000
1/23/2021 87,000
2/25/2021 119,000
2/26/2021 87,000
3/2/2021 100,000
3/3/2021 136,000
3/4/2021 121,000
3/5/2021 97,000
3/8/2021 140,000
3/9/2021 152,000
3/10/2021 136,000
3/11/2021 149,000
3/12/2021 118,000
3/15/2021 131,000
3/22/2021 75,000
3/23/2021 119,000
3/24/2021 6,000
3/25/2021 76,000
3/26/2021 98,000
3/30/2021 113,000
3/31/2021 114,000
4/2/2021 110,000
4/6/2021 125,000
4/7/2021 137,000
4/8/2021 117,000
4/9/2021 142,000
4/12/2021 143,000
4/13/2021 142,000
4/14/2021 119,000
4/19/2021 125,000
4/20/2021 117,000
4/21/2021 112,000
4/22/2021 86,000
4/23/2021 55,000
4/26/2021 89,000
4/27/2021 88,000
4/28/2021 88,000
4/29/2021 88,000
4/30/2021 88,000
5/3/2021 81,000
5/4/2021 38,000
10/5/2021 50,000
10/6/2021 97,000
10/7/2021 118,000
10/8/2021 86,000
10/11/2021 24,000
10/12/2021 61,000
10/13/2021 42,000
10/14/2021 43,000
10/15/2021 33,000
10/18/2021 111,000
10/19/2021 106,000
10/20/2021 106,000
10/21/2021 89,000
10/22/2021 88,000
10/25/2021 89,000
10/26/2021 112,000
10/27/2021 100,000
10/28/2021 76,000
11/1/2021 69,000
11/2/2021 92,000
11/3/2021 87,000
11/4/2021 84,000
11/5/2021 58,000
11/8/2021 128,000
11/9/2021 95,000
11/10/2021 88,000
11/11/2021 87,000
11/15/2021 88,000
11/16/2021 113,000
11/17/2021 100,000
11/18/2021 87,000
11/19/2021 86,000
11/29/2021 87,000
11/30/2021 98,000
12/1/2021 121,000
12/2/2021 116,000
12/3/2021 115,000
12/6/2021 122,000
12/7/2021 114,000
12/9/2012 67,000
12/10/2021 85,000
12/14/2021 112,000
12/15/2021 132,000
12/16/2021 133,000
12/17/2012 133,000
12/27/2021 76,000
12/28/2021 76,000
12/29/2021 87,000
Field Totals 356,000 312,000 401,000 362,000 1,976,000 589,000 1,023,000 601,000 365,000 639,000 485,000 899,000 560,000 1,032,000
Q1-2021 - - - - 598,000 414,000 646,000 428,000 202,000 454,000 - - - 401,000
Q2-2021 -
-
-
-
-
-
-
-
-
-
-
899,000 560,000 631,000
Q3-2021 -
Q4-2021 356,000 312,000 401,000 362,000 1,378,000 175,000 377,000 173,000 163,000 185,000 485,000 - -
zne/mzz

GRANVILLE FARMS, INC. CLIENT: CF NITROGEN, INC.
FIELD APPLICATION SUMMARY PERMIT#WQ0012404
2020 APPLICATION YEAR APPLICATION METHOD: Surface
William Ward,Jr. Site: 33 Site Total = 772,000 gallons
Acres Used = 28.7 acres
FIELD 3 4
ACRES 15.1 13.6
CROP soybeans soybeans
5/5/2021 - 44,000
5/10/2021 - 24,000
5/12/2021 - 63,000
5/14/2021 - 93,000
5/17/2021 - 99,000
5/18/2021 57,000 -
5/19/2021 93,000 -
5/20/2021 116,000 -
5/21/2021 80,000 -
5/25/2021 103,000 -
Field Totals 449,000 323,000
Q1-2021 - -
Q2-2021 449,000 323,000
Q3-2021 - -
Q4-2021 - -
2/19/2022

Attachment B

ATTACHMENT B-Approved Land Application Sites Certification Date: February 19,2021
CF Nitrogen,Inc. Permit Number:WQ0012404 Version:3.0
Site/ Owner Lessee County Latitude Longitude Net Acreage Dominant Soil Series Footnotes
Field
29-1 Ronald Byrd Bertie 36°09'30" -76°57'54" 6.7 Leaf Lf
29-2 Ronald Byrd Bertie 36°09'31" -76°58'02" 2.4 Leaf—Lf
29-3 Ronald Byrd Bertie 36°09'31" -76°58'09" 6 Exum ExA
29-4 Ronald Byrd Bertie 36°09'27" -76°58'09" 9.8 Exum ExA
29-5 Ronald Byrd Bertie 36°09'27" -76°58'20" 11.1 Exum ExA
29-6 Ronald Byrd Bertie 36°09'25" -76°58'34" 3.1 Leaf—Lf
29-7 Ronald Byrd Bertie 36°09'24" -76°58'10" 4.6 Granthum G
29-8 Ronald Byrd Bertie 36°09'21" -76°58'05" 10 Granthum Gt
29-9 Ronald Byrd Bertie 36°09'24" -76°58'00" 0.5 Exum ExA
29-10 Ronald Byrd Bertie 36°09'24" -76°57'56" 4.0 Exum ExB
30-1 Kendred C.Williams,Jr. Bertie 36°08'15" -76°57'12" 15.4 Exum ExA
30-2 Kendred C.Williams,Jr. Bertie 36°08'22" -76°57'13" 6.1 Exum ExA
30-3 Kendred C.Williams,Jr. Bertie 36°12'47" -76°56'35" 1.3 Craven CrA
30-4 Kendred C.Williams,Jr. Bertie 36°12'45" -76°56'22" 26.3 Norfo k NoB
30-5 Kendred C.Williams,Jr. Bertie 36°12'43" -76°56'07" 32.4 Craven CrB
30-6 Kendred C.Williams,Jr. Bertie 36°12'31" -76°56'09" 9.0 Craven CrB
30-7 Kendred C.Williams,Jr. Bertie 36°12'38" -76°56'25" 12.9 Craven CrB
30-8 Kendred C.Williams,Jr. Bertie 36°12'40" -76°56'34" 6.5 Craven CrB
30-9 Kendred C.Williams,Jr. Bertie 36°12'41" -76°56'49" 16.4 Norfolk NoA
30-10 Kendred C.Williams,Jr. Bertie 36°12'45" -76°56'47" 3.7 Norfolk—NoA
30-11 Kendred C.Williams,Jr. Bertie 36°12'48" -76°56'45" 1.4 Norfolk NoB
30-12 Kendred C.Williams,Jr. Bertie 36°12'48" -76°56'39" 1.5 Norfolk NoA
30-13 Kendred C.Williams,Jr. Bertie 36°12'51" -76°56'41" 5.1 Lenoir Ln
WQ0012404 Version: 3.0 Attachment B Page 1 of 16

ATTACHMENT B-Approved Land Application Sites Certification Date:February 19,2021
CF Nitrogen,Inc. Permit Number:WQ0012404 Version:3.0
Site/
Owner Lessee County Latitude Longitude Net Acreage Dominant Soil Series Footnotes
Field
30-14 Kendred C.Williams,Jr. Bertie 36°12'56" -76°56'38" 0.5 Lenoir Ln
30-15 Kendred C.Williams,Jr. Bertie 36°13'03" -76°56'36" 8.9 Leaf Lf
30-16 Kendred C.Williams,Jr. Bertie 36°13'09" -76°56'31" 4.5 Craven—CrA
30-17 Kendred C.Williams,Jr. Bertie 36°13'06" -76°57'03" 28.1 Craven—CrA
30-18 Kendred C.Williams,Jr. Bertie 36°12'55" -76°57'00" 20.9 Craven CrA
30-19 Kendred C.Williams,Jr. Bertie 36°12'54" -76°56'48" 9.3 Goldsboro-GoA
30-20 Kendred C.Williams,Jr. Bertie 36°12'13" -76°56'51" 10.7 Craven CrA
30-21 C.S.Hollomon,Jr. Kendred C.Williams,Jr. Bertie 36°12'23" -76°56'48" 7.0 Lenoir Ln
30-22 C.S.Hollomon,Jr. Kendred C.Williams,Jr. Bertie 36°12'16" -76°56'53" 7.5 Craven CrA
30-23 C.S.Hollomon,Jr. Kendred C.Williams,Jr. Bertie 36°12'16" -76°56'59" 9.2 Craven CrA
30-24 C.S.Hollomon,Jr. Kendred C.Williams,Jr. Bertie 36°12'18" -76°57'02" 4 Craven CrA
30-25 C.S.Hollomon,Jr. Kendred C.Williams,Jr. Bertie 36°12'19" -76°57'05" 1.5 Craven CrA
30-26 C.S.Hollomon,Jr. Kendred C.Williams,Jr. Bertie 36°12'26" -76°57'12" 4.3 Craven CrA
30-27 C.S.Hollomon,Jr. Kendred C.Williams,Jr. Bertie 36°12'16" -76°57'08" 4.0 Craven CrA
30-28 C.S.Hollomon,Jr. Kendred C.Williams,Jr. Bertie 36°12'13" -76°57'09" 5.1 Craven CrA
30-29 C.S.Hollomon,Jr. Kendred C.Williams,Jr. Bertie 36°12'08" -76°57'07" 13.3 Craven CrA
30-30 Kendred C.Williams,Jr. Bertie 36°10'35" -76°57'25" 4.5 Nahunta-Na
30-31 Kendred C.Williams,Jr. Bertie 36°10'28" -76°57'24" 20.8 Exum ExA
30-32 Kendred C.Williams,Jr. Bertie 36°10'24" -76°57'15" 7.5 Goldsboro GoA
30-33 Kendred C.Williams,Jr. Bertie 36°10'18" -76°57'19" 17.8 Goldsboro GoA
30-34 Kendred C.Williams,Jr. Bertie 36°10'18" -76°57'18" 24.1 Goldsboro GoA
30-35 Kendred C.Williams,Jr. Bertie 36°10'20" -76°57'37" 0.9 Exum ExA
30-36 David C.Powell Kendred C.Williams,Jr. Bertie 36°13'13" -76°54'33" 19.9 Exum ExA
30-37 E.M.Powell& Sons,Inc. Kendred C.Williams,Jr. Bertie 36°13'07" -76°54'26" 21.2 Exum ExA
30-38 E.M.Powell&Sons,Inc. Kendred C.Williams,Jr. Bertie 36°12'49" -76°54'30" 23.4 Exum ExA
WQ0012404 Version:3.0 Attachment B Page 2 of 16

ATTACHMENT B-Approved Land Application Sites Certification Date:February 19,2021
CF Nitrogen,Inc. Permit Number:WQ0012404 Version:3.0
Site/
Owner Lessee County Latitude Longitude Net Acreage Dominant Soil Series Footnotes
Field
30-39 E.M.Powell&Sons,Inc. Kendred C.Williams,Jr. Bertie 36°12'42" -76°54'24" 25.4 Exum ExA
30-40 T.E.Ruffm Kendred C.Williams,Jr. Bertie 36°09'22" -76°57'24" 19.9 Exum ExA
30-41 T.E.Ruffm Kendred C.Williams,Jr. Bertie 36°09'23" -76°57'37" 7.0 Exum ExA
30-42 T.E.Ruffm Kendred C.Williams,Jr. Bertie 36°09'26" -76°57'43" 4.7 Exum ExA
30-43 T.E.Ruffm Kendred C.Williams,Jr. Bertie 36°09'23" -76°57'46" 7.0 Exum ExA
30-44 James C.Askew Kendred C.Williams.Jr. Bertie 36°11'18" -76°57'21" 3 Exum—ExB
30-45 James C.Askew Kendred C.Williams,Jr. Bertie 36°11'18" -76°57'17" 6.3 Exum ExB
30-46 James C.Askew Kendred C.Williams,Jr. Bertie 36°11'17" -76°57'10" 12.0 Gritney Gt
30-47 Oliver B.Balance Kendred C.Williams,Jr. Bertie 36°11'12" -76°57'08" 11.6 Exum ExA
33-17 Leonard L.Godwin William Ward Bertie 36°13'38" -77°00'05" 11.2 Norfolk NoA
33-18 Leonard L.Godwin William Ward Bertie 36°13'31" -76°59'55" 11.2 Goldsboro—GoA
33-19 Ola Sanders William Ward Bertie 36°12'15" -76°56'09" 16.8 Goldsboro—GoA
33-20 Ruth H.Metcalf William Ward Bertie 36°14'16" -76°54'30" 3.3 Exum ExA
33-21 Ruth H.Metcalf,et al William Ward Bertie 36°14'02" -76°54'24" 12.9 Exum ExA
33-22 Mildred Harris William Ward Bertie 36°13'53" -76°54'12" 17.0 Exum ExA
33-23 Agnes 0.Moore,et al William Ward Bertie 36°13'42" -76°54'09" 10 Goldsboro GoA
County Total Bertie 653.6
3-1 Wiley B.Gillam III Hertford 36°19'51" -76°50'39" 19.6 Lynchburg-Ly
3-2 Wiley B.Gillam III Hertford 36°19'44" -76°50'43" 37.2 Lynchburg-Ly
3-3 Wiley B.Gillam III Hertford 36°19'45" -76°50'28" 19.9 Norfolk NoA
3-4 Wiley B.Gillam III Hertford 36°19'27" -76°48'06" 18.6 Wickham WkB
3-5 Wiley B.Gillam III Hertford 36°19'02" -76°48'02" 31.9 Tarboro TaB
6-1 Stuart Pierce Farms,Inc. Hertford 36°16'06" -76°56'20" 17.0 Craven CrA
6-2 Stuart Pierce Farms,Inc. Hertford 36°16'18" -76°56'20" 67.4 Caroline CaA
6-3 Stuart Pierce Farms,Inc. Hertford 36°16'09" -76°55'58" 7.9 Caroline CaA
WQ0012404 Version:3.0 Attachment B Page 3 of 16

ATTACHMENT B-Approved Land Application Sites Certification Date:February 19,2021
CF Nitrogen,Inc. Permit Number:WQ0012404 Version:3.0
Site/
Owner Lessee County Latitude Longitude Net Acreage Dominant Soil Series Footnotes
Field
6-4 Stuart Pierce Farms,Inc. Hertford 36°15'54" -76°56'16" 10.9 Caroline CaA
6-5 Stuart Pierce Farms,Inc. Hertford 36°15'47" -76°56'56" 54.0 Caroline CaA
6-6 Stuart Pierce Farms,Inc. Hertford 36°15'36" -76°56'34" 23.3 Craven—CrB
6-7 Stuart Pierce Farms,Inc. Hertford 36°15'27" -76°56'11" 42.2 Craven CrB
6-9 Stuart Pierce Farms,Inc. Hertford 36°16'O1" -76°57'17" 38.9 Craven CrA
6-10 Stuart Pierce Farms,Inc. Hertford 36°16'43" -76°55'34" 107.0 Caroline CaA
6-11A Stuart Pierce Farms,Inc. Hertford 36°15'52" -77°00'07" 41.0 Craven CrB
6-11B Stuart Pierce Farms,Inc. Hertford 36°15'41" -76°59'53" 72.2 Craven CrB
6-11C Stuart Pierce Farms,Inc. Hertford 36°15'37" -76°59'40" 29.4 Craven CrB
6-11D Stuart Pierce Farms,Inc. Hertford 36°15'24" -76°59'45" 41.2 Craven—CrB
6-11E Stuart Pierce Farms,Inc. Hertford 36°15'36" -76°59'37" 47.7 Craven CrA
6-12 Stuart Pierce Farms,Inc. Hertford 36°18'30" -77°01'47" 40.4 Caroline CaA
6-13 Stuart Pierce Farms,Inc. Hertford 36°18'27" -76°54'52" 41.4 Craven CrA
6-14 Stuart Pierce Farms,Inc. Hertford 36°18'10" -76°54'59" 30.9 Craven CrA
6-15 Stuart Pierce Farms,Inc. Hertford 36°18'14" -76°55'18" 48.8 Craven CrB
6-16 Stuart Pierce Farms,Inc. Hertford 36°16'51" -76°45'06" 46.1 Bonneau BoB
6-17 Stuart Pierce Farms,Inc. Hertford 36°16'44" -76°45'38" 41.9 Bonneau BoB
6-18 Stuart Pierce Farms,Inc. Hertford 36°17'04" -76°45'33" 21.0 Bonneau BoB
6-19 Stuart Pierce Farms,Inc. Hertford 36°16'33" -76 43'56" 46.3 Goldsboro GoA
6-20 Stuart Pierce Farms,Inc. Hertford 36°16'06" -76°44'18" 21.4 Goldsboro GoA
6-21 Stuart Pierce Farms,Inc. Hertford 36°17'50" -76°43'10" 70.8 Bonneau BoB
6-22 Stuart Pierce Farms,Inc. Hertford 36°16'19" -77°02'38" 56.4 Craven CrA
6-23 Stuart Pierce Farms,Inc. Hertford 36°16'32" -77°02'41" 94.9 Craven CrA
6-24 Stuart Pierce Farms,Inc. Hertford 36°16'20" -77°02'23" 41.6 Lenoir Ln
WQ0012404 Version:3.0 Attachment B Page 4 of 16

ATTACHMENT B-Approved Land Application Sites Certification Date:February 19,2021
CF Nitrogen,Inc. Permit Number:WQ0012404 Version:3.0
Site/ Net
Owner Lessee County Latitude Longitude Dominant Soil Series Footnotes
Field Acreage
9-2 Gray Pierce,et al Hertford 36°18'20" -76°51'10" 18.5 Norfolk NoA
9-3 Gray Pierce Hertford 36°18'14" -76°51'20" 8.5 Norfolk NoA
9-5 Carlyle Archer,et al Gray Pierce Hertford 36°18'13" -76°51'37" 22.8 Norfolk NoA
9-6 Gray Pierce Hertford 36°18'15" -76°51'46" 4.5 Goldsboro GoA
9-7 Gray Pierce Hertford 36°18'07" -76°51'28" 16.2 Norfolk NoA
9-8 Gray Pierce Hertford 36°18'03" -76°51'36" 11.6 Norfolk NoA
9-9 Gray Pierce Hertford 36°17'15" -76°51'30" 18.1 Craven CrB
9-10 Gray Pierce Hertford 36°17'59" -76°51'30" 5.6 Craven—CrB
9-11 Gray Pierce Hertford 36°17'45" -76°51'19" 10.6 Craven CrB
9-12 Gray Pierce Hertford 36°17'48" -76°51'05" 8.6 Conetoe—CoB
9-14 Gray Pierce Hertford 36°17'50" -76°50'58" 6.7 Tarboro—TaB
9-15 Gray Pierce Hertford 36°17'58" -76°50'50" 7.7 Tarboro—TaB
9-16 Gray Pierce Hertford 36°17'58" -76°51'22" 1.5 Craven CrB
9-17 Gray Pierce Hertford 36°18'01" -76°51'21" 3.6 Craven CrB
9-18 Gray Pierce Hertford 36°17'50" -76°51'25" 14.6 Wickham WkA
9-19 Gray Pierce Hertford 36°17'59" -76°51'10" 3.7 Tarboro—TaB
9-20 Gray Pierce Hertford 36°18'06" -76°51'13" 3.9 Bonneau BoB
9-21 Gray Pierce Hertford 36°17'38" -76°51'49" 6.0 Craven—CrA
9-22 Gray Pierce Hertford 36°17'45" -76°51'49" 9.6 Lenoir Ln
9-24 Gray Pierce Hertford 36°17'47" -76°51'43" 13.5 Craven CrA
9-26 Gray Pierce Hertford 36°18'34" -76°51'45" 27.0 Craven CrA
9-27 Gray Pierce Hertford 36°19'12" -76°51'48" 24.9 Tarboro TaB
9-28 Gray Pierce Hertford 36°18'51" -76°52'0I" 15.0 Wickham WkA
9-29 Gray Pierce Hertford 36°18'47" -76°51'57" 5.7 Wickham WkA
9-30 Gray Pierce Hertford 36°18'44" -76°51'53" 11.9 Wickham WkA
WQ0012404 Version:3.0 Attachment B Page 5 of 16

ATTACHMENT B-Approved Land Application Sites Certification Date:February 19,2021
CF Nitrogen,Inc. Permit Number:WQ0012404 Version:3.0
Site/
Owner Lessee County Latitude Longitude Net Acreage Dominant Soil Series Footnotes
Field
9-31 Gray Pierce,Merle Jones Gray Pierce Hertford 36°17'48" -76°52'45" 11.4 Craven CrA
9-32 Merle Jones Gray Pierce Hertford 36°17'34" -76°52'36" 17 6 Lenoir Ln
9-33 Gray Pierce Hertford 36°17'37" -76°52'10" 16.7 Craven CrA
9-34 Gray Pierce Hertford 36°17'52" -76°53'00" 8 Craven CrA
9-35 Gray Pierce Hertford 36°17'58" -76°52'55" 13 Craven CrA
9-37 R.C.Kennington Gray Pierce Hertford 36°18'33" -76°52'45" 16 Craven CrB
9-38 R.C.Kennington Gray Pierce Hertford 36°18'27" -76°52'32" 8 Craven CrB
9-40 Gray Pierce Hertford 36°19'21" -76°53'33" 11.2 Wickham WkB
9-41 Gray Pierce Hertford 36°19'33" -76°53'28" 12.4 Wickham WkA
9-42 Gray Pierce Hertford 36°19'23" -77°01'20" 26.4 Caroline CaA
9-43 Gray Pierce Hertford 36°19'16" -77°00'38" 39.4 Caroline CaA
9-45 Gray Pierce Hertford 36°19'11" -77°06'56" 73.7 Craven CrA
9-46A Gray Pierce Hertford 36°19'19" -77°07'49" 36.7 Craven CrA
9-46B Gray Pierce Hertford 36°19'15" -77°07'27" 42.5 Craven CrA
9-47 Gray Pierce Hertford 36°19'33" -77°08'09" 18.8 Craven CrA
9-48 Gray Pierce Hertford 36°1832' -77°06'31" 45.1 Craven CrA
9-50 Gray Pierce Hertford 36°18'53" -77°06'43" 63.8 Craven CrA
9-52 Gray Pierce Hertford 36°18'57" -77°07'03" 27.4 Craven CrA
9-53 Gray Pierce Hertford 36°19'06" -77°07'13" 26.7 Craven CrB
10-1 J.H.Drewry,III Hertford 36°32'36" -77°09'01" 7.8 Tarboro TaB
10-2 J.H.Drewry,III Hertford 36°32'30" -77°08'36" 34.1 Wickham WkA
10-3 J.H.Drewry,III Hertford 36°32'17" -77°08'33" 67.7 Autryville AuB
10-4 J.H.Drewry,III Hertford 36°32'35" -77°08'16" 6.9 Lynchburg Ly
10-5 J.H.Drewry,III Hertford 36°32'58" -77°08'17" 20.0 Norfolk NoA
10-6 J.H.Drewry,III Hertford 36°52'21" -77°07'56" 35.0 Craven CrA
WQ0012404 Version:3.0 Attachment B Page 6 of 16

ATTACHMENT B-Approved Land Application Sites Certification Date:February 19,2021
CF Nitrogen,Inc. Permit Number:WQ0012404 Version:3.0
Site/
Owner Lessee County Latitude Longitude Net Acreage Dominant Soil Series Footnotes
Field
10-7 J.H.Drewry,III Hertford 36°32'17" -77°08'07" 35.4 Norfolk NoA
10-8 J.H.Drewry,III Hertford 36°32'15" -77°08'18" 42.3 Norfolk NoA
10-9 J.H.Drewry,III Hertford 36°32'24" -77°07'46" 12.3 Autryville AuB
10-10 J.H.Drewry,III Hertford 36°32'27" -77°07'41" 26.3 Bonneau BoB
10-11 J.H.Drewry,III Hertford 36°32'01" -77°07'07" 4.9 Norfolk NoA
11-1 CF Industries,Inc. Granville Farms,Inc. Hertford 36°22'19" -76°52'10" 40.4 Craven CrA
11-2 CF Industries,Inc. Granville Farms,Inc. Hertford 36°22'17" -76°51'47" 67.2 Craven—CrA
11-3 CF Industries,Inc. Granville Farms,Inc. Hertford 36°22'01" -76°51'54" 41.4 Craven CrA
12-1 Douglas R.White Tuscarora Greens Hertford 36°23'03" -76°54'59" 8.3 Lenoir Ln
12-2 Douglas R.White Tuscarora Greens Hertford 36°22'57" -76°55'11" 8.8 Lenoir Ln
12-3 Douglas R.White Tuscarora Greens Hertford 36°22'40" -76°54'57" 6.3 Craven CrB
12-4 Douglas R.White Tuscarora Greens Hertford 36°22'43" -76°54'46" 30.0 Craven CrA
12-5 Douglas R.White Tuscarora Greens Hertford 36°22'33" -76°54'51" 5.0 Craven CrA
12-6 Douglas R.White Tuscarora Greens Hertford 36°22'55 -76°54'52" 18.0 Craven—CrA
23-1 Johnny Powell Hertford 36°17'O1" -76°44'02" 24.9 Norfolk NoA
23-2 Johnny Powell Hertford 36°16'42" -76°45'12" 13.1 Norfolk NoA
23-3 Thaddeus F.Scott Johnny Powell Hertford 36°17'46" -76°45'44" 39.1 Norfolk NoA
23-4 Thaddeus F.Scott Johnny Powell Hertford 36°17'55" -76°45'44" 22.0 Norfolk NoA
23-5 Johnny Powell Hertford 36°18'19" -76°47'17" 27.7 Norfolk NoB
23-6 Johnny Powell Hertford 36°18'02" -76°50'25" 19.9 Conetoe—CoB
23-7A Johnny Powell Hertford 36°17'42" -76°49'32" 33.5 Craven CrA
23-7B Johnny Powell Hertford 36°18'03" -76°49'10" 13.2 Bonneau BoB
23-8 Johnny Powell Hertford 36°17'12" -76°53'00" 29.8 Caroline CaA
23-9 Johnny Powell Hertford 36°19'50" -76°51'05" 19.8 Craven—CrA
23-10 Johnny Powell Hertford 36°20'26" -76°49'47" 15.8 Craven CrA
WQ0012404 Version:3.0 Attachment B Page 7 of 16

ATTACHMENT B-Approved Land Application Sites Certification Date:February 19,2021
CF Nitrogen,Inc. Permit Number:WQ0012404 Version:3.0
Site/ Owner Lessee County Latitude Longitude Net Acreage Dominant Soil Series Footnotes
Field
23-12 Johnny Powell Hertford 36°22'27" -76°54'50" 26.3 Craven CrA
23-13 Johnny Powell Hertford 36°21'38" -76°54'02" 20.5 Craven CrA
23-14 Johnny Powell Hertford 36°21'46" -76°54'23" 11.7 Craven CrA
23-15 Johnny Powell Hertford 36°22'38" -76°56'02" 19.0 Norfolk—NoA
23-16 Johnny Powell Hertford 36°18'35" -76°55'42" 45.0 Craven CrB
24-2 Chester Powell Hertford 36°19'15" -76°50'40" 14.6 Norfolk NoA
24-3 Chester Powell Hertford 36°19'28" -76°50'34" 11.6 Wickham-WkB
24-4 Chester Powell Hertford 369 8'56" -76°48'52" 10.8 Goldsboro GoA
24-5 Chester Powell Hertford 36°18'43" -76°48'52" 13.0 Bonneau BoB
24-6 Chester Powell Hertford 36°20'24" -76°51'54" 13.5 Craven CrA
24-7 Chester Powell Hertford 36°20'17" -76°51'46" 3.6 Craven CrA
24-8 Chester Powell Hertford 36°15'50" -76°56'33" 6.3 Lenoir In
24-9 Chester Powell Hertford 36°15'50" -76°53'54" 12.7 Craven CrA
24-10 Shirley Deramus Chester Powell Hertford 36°18'04" -76°43'20" 6.1 Bonneau BoB
24-11 Shirley Deramus Chester Powell Hertford 36°18'09" -76°43'13" 10.5 Goldsboro GoA
24-13 Chester Powell Hertford 36°15'23" -76°49'06" 14.8 Craven CrA
25-1 Tommy Castelow Hertford 36°21'58" -76°53'54" 39.8 Caroline CaA
25-2 Tommy Castelow Hertford 36°19'46" -76°49'06" 9.3 Norfolk NoA
25-3 Tommy Castelow Hertford 36°20'02" -76°49'03" 32.2 Norfolk NoA
25-4 Tommy Castelow Hertford 36°20'17" -76°49'02" 30.2 Craven CrA
25-5 Tommy Castelow Hertford 36°20'09" -76°48'42" 25.6 Craven CrA
25-6 Tommy Castelow Hertford 36°20'00" -76°47'36" 27.2 Craven CrA
25-7 Tommy Castelow Hertford 36°21'16" -76°47'38" 12.3 Craven CrA
25-8 Tommy Castelow Hertford 36°20'43" -76°54'05" 16.6 Craven CrA
25-9 Tommy Castelow Hertford 36°20'37" -76°54'01" 34.7 Craven CrA
WQ0012404 Version:3.0 Attachment B Page 8 of 16

ATTACHMENT B-Approved Land Application Sites Certification Date:February 19,2021
CF Nitrogen,Inc. Permit Number:WQ0012404 Version:3.0
Site/
Owner Lessee County Latitude Longitude Net Acreage Dominant Soil Series Footnotes
Field
25-10 Tommy Castelow Hertford 36°20'26" -76°54'07" 11.3 Craven CrA
25-11 Tommy Castelow Hertford 36°20'25" -76°54'13" 4.8 Craven CrA
25-12 Tommy Castelow Hertford 36°20'01" -76°54'28" 32.0 Craven CrA
26-1 Beechwood Country Club Hertford 36°21'58" -77°00'38" 7.9 Caroline CaA
26-2 Beechwood Country Club Hertford 36°21'53" -77°00'47" 10.5 Craven CrB
26-3 Beechwood Country Club Hertford 36°21'37" -77°00'37" 8.3 Craven CrB
26-4 Beechwood Country Club Hertford 36°21'43" -77°00'01" 18.2 Caroline CaB
27-52 Lori S.Burgess Steven Burgess Hertford 36°25'02" -77°06'01" 44.7 Norfolk NoA
27-53 Lori S.Burgess Steven Burgess Hertford 36°24'42" -77°05'55" 10.0 Norfolk—NoA
27-54 Steven Burgess Hertford 36°24'36" -77°06'06" 42.7 Norfolk—NoA
27-55 Steven Burgess Hertford 36°21'18" -77°07'40" 6.6 Craven CrA
27-56 Steven Burgess Hertford 36°21'19" -77°07'31" 9.8 Craven CrA
27-57 Steven Burgess Hertford 36°21'22" -77°07'21" 12 Craven CrA
27-58 Steven Burgess Hertford 36°21'11" -77°07'17" 4.5 Lenoir Ln
27-59 Steven Burgess Hertford 36°21'08" -77°07'23" 9.0 Lenoir Ln
27-60 Steven Burgess Hertford 36°21'03" -77°07'07" 2 Lenoir Ln
27-61 Steven Burgess Hertford 36°21'04" -77°06'59" 14.9 Craven CrA
27-62 Steven Burgess Hertford 36°20'55" -77°07'02" 3.1 Craven CrA
27-63 Adam&Wendy Burgess Steven Burgess Hertford 36°21'14" -77°06'55" 14.7 Craven CrA
27-64 Adam&Wendy Burgess Steven Burgess Hertford 36°21'24" -77°06'50" 29.5 Craven CrA
28-1 Judith,Allison,&Walter Perry Hertford 36°19'31" -77°50'15" 17.6 Norfolk—NoA
28-2 Judith,Allison,&Walter Perry Hertford 36°19'27" -76°50'05" 17.5 Norfolk NoA
28-3 Judith,Allison,&Walter Perry Hertford 36°19'48" -76°50'10" 25.1 Norfolk NoA
28-4 Judith,Allison,&Walter Perry Hertford 36°19'21" -76°49'51" 10.8 Wickham WkA
28-5 Judith,Allison,&Walter Perry Hertford 36°19'10" -76°49'34" 9.4 Conetoe CoB
WQ0012404 Version:3.0 Attachment B Page 9 of 16

ATTACHMENT B-Approved Land Application Sites Certification Date:February 19,2021
CF Nitrogen,Inc. Permit Number:WQ0012404 Version:3.0
Site/
Owner Lessee County Latitude Longitude Net Acreage Dominant Soil Series Footnotes
Field
28-6 Judith,Allison,&Walter Perry Hertford 36°19'24" -76°50'24" 20.4 Norfolk—NoA
28-7 Judith,Allison,&Walter Perry Hertford 36°19'50" -76°51'03" 16.0 Norfolk NoA
28-8 Judith,Allison,&Walter Perry Hertford 36°19'42" -76°51'06" 9.2 Goldsboro—GoA
28-9 Judith,Allison,&Walter Perry Hertford 36°19'42" -76°51'13" 9.9 Goldsboro GoA
28-10 Judith,Allison,&Walter Perry Hertford 36°19'44" -76°51'18" 1.7 Goldsboro GoA
28-11 Judith,Allison,&Walter Perry Hertford 36°19'48" -76°51'15" 3.7 Craven CrB
28-12 Judith,Allison,&Walter Perry Hertford 36°19'47" -76°51'11" 3.6 Craven CrB
28-13 John Lock Mitchell Walter Perry Hertford 36°17'42" -76°49'37" 8.7 Bonneau BoB
28-14 John Lock Mitchell Walter Perry Hertford 36°17'36" -76°49'45" 7.0 Bonneau BoB
28-15 Betty Perry,John Mitchell,Eleanor Lane,Penny Walter Perry Hertford 36°17'19" -76°50'11" 17.4 Craven CrA
Beasley,&Ken Mitchell
28-16 John Mitchell,Eleanor Lane,Penny Beasley,Ken Walter Perry Hertford 36°18'02" -76°50'23" 18.9 Conetoe CoB
Mitchell,&Wiccacon Properties,LLC
28-17 Margaret Hall Walter Perry Hertford 36°23'01" -76°56'51" 16.9 Craven CrA
28-18 Betty Everette Perry Walter Perry Hertford 36°17'30" -76°49'53" 7.4 Craven CrA
31-1 Ray&Linda Chamblee Hertford 36°20'42" -76°55'26" 8.8 Craven CrA
31-2 Jackie Chamblee Ray Chamblee Hertford 36°20'40" -76°55'20" 9.6 Craven—CrB
31-3 Jackie Chamblee Ray Chamblee Hertford 36°20'47" -76°55'13" 15.9 Craven CrA
31-4 Ray&Linda Chamblee Hertford 36°20'43" -76°55'04" 8.8 Craven CrA
31-5 Ray&Linda Chamblee Hertford 36°17'31" -76°55'16" 5.9 Goldsboro—GoA
32-1 Janice Simmons Sessoms William H.Sessoms Hertford 36°17'55" -76°48'53" 7.0 Wakulla-WaB
32-2 William H.Sessoms Hertford 36°17'55" -76°48'42" 30.6 Lynchburg Ly
32-3 William H.Sessoms Hertford 36°17'27" -76°48'38" 5.0 Craven CrB
32-4 Joyce Ann Sessoms William H.Sessoms Hertford 36°18'07" -76°48'45" 5.0 Bonneau BoB
32-5 Joyce Ann Sessoms William H.Sessoms Hertford 36°17'43" -76°49'16" 5.5 Lynchburg Ly
32-6 William H.Sessoms Hertford 36°17'42" -76°49'27" 2.7 Lynchburg Ly
WQ0012404 Version:3.0 Attachment B Page 10 of 16

ATTACHMENT B-Approved Land Application Sites Certification Date:February 19,2021
CF Nitrogen,Inc. Permit Number:WQ0012404 Version:3.0
Site/
Owner Lessee County Latitude Longitude Net Acreage Dominant Soil Series Footnotes
Field
32-7 William H.&Joyce Ann Sessoms Hertford 36°17'24" -76°47'58" 28.9 Goldsboro-Go
32-8 William H.&Delores Sessoms Hertford 36°17'33" -76°47'23" 23.2 Norfolk NoB
32-9 William H.&Delores Sessoms Hertford 36°17'36" -76°47'36" 13.3 Norfolk NoB
32-10 William H.&Delores Sessoms Hertford 36°17'42" -76°47'34" 7.3 Norfolk NoB
32-11 Wiccacon Properties,LLC William H.Sessoms Hertford 36°17'47" -76°49'32" 4.3 Craven CrA
32-12 Ernest Chamblee William H.Sessoms Hertford 36°15'23" -76°49'08" 14.0 Craven CrA
33-1 William W&Nellie Ward William Ward Hertford 36°14'36" -76°56'23" 3.0 Caroline CaB
33-2 William W&Nellie Ward William Ward Hertford 36°14'51" -76°56'23" 11.9 Craven CrC2
33-3 William W&Nellie Ward William Ward Hertford 36°14'47" -76°56'21" 15.1 Norfolk NoB
33-4 William W&Nellie Ward William Ward Hertford 36°14'48" -76°56'12" 13.6 Norfolk NoB
33-5 William W&Nellie Ward William Ward Hertford 36°15'10" -76°56'08" 14.2 Tarboro TaB
33-6 William W&Nellie Ward William Ward Hertford 36°14'43" -76°56'10" 14.6 Norfolk NoB
33-7 William W&Nellie Ward William Ward Hertford 36°14'37" -76°56'08" 5.9 Craven CrB
33-8 William W&Nellie Ward William Ward Hertford 36°14'35" -76°56'14" 3.0 Craven—CrB
33-9 Michael A.&Deborah Spalding William Ward Hertford 36°14'23" -76°58'28" 14.2 Craven CrA
33-10 Michael A.&Deborah Spalding William Ward Hertford 36°14'28" -76°58'27" 8.0 Craven CrB
33-11 Michael A.&Deborah Spalding William Ward Hertford 36°14'26" -76°58'17" 3.7 Craven-CrB
33-12 Michael A.&Deborah Spalding William Ward Hertford 36°14'21" -76°58'17" 2.4 Craven CrA
33-13 Rosa H.Sessoms William Ward Hertford Hertford 36°15'09" -77°00'47" 25.0 Craven CrA
33-14 Rosa H.Sessoms William Ward Hertford Hertford 36°15'12" -77°00'36" 6.3 Leaf Lf
33-15 Rosa H.Sessoms William Ward Hertford 36°15'15" -77°00'29" 2.8 Craven—CrA
33-16 Rosa H.Sessoms William Ward Hertford 36°15'20" -76°00'31" 4.2 Craven CrA
County Total Hertford 4,212.3
34-1 Nellie B.Brown Martin 35°59'36" -77°20'10" 26.5 Goldsboro GoA
34-2 Nellie B.Brown Martin 35°59'30" -77°20'17" 19.1 Goldsboro GoA
WQ0012404 Version:3.0 Attachment B Page 11 of 16

ATTACHMENT B-Approved Land Application Sites Certification Date:February 19,2021
CF Nitrogen,Inc. Permit Number:WQ0012404 Version:3.0
Site/
Field Owner Lessee County Latitude Longitude Net Acreage Dominant Soil Series Footnotes
34-3 Nellie B Brown Martin 35°59'26" -77°20'17" 3.8 Lynchburg Ly
34-4 Nellie B Brown Martin 35°59'20" -77°20'16" 27.1 Lynchburg Ly
County Total Martin 76.5
15-1 J.Elliot Stephenson Northampton 36°28'42" -77°26'06" 19.2 Lynchburg Ly
15-2 J.Elliot Stephenson Northampton 36°28'31" -77°25'43" 27.3 Craven CrA
15-3 J.Elliot Stephenson Northampton 36°28'19" -77°26'06" 38.0 Caroline CrB
15-4 J.Elliot Stephenson Northampton 36°25'47" -77°25'26" 41.3 Norfolk-NoA
15-5 J.Elliot Stephenson Northampton 36°26'06" -77°25'40" 71.3 Gritney GxB
15-6 J.Elliot Stephenson Northampton 36°26'17" -77°25'44" 37.1 Gritney GxB
15-7 J.Elliot Stephenson Northampton 36°26'12" -77°24'48' 13.1 Norfolk-NoA
15-8 J.Elliot Stephenson Northampton 36°26'19" -77°28'39" 35.6 Goldsboro GoA
15-9 J.Elliot Stephenson Northampton 36°26'49" -77°26'39" 15.1 Gritney GxB
15-10 J.Bentley Stephenson J.Elliot Stephenson Northampton 36°51'21" -77°26'21" 14.2 Gritney GxB
15-11 J.Bentley Stephenson J.Elliot Stephenson Northampton 36°26'44" -77°26'25" 14.5 Gritney GxB
15-12 J.Elliot Stephenson Northampton 36°26'09" -77°26'36" 9.2 Gritney GxB
15-13 J.Elliot Stephenson Northampton 36°26'03" -77°26'25" 17.2 Gritney GxB
15-14 J.Elliot Stephenson Northampton 36°26'21" -77°26'07" 19.9 Gritney GxB
15-15 J.Elliot Stephenson Northampton 36°28'18" -77°25'54" 24.3 Bonneau BoB
15-16 J.Elliot Stephenson Northampton 36°28'24" -77°25'41" 22.8 Bonneau BoB
15-17 J.Elliot Stephenson Northampton 36°28'09" -77°25'52" 33.7 Craven CrA
18-1 Thomas Williams Northampton 36°29'41" -77°07'55" 12.0 Craven CrB
18-2 Thomas Williams Northampton 36°29'52" -77°08'03" 15.0 Craven CrA
19-1W C.C.Woodard Northampton 36°30'46" -77°20'27" 31.7 Norfolk—NoB
19-2W C.C.Woodard Northampton 36°40'47" -77°20'48" 21.4 Norfolk NoB
19-3W C.C.Woodard Northampton 36°30'36" -77°20'56" 69.7 Norfolk NoB
WQ0012404 Version:3.0 Attachment B Page 12 of 16

ATTACHMENT B-Approved Land Application Sites Certification Date:February 19,2021
CF Nitrogen,Inc. Permit Number:WQ0012404 Version:3.0
Site/ Owner Lessee County Latitude Longitude Net Acreage Dominant Soil Series Footnotes
Field
19-4W C.C.Woodard Northampton 36°30'27" -77°20'45" 76.7 Norfolk NoB
19-5W Cecil Whitehead C.C.Woodard Northampton 36°30'18" -77°20'50" 12.8 Norfolk NoB
19-6W Amanda Cooke,et al Cecil Whitehead Northampton 36°30'32" -77°20'33" 18.6 Norfolk NoB
19-7W C.C.Woodard Northampton 36°30'18" -77°20'10" 85.6 Norfolk NoA
19-8W C.C.Woodard Northampton 36°30'15" -77°20'29" 10.9 Norfolk NoB
19-9W C.C.Woodard Northampton 36°30'35" -77°20'21" 15.7 Norfolk NoB
19-10W C.C.Woodard Northampton 36°31'25" -77°20'54" 3.9 Bonneau-BoB
19-11W C.C.Woodard Northampton 36°31'28" -77°20'44" 29.5 Bonneau-BoB
19-12W C.C.Woodard Northampton 36°31'43" -77°20'25" 4.6 Bonneau-BoB
19-13W C.C.Woodard Northampton 36°31'12" -77°20'10" 7.9 Norfolk NoB
19-14W C.C.Woodard Northampton 36°31'19" -77°20'10" 9.3 Norfolk NoB
19-15W C.C.Woodard Northampton 36°31'26" -77°20'10" 11 Norfolk NoB
19-1G C.C.Woodard Northampton 36°32'09" -77°21'07" 48.6 Altavista-AtA
19-2G C.C.Woodard Northampton 36°32'17" -77°21'22" 13.6 Tarboro-TaB
19-3G C.C.Woodard Northampton 36°32'26" -77°21'03" 36.2 Altavista-AtA
19-4G C.C.Woodard Northampton 36°32'43" -77°20'57" 42.5 Wickham-WkA
19-5G C.C.Woodard Northampton 36°32'39" -77°21'13" 20.7 Roanoke-Ro
21-1 C.G.Perry Northampton 36°25'48" -77°20'07" 19.6 Norfolk NoB
21-2 C.G.Perry Northampton 36°25'39" -77°20'45" 29.2 Caroline-CaB
21-3 C.G.Perry Northampton 36°25'38" -77°20'17" 11.2 Caroline-CaB
21-4 C.G.Perry Northampton 36°25'29" -77°20'34" 3.3 Norfolk-NoA
21-5 C.G.Perry Northampton 36°25'31" -77°20'37" 9.3 Norfolk NoB
21-6 C.G.Perry Northampton 36°25'26" -77°20'31" 4.0 Norfolk NoB
21-7 C.G.Perry Northampton 36°25'25" -77°20'25" 6.2 Norfolk NoB
21-8 Robert Jones Robert Jones Northampton 36°25'12" -77°20'28" 50.4 Norfolk NoA
WQ0012404 Version:3.0 Attachment B Page 13 of 16

ATTACHMENT B-Approved Land Application Sites Certification Date:February 19,2021
CF Nitrogen,Inc. Permit Number:WQ0012404 Version:3.0
Site/
Field Owner Lessee County Latitude Longitude Net Acreage Dominant Soil Series Footnotes
21-10 C.G.Perry Northampton 36°23'41" -77°24'16" 44.3 Norfolk NoB
21-11 C.G.Perry Northampton 36°27'57" -77°25'57" 33.7 Craven-CrA
21-13 C.G.Perry Northampton 36°27'40" -77°25'35" 15.4 Norfolk-NoA
21-14A C.G.Perry Northampton 36°27'28" -77°25'40" 13.8 Goldsboro-GoA
21-14B C.G.Perry Northampton 36°27'34" -77°25'39" 18.0 Goldsboro-GoA
21-15 C.G.Perry Northampton 36°27'34" -77°25'16" 17.5 Goldsboro-GoA
21-16 C.G.Perry Northampton 36°27'28" -77°25'16" 5.7 Goldsboro-GoA
21-17 C.G.Perry Northampton 36°25'40" -77°21'08" 4.5 Norfolk-NoA
21-18 Robert Jones Robert Jones Northampton 36°25'28" -77°21'13" 6.7 Norfolk-NoA
21-20 Robert Jones Robert Jones Northampton 36°25'23" -77°21'12" 3.7 Norfolk-NoA
21-21 Robert Jones Robert Jones Northampton 36°25'34" -77°21'02" 31.4 Norfolk-NoA
21-22 Robert Jones Robert Jones Northampton 36°25'25" -77°21'02" 5.7 Goldsboro-GoA
22-1 Charles J.Stephenson Northampton 36°27'24" -77°24'58" 23.7 Goldsboro-GoA
22-2 Charles J.Stephenson Northampton 36°27'21" -77°24'49" 19.6 Goldsboro-GoA
22-3 Charles J.Stephenson Northampton 36°27'17" -77°24'38" 11.4 Goldsboro-GoA
22-4 Charles L Stephenson Northampton 36°26'56" -77°24'31" 9.8 Goldsboro-GoA
22-5 Charles J.Stephenson Northampton 36°25'44" -77°23'58" 6.9 Goldsboro-GoA
27-1 Neil Burgess Stephen Burgess Northampton 36°20'00" -77°12'50" 47.8 Norfolk NoA
27-2 Neil Burgess Stephen Burgess Northampton 36°26'00" -77°12'36" 56.4 Norfolk NoA
27-3 Neil Burgess Stephen Burgess Northampton 36°25'54" -77°12'27" 25.5 Rains Ra
27-4 Neil Burgess Stephen Burgess Northampton 36°25'41" -77°12'41" 27.5 Norfolk NoA
27-5 Neil Burgess Stephen Burgess Northampton 36°25'18" -77°12'39" 16.0 Norfolk-NoA
27-6 Stephen Burgess Stephen Burgess Northampton 36°26'07" -77°11'22" 53.4 Bonneau-BoB
27-7 Judi B.Burgess Stephen Burgess Northampton 36°24'20" -77°13'28" 13.9 Craven-CrA
27-8 Judi B.Burgess Stephen Burgess Northampton 36°23'59" -77°14'10" 17.7 Norfolk NoB
WQ0012404 Version:3.0 Attachment B Page 14 of 16

ATTACHMENT B-Approved Land Application Sites Certification Date:February 19,2021
CF Nitrogen,Inc. Permit Number:WQ0012404 Version:3.0
Site/
Owner Lessee County Latitude Longitude Net Acreage Dominant Soil Series Footnotes
Field
27-9 Lori S.Burgess Northampton 36°23'56" -77°13'57" 18.6 Caroline-CaA
27-10 Stephen Burgess Northampton 36°23'52" -77°13'51" 20.3 Craven-CrA
27-11 Stephen Burgess Northampton 36°23'42" -77°13'50" 23.4 Craven-CrA
27-12 Stephen Burgess Northampton 36°23'39" -77°13'40" 16.7 Craven-CrA
27-13 Stephen Burgess Northampton 36°23'34" -77°13'13" 5.2 Craven-CrA
27-14 Lori S.Burgess Stephen Burgess Northampton 36°24'34" -77°16'04" 14.7 Goldsboro-GoA
27-15 Stephen Burgess Northampton 36°26'31" -77°17'10" 6.5 Norfolk—NoB
27-16 Stephen Burgess Northampton 36°26'27" -77°17'02" 5.1 Norfolk—NoB
27-17 Stephen Burgess Northampton 36°26'32" -77°16'52" 21.9 Norfolk—NoB
27-18 Lori S.Burgess Northampton 36°26'10" -77°14'39" 11.1 Goldsboro-GoA
27-19 Lori S.Burgess Northampton 36°26'18" -77°14'24" 18.4 Goldsboro-GoA
27-20 Eloise T.Ward Stephen Burgess Northampton 36°26'20" -77°14'17" 12.9 Goldsboro-GoA
27-21 Eloise T.Ward Stephen Burgess Northampton 36°26'19" -77°14'13" 3.8 Goldsboro-GoA
27-22 Eloise T.Ward Stephen Burgess Northampton 36°26'34" -77°14'15" 6.7 Goldsboro-GoA
27-23 Eloise T.Ward Stephen Burgess Northampton 36°27'49" -77°15'27" 32.5 Bonneau-BoB
27-24 Eloise T.Ward Stephen Burgess Northampton 36°28'07" -7715'16" 21.5 Bonneau-BoB
27-25 Eloise T.Ward Stephen Burgess Northampton 36°28'04" -77°14'45" 35.2 Bonneau-BoB
27-26 Eloise T.Ward Stephen Burgess Northampton 36°27'53" -77°14'41" 11.5 Norfolk-NoB
27-27 Eloise T.Ward Stephen Burgess Northampton 36°28'02" -77°14'34" 14.4 Norfolk NoB
27-28 Eloise T.Ward Stephen Burgess Northampton 36°27'52" -77°14'25" 25.3 Norfolk NoB
27-29 Eloise T.Ward Stephen Burgess Northampton 36°27'45" -77°14'17" 60.5 Norfolk NoB
27-30 Eloise T.Ward Stephen Burgess Northampton 36°28'11" -77°14'51" 5.7 Autryville-AuA
27-31 Eloise T.Ward Stephen Burgess Northampton 36°28'16" -77°14'52" 10.5 Norfolk—NoA
27-32 Eloise T.Ward Stephen Burgess Northampton 36°28'21" -77°14'52" 26.0 Bonneau BoB
27-33 Eloise T.Ward Stephen Burgess Northampton 36°28'21" -77°14'42" 9.9 Norfolk NoA
WQ0012404 Version:3.0 Attachment B Page 15 of 16

ATTACHMENT B-Approved Land Application Sites Certification Date:February 18,2022
CF Nitrogen,Inc. Permit Number:WQ0012404 Version:3.0
Site/
Field Owner Lessee County Latitude Longitude Net Acreage Dominant Soil Series Footnotes
27-34 Eloise T.Ward Stephen Burgess Northampton 36°28'26" -77°14'30" 17.6 Bonneau—BoB
27-35 Eloise T.Ward Stephen Burgess Northampton 36°28'30" -77°14'18" 9.1 Goldsboro GoA
27-36 Eloise T.Ward Stephen Burgess Northampton 36°28'24" -77°13'57" 9.3 Autryville—AuA
27-37 Eloise T.Ward Stephen Burgess Northampton 36°28'23" -77°14'12" 17.2 Autryville—AuA
27-38 Eloise T.Ward Stephen Burgess Northampton 36°28'10" -77°14'09" 3.0 Norfolk-NoA
27-39 Kevin B.Burgess Stephen Burgess Northampton 36°26'40" -77°12'40" 20.6 Norfolk-NoB
27-40 Kevin B.Burgess Stephen Burgess Northampton 36°26'33" -77°12'35" 21.0 Norfolk-NoB
27-41 Stephen Burgess Northampton 36°27'33" -77°11'45" 9.8 Norfolk-NoB
27-42 Stephen Burgess Northampton 36°27'43" -77°11'32" 93.5 Bonneau—BoB
27-43 Stephen Burgess Northampton 36°27'35" -77°11'21" 17.7 Norfolk NoB
27-44 Stephen Burgess Northampton 36°27'43" -77°11'11" 29 Bonneau BoB
27-45 Stephen Burgess Northampton 36°27'49" -77°11'04" 18 Norfolk NoB
27-46 Stephen Burgess Northampton 36°27'27" -77°11'18" 13.9 Bonneau BoB
27-47 Stephen Burgess Northampton 36°27'36" -77°11'06" 20.8 Bonneau-BoB
27-48 Kevin B.Burgess Stephen Burgess Northampton 36°27'31" -77°10'15" 14.8 State StA
27-49 Kevin B.Burgess Stephen Burgess Northampton 36°27'27" -77°10'07" 6.1 Tarboro TaB
27-50 Kevin B.Burgess Stephen Burgess Northampton 36°27'38" -77°09'59" 17.9 Altavista—AtA
27-51 Kevin B.Burgess Stephen Burgess Northampton 36°27'38" -77°09'40" 52.7 Tarboro—TaB
27-65 Bobby Bridges Neil Bridges Northampton 36°25'50" -77°15'O1" 67.3 Bonneau—BoB
27-66 Neil&Donna B.Burgess Northampton 36°24'50" -77°15'10" 18.1 Norfolk-NoB
27-67 Fannie Bryant(Maria R.Jones Trustee) Stephen Burgess Northampton 36°27'46" 77°10'47" 33.7 Bonneau-BoB
27-68 Martha Pearlman Northampton 36°30'5" 77°11'14" 58.0 Goldsboro-GoA
27-69 Ronald Woodard Northampton 36°29'56" 77°11'18" 42.2 Gritney-GxB
27-70 Ronald Woodard Northampton 36°28'54" 77°12'25" 85.4 Lynchburg-Ly
27-71 Stephen Burgess Northampton 36°27'29" 77°15'27" 61.8 Bonneau BoB
27-72 Stephen Burgess Northampton 36°27'28" 77°15'5" 39.7 Bonneau BoB
27-73 Stephen Burgess Northampton 36°27'11" 77°15'14" 74.9 Norfolk-NoA
County Total Northampton 3,026.2
Permit Total 7,968.6
WQ0012404 Version:3.0 Attachment B Page 16 of 16

Landowner Agreement Attachments & Lessee Agreement
Attachments
(NO NEW AGREEMENTS WERE OBTAINED IN 2021)

Groundwater Data

IF
s &
s
III ;
Annual Groundwater Monitoring Report
CF Nitrogen, Inc.
Cofield, North Carolina
S&ME Project No. 211218
PREPARED ON BEHALF OF:
CF Industries Holdings, Inc.
4 Parkway North
Suite 400
Deerfield, IL
PREPARED BY:
S&ME, Inc.
3201 Spring Forest Road
Raleigh, NC 27616
February 18, 2022

p
February 18, 2022
North Carolina Department of Environmental Quality
Division of Water Resources— UIC Program
1636 Mail Service Center
Raleigh, NC 27699-1636
Attention: Non-Discharge Permitting Unit
Reference: Groundwater Monitoring Report Permit No. WQ0012404
January 1, 2021 through December 31, 2021
CF Nitrogen, Inc.
Cofield, North Carolina
EPA ID No. NCD065288847
S&ME Project No. 211218
Non-Discharge Permitting Unit:
On behalf of CF Nitrogen, Inc. (CFN), a wholly-owned subsidiary of CF Industries Holding, Inc. (CFIH), S&ME, Inc.
(S&ME) is submitting the calendar year 2021 annual groundwater monitoring report for the CFN site located in
Cofield, North Carolina (Figure 1) as required by the Land Application Permit (Permit No. WQ0012404, effective
January 1, 2021). S&ME completed this annual report while under contract with CFIH.
Groundwater Recovery and Distribution Volumes
Based on weekly flow meter readings recorded from Transfer Pump Station #1 beginning December 24, 2020, and
ending December 31, 2021, approximately 15,554,600 gallons of groundwater were removed from the confined
shallow aquifer in 2021.
Quarterly flow amounts for 2021 Transfer Pump Station #1 were as follows:
1st Quarter(January— March 2021): 3,020,600 gallons
2nd Quarter(April —June 2021): 4,048,600 gallons
3rd Quarter(July— September 2021): 3,434,700 gallons
4th Quarter(October— December 2021): 5,050,700 gallons
Total Groundwater Recovery for 2021: 15,554,600 gallons
Based on flow meter readings from Transfer Pump Station #2, approximately 14,795,000 gallons of water were
transferred from the storage basin for subsequent land application.
The nitrogen-enriched groundwater was applied to a variety of crops throughout the year including wheat,
soybeans, and fescue. The following volumes of groundwater may differ slightly to those reported in the land
application report, because meter readings were recorded on dates when weekly inspections were conducted,
which may have been different than the days readings were recorded by the land application contractor. The flow
S&ME, Inc.13201 Spring Forest Road I Raleigh, NC 27616 I p 919.872.2660 I www.smeinc.com

Groundwater Monitoring Report Permit No. WQ0012404
January 1, 2021 through December 31, 2021
CF Nitrogen, Inc.
Cofield, North Carolina
EPA ID No. NCD065288847
S&ME Project No. 211218
volumes were recorded during weekly inspections and summed to calculate quarterly volumes of groundwater
that were land applied to agricultural fields.
Quarterly amounts for 2021 were as follows:
1st Quarter(January— March 2021): 3,150,000 gallons
2nd Quarter(April —June 2021): 3,650,000 gallons
3rd Quarter(July— September 2021): 3,562,000 gallons
4th Quarter(October— December 2021): 4,440,000 gallons
Total Groundwater Applied for 2021: 14,802,000 gallons
The total annual recorded rainfall at the subject CFN site was 42.37 inches, compared with the annual average of
46 inches for the area. Groundwater pumping for land application efforts for 2021, on average, maintained the
groundwater elevation within the slurry wall below 30 feet mean sea level (ft-msl).There were transitory
exceptions early in the year followed by improved groundwater elevations.
Onsite groundwater elevations were measured quarterly during 2021 (January, April,July, and October). The
groundwater elevations recorded from October 27, 2020, through January 25, 2022, are presented in Table 1. As
required in the permit, potentiometric maps showing quarterly interpretations of general groundwater elevations
based on end-of-month measurements for January, April,July, and October 2021 are included as Figures 2, 3, 4
and 5.
As required in Attachment C of the Non-Discharge Permit, cross-sectional views of water levels measured in
piezometers PI-11 — P0-12 and PI-2— P0-236 were prepared and are attached as Figures 2A, 3A, 4A and 5A for
each corresponding quarterly potentiometric map. Additional cross-sectional views of water levels measured in C-
designated wells C-23—C-22, C-29—C-28 are included as Figures 2B, 3B, 4B and 5B, and cross-sectional views of
C-33-C-32 and monitor wells MWI-4— MWI-6 are depicted in Figures 2C, 3C, 4C and 5C. The history of water
levels for piezometers PI-2, PI-11, P0-12 and P0-236 is graphically shown in Figure 6. The historical water level
data from the oldest C-designated wells on site (C-22, C-23, C-28, C-29, C-32 and C-33) are graphically shown in
Figure 7. Historical water level elevation data for MWI-3, MWI-4 and MWI-6 are depicted in Figure 8.
Precipitation events were recorded by an on-site rain gauge. The monthly precipitation totals for calendar year
2021 are presented in Table 2. Monthly recorded rainfall on-site ranged from 1.19 inches in October 2021 to a
season high of 7.09 inches in June 2021. The average monthly rainfall amounts for Cofield, North Carolina
(according to precipitation data from the USA.com website, www.USA.com), are presented on Table 2 and
depicted on Figure 9.
The amount of rainfall at the site in 2021 was approximately 3.6 inches less than the average rainfall reported for
Cofield, North Carolina.
February 18, 2022 2

Groundwater Monitoring Report Permit No. WQ0012404
January 1, 2021 through December 31, 2021
CF Nitrogen, Inc.
Cofield, North Carolina
EPA ID No. NCD065288847
S&ME Project No. 211218
Should you have any questions, please do not hesitate to contact us.
Sincerely,
S&ME, Inc.
Aci:)(ANAAr.'.
Cody McMechen Edmund Q. B. Henriques, P.G.
Environmental Staff Professional Principal Geologist/Senior Project
[e-mail] [e-mail]
cc: Ms. Diane Diks, CHMM, CPEA (CF Nitrogen, Inc.)
Attachments:
Tables
Table 1: Groundwater Elevation Data
Table 2: Monthly Rainfall 2021
Figures
Figure 1: Site Location Plan
Figure 2: Groundwater Potentiometric Map for January 2021
Figure 2A: Cross-sectional View PI-2— P0-236 & PI-11 — P0-12 for January 2021
Figure 2B: Cross-sectional View C-23—C-22 &C-29—C-28 for January 2021
Figure 2C: Cross-Sectional View C-33 —C-32 & MWI-4— MWI-6 for January 2021
Figure 3: Groundwater Potentiometric Map for April 2021
Figure 3A: Cross-sectional View PI-2— P0-236 & PI-11 — P0-12 for April 2021
Figure 3B: Cross-sectional View C-23—C-22 &C-29—C-28 for April 2021
Figure 3C: Cross-Sectional View C-33 —C-32 & MWI-4— MWI-6 for April 2021
Figure 4: Groundwater Potentiometric Maps for July 2021
Figure 4A: Cross-sectional View PI-2— P0-236 & PI-11 — PO-12 for July 2021
Figure 4B: Cross-sectional View C-23—C-22 &C-29—C-28 for July 2021
Figure 4C: Cross-Sectional View C-33 —C-32 & MWI-4— MWI-6 for July 2021
Figure 5: Groundwater Potentiometric Maps for October 2021
Figure 5A: Cross-sectional View PI-2— P0-236 & PI-11 — P0-12 for October 2021
Figure 5B: Cross-sectional View C-23—C-22 &C-29—C-28 for October 2021
Figure 5C: Cross-Sectional View C-33 —C-32 & MWI-4— MWI-6 for October 2021
Figure 6: Groundwater Elevations for PI-2, PI-11, P0-12, and P0-236
Figure 7: Groundwater Elevations for C-Designated Wells
Figure 8: Groundwater Elevations for MWI-3, MWI-4 and MWI-6
Figure 9: Monthly Rainfall 2021
February 18, 2022 3

Attachments

Attachment I — Tables

= TABLE 1
sr GROUNDWATER ELEVATION DATA
CFO NITROGEN-COF ELLD NORTH CAROLINA
S&ME PROJECT NO.211218
Measurement
Well ID 10/27/2020 1/27/2021 4/16/2021 7/13/2021 10/26/2021 1/25/2022
MWI-1 28.71 30.07 33.39 33.49 29.65 30.65
MWI-2 29.14 30.36 33.06 33.04 30.12 29.92
MWI-3 28.71 30.23 32.15 32.63 29.89 29.25
MWI-4 29.75 30.83 32.79 33.03 30.33 30.21
MWO-5 24.14 25.24 27.62 25.74 24.32 24.04
MWI-6 28.97 30.73 32.83 33.13 29.69 29.53
MWI-7 27.04 29.42 30.74 31.12 27.74 27.42
MWO-8 25.93 29.35 30.33 27.92 26.51 26.21
P1-1 28.51 29.07 31.69 32.83 29.23 29.73
P1-2 28.40 29.20 31.80 32.80 29.10 29.10
P0-3 18.87 18.87 20.81 21.21 20.61 19.57
P1-4 28.75 30.43 32.61 32.93 29.51 29.25
P1-5 28.25 29.85 32.77 32.81 29.17 29.37
P0-6 23.14 23.58 26.18 25.50 24.20 23.06
P1-7 28.70 29.92 32.74 32.82 29.80 29.38
P1-8 26.42 28.34 31.07 30.74 29.46 27.12
P1-9 29.29 29.21 33.21 32.31 30.01 29.31
P1-10 29.24 30.52 33.24 32.20 28.54 29.47
P1-11 26.65 28.89 30.71 30.91 27.67 27.27
P0-12 16.04 16.40 16.80 16.70 16.46 16.28
PI-13R 29.07 30.75 32.95 32.97 30.25 29.65
P1-14 27.84 29.28 31.86 31.68 28.14 28.46
P0-15 24.14 24.68 26.30 25.66 24.80 23.84
P0-16 27.11 29.83 30.95 28.25 26.81 26.69
P1-17 28.42 31.72 33.60 33.10 28.46 30.98
P1-18 28.27 29.87 31.97 32.85 28.87 29.09
P1-19 27.21 28.71 30.91 31.75 28.03 28.33
P1-20 27.88 29.68 31.66 32.90 28.98 29.46
P1-21 28.15 29.85 32.13 32.59 28.85 29.63
P1-22 29.09 30.23 43.13 32.35 29.75 29.45
P1-23 30.32 32.62 33.26 34.00 30.06 31.06
P1-24 28.77 30.03 32.43 31.95 29.53 29.39
P0-25 25.07 25.97 28.17 26.41 25.27 24.17
P0-26 26.87 29.17 29.87 28.49 26.99 26.51
C-22 14.75 14.85 17.25 17.29 16.91 16.05
C-23(Replaced 04/05) 26.83 28.94 31.98 32.38 28.94 29.46
C-28(Repaired 08/03) 8.83 9.97 15.61 10.35 9.51 9.31
C-29 25.82 27.74 29.48 30.36 26.30 25.72
C-32 10.97 12.37 13.17 12.33 11.05 10.51
C-33 26.02 28.12 29.70 30.32 26.68 26.86
C-4 27.76 29.46 31.98 32.12 29.46 29.08
P0-235 15.15 15.85 16.35 17.13 16.35 16.55
P0-236 13.04 14.82 16.62 16.42 14.42 14.14
P0-237 26.95 29.35 29.85 28.19 27.09 27.03

TABLE 2
I'I MONTHLY RAINFALL 2021
CF INDUSTRIES -COFIELD, NORTH CAROLINA
S&ME PROJECT NO. 211218
2021 Average Rainfall for Cofield
Month Recorded Rainfall (inches)
at CFI-Ahoskie Site (inches) www.usa.com
January 3.68 3.60
February 5.93 3.10
March 3.43 4.10
April 2.48 3.50
May 2.48 3.80
June 7.09 4.10
July 6.17 4.80
August 4.82 4.80
September 1.55 4.60
October 1.19 3.20
November 1.19 3.10
December 2.36 3.30
Annual Total: 42.37 46.00
Monthly Average: 3.53 3.83
Recorded rainfall at site taken from on-site rain gauge
Data for average monthly rainfall obtained from the USA.com website for Cofield, NC

Attachment II — Figures

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REFERENCE:ESRI STREETMAP USA DATSET
THIS MAP IS FOR INFORMATIONAL PURPOSES ONLY. ALL FEATURE 0LOCATIONS DISPLAYED ARE APPROXIMATED.THEY ARE NOT BASED ON 4111,101
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CIVIL SURVEY INFORMATION,UNLESS STATED OTHERWISE.
SCALE: FIGURE NO.
& SITE LOCATION PLAN 1 " - 4,000 '
DATE: 1
III = 2-15-22 1
CF NITROGEN INC. PROJECT NUMBER
COFIELD, NORTH CAROLINA 1040-98-044U

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in 14.820 —
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18 30. 0 PI-5
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.74 9.97N8
PO-3QA PI-4 ®RW-4 RW-8
18.870 30.430 SLURRY WALL
19
MWI-4 RW-9 C-32 GRAPHIC SCALE
30.830 29 C-33 / 2.370
p Nam' 400 0 200 400
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20 NQ
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21— 30.230 1--I Z
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o 29.350 ♦ 32.620 az 2> — GROUNDWATER CONTOUR
0 29.350
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(26.63) GROUNDWATER ELEVATION (FEET MEAN SEA LEVEL) SCALE:
N
o PI-17 400
1720A 2e (NM) NOT MEASURED
A •0-16 DATE:
ot
29.830 2/2/2022
L.z
PROJECT NUMBER
a NOTE: 211218
E
PIEZOMETERS PI-18 THRU PI-21 ARE GROUPED NEAR FIGURE NO.
6- PIEZOMETER PI-5 WHICH IS WITHIN THE RADIUS OF INFLUENCE,
WATER LEVELS OF THESE PIEZOMETERS ARE INTENTIONALLY 1
EXCLUDED FROM THIS POTENTIOMETRIC MAP.

45 _ P1-2 P0-236
42.60'MSL(T.O.C.) — 43.62'MSL(T.O.C.)
40
35 SLURRY
WALL
30 —Q 29.20 FT.MSL -30'MSL
25
20
15 -4 14.82 FT.MSL
10
5
0 -
-5
SECTION PI-2 - P0-236
45 — P1-11
— 42.57'MSL(T.O.C.)
P0-12
ai 40 39.20'MSL(T.O.C.)
U _
35 SLURRY
-
o WALL
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o — —Q 28.89 FT. MSL
m _
25
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Q -20O —
-Q 16.40 FT.MSL
15 -
Q _
10
v _
5
N 0
N _
-5 -
0
SECTION PI-11 - P0-12
z
NOTE:
GROUNDWATER DATA COLLECTED ON JANUARY 27,2021
CROSS - SECTIONAL VIEW SCALE: FIGURE NO.
1111 PI-2 - P0-236 & PI-11 - P0-12 1" 15'
DATE:
2-2-2022 2A
III CF NITROGEN, INC. PROJECT NUMBER
COFIELD, NORTH CAROLINA 211218 J

45
C-23
40.48'MSL(T.O.C.) C-22
40 — 39.65'MSL(T.O.C.) —
35 SLURRY
WALL
30 -Q 29.94 FT.MSL -30'MSL
25
20
15 14.85 FT.MSL Q-
10
5
0 -
-5 -
SECTION C-23 - C-22
45 C-29
— 43.14'MSL(T.O.C.)
— C-28
40 — — 39.01'MSL(T.O.C.)
s —
35 SLURRY
o WALL
30 -30'MSL
°0- — —Q 27.74 FT. MSL
25
C
Q 20 O —
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15
a
Q
10 _ — -Q 9.97 FT.MSL
v —
5 - -
Z
N 0
N
0 -5
SECTION C-29 - C-28
z
NOTE:
GROUNDWATER DATA COLLECTED ON JANUARY 27,2021
CROSS - SECTIONAL VIEW SCALE: FIGURE NO.
C-23 - C22 & C-29 - C28 1" 15'
DATE:
2-2-2022 2B
III CF NITROGEN, INC. PROJECT NUMBER
COFIELD, NORTH CAROLINA 211218 J

IN
45
C-33
40 — - 39.40'MSL(T.O.C.)
C-32
36.85'MSL(T.O.C.) -
35 _ SLURRY
WALL
30 --30'MSL
—Q 28.12 FT.MSL
25
20
15
12.37 FT.MSL Q-
10
5
0
-5
SECTION C-33 - C-32
50 _
MWI-6
MWI-3 46.31'MSL(T.O.C.) -
45 - 44.93'MSL(T.O.C.)
MWI-4
42.03'MSL(T.O.C.) —
a, 40
z
U _
35
N -
30 30.83 FT.MSL Q— —SZ 3023 FT.MSL 30.73 FT.MSL II—
o
a
w
25
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O
15
a
10
v _
5
0
N -
-5
SECTION MWI-4, MWI-3, MWI-6
z
NOTE:
GROUNDWATER DATA COLLECTED ON JANUARY 27,2021
CROSS - SECTIONAL VIEW SCALE: FIGURE NO.
C-33 - C-32 & MWI-4, MWI-3, MWI-6 1" = 15'
DATE:
2-2-2022 2C
III CF NITROGEN, INC. PROJECT NUMBER
COFIELD, NORTH CAROLINA 211218 J

AT
III
16620 III _
31. C-22
P0-235 17.250
16.350Q
t
Q PI-1 C-23
31.690 ®RW-2
32 31.980 n.
17
39-
18
( RW-1
®RW-5
MWI-1 16
19 33.390 Q PI-5
32.770
®RW-3 ®. 0 RW-7 d, C-28
15.605 20 -6 C-29
29.48 ^
PO-3QQ PI-4 / ®RW-4 SLURRY WALL
.W-8
20.810 32.610 a
21
GRAPHIC SCALE
,,., •MWI-4 ®RW-9 C-32 400 0 200 400 r 1
30.830 13.170 v
C-33 �
29.700 1Q ( IN FEET )
22 \.-0
N w Q
Q PI-8 ,5 �I N Z
'� 31.070 iC
MWI-3 O C V O
23 32.150 �6 1--I N Z *k ce
vS # U
PI-11 Z w w r
24 30.710Q . P0-12 W H�./ Fe 4t I
A WI-2 16.800 I-�I ~ #
Pr 33.060
O # Ce
O
U, MWI.7 7j P.4 0 *k z
25 c \ 30.740 7g a #
LLIja-
cs)
a PI-7 MWI-6 99 g ULL
O 32.740 33 32.830 el0
o `Lco Q Pc 6 2p U
6 26.1::
u 2, ~
z
0 22
0.
j 2�
0
a ti^ PI-9 Q PI-10 PI-14 2
N 31.860 33.210 33.240 A4 LEGEND
o 7.O5 2S
c 5
27.6 C--3'2 r _ 5
m c (NM) , 26.300 S MONITOR WELL
Q liv 31. 80 MWI-9 ''a t PI-24 �� ® RECOVERY WELL
32.430
A PI-22
0 PIEZOMETER
o AL33.1 33.130
P0-25 33 ' R
LU z 27.170 ,32.9v 4ti - GROUNDWATER CONTOUR
. ry w
N RWO A PI-23
30.330
A
% PO-2 o 6
_233.260 2,9 (26.63) GROUNDWATER ELEVATION (FEET MEAN SEA LEVEL) SCALE:
O 29.87oQ -' 29.850 400
N
(NM) NOT MEASURED DATE:
°' �o PI-17 J / /
so0� *WELL C-4 NOT CONSIDERED FOR CONTOURING 2 2 2022
A '0-16
30.950 PROJECT NUMBER
Q NOTE: 211218
.m PIEZOMETERS PI-18 THRU PI-21 ARE GROUPED NEAR FIGURE NO.
6 PIEZOMETER PI-5 WHICH IS WITHIN THE RADIUS OF INFLUENCE,
WATER LEVELS OF THESE PIEZOMETERS ARE INTENTIONALLY 2
\ EXCLUDED FROM THIS POTENTIOMETRIC MAP.
si

45 _ PI-2 P0-236
42.60'MSL(T.O.C.) — 43.62'MSL(T.O.C.)
40
35 SLURRY
WALL
30 -Q 29.20 FT.MSL -30'MSL
25
20
-Q 16.62 FT.MSL
15
10
5
0 -
-5
SECTION PI-2 - P0-236
45 — PI-11
— — 42.57'MSL(T.O.C.)
P0-12
40 39.20'MSL(T.O.C.)
35 SLURRY
—
o WALL
—Q 30.71 FT. MSL 30 30'MSL
0
a
25
C
Q -
20
o — -Q 16.80 FT.MSL
15
-
Q
10
v _
5
N 0
N _
-5 -
0
SECTION PI-11 - P0-12
z
NOTE:
GROUNDWATER DATA COLLECTED ON APRIL 16,2022
CROSS - SECTIONAL VIEW SCALE: FIGURE NO.
PI-2 - P0-236 & PI-11 - P0-12 1" 15'
DATE:
2-2-2022 3A
III CF NITROGEN, INC. PROJECT NUMBER
COFIELD, NORTH CAROLINA 211218 J

45
C-23
40.48'MSL(T.O.C.) C-22
40 _ 39.65'MSL(T.O.C.) —
35 SLURRY
—2 31.98 FT.MSL WALL
30 -30'MSL
25
20
17.25 FT.MSL 2-
15
10
5
0 —
-5 —
SECTION C-23 - C-22
45 C-29
_ — 43.14'MSL(T.O.C.)
— C-28
40 — — 39.01'MSL(T.O.C.)
35 SLURRY
o — WALL
30 —2 29.48 FT. MSL -30'MSL
o
a
m
25
C
Q _
20 O -
-
O -
-
15 —2 15.605 FT.MSL
-
10
v
5 —
N 0
N _
-5
SECTION C-29 - C-28
z
▪ NOTE:
GROUNDWATER DATA COLLECTED ON APRIL 16,2021
CROSS - SECTIONAL VIEW SCALE: FIGURE NO.
C-23 - C22 & C-29 - C-28 " _ 5'
DATE:
2-2-2022 3B
III CF NITROGEN, INC. PROJECT NUMBER
COFIELD, NORTH CAROLINA 211218 J

p
45
C-33
40 — — 39.40'MSL(T.O.C.)
C-32
36.85'MSL(T.O.C.) —
35 _ SLURRY
WALL
30 —2 29.70 FT.MSL -30'MSL
25
20
15 13.17 FT.MSL 2—
10
5
0
-5
SECTION C-33 - C-32
50 _
MWI-6
MWI-3 46.31'MSL(T.O.C.) —
45 — 44.93'MSL(T.O.C.)
MWI-4
— 42.03'MSL(T.O.C.) -
40 _
35 _
o — 32.79 FT.MSL 2— —2 32.15 FT.MSL 32.83 FT.MSL 2-
30
v
25
Q _
20 O _ _
O -
- 15
a 10
v _
5
La-
N 0
N -
-5
SECTION MWI-4, MWI-3, MWI-6
z
NOTE:
GROUNDWATER DATA COLLECTED ON APRIL 16,2021
CROSS - SECTIONAL VIEW SCALE: FIGURE NO.
C-33 - C-32 & MWI-4, MWI-3, MWI-6 1" = 15'
DATE:
2-2-2022 3 C
III CF NITROGEN, INC. PROJECT NUMBER
COFIELD, NORTH CAROLINA 211218

AT
iilfi
P0-236 III -
16.420
32. C-22
P0-235 -I 17.290
17.130A 16
1
QPI-1 C-23
32.830 ®RW-2
32.380
18 o o
33 ,''
19
®RW-1 (®RW-5 KL
Allk_MW1-1
20 33.490 A PI-5
32.810 .�
1
®RW 3 ®RW-6 Q RW-7 C-29 1 C-28
21 30.36 10.345
T
SLURRY WALL
PO-300 PI �®RW-4 ' -8® GRAPHIC SCALE
21.210 32."30 ,3,, T 400 0 200 400 "--"
w H
MWI-4 ®RW-9 C-32
22 33.030 41 2.330 ( IN FEET )
C-33
30.320, \ W Q
NI,, N Z
,p 33 0 PI-8 O o U O
23 30.740 ,g i--i ,�N// Z
MWI-3 F"� FBI N #
32.630 6 Z W w It U
W E. 2 * _
PI-11 E N #
30.910 A P0-12
-2 16.700 0
24 MWI # Z
33.040 w Z
0
a M LL
�,, 31.120 31 7) W U W
a en
25 7g U
N PI-7 MWI-6
0
N 32.820
33.130 /�
QPc 6 79 ICI
L) 25.5I:
0 20
a
a 33
73 2,
a 22 LEGEND C7
N PI-9 32.200 PI-14
32.310 3'3 31.680 A 2�
40-6 A & MONITOR WELL
25.7,
24
a
C-4 (NM 25.660
a 26 32.120 MWI• ® RECOVERY WELL
'IlA PI-24 32- 2E o PIEZOMETER
a 31.960
2
2 A PI-22
V
P0-25 A 32.350 Pi 3R - GROUNDWATER CONTOUR
CO 26.410 ^ '3..970
ry MWO-8`� 34 2) (26.63) GROUNDWATER ELEVATION (FEET MEAN SEA LEVEL) SCALE:
34.0 400
N 27.92OQry� -�34.000 (NM) NOT MEASURED
P0-26 28.190
v 28.490 DATE:
0
PI-17 2/2/2022
.1000 28 PROJECT NUMBER
A -0-16 NOTE: 211218
o 28.250
o
PIEZOMETERS PI-18 THRU PI-21 ARE GROUPED NEAR FIGURE NO.
o PIEZOMETER PI-5 WHICH IS WITHIN THE RADIUS OF INFLUENCE,
WATER LEVELS OF THESE PIEZOMETERS ARE INTENTIONALLY
EXCLUDED FROM THIS POTENTIOMETRIC MAP.
1

45 _ PI-2 P0-236
42.60'MSL(T.O.C.) — 43.62'MSL(T.O.C.)
40
—Q 32.80 FT.MSL
35 SLURRY
WALL
30 -30'MSL
25
20
—Q 16.42 FT.MSL
15
10
5
0 -
-5
SECTION PI-2 - P0-236
45 — PI-11
— — 42.57'MSL(T.O.C.)
P0-12
40 39.20'MSL(T.O.C.)
35 SLURRY
WALL
30 —Q 30.91 FT. MSL -30'MSL
0
a
25
C
Q —
20
4 _ —Q 16.70 FT.MSL
15
-
Q
10
v _
5
N 0
N _
-5 -
0
SECTION PI-11 - P0-12
z
NOTE:
GROUNDWATER DATA COLLECTED ON JULY 13,2021
CROSS - SECTIONAL VIEW SCALE: FIGURE NO.
PI-2 - P0-236 & PI-11 - P0-12 1" 15'
DATE:
2-2-2022 4A
III CF NITROGEN, INC. PROJECT NUMBER
COFIELD, NORTH CAROLINA 211218 J

45
C-23
40.48'MSL(T.O.C.) C-22
40 _ 39.65'MSL(T.O.C.) —
35 SLURRY
—Q 32.38 FT.MSL WALL
30 -30'MSL
25
20
17.29 FT.MSL Q-
15
10
5
0 —
-5 —
SECTION C-23 - C-22
45 C-29
— 43.14'MSL(T.O.C.)
C-28
a, 40 — — 39.01'MSL(T.O.C.)
35 SLURRY
o — WALL
Q —
30 —4 30.36 FT. MSL -30'MSL
o
a
m
a 25
a
Q _
20 O -
O
15 —
Q
Q
10 — —Q 10.345 FT.MSL
v _
a,
5 —
N 0
N _
-5
SECTION C-29 - C-28
z
▪ NOTE:
GROUNDWATER DATA COLLECTED ON JULY 13,2021
CROSS - SECTIONAL VIEW SCALE: FIGURE NO.
C-23 - C22 & C-29 - C-28 1" 15'
DATE:
2-2-2022 4B
III CF NITROGEN, INC. PROJECT NUMBER
COFIELD, NORTH CAROLINA 211218 J

p
45
C-33
40 — — 39.40'MSL(T.O.C.)
C-32
36.85'MSL(T.O.C.) —
35 _ SLURRY
WALL
30 —4 30.32 FT.MSL -30'MSL
25
20
15
12.33 FT.MSL 2-
10
5
0
-5
SECTION C-33 - C-32
50 _
MWI-6
MWI-3 46.31'MSL(T.O.C.) —
45 — 44.93'MSL(T.O.C.)
MWI-4
— 42.03'MSL(T.O.C.) -
40 _
35 _
33.03 FT.MSL Q— —4 32.63 FT.MSL 33.13 FT.MSL 0—
30
v
25
Q _
20 O _ _
O -
- 15
a 10
v _
5
La-
N 0
N -
-5
SECTION MWI-4, MWI-3, MWI-6
z
NOTE:
GROUNDWATER DATA COLLECTED ON JULY 13,2021
CROSS - SECTIONAL VIEW SCALE: FIGURE NO.
C-33 - C-32 & MWI-4, MWI-3, MWI-6 1" = 15'
DATE:
2-2-2022 4 C
III CF NITROGEN, INC. PROJECT NUMBER
COFIELD, NORTH CAROLINA 211218

fa
N 1
P 4 420 PIL_
29.1 I C-22
P0-235 16.910 A
16.350A IF ,\5
Q PI-1 .23
16 29.230 ®RW-2
28.94e
v M
®RW_I ®RW-5 ,\N
AAA MWI-1 '-
18 MY 29.650 A PI-5
29.170 ,LW ^O
®RW-3
®RW-6 ® W-7 C-29 1 C-28
26.301A IF 9.5Q5
P0-3QA PI-4 ®RW-4 J ^
W-g®
20.610 29.510 SLURRY WALL
GRAPHIC SCALE ..t
19 3 400 0 200 400
M I-4 ®RW-9 C-32 30. 0 1 1.050 U
C-33 I FH
.9 P6.680. 1 ( IN FEET )
20
\b‘ W Q
A PI-8
29.,''ee 27 \5 N J
MWI-3 O Q U
21 29.890 CVZ
^6 lit Q
PI-11
z W LU 1* U
3° 27.670A A P0-12 W H 2 it I
22 O
Y A_Ak_MW1- 16.460 D it O
3 0 r��� N * CC
MWI-7 P-I o *k z
27.740 7) �j a a, 6T4L—L # a.
23— w,
B
a PI-7 MWI-6 U 0
_ai 29.800 29.690
^' A P e 6 2g 7,9 U
o
0 24.2 e e
a 20
z
27
Occ
30 22
a A PI-9 28.540 PI-14
30.00 28.140 A 20 LEGEND
tih .�0-5 A
0 24.3 a ( �2 ��_ 5
_ 2
C-4 (NM) 2' `0° 4 % MONITOR WELL
Q 29.460 MWI-9 2s
2 • t PI-24 ® RECOVERY WELL
29.530
o P0-25 A' Pt-250 P01-13R 26 o PIEZOMETER
z 25.270 ti\ti `,30.250
U — GROUNDWATER CONTOUR
N �' `\°j I WO-: PI-23
26.510A-. 30.060 2>
•-2 (26.63) GROUNDWATER ELEVATION (FEET MEAN SEA LEVEL) SCALE:
`- PO-26 27 090
0 26.990 400
9 (NM) NOT MEASURED DATE:
o PI-17
:.a6o� 28 2/2/2022
w A '0-16
26.810 PROJECT NUMBER
Q NOTE: 211218
PIEZOMETERS PI-18 THRU PI-21 ARE GROUPED NEAR FIGURE NO.
6 PIEZOMETER PI-5 WHICH IS WITHIN THE RADIUS OF INFLUENCE,
WATER LEVELS OF THESE PIEZOMETERS ARE INTENTIONALLY 4
EXCLUDED FROM THIS POTENTIOMETRIC MAP.

45 _ PI-2 P0-236
42.60'MSL(T.O.C.) — 43.62'MSL(T.O.C.)
40
35 SLURRY
WALL
30 — -Q 29.10 FT.MSL 30'MSL
25
20
15 -Q 14.42 FT.MSL
10
5
0 -
-5
SECTION PI-2 - P0-236
45 — PI-11
— — 42.57'MSL(T.O.C.)
P0-12
40 39.20'MSL(T.O.C.)
35 _ SLURRY
o — WALL
30 -30'MSL
o
a
—Q 26.65 FT. MSL
25
C
Q -
20
- -Q 16.04 FT.MSL
15
-
Q
10
v _
5
N 0
N _
-5 -
0
SECTION PI-11 - P0-12
z
NOTE:
GROUNDWATER DATA COLLECTED ON OCTOBER 26,2021
CROSS - SECTIONAL VIEW SCALE: FIGURE NO.
PI-2 - P0-236 & PI-11 - P0-12 1" 15'
DATE:
2-2-2022 5A
III CF NITROGEN, INC. PROJECT NUMBER
COFIELD, NORTH CAROLINA 211218 J

45
C-23
40.48'MSL(T.O.C.) C-22
40 _ 39.65'MSL(T.O.C.) —
35 SLURRY
WALL
30 -30'MSL
—Q 26.30 FT.MSL
25
20
16.91 FT.MSL Q-
15
10
5
0 —
-5 —
SECTION C-23 - C-22
45 C-29
— 43.14'MSL(T.O.C.)
— C-28
40 — — 39.01'MSL(T.O.C.)
35 _ SLURRY
o — WALL
30 -30'MSL
o
a
_ —Q 26.30 FT. MSL
25
C
Q _
20 O -
O -
15
-
Q
10 — —Q 9.505 FT.MSL
v _
5 —
N 0
N _
-5
SECTION C-29 - C-28
z
▪ NOTE:
GROUNDWATER DATA COLLECTED ON OCTOBER 26,2021
CROSS - SECTIONAL VIEW SCALE: FIGURE NO.
C-23 - C22 & C-29 - C-28 1" 15'
DATE:
2-2-2022 5B
III CF NITROGEN, INC. PROJECT NUMBER
COFIELD, NORTH CAROLINA 211218 J

p
45
C-33
40 — — 39.40'MSL(T.O.C.)
C-32
36.85'MSL(T.O.C.) —
35 _ SLURRY
WALL
30 -30'MSL
—2 26.68 FT.MSL
25
20
15
10 11.05 FT.MSL 2—
5
0
-5
SECTION C-33 - C-32
50 _
MWI-6
MWI-3 46.31'MSL(T.O.C.) —
45 — 44.93'MSL(T.O.C.)
MWI-4
— 42.03'MSL(T.O.C.) —
40
35
s
30 30.33 FT.MSL 2— —2 29,89 FT.MSL
o — 29.69 FT.MSL 0—
a
v
25
Q _ —
20 O _ _
O
15
a
10
v _
5
La-
N 0
N -
-5
SECTION MWI-4, MWI-3, MWI-6
z
NOTE:
GROUNDWATER DATA COLLECTED ON OCTOBER 26,2021
CROSS - SECTIONAL VIEW SCALE: FIGURE NO.
C-33 - C-32 & MWI-4, MWI-3, MWI-6 1" = 15'
DATE:
2-15-2021 5 C
III CF NITROGEN, INC. PROJECT NUMBER
COFIELD, NORTH CAROLINA 211218

FIGURE 6
Groundwater Elevations for PI-2, PI-11, P0-12, P0-236
_- CF Nitrogen, Inc.
Cofield, North Carolina
/4 y
S&ME Project No. 211218
j r -_.
40.00 - - —
35.00
•
1it\ tcN
30.00 N/ArA4viI Top of Slurry Wall = 30 ft. MSL A
/4A14V&A
cr) f\ 1,//v% ti k.,,
,}; . PI-11
25.00 — y�
g
0
-PO-12
r3
a) 20.00
W ...f ..
PI-2
ea 4iiiiaaNalitidA
15.00 r,Ir i TS 114011r 7' 1
PIWNP11/ APO-236
g
O
10.00
Start Groundwater Recovery
5.00
0.00 111111111111111111111111111111111111111111111111
00 00 a, a, O O r--, — N N M M In In AO AO N N 00 00 01 01 O O ---- ,--1 N N M M In In AO AO N N 00 00 01 01 O O ---- T--1 N
Ci Ci Ci Ci O O O O O O O O O O O O O O O O O O O O ---- ,--i ---- ,--i ---- ,--i ---- ,--i ---- ,--i ---- ,--i r--- ,--i ---- ,--i ---- ,--i r--- T7' N N N N N
cq ti ti ti ti ti ti ti ti ti ti ti ti ti ti ti ti ti ti ti ti ti ti ti ti
Time

. & FIGURE 7
s Groundwater Elevations for C- Designated Wells
lv
CF Nitrogen, Inc.
iiik
Cofield, North Carolina
S&ME Project No. 211218
40.00
35.00
/1'
Top of Slurry Wall =30 ft. MSL W?4: it,
30.00 / i
-6.; \ ii. iktik , \ • /ell ., )
i ', k y )1k1 A
25.00 ,,,,,, 1 ' yv �`.. , ;. r ,� T v 1 . lk
C-22
0
Nr.„
-C-23
et
CU
-C-28
W 20.00 -. —
cu C-29
et
C-32
l
Z15.00 _ 17 I kar► r._ _ _ v.,^w �� , A
G �1 / -C-33
cloli ,%
14.
AWAIIIA A i
10.00 ;w V •• - — - 1+ . v v - — •• v I.gir
Start Groundwater Recovery
5.00
0.00 -r-F I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I
00 00 0, 0, O O . . N N M M in in VD VD N N 00 00 CT CT O O N N M M in in VD VD N N 00 00 CT CT O O ' ' N
I
O� I
O� O O O O O O O O O O O O O O O O O O O O N N N N N
ti � ti ti ti � ti ti ti ti ti ti ti � ti � ti ti ti � ti ti ti � ti ti ti � ti � ti ti ti ti ti ti ti � ti � ti ti AN
ti AN
ti ti
Time

FIGURE 8
Groundwater Elevations for MWI-3, MWI-4 & MWI-6
CF Nitrogen, Inc.
I I I
Cofield, North Carolina
S&ME Project No. 211218
40 —
35
a
tat
30
l
Top of Slurry Wall = 30 ft. MSL Qit
_ r \\f`1
4011. - tb"
V) lidihra\ "if /
25 —
0
MWI-3
a)
w 20 — MWI-4
a)
MWI-6
''S 15
g
Start Groundwater Recovery
CJ
10 —
5
0 I I
00 00 01 01 O O -- -- N N M M AO N N 00 00 C• 01 O O -- -- N N M M AO N N 00 00 C C O
01 01 01 01 O O O O O O O O O O O O O O O O O O O O -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- T--1 N N N N N
Time

Figure 9
Monthly Rainfall
■2021 Rainfall
I I I
CF Nitrogen, Inc.
Cofield, NC ■2020 Rainfall
■2019 Rainfall
S&ME Project 211218 Average Monthly Rain for Cofield, NC
8.00
7.00
6.00
5.00
w
C
_' 4.00
4-
C
3.00
2.00
1.00
0.00 ii II II
Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec