WQ0004095_Residual Annual Report 2021_20220228

Non-Discharge Branch Upload/Submittal Form �.
NORTH CAROLINA
EnWrvnmenfol Quoity
Version 2-Revised June 23,2020
Initial Review
Reviewer EADS\ndthornburg
Is this submittal an application?(Excluding additional information.)*
Yes No
If not an application what is the submittal type?* Annual Report
Residual Annual Report
Additional Information
Other
Annual Report Year* 2021
Permit Number(IR)* WQ0004095
Applicant/Permittee PCS Phosphate Company,Inc.
Email Notifications
Does this need review by the hydrogeologist?* Yes No
Regional Office Washington
CO Reviewer
Admin Reviewer

Submittal Form
Project Contact Information
Please provide information on the person to be contacted by NDB Staff regarding electronic submittal,confirmation of receipt,and other correspondence.
............................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................
Name* James Chandler Stroud
Email Address* Phone Number*
[e-mail] 252-402-6044
Project Information
Application/Document Type* New(Fee Required) Modification-Minor
Modification-Major(Fee Required) Renewal
Renewal with Major Modification(Fee GW-59, NDMR,NDMLR, NDAR-1,
Required) NDAR-2
Annual Report Residual Annual Report
Additional Information Change of Ownership
Other
We no longer accept these monitoring reports through this portal. Please click on the link below and it will take you to the correct form.
https://edocs.deq.nc.gov/Forms/NonDischarge_Monitoring_Report
Permit Type:* Wastewater Irrigation High-Rate Infiltration
Other Wastewater Reclaimed Water
Closed-Loop Recycle Residuals
Single-Family Residence Wastewater Other
Irrigation
Permit Number:* WQ0004095
Has Current Existing permit number
Applicant/Permittee Address* 1530 NC Highway 306 South
Facility Name* PCS Phosphate Class B Residuals Program
Please provide comments/notes on your current submittal below.
Attached is the 2021 Annual Residual Land Application Report for PCS Phosphate Company,
Inc.-Aurora facility.
At this time,paper copies are no longer required.If you have any questions about what is required,please contact Nathaniel Thornburg
at [e-mail].
Please attach all information required or requested for this submittal to be reviewed here.*
(Application Form,Engineering Plans,Specifications,Calculations,Etc.)
2021 Annual Report_Residuals Land Application
1.17MB
Program_WQ0004095 Final_Feb 2022.pdf
Upload only 1 PDF document(less than 250 MB).Multiple documents must be combined into one PDF file unless file is larger
than upload limit.
* By checking this box, I acknowledge that I understand the application will not be
accepted for pre-review until the fee(if required)has been received by the Non-
Discharge Branch.Application fees must be submitted by check or money order and
made payable to the North Carolina Department of Environmental Quality(NCDEQ).
I also confirm that the uploaded document is a single PDF with all parts of the
application in correct order(as specified by the application).
Mail payment to:
NCDEQ—Division of Water Resources
Attn:Non-Discharge Branch
1617 Mail Service Center
Raleigh,NC 27699-1617
Signature /7
L . Older

Submission Date 2/28/2022

aVutrien-
CERTIFIED MAIL
February 28,2022
Division of Water Resources
Information Processing Unit/Non-Discharge Branch
1617 Mail Service Center
Raleigh,North Carolina 27699-1617
Subject: Permit#WQ0004095
PCS Phosphate Company,Inc.'
Residual Land Application Program
2021 Annual Report
Dear Mr. Thornburg,
Per Monitoring and Reporting Requirement IV.8 of the above reference permit, attached is the
Annual Residual Land Application Report for the 2021 calendar year.
Please do not hesitate to contact me at [phone] if I can answer any questions or provide
any additional in ormation.
Sincerely,
G ■
James Chan er Stroud
Supervisor, Environmental Affairs
Nutrien—Aurora
Attachments
pc: 12-04-01 w/attach
ec: K.A.Alnandy w/attach
S.S. Wiggins w/attach
L. D. Davis w/attach
1530 NC Hwy 306 South,Aurora,NC USA 27806 nutrien.com
1 Effective January 1,2018,PCS Phosphate Company,inc.is an indirect subsidiary of Nutrien Ltd.PCS Phosphate Company,Inc.
remains the legal operating entity and permittee.

PCS Phosphate Company, Inc. Aurora
Residuals Land Application Program
Permit No. WQ0004095
2021 Annual Report

Table of Contents
1. Annual Land Application Certification Form: ACF
2. Annual Residual Sampling Summary Report Forms: RSSF
3. Monitoring Requirements - Condition IV.2
4. Annual Land Application Field Summary Form: FSF
5. Residual Analysis Report - Element One
6. Annual Pathogen & Vector Attraction Reduction Form: RF
7. Pathogens & Vector Attraction Reduction Lab
Sheets/Records
8. Soil Analysis

ANNUAL LAND APPLICATION CERTIFICATION FORM
WQ Permit#: WQ0004095 County: _ Beaufort Year: 2021
Facility Name(as shown on permit): PCS Phosphate Company,Inc.
Land Application Operator: PCS Phosphate Company,Inc. Phone: [phone]
Land application of residuals as allowed by the permit occurred during the past calendar year?
�'❑ Yes CI No -If No,skip Part A,and Part B and proceed to Part C. Also,If residuals were
generated but not land applied,please attach an explanation on how the residuals were handled.
Part A-Residuals Application Summary:
Total number of application fields in the permit: Two
Total number of fields utilized for land application during the year: One
Total amount of dry tons applied during the year for all application sites: 8.9
Total number of acres utilizes for land application during the year: 4.4
Part B-Annual Comniance Statement:
Facility was compliant during calendar year 2021 with all conditions of the land application permit
(including but not limited to items 1-13 below)issued by the Division of Water Resources. El Yes ❑ No
If no please,provide a written description why the facility was not compliant,the dates,and explain corrective action
taken.
1) Only residuals approved for this permit were applied to the permitted sites.
2) Soil pH was adjusted as specified in the permit and lime was applied(if needed)to achieve a soil pH of at least 6.0 or
the limit specified in the permit.
3) Annual soils analysis were performed on each site receiving residuals during the past calendar year and three(3)copies
of laboratory results are attached.
4) Annual TCLP analysis(if required)was performed and three(3)copies of certified laboratory results are attached.
5) All other monitoring was performed in accordance with the permit and reported during the year as required and three
(3)copies of certified laboratory results are attached.
6) The facility did not exceed any of the Pollutant Concentration Limits in 15A NCAC 02T.1105(a)or the Pollutant
Loading Rates in 15A NCAC 02T.1105(b)(applicable to 40 CFR Part 503 regulated facilities).
7) All general requirements in as specified in the Land Application Permit were complied with(applicable to 40 CFR Part
503 regulated.facilities).
8) All monitoring and reporting requirements in 15A NCAC 02T.1111 were complied with(applicable to 40 CFR Part
503 regulated facilities).
9) All operations and maintenance requirements in the permit were complied with or,in the case of a deviation, prior
authorization was received from the Division of Water Resources.
10) No contravention of Ground Water Quality Standards occurred at a monitoring well or explanations of violations are
attached to include appropriate actions and remediations.
11) Vegetative cover was maintained and proper crop management was performed on each site receing residuals,as
specified in the permit.
12) No runoff of residuals from the application sites onto adjacent property or nearby surface waters has occurred.
13) All buffer requirements as specified on the permit were maintained during each application of residuals.
Part C-Certification:
"I certify,under penalty of law,that the above information is,to the best of my knowledge and belief,true,accurate,
and complete.I am aware that there are significant penalties for submitting false information,including the
possibility of fines and imprisonment for knowing violations."
William M.Ponton _L'%%/� ' C77r7 X/ZvTZ—
f
Permittee Name and Title(type or print) Signature of Permittee Date
Signature of Preparer* Date Signature of Land Applier Date
(if different from Permittee) (if different from Permittee and Preparer)
*Preparer is defined in 40 CFR Part 503.9(r)and 15A NCAC 02T.1102(26) DENR FORM ACF(1212006)

ANNUAL RESIDUAL SAMPLING SUMMARY FORM
Please note that your permit may contain additional parameters to be analyzed. The parameters can be reported in FORM RSSF-B
WQ Permit Number: WQ0004095 Laboratory: 1) Element One, Inc.
Facility Name: PCS Phosphate Company, Inc. 2)
Residual Source WQ#or WQ0000889 3)
NPDES#: 4)
WWTP Name: PCS Phosphate Company, Inc. 5)
Residual Analysis Data
Conc. Sample or Composite Date
Parameter Limit I
(mg/kg) (mgtkg)aI 03/4/21
_
Percent Solids(%) NA 7.38
-
Arsenic 75 . <1.29
Cadmium 85 2.13
Copper 4,300 214
Chromium NA _ 22.6
Lead 840 7.38
Mercury 57 0.285
v
Molybdenum 75 17.1
Nickel 420 13.3 _
Selenium 100 <1.29 _
Zinc 7,500 . 1436
Total Phosphorus i NA 8062 -
TKN NA 7656
Ammonia-Nitrogen NA 783
Nitrate and Nitrite NA 549
a For surface disposal facilities the ceiling concentration limits listed in this form are not applicable. Reference the individual permit for metals limits.
"I certify, under penalty of law,that this document was prepared under my direction or supervision in accordance with a system designed
to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant
penalties for submitting false informatio including the possibility of fines and imprisonment for knowing violations."
(-X/ - .-! Z/Z g/ 2,P 2 a
Signature of Preparer* Date
DENR FORM RSSF(12/2006)

ANNUAL RESIDUAL SAMPLING SUMMARY FORM - B
Report all sampling analysis results for parameters not listed in FORM RSSF that are part of the WQ permit or were analyzed for over the past
calendar year. Use additional forms as needed.
WQ Permit Number: WQ0004095 Laboratory: 1) Element One,Inc.
Facility Name: PCS Phosphate Company, Inc. 2)
Residual Source WQ0000889 3)
NPDES#or WQ#: 4)
WWTP Name: PCS Phosphate Company, Inc. 5)
Residual Analysis Data
Sample or Composite Date
Parameter
(mg/kg) •
3/04/21
Aluminum 1152
Magnesium 4892
Potassium 1107
Sodium 1257
Calcium 366,192
pH SU 12.8
PAN 221.56
E
- k
"I certify,under penalty of law,that this document was prepared under my direction or supervision in accordance with a system
designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are
significant penalties for submitting false information,including the possibility of fines and imprisonment for knowing violations."
r�
ZIZW 20
Signature of Preparer* Date
*Preparer is defined in 40 CFR Part 503.9(r)and 15A NCAC 2T.1102(26)
DENR FORM RSSF-B(12/2006)

Monitoring Frequency of Condition IV. 2.
Annually

IV. MONITORING AND REPORTING REQUIREMENTS
1. The Permittee shall conduct and report any Division required monitoring necessary to evaluate this
program's impact on groundwater and surface water. [15A NCAC 02T.0108(c)]
2. The residuals from each source generating facility shall be analyzed to demonstrate they are non-
hazardous under the Resource Conservation and Recovery Act (RCRA). Residuals that test or are
classified as a hazardous or toxic waste under 40 CFR Part 261 shall not be land applied. The analyses
(i.e.,corrosivity,ignitability,reactivity,and toxicity characteristic leaching procedure(TCLP))shall be
performed at the frequency specified in Attachment A, and the Permittee shall maintain these results
for five years. Any exemptions from the requirements in this condition shall be specified in Attachment
A. The TCLP analysis shall include the following parameters,and the Federal regulatory level(mg/L)
is in parentheses:
Arsenic 1,4-Dichlorobenzene(7.5) Nitrobenzene(2.0)
Barium 1,2-Dichloroethane(0.5) Pentachlorophenol(100.0)
Benzene 1,1-Dichloroethylene(0.7) Pyridine(5.0)
Cadmium 2,4-Dinitrotoluene(0.13) Selenium(1.0)
Carbon tetrachloride(0.5) Endrin(0.02) Silver(5.0)
Chlordane 0.03 Heptachlor(and its epoxide)
( ) (0.00$) Tetrachloroethylene(0.7)
Chlorobenzene(100.0) Hexachlorobenzene(0.13) Toxaphene(0.5)
Chloroform(6.0) Hexachlorobutadiene(0.5) Trichloroethylene(0.5)
Chromium(5.0) Hexachloroethane(3.0) 2,4,5-Trichlorophenol(400.0)
m-Cresol(200.0) Lead(5.0) 2,4,6-Trichlorophenol(2.0)
o-Cresol(200.0) y _ Lindane(0.4) 2,4,5-TP(Silvex)(1.0) J
p-Cresol(200.0) Mercury(0.2) Vinyl chloride(0.2)
Cresol(200.0) Methoxychlor(10.0)
2,4-D(10.0) Methyl ethyl ketone(200.0)
Once the residuals have been monitored for two years at the frequency specified in Attachment A,the
Permittee may submit a permit modification request to reduce the frequency of this monitoring
requirement. In no case shall the monitoring frequency be less than once per permit cycle.
[15A NCAC 13A.0102(b),02T.1101,02T.1105]
WQ0004095 Version 4.0 Shell Version 190618 Page 8 of 12

w
ATTACHMENT A—APPROVED RESIDUAL SOURCES Certification Date:June 26,2019
PCS Phosphate,Inc. Permit Number: WQ0004095 Version: 4.0 •
Monitoring Monitoring Monitoring
Permit Biological Maximum Frequency for Frequency for Owner Facility Name County Dry
Frequency for Approved
Number Residuals Tons Non-hazardous Metals and Pathogen& Mineralization
per Year' Characteristics 2 Nutrients 45 Vector Attraction Rate
Reductions 4,s
PCS Phosphate,Inc. PCS Phosphate WWTP Beaufort WQ0000889 Yes 10 Annually Annually Annually 0.3
Total 10
1. Maximum Dry Tons per Year is the amount of residuals approved for land application from each permitted facility.
2. Analyses to demonstrate that residuals are non-hazardous(i.e.,TCLP,ignitability,reactivity,and corrosivity)as stipulated under permit Condition W.2.
3. Testing of metals and nutrients as stipulated under permit Condition IV.3.
4. Analyses of pathogen and vector attraction reductions as stipulated under permit Condition IV.4.
5. Monitoring frequencies are based on the actual dry tons applied per year using the table below,unless specified above.
Monitoring Frequency
Dry Tons Applied(metric tons) Dry Tons Applied (40 CFR 503 and 15A NCAC 02T
(short tons per year)
.1111(ci)
<290 <3 1 9 Once per year(Annually)
>_290 to<1,500 >319 to<1,650 Once per quarter(4 x Year)
>_1,500 to<15,000 >1,650 to<16,500 Once per 60 days(6 x Year)
>_15,000 >16,500 Once per month(12 x Year)
If no land application events occur during a required sampling period(e.g.,no land application occur during an entire year when annual monitoring is required),then no sampling data is
required during the period of inactivity.The annual report shall include an explanation for missing sampling data.Those required to submit the annual report to United States Environmental
Protection Agency(US EPA)may be required to make up the missed sampling.Contact the US EPA for additional information.
WQ0004095 Version 4.0 Attachment A Page 1 of 1

ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON
PLACE A"N/A"IN A BLANK OR BOX WHEN NOT APPLICABLE.
Facility Name: PCS Phosphate Company,Inc. WQ Permit#: WQ0004095 Field#: PCS 02 Acres Utilized: 4.4
Land Owner: Reservco,Inc. Annual Dry Tons Applied: 8.9190 Site#: PCS Acres Permitted: 9.99
Operator: PCS Phosphate Company, I Predominant Soil Series: Sand Cation Exchange Capacity(non 503):
Crop 1 Name: Crop 1 Max.PAN: Crop 2 Name: Crop 2 Max.PAN:
Volume applied Volume Residual Sources Soil Precip. > o p 4 Z Nitrate Name of Crop Type
(enter one)Solids/ % Appliedper Cond. a b w cE PAN Applied
y o pp (NPDES#,WQ#, D Past 24 rn �• ' TKN o and Receiving Residual
Liquid Solids Acre Fert.,Animal (Dry, Hrs. o ; k' a °= °co° °°° (lbs/acre)
A Wet, a .• * w * N' ° p, Nitrite Application
Waste,etc) * °� o' * a.
Cu.Yds_ Gallons (Dry Tons/Ac) Moist) inches ° ° mg/kg mg/kg mg/kg Crop 1 Crop 2_ Crop 1 Crop 2
0.000 0.000 0.000
6/14/21 13000 7.63 0.940 PCS WWTP Dry 0 S 0.5 0.3 7656 783 549 5.645 NA Bermuda
0.000 0.000 0.000
6/15/21 15,032 7.63 1.087 PCS WWTP Dry 0 S 0.5 0.3 7656 783 549 6.527 NA Bermuda
0.000 0.000 0.000
0.000 0.000 0.000
-
0.000 0.000 0.000
_
0.000 0.000 0.000
-
0.000 0.000 0.000
0.000 0.000 0.000
0.000 0.000 0.000
_ 0.000 0.000 0.000
l Residuals Applications totals on FORM FSF supp(attach FORM FSF supp to this form): 1
TOTAL.S °I 28032 As Cd Cu Cr Pb Hu _ Mo Ni ' Se Zn P 1 12.172 1 0.000 J Lime Applied
Annual lbs/acre 0.005 0.009 0.868 0.092 0.030 0.001 0.069 0.054 0.005 5.822 32.684 Date lbs/ac
v
Prior Years Cumulative lbs/ac 0.085 0.246 17.351 0.067 0.673 0.033 0.283 0.513 0.118 65.493
^
Current Cumulative lbs/ac 0.090 0.255 18.219 0.159 0.703 0.034 0.352 0.567 0.123 71.315
Permitted C.P.L.R.**** 36 34 , 1,338 n/a - 267 15 n/a 374 89 2,498
Permit PAN Limit 1 st/2nd Crop 220 50
1
"I certify,under penalty of law,that this document was prepared under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false
information, including the possibility of fines and imprisonment for knowing violations."
*Application Method:S-Surface,IN-Injection,INC-Incorporation
t � -�r � � **Volatilization Rate:Surface-0.5,Injection/Incorporation-1.0
Signature of Land Applier Date ***Mineralization Rates:Compost-0.1,anaerobially digested-0.2,
aerobically digested-0.3,raw sludge-0.4
****C.P.L.R.:Cumulative Pollutant Loading Rate
DENR FORM FSF(12/2006)

Element One Inc.
6319-D Carolina Beach Rd.
Wilmington,NC 28412
-1
Phone:[phone]
Fax:[phone]
el [e-mail]
elementOne
FINAL REPORT OF ANALYSES
Element One, Inc. Project Number e36307
Chandler Stroud March 18, 2021
Nutrien Client Project Name
1530 Hwy 306 South Client Project Number
Aurora, NC 27806 PO Number
Analytical Log No: El Project Number e36307
Sample ID: Bio Solids
Sample Matrix OT Sample Type Grab Date Received 03/05/2021
Date Sampled 03/04/2021 Time Sampled 1000 Time Received 1215
Delivered by FedEx Sampler Received by LLB
Extraction Begun 03/08/21 1600 Extraction Ended 03/09/21 0815 El Sample# 36307 TCLP
Parameter Result Unit Calc. RL Dilution DL Method Date
Chromium, TCLP digested < 0.05 mg/L 0.05 50 0.001 EPA 1311/6020B 03/11/21
Arsenic, TCLP digested < 0.05 mg/L 0.05 50 0.001 EPA 1311/6020B 03/11/21
Selenium, TCLP digested < 0.05 mg/L 0.05 50 0.001 EPA 1311/6020B 03/11/21
Silver, TCLP digested < 0.05 mg/L 0.05 50 0.001 EPA 1311/6020B 03/11/21
Cadmium, TCLP digested <0.05 mg/L 0.05 50 0.001 EPA 1311/6020B 03/11/21
Barium, TCLP digested 0.080 mg/L 0.05 50 0.001 EPA 1311/6020B 03/11/21
Lead, TCLP digested < 0.05 mg/L 0.05 50 0.001 EPA 1311/6020B 03/11/21
Mercury, TCLP digested <0.0004 mg/L 0.0004 2 0.0002 EPA 1311/7470A 03/17/21
Solids 7.38 % SM2540G 03/08/21
pH, Initial 12.99 SU EPA 1311 03/08/21
Fluid Determination pH 12.78 SU EPA 1311 03/08/21
TCLP pH, Final 12.95 SU EPA 1311 03/09/21
pH, Extraction Fluid#1 2.88 SU EPA 1311 03/08/21
Ken Smith, Laboratory Director Page 1 of 3
36307 Nutrien Report Packet Compiled by Val
Certifications: NJ NELAP NC009, NY FLAP 11889, NC DW 37788 and NC DWQ DENR 604

Element One Inc.
6319-D Carolina Beach Rd.
e 1 l Wilmington, NC 28412
Phone:[phone]
Fax: [phone]
el Iab@a el lab.com
elementOne
FINAL REPORT OF ANALYSES
Element One, Inc. Project Number e36307
Chandler Stroud March 18, 2021
Nutrien Client Project Name
1530 Hwy 306 South Client Project Number
Aurora, NC 27806 PO Number
Analytical Log No: El Project Number e36307
Sample ID: Bio Solids
Sample Matrix OT Sample Type Grab Date Received 03/05/2021
Date Sampled 03/04/2021 Time Sampled 1000 lime Received 1215
Delivered by FedEx Sampler Received by LLB
El Sample# 36307 TOT
Parameter Result Result Unit Dilution DL Method Date
As Received Dry Basis
Sodium, Total 92.8 1257 mg/kg 25 0.4 EPA 3010/6020B 03/16/21
Magnesium, Total 361 4892 mg/kg 25 0.4 EPA 3010/6020B 03/16/21
Aluminum, Total 85.0 1152 mg/kg 50 0.1 EPA 3010/6020B 03/16/21
Phosphorus, Total 595 8062 mg/kg 25 0.1 EPA 3010/6020B 03/16/21
Potassium, Total 81.7 1107 mg/kg 25 0.4 EPA 3010/6020B 03/16/21
Calcium, Total 27025 366192 mg/kg 1000 0.8 EPA 3010/6020B 03/16/21
Chromium, Total 1.67 22.6 mg/kg 1 0.1 EPA 3010/6020B 03/17/21
Nickel, Total 0.978 13.3 mg/kg 25 0.1 EPA 3010/6020B 03/16/21
Copper, Total 15.8 214 mg/kg 25 0.1 EPA 3010/6020B 03/16/21
Zinc, Total 106 1436 mg/kg 25 0.1 EPA 3010/6020B 03/16/21
Arsenic, Total <0.095 < 1.29 mg/kg 1 0.1 EPA 301016020E 03/17/21
Selenium, Total < 0.095 < 1.29 mg/kg 1 0.1 EPA 3010/6020B 03/17/21
Molybdenum, Total 1.26 17.1 mg/kg 25 0.1 EPA 3010/60203 03/16/21
Cadmium,Total 0.157 2.13 mg/kg 1 0.1 EPA 3010/6020B 03/17/21
Lead, Total 0.545 7.38 mg/kg 25 0.1 EPA 3010/6020B 03/16/21
Mercury, Total 0.021 0.285 mg/kg 1 0.008 EPA 7471 B 03/11/21
Solids 7.38 % SM2540G 03/08/21
pH, as received 12.80 SU EPA 9045D 03/17/21
Ken Smith, Laboratory Director Page 2 of 3
36307 Nutrien Report Packet Compiled by tk)
Certifications: NJ NELAP NC009, NY ELAP 11889, NC DW 37788 and NC DWQ DENR 604

Element One Inc.
8319-D Carolina Beach Rd.
Wilmington, NC 28412
«: I
Phone:[phone]
Fax:[phone]
[e-mail]
elementOne
FINAL REPORT OF ANALYSES
Element One, Inc. Project Number e36307
Chandler Stroud March 18, 2021
Nutrien Client Project Name
1530 Hwy 306 South Client Project Number
Aurora, NC 27806 PO Number
Analytical Log No: El Project Number e36307
Sample ID: Bio Solids
Sample Matrix OT Sample Type Grab Date Received 03/05/2021
Date Sampled 03/04/2021 Time Sampled 1000 Time Received 1215
Delivered by FedEx Sampler Received by LLB
El Sample# 36307 TOT
Parameter Result Result Unit Dilution DL Method Date
As Received Dry Basis
Total Nitrogen-N 606 8211 mg/kg 5 5.5 EPA 300.0+4500NH3C 03/17/21
Nitrate+Nitrite-N 40.5 549 mg/kg 5 0.5 EPA 300.0 03/17/21
Kjeldahl Nitrogen, TKN 565 7656 mg/kg 1 5.0 SM 4500 NH3 C 03/12/21
Ammonia as N 57.8 783 mg/kg 1 0.5 SM 4500 NH3 D 03/12/21
Organic Nitrogen-N 507 6870 mg/kg 1 0.4 calculation 03/12/21
Solids 7.38 % SM2540G 03/08/21
Ken Smith, La oratory i tor Page 3 of 3
36307 Nutrien Report Packet Compiled bdib
Certifications: NJ NELAP NCO.
09, NY ELAP 11889, NC DW 37788 and NC DWQ DENR 604

Element One, Inc. CHAIN OF CUSTODY Lab ID #e 3630-1 Page of
6319-D Carolina Beach Road Phone [phone]/FAX [phone]
Wilmington, NC 28412 email [e-mail]
Contact: Chandler Stroud PO#. Analyses Requested Delivery Due Date
Company: Nutrien Phone [phone] 0 Normal
*
1530 Hwy 306 South Fax i? []5 day
Address: Aurora, NC 27806 Email [e-mail] ° 0 3 day*
Email ' 0 2 day*
Project 1D: Email — CO I co 01 day*
Billing information if different:
� Z m ai *Rush work needs prior lab
E °' >, approval Additional charges
g _ : will apply.
pply.
0 Compliance 0 i � N °,,,-,- c r
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Element One, Inc. Form 026-Revision

ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM(02T Rules)
Facility Name: PCS Phosphate Company,Inc. WQ Permit Number: WQ0004095
WWTP Name: PCS Phosphate Company,Inc. NPDES Number: Non Discharge
Monitoring Period: From 1/1/2021 To 12/31/2021
Pathogen Reduction(15A NCAC 02T.1106)-Please indicate level achieved and alternative performed:
Class A: Alt.A(time/temp) ❑ I Alt B(Alk Treatment) 0 Alt.C(Prior Testing) 0
Alt.D(No Prior Test) ❑ Process to Further Reduce Pathogengs ❑
If applicable to alternative performed(Class A only)indicate"Process to Further Reduce Pathogens":
Compost 0 Heat Drying ❑ Heat Treatment ❑ Thermophilic 0
Beta Ray 0 Gamma Ray ❑ Pasteurization ❑
_Class B: Alt.(1)Fecal Density El Alt.(2)Process to Significantly Reduce Pathogens 0
If applicable to alternative performed(Class B only)indicate"Process to Significantly Reduce Pathogens":
Lime Stabilization El Air Drying ❑ Composting ❑ Aerobic Digestion 0
Anaerobic Digestion ❑
If applicable to alternative performed(Class A or Class B) complete the following monitoring data:
-Number o1' �lnai�t i cal
Allowable Level Pathogen Density Frequency Sample
Parameter Excee- Tech-
in Sludge Minimum Geo.Meagvlaximun Units deuces of Analysis Type niaue
2 x 10 to the MPN
6th power
per gram of Fecal Coliform total solids CFU
1000 mpn per gram
of total solid (dry
weight) _
Salmonella bacteria 3 MIN per 4 grams
(in lieu of fecal total solid(dry
conform) weight)
Vector Attraction Reduction(15A NCAC 02T.1107)-Please indicate alternative performed: _
Alt.1 (VS reduction) pklt.2(40-day bench) pelt.3(30-day bench) ❑ it.4(Spec.02 uptake) ❑
Alt.5(14-Day Aerobic) pAlt.6(Alk.Stabilization pelt 7(Drying-Stable) ❑Ut.8(Drying-Unstable) ❑
Alt.9(Injection) 0Alt. 10(Incorporation) pdo vector attraction reduction alternatives were performed ❑
CERTIFICATION STATEMENT(please check the appropriate statement)
❑v "I certify,under penalty of law,that the pathogen requirements in 15A NCAC 02T.1106 and the
vector attraction reduction requirement in 15A NCAC 02T.1107 have been met."
❑ "I certify,under penalty of law,that the pathogen requirements in 15A NCAC 02T.1106 and the
vector attraction reduction requirement in 15A NCAC 02T.1107 have not been met." (Please note
if you check this statement attach an explanation why you have not met one or both of the
requirements.) _
"This determination has been made under my direction and supervision in accordance with the system
designed to ensure that qualified personnel properly gather and evaluate the information used to determine
that the pathogen and vector attraction reduction requirements have been met. I am aware that there are
significant penalties for false certification including fine nd im isonment."
William M.Ponton,General Manager l -
Prep er Name and Title(type or rint) and Applier Name an Title(if applicable)(type or print)
,„' _ ,-. .69,,, ,_
Z.W&ZZ
Signature of Preparer* Date Signature of Land Applier(if applicable) Date
*Preparer is defined in 40 CFR Part 503.9(r)and 15A NCAC 2T.1102(26)
DENR FORM PVRF 02T(12/2006)

lutrien
Waste Water Treatment Plant (WWTP)
Sludge Stabilization Form
*pH Is read in SU. Instrument ID- Oakton 300 serial #459794 (temp and pH combo meter)
pH Meter Cal. *pH in SU pH Meter Cal. *pH in SU
Date/Time Starting pH ,} 0 N m� pH Temp in"C Date/Time After Lime 4.6 /1 1 pH Temp in'C
0 Buff pH 7 0 = n..t ��li 2b uff pH 100
• III t 4
awl MN. Meter- 10.0u = io.of 20 2?�t 09Yf 8M t 12 art=i2.Yr ► 9
7.0= 701 zo 7.00 i 1
pH Acceptance Criteria+/-0.1 su at 25°C
f�
*pH in SU Afit-�, Ertl, r,,., *pH in SU
Basin Date Starin,ti pH "'I'll {�,a,it,l;. Time Date a e , r,
of i n,1E .. .,
T�' tip C r0rt•i.
I t -t.?ott 4.19 ZL yoo 12.s's V- WTI I.- ---<< 12.10 Z .
2 (.-)-?e1.tt Cr? 12 400 'VI- 22 10 5Z 6-1-11 12. 1c L2
(Pt - 4'9 foot 22 2Sb I1.10 22 lor3 L, --Lt I2.zi 2z
4 41.4a9.t b.03 zz 2st 1240 21- (O5`f b- 2 11 ' (L.22 2Z
Wt,stu
e;,s,n NIA
ORC p,4) �r9dis
Signature &
Date /21

NCDA&CS Agronomic Division Phone: [phone] Website: www.ncagr.govlagronomi/ Report No. FY21-SL029367 -
4 r-i'4�,� Client: Dale Davis
�r a '' 'r�s Predictive 1530 NC Hwy 306 S Advisor:
';• , � A'll Aurora, NC 27806
-`- 7. �° 4 ) Soil Report Mehlich-3 Extraction
<r Sampled County: Beaufort
'`"`..; Links to Helpful Information
Client ID: 446314 Advisor ID:
Sampled: 04/05/2021 Received: 04/09/2021 Completed: 04/20/2021 Farm: Nutrien Field(small)
Sample ID: 0001 I Recommendations: Lime Nutrients(lb/acre) More
Crop (tons/acre) N P2O5 K2O Mg S Mn Zn Cu B Information
Lime History: 1 -Bermuda hay/past., E 0.0 60-80 0 70 0 0 pH$ 0 0 0 Note: 12 Note: $
^0.10 tons/acre;7/2020 , 2-Fescue/OGrass/Tim, E 0.0 50-70 0 30 0 0 pH$ 0 0 0 Note: 12 Note: $
Test Results[units-WN in g/crr?;CEC and Na in meq/100 cm3;NO3-N in mg/dni3]: Soil Class: Mineral
HM% WN CEC BS% Ac pH P-I K-I Ca% Mg% S-I Mn-I Mn-All Mn-Al2 Zn-I Zn-Al Cu-I Na ESP SS-I NO3-N
0.46 1.26 7.7 95 0.4 6.9 209 34 81 12 34 59 39 39 1070 1070 376 0.1 1
Sample ID: 0002 Recommendations: Lime Nutrients(lb/acre) More
Crop (tons/acre) N P2O5 K2O Mg S Mn Zn Cu B Information
Lime History: 1 -Bermuda hay/past., E 0.0 60-80 0 80 0 0 pH$ 0 0 0 Note: 12 Note: $
2-Fescue/OGrass/Tim, E 0.0 50-70 0 50 0 0 pH$ 0 0 0 Note: 12 Note: $
Test Results[units-WN in g/cm3;CEC and Na in meq/100 cm3;NO3-N in mg/dnf3]: Soil Class: Mineral
HM% WN CEC BS% Ac pH P-I K-I Ca% Mg% S-I Mn-I Mn-All Mn-Al2 Zn-I Zn-Al Cu-I Na ESP SS-I NO3-N
0.36 1.24 6.6 92 0.5 6.6 178 28 78 12 42 77 54 54 862 862 210 0.1 2
North Carolina Reprogramming of the laboratory-information-management system that makes this report possible is being funded
( `. ilipp
� through a grant from the North Carolina Tobacco Trust Fund Commission.
joitIleSt
Thank you for using agronomic services to manage nutrients and safeguard environmental quality.
- Steve Troxler, Commissioner of Agriculture
'lobar 0 Ttuwt Fia d(�MOVAian

NCDA&CS Agronomic Division Phone: [phone] Website: www.ncagr.gov/agronomi/ Report No. FY21-SL029367
Dale Davis Page 2 of 2
Understanding the Soil Report:explanation of measurements,abbreviations and units
Recommendations Report Abbreviations
Lime Ac exchangeable acidity
If testing finds that soil pH is too low for the crop(s) indicated, a lime recommendation will be given in units of either B boron
ton/acre or lb/1000 sq ft. For best results, mix the lime into the top 6 to 8 inches of soil several months before planting. BS% %CEC occupied by basic cations
For no-till or established plantings where this is not possible, apply no more than 1 to 1.5 ton/acre(50 lb/1000 sq ft)at on. Ca% %CEC occupied by calcium
time,even if the report recommends more.You can apply the rest in similar increments every six months until the full rate CEC cation exchange capacity
is applied. If MG is recommended and lime is needed, use dolomitric lime. Cu-I copper index
ESP exchangeable sodium percent
Fertilizer HM% percent humic matter
Recommendations for field crops or other large areas are listed separately for each nutrient to be added (in units of K-I potassium index
lb/acre unless otherwise specified). Recommendations for N (and sometimes for B)are based on research/field studies K20 potash
for the crop being grown, not on soil test results. K-I and P-I values are based on test results and should be> 50. If they Mg% %CEC occupied by magnesium
are not,follow the fertilizer recommendations given. If Mg is needed and no lime is recommended, 0-0-22(11.5% Mg) is MIN mineral soil class
an excellent source; 175 to 250 lb per acre alone or in a fertilizer blend will usually satisfy crop needs, SS-I levels appear Mn manganese
only on reports for greenhouse soil or problem samples. Mn-All Mn-availability index for crop 1
Mn-Al2 Mn-availability index for crop 2
Mn-I manganese index
Farmers and other commercial producers should pay special attention to micronutrient levels. If$,pH$, $pH, C or Z M_O mineral-organic soil class
notations appear on the soil report, refer to $Note:Secondary Nutrients and Micronutrients In general, homeowners do not N nitrogen
need to be concerned about micronutrients.Various crop notes also address lime fertilizer needs; visit Na sodium
ncagr.gov/agronomi/pubs.htm. NO3-N nitrate nitrogen
ORG organic soil class
Recommendations for small areas,such as home lawns/gardens, are listed in units of Ib/1000 sq ft. If you cannot find pH current soil pH
the exact fertilizer grade recommended on the report,visit www.ncadr.doy/agronomilobpart4.htmfrisfind information that P-I phosphorus index
may help you choose a comparable alternate. For more information, read A Homeowner's Guide to Fertilizer. P2Os phosphate
S-I sulfur index
Test Results SS-I soluble salt index
WN weight per volume
The first seven values[soil class, HM%, WN, CEC, BS%,Ac and pH]describe the soil and its degree of acidity.The Zn-Al zinc availability index
Zn-I zinc index
remaining 16[P-I, K-I, Ca%, Mg%, Mn-I, Mn-All, Mn-Al2, Zn-I, Zn-Al, Cu-I, S-I, SS-I, Na, ESP, SS-I, NO3-N (not routinely
available)] indicate levels of plant nutrients or other fertility measurement.Visit aorvov/agronomi/urrst.htm