NCG030694_2021 DMR_20220110

hart hickman
SMARTER ENVIRONMENTAL SOLUTIONS
Via Online Portal & Znd Day FedEx
January 10, 2022
North Carolina Department of Environmental Quality
Division of Energy, Mineral and Land Resources
450 West Hanes Mill Road, Suite 300
Winston-Salem, North Carolina 27105
Re: DMR December 2021 — NCG030694 — LLFIex, LLC
Oracle Flexible Packaging, Inc. (Former)
1300 Cunningham Avenue
Winston-Salem, Forsyth County
H&H Proiect No. LLF-007
Dear Madam/Sir:
On behalf of LLFIex, LLC (LLFIex), Hart & Hickman, PC (H&H) is submitting the enclosed
quarterly stormwater Discharge Monitoring Report (DMR) for the site referenced above in
accordance with the industrial stormwater permit (NCG030694). There were no benchmark value
exceedances in samples from this quarterly monitoring period.
Should you have any questions or need any additional information, please feel free to contact us.
Sincerely,
Htirt & Hickman, PC
A)r4jo
Matt Brannblett, PE
Principal
Enclosures
470� a,
Gregory Kanellis, PE
Project Manager
CC: Mr. Jason Caple, LLFIex (PDF via email)
Mr. Shawn Sylvester, LLFIex (PDF via email)
Ms. Mary Katherine Stukes, Moore & Van Allen (PDF via email)
2923 South Tryon Street, Suite 100 3921 Sunset Ridge Rd, Suite 301
Charlotte, NC 28203 Raleigh, NC 27607 www.harthickman.com
704.586,0007 main 919.847.4241 main

NCDEQ Division of Energy, Mineral and Land Resources
Stormwater Discharge Monitoring Report (DMR) Form for NCG030000
Metal Fabrication
Click here for instructions
Complete, sign, scan and submit the DMR via the Stormwater NPDES Permit Data Monitoring Report DMR Upload form within
30 days of receiving sampling results. Mail the original, signed hard copy of the DMR to the appropriate DEMLR Regional Office.
Certificate of Coverage No. NCG03 0694
Person Collecting Samples: Glenn Price (Pace Analytical)
Facility Name: Former Oracle 200 Facility
Laboratory Name: Pace Analytical
Facility County: Forsyth
Laboratory Cert. No.: Asheville, NC(40), Eden, NC (633), Huntersville, NC (12)
Discharge during this period: E]Yes
171
No (if no, skip to signature and date)
Has your facility implemented mandatory Tier response actions this sample period for any benchmark exceedances?171 Yes FINo
If so, which Tier (I, II, or III)?
A copy of this DMR has been uploaded electronically via https://edocs.deg.nc.gov/Forms/SW-DMR El Yes No
Date Uploaded: 1/10/2022
Analytical Monitoring Requirements for Outfalls with Industrial Activities - Benchmarks in (Red)
Parameter
Parameter
Outfall SD01
Outfall SD02
Outfall S003
Outfall SD04
Outfall SD05
Code
N/A
Receiving Stream Class
C
C
C
C
C
N/A
Date Sample Collected MM/DD/YYYY
12/19/2021
12/19/2021
12/19/2021
12/19/2021
12/19/2021
46529
24-Hour Rainfall in inches
0.7
0.7
0.7
0.7
0.7
C0530
T55 in mg/L (100 or 50")
<2.5
<2.7
<2.8
<2.5
<3.0
pH in standard units (6.0-9.0 FW,
00400
6.8-8.5 5W)
6.77
6.80
7.03
6.69
6.88
Copper, total recoverable in mg/L
01119
(0.010 FW, 0.0058 SW)
<O.D050
<0.0050
<0.0050
<0.0050
<0.0050
Lead, total recoverable in mg/ L
01051
(0.075 FW, 0.22 SW)
<0.0050
<0.0050
<0.0050
<0.0050
<0.0050
Zinc, total recoverable in mg/ L(0.126
01094
FW, 0.095 SW)
<0.01D
<0.010
<0.010
<0.010
<0.010
Chemical Oxygen Demand (COD) in
00340
mg/L (120)
<25.0
<25.0
<25.0
<25.0
<25.0
00552
Non -Polar Oil & Grease in mg/L (15)
<5.3
<5.0
<5.2
<5.1
<5.6
* outfalls to Outstanding Resource Waters (ORW), High Quality Waters (HQW), Trout Waters (Tr) and Primary Nursery Areas (PNA)
have a benchmark TSS limit of SO mg/L. All other water classifications have a benchmark of 100 mg/L
FW (Freshwater) SW (Saltwater)
Notes (optional):
"I certify by my signature below, under penalty of law, that this document and all attachments were prepared under my direction or supervision in
accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my
inquiry of the person or persons who manage the system, or those persons directly responsible for gathering the information, the information
submitted is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting
false informgt{on, irjcluWtg tl�e possibility of fines and imprisonment for knowing violations."
1 / 10/2022
Signature of Peoittee or Delegated Authorized Individual Date
[e-mail]
Email Address
3368031655
Phone Number
Page 28 of 28

aceAnalj6cal
www.pacelabs.cm
Pace Analytical Services, LLC
9800 KinceyAve. Suite 100
Huntersville, NC 28078
(704 }875-9092
January 05, 2022
Greg Kanellis
Hart & Hickman
3921 Sunset Ridge Rd.
Suite 301
Raleigh, NC 27607
RE: Project: Hart & Hickman Oracle 200
Pace Project No.: 92579041
Dear Greg Kanellis:
Enclosed are the analytical results for sample(s) received by the laboratory on December 20, 2021. The results relate only
to the samples included in this report. Results reported herein conform to the applicable TNIINFLAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace Analytical Services - Asheville
• Pace Analytical Services - Charlotte
• Pace Analytical Services - Eden
• Pace Analytical Services - Kernersville, NC
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
ce-lz a�-
Kevin Godwin
[e-mail]
1(704)875-9092
Project Manager
Enclosures
Q pCCRp�
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full;
without the written consent of Pace Analytical Services, LLC-
Page 1 of 28

aceAnalytical
www.pacelabs.com
Pace Analytical Services, Lt_C
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: Hart & Hickman Oracle 200
Pace Project No.: 92579041
Pace Analytical Services Charlotte
South Carolina Laboratory ID: 99006
9800 KinceyAve. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification M 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Laboratory ID: 99006
Pace Analytical Services Asheville
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: F87648
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
Pace Analytical Services Eden
205 East Meadow Road Suite A, Eden, NC 27288
North Carolina Drinking Water Certification #: 37738
CERTIFICATIONS
South Carolina Certification M 99006001
South Carolina Drinking Water Cort. #: 99006003
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Louisiana DoH Drinking Water #: LA029
VirginiaNFLAP Certification M 460221
South Carolina Laboratory ID: 99030
South Carolina Certification M 99030001
VirginiaNFLAP Certification #: 460222
North Carolina Wastewater Certification M 633
VirginiaNELAP Certification #: 460025
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 2 of 28

aceAnalytical
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SAMPLE ANALYTE COUNT
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project:
Pace Project No.:
Hart & Hickman Oracle 200
92579041
Analytes
Lab ID
Sample ID
Method
Analysts
Reported
laboratory
92579041001
OUTFALL SD01
SM 254OD-2015
AED
1
PASI-E
EPA 1664B
ICO
1
PASI-C
EPA 200.7 Rev 4.4 1994
DS
3
PASI-A
KRG
4
PASI-KR
SM 5220D-2011
JP1
1
PASI-A
92679041002
OUTFALL SD02
SM 254OD-2015
AED
1
PASI-E
EPA 1664B
ICO
1
PASI-C
EPA 200.7 Rev 4.4 1994
DS
3
PASI-A
KRG
4
PAS!-KR
SM 5220D-2011
JP1
1
PASI-A
92579041003
OUTFALL SD03
SM 2540D-2015
AED
1
PASI-E
EPA 1664E
ICO
1
PASI-C
EPA 200.7 Rev 4.4 1994
DS
3
PASI-A
KRG
4
PASI-KR
SM 5220D-2011
JP1
1
PASI-A
92579041004
OUTFALL SD04
SM 2540D-2015
AED
1
PASI-E
EPA 1664E
ICO
1
PASI-C
EPA 200.7 Rev 4.4 1994
DS
3
PASI-A
KRG
4
PASI-KR
SM 5220D-2011
JP1
1
PASI-A
92579041005
OUTFALL SD05
SM 2540D-2015
AED
1
PASI-E
EPA 1664E
ICO
1
PASI-C
EPA 200.7 Rev 4.4 1994
CBV
3
PASI-A
KRG
4
PASI-KR
SM 5220D-2011
JP1
1
PASI-A
PASI-A = Pace Analytical Services - Asheville
PASI-C = Pace Analytical Services - Charlotte
PASI-E = Pace Analytical Services - Eden
PASI-KR = Pace Analytical Services - Kernersville, NC
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 3 of 28

aceAnaljdical
www.pactiabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Hart & Hickman Oracle 200
Pace Project No.: 92579041
Sample: OUTFALL SD01 Lab ID: 92579041001 Collected: 12/19/21 06:15 Received: 12/20/21 08:00 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
2540D Total Suspended Solids
Analytical Method: SM 2540D-2015
Pace Analytical Services - Eden
Total Suspended Solids
ND mg/L
2.5
1
12/22/21 11:24
1664 SGT-HEM, TPH
Analytical Method: EPA 1664B
Pace Analytical Services - Charlotte
Total Petroleum Hydrocarbons
ND mg/L
5.3
1
12/22/21 10:15
200.7 MET ICP
Analytical Method: EPA 200.7 Rev 4.4
1994 Preparation Method: EPA 200.7 Rev 4.4 1994
Pace Analytical Services -Asheville
Copper
ND mg/L
0.0050
1
12/3012115:01 01103/2217:38 7440-50-8
Lead
ND mg1L
0.0050
1
12/3012115:01 01103/2217:38 7439-92-1
Zinc
NO mgfL
0.010
1
12/3012115:01 01103/2217:38 7440-66-6
Field Data Kernersville
Analytical Method:
Pace Analytical Services - Kernersville,
NC
Performed by
Pace
1
12/19/21 06A6
Collected By
Glenn
1
12/19/21 06:15
Price
pH
6 '.77 Sid. Units
1
12/19/21 06A5
Temperature
16.4 deg C
1
12/19/21 06A5
5220D COD
Analytical Method: SM 5220D-2011
Preparation Method:
SM 5220D-2011
Pace Analytical Services - Asheville
Chemical Oxygen Demand
ND mg/L
25.0
1
12/23/21 01:16 12/23/21 05:14
Date: 01/05/2022 09:44 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 4 of 28

aceAnalj cal
www.pactiabs.com
ANALYTICAL RESULTS
Project: Hart & Hickman Oracle 200
Pace Project No.: 92579041
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NO 28078
[phone]
Sample: OUTFALL SD02 Lab ID: 92579041002 Collected: 12/19/21 06:24 Received: 12/20/21 08:00 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
2540D Total Suspended Solids
Analytical Method: SM 254OD-2015
Pace Analytical Services - Eden
Total Suspended Solids
ND mg/L
2.7
1
12/22/21 11:24
1664 SGT-HEM, TPH
Analytical Method: EPA 1664B
Pace Analytical Services -Charlotte
Total Petroleum Hydrocarbons
ND mg/L
5.0
1
12/22/21 10:15
200.7 MET ICP
Analytical Method: EPA 200.7 Rev 4.4
1994 Preparation Method: EPA 200.7 Rev 4.4 1994
Pace Analytical Services -Asheville
Copper
ND mg/L
0.0050
1
12130/2115:01 01/0312217:41 7440-50-8
Lead
ND mg/L
0,0050
1
12/3012115:01 01/03/2217:41 7439-92-1
Zinc
ND mg/L
0.010
1
1213012115:01 0110312217:41 7440-66-6
Field Data Kernersville
Analytical Method:
Pace Analytical Services - Kernersville,
NC
Performed by
Pace
1
12/19/21 06:24
Collected By
Glenn
1
12/19/21 06:24
Price
pH
6.80 Std. Units
1
12/19/21 06:24
Temperature
16.1 deg C
1
12/19/21 06:24
5220D COD
Analytical Method: SM 5220D-2011
Preparation Method: SM 5220D-2011
Pace Analytical Services - Asheville
Chemical Oxygen Demand
ND mg/L
25.0
1
12/23/21 01:16 12/23/21 05:14
Date: 01/05/2022 09A4 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 5 of 28

aceAnalytical
www.pacolabs.com
Pace Analytical Services, LLG
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
(704 )875-9092
ANALYTICAL RESULTS
Project: Hart & Hickman Oracle 200
Pace Project No.: 92579041
Sample: OUTFALL SD03 Lab ID: 92579041003 Collected: 12/19/21 06:39 Received: 12/20/21 08:00 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
2540D Total Suspended Solids
Analytical Method: SM 2540D-2015
Pace Analytical Services - Eden
Total Suspended Solids
ND mglL
2.8
1
12/22/21 11:25
1664 SGT-HEM, TPH
Analytical Method: EPA 1664B
Pace Analytical Services -Charlotte
Total Petroleum Hydrocarbons
ND mg/L
5.2
1
12/22/21 10:15
200.7 MET ICP
Analytical Method: EPA 200.7 Rev 4.4
1994 Preparation
Method: EPA 200.7 Rev 4.4 1994
Pace Analytical Services -Asheville
Copper
ND mg1L
0.0050
1
12/30/2115:01 01/0312217:44 7440-50-8
Lead
ND mg/L
0.0050
1
12/30/2115:01 01/0312217:44 7439-92-1
Zinc
ND mg/L
0,010
1
12130/2115:01 01/0312217A4 7440-66-6
Field Data Kernersville
Analytical Method:
Pace Analytical Services - Kernersville,
NC
Performed by
Pace
1
12/19/21 06:39
Collected By
Glenn
1
12/19/21 06:39
Price
pH
7.03 Std. Units
1
12/19/21 06:39
Temperature
15.9 deg C
1
12/19/21 06:39
5220D COD
Analytical Method: SM 5220D-2011
Preparation Method: SM 5220D-2011
Pace Analytical Services -Asheville
Chemical Oxygen Demand
ND mg/L
25.0
1
12/23/21 01:16 12/23/21 05:16
Date: 01/05/2022 09:44 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 6 of 28

aceAnalyllcal
www.pacelabs.com
ANALYTICAL RESULTS
Project: Hart & Hickman Oracle 200
Pace Project No.: 92579041
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Sample: OUTFALL SD04 Lab ID: 92579041004 Collected: 12/19/21 06:44 Received: 12/20/21 08:00 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
2540D Total Suspended Solids
Analytical Method: SM 254OD-2015
Pace Analytical Services - Eden
Total Suspended Solids
ND mg/L
2.5
1
12/22/21 11:26
1664 SGT-HEM, TPH
Analytical Method: EPA 1664B
Pace Analytical Services - Charlotte
Total Petroleum Hydrocarbons
ND mg1L
5.1
1
12/22/21 10:15
200.7 MET ICP
Analytical Method: EPA 200.7 Rev 4.4
1994 Preparation
Method: EPA 200.7 Rev 4.4 1994
Pace Analytical Services -Asheville
Copper
ND mg1L
0.0050
1
12/30/2115:01 01/0312217:48 7440-50-8
Lead
ND mglL
0,0050
1
12/30/2115:01 01/03/2217:48 7439-92-1
Zinc
ND mg1L
0.010
1
12/30/2115:01 01/03/2217:48 7440-66-6
Field Data Kernersville
Analytical Method:
Pace Analytical Services - Kernersville,
NC
Performed by
Pace
1
12/19/21 06:44
Collected By
Glenn
1
12/19121 06:44
Price
pH
6.69 Std. Units
1
12/19/21 06:44
Temperature
16.3 deg C
1
12/19/21 06:44
5220D COD
Analytical Method: SM 5220D-2011
Preparation Method: SM 5220D-2011
Pace Analytical Services -Asheville
Chemical Oxygen Demand
ND mg/L
25.0
1
01/04/22 01:38 01/04/22 05:30
Date: 01/05/2022 09:44 AM
REPORT OF LABORATORY ANALYSIS
This report shal$ not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 7 of 28

aceAnalytical
www.pacolabs.com
ANALYTICAL RESULTS
Project: Hart & Hickman Oracle 200
Pace Project No.: 92579041
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Sample: OUTFALL SD05 Lab ID: 92579041005 Collected: 12/19/21 06:53 Received: 12/20/21 08:00 Matrix: Water
Parameters Results Units Report limit DF Prepared Analyzed CAS No. Qua]
2540D Total Suspended Solids
Analytical Method: SM 2540D-2015
Pace Analytical Services - Eden
Total Suspended Solids
ND mg1L
3.0
1
12/22/21 11:26
1664 SGT-HEM, TPH
Analytical Method: EPA 1664B
Pace Analytical Services - Charlotte
Total Petroleum Hydrocarbons
ND mg/L
5.6
1
12/22/21 10:15
200.7 MET ICP
Analytical Method: EPA 200.7 Rev 4.4
1994 Preparation Method: EPA 200.7 Rev 4.4 1994
Pace Analytical Services -Asheville
Copper
ND mg1L
0.0050
1
1213012115:01 01103/2218:04 7440-50-8
Lead
ND mg/L
0.0050
1
12/30/2115:01 01/03/2218:04 7439-92-1
Zinc
ND mg/L
0.010
1
12/30/2115:01 01/03/2218:04 7440-66-6
Field Data Kernersville
Analytical Method:
Pace Analytical Services - Kernersville,
NC
Performed by
Pace
1
12/19/21 06:53
Collected By
Glenn
1
12/19/21 06:53
Price
pH
6.88 Std. Units
1
12/19/21 06:53
Temperature
16.3 deg C
1
12/19/21 06:53
5220D COD
Analytical Method: SM 5220D-2011
Preparation Method: SM 5220D-2011
Pace Analytical Services - Asheville
Chemical Oxygen Demand
ND mg/L
25.0
1
01/04/22 01:38 01/04/22 05:30
Date: 01/05/2022 09:44 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 8 of 28

aceAnalytical
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QUALITY CONTROL DATA
Project: Hart & Hickman Oracle 200
Pace Project No.: 92579041
QC Batch: 667805 Analysis Method: SM 2540D-2015
QC Batch Method: SM 254OD-2015 Analysis Description: 2540D Total Suspended Solids
Laboratory: Pace Analytical Services - Eden
Associated Lab Samples: 92579041001, 92579041002, 92579041003, 92579041004, 92579041005
METHOD BLANK: 3498428 Matrix: Water
Associated Lab Samples: 92579041001, 92579041002, 92579041003, 92579041004, 92579041005
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Total Suspended Solids mg/L ND 2.5 12/22/21 11:22
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
LABORATORY CONTROL SAMPLE: 3498429
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Total Suspended Solids mg/L 250 236 94 90-110
SAMPLE DUPLICATE: 3498430
92579138001 Dup
Parameter Units Result Result RPD Qualifiers
Total Suspended Solids mg/L 160- 160 0
SAMPLE DUPLICATE: 3498431
92579243002 Dup
Parameter Units Result Result RPD Qualifiers
Total Suspended Solids mg/L 46.1 47.4 3
Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 01/05/2022 09:44 AM without the written consent of Pace Analytical Services, LLC. Page 9 of 28

aceAnalytical
�
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QUALITY CONTROL DATA
Project: Hart & Hickman Oracle 200
Pace Project No.: 92579041
QC Batch: 667686 Analysis Method: EPA 16646
QC Batch Method: EPA 1664B Analysis Description: 1664 SGT-HEM, TPH
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92579041001, 92579041002, 92579041003, 92579041004, 92579041005
METHOD BLANK: 3497974 Matrix: Water
Associated Lab Samples: 92579041001, 92579041002, 92579041003, 92579041004, 92579041005
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Total Petroleum Hydrocarbons mg1L ND 5.0 12/22/21 10:15
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
LABORATORY CONTROL SAMPLE: 3497975
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Total Petroleum Hydrocarbons mg/L 20 15.9 80 64-132
MATRIX SPIKE SAMPLE:
Parameter
3497976
Units
92579041001
Result
Spike MS MS % Rec
Conc. Result % Rec Limits Qualifiers
Total Petroleum Hydrocarbons
mg/L
ND
21.1 17.8 80 64-132
SAMPLE DUPLICATE: 3497977
92579041002
Dup
Parameter
Units
Result
Result RPD Qualifiers
Total Petroleum Hydrocarbons
mg/L
ND
ND
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 01/05/2022 09:44 AM without the written consent of Pace Analytical Services, LLC.
Page 10 of 28

aceAnalytical
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QUALITY CONTROL DATA
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: Hart & Hickman Oracle 200
Pace Project No.: 92579041
QC Batch: 668898
Analysis Method: EPA
200.7 Rev 4A 1994
QC Batch Method: EPA 200.7 Rev 4.4 1994
Analysis Description: 200.7 MET
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92579041001, 92579041002,
92579041003, 92579041004, 92579041005
METHOD BLANK: 3503178
Matrix: Water
Associated Lab Samples: 92579041001, 92579041002,
92579041003, 92579041004, 92579041005
Blank Reporting
Parameter Units
Result Limit
Analyzed Qualifiers
Copper mg/L
ND 0.0050
01103/2216:18
Lead mg1L
ND 0.0050
0110312216:18
Zinc mg1L
ND 0,010
0110312216A8
LABORATORY CONTROL SAMPLE: 3503179
Spike LCS
LCS % Rec
Parameter Units
Conc. Result
% Rec Limits Qualifiers
Copper mg/L
0.5 0.52
104 85-115
Lead mg/L
0.5 0.53
107 85-115
Zinc mg/L
0.5 0.49
99 85-115
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3503180 3503181
MS MSD
92578847001
Spike Spike MS
MSD MS MSD
% Rec
Parameter Units Result
Conc. Conc. Result
Result % Rec % Rec
Limits
RPD Qua)
Copper mg1L 0,11
0.5 0.5 0.63
0.62 104 102
70-130
2
Lead mg1L 0,026
0.5 0.5 0.56
0.55 106 104
70-130
1
Zinc mg/L 0.37
0.5 0.5 0.84
0.84 95 95
70-130
0
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3503182 3503183
MS MSD
92578979001
Spike Spike MS
MSD MS MSD
% Rec
Parameter Units Result
Conc. Conc. Result
Result % Rec % Rec
Limits
RPD Qua)
Copper mg/L 4.6J
0.5 0.5 0.50
0,51 100 101
70-130
1
ug/L
Lead mg1L ND
0.5 0.5 0,52
0,52 103 104
70-130
1
Zinc mg/L 37.0
0.5 0.5 0.52
0,53 97 98
70-130
1
ug1L
Results presented on this page are in the units Indicated by the "Units" column except where an alternate unit Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 01/05/2022 09:44 AM without the written consent of Pace Analytical Services, LLC.
Page 11 of 28

aceAna1j ca!
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Hart & Hickman Oracle 200
Pace Project No.: 92579041
QC Batch: 668082 Analysis Method: SM 5220D-2011
QC Batch Method: SM 5220D-2011 Analysis Description: 5220D COD
Laboratory: Pace Analytical Services - Asheville
Associated Lab Samples: 92579041001, 92579041002, 92579041003
METHOD BLANK: 3500045 Matrix: Water
Associated Lab Samples: 92579041001, 92579041002, 92579041003
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Chemical Oxygen Demand mglL ND 25.0 12/23/21 05:08
LABORATORY CONTROL SAMPLE: 3500046
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Chemical Oxygen Demand mglL 750 756 101 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3500047 3500048
MS MSD
92578477001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Chemical Oxygen Demand mglL 166 100 100 265 270 99 104 90-110 2
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3500049 3500050
MS MSD
92578477002 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Chemical Oxygen Demand 1 46.0 100 100 147 155 101 109 90-110 5 R1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 01/05/2022 09:44 AM without the written consent of Pace Analytical Services, LLC.
Page 12 of 28

aceAnalj4ical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: Hart & Hickman Oracle 200
Pace Project No.: 92579041
QC Batch: 669558
QC Batch Method: SM 5220D-2011
Associated Lab Samples: 92579041004, 92579041005
METHOD BLANK: 3506006
Associated Lab Samples: 92579041004, 92579041005
Parameter Units
Chemical Oxygen Demand mglL
LABORATORY CONTROL SAMPLE: 3506007
Parameter Units
Chemical Oxygen Demand mglL
QUALITY CONTROL DATA
Analysis Method:
Analysis Description:
Laboratory:
Matrix: Water
SM 5220D-2011
5220D COD
Pace Analytical Services -Asheville
Blank Reporting
Result Limit Analyzed Qualifiers
ND 25.0 01 /04/22 05:28
Spike LCS LCS % Rec
Conc. Result % Rec Limits Qualifiers
750 759 101 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3506008 3506009
MS MSD
92578787001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Chemical Oxygen Demand mg1L 75.2 100 100 185 190 110 114 90-110 2 M1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3506010 3506011
MS MSD
92579560002 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Chemical Oxygen Demand mglL 51.8 100 100 157 164 105 112 90-110 4 M1,R1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 01/05/2022 09:44 AM without the written consent of Pace Analytical Services, LLC.
Page 13 of 28

(�IaoAnalj4ical
www.pacelatrs.com
QUALIFIERS
Project: Hart & Hickman Oracle 200
Pace Project No.: 92579041
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
PQL- Practical Quantitation Limit.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis ofAcrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as
"Total" may vary slightly from the sum of the reported component parameters.
Pace Analytical is TNI accredited. Contact your Pace PM for the current fist of accredited analyles.
TN -The NELAC Institute.
ANALYTE QUALIFIERS
M 1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
R1 RPD value was outside control limits.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 01/05/2022 09:44 AM without the written consent of Pace Analytical Services, LLC. Page 14 of 28

aomnalXical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project:
Pace Project No.:
Hart & Hickman Oracle 200
92579041
Analytical
Lab ID
Sample ID
QC Batch Method
QC Batch
Analytical Method
Batch
92579041001
OUTFALL
SD01
SM 254OD-2015
667805
92579041002
OUTFALL
SD02
SM 254OD-2015
667805
92579041003
OUTFALL
SD03
SM 254OD-2015
667805
92579041004
OUTFALL
S1304
SM 254OD-2015
667805
92579041005
OUTFALL
SD05
SM 2540D-2015
667805
92579041001
OUTFALL
SD01
EPA 1664B
667686
92579041002
OUTFALL
SD02
EPA 1664B
667686
92579041003
OUTFALL
SD03
EPA 1664B
667686
92579041004
OUTFALL
SD04
EPA 1664B
667686
92579041005
OUTFALL
SD05
EPA 1664B
667686
92579041001
OUTFALL
SD01
EPA 200.7 Rev 4.4 1994
668898
EPA 200.7 Rev 4.4 1994
669314
92579041002
OUTFALL
SD02
EPA 200.7 Rev 4.4 1994
668898
EPA 200.7 Rev 4.4 1994
669314
92579041003
OUTFALL
S1303
EPA 200.7 Rev 4.4 1994
668898
EPA 200.7 Rev 4.4 1994
669314
92579041004
OUTFALL
SD04
EPA 200.7 Rev 4.4 1994
668898
EPA 200.7 Rev 4.4 1994
669314
92579041005
OUTFALL
SD05
EPA 200.7 Rev 4.4 1994
668898
EPA 200.7 Rev 4.4 1994
669314
92579041001
OUTFALL
S11301
92579041002
OUTFALL
SD02
92579041003
OUTFALL
SD03
92579041004
OUTFALL
SD04
92579041005
OUTFALL
SD05
92579041001
OUTFALL
SD01
SM 5220D-2011
668082
SM 5220D-2011
668103
92579041002
OUTFALL
S11302
SM 5220D-2011
668082
SM 5220D-2011
668103
92579041003
OUTFALL
SD03
SM 5220D-2011
668082
SM 5220D-2011
668103
92579041004
OUTFALL
SD04
SM 5220D-2011
669558
SM 5220D-2011
669569
92579041005
OUTFALL
SD05
SM 5220D-2011
669558
SM 5220D-2011
669569
Date: 01/05/2022 09:44 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 15 of 28

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`Chem6-1 mark top half of bo:< j f pH and/or &chlorination is Fro;ec[ WO# 92579041
Verifi_d a„c' -.iuMn the acceptance ranbe for preservation PM: KING clue Date: 12/2$/21
samples.
e.;',' -3 .erI CCC, L'_H3 CLIENT' • 52"Hart—Ral
.
"Bottom half of box is to list number of bottles
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PH Adjustment Log for preserved Samples
Safnpl: 10 Tipe of pre"ar•rative pH upon receipt ( Date preserl13tion adjusted Time preserv3ticn Amcunt PrPrzsarvativ±
adjusted added
Lot M
N3[e: V c
,hzn2'r2l thj,E is a discre;arn j al�ec:ir.r, Mun i Carchna ccmgli3ac i3ir¢I2s, a cc, p of li,i fcr�ti :AI �e szn; to tae Car_iina Uh,;R. Cert:f�cal;ian Oric: (i.e.
Cut of hind, incorrect preseriati+,e, out of letup, inccrfw, containers.
Page 17 of 28