WQ0019960_Residual Annual Report 2021_20220222

Non-Discharge Branch Upload/Submittal Form �.
NORTH CAROLINA
EnWrvnmenfol Quoity
Version 2-Revised June 23,2020
Initial Review
Reviewer Thornburg,Nathaniel D
Is this submittal an application?(Excluding additional information.)*
Yes No
If not an application what is the submittal type?* Annual Report
Residual Annual Report
Additional Information
Other
Annual Report Year* 2021
Permit Number(IR)* WQ0019960
Applicant/Permittee City of Marion
Email Notifications
Does this need review by the hydrogeologist?* Yes • No
Regional Office Asheville
CO Reviewer
Admin Reviewer

Submittal Form
Project Contact Information
Please provide information on the person to be contacted by NDB Staff regarding electronic submittal,confirmation of receipt,and other correspondence.
............................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................
Name* Brant Sikes
Email Address* Phone Number*
[e-mail] 8286524224
Project Information
Application/Document Type* New(Fee Required) Modification-Minor
Modification-Major(Fee Required) Renewal
Renewal with Major Modification(Fee GW-59, NDMR,NDMLR, NDAR-1,
Required) NDAR-2
Annual Report Residual Annual Report
Additional Information Change of Ownership
Other
We no longer accept these monitoring reports through this portal. Please click on the link below and it will take you to the correct form.
https://edocs.deg.nc.gov/Forms/NonDischarge_Monitoring_Report
Permit Type:* Wastewater Irrigation High-Rate Infiltration
Other Wastewater Reclaimed Water
Closed-Loop Recycle Residuals
Single-Family Residence Wastewater Other
Irrigation
Permit Number:* WQ0019960
Has Current Existing permit number
Applicant/Permittee Address* PO Drawer 700 Marion NC 28752
Facility Name* City of Marion Class B Residuals Program
Please provide comments/notes on your current submittal below.
At this time,paper copies are no longer required.If you have any questions about what is required,please contact Nathaniel Thornburg
at [e-mail].
Please attach all information required or requested for this submittal to be reviewed here.*
(Application Form,Engineering Plans,Specifications,Calculations,Etc.)
2021 Annual Report Submitted 2.22.22.pdf 10.34MB
Upload only 1 PDF document(less than 250 MB).Multiple documents must be combined into one PDF file unless file is larger
than upload limit.
* By checking this box, I acknowledge that I understand the application will not be
accepted for pre-review until the fee(if required)has been received by the Non-
Discharge Branch.Application fees must be submitted by check or money order and
made payable to the North Carolina Department of Environmental Quality(NCDEQ).
I also confirm that the uploaded document is a single PDF with all parts of the
application in correct order(as specified by the application).
Mail payment to:
NCDEQ—Division of Water Resources
Attn:Non-Discharge Branch
1617 Mail Service Center
Raleigh,NC 27699-1617
Signature
cf:ffea-re-.56e84
Submission Date 2/22/2022

2021
City of Marion
Wastewater Treatment Plant
2021 Annual Report
Land Application Program
Permit No. WQ0019960

ANNUAL LAND APPLICATION CERTIFICATION FORM
WQ Permit#: WQ0019960 County; McDowell Year: 2021
Facility Name(as shown on permit): City of Marion
Land Application Operator: US Biosolids, Inc. Phone: [phone]
Land application of residuals as allowed by the permit occurred during the past calendar year?
L7 Yes 0 No - If No,skip Part A,and Part B and proceed to Part C. Also, If residuals were
generated but not land applied,please attach an explanation on how the residuals were handled.
Part A- Residuals Application Summary;
Total number of application fields in the permit: 6
Total number of fields utilized for land application during the year: 4
Total amount of dry tons applied during the year for all application sites: 103.37
Total number of acres utilizes for land application during the year: 44.6
Part B-Annual Compiance Statement:
Facility was compliant during calendar year 2021 with all conditions of the land application permit
(including but not limited to items 1-13 below)issued by the Division of Water Resources. C_1 Yes Li No
If no please,provide a written description why the facility was not compliant, the dates,and explain corrective action
taken.
1) Only residuals approved for this permit were applied to the permitted sites.
2) Soil pH was adjusted as specified in the permit and lime was applied(if needed)to achieve a soil pH of at least 6.0 or
the limit specified in the permit.
3) Annual soils analysis were performed on each site receiving residuals during the past calendar year and three(3)copies
of laboratory results are attached.
4) Annual TCLP analysis(if required)was performed and three(3)copies of certified laboratory results are attached.
5) All other monitoring was performed in accordance with the permit and reported during the year as required and three
(3)copies of certified laboratory results are attached.
6) The facility did not exceed any of the Pollutant Concentration Limits in l5A NCAC 02T.1105(a)or the Pollutant
Loading Rates in I 5A NCAC 02T.1105(b)(applicable to 40 CFR Part 503 regulated facilities).
7) All general requirements in as specified in the Land Application Permit were complied with(applicable to 40 CFR Part
503 regulated facilities).
8) All monitoring and reporting requirements in I5A NCAC 021' .1 1 11 were complied with(applicable to 40 CFR Part
503 regulated facilities).
9) All operations and maintenance requirements in the permit were complied with or, in the case of a deviation, prior
authorization was received from the Division of Water Resources.
10) No contravention of Ground Water Quality Standards occurred at a monitoring well or explanations of violations are
attached to include appropriate actions and remediations,
11) Vegetative cover was maintained and proper crop management was performed on each site reccing residuals,as
specified in the permit.
12) No runoff of'residuals from the application sites onto adjacent property or nearby surface waters has occurred.
13) Ali buffer requirements as specified on the permit were maintained during each application ot'residuals.
Part C-Certification:
"I certify, under penalty of law, that the above information is,to the best of my knowledge and belief,true,accurate,
and complete. I am aware that there are significant penalties for submitting false information,including the
possibility of fines and imprisonment for knowing viola!' "
erf&D 2 2l 2z
Permittee Name art Title o print) Si ature f Permitte ry�_r
pe to a+� a mttte Date
/rip fixs- 2-n-7z
Signature of Preparer* Date Signature of Land 1[ppiier Date
(if different from Permittee) (if different from Permittee and Preparer)
Preparer is defined in 40 CFR Part 503.9(r)and I 5A NCAC 02T.1102(26) DENR FORM ACF(1212006)

ANNUAL RESIDUAL SAMPLING SUMMARY FORM
Please note that your permit may contain additional parameters to be analyzed. The parameters can be reported in FORM RSSF- B
WQ Permit Number: WQ0019960 Laboratory: 1) Pace Analytical
Facility Name: City of Marion 2)
Residual Source WQ #or 3)
N NC0031879
PDES#:
4)
WWTP Name: City of Marion 5)
Residual Analysis Data
Conc. Sample or Composite Date
Parameter Limit
(mg/kg) a 7_� �4
(mg/kg}
Percent Solids{%) NA 2.1
Arsenic 75 ND
Cadmium 85 ND
Copper 4,300 574
Chromium NA NA
Lead 840 59.3
Mercury 57 1.2
Molybdenum 75 ND
Nickel 420 22.8
Selenium 100 ND
Zinc 7,500 1280 _
Total Phosphorus NA 18400 _ _
TKN NA 30400
Ammonia-Nitrogen NA 2220
Nitrate and Nitrite NA 8970 t
''For surface disposal facilities the ceiling,concentration limits listed in this form are not applicable. Reference the individual permit for metals limits.
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed
to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant
penalties for submitt' g false information, including the possibility of fines and imprisonment for knowing violations."
—
---- :::777 . Z —2./ - 1?-1--.
Signature of Preparer * Date
*Preparer is defined in 40 CFR Pan 503.9(r)and ISA NCAC 2T .1 102 (26) DENR FORM RSSF (12/2006)

ANNUAL RESIDUAL SAMPLING SUMMARY FORM - B
Report all sampling analysis results for parameters not listed in FORM RSSF that are part of the WQ permit or were analyzed for over the past
calendar year. Use additional forms as needed_
WQ Permit Number: WQ0019960 Laboratory: 1) Pace Analytical
Facility Name: City of Marion 2)
Residual Source NC0031879 3)
NPDES#or WQ#: 4)
WWTP Name: City of Marion 5)
Residual Analysis Data
Sample or Composite Date
Parameter
-,_1_11
(mtz./kg)
Aluminum 19100
Calcium 43800
Magnesium 4630
Potassium ND
Sodium ND
•
pH 6
PAN 27534
SAR 0.004
"1 certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system
designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are
significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations."
Signature of Preparer Date
*Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26) DENR FORM RSSF - B(12l2006)

ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name: City of Marion Total Dry Tons Applied(Annual): 11.17
Permit#: WQ0019960 Cation Exchange Capacity (non 503 only):
Operator: John Fisher Owner: John Fisher Predominant Soil Series: FiaC
Acres Used: 7 Acres Permitted; 7 Site 0: F3 Field #: F3
Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, °A Solids use Raw Percent #):
Sample or!_1. 2 3I aj 5 6` 7' 8i 9 10t 11 12 ',
Com-
posite
Date 2/2/22
%Solids 2.1
Arsenic 0
Cadmium 0
Copper 574
Chromium 0
Lead 59.3
Mercury 1.2
Molyb- " 0
denum
Nickel 22.8
Selenium 0
Zinc 1280
Total Phos- 18400
phorus -
Annual Heavy Metal Field Loadings (Calculated in lbs/acre):
Total 1 2 3E _4 5 6 7 8° 9 10 11 12
D r/Ac./
App.
Event 1.60 ..
Arsenic 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000
Cadmium 0.000 0,000 0.000 _ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000
Copper 1.831 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 1.831
Chromium 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000
Lead 0.i 89 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.189
Mercury 0.004 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.004
Molyb 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000
denum
Nickel 0.073 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0,000 0.000 0.073
Selenium 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000
Zinc 4.083 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 4,083
Total
Plws- 58.696 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 58.696
phorus 1
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of lines and
imprisonment for knowing violations".
Signature of Land Ap ier Date
DENR FORM MFLSF (12/2006)

ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name: City of Marion Total Dry Tons Applied(Annual): 17.64
Permit#: WQ00l9960 Cation Exchange Capacity (non 503 only):
Operator: John Fisher Owner: John Fisher Predominant Soil Series: NaC
Acres Used: 6.7 Acres Permitted: 6.7 Site#: F4 Field #: F4
Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent#):
Sample or I 2 i - 3 E 4 9 ! 6' 7? 8` 9 10 11 12
Com-
posite
Date 2/2/22
%Solids 2.1
Arsenic 0
Cadmium 0
Copper 574
Chromium 0
Lead 59.3
Mercury 1.2
Molyb- 0
denum -
Nickel 2.2.8
Selenium 0
Zinc 1280
Total
Phos- 18400
phorus
Annual Heavy Metal Field Loadings (Calculated in lbs/acre):
Total 1 i z 3 ' 4 5' 6 7 `..$ 9 10 11 12
DT.I Ac.% e
App.
Lvent 2.63
Arsenic 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000
Cadmium 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000
Copper 3.023 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 3.023
Chromium 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000
Lead 0.312 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0,000 0.000 0.000 0.312
Mercury 0.006 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.006
Molyb- 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000
den um
Nickel 0.120 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.120
Selenium 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000
Zinc 6.740 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 6.740
Fotal
Phos- 96.894 0.000 0.000 0.000 0.000 0.000 0,000 0.000 0.000 0.000 0.000 0.000 96.894
phorus
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information,including the possibility of fines and
imprisonment for knowing violations".
15,•"..--- 2t-7z.
Signature of Land Applier Date
DENR FORM MFLSF(12/2006)

ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name: City of Marion Total Dry Tons Applied (Annual): 30.74
Permit#: W00019960 Cation Exchange Capacity (non 503 only):
Operator: Brain Kay Owner: Brian Kay Predominant Soil Series: HaC
Acres Used: 17.2 Acres Permitted: 17.2 Site #: R I Field #: RI
Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, "Ai Solids use Raw Percent #):
`Sample or_1_' 2 • 3 1 4 ! 5 5 i 7 ` B` 9. 110 11 12
Com-
posite
Date 212/22
%Solids 2.1
Arsenic 0
Cadmium 0 _
Copper 574
Chromium 0
Lead 59.3
Mercury 1.2
Molyb- 0
denum
Nickel 22.8
Selenium 0
Zinc 1280
Total
Phos- 18400
phorus - -
Annual Heavy Metal Field Loadings (Calculated in lbs/acre):
Total I 4 5 6 7 8 9 10 11 . 12 1 2 ; -3
DT Ac./ o
App. w
!;vent 1.79 "
Arsenic 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000
Cadmium 0.000 _ 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000
Copper 2.051 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 2.051
Chromium 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000
Lead 0.212 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.212
Mercury 0.004 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0,000 , 0.000 0.004
Molyb 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000
denum
Nickel 0.081 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.081
Selenium 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000
Zinc 4,575 0.000 0.000 0,000 0,000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 4.575
Total
Phos- 65.762 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 65.762
phorus
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
])./Ar '7/4),/ ?
Signature of Land Applier Date
DENR FORM MFLSF (12/2006)

ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name: City of Marion Total Dry Tons Applied(Annual): 43.83
Permit#: WQ0019960 Cation Exchange Capacity(non 503 only):
Operator: Brain Kay Owner: Brian Kay Predominant Soil Series: HaC
Acres Used: 13.7 Acres Permitted: 13,7 Site#: R2 Field #: R2
Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #):
Sample or .1 2! 3 1 4. 5 . 6, 7: 8 9 10 I 11 ; 12
Corn-
posite
Date 2/2/22
%Solids 2.1
Arsenic 0 _
Cadmium 0
Copper 574
Chromium 0
Lead 59.3
Mercury 1.2
Molyb- 0
denurn
Nickel 22.8
Selenium 0
Zinc 1280
Total
Phos- 18400
pliorus
Annual Heavy Metal Field Loadings (Calculated in lbs/acre):
Total 1 2 3; 4 : 5 5, 7 ' 8 9' 10 11 12
DT/Ac..'
App w
r
Event 3.20
r
Arsenic 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000
Cadmium 0.000 0.000 0.000 0,000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000
Copper 3.672 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 3.672
Chromium 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000
Lead 0.379 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.379
Mercury 0.008 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.008
Molyb- 0 000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000
denum
Nickel 0.146 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.146
Selenium 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000
Zinc 8.189 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 8.189
Total
Phos- 117.723 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 117.723
• phorus
"l certify, under penalty of law, that this document was prepared under my direction or supervision in accordance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of lines and
imprisonment for knowing violations".
Sign turc of Land Applier ��---- -- --- -- Date
DENR FORM MFLSF (12/2006)

ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
Facility Name: City of Marion WQ Permit#: WQ0019960 Field#: F3 Acres Utilized: 7
Land Owner: John Fisher Annual Dry Tons Applied: 11.1652 Site#: F3 Acres Permitted: 7
Operator: John Fisher Predominant Soil Series: HaC Cation Exchange Capacity(non 503):
Crop I Name: Fescue Crop I Max. PAN: 702 Crop 2 Name: Crop 2 Max. PAN:
Volumeapplied VolumeSoil
Residual Sources 1'rccip. z Niirate PAN Applied
Name ofCrop Type
t -2 (enter one)Solids/ oo Appliedper NI'1)1=.S ii.W t! Cond• fast 24 �. 7 � - pp
Y � pp { � _ _ 174' 'KN and Receiving Residual
e: ° Liquid Solids Acre Vert..Animal (1)rY' Firs. - N .* l rz _- Niiriie ( Ih;racrcl Application
Cu. Yds Gallons (Dry Tons/AC) Waste.ell} Moist) l'ches * 2 mglkg mg/kg mg/kg Crop I Crop 2 Crop I Crop 2
7.2021 110500 2.1 1.382 NC:0031879 dry 0 s 0.5 0.3 30400 2220 8970 51.241 NA Fescue
111-2021 17000 , 2.1 0.213 NC0031879 dry U s 0.5 0.3 30400 2220 8970 7.883 NA LFescue
0.000 0.000 , 0.000
0.000 _ _ - 0.000 _ 0.000
0.000 0.000 0.000
0.000 _ 0.000 0.000
0.000 0.000 0.000
-0.000 0.000 0.000 F
_ 0.000 0.000 0.000
0.000 0.000 0.000
0.000 0.000 0.000
0.000 0.000 0.000
Residuals Applications totals on FORM FSF supp(attach FORM FSF supp to this form):
TOTA1_S. 0 I27500 As _ Cd Cu Cr Pb Hg, Mo Ni Se Zn P 59.124 0.000 Lime Applied
Annual lbs/acre 0.000 0.000 1.831 0.000 0.189 0.004 0.000 0.073 0.000 4.083 58.696 L Date . lbs/ac
Prior Years Cumulative lbs/ac 0.424 0.171 10.947 s 1.763 1.579 0.055 0.737 0.675 0.42 29.95 0
Current Cumulative lbs/ac 0.424 0.171 12.778 1.763 1.768 0.059 0.737 (1.748 0.420 34.033
Permitted C. P. L. R.**** 36 34 NA 133 267 15 NA 374 89 2498
Permit PAN Limit 1st/2nd Crop 202
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false
information, including the possibility of fines and imprisonment for knowing violations."
*Application Method: S-Surface, IN - Injection, INC- Incorporation
/ .? 2 71-al. **Volatilization Rate: Surface-0.5, injection/Incorporation- 1.0
*** Mineralization Rates: Compost-0.1,anaerobially digested-0.2,
Signature of Land Applier Date
aerobically digested-0.3, raw sludge-0A
****C.P.L.R.: Cumulative Pollutant Loading Rate
DENR FORM FSF (12/2006)

ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
Facility Name: City of Marion WQ Permit#: WQ0019960 Field#: F4 Acres Utilized: 6.7
Land Owner: John Fisher Annual Dry Tons Applied: 17.6454 Site#: F4 Acres Permitted: 6.7
Operator: John Fisher Predominant Soil Series: HaC Cation Exchange Capacity(non 503):
Crop I Name: Fescue Crop 1 Max. PAN: 202 Crop 2 Name: Crop 2 Max. PAN:
Volume applied Volume Residual Sources Soil Preeip. :: C 4 ?. Nitrate Name of Crop 1�pc
`o = L'cmd. - z PAN Applied
= (enter one)Solids/ % Applied per (NPDES Y.W()Y, Past 24 '5 w = 1 KN and Receiving Residual
'-' o I.iitidfDn. = n ( Ihs,arrc)
c� 1 Solids Acre Fen_An Hrs. v Nitrite Application
Cu. Yds Gallons (DryTenslAcj waste.etC) M sit inches 7 mg/kg mg/kg mgfkg Crop I Crop 2 Crop 1 Crop 2
^7-202 1 91000 2.1 1.189 NC0031879 dry t) s 0.5 0.3 30400 2220 8970 44.088 NA Fescue
10-202 1 110500 2.1 1.444 NC0031879 dry 0 s 0.5 0.3 30400 2220) 8970 53.536 NA Fescuc
0.000 _ 0.000 0.000 _
_ 0.000 0.000 0.000
I
0.000 _ �_ 0.000 0.000
0.000 _ 0.000 0.000
0.000 0.000 0.000
- W
0.000 0.000 0.000
_ r 0.000 0.000 0.000
_0.000 5 0.000 _ 0.000
i
1)00() 0.000 0.000
0.000 0.000 0.000
Residuals Applications totals on FORM FSF supp(attach FORM FSF supp to this form):
FO1AI.S It 201500 As _ Cd Cu Cr ' Pb f Hj1 .. Mo , Ni Sc _ Zat ' P 97.624 (f.000 Lime Applied
Annual lbs/acre 0.000 0.000 3.023 0.000 0.312 0.006 0.000 0.120 0.000 6.740 96.894 Date lbs/ac
Prior Years Cumulative lbs/ac (1.394 0.905 13.278 2.109 1.849 0.065 0.706 0.793 0.404 32.344 0
Current Cumulative lbs/ac 0.394 0.905 _ 16.3()1 2.109 2.161 0.071 _ 0.706 0.913 0.404 39.084
Permitted C. P. L. It **** 36 34 NA 133 267 15 NA 374 89 2498
Permit PAN Limit 1st/2nd Crop 202
"I certify,under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false
information, including the possibility of fines and imprisonment for knowing violations."
*Application Method: S-Surface, 1N- Injection, INC- Incorporation
P
Z-)J.)) **Volatilization Rate: Surface-0.5, Injection/Incorporation- 1.0
Signature of Land Applier Date 's** Mineralization Rates: Compost-0.1,anaerobially digested-0.2,
aerobically digested-0.3, raw sludge-0.4
****C.P.L.R.: Cumulative Pollutant Loading Rate
DENR FORM FSF (12/2006)

ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
Facility Name: City of Marion WQ Permit#: WQ0019960 Field#: RI Acres Utilized: 17.2
Land Owner: Brian Kay Annual Dry Tons Applied: 30.7371 Site#: RI Acres Permitted: 17.2
Operator: Brian Kay Predominant Soil Series: HaC Cation Exchange Capacity(non 503):
Crop I Name: Fescue Crop I Max. PAN: 202 Crop 2 Name: Crop 2 Max. PAN:
Volume applied 1 Volume Residual Sources Soil Precip. > C z > Nitrate Name of Crop l'ypc
o s Cond. z' PAN Applied
-� (enter one)Solids/ % Applied per (NPDES#. WQ4- Past 24 ro ? c = z TKN and Receiving Residual
ro I.iyuid Solids Acre (1)r�. �' F = •; _ ( Ihs/acre)
Fen_ Animal Hrs. �' M' F. Nitrite Application
Waste.etc) mot- • o + •
Cu. YdsGallons lD Tons/Ac) Moist) +aches mg/kg mg/kg mg/kg Crop 1 Crop 2 Crop I Crop 2
-
7-2021 305500 2.1 1.555 NC0031879 din' 0 s _ 0.5 0.3 30400 2220 8970 57.655 NA Fescue
-
8-2021 45500 2.1 0.232 NC003)879 do 0 s 0.5 0.3 30400 2220 8970 8.587 NA Fescue
0.000 0.000 0.000
0.000 - _0.000 0.000
0.000 0.000 0.000
0.000 A 0.000 0.000 .
0.000 _ 0.000 0.000
0.000 0.000 - 0.000 .
0.000 0.000 0.000 -
0.00t1 - 0.000 0.000
0.000 _ 0.000 0.000 T
0.0110 0.000 0.000
Residuals Applications totals on FORM FSF supp(attach FORM FSF supp to this form):
'ttf�.S: of 351000� As Cd Cu Cr Pb Hg + Mo Ni Se Zn P 66.242 0.000 Lime Applied
Annual lbs/acre 0.000 0.000 2.051 0.000 0.212 0.004 0.000 0.081 0.000 4.575 65.762 Date ' lbs/ac
Prior Years Curnu;ative lbs/ac 0.202 0.1 1 1.023 1.475 1.631 0.062 1.401 0.672 0.243 27.842 11-21 2000
Current Cumulati'.•e lbs/ac 0.202 0.100 13.074 1.475 1.843 0.066 1.401 0.753 0.243 32.417
Permitted C. P. I.. R.**** 36 34 NA 1 33 267 15 NA 374 89 2498
Permit PAN Limit 1st/2nd Crop 202
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false
information,including the possibility of fines and imprisonment for knowing violations."
7 *Application Method: S-Surface, IN- injection, INC- Incorporation
J �� 2)1'7)- **Volatilization Rate: Surface-0.5, Injection/Incorporation - 1.0
Si, nature of Land Applier Date *** Mineralization Rates: Compost-0.1,anaerobially digested-0.2,
aerobically digested-0.3, raw sludge-0.4
****C.P.L.R.:Cumulative Pollutant Loading Rate
DENR FORM FSF(12/2006)

ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
Facility Name: City of Marion WQ Permit#: WQ0019960 Field#: R2 Acres Utilized: 13.7
Land Owner: Brian Kay Annual Dry Tons Applied: 43.8288 Site#: R.2 Acres Permitted: 13.7
Operator: Brian Kay Predominant Soil Series: HaC Cation Exchange Capacity(non 503):
Crop 1 Name: Fescue Crop 1 Max. PAN: 202 Crop 2 Name: Crop 2 Max. PAN:
Soil
Volume applied Volume Residual Sources 1'reeip. .W n Nitrate PAN Applied Name ofC rap Type
° = (enter one)Sol ids/ o, Cond. , -
o !1f>piied per (NPDFS#.i�r()i1. Past 24 T? = ? 1'!tN and Receiving Residual
_ - r. - ' t lbshdcret
1_i uid Acre Fen..Animal (1)r.. l lrs, o z� ;, n + ? Nitrite Application
Q 7 u SolidsU. wF. J
Cu. Yds Gallons (Dry Tons/AC; Waste.etc) inches ' n /x m rx m Jx CropI Crop2 CropI Crop2
Moist) �T�9 9 9 9 9 9 - -
7-2021 240500 2.1 1.537 NC0031879 dr. 0 s 0.5 0.3 30400 2220 8970 56.983 NA Fescue
10-2021 260E100 2.1 1.662 NC0031879 dry 0 s 0.5 0.3 30400 2220 8970 61.604 NA Fescue
0.000 0.000 0.000
0.000 - 0.000 0.000
0.000 - 1 0.000 0.000
0.000 _ 0.000 0.000 A -
0.000 _ 0.000 0.000
0.000 _ 0.000 0.000
0.000 ^ 0.000 '
0.000
0.000 0.000 0.000
0.000 _ 0.000 0.000
0.000 0.000 0.000
Residuals Applications totals on FOR!11 FSF supp(attach FORM FSF supp to this form):
1. .- - -
i OrAI s._ 0 500500 As Cd Cu Cr Pb Hg Mo Ni Se Zn P 118.587 0.000 Lime Applied
Annual lbs/acre 0.000 0.000 3.672 0.000 0.379 0.001i 0.000 0.146 0.000 8.189 117.723 Date lbs/ac
^
Prior Years Cumulative lbs/ac 0.2 ) 0.115 11-842 3 0.065 1.508 0.345 1.139 0.654 0.251 28.235 11.21 2000
Current Cumulative lbs/ac 0.231 0.115 15.514 0.065 1.887 0.353 1.139 0.800 0.251 36.424
Permitted C. P. 1_. R.**** 36 34 NA 133 267 15 NA 374 89 2498
Permit PAN Limit 1 st/2nd Crop 202
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false
information, including the possibility of fines and imprisonment for knowing violations."
*Application Method: S-Surface, IN- Injection, [NC- Incorporation
0, - 9." 1'x.2. **Vo1atifization Rate:Surface-0.5, Injection/Incorporation- 1.0
Signature of Land Applier Date `** Mineralization Rates: Compost-0.1,anaerobially digested-0.2.
aerobically digested-0.3, raw sludge-0.4
****C.P.L.R.: Cumulative Pollutant Loading Rate
DENR FORM FSF(12/2006)

ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (02T Rules)
Facility Name: City o#'Marion WQ Permit Number: WQ0019960
WWTP Name: Corpening Creek NPDES Number: NC0031879
Monitoring Period: From 1/1/2021 To 12/31/202I
Pathogen Reduction (15A NCAC 02T .1106) - Please indicate level achieved and alternative performed:
Class A: Alt. A (time/temp) Li Alt B (Alk Treatment)L] Alt. C (Prior Testing)❑
Alt.l) (No Prior Test) ❑ Process to Further Reduce Pathogengs ❑
If applicable to alternative performed (('hiss A only) indicate"Process to Further Reduce Pathogens":
Compost ❑ Heat Drying ❑ Heat Treatment ❑ Thermophilic ❑
Beta Ray ❑ Gamma Ray ❑ Pasteurization
Class B: Alt. (1) Fecal Density 0 All. (2) Process to Significantly Reduce Pathogens I]
If applicable to alternative performed (('lass B only) indicate"Process to Significantly Reduce Pathogens":
Lime Stabilization U Air Drying D 4 Composting J Aerobic Digestion ❑
Anaerobic Digestion 0 I
If applicable to alternative performed (Class A or Class B) complete the following monitoring data:
'Number of - AnalyticalAllowable Level Pathogen Density Frequency Sample
Parameter - Excee- fech-
in Sludge Minimum Geo. Mean Maximum Units deuces of Analysis Type nioue
2 x IO to the MPN
6th power
per gram of
Fecal Colifbrm total solids CFU
1444 rnpn per gram
of total solid (dry
weight)
Salmonella bacteria 3 MPN per 4 grams
(in lieu of fecal total solid(dry
coliform) weight)
Vector Attraction Reduction (15A NCAC 02T .1107) - Please indicate alternative performed:
Alt.I (VS reduction) I...] Alt. 2 (40-day bench) Li Alt. 3 (30-day bench) ❑ Alt. 4 (Spec. 02 uptake) it1
Alt. 5 (I4-Day Aerobic) J Alt. 6 (Alk. Stabilization Le Alt 7 (Drying- Stable) Li Alt. 8(Drying- Unstable)
Alt. 9(Injection) L.l Alt. 10(Incorporation) ❑ No vector attraction reduction alternatives were performed ❑
CERTIFICATION STATEMENT (please check the appropriate statement)
"I certify, under penalty of law, that the pathogen requirements in 1SA NCAC 02T .1106 and the
vector attraction reduction requirement in 15A NCAC 02T .1107 have been met,"
"I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T.1106 and the
vector attraction reduction requirement in 1SA NCAC 02'f .1107 have not been met." (Please note
if you check this statement attach an explanation why you have not met one or both of the
requirements.)
"This determination has been made under my direction and supervision in accordance with the system
designed to ensure that qualified personnel properly gather and evaluate the information used to determine
that the pathogen and vector attraction reduction requirements have been met. 1 am aware that there are
significant penalties for false certification including fine and imprisonment."
(/f1/] Dennis Key US Biosolids, Inc.
Preparer Name and Title (type or print) Land Applier Name and Title(if applicable)(type or print)
20 2Z___ 17/2.4.
Signature of Preparer* Date Signature of Land pplier(if applicable) Date
*Preparer is defined in 40 CFR Pan 503.9(r)and 15A NCAC 2T .1102 (26)
DENR FORM PVRF 02T (12/2006)

Pace Analytical Services,LLC
as 2225 Riverside Or
aceA!]alr ICI Asheville.NC 28804
www.pscslebs.care [phone]
ANALYTICAL RESULTS
Project' CC Digester
Pace Project No: 92585818
Sample: Dig 212122 Lab ID: 92585818001 Collected: 02/02122 13:50 Received: 02/02/22 15 44 Matrix: Solid
Results reported on a"city weight"basis and are adjusted for percent moisture,sample size and any dilutions.
Parameters Results Units Report Limit OF Prepared Analyzed CAS No Qua'
6010 MET ICP Analytical Method:EPA 60100 Preparation Method:EPA 3050B
Pace Analytical Services-Asheville
Aluminum 19100 mg/kg 439 1 02/03/22 09.34 02/08/22 00:57 7429-90-5
Arsenic ND mg/kg 110 1 02/03/22 09:34 02/08/22 00:57 7440-38-2
Cadmium ND mg/kg 4.4 1 02/03/22 09:34 02/08/22 00:57 7440-43-9
Calcium 43800 mg/kg 1100 1 02/03/22 09.34 02/08/22 00:57 7440-70-2
Copper 574 mg/kg 220 1 02/03/22 09:34 02/08/22 00 57 7440-50-8
Lead 59.3 mg/kg 43.9 1 02/03/22 09:34 02/08/22 00 57 7439-92-1
Magnesium 4630 mg/kg 439 1 02/03/22 09:34 02/08/22 00:57 7439-95-4
Molybdenum ND mg/kg 220 1 02103/22 09:34 02/08/22 00:57 7439-98-7
Nickel 22,8 mg/kg 22.0 1 02/03/22 09:34 02/08/22 00:57 7440-02-0
Potassium ND mg/kg 22000 1 02/03/22 09:34 02/08/22 00:57 7440-09-7
Selenium ND mg/kg 43.9 1 02/03/22 09:34 02/08/22 00:57 7782-49-2
Sodium ND mg/kg 22000 1 02/03/22 09:34 02/08122 00:57 7440-23-5
Zinc 1280 mg/kg 43.9 1 02/03122 09:34 02/08/22 00:57 7440-66-6
7471 Mercury Analytical Method:EPA 7471E Preparation Method:EPA 7471B
Pace Analytical Services-Asheville
Mercury 1.2 mg/kg 0.27 1 02/03/22 12:00 02/10/2211:37 7439-97-6
Percent Moisture Analytical Method:5W-846
Pace Analytical Services-Charlotte
Percent Moisture 97.9 '/0 0.10 1 02/03/22 15:17 N2
9045 pH Soil Analytical Method:EPA 90450
Pace Analytical Services-Asheville
pH at 25 Degrees C 6.0 Std. Units 0.10 1 02/03/22 16.25 H3
Plant Available Nitrogen Analytical Method.None
Pace Analytical Services-Asheville
Plant Available Nitrogen 9560 mg/kg 1 02/17/22 15:58 N2
351.2 Total Kjeldahl Nitrogen Analytical Method:EPA 351.2 Rev 2.0 1993 Preparation Method EPA 351.2 Rev 2.0 1993
Pace Analytical Services-Asheville
Nitrogen-Kjeldahl,Total 30400 mg/kg 2020 1 02/09/22 17 10 02/10/22 05:04 7727-37-9
365.1 Phosphorus,Total Analytical Method:EPA 365.1 Rev 2.0 1993 Preparation Method:EPA 365 1 Rev 2.0 1993
Pace Analytical Services-Asheville
Phosphorus 18400 mg/kg 423 10 02/03/22 18.26 02/03/22 23:30 7723-14-0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced.except in tuil,
Date:02/17/2022 05:41 PM without the written consent of Pace Analytical Services,LLC Page 5 of 25

Analytical Environmental Services, lnc Date: 16-Feb-22
Client: Pace Analytical Services.Inc. Client Sample ID: I)IG 2/2122
Project Name: 92585818 Collection Date: 2/2/2022 1:50:00 PM
Lab ID: 2202-198-001 'Matrix: Solid
--JRepurlinR Dilution -- -------.-...----
,Nnalvses Result Qual t nits l3atchtl) pateAnalyzed lna1►st
Limit Factor
Nitrogen,Nitrite(as N)Extractable E353.2 MOD (F.3S3.2 MOD)
Nitrogen.Nitrite(as N)Extractable l3Rl. 169 ntg:Kg-de 330309 1 02/09/2022 I I:53 AA
Nitrogen.Nitrate(as N)Ext. E353.2 MOD
Nitrogen.Nitrate(as N)Extractable 8970 K1;do It4771164 I 02/09/2022 00:00 AA
Nitrogen,Ammonia(as N)Extractable E350.1 MOD (E350.I I
Nitrogen.Ammonia(As N)Extractable 2220 343 330885 I 02/16/2022 08:38 I-I.
PERCENT MOISTURE D2216
Percent Moisture 97.2 0 xt'1°o IN76765 I 02/07/202200:00 ,IW
•
Qualifiers: • Vaiuc c,cceds maxaram coiiiamnram level F. Estimated i.alue aY ne,prantitavun ranee
RISL helms repotorig hmtl S Spike Reraserx nnaxiJe Intl/IS Jne n„macr�x
li !Inkling tires lift preparatwn :May:0e.e,eeetlt! Nan Sec case inn reins
N Aenlyte m4 NELAC cc,tartest F Anak vJ in the lsk,i,h,dt is a des,mint}noon the method
a Analyte detected to[he aenoepaled nretl,ot blonin Less than Result salve
• Greater than Result value I Estimated value detected 1,elou Reponathr Until Page 20 of 25

14/11/1
flY
ti - • PO Box 7565
0 Asheville,NC 28802
e Phone: [phone]
Fax: [phone]
— - �r. ./
EnvlronmentaI Testing Solutions,Inc. Certificate of Analysis
Project name: City of Marion Project number: 210215.507
Collection date: 15-Feb-21
Date received: 15-Feb-21
Sample identification: FS TCLP-Grab Sample number: 209872
Parameter Method Result RL Units Date Analyst Footnotes
Analyzed
Arsenic-TCLP 6010 D <0.25 0.25 mg/L s.t.i i MLR 1
Barium-TCLP 6010 D <2.50 2.50 mg/L 3.Mar-21 MLR 1
Cadmium-TCLP 6010 D <0.05 0.05 mg/L 3-Mar-21 MLR 1
Chromium-TCLP 6010 D <0.10 0.10 mg/L 3-Mar-21 MLR 1
Lead-TCLP 6010 D <0.25 0.25 mg/L 3-Mar-21 MLR 1
Selenium-TCLP 6010 D <0.25 0.25 mg/L 3-Mar-21 MLR 1
Silver-TCLP 6010 D <0.10 0.10 mg/L 3-Mar-21 MLR 1
Mercury-TCLP 7470A <0.0020 0.0020 mg/L 3-Feb-21 MLR 1
Full Scan TCLP Organics See attached sheets 1,2
Reactive Cyanide 335.4 1.70 0.05 mg/kg 22-Fcb-21 ECHEM 2
Reactive Sulfide SM 4500 S D 2.70 0.1 mg/kg 72-Fcb-21 ECHEM 2
Ignitability SW 846 1010 >190 190 °F 4.Mar-21 ECHEM 2
Footnotes:
RL—Reporting Limit. Values are reported down to the Reporting Limit only.
1. Sample analzyed by Rogers&Callcott Environmental.
2. Sample analyzed by Enviro Chemists,Inc.
Date reviewed: _ Q343 t NC Certification Number: 600
Data reviewed by: Kelley E.Keenan SC Certification Number: 99053
1 NC Drinking Water Certification Number: 37786
Signature: (
This report should not be reproduced,exept in its entirety,without the written consent of Environmental Testing Solutions,Inc.
The results in this report relate only to the samples submitted for analysis.

Rogers &Callcott
€ ,�___ ENVIRONMENTAL
i
Environmental Testing Solutions Project: Marion WWTP
351 Depot St. Work Order: 1020875
Asheville,NC 28801-4310 Reported: 03/23/21 09:49
r
Sample Data
Sample Number 1020875-01
Sample Description Marion WWTP Sludge-Grab collected on 02/15/21 07:40
Reporting
Parameter Result Limit Units OF Analyzed Method Flag Analyst Batch
TCLP Metals
Mercury ND 0.0020 mg/L 10.0 03/03/21 13:06 EPA 7470A MLR B1C0126
Arsenic ND 0.25 mg/L 5.00 03/03/21 04:43 EPA6010D MLR BIC0080
Barium ND 2.50 mg/l. 5.00 03/03/21 04:43 EPA6010D MLR BIC0080
Cadmium ND 0.05 mg/L 5.00 03/03/21 04:43 EPA 6010D MLR B tC0080
Chromium ND 0.10 mg/1- 5.00 03/03/21 04:43 EPA6010D MLR BIC0080
Lead ND 0.25 mg/I. 5.00 03/03/21 04:43 EPA6010D MLR BIC0080
Selenium ND 0.25 mg/L 5.00 03/03/21 04:43 EPA6010F) MLR BIC0080
Silver ND 0.10 mg/l- 5.00 03/03/21 04:43 EPA60101) MLR BIC0080
TCLP Volatile Organics
Benzene ND 0.100 mg/L 50.0 03/0 1/2 1 18:09 EPA 8260D AMF B 1C0582
2-Butanone(MEK) ND 0.200 mg/L 50.0 03/01/21 18:09 EPA 8260D AMF B IC0582
Carbon tetrachloride N13 0.100 mg/L 50.0 03/01/21 18:09 EPA 8260D AMF B1C0582
Chlarobeezene ND 0.100 mg/I. 50.0 03/01/21 18:09 EPA 82601) AMF B1C0582
Chloroform ND 0.100 malt 50.0 03/01/21 18:09 EPA 82601) AMF BIC0582
1,2-Dichloroethane ND 0.100 m8/1- 50.0 03/01/21 18:09 EPA 8260D AMF BIC0582
1,4-Dichlorobenzene ND 0.100 mg/I, 50.0 03/01/21 18:09 EPA8260D AMF B1C0582
1,I-Dichloroethene ND 0.100 mg/I. 50.0 03/01/21 18:09 EPA 8260D S AMF BICO582
Tetrachloroc1hene ND 0.100 mg/L 50.0 03/01/21 18:09 EPA82600 AMF BIC0582
Trichloroeihene ND 0.100 mg/L 50.0 03/01/21 18:09 EPA8260D AMF B1C0582
Vinyl chloride ND 0.100 mg/L 50.0 03/01/21 18:09 EPA 8260D AMF B 1C0582
Surrogates %REC %R£C Limns Flag
1,2-Dichioroerhane-D4 104 70-130
Totaene-D6 ill 70-130'
4-8mmoflvorobenzene 124 70.130
TCLP Semi-Volatile Organics
2-Methylphenol(o-Cresol) ND 0.100 m/L 10.0 03/09/21 15:00 EPA 8270E RJM BIC0071
3/4-Methyiphenol(ro,p-Cresal) ND 0.100 m€/l- 10.0 03/09/21 15:00 EPA 8270E RIM B I C0071
total Cresol ND 0.200 mg/L 10.0 03/09/21 15:00 EPA 8270E RJM B1C0071
2,4-Dinitrotoluenc ND 0-100 mgtt. 10.0 03/09/21 15:00 EPA 8270E RIM B1C0071
Hexachlorobenzene ND 0.100 mg/I. 10.0 03/09/21 15:00 EPA8270E RIM H100071
Hexeehlorobutadiene ND 0.100 mg/L 10.0 03/09/21 15:00 EPA8270E RIM 131C0071
Hexachloroethane ND 0.100 mg/L 10.0 03/09/21 I5:00 EPA 8270E RJM BIC0071
Nitrobenzene ND 0.100 mg/1- 10.0 03/09/21 15;00 EPA8270E RJM B1C0071
PO Box 5655 I Greenville,SC 23606 426 Fairforest Way ! Greenville,SC 29607 main 864.232.1556 . Fax B64.232.6140 rogersandcallcott-com
_.._._...._._____...__......---•------.. .._... .._..._._._--°---�---..___._.__..,_-_-_-•---_...-_.-._.--.--- an employee-owned company
03/23/2021 09:49 This nepor?may not be reproduced,except in fntl,without written permission from Rogers&CaRcott.Inc. Page 4 of 21

' ' .o !1-1,.: Rogers &Callcott
ENVIRONMENTAL
Environmental Testing Solutions Project: Marion WWTP
351 Depot St, Work Order: 1020875
Asheville,NC 28801-4310 Reported: 03/23/21 09:49
Sample Number 1020875-01
Sample Description Marion WWTP Sludge-Grab collected on 02/15/21 07:40
Reporting
Parameter Result Limit dolts DF Analyzed Method Flag Analyst Batch
TCLP Semi-Volatile Organics
Pentachloropheuol ND 0.200 mg/L 10.0 03/09/21 15:00 EPA8270E. RIM B1C0071
Pyridine ND 0.100 mg/L 10.0 03/09/21 15:00 EPA8270E UM BIC0071
2,4,5-Trichlorophenol ND 0.100 rng/L 10.0 03/09/21 15:00 EPA 8270E RJM 131C0071
2,4,6-Trichlorrop1icnol ND 0.100 mg/L 10.0 03/09/21 15:00 EPA8270E RIM BIC0071
Surrogates %REC %REC Molts Flag
Nitrobenzene-AS 69 15-314
2•Fluorabiphe yi 61 32-118
2-Flxarophenol 47 20-110
phenol-B5 35 8-424
2.4,6-Tribromophenol 75 39-130
Terphenyl-D14 85 26-173
TCLP Pesticides Z
Gamma-BHC(Lindane) ND 0.00050 mg/L 10.0 03/10/21 02:55 EPA808IB RICH BIC0171
Chlordane ND 0.0050 mg/1.. 10.0 03/10/21 02:55 EPA 808k B RKH 61C0171
Endrin ND 0.00050 mg/1. 10.0 03/10/21 02:55 EPA 808IB RICH B1C0171
Eleptachlor ND 0.00050 mg/L 10.0 03/10/21 02:55 EPA80RlB RICH BIC0171
Heptachlor epoxide ND 0,00050 mg/I 10.0 03/10/21 02:55 EPA80818 RKEE1 BIC0171
Toxaphene ND 0.0050 mg)L 10.0 03/10/21 02:55 EPA 8081E RICH 131C0171
Methoxychlor ND 0.00050 m8/L 10.0 03/10/21 02:55 EPA S081B RICH B1CO171
Surrogates %REC %REC Limits Flag
2.4.5,6-Tefrachlano-m-xy/ene 25 60-130 R
Decu h1orobipheny/ 23 30-I$0 R
PC Box 5655 Greenville,SC 29606 : 426 Fairforest Way • Greenville.SC 29607 roam 964.232.1556 + fax [phone] rogersandcalicott.com
-- __ ......—...___---�----......._.._-..-._.______ _ ._ ._..�_ _ ......_._._r_ anemployeeownedcompany
0311317021 04:44 This report may not be reproduced,except in full,without written permission from Rogers&Cason,Inc. Page 5 of 21

Environmental Chemists, Inc.
envirochem 6602 Windmill Way,Wilmington,NC 28405 • 910.392.0223 Lab • 910.392.4424 Fax
710 Bowsertown Road,Manteo,NC 27954 . 252.473.5702 Lab/Fax
255-A Wilmington Highway,Jacksonville,NC 28540 . 910.347.5843 Lab/Fax
ANALYTICAL&CONSULTING CHEMISTS info#environmentaichemists.com
Environmental Testing Solutions, Inc. Date of Report: Mar 04, 2021
Post Office Box 7565 Customer PO#:
Asheville NC 28802 Customer ID: 08100055
Attention: Kelley Keenan (ETS) Report#: 2021-02848
Project ID: Marion WWTP
Lab ID Sample ID: Collect Date/Time Matrix Sampled by
21-06871 Site:Sludge 002 2/15/2021 7:40 AM Solid/Sludge Client
Test Method Results Date Analyzed
2,4,5-TP(TCLP) 5W848 Method 8151A <0.003 mg/L 02/26/2021
2,4-D(TCLP) swa46 Method 6151A <0.003 mg/L 02/26/2021
RCI
Cyanide SM 4500 CN 0 1.70 mg/kg 02/22/2021
Sulfide Stu 4500 S Ez 2.70 mg/kg 02/22/2021
Ignitability SW 840 method 1010 >190°F 03/04/2021
Comment:
Reviewed by: KO LIA I1��
Report 4: 2021-02840 Page 1 of 1

LIME STABILIZATION
PROJECT: I1 ar: W 14 T I
LOCATION: PleS4f
r-
Date: ")— 15 ' a7o'J�
TIME: I ". 5 t
Gallons pH&Temp. at start Corrected pH Lime Added ph &Temp 2 Hours Corrected pH
` Pi 6 L .Si 17.1 •C 1 30,o00 r. la. 39 3aec l s �
ph&Temp 22 Hours Corrected pH
Signature:

Specific Oxygen Uptake Rate
SOUR
Facility Name: Corpenin?Creek
Biosolids Permit Number: WO 00'9960
Date: 10/8/2021
Digester Temperature: 23 degrees Celsius
Sampling Date/Time: 10/8/2'L 0813
Sampled By: TH
Analysis Date/Time: 10/8/2021 0845
4.
Analyzed By: TH
Sample Volume: 1000 milliliters
Total Solids: 0.73 % Dry Solids
Beginning Temperature: 25 degrees Celsius
End Temperature: 25 degrees Celsius
Time Dissolved Oxygen Level
(minutes) m•!t
0 7.63
1 7.58
2 7.54
3
4 7.4
5
6
7
8 7.34
9
10
11
12 111111111.110111.1111/12
13 7,18
14 7.14
15
Slope: 0 0
Intercept: 7 6
Correlation Coefficient: 1 0
Oxygen Uptake Rate: 2.02 mg Oxygen/hr
Ambient Specific Oxygen Uptake Rate: 0.28 mg Oxygen/g/hr
Average Temperature: 25 degrees Celsius
Temperature Correction Factor: 0.783526166
Temperature Corrected Specific Oxygen 1.ptake Rate: 0.22 mg Oxygen/g/hr
Instructions: Enter Data in the Blue Boxes. The Calculation and the Spreadsheet execute automatically.

Specific Oxygen U i ake Rate
SOUR
Facility Name: Corpenmg Cree f
Biosolids Permit Number: WQ 0019960
Date: 10/7/20-1
Digester Temperature: degrees Celsius
Sampling Date/Time: 10/7/2021 102 s
Sampled By: DM
Analysis Date/Time: 10/7/2e21 1031
Analyzed By: 'RGC
Sample Volume: 1010 milliliters
Total Solids: 1.•8 % Dry Solids
Beginning Temperature: •5 degrees Celsius
End Temperature: •5 degrees Celsius
Time Dissolved Oxygen Level
(minutes) muI
0 7.64
1 7.38
2 1111.111
3
4 7.06
5 111111011111.11.1110
6 6.94
7 6.87
8 6.81
9 6.74
10 6,68
11 6.6
12 6.54
13 6.46
14 6.37
15 6.28
Slope: +.1
Intercept 4
Correlation Coefficient: 1.0
Oxygen Uptake Rate: 4. 2 mg Oxygen/hr
Ambient Specific Oxygen Uptake Rate: 0. '3 mg Oxygen/g/hr
Average Temperature: '5 degrees Celsius
Temperature Correction Factor: 0.7835261'.6
Temperature Corrected Specific Oxygen Uptake Ra -: 0.18 mg Oxygen/g/hr
Instructions: Enter Data in the Blue Boxes. The Calculation nd the Spreadsheet execute automatically.

Specific Oxygen Uptake Rate
SOUR
Facility Name: Corpering Creek
Biosolids Permit Number: WO 0019960
Date: 10/12/2021
Digester Temperature: 25 degrees Celsius
Sampling Date[Time: 10/12/21 0759
Sampled By: ADM
Analysis DateiTime: 10/12/21 0941
Analyzed By: RGC
Sample Volume: i040 milliliters
Total Solids: 1.9 % Dry Solids
Beginning Temperature: 25 degrees Celsius
End Temperature: 25 degrees Celsius
Time Dissolved Oxygen Level
(minutes) m,Il
0 8.1
1 7.99
2 7.88
3 111111
4
5
6 7.19
7 6.98
8 6.85
9 6.67
10 6.48
11 6.31
12 6.16
13 5.97
14 5.82
15 5.65
Slope: 0,2
Intercept: 8_2
Correlation Coefficient: 1.0
Oxygen Uptake Rate: 10.'0 mg Oxygen/hr
Ambient Specific Oxygen Uptake Rate: 0.53 mg Oxygen/g/hr
Average Temperature: 25 degrees Celsius
Temperature Correction Factor: 0.783526166
Temperature Corrected Specific Oxygen Uptake Rabe; 0.42 mg Oxygenigihr
Instructions: Enter Data in the Blue Boxes. The Calculation and the Spreadsheet execute automatically.

Specific a xygen U• ake Rate
SOUR
Facility Name: Con - sp[ - p
Biosolids Permit Number: WQ 0019960
Date: 1111.10/13/20.a
Digester Temperature: IMIIIIMMIN degrees Celsius
Sampling Date/Time: 10/13/'1 0640
Sampled By: glimmili
Analysis Date/Time: 10/13/.1 0800
Analyzed By: RGC
Sample Volume: 10 IC milliliters
Total Solids: 11.111111111180 % Dry Solids
Beginning Temperature: degrees Celsius
End Temperature: miminsag degrees Celsius
Time Dissolved Oxygen Level
(minutes) (m t/1
0 7.75
1 7.35
2
3 6.97
4 6.78
5 6.57
6 6.39
7 6.22
8 5.99
9 5.78
10 5.62
11 5.39
12
13 11.1111111111111111111111.113
14 4.79
15 4,6
Slope: 0 2
Intercept: 7 6
Correlation Coefficient: 1 0
Oxygen Uptake Rate: 12.15 mg Oxygen/hr
Ambient Specific Oxygen Uptake Rate: 0.:3 mg Oxygen/g/hr
Average Temperature: 5 degrees Celsius
Temperature Correction Factor: $.7835261;6
Temperature Corrected Specific Oxygen ptake Ra -: 0.50 mg Oxygen/g/hr
Instructions: Enter Date in the Blue Boxes. The C.Iculation -nd the Spreadsheet execute automatically.

Specific •xygen Up ake Rate
SOUR
Facility Name: Cor.enEEM1
Biosolids Permit Number: WQ 00 9960 I
Date: _10/14/201
Digester Temperature: degrees Celsius
Sampling Date/Time: 10/14/.1 1018
Sampled By: DM -!
Analysis Date/Time: 10/14/.1 1150
Analyzed By: RGC _l
Sample Volume: gm 101E milliliters
Total Solids: I % Dry Solids
Beginning Temperature: _imEgi degrees Celsius
End Temperature: _gip degrees Celsius
Time Dissolved Oxygen Level
(minutes) m!/I
0 7.72
1 7.53
2
3 7.29
4 •
5 7.04
6 6.9
7 6.77
8 6.62
9 6.49
10 6.36
11 6.21
12 6.08
13 5.94
14 5.8
15 5.66
Slope: 0 1
Intercept: 7 7
Correlation Coefficient: 1 0
Oxygen Uptake Rate: 8. 0 mg Oxygen/hr
Ambient Specific Oxygen Uptake Rate: 0.•5 mg Oxygen/g/hr
Average Temperature: •5 degrees Celsius
Temperature Correction Factor: 0 7835261;6
Temperature Corrected Specific Oxygen ptake Rat•: 0.35 mg Oxygen/g/hr
Instructions: Enter Data in the Blue Boxes. The C-Iculation .nd the Spreadsheet execute automatically.

Specific Oxygen Uptake Rate
SOUR
Facility Name: Corpening Creek
Biosolids Permit Number: WC)OC 19960
Date: 10/15/2021
Digester Temperature: 27 degrees Celsius
tki
Sampling Date/Time: 10/15/21 0615
Sampled By: DM
Analysis Date/Time: 10/15/21 0930
Analyzed By: RGC
Sample Volume: 1000 milliliters
Total Solids: 1 t3 % Dry Solids
Beginning Temperature: 25 degrees Celsius
End Temperature: 25 degrees Celsius
Time Dissolved Oxygen Level
(minutes) m!11
0 11111113
1
2 7.01
3 6.91
4 6.8
5 6.7
6 6.61
7 6,51
8 6.41
9 6.28
10 6.16
11 6.06
12 5.95
13 5.84
14
15 5.62
Slope: 0.1
Intercept: 7,2
Correlation Coefficient. 1 0
Oxygen Uptake Rate: 6.:1.,5 mg Oxygen/hr
Ambient Specific Oxygen Uptake Rate: 0.25 mg Oxygen/g/hr
Average Temperature: 25 degrees Celsius
Temperature Correction Factor 0 783526166
Temperature Corrected Specific Oxygen Uptake Rate:) 0.28Jmg Oxygen/g/hr
Instructions: Enter Data in the Blue Boxes. The Calculation and the Spreadsheet execute automatically.

Specific Oxygen Uptake Rate
SOUR
Facility Name: 6orpeiling Creek
Biosolids Permit Number: WQ 0019960
Date: 10/18/2021
Digester Temperature: 5< 3210- G
Sampling Date/Time: 10/18/21 12(3
Sampled By: dm
Analysis Date/Time: 10/18/21 133'/
Analyzed By: ssg
Sample Volume: 1000 milliliters
Total Solids: 1.7 %Dry Solids
Beginning Temperature: ti5 degrees Celsius
End Temperature: 25 degrees Celsius
Time Dissolved Oxygen Level
(minutes) (mall)
0 7.89
1 7.85
2 7.8
3 7.76
4 7.71
5 7.66
6 7.61
7 7,54
8 7.5
9 7.43
10 7.37
11 5.3;
12 724
13 7.19
14 7.13
15 7.08
Slope: QE 1
Intercept: 7.9
Correlation Coefficient: 1.0
Oxygen Uptake Rate: 3.33 mg Oxygen/hr
Ambient Specific Oxygen Uptake Rate: 0.20 mg Oxygen/glhr
Average Temperature: 25 degrees Celsius
Temperature Correction Factor: 0.783526166
Temperature Corrected Specific Oxygen Uptake Rabe: 0.1 mg Oxygenlg/hr
Instructions: Enter Data in the Blue Boxes. The Calculation and the Spreadsheet execute automatically.

NCDA&CS Agronomic Division Phone: [phone] Website: www.ncagr.gov/agrortomi/ Report No. FY22-SL015863
// .�r1-2-11:`�„ Client: John Fisher Advisor: Zach Key
_j, F'. Predictive 400 Dairy Rd. Southern Soil Builders
INtt
i i'l ,ry,; ,- Maggie Valley, NC 28751 958 Hoots Rd
, �< OS�� Soil Report Mehlich-3 Extraction Roaring River,NC 28669
Sampled County:McDowell
11'" Links to Helpful Information
Client ID: 478472 Advisor ID: 231531
Sampled: 11/08/2021 Received: 11/15/2021 Completed: 12/13/2021 Farm:
Sample ID: Fl Recommendations: Lime Nutrients(Ib/acre) More
Crop (tons/acre) N P20s K20 Mg S Mn Zn Cu B Information
Lime History: 1 -Fescue/OGrass/Tim,M 0.0 120-200 0 70 0 0 0 0 0 0 Note: 12
2- 0.0
Test Results[units-WN in gfcnr3;CEC and Na in meg1100 crn3;NO3-N in mg/dm3j: Soil Class: Mineral
HM% WN CEC BS% Ac pH P-I K-I Ca% Mg% S-I Mn-1 Mn-All Mn-Al2 Zn4 Zn-Al Cu-I Na ESP SS-I NOs-N
0.32 0.95- 8.9 85 1.3 6.1 142 32 63 21 38 145 103 235 235 300 0.1 1
-.. .w.�
Sample ID: F2 Recommendations: Lime Nutrients(iblacre) More
Crop (tons/acre) N P205 K20 Mg S Mn Zn Cu B Information
Lime History: 1 -Fescue/OGrass/Tim, M 0.0 120-200 0 90 0 0 0 0 0 0 Note: 12
2- 0.0
Test Results[units-WN in glcm3;CEC and Na in meg/100 cm3;NO3-N in mgldn73]: Soil Class: Mineral
HM% WN CEC BS% Ac pH P-I K-I Ca% Mg% S-t Mn-I Mn-All Mn-Al2 Zn-I Zn-Al Cu-I Na ESP SS-I NO3-N
1 0.36 0.97 8.8 86 1.2 6.2 134 26 64 20 38 180 123 198 198 331 0.1 1
I
North Carolina
Reprogramming of the laboratory-information-management system that makes this report possible is being funded
through a grant from the North Carolina Tobacco Trust Fund Commission.
lip
Thank you for using agronomic services to manage nutrients and safeguard environmental quality.
- Steve Troxler. Commissioner ofAciriculture

•
NCDA&CS Agronomic Division Phone: [phone] Website: www.ncagr.govlagronomil Report No. FY22-SL015863
John Fisher Page 2 of 3
Sample ID: F3 Recommendations: Lime Nutrients(Iblacre) More
Crop (tonslacre) N P2O5 Kz0 Mg S Mn Zn Cu B Information
Lime History: 1 -FescuelOGrass/Tim, M 0.0 120-200 0 40 0 0 0 0 0 0 Note: 12
2- 0.0
Test Results[units-WN in glcrr CEC and Na in meg1100 cm3;NO3-N in mg/dm3]: Soil Class: Mineral
HM% WN CEC BS% Ac pH P-I K-I Ca% Mg% S-1 Mn-1 Mn-All Mn-Al2 Zn-I Zn-Al Cu-I Na ESP SS-I NO3-N
0.36 0.93 9.8 91 0.9 6.4 184 48 69 20 45 225 147 265 265 323 0.1 1
Sample ID: F4 Recommendations: Lime Nutrients(lb/acre) More
Crop (tons/acre) N P2O5 K2O Mg S Mn Zn Cu B information
Lime History: 1 -Fescue/OGrasslTim,M 0.0 120-200 0 10 0 0 0 0 0 0 Note: 12
2- 0.0
Test Results[units-WN in glcm3;CEC and Na in meg1100 cm3;NO3-N in mg/dm): Soil Class: Mineral
HM% WN CEC BS% Ac pH P-I K-I Ca% Mg% S-I Mn-1 Mn-All Mn-Al2 Zn-1 Zn-Al Cu-I Na ESP SS-1 NO3-N
0.60 0.99 9.8 89 1.1 6.2 219 75 66 19 47 209 139 303 303 317 0.1 1

NCDA&CS Agronomic Division Phone: {919)733-2655 Website: www.ncagr.govlagronomil Report No. FY22-SL015863
John Fisher Page 3 of 3
Understanding the Soil Report:explanation of measurements,abbreviations and units
Recommendations Report Abbreviations
Limp_ Ac exchangeable acidity
If testing finds that soil pH is too low for the crop(s)indicated, a lime recommendation will be given in units of either B boron
ton/acre or lb/1000 sq ft. For best results, mix the lime into the top 6 to 8 inches of soil several months before planting. BS% %CEC occupied by basic cations
For no-till or established plantings where this is not possible,apply no more than 1 to 1.5 ton/acre (50 lb/1000 sq ft)at one Ca% %CEC occupied by calcium
time,even if the report recommends more.You can apply the rest in similar increments every six months until the full rate CEC cation exchange capacity
is applied. If MG is recommended and lime is needed,use dolomitric lime. Cu-I copper index
ESP exchangeable sodium percent
Fertilizer HM% percent humic matter
Recommendations for field crops or other large areas are listed separately for each nutrient to be added (in units of K-I potassium index
lb/acre unless otherwise specified). Recommendations for N (and sometimes for B)are based on research/field studies K20 potash
for the crop being grown, not on soil test results. K-I and P-I values are based on test results and should be>50. If they Mg% %CEC occupied by magnesium
are not, follow the fertilizer recommendations given. If Mg is needed and no lime is recommended, 0-0-22(11.5% Mg)is MIN mineral soil class
an excellent source; 175 to 250 lb per acre alone or in a fertilizer blend will usually satisfy crop needs, SS-I levels appear Mn manganese
Mn-Ali Mn-availability index for crop 1
only on reports for greenhouse soil or problem samples. Mn-Al2 Mn-availability index for crop 2
Mn-i manganese index
Farmers and other commercial producers should pay special attention to micronutrient levels. if$,pH$, $pH, C or Z M-O mineral-organic sail class
notations appear on the soil report, refer to $Note:Secondary Nutrients and Micronutrients In general, homeowners do not N nitrogen
need to be concerned about micronutrients.Various crop notes also address lime fertilizer needs; visit Na sodium
ncagr.govlagronomi/pubs.htm. NO3-N nitrate nitrogen
ORG organic soil class
Recommendations for small areas,such as home lawns/gardens,are listed in units of lb/1000 sq ft . If you cannot find pH current soil pH
the exact fertilizer grade recommended on the report, visit www.ncacircioviaqronoini/obpart4.htrntWind information that P-I phosphorus index
may help you choose a comparable alternate. For more information, read A Homeowner's Guide to Fertilizer. P2O5 phosphate
S-I sulfur index
Test Results SS-I soluble salt index
WN weight per volume
The first seven values[soil class, HM%, WN, CEC, BS%,Ac and pH]describe the soil and its degree of acidity.The Zn-AI zinc availability index
Zn-1 zinc index
remaining 16 [P-I, K-I,Ca%, Mg%, Mn-I, Mn-All, Mn-Al2,Zn-I,Zn-Al, Cu-I, S-1, SS-I, Na, ESP, SS-I, NO3-N(not routinely
www.ncagr.qov/agror�omi/uyrst.htm
available)] indicate levels of plant nutrients or other fertility measurement.Visit

,
NCDA&CS Agronomic Division Phone: [phone] Website: www.ncagr.govlagronomil Report No. FY22-SL015866
�11 1 y
// Client: Brian Kay Advisor: Zach Key
/ ,,_:w., Predictive 980 Ari s Lane
_.;.: Y Southern Soil Builders
I .: ,f«,k1rl l{ Tryon, NC 28782 958 Hoots Rd
'"` Soil Report
{ f',Ek«' MehliCl1-3 Extraction Roaring River,NC 28669
Sampled County McDowell Links to Helpful tnformatior;
Client ID: 504558 Advisor ID: 231531
Sampled: 11/08/2021 Received: 11/15/2021 Completed: 12/13/2021` Farm:
Sample ID: R1 Recommendations: Lime Nutrients(lb/acre) More
Crop (tonslacre) N P2Os K20 Mg S Mn Zn Cu B Information
Lime History: I -Fescue/OGrassfTim,M 0.6 120-200 0 70 0 0 0 0 0 0 Note: 12
2- 0.0
Test Results junits-WN in glcrtts;CEC and Na in meq/100 cm3;NO3-N in mgldm3]: Soil Class: Mineral
HM% WN CEC BS% Ac pH P-I K-I Ca% Mg% S-I Mn-I Mn-All Mn-Al2 Zn-I Zn-Al Cu-I Na ESP 55-I NO3-N
0.46 0.96 8.6 78 1.8 5.7 147 35 60 17 42 89 70 248 248 220 0.1 1 —
•
Sample ID: R2 Recommendations: Lime Nutrients(lb/acre) More
Crop (tonslacre) N P20s K20 Mg S Mn Zn Cu B Information
Lime History: 1 -Fescue/OGrassfTim,M 0.8 120-200 70 90 0 0 0 0 0 0 Note: 12
2- 0.0
Test Results[units-WN in gIcm3;CEC and Na in megf100 cm3;NO3-N in rngldttr31: Soil Class: Mineral
HM% WN CEC BS% Ac pH P-I K-I Ca% Mg% S-I Mn-I Mn-All Mn-AI2 Zn-I Zn-Al Cu-1 Na ESP SS-I NO3-N
1 0.71 0.96 6.7 71 1.9 5.6 27 26 52 17 50 181 126 60 60 63 0.1 1
North Carolina Reprogramming of the laboratory-information-management system that makes this report possible is being funded
through a grant from the North Carolina Tobacco Trust Fund Commission.
l Thank you for using agronomic services to manage nutrients and safeguard environmental quality.
- Steve Troxler. Commissioner of Agriculture

1 NCDA&CS Agronomic Division Phone: [phone] Website: www.ncagr.govlagronomif Report No. FY22-5L015856
Brian Kay
Page 2 of 2
Understanding the Soil Report:explanation of measurements,abbreviations and units
Recommendations Report Abbreviations
Lime Ac exchangeable acidity
If testing finds that soil pH is too low for the crop(s)indicated,a lime recommendation will be given in units of either B boron
ton/acre or lb/10O0 sq ft. For best results, mix the lime into the top 6 to 8 inches of soil several months before planting. BS% %CEC occupied by basic cations
For no-till or established plantings where this is not possible, apply no more than 1 to 1.5 ton/acre(50 lb/1000 sq ft)at on: Ca% %CEC occupied by calcium
time,even if the report recommends more.You can apply the rest in similar increments every six months until the full rate CEC cation exchange capacity
is applied. If MG is recommended and lime is needed,use dolomitric lime. Cu-I copper index
ESP exchangeable sodium percent
Fertilizer HM% percent humic matter
Recommendations for field crops or other large areas are listed separately for each nutrient to be added(in units of K-1 potassium index
lb/acre unless otherwise specified). Recommendations for N(and sometimes for B)are based on research/field studies K20 potash
for the crop being grown, not on soil test results.K-I and P-I values are based on test results and should be> 50. If they Mg% %CEC occupied by magnesium
are not, follow the fertilizer recommendations given. If Mg is needed and no lime is recommended, 0-0-22(11.5% Mg)is MIN mineral soil class
an excellent source; 175 to 250 lb per acre alone or in a fertilizer blend will usually satisfy crop needs, SS-I levels appear Mn manganese
only on reports for greenhouse soil or problem samples. Mn-Alt Mn availability index for crop 1
Mn-Al2 Mn-availability index for crop 2
Mn-1 manganese index
Farmers and other commercial producers should pay special attention to micronutrient levels. If$,pH$, $pH. C or Z M-0 mineral-organic soil class
notations appear on the soil report, refer to $Note_Secondary Nutrients and Micronutrients In general, homeowners do not N nitrogen
need to be concerned about rnicronutrients.Various crop notes also address lime fertilizer needs; visit Na sodium
ncagr.govlagronomi/pubs.htm. NO3-N nitrate nitrogen
ORG organic soil class
Recommendations for small areas, such as home lawns/gardens, are listed in units of Ib/1000 sq ft . If you cannot find pH current soil pH
the exact fertilizer grade recommended on the report, visit www.ncactroov/acironomi/oboart4.17tmittlind information that P-I phosphorus index
may help you choose a comparable alternate. For more information, read A Homeowner's Guide to Fertilizer. P2O5 phosphate
S-I sulfur index
Test Results SS-I soluble salt index
WN weight per volume
0 Zn-Al zinc availability index
The first seven values[soil class, HM/o,WN, CEC, BSo/o,Ac and pH]describe the soil and its degree of acidity.The Zn-I zinc index
remaining 16[P-I. K-I,Ca%, Mg%, Mn-I, Mn-All, Mn-At2, Zn-I,Zn-Al, Cu-I, S-I, SS-I, Na, ESP,SS-I, NO3-N (not routinely
available)]indicate levels of plant nutrients or other fertility measurement.Visit + s^'.ncagr.gpv/agronomi/uyrst.htm

#=CL#
May 18, 2022
LIMS USE: FR - TIM HORTON
LIMS OBJECT ID: 92585818
92585818
Project:
Pace Project No.:
RE:
Mr. Tim Horton
City of Marion
3982 NC Hwy 226 South
Marion, NC 28752
CC Digestor
Dear Mr. Horton:
Enclosed are the analytical results for sample(s) received by the laboratory on February 02, 2022. The results relate only
to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
Some analyses were subcontracted outside of the Pace Network. The test report from the external subcontractor is
attached to this report in its entirety.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace Analytical Services - Asheville
• Pace Analytical Services - Charlotte
Revised Report - Report revised to report results down to MDL
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Chris Derouen for
[e-mail]
Project Manager
Lorri Patton
1(828)254-7176
Enclosures
cc:Mr. Zach Key, Southern Soil Builders
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 1 of 25
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92585818
CC Digestor
Pace Analytical Services Charlotte
South Carolina Laboratory ID: 99006
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Laboratory ID: 99006
South Carolina Certification #: 99006001
South Carolina Drinking Water Cert. #: 99006003
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Louisiana DoH Drinking Water #: LA029
Virginia/VELAP Certification #: 460221
Pace Analytical Services Asheville
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
South Carolina Laboratory ID: 99030
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 2 of 25
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92585818
CC Digestor
Lab ID Sample ID Matrix Date Collected Date Received
92585818001 Dig 2/2/22 Solid 02/02/22 13:50 02/02/22 15:44
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 3 of 25
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92585818
CC Digestor
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92585818001 Dig 2/2/22 EPA 6010D 13 PASI-ARDT
EPA 7471B 1 PASI-ADBB1
SW-846 1 PASI-CKDF
EPA 9045D 1 PASI-AYEG
None 1 PASI-ADMN
EPA 351.2 Rev 2.0 1993 1 PASI-AMFO
EPA 365.1 Rev 2.0 1993 1 PASI-AMDW
PASI-A = Pace Analytical Services - Asheville
PASI-C = Pace Analytical Services - Charlotte
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 4 of 25
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92585818
CC Digestor
Sample:Dig 2/2/22 Lab ID:92585818001 Collected:02/02/22 13:50 Received:02/02/22 15:44 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010D Preparation Method: EPA 3050B
Pace Analytical Services - Asheville
6010 MET ICP
Aluminum 19100 mg/kg 02/08/22 00:57 7429-90-502/03/22 09:344392201
Arsenic ND mg/kg 02/08/22 00:57 7440-38-202/03/22 09:3411022.0 1
Cadmium 2.8J mg/kg 02/08/22 00:57 7440-43-902/03/22 09:344.4 2.2 1
Calcium 43800 mg/kg 02/08/22 00:57 7440-70-202/03/22 09:3411002201
Copper 574 mg/kg 02/08/22 00:57 7440-50-802/03/22 09:3422011.0 1
Lead 59.3 mg/kg 02/08/22 00:57 7439-92-102/03/22 09:3443.9 11.0 1
Magnesium 4630 mg/kg 02/08/22 00:57 7439-95-402/03/22 09:3443911.0 1
Molybdenum 93.3J mg/kg 02/08/22 00:57 7439-98-702/03/22 09:3422011.0 1
Nickel 22.8 mg/kg 02/08/22 00:57 7440-02-002/03/22 09:3422.0 11.0 1
Potassium ND mg/kg 02/08/22 00:57 7440-09-702/03/22 09:3422000220001
Selenium ND mg/kg 02/08/22 00:57 7782-49-202/03/22 09:3443.9 22.0 1
Sodium ND mg/kg 02/08/22 00:57 7440-23-502/03/22 09:3422000110001
Zinc 1280 mg/kg 02/08/22 00:57 7440-66-602/03/22 09:3443.9 22.0 1
Analytical Method: EPA 7471B Preparation Method: EPA 7471B
Pace Analytical Services - Asheville
7471 Mercury
Mercury 1.2 mg/kg 02/10/22 11:37 7439-97-602/03/22 12:000.27 0.21 1
Analytical Method: SW-846
Pace Analytical Services - Charlotte
Percent Moisture
Percent Moisture 97.9 %02/03/22 15:17 N20.10 0.10 1
Analytical Method: EPA 9045D
Pace Analytical Services - Asheville
9045 pH Soil
pH at 25 Degrees C 6.0 Std. Units 02/03/22 16:25 H30.10 0.10 1
Analytical Method: None
Pace Analytical Services - Asheville
Plant Available Nitrogen
Plant Available Nitrogen 9560 mg/kg 02/17/22 15:58 N21
Analytical Method: EPA 351.2 Rev 2.0 1993 Preparation Method: EPA 351.2 Rev 2.0 1993
Pace Analytical Services - Asheville
351.2 Total Kjeldahl Nitrogen
Nitrogen, Kjeldahl, Total 30400 mg/kg 02/10/22 05:04 7727-37-902/09/22 17:10202010101
Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation Method: EPA 365.1 Rev 2.0 1993
Pace Analytical Services - Asheville
365.1 Phosphorus, Total
Phosphorus 18400 mg/kg 02/03/22 23:30 7723-14-002/03/22 18:2642321210
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 05/18/2022 01:46 PM
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2225 Riverside Dr.
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[phone]
Page 5 of 25
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92585818
CC Digestor
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
675796
EPA 7471B
EPA 7471B
7471 Mercury
Laboratory:Pace Analytical Services - Asheville
Associated Lab Samples:92585818001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3536872
Associated Lab Samples:92585818001
Matrix:Solid
AnalyzedMDL
Mercury mg/kg ND 0.0036 02/09/22 11:350.0028
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3536873LABORATORY CONTROL SAMPLE:
LCSSpike
Mercury mg/kg 0.0520.05 104 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
3536874MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92585614001
3536875
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Mercury mg/kg M1,R10.092 107 75-125146 27 200.0920.017 0.12 0.15
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 05/18/2022 01:46 PM
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2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 6 of 25
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92585818
CC Digestor
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
675735
EPA 3050B
EPA 6010D
6010 MET
Laboratory:Pace Analytical Services - Asheville
Associated Lab Samples:92585818001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3536671
Associated Lab Samples:92585818001
Matrix:Solid
AnalyzedMDL
Aluminum mg/kg ND 10.0 02/07/22 23:565.0
Arsenic mg/kg ND 2.5 02/07/22 23:560.50
Cadmium mg/kg ND 0.10 02/07/22 23:560.050
Calcium mg/kg ND 25.0 02/07/22 23:565.0
Copper mg/kg ND 5.0 02/07/22 23:560.25
Lead mg/kg ND 1.0 02/07/22 23:560.25
Magnesium mg/kg ND 10.0 02/07/22 23:560.25
Molybdenum mg/kg ND 5.0 02/07/22 23:560.25
Nickel mg/kg ND 0.50 02/07/22 23:560.25
Potassium mg/kg ND 500 02/07/22 23:56500
Selenium mg/kg ND 1.0 02/07/22 23:560.50
Sodium mg/kg ND 500 02/07/22 23:56250
Zinc mg/kg ND 1.0 02/08/22 17:490.50
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3536672LABORATORY CONTROL SAMPLE:
LCSSpike
Aluminum mg/kg 498500 100 80-120
Arsenic mg/kg 48.350 97 80-120
Cadmium mg/kg 48.350 97 80-120
Calcium mg/kg 482500 96 80-120
Copper mg/kg 50.650 101 80-120
Lead mg/kg 48.950 98 80-120
Magnesium mg/kg 470500 94 80-120
Molybdenum mg/kg 52.350 105 80-120
Nickel mg/kg 48.350 97 80-120
Potassium mg/kg 520500 104 80-120
Selenium mg/kg 43.850 88 80-120
Sodium mg/kg 510500 102 80-120
Zinc mg/kg 48.250 96 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
3536673MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92585617001
3536674
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Aluminum mg/kg M1697186075-1252050 3 206712610026800
Arsenic mg/kg M169.7 75 75-12574 5 2067.1ND 52.4 49.8
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 05/18/2022 01:46 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 7 of 25
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92585818
CC Digestor
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
3536673MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92585617001
3536674
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Cadmium mg/kg 69.7 86 75-12587 3 2067.1ND 60.2 58.4
Calcium mg/kg 697 88 75-12597 5 20671750789
Copper mg/kg 69.7 96 75-12590 6 2067.1 108 102
Lead mg/kg 69.7 75 75-12581 3 2067.114.3 66.4 68.4
Magnesium mg/kg 697 102 75-125106 0 2067113601350
Molybdenum mg/kg 69.7 81 75-12580 5 2067.1 56.8 54.2
Nickel mg/kg M169.7 43 75-12542 3 2067.1 74.3 72.4
Potassium mg/kg 697 103 75-125104 2 20671884866
Selenium mg/kg M169.7 73 75-12572 5 2067.1ND 50.8 48.4
Sodium mg/kg 697 99 75-12599 4 20671716688
Zinc mg/kg M169.7 64 75-12569 2 2067.1 87.4 89.6
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 05/18/2022 01:46 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 8 of 25
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92585818
CC Digestor
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
675905
SW-846
SW-846
Dry Weight/Percent Moisture
Laboratory:Pace Analytical Services - Charlotte
Associated Lab Samples:92585818001
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92585406004
3537770SAMPLE DUPLICATE:
Percent Moisture %20.7 N2102522.9
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92585885005
3537771SAMPLE DUPLICATE:
Percent Moisture %18.0 N212518.2
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 05/18/2022 01:46 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 9 of 25
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92585818
CC Digestor
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
675769
EPA 9045D
EPA 9045D
9045 pH
Laboratory:Pace Analytical Services - Asheville
Associated Lab Samples:92585818001
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92584854001
3536777SAMPLE DUPLICATE:
pH at 25 Degrees C Std. Units 7.3 H31107.3
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92585631001
3536778SAMPLE DUPLICATE:
pH at 25 Degrees C Std. Units 8.2 H31108.1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 05/18/2022 01:46 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 10 of 25
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92585818
CC Digestor
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
677073
EPA 351.2 Rev 2.0 1993
EPA 351.2 Rev 2.0 1993
351.2 TKN
Laboratory:Pace Analytical Services - Asheville
Associated Lab Samples:92585818001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3543491
Associated Lab Samples:92585818001
Matrix:Solid
AnalyzedMDL
Nitrogen, Kjeldahl, Total mg/kg ND 50.0 02/10/22 04:5625.0
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3543492LABORATORY CONTROL SAMPLE:
LCSSpike
Nitrogen, Kjeldahl, Total mg/kg 9761000 98 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
3543493MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92585631001
3543494
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Nitrogen, Kjeldahl, Total mg/kg M138102590-11038 2 104190306003150032200
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 05/18/2022 01:46 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 11 of 25
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92585818
CC Digestor
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
675907
EPA 365.1 Rev 2.0 1993
EPA 365.1 Rev 2.0 1993
365.1 Phosphorus, Total
Laboratory:Pace Analytical Services - Asheville
Associated Lab Samples:92585818001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3537786
Associated Lab Samples:92585818001
Matrix:Solid
AnalyzedMDL
Phosphorus mg/kg ND 0.93 02/03/22 22:330.46
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3537787LABORATORY CONTROL SAMPLE:
LCSSpike
Phosphorus mg/kg 49.147.2 104 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
3537788MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92584099001
3537789
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Phosphorus mg/kg M146.3 -14 90-11086 10 1045.5463 457 502
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
3537790MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92584849001
3537791
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Phosphorus mg/kg M154.2 -1080 90-110-488 3 1051.210200 9660 9990
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 05/18/2022 01:46 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 12 of 25
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92585818
CC Digestor
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as
"Total" may vary slightly from the sum of the reported component parameters.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
ANALYTE QUALIFIERS
Sample was received or analysis requested beyond the recognized method holding time.H3
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
The lab does not hold NELAC/TNI accreditation for this parameter but other accreditations/certifications may apply. A
complete list of accreditations/certifications is available upon request.N2
RPD value was outside control limits.R1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 05/18/2022 01:46 PM
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2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 13 of 25
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92585818
CC Digestor
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92585818001 675735 675775Dig 2/2/22 EPA 3050B EPA 6010D
92585818001 675796 675849Dig 2/2/22 EPA 7471B EPA 7471B
92585818001 675905Dig 2/2/22 SW-846
92585818001 675769Dig 2/2/22 EPA 9045D
92585818001 679160Dig 2/2/22 None
92585818001 677073 677249Dig 2/2/22 EPA 351.2 Rev 2.0 1993 EPA 351.2 Rev 2.0 1993
92585818001 675907 675970Dig 2/2/22 EPA 365.1 Rev 2.0 1993 EPA 365.1 Rev 2.0 1993
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 05/18/2022 01:46 PM
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2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 14 of 25
Page 15 of 25
Page 16 of 25
February 16, 2022
Dear Order No:
RE:
Analytical Environmental Services, Inc. received samples on
for the analyses presented in following report.
1
“No problems were encountered during the analyses except as noted in the Case Narrative or by qualifiers in
the report or QC Summary. Additionally, all results for the associated Quality Control samples were within
EPA and/or AES established limits.
AES’ certifications are as follows:
-NELAP/Florida State Laboratory ID E87582 for analysis of Non-Potable Water, Solid & Chemical Materials,
Air & Emissions for Organics, and Drinking Water Microbiology & Metals, effective 07/01/21-06/30/22.
-North Carolina Certification number 562 for analysis of Surface Water, Groundwater, Effluent, effective until
12/31/22.
-South Carolina Environmental Laboratory Certification number 98016003 effective until 6/30/22.
These results relate only to the items tested as received. This report may only be reproduced in full and with
written permission from the laboratory.
If you have any questions regarding these test results, please feel free to call.
Sincerely,
Project Manager
2202498
Lorri Patton
Pace Analytical Services, Inc.
2225 Riverside Dr
Asheville NC 28804
92585818
Paris Masoudi
February 3, 2022 9:52 am
Lorri Patton:
Page 1 of 9
Page 17 of 25
Page 2 of 9
Page 18 of 25
Page 3 of 9
Page 19 of 25
2202498-001
16-Feb-22Date:Analytical Environmental Services, Inc
Analyses Date Analyzed
Dilution
FactorBatchIDUnitsQualReporting
LimitResult
Client:
Solid
2/2/2022 1:50:00 PM
DIG 2/2/22
Matrix:
Collection Date:
Client Sample ID:
92585818
Pace Analytical Services, Inc.
Lab ID:
Project Name:
Analyst
(E353.2 MOD)Nitrogen, Nitrite (as N) Extractable E353.2 MOD
Nitrogen, Nitrite (as N) Extractable BRL 169
mg/Kg-dry 330309 1 02/09/2022 11:53 AA
Nitrogen, Nitrate (as N) Ext. E353.2 MOD
Nitrogen, Nitrate (as N) Extractable 8970 5.00
mg/Kg-dry R477064 1 02/09/2022 00:00 AA
(E350.1)Nitrogen, Ammonia (as N) Extractable E350.1 MOD
Nitrogen, Ammonia (As N) Extractable 2220 344
mg/Kg-dry 330885 1 02/16/2022 08:38 TL
PERCENT MOISTURE D2216
Percent Moisture 97.2 0
wt%R476765 1 02/07/2022 00:00 JW
Qualifiers: * Value exceeds maximum contaminant level
BRL Below reporting limit
H Holding times for preparation or analysis exceeded
N Analyte not NELAC certified
B Analyte detected in the associated method blank
E Estimated (value above quantitation range)
S Spike Recovery outside limits due to matrix
Narr See case narrative
F Analyzed in the lab which is a deviation from the method
< Less than Result value
> Greater than Result value J Estimated value detected below Reporting Limit
Page 4 of 9
Page 20 of 25
SAMPLE/COOLERRECEIPTCHECKLIST1. ClientName:AESWorkOrderNumber:2.Carrier:FedExUPSUSPSClientCourierOtherYes No N/A DetailsComments3.Shippingcontainer/coolerreceivedingoodcondition?damagedleakingother4.Custodysealspresentonshippingcontainer?5.Custodysealsintactonshippingcontainer?6.Temperatureblankspresent?7.Coolertemperature(s)withinlimitsof0Ͳ6϶C?[Seeitem13 and 14fortemperature recordings.]Coolinginitiatedforrecentlycollectedsamples/icepresent8.ChainofCustody(COC)present?9.ChainofCustodysigned,dated,andtimedwhenrelinquishedandreceived?10.Samplernameand/orsignatureonCOC?11.Wereallsamplesreceivedwithinholdingtime?12.TATmarkedontheCOC?IfnoTATindicated,proceededwithstandardTATperTerms&Conditions.13.Cooler1Temperature϶CCooler2Temperature϶CCooler3Temperature϶CCooler4Temperature϶CCooler5Temperature϶CCooler6Temperature϶CCooler7Temperature϶CCooler8Temperature϶C15.Comments:IcertifythatIhavecompletedsections1Ͳ1ϱ(datedinitials).Yes No N/A DetailsComments16.Weresamplecontainersintactuponreceipt?17.Custodysealspresentonsamplecontainers?18.Custodysealsintactonsamplecontainers?19. DosamplecontainerlabelsmatchtheCOC?incompleteinfoillegiblenolabelother20.AreanalysesrequestedindicatedontheCOC?21. WereallofthesampleslistedontheCOCreceived?samplesreceivedbutnotlistedonCOCsampleslistedonCOCnotreceived22.Wasthesamplecollectiondate/timenoted?23.Didwereceivesufficientsamplevolumeforindicatedanalyses?24.Weresamplesreceivedinappropriatecontainers?25.WereVOAsamplesreceivedwithoutheadspace(<1/4"bubble)?26.Weretripblankssubmitted?listedonCOCnotlistedonCOC27.Comments:IcertifythatIhavecompletedsections1ϲͲ27(datedinitials).Yes No N/ADetailsComments28.Havecontainersneedingchemicalpreservationbeenchecked? *29.Containersmeetpreservationguidelines?30.WaspHadjusted at Sample Receipt?IcertifythatIhavecompletedsections28Ͳ30(datedinitials).ClearSave asPace Analytical Services, Inc.2202498■3.814.CW 2/4/22This section only applies to samples where pH can be checked at Sample Receipt.CW 2/4/22* Note: Certain analyses require chemical preservation but must be checked in the laboratory and not upon Sample Receipt such as Coliforms, VOCs and Oil & Grease/TPH.This also excludes metals by EPA 200.7, 200.8 and 245.1 which will be verified between 16 and 24 hours after preservation.CW 2/4/22LockedChecklist 7.9.20 Rev 3Page 5 of 9Page 21 of 25
16-Feb-22Date:Analytical Environmental Services, Inc
Client:
Dates Report
Lab Order:
Project Name:
Lab Sample ID Client Sample ID Test NameCollection Date Matrix TCLP Date Prep Date Analysis Date
2202498
92585818
Pace Analytical Services, Inc.
2202498-001A DIG 2/2/22 2/2/2022 1:50:00PM Solid Nitrogen, Ammonia (as N) Extractable 2/14/2022 6:00:00PM 02/16/2022
2202498-001A DIG 2/2/22 2/2/2022 1:50:00PM Solid Nitrogen, Nitrite (as N) Extractable 2/9/2022 7:36:38AM 02/09/2022
2202498-001A DIG 2/2/22 2/2/2022 1:50:00PM Solid Nitrogen, Nitrate-Nitrite (as N) Extractable 2/9/2022 7:36:38AM 02/09/2022
2202498-001A DIG 2/2/22 2/2/2022 1:50:00PM Solid Nitrogen, Nitrate (as N) Extractable 02/09/2022
2202498-001A DIG 2/2/22 2/2/2022 1:50:00PM Solid PERCENT MOISTURE 02/07/2022
Page 6 of 9
Page 22 of 25
16-Feb-22Date:Analytical Environmental Services, Inc
Client:
BatchID:Workorder:
Project Name:
ANALYTICAL QC SUMMARY REPORT92585818
2202498
Pace Analytical Services, Inc.
330309
RPT Limit QualAnalyte Result SPK value SPK Ref Val %REC Low Limit High Limit RPD Ref Val %RPD RPD Limit
SampleType: BatchID: Analysis Date: Seq No:TestCode:330309MBLK 02/09/2022
Nitrogen, Nitrite (as N) Extractable E353.2 MOD
Units: Prep Date:Sample ID: Client ID: Run No:mg/Kg 02/09/2022 477065MB-330309
11016142
Nitrogen, Nitrite (as N) Extractable 5.00BRL
RPT Limit QualAnalyte Result SPK value SPK Ref Val %REC Low Limit High Limit RPD Ref Val %RPD RPD Limit
SampleType: BatchID: Analysis Date: Seq No:TestCode:330309LCS 02/09/2022
Nitrogen, Nitrite (as N) Extractable E353.2 MOD
Units: Prep Date:Sample ID: Client ID: Run No:mg/Kg 02/09/2022 477065LCS-330309
11016143
Nitrogen, Nitrite (as N) Extractable 5.0050.10 50.00 100 90 110
RPT Limit QualAnalyte Result SPK value SPK Ref Val %REC Low Limit High Limit RPD Ref Val %RPD RPD Limit
SampleType: BatchID: Analysis Date: Seq No:TestCode:330309MS 02/09/2022
Nitrogen, Nitrite (as N) Extractable E353.2 MOD
Units: Prep Date:Sample ID: Client ID: Run No:mg/Kg-dry 02/09/2022 4770652202323-001AMS
11016145
Nitrogen, Nitrite (as N) Extractable 4714762 4715 101 90 110
RPT Limit QualAnalyte Result SPK value SPK Ref Val %REC Low Limit High Limit RPD Ref Val %RPD RPD Limit
SampleType: BatchID: Analysis Date: Seq No:TestCode:330309MSD 02/09/2022
Nitrogen, Nitrite (as N) Extractable E353.2 MOD
Units: Prep Date:Sample ID: Client ID: Run No:mg/Kg-dry 02/09/2022 4770652202323-001AMSD
11016146
Nitrogen, Nitrite (as N) Extractable 4714611 304715 97.8 90 110 4762 3.22
Qualifiers:
J Estimated value detected below Reporting Limit
BRL Below reporting limit H Holding times for preparation or analysis exceeded
N Analyte not NELAC certified
B Analyte detected in the associated method blank
E Estimated (value above quantitation range)
S Spike Recovery outside limits due to matrix
< Less than Result value> Greater than Result value
R RPD outside limits due to matrix
Rpt Lim Reporting Limit
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16-Feb-22Date:Analytical Environmental Services, Inc
Client:
BatchID:Workorder:
Project Name:ANALYTICAL QC SUMMARY REPORT92585818
2202498
Pace Analytical Services, Inc.
330885
RPT Limit QualAnalyte Result SPK value SPK Ref Val %REC Low Limit High Limit RPD Ref Val %RPD RPD Limit
SampleType: BatchID: Analysis Date: Seq No:TestCode:330885MBLK 02/16/2022
Nitrogen, Ammonia (as N) Extractable E350.1 MOD
Units: Prep Date:Sample ID: Client ID: Run No:mg/Kg 02/14/2022 477633MB-330885
11032430
Nitrogen, Ammonia (As N) Extractable 10.0BRL
RPT Limit QualAnalyte Result SPK value SPK Ref Val %REC Low Limit High Limit RPD Ref Val %RPD RPD Limit
SampleType: BatchID: Analysis Date: Seq No:TestCode:330885LCS 02/16/2022
Nitrogen, Ammonia (as N) Extractable E350.1 MOD
Units: Prep Date:Sample ID: Client ID: Run No:mg/Kg 02/14/2022 477633LCS-330885
11032431
Nitrogen, Ammonia (As N) Extractable 10.0101.2 100.0 101 90 110
RPT Limit QualAnalyte Result SPK value SPK Ref Val %REC Low Limit High Limit RPD Ref Val %RPD RPD Limit
SampleType: BatchID: Analysis Date: Seq No:TestCode:330885MS 02/16/2022
Nitrogen, Ammonia (as N) Extractable E350.1 MOD
DIG 2/2/22 Units: Prep Date:Sample ID: Client ID: Run No:mg/Kg-dry 02/14/2022 4776332202498-001AMS
11032433
Nitrogen, Ammonia (As N) Extractable 3545203 3540 2216 84.4 90 110 S
RPT Limit QualAnalyte Result SPK value SPK Ref Val %REC Low Limit High Limit RPD Ref Val %RPD RPD Limit
SampleType: BatchID: Analysis Date: Seq No:TestCode:330885MSD 02/16/2022
Nitrogen, Ammonia (as N) Extractable E350.1 MOD
DIG 2/2/22 Units: Prep Date:Sample ID: Client ID: Run No:mg/Kg-dry 02/14/2022 4776332202498-001AMSD
11032434
Nitrogen, Ammonia (As N) Extractable 3505064 18.23504 2216 81.3 90 110 5203 S2.71
Qualifiers:
J Estimated value detected below Reporting Limit
BRL Below reporting limit H Holding times for preparation or analysis exceeded
N Analyte not NELAC certified
B Analyte detected in the associated method blank
E Estimated (value above quantitation range)
S Spike Recovery outside limits due to matrix
< Less than Result value> Greater than Result value
R RPD outside limits due to matrix
Rpt Lim Reporting Limit
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End of Report
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