WQ0008778_Residual Annual Report 2021_20220217

Non-Discharge Branch Upload/Submittal Form �.
NORTH CAROLINA
EnWrvnmenfol Quoity
Version 2-Revised June 23,2020
Initial Review
Reviewer Thornburg,Nathaniel D
Is this submittal an application?(Excluding additional information.)*
Yes No
If not an application what is the submittal type?* Annual Report
Residual Annual Report
Additional Information
Other
Annual Report Year* 2021
Permit Number(IR)* WQ0008778
Applicant/Permittee Town of Farmville
Email Notifications
Does this need review by the hydrogeologist?* Yes No
Regional Office Washington
CO Reviewer
Admin Reviewer

Submittal Form
Project Contact Information
Please provide information on the person to be contacted by NDB Staff regarding electronic submittal,confirmation of receipt,and other correspondence.
............................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................
Name* Lysa Finnerty
Email Address* Phone Number*
[e-mail] 14105376150
Project Information
Application/Document Type* New(Fee Required) Modification-Minor
Modification-Major(Fee Required) Renewal
Renewal with Major Modification(Fee GW-59, NDMR,NDMLR, NDAR-1,
Required) NDAR-2
Annual Report Residual Annual Report
Additional Information Change of Ownership
Other
We no longer accept these monitoring reports through this portal. Please click on the link below and it will take you to the correct form.
https://edocs.deg.nc.gov/Forms/NonDischarge_Monitoring_Report
Permit Type:* Wastewater Irrigation High-Rate Infiltration
Other Wastewater Reclaimed Water
Closed-Loop Recycle Residuals
Single-Family Residence Wastewater Other
Irrigation
Permit Number:* WQ0008778
Has Current Existing permit number
Applicant/Permittee Address* 435 Williams Court,Ste 100,Baltimore,MD 21220
Facility Name* Town of Farmville Class B Residuals Program
Please provide comments/notes on your current submittal below.
2021 Annual Report for Town of Farmville,NC
At this time,paper copies are no longer required.If you have any questions about what is required,please contact Nathaniel Thornburg
at [e-mail].
Please attach all information required or requested for this submittal to be reviewed here.*
(Application Form,Engineering Plans,Specifications,Calculations,Etc.)
Farmville NC 2021 Annual Report FINAL.pdf 5.87MB
Upload only 1 PDF document(less than 250 MB).Multiple documents must be combined into one PDF file unless file is larger
than upload limit.
* By checking this box, I acknowledge that I understand the application will not be
accepted for pre-review until the fee(if required)has been received by the Non-
Discharge Branch.Application fees must be submitted by check or money order and
made payable to the North Carolina Department of Environmental Quality(NCDEQ).
I also confirm that the uploaded document is a single PDF with all parts of the
application in correct order(as specified by the application).
Mail payment to:
NCDEQ—Division of Water Resources
Attn:Non-Discharge Branch
1617 Mail Service Center
Raleigh,NC 27699-1617
Signature Lp
Ja TM/WO
Submission Date 2/17/2022

435 Williams Court,Suite 100
Baltimore,MD 21220 SYNAG R
www.synagro.com
FEBRUARY 17,2022
NCDEQ
Division of Water Resources
Information Processing Unit
1617 Mail Service Center
Raleigh, NC 27699-1617
Re: 2021 Annual Report for Permit No. WQ0008778
Dear NCDEQ:
Synagro is submitting one electronic copy of the above referenced report on behalf of the Town
of Farmville, NC.
If you have any questions or need additional information, please do not hesitate to contact
David Hodgkins at [phone] or Chris Wynne at [phone].
Sincerely,
Devddi Sfiium 25
Derrick Shivar
Environmental Compliance Manager
Enclosures
cc: David Hodgkins
Chris Wynne, Synagro
YOUR PARTNER FORA CLEANER,GREENER WORLD

TOWN OF FARMVILLE, NC
RESIDUALS LAND APPLICATION PROGRAM
Permit No. WQ0008778
2021 ANNUAL REPORT

Town of Farmville, NC
Residuals Land Application Program
2021 Annual Report
TABLE OF CONTENTS
1. Certification Form and Annual Operations Summary
2. Annual Residual Sampling Summary Forms and Residuals
Analyses
3. Annual Land Application Field Summary Forms
4. TCLP Analysis
5. Pathogen ReductionNector Attraction Reduction
6. Soil pH & Lime Application Records
7. Soil Analyses

SECTION 1

•
ANNUAL LAND APPLICATION CERTIFICATION FORM
WQ Permit#: WQ0008778 County Pitt Year 2021
Facility Name(as shown on permit)Farmville WWTP NPDES No.NC0029572
Land Application Operator Synagro Phone [phone]
Land application of residuals as allowed by the above permit occurred during the past calendar year?
X YES NO. If NO,skip Part A,and Part B and proceed to Part C. Also,if residuals were generated but not land applied,
please attach an explanation on how the residuals were handled.
Part A—Residuals Application Summary:
Total number of application fields in the permit: 7
Total number of fields utilized for land application during the year: 3
Total amount of dry tons applied during the year for all application sites: 93.22
Total number of acres utilized for land application during the year: 45.60
Part B—Annual Compliance Statement:
Facility was compliant during calendar year 2021 with all conditions of the land application permit(including but not limited to items
1-13 below)issued by the Division of Water Quality X YES NO.
If no,please provide a written description why the facility was not compliant,the dates,and explain corrective action taken.
1. Only residuals approved for this permit were applied to the permitted sites.
2. Soil pH was adjusted as specified in the permit and lime was applied(if needed)to achieve a soil pH of at least 6.0 or the
limit specified in the permit.
3. Annual soils analysis was performed on each site receiving residuals during the past calendar year and three(3)copies of
laboratory results are attached.
4. Annual TCLP analysis(if required)was performed and three(3)copies of certified laboratory results are attached.
5. All other monitoring was performed in accordance with the permit and reported during the year as required and three(3)
copies of certified laboratory results are attached.
6. The facility did not exceed any of the Pollutant Concentration Limits in 15A NCAC 02T.1105(a)or the Pollutant Loading
Rates in 15A NCAC 02T.1105(b)(Applicable to 40 CFR Part 503 regulated facilities).
7. All general requirements as specified in the Land Application Permit were complied with(applicable to 40 CFR Part 503 yy
regulated facilities).
8. All monitoring and reporting requirements in 15A NCAC 02T.1111 were complied with(applicable to 40 CFR Part 503
regulated facilities).
9. All operations and maintenance requirements in the permit were complied with or,in the case of a deviation,prior
authorization was received from the Division of Water Quality.
10. No contravention of Ground Water Quality Standards occurred at a monitoring well or explanations of violations are
attached to include appropriate actions and remediations,
11. Vegetative cover was maintained and proper crop management was performed on each site receiving residuals,as specified
in the permit.
12. No runoff of residuals from the application sites onto adjacent property or nearby surface waters has occurred.
13. All buffer requirements as specified on the permit were maintained during each application of residuals.
Part C—Certification:
"I certify,under penalty of law,that the above information is,to the best of my knowledge and belief,true,accurate,and complete. I
am aware that there are significant penalties for submitting false information,including the possibility of fines and imprisonment for
knowing violations."
jg �
David P.Hodgkins,Town Manager 2/9/2022
Permittee Name and Title(type or print) Signature of Per.,itt / Date
2/9/2022
Signature of Preparer* Date Sign i re of Land plies Date
(if different from Permittee) (if different from Permittee and Preparer)
*Prepares is defined in 40 CFR Part 503.9(r)and 15A NCAC 02T.1102(26) DENR FORM ACF(12/2006)
'I'

OPERATIONS SUMMARY-LAND APPLICATION - NORTH CAROLINA
ALL COUNTIES -ALL SITES
DATE RANGE: 1/1/2021 - 12/31/2021
FARMVILLE,NC
FARMVILLE,NC AEROBICALLY DIGESTED LIQUID
MONTH/YEAR AMOUNT UNIT DRY TONS UNIT DRY METRIC TONS
May 2021 341,000.00 G 50.76 D 46.04
December 2021 285,200.00 G 42.46 D 38.51
TOTAL 626,200.00 G 93.22 D 84.55
Units Key: D-Dry Tons; G—Gallons;W—Wet Tons;Y—Cubic Yards
Report Date:2/2/2022 8:30:30 AM

SECTION 2

ANNUAL RESIDUAL SAMPLING SUMMARY FORM
Please note that your permit may contain additional parameters to be analyzed.The parameters can be reported in FORM RSSF-B
WQ Permit Number: W00008778 Laboratory:
Facility Name: FARMVILLE,NC PACE ANALYTICAL
Residual Source WQ#or
NPDES#: NC0029572
WWTP Name: FARMVILLE
Residual Analysis Data
Product Type AEDLIQ
Sample or Composite Date 01/07/21
Parameter(mg/kg dry weight) Ceiling Conc.
Limit
Percent Solids(%) NA 3.57
Arsenic 75 6.1
Cadmium 85 0.73
Copper 4300 310
Chromium NA 33
Lead 840 30
Mercury 57 <0.51
Molybdenum 75 5.9
Nickel 420 23
Selenium 100 7.1
Zinc 7500 760
Total Phosphorus NA 14000
TKN NA 45000
Ammonia-Nitrogen NA <15
Nitrate and Nitrite NA 210
For surface disposal facilities the ceiling concentration limits listed in this form are not applicable.Reference the individual permit for metals limits.
"I certify,under penalty of law,that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified
personnel properly gathered and evaluated the information submitted.I am aware that there are significant penalties for submitting false information,including the
possibility of fines and impris ment for knowing violations."
jj id(1 .
2.1 FIZZ-
Signature of Preparer* " Date
'Preparer is defined in 40 CFR Part 503.9(r)and 15 A NCAC 2T.1102(26) DENR FORM RSSF(12/2006)
Printed:1/27/2022 4:53:27 PM For:2015 01

ANNUAL RESIDUAL SAMPLING SUMMARY FORM -B
Report all sampling analysis results for parameters not listed in FORM RSSF that are part of the WQ permit or were analyzed for over the past
calendar year.Use additional forms as needed.
WQ Permit Number: WQ0008778 Laboratory:
Facility Name: FARMVILLE,NC PACE ANALYTICAL
Residual Source
NPDES#or WQ#: NC0029572
WWTP Name: FARMVILLE
Residual Analysis Data
Product Type AEDLIQ
Sample or Composite Date 01/07/21
Parameters(mg/kg dry weight)
Aluminium 12000
Calcium 8300
Magnesium 2700
pH(s.u.) 5.70
Potassium 3600
Sodium 1300
PAN 13713
SAR(Ratio) 0.5970
"I certify,under penalty of law,that this document was prepared under my direction or supervision in accordiance with a system designed to assure that qualified
personnel properly gathered and evaluated the information submitted.I am aware that there are significant penalties for submitting false information,including the
possibility of fines,ando imprisonment for knowing violations."
AlL- P-e416-1 2
Signature of Preparer* Date
*Preparer is defined in 40 CFR Part 503.9(r)and 15 A NCAC 2T.1102(26)
Printed:1/27/2022 4:51:58 PM For:2015 01 DENR FORM RSSF-B(12/2006)

0
Pace Analytical
Report of Analysis
Synagro
12701 Lancaster Hwy
Pineville, NC 28134
Attention: Chris Wynne
Project Name: Farmville VWVTP
Lot Number:WA08031
Date Completed:01/26/2021
01/26/2021 11:59 AM
Approved and released by:
Project Manager II: Lucas Odom
MILB
Q PCCR�c��
'ye I ANSI NatonalAccredltatlon Board
ACCREDITEDeORA16,
TESTING LABORATORY
The electronic signature above is the equivalent of a handwritten signature.
This report shall not be reproduced, except in its entirety, without the written approval of Pace Analytical Services, LLC.
Pace Analytical Services, LLC(formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172
Tel: [phone] Fax: [phone] www.pacelabs.com
Page 1 of 7

PACE ANALYTICAL SERVICES, LLC
SC DHEC No:32010001 NELAC No: E87653 NC DENR No:329 NC Field Parameters No:5639
Case Narrative
Synagro
Lot Number: WA08031
This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary
following this Case Narrative. The sample receiving date is documented in the header information
associated with each sample.
All results listed in this report relate only to the samples that are contained within this report.
Sample receipt, sample analysis, and data review have been performed in accordance with the most
current approved The NELAC Institute (TNI) standards, the Pace Analytical Services, LLC ("Pace")
Laboratory Quality Manual, standard operating procedures (SOPs), and Pace policies. Any exceptions to
the TNI standards, the Laboratory Quality Manual, SOPs or policies are qualified on the results page or
discussed below.
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
qualifier
If you have any questions regarding this report please contact the Pace Project Manager listed on the
cover page.
The pH analysis associated with the sample(s) in this report was/were performed after the method
recommended 15 minute holding time.
Metals by ICP
Due to low% solids the initial amount of these samples was 3 times the standard procedure amount per
PM's request. The LOQ has been adjusted accordingly.
TKN
Samples run at decreased volume due to sample matrix.
Pace Analytical Services,LLC(formerly ShealyEnvironmetal Services,Inc.)
106 Vantage Point Drive West Columbia,SC 29172(803)791-9700 Fax[phone] www.pacelabs.com
Page 2of7

Client:Synagro Laboratory ID:WA08031-001
Description:Farmville WWTP Matrix:Solid
Date Sampled:01/07/2021 1230 % Solids: 3.57 01/09/2021 0052
Date Received:01/08/2021
Inorganic non-metals
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 (% Solids)SM 2540G 1 01/09/2021 0052 AAB 78939
1 350.1 (Ammonia-N )350.1 1 01/13/2021 1306 CAG2 79167
1 (Nitrate-N )9056A 1 01/13/2021 1402 AMR 79439
1 (Nitrite-N )9056A 1 01/13/2021 1402 AMR 79441
3 (Phosphorus)365.1 25 01/22/2021 1055 DMA 01/20/2021 1747 80124
1 (Soil pH meas)9045D 1 01/08/2021 2321 AAB 78951
1 351.4 (TKN)351.2 1 01/19/2021 1236 DMA 01/16/2021 1242 79666
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
% Solids SM 2540G 3.57 % 1
Ammonia-N (gas diffusion) 350.1 ND 28 15 mg/kg 1
Nitrate-N (soluble) 9056A 210 14 2.8 mg/kg 1
Nitrite-N (soluble) 9056A ND 5.6 2.8 mg/kg 1
Phosphorus 7723-14-0 365.1 14000 3500 700 mg/kg 3
Soil pH measured in water @ 18.1 ° C 9045D 5.7 su 1
TKN 351.2 45000 700 700 mg/kg 1
CVAA
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 7471B 7471B 1 01/13/2021 1502 JAB2 01/13/2021 0455 79069
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Mercury 7439-97-6 7471B ND 2.1 0.51 mg/kg 1
ICP-AES
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 3050B 6010D 1 01/13/2021 1319 KSH2 01/12/2021 0520 78979
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Aluminum 7429-90-5 6010D 12000 180 69 mg/kg 1
Arsenic 7440-38-2 6010D 6.1 J 6.9 2.3 mg/kg 1
Cadmium 7440-43-9 6010D 0.73 J 2.3 0.58 mg/kg 1
Calcium 7440-70-2 6010D 8300 2300 290 mg/kg 1
Chromium 7440-47-3 6010D 33 4.6 1.1 mg/kg 1
Copper 7440-50-8 6010D 310 4.6 2.1 mg/kg 1
Iron 7439-89-6 6010D 24000 46 21 mg/kg 1
Lead 7439-92-1 6010D 30 4.6 2.1 mg/kg 1
Magnesium 7439-95-4 6010D 2700 2300 290 mg/kg 1
Manganese 7439-96-5 6010D 340 6.9 2.7 mg/kg 1
Molybdenum 7439-98-7 6010D 5.9 J 18 4.6 mg/kg 1
Nickel 7440-02-0 6010D 23 18 4.8 mg/kg 1
LOQ=Limit of Quantitation B=Detected in the method blank E=Quantitation of compound exceeded the calibration range DL=Detection Limit
ND=Not detected at or above the DL N=Recovery is out of criteria P=The RPD between two GC columns exceeds 40% J=Estimated result<LOQ and>DL
H=Out of holding time W=Reported on wet weight basis
Pace Analytical Services,LLC (formerly Shealy Environmental Services,Inc.)
106 Vantage Point Drive West Columbia,SC 29172 [phone] Fax[phone] www.pacelabs.com
Page 3of7

Client:Synagro Laboratory ID:WA08031-001
Description:Farmville WWTP Matrix:Solid
Date Sampled:01/07/2021 1230 % Solids: 3.57 01/09/2021 0052
Date Received:01/08/2021
ICP-AES
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 3050B 6010D 1 01/13/2021 1319 KSH2 01/12/2021 0520 78979
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Potassium 7440-09-7 6010D 3600 2300 290 mg/kg 1
Selenium 7782-49-2 6010D 7.1 J 9.1 3.7 mg/kg 1
Sodium 7440-23-5 6010D 1300 J 2300 290 mg/kg 1
Zinc 7440-66-6 6010D 760 23 5.7 mg/kg 1
LOQ=Limit of Quantitation B=Detected in the method blank E=Quantitation of compound exceeded the calibration range DL=Detection Limit
ND=Not detected at or above the DL N=Recovery is out of criteria P=The RPD between two GC columns exceeds 40% J=Estimated result<LOQ and>DL
H=Out of holding time W=Reported on wet weight basis
Pace Analytical Services,LLC (formerly Shealy Environmental Services,Inc.)
106 Vantage Point Drive West Columbia,SC 29172 [phone] Fax[phone] www.pacelabs.com
Page 4of7

Chain of Custody
and
Miscellaneous Documents
Pace Analytical Services,LLC (formerly Shealy Environmental Services,Inc.)
106 Vantage Point Drive West Columbia,SC 29172 [phone] Fax[phone] www.pacelabs.com
Page 5 of 7

Shealy EnVirofrrierital SeiviceS, Inc_
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PACE ANALYTICAL SERVICES, LLC
Samples Receipt checklist(SRC){MEonlAt-15) Rt issd:9i29/7t i1
/CZrlra3rtiet't1 Issuing Authority,PRre ENV-WCOL Page 1 of 1
•
Sam& Receipt Checklist (SRC) ,
Client SVna.'F:' P KS: OL+tbl' 42I _ Lot . 'ADI L — —
Cooler ins eked Jdate_
'Means Cd.)1.irL:_[3U t_'licnt UP Pedhx Other: ..z
RYes — A No, 1.'Mew'Mewc ASl. se.a1s present on the cooler? =
Yrs No El2.If custcd•seals were ent,weirintact and unbroken?
liH Strip ID: xr• Chiming:Ship LT] ruk Ted by:ria�uta]teroperalur upon receipt f Derived(CAuyedcted)temperature upon receipt %Solid Snap-Cup la 13475
2,6 (2.6 uc. PA r NA - NA ihfA off., NA /NA "C
Method:Erezinperature Blank phgaiast Bottles IR Cun ID: 5 IR C;r_n Correction Foetal': 4 °C'
Method of coolant: .❑em s e 0 Tr, Packs D Dry Ice ❑ 3\Tooe
. 3- if temperature of any cooler excc,�dorl€t°C,was i'roj:ct Manaecr Notifled?
BS ❑A a [�lw]A Pm was Notified by: phone!ein ii l f f -to-race(circlo one).
ID Yes ❑No NA 4, Is trio eoim ie cial entiHef's packing slip�rrtached to this form?
▪Yes ❑j No1 Yes U No . Were proper custody procedures(reGnquishcs]iroceived)followed?
6. Were sample'Ds listed on the COC? —
1.
L Yar N 7- e c sample Ms Listed an all 55ri?l, can[ainers`�
❑1.7 'e ND i , W callc:otiuii dit tiros I1,Led on the COC?
li:YES LNo ..19. Was collection date&time iisted ern all sarnrle containers?
RYe9 ©No ID.Did all Cont3ainer label informatticn(ID,date,time)agree with fie COC?
Yes n No 11.Were tests to bG put formed livid on Ll:e COC°
12 Did all samples arrive in the groper containers for each test.ail Dor in good ea lid iLiort
[1 Yes ❑Na (unbroken.,lids on,00.)? _
Yes 1- I No 13, Was adequate!.-.ample volume availabllu'f
Jj i' UNu Id-Were all samples received Within , -the holding time or 46 how, ,wliidievcr Comes first'
ElYesi /INo 15.Were any saiop]es oonteiaers rnlssin oxecss(circle one;samples Not listcx[Do.CDC? _j
'b, For VOA and 1tSIC-175 sainpes,were l,ubbl p:g :`-p eneea•sin '('(i,br 6n11n in dizuncler)
❑ cs [�Na: n1 A m any of the VOA YIt11S°
Ye4 .1'co ®NA 17, Were all DRO1me4a] iii jrrient samples motel ved at a pH of<2°
Yes 'Li No ONA 18.Vdcro all cyanide sampkcs received at apE> 12 and suifde=]e3 rci ive1 at a pH -94
•19,Were ell applicable NHvTI t'1 cvam iphena! .,1;6D8 { n'.g .)samples Free of
©Yes ❑Niel D
N. residual chlorine?I20.Were client rexnarksirequcs1.s(i.e-requested(lilntinns,MS MSD eesignacions,etc...)
Ygs ❑ #
No Q cc,rroctly transanibcd from the COC into he comment fieztian in LIMS? _
In Yr..s� 1/INo .21. 1'as the quatl.number listed on the Ls]:ILainc:1oLbe]?If yes,Quoto fr
Sample Preservation (Must be completed for any sa--nplsr(s)i:Lcon ct#y gre•Nerved a.with IteadWaee.)
amflle(s) " were rctieived incorrectly?re erwed and were adjusted atc4rdmgly
in sample receiving will! NA _LnT.of'circle one 1-12S0 ,H1M1103,HQ-,NaCH using SR tf 'IA
rime of presemiion WA If more tliar,one pmservative is needed,please polo in die rattrnnnIA below.
Sample(s) NA __ _were rccoived with bubble45>6 mm.n daurneter.
SSarnpL# $) 1%A were received with TRC>0.5 ingot(lf#19 is no)and w rc
adjuster]accLI'd insly in sample receiving-,s'ila'sodium Ihiosu]fate()NI a�S2O�)with Shealy JD tag
SR harm& labels upplied bey: f date:
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Pace Analytical Services,LLC (formerly Shealy Environmental Services,Inc.)
106 Vantage Point Drive West Columbia,SC 29172 [phone] Fax[phone] www.pacelabs.com
Page 7 of 7

SECTION 3

ANNUAL LAND APPLICATION FIELD SUMMARY FORM Page: 1
FACILITY NAME:FARMVILLE,NC WQ PERMIT#:WQ0008778 FIELD#:NC-PI-00001-0-0003- ACRES UTILIZED:6.5
LAND OWNER:HAROLD FLANAGAN ANNUAL DRY TONS APPLIED:21.23 SITE#:NC PI 00001 ACRES PERMITTED:6.5
OPERATOR:HAROLD FLANAGAN PREDOMINANT SOIL SERIES:OCILLA CATION EXCHANGE CAPACITY(NON-503):
CROP 1 NAME:BERMUDAGRASS,COMMON- CROP 1 MAX.PAN:121 CROP 2 NAME: CROP 2 MAX.PAN:
['ACT!IC=(ue r o
RESIDUAL SOURCE(S):*See list at bottom of report
Gallons(G) Site Name of Crop Type
or Cubic Yards(Y) Cond. Precip Volati- Mineral- Ammonia Nitrate PAN Applied Receiving Residual
Date or or Wet Tons(W) % Residual Dry,Wet, Past 24 Hrs. Application lization ization TKN Nitrogen and Nitrite (Ibs/acre) Application
Month Amount UOM Solids Dry Tons/Ac Source Moist Inches Method* Rate** Rate*** mg/kg mg/kg mg/kg Crop 1 Crop 2 Crop 1 Crop 2
12/6/2021 93,000.00 (G) 3.570 2.130 FARAEDL DRY 0-<1/2" SUR 0.5 0.30 45,000.00 15.00 210.00 58.417 BCOP
12/7/2021 49,600.00 (G) 3.570 1,136 FARAEDL DRY "0-<1/2" SUR 0.5 0.30 45,000.00 15.00 210.00 31.156 BCOP
Dec-21 142,600.00, (G)
Total 3.266 Total 89.573 0.000
AS CD CU CR PB HG - MO NI SE ZN P Lime Applied
Annual Ibs/acre Applied 0.040 0.005 2.025 0.216 0.196 0.003 0.039 0.150 0.046 4.964 91.447 Date Lbs/Ac
Cumulative Ibs/acre Applied 0.164 0.098 40.785 2.771 1.744 0.038 0.463 1.440 0.160 29.645
Permit PAN Limit(lbs/acre) 1st Crop i 121
-.
Federal C,P.L.R.(lbs/acre)**** 36.6 34.8 ( 1,339.0 ( 267.9 15.0 �1 375.0 89.0 2,500.0
FARAEDL=FARMVILLE,NC AEROBICALLY DIGESTED LIQUID
t
"I certify,under penalty of law,that this doc a was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.I am
aware that there are significant pe s i-s '. s0tbtting false information,including the possibility of fines and imprisonm t for owing violations."
,- — i Z2
SII ' RE OF LAND APPLIER DAT
NR=Not Reported or Not Re.- ..' *** Mineralization Rates:Compost-0.1,Anaerobically digested-0.2,Aerobically digested-0.3,Raw Sludge-0.4
* Application Method:SUR-Surface,INJ-Injection,SURIN-Incorporation **** C,P.L.R.:Cumulative Pollutant Loading Rate
** Volatilization Rate: Surface 0.5, Injection/Incorporation 1.0 ***** See Site pH&Lime Application Records Section of Report
Printed:1/27/2022 DENR FORM FSF(12/2006)

ANNUAL LAND APPLICATION FIELD SUMMARY FORM Page: 1
FACILITY NAME:FARMVILLE,NC WQ PERMIT#:WQ0008778 FIELD#:NC-PI-00001-0-0004- ACRES UTILIZED:6.4
LAND OWNER:HAROLD FLANAGAN ANNUAL DRY TONS APPLIED:21.23 SITE#:NC P1 00001 ACRES PERMITTED:6.4
OPERATOR:HAROLD FLANAGAN PREDOMINANT SOIL SERIES:GOLDSBORO CATION EXCHANGE CAPACITY(NON-503):
CROP 1 NAME:MIXED COOL SEASON GRASS CROP 1 MAX.PAN:127 CROP 2 NAME: CROP 2 MAX.PAN:
rnercrn
RESIDUAL SOURCE(S):*See list at bottom of report
Gallons(G) Site Name of Crop Type
or Cubic Yards(Y) Cond. Precip Volati- Mineral- Ammonia Nitrate PAN Applied Receiving Residual
Date or or Wet Tons(W) % Residual Dry,Wet, Past 24 Hrs. Application lization ization TKN Nitrogen and Nitrite (lbs/acre) Application
Month Amount UOM Solids Dry Tons/Ac Source Moist Inches Method* Rate** Rate*** mg/kg mg/kg mg/kg Crop 1 ! Crop 2 Crop 1 Crop 2
12/7/2021 49,600.00 (G) 3.570 1.154 FARAEDL DRY "0-<1/2" SUR 0.5 0.30 45,000.00 15.00 210.00 31.642 MCSG
12/13/2021 93,000.00 (G) 3.570 2.163 FARAEDL DRY "0-<1/2" SUR 0.5 0.30 45,000.00 15.00 210.00 59.329 MCSG
Dec-21 142,600.00 (G)
Total 3.317 Totaf 90.971 0.000
AS CD CU CR PB HG MO NI SE ZN P Litre Applied
Annual lbs/acre Applied 0.040 0.005 2.057 0.219 0.199 0.003 0.039 0.153 0.047 5.042 92.876 Date — Lbs/Ac
Cumulative lbs/acre Applied 0.226 I 0.149 50.847 3.568 2.030 0.045 0.485 I 1.995 0.259 41.890
Permit PAN Limit(lbs/acre) 1st Crop
127
Federal C.P.L.R.(lbs/acre)**"* 36.6 I 34,8 1,339.0 267.9 15.0 375.0 89.0 2,500.0
FARAEDL=FARMVILLE,NC AEROBICALLY DIGESTED LIQUID
"I certify,under penalty of law,that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.I am
aware that there are signi t es for submitting false information,including the possibility of fines and impriso ent r knowing violations."
�G Z i- 2Z-
SIGNATURE OF LAND APPLIER D TE
NR=Not Reported r N equired *** Mineralization Rates:Compost-0.1,Anaerobically digested-0.2,Aerobically digested-0.3,Raw Sludge-0.4
* Application Method:SUR-Surface,INJ-Injection,SURIN-Incorporation **** C.P.L.R.:Cumulative Pollutant Loading Rate
** Volatilization Rate: Surface 0.5, Injection/Incorporation 1.0 ***"* See Site pH&Lime Application Records Section of Report
Printed:1/27/2022 DENR FORM FSF(12/2006)

ANNUAL LAND APPLICATION FIELD SUMMARY FORM Page: 1
FACILITY NAME:FARMVILLE,NC WQ PERMIT#:WQ0008778 FIELD#:NC-PI-00001-0-0006- ACRES UTILIZED:32.7
LAND OWNER:HAROLD FLANAGAN ANNUAL DRY TONS APPLIED:50.77 SITE#:NC PI 00001 ACRES PERMITTED:32.7
OPERATOR:HAROLD FLANAGAN PREDOMINANT SOIL SERIES:GOLDSBORO CATION EXCHANGE CAPACITY(NON-503):
CROP 1 NAME:BERMUDAGRASS,COASTAL- CROP 1 MAX.PAN:224 CROP 2 NAME: CROP 2 MAX.PAN:
PACT'IR/RC•01
RESIDUAL SOURCE(S):*See list at bottom of report
Gallons(G) Site Name of Crop Ty
YPe
or Cubic Yards(Y) Cond. Precip Volati- Mineral- Ammonia Nitrate PAN Applied Receiving Residual
Date or or Wet Tons(W) % Residual Dry,Wet, Past 24 Hrs. Application lization ization TKN Nitrogen and Nitrite (lbs/acre) Application
Month Amount UOM Solids Dry Tons/Ac Source Moist Inches Method* Rate** Rate*** mg/kg mg/kg mg/kg Crop 1 Crop 2 Crop 1 Crop 2
5/11/2021 186,000.00 (G) 3.570 0.847 FARAEDL DRY "0-<1/2" SUR 0.5 0.30 45,000.00 15.00 210.00 23.224 BCP
5/12/2021 155,000.00 (G) 3.570 0.706 FARAEDL DRY "0-<1/2" SUR 0.5 0.30 45,000.00 15.00 210.00 19.353 BCP
y
May-21 341,000.00 (G)
Total 1.553 Total 42.577 0.000
AS CD CU CR PB HG — MO NI SE ZN P Lime Applied
Annual lbs/acre Applied 0.019 0.002 0.963 0.102 0.093 0.002 0.018 0.071 0.022 2.360 43.468 Date Lbs/Ac
***** *****
[Cumulative lbs/acre Applied 0.039 0.010 NM 0.288 0.204 0.004 0.044 0.176 0.044 5.496
Permit PAN Limit(lbs/acre) 1st Crop 224
Federal C.P.LR.(Ibs/acre)**** 36.6 I 34.8 1,339.0 I 267.9 15.0 375.0 89.0 2,500.0 J
FARAEDL=FARMVILLE,NC AEROBICALLY DIGESTED LIQUID
"I certify,under penalty of law,that this document w prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.I am
aware that there are significant pe 'es t sub 't g false information,including the possibility of fines and impriso ent.or knowing violations."
SIGN U E OF LAND APPLIER ATE
NR=Not Reported or Not Requir.. *** Mineralization Rates:Compost-0.1,Anaerobically digested-0.2,Aerobically digested-0.3,Raw Sludge-0.4
* Application Method:SUR-Surface,INJ-Injection,SURIN-Incorporation **** C.P.L.R.:Cumulative Pollutant Loading Rate
** Volatilization Rate: Surface 0.5, Injection/Incorporation 1.0 ***** See Site pH&Lime Application Records Section of Report
Printed:1/27/2022 DENR FORM FSF(12/2006)

SECTION 4

S
a i' Summit Environmental Technologies,Inc.
inIrg 3310 Win St.
ENVIRONMENTAL TECHNO LOCiES,INC Cuyahoga Falls,Ohio 44223
rralyt�cal L9boraIi rlas TEL:[phone] FAX. [phone]
Website:http://www.settek.com
January 25,2021
Alex Fox
Synagro
284 Boger Rd.
Mocksville,NC 27028
TEL:
FAX:
RE: Farmville WWTP
Dear Alex Fox: Order No.: 21010359
Summit Environmental Technologies, Inc. received 1 sample(s) on 1/8/2021 for the
analyses presented in the following report.
There were no problems with the analytical events associated with this report unless noted
in the Case Narrative.
Quality control data is within laboratory defined or method specified acceptance limits
except where noted.
If you have any questions regarding these tests results,please feel free to call the
laboratory.
Sincerely,
/.....?-74424f4 177��
Jennifer Woolf
Project Manager
3310 Win St.
Cuyahoga Falls,Ohio 44223
Arkansas 88-0735,California 2943,Colorado,Connecticut PH-0108,Florida NELAC E87688,Idaho OH00923,Illinois 200061,Indiana C-OH-13,Kansas
E-10347,Kentucky(Underground Storage Tank)3,Kentucky 90146,Maryland 339,Michigan 9988,Minnesota 1780279,Nevada OH009232020-1,New
Hampshire 2996,New Jersey OH006,New York 11777,North Carolina 39705 and 631,North Dakota R-201,Ohio DW,Ohio VAP CL0052,Oklahoma
2019-155,Oregon OH200001, Pennsylvania 011,Rhode Island LA000317,South Carolina 92016001,Texas T104704466-19-16,Utah OH009232020-12,
Virginia VELAP 10381,West Virginia 9957C
Page 1 of 36

SUMMIT
Summit Environmental Technologies,Inc.imil*;;:ra Case Narrative
331 Ohio Wm St.
mium
AnalENVIRONMENTAL calLaoraloriNO LOGI ,INC. Cuyahoga Falls, 44223 WO#: 21010359rrafyt�caf iaboralorlas TEL:[phone] FAX. [phone]
Website:http://www.settek.com Date: 1/25/2021
CLIENT: Synagro
Project: Farmville WWTP
WorkOrder Narrative:
21010359: This report in its entirety consists of the following documents: Cover Letter, Case Narrative,
Analytical Results, QC Summary Report, Applicable Accreditation Information, Chain-of-Custody,
Cooler Receipt Form, and other applicable forms as necessary. All documents contain the Summit
Environmental Technologies, Inc., Work Order Number assigned to this report.
Summit Environmental Technologies, Inc., holds the accreditations/certifications listed at the bottom of
the cover letter that may or may not pertain to this report. Please refer to the "Accreditation Program
Analytes Report" for accredited analytes list.
The information contained in this analytical report is the sole property of Summit Environmental
Technologies, Inc. and that of the customer. It cannot be reproduced in any form without the consent of
Summit Environmental Technologies, Inc. or the customer for which this report was issued. The results
contained in this report are only representative of the samples received. Conditions can vary at different
times and at different sampling conditions. Summit Environmental Technologies, Inc. is not responsible
for use or interpretation of the data included herein.
All results for Solid Samples are reported on an "as received" or "wet weight" basis unless indicated as
"dry weight" using the "-dry" designation on the reporting units.
This report is believed to meet all of the requirements of the accrediting agency, where applicable. Any
comments or problems with the analytical events associated with this report are noted below.
Analytical Sequence Sample Notes:
21010359-001a CYANIDE,REACTIVES(9014): Below detection level data was reported based on
Total CN data.
21010359-001a TCLP-SVOC-CPest(8081B): High recovery(ies) in the CCV indicate high bias. Data
deemed acceptable as no target analytes were observed in the field sample(s).
Analytical Sequence QC Notes:
CCV VOC-MSTR_NPW(8260): CCV exhibits high recovery for Vinyl chloride. All reported samples
are ND for this analyte.
LCS-47331 TCLP-VOC-MSTR TCLP(8260): Possible high bias for Vinyl chloride due to high
recovery in CCV. Associated samples are N.D. for this analyte.
Original
Page 2 of 36

SUMMIT
Summit Environmental Technologies,Inc.3310 Win 2t. Case Narrative
imil*;;:ra ENVIRONMENTAL TECliN❑LOGIES.INC. Cuyahoga Falls,Ohio 44223 WO#: 21010359
4rraly0cal Laboralorlas TEL:[phone] FAX [phone]
Website:http://www.settek.com Date: 1/25/2021
CLIENT: Synagro
Project: Farmville WWTP
21010359-001ams TCLP-SVOC-CPest(8081B): Possible high bias for Heptachlor and Methoxychlor
due to high recoveries in bracketing CCV's. Parent sample is N.D. for these analytes.
21010359-001amsd TCLP-SVOC-CPest(8081B): Possible high bias for Heptachlor and Methoxychlor
due to high recoveries in bracketing CCV's. Parent sample is N.D. for these analytes.
LCS-47347 TCLP-SVOC-CPest(8081B): Possible high bias for Heptachlor and Methoxychlor due to
high recoveries in bracketing CCV's.
MB-47347 TCLP-SVOC-CPest(8081B): High recovery(ies) in the CCV indicate high bias. Data
deemed acceptable as no target analytes were observed in the field sample(s).
Original
Page 3 of 36

•
17 S
Mm iT Summit Environmental Techno3310Wlogies,Ins
Qualifiers and Acronyms
EkiwllxsStJM@N1'nLTecriw❑LOG{ES.rFtI; Cuyahoga Falls,Ohio 442 WO#: 21010359
4rraly0cal Laboralorlas TEL:[phone] FAX. [phone]E
Website:http://www.settek.co Date: 1/25/2021
These commonly used Qualifiers and Acronyms may or may not be present in this report.
Qualifiers
U The compound was analyzed for but was not detected.
J The reported value is greater than the Method Detection Limit but less than the Reporting Limit.
H The hold time for sample preparation and/or analysis was exceeded.
D The result is reported from a dilution.
E The result exceeded the linear range of the calibration or is estimated due to interference.
MC The result is below the Minimum Compound Limit.
The result exceeds the Regulatory Limit or Maximum Contamination Limit.
m Manual integration was used to determine the area response.
d Manual integration in which peak was deleted
N The result is presumptive based on a Mass Spectral library search assuming a 1:1 response.
P The second column confirmation exceeded 25%difference.
C The result has been confirmed by GC/MS.
X The result was not confirmed when GC/MS Analysis was performed.
B/MB+ The analyte was detected in the associated blank.
G The ICB or CCB contained reportable amounts of analyte.
QC-/+ The CCV recovery failed low(-)or high(+).
R/QDR The RPD was outside of accepted recovery limits.
QL-/+ The LCS or LCSD recovery failed low(-)or high(+).
QLR The LCS/LCSD RPD was outside of accepted recovery limits.
QM-/+ The MS or MSD recovery failed low(-)or high(+).
QMR The MS/MSD RPD was outside of accepted recovery limits.
QV-/+ The ICV recovery failed low(-)or high(+).
S The spike result was outside of accepted recovery limits.
Z Deviation;A deviation from the method was performed;Please refer to the Case Narrative for
additional information
Acronyms
ND Not Detected RL Reporting Limit
QC Quality Control MDL Method Detection Limit
MB Method Blank LOD Level of Detection
LCS Laboratory Control Sample LOQ Level of Quantitation
LCSD Laboratory Control Sample Duplicate PQL Practical Quantitation Limit
QCS Quality Control Sample CRQL Contract Required Quantitation Limit
DUP Duplicate PL Permit Limit
MS Matrix Spike RegLvl Regulatory Limit
MSD Matrix Spike Duplicate MCL Maximum Contamination Limit
RPD Relative Percent Different MinCL Minimum Compound Limit
ICV Initial Calibration Verification RA Reanalysis
ICB Initial Calibration Blank RE Reextraction
CCV Continuing Calibration Verification TIC Tentatively Identified Compound
CCB Continuing Calibration Blank RT Retention Time
RLC Reporting Limit Check CF Calibration Factor
DF Dilution Factor RF Response Factor
This list of Qualifiers and Acronyms reflects the most commonly utilized Qualifiers and Acronyms for reporting.
Please refer to the Analytical Notes in the Case Narrative for any Qualifiers or Acronyms that do not appear in this
list or for additional information regarding the use of these Qualifiers on reported data.
Original
Page 4 of 36

S t�' Summit Environmental Technologies,Inc. Workorder
3310 Win St.
1.7 ENVIRONMENTAL TECHNQI. oiEs,iric, Cuyahoga Falls,Ohio 44223 Sample Summary
4rralyt�cai iaboralorlas TEL:[phone] FAX [phone] WO#: 21010359
Website:http://www.settek.com 25-Jan-21
CLIENT: Synagro
Project: Farmville WWTP
Lab SamplelD Client Sample ID Tag No Date Collected Date Received Matrix
21010359-001 Farmville WWTP 1/7/2021 12:30:00 PM 1/8/2021 10:25:00 AM Sludge
Page 5 of 36

SUMMIT
Summit Environmental Technologies,Inc. DATES REPORT
MN rg 33hi Win St.
AnalOc t Lab ratorf NO LOi,I S,INC Cuyahoga Falls, Ohio 44223 WO#: 21010359
�a�}lkai iaboralorlas TEL:[phone] FAX:[phone]
Website:http://www.settekcom 25-Jan-21
Client: Synagro
Project: Farmville WWTP
Sample ID Client Sample ID Collection Date Matrix Test Name Leachate Date Prep Date Analysis Date
21010359-001A Farmville WWTP 1/7/2021 12:30:00 PM Sludge Ignitability of Solids(SW-846: 1030) 1/13/2021 11:15:56 AM
pH(SW9045D) 1/13/2021 12:15:13 PM
Reactive Cyanide(9014/7.3.3.2)-Solid 1/17/2021 4:20:00 PM
Reactive Sulfide(9034)/7.3.4.2 1/19/2021
TCLP Herbicides by EPA 8321B 1/17/2021 4:00:00 PM 1/23/2021 2:43:00 AM
TCLP Herbicides by EPA 8321B 1/19/2021 4:46:00 AM
TCLP Mercury Analysis(SW1311/7471/16/2021 6:00:00 PM 1/18/2021 2:35:00 PM 1/19/2021 10:19:00 AM
TCLP Metals Analysis(SW1311/6010:1/16/2021 6:00:00 PM 1/18/2021 1:10:00 PM 1/19/2021 10:35:33 AM
TCLP Pesticides Analysis(SW1311/8(1/16/2021 6:00:00 PM 1/18/2021 11:45:00 AM 1/19/2021 8:31:00 PM
TCLP Pesticides Analysis(SW1311/8(1/16/2021 6:00:00 PM 1/18/2021 11:45:00 AM 1/19/2021 8:31:00 PM
TCLP Semi-Volatiles Analysis 1/16/2021 6:00:00 PM 1/18/2021 11:45:00 AM 1/19/2021 6:19:00 PM
(SW1311/8270)
TCLP Volatiles Analysis 1/17/2021 4:00:00 PM 1/19/2021 3:29:00 AM
Original
Page 6 of 36

S
it• Summit Environmental Technologies,Inc.3310 Win St. Analytical Report
INiM itrgENb1R01JMENTAL TECliK10LOG1ES,IN'C Cuyahoga Falls, Ohio 44223 (base report)
�afyt�caf iaboralorfas TEL:[phone] FAX [phone] WON: 21010359
Website:http://www.settek.com Date Reported: 1/25/2021
CLIENT: Synagro Tag Number:
Matrix: SLUDGE Collection Date: 1/7/2021 12:30:00 PM
Lab ID: 21010359-001A
Project: Farmville WWTP
Client Sample ID Farmville WWTP
Analyses Result RL Qual Units DF Date Analyzed
TCLP METALS,VOC, BNA, PEST, HERB-SOLID SW7470A SW7470A Analyst: ERA
TCLP MERCURY ANALYSIS (SW1311/7470)
TCLP Mercury ND 0.00200 mg/L 1 1/19/2021 10:19:00 AM
TCLP METALS,VOC, BNA, PEST, HERB-SOLID SW6010D SW3010A Analyst: EAM
TCLP METALS ANALYSIS (SW1311/6010)
TCLP Arsenic(As) ND 0.500 mg/L 1 1/19/2021 10:35:33 AM
TCLP Barium(Ba) ND 5.00 mg/L 1 1/19/2021 10:35:33 AM
TCLP Cadmium(Cd) ND 0.100 mg/L 1 1/19/2021 10:35:33 AM
TCLP Chromium(Cr) ND 0.200 mg/L 1 1/19/2021 10:35:33 AM
TCLP Lead(Pb) ND 0.500 mg/L 1 1/19/2021 10:35:33 AM
TCLP Selenium(Se) ND 0.0500 mg/L 1 1/19/2021 10:35:33 AM
TCLP Silver(Ag) ND 0.500 mg/L 1 1/19/2021 10:35:33 AM
TCLP METALS,VOC, BNA, PEST, HERB-SOLID SW8270 SW3510C Analyst: SFG
TCLP SEMI-VOLATILES ANALYSIS (SW1311/8270)
1,4-Dichlorobenzene ND 0.200 mg/L 2 1/19/2021 6:19:00 PM
2,4,5-Trichlorophenol ND 0.500 mg/L 2 1/19/2021 6:19:00 PM
2,4,6-Trichlorophenol ND 0.500 mg/L 2 1/19/2021 6:19:00 PM
2,4-Dinitrotoluene ND 0.100 mg/L 2 1/19/2021 6:19:00 PM
Cresols,Total ND 10.0 mg/L 2 1/19/2021 6:19:00 PM
Hexachloro-1,3-butadiene ND 0.0400 mg/L 2 1/19/2021 6:19:00 PM
Hexachlorobenzene ND 0.100 mg/L 2 1/19/2021 6:19:00 PM
Hexachloroethane ND 0.200 mg/L 2 1/19/2021 6:19:00 PM
Nitrobenzene ND 0.200 mg/L 2 1/19/2021 6:19:00 PM
Pentachlorophenol ND 0.500 mg/L 2 1/19/2021 6:19:00 PM
Pyridine ND 0.500 mg/L 2 1/19/2021 6:19:00 PM
Surr:2-Fluorophenol 71.4 10-157 %Rec 2 1/19/2021 6:19:00 PM
Surr: Phenol-d6 79.6 10-169 %Rec 2 1/19/2021 6:19:00 PM
Surr: Nitrobenzene-d5 74.1 32.1 -130 %Rec 2 1/19/2021 6:19:00 PM
Surr:2,4,6-Tribromophenol 93.2 45.4-166 %Rec 2 1/19/2021 6:19:00 PM
Surr:2-Fluorobiphenyl 66.1 35.7-130 %Rec 2 1/19/2021 6:19:00 PM
Surr:p-Terphenyl-d14 103 74.7-145 %Rec 2 1/19/2021 6:19:00 PM
Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range
H Holding times for preparation or analysis exceeded M Manual Integration used to determine area response
MC Value is below Minimum Compound Limit. N Tentatively identified compounds
ND Not Detected P Second column confirmation exceeds
PL Permit Limit R RPD outside accepted recovery limits Original
RL Reporting Detection Limit U Samples with CalcVal<MDL
Page 7 of 36

S
it• Summit Environmental Technologies,Inc. Analytical Report
mu 3310 Win St.
ENVIRONMENTAL TECliK10LOG1ES,IN'C Cuyahoga Falls, Ohio 44223 (base report)
�afyt�caf iaboralorfas TEL:[phone] FAX [phone] WON: 21010359
Website:http://www.settek.com Date Reported: 1/25/2021
CLIENT: Synagro Tag Number:
Matrix: SLUDGE Collection Date: 1/7/2021 12:30:00 PM
Lab ID: 21010359-001A
Project: Farmville WWTP
Client Sample ID Farmville WWTP
Analyses Result RL Qual Units DF Date Analyzed
TCLP METALS,VOC, BNA, PEST, HERB-SOLID SW8081 SW3510C Analyst: CSS
TCLP PESTICIDES ANALYSIS (SW1311/8081)
Chlordane,total ND 0.0250 mg/L 1 1/19/2021 8:31:00 PM
Toxaphene ND 0.0500 mg/L 1 1/19/2021 8:31:00 PM
Endrin ND 0.00250 mg/L 1 1/19/2021 8:31:00 PM
gamma-BHC ND 0.00250 mg/L 1 1/19/2021 8:31:00 PM
Heptachlor ND 0.00250 QC+ mg/L 1 1/19/2021 8:31:00 PM
Heptachlor epoxide ND 0.00250 mg/L 1 1/19/2021 8:31:00 PM
Methoxychlor ND 0.00250 QC+ mg/L 1 1/19/2021 8:31:00 PM
Surr:TCMX 71.4 10-119 %Rec 1 1/19/2021 8:31:00 PM
Surr: DCB 83.9 10-119 %Rec 1 1/19/2021 8:31:00 PM
TCLP HERBICIDES BY EPA 8321B SW8321 SW1311M Analyst: JPG
2,4-D ND 0.500 mg/L 50 1/23/2021 2:43:00 AM
2,4,5-TP ND 0.500 mg/L 50 1/23/2021 2:43:00 AM
Surr:2,4-Dichlorophenylacetic aci 111 70-130 %Rec 50 1/23/2021 2:43:00 AM
TCLP METALS,VOC, BNA, PEST, HERB-SOLID SW8260 SW1311M Analyst: MES
TCLP VOLATILES ANALYSIS
1,1-Dichloroethene ND 0.250 mg/L 50 1/19/2021 3:29:00 AM
1,2-Dichloroethane ND 0.250 mg/L 50 1/19/2021 3:29:00 AM
MEK ND 5.00 mg/L 50 1/19/2021 3:29:00 AM
Benzene ND 0.250 mg/L 50 1/19/2021 3:29:00 AM
Carbon tetrachloride ND 0.250 mg/L 50 1/19/2021 3:29:00 AM
Chlorobenzene ND 2.50 mg/L 50 1/19/2021 3:29:00 AM
Chloroform ND 0.250 mg/L 50 1/19/2021 3:29:00 AM
Tetrachloroethene ND 0.250 mg/L 50 1/19/2021 3:29:00 AM
Trichloroethene ND 0.250 mg/L 50 1/19/2021 3:29:00 AM
Vinyl chloride ND 0.100 QC+ mg/L 50 1/19/2021 3:29:00 AM
Surr:4-Bromofluorobenzene 96.4 70-130 %Rec 50 1/19/2021 3:29:00 AM
Surr: Dibromofluoromethane 97.9 70-130 %Rec 50 1/19/2021 3:29:00 AM
Surr:Toluene-d8 99.4 70-130 %Rec 50 1/19/2021 3:29:00 AM
Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range
H Holding times for preparation or analysis exceeded M Manual Integration used to determine area response
MC Value is below Minimum Compound Limit. N Tentatively identified compounds
ND Not Detected P Second column confirmation exceeds
PL Permit Limit R RPD outside accepted recovery limits Original
RL Reporting Detection Limit U Samples with CalcVal<MDL
Page 8 of 36

S
it• Summit Environmental Technologies,Inc.3310 Win St. Analytical Report
INiM itrgENVIRONMENTAL TECHNOLOGIES,IN'C Cuyahoga Falls, Ohio 44223 (base report)
�afyt�caf iaboralorfas TEL:[phone] FAX [phone] WON: 21010359
Website:http://www.settek.com Date Reported: 1/25/2021
CLIENT: Synagro Tag Number:
Matrix: SLUDGE Collection Date: 1/7/2021 12:30:00 PM
Lab ID: 21010359-001A
Project: Farmville WWTP
Client Sample ID Farmville WWTP
Analyses Result RL Qual Units DF Date Analyzed
RCI SW9014 Analyst: JAP
REACTIVE CYANIDE(9014/7.3.3.2)-SOLID
Cyanide, Reactive ND 0.962 mg/Kg 1 1/17/2021 4:20:00 PM
IGNITABILITY OF SOLIDS(SW-846: 1030) SW1030 Analyst: SEE
Ignitability nonflammable mm/sec 1 1/13/2021 11:15:56 AM
RCI SW9045D Analyst: WK
PH (SW9045D)
pH 6.7 s.u.@20.0C 1 1/13/2021 12:15:13 PM
RCI SW9034 Analyst: JAP
REACTIVE SULFIDE(9034)/7.3.4.2
Sulfide, Reactive ND 25.0 mg/Kg 1 1/19/2021
Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range
H Holding times for preparation or analysis exceeded M Manual Integration used to determine area response
MC Value is below Minimum Compound Limit. N Tentatively identified compounds
ND Not Detected P Second column confirmation exceeds
PL Permit Limit R RPD outside accepted recovery limits Original
RL Reporting Detection Limit U Samples with CalcVal<MDL
Page 9 of 36

S
MM IT Summit Environmental Technologies,Inc. Accreditation Program
3310 Win St. Anal�7teS RenOrt
MI ENVIRONMENTAL TECHNaLOGES,INCCuyahoga Falls,Ohio 44223 J Y
rral}'t�caf iaboralorlas TEL:[phone] FAX [phone] WO#: 21010359
Website:http://www.settek.com 25-Jan-21
Client: Synagro State: NW
Project: Farmville WWTP Program Name: NC_WW_SCM
Sample ID Matrix Test Name Analyte Status
21010359-001A Sludge Ignitability of Solids(SW-846: 1030) Ignitability A
Sludge pH(SW9045D) Hydrogen Ion(pH) A
Sludge Reactive Cyanide(9014/7.3.3.2)-Solid Cyanide,Reactive N
Sludge Reactive Sulfide(9034)/7.3.4.2 Sulfide,Reactive N
Sludge TCLP Herbicides by EPA 8321B 2,4,5-TP A
Sludge TCLP Herbicides by EPA 8321B 2,4-D A
Sludge TCLP Mercury Analysis(SW1311/7470) Mercury A
Sludge TCLP Metals Analysis(SW1311/6010) Arsenic A
Sludge TCLP Metals Analysis(SW1311/6010) Barium A
Sludge TCLP Metals Analysis(SW1311/6010) Cadmium A
Sludge TCLP Metals Analysis(SW1311/6010) Chromium A
Sludge TCLP Metals Analysis(SW1311/6010) Lead A
Sludge TCLP Metals Analysis(SW1311/6010) Selenium A
Sludge TCLP Metals Analysis(SW1311/6010) Silver A
Sludge TCLP Pesticides Analysis(SW1311/8081) Chlordane,total A
Sludge TCLP Pesticides Analysis(SW1311/8081) Endrin A
Sludge TCLP Pesticides Analysis(SW1311/8081) gamma-BHC A
Sludge TCLP Pesticides Analysis(SW1311/8081) Heptachlor A
Sludge TCLP Pesticides Analysis(SW1311/8081) Heptachlor epoxide A
Sludge TCLP Pesticides Analysis(SW1311/8081) Methoxychlor A
Sludge TCLP Pesticides Analysis(SW1311/8081) Toxaphene A
Sludge TCLP Semi-Volatiles Analysis(SW1311/8270) 1,4-Dichlorobenzene A
Sludge TCLP Semi-Volatiles Analysis(SW1311/8270) 2,4,5-Trichlorophenol A
Sludge TCLP Semi-Volatiles Analysis(SW1311/8270) 2,4,6-Trichlorophenol A
Sludge TCLP Semi-Volatiles Analysis(SW1311/8270) 2,4-Dinitrotoluene A
Sludge TCLP Semi-Volatiles Analysis(SW1311/8270) Cresols,Total A
Sludge TCLP Semi-Volatiles Analysis(SW1311/8270) Hexachlorobenzene A
Sludge TCLP Semi-Volatiles Analysis(SW1311/8270) Hexachlorobutadiene A
Sludge TCLP Semi-Volatiles Analysis(SW1311/8270) Hexachloroethane A
Sludge TCLP Semi-Volatiles Analysis(SW1311/8270) Nitrobenzene A
Sludge TCLP Semi-Volatiles Analysis(SW1311/8270) Pentachlorophenol A
Sludge TCLP Semi-Volatiles Analysis(SW1311/8270) Pyridine A
Key Key
NC WW SCM A Accredited NC WW SCM N Not Accredited
Original#1
Page 10 of 36

S UMM IT Summit Environmental Technologies,Inc. Accreditation Program
3310 Win St. Anal�7tes Report
EN ENWIRONM@NtAL TECHNaLOGES,iri Cuyahoga Falls,Ohio 44223 Analytes
rral}'tiicaf iaboralorlas TEL:[phone] FAX [phone] WO#: 21010359
Website:http://www.settek.com 25-Jan-21
Client: Synagro State: NW
Project: Farmville WWTP Program Name: NC_WW_SCM
Sample ID Matrix Test Name Analyte Status
21010359-001A Sludge TCLP Volatiles Analysis 1,1-Dichloroethene A
Sludge TCLP Volatiles Analysis 1,2-Dichloroethane A
Sludge TCLP Volatiles Analysis 2-Butanone A
Sludge TCLP Volatiles Analysis Benzene A
Sludge TCLP Volatiles Analysis Carbon tetrachloride A
Sludge TCLP Volatiles Analysis Chlorobenzene A
Sludge TCLP Volatiles Analysis Chloroform A
Sludge TCLP Volatiles Analysis Tetrachloroethene A
Sludge TCLP Volatiles Analysis Trichloroethene A
Sludge TCLP Volatiles Analysis Vinyl chloride A
Key Key
NC WW SCM A Accredited NC WW SCM N Not Accredited
Original#1
Page 11 of 36

MM Summit Environmental Technologies,Inc. QC SUMMARY REPORT
III rg 5 U IT 331 Ohio Win St.
ENVIRONMENTAL rmy' 'LaboTtorfes LOi,I S,INC Cuyahoga Falls, 44223 WO#: 21010359
4na/yt�caf iaboralorfas TEL:[phone] FAX[phone]
Website:http://www.settek.com 25-Jan-21
Client: Synagro
Project: Farmville WWTP BatchID: 47331
Sample ID: MB-47331 SampType: MBLK TestCode: TCLP-VOC-M Units: mg/L Prep Date: 1/17/2021 RunNo: 122624
Client ID: PBS Batch ID: 47331 TestNo: SW8260 SW1311M Analysis Date: 1/19/2021 SegNo: 3160953
Analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual
1,1-Dichloroethene ND 0.250
1,2-Dichloroethane ND 0.250
MEK ND 5.00
Benzene ND 0.250
Carbon tetrachloride ND 0.250
Chlorobenzene ND 2.50
Chloroform ND 0.250
Tetrachloroethene ND 0.250
Trichloroethene ND 0.250
Vinyl chloride ND 0.100 QC+
Surr:4-Bromofluorobenzene 2360 2500 94.6 70 130
Surr: Dibromofluoromethane 2410 2500 96.4 70 130
Surr:Toluene-d8 2450 2500 98.1 70 130
Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal}
J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound
ND Not Detected P Second column confirmation exceeds PL Permit Limit Original
R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted reco
Page 12 of 36

MM Summit Environmental Technologies,Inc. QC SUMMARY REPORT
III rg 5 U IT 331 Ohio Win St.
ENVIRONMENTAL rmy' 'LaboTtorfes LOi,I S,INC Cuyahoga Falls, 44223 WO#: 21010359
4na/yt�caf iaboralorfas TEL:[phone] FAX[phone]
Website:http://www.settek.com 25-Jan-21
Client: Synagro
Project: Farmville WWTP BatchID: 47331
Sample ID: 21010360-001AMS SampType: MS TestCode: TCLP-VOC-M Units: mg/L Prep Date: RunNo: 122624
Client ID: BatchQC Batch ID: 47331 TestNo: SW8260 SW1311M Analysis Date: 1/19/2021 SeqNo: 3160964
Analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual
1,1-Dichloroethene 1.07 0.250 1.00 0 107 13.6 202
1,2-Dichloroethane 0.954 0.250 1.00 0 95.4 55.7 138
MEK ND 5.00 5.00 0 91.3 65.3 118
Benzene 1.03 0.250 1.00 0 103 49.2 145
Carbon tetrachloride 0.933 0.250 1.00 0 93.3 26.7 156
Chlorobenzene ND 2.50 1.00 0 94.2 33.7 159
Chloroform 0.986 0.250 1.00 0 98.6 48.5 145
Tetrachloroethene 0.880 0.250 1.00 0 88.0 19.2 191
Trichloroethene 0.897 0.250 1.00 0 89.7 38.4 167
Vinyl chloride 1.31 0.100 1.00 0 131 27.3 161 QC+
Surr:4-Bromofluorobenzene 2520 2500 101 91.7 109
Surr: Dibromofluoromethane 2470 2500 98.7 75.5 118
Surr:Toluene-d8 2530 2500 101 94.1 105
Sample ID: 21010360-001AMSD SampType: MSD TestCode: TCLP-VOC-M Units: mg/L Prep Date: RunNo: 122624
Client ID: BatchQC Batch ID: 47331 TestNo: SW8260 SW1311M Analysis Date: 1/19/2021 SeqNo: 3160965
Analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual
1,1-Dichloroethene 1.12 0.250 1.00 0 112 13.6 202 1.07 4.72 25
1,2-Dichloroethane 0.957 0.250 1.00 0 95.7 55.7 138 0.954 0.314 25
MEK ND 5.00 5.00 0 91.1 65.3 118 0 0 25
Benzene 1.05 0.250 1.00 0 105 49.2 145 1.03 1.39 25
Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal}
J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound
ND Not Detected P Second column confirmation exceeds PL Permit Limit Original
R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted reco
Page 13 of 36

MM Summit Environmental Technologies,Inc. QC SUMMARY REPORT
III rg 5 U IT 331 Ohio Win St.
ENVIRONMENTAL rmy' 'LaboTtorfes LOi,I S,INC Cuyahoga Falls, 44223 WO#: 21010359
4na/yt�caf iaboralorfas TEL:[phone] FAX[phone]
Website:http://www.settek.com 25-Jan-21
Client: Synagro
Project: Farmville WWTP BatchID: 47331
Sample ID: 21010360-001AMSD SampType: MSD TestCode: TCLP-VOC-M Units: mg/L Prep Date: RunNo: 122624
Client ID: BatchQC Batch ID: 47331 TestNo: SW8260 SW1311M Analysis Date: 1/19/2021 SegNo: 3160965
Analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual
Carbon tetrachloride 0.977 0.250 1.00 0 97.7 26.7 156 0.933 4.61 25
Chlorobenzene ND 2.50 1.00 0 95.2 33.7 159 0 0 25
Chloroform 1.01 0.250 1.00 0 101 48.5 145 0.986 2.21 25
Tetrachloroethene 0.867 0.250 1.00 0 86.7 19.2 191 0.880 1.49 25
Trichloroethene 0.912 0.250 1.00 0 91.2 38.4 167 0.897 1.60 25
Vinyl chloride 1.40 0.100 1.00 0 140 27.3 161 1.31 6.05 25 QC+
Surr:4-Bromofluorobenzene 2470 2500 98.9 91.7 109 0 25
Surr: Dibromofluoromethane 2500 2500 99.8 75.5 118 0 25
Surr:Toluene-d8 2560 2500 102 94.1 105 0 25
Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal}
J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound
ND Not Detected P Second column confirmation exceeds PL Permit Limit Original
R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted reco
Page 14 of 36

MM Summit Environmental Technologies,Inc. QC SUMMARY REPORT
III rg 5 U IT 331 Ohio Win St.
ENVIRONMENTAL rmy' 'LaboTtorfes LOi,I S,INC Cuyahoga Falls, 44223 WO#: 21010359
4na/yt�caf iaboralorfas TEL:[phone] FAX[phone]
Website:http://www.settek.com 25-Jan-21
Client: Synagro
Project: Farmville WWTP BatchlD: 47345
Sample ID: TCLP BLANK 1 1-16 SampType: MBLK TestCode: MtI-TCLP-7(6 Units: mg/L Prep Date: 1/18/2021 RunNo: 122637
Client ID: PBS Batch ID: 47345 TestNo: SW6010D SW3010A Analysis Date: 1/19/2021 SeqNo: 3161701
Analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual
TCLP Arsenic(As) ND 0.500
TCLP Barium(Ba) ND 5.00
TCLP Cadmium(Cd) ND 0.100
TCLP Chromium(Cr) ND 0.200
TCLP Lead(Pb) ND 0.500
TCLP Selenium(Se) ND 0.0500
TCLP Silver(Ag) ND 0.500
Sample ID: TCLP BLANK 2 1-16 SampType: MBLK TestCode: MtI-TCLP-7(6 Units: mg/L Prep Date: 1/18/2021 RunNo: 122637
Client ID: PBS Batch ID: 47345 TestNo: SW6010D SW3010A Analysis Date: 1/19/2021 SeqNo: 3161702
Analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual
TCLP Arsenic(As) ND 0.500
TCLP Barium(Ba) ND 5.00
TCLP Cadmium(Cd) ND 0.100
TCLP Chromium(Cr) ND 0.200
TCLP Lead(Pb) ND 0.500
TCLP Selenium(Se) ND 0.0500
TCLP Silver(Ag) ND 0.500
Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal}
J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound
ND Not Detected P Second column confirmation exceeds PL Permit Limit Original
R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted reco
Page 15 of 36

MM Summit Environmental Technologies,Inc. QC SUMMARY REPORT
III rg 5 U IT 331 Ohio Win St.
ENVIRONMENTAL rmy' 'LaboTtorfes LOi,I S,INC Cuyahoga Falls, 44223 WO#: 21010359
4na/yt�caf iaboralorfas TEL:[phone] FAX[phone]
Website:http://www.settek.com 25-Jan-21
Client: Synagro
Project: Farmville WWTP BatchlD: 47345
Sample ID: MB-47345 SampType: MBLK TestCode: MtI-TCLP-7(6 Units: mg/L Prep Date: 1/18/2021 RunNo: 122583
Client ID: PBS Batch ID: 47345 TestNo: SW6010D SW3010A Analysis Date: 1/18/2021 SegNo: 3160416
Analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual
TCLP Arsenic(As) ND 0.500
TCLP Barium(Ba) ND 5.00
TCLP Cadmium(Cd) ND 0.100
TCLP Chromium(Cr) ND 0.200
TCLP Lead(Pb) ND 0.500
TCLP Selenium(Se) ND 0.0500
TCLP Silver(Ag) ND 0.500
Sample ID: LCS-47345 SampType: LCS TestCode: MtI-TCLP-7(6 Units: mg/L Prep Date: 1/18/2021 RunNo: 122583
Client ID: LCSS Batch ID: 47345 TestNo: SW6010D SW3010A Analysis Date: 1/18/2021 SegNo: 3160417
Analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual
TCLP Arsenic(As) 1.77 0.500 2.000 0 88.4 80 120
TCLP Barium(Ba) ND 5.00 2.000 0 99.5 80 120
TCLP Cadmium(Cd) 1.95 0.100 2.000 0 97.4 80 120
TCLP Chromium(Cr) 2.02 0.200 2.000 0 101 80 120
TCLP Lead(Pb) 1.92 0.500 2.000 0 95.8 80 120
TCLP Selenium(Se) 1.98 0.0500 2.000 0 98.8 80 120
TCLP Silver(Ag) 2.02 0.500 2.000 0 101 80 120
Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal}
J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound
ND Not Detected P Second column confirmation exceeds PL Permit Limit Original
R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted reco
Page 16 of 36

MM Summit Environmental Technologies,Inc. QC SUMMARY REPORT
III rg 5 U IT 331 Ohio Win St.
ENVIRONMENTAL rmy' 'LaboTtorfes LOi,I S,INC Cuyahoga Falls, 44223 WO#: 21010359
4na/yt�caf iaboralorfas TEL:[phone] FAX[phone]
Website:http://www.settek.com 25-Jan-21
Client: Synagro
Project: Farmville WWTP BatchlD: 47345
Sample ID: 21010699-001AMS SampType: MS TestCode: MtI-TCLP-7(6 Units: mg/L Prep Date: 1/18/2021 RunNo: 122583
Client ID: BatchQC Batch ID: 47345 TestNo: SW6010D SW3010A Analysis Date: 1/18/2021 SeqNo: 3160422
Analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual
TCLP Arsenic(As) 1.84 0.500 2.000 0.002924 91.7 70 130
TCLP Barium(Ba) ND 5.00 2.000 0.1995 87.6 70 130
TCLP Cadmium(Cd) 1.85 0.100 2.000 0 92.5 70 130
TCLP Chromium(Cr) 1.82 0.200 2.000 0 91.2 70 130
TCLP Lead(Pb) 1.64 0.500 2.000 0 82.0 70 130
TCLP Selenium(Se) 2.21 0.0500 2.000 0.01535 110 70 130
TCLP Silver(Ag) 2.00 0.500 2.000 0 100 70 130
Sample ID: 21010699-001AMSD SampType: MSD TestCode: MtI-TCLP-7(6 Units: mg/L Prep Date: 1/18/2021 RunNo: 122583
Client ID: BatchQC Batch ID: 47345 TestNo: SW6010D SW3010A Analysis Date: 1/18/2021 SeqNo: 3160423
Analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual
TCLP Arsenic(As) 1.76 0.500 2.000 0.002924 88.1 70 130 1.837 4.02 20
TCLP Barium(Ba) ND 5.00 2.000 0.1995 83.2 70 130 0 0 20
TCLP Cadmium(Cd) 1.78 0.100 2.000 0 88.8 70 130 1.850 4.09 20
TCLP Chromium(Cr) 1.75 0.200 2.000 0 87.3 70 130 1.823 4.35 20
TCLP Lead(Pb) 1.59 0.500 2.000 0 79.4 70 130 1.639 3.17 20
TCLP Selenium(Se) 2.14 0.0500 2.000 0.01535 106 70 130 2.207 2.91 20
TCLP Silver(Ag) 1.91 0.500 2.000 0 95.6 70 130 2.002 4.62 20
Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal}
J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound
ND Not Detected P Second column confirmation exceeds PL Permit Limit Original
R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted reco
Page 17 of 36

MM Summit Environmental Technologies,Inc. QC SUMMARY REPORT
III rg 5 U IT 331 Ohio Win St.
ENVIRONMENTAL rmy' 'LaboTtorfes LOi,I S,INC Cuyahoga Falls, 44223 WO#: 21010359
4na/yt�caf iaboralorfas TEL:[phone] FAX[phone]
Website:http://www.settek.com 25-Jan-21
Client: Synagro
Project: Farmville WWTP BatchlD: 47346
Sample ID: 21010399-001AMS SampType: MS TestCode: SVOC-BNA T Units: mg/L Prep Date: 1/18/2021 RunNo: 122610
Client ID: BatchQC Batch ID: 47346 TestNo: SW8270 SW3510C Analysis Date: 1/18/2021 SegNo: 3161396
Analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual
1,4-Dichlorobenzene 0.624 0.200 0.8000 0 78.0 15.2 124
2,4,5-Trichlorophenol 0.864 0.500 0.8000 0 108 30.6 152
2,4,6-Trichlorophenol 0.833 0.500 0.8000 0 104 27.6 150
2,4-Dinitrotoluene 0.920 0.100 0.8000 0 115 58 141
o-Cresol 0.802 0.500 0.8000 0 100 26.9 132
Hexachloro-1,3-butadiene 0.651 0.0400 0.8000 0 81.4 10 156
Hexachlorobenzene 0.740 0.100 0.8000 0 92.5 54.3 142
Hexachloroethane 0.612 0.200 0.8000 0 76.5 1.92 131
Nitrobenzene 0.762 0.200 0.8000 0 95.2 21 135
Pentachlorophenol 0.876 0.500 0.8000 0 110 47.4 134
Pyridine ND 0.500 0.8000 0 26.8 10 130
Surr:2-Fluorophenol 0.859 1.000 85.9 9.77 146
Surr: Phenol-d6 0.962 1.000 96.2 20.7 130
Surr: Nitrobenzene-d5 0.869 1.000 86.9 13.9 156
Surr:2,4,6-Tribromophenol 1.25 1.000 125 27.3 183
Surr:2-Fluorobiphenyl 0.743 1.000 74.3 21.4 153
Surr: p-Terphenyl-d14 1.14 1.000 114 54.8 154
Sample ID: 21010399-001AMSD SampType: MSD TestCode: SVOC-BNA T Units: mg/L Prep Date: 1/18/2021 RunNo: 122610
Client ID: BatchQC Batch ID: 47346 TestNo: SW8270 SW3510C Analysis Date: 1/18/2021 SegNo: 3161397
Analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual
Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal}
J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound
ND Not Detected P Second column confirmation exceeds PL Permit Limit Original
R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted reco
Page 18 of 36

MM Summit Environmental Technologies,Inc. QC SUMMARY REPORT
III rg 5 U IT 331 Ohio Win St.
ENVIRONMENTAL rmy' 'LaboTtorfes LOi,I S,INC Cuyahoga Falls, 44223 WO#: 21010359
4na/yt�caf iaboralorfas TEL:[phone] FAX[phone]
Website:http://www.settek.com 25-Jan-21
Client: Synagro
Project: Farmville WWTP BatchlD: 47346
Sample ID: 21010399-001AMSD SampType: MSD TestCode: SVOC-BNA T Units: mg/L Prep Date: 1/18/2021 RunNo: 122610
Client ID: BatchQC Batch ID: 47346 TestNo: SW8270 SW3510C Analysis Date: 1/18/2021 SegNo: 3161397
Analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual
1,4-Dichlorobenzene 0.680 0.200 0.8000 0 85.0 15.2 124 0.6236 8.59 30
2,4,5-Trichlorophenol 0.908 0.500 0.8000 0 114 30.6 152 0.8640 4.97 30
2,4,6-Trichlorophenol 0.873 0.500 0.8000 0 109 27.6 150 0.8332 4.64 30
2,4-Dinitrotoluene 1.01 0.100 0.8000 0 126 58 141 0.9200 9.48 30
o-Cresol 0.854 0.500 0.8000 0 107 26.9 132 0.8020 6.33 30
Hexachloro-1,3-butadiene 0.678 0.0400 0.8000 0 84.8 10 156 0.6512 4.09 30
Hexachlorobenzene 0.779 0.100 0.8000 0 97.4 54.3 142 0.7396 5.21 30
Hexachloroethane 0.679 0.200 0.8000 0 84.8 1.92 131 0.6116 10.4 30
Nitrobenzene 0.844 0.200 0.8000 0 106 21 135 0.7616 10.3 30
Pentachlorophenol 0.924 0.500 0.8000 0 116 47.4 134 0.8760 5.33 30
Pyridine ND 0.500 0.8000 0 26.5 10 130 0 0 30
Surr:2-Fluorophenol 0.946 1.000 94.6 9.77 146 0
Surr: Phenol-d6 0.966 1.000 96.6 20.7 130 0
Surr: Nitrobenzene-d5 0.937 1.000 93.7 13.9 156 0
Surr:2,4,6-Tribromophenol 1.38 1.000 138 27.3 183 0
Surr:2-Fluorobiphenyl 0.767 1.000 76.7 21.4 153 0
Surr: p-Terphenyl-d14 1.21 1.000 121 54.8 154 0
Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal}
J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound
ND Not Detected P Second column confirmation exceeds PL Permit Limit Original
R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted reco
Page 19 of 36

MM Summit Environmental Technologies,Inc. QC SUMMARY REPORT
III rg 5 U IT 331 Ohio Win St.
ENVIRONMENTAL rmy' 'LaboTtorfes LOi,I S,INC Cuyahoga Falls, 44223 WO#: 21010359
4na/yt�caf iaboralorfas TEL:[phone] FAX[phone]
Website:http://www.settek.com 25-Jan-21
Client: Synagro
Project: Farmville WWTP BatchlD: 47346
Sample ID: 21010399-001AMS SampType: MS TestCode: SVOC-BNA T Units: mg/L Prep Date: 1/18/2021 RunNo: 122695
Client ID: BatchQC Batch ID: 47346 TestNo: SW8270 SW3510C Analysis Date: 1/19/2021 SegNo: 3165442
Analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual
Cresols,Total ND 50.0 1.600 0 347 10 148 S
Sample ID: 21010399-001AMSD SampType: MSD TestCode: SVOC-BNA T Units: mg/L Prep Date: 1/18/2021 RunNo: 122695
Client ID: BatchQC Batch ID: 47346 TestNo: SW8270 SW3510C Analysis Date: 1/19/2021 SegNo: 3165443
Analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual
Cresols,Total ND 50.0 1.600 0 330 10 148 0 0 30 S
Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal}
J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound
ND Not Detected P Second column confirmation exceeds PL Permit Limit Original
R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted reco
Page 20 of 36

MM Summit Environmental Technologies,Inc. QC SUMMARY REPORT
III rg 5 U IT 331 Ohio Win St.
ENVIRONMENTAL rmy' 'LaboTtorfes LOi,I S,INC Cuyahoga Falls, 44223 WO#: 21010359
4na/yt�caf iaboralorfas TEL:[phone] FAX[phone]
Website:http://www.settek.com 25-Jan-21
Client: Synagro
Project: Farmville WWTP BatchlD: 47346
Sample ID: MB-47346 SampType: MBLK TestCode: SVOC-BNA T Units: mg/L Prep Date: 1/18/2021 RunNo: 122610
Client ID: PBS Batch ID: 47346 TestNo: SW8270 SW3510C Analysis Date: 1/18/2021 SegNo: 3160440
Analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual
1,4-Dichlorobenzene ND 0.100
2,4,5-Trichlorophenol ND 0.250
2,4,6-Trichlorophenol ND 0.250
2,4-Dinitrotoluene ND 0.0500
o-Cresol ND 0.250
Cresols,Total ND 5.00
Hexachloro-1,3-butadiene ND 0.0200
Hexachlorobenzene ND 0.0500
Hexachloroethane ND 0.100
Nitrobenzene ND 0.100
Pentachlorophenol ND 0.250
Pyridine ND 0.250
Surr:2-Fluorophenol 0.875 1.000 87.5 10 130
Surr: Phenol-d6 0.931 1.000 93.1 10 130
Surr: Nitrobenzene-d5 0.898 1.000 89.8 19 130
Surr:2,4,6-Tribromophenol 1.09 1.000 109 10 130
Surr:2-Fluorobiphenyl 0.771 1.000 77.1 22 130
Surr: p-Terphenyl-d14 1.10 1.000 110 34 130
Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal}
J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound
ND Not Detected P Second column confirmation exceeds PL Permit Limit Original
R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted reco
Page 21 of 36

MM Summit Environmental Technologies,Inc. QC SUMMARY REPORT
III rg 5 U IT 331 Ohio Win St.
ENVIRONMENTAL rmy' 'LaboTtorfes LOi,I S,INC Cuyahoga Falls, 44223 WO#: 21010359
4na/yt�caf iaboralorfas TEL:[phone] FAX[phone]
Website:http://www.settek.com 25-Jan-21
Client: Synagro
Project: Farmville WWTP BatchlD: 47346
Sample ID: LCS-47346 SampType: LCS TestCode: SVOC-BNA T Units: mg/L Prep Date: 1/18/2021 RunNo: 122610
Client ID: LCSS Batch ID: 47346 TestNo: SW8270 SW3510C Analysis Date: 1/18/2021 SegNo: 3160441
Analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual
1,4-Dichlorobenzene 0.640 0.100 0.8000 0 80.0 36.4 130
2,4,5-Trichlorophenol 0.982 0.250 0.8000 0 123 31.7 132
2,4,6-Trichlorophenol 0.942 0.250 0.8000 0 118 31.1 133
2,4-Dinitrotoluene 0.997 0.0500 0.8000 0 125 43.3 130
o-Cresol 0.838 0.250 0.8000 0 105 32.9 130
Cresols,Total ND 5.00 1.600 0 107 31.7 130
Hexachloro-1,3-butadiene 0.656 0.0200 0.8000 0 82.0 31.4 130
Hexachlorobenzene 0.778 0.0500 0.8000 0 97.3 43.1 130
Hexachloroethane 0.645 0.100 0.8000 0 80.6 36.5 130
Nitrobenzene 0.828 0.100 0.8000 0 103 39.5 130
Pentachlorophenol 0.902 0.250 0.8000 0 113 34 130
Pyridine 0.319 0.250 0.8000 0 39.9 10 130
Surr:2-Fluorophenol 0.965 1.000 96.5 17.1 130
Surr: Phenol-d6 1.06 1.000 106 10 130
Surr: Nitrobenzene-d5 0.923 1.000 92.3 32.6 130
Surr:2,4,6-Tribromophenol 1.39 1.000 139 4.43 130 S
Surr:2-Fluorobiphenyl 0.768 1.000 76.8 41.8 130
Surr: p-Terphenyl-d14 1.21 1.000 121 36.4 130
Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal}
J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound
ND Not Detected P Second column confirmation exceeds PL Permit Limit Original
R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted reco
Page 22 of 36

MM Summit Environmental Technologies,Inc. QC SUMMARY REPORT
III rg 5 U IT 331 Ohio Win St.
ENVIRONMENTAL rmy' 'LaboTtorfes LOi,I S,INC Cuyahoga Falls, 44223 WO#: 21010359
4na/yt�caf iaboralorfas TEL:[phone] FAX[phone]
Website:http://www.settek.com 25-Jan-21
Client: Synagro
Project: Farmville WWTP BatchlD: 47347
Sample ID: 21010359-001ams SampType: MS TestCode: TCLP-SVOC- Units: mg/L Prep Date: 1/18/2021 RunNo: 122687
Client ID: Farmville WWTP Batch ID: 47347 TestNo: SW8081 SW3510C Analysis Date: 1/19/2021 SegNo: 3165893
Analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual
Endrin 0.00751 0.000500 0.0100 0 75.1 10 224 m
gamma-BHC 0.00798 0.000500 0.0100 0 79.8 10 192
Heptachlor 0.00971 0.000500 0.0100 0 97.1 10 197 QC+
Heptachlor epoxide 0.00868 0.000500 0.0100 0 86.8 10 208
Methoxychlor 0.0115 0.000500 0.0100 0 115 10 251 QC+
Surr:TCMX 13.1 20.00 65.5 10 157
Surr: DCB 16.1 20.00 80.4 10 194
Sample ID: 21010359-001amsd SampType: MSD TestCode: TCLP-SVOC- Units: mg/L Prep Date: 1/18/2021 RunNo: 122687
Client ID: Farmville WWTP Batch ID: 47347 TestNo: SW8081 SW3510C Analysis Date: 1/19/2021 SegNo: 3165894
Analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual
Endrin 0.00968 0.000500 0.0100 0 96.8 10 224 0.00751 25.3 30 m
gamma-BHC 0.00837 0.000500 0.0100 0 83.7 10 192 0.00798 4.77 30
Heptachlor 0.0102 0.000500 0.0100 0 102 10 197 0.00971 4.72 30 QC+
Heptachlor epoxide 0.00929 0.000500 0.0100 0 92.9 10 208 0.00868 6.81 30
Methoxychlor 0.0124 0.000500 0.0100 0 124 10 251 0.0115 7.18 30 QC+
Surr:TCMX 14.2 20.00 71.2 10 157 0
Surr: DCB 17.4 20.00 86.8 10 194 0
Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal}
J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound
ND Not Detected P Second column confirmation exceeds PL Permit Limit Original
R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted reco
Page 23 of 36

MM Summit Environmental Technologies,Inc. QC SUMMARY REPORT
III rg 5 U IT 331 Ohio Win St.
ENVIRONMENTAL rmy' 'LaboTtorfes LOi,I S,INC Cuyahoga Falls, 44223 WO#: 21010359
4na/yt�caf iaboralorfas TEL:[phone] FAX[phone]
Website:http://www.settek.com 25-Jan-21
Client: Synagro
Project: Farmville WWTP BatchlD: 47347
Sample ID: LCS-47347 SampType: LCS TestCode: TCLP-SVOC- Units: mg/L Prep Date: 1/18/2021 RunNo: 122687
Client ID: LCSS Batch ID: 47347 TestNo: SW8081 SW3510C Analysis Date: 1/19/2021 SegNo: 3165906
Analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual
Endrin 0.00711 0.000500 0.0100 0 71.1 10 130 m
gamma-BHC 0.00808 0.000500 0.0100 0 80.8 10 130
Heptachlor 0.00983 0.000500 0.0100 0 98.3 10 130 QC+
Heptachlor epoxide 0.00867 0.000500 0.0100 0 86.7 10 130
Methoxychlor 0.0111 0.000500 0.0100 0 111 10 178 QC+
Surr:TCMX 13.4 20.00 66.8 10 130
Surr: DCB 16.6 20.00 82.9 10 130
Sample ID: MB-47347 SampType: MBLK TestCode: TCLP-SVOC- Units: mg/L Prep Date: 1/18/2021 RunNo: 122687
Client ID: PBS Batch ID: 47347 TestNo: SW8081 SW3510C Analysis Date: 1/19/2021 SegNo: 3165908
Analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual
Chlordane,total ND 0.00250
Toxaphene ND 0.00500
Endrin ND 0.000500
gamma-BHC ND 0.000500
Heptachlor ND 0.000500 QC+
Heptachlor epoxide ND 0.000500
Methoxychlor ND 0.000500 QC+
Surr:TCMX 13.1 20.00 65.4 10 119
Surr: DCB 16.5 20.00 82.6 10 119
Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal}
J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound
ND Not Detected P Second column confirmation exceeds PL Permit Limit Original
R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted reco
Page 24 of 36

MM Summit Environmental Technologies,Inc. QC SUMMARY REPORT
III rg 5 U IT 331 Ohio Win St.
ENVIRONMENTAL rmy' 'LaboTtorfes LOi,I S,INC Cuyahoga Falls, 44223 WO#: 21010359
4na/yt�caf iaboralorfas TEL:[phone] FAX[phone]
Website:http://www.settek.com 25-Jan-21
Client: Synagro
Project: Farmville WWTP BatchlD: 47349
Sample ID: MB-47349 SampType: MBLK TestCode: HG_TCLP(74 Units: PPM Prep Date: 1/18/2021 RunNo: 122631
Client ID: PBS Batch ID: 47349 TestNo: SW7470A SW7470A Analysis Date: 1/19/2021 SegNo: 3161072
Analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual
TCLP Mercury ND 0.00200
Sample ID: LCS-47349 SampType: LCS TestCode: HG_TCLP(74 Units: PPM Prep Date: 1/18/2021 RunNo: 122631
Client ID: LCSS Batch ID: 47349 TestNo: SW7470A SW7470A Analysis Date: 1/19/2021 SegNo: 3161073
Analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual
TCLP Mercury 0.00363 0.00200 0.00400 0 90.8 80 120
Sample ID: LCSD-47349 SampType: LCSD TestCode: HG_TCLP(74 Units: PPM Prep Date: 1/18/2021 RunNo: 122631
Client ID: LCSSO2 Batch ID: 47349 TestNo: SW7470A SW7470A Analysis Date: 1/19/2021 SegNo: 3161074
Analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual
TCLP Mercury 0.00359 0.00200 0.00400 0 89.8 80 120 0.00363 1.11 20
Sample ID: MB2-47349 SampType: MBLK TestCode: HG_TCLP(74 Units: PPM Prep Date: 1/18/2021 RunNo: 122631
Client ID: PBS Batch ID: 47349 TestNo: SW7470A SW7470A Analysis Date: 1/19/2021 SegNo: 3161090
Analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual
TCLP Mercury ND 0.00200
Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal)
J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound
ND Not Detected P Second column confirmation exceeds PL Permit Limit Original
R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted reco
Page 25 of 36

MM Summit Environmental Technologies,Inc. QC SUMMARY REPORT
III rg 5 U IT 331 Ohio Win St.
ENVIRONMENTAL rmy' 'LaboTtorfes LOi,I S,INC Cuyahoga Falls, 44223 WO#: 21010359
4na/yt�caf iaboralorfas TEL:[phone] FAX[phone]
Website:http://www.settek.com 25-Jan-21
Client: Synagro
Project: Farmville WWTP BatchlD: 47349
Sample ID: MB2-47349 SampType: MBLK TestCode: HG_TCLP(74 Units: PPM Prep Date: 1/18/2021 RunNo: 122631
Client ID: PBS Batch ID: 47349 TestNo: SW7470A SW7470A Analysis Date: 1/19/2021 SegNo: 3161090
Analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual
Sample ID: MB3-47349 SampType: MBLK TestCode: HG_TCLP(74 Units: PPM Prep Date: 1/18/2021 RunNo: 122631
Client ID: PBS Batch ID: 47349 TestNo: SW7470A SW7470A Analysis Date: 1/19/2021 SegNo: 3161093
Analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual
TCLP Mercury ND 0.00200
Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal)
J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound
ND Not Detected P Second column confirmation exceeds PL Permit Limit Original
R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted reco
Page 26 of 36

MM Summit Environmental Technologies,Inc. QC SUMMARY REPORT
III rg 5 U IT 331 Ohio Win St.
ENVIRONMENTAL rmy' 'LaboTtorfes LOi,I S,INC Cuyahoga Falls, 44223 WO#: 21010359
4na/yt�caf iaboralorfas TEL:[phone] FAX[phone]
Website:http://www.settek.com 25-Jan-21
Client: Synagro
Project: Farmville WWTP BatchlD: R122408
Sample ID: LCS-R122408 SampType: LCS TestCode: Ignitability_S Units: mm/sec Prep Date: RunNo: 122408
Client ID: LCSS Batch ID: R122408 TestNo: SW1030 Analysis Date: 1/13/2021 SegNo: 3152374
Analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual
Ignitability 6.87 7.240 0 94.9 70 130
Sample ID: 21010307-001ADUP SampType: DUP TestCode: Ignitability_S Units: mm/sec Prep Date: RunNo: 122408
Client ID: BatchQC Batch ID: R122408 TestNo: SW1030 Analysis Date: 1/13/2021 SegNo: 3152376
Analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual
Ignitability <2.2 0 0 20
Sample ID: 21010307-002ADUP SampType: DUP TestCode: Ignitability_S Units: mm/sec Prep Date: RunNo: 122408
Client ID: BatchQC Batch ID: R122408 TestNo: SW1030 Analysis Date: 1/13/2021 SegNo: 3152379
Analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual
Ignitability <2.2 0 0 20
Sample ID: 21010307-003ADUP SampType: DUP TestCode: Ignitability_S Units: mm/sec Prep Date: RunNo: 122408
Client ID: BatchQC Batch ID: R122408 TestNo: SW1030 Analysis Date: 1/13/2021 SegNo: 3152382
Analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual
Ignitability nonflammable 0 0 20
Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal}
J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound
ND Not Detected P Second column confirmation exceeds PL Permit Limit Original
R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted reco
Page 27 of 36

MM Summit Environmental Technologies,Inc. QC SUMMARY REPORT
III rg 5 U IT 331 Ohio Win St.
ENVIRONMENTAL rmy' 'LaboTtorfes LOi,I S,INC Cuyahoga Falls, 44223 WO#: 21010359
4na/yt�caf iaboralorfas TEL:[phone] FAX[phone]
Website:http://www.settek.com 25-Jan-21
Client: Synagro
Project: Farmville WWTP BatchlD: R122408
Sample ID: 21010307-003ADUP SampType: DUP TestCode: Ignitability_S Units: mm/sec Prep Date: RunNo: 122408
Client ID: BatchQC Batch ID: R122408 TestNo: SW1030 Analysis Date: 1/13/2021 SegNo: 3152382
Analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual
Sample ID: 21010307-004ADUP SampType: DUP TestCode: Ignitability_S Units: mm/sec Prep Date: RunNo: 122408
Client ID: BatchQC Batch ID: R122408 TestNo: SW1030 Analysis Date: 1/13/2021 SegNo: 3152384
Analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual
Ignitability nonflammable 0 0 20
Sample ID: 21010307-005ADUP SampType: DUP TestCode: Ignitability_S Units: mm/sec Prep Date: RunNo: 122408
Client ID: BatchQC Batch ID: R122408 TestNo: SW1030 Analysis Date: 1/13/2021 SegNo: 3152386
Analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual
Ignitability nonflammable 0 0 20
Sample ID: 21010307-006ADUP SampType: DUP TestCode: Ignitability_S Units: mm/sec Prep Date: RunNo: 122408
Client ID: BatchQC Batch ID: R122408 TestNo: SW1030 Analysis Date: 1/13/2021 SegNo: 3152388
Analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual
Ignitability <2.2 0 0 20
Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal}
J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound
ND Not Detected P Second column confirmation exceeds PL Permit Limit Original
R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted reco
Page 28 of 36

MM Summit Environmental Technologies,Inc. QC SUMMARY REPORT
III rg 5 U IT 331 Ohio Win St.
ENVIRONMENTAL rmy' 'LaboTtorfes LOi,I S,INC Cuyahoga Falls, 44223 WO#: 21010359
4na/yt�caf iaboralorfas TEL:[phone] FAX[phone]
Website:http://www.settek.com 25-Jan-21
Client: Synagro
Project: Farmville WWTP BatchlD: R122408
Sample ID: 21010307-008ADUP SampType: DUP TestCode: Ignitability_S Units: mm/sec Prep Date: RunNo: 122408
Client ID: BatchQC Batch ID: R122408 TestNo: SW1030 Analysis Date: 1/13/2021 SegNo: 3152394
Analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual
Ignitability <2.2 0 0 20
Sample ID: 21010307-009ADUP SampType: DUP TestCode: Ignitability_S Units: mm/sec Prep Date: RunNo: 122408
Client ID: BatchQC Batch ID: R122408 TestNo: SW1030 Analysis Date: 1/13/2021 SegNo: 3152397
Analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual
Ignitability <2.2 0 0 20
Sample ID: 21010307-010ADUP SampType: DUP TestCode: Ignitability_S Units: mm/sec Prep Date: RunNo: 122408
Client ID: BatchQC Batch ID: R122408 TestNo: SW1030 Analysis Date: 1/13/2021 SegNo: 3152400
Analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual
Ignitability <2.2 0 0 20
Sample ID: 21010192-001ADUP SampType: DUP TestCode: Ignitability_S Units: mm/sec Prep Date: RunNo: 122408
Client ID: BatchQC Batch ID: R122408 TestNo: SW1030 Analysis Date: 1/13/2021 SegNo: 3152403
Analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual
Ignitability nonflammable 0 0 20
Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal}
J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound
ND Not Detected P Second column confirmation exceeds PL Permit Limit Original
R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted reco
Page 29 of 36

MM Summit Environmental Technologies,Inc. QC SUMMARY REPORT
III rg 5 U IT 331 Ohio Win St.
ENVIRONMENTAL rmy' 'LaboTtorfes LOi,I S,INC Cuyahoga Falls, 44223 WO#: 21010359
4na/yt�caf iaboralorfas TEL:[phone] FAX[phone]
Website:http://www.settek.com 25-Jan-21
Client: Synagro
Project: Farmville WWTP BatchlD: R122408
Sample ID: 21010192-001ADUP SampType: DUP TestCode: Ignitability_S Units: mm/sec Prep Date: RunNo: 122408
Client ID: BatchQC Batch ID: R122408 TestNo: SW1030 Analysis Date: 1/13/2021 SegNo: 3152403
Analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual
Sample ID: 21010278-001ADUP SampType: DUP TestCode: Ignitability_S Units: mm/sec Prep Date: RunNo: 122408
Client ID: BatchQC Batch ID: R122408 TestNo: SW1030 Analysis Date: 1/13/2021 SegNo: 3152405
Analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual
Ignitability nonflammable 0 0 20
Sample ID: 21010279-001ADUP SampType: DUP TestCode: Ignitability_S Units: mm/sec Prep Date: RunNo: 122408
Client ID: BatchQC Batch ID: R122408 TestNo: SW1030 Analysis Date: 1/13/2021 SegNo: 3152407
Analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual
Ignitability nonflammable 0 0 20
Sample ID: 21010280-001ADUP SampType: DUP TestCode: Ignitability_S Units: mm/sec Prep Date: RunNo: 122408
Client ID: BatchQC Batch ID: R122408 TestNo: SW1030 Analysis Date: 1/13/2021 SegNo: 3152409
Analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual
Ignitability nonflammable 0 0 20
Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal}
J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound
ND Not Detected P Second column confirmation exceeds PL Permit Limit Original
R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted reco
Page 30 of 36

MM Summit Environmental Technologies,Inc. QC SUMMARY REPORT
III rg 5 U IT 331 Ohio Win St.
ENVIRONMENTAL rmy' 'LaboTtorfes LOi,I S,INC Cuyahoga Falls, 44223 WO#: 21010359
4na/yt�caf iaboralorfas TEL:[phone] FAX[phone]
Website:http://www.settek.com 25-Jan-21
Client: Synagro
Project: Farmville WWTP BatchlD: R122408
Sample ID: 21010359-001ADUP SampType: DUP TestCode: Ignitability_S Units: mm/sec Prep Date: RunNo: 122408
Client ID: Farmville WWTP Batch ID: R122408 TestNo: SW1030 Analysis Date: 1/13/2021 SegNo: 3152411
Analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual
Ignitability nonflammable 0 0 20
Sample ID: 21010360-001ADUP SampType: DUP TestCode: Ignitability_S Units: mm/sec Prep Date: RunNo: 122408
Client ID: BatchQC Batch ID: R122408 TestNo: SW1030 Analysis Date: 1/13/2021 SegNo: 3152413
Analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual
Ignitability nonflammable 0 0 20
Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal}
J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound
ND Not Detected P Second column confirmation exceeds PL Permit Limit Original
R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted reco
Page 31 of 36

MM Summit Environmental Technologies,Inc. QC SUMMARY REPORT
inIrg 5 U IT 331 Ohio Win St.
ENVIRONMENTAL rmy' 'LaboTtorfes LOi,I S,INC Cuyahoga Falls, 44223 WO#: 21010359
4na/yt�caf iaboralorfas TEL:[phone] FAX[phone]
Website:http://www.settek.com 25-Jan-21
Client: Synagro
Project: Farmville WWTP BatchlD: R122413
Sample ID: 21010545-001ADUP SampType: DUP TestCode: pH_Oil(9045D Units: s.u.@20.0C Prep Date: RunNo: 122413
Client ID: BatchQC Batch ID: R122413 TestNo: SW9045D Analysis Date: 1/13/2021 SegNo: 3153357
Analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual
pH 6.6 0 0 6.7 0.3 10
Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal)
J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound
ND Not Detected P Second column confirmation exceeds PL Permit Limit Original
R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted reco
Page 32 of 36

MM Summit Environmental Technologies,Inc. QC SUMMARY REPORT
III rg 5 U IT 331 Ohio Win St.
ENVIRONMENTAL rmy' 'LaboTtorfes LOi,I S,INC Cuyahoga Falls, 44223 WO#: 21010359
4na/yt�caf iaboralorfas TEL:[phone] FAX[phone]
Website:http://www.settek.com 25-Jan-21
Client: Synagro
Project: Farmville WWTP BatchlD: R122413
Sample ID: LCS-R122413 SampType: LCS TestCode: pH_NPW(450 Units: s.u.@20.2C Prep Date: RunNo: 122413
Client ID: LCSW Batch ID: R122413 TestNo: SW9045D Analysis Date: 1/13/2021 SegNo: 3153317
Analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual
pH 7.0 7.0 0 101 98.6 101.4
Sample ID: CHECK 7 SampType: LCS TestCode: pH_NPW(450 Units: s.u.@20.3C Prep Date: RunNo: 122413
Client ID: LCSW Batch ID: R122413 TestNo: SW9045D Analysis Date: 1/13/2021 SegNo: 3153801
Analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual
pH 7.0 7.0 0 100 98.6 101.4
Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal)
J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound
ND Not Detected P Second column confirmation exceeds PL Permit Limit Original
R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted reco
Page 33 of 36

MM Summit Environmental Technologies,Inc. QC SUMMARY REPORT
III rg 5 U IT 331 Ohio Win St.
ENVIRONMENTAL rmy' 'LaboTtorfes LOi,I S,INC Cuyahoga Falls, 44223 WO#: 21010359
4na/yt�caf iaboralorfas TEL:[phone] FAX[phone]
Website:http://www.settek.com 25-Jan-21
Client: Synagro
Project: Farmville WWTP BatchlD: R122714
Sample ID: 21010278-001AMS SampType: MS TestCode: TCLP-SVOC- Units: %Rec Prep Date: RunNo: 122714
Client ID: BatchQC Batch ID: R122714 TestNo: SW8321 Analysis Date: 1/18/2021 SegNo: 3166169
Analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual
Surr:2,4-Dichlorophenylacetic acid 162 150.0 108 70 130
Sample ID: 21010278-001AMSD SampType: MSD TestCode: TCLP-SVOC- Units: %Rec Prep Date: RunNo: 122714
Client ID: BatchQC Batch ID: R122714 TestNo: SW8321 Analysis Date: 1/18/2021 SegNo: 3166170
Analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual
Surr:2,4-Dichlorophenylacetic acid 164 150.0 109 70 130 0 0
Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal}
J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound
ND Not Detected P Second column confirmation exceeds PL Permit Limit Original
R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted reco
Page 34 of 36

:..:'0: Summit Environmental Technologies,Inc.
'^"� 3310 Win Street •analysis Request/Chain of Custody
il.+� Cuyahoga •
Falls,Ohio 44223 Tel: [phone] Fax: [phone] For Summit Environmental•ihchnologies,Inc.use only
— Page of SET Nor 1 J I
Company Name (Please Prim) Project Name 7 l Analytical Parameters and Methods
w ui-rnv;I ig lniw
____,____^
Company Address Project Address I I
f
Client Phone No. 5.3(ogoq 8.62 77 Report to '� I U
'Client Pax Isla. use Fax Results,. 0 po#
CA
Client Email Quote Na ,:a g T CLiyv, tn�5 RViii .t . k r .: ,
Contact Person tC j - ,_ r o
Sampled h7 + + I Cheek if VAI apesI [ 1 'a j ' pi�ltwf 1i[, I
Er ie � 1 V q�
Sample Identification Datepime ' f . ("
I Collectedlett,ed.i t5 { x z r _ ,
' I — - Pea,eacenkMAlytew Bea
FA.rYri v i 11,t WWI'? i/7[i! 1 G x L 4 c _t ,sc 1C X '
1 1
•
f
•
. _ .17
- - - - , - .
��++Relingt s{hed t y: to Thine UPS
by: Date L Time Notes/Comments: NC
C $ 5 irk K(.d i f 1.04 UC S • a:fleurSmirkUris;.1_
rr I'D:t cum Rl_IA-^14.1'_ Y• !!
[l.'iCi-IT•'iC'hilOi1I EQ ER NO
eq.EPorr'i o S i ATL•(ow ONLY ES nio
'---- qQ/f(-- I I I[1%6,plea�cr'rwa.&TU,RMP
C0 eli� -1 ,_ J ¢2021 e y Mast be
managerraved �,1 t "if i ...4 n vrI l kIr'1..a-:uwuia rl�nrc ie. •irrh:s te,[
LJl S{II!! 111 hRequested
B hate h}'I ` '�L� �f� V� ( •aiavrw,.r�nV„�,aro.•r•.x
W 'e ," White and yellow pages should accompany samples is the laboratory.TM client retains the pink page. 1 ty•I 4 1 4
cn ,..- �� L1 L
o - Page1 of
CO
rn

itraSUMMIT
Summit Environmental Technologies,Inc.
3310 Win St.
Arm' OtJMENtAL tiriNOL4Ga S.lFr Cuyahoga Falls, Ohio 44223 Sample Log-In Check List
�1rrafyt�caf iabora�orJas TEL:[phone] FAX. [phone]
Website:http://wm-w.settek.com
Client Name: SYN-NC-27028 Work Order Number: 21010359 RcptNo: 1
Logged by: Jesseca E.Westfall 1/8/2021 10:25:00 AM
Completed By: Jacqueline Rasile 1/10/2021 10:38:15 AM
Reviewed By: Sara E. Kidd 1/11/2021 1:23:52 PM dILA IG
Chain of Custody
1. Is Chain of Custody complete? Yes ❑d No ❑ Not Present ❑
2. How was the sample delivered? UPS
Lop In
3. Coolers are present? Yes ❑d No ❑ NA ❑
4. Shipping container/cooler in good condition? Yes d❑ No ❑
Custody seals intact on shipping container/cooler? Yes ❑ No ❑ Not Present V
No. Seal Date: Signed By:
5. Was an attempt made to cool the samples? Yes ❑d No ❑ NA ❑
6. Were all samples received at a temperature of >0°C to 6.0°C Yes ❑d No ❑ NA ❑
7. Sample(s)in proper container(s)? Yes ❑d No ❑
8. Sufficient sample volume for indicated test(s)? Yes ❑d No ❑
g. Are samples(except VOA and ONG)properly preserved? Yes ❑d No ❑
10.Was preservative added to bottles? Yes ❑ No ❑d NA ❑
it Is the headspace in the VOA vials less than 1/4 inch or 6 mm? Yes ❑ No ❑ No VOA Vials V
12.Were any sample containers received broken? Yes ❑ No ❑d
13. Does paperwork match bottle labels? Yes ❑d No ❑
(Note discrepancies on chain of custody)
14.Are matrices correctly identified on Chain of Custody? Yes ❑d No ❑
15. Is it clear what analyses were requested? Yes ❑d No ❑
16. Were all holding times able to be met? Yes ❑d No ❑
(If no,notify customer for authorization.)
Special Handling(if applicable)
17. Was client notified of all discrepancies with this order? Yes ❑ No ❑ NA V
Person Notified: I Date:
By Whom: Via: ❑ eMail ❑ Phone ❑ Fax ❑ In Person
Regarding:
Client Instructions:
18.Additional remarks:
Cooler Information
Cooler No Temp°C Condition Seal Intact Seal No Seal Date Signed By
1 3.5 Good Not Present
Page 36 of 36

SECTION 5

it
ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM(02T Rules)
Facility Name: Town of Farmville WQ Permit Number: WQ0008778
WWTP Name: Town of Farmville WWTP,Digester Basin NPDES Number: NC0029572
Monitoring Period: From 01/01/21 To 12/31/21
Pathogen Reduction(40 CFR 503.32/15A NCAC 02T.1106)-Please indicate level achieved and alternative performed:
4
Class A:
Alt. 1/A(time/temp) Alt.2/B(Alk Treatment) Alt.3/C(Prior Testing)
Alt.4/D(No Prior Test) Alt.5/Process to Further Reduce Pathogens Alt.6(Equivalent to PFRP)
If applicable to alternative performed(Class A only)indicate"Process to Further Reduce Pathogens":
Compost Heat Drying Heat Treatment Thermophilic
Beta Ray Gamma Ray Pasteurization
Class B:
Alt.(1)Fecal Density X Alt.(2)Process to Significantly Reduce Pathogens
If applicable to alternative performed(Class B only)indicate"Process to Significantly Reduce Pathogens":
Lime Stabilization Air Drying Composting Aerobic Digestion ti
Anaerobic Digestion
If applicable to alternative performed(Class A or Class B)complete the following monitoring data:
Parameter Allowable Level in Sludge Pathogen Density No.of Frequency Sample Analytical
Excee- of Type Technique
Minimum Geo.Mean Maximum Units deuces Analysis
Fecal 2x10 to the 6'h MPN MPN/g
Coliform power per gram
of total solids
CFU <29400 29500 <29500 CFU/g 0 Annually Grab SM9222D
-MF
1000 MPN per gram of MPN/g r
total solids(dreight)
Salmonella 3 MPN per 4 grams total
bacteria(in solids(dry weight)
lieu of fecal
conform)
Vector Attraction Reduction(40 CFR 503.33/15A NCAC 02T.1107)-Please indicate option/alternative performed:
Option/Alt.1 Option/Alt.2 Option/Alt.3 Option/Alt.4
(VS reduction) (40-day bench) (30-day bench) X (Spec,02 uptake)
Option/Alt.5 Option/Alt.6 Option/Alt.7 Option/Alt.8
(14-Day Aerobic) (Alk Stabilization) (Drying—Stable) (Drying—Unstable)
Option/Alt.9 Option/Alt. 10
(Injection) (Incorporation) No vector attraction reduction alternatives were performed
,
CERTIFICATION STATEMENT(please check the appropriate statement)
"I certify,under penalty of law,that the pathogen requirements in 40 CFR 503.32/15A NCAC 02T.1106 and the vector attraction
X reduction requirement in 40 CFR 503.33/15A NCAC 02T.1107 have been met."
"I certify,under penalty of law,that the pathogen requirements in 40 CFR 503.32/15A NCAC 02T.1106 and the vector attraction
reduction requirement in 40 CFR 503.33/15A NCAC 02T.1107 have not been met."(Please note if you check this statement attach an
explanation why you have not met one or both of the requirements.) r'
"This determination has been made under my direction and supervision in accordance with the system designed to ensure that qualified
personnel properly gather and evaluate the information used to determine that the pathogen and vector attraction reduction requirements have
been met. I am aware that there are significant penalties for false certification including foe and imprisonment."
David Hodgkins,Town Manager
Preparer Name an Ti e(type or print) Land Applier Name and Title(if applicable)(type or print)
,,P
'tv
•
Signature of Prepay •* Date Signature of Land Applies(if applicable) Date
*Preparer is defined in 40 CFR Part 503.9(r)and 15A NCAC 2T.1102(26)

Cameron Testing Services, Inc. Laboratory Report NCOENR*554
NC PHHS 1L3T799
uS EPA 6-NC41918
Client; Synagro CIS Proj. 101-Q43 DWCer1*37799
Project: Farrnville WWTP Regu#atory Yes
Sample Information
•Sampled C. Wynne Date 011071 1 Received M. Sims sat% 01/07121
Analyses and Results
.57
2 #' h7 2 .. Std.Methods
Lab ID Sample ID # Artalyli Basalt +.
CS M Cr J 2 ci Reference
2t01-043 -01 116uVE G. Few CciLferm-S <29500 CA)e 2s4a 01107121 EtUtSC 92220-h F
-02 <29500 c$uro n5 5
-03 29500 CFLjsp 295M
-04 <29400 utwo 2g4en
-05 <29400 ' urn wino
-06 <29500 cFLJt; zesoa
-07 <29400 EF14 xwnn
Geomspn 29500
2101-043 -01 s�,opE G. TS OW 3.39% act' 01107021 ERR 2540 G-TS
-02 3.39% o cm
-03 3.39% ow
-04 3.40% aim
-05 3-39% a.o1
-06 0.40% aaa
-07 3,36% ow
Report
Review / . -r._, !/4 l
Project Mani of Dake
219 S.Suck Sr. 919-2 -4240
Sinford NC 27130 dlni►dxamereceepme.can

Steeht a Sh. Cameron Testing Services, Inc_ ChainofCustody
Sanford,NC 27330 Page of
Phone- i 20B 42e40 NC+ rGW Cert.*654 NC PH Ceti*37799 USEPA NC01 Bi 8
Company; — Email_ I v Mt 1 e& S 4t.1C rD. . . Slab use
•
Gam. .. Cr5 IN Ili+til P t Sample Terap Pro}iG I .- Ll7�
it 0, ee {2. EGa(Y!N) I •
—
Address{City', _ — 1
State dip} lifor,k5yd +L Iic+ 7O , •**e.;_ PernaRll'+N}
proiect 4, .riI(c 14 Vire .- Rush corn,!) Dr.ke. r
SampleName: i.VLF—. I.' ,
VL-4 (All F—. Signature: / .— .
Quitccecion:
Sample Information Number of • 4 3.. Required Testin Anatysi .`TS
Client Sample : ne I E- t • Sam ple
e 44 -1 1 1 zi 1240' G 5L ' r 'r
30 - , a ea _ 2, MIEM. ::,, -Al „vs-- 0 gi .
11 M I"? ., .5 1 w EMINIIMMII — — -
EM-__. . _. —..
.UU■
___ 11.11111111..1111.11.1
.11111.1111RE ___ - --— — — —
-• i 1 mommir..1 _ • _ •
., ,
•
Relinquished:l ed: I (+ Received: _ _ _ _ f
Oki-if itc., ,.. ElliMill
Check-irti _
Rush work will require prior approval. Additional charges wiii appFy

30D Report Sheet
! Project: Farmville 30 Day Benchtop Test CTS Proj. 2102-196
Client: Synagro (EPA 625/R-921013, Appendix 0) Regulatory
Sampled Received - — Due ` Ref, Methods Std. Meth. 192'ed�
By C. Wynne By J. Cameron 2540 G -TS
Date 02/24/21 j Date 02124/21 Date ! Requested Anatysis 2540 G -VS
Type Grab MDtrix _ Mudge
Sample ID Lab ID TS(%) VS (Vol n o $3s l Analyst
imatolmillIM
2ff)2•196 01 Start (< 2%) 1.73% 69.2% o 5r21 CSCIERP
1.67% 67 5% 31421 FVSROnb.) 5.97
I 1.60% 66.1% 3111121 FVSR(mb.) . 11,50 1/11
-.59% 64.6% 311f21 FVSR Im.b.) . 4.47%
End (+ 30) 1.63% 64.8% 03/2721 FV R(m.b.) 11.89%
Final Results FVSR (m b.) 111.85% Pass.< 15%
qi.... t.....,57:77
Proj. Mgr.
Notes: Sample started at TS s 2%. — — -- --
Page 1

219S-Steele!Str, Cameron Testing Services, Inc. Chain of Custody
Sanford, NG 27330
Phone:[phone] NC 0N4'1GW Cert. *654 NC PHHS Cert#37799 US EPA NC01g13 Page Of
Company: q p ct LL. Emil: e. Coe/k. ;C +S r....0-1►'' CO% 1 CIS lab use _-
Contact: Phone: 701 r62.71
Sam )Temp Pro;-Jn
Address(City, 2‘t7-1 0)e+ ell Fax: Ice{YIN} ell
r
State,Zip) F,(a C- 4 vi tk Nc. 2_ ,0 dates: Permit(YIN) 1 -- -
•
Project ',vv.'. L It e- Vd'i- Rush(Y/N) I due-
1
"Sample
Colleciore Name: et.,+5 G U rt - --- Signature: ar '
Sample Information Number of bathes + preservative Required Testing/Analysis 7
Client Sample a M g ° I as . . 2 c„ a. Preservatives. (UlnpreseRred, H(c}I- sample
i ? 0 0 o -J _ H2(S)04, H{N}03,(NarThiosulfate,
ID I- [7 u a� y) m T > Na(01H- ;Pghosphofic,Other(X), Indicate ID
0-el a I 14Ii Aaffie C N ! 1 30 -etof 6cktc j
0 --Cl&/ 144 ill Ri5 A" C 5 L i‘i I go -eisi Le.,cL._
. /kc►'K Iiiii'lIzi ID' h 5L tJ 1 - 0- 4- k&fr c.
r
— •
E j .. .-
: —[
Relinquished: •.- batetfline
tri . :► ill 6 .1 Z - sr-.
I
Check-iin
Rush work will require prior approval, Additional charges will apply

SECTION 6

Agricultural Lime Application Log
2021
Farmville WWTP
Field Soil Lime Requirement Tons/Acre Date Applied
(state-county-site-field) pH (tons/acre) Applied
NC-PI-01-3 6.2 0.0 0.0 *
NC-PI-01-4 6.3 0.0 0.0 *
NC-PI-01-6 5.7 0.7 0.0 *

SECTION 7

WPage1 of 1
r 0
Report No: 22 035 0646
Account No: 46622 \Ilafpoint,, 7621 Whitepine Road,Richmond,VA 23237
Main 804-743-9401°Fax [phone]
ANALYTICAL www.waypointanalytical.com
Advisor: Synagro Central LLC/Technical Client: Harold Flanagan Farm:
Mary Brewer
284 Boger Road
Mocksville NC 27028 Date Received:02/04/2022
Date of Report:02/07/2022
Lab No Field ID Sample ID Soil Class HM% W/V pH Ac P-I K-I S-I Mn-I Mn-All Mn-Al2 Zn-I Zn-Al Cu-I CEC BS% Ca% Mg% ESP Na
09078 P1-01 3 MIN 6.2 0.6 167 24 0 0 4.7 87 66 18
Crop Recommendations: Rec Uom Lime(t/acre) N P205 K20 S Mn Zn Cu B Mg Last Crop
1-Pasture lb/acre 0.0 50 0 110 0
09079 P1-01 4 MIN 6.3 0.5 168 20 0 0 4.6 89 68 19
Crop Recommendations: Rec Uom Lime(t/acre) N P205 K20 S Mn Zn Cu B Mg Last Crop
1 Mix Grass Hay lb/acre 0.0 160 0 250 0
Comment:
Test result units=CEC and Na in meq/100cm3;NO3 N in mg/dm3;WA/in g/cm3
North Carolina Division of Water Quality Certification#257,Analysis and fertility recommendations shown on this report are performed in accordance within NCDA guidelines,Analysis prepared by:Waypoint Analytical Virginia,Inc.

NCDA&CS Agronomic Division Phone: [phone] Website: www.ncagr.gov/agronomi/ Report No. FY21-SL034247
oci 11
4,,, Client: Harold Flanagan Advisor: Chris Wynne
k' *r " , , Predictive 3625 Arch Flanagan Rd Synagro LLC
_$ ���`it ��
Farmville, NC 27828 284 Boger Road
1 , � Soil Report Mehlich-3 Extraction Mocksville, NC27028
- -•I , '. Sampled County: Pitt
'66.y,i,.%;l '. Links to Helpful Information
Client ID: 463740 Advisor ID: 509090
Sampled: 05/18/2021 Received: 06/17/2021 Completed: 06/24/2021 Farm: PI-1
Sample ID: 6 Recommendations: Lime Nutrients(lb/acre) More
Crop (tons/acre) N P2O5 K2O Mg S Mn Zn Cu B Information
Lime History: 1 -Bermuda hay/past., M 0.7 180-220 0 140 0 0 0 0 0 0 Note: 12
2- 0.0
Test Results [units-W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]: Soil Class: Mineral
HM% W/V CEC BS% Ac pH P-I K-I Ca% Mg% S-I Mn-I Mn-All Mn-Al2 Zn-I Zn-Al Cu-I Na ESP SS-I NO3-N
1.67 1.07 11.8 83 2.0 5.7 313 39 62 19 46 75 62 1103 1103 459 0.1 1
e1 1orkh Carolina Reprogramming of the laboratory-information-management system that makes this report possible is being funded
through a grant from the North Carolina Tobacco Trust Fund Commission.
.# k rThank you for using agronomic services to manage nutrients and safeguard environmental quality.
- Steve Troxler, Commissioner of Aqriculture
Totr7Ciwfrus!fLindCi iibIm

NCDA&CS Agronomic Division Phone: [phone] Website: www.ncagr.gov/agronomi/ Report No. FY21-SL034247
Harold Flanagan Page 2 of 2
Understanding the Soil Report: explanation of measurements, abbreviations and units
Recommendations Report Abbreviations
Lime Ac exchangeable acidity
If testing finds that soil pH is too low for the crop(s) indicated, a lime recommendation will be given in units of either B boron
ton/acre or lb/1000 sq ft. For best results, mix the lime into the top 6 to 8 inches of soil several months before planting. BS% % CEC occupied by basic cations
For no-till or established plantings where this is not possible, apply no more than 1 to 1.5 ton/acre (50 lb/1000 sq ft) at one Ca% % CEC occupied by calcium
time, even if the report recommends more. You can apply the rest in similar increments every six months until the full rate CEC cation exchange capacity
is applied. If MG is recommended and lime is needed, use dolomitric lime. Cu-I copper index
ESP exchangeable sodium percent
Fertilizer HM% percent humic matter
Recommendations for field crops or other large areas are listed separately for each nutrient to be added (in units of K-I potassium index
lb/acre unless otherwise specified). Recommendations for N (and sometimes for B) are based on research/field studies K20 potash
for the crop being grown, not on soil test results. K-I and P-I values are based on test results and should be > 50. If they Mg% % CEC occupied by magnesium
are not, follow the fertilizer recommendations given. If Mg is needed and no lime is recommended, 0-0-22 (11.5% Mg) is MIN mineral soil class
an excellent source; 175 to 250 lb per acre alone or in a fertilizer blend will usually satisfy crop needs, SS-I levels appear Mn manganese
only on reports for greenhouse soil or problem samples. Mn-All Mn availability index for crop 1
Mn-Al2 Mn-availability index for crop 2
Mn-I manganese index
Farmers and other commercial producers should pay special attention to micronutrient levels. If$, pH$, $pH, C or Z M-O mineral-organic soil class
notations appear on the soil report, refer to $Note: Secondary Nutrients and Micronutrients In general, homeowners do not N nitrogen
need to be concerned about micronutrients. Various crop notes also address lime fertilizer needs; visit Na sodium
ncagr.gov/agronomi/pubs.htm. NO3-N nitrate nitrogen
ORG organic soil class
Recommendations for small areas, such as home lawns/gardens, are listed in units of lb/1000 sq ft . If you cannot find pH current soil pH
the exact fertilizer grade recommended on the report, visit www.ncagr.gov/agronomi/obpart4.htmsfind information that P-I phosphorus index
may help you choose a comparable alternate. For more information, read A Homeowner's Guide to Fertilizer.. P205 phosphate
S-I sulfur index
Test Results SS-I soluble salt index
W/V weight per volume
Zn-Al zinc availability index
The first seven values [soil class, HM%, W/V, CEC, BS%, Ac and pH] describe the soil and its degree of acidity. The Zn-I zinc index
remaining 16 [P-I, K-I, Ca%, Mg%, Mn-I, Mn-A11, Mn-Al2, Zn-I, Zn-Al, Cu-I, S-I, SS-I, Na, ESP, SS-I, NO3-N (not routinely
www.ncagr.gov/agronomi/uyrst.htm
available)] indicate levels of plant nutrients or other fertility measurement. Visit