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HomeMy WebLinkAboutWQ0006017_Residual Annual Report 2021_20220216 I Non-Discharge Branch Upload/Submittal Form NORTH CAROLINA EnWron.M&IQualfty Version 2-Revised June 23.2020 Initial Review Reviewer Thornburg,Nathaniel D Is this submittal an application?(Excluding additional information.)* Yes No If not an application what is the submittal type?* Annual Report Residual Annual Report Additional Information Other Annual Report Year* 2021 Permit Number(IR)* WQ0006017 Applicant/Permittee Town of Beaufort Email Notifications Does this need review by the hydrogeologist?* 0 Yes OO No Regional Office Wilmington CO Reviewer Admin Reviewer Submittal Form Project Contact Information Please provide information on the person to be contacted by NDB Staff regarding electronic submittal,confirmation of receipt,and other correspondence. ............................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................ Name* Lysa Finnerty Email Address* Phone Number* LFinnerty@synagro.com 14105376150 Project Information Application/Document Type* New(Fee Required) Modification-Minor Modification-Major(Fee Required) Renewal Renewal with Major Modification(Fee GW-59, NDMR,NDMLR, NDAR-1, Required) NDAR-2 Annual Report Residual Annual Report Additional Information Change of Ownership Other We no longer accept these monitoring reports through this portal. Please click on the link below and it will take you to the correct form. https://edocs.deq.nc.gov/Forms/NonDischarge_Monitoring_Report Permit Type:* Wastewater Irrigation High-Rate Infiltration Other Wastewater Reclaimed Water Closed-Loop Recycle Residuals Single-Family Residence Wastewater Other Irrigation Permit Number:* WQ0006017 Has Current Existing permit number Applicant/Permittee Address* 435 Williams Court,Ste 100,Baltimore,MD 21220 Facility Name* Town of Beaufort Class B Residuals Program Please provide comments/notes on your current submittal below. 2021 Annual Report for Town of Beaufort,NC At this time,paper copies are no longer required.If you have any questions about what is required,please contact Nathaniel Thornburg at nathaniel.thornburg@ncdenr.gov. Please attach all information required or requested for this submittal to be reviewed here.* (Application Form,Engineering Plans,Specifications,Calculations,Etc.) Beaufort,NC 2021 Annual Report FINAL.pdf 7.42MB Upload only 1 PDF document(less than 250 MB).Multiple documents must be combined into one PDF file unless file is larger than upload limit. * By checking this box, I acknowledge that I understand the application will not be accepted for pre-review until the fee(if required)has been received by the Non- Discharge Branch.Application fees must be submitted by check or money order and made payable to the North Carolina Department of Environmental Quality(NCDEQ). I also confirm that the uploaded document is a single PDF with all parts of the application in correct order(as specified by the application). Mail payment to: NCDEQ—Division of Water Resources Attn:Non-Discharge Branch 1617 Mail Service Center Raleigh,NC 27699-1617 Signature Submission Date 2/16/2022 435 Williams Court,Suite 100 Baltimore,MD 21220 SYNAG R www.synagro.com FEBRUARY 16,2022 NCDEQ Division of Water Resources Information Processing Unit 1617 Mail Service Center Raleigh, NC 27699-1617 Re: 2021 Annual Report for Permit No. WQ0006017 Dear NCDEQ: Synagro is submitting one electronic copy of the above referenced report on behalf of the Town of Beaufort, NC. If you have any questions or need additional information,please do not hesitate to contact Donovan Willis at(252) 728-7166 or Chris Wynne at 336-909-8627. Sincerely, l e't ic& Sfiiva'G 25 Derrick Shivar Environmental Compliance Manager Enclosures cc: Donovan Willis—Town of Beaufort Chris Wynne, Synagro YOUR PARTNER FORA CLEANER,GREENER WORLD TOWN OF BEAUFORT,NC RESIDUALS LAND APPLICATION PROGRAM Permit No.WQ0006017 2021 ANNUAL REPORT Town of Beaufort, NC Residuals Land Application Program 2021 Annual Report TABLE OF CONTENTS 1. Certification Form and Annual Operations Summary 2. Annual Residual Sampling Summary Forms and Residuals Analyses 3. Annual Land Application Field Summary Form 4. TCLP Analysis 5. Pathogen Reduction/Vector Attraction Reduction 6. Soil pH & Lime Application Records 7. Soil Analysis SECTION 1 ANNUAL LAND APPLICATION CERTIFICATION FORM Permit Number WQ0006017 County Carteret Year 2021 Facility Name(as shown on permit)Beaufort WWTP NPDES No.NC0021831 Land Application Operator Synagro Phone# (336)998-7150 Land application of residuals as allowed by the above permit occurred during the past calendar year X YES NO. If NO,skip Part A,and Part B and proceed to Part C. Also,if residuals were generated but not land applied, please attach an explanation on how the residuals were handled. Part A—Residuals Application Summary *Total number of application fields in permit. 2 *Total number of fields utilized for land application during the year. 2 *Total amount of dry tons applied during the year for all application sites. 80.54 *Total number of acres utilized for land application during the year. 63.40 Part B—Annual Compliance Statement Facility was compliant during calendar year 2021 with all conditions of the land application permit(including but not limited to items 1-13 below)issued by the Division of Water Quality X YES NO. If no,please provide a written description why the facility was not compliant,the dates,and explain corrective action taken. 1. Only residuals approved for this permit were applied to the permitted sites. 2. Soil pH was adjusted as specified in the permit and lime was applied(if needed)to achieve a soil pH of at least 6.0 or the limit specified in the permit. 3. Annual soils analysis was performed on each site receiving residuals during the past calendar year and three(3)copies of laboratory results are attached. 4. Annual TCLP analysis(if required)was performed and three(3)copies of certified laboratory results are attached. 5. All other monitoring was performed in accordance with the permit and reported during the year as required and three(3) copies of certified laboratory results are attached. 6. The facility did not exceed any of the Pollutant Concentration Limits in 15A NCAC 02T.1105(a)or the Pollutant Loading Rates in 15A NCAC 02T.1105(b)(Applicable to 40 CFR Part 503 regulated facilities). 7. All general requirements as specified in the Land Application Permit were complied with(applicable to 40 CFR Part 503 regulated facilities). 8. All monitoring and reporting requirements in 15A NCAC 02T.1111 were complied with(applicable to 40 CFR Part 503 regulated facilities). 9. All operations and maintenance requirements in the permit were complied with or,in the case of a deviation,prior authorization was received from the Division of Water Quality. 10. No contravention of Ground Water Quality Standards occurred at a monitoring well or explanations of violations are attached to include appropriate actions and remediations. 11. Vegetative cover was maintained and proper crop management was performed on each site receiving residuals,as specified in the permit. 12. No runoff of residuals from the application sites onto adjacent property or nearby surface waters has occurred. 13. All buffer requirements as specified on the permit were maintained during each application of residuals. Part C—Certification "I certify,under penalty of law,that the above information is,to the best of my knowledge and belief,true,accurate,and complete. I am aware that there are significant penalties for submitting false information,including the possibility of fines and imprisonment for knowing violations." Donovan Willis,Public Utilities Director S/�'11- 7%403 Permittee Name and Title(type or print) Signature of 'ttee Date 2/9/2022 Signature of Preparer* Date S nature of La Applier Date (if different from Permittee) (if different from Permittee and Preparer) *Preparer is defined in 40 CFR Part 503.9(r)and 15A NCAC 02T.1102(26) DENR FORM ACF(12/2006) OPERATIONS SUMMARY-LAND APPLICATION - NORTH CAROLINA ALL COUNTIES -ALL SITES DATE RANGE: 1/1/2021 - 12/31/2021 BEAUFORT,NC BEAUFORT,NC AEROBICALLY DIGESTED CAKE MONTH/YEAR AMOUNT UNIT DRY TONS UNIT DRY METRIC TONS May 2021 625.00 Y 80.54 D 73.05 TOTAL 625.00 Y 80.54 D 73.05 Units Key: D-Dry Tons; G—Gallons;W—Wet Tons;Y—Cubic Yards Report Date: 12/20/2021 1:53:56 PM SECTION 2 ANNUAL RESIDUAL SAMPLING SUMMARY FORM Please note that your permit may contain additional parameters to be analyzed.The parameters can be reported in FORM RSSF-B WQ Permit Number: WQ0006017 Laboratory: Facility Name: BEAUFORT, NC PACE ANALYTICAL Residual Source WQ#or NPDES#: NC0021831 WWTP Name: BEAUFORT Residual Analysis Data Product Type AEDCAK Sample or Composite Date 01/13/21 Parameter(mg/kg dry weight) Ceiling Conc. Limit Percent Solids(%) NA 15.30 Arsenic 75 16 Cadmium 85 1.4 Copper 4300 630 Chromium NA 29 Lead 840 30 • Mercury 57 <0.58 Molybdenum 75 7.3 Nickel 420 16 Selenium 100 10 Zinc 7500 1200 Total Phosphorus NA 23000 TKN NA 45000 Ammonia-Nitrogen NA 710 Nitrate and Nitrite NA 67.68 For surface disposal facilities the ceiling concentration limits listed in this form are not applicable.Reference the individual permit for metals limits. "I certify,under penalty of law,that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.I am aware that there are significant penalties for submitting false information,including the possibility of fines and imprisonment for knowing violations." C p Signature of Preparer* Date *Preparer is defined in 40 CFR Part 503.9(r)and 15 A NCAC 2T.1102(26) DENR FORM RSSF(12/2006) Printed:12/20/2021 1:58:59 PM For:2226 01 ANNUAL RESIDUAL SAMPLING SUMMARY FORM-B Report all sampling analysis results for parameters not listed in FORM RSSF that are part of the WQ permit or were analyzed for over the past calendar year.Use additional forms as needed. WQ Permit Number: WQ0006017 Laboratory: Facility Name: BEAUFORT,NC PACE ANALYTICAL Residual Source NPDES#or WQ#: NC0021831 WWTP Name: BEAUFORT Residual Analysis Data Product Type AEDCAK Sample or Composite Date 01/13/21 Parameters(mg/kg dry weight) Aluminium 9300 Calcium 41000 Magnesium 4600 pH(s.u.) 7.40 Potassium 1900 Sodium 3700 PAN 13710 SAR(Ratio) 1.8040 "I certify, under penalty of law,that this document was prepared under my direction or supervision in accordiance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.I am aware that there are significant penalties for submitting false information,including the possibility of fines and imprisonment for knowing violations." _r...2.19/:;;;7;07 Signature of Preparer Date *Preparer is defined in 40 CFR Part 503.9(r)and 15 A NCAC 2T.1102(26) Printed:12/20/2021 1:59:52 PM For:2226 01 DENR FORM RSSF-B(12/2006) 0 Pace Analytical Report of Analysis Synagro 12701 Lancaster Hwy Pineville, NC 28134 Attention: Chris Wynne Project Name: Beaufort WWTP Lot Number:WA14014 Date Completed:01/29/2021 02/01/2021 10:22 AM Approved and released by: Project Manager II: Lucas Odom MILB Q PCCR�c�� 'ye I ANSI NatonalAccredltatlon Board ACCREDITEDeORA16, TESTING LABORATORY The electronic signature above is the equivalent of a handwritten signature. This report shall not be reproduced, except in its entirety, without the written approval of Pace Analytical Services, LLC. Pace Analytical Services, LLC(formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 Tel: 803-791-9700 Fax: 803-791-9111 www.pacelabs.com Page 1 of 7 PACE ANALYTICAL SERVICES, LLC SC DHEC No:32010001 NELAC No: E87653 NC DENR No:329 NC Field Parameters No:5639 Case Narrative Synagro Lot Number: WA14014 This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary following this Case Narrative. The sample receiving date is documented in the header information associated with each sample. All results listed in this report relate only to the samples that are contained within this report. Sample receipt, sample analysis, and data review have been performed in accordance with the most current approved The NELAC Institute (TNI) standards, the Pace Analytical Services, LLC ("Pace") Laboratory Quality Manual, standard operating procedures (SOPs), and Pace policies. Any exceptions to the TNI standards, the Laboratory Quality Manual, SOPs or policies are qualified on the results page or discussed below. Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" qualifier If you have any questions regarding this report please contact the Pace Project Manager listed on the cover page. The pH analysis associated with the sample(s) in this report was/were performed after the method recommended 15 minute holding time. Metals by ICP Due to the matrix and low percent solids, the initial sample amount used for sample -001 was 3X more than the standard procedure. The LOQ has been adjusted accordingly. TKN The following samples were not fully oxidized after the addition of 15mL of HNO3: WA14013-001. This is indicated by the samples exhibiting persistent brown fumes after complete acid addition. Due to being biosolids and having low percent solids, the samples will not be weighed to a lower mass and analysis will proceed as usual. Pace Analytical Services,LLC(formerly ShealyEnvironmetal Services,Inc.) 106 Vantage Point Drive West Columbia,SC 29172(803)791-9700 Fax(803)791-9111 www.pacelabs.com Page 2of7 Client:Synagro Laboratory ID:WA14014-001 Description:Beaufort WWTP Matrix:Solid Date Sampled:01/13/2021 1130 % Solids: 15.3 01/20/2021 0110 Date Received:01/14/2021 Inorganic non-metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 2 (% Solids)SM 2540G 1 01/20/2021 0110 AAB 79998 1 350.1 (Ammonia-N )350.1 5 01/19/2021 1315 DRD 79842 1 (Nitrate-N )9056A 1 01/19/2021 1200 AMR 79937 1 (Nitrite-N )9056A 1 01/19/2021 1200 AMR 79944 2 (Phosphorus)365.1 100 01/27/2021 1129 DMA 01/26/2021 1924 80750 1 (Soil pH meas)9045D 1 01/14/2021 1812 AAB 79516 1 351.4 (TKN)351.2 10 01/21/2021 1352 DMA 01/20/2021 1747 80122 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run % Solids SM 2540G 15.3 % 2 Ammonia-N (gas diffusion) 350.1 710 33 17 mg/kg 1 Nitrate-N (soluble) 9056A 67 3.3 0.65 mg/kg 1 Nitrite-N (soluble) 9056A 0.68 J 1.3 0.65 mg/kg 1 Phosphorus 7723-14-0 365.1 23000 3300 650 mg/kg 2 Soil pH measured in water @ 17.9° C 9045D 7.4 su 1 TKN 351.2 45000 1600 1600 mg/kg 1 CVAA Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 7471B 7471B 5 01/21/2021 1233 JAB2 01/20/2021 1110 79538 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Mercury 7439-97-6 7471B ND 2.4 0.58 mg/kg 1 ICP-AES Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3050B 6010D 1 01/20/2021 1010 KSH2 01/19/2021 0905 79720 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Aluminum 7429-90-5 6010D 9300 120 44 mg/kg 1 Arsenic 7440-38-2 6010D 16 4.4 1.5 mg/kg 1 Cadmium 7440-43-9 6010D 1.4 J 1.5 0.37 mg/kg 1 Calcium 7440-70-2 6010D 41000 1500 180 mg/kg 1 Chromium 7440-47-3 6010D 29 2.9 0.73 mg/kg 1 Copper 7440-50-8 6010D 630 2.9 1.3 mg/kg 1 Iron 7439-89-6 6010D 31000 29 13 mg/kg 1 Lead 7439-92-1 6010D 30 2.9 1.3 mg/kg 1 Magnesium 7439-95-4 6010D 4600 1500 180 mg/kg 1 Manganese 7439-96-5 6010D 800 4.4 1.7 mg/kg 1 Molybdenum 7439-98-7 6010D 7.3 J 12 2.9 mg/kg 1 Nickel 7440-02-0 6010D 16 12 3.1 mg/kg 1 LOQ=Limit of Quantitation B=Detected in the method blank E=Quantitation of compound exceeded the calibration range DL=Detection Limit ND=Not detected at or above the DL N=Recovery is out of criteria P=The RPD between two GC columns exceeds 40% J=Estimated result<LOQ and>DL H=Out of holding time W=Reported on wet weight basis Pace Analytical Services,LLC (formerly Shealy Environmental Services,Inc.) 106 Vantage Point Drive West Columbia,SC 29172 (803)791-9700 Fax(803)791-9111 www.pacelabs.com Page 3of7 Client:Synagro Laboratory ID:WA14014-001 Description:Beaufort WWTP Matrix:Solid Date Sampled:01/13/2021 1130 % Solids: 15.3 01/20/2021 0110 Date Received:01/14/2021 ICP-AES Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3050B 6010D 1 01/20/2021 1010 KSH2 01/19/2021 0905 79720 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Potassium 7440-09-7 6010D 1900 1500 180 mg/kg 1 Selenium 7782-49-2 6010D 10 5.8 2.4 mg/kg 1 Sodium 7440-23-5 6010D 3700 1500 180 mg/kg 1 Zinc 7440-66-6 6010D 1200 15 3.6 mg/kg 1 LOQ=Limit of Quantitation B=Detected in the method blank E=Quantitation of compound exceeded the calibration range DL=Detection Limit ND=Not detected at or above the DL N=Recovery is out of criteria P=The RPD between two GC columns exceeds 40% J=Estimated result<LOQ and>DL H=Out of holding time W=Reported on wet weight basis Pace Analytical Services,LLC (formerly Shealy Environmental Services,Inc.) 106 Vantage Point Drive West Columbia,SC 29172 (803)791-9700 Fax(803)791-9111 www.pacelabs.com Page 4of7 Chain of Custody and Miscellaneous Documents Pace Analytical Services,LLC (formerly Shealy Environmental Services,Inc.) 106 Vantage Point Drive West Columbia,SC 29172 (803)791-9700 Fax(803)791-9111 www.pacelabs.com Page 5 of 7 , ) m D ro Shealy Envirorrmerr#al Services, frc_ I 1 Vintage.. F'olrli D rive II) e, Chain of Custody Record West Columbia,Souti Carolina 29172 Number o, •z. Telephnrre NO. (813)791-A7O 1 pax No. 6 ) 71-911J 1 . o m m msw.ahealyisma:rn p Client R49r11dCOntatl - 3drri {Pi iiiI i Now) Quote No. } m n .Syrlagro Cbr:a'Jdymre i.1 r Wynn= V 0 o Address Telephone N .I Fax No.I E-riil -- —. '.NasihIH No. race - g 2S4 eager Rd_ _ _ 337201aE27 ewynneetsynargo.com 1' r' I c-' Cay -- 'S to apCOOc Preservative I I1unilrui y�1Cmlainsis z- Iicwksvlz: NC 2702E 1.UA1AS_ 4.HINO2 7.NsEH Buds o m LLe 1rT P� 2.NRO1-12n� 5.HCL --.... — -- Prai�7.Namm yq r`rssrYR�lva 13 m 3.H2s�a 5.NOrnb, i — - co o I 1 > )• a. Praigc-%mum ... P.O MIrPN!r :`-' 'S I 1.7�j�t E J� l litinl� " Jai hiletrix ;3 I l• -Eav I - -. ; , - R I ' VVA14014 - m $#urlple I b A ' fl9n �' .E. 4 �. 0 i '3 i yr ?Ca•rteinera Far each sample may 1}e Date Time ra`rr Uirf DIN 'uifiI 5 l� lo.i}j I w ' ` 2 i x y} r D coni ltidd on o' Iinr) '5 ' t ' - c.} h ?_] m m Q . i1 L.f) r Z . 2 Q -..• s_ c_. ra •. ua L o F- I 0 i p zo r o � D tiGll# I � � 2tI F 'SI�+frarlltoring r ro ti x• `- le z . CD no o •.Y I -- J 0 � .' 1I i J m 1 m ihrnAr0undnme5ecurod[ ,rki appmvr#regiiirodfornxprxlItad-M} Sar1- liyecsnl QC Requir menta(please.$pedfy} POaSibla Hazard Identfickan grioa Wizard Flarnrriable DSkin Ir itarlt .Eterrd d Lrtv9h Ni..25SRe IA 7 days ler Lutes E Rilurri Lc.Cliurd ax Oisp i I by Lab taC Certification llvoiaon Unkrowa ^r `,ROlingr,i by a pier Lie'e roe poi1,Received by Date Tina " ntli5 [A11149.e'' il(3 Pi i:o. 7.Rulinquisl-etJ by Cae ;Time t_re4r. ed, ••-iOete (Time 1 i Z.Ralinquistrr1 by - - 'Lrd-3 Tlrie 1}_Receive:!.Ey !iaie I:me -- — 4.FdPIIngWiShrrl by 3;a The I_ ' ' Iizi -- ka:J R#t�ivsd by� data�..--- T�mF Note:All samples are r` C otained for sax weeks from receipt unless other !..kR IJSE ONLY ` .Fweipt Tet1 _ 4.np.Bark I - arrunmements are made Receded Cr!.roe{Cre to ❑Y N 1 Oleo Pam - - 'c-n Y Frrpc-ive Sara od-2 F-202 PACE ANALYTICAL SERVICES, LLC Samples Recei4Jt Checklist 1-5RC1€MEOOTsC-15) Revised,!1{.39{2.024 .f.2ce.srratyJrcaf' Issuirsg ALthorityr Pace FNU-W LOL Pagel oi 1 Sample Receipt Checklist (SRC) CliRMr`_t; Syr,arra Coulnr:JIG 3t.r.trclI Mate. 1CSL' f OElt4f20.',I Lot Wil]40t4 . n3 ofrceeipt: n Pare d I- !Client IP'S FedE.,t ElOther: RY€ s bra l.Were custody scaly plsent on the cooler?' _ _ _ - _ Yes: No INN'A 2-Ifcusto€ly eRlsWere rescn- were the i,s'aC xttidunbroken? .i Ip1- Strip ID: NJ Chlorine Strip 11 ; ran Tested b w."" Orls=naltemperature upon raa:iptJDerived(Co1TeCtCd)tomperatureiiponxeccipt %Solid Snap-Cup ID: 2'j Er75 _- 3.$ j3A. 0,c NA )..t<A ck(* NA LN . +,c NA ,NA oc Method:Qlctrpor Wre Blank aigainst Bottles Ill Gun 1a s _IR Gun(!,rreeticm Patton 3._°C kNiet11Od of c.onlant: 0 We Ike 0 ice Pax lin ❑ Dry ke 0 None I Eva] , If temperature of any erl 1erexceeded G.1P C, 1s Project ManagerNotificd? No ID NA T PM xis Notified by: phone i email!!face-to-face(circle epee), 0 ycs [No ©NA 4-, :s the commercial couner'3 packing slip at-ncied to this form? El'4'c; ❑No; 3. Were pre austot:procedures(rctinquishcdfr ` ived)followed? • fui Yrw; ©No 6. Were sample IDS listed on the COC?. al Yes ❑No 7. Wcrc sample Ds listed on all sample containers? • ,e. Yes 11 No 5- Was collection elate&time listed an thr COC? __I �:J Year ❑NO q- LVas calicetism date&lime Listed on all.rrnrl,le containers? Y -I Cy T❑�tN .0-Did all;.ant rtior label information(ll ,dates, time)a ree with the COC? _ Yi s t�Nol ]I,were tesic to be performed listed or the COC? El No' 12,Did all samples arrive in the proper ourttainats for each tact ar•.dint in good condition 0 Yes (unbroken,lids oa,tee.)? _-.. . . Ye_S LI No 13.Was a..*,, i e sample volume availth[c? . _ /I Yes _ No 14. Wore all samples.received within V tl,rs holding time or L8 hours,whichever first? ❑Yes J No: 15.Ws:re oar+samples containers missing'excess(circle one)Samples Not listed an CCC7 ' [fi- For VOA and RSK-175 samples,were•3ubb]cs presehr>-`Trea..size"('l."or 6mm fir:diameter) nI3'ca LiNci MNA. . in sly of t:le VOA vials? rs LINO: on NA 17.VFrerc all DRD,Aroeials1natrierrt sxmplcs received at a pH of<7.? .ri 1'Yes Y❑Ni) Q7tih 18, Were all cyan'-de samples received at a pH> ]2 and sultide samples received at a pH >Ce? 19.-Were all applicabloN S?TI N�cy'ani elphena l/608.3(<:0.5roarnple5 free Of Yes ❑No EINAresidual chlorine? ri 120. s re clip ul, ,rrar rs'r guests{i.e.rcr.urgled dilutions,[4#S+la15t7 dcsig�rrticsns:etc---; Yes ❑No ON correctly truz cubed from the COC inn,he e n anent section in L1MS? — �Yes Nu 21. Was the r uutc JILLillblijr listr d co the Colitainer label'?lives,[nasty 4 • ISample P SCrvatIon (must be completed fonr arty samples)•incorrecily pres.erued or with hcadspa .) Samplets) 1.44 -_ were received incorrectly presr:ry d ini d were adjusted accordingly Ian cam pie receiving with NA__rtiLCf Ode one:H2SOA1,HNO"a,HCI,haDHmingSRt NA Timis of preservation NA . If more than aye prese-vavc is needed.please nate in the cornmen4S belpw. Sample(s) NA were rocsivcxl with hobbits >15.trim indiameter. • Srunp]cs s) NA -._wee reCeive&I wills TRC>0-5:ng/l.,(If4I9 is no)and vtmcrc..: 'adjusted accard'utialy in sample receiving with sodium thiosialfa'e(NaaSsO.)wi[!s Shealy I D. NA ititi::CUKriSdilt4T21) L harco-dc:ahylf applied by Dale: Cr}rnre tints: Pace Analytical Services,LLC (formerly Shealy Environmental Services,Inc.) 106 Vantage Point Drive West Columbia,SC 29172 (803)791-9700 Fax(803)791-9111 www.pacelabs.com Page 7 of 7 SECTION 3 ANNUAL LAND APPLICATION FIELD SUMMARY FORM Page:1 FACILITY NAME:BEAUFORT,NC WQ PERMIT#:WQ0006017 FIELD#:NC-CR-00007-0-0003-A ACRES UTILIZED:23.4 LAND OWNER:WALTER WETHERINGTON ANNUAL DRY TONS APPLIED:32.22 SITE#:NC CR 00007 ACRES PERMITTED:23.4 OPERATOR:ROBERT RIGGS PREDOMINANT SOIL SERIES:NORFOLK CATION EXCHANGE CAPACITY(NON-503): CROP 1 NAME:SOYBEANS(SB) CROP 1 MAX.PAN:118 CROP 2 NAME: CROP 2 MAX.PAN: RESIDUAL SOURCE(S):*See list at bottom of report Gallons(G) Site Name of Crop Type or Cubic Yards(Y) Cond. Precip Volati- Mineral- Ammonia Nitrate PAN Applied Receiving Residual Date or or Wet Tons(W) % Residual Dry,Wet, Past 24 Hrs. Application lization ization TKN Nitrogen and Nitrite (lbs/acre) Application Month Amount UOM Solids Dry Tons/Ac Source Moist Inches Method* Rate** Rate*** mg/kg mg/kg mg/kg Crop 1 Crop 2 Crop 1 Crop 2 5/24/2021 50.00 (Y) 15.300 0.275 BAEDC DRY "0-<1/2" SURIN 1.0 0.30 45,000.00 710.00 67.68 7.745 SB 5/25/2021 200.00 (Y) 15.300 1.101 BAEDC DRY "0-<1/2" SURIN 1.0 0.30 45,000.00 710.00 67.68 30.981 SB May-21 250.00 (Y) Total 1.376 Total 38.726 0.000 AS CD CU CR PB HG MO NI SE ZN P Lime Applied Annual lbs/acre Applied i 0.044 0.004 1.735 0.080 0.083 0.002 0.020 0.044 0.028 3.304 63.329 Date Lbs/Ac Cumulative lbs/acre Applied 0.590 0.243 46.921 6.364 2.883 0.159 0.476 2.969 0.382 72.823 ***** ***** Permit PAN Limit(lbs/acre) 1st Crop I 1_. I' .,. . . .. .. .I a 118 Federal C.P.L.R.(lbs/acre)**** 111=11211 1,339.0 IC= 15.0 375.13 89.0 2,500.0 BAEDC=BEAUFORT,NC AEROBICALLY DIGESTED CAKE "I certify,under penalty of law,that this docum- t w s prepared under my direction or supervision int accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.I am aware that there are s' 'fic.,,rf en ties for submitting false information,including the possibil' of Ines and imprisonment for knowing violations."on SIGNAT LAND APPLIER D E NR=Not Reported or Not Requir•. *** Mineralization Rates:Compost-0.1,Anaerobically digested-0.2,Aerobically digested-0.3,Raw Sludge-0.4 * Application Method:SUR-Surface,INJ-Injection,SURIN-Incorporation **** C.P.L.R.:Cumulative Pollutant Loading Rate ** Volatilization Rate: Surface 0.5, Injection/Incorporation 1.0 **`*** See Site pH&Lime Application Records Section of Report Printed:12/6/2021 DENR FORM FSF(12/2006) ANNUAL LAND APPLICATION FIELD SUMMARY FORM Page:1 FACILITY NAME:BEAUFORT,NC WQ PERMIT#:W00006017 FIELD#:NC-CR-00007-0-0003-B ACRES UTILIZED:40,0 LAND OWNER:WALTER WETHERINGTON ANNUAL DRY TONS APPLIED:48.32 SITE#:NC CR 00007 ACRES PERMITTED:40.0 OPERATOR:ROBERT RIGGS PREDOMINANT SOIL SERIES:NORFOLK CATION EXCHANGE CAPACITY(NON-503): CROP 1 NAME:SOYBEANS(SB) CROP 1 MAX.PAN:118 CROP 2 NAME: CROP 2 MAX.PAN: RESIDUAL SOURCE(S):*See list at bottom of report Gallons(G) Site Name of Crop Type or Cubic Yards(Y) Cond. Precip Volati- Mineral- Ammonia Nitrate PAN Applied Receiving Residual Date or or Wet Tons(W) % Residual Dry,Wet, Past 24 Hrs. Application lization ization TKN Nitrogen and Nitrite (lbs/acre) Application Month Amount UOM Solids Dry Tons/Ac Source Moist Inches Method* Rate** Rate*** mg/kg mg/kg mg/kg Crop 1 Crop 2 Crop 1 Crop 2 5/24/2021 100.00 (Y) 15.300 0.322 BAEDC DRY "0-<1/2" SURIN 1.0 0.30 45,000.00 710.00 67.68 9.062 SB 5/25/2021 275.00 (Y) 15.300 0.886 BAEDC DRY "0-<1/2" SURIN 1.0 0.30 45,000.00 710.00 67.68 24.920 SB May-21 375.00 (Y) Total 1.208 Total 33.982 0.000 AS CD CU CR PB HG MO NI SE ZN P Lime Applied Annual lbs/acre Applied 0.039 0.003 1.522 0.070 0.072 0.001 0.018 0.039 0.024 2.899 55.571 Date Lbs/Ac ***** ***** I Cumulative lbs/acre Applied I 0.978 0.391 78,761 22.648 5.580 0.328 1.030 9.742 0,576 119.664 Permit PAN Limit(lbs/acre) 1st Crop Iiiiminimuit F 118 Federal C.P.L.R.(Ibs/acre)* ** 36.6 8 1,339.0 I ., , 267.9 15.0 9 I _375.0 j 89, i BAEDC=BEAUFORT,NC AEROBICALLY DIGESTED CAKE "I certify,under penalty of law,that this doc ent was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.I am aware that there are Off ant pe hies for submitting false information,including the possibili of f es and imprisonment for knowing violations." Z q Z2— SIGN• URE SF LAND APPL1tR DA E NR=Not Reported or Not Re. ir-c, *** Mineralization Rates:Compost-0.1,Anaerobically digested-0.2,Aerobically digested-0.3,Raw Sludge-0.4 * Application Method: SUR-Surface,INJ-Injection,SURIN-Incorporation **** C.P.L.R.:Cumulative Pollutant Loading Rate ** Volatilization Rate: Surface 0.5, Injection/Incorporation 1.0 ***** See Site pH&Lime Application Records Section of Report Printed:12/6/2021 DENR FORM FSF(12/2006) SECTION 4 0 Pace Analytical Report of Analysis Synagro 12701 Lancaster Hwy Pineville, NC 28134 Attention: Nate Roth Project Name: Beaufort WWTP Lot Number:VC03018 Date Completed:03/17/2020 03/17/2020 3:50 PM Approved and released by: Lab Director- Greenville: Lucas Odom Q PCCR�c0 'ye ) MILD ANSI NatonalAccredltatlon Board ACCREDITEDORA1O, TESTING LABORATORY The electronic signature above is the equivalent of a handwritten signature. This report shall not be reproduced, except in its entirety, without the written approval of Pace Analytical Services, LLC. Pace Analytical Services, LLC(formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 Tel: 803-791-9700 Fax: 803-791-9111 www.pacelabs.com Page 1 of 10 PACE ANALYTICAL SERVICES, LLC SC DHEC No:32010001 NELAC No: E87653 NC DENR No:329 NC Field Parameters No:5639 Case Narrative Synagro Lot Number: VC03018 This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary following this Case Narrative. The sample receiving date is documented in the header information associated with each sample. All results listed in this report relate only to the samples that are contained within this report. Sample receipt, sample analysis, and data review have been performed in accordance with the most current approved NELAC standards, the Pace Analytical Services, LLC ("Pace") Quality Assurance Management Plan (QAMP), standard operating procedures (SOPs), and Pace policies. Any exceptions to the NELAC standards, the QAMP, SOPs or policies are qualified on the results page or discussed below. Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" qualifier If you have any questions regarding this report please contact the Pace Project Manager listed on the cover page. The pH analysis associated with the sample(s) in this report was/were performed after the method recommended 15 minute holding time. ICP Metals Due to low percent solids sample -001 was weighed out 3 times the normal weight. The LOQ has been elevated to reflect the dilution. Nitrate The continuing calibration blank for analytical batch 47694 contained Nitrate greater than the acceptance criteria. The associated sample, VC03018-002, contained detections for this analyte at concentrations greater than 10X the value found in the method blank; therefore sample results are not impacted. The data has been reported. Pace Analytical Services,LLC(formerly ShealyEnvironmetal Services,Inc.) 106 Vantage Point Drive West Columbia,SC 29172(803)791-9700 Fax(803)791-9111 www.pacelabs.com Page 2 of 10 Client:Synagro Laboratory ID:VC03018-001 Description:Beaufort 2020 Matrix: Solid Date Sampled:02/26/2020 1100 %Solids: 19.1 03/03/2020 2237 Date Received:03/03/2020 Inorganic non-metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (%Solids)SM 2540G 1 03/03/2020 2237 MDD 46788 1 (Ignitability) 1010A 1 03/09/2020 1546 SLC 47298 1 (Paint Filter)9095B 1 03/12/2020 1035 SLC 1 (Reactive Cya)7.3.3 1 03/10/2020 0000 KFE 03/10/2020 1046 1 (Reactive Sul)7.3.4 1 03/10/2020 1925 HET 03/10/2020 1046 1 (Soil pH meas)9045D 1 03/05/2020 2203 SRB 47065 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run %Solids SM 2540G 19.1 % 1 Ignitability(Pensky-Martens Closed-Cup) 1010A >140 140 0 ° F 1 Paint Filter Test 9095B Pass pass/fail 1 Reactive Cyanide 7.3.3 ND 50 50 mg/kg 1 Reactive Sulfide 7.3.4 ND 50 50 mg/kg 1 Soil pH measured in water @ 20.9° C 9045D 6.5 su 1 TCLP Volatiles Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch Leachate Date 1 1311/5030B 8260D 10 03/13/2020 0417 JTH 47756 03/11/2020 2110 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Benzene 71-43-2 8260D ND 0.050 0.0040 mg/L 1 2-Butanone(MEK) 78-93-3 8260D ND 0.10 0.020 mg/L 1 Carbon tetrachloride 56-23-5 8260D ND 0.050 0.0040 mg/L 1 Chlorobenzene 108-90-7 8260D ND 0.050 0.0040 mg/L 1 Chloroform 67-66-3 8260D ND 0.050 0.0040 mg/L 1 1,2-Dichloroethane 107-06-2 8260D ND 0.050 0.0040 mg/L 1 1,1-Dichloroethene 75-35-4 8260D ND 0.050 0.0040 mg/L 1 Tetrachloroethene 127-18-4 8260D 0.0060 J 0.050 0.0040 mg/L 1 Trichloroethene 79-01-6 8260D ND 0.050 0.0040 mg/L 1 Vinyl chloride 75-01-4 8260D ND 0.010 0.0040 mg/L 1 Run 1 Acceptance Surrogate Q %Recovery Limits Bromofluorobenzene 98 70-130 1,2-Dichloroethane-d4 96 70-130 Toluene-d8 103 70-130 TCLP Semivolatiles Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch Leachate Date 1 1311/3520C 8270E 1 03/12/2020 1632 SCD 03/10/2020 1710 47402 03/08/2020 2357 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run LOQ=Limit of Quantitation B=Detected in the method blank E=Quantitation of compound exceeded the calibration range DL=Detection Limit ND=Not detected at or above the DL N=Recovery is out of criteria P=The RPD between two GC columns exceeds 40% J=Estimated result<LOQ and>DL H=Out of holding time W=Reported on wet weight basis Pace Analytical Services,LLC (formerly Shealy Environmental Services,Inc.) 106 Vantage Point Drive West Columbia,SC 29172 (803)791-9700 Fax(803)791-9111 www.pacelabs.com Page 3 of 10 Client:Synagro Laboratory ID:VC03018-001 Description:Beaufort 2020 Matrix: Solid Date Sampled:02/26/2020 1100 %Solids: 19.1 03/03/2020 2237 Date Received:03/03/2020 TCLP Semivolatiles Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch Leachate Date 1 1311/3520C 8270E 1 03/12/2020 1632 SCD 03/10/2020 1710 47402 03/08/2020 2357 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dichlorobenzene 106-46-7 8270E ND 0.040 0.0050 mg/L 1 2,4-Dinitrotoluene 121-14-2 8270E ND 0.080 0.0050 mg/L 1 Hexachlorobenzene 118-74-1 8270E N D 0.040 0.0050 mg/L 1 Hexachlorobutadiene 87-68-3 8270E N D 0.040 0.0050 mg/L 1 Hexachloroethane 67-72-1 8270E N D 0.040 0.010 mg/L 1 2-Methylphenol 95-48-7 8270E N D 0.040 0.010 mg/L 1 3+4-Methylphenol 106-44-5 8270E N D 0.040 0.015 mg/L 1 Nitrobenzene 98-95-3 8270E ND 0.040 0.015 mg/L 1 Pentachlorophenol 87-86-5 8270E N D 0.20 0.020 mg/L 1 Pyridine 110-86-1 8270E N D 0.040 0.0050 mg/L 1 2,4,5-Trichlorophenol 95-95-4 8270E ND 0.040 0.0050 mg/L 1 2,4,6-Trichlorophenol 88-06-2 8270E ND 0.040 0.0050 mg/L 1 Run 1 Acceptance Surrogate Q %Recovery Limits 2-Fluorobiphenyl 67 37-129 2-Fluorophenol 40 24-127 Nitrobenzene-d5 74 38-127 Phenol-d5 81 28-128 Terphenyl-d14 85 10-148 2,4,6-Tribromophenol 74 41-144 TCLP Herbicides Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch Leachate Date 1 1311/8151A 8151A 1 03/16/2020 1801 JJG 03/12/2020 1747 47726 03/08/2020 2357 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 2,4-D 94-75-7 8151A N D 0.020 0.0050 mg/L 1 2,4,5-TP(Silvex) 93-72-1 8151A N D 0.0050 0.0013 mg/L 1 Run 1 Acceptance Surrogate Q %Recovery Limits DCAA 75 50-112 TCLP Pesticides Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch Leachate Date 1 1311/3520C 8081B 1 03/13/20201606 DAL1 03/11/20201452 47527 03/08/2020 2357 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run gamma-BHC(Lindane) 58-89-9 8081B ND 0.00040 0.00017 mg/L 1 LOQ=Limit of Quantitation B=Detected in the method blank E=Quantitation of compound exceeded the calibration range DL=Detection Limit ND=Not detected at or above the DL N=Recovery is out of criteria P=The RPD between two GC columns exceeds 40% J=Estimated result<LOQ and>DL H=Out of holding time W=Reported on wet weight basis Pace Analytical Services,LLC (formerly Shealy Environmental Services,Inc.) 106 Vantage Point Drive West Columbia,SC 29172 (803)791-9700 Fax(803)791-9111 www.pacelabs.com Page 4 of 10 Client:Synagro Laboratory ID:VC03018-001 Description:Beaufort 2020 Matrix: Solid Date Sampled:02/26/2020 1100 %Solids: 19.1 03/03/2020 2237 Date Received:03/03/2020 TCLP Pesticides Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch Leachate Date 1 1311/3520C 8081B 1 03/13/20201606 DAL1 03/11/20201452 47527 03/08/2020 2357 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Chlordane 57-74-9 8081B ND 0.0040 0.0015 mg/L 1 Endrin 72-20-8 8081B ND 0.00040 0.00015 mg/L 1 Heptachlor 76-44-8 8081B ND 0.00040 0.00015 mg/L 1 Heptachlor epoxide 1024-57-3 8081B ND 0.00040 0.00016 mg/L 1 Methoxychlor 72-43-5 8081B ND 0.0016 0.00021 mg/L 1 Toxaphene 8001-35-2 8081B ND 0.0080 0.0030 mg/L 1 Run 1 Acceptance Surrogate Q %Recovery Limits Decachlorobiphenyl 77 20-131 Tetrachloro-m-xylene 83 26-132 TCLP Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch Leachate Date 1 1311/3010A 6010D 1 03/10/2020 1028 LLL 03/09/2020 2018 47306 03/08/2020 2357 1 1311/7470A 7470A 1 03/10/2020 1520 KSH2 03/10/2020 0941 47316 03/08/2020 2357 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Arsenic 7440-38-2 6010D ND 0.15 0.025 mg/L 1 Barium 7440-39-3 6010D 0.41 0.25 0.031 mg/L 1 Cadmium 7440-43-9 6010D ND 0.050 0.0060 mg/L 1 Chromium 7440-47-3 6010D ND 0.10 0.013 mg/L 1 Lead 7439-92-1 6010D ND 0.10 0.047 mg/L 1 Mercury 7439-97-6 7470A ND 0.0020 0.00091 mg/L 1 Selenium 7782-49-2 6010D ND 0.20 0.085 mg/L 1 Silver 7440-22-4 6010D ND 0.10 0.021 mg/L 1 LOQ=Limit of Quantitation B=Detected in the method blank E=Quantitation of compound exceeded the calibration range DL=Detection Limit ND=Not detected at or above the DL N=Recovery is out of criteria P=The RPD between two GC columns exceeds 40% J=Estimated result<LOQ and>DL H=Out of holding time W=Reported on wet weight basis Pace Analytical Services,LLC (formerly Shealy Environmental Services,Inc.) 106 Vantage Point Drive West Columbia,SC 29172 (803)791-9700 Fax(803)791-9111 www.pacelabs.com Page 5 of 10 Client:Synagro Laboratory ID:VC03018-002 Description:B 2020 Matrix: Solid Date Sampled:02/26/2020 1100 %Solids: 19.5 03/03/2020 2237 Date Received:03/03/2020 Inorganic non-metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (%Solids)SM 2540G 1 03/03/2020 2237 MDD 46788 1 350.1 (Ammonia-N)350.1 5 03/09/2020 1322 SLC 46871 1 (Nitrate-N)9056A 5 03/11/2020 1758 AMR 47694 1 (Nitrite-N)9056A 5 03/11/2020 1758 AMR 47697 1 (Phosphorus)365.1 250 03/06/2020 1456 DMA 03/06/2020 0937 47087 1 (Soil pH meas)9045D 1 03/05/2020 2205 SRB 47065 1 351.4 (TKN)351.2 5 03/04/2020 1550 DMA 03/04/2020 1002 46808 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run %Solids SM 2540G 19.5 % 1 Ammonia-N (gas diffusion) 350.1 1000 26 13 mg/kg 1 Nitrate-N (soluble) 9056A 680 13 0.63 mg/kg 1 Nitrite-N (soluble) 9056A 16 5.1 0.49 mg/kg 1 Phosphorus 7723-14-0 365.1 25000 6400 1300 mg/kg 1 Soil pH measured in water @ 20.9° C 9045D 6.4 su 1 TKN 351.2 48000 640 640 mg/kg 1 CVAA Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 7471B 7471B 10 03/04/2020 1632 KSH2 03/04/2020 1230 46714 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Mercury 7439-97-6 7471B 1.8 J 3.6 0.88 mg/kg 1 ICP-AES Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3050B 6010D 1 03/09/2020 1924 LLL 03/06/2020 1452 46709 2 3050B 6010D 2 03/09/2020 2241 LLL 03/06/2020 1452 46709 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Aluminum 7429-90-5 6010D 13000 30 11 mg/kg 1 Arsenic 7440-38-2 6010D 20 2.3 0.76 mg/kg 2 Cadmium 7440-43-9 6010D 2.8 0.76 0.19 mg/kg 2 Calcium 7440-70-2 6010D 48000 760 95 mg/kg 2 Chromium 7440-47-3 6010D 38 0.76 0.19 mg/kg 1 Copper 7440-50-8 6010D 1100 1.5 0.68 mg/kg 2 Iron 7439-89-6 6010D 45000 15 6.9 mg/kg 2 Lead 7439-92-1 6010D 45 1.5 0.68 mg/kg 2 Magnesium 7439-95-4 6010D 7000 380 47 mg/kg 1 Manganese 7439-96-5 6010D 900 1.1 0.45 mg/kg 1 Molybdenum 7439-98-7 6010D 9.0 3.0 0.76 mg/kg 1 LOQ=Limit of Quantitation B=Detected in the method blank E=Quantitation of compound exceeded the calibration range DL=Detection Limit ND=Not detected at or above the DL N=Recovery is out of criteria P=The RPD between two GC columns exceeds 40% J=Estimated result<LOQ and>DL H=Out of holding time W=Reported on wet weight basis Pace Analytical Services,LLC (formerly Shealy Environmental Services,Inc.) 106 Vantage Point Drive West Columbia,SC 29172 (803)791-9700 Fax(803)791-9111 www.pacelabs.com Page 6 of 10 Client:Synagro Laboratory ID:VC03018-002 Description:B 2020 Matrix: Solid Date Sampled:02/26/2020 1100 %Solids: 19.5 03/03/2020 2237 Date Received:03/03/2020 ICP-AES Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3050B 6010D 1 03/09/2020 1924 LLL 03/06/2020 1452 46709 2 3050B 6010D 2 03/09/2020 2241 LLL 03/06/2020 1452 46709 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Nickel 7440-02-0 6010D 21 6.1 1.6 mg/kg 2 Potassium 7440-09-7 6010D 2400 380 47 mg/kg 1 Selenium 7782-49-2 6010D 11 3.0 1.2 mg/kg 2 Sodium 7440-23-5 6010D 7700 380 47 mg/kg 1 Zinc 7440-66-6 6010D 2000 3.8 0.95 mg/kg 1 LOQ=Limit of Quantitation B=Detected in the method blank E=Quantitation of compound exceeded the calibration range DL=Detection Limit ND=Not detected at or above the DL N=Recovery is out of criteria P=The RPD between two GC columns exceeds 40% J=Estimated result<LOQ and>DL H=Out of holding time W=Reported on wet weight basis Pace Analytical Services,LLC (formerly Shealy Environmental Services,Inc.) 106 Vantage Point Drive West Columbia,SC 29172 (803)791-9700 Fax(803)791-9111 www.pacelabs.com Page 7 of 10 Chain of Custody and Miscellaneous Documents Pace Analytical Services, LLC (formerly Shealy Environmental Services,Inc.) 106 Vantage Point Drive West Columbia,SC 29172 (803)791-9700 Fax(803)791-9111 www.pacelabs.com Page 8 of 10 O m i v D R.1• : �, SI-tealy Environmental Services_ Inc_ • v 105 Var age Poirrt Diva s. N S T� Chain of Custody Record We Collirtia,South Carolina 29172 Number o . Te3e ?lone Min_(803)711-97C0 Fax No. (803)791-9111 �' N wurksheelyigb,Galn j r [v7 -"-- Fcepart Dri ct "- -- se r�PdnledNeme}.-....... .�"w_.. Qu4leNa. Yns r7I,.ii _ ~<; fl 1,.\{tom (-)c, f '.x0( gs Telephpne No,I Fax No.f&aim Waybill Mo. 1 pig 3 lea a Ed- -)'i4 'ji •-S 4,1- rr.1-'.'.1ia -fat i v 1 a rr 3 Cry Staltlx Zip ads �reSEir+r2#Iv 1 -- — 1 111I14311.11 i a ' I , --- Q P T ���ili� i hi��&sville NC: 27428 1.un res, 4.I-INQ3 7,WON • n v .prate cr rramr: ,NaOHr lu1 S,EtCL i cro 018 7 r j Iti iIL-rl WIMPY i,I126O1 fi.lea Thin. - <_. Pmjr Number P,O NuiFiL�u ' 'SMaIrlx i D OW ID/De6t'411m o A J 'g p 96 g -4 ME N {C0cIsinurs fur eacitaample may be du69 .rim_ i , 1 n 13N! WW'1 s Eu 1- . m ,� �y IC Remorka1C}1er1D D rp CUrnR:nea Qn one f15�; <:LL a'S t?*_' n. 2S7 r4 7) a Q O co' Z io z. - _ ._ .. _ o N assurort 2020 Gam:{w I I•...ti G ' •• x . I } NC Mardbul112 3 D CD C i I H o • coi n l - r; O — ' Tun AroardTwrtIRMinglOpnarNOEip piwagrayailadk,iryerd77nd T/.T) 3Sanwaalepar>ai IGC>ti.puirCr nts[P1 .3 opcou r'iEik Hew('IderrOcKan x F an-Hazard Flennehle in IrrltiEnt r hllama rdard OFEESpa* 7 days por Lui- +Ci Raton to CIIBEE ID DFspasal by Lab 1JCCydOw liuri Peson Unknown r 11.ideI!r ilShal In;S9rtsplor 17ate Time i,psrcaivad by Dale Tim3 \ J 2.R m:lois/0,i by (Date TTe -: eI.*p by date Time 3.n 'IQuistiei by Doti i i,rI 3.Rcaaived by n.-- te— Tlme a.Ras rguishedl uyon 1 1�t.�.o; ---- i7afa Tire „Jo.,d c...„, ....,,,n,0 Note:All samples are retafned for six week from receipt unless other LAB USE roil v t ,.IpI T ,}x Tar7F..I4r.M arranriements are made. — t }h'ed an Ice(Chadic) DIN ace Pack / 4 c E y ' Um-Um D to C 27 2012 PACE ANALYTICAL SERVICES, LLC Slimly Er.virpnr7ciilnI 3cmum,Inc. vase I err] UNLIMnnINunkeT; -0EJ? au-J9 Fflirri _C1nle BQ'TCIB Samp(e Receipt Checklist (SRC) client:.Syi ro -. CDDIralnspectad hi /date;MI c { s)3}0312[)20 Loth: VCO301E 'Meansofreceipt. SESI 0Clic:1t © UP " Fed&rx i] Oaf& 0 Yes ®TV�ai I.Were ctlsrOdy Seals pre3etlt on the coc:cr7 - ' Yes ❑N❑ Z NA.2.If castodv srtah;vec..,-re},resent,were they:mace and unbrnkcc? I pi.I Strip F(7; NA Chlorine Strip iD: NA Tested but NA _ Otiginsi temperature upon roceipt/Derived(Corrected)telr_perdturer ttpor,receipt %Solid Slap-Cup ill: 19-2111 14.2 /4, . NA /NA Pc NA /NA C NA INA °C Method; ®Teartpertatitre Blank❑Ag'nst notifies J .Gun ID: a IR Gun COrruction Factor 0 Method of coolant; 0 W`[lee ❑ Ice Packs © Dry ice H] None _ YLy ID No ®1dA _ __!• 3- ICtemperaturree of any u-nlerexceeded 6d1%,was Project ManezerNotiified? i_ El PM wua Notified by: phone f email i tur_-to-face(circle one), 7 Yc [l No. DNA 4_ Is the commercial unurie:'s packirso Slip attached iv[his form? IZ Yes d No '5. Were prat ousted nx,cxdures(relinq�aishndl]-esr•.eived)folluwed'f PI `'es ❑Nol ni-_ 6- Were sample.II:s]ist•zd on the COG? f Yet El No 7- Wsirc sample]DS'iSt;,•d on all sample guataincrs? Yes I]No_ _$i Was caliectiorr date A-.tine listed eri he COC7 [J Yes 171 No 9- W c r.;,llection date&time Listed on al[Sample containers? Q Ye,3 Q No ]D.Did all container label inform aLkrn(1D,date,time)atf-rt-with the CC7C2 0 YCs 11 No '[. Wem tests to be performed listed on the CAC? 0 Yes LI No 12.Did nil samples arrive in the properconinircrs for each le,c-audio:_'n good mind don (unbroken,]ids on,c-fc,)`f - l € • Yes ❑ No 13. Was adequate sa:up[e w1flrnle availab'e?- E1 Yam; ❑]N 14. Wens all samples ruccivcd within 'A the holding time or48 Fours, 4wiichi}ter crnues first 11 'cs VINUI ;15,}`cro any sanp[e£cordainers ini4sin bides,(circle one)samples NOEL listed on COG? 16,Jar VOA and RSH-]73 sum pies,were bubbles present>"pea-size"(fa"or 6JDLn In+l iumctcr) {] es l} NA in any ante VOA vials? ❑ Yes J NI, z NA 17-%Vere as l DRO/meta[s!ntaxiert sarnp[cs rcce ivcd at a p]-I of<2? ❑ Yes El No lZITCA. IS.%Vero all cyanide samples received at a Fl[I> 12 end made saJ]tpdc5 rc{ae'ti'ed at a pH>97 n Yes ,DNo zI~;A 19. Were all applicable NIdg1TKNlyanide. 1i iiol(<0-.5i-i !I)samples ('re residua] _• Chlorine? ❑ 'es � ®,V}12t1- Vern c Rent remeiksireq nests(i.e. requested-dilutions,fyl..SNISD designations,et.L....) Lprirrently transcribed from the COC into the comment— — — section in I.INTS C bQ N D; 2I. Was they .',, uu:tumber listed on the container label?I f yes,Qu0te* NA -- Sample Preservation (Must he E.wrrp[eted for ally s u-rip]e(s)incorrectly pr+eatrrcd or with headspacc.) Sample(s) NA were received irtccxrcctly preSvrced and were adjns[ed accerdj ugly '1 sample receiving with NA InL eIFcircle one: II2$D41,HNO3,I IC1,NaOH using SR a~ NA rine of pruverea*ion NA_. . If murc their one preservative is needed,please tulle in the comments befow- ` p[e(s) NA —Si _sere rCGcived will lxtl> Jcs a inrn In diameter_ NA were received with TRC>0.5 mgfL(IfP19 is no)and Tet-e adjusted accordingly i_r sample receiving with sodium thiosu[fate(NalSlO;)with Shealy ED: NA, t5R bareode labels applied by: Brvf0 _ Dale: 0310312020• — — COMMe.ut; - r— Pace Analytical Services,LLC (formerly Shealy Environmental Services,Inc.) 106 Vantage Point Drive West Columbia,SC 29172 (803)791-9700 Fax(803)791-9111 www.pacelabs.com Page 10 of 10 SECTION 5 ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM(02T Rules) Facility Name: Town of Beaufort WQ Permit Number: WQ0006017 WWTP Name: Town of Beaufort WWTP NPDES Number: NC0021831 Monitoring Period: From 01/01/2021 To 12/31/2021 Pathogen Reduction(40 CFR 503.32/15A NCAC 02T.1106)-Please indicate level achieved and alternative performed: Class A: Alt. 1/A(time/temp) Alt.2/B(Alk Treatment) Alt.3/C(Prior Testing) Alt.4(D(No Prior Test) Alt.5/Process to Further Reduce Pathogens Alt.6(Equivalent to PPRP) If applicable to alternative performed(Class A only)indicate"Process to Further Reduce Pathogens": Compost Heat Drying Heat Treatment Thermophilic Beta Ray - Gamma Ray Pasteurization Class B: Alt.(1)Fecal Density X Alt.(2)Process to Significantly Reduce Pathogens If applicable to alternative performed(Class B only)indicate"Process to Significantly Reduce Pathogens": Lime Stabilization Air Drying Composting Aerobic Digestion Anaerobic Digestion If applicable to alternative performed(Class A or Class B)complete the following monitoring data: Parameter Allowable Level in Sludge Pathogen Density No.of Frequency Sample Analytical Excee- of Type Technique Minimum Geo.Mean Maximum Units dences Analysis Fecal 2x10 to the 6th MPN MPN/g Coliform power per gram of total solids CFU <13200 <47200 <92600 CFU/g 0 Annually Grab SM9222D- MF 1000 MPN per gram of MPN/g total solids(dry weight) Salmonella 3 MPN per 4 grams total bacteria(in solids(dry weight) lieu of fecal coliform) Vector Attraction Reduction(40 CFR 503.33/15A NCAC 02T.1107)-Please indicate option/alternative performed: Option/Alt. 1 Option/Alt.2 Option/Alt.3 Option/Alt.4 (VS reduction) (40-day bench) (30-day bench) (Spec.02 uptake) Option/Alt.5 Option/Alt.6 Option/Alt.7 Option/Alt.8 (14-Day Aerobic) (Alk Stabilization) (Drying—Stable) (Drying—Unstable) Option/Alt.9 Option/Alt. 10 (Injection) (Incorporation) X No vector attraction reduction alternatives were performed CERTIFICATION STATEMENT(please check the appropriate statement) "I certify,under penalty of law,that the pathogen requirements in 40 CFR 503.32/15A NCAC 02T.1106 and the vector attraction X reduction requirement in 40 CFR 503.33/15ANCAC 02T.1107 have been met." "I certify,under penalty of law,that the pathogen requirements in 40 CFR 503.32/15A NCAC 02T.1106 and the vector attraction reduction requirement m 40 CFR 503.33/15A NCAC 02T.1107 have not been met."(Please note if you check this statement attach an explanation why you have not met one or both of the requirements.) "This determination has been made under my direction and supervision in accordance with the system designed to ensure that qualified personnel properly gather and evaluate the information used to determine that the pathogen and vector attraction reduction requirements have been met. I am aware that there are significant penalties for false certification including fine and imprisonment Donovan Willis,Public Utilities Director Todd Larson,Operations Director Preparer Name and Title(type or print) Land Applier Name Title(if applicable)(type or print) 4 ' t 2/9/2022 Signature of Preparer* Date Signa of Land Ap ier(if applicable) Date *Preparer is defined in 40 CFR Part 503.9(r)and 15A NCAC 2T.1102(26) Cameron Testing Services, Inc. Laboratory Report NC DEN1R*654 NC PHI-IS t+37799 US SPA#NCO191 a Client: Synagro CTS Prof. 2101-095 CM Cen 11k 37799 Project; Beaufort Regulatory Yea Sample Information Sampled C Wynne Oats i 01/13/21 Received J. Cameron jail01/13/21 Analyses and Results .t 3,1111111W = Loh IQ Sample ID r v 2 Arralyke Result eiult D rf 7 IS' Std. Meknods 0 Reference 2101-095 01 -01 €wd i r Fec.Callform-S 81900 CFLUp 6300 01114f21 CSC 9227C)- 141I- -02 30900 ++a 620 a0 -03 48 00 env: 697o -04 73900 um; 6720 -05 46900 awe 6690 -06 92600 GFI•uo 7130 -07 13200 cFwo 43580 Ceo^ n 47200 2101-095 0"i -01 3►.epe pr TS(°6) 15.9% 00: 0ff14121 CSC 2540 4•TS -02 16.2° 001 -03 14.3% 0.01 -04 14.9% 0.01 -05 155.0% aoi -06 14.0% 0.01 -07 15.2% ow Report 31)7LiRevw - //46/4411 ie Prof ect Manager Oats 219 S.Steele Si,. 919-208-4240 Sanford NC :7330 chrts@czernerontriting.com 4111111711" } j w- # 219 S. Steele Sir. Cameron Testing Services, Inc. chain of Custody Sanford. NC 27310 Page,O Phalle g1{}7r18 24 NC WW/GW Cert.I&4 NC PHHS Cer1 t 37799 US EPA NC019t8 Comp ay: 0ynagro Emit —sslasMiteynsgro.rAm CTS lab use only Conti ct: — eli C.d Boyd-- 11 S 'PhO . + *t Sample hemp . Lars Ii3 84 Boger Rd. Fox: Ice '} Address ictty, _— Stria,Zip) Mocksville, NC 2702E i n: PerreK(Y/N) Project: r Rush(YIN) , r Collected; Name: M lincld Boyd , , k, II, „,.. signature: • Sample Information Number of bottles 77 Requested Analysis s ID C]. �` z T. r , 'i I Preservatives: (tlinpreeerved. HfC]F, C'TS Lab Sample ID va L e _icy � ?- 'I -r142(S)O4, H(N)03,(Na)ThiosuIfate, Na(0)H, ID 0 F- S a r •gl r, .-I 5 , other(X),indicate .� I , -.1r t . � - 7 . - - -c - c4I Ci - . I. o{ - - - . . I I. - ,- T - • • 7..._ 4:0 • • • Relin'uished. Received: DatefTime ' . f. l - {Ai ( � .� I r ' 0 PM - Rush work will require prior approver. Additiana/ charges will apply SECTION 6 Agricultural Lime Application Log Year: 2021 Beaufort, NC Field Soil Lime Requirement Tons/Acre Date Applied (state-county-site-field) pH (tons/acre) Applied NC-CR-7-3A 5.7 0.7 0 N/A NC-CR-7-3B 5.4 0.8 0 N/A *Lime will be spread when conditions improve SECTION 7 NCDA&CS Agronomic Division Phone: (919)733-2655 Website: www.ncagr.gov/agronomi/ Report No. FY21-SL034243 ,c.i 1t4+•.• Client: Bobby Riggs Advisor: Chris Wynne ' :Wk.., Predictive 483 Weatherington Landing Rd Synagro LLC _$ �� ,it �� Stella, NC 28582 284 Boger Road 1 , Soil Report Mehlich-3 Extraction Mocksville, NC27028 .-::: '. Sampled County: Camden '66.y,i,.%;l '. Links to Helpful Information Client ID: 467267 Advisor ID: 509090 Sampled: 05/17/2021 Received: 06/17/2021 Completed: 06/24/2021 Farm: CR-07 Sample ID: 3A Recommendations: Lime Nutrients(lb/acre) More Crop (tons/acre) N P2O5 K2O Mg S Mn Zn Cu B Information Lime History: 1 -Soybean 0.7 0 0 50 0 0 0 0 0 0 Note: 3 2- 0.0 Test Results [units-WN in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]: Soil Class: Mineral HM% W/V CEC BS% Ac pH P-I K-I Ca% Mg% S-I Mn-I Mn-All Mn-Al2 Zn-I Zn-Al Cu-I Na ESP SS-I NO3-N 2.44 1.19 6.4 69 2.0 5.7 121 46 55 11 44 29 27 234 234 245 0.0 Sample ID: 3B Recommendations: Lime Nutrients(lb/acre) More Crop (tons/acre) N P2O5 K2O Mg S Mn Zn Cu B Information Lime History: 1 -Soybean 0.8 0 0 60 0 0 0 0 0 0 Note: 3 2- 0.0 Test Results [units-WN in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]: Soil Class: Mineral HM% W/V CEC BS% Ac pH P-I K-I Ca% Mg% S-I Mn-I Mn-All Mn-Al2 Zn-I Zn-Al Cu-I Na ESP SS-I NO3-N 0.51 1.33 4.3 64 1.5 5.4 348 39 46 14 40 84 60 278 278 538 0.0 e1 1orkh Carolina Reprogramming of the laboratory-information-management system that makes this report possible is being funded through a grant from the North Carolina Tobacco Trust Fund Commission. .# k rThank you for using agronomic services to manage nutrients and safeguard environmental quality. - Steve Troxler, Commissioner of Aqriculture Totr7CiwTruskfLindCi iibIm NCDA&CS Agronomic Division Phone: (919)733-2655 Website: www.ncagr.gov/agronomi/ Report No. FY21-SL034243 Bobby Riggs Page 2 of 3 Sample ID: 2 Recommendations: Lime Nutrients(Ib/acre) More Crop (tons/acre) N P2O5 K2O Mg S Mn Zn Cu B Information Lime History: 1 -Soybean 0.9 0 0 70 25 0 0 0 0 0 Note: 3 2- 0.0 Test Results [units-W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]: Soil Class: Mineral HM% W/V CEC BS% Ac pH P-I K-I Ca% Mg% S-I Mn-I Mn-All Mn-Al2 Zn-I Zn-Al Cu-I Na ESP SS-I NO3-N 0.46 1.38 4.0 59 1.6 5.2 329 34 48 7 38 68 51 252 252 599 0.0 NCDA&CS Agronomic Division Phone: (919)733-2655 Website: www.ncagr.gov/agronomi/ Report No. FY21-SL034243 Bobby Riggs Page 3 of 3 Understanding the Soil Report: explanation of measurements, abbreviations and units Recommendations Report Abbreviations Lime Ac exchangeable acidity If testing finds that soil pH is too low for the crop(s) indicated, a lime recommendation will be given in units of either B boron ton/acre or lb/1000 sq ft. For best results, mix the lime into the top 6 to 8 inches of soil several months before planting. BS% % CEC occupied by basic cations For no-till or established plantings where this is not possible, apply no more than 1 to 1.5 ton/acre (50 lb/1000 sq ft) at one Ca% % CEC occupied by calcium time, even if the report recommends more. You can apply the rest in similar increments every six months until the full rate CEC cation exchange capacity is applied. If MG is recommended and lime is needed, use dolomitric lime. Cu-I copper index ESP exchangeable sodium percent Fertilizer HM% percent humic matter Recommendations for field crops or other large areas are listed separately for each nutrient to be added (in units of K-I potassium index lb/acre unless otherwise specified). Recommendations for N (and sometimes for B) are based on research/field studies K20 potash for the crop being grown, not on soil test results. K-I and P-I values are based on test results and should be > 50. If they Mg% % CEC occupied by magnesium are not, follow the fertilizer recommendations given. If Mg is needed and no lime is recommended, 0-0-22 (11.5% Mg) is MIN mineral soil class an excellent source; 175 to 250 lb per acre alone or in a fertilizer blend will usually satisfy crop needs, SS-I levels appear Mn manganese only on reports for greenhouse soil or problem samples. Mn-All Mn availability index for crop 1 Mn-Al2 Mn-availability index for crop 2 Mn-I manganese index Farmers and other commercial producers should pay special attention to micronutrient levels. If$, pH$, $pH, C or Z M-O mineral-organic soil class notations appear on the soil report, refer to $Note: Secondary Nutrients and Micronutrients In general, homeowners do not N nitrogen need to be concerned about micronutrients. Various crop notes also address lime fertilizer needs; visit Na sodium ncagr.gov/agronomi/pubs.htm. NO3-N nitrate nitrogen ORG organic soil class Recommendations for small areas, such as home lawns/gardens, are listed in units of lb/1000 sq ft . If you cannot find pH current soil pH the exact fertilizer grade recommended on the report, visit www.ncagr.gov/agronomi/obpart4.htmsfind information that P-I phosphorus index may help you choose a comparable alternate. For more information, read A Homeowner's Guide to Fertilizer.. P205 phosphate S-I sulfur index Test Results SS-I soluble salt index W/V weight per volume Zn-Al zinc availability index The first seven values [soil class, HM%, W/V, CEC, BS%, Ac and pH] describe the soil and its degree of acidity. The Zn-I zinc index remaining 16 [P-I, K-I, Ca%, Mg%, Mn-I, Mn-A11, Mn-Al2, Zn-I, Zn-Al, Cu-I, S-I, SS-I, Na, ESP, SS-I, NO3-N (not routinely www.ncagr.gov/agronomi/uyrst.htm available)] indicate levels of plant nutrients or other fertility measurement. Visit