WQ0031674_Residual Annual Report 2021_20220214

Non-Discharge Branch Upload/Submittal Form
NORTH CAROLINA
EnWron.M&IQualfty
Version 2-Revised June 23.2020
Initial Review
Reviewer Thornburg,Nathaniel D
Is this submittal an application?(Excluding additional information.)*
Yes No
If not an application what is the submittal type?* Annual Report
Residual Annual Report
Additional Information
Other
Annual Report Year* 2021
Permit Number(IR)* WQ0031674
Applicant/Permittee City of Marion
Email Notifications
Does this need review by the hydrogeologist?* 0 Yes • No
Regional Office Asheville
CO Reviewer
Admin Reviewer

Submittal Form
Project Contact Information
Please provide information on the person to be contacted by NDB Staff regarding electronic submittal,confirmation of receipt,and other correspondence.
............................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................
Name* Benjamin Worley
Email Address* Phone Number*
[e-mail] 8286522428
Project Information
Application/Document Type* New(Fee Required) Modification-Minor
Modification-Major(Fee Required) Renewal
Renewal with Major Modification(Fee GW-59, NDMR,NDMLR, NDAR-1,
Required) NDAR-2
Annual Report Residual Annual Report
Additional Information Change of Ownership
Other
We no longer accept these monitoring reports through this portal. Please click on the link below and it will take you to the correct form.
https://edocs.deq.nc.gov/Forms/NonDischarge_Monitoring_Report
Permit Type:* Wastewater Irrigation High-Rate Infiltration
Other Wastewater Reclaimed Water
Closed-Loop Recycle Residuals
Single-Family Residence Wastewater Other
Irrigation
Permit Number:* WQ0031674
Has Current Existing permit number
Applicant/Permittee Address* City of Marion P.O Drawer 700 Marion,NC 28752
Facility Name* City of Marion Class A Residuals Program
Please provide comments/notes on your current submittal below.
City of Marion
Water Treatment Plant
2021 Annual Report
Land Application Program
Permit No.WQ0031674
At this time,paper copies are no longer required.If you have any questions about what is required,please contact Nathaniel Thornburg
at [e-mail].
Please attach all information required or requested for this submittal to be reviewed here.*
(Application Form,Engineering Plans,Specifications,Calculations,Etc.)
Marion WFP 2021 Annual Report.pdf 3.76MB
Upload only 1 PDF document(less than 250 MB).Multiple documents must be combined into one PDF file unless file is larger
than upload limit.
* By checking this box, I acknowledge that I understand the application will not be
accepted for pre-review until the fee(if required)has been received by the Non-
Discharge Branch.Application fees must be submitted by check or money order and
made payable to the North Carolina Department of Environmental Quality(NCDEQ).
I also confirm that the uploaded document is a single PDF with all parts of the
application in correct order(as specified by the application).
Mail payment to:
NCDEQ—Division of Water Resources
Attn:Non-Discharge Branch
1617 Mail Service Center
Raleigh,NC 27699-1617

Signature
Submission Date 2/14/2022

CITY OF MAfION — � V 5 .c Y .,
j , 'Y- xs 27
2021
City of Marion
Water Treatment Plant
2021 Annual Report
Land Application Program
Permit No. WQ0031674

ANNUAL LAND APPLICATION CERTIFICATION FORM
WQ Permit#: WQ0031674 County: McDowell Year: 2021
Facility Name(as shown on permit): City of Marion, WTP
Land Application Operator: US Biosolids, Inc. Phone: [phone]
Land application of residuals as allowed by the permit occurred during the past calendar year?
a Yes D No - If No,skip Part A,and Part I3 and proceed to Part C. Also, If residuals were
generated but not land applied, please attach an explanation on how the residuals were handled.
Part A- Residuals A t a lication Summar
Total number of application fields in the permit: NA
Total number of fields utilized for land application during the year:J 6
Total amount of dry tons applied during the year for all application sites: 49.12
Total number ofacres utilizes for land application during the year: 42
Part B-Annual Compianee Statement:
Facility was compliant during calendar year 2021 with all conditions of the land application permit
(including but not limited to items 1-13 below) issued by the Division of Water Resources. l:3 Yes ❑ No
If no please, provide a written description why the facility was not compliant,the dates,and explain corrective action
taken.
t) Only residuals approved for this permit were applied to the permitted sites.
2) Soil pH was adjusted as specified in the permit and lime was applied(if needed)to achieve a soil pH of at least 6.0 or
the limit specified in the permit.
3) Annual soils analysis were performed on each site receiving residuals during the past calendar year and three(3)copies
of laboratory results are attached.
4) Annual TCLP analysis(if required) was performed and three(3)copies of certified laboratory results are attached.
5) All other monitoring was performed in accordance with the permit and reported during the year as required and three
(3)copies of certified laboratory results are attached.
6) The facility did not exceed any of the Pollutant Concentration Limits in 15A NCAC 02T .1105(a)or the Pollutant
Loading Rates in I SA NCAC 02T.1 105(b)(applicable to 40 CFR Part 503 regulated facilities).
7) All general requirements in as specified in the Land Application Permit were complied with (applicable to40 CFR Part
503 regulated facilities).
8) AU monitoring and reporting requirements in I5A NCAC 02T.1 1 1 1 were complied with (applicable to 40 CFR Part
503 regulated facilities).
9) All operations and maintenance requirements in the permit were complied with or. in the case of a deviation. prior
authorization was received from the Division of Water Resources.
10) No contravention of Ground Water Quality Standards occurred at a monitoring well or explanations of violations are
attached to include appropriate actions and remediations.
11) Vegetative cover was maintained and proper crop management was performed on each site receing residuals, as
specified in the permit.
12) No runoff of residuals from the application sites onto adjacent property or nearby surface waters has occurred.
13) All buffer requirements as specified on the permit were maintained during each application of residuals.
Part C-Certification:
"I certify,under penalty of law, that the above information is, to the best of my knowledge and belief,true,accurate,
and complete. I am aware that there are significant penalties for submitting false information, including the
possibility of fines and imprisonment for knowing violation "
C.:4-117 q",a _ a _� Z- (-2022.
Permittee Name and Title(type or print) Si azure of Permittee Date
_
Signatus* of Preparer* Date S gnature of Land Applier Date
(if different from Permittee) (if different from Pcrmittee arid Preparer)
Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 02T 1 102 (26) DE.NR FORM ACF (12/2006)

CLASS A ANNUAL DISTRIBUTION AND MARKETING/ SURFACE DISPOSAL CERTIFICATION AND SUMMARY FORM
kIVQ PERMIT#: WQ003 1674 FACILITY NAME: City of Marion, WTP
PHONE: [phone] COUNTY: McDowell OPERATOR: Ben Worley
FACILITY TYPE(please check one): U Surface Disposal (complete Part A(Source(s)and "Residual In"Volume only)and Part C)
El Distribution and Marketing(complete Parts A, B,and C)
Vas the facility in operation during the past calendar year? Yes 0 No 0 —• If No skip parts A, B,C and certify form below
Part A*: Part B*:
Volume(dry tons) Recipient Information
Sources(s)(include NPDES tt if
Month Amendment/
applicable) Residual In Product Out Name(s) Volume(dry tons) Intended use(s)
Bulking Agent
anuary
'ebruary
larch
Lpril
lay
tine I
my ,
,ugust _
eptember NCG590032 0 3.83 3.83 Miller 3.83 Soil Admedment
►etober NCG590032 0 32.3 32.3 Miller 32.3 Soil Admedment
lovember __ NCG590032 0 7.99 7.99 Miller 7.99 -Soil Admedment
lecember
Total from FORM DMSDF(sup)
'otals: Annual (dry tons): 0 44.12 44,12 44.12
Amendment(s)used:1 0 Bulking Agent(s)used: 0
If more space is required,attach additional information sheets(FORM DMSDF(supp)): Total Number of Form DMSDF(Supp)I
art C:
'acility was compliant during the past calendar year with all conditions of the land application permit 0 Yes
including but not limited to items 1-3 below)issued by the Division of Water Resources: 0 No— P If No, Explain in Narritive
. All monitoring was done in accordance with the permit and reported for the year as required and three(3)copies of certified laboratory results are attached.
. All operation and maintenance requirements were compiled with or,in the case of a deviation,prior authorization was received from the Division of Water Resources.
. No contravention of Ground Water Quality Standards occurred at a monitoring well.
I certify,under penalty of law,that the above information is, to the best of my knowledge and belief, true,accurate and complete. I am aware that there are significant
enalties for submitting false information,including the possibility of fines and imprisonment for knowing violations."
//I .
:gnature Permittee ` Date Signature off Preparer** Date
(if different from Permittee)
:*Preparer is defined in 40 CFR Part 503.9(r)and 15A NCAC 2T.1102(26)
DENR FORM DMSDF (1212006)

ANNUAL RESIDUAL SAMPLING SUMMARY FORM
Please note that your permit may contain additional parameters to be analyzed. The parameters can be reported in FORM RSSF- B
WQ Permit Number: WQ0031674 Laboratory: 1) Statesville Analytical
Facility Name: City of Marion, WTP 2)
Residual Source WQ #or - 3)
NPDI;S#: NCG590032 4)
WWTP Name: 5)
City of Marion, WTP
Residual Analysis Data
Conc. Sample or Composite Date
Parameter Limit
12-30-21
(mg/kg) (mg/kg)a _ ,
Percent Solids(%) NA 1.18
Arsenic 75 0.17 ,
Cadmium 85 0.085
Copper 4,300 27.97 _
Chromium NA NA
lead 840 _ 5.678 ry _ _
Mercury 57 0.534
Molybdenum 75 0.678 _ -
Nickel 420 3.559 --
Selenium 100 0.847
Zinc 7,500 73.729
Total Phosphorus NA 508.5 _
TKN NA 5647.5 L _
rAmmonia-Nitrogen NA 104.2
Nitrate and Nitrite NA 0,1 _ J -
'For surface disposal facilities the ceiling concentration limits listed in this form are not applicable. Reference the individual permit for metals limits.
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed
to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant
penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations."
_.../fe-,..7,g.--_-,-,-...,....-1 Jc;2 Z ,4-4-1/ 7 -it, •2._2__
Signature di Preparer* O Date
*Preparer is defined in 40 CFR Part 503.9(r)and 15A NCAC 21-.l 102(26) DENR FORM RSSF (12/2006)

ANNUAL RESIDUAL SAMPLING SUMMARY FORM - B
Report all sampling analysis results for parameters riot listed in FORM RSSF that are part of the WQ permit or were analyzed for over the past
calendar year. Use additional forms as needed.
WQ Permit Number: WQ0031674 Laboratory: 1) Statesville Analytical
Facility Name: City of Marion, WTP 2)
Residual Source 3)
NPDES#or WQ#: NCGS90032 4)
WWTP Name: 5)
City of Marion. WTP
Residual Analysis Data
Sample or Composite Date
Parameter
12-30-21
(mg/kg) ` _
Aluminum 4194.92
Calcium 6805.08 _
Magnesium 997 _ _ _ __ _ _ ._
pH 6.94 _
Potassium 73.6
Sodium 949.15
W
PAN 2269.5
SAR 0.31 _ _
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system
designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are
significant penalties for submitting false information,including the possibility of fines and imprisonment for knowing violations_"
XL-5., r 72-----, Z--t7 ,4 ,
Signature ofi'reparer* Date
*Preparer is defined in 40 CPR Part 503.9(r) and 15A NCAC 2T .1102(26) DENR FORM RSSF - B (1212006)

ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (503 Rules)
Facility Name: City of Marion, WTP WQ Permit Number: WQ0031674
WWTP Name: City of Marion, WTP
NPDES Number: NCti590032
Monitoring Period: From I/1/2021 To 12/31/2021
Pathogen Reduction (40 CFR 503.32) - Please indicate level achieved and alternative performed:
Alternative I Cl Alternative 2 ❑ Alternative 3 ❑
Class A: — Alternative 6 El
Altertiati��e 4 ❑ Alternative 5 ❑
If applicable to alternative performed (Class A only) indicate"Process to Further Redu�etPa oo hil c'- CICompost ❑ Heat Drying ❑ Heat Treatment 0 p !
Beta Ray ❑ [ Gamma Roy ❑ 1 Pasteurization ❑
Class B: [ Alternative 1 ❑ I Alternative 2 ❑ _if applicable to alternative performed (Class B only) indicate "Process to Significantly Reduce Pathogens": ,
1 Composting, ❑ AeI'obie Digestion 0
_ Air Dtvg.7 l )� ._._�._w...�
Lime Stabilization ID j _ _ in �_..._..__. ._ ---- ----.---•---.'
Anaerobic Digestion ❑ I
If applicable to alternative performed (Class A or Class B) complete the r�olrlowing monitoring data: ytecai
Allowable Level Pathogen Density Frequency ber orSample Tech-
f:xcee of Analysis Type ,tio::
Parameter in Sludge Minimum Geo. Mean Maximurri Units dcnces
2x10tothe MPN
6th power
per grain of CFU
Fecal Coliform total solids
1000 mpn per gram
of total solid (dry
weight) '"
Salmonella bacteria 3 MPN per 4 grams
(in lieu of fecal total solid(dry
coil form) weight)
Vector Attraction Reduction (40 CFR 503.33) - Please indicate option performed:A1t.I (VS reduction) 0 Alt.2 (40-day bench) Di Alt. 3 (30-day bench) 01Alt 4
(Spec O, uptake) A
Alt. 5 (14-Day Aerobic) ❑ Alt. 6(Alk. Stabilization ❑ Alt 7(Drying- Stable) D'Alt. 8 (Drying- Unstable) ❑
Alt. 9 (injection) U Alt, 10(Incorporation) 0 No vector attraction reduction alternatives were performed ll
CERTIFICATION STATEMENT (please check the appropriate statement)
` "I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32 and the vector
attraction reduction requirement in 40 CFR 503.33 have been met."
"I certify, under penalty of law,that the pathogen requirements in 40 CFR 503.32 and the vector
attraction reduction requirement in 40 CFR 503.33 have not been met." (Please note if you check
this statement attach an explanation why you have not met one or both of the requirements.)
"This determination has been made under my direction and supervision in accordance with the system
designed to ensure that qualified personnel properly gather and evaluate the information used to determine
that the pathogen and vector attraction reduction requirements have been met. I am aware that there are
significant penalties for false certification including fine and imprisonment."
1r�.��.`.�, e:4r / WiP {� -, 17 Dennis Key US Biosolids, Inc.
Preprer Name and Title (te o'r print) Land Applier Name and Title (if applicable)(type or print)
C(' -'4 -1''' "'" V-1Z19/ ,12-,-
i7ei . 7IV P 4-414.1
Si gna re of Prcparer* Date Signature of l,arrd Applier (if applicable) Date
*Preparer is defined in 40 CFR Part 503.9(r)and I SA NCAC 2T .1102(26)
DENR FORM PVRF 503 (12/2006)

Analytical Results ._ s. ANAL TICAL
U.S. Biosolids inc '` . _ .•r.
958 Hoots Road
Roaring River, NC 28669
Receive Date: 12/30/2021
Reported: 01/25/2022
For: Marion
Comments:
Sample Number Parameter Sample ID Result Unit Method Analyzed Analyst
211230-20-01 Aluminum Marion 4194.92 mg/kg 5M3111 D•2o11 01/07/2022 MD
211230-20-01 Ammonia Nitrogen Marion 104.237 mg/kg 5M45001F BE-1897 01/03/2021 CE/LE
211230-20-01 Arsenic-Solid Marion 0,17 mg/kg SM3113 B•2OO4 01/05/2022 MD
211230-20-01 Cadmium-Solid Marion <0.085 mg/kg SM31118•1999 01/0512022 MD
211230-20-01 Calcium Marion 6805.08 mg/kg 8M3111B 2011 01/06/2022 MD
211230-20-01 Copper-Solid Marion 27.97 mg/kg 5M3111B-2011 01/04/2022 MD
211230-20-01 Lead-Solid Marion 5.678 mg/kg SM31135 01/07/2022 MD
211230-20-01 Magnesium Marion 997 mg/kg EPA 2CO r 01/06/2022 MD
211230-20-01 Mercury Solid Marion 0.534 mg/kg SM3112B•2011 01/21/2022 MD
211230-20-01 Molybdenum-Solid Marion 0.678 mg/kg EPA20a.7 01/19/2022 MT
211230-20-01 Nickel-Solid Marion 3.559 mg/kg SM3113 8 01/04/2022 MD
211230-20-01 Nitrate/Nitrite- Marion <0.1 mg/kg SM45COF/A 01/04/2022 CL
Solids
211230-20-01 Percent Solids Marion 1.18 % SM2S40B•2C11 01/03/2022 MD
211230-20-01 pH Marion 6.94 Sid. Units SM45ocHB-2011 12/30/2021 CL
211230-20-01 Potassium -Solid Marion 73.6 mg/kg EPA2ab.' 01/19/2022 MT
211230-20-01 Selenium Solid Marion <0.847 mg/kg SM3113B 01/19/2022 MT
211230-20-01 Sodium-Solid Marion 949.153 mg/kg SM 3111 8 01107/2p22 MD
211230-20-01 T. Phosphorus Solid Marion 508.5 mg/kg SM45OOPE•2011 12/30/2021 CL
211230-20-01 TKN Marion 5647.46 mg/kg SM4601:N0r0 B•2C11 01/05/2022 CE
211230-20-01 Zinc-Solid Marion 73.7288 mg/kg 5M31118-2011 01/04/2022 MD
Respectfully submitted,
Melissa Myers
NC Cert#440,
NCDW Cert#37755,
EPA#NC00909
PO Box 228 •Statesville, NC 28687 •704/872/4697
Page 1 of 8

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SAR
Sodium Absorption Ratio NajMg/L). CajMg./L1 Mg(MgIL1
Na : Sodium (Mg/L) Equivalent weight: 23 11.2 I 80.29 11.76
Ca : Calcium (Mg/L) Equivalent weight: 20
Mg : Magnesium(Mg/L) Equivalent weight: 12 Na(ME) Ca(ME) Mg (ME)
0.486957 4.0145 0.98
Milli Equivalent= MgJL/Equivalent weight The amour
amount of
SAR= Na Milli Equivalent/10.5 X (Ca Milli Equivalent+ Mg Milli equivalent)]0.5 power
Permitting
I SAR= 0.308148 (From Mg/L entered above)
[SAR= 0.310214 1(From ME entered below)
Na ME) Ca(II/ 1 Mc (ME)
0.49 L 4.01 0.98

Pace AnaiyYtat Services,ILO
ceArralytrcal. 9800 tCncey Ave. Sate 100
NC 7e0713
urnr.alytssaa Hunters+ntie,)875-MS2
t7o4)B75-�o92
ANALYTICAL RESULTS
Protect: 211165-08-01
Pace Project No 92571292
Semple: 211105-08-01 Lab IV: 92571292001 Collected: 11/04/21 11:00 Received 11/08/21 12:00 Matrix:Water
Parameters Results Units Report Lima OF Prepared Analyzed GAS No. qual
Pesticides(GC)80818 TCLP Analytical Method:EPA 80818 Preparation Method:3510C
Leachate Method/Date:1311;12/15/21 10:35
Pace National-Mt.Juliet
Chlordane(Technical) ND mg/€ 000500 1 12/19/21 10:13 12(20/210026 57-74.9 H3
Endrin ND mg/L 0 00500 1 12119/21 10:13 12/2812101126 72-20-8 H3
Heptachlor ND mgli 0.00500 1 12/19/21 10:13 12/2012100:26 76-44-8 H3
Heptachlor epoxide NC mg/L 0.00500 t 12719/21 10-13 12/20/21 00'26 1024-57-3 H3
gamma•B14C(Lindane) ND mg!L 0.00500 1 12/19/21 10:13 12/20121 00'26 58-89-9 H3
Methoxychlor ND mg/L 0.00500 I 1211 912 1 10:13 12/2012100:26 72-43-5 H3
Toxaphene ND mg/L 0.0100 1 1211912110:13 12121312100:26 8001.35.2 H3
Surrogates
0ecachlorobiprenyl(5) 99.2 11, 10 0-128 1 12/19/21 10:13 12/2012100:26 2051-24-3
Tetrachloro-m-xylene(S) 85.6 % 10.0-127 1 12/19/21 10:13 12/20/21 00:26 877-09-8
Chlorinated Herb.(GC)8151A Analytical Method:EPA 8151A Preparation Method:8151A
Leachate Method/Date:1311;12/15.21 10.35
Pace National-Mt.Juliet
2,4.5-TP(5itaex) ND mg/L 0.00200 I 12120/21 08:06 12/21121 10:31 93-72.1 113
2,449 ND mg/ 0.60200 1 12/20/2108.06 12/2112110:31 94.75.7 H3
Surrogates
2,4-0CAA(S) 74-8 % 14.0.158 1 12/20/21 08:06 12/21121 10:31 19719-28-9
8082 GCS PCB RVE Analytical Method:EPA 8082A Preparation Method:EPA 3510C
Pace Analytical Services-Charlotte
P08-1016(Proctor 10161 ND ug/L 0.50 1 11112/21 05:39 102121 16:36 12674.11-2
PCB-1221(Proctor 1221) ND ug/L 0.50 1 11112/21 05:39 102/21 16:36 11104-28-2
PC8-1232(Proctor 1232) ND ug/L 0.50 1 11112/21 05:39 11112t21 16:36 11141-16-5
P08-1242(Proctor 1242) NO uglt. 0.50 1 11/12/21 05:39 11/12/21 16:36 53469-21-9
P08-1248(Proctor 1248) NO ug/L 0.50 1 11112/21 05:39 11/12/21 16:36 12672-29-6
P08-1254(Proctor 12541 ND ug/L 0.60 1 11112/21 05:39 11/12/21 16:36 11097,69.1
P08-1260(Aroder 1260) ND ug/1. 0.50 1 11/12121 05:39 11112121 16:36 11096-82-5
Surrogates
Decachiorobiphenyl42) 66 % 10.181 1 11112/21 05:39 11112121 16:36 2051-24.3
8082 TCLP PC8s RVE Analytical Method'EPA 8082A Preparation Method'EPA 3510C
LeaChate Method/Dale:EPA 1311;11/09121 15:21 Initial pH';Final pH'5
Pace Analytical Services-Charlotte
PCB-1016(Proctor 1016) ND ug/L 1000 1 11110/21 20:29 11/11121 13:08 12674.11-2
P08-1221(Aroclor 1221) NO ug/L 1000 1 11110/21 20:29 11111121 13:08 11104-28-2
PC8.1232(Proctor 1232) N0 ug/L 1000 1 11110/21 20:29 11/11/21 13:08 11141.16.5
P06-1242(Aroc)or 1242) ND ugh. 1000 1 11/10/21 20:29 11/11f21 13.08 53469.21.9
P08-1248(Proctor 1248) ND ug/L 1000 1 11/10121 20:29 11/11121 13:08 12672-29-6
PCB-1254(Proctor 1254) ND ug/L 1000 1 11/10/21 20:29 11/11/21 13:08 11097-69-1
PC8.1260(Arador 1260) ND ug1L 1000 1 11110/21 20:29 11/11/21 13:08 11096-82-5
Surrogates
Decachlnrnhiphenyt(5) 96 e/, 10-181 1 11110121 20:29 11/11121 13:08 2051-24.3
REPORT OF LABORATORY ANALYSIS
TAs report anal nal be reproduced.except in iva.
Date:12/22/2021 04:42 PM ,Selhojl the*rotten consenter;lee Analytical Services.LLC Page 5 of 29
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 8 of 32

Pace Analytical Services,LLC
/7 �/n+ �r�! /�r�f ar 9800 Krneey Ave_ Sena 100
ce, lClf lca, Huntersvi®e,NC 28078
wwtweist.eeel PO4)878,9092
ANALYTICAL RESULTS
Project; 211105-08-01
Pace Project No.. 92571292
Sample: 211105.08.01 Lab 1D: 92571292001 Collected: 11/04721 11:00 Received. 11108/21 12:00 Matrix: Water
Parameters Results Units Report Lirmt OF Prepared Analyzed CAS No. Suai
6010 MET ICP.TCLP Analytical Method:EPA 6010D Preparation Method.EPA 3019A
Leachate rvtethod/Date:EPA 1311:11/09/21 15:21 iniliai pH::Final pH;2
Pace Analytical Services•Asheville
Arsenic ND mg/L 0.050 1 11/11121 02:52 11116/21 23:23 7440-38-2
Barium ND mg/L 0.25 1 11/11/2102.52 11116/2123.23 7440-39-3
Cadmium ND mgf. 0.0050 1 11/11/21 02:52 11/16/2123.23 7440-43-9
Chromium ND mg/L 0.050 1 11111121 02:52 11/1612123.23 7440-47-3
Lead ND mg/L 0.025 1 11/11/21 02:52 11/16/21 23:23 7439-92-1
Selenium ND mg/L C.10 1 11/11/2182:52 11/16/2123:23 7782-49-2
Silver ND mg/L 0.026 1 11/11f2102:52 11/18/21 23:23 7440-22-4
7470 Mercury,TCLP Analytical Method:EPA 7470A Prertaralton Method:EPA 7470A
Leachale Method/Date:EPA 1311:11/09/21 15:21 initial pH:;Peal ph.2
Pace Analytical Services-Asheville
Mercury ND mg/I. 0.00020 1 1111112108:30 11/18/21 12:05 7439-97-6
8270E TCLPRVE Analytical Method:EPA 8270E Preparation Method:EPA 3510C
LeaChate Method/flare:EPA 1311; 11/09/21 15:21 initial ph:;Final pH.5
Pace Analytical Services•Charlotte
1 4-Dichiorobenzene ND ug/L 50 0 1 11/10/21 10.40 11111/21 21:C7 106.46.7
2,4-Dinitratoluene NO ug/L 50.0 1 11/10/21 16:40 11/1t/2121:07 121-14-2 Li
Hexachloro-1.3-buladierte NO ug/L 50.0 1 11/10121 16:40 11/11/21 21:07 87-88-3
Hexachlorobenzene ND ug& 50.0 1 11/10/21 16:40 11/11121 21:07 118-74-1
Hexachloroelhane ND ug/L 500 1 1111C/21 16:40 11/11/21 21:07 67-72.1
2-Melhylphenol(o-Cresol) NO ug/L 50.0 1 11/10/21 16:40 11/11)21 21:07 95-48-7
3&4-Methylpheno€(m&pCresol) ND ug/L 50.0 1 11/10/21 16:40 11/11/21 21:07 15831-10-4
Nitrobenzene ND ug/L 50.0 1 11110/21 16:40 11/11/21 21:07 98-95-3
Pentachlorophenol ND ug/L 100 1 1111012116:40 11/1112121.07 87.16.5
Pyridine NO ug/L 50.0 1 11/10/21 16:40 11/1712121:07 110-86-1
2,4.5-Tdchlamophenol NO ug/L 50.0 1 11110/2116:40 11/11/21 21:07 95-95.4
2.4.6-Trichloraphenol ND ug/L 50.0 1 11/1012116:40 11/11/2121.07 86-06-2
Surrogates
Nitrober12ene-d5(S) 101 % 10-144 1 11/10121 16:40 11/11/21 21:07 4165.60-0
2•Fluorebiphenyl(S) 84 % 10.130 1 11110/21 15.40 11/11/21 21:07 321-60-8
Terphenyl-414(5) 124 % 34.163 1 11/10/21 15.40 11/11121 21.07 1718-51-0
Phenol-416(S) 50 % 10-130 1 11110/21 16:40 11/11/21 21:07 13127-88-3
2-Fluorophenal(S) 62 % 10-130 1 11i10/21 18:40 11/11/21 21:07 367-12-4
24.6-Tribromophenot(S) 81 % 10.144 1 11/10/21 16:40 11/11/21 21:07 118.79.6
8280D MSV TCLP Analytical Method:EPA 826013 Leachate Method/Date:EPA 1311;11/18/21 08:58
Pace Analytical Services-Charlotte
Benzene ND ug/L 100 20 11/18/21 16:11 71-43-2
2-6utanone(MEK) ND ug/L 200 20 11118/21 16:11 78-93-3
Carbon tetrachloride ND u91i. 100 20 11/18/21 16:11 56-23-5
Chloraben2ene ND ug/L 100 20 11/18/21 16:11 108-90-7
Chloroform ND ug/t. 100 20 11/18/2116:11 67-66-3
1.4•Dichioroben2ene ND ug1L 100 20 11/18/2116:11 106-46-7
REPORT OF LABORATORY ANALYSIS
This report shad net be reproduced,exeepl in lull.
Date:12/22/2021 04.42 PM without the mitten consent of Pace Analyircal Services,LIC Page 6 of 29
PO Box 228 •Statesville, NC 28687 • 704/872/4697
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Pace Anatytical Services.ILO
t
le Analytical 98001nce/Ave. ' 100
% ,. Hun,.....NC 2t1078
view.i icetiLr.roe [phone]
ANALYTICAL RESULTS
Project: 211105-08.04
Pace Project No 92571292
Sample: 211105.06.01 Lab ID: 92511292001 CoElecled: 11/04/21 11.00 Rececver. 11/08121 12:00 Matrix:Water
Parameters Results Units Report Limit OF Prepares Analyzed CAS No. Qual
8260D MSV TCLP Anaiyticaf Method:EPA 8260D Leachale Mellwd2Date:EPA 1311;11118121 08:59
Pace Analytical Services-Charlotte
1,2-Dichloroethane NO ug1L 100 20 1111812116:11 107-06-2
1,1-Dichioroetbene NO ug1L 100 20 11N812116:11 75-35.4
Tetrachloroethene ND ug/L 100 20 11/1B/21 16:11 127-18.4
Trichloroethene ND ug/L 100 20 11118/21 16:11 79.01.6
Vinyl chloride ND ug/L 100 24 11/18/21 16:11 75.01-4
Surrogates
1,2-Dichloreetliane.4IS) 92 95 70-130 20 11/18121 16.11 17060.07.0
Toluene-d8(94 111 "4 67-135 20 yin 8l21 15.11 2037-28-5
4-Brdnlofluorobenzene 0) 97 %r 70-130 20 11118/21 16.11 460-00-4
1010 Flashpoint,Closed Cup Analytical Method:EPA 10108
Pace Analytical Services-Asheville
Ftashpoinl a•200 deg F 1 11/21/21 12.00
9040 pH Analytical Method:EPA 9040C
Pace Analytical Services-Asheville
pH a1 25 Degrees C 6.4 Std.Uni1S 0.10 1 11/21121 14:22 06.H3
909S Paint Filter Liquid Test Analytical INethad:EPA 90958
Pace Analytical Services-Asheville
Free Liquids FAIL 1.0 1 11112/21 14:14
733C S Reactive Cyanide Analytical Method:EPA 9014 Preoeration Method:SW-846 7.3.3.2
Pace Analytical Services-Greensburg
Cyanide,Reactive ND n191kg 1.0 1 11118/21 08:00 11/19/21 10.09 Hi
Cyanide.Reactive ND mgltig 1.0 1 11/24121 14:14 11/26/21 11:57 H3
7343 Reactive Sulfide Analytical Method.SM 4500-S2-F-2011 Preparalion Method'SW-846 7.3.4.2
Pace Analytical Services-Greensburg
Sulfide.Reactive ND mg111g 25 I 11/24/21 11:51 11/24(2111:54 H3
Sulfide,Reactive ND mg/kg 100 1 11/18/21 14:52 11/18/21 15:10 H3
REPORT OF LABORATORY ANALYSIS
This report that no4 be reproduced,encepa in full.
Date:12/22/2021 04:42 PM wrlhout the wnllrn curisent or Pace nnatytical Services.LLC Page 7 of 29
PO Box 228 • Statesville, NC 28687 • 704/872/4697
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