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HomeMy WebLinkAboutWQ0001953_Residual Annual Report 2021_20220210Non -Discharge Branch Upload/Submittal Form NORTH CAROLINA En.anmemfal Qualify Version 2 - Revised June 23, 2020 Initial Review Reviewer EADS\ndthornburg Is this submittal an application? (Excluding additional information.)* Yes No If not an application what is the submittal type?* Annual Report Residual Annual Report Additional Information Other Annual Report Year* 2021 Permit Number (IR) * WQ0001953 Applicant/Permittee Town of Spindale Email Notifications Does this need review by the hydrogeologist?* Yes • No Regional Office CO Reviewer Admin Reviewer Asheville Submittal Form Project Contact Information Please provide information on the person to be contacted by NDB Staff regarding electronic submittal, confirmation of receipt, and other correspondence. Name* Guy O'Connor Email Address* Phone Number* goconnor@spindalenc.net 8282863403 Project Information Application/Document Type * New (Fee Required) Modification - Major (Fee Required) Renewal with Major Modification (Fee Required) Annual Report Additional Information Other Modification - Minor Renewal GW-59, NDMR, NDMLR, NDAR-1, NDAR-2 Residual Annual Report Change of Ownership We no longer accept these monitoring reports through this portal. Please click on the link below and it will take you to the correct form. https://edocs.deg.nc.gov/Forms/NonDischarge_Monitoring_Report Permit Type: * Wastewater Irrigation Other Wastewater Closed -Loop Recycle Single -Family Residence Wastewater Irrigation Permit Number:* WQ0001953 Has Current Existing permit number Applicant/Permittee Address* PO Box 186 Spindale NC 28160 Facility Name* Town of Spindale Class B Residuals Program Please provide comments/notes on your current submittal below. High -Rate Infiltration Reclaimed Water Residuals Other At this time, paper copies are no longer required. If you have any questions about what is required, please contact Nathaniel Thornburg at nathaniel.thornburg@ncdenr.gov. Please attach all information required or requested for this submittal to be reviewed here. * (Application Form, Engineering Plans, Specifications, Calculations, Etc.) 2020 LAND APPICATION ANNUAL REPORT.pdf 13.56MB Upload only 1 PDF document (less than 250 MB). Multiple documents must be combined into one PDF file unless file is larger than upload limit. By checking this box, I acknowledge that I understand the application will not be accepted for pre -review until the fee (if required) has been received by the Non - Discharge Branch. Application fees must be submitted by check or money order and made payable to the North Carolina Department of Environmental Quality (NCDEQ). I also confirm that the uploaded document is a single PDF with all parts of the application in correct order (as specified by the application). Mail payment to: NCDEQ — Division of Water Resources Attn: Non -Discharge Branch 1617 Mail Service Center Raleigh, NC 27699-1617 Signature lj 0Cor ve Submission Date 2/10/2022 2020 Town of Spindale Wastewater Treatment Plant 2020 Annual Report Land Application Program Permit No. WQ0001953 ANNUAL LAND APPLICATION CERTIFICATION FORM WQ Permit#: WQ0001953 County: Facility Name (as shown on permit): Land Application Operator: Rutherford Year: 2020 Town of Spindale US Biosolids, Inc. Phone: 336-957-7871 Land application of residuals as allowed by the permit occurred during the past calendar year? Yes No - If No, skip Part A, and Part B and proceed to Part C. Also, If residuals were generated but not land applied, please attach an explanation on how the residuals were handled. Part A - Residuals Application Summary: Total number of application fields in the permit: 6 Total number of fields utilized for land application during the year: 4 Total amount of dry tons applied during the year for all application sites: 10.2 Total number of acres utilizes for land application during the year: 58.3 Part B - Annual Compiance Statement: Facility was compliant during calendar year 2020 with all conditions of the land application permit (including but not limited to items 1-13 below) issued by the Division of Water Resources. 0 Yes 0 No If no please, provide a written description why the facility was not compliant, the dates, and explain corrective action taken. 1) Only residuals approved for this permit were applied to the permitted sites. 2) Soil pH was adjusted as specified in the permit and lime was applied (if needed) to achieve a soil pH of at least 6.0 or the limit specified in the permit. 3) Annual soils analysis were performed on each site receiving residuals during the past calendar year and three (3) copies of laboratory results are attached. 4) Annual TCLP analysis (if required) was performed and three (3) copies of certified laboratory results are attached. 5) All other monitoring was performed in accordance with the permit and reported during the year as required and three (3) copies of certified laboratory results are attached. 6) The facility did not exceed any of the Pollutant Concentration Limits in 15A NCAC 02T .1 105(a) or the Pollutant Loading Rates in 15A NCAC 02T .1105(b) (applicable to 40 CFR Part 503 regulated facilities). 7) All general requirements in as specified in the Land Application Permit were complied with (applicable to 40 CFR Part 503 regulated facilities). 8) All monitoring and reporting requirements in 15A NCAC 02T .1111 were complied with (applicable to 40 CFR Part 503 regulated facilities). 9) All operations and maintenance requirements in the permit were complied with or, in the case of a deviation, prior authorization was received from the Division of Water Resources. 10) No contravention of Ground Water Quality Standards occurred at a monitoring well or explanations of violations are attached to include appropriate actions and remediations. 1 1) Vegetative cover was maintained and proper crop management was performed on each site receing residuals, as specified in the permit. 12) No runoff of residuals from the application sites onto adjacent property or nearby surface waters has occurred. 13) All buffer requirements as specified on the permit were maintained during each application of residuals. Part C - Certification: "I certify, under penalty of law, that the above information is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." Sc71✓t ct.,c ,) , -2 /7 0_( Permittee Name and Title (type or print) Signature of Permittee Date Signature of Preparer* Date Signature of Land ATier (if different from Permittee) 2-$-29at Date (if different from Permittee and Preparer) * Preparer is defined in 40 CFR Part 503.9 (r) and 15A NCAC 02T .1102 (26) DENR FORM ACF (12/2006) ANNUAL RESIDUAL SAMPLING SUMMARY FORM Please note that your permit may contain additional parameters to be analyzed. The parameters can be reported in FORM RSSF - B Waypoint Analytical 0 Town of Spindale Facility Name: Town of Spindale WWTP Sample or Composite Date O 0 N v) 00• M O N 25 — �,� — Vl • ‹ M 00 M i • < V) f • ZI M ,_ , ) 9330 0 O N 31800 0 O - Conc. Limit (mg/kg)a Q z k ) v, 0 0 M NA 840 LS 420 0 C) NA < z < z NA Parameter (mg/kg) Percent Solids (%) Arsenic Cadmium Copper Chromium Lead Mercury Molybdenum ) U z E .=• 8 U •- N Total Phosphorus TKN Ammonia -Nitrogen Nitrate and Nitrite DENR FORM RSSF (12/2006) *Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1 102 (26) ANNUAL RESIDUAL SAMPLING SUMMARY FORM - B CAS A RS Cd 6J L • E oco ee C et E rti `o cip a� oas 44 ••-• .. ea co 4.4 ett C C StOi CC E te Waypoint Analytical WQ Permit Number: WQ0001953 Town of Spindale Facility Name: Residual Source NPDES # or WQ#: Town of Spindale WWTP Sample or Composite Date O v) 97000 . 6230 12500 cc.O N 117000 255 23500 1 2950 O 3.29 1 Parameter (mg/kg) Organic N A. E C c Q O_ U U O Magnesium Maganese Poatassium Sodium Sulfur PAN SAR Signature of Preparer *Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26) DENR FORM RSSF - ANNUAL METALS FIELD LOADING SUMMARY FORM* Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Facility Name: Permit #: Town of Spindale WQ0001953 Total Dry Tons Applied (Annual): 2.05 Cation Exchange Capacity (non 503 only): Operator: John McFadden Owner: John McFadden Predominant Soil Series: PaC2 Acres Used: 15.1 Acres Permitted: 15.1 Site #: M Field #: Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, "A) Solids use Raw Percent # Sample or Com- posite Date 1 6/5/20 2 3 j 4' 5 6 7 8 9 10 i 11 . 12 Solids 0.38 Arsenic 25 Cadmium 25 Copper 131 Chromium 62.5 Lead 75 Mercury 3.83 Molyb- denum 62.5 Nickel 62.5 Selenium 12 Zinc 313 Total Phos- phorus 9330 Annual Heavy Metal Field Loadings (Calculated in Ibs/acre): Total App. Event 1 '' 0.14 2 j 3 4. 5 6 7 8 i 9 10 £ 11 12 Totals: Arsenic 0.007 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.007 Cadmium 0.007 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.007 Copper 0.036 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.036 Chromium 0.017 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.017 Lead 0.020 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.020 Mercury 0.001 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.001 Molyb denum 0 017 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.017 Nickel 0.017 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.017 Selenium 0.003 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.003 Zinc 0.085 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.085 Total Phos- phorus 2.538 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 2.538 "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations". Signature of Land Applier t-$J03\ Date DENR FORM MFLSF (12/2006) ANNUAL LAND APPLICATION FIELD SUMMARY FORM PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE. It• Acres Utilized: Facility Name: Town of Spindale Acres Permitted: Land Owner: John McFadden Cation Exchange Capacity (non 503): Predominant Soil Series: PaC2 John McFadden 0 z a L 2 L. U Name of Crop Type Receiving Residual Application Crop 2 I Lime Applied I Ual O O O N — =- O U 0 U N ti PAN Applied ( lbs/acre) N o. 2 V < z O o O o co 0 0 0 co 0 O 0 O 0 O 0 O 0 O 0 0 0 O 0 O 0 O 0 0 0 0 0 O 0 0 0 0 o O 0 0 O O 0 0 0 0 0 CO .r ^ 0 2 U 00 N 0 0 O O 0 0 CD O 0 0 CD O 0 0 CD O 0 o O 0 O 0 O 0 o 0 O 0 0 0 O 0 o 0 O 0 O 0 O 0 o 0 O O0 rV y •y. a • •� m 'z `t z E c — Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp to this form): I —en 00 N c N 00 00 O O so r` N N 00 c, N N o0 o. N Ammonia CA 0, Nitrogen E O o cc --re, �o��o. O O O z OD F' E 0 N I Z 0.017 3.004 o ri 374 Mineralization Rate*** o Volatilization Rate** .n o o - o rn 0 o z Z 0 o 0 0 0- 0 ^ Application Method* y . c,_O O Cl c, N p� O N p� O �o N 0. -,I- N y Nv� ((0 r ' cC C O 3.. U O o �i 00 ri Q z ' O Ti, i ., y, `n U C 3 2 `, = U M O O 0 N N cc rn Residual Sources ' (NPDES #. WQ#. Fert.. Animal Waste. etc) M V, O 0 0 3 U co 0 0.047 0.054 M Volume Applied per Acre (Dry Tons/Ac) — O 0.000 I 0.000 O O 0.000 O 0 0 O 0 O 0.000 0.000 0.000 O d < 0 O 0 O O O I 36 cA -G cn CO O Annual lbs/acre Prior Years Cumulative lbs/ac Current Cumulative lbs/ac Permitted C. P. L. R.**** 'Permit PAN Limit lst/2nd Crop Volume applied (enter one) Solids/ Liquid Cu. Yds I Gallons 0 O 0 rn I 130000' glumW JO MG 4-2020 TOTALS: 0 Signature of Land Applier DENR FORM FSF (12/2006) ANNUAL METALS FIELD LOADING SUMMARY FORM* Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Facility Name: Permit #: Town of Spindale WQ0001953 Total Dry Tons Applied (Annual): 2.17 Cation Exchange Capacity (non 503 only): Operator: John McFadden Owner: John McFadden Predominant Soil Series: PaC2 Acres Used: 15.5 Acres Permitted: 15.5 Site #: M Field #: 3 Residual Analysis Data (Ekeavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #): Sample or Com- posite Date 1 6/5/20 2! 3_._ 4 5' 6 7+ v 8 v 9 10 1 11 ' 12 I ............. % Solids 0.38 Arsenic 25 Cadmium 25 Copper 131 Chromium 62.5 Lead 75 Mercury 3.83 Molyb- denum 62.5 Nickel 62.5 Selenium 12 Zinc 313 Total Phos- phorus 9330 nnual Heavy Metal Ficld Loadings (Calculated in lbs/acre): Iota I App. Event 1 0.14 2 3; 4 5 '. 6 7 '.' 8 9 10 11 12 1 Totals: Arsenic 0.007 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.007 Cadmium 0.007 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.007 Copper 0.037 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.037 Chromium 0.018 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.018 I,ead 0.021 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.021 Mercury 0.001 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.001 Molyb denum 0.018 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.018 Nickel 0.018 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.018 Selenium 0.003 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.003 Zinc 0.088 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.088 Total Phos- phorus IIN 2.612 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 2.612 certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. 1 am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations". Signature of Land Applier Date DENR FORM MFLSF (12/2006) ANNUAL LAND APPLICATION FIELD SUMMARY FORM PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE. Acres Utilized: Field #: M3 WQ Permit #: WQ0001953 Facility Name: Town of Spindale Acres Permitted: Annual Dry Tons Applied: 2.1630 Land Owner: John McFadden Cation Exchange Capacity (non 503): Predominant Soil Series: PaC2 John McFadden Crop 2 Max. PAN: R Z 0 00 Name of Crop Type Receiving Residual Appl ication Crop 2 I Lime Applied cod VI o O O 0. O y v [i L...1 ON CV PAN Applied ( Ibs/acre) N Ci o U < z O o o O O 0 o o O 0 O 0 O 0 o 0 O 0 o 0 O 0 c 0 O 0 o 0 O 0 o 0 O 0 O C O 0 o 0 O 0 0 0 O 0 0 0 00 - -. - n^ c U 0 o 0 0 0 0 o 0 0 0 0 0 o 0 0 0 0 0 0 0 0 0 o 0 o 0 O 0 o 0 o 0 0 0 0 0 o 0 0 0 o O 0 0 O 0 ^ o M N 412 CZ b • C m Z d Z E 0 O ^ Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp to this form): rl r‘i Ammonia m Nitrogen E f., c N o o V1 oo N M N 0* co.] H. E^ 0 o 0 0 Mineralization Rate*** ,- o z O0 0 o N 0 e; M 0 r M Volatilization Rate** '^ O o o o 0 o — Application Method* y ono = 0 o elN 0 0 0 0 .-. C.V N N y 73 ctT c a a •� U -- N o N 00 o- M O n N _ c/D o n -o U 00 o O N N co o N z Residual Sources (NPDES #, WQ#. Pert.. Animal Waste. etc) n Q, 0 0 0 a O U O O I. N t` '^. N en - b U o 0 0 nr 0 0 o 0 0 r en Volume Applied per Acre (Dry Tons/Ac) •-- O o CD O 0 CDO O 0.000 0.000 0 O 0.000 0.000 0.000 I 0.000 0.000 0.000 sd 0.007 .o O O L 0.068 M 00 M O (Annual lbs/acre Prior Years Cumulative lbs/ac Current Cumulative Ibs/ac Permitted C. P. L. R.**** Permit PAN Limit lst/2nd Crop Volume applied (enter one) Solids/ Liquid Cu. Yds I Gallons 136500 136500 0 1ppUO AI ao alga 4-2020 (TOTALS: 6> 6> L. V�i CpR. bA R C telt L w V) R y s Q- 3 C y u R o u y, u R R to O .. R ajoo. C R R '. Cl3 C R u > � C a 3 o V C C C � O L T - 6 et v C •u h om. G 3 -0 E 6o cs C E cQ R y ^C ^O R r.+ R y r. 7a C2. 4. y R C Q. C to L C u ti CA •q L E o L v ea — w. Cr • Signature of Land Applier DENR FORM FSF (12/2006) ANNUAL METALS FIELD LOADING SUMMARY FORM* Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Facility Name: Town of Spindale Total Dry Tons Applied (Annual): 3.71 Permit #: WQ0001953 Cation Exchange Capacity (non 503 only): Operator: John McFadden Owner: John McFadden Predominant Soil Series: PaC2 Acres Used: 17.1 Acres Permitted: 17.1 Site #: M Field #: 4 Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #): Sample or Com- posite Date _ ?_' 6/5/20 2 j 3 4 5 6 7 8 9 10� 11 r __. 12 _T % Solids 0.38 Arsenic 25 Cadmium 25 Copper 131 Chromium 62.5 Lead 75 Mercury 3.83 Molyb- denum 62.5 Nickel 62.5 Selenium 12 Zinc 313 Total Phos- phorus 9330 nnual Heavy Metal Field Loadings (Calculated in Ibs/acre): Total DT/Ac./ App. Event 1! 2 3 4 5 6 7 8! 9 10 11 12 Totals: 0.22 _ Arsenic 0.011 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.011 Cadmium 0.011 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.011 Copper 0.057 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.057 Chromium 0.027 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.027 Lead 0.033 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.033 Mercury 0.002 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.002 Molyb denum 0.027 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.027 Nickel 0.027 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.027 Selenium 0.005 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.005 Zinc 0.136 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.136 Total Phos- phorus 4.049 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 4.049 I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations". 11 t741 Signature of Land Applier Date DENR FORM MFLSF (12/2006) ANNUAL LAND APPLICATION FIELD SUMMARY FORM PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE. N L Field #: M4 WQ Permit #: WQ0001953 Facility Name: Town of Spindale Acres Permitted: 17.1 Annual Dry Tons Applied: 3.7080 Land Owner: John McFadden Cation Exchange Capacity (non 503): Predominant Soil Series: PaC2 John McFadden Crop 2 Max. PAN: 00 Name of Crop Type Receiving Residual Application Crop 2 I Lime Applied lbs/ac I 0 0 0 O U N [i vv Ca. Y 0 o N PAN Applied ( lbs/acre) N a. 2 C..)o < z < z 0 o O 0 O O 0 0 o O 0 0 O O 0 O o O 0 0 O O 0 0 o C 0 0 o O 0 O O O 0 O 0 O 0 0 O O 0 158 - Q. CJ °` ut _ 0 l� s.0 0 O O 0 0 o O C 0 0 O 0 0 0 O 0 0 0 O 0 0 0 O 0 0 0 O 0 0 0 O 0 0 0 O 0 0 0 O O Cr N ON U O� rn z Z E O oc> � 0Y Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp to this form): a` 0 v Ammonia rn Nitrogen E 00 ,., 0 ,., c°° N o to v 0,_° CN N z m E-' E 0 0 N - 0 0 N - a> v.) 0 o O .1. O et O 00 Mineralization Rate*** en o enN o z O 0^ s0 O` o D — ' M Volatilization Rate** . o v, 0 0 c 0 o 0 _N 0 z Application Method* y op z o 0 o - 0 o o 0 c ^ d N •N U 0 0 clt.O en 000 C l- 0c r- N Q cA u 'S -, -. U N O 0 N ^^ z Residual Sources (NPDES #, WQ#. Fert., Animal Waste, etc) M v, T 0 0 0. 3 M V", O• 0 0 0' 3 U 0.057 cr• ^ so VI ^ 1338 — o o c� 0 O 00 0 O ;V � Volume Applied per Acre (Dry Tons/Ac) tr) - O el 00 O 0.000 0 O 00 0 O 0 0 O 0 0 O 0.000 0.000 0.000 0 0 O 0.000 As 110'0 0.047 v�i 0 O ` M° o - cA 00 <--)M O 00 o Annual Ibs/acre Prior Years Cumulative lbs/ac Current Cumulative lbs/ac i Permitted C. P. L. R.**** Permit PAN Limit lst/2nd Crop Volume applied (enter one) Solids/ Liquid Cu. Yds Gallons 156000 78000 234000 glumW ao aje4 0 O N TOTALS: CC 0 on O L E 0 L E •C 0 1r' R 0 >, o 0 CI y c a c44 rOj, •� c L a. 0 4. u e0 O Signature of Land Applier DENR FORM FSF (12/2006) ANNUAL METALS FIELD LOADING SUMMARY FORM* Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Facility Name: Permit #: Operator: Acres Used: Town of Spindale . Total Dry Tons Applied (Annual): WQ0001953 Cation Exchange Capacity (non 503 only): 2.27 John McFadden Owner: John McFadden Predominant Soil Series: CaB2 10.6 Acres Permitted: 10.6 Site #: M Field #: Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, °Ao Solids use Raw Percent #): Sample or Com- posite Date .._11_ ` 6/5/20 2 3 4; ._. 5 6( 7, 8 1 9 10 -11 12 ; % Solids 0.38 Arsenic 25 Cadmium 25 Copper 131 Chromium 62.5 Lead 75 Mercury 3.83 Molyb- denum 62.5 Nickel 62.5 Selenium 12 Zinc 313 Total Phos- phorus 9330 Annual Heavy Metal Field Loadings (Calculated in lbs/acre): Total DT/Ac./ App. Event 11 0.21 21 3] 4 5 6! 7 8) 9 10 11 12] Totals: Arsenic 0.011 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.011 Cadmium 0.011 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.011 Copper 0.056 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.056 Chromium 0.027 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.027 Lead 0.032 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.032 Mercury 0.002 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.002 Molyb denum 0 027 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.027 Nickel 0.027 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.027 Selenium 0.005 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.005 Zinc 0.134 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.134 Total Phos- phorus 3.993 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 3.993 "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations". )7i'v 7� Signature of Land Appier g - -702. Date DENR FORM MFLSF (12/2006) Acres Utilized: 10.6 Field #: M5 WQ Permit #: WQ0001953 Annual Dry Tons Applied: 2.2660 Land Owner: John McFadden Cation Exchange Capacity (non 503): Predominant Soil Series: CaB2 John McFadden. 0 L 0. 0 z 0. 0 0 N z a cR C 0 co) Name of Crop Type Receiving Residual Application Crop 2 ILime Applied I ca v 0 0 Date CD N 0. O U U ti [i PAN Applied ( Ibs/acre) N 0 o U Q z O O o o O O 0 0 O O 0 0 0 O 0 0 0 O 0 0 O O 0 0 O O 0 0 O 0 0 0 0 0 0 0 O 0 0 o O 0 0 c O 0 0 o 0 �,y '-" O o U N a' O 0 0 C O 0 0 O O 0 0 O O 0 0 O O 0 0 O O 0 0 O O 0 0 O O 0 0 C O 0 0 O 0 0 0 O 0 0 0 6 0, L 0) • .1)..) Z ..... E CD c::,ci. Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp to this form): Ij Cd I Cu I Cr Pb H Mo Ni Se Zn P M rn M 0.134 25.642 N 2498 Ammonia a, Nitrogen E 000c _ M o o O un N O "0 N O rn 00 z $' a E-- E 0 oo 0 N N o o 0000 c-- cti - co r.f `r M Mineralization Rate*** M o 0.002 0.027 - 0 o < z Volatilization Rate** v., O Application Method* N 0 d 0 o '- v O. i .Cc O 0 0 0 N O N N Z ✓1 U Q 3 2 'O 40 o O M r _• N 0 00 N en Residual Sources (NPDES #, WQ#, Fert., Animal Waste, etc) M 0 0 CD d _ C. 0 0.05 J .o 0 0 f^ 1' U L o. < F 'O . c d '-i o ° .11 a¢ � Q 0 - N 0 CD O 0 0 CD O 0 0 CD O 0 0 0.000 I CD O O .O CD O O O CD O O O 0 O co C 0.000 0 O O O 0.000 in—'0 Q _ 0 O^ 0 r- 0 1 36 .- Volume applied o : (enter one) Solids/ Liquid Solids 0 Cu. Yds I Gallons 00 0 Annual�lbs/acre Prior Years Cumulative Ibs/ac Current Cumulative lbs/ac Permitted C. P. L. R.**** Permit PAN Limit lst/2nd Crop 143000 I I 143000 0 4-2020 TOTALS: eu c ° • 7...O O • Ci •p • S. , I.a, c CO • O y .0 , . i tL e0 L U a a' O — p R 4. v ae ea C O CC -1.,. v C bf ca ea ae e e c O R "O a) y R z — 0 c W tic v On c R R 3 0 L •• U 1ea .. d , = H > V) �14 M i+ R 0 R? O ar Ce ' 7 . t:4 ° INU �c N O o R la C�. i:. ._ 7.. �' ..� CO �, c u a: O ea W) a ° c E c • Q. O ea O * u ~ 0 r a. 44 > f; on >s'; 0 E at 3 .. • y 10 c • O L .O R a'.' u +• E c at L.a) to c c 0.. to 0 •L 0:- E 0 E • ° O cp R �,., R 4.., 0 - ^0 y 4. eGA ^a bA O O y 6, • 0 +.+ ca • 0-q c. c s- • c • u o o. 0 1 c.�o 0 y, !- E 6o = L co R 4. - .. c 1) ignature of Land Applier U DENR FORM FSF (12/2006) ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (02T Rules) Facility Name: Town of Spindale WWTP Name: Town of Spindale WWTP WQ Permit Number: WQ0001953 NPDES Number: NC0020664 Monitoring Period: From 1 / 1 /2020 To 12/31/2020 Pathogen Reduction (15A NCAC 02T .1106) - Please indicate level achieved and alternative performed: Class A: Alt. A (time/temp) 0 Alt B (Alk Treatment)❑ Alt. C (Prior Testing)i A1t.D (No Prior Test) ® Process to Further Reduce Pathogengs L: If applicable to alternative performed (Class A only) indicate "Process to Further Reduce Pathogens": Compost Li Heat Drying 0 Heat Treatment C] Thermophilic Beta Ray 0 Gamma Ray 0 Pasteurization Class B: Alt. (1) Fecal Density Ltd Alt. (2) Process to Significantly Reduce Pathogens LJ If applicable to alternative performed (Class B only) indicate "Process to Significantly Reduce Pathogens": Lime Stabilization Li Air Drying 0 Composting 0 Aerobic Digestion L.J. Anaerobic Digestion 10 If applicable to alternative performed (Class A or Class B) complete the following monitoring data: Parameter Allowable Level in Sludge Pathogen Density f o NumberFrequency Excee- dences Analysis of Anal y Sample Type Analytical Tech - niaue Minimum Geo. Mean Maximum Units Fecal Coliform 2 x 10 to the 6th power per gram of total solids MPN 7692 8195 8696 MPN/g 0 7 grab sm9221 CFU 1000 mpn per gram of total solid (dry weight) Salmonella bacteria (in lieu of fecal coliform) 3 MPN per 4 grams total solid (dry weight) Vector Attraction Reduction (15A NCAC 02T .1107) - Please indicate alternative performed: Alt.1 (VS reduction) ❑ Alt. 2 (40-day bench) ❑ Alt. 3 (30-day bench) Q Alt. 4 (Spec. 02 uptake) 10 Alt. 5 (14-Day Aerobic) El Alt. 6 (Alk. Stabilization El Alt 7 (Drying - Stable) lJ Alt. 8 (Drying - Unstable) ij Alt. 9 (Injection) 0 Alt. 10 (Incorporation) 0 No vector attraction reduction alternatives were performed 0 CERTIFICATION STATEMENT (please check the appropriate statement) I "I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the vector attraction reduction requirement in 15A NCAC 02T .1107 have been met." Li "I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the vector attraction reduction requirement in 15A NCAC 02T .1107 have not been met." (Please note if you check this statement attach an explanation why you have not met one or both of the requirements.) "This determination has been made under my direction and supervision in accordance with the system designed to ensure that qualified personnel properly gather and evaluate the information used to determine that the pathogen and vector attraction reduction requirements have been met. I am aware that there are significant penalties for false certification including fine and imprisonment." 6,7 o e.„, or c. L Dennis Key US Biosolids, Inc. Preparer Name and Title (type or print) Land Applier Name and Title (if applicable)(type or print) Signature of Preparer* /7 1 Date Si nafure of Land Applier if applicable) Date g PP ( PP ) *Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26) DENR FORM PVRF 02T (12/2006) Waypoint. ANALYTICAL 46381 Southern Soil Builders Dennis Key 958 Hoots Road Roaring River , NC 28669 Project Spindale Information : 7621 Whitepine Road, Richmond, VA 23237 Main 804-743-9401 'Fax 804-271-6446 www.waypointanalyticai.com Report Number : 20-155-0004 REPORT Of ANALYSIS Lab No: 72556 Sample ID : Spindale Report Date: 06/11/2020 Received : 06/03/2020 pa v« tn` G°o"fr Pauric McGroary Agronomist Matrix: Solids Sampled: 6/ 1 / 2020 10:00 Test Results Units MOL DF Date / Time By Analytical Analyzed Method Moisture 99.6 0/0 0.010 1 06/05/20 16:47 FMM 5M-2540G Test Results Units MOL DF Date / Time By Analytical Analyzed Method Ammonia Nitrogen Nitrate+Nitrite-N Organic N pH Total Solids Total Kjeldahl Nitrogen Phosphorus Aluminum Arsenic Calcium Cadmium Chromium Copper Iron Lead Magnesium Manganese 31800 mg/Kg - dry 1700 mg/Kg - dry 97000 mg/Kg - dry 6.3 s.u. 0.380 % 129000 mg/Kg - dry 9330 mg/Kg - dry 6230 mg/Kg - dry 25 mg/Kg - dry <12500 nig/Kg - dry <25.0 mg/Kg - dry <62.5 mg/Kg - dry 131 mg/Kg - dry 9730 mg/Kg - dry <75.0 mg/,Kg - dry 1700 mg/Kg - dry 255 mg/Kg - dry 6250 1 06/10/20 14:00 JPJ SM-4500-NH3C 1210 1 06/09/20 15:40 MD 4500NO3F-2011 62500 1 06/10/20 10:00 CALCULATION 1 06/09/20 05:20 3SL 9045D 0.010 1 06/05/20 16:47 FMM SM-2540G 62500 1 06/10/20 10:00 JPJ ;M-4500-NH3C-TO 1250 1 06/09/20 22:09 KKM 60100 1250 1 06/09/20 22:09 KKM 60100 125 1 06/09/20 22:09 KKM 6010D 12500 1 06/09/20 22:09 KKM 6010D 25.0 1 06/09/20 22:09 KKM 6010D 62.5 t 06/09/20 22:09 KKM 60100 125 1 06/09/20 22:09 KKM 6010D 2500 1 06/09/20 22:09 KKM 6010D 75.0 1 06/09/20 22:09 KKM 6010D 1250 1 06/09/20 22:09 KKM 6010D 125 1 06/09/20 22:09 KKM 60100 Qualifiers/ Definitions DF Dilution Factor MQL Method Quantitation Limit L Limit Exceeded Page 3 cf 6 Waypoint ANALYTICAL 46381 Southern Soil Builders Dennis Key 958 Hoots Road Roaring River , NC 28669 Project Spindale Information 7621 Whitepine Road, Richmond, VA 23237 Main 804-743-9401 ° Fax 804-271-6446 www.waypointanalytical. com Report Number : 20-155-0004 REPORT Of ANALYSIS Lab No : 72556 Sample ID : Spindale Report Date : 06/11/2020 Received : 06/03/2020 Pam« (tic 0°7- Pauric McGroary Agronomist Matrix: Solids Sampled: 6/1/2020 10:00 Test Results Units MOL LW Date / Time By Analytical Analyzed Method Mercury <3.83 mg/Kg - dry 3.83 1 06/09/20 11:59 DDB SW-7471B Molybdenum <62.5 mg/Kg - dry 62.5 1 06/09/20 22:09 KKM 60100 Nickel <62.5 mg/Kg - dry 62.5 1 06/09/20 22:09 KKM 6010D Potassium 6250 mg/Kg - dry 2500 1 06/09/20 22:09 KKM 6010D Selenium 12 mg/Kg - dry 125 1 06/09/20 22:09 KKM 6010D Sodium 23500 mg/Kg - dry 6250 1 06/09/20 22:09 KKM 6010D Zinc <313 mg/Kg - dry 313 1 06/09/20 22:09 KKM 6010D Sulfur 2950 mg/Kg - dry 2500 1 06/09/20 22:09 KKM 6010D Qualifiers/ Definitions DF Dilution Factor MQL Method Quantitation Limit L Limit Exceeded Page 4 of 6 SAR Sodium Absorption Ratio Na : Sodium (Mg/L) Equivalent weight: 23 Ca : Calcium (Mg/L) Equivalent weight: 20 Mg : Magnesium (Mg/L) Equivalent weight: 12 Na(Mg/L) Ca(Mg/L) Mg(Mq/L) 89.3 47.5 6.46 Na_(M E.) Ca...(M E). Mg(ME) 3.882609 2.375 0.538333 Milli Equivalent = Mg/L / Equivalent weight SAR= Na Milli Equivalent/[0.5 X (Ca Milli Equivalent + Mg Milli equivalent)]0.5 power (From Mg/L entered above) SAR = 3.216944 SAR= 3.296102 Na (ME) Ca (ME) Mg (ME) 3.9 2.3 0.5 (From ME entered below) The amour amount of Permitting z a_ Applied on t4 w O F- N to L t4 N to 0 CO CD CD • 0 M 0 z O O M z O O tb CO CD • • • Mineralization CD c c 0 0 0) a- 0) a- Y - Y -0 0) 0) E _a E 2 II II II II PAN Surface X X 0) N 0) 0 to .0 N 0) z 0 t6 0 to Ibs PAN/acre 0 O n CO MR(TKN-NH3) + 1(NH3)+NO3 0 0 O C z 0 z a O to Ibs PAN/acre 0 O_ 0 O) E 0 CD CD N "=dry tons/1000ga 1000 X 8.34 X %solids X s O O _O to c 0 0 O z • Q rn CD A 0 (1) o 0 O Analytical Results U.S. Biosolids Inc 958 Hoots Road Roaring River, NC 28669 Receive Date: 03/24/2020 Reported: 04/30/2020 For: Spindale Comments: Sample Number Parameter Sample ID Result Unit Method Analyzed Analyst 200324-25-01 2 30 Day Benchscale Spindale <1 o/a EPA62S.R-g210 03/24/2020 WC PO Box 228 • Statesville, NC 28687 • 704/872/4697 Page 1 of 38 30 Day Bench Worksheet WEEK 1 Sample ID # 200 j7_U . 25 Samples Total S lids Volatile Solids % Volatile Fraction 0.5000 1 - silL.P -1 0 2 I 0•14'W2 3 - fAl 0. 1.0 0• `1-5/-1 Average: 0. 2 3 O. 11 0. `t 1(p WEEK 2 Samples Total Solids Volatile Solids % Volatile Fraction 1 0 - 0.30 0.5351 2 1.06 G - 5LD 0.5333 3 0.1(0 O.4I 0-3R5 Average: 0- i q 0.1+2 0. c 3 (0 2 WEEK 3 Samples Total Solids Volatile Solids % Volatile Fraction 1 0.42 0.22 0 523 2 O 3�S O •1ci 0 • 5 6 3 0.20 0. 1 ? 0 - 6000 Average: 0.3.S O - ► S 0 • F) G7 g WEEK 4 Samples Total Solids Volatile Solids % Volatile Fraction I 0.3S 0. ►q 0•SL261 2 0-32 O.17 0-6 13 3 - �� O • I� Q•54 2g Average: ()-% j 0. ' b V, 53410 WEEK 5 Samples Total Solids Volatile Solids % Volatile Fraction 1 0.27 0. 14 0.51'35 2 0.2ai 0.ILo 0•551/ 3 G• L G. 24 0. 5333 Average: 0.3 0 . 18 0.53 4-5 WEEK 6 Samples Total Solids Volatile Solids % Volatile Fraction 1 0-2.to 0•I5 O. I 4•,53�55 0,57(Pq 0- 55 1'7 2 O. ao 3 0.2C1 O- 1 to Average: 0.2 7 0. 15 0. S'JS 7 0-Q.555-7 Van Kleeck Reduction: Initial % Vol. Frac. - Final % Vol. Frac. X 100 = % Initial % Vol. Frac. — ( Initial % Vol. Frac. X Final % Vol. Frac.) FINAL RESULT I ism_Relinquished by: Y Received by: w W W V V `- Relinquished by: Received by: Composite Sampling #1; Time beoin am, pm Date _//_ fe Q....- 0 _ .. _.._..._ Client: V $ i 0 $ c I: dFs n� . Address: t> Oo)C 14A Contact Person: Z tc �t Phone # 33c )11 (, goct FARM PO 0 Requisitioned by: IT1rt1e .C, t•••. 6 m v 0 z 3 0 a o $v C. $6 .$ Time am, pm Date !/_ Holding times met: Cane kI *iC 3 x W o 0 S 1 a 2 1 Samples Transported On Ice Initials: gTaTRVII.I F ,i� Af'1ALYTICAL 122 Court Struet • P.O. Box 228 Statcsvillc, NC 28687 (7941872-4697 Chain of Custody Record r , PO Box 228 • Statesville, NC 28687 • 704/872/4697 Page 5 of 38 .2ceAnal ical www.pacelabs.com ANALYTICAL RESULTS Project: US. Bio. Spindale Pace Project No: 92470995 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville. NC 28078 (704)875-9092 Sample: 200324.25.01 Lab ID: 92470995001 Collected: 03/24/20 12:45 Received. 03/25/20 11:32 Matrix: Solid Results reported on a 'dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Comments: • Samples requiring thermal preservation were received outside of recommended temperature limits of 0-6 degrees Celsius. Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual Chlorinated Herb. (GC) 8151A Analytical Method: EPA 8151A Preparation Method: 8151A Leachate Method/Date: 1311: 03/28/20 15:06 Initial pH: 6.98; Final pH: 4.96 Pace National - Mt. Juliet 2,4,5-TP (Silvex) ND mg/L 0.00200 1 03/31/20 21:16 04/02/20 01:47 93-72-1 2,4-D ND mg/L 0.00200 1 03/31/20 21:16 04/02/20 01:47 94-75-7 Surrogates 2,4-DCAA (S) 89 8 % 14.0-158 1 03/31/20 21:16 04/02/20 01:47 19719-28-9 8081 TCLP Pesticides RVE Analytical Method: EPA 8081E Preparation Method: EPA 3510C Leachate Method/Date: EPA 1311; 03/26/20 16:12 Pace Analytical Services - Charlotte gamma-BHC (Lindane) ND ug/L 0.50 1 03/30/20 17:06 04/01/20 17:21 58-89-9 Chlordane (Technical) ND ug/L 3.0 1 03/30/20 17:06 04/01/20 17:21 57-74-9 Endrin ND ug/L 0.50 1 03/30/20 17:06 04/01/20 17:21 72-20-8 Heptachlor ND ug/L 0.50 1 03/30/20 17:06 04/01/20 17:21 76-44-8 Heptachlor epoxide ND ug/L 0.50 1 03/30/20 17:06 04/01/20 17:21 1024-57-3 Methoxychlor ND ug/L 1000 1 03/30/20 17:06 04/01/20 17:21 72-43-5 Toxaphene ND ug/L 3.0 1 03/30/20 17:06 04/01/20 17:21 8001-35-2 Surrogates Decachlorobiphenyl (S) 78 % 10-138 1 03/30/20 17:06 04/01/20 17:21 2051-24-3 Tetrachloro-m-xylene (S) 86 % 10-110 1 03/30/20 17:06 04/01/20 17:21 877-09-8 8082 TCLP PCBs RVE Analytical Method: EPA 8082A Preparation Method: EPA 3510C Leachate Method/Date: EPA 1311: 03/26/20 16:12 Pace Analytical Services - Charlotte PCB-1016 (Aroclor 1016) ND ug/L 1000 1 03/30/20 17:41 04/01/20 00:25 12674-11-2 PCB-1221 (Aroclor 1221) ND ug/L 1000 1 03/30/20 17:41 04/01/20 00:25 11104-28-2 PCB-1232 (Aroclor 1232) ND ug/L 1000 1 03/30/20 17:41 04/01/20 00:25 11141-16-5 PCB-1242 (Aroclor 1242) ND ug/L 1000 1 03/30/20 17:41 04/01/20 00:25 53469-21-9 PCB-1248 (Aroclor 1248) ND ug/L 1000 1 03/30/20 17:41 04/01/20 00:25 12672-29-6 PCB-1254 (Aroclor 1254) ND ug/L 1000 1 03/30/20 17:41 04/01/20 00:25 11097-69-1 PCB-1260 (Aroclor 1260) ND ug/L 1000 1 03/30/20 17:41 04/01/20 00:25 11096-82-5 Surrogates Decachlorobiphenyl (S) 91 % 10-132 1 03/30/20 17:41 04/01/2000:25 2051-24-3 6010 MET ICP, TCLP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Leachate Method/Date: EPA 1311; 04/05/20 1629 Initial pH: 7.79; Final pH: 4.5 Pace Analytical Services - Asheville Arsenic ND mg/L 0.050 1 04/06/20 12:15 04/07/20 02;52 7440-38-2 Barium ND mg/L 0.25 1 04/06/20 12:15 04/07/20 02:52 7440-39-3 Cadmium ND mg/L 0.0050 1 04/06/20 12:15 04/07/20 02:52 7440-43-9 Chromium ND mg/L 0.050 1 04/06/20 12:15 04/07/20 02:52 7440-47-3 Lead ND mg/L 0.025 1 04/06/20 12:15 04/07/20 02:52 7439-92-1 Selenium ND mg/L 0.10 1 04/06/20 12:15 04/07/20 02:52 7782-49-2 Silver ND mg/L 0.025 1 04/06/20 12:15 04/07/20 02:52 7440-22-4 Date: 04/07/2020 04:48 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced. except in full, without the written consent of Pace Analytical Services. LLC. Page 5 of 28 PO Box 228 • Statesville, NC 28687 • 704/872/4697 Page 15 of 38 -� -�aceAnal lcal VI VA*. pinhbs.com ANALYTICAL RESULTS Project: US. Bio. Spindale Pace Project No.. 92470995 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersvilte, NC 28078 (704)875-9092 Sample: 200324.25.01 Lab ID: 92470995001 Collected: 03/24/20 12:45 Received: 03/25/20 11:32 Matrix. Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Comments • Samples requiring thermal preservation were received outside of recommended temperature limits of 0-6 degrees Celsius. Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 7470 Mercury, TCLP Mercury Analytical Method: EPA 7470A Preparation Method: EPA 7470A Leachate Method/Date: EPA 1311. 04/05/20 1629 Initial pH: 7.79: Final pH: 4.5 Pace Analytical Services - Asheville ND mg/L 0.00020 1 04/07/20 10:46 04/07/20 14:07 7439-97-6 8270E TCLP RVE Analytical Method: EPA 8270E Preparation Method: EPA 3510C Pace Analytical Services - Charlotte 1,4-Dichlorobenzene ND ug/L 50.0 1 03/30/20 20:50 03/31/20 17:10 106-46-7 2,4-Dinitrotoluene ND ug/L 50.0 1 03/30/20 20:50 03/31/20 17:10 121-14-2 Hexachloro-1,3-butadiene ND ug/L 50.0 1 03/30/20 20:50 03/31/20 17:10 87-68-3 Hexachlorobenzene ND ug/L 50.0 1 03/30/20 20:50 03/31/20 17:10 118-74-1 Hexachloroethane ND ug/L 50.0 1 03/30/20 20:50 03/31/20 17:10 67-72-1 2-Methylphenol(o-Cresol) ND ug/L 50.0 1 03/30/20 20:50 03/31/20 17:10 95-48-7 384-Methylphenol(m&p Cresol) ND ug/L 50.0 1 03/30/20 20:50 03/31/20 17:10 15831-10-4 Nitrobenzene ND ug/L 50.0 1 03/30/20 20:50 03/31/20 17:10 98-95-3 Pentachlorophenol ND ug/L 100 1 03/30/20 20:50 03/31/20 17:10 87-86-5 Pyridine ND ug/L 50.0 1 03/30/20 20:50 03/31/20 17:10 110-86-1 2,4,5-Trichlorophenol ND ug/L 50.0 1 03/30/20 20:50 03/31/20 17:10 95-95-4 2,4.6-Trichlorophenol ND ug/L 50.0 1 03/30/20 20:50 03/31/20 17:10 88-06-2 Surrogates Nitrobenzene-d5 (S) 65 % 12-102 1 03/30/20 20:50 03/31/20 17:10 4165-60-0 2-Fluorobiphenyl (S) 58 % 13-107 1 03/30/20 20:50 03/31/20 17:10 321-60-8 Terphenyl-d14 (S) 80 % 21-132 1 03/30/20 20:50 03/31/20 17:10 1718-51-0 Phenol-d6 (S) 30 % 10-110 1 03/30/20 20:50 03/31/20 17:10 13127-88-3 2-Fluorophenol(S) 20 % 10-110 1 03/30/20 20:50 03/31/20 17:10 367-12-4 2,4,6-Tribromophenol (S) 33 % 27-108 1 03/30/20 20:50 03/31/20 17:10 118-79-6 8260D MSV TCLP Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Benzene ND ug/L 100 20 04/04/20 08:20 71-43-2 2-8utanone (MEK) ND ug/L 200 20 04/04/20 0820 78-93-3 Carbon tetrachloride ND ug/L 100 20 04/04/20 0820 56-23-5 Chlorobenzene ND ug/L 100 20 04/04/20 08:20 108-90-7 Chloroform ND ug/L 100 20 04/04/20 08:20 67-66-3 1,4-Dichlorobenzene ND ug/L 100 20 04/04/20 08:20 106-46-7 1,2-Dichloroethane ND ug/L 100 20 04/04/20 08:20 107-06-2 1,1-Dichloroethene ND ug/L 100 20 04/04/20 08:20 75-35-4 Tetrachloroethene ND ug/L 100 20 04/04/20 08:20 127-18-4 Trichloroethene ND ug/L 100 20 04/04/20 08:20 79-01-6 Vinyl chloride ND ug/L 100 20 04/04/20 08:20 75-01-4 Surrogates 1,2-Dichloroethane-d4 (S) 99 % 70-130 20 04/04/20 08:20 17060-07-0 Toluene-48 (S) 105 % 67-135 20 04/04/20 08:20 2037-26-5 4-Bromofluorobenzene (S) 97 % 70-130 20 04/04/20 08:20 460-00-4 Date: 04/07/2020 04:48 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full. without the written consent of Pace Analytical Services, LLC. Page 6 of 28 PO Box 228 • Statesville, NC 28687 • 704/872/4697 Page 16 of 38 .2eAnalytical www.parrdabs.com ANALYTICAL RESULTS Project: US. Bio. Spindale Pace Project No. 92470995 Pace Analytical Services, LLC 9800 Kinney Ave. Suite 100 iunterswlle. NC 28078 (7041875-9092 Sample: 200324.25.01 Lab ID: 92470995001 Collected: 03/24/20 12:45 Received: 03/25/20 11:32 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Comments' • Samples requiring thermal preservation were received outside of recommended temperature limits of 0-6 degrees Celsius. Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual Percent Moisture Analytical Method: ASTM D2974-87 Pace Analytical Services - Charlotte Percent Moisture 99.6 % 0.10 1 04/01/20 16:15 1010 Flashpoint,Closed Cup Analytical Method: EPA 1010A Pace Analytical Services - Asheville Flashpoint >200 deg F 70 0 1 04/06/20 15:09 9045 pH Soil Analytical Method: EPA 9045D Pace Analytical Services - Asheville pH at 25 Degrees C 7.3 Std. Units 0.10 1 04/06/20 14:04 9095 Paint Filter Liquid Test Analytical Method: EPA 9095E Pace Analytical Services - Asheville Free Liquids Fail 1.0 1 03/27/20 18:40 733C S Reactive Cyanide Analytical Method: EPA 9014 Preparation Method: SW-846 7.3.3.2 Pace Analytical Services - Greensburg Cyanide. Reactive ND mg/kg 248 1 03/30/20 15:18 03/30/20 15:50 734S Reactive Sulfide Analytical Method: SM 4500S2F-2011 Preparation Method: SW-846 7.3.4.2 Pace Analytical Services - Greensburg Sulfide, Reactive ND mg/kg 2480 1 03/30/20 15:18 03/30/20 15:23 H3 Sample: 200324.25.01 Lab 10: 92470995002 Collected: 03/24/20 12:45 Received: 03/25/20 11:32 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 8082 GCS PCB RVE Analytical Method: EPA 8082A Preparation Method: EPA 3510C Pace Analytical Services - Charlotte PCB-1016 (Aroclor 1016) ND ug/L 1.0 1 03/31/20 15:55 04/02/20 20:28 12674-11-2 PCB-1221 (Aroclor 1221) ND ug/L 1.0 1 03/31/20 15:55 04/02/20 20:28 11104-28-2 PCB-1232 (Aroclor 1232) ND ug/L 1.0 1 03/31/20 15:55 04/02/20 20:28 11141-16-5 PCB-1242 (Aroclor 1242) ND ug/L 1.0 1 03/31/20 15:55 04/02/20 2028 53469-21-9 PCB-1248 (Aroclor 1248) ND ug/L 1.0 1 03/31/20 15:55 04/02/20 20:28 12672-29-6 PCB-1254 (Aroclor 1254) ND ug/L 1.0 1 03/31/20 15:55 04/02/20 20:28 11097-69-1 PCB-1260 (Aroclor 1260) ND ug/L 1.0 1 03/31/20 15:55 04/02/20 20:28 11096-82-5 Surrogates Decachlorobiphenyl(S) 64 % 10-130 1 03/31/20 15:55 04/02/20 20:28 2051-24-3 Date: 04/07/2020 04:48 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced. except in full, without the written consent of Pace Analytical Services, LLC. Page 7 of 28 PO Box 228 • Statesville, NC 28687 • 704/872/4697 Page 17 of 38 Relinquished by: Time am, pm Date ____J__/, Holding times met: Received by: Time am, pm Date / / _ — Compliance work: Composite Sampling #1; Time begin am, pm Date / / Non-compliance work: In J Q s [Customer Sarnpls IDS Client: V' B;c?jC S Address: Po Qox 19C R ��a (sox 78>;-)0 Contact Person: 2ec is (, e Phone # 3 3 C '} I / gk vCfAXM -- PO M Requisitioned by: --- (Time Date) 1 10 4- t‘. i fi 3 w V Z n r 13 Q a' PO Box 228 • Statesville, NC 28687 • 704/872/4697 Page 6 of 38 Analytical Results U.S. Biosolids Inc 958 Hoots Road Roaring River, NC 28669 Receive Date: 03/24/2020 Reported: 03/26/2020 For: Spindale Comments: GM 8,195 MPN/g Sample Number Parameter Sample ID Result Unit Method Analyzed Analyst 200324-26-01 Fecal Coliforms 1 8696 MPN/g 200324-26-01 Percent Solids 1 0.23 cyo 200324-26-02 Fecal Coliforms 2 8000 MPN/g 200324-26-02 Percent Solids 2 0.25 200324-26-03 Fecal Coliforms 3 8333 MPN/g 200324-26-03 Percent Solids 3 0.24 % 200324-26-04 Fecal Coliforms 4 8696 MPN/g 200324-26-04 Percent Solids 4 0.23 cyo 200324-26-05 Fecal Coliforms 5 8000 MPN/g 200324-26-05 Percent Solids 5 0.25 0/0 200324-26-06 Fecal Coliforms 6 8000 MPN/g 200324-26-06 Percent Solids 6 0.25 % 200324-26-07 Fecal Coliforms 7 7692 MPN/g 200324-26-07 Percent Solids 7 0.26 Respectfully submitted, Dena Myers NC Cert #440, NCDW Cert #37755, EPA #NC00909 SM9221 CEi-2006 SM2540B-2011 SM9221 CE-2006 SM25406-2011 SM92210E-2006 SM2540B-201 1 SM9221 CE-2006 SM2540B-2011 SM9221 CE-2006 SM2540B-2011 SM92210E-2006 SM2540B -2011 SM9221 CE-2006 SM2540B-2011 03/25/2020 WC 03/25/2020 WC 03/25/2020 WC 03/25/2020 WC 03/25/2020 WC 03/25/2020 WC 03/25/2020 WC 03/25/2020 WC 03/25/2020 WC 03/25/2020 WC 03/25/2020 WC 03/25/2020 WC 03/25/2020 WC 03/25/2020 WC PO Box 228 • Statesville, NC 28687 • 704/872/4697 Page 1 of 4 Condition of Receipt Sample Number 200324-26-01 Temp on Arrival: Parameter Schedule: Percent Solids Received on Ice Parameter Schedule: Fecal Coliforms Sodium Thiosulfate Received on Ice Chemicals in containers, lab Sample Number 200324-26-02 Temp on Arrival: Parameter Schedule: Percent Solids Received on Ice Parameter Schedule: Fecal Coliforms Sodium Thiosulfate Received on Ice Chemicals in containers, lab Sample Number 200324-26-03 Temp on Arrival: Parameter Schedule: Percent Solids Received on Ice Parameter Schedule: Fecal Coliforms Sodium Thiosulfate Received on Ice Chemicals in containers, lab Sample Number 200324-26-04 Temp on Arrival: Parameter Schedule: Percent Solids Received on Ice Parameter Schedule: Fecal Coliforms Sodium Thiosulfate Received on Ice Chemicals in containers, lab Sample Number 200324-26-05 Temp on Arrival: Parameter Schedule: Percent Solids Received on Ice PO Box 228 • Statesville, NC 28687 • 704/872/4697 Page 2 of 4 Parameter Schedule: Fecal Coliforms Sodium Thiosulfate Received on Ice Chemicals in containers, lab Sample Number 200324-26-06 Temp on Arrival: Parameter Schedule: Percent Solids Received on Ice Parameter Schedule: Fecal Coliforms Sodium Thiosulfate Received on Ice Chemicals in containers, lab Sample Number 200324-26-07 Temp on Arrival: Parameter Schedule: Percent Solids Received on Ice Parameter Schedule: Fecal Coliforms Sodium Thiosulfate Received on Ice Chemicals in containers, lab PO Box 228 • Statesville, NC 28687 • 704/872/4697 Page 3 of 4 STATFS1f1! t t- M1ALYricAL A- 122 court Street • PO. Box 228 Statesville, NC 28687 r (704) 872-4697 ti Chain of Custody Record w _b Sampled by: Z ZQTransported by: -- Holding times met: Compliance work: Non-compliance work: Samples Transported On Ice: Initials: `c G U r Address: i3 o (3. , J 9 Rondo. NL Contact Person: Zarrr i`c _._..... Phone # 23 c_ PO # Requisitioned by: (Time bete) Time )r /f am,Gii Date 2 / 2 . Time 14 l 5 am, ate Time am, pm Date /_/ Time am, pm Date /_/ Lab Comments: okw71 o gR�cy % >' [yam X 4 66 Date Sampled (Grab Only) 0 r ry Relinquished by: '% ,7,, Received by: 'Ale/ Relinquished by. Received by: Compo#ite Snmpling #1: ._ g. N F r 0 A O if — '6 C of crM .: Cr1 <.o.-C PO Box 228 • Statesville, NC 28687 • 704/872/4697 Page 4 of 4 FY21-SL020227 NCDA&CS Agrono O (D i co N U m 0 0 c Y L 0• O U 7 O CO CO 0 (f) 0 N U) co X 0 'D John McFadden 345 McFadden Rd. Predictive Forest City, NC 28043 Sampled County : Rutherford Mehlich-3 Extraction t O O Advisor ID: Links to Helpful Information N 0 O N O E 0 O N 0 N O 0 8 2 E �; 0 O c Z m O Z N a) Q) U M O E O co J C O E F- O) 0 0 a) 7 E 0 o 0 O o m o � IX U N endations: O O O N Lime History: (0 0 Soil Class: Z 0 Z co a co W (0 Z 7 co 7 r- t.) Lo a 7 In C N M Mn-All Mn-Al2 C p 2 N 7 in U1 V C d .2L a. N o c0 • E O c Z 0 U a) C 7 Z N Recommendati mple ID: M3 V) N co E rn• o O O CA 0 a O O Z 0 N co. O 0 0 Lime History: Z 0 Z a W N Z • o Q N L0 0 N a) 2 N O Soil Class: Mn-All Mn-Al2 N N N C N g M U) V C y O E 0 N a) O Z a) U (0 Q c a) 7 Z V) c Recommendati a) E U) 0 O2) 0 a O O O N O N Lime History: O 0 N Soil Class: Z 0 Z (0 • p rn U c') C N Mn-All Mn-Al2 N_ N CO N C • V N LC) c O O C N 7 E C • EO � 0 7 00 ` d I- t O m .L. • C O as co E E Z a) N • E E. O w E c a) f0 N co c • L E •o) c 3 O 2 r E O C 0 (0 0 c0 0) L. O m c E E (O 0) O c. a) FY21-SL020227 0 Z t O a w Phone: (919) 733-2655 NCDA&CS Agronomic Division John McFadden N O O co V) O 7 Z • O in O 0 0 Recommendati Sample ID: M5 Lime History: Soil Class: Test Results [units - WN in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]: M 0 N U) co Z 7 N U N- Q N C N tr) Mn-AI1 Mn-Al2 v N c CO 5 co rn 5 R U a O co O 2 03. a in c) c0 Q 0) U w 0 %> CO O CO 5 2 O O 5 Information N a) O Z a) O co N a) Z a) E J N C Recommendati N E O fn O O N O a O O N N m co • O O • 00 C 0 a) a E Lime History: Soil Class: Test Results [units - WN in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]: Z 8 Z 0) a 0 w cn 7 AI- () CO C N Mn-AI1 Mn-Al2 A U a 2 a CO CO N N CO 00 M N ✓ v m U w U co rn >� m > O NCDA&CS Agronomic Division Phone: (919) 733-2655 Website: www.ncagr.gov/agronomi/ Report No. FY21-SL020227 John McFadden Page 3 of 3 Understanding the Soil Report: explanation of measurements, abbreviations and units Recommendations Report Abbreviations Lime Ac exchangeable acidity If testing finds that soil pH is too low for the crop(s) indicated, a lime recommendation will be given in units of either B boron ton/acre or lb/1000 sq ft. For best results, mix the lime into the top 6 to 8 inches of soil several months before planting. BS% % CEC occupied by basic cations For no -till or established plantings where this is not possible, apply no more than 1 to 1.5 ton/acre (50 Ib/1000 sq ft) at one Ca% % CEC occupied by calcium time, even if the report recommends more. You can apply the rest in similar increments every six months until the full rate CEC cation exchange capacity is applied. If MG is recommended and lime is needed, use dolomitric lime. Cu-1 copper index ESP exchangeable sodium percent Fertilizer HM% percent humic matter Recommendations for field crops or other large areas are listed separately for each nutrient to be added (in units of K-I potassium index lb/acre unless otherwise specified). Recommendations for N (and sometimes for B) are based on research/field studies K2O potash for the crop being grown, not on soil test results. K-I and P-I values are based on test results and should be > 50. If they Mg% % CEC occupied by magnesium are not, follow the fertilizer recommendations given. If Mg is needed and no lime is recommended, 0-0-22 (11.5% Mg) is MIN mineral soil class an excellent source; 175 to 250 Ib, per acre alone or in a fertilizer blend will usually satisfy crop needs, SS -I levels appear Mn manganese Mn-AI1 Mn-availability index for crop 1 only on reports for greenhouse soil or problem samples. Mn-Al2 Mn-availability index for crop 2 Mn-I manganese index Farmers and other commercial producers should pay special attention to micronutrient levels. If $, pH$, $pH, C or Z M-0 mineral -organic soil class notations appear on the soil report, refer to $Note: Secondary Nutrients and Micronutrients In general, homeowners do not N nitrogen need to be concerned about micronutrients. Various crop notes also address lime fertilizer needs; visit Na sodium ncagr.gov/agronomi/pubs.htm. NO3-N nitrate nitrogen ORG organic soil class Recommendations for small areas, such as home lawns/gardens, are listed in units of Ib/1000 sq ft . If you cannot find pH current soil pH the exact fertilizer grade recommended on the report, visit www.ncagr.gov/agronomi/obpart4.htmitisfind information that P-I phosphorus index may help you choose a comparable alternate. For more information, read A Homeowner's Guide to Fertilizer.) P205 phosphate S-I sulfur index Test Results SS -I soluble salt index W/V weight per volume Zn-AI zinc availability index The first seven values [soil class, HM%, W/V, CEC, BS%, Ac and pH] describe the soil and its degree of acidity. The Zn-I zinc index remaining 16 [P-I, K-I, Ca%, Mg%, Mn-I, Mn-AI1, Mn-Al2, Zn-I, Zn-Al, Cu-I, S-I, SS -I, Na, ESP, SS -I, NO3-N (not routinely available)] indicate levels of plant nutrients or other fertility measurement. Visit www.ncagr.gov/agronomi/uyrst.htm