WQ0028693_Monitoring - 11-2021_20211222 (2)

ti
DWR - NonDischarge Monitoring Report Submittal
'
•4 ..
NORTH CAROLINA
Enrlranmenlel QHaflly
Monitoring Report Submittal
..............................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................
Permit Number#* WQ0028693
Name of Facility:* Mountaintop Golf&Lake Club
Month:* November Year:* 2021
Report Information
Type* Upload Document*
GW-59 Mountaintop(WQ0028693) 4.35MB
GW-59(with lab results)Nov
2021.pdf
PDF Only
Please upload one PDF containing all applicable monitoring reports
(i.e., NDMR, NDAR-1,NDAR-2,NDMLR,GW-59).
Confirmation Email Address:* [e-mail]
Name of Submitter:* Kimber Reese
Signature:
Date of submittal: 12/22/2021
This will be filled in automatically
Initial Review

Reviewer: Mokashi, Poorva
Is the project number correct?* WQ0028693
Is the monitoring report accepted?* Yes No
Regional Office* Asheville
Accepted Date: 1/21/2022

W-59A COMPLIANCE REPORT FOR
° ) (:"17)
Per t )
(Submit.une etech in n iisorilig period;vitli 6 ii/-59forias,)
1 Enter date monitoring results were due.( 2.1N/24 ) Will this monitoring report(GW-59 and GW-59A) YES NO
be submitted after the established due date?
7
2 Was any required information missing on the CW-59 report forms? YES NO
— I
IF the answer to question 1 or 2 is "YES'', list in the space provided below the well identification number(s)and
explain the problems encountered in obtaining the required information.
3 Are any of the monitor wells in need of repair or maintenance(damaged casing,unlocked or missing cap, missing YES N
identification plate,area overgrown,etc.)?If/lie an.siver is -Yes", contact the Regional Wee far guidance.
4 Are any monitored constituents equal to or above the established standards? YES N(
If the answer to question 4 is "NO", skip to section 8.
If the answer to question 4 is "YES"list the affected wells individually with constituent(s) and concentration(s)
exceeding standards in the space provided below:
5 For the constituents identified in question 4 above, have standards been exceeded previously for the YES NO
same constituent(s) in the same well(s) in the last two years?
If the answer to question 5 is "NO", skip to section 8.
If the answer to question 5 is "YES", list in the space provided below, each well with constituent(s) exceeding
standards, concentration(s)reported, and sample collection date for each occurrence (for the last two years)
NAV,/ • ,) H )
NA\ — 9 , p I f ":5. 6
itv (-) P• .r)
6 Are the monitoring wells listed in section 5 located at or beyond the review boundary? YES NO
If the answer is "YES", a groundwater quality problem may be occurring. CONTACT THE REGIONAL — I
OFFICE IMMEDIATELY FOR GUIDANCE. If the answer is "NO", monitoring wells may be improperly
located;contact the Regional Office.
7 Is the permittee implementing previously approved actions required by the Division involving this YES NO
groundwater quality problem?
If the answer to question 7 is "YES", describe those actions in the space provided below.
If the answer to question 7 is "NO", contact the Regional Office within 90 days;an evaluation may be
required to determine the impact the waste disposal system is having at the review and compliance
boundaries surrounding this facility. Failure to do so may sublect the permittee to a Notice of Violation,
fines, and/or penalties.
8 The person completing this portion(GW-59A)of the monitoring report should sign below and submit this I
form with GW-59 forms for required wells to the address provided at the top of the current GW-59 form.
I hereby acknowledge that the above information was evaluated and the information submitted in this
report(Compliance Report GW-59A)is true and complete to the best of my knowledge.
L i
Signature of Permittee(or Authorized Agent) Date
,;W-59, 12/8/20113

SUBMIT FORM ON YELLOW PAPER ONLY
Mail original DEPARTMENT OF ENVIRONMENTAL QUALITY-DIV.DW OF WATER RESOURCES
GROUNDWATER QUALITY MONITORING: INFORMATION UNIT
COMPLIANCE REPORT FORM and spy to: 1617MAILSERVICECEN'CENTER, 276 9 9-1 61 7
FACILITY INFORMATION Please Pnnf Clearly orType PERMIT Number: Expiration Date. 4/30/2025
Facility Name: Mountaintop Golf&Lake Club Non-Discharge W00028893 UIC
Permit Name(if different): Mountaintop Community Association Inc NPDES Other
Facility Address: P.O.Box 1460 TYPE OF PERMITTED OPERATION BEING MONITORED
Cashiers NC 28717 County Jackson ❑ Lagoon ❑ Remediation: Infiltration Gallery
El Spray Field ❑ Remediation:
Contact Person: Bob Barr Telephone#: [phone] ❑ Rotary Distributor ❑ Land Application of Sludge
Well Location/Site Name:MW-01 R No.of wells to be sampled: 3 ❑ Water Source Heat Pump ❑ Other:
(from Parma)
SAMPLING INFORMATION If WELL
WELL ID NUMBER(from Permit): MW 01R Date sample collected: 1 1/22/202 1 FIELD ANALYSES: WAS
Well Depth: 26.6 ft, Well Diameter 2 in. units Temp.00010: C PpH 00400 5.5 16.2 DRY at
Depth to Water Level 82546:13_61 ft. below measuring point Screened Interval: 15.6 ft. to 25-6 ft. Spec. Cond. 00094: 61.5 uMhos time of
sampling,
Measuring Point is 0 ft. above land surface Relative M.P. Elevation: ft_ Odor 00085: Sulfur check
Volume of water pumped/bailed before sampling: gallons Appearance Cloudy here:
Samples for metals were collected unfiltered: ❑■ YES ❑ NO and field acidified: 0 YES ❑ NO
LABORATORY INFORMATION
Date sample analyzed:12/13/2021 Laboratory Name: Pace Analytical Certification No. 40
PARAMETERS NOTE:Values should reflect dissolved and colloidal concentrations.
COD 00335 mglL Nitrite(NO2)as N 00615 mg/L Pb-Lead 01051 ug/L
Coiiform: MF Fecal 31616 <1mg/L
f100mL Nitrate(NO3)(NO )as N 00s20 <0.1 mg/L Zn-Zinc 01092 m fL
Coliform: MF Total 31504 f100mL Phosphorus:Total as P 00665 0.23 mg/L
(Note Line MPN method for highly tor5id samples) Orthophosphate 70507 mg/L Other(Specify Compounds and Concentration Units):
Dissolved Solids:Total 70300 40.0 mg/L Al-Aluminum 01105 mg/L
......_..._
pH (Lab)00403 units Ba-Barium 01007 ug/L
TOC ocean 1.6 mglL Ca-Calcium 00916 mg/L
Chloride 00940 3.8 mg/L Cd-Cadmium 01027 ug/L
Arsenic 01002 ug/L Chromium: Total 01034 ug/L
Grease and Oils 00552 mg/L Cu-Copper 01042 mg/L ORGANICS: (by GC, GC/MS, HPLC)
Phenol 32730 ug/L Fe-Iron 01045 ugh. (Specify test and method#.ATTACH LAB REPORT.)
Sulfate 00945 mg/L Hg-Mercury 71900 ugiL Lab Report Attached? ® Yes(1) ❑ No(0)
Specific Conductance coo95 .:Mhos K-Potassium 00937 mg/L VOC 7873 method# SM 6200B
Total Ammonia 00610 0.19 mg/L Mg-Magnesium 00927 mg/L , method#
(Ammonia Nitrogen,NH as N Ammonia Nitrogen,Total) Mn-Manganese 01055 ug/L , method#
TKN as N 00625 mg/L Ni-Nickel 01067 ug/L , method#
For Remediation Systems Only(Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal%
I certify that,to the best of my knowledge and belief,the information submitted in this report is true,accurate,and complete,and that the laboratory analytical data was produced using approved methods of analysis by a
MR-certified laboratory. I am aware that there are significant penalties for submitting false information,including the possibility of fines and imprisonment for knowing violations.Robert P.Barr/Authorized Agent i; ..`2 t tt
_2.
Permittee(or Authorized Agent)Name and Title-Please print or type Signature of Permlttee(or Authorized Agent) (Date)
GW=59 Rev.06-07-2018

SUBMIT FORM ON YELLOW PAPER ONLY
Mail original DEPARTMENT OFENVIRO ENTALtUAUUTY-t IV Of WATER RESOURCES
GROUNDWATER QUALITY MONITORING: and I � y to: INFORMAlION PROCESSING UNIT
COMPLIANCE REPORT FORM 1617 NAILSERVtCE CENTER,R LEIGH,NC 270994617
FACILITY INFORMATION Please Print Deady orType PERMIT Number: Expiration Date: 4/30/2025
Facility Name: Mountaintop Golf&Lake Club Non-Discharge WO0028693 UIC
Permit Name(if different): Mountaintop Community Association Inc NPDES Other
Facility Address: P.O.Box 1460 TYPE OF PERMITTED OPERATION BEING MONITORED
Cashiers NC 28717 County Jackson ❑ Lagoon El Remediation: Infiltration Gallery
•.. Spray Field ❑ Remediation'
Contact Person: Bob Barr Telephone#: [phone] El Rotary Distributor ❑ Land Application of Sludge.
Well Location/Site Name:MW-2 No.of wells to be sampled: 3 ❑ Water Source Heat Pump El Other:
(from Perth)
SAMPLING INFORMATION If WELL
WELL ID NUMBER(from Permit): MW-2 Date sample collected: 11/2212021 FIELD ANALYSES: WAS
Well Depth: 42 ft. Well Diameter: 2 in. pH 00400: 5.8 units Temp. °cola: 14-2 DC DRY at
Depth to Water Level 82546:15-05rMhos time of
p ft. below measuring point Screened Interval: 42 ft. to 32 ft. Spec. Cond. 00094: 146.5 f sampling,
Measuring Point is 0 ft.above land surface Relative M.P. Elevation: ft. Odor 00085: No Odor check
Volume of water pumped/bailed before sampling' gallons Appearance Clearhere:
Samples for metals were collected unfiltered: Q YES ❑ NO and field acidified: ❑■.YES El NO
LABORATORY INFORMATION
Date sample analyzed:12t1312021 Laboratory Name: Pace Analytical Certification No. 40
PARAMETERS NOTE:Values should reflect dissolved and colloidal concentrations.
COD 00335 mg/L Nitrite(NO2)as N 00615 mg/L Pb-Lead 01051 uglL
Coliform: ME Fecal 31616 <1 /100mL Nitrate(NO3)as N 00620 1.8 mg/L Zn-Zinc et092 mglL
Coliform: ME Total 31504 /100mL Phosphorus:Total as P 00665 <0.50 mg/L
(Note' use MPN method far highly bras samgieu( Orthophosphate 70507 mg/L Other(Specify Compounds and Concentration Units):
Dissolved Solids:Total 70300 118 mg/L Al-Aluminum a11a5 mglL
pH(Lab)00403 units Ba-Barium 01007 ug/L
TOC 00680 1.1 mg/L Ca-Calcium 00916 mg/L
Chloride 00940 6.8
mg/L Cd-Cadmium 01027 uglL
Arsenic 01002 ug/L Chromium:Total 01034 ug/L
Grease and Oils 00552 mg/L Cu-Copper 01042 mg/L ORGANICS:(by GC, GC/MS, HPLC)
Phenol 32730 ug/L Fe-Iron 01045 ug/L (Specify test and method#.ATTACH LAB REPORT.)
Sulfate 00945 mg/L Hg-Mercury 71900 ug/L Lab Report Attached? ❑® Yes(1) El No(0)
Specific Conductance 00095 tiMhos K-Potassium 00937 mg/L VOC 7873 , method# SM 6200B
Total Ammonia 00610 3.4 mg/L Mg-Magnesium 00927 mg/L , method#
(Ammonia Nitrogen,N13as N Ammonia Nitrogen.Total) _. Mn-Manganese at055 ug/L , method#
TKN as N 00625 mg/L Ni-Nickel 01067 ug/L , method#
For Remediation Systems Only(Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal%
_
I oenify that,to the best of my knowledge and belief.the information submitted in this report is true,accurate.and complete,and that the laboratory analytical data was produced using approved methods of analysis by a
5WRtc ertified laboratory. I am aware that there are significant penalties for subm itting false information,including the possibility;,of fines and imprisonment for knowing violations.
Robert P.Barr/Authorized Agent / L 7,1-2-1
Permittee(or Authorized Agent)Name and Title-Pease print or type Signature of Permittee(or Authorized Agent) (Date)
GW-59 Rev.06-07-2018

SUBMIT FORM ON YELLOW PAPER ONLY
Mail original D PARThIE[T OF ENVIRONMENTAL CRIALITT-DN.OF WATER RESOURtiES
GROUNDWATER QUALITY MONITORING: and.1INF 11ONPROCESSINGUNIT
COMPLIANCE REPORT FORM coPY#': 1617'MAIL SERVICE CENTER.RALEIGH,NC2T69e-1 SIT
FACILITY INFORMATION Please Pont Clearly or Type PERMIT Number: Expiration Date: 4/30/2025
Facility Name: Mountaintop Golf&Lake Club Non-Discharge W00028593 UIC
Permit Name(if different): Mountaintop Community Association Inc NPDES Other
Facility Address: P.O.Box 1460 TYPE OF PERMITTED OPERATION BEING MONITORED
Cashiers NC 28717 County Jackson ❑ Lagoon ❑ Remediation: Infiltration Gallery
El Spray Field ❑ Remediation:
Contact Person: Bob Barr Telephone#: [phone] ❑ Rotary Distributor ❑ Land Application of Sludge
Well Location/Site Name:MW-3 No.of wells to be sampled: 3 ❑ Water Source Heat Pump ❑Other:
(from Permit)
. ...-_--------_—
SAMPLING INFORMATION If WELL
WELL ID NUMBER(from Permit): MW-3 Date sample collected: 11/22/2021 FIELD ANALYSES: WAS
Well Depth: 160 ft. Well Diameter: 4 in. pH 00400 6.0 units Temp. 00olo. 12.9 °C DRY at
Depth to Water Level 82546 13.34Mhos time of
P ft.below measuring point Screened Interval: ft. to ft. Spec. Cond. 00094. 87.1 Fc sampling,
Measuring Point is 0 ft. above land surface Relative M.P. Elevation: ft. Odor 00085: No Odor check
Volume of water pumped/bailed before sampling, gallons Appearance Clear here:
ri
Samples for metals were collected unfiltered: El YES ❑ NO and field acidified: ❑■ YES ❑NO
LABORATORY INFORMATION
Date sample analyzed:12/13/2021 Laboratory Name: Pace Analytical Certification No. 40
PARAMETERS NOTE:Values should reflect dissolved and colloidal concentrations.
COD 00335 mg/L Nitrite(NO2)as N a0615 mg/L Pb-Lead 01051 ugiL
Coliform: MF Fecal 31616 <1 /100mL Nitrate(NO3)as N 00620 0.52 mg/L Zn-Zinc 01092 mg/L
Coliform: MF Total 31504 /100mL Phosphorus.Total as P 00665 <0.50 mg/L
(Note. Use MPN method for highly turbid samples) Orthophosphate 70507 mg/L Other(Specify Compounds and Concentration Units):
Dissolved Solids:Total 70300 59.0 mg/L Al-Aluminum 01105 mg/L
pH (Lab)00403 units Ba-Barium 01007 ug/L
TOC 00680 <1.0 mg/L Ca-Calcium 00916 mg/L
Chloride 00940 3,7 mg/L Cd-Cadmium 01027 ugiL
Arsenic a1002 ug/L Chromium: Total 01034 ug/L
Grease and Oils 00552 mg/L Cu-Copper 01042 mg/L ORGANICS: (by GC, GC/MS, HPLC)
Phenol 32730 ug/L Fe-Iron 01045 ug/L (Specify test and method#.ATTACH LAB REPORT.)
Sulfate 00945 mg/L Hg=Mercury 71930 ug/L Lab Report Attached? ❑® Yes(1) El No(0)
Specific Conductance 00095 .Mhos K-Potassium 0a937 mg/L VOC 7673 , method# SM 6200B
Total Ammonia 00610 <0.10 mg/L Mg-Magnesium 00927 mg/L , method#
(Ammonia Nitrogen.NH,as N.Ammonia Nitrogen,Total) Mn-Manganese 01055 ug/L method#
TKN as N 00625 mg/L Ni-Nickel o'067 ug/L , method#
For Remediation Systems Only(Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal%
I certify that,to the best of my knowledge and belief,the information submitted in this report is true accurate,and complete,and that the laboratory analytical data was produced using approved methods of analysis by a
DVYR-certified laboratory. I am aware that there are significant penalties for submitting false information.including the possibility of fines and imprisonment for knowing violations.
Robert P.Barr/Authorized Agent (2,-2i-2-ti
Permittee(or Authorized Agent)Name and Title Please print or type Signature of Permittee(or Authorized Agent) (Date)
GW-59 Reu.06-07-2018

Pace Analytical Services,LLC
2225 Riverside Dr.
aceAnalyticala Asheville,NC 28804_..,,
www.pacelabs.com [phone]
t
1
ANALYTICAL RESULTS
Project: Mtn Top MW 11(22
Pace Project No.: 92573821
Sample: MW-01R Lab ID: 92573821003 Collected: 11/22/21 11:50 Received: 11/22/21 14:30 Matrix: Water
Parameters Results Units Report Limit OF Prepared Analyzed CAS No. Dual
Monitoring Well Data Analytical Method:
Pace Analytical Services-Charlotte
Performed by Pace 1 12/13/21 12:19
Collected By RMB 1 12/13/21 12:19
Collected Date 11/22/21 1 12/13/21 12:19
Collected Time 11:50 1 12/13/21 12:19
pH 5.5 Std.Units 1 12/13/21 12:19
Temperature 16.2 deg C 1 12/13/21 12:19
Static Water Level 13.61 feel 1 12/13/21 12:19
Specific Conductance 61.5 umhos/cm 1 12/13/21 12:19
Turbidity 241.3 NTU 1 12/13/21 12:19
Odor Sulfur 1 12/13/21 12:19
Appearance Cloudy 1 12/13/21 12:19
6200B MSV Analytical Method:SM 6200B
Pace Analytical Services-Charlotte
Benzene ND ug/L 0.50 1 12/03/21 10:02 71-43-2
Bromobenzene ND ug/L 0.50 1 12/03/21 10:02 108-86-1
Bromochloromethane ND ug/L 0.50 1 12/03/21 10:02 74-97-5
Bromodichloromethane ND ug/L 0.50 1 12/03/21 10:02 75-27-4
Bromoform ND ug/L 0.50 1 12/03/21 10:02 75-25-2 L1
Bromomethane ND ug/L 5.0 1 12/03/21 10:02 74-83-9
n-Butylbenzene ND ug/L 0.50 1 12/03/21 10:02 104-51-8
sec-Butylbenzene ND ug/L 0.50 1 12/03/2110:02 135-98-8
tert-Butylbenzene ND ug/L 0.50 1 12/03/21 10:02 98-06-6
Carbon tetrachloride ND ug/L 0.50 1 12/03/21 10:02 56-23-5 L1
Chlorobenzene ND ug/L 0.50 1 12/03/21 10.02 108-90-7
Chloroethane ND ug/L 1.0 1 12/03/21 10:02 75-00-3
Chloroform ND ug/L 0.50 1 12/03/2110:02 67-66-3
Chloromethane ND ug/L 1.0 1 12/03/21 10:02 74-87-3
2-Chlorotoluene ND ug/L 0.50 1 12/03/2110:02 95-49-8
4-Chlorotoluene ND ug/L 0.50 1 12/03/21 10:02 106-43-4
1,2-Dibromo-3-chloropropane ND ug/L 1.0 1 12/03/2110:02 96-12-8
Dibromochloromethane ND ug/L 0.50 1 12/03/2110:02 124-48-1
1,2-Dibromoethane(EDB) ND ug/L 0.50 1 12/03/21 10:02 106-93-4
Dibromomethane ND ug/L 0.50 1 12/03/21 10:02 74-95-3
1,2-Dichlorobenzene ND ug/L 0.50 1 12/03/21 10:02 95-50-1
1,3-Dichlorobenzene ND ug/L 0.50 1 12/03/21 10:02 541-73-1
1,4-Dichlorobenzene ND ug/L 0.50 1 12/03/21 10:02 106-46-7
Dichlorodifluoromethane ND ug/L 0,50 1 12/03/21 10:02 75-71-8
1,1-Dichloroethane NO ug/L 0.50 1 12/03/21 10:02 75-34-3
1,2-Dichloroethane ND ug/L 0,50 1 12/03/21 10:02 107-06-2
1,1-Dchloroethene ND ug/L 0.50 1 12/03/21 10:02 75-35-4
cis-1,2-Dichloroethene ND ug/L 0.50 1 12/03/21 10:02 156-59-2
trans-1,2-Dichloroethene ND ug/L 0.50 1 12/03/21 10:02 156-60-5
1,2-Dichloropropane ND ug/L 0.50 1 12/03/21 10.02 78-87-5
1,3-Dichloropropane ND ug/L 0.50 1 12/03/21 10:02 142-28-9
2,2-Dichloropropane ND ug/L 0.50 1 12/03/21 10:02 594-20-7
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except on full,
Date: 12/13/2021 01:47 PM without the written consent of Pace Analytical Services,LLC. Page 10 of 29

Pace Analytical Services,LLC
o 2225 Riverside Dr.
.,--- aceAnalytical
Asheville,NC 28604
wwmpacelaln.com [phone]
1i
ANALYTICAL RESULTS
Project: Mtn Top MW 11/22
Pace Project No.: 92573821
Sample: MW-01R Lab ID: '92573821003 Collected: 11/22/21 11:50 Received: 11/22/21 14:30 Matrix: Water
Parameters Results Units Report Limit OF Prepared Analyzed CAS No. Qual
6200B MSV Analytical Method:SM 6200B
Pace Analytical Services-Charlotte
1,1-Dichloropropene ND ug/L 0.50 1 12/03/21 10:02 563-58-6
cis-1,3-Dichloropropene ND ug/L 0.50 1 12/03/21 10:02 10061-01-5
trans-1,3-Dichloropropene ND ug/L 0.50 1 12/03/21 10:02 10061-02-6
Diisopropyl ether ND ug/L 0.50 1 12/03/21 10:02 108-20-3
Ethylbenzene ND ug/L 0.50 1 12/03/21 10:02 100-41-4
Hexachloro-1,3-butadiene ND ug/L 2.0 1 12/03/21 10:02 87-68-3
Isopropylbenzene(Cumene) ND ug/L 0.50 1 12/03/21 10:02 98-82-8
Methylene Chloride ND ug/L 2.0 1 12/03/21 10:02 75-09-2
Methyl-tert-butyl ether ND ug/L 0.50 1 12/03/21 10:02 1634-04-4
Naphthalene ND ug/L 2.0 1 12/03/21 10:02 91-20-3
n-Propylbenzene ND ug/L 0.50 1 12/03/21 10:02 103-65-1
Styrene ND ug/L 0.50 1 12/03/21 10:02 100-42-5
1,1,1,2-Tetrachloroethane ND ug/L 0.50 1 12/03/21 10:02 630-20-6
1,1,2,2-Tetrachloroethane ND ug/L 0.50 1 12/03/21 10:02 79-34-5
Tetrachloroethene ND ug/L 0.50 1 12/03/21 10:02 127-18-4
Toluene ND ug/L 0.50 1 12/03/21 10:02 108-88-3
1,2,3-Trichlorobenzene ND ug/L 2.0 1 12/03/21 10:02 87-61-6
1,2,4-Trichlorobenzene ND ug/L 2.0 1 12/03/21 10:02 120-82-1
1,1,1-Trichloroethane ND ug/L 0.50 1 12/03/21 10:02 71-55-6
1,1,2-Trichloroethane ND ug/L 0.50 1 12/03/21 10:02 79-00-5
Trichloroethene ND ug/L 0.50 1 12/03/21 10:02 79-01-6
Trichlorofluoromethane ND ug/L 1.0 1 12/03/21 10:02 75-69-4
1,2,3-Trichloropropane ND ug/L 0.50 1 12/03/21 10:02 96-18-4
1,2,4-Trimethylbenzene ND ug/L 0.50 1 12/03/21 10:02 95-63-6
1,3,5-Trimethylbenzene ND ug/L 0.50 1 12/03/21 10:02 108-67-8
Vinyl chloride ND ug/L 1.0 1 12/03/21 10:02 75-01-4
m&p-Xylene ND ug/L 1.0 1 12/03/21 10:02 179601-23-1
o-Xylene ND ug/L 0.50 1 12/03/21 10:02 95-47-6
Surrogates
1,2-Dichtoroethane-d4(S) 107 % 70-130 1 12/03/21 10:02 17060-07-0
4-Bromofluorobenzene(S) 100 % 70-130 1 12/03/21 10:02 460-00-4
Toluene-d8(S) 100 % 70-130 1 12/03/21 10:02 2037-26-5
2540C Total Dissolved Solids Analytical Method:SM 2540C-2015
Pace Analytical Services-Asheville
Total Dissolved Solids 40.0 mg/L 25.0 1 11/24/21 13:36
MI10 9222D Fecal Coliform AVL Analytical Method:SM 9222D-2015 Preparation Method:SM 9222D-2015
Pace Analytical Services-Asheville
Fecal Coliforms ND CFU/100 mL 1.0 1 11/22/21 16:12 11/23/21 15:47
350.1 Ammonia Analytical Method:EPA 350.1 Rev 2.0 1993
Pace Analytical Services-Asheville
Nitrogen,Ammonia 0.19 mg/L 0.10 1 12/03/21 11:19 7664-41-7
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date: 12/13/2021 01:47 PM without the written consent of Pace Analytical Services,LLC, Page 11 of 29

Pace Analytical SerOces,LLC
2225 Riverside Dr.
aceAnalytical Asheville,NC 28804
wmpacolabs,com [phone]
ANALYTICAL RESULTS
Project: Mtn Top MW 11/22
Pace Project No.: 92573821
Sample: MW-01R Lab ID: 92573821003 Collected: 11/22/21 11:50 Received: 11/22/21 14:30 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
353.2 Nitrogen, NO2/NO3 unpres Analytical Method:EPA 353.2 Rev 2.0 1993
Pace Analytical Services-Asheville
Nitrogen,Nitrate ND mg/L 0.040 1 11/24/21 08:58 14797-55-8
365.1 Phosphorus,Total Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation Method: EPA 365.1 Rev 2.0 1993
Pace Analytical Services-Asheville
Phosphorus 0.23 mg/ 0,050 1 12/02/21 12:55 12/03/21 08:22 7723-14-0
4500 Chloride Analytical Method:SM 4500-CI-E-2011
Pace Analytical Services-Asheville
Chloride 3.8 rng/L 1.0 1 12/01/21 15:35 16887-00-6
5310B TOC Analytical Method:SM 5310B-2014
Pace Analytical Services-Asheville
Total Organic Carbon 1.6 mg/L 1.0 1 12/05/21 15:56 7440-44-0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date: 12/13/2021 01:47 PM without the written consent of Pace Analytical Services,LLC Page 12 of 29

Pace Analytical Services,LLC
ios
2225 Riverside Dr.
t.
., ace Analytical Asheville,NC 28804
.,--
www.pacelatn.com [phone]
l
ANALYTICAL RESULTS
Project: Mtn Top MW 11/22
Pace Project No.: 92573821
Sample: MW-2 Lab ID: 92573821001 Collected: 11/22/21 12:10 Received: 11/22/21 14:30 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
Monitoring Well Data Analytical Method:
Pace Analytical Services-Charlotte
Performed by Pace 1 12/13/21 12:16
Collected By RMB 1 12/13/21 12:16
Collected Date 11/22121 1 12/13/21 12:16
Collected Time 12:10 1 12/13/21 12:16
pH 5.8 Std.Units 1 12/13/21 12:16
Temperature 14.2 deg C 1 12/13/21 12:16
State Water Level 15.05 feet 1 12/13/21 12:16
Specific Conductance 146.5 umhos/crn 1 12/13/21 12:16
Turbidity 2.6 NTU 1 12/13/21 12:16
Odor None 1 12/13/21 12:16
Appearance Clear 1 12/13/21 12:16
6200B MSV Analytical Method:SM 6200B
Pace Analytical Services-Charlotte
Benzene ND ug/L 0.50 1 12/03/21 09:25 71-43-2
Bromobenzene ND ug/L 0.50 1 12/03/21 09:25 108-86-1
Bromochloromethane ND ug/L 0.50 1 12/03/21 09:25 74-97-5
Bromodichloromethane ND ug/L 0.50 1 12/03/21 09:25 75-27-4
Bromoform ND ug/L 0.50 1 12/03/21 09:25 75-25-2 Li
Bromomethane ND ug/L 5.0 1 12/03/21 09:25 74-83-9
n-Butylbenzene ND ug/L 0.50 1 12/03/21 09:25 104-51-8
sec-Butylbenzene ND ug/L 0.50 1 12/03/21 09:25 135-98-8
tert-Butylbenzene ND ug/L 0.50 1 12/03/21 09:25 98-06-6
Carbon tetrachloride ND ug/L 0.50 1 12/03/21 09:25 56-23-5 L1
Chlorobenzene ND ug/L 0.50 1 12/0,3/21 09:25 108-90-7
Chloroethane ND ug/L 1.0 1 12/03/21 09:25 75-00-3
Chloroform ND ug/L 0.50 1 12/03/21 09:25 67-66-3
Chloromethane ND ug/L 1.0 1 12/03/21 09:25 74-87-3
2-Chlorotoluene ND ug/L 0.50 1 12/03/21 0925 95-49-8
4-Chlorotoluene ND ug/L 0.50 1 12/03/21 09:25 106-43-4
1,2-Dibromo-3-chloropropane ND ug/L 1.0 1 12/03/21 09:25 96-12-8
Dibromochloromethane ND ug/L 0.50 'I 12/03/21 09:25 124-48-1
1,2-Dibromoethane(BOB) ND ug/L 0.50 1 12/03/21 09:25 106-93-4
Dibromomethane ND ug/L 0.50 1 12/03/21 09:25 74-95-3
i,2-Dichlorobenzene ND ug/L 0.50 1 12/03/21 09:25 95-50-1
1,3-Dichlorobenzene ND ug/L 0.50 1 12/03/21 09:25 541-73-1
1,4-Dichlorobenzene ND ug/L 0.50 1 12/03/21 09:25 106-46-7
Dichlorodifluoromethane ND ug/L 0.50 1 12/03/21 09:25 75-71-8
1,1-Dichloroethane ND ug/L 0.50 1 12/03/21 09:25 75-34-3
1,2-Dichloroethane ND ug/L 0.50 1 12/03/21 09:25 107-06-2
1,i-Dichloroethene ND ug/L 0.50 1 12/03/21 09:25 75-35-4
cis-1,2-Dichloroethene ND ug/L 0.50 1 12/03/21 09:25 156-59-2
trans-1,2-Dichloroethene ND ug/L 0.50 1 12/03/21 09:25 156-60-5
1,2-Dichloropropane ND ug/L 0.50 1 12/03/21 09:25 78-87-5
1,3-Dichloropropane ND ug/L 0.50 1 12/03/21 0925 142-28-9
2,2-Dichloropropane ND ug/L 0.50 1 12/03/21 09:25 594-20-7
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except E n full,
Date: 12/13/2021 01:47 PM without the written consent of Pace Analytical Services,TLC, Page 4 of 29

Pace Analytical Services,LLC
2225 Riverside Dr.
aceAnalytical& Asheville,NC 28804
www,pacciabs.com [phone]
I
ANALYTICAL RESULTS
Project: Mtn Top MW 11/22
Pace Project No.: 92573821
Sample: MW-2 Lab ID: 925'73821001 Collected: 11/22/21 12:10 Received: 11/22/21 14:30 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
6200B MSV Analytical Method:SM 6200B
Pace Analytical Services-Charlotte
1,1-Dichloropropene ND ug/L 0.50 1 12/03/21 09:25 563-58-6
cis-1,3-Dichloropropene ND ug/L 0.50 1 12/03/21 09:25 10061-01-5
trans-1,3-Dichloropropene ND ug/L 0.50 1 12/03/21 09:25 10061-02-6
Diisopropyl ether ND ugIL 0.50 1 12/03/21 09:25 108-20-3
Ethylbenzene ND ug/L 0.50 1 12/03/21 09:25 100-41-4
Hexachloro-1,3-butadiene ND ug/L 2.0 1 12/03/21 09:25 87-68-3
lsopropylbenzene(Cumene) ND ug/L 0.50 1 12/03/21 09:25 98-82-8
Methylene Chloride ND ug/L 2.0 1 12/03/21 09:25 75-09-2
Methyl-tert-butyf ether ND ug/L 0.50 1 12/03/21 09:25 1634-04-4
Naphthalene ND ug/L 2.0 1 12/03/21 09:25 91-20-3
n-Propyibenzene ND ug/L 0.50 1 12/03/21 09:25 103-65-1
Styrene ND ug/L 0.50 1 12/03/21 09:25 100-42-5
1,1,1,2-Tetrachloroethane ND ug/L 0.50 1 12/03/21 09:25 630-20-6
1,1,2,2-Tetrachloroethane ND ug/L 0.50 1 12/03/21 09:25 79-34-5
Tetrachloroethene ND ug/L 0.50 1 12/03/21 09:25 127-18-4
Toluene ND ug/L 0.50 1 12/03/21 09:25 108-88-3
1,2,3-Trichlorobenzene ND ug/L 2.0 1 12/03/21 09:25 87-61-6
1,2,4-Trichlorobenzene ND ug/L 2.0 1 12/03/21 09:25 120-82-1
1,1,1-Trichloroethane ND ug/L 0.50 1 12/03/21 09:25 71-55-6
1,1,2-Trichloroethane ND ug/L 0.50 1 12/03/21 09;25 79-00-5
Trichloroethene ND ug/L 0.50 1 12/03/21 09:25 79-01-6
Trichlorofluoromethane ND ug/L 1.0 1 12/03/21 09:25 75-69-4
1,2,3-Trichloropropane ND ug/L 0.50 1 12/03/21 09:25 96-18-4
1,2,4-Trimethylbenzene ND ug/L 0.50 1 12/03/21 09:25 95-63-6
1,3,5-Tri methylbe nzen e ND ug/L 0.50 1 12/03/21 09:25 108-67-8
Vinyl chloride ND ug/L 1.0 1 12/03/21 09:25 75-01-4
m&p-Xylene NO ug/L 1.0 1 12/03/21 09:25 179601-23-1
o-Xylene ND ug/L 0.50 1 12/03/21 09:25 95-47-6
Surrogates
1,2-Dichloroethane-d4(S) 108 % 70-130 1 12/03/21 09:25 17060-07-0
4-Bromofluorobenzene(S) 100 % 70-130 1 12/03/21 09:25 460-00-4
Toluene-d8(S) 100 % 70-130 1 12/03/21 09:25 2037-26-5
2540C Total Dissolved Solids Analytical Method:SM 2540C-2015
Pace Analytical Services-Asheville
Total Dissolved Solids 118 mg/L 25.0 1 11/24/21 13:35
MBIO 9222D Fecal Coliform AVL Analytical Method:SM 9222D-2015 Preparation Method.SM 9222D-2015
Pace Analytical Services-Asheville
Fecal Coliforms ND CPU/100 mL 1.0 1 11/22/21 16:50 11/23/21 15:47
350.1 Ammonia Analytical Method: EPA 350.1 Rev 2.0 1993
Pace Analytical Services-Asheville
Nitrogen,Ammonia 3.4 mg/L 0.10 1 12/03/21 11:16 7664-41-7
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date: 12/13/2021 01:47 PM without the written consent of Pace Analytical Services,LLC, Page 5 of 29

Pace Analytical Services,LLC
2225 Riverside Dr.
ace Analytical Asheville,NC 28804
wwmpacelabs.corn 028)254-7176
ANALYTICAL RESULTS
Project: Mtn Top MW 11/22
Pace Project Na: 92573821
Sample: MW-2 Lab ID: 92573821001 Collected: 11/22/21 12:10 Received: 11/22/21 14:30 Matrix: Water
Parameters Results Units Report Limit OF Prepared Analyzed CAS No. Qual
353.2 Nitrogen, NO2/NO3 unpres Analytical Method:EPA 353.2 Rev 2.0 1993
Pace Analytical Services-Asheville
Nitrogen,Nitrate 1.8 mg/L 0.040 1 11/24/21 08:59 147'97-55-8
365.1 Phosphorus,Total Analytical Method:EPA 365.1 Rev 2.0 1993 Preparation Method:EPA 365.1 Rev 2.0 1993
Pace Analytical Services-Asheville
Phosphorus ND mg/L 0.050 1 12/02/21 12:55 12/03/21 08:20 7723-14-0
4500 Chloride Analytical Method:SM 4500-CI-E-2011
Pace Analytical Services-Asheville
Chloride 6.8 mg/L 1.0 1 12/01/21 15:34 16887-00-6
5310B TOC Analytical Method:SM 5310B-2014
Pace Analytical Services-Asheville
Total Organic Carbon 1.1 mg/L 1.0 1 12/04/21 19:11 7440-44-0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in lull,
Date: 12/13/2021 01:47 PM without the written consent of Pace Analytical Services,LLC. Page 6 of 29

Pace Analytical Services,LLC
o,
2225 Riverside Dr.
r.:.-
aceAnalytical
......e." Asheville,NC 28804
www.pacalabs.com [phone]
ANALYTICAL RESULTS
Project: Mtn Top MW 11/22
Pace Project No.: 92573821
Sample: MW-3 Lab ID: 92573821002 Collected: 11/22/21 1120 Received: 11/22/21 14:30 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Dual
Monitoring Well Data Analytical Method:
Pace Analytical Services-Charlotte
Performed by Pace 1 12/13/21 12:18
Collected By RMB 1 12/13/21 12:18
Collected Date 11/22/21 1 12/13/21 12:18
Collected Time 11:20 1 12/13/21 12:18
pH 6.0 Std.Units 1 12/13/21 12:18
Temperature 12.9 deg C 1 12/13/21 12:18
Static Water Level 13.34 feet 1 12/13/21 12:18
Specific Conductance 87.1 umhos/cm 1 12/13/21 12:18
Turbidity 4.4 NTU 1 12/13/21 12:18
Odor None 1 12/13/21 12:18
Appearance Clear 1 12/13/21 1218
6200B MSV Analytical Method:SM 6200B
Pace Analytical Services-Charlotte
Benzene ND ug/L 0.50 1 12/03/21 09:43 71-43-2
Bromobenzene ND ug/L 0.50 1 12/03/21 0943 108-86-1
Bromochloromethane ND ug/L 0.50 1 12/03/21 09:43 74-97-5
Bromodichloromethane ND ug/L 0.50 1 12/03/21 09:43 75-27-4
Bromoform ND ug/L 0.50 1 12/03/21 09:43 75-25-2 L1
Bromomethane ND ug/L 5.0 1 12/03/21 09:43 74-83-9
n-Butylbenzene ND ug/L 0.50 1 12/03/21 09:43 104-51-8
sec-Butylbenzene ND ug/L 0.50 1 12/03/21 09:43 135-98-8
tert-Butylbenzene ND ug/L 0.50 1 12/03/21 09:43 98-06-6
Carbon tetrachloride ND ug/L 0.50 1 12/03/21 09:43 56-23-5 L1
Chlorobenzene ND ug/L 0.50 1 12/03/21 09:43 108-90-7
Chloroethane ND ug/L 1.0 1 12/03/21 09:43 75-00-3
Chloroform ND ug/L 0.50 1 12/03/21 09:43 67-66-3
Chloromethane ND ug/L 1,0 1 12/03/21 09:43 74-87-3
2-Chlorotoluene ND ug/L 0.50 1 12/03/21 09:43 95-49-8
4-Chlorotoluene ND ug/L.. 0,50 1 12/03/21 09:43 106-43-4
1,2-Dibromo-3-chloropropane ND ug/L 1.0 1 12/03/21 09:43 96-12-8
Dibromochloromethane ND ug/L 0.50 1 12/03/21 09:43 124-48-1
1,2-Dibromoethane(EDB) ND ug/L 0.50 1 12/03/21 09:43 106-93-4
Dibromomethane ND ug/L 0.50 1 12/03/21 09:43 74-95-3
1,2-Dichlorobenzene ND ug/L 0.50 1 12/03/21 09:43 95-50-1
1,3-Dichlorobenzene ND ug/L 0.50 1 12/03/21 09:43 541-73-1
1,4-Dichlorobenzene ND ug/L 0.50 1 12/03/21 09:43 106-46-7
Dichlorodifluoromethane ND ug/L 0.50 1 12/03/21 09:43 75-71-8
1,1-Dichloroethane ND ug/L 0.50 1 12/03/21 09:43 75-34-3
1,2-Dichloroethane ND ug/L 0.50 1 12/03/21 09:43 107-06-2
1,1-Dichloroethene ND ug/L 0.50 1 12/03/21 09:43 75-35-4
cis-1,2-Dichloroethene ND ogi., 0.50 1 12/03/21 09:43 156-59-2
trans-1,2-Dichloroethene ND ug/L 0.50 1 12/03/21 09:43 156-60-5
1,2-Dichloropropane ND ug/L 0.50 1 12/03/21 09:43 78-87-5
1,3-Dichloropropane ND ug/L 0.50 1 12/03/21 09:43 142-28-9
2,2-Dichloropropane ND ug/L 0.50 1 12/03/21 09:43 594-20-7
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date: 12/13/2021 01:47 PM without the written consent of Pace Analytical Services,LLC Page 7 of 29

,
Pace Analytical Services,LLC
,
2225 RWerside Dr.
aceAnalytical Asheville,NC 28804
wing.pacotabs,corn [phone]
1
ANALYTICAL RESULTS
Project: Mtn Top MW 11/22
Pace Project No.: 92573821
Sample: MW-3 Lab ID: 92573821002 Collected: 11/22/21 11:20 Received: 11/22/21 14:30 Matrix: Water
Parameters Results Units Report Limit OF Prepared Analyzed CAS No. Qual
6200B MSV Analytical Method:SM 6200B
Pace Analytical Services-Charlotte
1,1-Dichloropropene ND ug/L 0.50 1 12/03/21 09:43 563-58-6
cis-1,3-Dichloropropene ND ug/L 0.50 1 12/03/21 09:43 10061-01-5
trans-1,3-Dichloropropene NO ug/L 0.50 1 12/03/21 09:43 10061-02-6
Diisopropyl ether NO ug/L 0.50 1 12/03/21 0943 108-20-3
Ethylbenzene ND ug/L 0.50 1 12/03/21 0943 100-41-4
Hexachloro-1,3-butadiene ND ug/L 2.0 1 12/03/21 09:43 87-68-3
lsopropylbenzene(Cumene) ND ug/L 0.50 1 12/03/21 09:43 98-82-8
Methylene Chloride ND ug/L 2.0 1 12/03/21 09:43 75-09-2
Methyl-tert-butyl ether ND ug/L 0.50 1 12/03/21 09:43 1634-04-4
Naphthalene ND ug/L 2.0 1 12/03/21 09:43 91-20-3
n-Propylbenzene ND ug/L 0.50 1 12/03/21 09:43 103-65-1
Styrene ND ug/L 0,50 1 12/03/21 09:43 100-42-5
1,1,1,2-Tetrachloroethane ND ug/L 0.50 1 12/03/21 0943 630-20-6
1,1,2,2-Tetrachloroethane NO ug/L 0.50 1 12/03/21 09:43 79-34-5
Tetrachloroethene ND ug/L 0.50 1 12/03/21 09:43 127-18-4
Toluene ND ug/L 0.50 1 12/03/21 09:43 108-88-3
1,2,3-Trichlorobenzene ND ug/L 2.0 1 12/03/21 09:43 87-61-6
1,2,4-Trichlorobenzene ND ug/L 2.0 1 12/03/21 09:43 120-82-1
1,1,1-Trichloroethane ND ug/L 0.50 1 12/03/21 09:43 71-55-6
1,1,2-Trichtoroethane ND ug/L 0.50 1 12/03/21 09:43 79-00-5
Trichloroethene ND ug/L 0.50 1 12/03/21 09:43 79-01-6
Trichlorofluoromethane ND ug/L 1.0 1 12/03/21 09:43 75-69-4
1,2,3-Trichloropropane ND ug/L 0,50 1 12/03/21 09:43 96-18-4
1,2,4-Trimethylbenzene ND ug/L 0.50 1 12/03/21 09:43 95-63-6
1,3.5-Trimethylbenzene ND ug/L 0.50 1 12/03/21 09:43 108-67-8
Vinyl chloride ND ug/L 1.0 1 12/03/21 09:43 75-01-4
m&p-Xylene ND ug/L 1.0 1 12/03/21 09:43 179601-23-1
o-Xylene ND ug/L 0.50 1 12/03/21 09:43 95-47-6
Surrogates
1,2-Dichloroethane-d4(S) 108 % 70-130 1 12/03/21 09:43 17060-07-0
4-Bromofluorobenzene(S) 102 % 70-130 1 12/03/21 0943 460-00-4
Toluene-d8(S) 100 % 70-130 1 12/03/21 09:43 2037-26-5
2540C Total Dissolved Solids Analytical Method:SM 2540C-2015
Pace Analytical Services-Asheville
Total Dissolved Solids 59.0 mg/L 25.0 1 11/24/21 13:35
MBIO 9222D Fecal Coliform AVL Analytical Method:SM 9222D-2015 Preparation Method'SM 9222D-2015
Pace Analytical Services-Asheville
Fecal Coliforms ND CFU/100 mL 1,0 1 11/22/21 16:12 11/23/21 15,47
350.1 Ammonia Analytical Method:EPA 350.1 Rev 2.0 1993
Pace Analytical Services-Asheville
Nitrogen,Ammonia ND mg/L 0.10 1 12/03/21 11:18 7664-41-7
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date: 12/13/2021 01:47 PM without the written consent of Pace Analytical Services,LLC. Page 8 of 29

Pace Analytical Services,LLC
+tr 2225 Riversde Dr.
aceAnalytical
Asheville,NC 28804
www.pacelabs.c©m [phone]
ANALYTICAL RESULTS
Project: Mtn Top MW 11/22
Pace Project No.: 92573821
Sample: MW-3 Lab ID: 92573821002 Collected: 11/22/21 11:20 Received: 11/22/21 14:30 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
353.2 Nitrogen, NO2iNO3 unpres Analytical Method: EPA 353,2 Rev 2.0 1993
Pace Analytical Services-Asheville
Nitrogen,Nitrate 0.52 mg/L 0.040 1 11/24/21 08:57 14797-55-8
365.1 Phosphorus,Total Analytical Method: EPA 365,1 Rev 2.0 1993 Preparation Method: EPA 365.1 Rev 2.0 1993
Pace Analytical Services-Asheville
Phosphorus ND mg/L 0.050 1 12/02/21 12:55 12/03/21 08:21 7723-14-0
4500 Chloride Analytical Method:SM 4500-CI-E-2011
Pace Analytical Services-Asheville
Chloride 3.7 mg/L 1.0 1 12/01/21 15:35 16887-00-6
5310B TOC Analytical Method:SM 5310B-2014
Pace Analytical Services-Asheville
Total Organic Carbon ND mg/L 1.0 1 12/05/21 15:41 7440-44-0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date: 12/13/2021 01:47 PM without the written consent of Pace Analytical Services,LLC, Page 9 of 29

Pace Analytical Services,LLC
v 2225 Riverside Dr
aceAnalyttcal Asheville,NC 28804
www.pacelabs,com [phone]
QUALIFIERS
Project: Mtn Top MW 11/22
Pace Project No.: 92573821
DEFINITIONS
OF-Dilution Factor, if reported,represents the factor applied to the reported data due to dilution of the sample aliquot.
ND-Not Detected at or above adjusted reporting limit.
TNTC-Too Numerous To Count
J-Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL-Adjusted Method Detection Limit.
PQL-Practical Quantitation Limit.
RL-Reporting Limit-The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S-Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270.The result for each analyte is
a combined concentration.
Consistent with EPA guidelines,unrounded data are displayed and have been used to calculate%recovery and RPD values.
LCS(D)-Laboratory Control Sample(Duplicate)
MS(D)-Matrix Spike(Duplicate)
DUP-Sample Duplicate
RPD-Relative Percent Difference
NC-Not Calculable.
SG-Silica Gel-Clean-Up
U-Indicates the compound was analyzed for,but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Reported results are not rounded until the final step prior to reporting.Therefore,calculated parameters that are typically reported as
"Total"may vary slightly from the sum of the reported component parameters.
Pace Analytical is TNI accredited.Contact your Pace PM for the current list of accredited analytes.
TNI-The NELAC Institute,
ANALYTE QUALIFIERS
IH This analyte exceeded secondary source verification criteria high for the initial calibration.The reported results should be
considered an estimated value.
Li Analyte recovery in the laboratory control sample(LCS)was above QC limits, Results for this analyte in associated
samples may be biased high.
MO Matrix spike recovery and/or matrix spike duplicate recovery was outside laboratory control limits.
M1 Matrix spike recovery exceeded QC limits, Batch accepted based on laboratory control sample(LCS)recovery.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date: 12/13/2021 01:47 PM without the written consent of Pace Analytical Services,LLC. Page 25 of 29

0,
c.,
CHAIN-OF-CUSTODY/Analytical Request Document 15
/62_ ceArReicar ca
The Chain-of-Custody is a LEGAL DOCUMENT.All relevant fields must be completed accurately. r‘i
Submitting a sample via this Chain of custody constitutes acknowledgment and aeePotance of the Pace Terms and Conditions found at https://info,pacelabs cesm/hubfarpas-standard-lerMs,pciT gt
Section A Secfion 8 Section C to
a.
Required Client Information: Required Project Information: Invoice Intern-talent Page: 1 Of 1
company: RIPS Systems Inc. Report To Rotten Barr Attention
-.Address. P 0 toe 1325 Copy To- Company Name: _
Ashes IC NC 28802 Address: Regotntort Agency
Email: rbarr@mbsysterns cam Purchase Order A Pace Quote'
Phone [phone]C Fax Promot Name. mountain Top MVVs Pace PIP/eel Manager torrt.petien@pacembeuom,— state jLocaugrj
Requested Due Date- Project a Pace Profile a• mws
ReqUested Anatysis Filtered
-.,
„,...
Z
„ii. 6 COLLECTED Preservatives amps COOT e o an
-o g . .-
Ortltn g Wagx DP., rs 6 '8
, im 1 -1,
wee,, 7a b
aia .c
Wat-te Wale. WIN 1 LE A sa 2'
P,AxlucT P 8 XC Iji 'AS
SAMPLE ID OzatilOorld SL .1 a
6 START END 0 . .4
De Cu „ - , ,, ,:: 1- 2 a- a
One Character per box. PV.,,-. we
XI A.LA 1 < ,y, LO E
9.
A, AR CD
r-i
0 P.
Sample ids must be unique Txxo TO X '2, !E 0 x x ,',4 ewes oc.J go ,e'il,2 13= C. a. e o 0 :n I _ t, , ..
LI..5550 0 4.. - 9 < 2 Z e re r-) l-,
l.- 7r- d cnizEio n ow :ea 0 F12 .9 a
-,4 1 If5 DATE TIME DATE TIME e) . X -= X Z Z M 0 2 L- .c . I- , CC
i
i AlW2 WT iVaill tit° ri 2 1 4 1 3 x x
I i i
2 MW-1,21.3 WIT lia.0 i i Z I 4 1 ,
3 xxxxxx
a*,-41arl,k 1 ' T.- i
95 0 it 6 2 1 ti 1 1 -3
1,
3 mi,v7/901 9.,,
' 1
4 I 9
.,
1
6 i I9 ,
6 ,-
7
1 1 ;
8-- -- ,
9 1 7 -1 '-
10
1 i i I
11 -
12
ADOMONADDOMMENTS EEI-INDAADDED Sy/AFFILIATION DATE TARE ACCEPTED BY!AFFILIATION DA,TE, TIME SAME CONDITIONS
got ek A 8,,y9a.,,) ,if 4P4P9,7z,a., ---- -'" ---k—
11/27.12:1 11130 '.r--- -----7.— ' -'-' --
4;----, :;-,./ 1=i - - -; --,-
111111.11.111111.1111 PRINT Name of SAMPLER: A
KY t.ABYtS4 8
la L —
,2— 0-——
1 SIGNATURE of SAMPLER: I DATE Signed: 11/-z..., ,..., f 1 g, ''E. 8:F._ .g .8-4.
R y.." .19 '5 - = 23 t E.)fAT.,)?.7. r Z t

Pace Analytical Services,LLC
2225 Rlverside Dr
aceAnalytical Asheville,NC 28804
wympacelalmcom [phone]
December 13, 2021
Kimber Reese
RPB Systems Inc.
P.O. Box 1325
Asheville, NC 28802
RE: Project: Mtn Top MW 11/22
Pace Project No.: 92573821
Dear Kimber Reese:
Enclosed are the analytical results for sample(s)received by the laboratory on November 22, 2021, The results relate only
to the samples included in this report. Results reported herein conform to the applicable TNINELAC Standards and the
laboratory's Quality Manual,where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace Analytical Services-Asheville
• Pace Analytical Services-Charlotte
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Lorri Patton
lorri,patton©pacelabs.com
1(828)254-7176
Project Manager
Enclosures
cc: Mr.Robert Barr, RPB Systems Inc,
Ms. Liz Barr, RPB Systems Inc.
Cody Pannell, RPB Systems
sijr, csai.,
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
44, without the written consent of Pace Analytical Services,LLC. Page 1 of 29