WQ0004797_Monitoring - 11-2021_20211221 (2)

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DWR - NonDischarge Monitoring Report Submittal •4 ..
NORTH CAROLINA
Enrlranmenlel QHaffly
Monitoring Report Submittal
..............................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................
Permit Number#* WQ0004797
Name of Facility:* Clement Pappas NC LLC
Month:* November Year:* 2021
Report Information
Type* Upload Document*
GW-59 November2021Ground water 8.6MB
reports signed.pdf
PDF Only
Please upload one PDF containing all applicable monitoring reports
(i.e., NDMR, NDAR-1, NDAR-2,NDMLR,GW-59).
Confirmation Email Address:* [e-mail]
Name of Submitter:* Dale I Wolfe
Signature:
a '
Date of submittal: 12/21/2021
This will be filled in automatically
Initial Review
...................
Reviewer: Mokashi, Poorva

Is the project number correct?* WQ0004797
Is the monitoring report accepted?* Yes No
Regional Office* Asheville
Accepted Date: 1/14/2022

Anchor QEA of North Carolina, PLLC ANCHOR
231 Haywood Street
Asheville, North Carolina 28801 QEA
828.281.3350
December 17, 2021
Blake Kehoe
Director, Engineering
Lassonde Pappas &Company., Inc.
125 Industrial Park Road
Hendersonville, North Carolina 28792
Re: Fall 2021 Groundwater Sampling Event and Well Integrity Evaluation
Clement Pappas NC, LLC
Dear Mr. Kehoe,
Anchor QEA of North Carolina, PLLC, is pleased to present the results of the Fall 2021 well
integrity evaluation for monitoring well MW-7R and water quality monitoring event at the
Clement Pappas NC, LLC (Clement Pappas)facility(the Site), located at 485 Brookside Camp Road
in Hendersonville, North Carolina.The company that operates the facility rebranded to
Lassonde Pappas&Company in 2016. However,for permitting purposes,the Hendersonville facility
retains the Clement Pappas NC LLC name that is designated on the property deed.Clement Pappas is
currently permitted under a Wastewater Irrigation System Permit by the North Carolina Department of
Environmental Quality(DEQ) Environmental Management Commission for the operation of a
99,900gallon per day wastewater treatment and irrigation facility.
Groundwater Quality
Anchor QEA performed the groundwater sampling event at the Site on October 27 and 28, 2021.A Site
location map is included in Figure 1.The groundwater sampling event was performed in accordance
with DEQ wastewater irrigation system permit No.WQ0004797 issued September 3, 2015, and renewed
May 15, 2020 (referred to as the permit in this letter; effective September 1, 2020, and expires July 31,
2026).Anchor QEA used low-flow methods to purge and collect groundwater samples from six
monitoring wells: MW-4, MW-5, MW-6, MW-7R, MW-8, and MW-9. Monitoring well MW-9 was installed
April 14, 2015,to replace the previously damaged monitoring well MW-2R.The locations of the
monitoring wells are shown in Figure 2.Anchor QEA submitted the groundwater samples to Pace
Analytical Services, Inc., a North Carolina-certified laboratory,for analysis of the parameters specified in
the permit, as follows:
• Total organic carbon • Total nitrate
• Chloride • Phosphorous
• Fecal coliform • Total dissolved solids
• Total ammonia • Volatile organic compounds (VOCs)
\\Athena\Asheville\Projects\Clement Pappas\Reports\2021\October\2021217 Fall 2021 Groundwater Sampling Event Clement Pappas NC,LLCdocx

December 17,2021
Page 2
Groundwater Elevation
Table 1 summarizes current and historical groundwater elevations from November 2018 to October 2021.
Except for monitoring well MW-9, all monitoring well concrete pads and top-of-well casing (TOC)
elevations were surveyed by Wes Cole Land Surveying, PA, on November 21, 2012. Monitoring well
MW-9 was surveyed by Wes Cole Land Surveying, PA, on May 29, 2015.The surveyed TOC elevations are
indicated in Table 1.
Groundwater Analytical Results
Table 2 summarizes the current and historical groundwater analytical results from November 2018 to
October 2021. During the current sampling event,the parameters analyzed were below or within the
groundwater standards provided in the permit,' except for nitrate and pH,which are described as follows:
• The pH of the samples collected from MW-4 (5.7 standard units [SU]), MW-5 (5.7 SU),
MW-6 (5.4 SU), MW-7R (5.3 SU), and MW-9 (5.4 SU) were below the groundwater standard
range of 6.5 to 8.5 SU.The sample collected from the background monitoring well, MW-5, has
a pH (5.7) that is similar to the other groundwater monitoring wells.
• The nitrate concentration exceeded the permit groundwater standard of 10 milligrams per
liter (mg/L) in the sample collected from one monitoring well, MW-7R (26.0 mg/L).
• Two VOCs (tetrachloroethene and trichloroethene) were detected in background monitoring
well MW-5.
— Tetrachloroethene was detected at a concentration of 30.7 microgram per liter (pg/L),
which exceeds the Title 15A, North Carolina Administrative Code [NCAC],
Subchapter 2L, Section .0202 standard (2L standard) of 0.70 pg/L.
— Trichloroethene was detected at a concentration of 11.6 pg/L, which exceeds the
2L groundwater standard (3.0 pg/L).
The 2L standard for total coliform is 1 colony-forming unit per 100 milliliters (1 CFU/100 mL).There is
no specific permit limit or 2L standard for fecal coliform; however, total coliform includes fecal
coliform.The following summarizes fecal coliform results from the groundwater monitoring wells:
• Fecal coliform concentrations exceeded the 2L standard for total coliform in monitoring well
MW-5 (5.0 CFU/100 mL) and was detected at the 2L standard in MW-8 (1.0 CFU/100 mL) and
MW-9 (1.0 CFU/100 mL). Fecal coliform was not detected at or above laboratory detection
limits in the samples collected from all other monitoring wells.
Surface Water Quality
Beginning in May 2017, Clement Pappas voluntarily collected surface water samples from Mud Creek,
analyzing for the same constituents as those sampled in groundwater.The renewed permit issued in
May 2020 and effective September 2020 requires semiannual sampling of the surface water
1 Most of the groundwater standards are represented by the 2L standards,with the exception of nitrate and total organic carbon,
which are set in the Wastewater Irrigation System Permit Number WQ0004797.
\\Athena\Asheville\Projects\Clement Pappas\Reports\2021\October\2021217 Fall 2021 Groundwater Sampling Event Clement Pappas NC,LLCdocx

December 17,2021
Page 3
locations. Sampling point SW-1 is located upstream of the Site, and sampling point SW-2 is located
downstream of the Site. Sampling locations are shown in Figure 2.
Surface Water Analytical Results
Table 3 summarizes the historical and current surface water analytical results. For the October 2021
sampling event, no parameters were detected at concentrations above the associated Title 15A
NCAC Subchapter 2B surface water standards (2B standards).
Since collection of surface water samples for all permit constituents began in May 2017, nitrate
concentrations have been similar in SW-1 (upstream) and SW-2 (downstream).The Fall 2021
sampling showed a similar relationship: upstream sample SW-1 had a nitrate concentration of
0.72 mg/L, while downstream sample SW-2 had a concentration of 0.71 mg/L.The results for total
organic carbon, chloride, total dissolved solids (TDS), ammonia, and total phosphorus were also
similar for upstream and downstream samples, indicating the unlikelihood that the Site is impacting
Mud Creek.
Monitoring Well MW-7R Integrity Evaluation
Monitoring well MW-7R was installed on June 28, 2012 to replace MW-7, which was destroyed in
June 2012 by field equipment. Nitrate concentrations have generally exceeded the groundwater
standard of 10 mg/L(which was established in the permit) since MW-7R was installed in 2012.
However, nitrate concentrations were below the nitrate standard in all samples collected from the
original monitoring well, MW-7. Elevated nitrate concentrations in MW-7R could be an indicator that
overland flow from an irrigation field, in combination with heavy rainfall events, may be infiltrating
directly into MW-7R as surface water.
Before the Fall 2021 sampling event, Anchor QEA evaluated the integrity of MW-7R by inspecting the
well with a downhole camera and deploying transducers in MW-7R and MW-9 to measure water
levels for an extended period.Water levels were compared between the two wells following spray
irrigation application events and heavy rainfall events to determine if groundwater patterns observed
in MW-7R were characteristic of other site groundwater monitoring wells.
Well Inspection
On September 30, 2021, Anchor QEA staff mobilized to the site to perform the well integrity
evaluation.Anchor QEA staff performed a visual inspection of the exterior of the monitoring well. To
inspect the interior of the well, Anchor QEA used a downhole camera to look for any cracks or
pathways for water to enter the well casing outside of the screened interval.
The well stick-up and well pad were inspected for any damage or pathways for infiltration into the
well. The well pad was observed to be in good condition with no cracks and the well stick-up was in
good condition with no damage.The downhole camera showed roots growing through the screen
interval and a large mass of broken off roots approximately 12 feet below TOC.

December 17,2021
Page 4
Water Level Measurements
After inspecting MW-7R with the downhole camera, a Solinst Levellogger transducer and barologger
transducer were deployed in MW-7R to record water level and air pressure in the well. The water
level transducer was deployed 15 feet below TOC and the barologger was installed just inside the
well casing.
For comparison, a Solinst Levellogger was also deployed in monitoring well MW-9. This well was
selected based on a similar topography to MW-7R. The transducer in MW-9 was also set 15 feet
below TOC.All transducers were set to record measurements every 5 minutes starting at 12:00 PM
on September 30, 2021.
Results
On October 27, 2021, during the fall sampling event, the transducers were retrieved from the wells
and their data were downloaded.The water level measurements were corrected for air pressure from
the barologger in MW-7R using Solinst's Levellogger Software Version 4.40. Figure 3 shows the water
level measurements and their changes over the measurement period.
Rainfall data were downloaded from the National Oceanic and Atmospheric Administration's
National Centers for Environmental Information Climate Data Online portal for Station
US1 NCHN0060— Fletcher 2.6 SSW, NC US. A rainfall event of 0.31 inches was measured on
October 4, 2021, and a 5-day precipitation total of 4.67 inches was recorded on October 9, 2021.
Figure 3 shows that the water level in both the wells showed similar responses to the rainfall events,.
Spray irrigation data provided by Clement Pappas indicates that only one application of
17,812 gallons of water was applied to Zone 9 on October 1, 2021, before the heavy rainfall event.
Figure 2 shows that Zone 9 is the most upgradient irrigation zone from MW-7R. Other spray
irrigation events occurred in the other upgradient zones for each monitoring well after the multiday
rain event, and no response was seen in either well from spray irrigation.
Based on the similar responses in water levels between the monitoring wells following a heavy rain
event and spray irrigations, surface water does not appear to be infiltrating the well casing.
Discussion and Recommendations
All of the samples collected during the Fall 2021 sampling event were below the permit standard for
nitrate except for MW-7R,which is consistent with historical results. Based on the evaluation of
MW-7R, Anchor QEA determined that nitrogen leaching from decaying root matter in MW-7R is the
likely cause of elevated nitrate concentrations in MW-7R. Per a discussion regarding the results with
DEQ Hydrogeologist, Brett Laverty, Anchor QEA recommends extracting organic debris, purging, and
chlorinating MW-7R prior to the next sampling event in May 2022.The results for all analyzed
constituents in surface water, including nitrate, were below applicable standards and similar for
upstream and downstream samples.

December 17,2021
Page 5
In accordance with the spray irrigation permit WQ0004797, Clement Pappas is required to submit the
following to the DEQ by December 31, 2021 (on or before the last working day of the month
following the sampling month):
▪ Laboratory analytical reports and chain-of-custody forms (Attachment 1)
i Well sampling logs and the equipment documentation and instrument calibration data sheet
(Attachment 2)
• DEQ GW-59A—Compliance Report Form (Attachment 3)
▪ DEQ GW-59—Groundwater Quality Monitoring: Compliance Report Form, for each
monitoring well (Attachment 4)
Anchor QEA proposes to complete the next scheduled groundwater and surface water sampling
event in May 2022.
If you have any questions or would like additional information, please do not hesitate to contact me
at [phone] or [e-mail].
Sincerely,
I!WI 1
„
t�.
Jennifer Verde, PE / /James Robert Howell, PG '
Managing Engineer Principal Scientist ``
110000
Attachments wlooi
Table 1 Current and Historical Groundwater Elevation Measurements
Table 2 Current and Historical Groundwater Analytical Results
Table 3 Current and Historical Surface Water Analytical Results
Figure 1 Site Location Map
Figure 2 Site Map
Figure 3 Transducer Water Level Measurements at MW-9 and MW-7R
Attachment 1 Laboratory Analytical Reports and Chain-of-Custody Forms
Attachment 2 Well Sampling Logs and Instrument Calibration Data Sheet
Attachment 3 DEQ GW-59A—Compliance Report Form
i;.
Attachment 4 DEQ GW-59—Groundwater Quality Monitoring: Compliance Report Forms

Tables

Table 1
Current and Historical Groundwater Elevation Measurements
Top-of-Casing
Screened Depth to 1 Top-of-Casing Height Above Groundwater
Well Interval Groundwater Elevation Ground Surface Elevation
Identification (ft bgs) Date Measured (ft) (ft AMSL) (ft) (ft AMSL)
05/02/2018 1 8.44 2055.33
1
11/02/2018 8.00 2055.77
05/21/2019 8,49 2055.28
11/14/2019 8.82 2054.95
MW-4 5.0- 15.0 2063.77 2.43
05/06/2020 7.98 2055.79
11/06/2020 8.02 2055.75
05/11/2021 8.52 2055 25
10/28/2021 9.15 2054.62
05/02/2018 8.47 2077.93
11/02/2018 1 8.23 2078.17
05/21/2019 8.57 2077.83
i
11/14/2019 8.90 2077.50
MW-5 9.0- 19.0 2085.60 3.00
05/06/2020 8.28 2078.12
11/06/2020 8.90 2077.50
05/11/2021 8.77 2077.63
10/28/2021 9.44 2076.96
05/02/2018 5.36 2056.54
r
11/02/2018 5.03 2056.87
05/21/2019 I 5.53 2056.37
11/14/2019 5.59 2056.31
MW-6 5.0- 10.0 2061.17 3.00
05/06/2020 5.41 2056.49
11/06/2020 5.33 2056.57
05/11/2021 1-71 5.68 2056.22
10/28/2021 5.94 2055.96
05/02/2018 10.99 2051.87
11/02/2018 10.33 2052.53
05/21/2019 10.88 2051.98
11/14/2019 11.33 2051.53
MW-7R 5.0- 15.0 2062.86 3.00
05/06/2020 10.11 2052.75
11/06/2020 10.05 2052.81
05/11/2021 10.85 2052.01
10/27/2021 11.74 2051.12
05/02/2018 9.39 I 2051.41
11/02/2018 8.85 2051.95
05/21/2019 9.38 2051.42
11/14/2019 9.75 2051.05
MW-8 3.0- 13.0 2060.80 3,00
05/06/2020 8.54 2052.26
11/06/2020 8.37 2052.43
05/11/2021 9.24 2051.56
10/27/2021 I 10.06 2050.74
Fall 2021 Groundwater Sampling Event Page 1 of 2
Clement Pappas,Hendersonville, North Carolina December 2021

Table 1
Current and Historical Groundwater Elevation Measurements
Top-of-Casing
Screened Depth to Top-of-Casing Height Above Groundwater
Well Interval Groundwater". Elevation Ground Surface Elevation
Identification (ft b s) Date Measured (ft) (ft AIWISL) (ft) (ft AMSL)
05/02/2018 5.07 2055.16
11/02/2018 4.55 2055.68
05/21/2019 4.89 2055.34
11/14/2019 5.15 2055.08
MW-9 3.0-13.0 2060.23 1.44
05/06/2020 4.30 2055.93
11/06/2020 4.10 2056.13
05/11/2021 4.75 2055.48
10/27/2021 5.57 2054.66
Notes:
Top-of-casing elevations:MW-5 through MW-8 top-of-casing elevations are based on a survey by Hill and Associates Surveyors,dated January 10,2002,
through May 2012.MW-2R and MW-4 top-of-casing elevations are based on differential level measurements made by Altamont Environmental,Inc.,on
June 26,2006,through May 2012.The top-of-casing elevations for the monitoring wells were resurveyed on November 21,2012,by Wes Cole Land
Surveying.The top-of-casing elevations for MW-9 were surveyed on May 29,2015,by Wes Cole Land Surveying.
Monitoring is performed in accordance with Permit No.WQ0004797 issued to Clement Pappas on May 15,2020 and effective on September 1,2020.
AMSL:above mean sea level
bgs:below ground surface
ft:feet
Fall 2021 Groundwater Sampling Event Page 2 of 2
Clement Pappas,Hendersonville,North Carolina December 2021

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)19 6.71 NM 7.2 2.0 1.2 51 <0.10 0.100 <0.50 i <0.50 I <0.50 <0.50 <1.0 j <0.50
)20 6.41 2.8 <1.0 3.6 139 <0.10 <0.050 NR
)20 6.34 2.8 Min 14.0 2.4 127 <0.10 <0.050 <0.50 <0.50 <0.50 <0.50 <1.0 <0.50
)21 6.6 3.8 2.0 <1.0 1.7 114 <0.10 <0.050 NR
)21 6.6 4.7 3.5 1.0 0.86 189 < 0.10 < 0.050 <0.50 I <0.50 <0.50 <0.50 <1.0 <0.50

et
.
a° cw
I CY
_ d a a 0
•- L.
N ;.! 4. ..N W
0
� ..., .tJ.. 1 0 , �. �C. d 0 N ,,- r O. V _ ui
E
Es ` U� _ LP _v
, i. - ty_ I-,,,iti ^ ,.
sate (SU)
(mg/L) (mg/L) per 100 mL) (mg/L) (m9/1) (m9/I) (mg/1) (pg/L) (pg/L) (pg/L) (N9/1-) (pg/L) (pg/L)
)18 5.52 4.6 4.9 <2.0 0.58 69 <0.10 0.370 NR
)18 5.11 8.4 5.8 <10.0 0.57 88 <0.10 0.470 f <0.50 <0.50J <0.50 I <0.50 [<1.0 <0.50
)19 5.64 7.2 4.6 <10.0 0.20 80 <0.050 0.230 NR
119 5.57 6.1 5.4 <1.0 0.89 56 <0.10 0.076 <0.50 1 <0.50 I <0.50 <0.50 I <1.0 <0.50
)20 5.52 5.9 1.8 <1.0 <0.040 68.0 <0.10 0.099 NR
)20 4.93 4.5 1.4 16.0 0.043 88.0 <0.10 0.095 <0.50 <0.50 <0.50 <0.50 <1.0 <0.50
)21 5.4 3.6 9.8 <2.0 1.9 <25.0 <0.10 0.089 NR
121 5.4 I 3.8 3.2 1.0 1 0.35 I 48.0 < 0.10 < 0.050 <0.50 1 <0.50 I <0.50 ( <0.50 <1.0 I <0.50
Live Code,Title 15A Subchapter 2L-Groundwater Classifications and Standards, Department of Environmental Quality(Amended April 1,2013).Total organic carbon and nitrate standards are set in Wastewater Irrigatic
defined 2L standard for fecal coliform;therefore,the standard listed is for"total coliform."
tr above the respective groundwater standard or outside the groundwater standard range.
event.
PLLC;NC lab certification number 5445.
lit No.WQ0004797 issued to Clement Pappas on May 15,2020 and effective on September 1,2020.
s not detected above the method detection limit
d detection limit and below the adjusted reporting limit and is therefore considered an estimate.

Table 3
Current and Historical Surface Water Analytical Results
12 C 13 E Ih
ZO U 1 : 1!- 47 LL 47
Sample Name Sample Date (mg/L) (CFUs per 100 mL) (mg/L)'
2B Standard • I • a NL 230 200 NL NL NL NL
5/2/2018 • :: 1.5 4.8 53.0 0.74 54.0 <0.10 0.044 J
11/2/2018 • 2.9 5.1 780 0.72 54.0 <0.10 0.077
5/21/2019 7.02 1.6 5.0 98.0 0.75 42.0 <0.050 0.067
SW-1 11/14/2019 . 1.9 5.3 118 0.83 1 <0.10 0.1
(Upstream) 5/6/2020 7.20 1.6 4.6 290 1 • 49.0 <0.10 0.092
6 1 1 5.83 1.6 4 145 0.71 56.0 <0.10 <0.050
5/11/2021 6.8 1.3 115.3 1910.80 48.0 <0.10 0.068
10/27/2021® 7.0 El 5.2 145 0.72 52.0 <0.10 0.061
5/2/2018 6.98 1.4 4.4 118.0 0.72 51.0 0.052 1 11
11/2/2018 7.08 2.9 11111 940_0 0.75 53.0 0.099 J 0.076
5/21/2019 6.99 I . 47.0 <0.050 0.068
7.01
(Downstream) .I 111• 6.67
•1 1 <0.10 1111 •1
11/6/2020 6.19 1.6 4.4 97.0 0.70 59.0 <0.10 <0.050
5/11/2021 6.9 1.4 5.0 146 0.74 47.0 <0.10Ni 1
10/27/2021 6.9 1.9 5.2 145 [ 0.71 55.0 F <0.10 0.063
Notes:
2B standard:surface water standard per North Carolina Administrative Code,Title 15A:Department of Environmental Quality,Subchapter 2B-Surface Water
and Wetland Standards(last amended in September 2017),or the standard obtained from the U.S.Environmental Protection Agency Nationally
Recommended Water Quality Criteria for Aquatic Life and Human Health.
Bolded values indicate a concentration equal to or above the respective 2B standard or a value outside the 2B standard range.
<indicates that the constituent concentration was not detected above the laboratory reporting limit
Monitoring is performed in accordance with Permit No.WQ0004797 issued to Clement Pappas on May 15,2020 and effective on September 1,2020.
CFU:coliform-forming unit
1:The concentration is above the adjusted method detection limit and below the adjusted reporting limit and is therefore considered an estimate.
mg/L:milligrams per liter
mL:milliliters
NL: No NC 2B standard exists
SU:standard unit
Fall 2021 Groundwater Sampling Event Page 1 of 1
Clement Pappas,Hendersonville, North Carolina December 2021

Figures

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LEGEND: SOURCE(S):
0 IIIIIIIIIIIIIII
Basemap:USGS Topographic Maps, Fruitland and Hendersonville 0 2,000
® Site Location Quadrangles, 1997.
Parcel:Henderson County GIS 2016 IIIIi
Feet
Publish Dale 2021/12/17 1103 AM I Use, sadyuhoun
F,lepalh �`,dlhenaAA i,ev,lle\ProledsVClement Papl,asVR_urI- G6'F1y,na1 SIIt Lr rau.m M.ii,I rr'
Figure 1
ANCHOR
QEA `�`�`. Site Location Map
Fall 2021 Groundwater Monitoring Report
Lassonde Pappas and Company,Inc.

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2021-10-01 2021-10-05 2021-10-09 2021-10-13 2021-10-17 2021-10-21 2021-10-25
Date
1 Notes:
1.Transducers were deployed 15 ft below the top of casing elevation. — MW-7R
1 2.Water levels were corrected using a barologger that was deployed and recording on the same intervals in MW-7R.
3.Transducers were deployed on 09/30/2021 and began recording at 5-minute intervals at 12:00.Transducers were retrieved on 10/27/2021 during the fall monitoring event. — MW-9
14.The water level shown is the length of the water column above the transducer.
5.Blue vertical lines represent a 5-day rain event totaling 4.67 inches.Rainfall data is from NOAA Station US1NCHN0060-FLETCHER 2.6 55W,NC US.
Pubbsh Date 1,.:,'1i,..0 11128 Ali:I UJsar SVR•SCOT.
File Path`;athera';Aslnevillo\Projects\,CIament PappassMW 71?Integaty As5e5srne!iiApythontt.assonde_Pappa.;F.^:x/'P_As,esmoot py
,\ZANCHOR Figure 3
OTA", Transducer Water Level Measurements at MW-9 and MW-7R
Fall 2021 Groundwater Sampling Event
Clement Pappas,Hendersonville,North Carolina

Attachment 1
Laboratory Analytical Reports and
Chain-of-Custody Forms

Pace Analytical Services,LLC
Analytical Asheville,NC 28804
www.pecelabs.cam [phone]
November 05, 2021
Jennifer Verde
Anchor QEA
231 Haywood Street
Asheville, NC 28801
RE: Project: Lassonde Pappas
Pace Project No.: 92569098
Dear Jennifer Verde:
Enclosed are the analytical results for sample(s) received by the laboratory on October 27,2021. The results relate only to
the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual,where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace Analytical Services-Asheville
• Pace Analytical Services-Charlotte
• Pace Analytical Services-Eden
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Lorri Patton
[e-mail]
1(828)254-7176
Project Manager
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
without the written consent of Pace Analytical Services,LLC. Page 1 of 34

(51 Pace Analytical Services,LLC
Analytical
tical® 2225 Riverside Dr__„?':ce .
lYr Asheville,NC 28804
www.pacslsbs.com
[phone]
CERTIFICATIONS
Project: Lassonde Pappas
Pace Project No.: 92569098
Pace Analytical Services Charlotte
9800 Kincey Ave.Ste 100, Huntersville, NC 28078 South Carolina Certification#:99006001
Louisiana/NELAP Certification#LA170028 Florida/NELAP Certification#:E87627
North Carolina Drinking Water Certification#:37706 Kentucky UST Certification#:84
North Carolina Field Services Certification#:5342 VirginiaNELAP Certification#:460221
North Carolina Wastewater Certification#: 12
Pace Analytical Services Asheville
2225 Riverside Drive,Asheville, NC 28804 North Carolina Wastewater Certification#:40
Florida/NELAP Certification#:E87648 South Carolina Certification#:99030001
North Carolina Drinking Water Certification#:37712 VirginiaNELAP Certification#:460222
Pace Analytical Services Eden
205 East Meadow Road Suite A, Eden, NC 27288 North Carolina Wastewater Certification#:633
North Carolina Drinking Water Certification#:37738 VirginiaNELAP Certification#:460025
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
without the written consent of Pace Analytical Services,LLC. Page 2 of 34

Pace Analytical Services,LLC
a���ww Analytical
®
2225 Riverside Dr.
r (06 �111RI I al Asheville,NC 28804
www.pecelabs.cam [phone]
SAMPLE ANALYTE COUNT
Project: Lassonde Pappas
Pace Project No,: 92569098
Analytes
Lab ID Sample ID Method Analysts Reported Laboratory
92569098001 MW-7R EPA 350.1 Rev 2.0 1993 SRS 11 PASI-E
SM 6200B SAS 63 PASI-C
SM 2540C-2015 MJP 1 PASI-A
SM 9222D-2015 SMK 1 PASI-A
EPA 353.2 Rev 2.0 1993 MFO 1 PASI-A
EPA 365.1 Rev 2.0 1993 MDW 1 PASI-A
SM 4500-CI-E-2011 MDW 1 PASI-A
SM 5310B-2014 MDW 1 PASI-A
92569098002 MW-8 EPA 350.1 Rev 2.0 1993 SRS 1 PASI-E
SM 6200B SAS 63 PASI-C
SM 2540C-2015 MJP 1 PASI-A
SM 9222D-2015 SMK 1 PASI-A
EPA 353.2 Rev 2.0 1993 MFO 1 PASI-A
EPA 365.1 Rev 2.0 1993 MDW 1 PASI-A
SM 4500-CI-E-2011 MDW 1 PASI-A
SM 5310B-2014 MDW 1 PASI-A
92569098003 MW-9 EPA 350.1 Rev 2.0 1993 SRS 1 PASI-E
SM 6200B SAS 63 PASI-C
SM 2540C-2015 MJP 1 PASI-A
SM 9222D-2015 SMK 1 PASI-A
EPA 353.2 Rev 2.0 1993 MFO 1 PASI-A
EPA 365.1 Rev 2.0 1993 MDW 1 PASI-A
SM 4500-CI-E-2011 MDW 1 PASI-A
SM 5310B-2014 MDW 1 PASI-A
92569098004 SW-1 EPA 350.1 Rev 2.0 1993 SRS 1 PASI-E
SM 2540C-2015 MJP 1 PASI-A
SM 9222D-2015 SMK 1 PASI-A
EPA 353.2 Rev 2.0 1993 MFO 1 PASI-A
EPA 365.1 Rev 2.0 1993 MDW 1 PASI-A
SM 4500-CI-E-2011 MDW 1 PASI-A
SM 5310B-2014 MDW 1 PASI-A
92569098005 SW-2 EPA 350.1 Rev 2.0 1993 SRS 1 PASI-E
SM 2540C-2015 MJP 1 PASI-A
SM 9222D-2015 SMK 1 PASI-A
EPA 353.2 Rev 2.0 1993 MFO 1 PASI-A
EPA 365.1 Rev 2.0 1993 MDW 1 PASI-A
SM 4500-CI-E-2011 MDW 1 PASI-A
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
without the written consent of Pace Analytical Services,LLC Page 3 of 34

A n�', tical Pace Analytical Services,LLC
2225 Riverside Dr.
HIS Y( li Asheville,NC28804
www.pacalabs.eom [phone]
SAMPLE ANALYTE COUNT
Project: Lassonde Pappas
Pace Project No.: 92569098
Analytes
Lab ID Sample ID Method Analysts Reported Laboratory
SM 5310B-2014 MDW 1 PASI-A
92569098006 Trip Blank 1 SM 6200B SAS 63 PASI-C
PASI-A=Pace Analytical Services-Asheville
PASI-C=Pace Analytical Services-Charlotte
PASI-E=Pace Analytical Services-Eden
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
without the written consent of Pace Analytical Services,LLC. Page 4 of 34

Pace Analytical Services,LLC
d 2225 Riverside Dr.
IeAnalytrcal Asheville,NC 28804
(7./17/11
www.pacslabs.cam [phone]
ANALYTICAL RESULTS
Project: Lassonde Pappas
Pace Project No.: 92569098
Sample: MW-7R Lab ID: 92569098001 Collected: 10/27/21 11:43 Received: 10/27/21 14:22 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
350.1 Ammonia EDN Analytical Method: EPA 350.1 Rev 2.0 1993
Pace Analytical Services-Eden
Nitrogen,Ammonia ND mg/L 0.10 1 10/29/21 10:36 7664-41-7
6200E MSV Analytical Method:SM 6200B
Pace Analytical Services-Charlotte
Benzene ND ug/L 0.50 1 10/28/21 23:23 71-43-2
Bromobenzene ND ug/L 0.50 1 10/28/21 23:23 108-86-1
Bromochloromethane ND ug/L 0.50 1 10/28/21 23:23 74-97-5
Bromodichloromethane ND ug/L 0.50 1 10/28/21 23:23 75-27-4
Bromoform ND ug/L 0.50 1 10/28/21 23:23 75-25-2
Bromomethane ND ug/L 5.0 1 10/28/21 23:23 74-83-9
n-Butylbenzene ND ug/L 0.50 1 10/28/21 23:23 104-51-8
sec-Butylbenzene ND ug/L 0.50 1 10/28/21 23:23 135-98-8
tert-Butylbenzene ND ug/L 0.50 1 10/28/21 23:23 98-06-6
Carbon tetrachloride ND ug/L 0.50 1 10/28/21 23:23 56-23-5
Chlorobenzene ND ug/L 0.50 1 10/28/21 23:23 108 90 7
Chloroethane ND ug/L 1.0 1 10/28/21 23:23 75-00-3
Chloroform ND ug/L 0.50 1 10/28/21 23:23 67-66-3
Chloromethane ND ug/L 1.0 1 10/28/21 23:23 74-87-3
2-Chlorotoluene ND ug/L 0.50 1 10/28/21 23:23 95-49-8
4-Chlorotoluene ND ug/L 0.50 1 10/28/21 23:23 106-43-4
1,2-Dibromo-3-chloropropane ND ug/L 1.0 1 10/28/21 23:23 96-12-8
Dibromochloromethane ND ug/L 0.50 1 10/28/21 23:23 124-48-1
1,2-Dibromoethane(EDB) ND ug/L 0.50 1 10/28/21 23:23 106-93-4
Dibromomethane ND ug/L 0.50 1 10/28/21 23:23 74-95-3
1,2-Dichlorobenzene ND ug/L 0.50 1 10/28/21 23:23 95-50-1
1,3-Dichlorobenzene ND ug/L 0.50 1 10/28/21 23:23 541-73-1
1,4-Dichlorobenzene ND ug/L 0.50 1 10/28/21 23:23 106-46-7
Dichlorodifluoromethane ND ug/L 0.50 1 10/28/21 23:23 75-71-8
1,1-Dichloroethane ND ug/L 0.50 1 10/28/21 23:23 75-34-3
1,2-Dichloroethane ND ug/L 0.50 1 10/28/21 23:23 107-06-2
1,1-Dichloroethene ND ug/L 0.50 1 10/28/21 23:23 75-35-4
cis-1,2-Dichloroethene ND ug/L 0.50 1 10/28/21 23:23 156-59-2
trans-1,2-Dichloroethene ND ug/L 0.50 1 10/28/21 23:23 156-60-5
1,2-Dichloropropane ND ug/L 0.50 1 10/28/21 23:23 78-87-5
1,3-Dichloropropane ND ug/L 0.50 1 10/28/21 23:23 142-28-9
2,2-Dichloropropane ND ug/L 0.50 1 10/28/21 23:23 594-20-7
1,1-Dichloropropene ND ug/L 0.50 1 10/28/21 23:23 563-58-6
cis-1,3-Dichloropropene ND ug/L 0.50 1 10/28/21 23:23 10061-01-5
trans-1,3-Dichloropropene ND ug/L 0.50 1 10/28/21 23:23 10061-02-6
Diisopropyl ether ND ug/L 0.50 1 10/28/21 23:23 108-20-3
Ethylbenzene ND ug/L 0.50 1 10/28/21 23:23 100-41-4
Hexachloro-1,3-butadiene ND ug/L 2.0 1 10/28/21 23:23 87-68-3
lsopropylbenzene(Cumene) ND ug/L 0.50 1 10/28/21 23:23 98-82-8
Methylene Chloride ND ug/L 2.0 1 10/28/21 23:23 75-09-2
Methyl-tert-butyl ether ND ug/L 0.50 1 10/28/21 23:23 1634-04-4
Naphthalene ND ug/L 2.0 1 10/28/21 23:23 91-20-3
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date: 11/05/2021 03:28 PM without the written consent of Pace Analytical Services,LLC Page 5 of 34

Pace Analytical Services,LLC
ca ® 2225 Riverside Dr.
Analytical' Asheville,NC 28804
www.pacelabs.com [phone]
ANALYTICAL RESULTS
Project: Lassonde Pappas
Pace Project No,: 92569098
Sample: MW-7R Lab ID: 92569098001 Collected: 10/27/21 11:43 Received: 10/27/21 14:22 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
6200E MSV Analytical Method:SM 6200B
Pace Analytical Services-Charlotte
n-Propylbenzene ND ug/L 0.50 1 10/28/21 23:23 103-65-1
Styrene ND ug/L 0.50 1 10/28/21 23:23 100-42-5
1,1,1,2-Tetrachloroethane ND ug/L 0.50 1 10/28/21 23:23 630-20-6
1,1,2,2-Tetrachloroethane ND ug/L 0.50 1 10/28/21 23:23 79-34-5
Tetrachloroethene ND ug/L 0.50 1 10/28/21 23:23 127-18-4
Toluene ND ug/L 0.50 1 10/28/21 23:23 108-88-3
1,2,3-Trichlorobenzene ND ug/L 2.0 1 10/28/21 23:23 87-61-6
1,2,4-Trichlorobenzene ND ug/L 2.0 1 10/28/21 23:23 120-82-1
1,1,1-Trichloroethane ND ug/L 0.50 1 10/28/21 23:23 71-55-6
1,1,2-Trichloroethane ND ug/L 0.50 1 10/28/21 23:23 79-00-5
Trichloroethene ND ug/L 0.50 1 10/28/21 23:23 79-01-6
Trichlorofluoromethane ND ug/L 1.0 1 10/28/21 23:23 75-69-4
1,2,3-Trichloropropane ND ug/L 0.50 1 10/28/21 23:23 96-18-4
1,2,4-Trimethylbenzene ND ug/L 0.50 1 10/28/21 23:23 95-63-6
1,3,5-Trimethylbenzene ND ug/L 0.50 1 10/28/21 23:23 108-67-8
Vinyl chloride ND ug/L 1.0 1 10/28/21 23:23 75-01-4
m&p-Xylene ND ug/L 1.0 1 10/28/21 23:23 179601-23-1
o-Xylene ND ug/L 0.50 1 10/28/21 23:23 95-47-6
Surrogates
1,2-Dichloroethane-d4(S) 94 % 70-130 1 10/28/21 23:23 17060-07-0
4-Bromofluorobenzene(S) 100 % 70-130 1 10/28/21 23:23 460-00-4
Toluene-d8(S) 103 % 70-130 1 10/28/21 23:23 2037-26-5
2540C 0 Total Dissolved Solids Analytical Method:SM 2540C-2015
Pace Analytical Services-Asheville
Total Dissolved Solids 222 mg/L 25.0 1 11/02/21 10:33
MBIO 9222D Fecal Coliform AVL Analytical Method:SM 9222D-2015 Preparation Method:SM 9222D-2015
Pace Analytical Services-Asheville
Fecal Coliforms ND CFU/100 mL 1.0 1 10/27/21 17:52 10/28/21 16:14
353.2 Nitrogen,NO2/NO3 unpres Analytical Method:EPA 353.2 Rev 2.0 1993
Pace Analytical Services-Asheville
Nitrogen,Nitrate 26.0 mg/L 0.40 10 10/28/21 01:46 14797-55-8
365.1 Phosphorus,Total Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation Method: EPA 365.1 Rev 2.0 1993
Pace Analytical Services-Asheville
Phosphorus ND mg/L 0.050 1 11/01/21 18:05 11/01/21 22:15 7723-14-0
4500 Chloride Analytical Method:SM 4500-CI-E-2011
Pace Analytical Services-Asheville
Chloride 24.9 mg/L 1.0 1 11/01/2120:39 16887-00-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date: 11/05/2021 03:28 PM without the written consent of Pace Analytical Services,LLC. Page 6 of 34

Pace Analytical Services,LLC
/',J4eAnalytical4 2225 Riverside Dr.
Asheville,NC 28804
(/',"
www.pacelabs.com
[phone]
ANALYTICAL RESULTS
Project: Lassonde Pappas
Pace Project No.: 92569098
Sample: MW 7R Lab ID: 92569098001 Collected: 10/27/21 11:43 Received: 10/27/21 14:22 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
5310B TOC Analytical Method:SM 5310B-2014
Pace Analytical Services-Asheville
Total Organic Carbon 1.1 mg/L 1.0 1 11/02/21 03:00 7440-44-0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date: 11/05/2021 03:28 PM without the written consent of Pace Analytical Services,LLC. Page 7 of 34

Pace Analytical Services,LLC
A n�f, tical 2225 Riverside Dr.
HI I /Yr lr Asheville,NC 28804
itit
www.pacalabs.cam [phone]
ANALYTICAL RESULTS
Project: Lassonde Pappas
Pace Project No. 92569098
Sample: MW-8 Lab ID: 92569098002 Collected: 10/27/21 10:28 Received: 10/27/21 14:22 Matrix:Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
350.1 Ammonia EDN Analytical Method:EPA 350.1 Rev 2.0 1993
Pace Analytical Services-Eden
Nitrogen,Ammonia ND mg/L 0.10 1 10/29/21 10:40 7664-41-7
6200B MSV Analytical Method:SM 6200B
Pace Analytical Services-Charlotte
Benzene ND ug/L 0.50 1 10/28/21 23:41 71-43-2
Bromobenzene ND ug/L 0.50 1 10/28/21 23:41 108-86-1
Bromochloromethane ND ug/L 0.50 1 10/28/21 23:41 74-97-5
Bromodichloromethane ND ug/L 0.50 '1 10/28/21 23:41 75-27-4
Bromoform ND ug/L 0.50 1 10/28/21 23:41 75-25-2
Bromomethane ND ug/L 5.0 1 10/28/21 23:41 74-83-9
n-Butylbenzene ND ug/L 0.50 1 10/28/21 23:41 104-51-8
sec-Butylbenzene ND ug/L 0.50 1 10/28/21 23:41 135-98-8
tert-Butylbenzene ND ug/L 0.50 1 10/28/21 23:41 98-06-6
Carbon tetrachloride ND ug/L 0.50 1 10/28/21 23:41 56-23-5
Chlorobenzene ND ug/L 0.50 1 10/28/21 23:41 108-90-7
Chloroethane ND ug/L 1.0 1 10/28/21 23:41 75-00-3
Chloroform ND ug/L 0.50 1 10/28/21 23:41 67-66-3
Chloromethane ND ug/L 1.0 1 10/28/21 23:41 74-87-3
2-Chlorotoluene ND ug/L 0.50 1 10/28/21 23:41 95-49-8
4-Chlorotoluene ND ug/L 0.50 1 10/28/21 23:41 106-43-4
1,2-Dibromo-3-chloropropane ND ug/L 1.0 1 10/28/21 23:41 96-12-8
Dibromochloromethane ND ug/L 0.50 1 10/28/21 23:41 124-48-1
1,2-Dibromoethane(EDB) ND ug/L 0.50 1 10/28/21 23:41 106-93-4
Dibromomethane ND ug/L 0.50 1 10/28/21 23:41 74-95-3
1,2-Dichlorobenzene ND ug/L 0.50 1 10/28/21 23:41 95-50-1
1,3-Dichlorobenzene ND ug/L 0.50 1 10/28/21 23:41 541-73-1
1,4-Dichlorobenzene ND ug/L 0.50 1 10/28/21 23:41 106-46-7
Dichlorodifluoromethane ND ug/L 0.50 1 10/28/21 23:41 75-71-8
1,1-Dichloroethane ND ug/L 0.50 1 10/28/21 23:41 75-34-3
1,2-Dichloroethane ND ug/L 0.50 1 10/28/21 23:41 107-06-2
1,1-Dichloroethene ND ug/L 0.50 1 10/28/21 23:41 75-35-4
cis-1,2-Dichloroethene ND ug/L 0.50 1 10/28/21 23:41 156-59-2
trans-1,2-Dichloroethene ND ug/L 0.50 1 10/28/21 23:41 156-60-5
1,2-Dichloropropane ND ug/L 0.50 1 10/28/21 23:41 78-87-5
1,3-Dichloropropane ND ug/L 0.50 1 10/28/21 23:41 142-28-9
2,2-Dichloropropane ND ug/L 0.50 1 10/28/21 23:41 594-20-7
1,1-Dichloropropene ND ug/L 0.50 1 10/28/21 23:41 563-58-6
cis-1,3-Dichloropropene ND ug/L 0.50 1 10/28/21 23:41 10061-01-5
trans-1,3-Dichloropropene ND ug/L 0.50 1 10/28/21 23:41 10061-02-6
Diisopropyl ether ND ug/L 0.50 1 10/28/21 23:41 108-20-3
Ethylbenzene ND ug/L 0.50 1 10/28/21 23:41 100-41-4
Hexachloro-1,3-butadiene ND ug/L 2.0 1 10/28/21 23:41 87-68-3
Isopropylbenzene(Cumene) ND ug/L 0.50 1 10/28/21 23:41 98-82-8
Methylene Chloride ND ug/L 2.0 1 10/28/21 23:41 75-09-2
Methyl-tert-butyl ether ND ug/L 0.50 1 10/28/21 23:41 1634-04-4
Naphthalene ND ug/L 2.0 1 10/28/21 23:41 91-20-3
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date: 11/05/2021 03:28 PM without the written consent of Pace Analytical Services,LLC. Page 8 of 34

Pace Analytical Services,LLC
d
(77,4
2225 Riverside Dr.
a 'A1lalytical Asheville,NC 28804
www.pacslabs.com [phone]
ANALYTICAL RESULTS
Project: Lassonde Pappas
Pace Project No.: 92569098
Sample: MW-8 Lab ID: 92569098002 Collected: 10/27/21 10:28 Received: 10/27/21 14:22 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
6200B MSV Analytical Method:SM 6200E
Pace Analytical Services-Charlotte
n-Propylbenzene ND ug/L 0.50 1 10/28/21 23:41 103-65-1
Styrene ND ug/L 0.50 1 10/28/21 23:41 100-42-5
1,1,1,2-Tetrachloroethane ND ug/L 0.50 1 10/28/21 23:41 630-20-6
1,1,2,2-Tetrachloroethane ND ug/L 0.50 11 10/28/21 23:41 79-34-5
Tetrachloroethene ND ug/L 0.50 1 10/28/21 23:41 127-18-4
Toluene ND ug/L 0.50 1 10/28/21 23:41 108-88-3
1,2,3-Trichlorobenzene ND ug/L 2.0 1 10/28/21 23:41 87-61-6
1,2,4-Trichlorobenzene ND ug/L 2.0 1 10/28/21 23:41 120-82-1
1,1,1-Trichloroethane ND ug/L 0.50 1 10/28/21 23:41 71-55-6
1,1,2-Trichloroethane ND ug/L 0.50 1 10/28/21 23:41 79-00-5
Trichloroethene ND ug/L 0.50 1 10/28/21 23:41 79-01-6
Trichlorofluoromethane ND ug/L 1.0 1 10/28/21 23:41 75-69-4
1,2,3-Trichloropropane ND ug/L 0.50 1 10/28/21 23:41 96-18-4
1,2,4-Trimethylbenzene ND ug/L 0.50 1 10/28/21 23:41 95-63-6
1,3,5-Trimethylbenzene ND ug/L 0.50 1 10/28/21 23:41 108-67-8
Vinyl chloride ND ug/L 1.0 1 10/28/21 23:41 75-01-4
m&p-Xylene ND ug/L 1.0 1 10/28/21 23:41 179601-23-1
o-Xylene ND ug/L 0.50 11 10/28/21 23:41 95-47-6
Surrogates
1,2-Dichloroethane-d4(S) 94 % 70-130 1 10/28/21 23:41 17060-07-0
4-Bromofluorobenzene(S) 99 % 70-130 1 10/28/21 23:41 460-00-4
Toluene-d8(S) 102 % 70-130 1 10/28/21 23:41 2037-26-5
2540C Total Dissolved Solids Analytical Method:SM 2540C-2015
Pace Analytical Services-Asheville
Total Dissolved Solids 189 mg/L 25.0 1 11/02/21 10:33
MBIO 9222D Fecal Coliform AVL Analytical Method:SM 9222D-2015 Preparation Method:SM 9222D-2015
Pace Analytical Services-Asheville
Fecal Coliforms 1.0 CFU/100 mL 1.0 1 10/27/21 17:52 10/28/21 16:14
353.2 Nitrogen,NO2/NO3 unpres Analytical Method:EPA 353.2 Rev 2.0 1993
Pace Analytical Services-Asheville
Nitrogen,Nitrate 0.86 mg/L 0.040 1 10/28/21 01:22 14797-55-8
365.1 Phosphorus,Total Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation Method: EPA 365.1 Rev 2.0 1993
Pace Analytical Services-Asheville
Phosphorus ND mg/L 0.050 1 11/01/21 18:05 11/01/21 22:19 7723-14-0
4500 Chloride Analytical Method:SM 4500-CI-E-2011
Pace Analytical Services-Asheville
Chloride 3.5 mg/L 1.0 1 11/01/21 20:40 16887-00-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date: 11/05/2021 03:28 PM without the written consent of Pace Analytical Services,LLC. Page 9 of 34

Pace Analytical Services,LLC
__Ac7J'ce
/Inaltical hevNC804Hl 1 J�/`�l� Asheville,NC 28804
www.pacalabs.cam [phone]
it(
ANALYTICAL RESULTS
Project: Lassonde Pappas
Pace Project No.: 92569098
Sample: MW-8 Lab ID: 92569098002 Collected: 10/27/21 10:28 Received: 10/27/21 14:22 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
5310E TOC Analytical Method:SM 5310B-2014
Pace Analytical Services-Asheville
Total Organic Carbon 4.7 mg/L 1.0 1 11/02/21 03:18 7440-44-0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date: 11/05/2021 03:28 PM without the written consent of Pace Analytical Services,LLC. Page 10 of 34

Pace Analytical Services,LLC
Analytical ace ® 2225 Riverside Dr.
Asheville,NC 28804
177-,""e
www.pacelabs.cam [phone]
ANALYTICAL RESULTS
Project: Lassonde Pappas
Pace Project No.: 92569098
Sample: MW-9 Lab ID: 92569098003 Collected: 10/27/21 12:42 Received: 10/27/21 14:22 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
350.1 Ammonia EDN Analytical Method: EPA 350.1 Rev 2.0 1993
Pace Analytical Services-Eden
Nitrogen,Ammonia ND mg/L 0.10 1 10/29/21 10:42 7664-41-7
6200B MSV Analytical Method:SM 6200B
Pace Analytical Services-Charlotte
Benzene ND ug/L 0.50 1 10/28/21 23:58 71-43-2
Bromobenzene ND ug/L 0.50 1 10/28/21 23:58 108-86-1
Bromochloromethane ND ug/L 0.50 1 10/28/21 23:58 74-97-5
Bromodichloromethane ND ug/L 0.50 1 10/28/21 23:58 75-27-4
Bromoform ND ug/L 0.50 1 10/28/21 23:58 75-25-2
Bromomethane ND ug/L 5.0 1 10/28/21 23:58 74-83-9
n-Butylbenzene ND ug/L 0.50 1 10/28/21 23:58 104-51-8
sec-Butylbenzene ND ug/L 0.50 1 10/28/21 23:58 135-98-8
tert-Butylbenzene ND ug/L 0.50 1 10/28/21 23:58 98-06-6
Carbon tetrachloride ND ug/L 0.50 1 10/28/21 23:58 56-23-5
Chlorobenzene ND ug/L 0.50 1 10/28/21 23:58 108-90-7
Chloroethane ND ug/L 1.0 1 10/28/21 23:58 75-00-3
Chloroform ND ug/L 0.50 1 10/28/21 23:58 67-66-3
Chloromethane ND ug/L 1.0 1 10/28/21 23:58 74-87-3
2-Chlorotoluene ND ug/L 0.50 1 10/28/21 23:58 95-49-8
4-Chlorotoluene ND ug/L 0.50 1 10/28/21 23:58 106-43-4
1,2-Dibromo-3-chloropropane ND ug/L 1.0 1 10/28/21 23:58 96-12-8
Dibromochloromethane ND ug/L 0.50 1 10/28/21 23:58 124-48-1
1,2-Dibromoethane(EDB) ND ug/L 0.50 1 10/28/21 23:58 106-93-4
Dibromomethane ND ug/L 0.50 1 10/28/21 23:58 74-95-3
1,2-Dichlorobenzene ND ug/L 0.50 1 10/28/21 23:58 95-50-1
1,3-Dichlorobenzene ND ug/L 0.50 1 10/28/21 23:58 541-73-1
1,4-Dichlorobenzene ND ug/L 0.50 1 10/28/21 23:58 106-46-7
Dichlorodifluoromethane ND ug/L 0.50 1 10/28/21 23:58 75-71-8
1,1-Dichloroethane ND ug/L 0.50 1 10/28/21 23:58 75-34-3
1,2-Dichloroethane ND ug/L 0.50 1 10/28/21 23:58 107-06-2
1,1-Dichloroethene ND ug/L 0.50 1 10/28/21 23:58 75-35-4
cis-1,2-Dichloroethene ND ug/L 0.50 1 10/28/21 23:58 156-59-2
trans-1,2-Dichloroethene ND ug/L 0.50 1 10/28/21 23:58 156-60-5
1,2-Dichloropropane ND ug/L 0.50 1 10/28/21 23:58 78-87-5
1,3-Dichloropropane ND ug/L 0.50 1 10/28/21 23:58 142-28-9
2,2-Dichloropropane ND ug/L 0.50 1 10/28/21 23:58 594-20-7
1,1-Dichloropropene ND ug/L 0.50 1 10/28/21 23:58 563-58-6
cis-1,3-Dichloropropene ND ug/L 0.50 1 10/28/21 23:58 10061-01-5
trans-1,3-Dichloropropene ND ug/L 0.50 1 10/28/21 23:58 10061-02-6
Diisopropyl ether ND ug/L 0.50 1 10/28/21 23:58 108-20-3
Ethylbenzene ND ug/L 0.50 1 10/28/21 23:58 100-41-4
Hexachloro-1,3-butadiene ND ug/L 2.0 1 10/28/21 23:58 87-68-3
lsopropylbenzene(Cumene) ND ug/L 0.50 1 10/28/21 23:58 98-82-8
Methylene Chloride ND ug/L 2.0 1 10/28/21 23:58 75-09-2
Methyl-tent-butyl ether ND ug/L 0.50 1 10/28/21 23:58 1634-04-4
Naphthalene ND ug/L 2.0 1 10/28/21 23:58 91-20-3
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date: 11/05/2021 03:28 PM without the written consent of Pace Analytical Services,LLC. Page 11 of 34

761
Pace Analytical Services,LLC
ceAnalytical 2225 Riverside Dr.
Asheville,NC 28804
www.pecelabs.com [phone]
I
ANALYTICAL RESULTS
Project: Lassonde Pappas
Pace Project No.: 92569098
Sample: MW-9 Lab ID: 92569098003 Collected: 10/27/21 12:42 Received: 10/27/21 14:22 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
6200B MSV Analytical Method:SM 6200B
Pace Analytical Services-Charlotte
n-Propylbenzene ND ug/L 0.50 1 10/28/21 23:58 103-65-1
Styrene ND ug/L 0.50 1 10/28/21 23:58 100-42-5
1,1,1,2-Tetrachloroethane ND ug/L 0.50 1 10/28/21 23:58 630-20-6
1,1,2,2-Tetrachloroethane ND ug/L 0.50 1 10/28/21 23:58 79-34-5
Tetrachloroethene ND ug/L 0.50 1 10/28/21 23:58 127-18-4
Toluene ND ug/L 0.50 1 10/28/21 23:58 108-88-3
1,2,3-Trichlorobenzene ND ug/L 2.0 1 10/28/21 23:58 87-61-6
1,2,4-Trichlorobenzene ND ug/L 2.0 1 10/28/21 23:58 120-82-1
1,1,1-Trichloroethane ND ug/L 0.50 1 10/28/21 23:58 71-55-6
1,1,2-Trichloroethane ND ug/L 0.50 1 10/28/21 23:58 79-00-5
Trichloroethene ND ug/L 0.50 1 10/28/21 23:58 79-01-6
Trichlorofluoromethane ND ug/L 1.0 '1 10/28/21 23:58 75-69-4
1,2,3-Trichloropropane ND ug/L 0.50 1 10/28/21 23:58 96-18-4
1,2,4-Trimethylbenzene ND ug/L 0.50 1 10/28/21 23:58 95-63-6
1,3,5-Trimethylbenzene ND ug/L 0.50 1 10/28/21 23:58 108-67-8
Vinyl chloride ND ug/L 1.0 1 10/28/21 23:58 75-01-4
m&p-Xylene ND ug/L 1.0 1 10/28/21 23:58 179601-23-1
o-Xylene ND ug/L 0.50 1 10/28/21 23:58 95-47-6
Surrogates
1,2-Dichloroethane-d4(S) 94 % 70-130 1 10/28/21 23:58 17060-07-0
4-Bromofluorobenzene(S) 96 % 70-130 1 10/28/21 23:58 460-00-4
Toluene-d8(S) 102 % 70-130 1 10/28/21 23:58 2037-26-5
2540C Total Dissolved Solids Analytical Method:SM 2540C-2015
Pace Analytical Services-Asheville
Total Dissolved Solids 48.0 mg/L 25.0 1 11/02/21 10:33
MBIO 9222D Fecal Coliform AVL Analytical Method:SM 9222D-2015 Preparation Method:SM 9222D-2015
Pace Analytical Services-Asheville
Fecal Coliforms 1.0 CFU/100 mL 1.0 1 10/27/21 17:52 10/28/21 16:14
353.2 Nitrogen,NO2/NO3 unpres Analytical Method: EPA 353.2 Rev 2.0 1993
Pace Analytical Services-Asheville
Nitrogen,Nitrate 0.35 mg/L 0.040 1 10/28/21 01:29 14797-55-8
365.1 Phosphorus,Total Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation Method:EPA 365.1 Rev 2.0 1993
Pace Analytical Services-Asheville
Phosphorus ND mg/L 0.050 1 11/01/21 18:05 11/01/21 22:22 7723-14-0
4500 Chloride Analytical Method:SM 4500-CI-E-2011
Pace Analytical Services-Asheville
Chloride 3.2 mg/L 1.0 1 11/01/21 20:41 16887-00-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date: 11/05/2021 03:28 PM without the written consent of Pace Analytical Services,LLC. Page 12 of 34

Pace Analytical Services,LLC
a 2225 Riverside Dr.
ace Analytical
1(M
www.pacelabs.com Asheville,NC 28804
[phone]
ANALYTICAL RESULTS
Project: Lassonde Pappas
Pace Project No.: 92569098
Sample: MW-9 Lab ID: 92569098003 Collected: 10/27/21 12:42 Received: 10/27/21 14:22 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
5310E TOC Analytical Method:SM 5310B-2014
Pace Analytical Services-Asheville
Total Organic Carbon 3.8 mg/L 1.0 1 11/02/21 03:36 7440-44-0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date: 11/05/2021 03:28 PM without the written consent of Pace Analytical Services,LLC. Page 13 of 34

Pace Analytical Services,LLC
7?
ccAnalytical® 2225 Riverside Dr.
Asheville,NC 28804
www.pecelebs.cem [phone]
i
ANALYTICAL RESULTS
Project: Lassonde Pappas
Pace Project No.: 92569098
Sample: SW-1 Lab ID: 92569098004 Collected: 10/27/21 13:17 Received: 10/27/21 14:22 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
350.1 Ammonia EDN Analytical Method:EPA 350.1 Rev 2.0 1993
Pace Analytical Services-Eden
Nitrogen,Ammonia ND mg/L 0.10 1 10/29/21 10:43 7664-41-7
2540C Total Dissolved Solids Analytical Method:SM 2540C-2015
Pace Analytical Services-Asheville
Total Dissolved Solids 52.0 mg/L 25.0 1 11/02/21 10:33
MBIO 9222D Fecal Coliform AVL Analytical Method:SM 9222D-2015 Preparation Method:SM 9222D-2015
Pace Analytical Services-Asheville
Fecal Coliforms 145 CFU/100 mL 1.0 1 10/27/21 17:52 10/28/21 16:14
353.2 Nitrogen,NO2/NO3 unpres Analytical Method:EPA 353.2 Rev 2.0 1993
Pace Analytical Services-Asheville
Nitrogen,Nitrate 0.72 mg/L 0.040 1 10/28/21 01:30 14797-55-8
365.1 Phosphorus,Total Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation Method:EPA 365.1 Rev 2.0 1993
Pace Analytical Services-Asheville
Phosphorus 0.061 mg/L 0.050 1 11/01/21 18:05 11/01/21 22:23 7723-14-0
4500 Chloride Analytical Method:SM 4500-CI-E-2011
Pace Analytical Services-Asheville
Chloride 5.2 mg/L 1.0 1 11/01/21 20:41 16887-00-6
5310B TOC Analytical Method:SM 5310B-2014
Pace Analytical Services-Asheville
Total Organic Carbon 1.8 mg/L 1.0 1 11/02/21 03:53 7440-44-0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date: 11/05/2021 03:28 PM without the written consent of Pace Analytical Services,LLC. Page 14 of 34

Pace Analytical Services,LLC
1 d l® 2225 Riverside Dr.
n��' �C�I Asheville,NC 28804
www.pacslabs.cam [phone]
ANALYTICAL RESULTS
Project: Lassonde Pappas
Pace Project No.: 92569098
Sample: SW-2 Lab ID: 92569098005 Collected: 10/27/21 09:52 Received: 10/27/21 14:22 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
350.1 Ammonia EDN Analytical Method: EPA 350.1 Rev 2.0 1993
Pace Analytical Services-Eden
Nitrogen,Ammonia ND mg/L 0.10 1 10/29/21 10:46 7664-41-7
2540C Total Dissolved Solids Analytical Method:SM 2540C-2015
Pace Analytical Services-Asheville
Total Dissolved Solids 55.0 mg/L 25.0 1 11/02/21 10:33
MBIO 9222D Fecal Coliform AVL Analytical Method:SM 9222D-2015 Preparation Method:SM 9222D-2015
Pace Analytical Services-Asheville
Fecal Coliforms 145 CFU/100 mL 1.0 1 10/27/21 17:52 10/28/21 16:14
353.2 Nitrogen,NO2/NO3 unpres Analytical Method:EPA 353.2 Rev 2.0 1993
Pace Analytical Services-Asheville
Nitrogen, Nitrate 0.71 mg/L 0.040 1 10/28/21 01:19 14797-55-8
365.1 Phosphorus,Total Analytical Method:EPA 365.1 Rev 2.0 1993 Preparation Method: EPA 365.1 Rev 2.0 1993
Pace Analytical Services-Asheville
Phosphorus 0.063 mg/L 0.050 1 11/01/21 18:05 11/01/21 22:23 7723-14-0
4500 Chloride Analytical Method:SM 4500-CI-E-2011
Pace Analytical Services-Asheville
Chloride 5.2 mg/L 1.0 1 11/01/21 20:42 16887-00-6
5310B TOC Analytical Method:SM 5310B-2014
Pace Analytical Services-Asheville
Total Organic Carbon 1.9 mg/L 1.0 1 11/02/21 04:11 7440-44-0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date: 11/05/2021 03:28 PM without the written consent of Pace Analytical Services,LLC. Page 15 of 34

Pace Analytical Services,LLC
2225 Riverside Dr,
accAnalytical® Asheville,NC 28804
(///:11-7
www.pacalabs.com [phone]
ANALYTICAL RESULTS
Project: Lassonde Pappas
Pace Project No..: 92569098
Sample: Trip Blank 1 Lab ID: 92569098006 Collected: 10/27/21 00:00 Received: 10/27/21 14:22 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
6200E MSV Analytical Method:SM 6200B
Pace Analytical Services-Charlotte
Benzene ND ug/L 0.50 1 10/28/21 23:05 71-43-2
Bromobenzene ND ug/L 0.50 1 10/28/21 23:05 108-86-1
Bromochloromethane ND ug/L 0.50 1 10/28/21 23:05 74-97-5
Bromodichloromethane ND ug/L 0.50 1 10/28/21 23:05 75-27-4
Bromoform ND ug/L 0.50 1 10/28/21 23:05 75-25-2
Bromomethane ND ug/L 5.0 1 10/28/21 23:05 74-83-9
n-Butylbenzene ND ug/L 0.50 1 10/28/21 23:05 104-51-8
sec-Butylbenzene ND ug/L 0.50 1 10/28/21 23:05 135-98-8
tert-Butylbenzene ND ug/L 0.50 1 10/28/21 23:05 98-06-6
Carbon tetrachloride ND ug/L 0.50 1 10/28/21 23:05 56-23-5
Chlorobenzene ND ug/L 0.50 1 10/28/21 23:05 108-90-7
Chloroethane ND ug/L 1.0 1 10/28/21 23:05 75-00-3
Chloroform ND ug/L 0.50 1 10/28/21 23:05 67-66-3
Chloromethane ND ug/L 1.0 1 10/28/21 23:05 74-87-3
2-Chlorotoluene ND ug/L 0.50 1 10/28/21 23:05 95-49-8
4-Chlorotoluene ND ug/L 0.50 1 10/28/21 23:05 106-43-4
1,2-Dibromo-3-chloropropane ND ug/L 1.0 1 10/28/21 23:05 96-12-8
Dibromochloromethane ND ug/L 0.50 1 10/28/21 23:05 124-48-1
1,2-Dibromoethane(EDB) ND ug/L 0.50 1 10/28/21 23:05 106-93-4
Dibromomethane ND ug/L 0.50 1 10/28/21 23:05 74-95-3
1,2-Dichlorobenzene ND ug/L 0.50 1 10/28/21 23:05 95-50-1
1,3-Dichlorobenzene ND ug/L 0.50 1 10/28/21 23:05 541-73-1
1,4-Dichlorobenzene ND ug/L 0.50 1 10/28/21 23:05 106-46-7
Dichlorodifluoromethane ND ug/L 0.50 1 10/28/21 23:05 75-71-8
it 1,1-Dichloroethane ND ug/L 0.50 1 10/28/21 23:05 75-34-3
1,2-Dichloroethane ND ug/L 0.50 1 10/28/21 23:05 107-06-2
1,1-Dichloroethene ND ug/L 0.50 1 10/28/21 23:05 75-35-4
cis-1,2-Dichloroethene ND ug/L 0.50 1 10/28/21 23:05 156-59-2
trans-1,2-Dichloroethene ND ug/L 0.50 1 10/28/21 23:05 156-60-5
1,2-Dichloropropane ND ug/L 0.50 1 10/28/21 23:05 78-87-5
1,3-Dichloropropane ND ug/L 0.50 1 10/28/21 23:05 142-28-9
2,2-Dichloropropane ND ug/L 0.50 1 10/28/21 23:05 594-20-7
1,1-Dichloropropene ND ug/L 0.50 1 10/28/21 23:05 563-58-6
cis-1,3-Dichloropropene ND ug/L 0.50 1 10/28/21 23:05 10061-01-5
trans-1,3-Dichloropropene ND ug/L 0.50 1 10/28/21 23:05 10061-02-6
Diisopropyl ether ND ug/L 0.50 1 10/28/21 23:05 108-20-3
Ethylbenzene ND ug/L 0.50 1 10/28/21 23:05 100-41-4
Hexachloro-1,3-butadiene ND ug/L 2.0 1 10/28/21 23:05 87-68-3
Isopropylbenzene(Cumene) ND ug/L 0.50 1 10/28/21 23:05 98-82-8
Methylene Chloride ND ug/L 2.0 1 10/28/21 23:05 75-09-2
Methyl-tert-butyl ether ND ug/L 0.50 1 10/28/21 23:05 1634-04-4
Naphthalene ND ug/L 2.0 1 10/28/21 23:05 91-20-3
n-Propylbenzene ND ug/L 0.50 1 10/28/21 23:05 103-65-1
Styrene ND ug/L 0.50 1 10/28/21 23:05 100-42-5
1,1,1,2-Tetrachloroethane ND ug/L 0.50 1 10/28/21 23:05 630-20-6
1,1,2,2-Tetrachloroethane ND ug/L 0.50 1 10/28/21 23:05 79-34-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date: 11/05/2021 03:28 PM without the written consent of Pace Analytical Services,LLC Page 16 of 34

Pace Analytical Services,LLC
7 ,Pce Analytical® 2225 e,NCi28 04
Asheville, 28804
www.pacelabs.cam [phone]
ANALYTICAL RESULTS
Project: Lassonde Pappas
Pace Project No.: 92569098
Sample: Trip Blank 1 Lab ID: 92569098006 Collected: 10/27/21 00:00 Received: 10/27/21 14:22 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
6200B MSV Analytical Method:SM 6200B
Pace Analytical Services-Charlotte
Tetrachloroethene ND ug/L 0.50 1 10/28/21 23:05 127-18-4
Toluene ND ug/L 0.50 1 10/28/21 23:05 108-88-3
1,2,3-Trichlorobenzene ND ug/L 2.0 1 10/28/21 23:05 87-61-6
1,2,4-Trichlorobenzene ND ug/L 2.0 1 10/28/21 23:05 120-82-1
1,1,1-Trichloroethane ND ug/L 0.50 1 10/28/21 23:05 71-55-6
1,1,2-Trichloroethane ND ug/L 0.50 1 10/28/21 23:05 79-00-5
Trichloroethene ND ug/L 0.50 1 10/28/21 23:05 79-01-6
Trichlorofluoromethane ND ug/L 1.0 1 10/28/21 23:05 75-69-4
1,2,3-Trichloropropane ND ug/L 0.50 1 10/28/21 23:05 96-18-4
1,2,4-Trimethylbenzene ND ug/L 0.50 1 10/28/21 23:05 95-63-6
1,3,5-Trimethylbenzene ND ug/L 0.50 1 10/28/21 23:05 108-67-8
Vinyl chloride ND ug/L 1.0 1 10/28/21 23:05 75-01-4
m&p-Xylene ND ug/L 1.0 1 10/28/21 23:05 179601-23-1
o-Xylene ND ug/L 0.50 1 10/28/21 23:05 95-47-6
Surrogates
1,2-Dichloroethane-d4(S) 96 % 70-130 1 10/28/21 23:05 17060-07-0
4-Bromofluorobenzene(S) 100 % 70-130 1 10/28/21 23:05 460-00-4
Toluene-d8(S) 101 % 70-130 1 10/28/21 23:05 2037-26-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:11/05/2021 03:28 PM without the written consent of Pace Analytical Services,LLC. Page 17 of 34

Pace Analytical Services,LLC
A4/
n��_ tical 2225 Riverside Dr.
I J�/`�li Asheville,NC 28804
www.pecelebs.com [phone]
ilt/t
QUALITY CONTROL DATA
Project: Lassonde Pappas
Pace Project No.: 92569098
QC Batch: 656163 Analysis Method: EPA 350.1 Rev 2.0 1993
QC Batch Method: EPA 350.1 Rev 2.0 1993 Analysis Description: 350.1 Ammonia, EDN
Laboratory: Pace Analytical Services-Eden
Associated Lab Samples: 92569098001,92569098002,92569098003,92569098004,92569098005
METHOD BLANK: 3439820 Matrix: Water
Associated Lab Samples: 92569098001,92569098002,92569098003,92569098004,92569098005
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Nitrogen,Ammonia mg/L ND ...__ _ .. 0.10 10/29/21 10:13
LABORATORY CONTROL SAMPLE: 3439821
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
Nitrogen,Ammonia mg/L 5 4.8 96 90-110
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 3439822 3439823
MS MSD
92568980001 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
Nitrogen,Ammonia mg/L ND 5 5 5.3 5.3 106 107 90-110 0
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 3439824 3439825 �w
MS MSD
92568980002 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
Nitrogen,Ammonia mg/L ND 5 5 5.3 5.3 105 105 .... ... .._......
g g 90-110 0
Results presented on this page are In the units indicated by the"Units"column except where an alternate unit Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date: 11/05/2021 03:28 PM without the written consent of Pace Analytical Services,LLC, Page 18 of 34

Pace Analytical Services,LLC
ace Analytical® Riverside Dr.
Asheville,
lle,NC 28804
www.pacelabs.cam [phone]
QUALITY CONTROL DATA
Project: Lassonde Pappas
PPas
Pace Project No.: 92569098
QC Batch: 656048 Analysis Method: SM 6200B
QC Batch Method: SM 6200B Analysis Description: 6200B MSV
Laboratory: Pace Analytical Services-Charlotte
Associated Lab Samples: 92569098001,92569098002,92569098003, 92569098006
METHOD BLANK: 3439387 Matrix: Water
Associated Lab Samples: 92569098001,92569098002,92569098003,92569098006
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
1,1,1,2-Tetrachloroethane ug/L ND 0.50 10/28/21 22:47
1,1,1-Trichloroethane ug/L ND 0.50 10/28/21 22:47
1,1,2,2-Tetrachloroethane ug/L ND 0.50 10/28/21 22:47
1,1,2-Trichloroethane ug/L ND 0.50 10/28/21 22:47
1,1-Dichloroethane ug/L ND 0.50 10/28/21 22:47
1,1-Dichloroethene ug/L ND 0.50 10/28/21 22:47
1,1-Dichloropropene ug/L ND 0.50 10/28/21 22:47
1,2,3-Trichlorobenzene ug/L ND 2.0 10/28/21 22:47
1,2,3-Trichloropropane ug/L ND 0.50 10/28/21 22:47
1,2,4-Trichlorobenzene ug/L ND 2.0 10/28/21 22:47
1,2,4-Trimethylbenzene ug/L ND 0.50 10/28/21 22:47
1,2-Dibromo-3-chloropropane ug/L ND 1.0 10/28/21 22:47
1,2-Dibromoethane(EDB) ug/L ND 0.50 10/28/21 22:47
1,2-Dichlorobenzene ug/L ND 0.50 10/28/21 22:47
1,2-Dichloroethane ug/L ND 0.50 10/28/21 22:47
1,2-Dichloropropane ug/L ND 0.50 10/28/21 22:47
1,3,5-Trimethylbenzene ug/L ND 0.50 10/28/21 22:47
1,3-Dichlorobenzene ug/L ND 0.50 10/28/21 22:47
1,3-Dichloropropane ug/L ND 0.50 10/28/21 22:47
1,4-Dichlorobenzene ug/L ND 0.50 10/28/21 22:47
2,2-Dichloropropane ug/L ND 0.50 10/28/21 22:47
2-Chlorotoluene ug/L ND 0.50 10/28/21 22:47
4-Chlorotoluene ug/L ND 0.50 10/28/21 22:47
Benzene ug/L ND 0.50 10/28/21 22:47
Bromobenzene ug/L ND 0.50 10/28/21 22:47
Bromochloromethane ug/L ND 0.50 10/28/21 22:47
Bromodichloromethane ug/L ND 0.50 10/28/21 22:47
Bromoform ug/L ND 0.50 10/28/21 22:47
Bromomethane ug/L ND 5.0 10/28/21 22:47
Carbon tetrachloride ug/L ND 0.50 10/28/21 22:47
Chlorobenzene ug/L ND 0.50 10/28/21 22:47
Chloroethane ug/L ND 1.0 10/28/21 22:47
Chloroform ug/L ND 0.50 10/28/21 22:47
Chloromethane ug/L ND 1.0 10/28/21 22:47
cis-1,2-Dichloroethene ug/L ND 0.50 10/28/21 22:47
cis-1,3-Dichloropropene ug/L ND 0.50 10/28/21 22:47
Dibromochloromethane ug/L ND 0.50 10/28/21 22:47
Dibromomethane ug/L ND 0.50 10/28/21 22:47
Dichlorodifluoromethane ug/L ND 0.50 10/28/21 22:47
Diisopropyl ether ug/L ND 0.50 10/28/21 22:47
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date: 11/05/2021 03:28 PM without the written consent of Pace Analytical Services,LLC. Page 19 of 34

Pace Analytical Services,LLC
Analytical
ical 2225 Riverside Dr.
IJI/'�fl� Asheville,NC 28804
ii(Jace
www.pecelabs.com [phone]
QUALITY CONTROL DATA
Project: Lassonde Pappas
Pace Project No.: 92569098
METHOD BLANK: 3439387 Matrix: Water
Associated Lab Samples: 92569098001,92569098002,92569098003,92569098006
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Ethylbenzene ug/L ND 0.50 10/28/21 22:47
Hexachloro-1,3-butadiene ug/L ND 2.0 10/28/21 22:47
Isopropylbenzene(Cumene) ug/L ND 0.50 10/28/21 22:47
m&p-Xylene ug/L ND 1.0 10/28/21 22:47
Methyl-tert-butyl ether ug/L ND 0.50 10/28/21 22:47
Methylene Chloride ug/L ND 2.0 10/28/21 22:47
n-Butylbenzene ug/L ND 0.50 10/28/21 22:47
n-Propylbenzene ug/L ND 0.50 10/28/21 22:47
Naphthalene ug/L ND 2.0 10/28/21 22:47
o-Xylene ug/L ND 0.50 10/28/21 22:47
sec-Butylbenzene ug/L ND 0.50 10/28/21 22:47
Styrene ug/L ND 0.50 10/28/21 22:47
tert-Butylbenzene ug/L ND 0.50 10/28/21 22:47
Tetrachloroethene ug/L ND 0.50 10/28/21 22:47
Toluene ug/L ND 0.50 10/28/21 22:47
trans-1,2-Dichloroethene ug/L ND 0.50 10/28/21 22:47
trans-1,3-Dichloropropene ug/L ND 0.50 10/28/21 22:47
Trichloroethene ug/L ND 0.50 10/28/21 22:47
Trichlorofluoromethane ug/L ND 1.0 10/28/21 22:47
Vinyl chloride ug/L ND 1.0 10/28/21 22:47
1,2-Dichloroethane-d4(S) % 94 70-130 10/28/21 22:47
4-Bromofluorobenzene(S) % 100 70-130 10/28/21 22:47
Toluene-d8(S) % 103 70-130 10/28/21 22:47
LABORATORY CONTROL SAMPLE: 3439388
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
1,1,1,2-Tetrachloroethane ug/L 50 50.0 100 60-140
1,1,1-Trichloroethane ug/L 50 48.8 98 60-140
1,1,2,2-Tetrachloroethane ug/L 50 49.5 99 60-140
1,1,2-Trichloroethane ug/L 50 51.5 103 60-140
1,1-Dichloroethane ug/L 50 48.5 97 60-140
1,1-Dichloroethene ug/L 50 48.2 96 60-140
1,1-Dichloropropene ug/L 50 51.2 102 60-140
1,2,3-Trichlorobenzene ug/L 50 54.3 109 60-140
1,2,3-Trichloropropane ug/L 50 47.3 95 60-140
1,2,4-Trichlorobenzene ug/L 50 53.4 107 60-140
1,2,4-Trimethylbenzene ug/L 50 49.0 98 60-140
1,2-Dibromo-3-chloropropane ug/L 50 54.1 108 60-140
1,2-Dibromoethane(EDB) ug/L 50 51.9 104 60-140
1,2-Dichlorobenzene ug/L 50 48.8 98 60-140
1,2-Dichloroethane ug/L 50 46.6 93 60-140
1,2-Dichloropropane ug/L 50 51.1 102 60-140
1,3,5-Trimethylbenzene ug/L 50 50.4 101 60-140
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date: 11/05/2021 03:28 PM without the written consent of Pace Analytical Services,LLC. Page 20 of 34

Pace Analytical Services,LLC
ddn r 9 2225 Riverside Dr.
(71"
Asheville,NC 28804
7,Sce 111 al i al
www.pacelabs.com
[phone]
QUALITY CONTROL DATA
Project: Lassonde Pappas
Pace Project No.: 92569098
LABORATORY CONTROL SAMPLE: 3439388
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
1,3-Dichlorobenzene ...._W._ .... ._...._W... ug/L....._.. ...w ...ww 50
48.7 97 60-140
1,3-Dichloropropane ug/L 50 51.2 102 60-140
1,4-Dichlorobenzene ug/L 50 49.6 99 60-140
2,2-Dichloropropane ug/L 50 50.2 100 60-140
2-Chlorotoluene ug/L 50 50.1 100 60-140
4-Chlorotoluene ug/L 50 47.6 95 60-140
Benzene ug/L 50 49.5 99 60-140
Bromobenzene ug/L 50 49.5 99 60-140
Bromochloromethane ug/L 50 49.0 98 60-140
Bromodichloromethane ug/L 50 48.0 96 60-140
Bromoform ug/L 50 51.3 103 60-140
Bromomethane ug/L 50 43.5 87 60-140
Carbon tetrachloride ug/L 50 50.8 102 60-140
Chlorobenzene ug/L 50 48.0 96 60-140
Chloroethane ug/L 50 42.0 84 60-140
Chloroform ug/L 50 46.5 93 60-140
Chloromethane ug/L 50 46.2 92 60-140
cis-1,2-Dichloroethene ug/L 50 47.1 94 60-140
cis-1,3-Dichloropropene ug/L 50 52.4 105 60-140
Dibromochloromethane ug/L 50 53.0 106 60-140
Dibromomethane ug/L 50 47.6 95 60-140
Dichlorodifluoromethane ug/L 50 45.8 92 60-140
Diisopropyl ether ug/L 50 50.9 102 60-140
Ethylbenzene ug/L 50 49.4 99 60-140
Hexachloro-1,3-butadiene ug/L 50 53.9 108 60-140
Isopropylbenzene(Cumene) ug/L 50 50.9 102 60-140
m&p-Xylene ug/L 100 98.0 98 60-140
Methyl-tert-butyl ether ug/L 50 51.6 103 60-140
Methylene Chloride ug/L 50 46.5 93 60-140
n-Butylbenzene ug/L 50 51.0 102 60-140
n-Propylbenzene ug/L 50 50.4 101 60-140
Naphthalene ug/L 50 53.4 107 60-140
o-Xylene ug/L 50 48.4 97 60-140
sec-Butylbenzene ug/L 50 49.5 99 60-140
Styrene ug/L 50 51.0 102 60-140
tert-Butylbenzene ug/L 50 41.8 84 60-140
Tetrachloroethene ug/L 50 48.5 97 60-140
Toluene ug/L 50 46.9 94 60-140
trans-1,2-Dichloroethene ug/L 50 48.5 97 60-140
trans-1,3-Dichloropropene ug/L 50 50.6 101 60-140
Trichloroethene ug/L 50 50.1 100 60-140
Trichlorofluoromethane ug/L 50 40.3 81 60-140
Vinyl chloride ug/L 50 45.6 91 60-140
1,2-Dichloroethane-d4(S) % 92 70-130
4-Bromofluorobenzene(S) % 98 70-130
Toluene-d8(S) % 99 70-130
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:11/05/2021 03:28 PM without the written consent of Pace Analytical Services,LLC. Page 21 of 34

Pace Analytical Services,LLC
aceAa�p�wd�7g) I/+q ® 2225 Riverside Dr.
r 1aIytIva1 Asheville,NC 28804
lit
www.pacalabs.com [phone]
QUALITY CONTROL DATA
Project: Lassonde Pappas
Pace Project No.: 92569098
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 3439389 3439390
MS MSD
92569231004 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
1,1,1,2-Tetrachloroethane ug/L ND 80 80 89.3 87.2
.............� 112 109 60-140 2
1,1,1-Trichloroethane ug/L ND 80 80 80.9 84.4 101 106 60-140 4
1,1,2,2-Tetrachloroethane ug/L ND 80 80 85.0 84.7 106 106 60-140 0
1,1,2-Trichloroethane ug/L ND 80 80 88.3 88.1 110 110 60-140 0
1,1-Dichloroethane ug/L ND 80 80 76.4 78.1 96 98 60-140 2
1,1-Dichloroethene ug/L ND 80 80 76.0 75.3 95 94 60-140 1
1,1-Dichloropropene ug/L ND 80 80 81.9 86.2 102 108 60-140 5
1,2,3-Trichlorobenzene ug/L ND 80 80 85.3 87.9 107 110 60-140 3
1,2,3-Trichloropropane ug/L ND 80 80 84.0 85.6 105 107 60-140 2
1,2,4-Trichlorobenzene ug/L ND 80 80 86.3 91.5 108 114 60-140 6
1,2,4-Trimethylbenzene ug/L 570 80 80 676 679 133 137 60-140 0
1,2-Dibromo-3-chloropropane ug/L ND 80 80 88.0 95.4 110 119 60-140 8
1,2-Dibromoethane(EDB) ug/L ND 80 80 85.1 89.7 106 112 60-140 5
1,2-Dichlorobenzene ug/L ND 80 80 88.2 88.4 110 111 60-140 0
1,2-Dichloroethane ug/L ND 80 80 76.3 78.4 95 98 60-140 3
1,2-Dichloropropane ug/L ND 80 80 87.5 87.2 109 109 60-140 0
1,3,5-Trimethylbenzene ug/L 191 80 80 291 293 124 126 60-140 1
1,3-Dichlorobenzene ug/L ND 80 80 89.2 90.1 111 113 60-140 1
1,3-Dichloropropane ug/L ND 80 80 87.8 89.4 110 112 60-140 2
1,4-Dichlorobenzene ug/L ND 80 80 86.3 92.5 108 116 60-140 7
2,2-Dichloropropane ug/L ND 80 80 71.9 71.5 90 89 60-140 1
2-Chlorotoluene ug/L ND 80 80 98.2 102 123 127 60-140 4
4-Chlorotoluene ug/L ND 80 80 87.8 90.6 110 113 60-140 3
Benzene ug/L ND 80 80 155 152 193 190 60-140 2 M1
Bromobenzene ug/L ND 80 80 92.9 93.4 116 117 60-140 1
Bromochloromethane ug/L ND 80 80 77.1 77.5 96 97 60-140 1
Bromodichloromethane ug/L ND 80 80 80.9 81.8 101 102 60-140 1
Bromoform ug/L ND 80 80 79.8 81.6 100 102 60-140 2
Bromomethane ug/L ND 80 80 43.2 55.9 54 70 60-140 26 M1
Carbon tetrachloride ug/L ND 80 80 85.8 86.5 107 108 60-140 1
Chlorobenzene ug/L ND 80 80 86.4 85.7 108 107 60-140 1
Chloroethane ug/L ND 80 80 65.5 67.6 82 84 60-140 3
Chloroform ug/L ND 80 80 79.3 80.2 99 100 60-140 1
Chloromethane ug/L ND 80 80 55.6 57.0 69 71 60-140 2
cis-1,2-Dichloroethene ug/L ND 80 80 77.5 78.1 97 98 60-140 1
cis-1,3-Dichloropropene ug/L ND 80 80 80.9 84.7 101 106 60-140 5
Dibromochloromethane ug/L ND 80 80 86.2 87.2 108 109 60-140 1
Dibromomethane ug/L ND 80 80 79.5 80.0 99 100 60-140 1
Dichlorodifluoromethane ug/L ND 80 80 56.3 56.4 70 70 60-140 0
Diisopropyl ether ug/L 70.2 80 80 155 156 106 107 60-140 0
Ethylbenzene ug/L 164 80 80 252 249 110 107 60-140 1
Hexachloro-1,3-butadiene ug/L ND 80 80 92.0 98.9 115 124 60-140 7
Isopropylbenzene(Cumene) ug/L 10.4 80 80 102 101 114 114 60-140 1
m&p-Xylene ug/L 861 160 160 1010 1000 92 89 60-140 0
Methyl-tert-butyl ether ug/L 38.3 80 80 121 123 104 106 60-140 2
Methylene Chloride ug/L ND 80 80 74.7 77.0 93 96 60-140 3
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:11/05/2021 03:28 PM without the written consent of Pace Analytical Services,LLC. Page 22 of 34

aceAl1alICalPace Analytical Services,LLC
2225 Riverside Dr.
Asheville,NC 28804
www.paalabs.cam [phone]
QUALITY CONTROL DATA
Project: Lassonde Pappas
Pace Project No.: 92569098
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 3439389 3439390
MS MSD
92569231004 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
n-Butylbenzene ug/L ND 80 80 114 105 142 131 60-140 8 M1
n-Propylbenzene ug/L 26.4 80 80 121 123 119 121 60-140 1
Naphthalene ug/L 102 80 80 201 211 124 136 60-140 5
o-Xylene ug/L 492 80 80 575 560 103 85 60-140 3
sec-Butylbenzene ug/L ND 80 80 88.4 95.1 111 119 60-140 7
Styrene ug/L 10.6 80 80 99.9 99.6 112 111 60-140 0
tert-Butylbenzene ug/L ND 80 80 75.3 80.3 94 100 60-140 6
Tetrachloroethene ug/L ND 80 80 87.5 85.4 109 107 60-140 2
Toluene ug/L 488 80 80 567 564 99 95 60-140 1
trans-1,2-Dichloroethene ug/L ND 80 80 77.4 76.7 97 96 60-140 1
trans-1,3-Dichloropropene ug/L ND 80 80 81.2 81.4 101 102 60-140 0
Trichloroethene ug/L ND 80 80 84.9 86.1 106 108 60-140 1
Trichlorofluoromethane ug/L ND 80 80 64.6 63.5 81 79 60-140 2
Vinyl chloride ug/L ND 80 80 62.2 63.7 78 80 60-140 2
1,2-Dichloroethane-d4(S) % 94 96 70-130
4-Bromofluorobenzene(S) % 98 95 70-130
Toluene-d8(S) % 98 96 70-130
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date: 11/05/2021 03:28 PM without the written consent of Pace Analytical Services,LLC. Page 23 of 34

Pace Analytical Services,LLC
"lace
r1 l® 2225 Riverside Dr.
�I'�� �C�I Asheville,NC 28804
www.pacelabs.cam [phone]
QUALITY CONTROL DATA
Project: Lassonde Pappas
Pace Project No.: 92569098
QC Batch: 656823 Analysis Method: SM 2540C-2015
QC Batch Method: SM 2540C-2015 Analysis Description: 2540C Total Dissolved Solids
Laboratory: Pace Analytical Services-Asheville
Associated Lab Samples: 92569098001,92569098002,92569098003,92569098004,92569098005
METHOD BLANK: 3442964 Matrix: Water
Associated Lab Samples: 92569098001,92569098002,92569098003,92569098004,92569098005
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Total Dissolved Solids mg/L ND 25.0 11/02/21 10:31
LABORATORY CONTROL SAMPLE: 3442965
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
Total Dissolved Solids ,.......... mg/L 250 246 9 IT ...
g B 90 90-110
SAMPLE DUPLICATE: 3442966
92569158010 Dup
Parameter Units Result Result RPD Qualifiers
Total Dissolved Solids mg/L 606
g 618 2
SAMPLE DUPLICATE: 3442967
92569158020 Dup
Parameter Units Result Result RPD Qualifiers
Total Dissolved Solids mg/L 83.0 86.0 4
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date: 11/05/2021 03:28 PM without the written consent of Pace Analytical Services,LLC Page 24 of 34

Pace Analytical Services,LLC
(91,,,,P4eAnalytical6 2225 Riverside Dr.
Asheville,NC 28804
www.pacelabs.cam
[phone]
QUALITY CONTROL DATA
Project: Lassonde Pappas
Pace Project No.: 92569098
QC Batch: 656989 Analysis Method: SM 9222D-2015
QC Batch Method: SM 9222D-2015 Analysis Description: 9222D Fecal Coliform(MF)-AVL
Laboratory: Pace Analytical Services-Asheville
Associated Lab Samples: 92569098001,92569098002,92569098003,92569098004,92569098005
METHOD BLANK: 3443944 Matrix: Water
Associated Lab Samples: 92569098001,92569098002,92569098003,92569098004,92569098005
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Fecal Coliforms CFU/100 mL ND 1.0 10/28/21 16:14
SAMPLE DUPLICATE: 3443945
92569017004 Dup
Parameter Units Result Result RPD Qualifiers
Fecal Coliforms CFU/100 mL 60.0 48.0 22
Results presented on this page are In the units Indicated by the"Units"column except where an alternate unit Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:11/05/2021 03:28 PM without the written consent of Pace Analytical Services,LLC Page 25 of 34

Pace Analytical Services,LLC
iJ��yAng q/®7/: 2225 Riverside Dr
4rl r111ClIICLl1 Asheville,NC 28804
f www.pacelabs.corn [phone]
I
QUALITY CONTROL DATA
Project: Lassonde Pappas
Pace Project No.: 92569098
QC Batch: 655776 Analysis Method: EPA 353.2 Rev 2.0 1993
QC Batch Method: EPA 353.2 Rev 2.0 1993 Analysis Description: 353.2 Nitrate+Nitrite,Unpres.
Laboratory: Pace Analytical Services-Asheville
Associated Lab Samples: 92569098001,92569098002,92569098003,92569098004,92569098005
METHOD BLANK: 3438034 Matrix: Water
Associated Lab Samples: 92569098001,92569098002,92569098003,92569098004,92569098005
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Nitrogen,Nitrate mg/L ND 0.040 10/28/21 01:14
LABORATORY CONTROL SAMPLE: 3438035
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
Nitrogen,Nitrate mg/L 1.5 ............ .._. . _.
1.5
101 90-110
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 3438036 3438037
MS MSD
92569098005 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
Nitrogen,Nitrate mg/L 0.71 _� _ .._...._-.._.__... W........
g g 1.5 1.5 2.2 2.3 101 103 90-110 2
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 3438038 3438039
MS MSD
92569098002 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
Nitrogen,Nitrate mg/L 0.86 1.5 1.5 2.4 2.4 101 101 90-110 0
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date: 11/05/2021 03:28 PM without the written consent of Pace Analytical Services,LLC. Page 26 of 34

Pace Analytical Services,LLC
�*
,s 2225 Riverside Dr.
ac I`d naIyticaI Asheville,NC 28804
17/:111 www.pacelabs.cam [phone]
QUALITY CONTROL DATA
Project: Lassonde Pappas
Pace Project No.: 92569098
QC Batch: 656677 Analysis Method: EPA 365.1 Rev 2.0 1993
QC Batch Method: EPA 365.1 Rev 2.0 1993 Analysis Description: 365.1 Phosphorus,Total
Laboratory: Pace Analytical Services-Asheville
Associated Lab Samples: 92569098001,92569098002,92569098003,92569098004,92569098005
METHOD BLANK: 3442338 Matrix: Water
Associated Lab Samples: 92569098001,92569098002,92569098003,92569098004,92569098005
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Phosphorus -.-...__ .._._mg/L ND .... ____.__...._ .__..
0.050 11/01/21 22:14
LABORATORY CONTROL SAMPLE: 3442339
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
Phosphorus mg/L 2.5 2.5 102 90-110
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 3442340 3442341
MS MSD
92569098001 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
Phosphorus mg/L
ND 2.5 _..__. ...2.5 2.6 2.6,.......... 102 103 90-110 _.... .._0
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 3442343 3442344
MS MSD
92569098002 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
Phosphorus mg/L ND 2.5 2.5 2.6 2.6 104 103 9 0-110 1
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date: 11/05/2021 03:28 PM without the written consent of Pace Analytical Services,LLC. Page 27 of 34

Pace Analytical Services,LLC
( raceAnal, tical6 2225 Riverside Dr.
Anal l� Asheville,NC 28804
www.pacelabs.com [phone]
ff�
QUALITY CONTROL DATA
Project: Lassonde Pappas
Pace Project No.: 92569098
QC Batch: 656672 Analysis Method: SM 4500-CI-E-2011
QC Batch Method: SM 4500-CI-E-2011 Analysis Description: 4500 Chloride
Laboratory: Pace Analytical Services-Asheville
Associated Lab Samples: 92569098001,92569098002,92569098003,92569098004,92569098005
METHOD BLANK: 3442321 Matrix: Water
Associated Lab Samples: 92569098001,92569098002,92569098003,92569098004,92569098005
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Chloride mg/L ND 1.0 11/01/21 20:29
LABORATORY CONTROL SAMPLE: 3442322
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
Chloride mg/L 20 20.2 101 90-110
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 3442323 3442324
MS MSD
92568559006 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
Chloride mg/L 72.1 10 10 86.0 84.1 139 120 90-110 2 M1
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 3442325 3442326
MS MSD
92568822002 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
Chloride mg/L 59.2 10 10 67.4 69.9 82 106 .... 0-1 90.1 0
10 4 M1
Results presented on this page are In the units indicated by the"Units"column except where an alternate unit Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:11/05/2021 03:28 PM without the written consent of Pace Analytical Services,LLC. Page 28 of 34

Pace Analytical Services,LLC
,n dn eA(//jig11nn I ® 2225 Riverside Dr.
aIyticaI
Asheville,NC 28804
www.pacelabs,com [phone]
QUALITY CONTROL DATA
Project: Lassonde Pappas
Pace Project No.: 92569098
QC Batch: 656656 Analysis Method: SM 5310B-2014
QC Batch Method: SM 5310B-2014 Analysis Description: 5310B TOC
Laboratory: Pace Analytical Services-Asheville
Associated Lab Samples: 92569098001,92569098002,92569098003,92569098004,92569098005
METHOD BLANK: 3442284 Matrix: Water
Associated Lab Samples: 92569098001,92569098002,92569098003,92569098004, 92569098005
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Total Organic Carbon mg/L ND 1.0 11/01/21 21:59
LABORATORY CONTROL SAMPLE: 3442285
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
Total Organic Carbon mg/L 25 26.3 ... ...... 105
90-110
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 3442286 3442287
MS MSD
92568412004 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
Total Organic Carbon mg/L 25 �........... ....... ..._
g g 25 3800 3820 240 328 90-110 1 M1
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 3442288 3442289
MS MSD
92568412005 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
Total Organic Carbon
mg/L 25 25 1310 1320 -267 -250 90-110 0 M1
Results presented on this page are In the units indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:11/05/2021 03:28 PM without the written consent of Pace Analytical Services,LLC. Page 29 of 34

Pace Analytical Services,LLC
accAnalytical 2225 Riverside Dr
Asheville,NC 28804
(//2
www.pacslabs.com [phone]
QUALIFIERS
Project: Lassonde Pappas
Pace Project No.: 92569098
DEFINITIONS
DF-Dilution Factor,if reported,represents the factor applied to the reported data due to dilution of the sample aliquot.
ND-Not Detected at or above adjusted reporting limit.
TNTC-Too Numerous To Count
J-Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL-Adjusted Method Detection Limit.
PQL-Practical Quantitation Limit.
RL-Reporting Limit-The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S-Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270.The result for each analyte is
a combined concentration.
Consistent with EPA guidelines,unrounded data are displayed and have been used to calculate%recovery and RPD values.
LCS(D)-Laboratory Control Sample(Duplicate)
MS(D)-Matrix Spike(Duplicate)
DUP-Sample Duplicate
RPD-Relative Percent Difference
NC-Not Calculable.
SG-Silica Gel-Clean-Up
U-Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Reported results are not rounded until the final step prior to reporting.Therefore,calculated parameters that are typically reported as
"Total"may vary slightly from the sum of the reported component parameters.
Pace Analytical is TNI accredited.Contact your Pace PM for the current list of accredited analytes.
TNI-The NELAC Institute.
ANALYTE QUALIFIERS
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample(LCS)recovery.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date: 11/05/2021 03:28 PM without the written consent of Pace Analytical Services,LLC. Page 30 of 34

Pace Analytical Services,LLC
a 2225 Riverside Dr.
Gtt A11Qlytil�Ql Asheville,NC 28804
www.pacslabs.com
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: Lassonde Pappas
Pace Project No.: 92569098
Analytical
Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch
92569098001 MW-7R EPA 350.1 Rev 2.0 1993 656163
92569098002 MW-8 EPA 350.1 Rev 2.0 1993 656163
92569098003 MW-9 EPA 350.1 Rev 2.0 1993 656163
92569098004 SW-1 EPA 350.1 Rev 2.0 1993 656163
92569098005 SW-2 EPA 350.1 Rev 2.0 1993 656163
92569098001 MW-7R SM 6200B 656048
92569098002 MW-8 SM 6200B 656048
92569098003 MW-9 SM 6200B 656048
92569098006 Trip Blank 1 SM 6200B 656048
92569098001 MW-7R SM 2540C-2015 656823
92569098002 MW-8 SM 2540C-2015 656823
92569098003 MW-9 SM 2540C-2015 656823
92569098004 SW-1 SM 2540C-2015 656823
92569098005 SW-2 SM 2540C-2015 656823
92569098001 MW-7R SM 92220-2015 656989 SM 9222D-2015 657146
92569098002 MW-8 SM 9222D-2015 656989 SM 9222D-2015 657146
92569098003 MW-9 SM 9222D-2015 656989 SM 9222D-2015 657146
92569098004 SW-1 SM 9222D-2015 656989 SM 9222D-2015 657146
92569098005 5W-2 SM 92220-2015 656989 SM 9222D-2015 657146
92569098001 MW-7R EPA 353.2 Rev 2.0 1993 655776
92569098002 MW-8 EPA 353.2 Rev 2.0 1993 655776
92569098003 MW-9 EPA 353.2 Rev 2.0 1993 655776
92569098004 SW-1 EPA 353.2 Rev 2.0 1993 655776
92569098005 SW-2 EPA 353.2 Rev 2.0 1993 655776
92569098001 MW-7R EPA 365.1 Rev 2.0 1993 656677 EPA 365.1 Rev 2.0 1993 656736
92569098002 MW-8 EPA 365.1 Rev 2.0 1993 656677 EPA 365.1 Rev 2.0 1993 656736
92569098003 MW-9 EPA 365.1 Rev 2.0 1993 656677 EPA 365.1 Rev 2.0 1993 656736
92569098004 SW-1 EPA 365.1 Rev 2.0 1993 656677 EPA 365.1 Rev 2.0 1993 656736
92569098005 SW-2 EPA 365.1 Rev 2.0 1993 656677 EPA 365.1 Rev 2.0 1993 656736
92569098001 MW-7R SM 4500-CI-E-2011 656672
92569098002 MW-8 SM 4500-CI-E-2011 656672
92569098003 MW-9 SM 4500-CI-E-2011 656672
92569098004 SW-1 SM 4500-CI-E-2011 656672
92569098005 5W-2 SM 4500-CI-E-2011 656672
92569098001 MW-7R SM 5310B-2014 656656
92569098002 MW-8 SM 5310B-2014 656656
92569098003 MW-9 SM 5310B-2014 656656
92569098004 SW-1 SM 5310E-2014 656656
92569098005 SW-2 SM 5310B-2014 656656
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date: 11/05/2021 03:28 PM without the written consent of Pace Analytical Services,LLC. Page 31 of 34

DocumentName: Document Revised:October 28,2020
/1nalycai Sample Condition Upon Recelpt(SCUR) Page I of 2
co,itfn
......" Document No.: Issuing Authority:
i,
/ F-CAR-CS-033.Rev.07 Pace Carolinas Quality Office
— ,
Laboratory r_TpeIving samples:
Asheville 2111 EdenE] Greenwood 0 Huntersville 0 RaleIghE AlechanicsvilleD Atlantalli KernersvIlle0
1 Sample Condition 1 Client Name: WO# : 92569098
Upon Receipt Project ll: 1
Courier; OFed EX ClUPS EUPS OCIlent 11 I II I 1111111 ll III 111
0 Commercial ,OPace :Other: ..... 92559098
Custody Seal Present? OYes .,13No Seals Intact? t]Yes END
Date/Initials Person Examining Contents: C21fD \1021
Packing Material: 2Frabble Wrap ElBubble Bags CINone p Other Biological Tissue Frozen?
Therm orneter: Oyes EjNo EN/A
1318 Gun ID: CI ,5-,;(3-1 1, Type of Ice: Owe; EBlue EINone
Correction Factor: C
Cooler Temp: Add/Subtract(T) Temp should be above freezing to 6'C
OSarnpir.vs out of temp triteria.Saniples on ice,cooling process
Cooler Temp Corrected(*C):
ILI i-1
Li:1 has begun
USDA Regulated Soil(,ErN/A,water sample)
Did samples originate in a quarantine zone Within the United States CA NY,or SC4heck maps)? Did samples originate Irani a foreign source lintansatuseally,
"'Yes le la_ IncluacigHawall and Puerto Ricol?Des ONo
----
COMments/Olscregancyl
I Chain of Custody Present? Oles 0 CI 0 DNA 1.
Sam.les Arrived within lloid Time? ini-IeLmattals OutA 2. --
Short Hold'Male Analysis lrc72 110? "-Eves Don rsia 3
Rush Turn Around lime Requested? 0 Ms _Erri; Do_ 4.
Sufficient Volume? [Xes alga El WA 5.
-- -
Correct Containers Used? -Erros Oho ON/A 6.
-Pace Containers Used? 2Yes I=]No ON/A,
Containers Intact? LeTles Dun El N ia
,,__
Uffsol E Sam
ved anal sIples Field Filtered? 0 Yes ONO ---C.N/A 8. -
11 Sample Labels Match COC7 -42Yes ONo ON/A 9.
-Includes Dateitime/tD/Anallyils Martian
Heads ace in VOA Vials InS.6mm)? D Vet 0 No alv, to
1 Trip Blank Present? Dyes ONo .211/A IL
In 6 Blank Custody Seals Present? cif cs El PI o lallt OA ,,.
_
COMMENTS/SAMPLE DISCREPANCY Field Data Required? ares DR)
— -. -
—__ —
Lot ID of split containers —
CLIENT NOTIFICATION/RESOLUTION
-- —
Person contacted:_ Date/lime:
Project Manager SCURF Review: Date;
Project Manager SRF Review: Date: —_
:------"
Page 32 of 34

�__.... Doc'unler�t Name:
aceAnalytical" Sample Conditiont io Document RePage 2 Of 2
vised:October 28,2020ecefpt COR1' IssuingAuthority:
I P-CARMCS-OU3-Rev.07 Pace Carolinas flu Office
mark top half of box If pH and/or dechiorination is Protect# WO# Quality
92569098
verified and within the acceptance range for preservation PM: LJP Due Date: 11/03/21
samples. CLIENT: 93—ALTAMONT
Exceptions:VOA,Coliform,TOC,OH and Grease,O8O/8015(water)DOC,LLHg
**Bottom half of box Is to list number of bottles
0 > i 7: a iil 1 :-_-° " ' _ z z
',. 2 Z z Qr 1 m. 2 Z �� . A tli V.
m >
Z tV c . N Q 6 La I ' 6 a i
N ; al N 1 io A , Ti y V V 2 s I Q Q > ? L
2 2 i u = W °' ry v = ' n a 7 m I z o ri �
yayk v : - y a '� v ([ a • 1 1 .gl v VI
,_ W E g 04l N T L C N 1� Q nt Q ? M y V = r N a 1 u
g c c n r I. Z 1 u t7 �.. K. `- 7 1 p O n a G ?71 O w a Z 04 ? c a
O o. '� E71 y o c _
7 ., N 2 y S S Z J U a m + r ty U L .Y
u w-, u• u .,, u , L a Q' E i z . S -x �c v _ l r. 11
.� m y tt tt 0 - II E 2 E '.. a c Q Q Q `y c`J 5 § m E tE ,e
0- Y. a Ca ti E 1 E a L c E J '4 I D o a l O a N < ✓t c7
E E E c E E E n ar `a E v E ro E E E E ,m a E E E E E E
a gi n
1 n ry
E v m N A w u w 7 2 g VI Q Y ; , 1L W x }. r S G t
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2
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1 i _...,,. 011 1 ,J 1 li . 1. ,_ 1_,1
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9 1
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pH Adjustment Log for Preserved Samples
g
Sample ID Type of Preservative pH upon receipt Date preservation adjusted Time preservation Amount of Preservative Lot It
adjusted added
1
Note: Whenever there is a discrepancy ariacthnd North Caraiilta compliance samples,a copy of this form will be sent to the North Carolina OEHNR Certification Office li.e
Out of hold,incorrect preservative,out of temp,incorrect containers.
Page 33 of 34

CHAIN-OF-CUSTODY 1 Analytical Request Document
r£ The Chain-of-Custody is a LEGAL DOCUMENT.All relevant fields must be completed accurately.
p .r..ncIXIS COM
i Submitting a sample via this chain of custody constitutes acknowledgment and acceptance of the Pace Terms and Conditions found at haps://info_paceiabs.cornibubfsipaa-stanclard-terms.prif.
;action A Section B Section C
tequired Client Informatiem Requirer:t Project Information: Invoice Information: 1 Pa 1 Of 1
:cups: ANCHOR(}EA OF NC,PLf.0 Report To: Sty Ct n :Attention: I
\ddress: 2S1 Hated Street CI41 To e." t - ra Company flame: „,-
r - (O „ Addr4ft As
aal- n Agency z- v
_seviiie,NC 28B01 � - > -L .�.-._= � ��, ,,_
vi
sal � .�a ,.i,,,,—>ft_
Pub Order*: i., Pace Quote:
Far Pr Marna: :a__ondePace ProManager .'t s, States Location k `. `~...;7
'hone: l �}�Ca'T7 �l�t »u Pappaslei lorri.patlon�pacelabs_com. .�.A,a=,.;��oC�
leolkested Due Date. Pr i#: I-F -L" 1, j1; Pace Profile#: 8114 l
R . .., ..Aria •"Rltand
MATRIX cone 9_ ° COLLECTED Preservatives }_���� �` = ` �,�,.,�_
o Z
Drinking Water ow ; - -- o - -
Water WT i; U ,�o< o
:1Waste Water NM 3 "" a Z
Product P s Eg
SAMPLE ID i; o r
Soil/Solid SL U m a-
Du OL START END I ;}-: a
b �
One Character per box. Wpa WP w w a z m o2
(A-Z,0-9 J,-) Omar oT o8 tu i y: a ci g 2
Sample Ids must be unique TImua Ts ,� o in m . ON c rA' v .c a. 3
2 cc a a. O a 0 ' _ = CD a a. o m a121 7
_ © `o E m
r q Q O C N Z U m m L Q. L EE = U U d ~t t 3
a DATE TIME DATE rn x 7 _ _ = Z Z O U d 2 ' 7 t` o: 1. .=_Y - > 7
IIIIMMIli ... — ®111111111 LIE--:--
,...
MW-7R WT i 1 - fA X
6' :: MWe
WT m�� X ��
WTI IME �� 11�111��
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WT1.11M x Wi, /Vo _
8' SW-2 WTI �y _ I >l X 'x x x x x x 4,zf \�O('an.�,�ti,;
9 TrioBlankl WT of / 0
L iJy
11
ADomoNAL COMfi'sihTs' ,.,, ::°: RELINQUISHED BY I AFF1UAT)ON DATE TIME.'. ACCEPTED BY I AFFILIATION,:: OATEN TIME SAMPLE COND ONS
rilLWRIINEMI
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I i AnaIytca�m Pace Analytical Services,LLC
2225 Riverside Dr.
I li Asheville,NC 28804
www.pecelahs.eem [phone]
tit
November 04, 2021
Jennifer Verde
Anchor QEA
231 Haywood Street
Asheville, NC 28801
RE: Project: Lassonde Pappas C11482-01.01
Pace Project No.: 92569443
Dear Jennifer Verde:
Enclosed are the analytical results for sample(s) received by the laboratory on October 28,2021. The results relate only to
the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual,where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace Analytical Services-Asheville
• Pace Analytical Services-Charlotte
If you have any questions concerning this report, please feel free to contact me..
Sincerely,
�w-t.. ...___
Lorri Patton
[e-mail]
1(828)254-7176
Project Manager
Enclosures
l
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
iJ .
, „ ,,
without the written consent of Pace Analytical Services,LLC Page 1 of 31

H(9/aCe
Pace Analytical Services,LLC
AY
��l,1'��'� 2225 Riverside Dr.
� Asheville,NC 28804
www.pacelabs.com [phone]
CERTIFICATIONS
Project: Lassonde Pappas C11482-01.01
Pace Project No.: 92569443
Pace Analytical Services Charlotte
9800 Kincey Ave.Ste 100,Huntersville,NC 28078 South Carolina Certification#:99006001
Louisiana/NELAP Certification#LA170028 Florida/NELAP Certification#:E87627
North Carolina Drinking Water Certification#:37706 Kentucky UST Certification#:84
North Carolina Field Services Certification#:5342 Virginia/VELAP Certification#:460221
North Carolina Wastewater Certification#: 12
Pace Analytical Services Asheville
2225 Riverside Drive,Asheville, NC 28804 North Carolina Wastewater Certification#:40
Florida/NELAP Certification#:E87648 South Carolina Certification#:99030001
North Carolina Drinking Water Certification#:37712 VirginiaNELAP Certification#:460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
without the written consent of Pace Analytical Services,LLC Page 2 of 31

Al]a�
(411
L Pace Analytical Services,LLC
+LL�d r ® 2225 Riverside Dr.
L 1Ca� Asheville,NC 28804
www.pacelaba.cam [phone]
SAMPLE ANALYTE COUNT
Project: Lassonde Pappas C11482-01.01
Pace Project No.: 92569443
Analytes
Lab ID Sample ID Method Analysts Reported Laboratory
92569443001 MW-4 SM 6200B SAS 63 PASI-C
SM 2540C-2015 MJP 1 PASI-A
SM 9222D-2015 SMK 1 PASI-A
EPA 350.1 Rev 2.0 1993 NGP 1 PASI-A
EPA 353.2 Rev 2.0 1993 MFO 1 PASI-A
EPA 365.1 Rev 2.0 1993 MDW 1 PASI-A
SM 4500-CI-E-2011 MDW 1 PASI-A
SM 5310B-2014 MDW 1 PASI-A
92569443002 MW-5 SM 6200B SAS 63 PASI-C
SM 2540C-2015 MJP 1 PASI-A
SM 9222D-2015 SMK 1 PASI-A
EPA 350.1 Rev 2.0 1993 NGP 1 PASI-A
EPA 353.2 Rev 2.0 1993 MFO 1 PASI-A
EPA 365.1 Rev 2.0 1993 MDW 1 PASI-A
SM 4500-CI-E-2011 MDW 1 PASI-A
SM 5310B-2014 MDW 1 PASI-A
92569443003 MW-6 SM 6200B SAS 63 PASI-C
SM 2540C-2015 MJP 1 PASI-A
SM 9222D-2015 SMK 1 PASI-A
EPA 350.1 Rev 2.0 1993 NGP 1 PASI-A
EPA 353.2 Rev 2.0 1993 MFO 1 PASI-A
EPA 365.1 Rev 2.0 1993 MDW 1 PASI-A
SM 4500-CI-E-2011 MDW 1 PASI-A
SM 5310B-2014 MDW 1 PASI-A
92569443004 TRIP BLANK SM 6200B SAS 63 PASI-C
PASI-A=Pace Analytical
Services-Asheville
PASI-C=Pace Analytical Services-Charlotte
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
without the written consent of Pace Analytical Services,LLC. Page 3 of 31

Pace Analytical Services,LLC
rp n 9 ® 2225 Riverside Dr.
eAnalyticaI Asheville,NC 28804
(7,1_7,,P
www.pacelabs.com [phone]
ANALYTICAL RESULTS
Project: Lassonde Pappas C11482-01.01
Pace Project No.: 92569443
Sample: MW-4 Lab ID: 92569443001 Collected: 10/28/21 11:36 Received: 10/28/21 14:58 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
6200E MSV Analytical Method:SM 6200B
Pace Analytical Services-Charlotte
Benzene ND ug/L 0.50 1 10/29/21 16:10 71-43-2
Bromobenzene ND ug/L 0.50 1 10/29/21 16:10 108-86-1
Bromochloromethane ND ug/L 0.50 1 10/29/21 16:10 74-97-5
Bromodichloromethane ND ug/L 0.50 1 10/29/21 16:10 75-27-4
Bromoform ND ug/L 0.50 '1 10/29/21 16:10 75-25-2
Bromomethane ND ug/L 5.0 1 10/29/21 16:10 74-83-9
n-Butylbenzene ND ug/L 0.50 1 10/29/21 16:10 104-51-8
sec-Butylbenzene ND ug/L 0.50 1 10/29/21 16:10 135-98-8
tert-Butylbenzene ND ug/L 0.50 1 10/29/21 16:10 98-06-6
Carbon tetrachloride ND ug/L 0.50 1 10/29/21 16:10 56-23-5
Chlorobenzene ND ug/L 0.50 1 10/29/21 16:10 108-90-7
Chloroethane ND ug/L 1.0 1 10/29/21 16:10 75-00-3
Chloroform ND ug/L 0.50 1 10/29/21 16:10 67-66-3
Chloromethane ND ug/L 1.0 1 10/29/21 16:10 74-87-3
2-Chlorotoluene ND ug/L 0.50 1 10/29/21 16:10 95-49-8
4-Chlorotoluene ND ug/L 0.50 1 10/29/21 16:10 106-43-4
1,2-Dibromo-3-chloropropane ND ug/L 1.0 1 10/29/21 16:10 96-12-8
Dibromochloromethane ND ug/L 0.50 1 10/29/21 16:10 124-48-1
1,2-Dibromoethane(EDB) ND ug/L 0.50 11 10/29/21 16:10 106-93-4
Dibromomethane ND ug/L 0.50 1 10/29/21 16:10 74-95-3
1,2-Dichlorobenzene ND ug/L 0.50 1 10/29/21 16:10 95-50-1
1,3-Dichlorobenzene ND ug/L 0.50 1 10/29/21 16:10 541-73-1
1,4-Dichlorobenzene ND ug/L 0.50 1 10/29/21 16:10 106-46-7
Dichlorodifluoromethane ND ug/L 0.50 1 10/29/21 16:10 75-71-8
1,1-Dichloroethane ND ug/L 0.50 1 10/29/21 16:10 75-34-3
1,2-Dichloroethane ND ug/L 0.50 1 10/29/21 16:10 107-06-2
1,1-Dichloroethene ND ug/L 0.50 1 10/29/21 16:10 75-35-4
cis-1,2-Dichloroethene ND ug/L 0.50 1 10/29/21 16:10 156-59-2
trans-1,2-Dichloroethene ND ug/L 0.50 1 10/29/21 16:10 156-60-5
1,2-Dichloropropane ND ug/L 0.50 1 10/29/21 16:10 78-87-5
1,3-Dichloropropane ND ug/L 0.50 1 10/29/21 16:10 142-28-9
2,2-Dichloropropane ND ug/L 0.50 1 10/29/21 16:10 594-20-7
1,1-Dichloropropene ND ug/L 0.50 1 10/29/21 16:10 563-58-6
cis-1,3-Dichloropropene ND ug/L 0.50 1 10/29/21 16:10 10061-01-5
trans-1,3-Dichloropropene ND ug/L 0.50 11 10/29/21 16:10 10061-02-6
Diisopropyl ether ND ug/L 0.50 1 10/29/21 16:10 108-20-3
Ethylbenzene ND ug/L 0.50 1 10/29/21 16:10 100-41-4
Hexachloro-1,3-butadiene ND ug/L 2.0 1 10/29/21 16:10 87-68-3
lsopropylbenzene(Cumene) ND ug/L 0.50 1 10/29/21 16:10 98-82-8
Methylene Chloride ND ug/L 2.0 1 10/29/21 16:10 75-09-2
Methyl-tert-butyl ether ND ug/L 0.50 1 10/29/21 16:10 1634-04-4
Naphthalene ND ug/L 2.0 1 10/29/21 16:10 91-20-3
n-Propylbenzene ND ug/L 0.50 1 10/29/21 16:10 103-65-1
Styrene ND ug/L 0.50 1 10/29/21 16:10 100-42-5
1,1,1,2-Tetrachloroethane ND ug/L 0.50 1 10/29/21 16:10 630-20-6
1,1,2,2-Tetrachloroethane ND ug/L 0.50 1 10/29/21 16:10 79-34-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date: 11/04/2021 04:57 PM without the written consent of Pace Analytical Services,LLC Page 4 of 31

Pace Analytical Services,LLC
dn ® 2225 Riverside Dr.
7/19:AceAnalytical® Asheville,NC 28804
www.pacalabs.cam
[phone]
ANALYTICAL RESULTS
Project: Lassonde Pappas C11482-01.01
Pace Project No.: 92569443
Sample: MW-4 Lab ID: 92569443001 Collected: 10/28/21 11:36 Received: 10/28/21 14:58 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
6200E MSV Analytical Method:SM 6200B
Pace Analytical Services-Charlotte
Tetrachloroethene ND ug/L 0.50 1 10/29/21 16:10 127-18-4
Toluene ND ug/L 0.50 1 10/29/21 16:10 108-88-3
1,2,3-Trichlorobenzene ND ug/L 2.0 1 10/29/21 16:10 87-61-6
1,2,4-Trichlorobenzene ND ug/L 2.0 1 10/29/21 16:10 120-82-1
1,1,1-Trichloroethane ND ug/L 0.50 1 10/29/21 16:10 71-55-6
1,1,2-Trichloroethane ND ug/L 0.50 1 10/29/21 16:10 79-00-5
Trichloroethene ND ug/L 0.50 1 10/29/21 16:10 79-01-6
Trichlorofluoromethane ND ug/L 1.0 1 10/29/21 16:10 75-69-4
1,2,3-Trichloropropane ND ug/L 0.50 1 10/29/21 16:10 96-18-4
1,2,4-Trimethylbenzene ND ug/L 0.50 1 10/29/21 16:10 95-63-6
1,3,5-Trimethylbenzene ND ug/L 0.50 1 10/29/21 16:10 108-67-8
Vinyl chloride ND ug/L 1.0 1 10/29/21 16:10 75-01-4
m&p-Xylene ND ug/L 1.0 1 10/29/21 16:10 179601-23-1
o-Xylene ND ug/L 0.50 1 10/29/21 16:10 95-47-6
Surrogates
1,2-Dichloroethane-d4(S) 99 % 70-130 1 10/29/21 16:10 17060-07-0
4-Bromofluorobenzene(S) 91 % 70-130 1 10/29/21 16:10 460-00-4
Toluene-d8(S) 96 % 70-130 1 10/29/21 16:10 2037-26-5
2540C Total Dissolved Solids Analytical Method:SM 2540C-2015
Pace Analytical Services-Asheville
Total Dissolved Solids 161 mg/L 25.0 1 11/02/21 10:38
MBIO 9222D Fecal Coliform AVL Analytical Method:SM 9222D-2015 Preparation Method:SM 9222D-2015
Pace Analytical Services-Asheville
Fecal Coliforms ND CFU/100 mL 1.0 1 10/28/21 17:20 10/29/21 16:00
350.1 Ammonia Analytical Method:EPA 350.1 Rev 2.0 1993
Pace Analytical Services-Asheville
Nitrogen,Ammonia ND mg/L 0.10 1 11/02/21 13:21 7664-41-7
353.2 Nitrogen,NO2/NO3 unpres Analytical Method: EPA 353.2 Rev 2.0 1993
Pace Analytical Services-Asheville
Nitrogen,Nitrate 0.084 mg/L 0.040 1 10/29/21 00:57 14797-55-8
365.1 Phosphorus,Total Analytical Method:EPA 365.1 Rev 2.0 1993 Preparation Method:EPA 365.1 Rev 2.0 1993
Pace Analytical Services-Asheville
Phosphorus ND mg/L 0.050 1 11/03/21 20:08 11/03/21 23:24 7723-14-0
4500 Chloride Analytical Method:SM 4500-CI-E-2011
Pace Analytical Services-Asheville
Chloride 6.7 mg/L 1.0 1 11/01/21 20:43 16887-00-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:11/04/2021 04:57 PM without the written consent of Pace Analytical Services,LLC. Page 5 of 31

are H�IPace Analytical Services,LLC
l l® 2225 Riverside Dr.
na Y( 1,tica Asheville,NC 28804
www.pacelabs.com
[phone]
ANALYTICAL RESULTS
Project: Lassonde Pappas C11482-01.01
Pace Project No.. 92569443
Sample: MW-4 Lab ID: 92569443001 Collected: 10/28/21 11:36 Received: 10/28/21 14:58 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
5310B TOC Analytical Method:SM 5310B-2014
Pace Analytical Services-Asheville
Total Organic Carbon 3.1 mg/L 1.0 1 11/03/21 23:06 7440-44-0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:11/04/2021 04:57 PM without the written consent of Pace Analytical Services,LLC, Page 6 of 31

Pace Analytical Services,LLC
® 2225 Riverside Dr
(706:„Jac
�g
eAnalytical Asheville.NC 28804
www.pacelabs.com [phone]
ANALYTICAL RESULTS
Project: Lassonde Pappas C11482-01.01
Pace Project No.: 92569443
Sample: MW-5 Lab ID: 92569443002 Collected: 10/28/21 13:13 Received: 10/28/21 14:58 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
6200B MSV Analytical Method:SM 6200B
Pace Analytical Services-Charlotte
Benzene ND ug/L 0.50 1 10/29/21 16:28 71-43-2
Bromobenzene ND ug/L 0.50 1 10/29/21 16:28 108-86-1
Bromochloromethane ND ug/L 0.50 1 10/29/21 16:28 74-97-5
Bromodichloromethane ND ug/L 0.50 1 10/29/21 16:28 75-27-4
Bromoform ND ug/L 0.50 1 10/29/21 16:28 75-25-2
Bromomethane ND ug/L 5.0 1 10/29/21 16:28 74-83-9
n-Butylbenzene ND ug/L 0.50 1 10/29/21 16:28 104-51-8
sec-Butylbenzene ND ug/L 0.50 1 10/29/21 16:28 135-98-8
tert-Butylbenzene ND ug/L 0.50 1 10/29/21 16:28 98-06-6
Carbon tetrachloride ND ug/L 0.50 1 10/29/21 16:28 56-23-5
Chlorobenzene ND ug/L 0.50 1 10/29/21 16:28 108-90-7
Chloroethane ND ug/L 1.0 1 10/29/21 16:28 75-00-3
Chloroform ND ug/L 0.50 1 10/29/21 16:28 67-66-3
Chloromethane ND ug/L 1.0 1 10/29/21 16:28 74-87-3
2-Chlorotoluene ND ug/L 0.50 1 10/29/21 16:28 95-49-8
4-Chlorotoluene ND ug/L 0.50 1 10/29/21 16:28 106-43-4
1,2-Dibromo-3-chloropropane ND ug/L 1.0 1 10/29/21 16:28 96-12-8
Dibromochloromethane ND ug/L 0.50 1 10/29/21 16:28 124-48-1
1,2-Dibromoethane(EDB) ND ug/L 0.50 1 10/29/21 16:28 106-93-4
Dibromomethane ND ug/L 0.50 1 10/29/21 16:28 74-95-3
1,2-Dichlorobenzene ND ug/L 0.50 1 10/29/21 16:28 95-50-1
1,3-Dichlorobenzene ND ug/L 0.50 1 10/29/21 16:28 541-73-1
1,4-Dichlorobenzene ND ug/L 0.50 1 10/29/21 16:28 106-46-7
Dichlorodifluoromethane ND ug/L 0.50 1 10/29/21 16:28 75-71-8
1,1-Dichloroethane ND ug/L 0.50 1 10/29/21 16:28 75-34-3
1,2-Dichloroethane ND ug/L 0.50 11 10/29/21 16:28 107-06-2
1,1-Dichloroethene ND ug/L 0.50 11 10/29/21 16:28 75-35-4
cis-1,2-Dichloroethene 12.6 ug/L 0.50 1 10/29/21 16:28 156-59-2
trans-1,2-Dichloroethene ND ug/L 0.50 1 10/29/21 16:28 156-60-5
1,2-Dichloropropane ND ug/L 0.50 1 10/29/21 16:28 78-87-5
1,3-Dichloropropane ND ug/L 0.50 1 10/29/21 16:28 142-28-9
2,2-Dichloropropane ND ug/L 0.50 1 10/29/21 16:28 594-20-7
1,1-Dichloropropene ND ug/L 0.50 1 10/29/21 16:28 563-58-6
cis-1,3-Dichloropropene ND ug/L 0.50 1 10/29/21 16:28 10061-01-5
trans-1,3-Dichloropropene ND ug/L 0.50 1 10/29/21 16:28 10061-02-6
Diisopropyl ether ND ug/L 0.50 1 10/29/21 16:28 108-20-3
Ethylbenzene ND ug/L 0.50 1 10/29/21 16:28 100-41-4
Hexachloro-1,3-butadiene ND ug/L 2.0 1 10/29/21 16:28 87-68-3
Isopropylbenzene(Cumene) ND ug/L 0.50 'I 10/29/21 16:28 98-82-8
Methylene Chloride ND ug/L 2.0 1 10/29/21 16:28 75-09-2
Methyl-tert-butyl ether ND ug/L 0.50 1 10/29/21 16:28 1634-04-4
Naphthalene ND ug/L 2.0 1 10/29/21 16:28 91-20-3
n-Propylbenzene ND ug/L 0.50 1 10/29/21 16:28 103-65-1
Styrene ND ug/L 0.50 1 10/29/21 16:28 100-42-5
1,1,1,2-Tetrachloroethane ND ug/L 0.50 1 10/29/21 16:28 630-20-6
1,1,2,2-Tetrachloroethane ND ug/L 0.50 1 10/29/21 16:28 79-34-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date: 11/04/2021 04:57 PM without the written consent of Pace Analytical Services,LLC. Page 7 of 31

e Analytical Pace Analytical Services,LLC
2225 Riverside Dr.
tAsheville,NC 28804
www.pacalabs.cam [phone]
(1/9"rac
ANALYTICAL RESULTS
Project: Lassonde Pappas C11482-01.01
Pace Project No,: 92569443
Sample: MW-5 Lab ID: 92569443002 Collected: 10/28/21 13:13 Received: 10/28/21 14:58 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
6200B MSV Analytical Method:SM 6200B
Pace Analytical Services-Charlotte
Tetrachloroethene 30.7 ug/L 0.50 1 10/29/21 16:28 127-18-4
Toluene ND ug/L 0.50 1 10/29/21 16:28 108-88-3
1,2,3-Trichlorobenzene ND ug/L 2.0 1 10/29/21 16:28 87-61-6
1,2,4-Trichlorobenzene ND ug/L 2.0 1 10/29/21 16:28 120-82-1
1,1,1-Trichloroethane ND ug/L 0.50 1 10/29/21 16:28 71-55-6
1,1,2-Trichloroethane ND ug/L 0.50 1 10/29/21 16:28 79-00-5
Trichloroethene 11.6 ug/L 0.50 1 10/29/21 16:28 79-01-6
Trichlorofluoromethane ND ug/L 1.0 1 10/29/21 16:28 75-69-4
1,2,3-Trichloropropane ND ug/L 0.50 1 10/29/21 16:28 96-18-4
1,2,4-Trimethylbenzene ND ug/L 0.50 1 10/29/21 16:28 95-63-6
1,3,5-Trimethylbenzene ND ug/L 0.50 1 10/29/21 16:28 108-67-8
Vinyl chloride ND ug/L 1.0 1 10/29/21 16:28 75-01-4
m&p-Xylene ND ug/L 1.0 1 10/29/21 16:28 179601-23-1
o-Xylene ND ug/L 0.50 1 10/29/21 16:28 95-47-6
Surrogates
1,2-Dichloroethane-d4(S) 95 % 70-130 1 10/29/21 16:28 17060-07-0
4-Bromofluorobenzene(S) 93 % 70-130 1 10/29/21 16:28 460-00-4
Toluene-d8(S) 97 % 70-130 1 10/29/21 16:28 2037-26-5
2540C Total Dissolved Solids Analytical Method:SM 2540C-2015
Pace Analytical Services-Asheville
Total Dissolved Solids 76.0 mg/L 25.0 1 11/02/21 10:38
MBIO 9222D Fecal Coliform AVL Analytical Method:SM 9222D-2015 Preparation Method:SM 9222D-2015
Pace Analytical Services-Asheville
Fecal Coliforms 5.0 CFU/100 mL 1.0 1 10/28/21 17:20 10/29/21 16:00
350.1 Ammonia Analytical Method: EPA 350.1 Rev 2.0 1993
Pace Analytical Services-Asheville
Nitrogen,Ammonia ND mg/L 0.10 1 11/02/21 13:22 7664-41-7
353.2 Nitrogen,NO2/NO3 unpres Analytical Method:EPA 353.2 Rev 2.0 1993
Pace Analytical Services-Asheville
Nitrogen,Nitrate ND mg/L 0.040 1 10/29/21 00:58 14797-55-8
365.1 Phosphorus,Total Analytical Method:EPA 365.1 Rev 2.0 1993 Preparation Method: EPA 365.1 Rev 2.0 1993
Pace Analytical Services-Asheville
Phosphorus 0.054 mg/L 0.050 1 11/03/21 20:08 11/03/21 23:25 7723-14-0
4500 Chloride Analytical Method:SM 4500-CI-E-2011
Pace Analytical Services-Asheville
Chloride 17.3 mg/L 1.0 1 11/01/21 20:44 16887-00-6
REPORT OF LABORATORY ANALYSIS
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Date: 11/04/2021 04:57 PM without the written consent of Pace Analytical Services,LLC, Page 8 of 31

Pace Analytical Services,LLC
d r1 �s 2225 Riverside Dr.
13e nalytical Asheville,NC 28804
www.pecelabs.cem
[phone]
ANALYTICAL RESULTS
Project: Lassonde Pappas C11482-01.01
Pace Project No...: 92569443
Sample: MW-5 Lab ID: 92569443002 Collected: 10/28/21 13:13 Received: 10/28/21 14:58 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
5310E TOC Analytical Method:SM 5310B-2014
Pace Analytical Services-Asheville
Total Organic Carbon 6.6 mg/L 1.0 1 11/03/21 23:21 7440-44-0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:11/04/2021 04:57 PM without the written consent of Pace Analytical Services,LLC. Page 9 of 31

Pace Analytical Services,LLC
® 2225 Riverside Dr.
Analytical Asheville,NC 28804
www.pacelabs.com [phone]
ANALYTICAL RESULTS
Project: Lassonde Pappas C11482-01.01
Pace Project No.: 92569443
Sample: MW-6 Lab ID: 92569443003 Collected: 10/28/21 10:15 Received: 10/28/21 14:58 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
6200B MSV Analytical Method:SM 6200B
Pace Analytical Services-Charlotte
Benzene ND ug/L 0.50 1 10/29/21 16:46 71-43-2
Bromobenzene ND ug/L 0.50 1 10/29/21 16:46 108-86-1
Bromochloromethane ND ug/L 0.50 1 10/29/21 16:46 74-97-5
Bromodichloromethane ND ug/L 0.50 1 10/29/21 16:46 75-27-4
Bromoform ND ug/L 0.50 1 10/29/21 16:46 75-25-2
Bromomethane ND ug/L 5.0 1 10/29/21 16:46 74-83-9
n-Butylbenzene ND ug/L 0.50 1 10/29/21 16:46 104-51-8
sec-Butylbenzene ND ug/L 0.50 1 10/29/21 16:46 135-98-8
tert-Butylbenzene ND ug/L 0.50 1 10/29/21 16:46 98-06-6
Carbon tetrachloride ND ug/L 0.50 1 10/29/21 16:46 56-23-5
Chlorobenzene ND ug/L 0.50 1 10/29/21 16:46 108-90-7
Chloroethane ND ug/L 1.0 1 10/29/21 16:46 75-00-3
Chloroform ND ug/L 0.50 1 10/29/21 16:46 67-66-3
Chloromethane ND ug/L 1.0 1 10/29/21 16:46 74-87-3
2-Chlorotoluene ND ug/L 0.50 1 10/29/21 16:46 95-49-8
4-Chlorotoluene ND ug/L 0.50 1 10/29/21 16:46 106-43-4
1,2-Dibromo-3-chloropropane ND ug/L 1.0 1 10/29/21 16:46 96-12-8
Dibromochloromethane ND ug/L 0.50 1 10/29/21 16:46 124-48-1
1,2-Dibromoethane(EDB) ND ug/L 0.50 1 10/29/21 16:46 106-93-4
Dibromomethane ND ug/L 0.50 1 10/29/21 16:46 74-95-3
1,2-Dichlorobenzene ND ug/L 0.50 1 10/29/21 16:46 95-50-1
1,3-Dichlorobenzene ND ug/L 0.50 1 10/29/21 16:46 541-73-1
1,4-Dichlorobenzene ND ug/L 0.50 1 10/29/21 16:46 106-46-7
Dichlorodifluoromethane ND ug/L 0.50 1 10/29/21 16:46 75-71-8
1,1-Dichloroethane ND ug/L 0.50 1 10/29/21 16:46 75-34-3
1,2-Dichloroethane ND ug/L 0.50 1 10/29/21 16:46 107-06-2
1,1-Dichloroethene ND ug/L 0.50 1 10/29/21 16:46 75-35-4
cis-1,2-Dichloroethene ND ug/L 0.50 1 10/29/21 16:46 156-59-2
trans-1,2-Dichloroethene ND ug/L 0.50 1 10/29/21 16:46 156-60-5
1,2-Dichloropropane ND ug/L 0.50 1 10/29/21 16:46 78-87-5
1,3-Dichloropropane ND ug/L 0.50 1 10/29/21 16:46 142-28-9
2,2-Dichloropropane ND ug/L 0.50 1 10/29/21 16:46 594-20-7
1,1-Dichloropropene ND ug/L 0.50 1 10/29/21 16:46 563-58-6
cis-1,3-Dichloropropene ND ug/L 0.50 1 10/29/21 16:46 10061-01-5
trans-1,3-Dichloropropene ND ug/L 0.50 1 10/29/21 16:46 10061-02-6
Diisopropyl ether ND ug/L 0.50 1 10/29/21 16:46 108-20-3
Ethylbenzene ND ug/L 0.50 1 10/29/21 16:46 100-41-4
Hexachloro-1,3-butadiene ND ug/L 2.0 1 10/29/21 16:46 87-68-3
Isopropylbenzene(Cumene) ND ug/L 0.50 1 10/29/21 16:46 98-82-8
Methylene Chloride ND ug/L 2.0 1 10/29/21 16:46 75-09-2
Methyl-tert-butyl ether ND ug/L 0.50 1 10/29/21 16:46 1634-04-4
Naphthalene ND ug/L 2.0 1 10/29/21 16:46 91-20-3
n-Propylbenzene ND ug/L 0.50 1 10/29/21 16:46 103-65-1
Styrene ND ug/L 0.50 1 10/29/21 16:46 100-42-5
1,1,1,2-Tetrachloroethane ND ug/L 0.50 1 10/29/21 16:46 630-20-6
1,1,2,2-Tetrachloroethane ND ug/L 0.50 1 10/29/21 16:46 79-34-5
REPORT OF LABORATORY ANALYSIS
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Date: 11/04/2021 04:57 PM without the written consent of Pace Analytical Services,LLC, Page 10 of 31

Pace Analytical Services,LLC
eAnalytical® 225 Riverside Dr
1/ Asheville,NC 28804
(77,,lac
www.pacslabs.com
[phone]
ANALYTICAL RESULTS
Project: Lassonde Pappas C11482-01.01
Pace Project No. 92569443
Sample: MW-6 Lab ID: 92569443003 Collected: 10/28/21 10:15 Received: 10/28/21 14:58 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
6200B MSV Analytical Method:SM 6200B
Pace Analytical Services-Charlotte
Tetrachloroethene ND ug/L 0.50 1 10/29/21 16:46 127-18-4
Toluene ND ug/L 0.50 1 10/29/21 16:46 108-88-3
1,2,3-Trichlorobenzene ND ug/L 2.0 1 10/29/21 16:46 87-61-6
1,2,4-Trichlorobenzene ND ug/L 2.0 1 10/29/21 16:46 120-82-1
1,1,1-Trichloroethane ND ug/L 0.50 1 10/29/21 16:46 71-55-6
1,1,2-Trichloroethane ND ug/L 0.50 1 10/29/21 16:46 79-00-5
Trichloroethene ND ug/L 0.50 1 10/29/21 16:46 79-01-6
Trichlorofluoromethane ND ug/L 1.0 1 10/29/21 16:46 75-69-4
1,2,3-Trichloropropane ND ug/L 0.50 1 10/29/21 16:46 96-18-4
1,2,4-Trimethylbenzene ND ug/L 0.50 1 10/29/21 16:46 95-63-6
1,3,5-Trimethylbenzene ND ug/L 0.50 1 10/29/21 16:46 108-67-8
Vinyl chloride ND ug/L 1.0 1 10/29/21 16:46 75-01-4
m&p-Xylene ND ug/L 1.0 1 10/29/21 16:46 179601-23-1
o-Xylene ND ug/L 0.50 1 10/29/21 16:46 95-47-6
Surrogates
1,2-Dichloroethane-d4(S) 94 % 70-130 1 10/29/21 16:46 17060-07-0
4-Bromofluorobenzene(S) 93 % 70-130 1 10/29/21 16:46 460-00-4
Toluene-d8(S) 94 % 70-130 1 10/29/21 16:46 2037-26-5
2540C Total Dissolved Solids Analytical Method:SM 2540C-2015
Pace Analytical Services-Asheville
Total Dissolved Solids 85.0 mg/L 25.0 1 11/02/21 10:39
MBIO 9222D Fecal Coliform AVL Analytical Method:SM 9222D-2015 Preparation Method:SM 9222D-2015
Pace Analytical Services-Asheville
Fecal Coliforms ND CFU/100 mL 1.0 1 10/28/21 17:20 10/29/21 16:00
350.1 Ammonia Analytical Method:EPA 350.1 Rev 2.0 1993
Pace Analytical Services-Asheville
Nitrogen,Ammonia ND mg/L 0.10 1 11/02/21 13:24 7664-41-7
353.2 Nitrogen,NO2/NO3 unpres Analytical Method:EPA 353.2 Rev 2.0 1993
Pace Analytical Services-Asheville
Nitrogen,Nitrate ND mg/L 0.040 1 10/29/21 00:54 14797-55-8
365.1 Phosphorus,Total Analytical Method:EPA 365.1 Rev 2.0 1993 Preparation Method: EPA 365.1 Rev 2.0 1993
Pace Analytical Services-Asheville
Phosphorus ND mg/L 0.050 1 11/03/21 20:08 11/03/21 23:25 7723-14-0
4500 Chloride Analytical Method:SM 4500-CI-E-2011
Pace Analytical Services-Asheville
Chloride 8.7 mg/L 1.0 1 11/01/21 20:45 16887-00-6
REPORT OF LABORATORY ANALYSIS
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Date: 11/04/2021 04:57 PM without the written consent of Pace Analytical Services,LLC. Page 11 of 31

Pace Analytical Services,LLC
cAnal tical® 2225 Riverside Dr
Anal JI/`1 l� Asheville,NC 28604
www.pacelabs.com [phone]
ANALYTICAL RESULTS
Project: Lassonde Pappas C11482-01.01
Pace Project No.: 92569443
Sample: MW-6 Lab ID: 92569443003 Collected: 10/28/21 10:15 Received: 10/28/21 14:58 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
5310B TOC Analytical Method:SM 5310B-2014
Pace Analytical Services-Asheville
Total Organic Carbon 2.3 mg/L 1.0 1 11/03/21 23:37 7440-44-0
REPORT OF LABORATORY ANALYSIS
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Date:11/04/2021 04:57 PM without the written consent of Pace Analytical Services,LLC, Page 12 of 31

Pace Analytical Services,LLC
�w /� f 0 2225 Riverside Dr.
Analyt!Cal(m„,,Plifa Asheville,NC 28804
www.pacelaba.cem [phone]
ANALYTICAL RESULTS
Project: Lassonde Pappas C11482-01.01
Pace Project No.: 92569443
Sample: TRIP BLANK Lab ID: 92569443004 Collected: 10/28/21 00:00 Received: 10/28/21 14:58 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
6200E MSV Analytical Method:SM 6200B
Pace Analytical Services-Charlotte
Benzene ND ug/L 0.50 1 10/29/21 13:10 71-43-2
Bromobenzene ND ug/L 0.50 1 10/29/21 13:10 108-86-1
Bromochloromethane ND ug/L 0.50 1 10/29/21 13:10 74-97-5
Bromodichloromethane ND ug/L 0.50 1 10/29/21 13:10 75-27-4
Bromoform ND ug/L 0.50 1 10/29/21 13:10 75-25-2
Bromomethane ND ug/L 5.0 1 10/29/21 13:10 74-83-9
n-Butylbenzene ND ug/L 0.50 1 10/29/21 13:10 104-51-8
sec-Butylbenzene ND ug/L 0.50 1 10/29/21 13:10 135-98-8
tert-Butylbenzene ND ug/L 0.50 1 10/29/21 13:10 98-06-6
Carbon tetrachloride ND ug/L 0.50 1 10/29/21 13:10 56-23-5
Chlorobenzene ND ug/L 0.50 1 10/29/21 13:10 108-90-7
Chloroethane ND ug/L 1.0 1 10/29/21 13:10 75-00-3
Chloroform ND ug/L 0.50 1 10/29/21 13:10 67-66-3
Chloromethane ND ug/L 1.0 1 10/29/21 13:10 74-87-3
2-Chlorotoluene ND ug/L 0.50 1 10/29/21 13:10 95-49-8
4-Chlorotoluene ND ug/L 0.50 1 10/29/21 13:10 106-43-4
1,2-Dibromo-3-chloropropane ND ug/L 1.0 1 10/29/21 13:10 96-12-8
Dibromochloromethane ND ug/L 0.50 1 10/29/21 13:10 124-48-1
1,2-Dibromoethane(EDB) ND ug/L 0.50 1 10/29/21 13:10 106-93-4
Dibromomethane ND ug/L 0.50 1 10/29/21 13:10 74-95-3
1,2-Dichlorobenzene ND ug/L 0.50 1 10/29/21 13:10 95-50-1
1,3-Dichlorobenzene ND ug/L 0.50 1 10/29/21 13:10 541-73-1
1,4-Dichlorobenzene ND ug/L 0.50 1 10/29/21 13:10 106-46-7
Dichlorodifluoromethane ND ug/L 0.50 1 10/29/21 13:10 75-71-8
1,1-Dichloroethane ND ug/L 0.50 1 10/29/21 13:10 75-34-3
1,2-Dichloroethane ND ug/L 0.50 1 10/29/21 13:10 107-06-2
1,1-Dichloroethene ND ug/L 0.50 1 10/29/21 13:10 75-35-4
cis-1,2-Dichloroethene ND ug/L 0.50 1 10/29/21 13:10 156-59-2
trans-1,2-Dichloroethene ND ug/L 0.50 1 10/29/21 13:10 156-60-5
1,2-Dichloropropane ND ug/L 0.50 1 10/29/21 13:10 78-87-5
1,3-Dichloropropane ND ug/L 0.50 1 10/29/21 13:10 142-28-9
2,2-Dichloropropane ND ug/L 0.50 1 10/29/21 13:10 594-20-7
1,1-Dichloropropene ND ug/L 0.50 1 10/29/21 13:10 563-58-6
cis-1,3-Dichloropropene ND ug/L 0.50 1 10/29/21 13:10 10061-01-5
trans-1,3-Dichloropropene ND ug/L 0.50 1 10/29/21 13:10 10061-02-6
Diisopropyl ether ND ug/L 0.50 1 10/29/21 13:10 108-20-3
Ethylbenzene ND ug/L 0.50 1 10/29/21 13:10 100-41-4
Hexachloro-1,3-butadiene ND ug/L 2.0 1 10/29/21 13:10 87-68-3
Isopropylbenzene(Cumene) ND ug/L 0.50 1 10/29/21 13:10 98-82-8
Methylene Chloride ND ug/L 2.0 1 10/29/21 13:10 75-09-2
Methyl-tert-butyl ether ND ug/L 0.50 1 10/29/21 13:10 1634-04-4
Naphthalene ND ug/L 2.0 1 10/29/21 13:10 91-20-3
n-Propylbenzene ND ug/L 0.50 1 10/29/21 13:10 103-65-1
Styrene ND ug/L 0.50 1 10/29/21 13:10 100-42-5
1,1,1,2-Tetrachloroethane ND ug/L 0.50 1 10/29/21 13:10 630-20-6
1,1,2,2-Tetrachloroethane ND ug/L 0.50 1 10/29/21 13:10 79-34-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:11/04/2021 04:57 PM without the written consent of Pace Analytical Services,LLC Page 13 of 31

n Pace Analytical Services,LLC
F � al tical 2225 Riverside Dr.
11 JI/`f li Asheville,NC 28804
1719
www.pacalabs.com [phone]
ANALYTICAL RESULTS
Project: Lassonde Pappas C11482-01.01
Pace Project No.: 92569443
Sample: TRIP BLANK Lab ID: 92569443004 Collected: 10/28/21 00:00 Received: 10/28/21 14:58 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
6200B MSV Analytical Method:SM 6200B
Pace Analytical Services-Charlotte
Tetrachloroethene ND ug/L 0.50 1 10/29/21 13:10 127-18-4
Toluene ND ug/L 0.50 1 10/29/21 13:10 108-88-3
1,2,3-Trichlorobenzene ND ug/L 2.0 1 10/29/21 13:10 87-61-6
1,2,4-Trichlorobenzene ND ug/L 2.0 1 10/29/21 13:10 120-82-1
1,1,1-Trichloroethane ND ug/L 0.50 1 10/29/21 13:10 71-55-6
1,1,2-Trichloroethane ND ug/L 0.50 1 10/29/21 13:10 79-00-5
Trichloroethene ND ug/L 0.50 1 10/29/21 13:10 79-01-6
Trichlorofluoromethane ND ug/L 1.0 1 10/29/21 13:10 75-69-4
1,2,3-Trichloropropane ND ug/L 0.50 1 10/29/21 13:10 96-18-4
1,2,4-Trimethylbenzene ND ug/L 0.50 1 10/29/21 13:10 95-63-6
1,3,5-Trimethylbenzene ND ug/L 0.50 1 10/29/21 13:10 108-67-8
Vinyl chloride ND ug/L 1.0 1 10/29/21 13:10 75-01-4
m&p-Xylene ND ug/L 1.0 1 10/29/21 13:10 179601-23-1
o-Xylene ND ug/L 0.50 1 10/29/21 13:10 95-47-6
Surrogates
1,2-Dichloroethane-d4(S) 94 % 70-130 1 10/29/21 13:10 17060-07-0
4-Bromofluorobenzene(S) 91 % 70-130 1 10/29/21 13:10 460-00-4
Toluene-d8(S) 94 % 70-130 1 10/29/21 13:10 2037-26-5
REPORT OF LABORATORY ANALYSIS
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Date: 11/04/2021 04:57 PM without the written consent of Pace Analytical Services,LLC. Page 14 of 31

Pace Analytical Services,LLC
ace Ana ytical Asheville,225 Riverside 0
� Dr
7/SP, f'I 1 li NC 26804
www.pacelabs.com [phone]
C
QUALITY CONTROL DATA
Project: Lassonde Pappas C11482-01.01
Pace Project No.: 92569443
QC Batch: 656203 Analysis Method: SM 6200B
QC Batch Method: SM 6200B Analysis Description: 6200B MSV
Laboratory: Pace Analytical Services-Charlotte
Associated Lab Samples: 92569443001,92569443002,92569443003,92569443004
METHOD BLANK: 3440029 Matrix: Water
Associated Lab Samples: 92569443001,92569443002,92569443003,92569443004
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
1,1,1,2-Tetrachloroethane ug/L ND 0.50 10/29/21 12:16
1,1,1-Trichloroethane ug/L ND 0.50 10/29/21 12:16
1,1,2,2-Tetrachloroethane ug/L ND 0.50 10/29/21 12:16
1,1,2-Trichloroethane ug/L ND 0.50 10/29/21 12:16
1,1-Dichloroethane ug/L ND 0.50 10/29/21 12:16
1,1-Dichloroethene ug/L ND 0.50 10/29/21 12:16
1,1-Dichloropropene ug/L ND 0.50 10/29/21 12:16
1,2,3-Trichlorobenzene ug/L ND 2.0 10/29/21 12:16
1,2,3-Trichloropropane ug/L ND 0.50 10/29/21 12:16
1,2,4-Trichlorobenzene ug/L ND 2.0 10/29/21 12:16
1,2,4-Trimethylbenzene ug/L ND 0.50 10/29/21 12:16
1,2-Dibromo-3-chloropropane ug/L ND 1.0 10/29/21 12:16
1,2-Dibromoethane(EDB) ug/L ND 0.50 10/29/21 12:16
1,2-Dichlorobenzene ug/L ND 0.50 10/29/21 12:16
1,2-Dichloroethane ug/L ND 0.50 10/29/21 12:16
1,2-Dichloropropane ug/L ND 0.50 10/29/21 12:16
1,3,5-Trimethylbenzene ug/L ND 0.50 10/29/21 12:16
1,3-Dichlorobenzene ug/L ND 0.50 10/29/21 12:16
1,3-Dichloropropane ug/L ND 0.50 10/29/21 12:16
1,4-Dichlorobenzene ug/L ND 0.50 10/29/21 12:16
2,2-Dichloropropane ug/L ND 0.50 10/29/21 12:16
2-Chlorotoluene ug/L ND 0.50 10/29/21 12:16
4-Chlorotoluene ug/L ND 0.50 10/29/21 12:16
Benzene ug/L ND 0.50 10/29/21 12:16
Bromobenzene ug/L ND 0.50 10/29/21 12:16
Bromochloromethane ug/L ND 0.50 10/29/21 12:16
Bromodichloromethane ug/L ND 0.50 10/29/21 12:16
Bromoform ug/L ND 0.50 10/29/21 12:16
Bromomethane ug/L ND 5.0 10/29/21 12:16
Carbon tetrachloride ug/L ND 0.50 10/29/21 12:16
Chlorobenzene ug/L ND 0.50 10/29/21 12:16
Chloroethane ug/L ND 1.0 10/29/21 12:16
Chloroform ug/L ND 0.50 10/29/21 12:16
Chloromethane ug/L ND 1.0 10/29/21 12:16
cis-1,2-Dichloroethene ug/L ND 0.50 10/29/21 12:16
cis-1,3-Dichloropropene ug/L ND 0.50 10/29/21 12:16
Dibromochloromethane ug/L ND 0.50 10/29/21 12:16
Dibromomethane ug/L ND 0.50 10/29/21 12:16
Dichlorodifluoromethane ug/L ND 0.50 10/29/21 12:16
Diisopropyl ether ug/L ND 0.50 10/29/21 12:16
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Pace Analytical Services,LLC
r1
ii/t
el2225 Riverside Dr.
Analytical Asheville,NC 28804
www.pacelabs.com [phone]
QUALITY CONTROL DATA
Project: Lassonde Pappas C11482-01.01
Pace Project No.: 92569443
METHOD BLANK: 3440029 Matrix: Water
Associated Lab Samples: 92569443001,92569443002,92569443003,92569443004
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Ethylbenzene ug/L ND 0.50 10/29/21 12:16
Hexachloro-1,3-butadiene ug/L ND 2.0 10/29/21 12:16
lsopropylbenzene(Cumene) ug/L ND 0.50 10/29/21 12:16
m&p-Xylene ug/L ND 1.0 10/29/21 12:16
Methyl-tert-butyl ether ug/L ND 0.50 10/29/21 12:16
Methylene Chloride ug/L ND 2.0 10/29/21 12:16
n-Butylbenzene ug/L ND 0.50 10/29/21 12:16
n-Propylbenzene ug/L ND 0.50 10/29/21 12:16
Naphthalene ug/L ND 2.0 10/29/21 12:16
o-Xylene ug/L ND 0.50 10/29/21 12:16
sec-Butylbenzene ug/L ND 0.50 10/29/21 12:16
Styrene ug/L ND 0.50 10/29/21 12:16
tert-Butylbenzene ug/L ND 0.50 10/29/21 12:16
Tetrachloroethene ug/L ND 0.50 10/29/21 12:16
Toluene ug/L ND 0.50 10/29/21 12:16
trans-1,2-Dichloroethene ug/L ND 0.50 10/29/21 12:16
trans-1,3-Dichloropropene ug/L ND 0.50 10/29/21 12:16
Trichloroethene ug/L ND 0.50 10/29/21 12:16
Trichlorofluoromethane ug/L ND 1.0 10/29/21 12:16
Vinyl chloride ug/L ND 1.0 10/29/21 12:16
1,2-Dichloroethane-d4(S) % 97 70-130 10/29/21 12:16
4-Bromofluorobenzene(S) % 93 70-130 10/29/21 12:16
Toluene-d8(S) % 98 70-130 10/29/21 12:16
LABORATORY CONTROL SAMPLE: 3440030
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
1,1,1,2 Tetrachlor.. .. m ..-.._ _�
oethane ug/L 50 51.3 103 60-140
1,1,1-Trichloroethane ug/L 50 46.8 94 60-140
1,1,2,2-Tetrachloroethane ug/L 50 47.4 95 60-140
1,1,2-Trichloroethane ug/L 50 45.4 91 60-140
1,1-Dichloroethane ug/L 50 42.5 85 60-140
1,1-Dichloroethene ug/L 50 41.2 82 60-140
1,1-Dichloropropene ug/L 50 43.7 87 60-140
1,2,3-Trichlorobenzene ug/L 50 57.0 114 60-140
1,2,3-Trichloropropane ug/L 50 46.5 93 60-140
1,2,4-Trichlorobenzene ug/L 50 57.7 115 60-140
1,2,4-Trimethylbenzene ug/L 50 50.8 102 60-140
1,2-Dibromo-3-chloropropane ug/L 50 50.6 101 60-140
1,2-Dibromoethane(EDB) ug/L 50 51.9 104 60-140
1,2-Dichlorobenzene ug/L 50 53.8 108 60-140
1,2-Dichloroethane ug/L 50 40.2 80 60-140
1,2-Dichloropropane ug/L 50 44.1 88 60-140
1,3,5-Trimethylbenzene ug/L 50 51.2 102 60-140
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 11/04/2021 04:57 PM without the written consent of Pace Analytical Services,LLC Page 16 of 31

/00:,Aceelac,
Analytical
Pace Analytical Services,LLC
Itif
2225 Riverside Dr.
Asheville,NC 28804
www.pacelabs.com [phone]
I
QUALITY CONTROL DATA
Project: Lassonde Pappas C11482-01.01
Pace Project No.: 92569443
LABORATORY CONTROL SAMPLE: 3440030
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
1,3-Dichlorobenzene ug/L 50 53.4 107 60-140
1,3-Dichloropropane ug/L 50 48.7 97 60-140
1,4-Dichlorobenzene ug/L 50 54.2 108 60-140
2,2-Dichloropropane ug/L 50 43.4 87 60-140
2-Chlorotoluene ug/L 50 51.2 102 60-140
4-Chlorotoluene ug/L 50 49.1 98 60-140
Benzene ug/L 50 44.6 89 60-140
Bromobenzene ug/L 50 55.0 110 60-140
Bromochloromethane ug/L 50 46.7 93 60-140
Bromodichloromethane ug/L 50 47.3 95 60-140
Bromoform ug/L 50 52.0 104 60-140
Bromomethane ug/L 50 41.8 84 60-140
Carbon tetrachloride ug/L 50 47.7 95 60-140
Chlorobenzene ug/L 50 51.1 102 60-140
Chloroethane ug/L 50 48.2 96 60-140
Chloroform ug/L 50 43.4 87 60-140
Chloromethane ug/L 50 38.8 78 60-140
cis-1,2-Dichloroethene ug/L 50 41.9 84 60-140
cis-1,3-Dichloropropene ug/L 50 45.1 90 60-140
Dibromochloromethane ug/L 50 50.2 100 60-140
Dibromomethane ug/L 50 49.2 98 60-140
Dichlorodifluoromethane ug/L 50 56.3 113 60-140
Diisopropyl ether ug/L 50 39.8 80 60-140
Ethylbenzene ug/L 50 51.2 102 60-140
Hexachloro-1,3-butadiene ug/L 50 64.1 128 60-140
Isopropylbenzene(Cumene) ug/L 50 53.8 108 60-140
m&p-Xylene ug/L 100 102 102 60-140
Methyl-tert-butyl ether ug/L 50 41.3 83 60-140
Methylene Chloride ug/L 50 46.0 92 60-140
n-Butylbenzene ug/L 50 52.0 104 60-140
n-Propylbenzene ug/L 50 49.3 99 60-140
Naphthalene ug/L 50 53.1 106 60-140
o-Xylene ug/L 50 50.7 101 60-140
sec-Butylbenzene ug/L 50 50.3 101 60-140
Styrene ug/L 50 51.3 103 60-140
tert-Butylbenzene ug/L 50 42.4 85 60-140
Tetrachloroethene ug/L 50 54.5 109 60-140
Toluene ug/L 50 46.4 93 60-140
trans-1,2-Dichloroethene ug/L 50 44.5 89 60-140
trans-1,3-Dichloropropene ug/L 50 45.8 92 60-140
Trichloroethene ug/L 50 50.4 101 60-140
Trichlorofluoromethane ug/L 50 53.2 106 60-140
Vinyl chloride ug/L 50 47.2 94 60-140
1,2-Dichloroethane-d4(S) % 87 70-130
4-Bromofluorobenzene(S) % 96 70-130
Toluene-d8(S) % 96 70-130
Results presented on this page are In the units indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date: 11/04/2021 04:57 PM without the written consent of Pace Analytical Services,LLC. Page 17 of 31

Pace Analytical Services,LLC
nal J�/'�l�tical® 2225 Riverside Dr.
�-- Analytical'
Asheville,NC 28804
www.pacalabs.com [phone]
.111
QUALITY CONTROL DATA
Project: Lassonde Pappas C11482-01.01
Pace Project No.: 92569443
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 3440031 3440032
MS MSD
92568851002 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
1,1,1,2-Tetrachloroethane ug/L <15.6 1000 1000 1110 1170 ._.----......_..1.__ 0-- ._
g 111 117 60-140 5
1,1,1-Trichloroethane ug/L <16.6 1000 1000 1000 977 100 98 60-140 2
1,1,2,2-Tetrachloroethane ug/L <11.2 1000 1000 1080 1110 108 111 60-140 3
1,1,2-Trichloroethane ug/L <16.2 1000 1000 970 1000 97 100 60-140 3
1,1-Dichloroethane ug/L <18.4 1000 1000 860 865 86 86 60-140 1
1,1-Dichloroethene ug/L <17.4 1000 1000 706 679 71 68 60-140 4
1,1-Dichloropropene ug/L <21.4 1000 1000 902 920 90 92 60-140 2
1,2,3-Trichlorobenzene ug/L <40.3 1000 1000 1120 1190 112 119 60-140 6
1,2,3-Trichloropropane ug/L <13.0 1000 1000 981 1060 98 106 60-140 8
1,2,4-Trichlorobenzene ug/L <32.0 1000 1000 1140 1230 114 123 60-140 8
1,2,4-Trimethylbenzene ug/L 4660 1000 1000 7410 7800 276 314 60-140 5 M1
1,2-Dibromo-3-chloropropane ug/L <17.0 1000 1000 960 1090 96 109 60-140 12
1,2-Dibromoethane(EDB) ug/L <13.6 1000 1000 1110 1120 111 112 60-140 1
1,2-Dichlorobenzene ug/L <17.0 1000 1000 1100 1160 110 116 60-140 6
1,2-Dichloroethane ug/L <16.1 1000 1000 871 887 87 89 60-140 2
1,2-Dichloropropane ug/L <17.8 1000 1000 956 991 96 99 60-140 4
1,3,5-Trimethylbenzene ug/L 1230 1000 1000 2840 2950 161 172 60-140 4 M1
1,3-Dichlorobenzene ug/L <17.0 1000 1000 1110 1170 111 117 60-140 5
1,3-Dichloropropane ug/L <14.2 1000 1000 1040 1070 104 107 60-140 2
1,4-Dichlorobenzene ug/L <16.6 1000 1000 1120 1200 112 120 60-140 8
2,2-Dichloropropane ug/L <19.4 1000 1000 777 831 78 83 60-140 7
2-Chlorotoluene ug/L <16.0 1000 1000 1210 1410 121 141 60-140 16 M1
4-Chlorotoluene ug/L <16.2 1000 1000 1000 1070 100 107 60-140 6
Benzene ug/L 1670 1000 1000 2630 2640 97 98 60-140 0
Bromobenzene ug/L <14.5 1000 1000 1170 1240 117 124 60-140 6
Bromochloromethane ug/L <23.4 1000 1000 939 996 94 100 60-140 6
Bromodichloromethane ug/L <15.4 1000 1000 976 989 98 99 60-140 1
Bromoform ug/L <17.0 1000 1000 1030 1070 103 107 60-140 4
Bromomethane ug/L <83.0 1000 1000 333 420 33 42 60-140 23 M1
Carbon tetrachloride ug/L <16.6 1000 1000 935 967 94 97 60-140 3
Chlorobenzene ug/L <14.2 1000 1000 1100 1150 110 115 60-140 5
Chloroethane ug/L <32.4 1000 1000 704 745 70 75 60-140 6
Chloroform ug/L <17.6 1000 1000 935 984 94 98 60-140 5
Chloromethane ug/L <27.0 1000 1000 260 295 26 30 60-140 13 M1
cis-1,2-Dichloroethene ug/L <19.2 1000 1000 852 889 85 89 60-140 4
cis-1,3-Dichloropropene ug/L <18.2 1000 1000 923 966 92 97 60-140 5
Dibromochloromethane ug/L <18.0 1000 1000 1050 1130 105 113 60-140 8
Dibromomethane ug/L <19.7 1000 1000 1010 1080 101 108 60-140 6
Dichlorodifluoromethane ug/L <17.3 1000 1000 139 140 14 14 60-140 1 M1
Diisopropyl ether ug/L <15.4 1000 1000 785 801 78 80 60-140 2
Ethylbenzene ug/L 5250 1000 1000 6880 7010 163 176 60-140 2 M1
Hexachloro-1,3-butadiene ug/L <76.5 1000 1000 1260 1330 126 133 60-140 6
lsopropylbenzene(Cumene) ug/L 251 1000 1000 1540 1560 129 131 60-140 1
m&p-Xylene ug/L 18000 2000 2000 22500 23000 223 247 60-140 2 E,M1
Methyl-tert-butyl ether ug/L 77.2 1000 1000 862 868 78 79 60-140 1
Methylene Chloride ug/L <97.5 1000 1000 878 876 88 88 60-140 0
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date: 11/04/2021 04:57 PM without the written consent of Pace Analytical Services,LLC. Page 18 of 31

Pace Analytical Services,LLC
Dr
are Analytical Asheville,225 Riverside 2 28804
(7/19H11 1. 25 7176
www.pacelabs.com [phone]
QUALITY CONTROL DATA
Project: Lassonde Pappas C11482-01.01
Pace Project No.: 92569443
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 3440031 3440032
MS MSD
92568851002 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
n-Butylbenzene ug/L 122 1000 1000 1370 1450 125 132 60-140
g5
n-Propylbenzene ug/L 692 1000 1000 2020 2140 133 144 60-140 6 M1
Naphthalene ug/L 805 1000 1000 1940 2090 113 128 60-140 7
o-Xylene ug/L 1320 1000 1000 2580 2640 126 132 60-140 2
sec-Butylbenzene ug/L <20.0 1000 1000 1110 1170 111 117 60-140 6
Styrene ug/L <14.6 1000 1000 1080 1140 108 114 60-140 5
tert-Butylbenzene ug/L <16.2 1000 1000 907 962 91 96 60-140 6
Tetrachloroethene ug/L <14.6 1000 1000 1130 1160 113 116 60-140 2
Toluene ug/L 299 1000 1000 1240 1300 94 100 60-140 4
trans-1,2-Dichloroethene ug/L <19.8 1000 1000 815 840 81 84 60-140 3
trans-1,3-Dichloropropene ug/L <18.2 1000 1000 954 930 95 93 60-140 3
Trichloroethene ug/L <19.2 1000 1000 1070 1070 107 107 60-140 0
Trichlorofluoromethane ug/L <14.9 1000 1000 633 660 63 66 60-140 4
Vinyl chloride ug/L <19.3 1000 1000 429 442 43 44 60-140 3 M1
1,2-Dichloroethane-d4(S) % 94 95 70-130
4-Bromofluorobenzene(S) % 97 94 70-130
Toluene-d8(S) % 95 94 70-130
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date: 11/04/2021 04:57 PM without the written consent of Pace Analytical Services,LLC Page 19 of 31

Pace Analytical Services,LLC
An�l- tical 2225 Riverside Dr
/PACe11 IJI/`T Asheville,NC 28804
www.pacelabs.corn [phone]
QUALITY CONTROL DATA
Project: Lassonde Pappas C11482-01.01
Pace Project No.: 92569443
QC Batch: 656825 Analysis Method: SM 2540C-2015
QC Batch Method: SM 2540C-2015 Analysis Description: 2540C Total Dissolved Solids
Laboratory: Pace Analytical Services-Asheville
Associated Lab Samples: 92569443001,92569443002,92569443003
METHOD BLANK: 3442970 Matrix: Water
Associated Lab Samples: 92569443001,92569443002,92569443003
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Total Dissolved Solids mg/L ND 25.0 11/02/21 10:38
wwwwW__WwwW
LABORATORY CONTROL SAMPLE: 3442971
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
Total Dissolved Solids mg/L 2502............... ___....._5._ _._.�...................�.__... ...ww_-_-_-_-----�_.
0 100 90-110
SAMPLE DUPLICATE: 3442972
92569404001 Dup
Parameter Units Result Result RPD Qualifiers
Total Dissolved Solids mg/L 725 706 3.__...�_.._
SAMPLE DUPLICATE: 3442973
92569641002 Dup
Parameter Units Result Result RPD Qualifiers
Total Dissolved Solids mg/L 564 572 1
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date: 11/04/2021 04:57 PM without the written consent of Pace Analytical Services,LLC. Page 20 of 31

Pace Analytical Services,LLC
2225 Riverside Dr.
(„_,/aceAnalytical Asheville,NC 28804
www.pacelabs.com [phone]
QUALITY CONTROL DATA
Project: Lassonde Pappas C11482-01.01
Pace Project No.: 92569443
QC Batch: 656990 Analysis Method: SM 9222D-2015
QC Batch Method' SM 9222D-2015 Analysis Description: 9222D Fecal Coliform(MF)-AVL
Laboratory: Pace Analytical Services-Asheville
Associated Lab Samples: 92569443001,92569443002,92569443003
METHOD BLANK: 3443951 Matrix: Water
Associated Lab Samples: 92569443001,92569443002,92569443003
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Fecal Coliforms CFU/100 mL ND 1.0 10/29/21 16:00
SAMPLE DUPLICATE: 3443952
92569468001 Dup
Parameter Units Result Result RPD Qualifiers
Fecal Coliforms ITITITITITITITITmmITITmmmm WWW CFU/100 mL ND _. ......_ ND
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date: 11/04/2021 04:57 PM without the written consent of Pace Analytical Services,LLC. Page 21 of 31

Pace Analytical Services,LLC
2225 Riverside Dr.
(74eAnalytical® Asheville,NC 28804
www.pacalabs.cam
pp [phone]
QUALITY CONTROL DATA
Project: Lassonde Pappas C11482-01.01
Pace Project No.: 92569443
QC Batch: 656769 Analysis Method: EPA 350.1 Rev 2.0 1993
QC Batch Method: EPA 350.1 Rev 2.0 1993 Analysis Description: 350.1 Ammonia
Laboratory: Pace Analytical Services-Asheville
Associated Lab Samples: 92569443001,92569443002,92569443003
METHOD BLANK: 3442791 Matrix: Water
Associated Lab Samples: 92569443001,92569443002,92569443003
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Nitrogen,Ammonia mm ... mmITmmmmmµ mg/L ND 0.10 11/02/21 12:52
LABORATORY CONTROL SAMPLE: 3442792
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
Nitrogen,Ammonia mg/L 5 5.1 102 90-110
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 3442793 3442794
MS MSD
92568878004 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
Nitrogen,Ammonia mg/L 1120 5 5 1130 1100 158 -504 90-110 3 M1
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 3442795 3442796
MS MSD
92568878005 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
Nitrogen,Ammonia mg/L 814 5 5 937 851 2460 738 90-110 10 M1
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:11/04/2021 04:57 PM without the written consent of Pace Analytical Services,LLC Page 22 of 31

Pace Analytical Services,LLC
2225
CeAnalytical hevi Riverside D04
r
i 1 s Asheville,NC 28804
17:7,,a,P
www.pecelabs.com [phone]
QUALITY CONTROL DATA
Project: Lassonde Pappas C11482-01.01
Pace Project No.: 92569443
QC Batch: 656094 Analysis Method: EPA 353.2 Rev 2.0 1993
QC Batch Method: EPA 353.2 Rev 2.0 1993 Analysis Description: 353.2 Nitrate+Nitrite, Unpres.
Laboratory: Pace Analytical Services-Asheville
Associated Lab Samples: 92569443001,92569443002,92569443003
METHOD BLANK: 3439643 Matrix: Water
Associated Lab Samples: 92569443001,92569443002,92569443003
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Nitrogen,Nitrate mg/L ND 0.040 10/29/21 00:30
LABORATORY CONTROL SAMPLE: 3439644
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
Nitrogen,Nitrate mg/L 1.5 1.5 99 90-110
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 3439645 3439646
MS MSD
92569273002 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
Nitrogen,Nitrate m /L 0.35 1.5 1.5 1.9 1.9 _... ... 103 101
g g90-110 1
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 3439647 3439648
MS MSD
92569468001 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
Nitrogen, Nitrate mg/L 13.3 1.5 1.5 18.1 19.1 320 85 ......9 -
g g 385 90-110 5
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:11/04/2021 04:57 PM without the written consent of Pace Analytical Services,LLC,. Page 23 of 31

Pace Analytical Services,LLC
® 2225 Riverside Dr.
aceAnalyfical Asheville,NC 28804
www.pacslabs.com [phone]
QUALITY CONTROL DATA
Project: Lassonde Pappas C11482-01.01
Pace Project No.: 92569443
QC Batch: 657332 Analysis Method: EPA 365.1 Rev 2.0 1993
QC Batch Method: EPA 365.1 Rev 2.0 1993 Analysis Description: 365.1 Phosphorus,Total
Laboratory: Pace Analytical Services-Asheville
Associated Lab Samples: 92569443001,92569443002,92569443003
METHOD BLANK: 3445906 Matrix: Water
Associated Lab Samples: 92569443001,92569443002,92569443003
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Phosphorus mg/L ND 0.050 11/03/21 23:04
LABORATORY CONTROL SAMPLE: 3445907
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
2.6 2,5 Phosphorus mg/L _ .... ,... .. .._ __, .... ._
p g 103 90-110
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 3445908 3445909
MS MSD
92568854001 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
Phosphorus m /L 0.43 2.5 2.5 3.0 3.1 104 106 �..... �� , ... -
P 990-110 2
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 3445910 3445911
MS MSD
92568854002 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
Phosphorus
..�.-..... .�.- ._. ... ... 0.45 2.5 2.5 _ .... 3.0 3.1
p mg/L 103 104 90-110 1
Results presented on this page are in the units indicated by the"units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date: 11/04/2021 04:57 PM without the written consent of Pace Analytical Services,LLC. Page 24 of 31

Pace Analytical Services,LLC
c J�/
1///?7,„
Anal_ tIcaI 2225 Riverside Dr
I 1 `�l� Asheville,NC 28804
www.pacelabs.com [phone]
QUALITY CONTROL DATA
Project: Lassonde Pappas C11482-01.01
Pace Project No.: 92569443
QC Batch: 656672 Analysis Method: SM 4500-CI-E-2011
QC Batch Method: SM 4500-CI-E-2011 Analysis Description: 4500 Chloride
Laboratory: Pace Analytical Services-Asheville
Associated Lab Samples: 92569443001,92569443002,92569443003
METHOD BLANK: 3442321 Matrix: Water
Associated Lab Samples: 92569443001,92569443002,92569443003
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Chloride.._ mg/L....._.....__....._ ND........�......_..........1.o 11/01/21 20:29
LABORATORY CONTROL SAMPLE: 3442322
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
Chloride mg/L 20 20.2 101 90-110
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 3442323 3442324
MS MSD
92568559006 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
Chloride mg/L 72.1 10 10 86.0 84.1 139 120 90-110 2 M1
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 3442325 3442326
MS MSD
92568822002 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
Chloride mg/L 59.2 10 10 67.4 69.9 82 106 90-110 4 M1
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date: 11/04/2021 04:57 PM without the written consent of Pace Analytical Services,LLC. Page 25 of 31

Pace Analytical Services,LLC
1� °p119
2225 Riverside Dr
_ eAnaiyticai Asheville,NC 28804
www.pacalabs.com [phone]
l
QUALITY CONTROL DATA
Project: Lassonde Pappas C11482-01.01
Pace Project No.: 92569443
QC Batch: 656992 Analysis Method: SM 5310B-2014
QC Batch Method: SM 5310B-2014 Analysis Description: 5310B TOC
Laboratory: Pace Analytical Services-Asheville
Associated Lab Samples: 92569443001,92569443002,92569443003
METHOD BLANK: 3443954 Matrix: Water
Associated Lab Samples: 92569443001,92569443002,92569443003
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Total Organic Carbon mg/L ND 1.0 11/03/21 17:11 _ ...... ... _........W.---.....
LABORATORY CONTROL SAMPLE: 3443955
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
Total Organic Carbon mg/L 25 26.0 104 90-110
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 3443956 3443957
MS MSD
92569014001 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
Total Organic Carbon mg/L ND IT 25 25 26.8 27.3 106 108 90-110 2
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 3443958 3443959
MS MSD
92569014002 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
11 Total Organic Carbon mg/L ND 25 25 26.7 27.0 105 106 90-110 1
Results presented on this page are In the units indicated by the"Units"column except where an altemate unit is presented to the right of the result
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date: 11/04/2021 04:57 PM without the written consent of Pace Analytical Services,LLC. Page 26 of 31

�'
An 1 Pace Analytical Services,LLC
cl^�IQO 2225 Riverside Dr
I 1 l� I Asheville,NC 28804
www.pecelabs.com [phone]
QUALIFIERS
Project: Lassonde Pappas C11482-01.01
Pace Project No.: 92569443
DEFINITIONS
DF-Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND-Not Detected at or above adjusted reporting limit.
TNTC-Too Numerous To Count
J-Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL-Adjusted Method Detection Limit.
PQL-Practical Quantitation Limit.
RL-Reporting Limit-The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S-Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270.The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate%recovery and RPD values.
LCS(D)-Laboratory Control Sample(Duplicate)
MS(D)-Matrix Spike(Duplicate)
DUP-Sample Duplicate
RPD-Relative Percent Difference
NC-Not Calculable.
SG-Silica Gel-Clean-Up
U-Indicates the compound was analyzed for,but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Reported results are not rounded until the final step prior to reporting.Therefore,calculated parameters that are typically reported as
"Total"may vary slightly from the sum of the reported component parameters.
Pace Analytical is TNI accredited.Contact your Pace PM for the current list of accredited analytes.
TNI-The NELAC Institute.
ANALYTE QUALIFIERS
E Analyte concentration exceeded the calibration range.The reported result is estimated.
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample(LCS)recovery.
REPORT OF LABORATORY ANALYSIS
J This report shall not be reproduced,except in full,
Date: 11/04/2021 04:57 PM without the written consent of Pace Analytical Services,LLC. Page 27 of 31

Pace Analytical Services,LLC
7,,,xyaceA
co 2225 Riverside Dr.
nalXical Asheville,NC 28804
www.pacslabs.corn [phone]
l
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: Lassonde Pappas C11482-01.01
Pace Project No.: 92569443
Analytical
Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch
92569443001 MW-4 SM 6200B 656203
92569443002 MW-5 SM 6200B 656203
92569443003 MW-6 SM 6200B 656203
92569443004 TRIP BLANK SM 6200B 656203
92569443001 MW-4 SM 2540C-2015 656825
92569443002 MW-5 SM 2540C-2015 656825
92569443003 MW-6 SM 2540C-2015 656825
92569443001 MW-4 SM 9222D-2015 656990 SM 9222D-2015 656991
92569443002 MW-5 SM 9222D-2015 656990 SM 9222D-2015 656991
92569443003 MW-6 SM 9222D-2015 656990 SM 9222D-2015 656991
92569443001 MW-4 EPA 350.1 Rev 2.0 1993 656769
92569443002 MW-5 EPA 350.1 Rev 2.0 1993 656769
92569443003 MW-6 EPA 350.1 Rev 2.0 1993 656769
92569443001 MW-4 EPA 353.2 Rev 2.0 1993 656094
92569443002 MW-5 EPA 353.2 Rev 2.0 1993 656094
92569443003 MW-6 EPA 353.2 Rev 2.0 1993 656094
92569443001 MW-4 EPA 365.1 Rev 2.0 1993 657332 EPA 365.1 Rev 2.0 1993 657367
92569443002 MW-5 EPA 365.1 Rev 2.0 1993 657332 EPA 365.1 Rev 2.0 1993 657367
92569443003 MW-6 EPA 365.1 Rev 2.0 1993 657332 EPA 365.1 Rev 2.0 1993 657367
92569443001 MW-4 SM 4500-CI-E-2011 656672
92569443002 MW-5 SM 4500-CI-E-2011 656672
92569443003 MW-6 SM 4500-CI-E-2011 656672
92569443001 MW-4 SM 5310B-2014 656992
92569443002 MW-5 SM 5310B-2014 656992
92569443003 MW-6 SM 5310B-2014 656992
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:11/04/2021 04:57 PM without the written consent of Pace Analytical Services,LLC Page 28 of 31

Document Name: I Document Revised:October 28,2020
Sample Condition Upon Receipt(SCUR) Page 1 of 2
aceiltialytical Document No.: Issuing Authority:
p F CAR-C'S 033-Rev.07 Pace:Carolinas Quality Office
Laboratory receiving samples:
Asheville E] Eden❑ Greenwood❑ Huntersville❑ Raleigh❑ Mechanicsville❑ Atlanta❑ Kernersville❑
Sample Condition Client Name: 92569443
I
i1��,,,Uport Recelpt, ; .% � � u Project k
ie/?or �qLA of NC
Courier: ❑Fed Ex ❑UPS ❑USPSS 31Client 11111
1111111111111
❑Commercial Dare nth 2669443
Custody Seal Present? Dyes NNo Seals Intact? ❑Yes ©Nn
Date/Initials Person Examining Contents 1 a r /� u
rd "
Packing Material: DBubble Wrap QjBubble Bags ❑None ❑ Other Biological Tissue Frozen?
Thermometer: ❑Yes ❑No ON/A
r
at IR Gun ID: ! 3 T 7 1 Type of Ice: ®wet ❑Glue ❑None
c Correction Factor:
Cooler Temp: 5' Add/Subtract('C) Q Temp should be above freezing to 6'C
❑Samples out of temp criteria.Samples on ice,cooling process
Cooler Temp Corrected('C): has begun
USDA Regulated Soil(.Ej N/A,water sample)
Did samples originate in a quarantine zone within the United States:CA,NY,or SC(check maps)? Did samples originate from a foreign source{imt y atimriaiiy,
❑Yes , No Incliddiuig Hawaii and�l'rIrerte Rico)?❑Yes LAJ No
enis Discre Banc
Chain of Custody Present? tlYes brio Ori/A I—
Samples Arrived within ttold Time? j'""s... le ON,/rt 2,
Short Hold Time Analysis(c77 hr.,)? ,lye".... bl Neu _tuo,, 3.
Around Time Requested? Dyes _Bide ❑NIA 1 .4. .� mM_...__,!
..Rush Turn
�.._ ._.._._... _.._..._ .__ ....... �_....
Sufficient Volume? Cu Yes [inn NM S. _.
Correct Containers Used? Yes ON ON/A 6.
Pacer Containers.Used? , Yes ?o __❑N/A .�w_.....
Containers
ct? ,iny05 Ono
Dissolved analysis:Samples Field Filtered? Yes NI N/� 7 �
Y P ' _Des .
Sample Labels Match COC? ilses Die QN/A 9.
-Includes Oaten hne ID AnallsIs Ma iriv
9Uletuuispace in VOA Vials)>S.6mm)"? Dyes f rdwr 6 U/A 10,
Trip Blank Present? Des ❑No ®N/A 11,
Tri• Blank Custody Seals Present? )Yes Clive ( tddA -- ...._ . ._ _... . ...
COMMENTS/SAMPLE DISCREPANCY Field Data Required? Oyes ❑No
Lot ID p spout containers: „, ..._
CLIENT NOTIFICATION/RIESOLUTIDN
Person contacted: Date/lime: .,. ..._.,m_..
Project Manager SCURF Review: Date:
Project Manager SRF Review: Date:
..... Page 29 of 31

Document Name: Document Revised:October 28,2020
Sample Condition Upon Recelprl SCUri) Page 2 of 2
. r nalf tfca _ m._.
... " Document No.: Issuing AUthotity;
f F-CAR-CS-033-Rev.07 Pace Carolinas Quality Office
_. . _.
*Check mark top half of box If pH and/or dechlorination Is Project; W : 925693
verified and within the acceptance range for preservation
PMI WP Due Date: 11/04/21
samples, CLENT: 93-ALTAMONT
Exceptions;VOA,Coliform,TOC,Oil and Grease,DRO/8015(water)DOC,LLHg
**Bottom half of box is to list number of bottles
w _
z Z z L. O a G j Z m m 10
0 2 Z.
Z. N Z H Z a N = r a p j
a l I
v v '5 n 3 n a v a 2 -, I a z L I
a z
T x r 2 i' M T a Z i. -' I z -• H 1 ,
C4 I 'a :44 O O 4 0 m ` _ c 0 8 0 z p, Z V o a ,"'n N ' a r a
c C c n N z n C� °' 7 vi E N O rn 7 m f0 7 o c
7 7 r ry T Z .o c u A T Q v al n_ E. .A 7
u I u u n T u N 2 y 7 S T J U o c AA : Y y a) U al
u 4 U i. w y N E i 7 2 -R 11 = _ d 11 I 61
A m g ti m 2 2 v a -0 E .o I E p < Q Q Q d ' y ro E c -
E. a a 2 a a a a E E G E Q D I .9 Q O . A. in u" �- �c ,n E
E J J d J -J J J E Q q J d J IZ. J -, > J N .J E E E J
E o o m E d uEi VE v ? L w on tri Q o E y g vvEyyl Q a of o
'-1 N v�,� ry , 0 ,).i ,�., j -; .i rl �'S-+,1 rJ 0 q `f `f $ Y N IP dN a 7
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a a a a a l�7 l7 to l7 lm7 SD hD SD l�7 '', t�7 0 a d i t9 v>i SD
`B m m m m m m m m a a ¢ a a a l o > > o > > ei ei m a l v, Cl.
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, .,.41 ..\—\ N. \ 1\ Li 3
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5 \\
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L
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12
pH Adjustment Log for Preserved Samples
Sample ID Type of Preservative pH upon receipt Date preservation adjusted Time
re preservation Amount of Preservative Lot II
adjusted added
liters is a discrepancy affecting North Carolina compliance samples,a copyof this form will be sent to the North Carolina DEHNtt CnIrtalicatlon Office it
Note: Whenever � -_� ,a.
Out of hold,Incorrect preservative,out of temp,Incorrect containers.
Page 30 of 31

CHAIN-OF-CUSTODY/Analytical Request Document _
The Chain-of-Custody relevant
f-Custody is a LEGAL DOCUMENT.All relt fields must be completed accurately, c�
PaceAnalytical'
www.pacelabs.corn _----_ o ---
it
iii
En
Section A Section B Section C Page: of
Required Client Information: Required Project Information: Invoice Information: r/'� }(-'��
Company: Report 7 , - - ".�-. Attention: -- ----_- - - t-. 0 V 6 ...1 4+7
Address: CrpyTom °h- C)-14 Company Name:
3 +_ }kartr OCKI et . f, i1 1 4I. 1r_Litz
l REG1d A I O Y AGENCY
� [i 1 _£ ) � S.C . ti I ICI l I763 X NPDES GROUND WATER DRINKING WATER
'Email T .z r P e.Order riot `.ems tl,ran - P"
`'L UST RCRA rOTHER
'',1, t tit R�tn n
Phr -, r ox_ Pfc t Ads; ( Pie Project
at t A 4 li t J Site L ca ion
Requested Due Date/TAT: Pry- t*,mb r 1 Pace Prose z' _
I Li g — `I = t STATE:
Requested Analysis Filtered(YIN)
Section D Matrix Codes =
a
Required Client Information r T€�a co— a o ---- COLLECTED ---. Preservatives 5--
-
Drinking Water OW m o p s ---- -----_.-.
Water WT 8
U COMPOSITE COMPOSITE F- D 2-
Product Waste Water WWc tD START ENOfGRAB J �I P.
m ¢
Sotl;+Sals[I St w 0 O y,
SAMPLE ID �? [ QWipe WP W "_ J '
(A Z 0-9/.-) AO AR p w a Q s -
Sample IDs MUST BE UNIQUE Tissue TS 0 a r H m UO 0
ORes f T (/'�� -
x lL w O 92' O >, s-3 �•.a RS
1t Fr J J U
0
W ¢ ¢ O n - OZ U O� m - Q lL l m I '�T I-/ _ --
F- co DATE TIME DATE TIME co S 0 Z:.I I Z Z O y d Er Pace Pro} No./Lab I-D.
1 NNW ' \ WI C1 i. lOtallii l►3UI. IR.` K ) X x, I L.
2 P - wZ el ' y_ ' 3i3 1 i x. K X )qX X, X X, X, 7C
3 nA - -l Cat, IM 151 i V K K 1 = .I X X _
4 t ►e t? �r 4 OO „ CI : A X
5 C
61 I I I 1 j
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9
10 [ s
11
-
12 I � ` — -
ADDITIONAL COMMENTS RELINQUISHED BY I AFFILIATION DATE TIME ACCEPTED BY I AFFILIATION DATE TIME SAMPLE CONDmONS
t4
-tom tl;j ,M i ;6 ' g,i i :4e' --"t /0-2171 iLi5` Y
oil 1
I j _
SAMPLER NAME AND SIGNATURE v _
z o
ORIGINAL
PRINT Name of SAMPLER: Y B c^
�z
0 t
DATE Signed F m ` 0
I- r
' U E
SIGNATURE of SAMPLER: to n
(MMIDD/YY):
'Impnrtanl Nate•By::inning this form you am accepting Pace's NET 30 day paymanl terms and egrraing to Into chargutr of 1.5%per month for any invoices not paid within 30 days. F-ALL-Q-020rev.07,15-May-2007

Attachment 2
Well Sampling Logs and Instrument
Calibration Data Sheet

ik,ZANCHOR Anchor QEA of North Carolina,PLLC
QEA Ro-rk..' 231 Haywood Street
Asheville,North Carolina 28801
ow-Flow Sampling Log 'Elk II ID: 44,LiQ— p �. ..�
Project Name: Lot6 54,AJ '.+",f e,t Date: 1,01",..1:,312 Z.".. I , y( ` '", i't„,,i 1° ;I
11
Project Number : 01
Project Location: It to) ° v: i( i Facility ID or Permit ft(if applicable): $ pf 7cI
Sample Collectors) „p. .,. ,....., Sample ID(on COC): 4
Well Diameter: %1 in Arrive at Well: t 0
Screen Interval: ft bgs Start Time: ))1.1
Well Depth(as constructed) ft bgs Sample Time: "
Depth to Water �)y 1 i ... e.
P w g "'Y ft Leave Well: 11.1
MeasuringPoint: 1 �
p C:, Well Type. lick Up oFlush Mount
Depth of Pump Intake: ft lagged Bottom: "& ft at(time): 1 1, q fj
P Pump Used(circle): tist:aitl Bladder Other(describe): Purge Rate:
Comments 1 .,.. .. � _ 1,a" l t 3 4' Al 1,0� ) 4w a ,,,,,TotalV Pump Speed: ,,. .,,
'
„ 411,
Specific Oxidation
Dissolved Oxygen Conductivity pH S ,) Reduction
yy Tiime DTW(feet) I Temperature(°C) (mg/L) (Nmhos/cm) report to 0.1 S.U. Potential(mV) Turbidity(NW)
i
0
�1 .I ci•A i ,I. . . (,. 1 il, , . . $• I-ro , 5�
1t 'WI-I- ,)
It 4 - g,T -_ Itf , t.� '2 ' '1 i 9.-i 'w wp .4 ;',L
1, tt 6t liprl °� , 1 ! � � r�le, 1)
),,a 61. , ' ,7
tt I Ll , • , '3 ,
I 1
µ
I
i
i
Sample Analyst
Sample Analyst Signature. Name Q ViitaN Date: I oI a i
Notes:
1:Stabilization(3 successive readings,3 minutes apart):within+/-10%DO and ld::,ridiay„ +/-3%Conductivity, +/-0.1 pH unit; +/-70 mV for ORP
from EPA-Low-Flow(Minimal Drawdown)Groundwater Sampling Procedures,April 1996(Rev 2017)
2.Documentation errors are to be crossed out with a single line,so the original text is still legible,followed by the staff members initials and date
3.Samples are analyzed immediately upon collection.
4.NC Field Laboratory Certificate Number 5445
5.1 pmho/cm=1 pS/cm
Abbreviations: Method Reference:
'C:degrees Celsius S.U.:standard units Temperature:SM 2550 B-2010
pmhos/cm:micromhos per centimeter ft:feet Specific conductivity:EPA Method 120.1,Rev.1982
mg/L•milligrams per liter in:inches DO:SM 4500 0 G-2011
mV:millivolt bgs:below ground surface pH:SM 4500-H'B-2011
NTU:nephelometric turbidity units TOC:top of casing Turbidity.SM 2130 B-2011
wy: r } r ':a tr. M ( }
. ` n
O .J
6 fdh p � l. fi
1� � 1
�°cp w� � r i!h ') � ti 62rL �'d� 1 c .'�*'w.e° � - ` "" � Y! <„,t�v/e� ✓"'/ :Gt (,t.br,_.<T'd
\ zAn r - if) c \ 19) \
Page 1 of 1

ANCHOR Anchor QEA of North Carolina,PLLC
( A 231 Haywood Street
Asheville, North Carolina 28801
..aw-Flow Sampling Log WeD ID:,. 61,,_,5_"
Project Name: s..",,arrf yd.„e wri„5 Date: to f,A,7/-2 6 q
j �(
�r dl,
Project Number o ). 0, 1 ,.6,. 9
� �� of 1 k/°(f/ NCFacility (ifapplicable):Weather: � 1
Project Location: � ID or Permit# a Ircable), 1 f ref ,
Sample Collector(s): K.p 5G Sample ID(on COO): Lk/—
Well Diameter: in fil . ......
Arrive at Well: ik
Screen Interval: q (c( ftbgs Start Time: L )
Well Depth(as constructed): 1`i ft bgs Sample Time:
Depth to Water: r llft Leave Well; p
Measuring Point: ate Well Type: *tick Up oFlush Mount
Depth of Pump Intake._. es^ ., ft Tagged Bottom: ). _- C _ft at(time): it 2_,,,,,,,,,'L
Pump Used(circle): 4112DBladder Other'describe): Purge Rate: r°(;
Cornments )t 11V_� lbwp � dY
_ 1,. .fl., a .,,�J.k
at k V Pump Speed: . t t b tom+ , .
Specific Oxidation
Dissolved Oxygen Conductivity pH(LU.) Reduction
Time _,/, DTW(feet) j Temperature CC) (mg/L) (pmhos/cm) report to 0.1 S.U. Potential(mV) Turbidity(NTU)
i5 01 t (r.) Cl, 1 ci Li-, r t t 1 4D,
I
-
Sample Analyst
Sample Analyst Signature i � Name: N , P
distil . Date: m� � �
Notes:
1:Stabilization(3 successive readings,3 minutes apart):within+/-10%DO and turbidity, +/3%Conductivity, +/-0.1 pH unit; +/- 10 mV for ORP I 4. ji✓,$
from EPA-Low-Flow(Minimal Drawdown)Groundwater Sampling Procedures,April 1996(Rev 2017) 1 i
2.Documentation errors are to be crossed out with a single line,so the original text is still legible,followed by the staff members initials and date 7 ,
3 Samples are analyzed immediately upon collection.
4 NC Field Laboratory Certificate Number 5445
5. 1 pmho/cm=1 yS/cm
Abbreviations Method Reference:
'C:degrees Celsius S.U.:standard units Temperature:SM 2550 B-2010
pmhos/cm:micromhos per centimeter ft:feet Specific conductivity:EPA Method 1201,Rev.1982
mg/L:milligrams per liter in:inches DO:SM 4500 0 G-2011
mV:millivolt bgs:below ground surface pH:SM 4500-H'13-2011
NTU:nephelometric turbidity units TOC:top of casing Turbidity:SM 2130 8-2011
.,.t'�ti°�r " L\ z: 'cA. )
i r i - }(
K .,* s" 1� K r:.t ,u'
,� ,.�,,. h iti i)h , .vim . � /, ,. .
\..A.a al p 'l f 5 . "e k30 3
Page 1 of 1

INZANCHOR Anchor QEA of North Carolina,PLLC
QEA c.. '' 231 Haywood Street
Asheville,North Carolina 28801
ow-Flow Sampling Log Well tO 1 i--E
.e,. R
il Project NaZ.me: �,.,. .,.. ar � ��I ��, ��" � � M
Project Number. (�I "t �+—Of 0l rn Weather. 1_ 4 of (Ail ( 1,1 L "
Project Location: Tt,,11 c,,,, s,, 1v (t Gf /Vc Facility ID or Permit#(if applicable): ^�'( r`f 7 c(7
....
Sample Collector(s):p (s) 1{.t7 'cZ. Sample ID(on COC): /l^,y,—6r
Well Diameter g, in Arrive at Well: 6(11 tr"
Screen Interval: 4t ._l C) ft bgs Start Time; pci H.,"
Well Depth(as constructed): ID ft bgs Sample lime: M Ci )19
. ,
Depth to Water: SoAlkk ft Leave Well: (c ,, NX
Measuring Point. Ti„?‘ Well Type:'7'&rik Up ❑Flush Mount
Depth of Pump Intake: ft T'UG Tagged Bottom I ft at(time): 0 1
Commens: (describe): Purge Rate: v t 1 i
rt
y ( 1
Pump Used(circle): � Psfalt ""� Bladder ��. Other t �'�„.. �u"t �l'��( �� � 141�Total Volume Purged;
Pump Speed: 4, 'i—
Specific Oxidation
Dissolved Oxygen Conductivity pHl( .U.) Reduction
Time DTW(feet) Temperature et) (mglL) (pmhos/cm) report to 0.7 S.U. 1 Potential(mV) I Turbidity(NTU)
01 Lf,1 Ii; , (s) I , .- ' "3: I iCl,, -. 3. [), , �--9_. 2 . 19
( ,, ,
3.
� J, 4 � et „
e
I DI
l-- C«
r e�
,r t t
$ tt-. ( .
w
y Sample Analyst {
Sample Analyst Signature. � � * + �p Name: , presst et,i Date:ff kR
Notes:
1:Stabilization(3 successive readings,3 minutes apart):within+/-70%DO and to';:h ihtyr; +/-3%Conductivity; +/-0.7 pH unit; +/-10 mV for ORP
from EPA-Low-Flow(Minimal Drawdown)Groundwater Sampling Procedures,April 1996(Rev 2017)
2.Documentation errors are to be crossed out with a single line,so the original text is still legible,followed by the staff members initials and date
3.Samples are analyzed Immediately upon collection.
4.NC Field Laboratory Certificate Number 5445
5. 1 umho/cm=1 uS/cm
Abbreviations: Method Reference:
'C:degrees Celsius S.U.:standard units Temperature:SM 2550 B-2010
pmhos/cm:micromhos per centimeter ft:feet Specific conductivity:EPA Method 120.1,Rev.1932
mg/L:milligrams per liter in:inches DO:SM 4500 O G-2011
mV:millivolt bgs:below ground surface pH:SM 4500-H-B-2011
NTU:nephelometric turbidity units TOC:top of casing Turbidity SM 2130 B-2011
11acM r 0-r-5 ® 0a5 -
10(c) 1-v appmvtd S� .1( 4)I idiwii j6‘ 'fi oldide I0"!a e
1c .1 yta oli r
U 1 rt�! s t��
ti rr r.
We ,o gee)be. d An,, (_,\., 10rcZJ,t ...o Page 1 of 1
l v�Ci, i L�� sp `sue het\ t7 C ryv2M,Sv.f'Gt/� :f C.=A(« (, a't) t `‘ 1 rr.

ANCHOR Anchor QEA of North Carolina,PLLC
QEA u 231 Haywood Street
Asheville,North Carolina 28801
ow-Flow Sampling Log Well ID: ilk tA)--7 R
Project Name �t�.� t 6-"� �1,-, ,1.i'Z.)
Project Number. Weather. y u+t _ g
���,r ^w � � a � _ e1
Date: /
Project Location: L; A 3 r „r tlC / r Facility ID or Permit;'1(if applicable):WO. ,1 1,.-1 7u
Sample Collector(s): " .,? 54 Sample ID(on COC). / ,H r,a ct,
Well Diameter •.3., in Arrive at Well: w , ) °1 ,(
Screen Interval: 5--1 ft bgs StartTime: I 1 ( r ..
Well Depth(as constructed): I .'''1 ft ft bgs Sample lime s, 14
Depth to Water. "i,' ,, 1 1a k. ft Leave Well:
Measuring Point: Well Type: ^�tlaf Up cFlush Mount
Depth of Pump Intake: i ft Tagged Bottom: ft at(time): i , O t
1r
cube) Purge Rate:Z.2) "1, „ r
-. . I '�, ,d�..,
dL � i I@:)tlrota�(des , jr , � „„t,4 � ' Total Volume Purged:
Pump UComsed(ments: rtcircle); �t� Bladder �
jitAgi
Pump p 5 eed: (' J)
_
w 1 Speri °
is —
.. .. Oxidation
I,_2 Dissolved Oxygen Conductivity p (S.U.) Reduction
Time Temperatuie(C) (mg/L) (pmhos/cm) report to 0.1 S.U. Potential(mV) Turbidity(NTU)
— _,
it,x) 1t, 7 „,,, f •-: q 3, (I'll 7.1,S— 3, Y 373 -0 I # t r S.
1 IA5.r ill•?,Z 1 7, . S 3, 3 3' •56
1 i t 11,7- tp. i Z.ci 1 3 301..b f a 5: 3((. 7.r e2
li3` 1L73 16 !r0 ),- Y 3- 7, ` . 3 3zz...6 3, -77
It a"� I I,73 ` . el
2 . 75" s 1.f 32'i.'f "7
11° 0 11.`7 S i o 4v 3 5-1,0 ' 412.,' 32-1 • i �4/
/III 11.72) l 6,0 2, ; 7 3'-4`./. F 'i .<3 1 .3 t-I. i ., 54
u�m
I
Sample Analyst
ggl� yy� i
P AnalystSignature: '• / ..i rt,to Name• *" I y mf e p c l0 1 Date: /�
Sample '
Notes: r )
1:Stabilization(3 successive readings,3 minutes apart):within+/-1056 DO and turbidity; +/396 Conductivity; +/.0.1 pH unit; +/-10 mV for ORP 0) , " % d,,)
from EPA-Low-Flow(Minimal Drawdown)Groundwater Sampling Procedures,April 1996(Rev 2017)
2,Documentation errors am to be crossed out with a single line,so the original text is still legible,followed by the staff members Initials and date i ~
3 Samples are analyzed Immediately upon collection.
4 NC Field Laboratory Certificate Number 5445
5. 1 umho/cm=1 p5/cm
Abbrevlatlons: Method Reference:
'C:degrees Celsius S.U.:standard units Temperature:SM 2550 8-2010
umhos/cm:micromhos per centimeter ft:feet Specific conductivity:EPA Method 120.1,Rev.1982
mg/L•milligrams per liter in:Inches DO:SM 4500 O G-2011
my:millivolt bgs:below ground surface pH:SM 4500-H'B-2011
NTU:nephelometric turbidity units TOC:top of casing Turbidity:SM 2130 B-2011
ki,A_ re1 ,5 , 5
v
e ( o T VC r e in c) ,ir.�1 S 0\ rt.
e S �`�� f r S
` '\--ko�V1 i `i'iyt, I-". la 1l' t^"Ct5 rvVJL'.t,5,.�r`ecA. vL/- C`'L t r jcM +"r Vl
��-(} l Page 1 of 1
\5c -F ' pC) O1

ANCHOR Anchor QEA of North Carolina,PLLC
QEA e 231 Haywood Street
Asheville,North Carolina 28801
.ow-Flow Sarttplitt Log Well ID: ,fir LA)'
Project Name: .9„*,rat.a' r,n �e t1 ^T,"". ....,...... Date: it'd/,,1 T/2 c �t...,
Project Number, t r Ta cs r1l` Facility (ifapplicable): fl_ r l , h 1 M
Weather
Project Location: ( ID or Permit# a licable x y v t>&"^ r c +�
Sample Collector(s) ^ ,„ Sample ID Ion COC): /11,1,v
r
Well Diameter: in Arrive at Well: 0 , �j ,
Screen Interval:
. t3 ft bgs Start Time: Qq 4/
Well Depth(as constructed): t ft bgs Sample Time: /ti2..s
Depth to Water. 1p.06 ft Leave Weil: t o3,3
m,. �.,.... ,x-
Measuring Point: T Well Type: 'Ji tick Up ❑Flush Mount
Depth of Pump Intake: t 2,,,. ft Tagged Bottom: t I 4 ft at(time): 04( 2,
Pump Used(circle): evktstilt , Bladder Other(describe): Purge Rate: l ("'"` ki1
Comments: ro, e ' .,..,,.,. ,,. . or u e L t ,.,0 ci aLt I. Total Volume Purged: ..
Pump Speed: a rJx7i
Specific Oxidation
Dissolved Oxygen Conductivity pl-(S.U.) Reduction
Time DTW(feet) Temperature("C) (ttlg/L) (pmhoslcm) report to 0,7 S.U. Potential(mV) Turbidity(Nil))
1) 1 Ll
r ° tI 13 . . 1 4t.' L , 1, SW
� , �' -{ '--191(7' l t, 1—
10 c e, s 6. 1 " I i 5r r f, it
1
M 1p pp 9 � � }°^) rnwn.r.
1 J
ito rtbri ---, C 1, —rt 01 ---4--
, .,. tc-,„ 'nil 1 f,-- tcio
•
t . . ' � .,° c (�" 4-3— , i t i;
w�, C ,1 , )117e
t) 1 ) lo,o is--,3 . , 1' - C> ., . t ,Y. o I 7- c
„ '� .� 1+
f
/ Sample Analyst {^�
Sample Analyst Signature: °w„, I °' 4„„ A, Name: �i ��J J 1 Data ; )k
N
Notes: d
1:Stabilization(3 successive readings,3 minutes apart):within+/-10%DO and turbidity, +/-3%Conductivity,' +/-0.1 pH unit +/-10 mV for ORP f c I
from EPA-Low-Flow(Minimal Drawdown)Groundwater Sampling Procedures,April 1996(Rev 2017)
2.Documentation errors are to be crossed out with a single line,so the original text is still legible,followed by the staff members initials and date _
3.Samples are analyzed immediately upon collection. 1,,,, „J
4 NC Field Laboratory Certificate Number 5445
5. 1 pmho/cm=1 pS/cm
Abbreviations: Method Reference:
°C degrees Celsius S.U.:standard units Temperature:SM 2550 B-2010
pmhos/cm:micromhos per centimeter ft:Feet Specific conductivity:EPA Method 1201,Rev.1982
mg/L:milligrams per liter in:inches DO:SM 4500 0 G-2011
mV:millivolt bgs:below ground surface pH:SM 4500-H'B-2011
NTU:nephelometric turbidity units TOC:top of casing Turbidity:SM 2130 B-2011
1 ,i4,4c.44,jc\. Ft t:7I— it--te&r.JC . -7" 6... 6
t1_ [` L N v�i,.-1{� i + i`', ' 1 Ir 'II, ) tl�1j.. I[.,, 1I (,.y�1 r��
S �.], V t ,4\T 0 A. , l r J\Ct p 1 4 �a Ira....£_rst.�-reel , / C.dt `, U.,q. :c:..t l 1�1{-. •\ `�" l t✓'
1 Page 1 of 1
1�( bQ

ANCHOR Anchor QEA of North Carolina,PLLC
QEA`....,•,J 231 Haywood Street
Asheville,North Carolina 28801
ow-Flow Sampling Log �Wei1 lD „,,i,f l.L/--dam' —,
"
Project Name o qi W '„ m, '^rgyp ." Date:„ ( / „ f�dz I I
i 1.�55
Project Number C.w \. O Weather: ' c ' ,ti- ,r.' / /r f raw 4 L /,8 1
Project Location k,°si, ,t �l r"Sr„�r, y;0k.,Aft." Facility ID or Permit#(if applicable): N &,:1'`E Cleo w^ 7'[ 7
Sample Collectors) ii„. SC. Sample ID(on COC): •44,w-.L 41,
d,
Well Diameter: in Arrive at Well: , ." n
w ..
Screen Interval: wl- t Z. ft bgs Start Time: a,,/,.1 „�j i r�� f""
._-gyp -«+....
Well Depth(as constructed): ft bgs Sample Time: i 0,1 i... ,
Depth to Water C rZ. ft Leave Well:
Measuring Point: 'IC)C-- Well Type: oStick Up ❑Flush Mount
p Other t1 '� �� at(time): m Vi�,
Depth of PumpIntake ft Tagged Bottom: (G x (1
PumpUsed(circle): Penstaltic Bladder ° ( � d`se' Purge Fiate:"`'1 iU r� (.
Comment: �� i , d�„ Total Volume Purged:
m,.. ,,V ,... . ,-- d,fn �(, ''r r ,vs ._� . . w , Pump Speed: 1 t i„.
Specific 22.. At fQ• OxIdat)on
e.
11
Dissolved Oxygen Conductivity pH(S.U.) Reduction
Time D11W(feet) Temperature CC) (mg/L) (pmhos/cm) report to 0.7 S.U. I, Potential(my) 1 Turbidity(NTU)
RE) d
t.2_5 i 7, .c f . 7i, � S' `, 6 1 , '
12 3,1 *-- f -_-4 x . S �0
y ,
a i 1 m (,,,f r f • t- f , z Li` • 6 i �t h 4 ., i gyre,''`
1
1 Sample Analyst
P � C 4c� P � i 1 Name: .r e V U Date:
Sample Analyst Signature: ��� ��3 �� i(
1:Stabilization(3 successive readings,3 minutes apart):within+/-10%DO and turbidity; +/ 3'��" 'anductiviiyd +%0.1 pH unit• +/-10 mV for ORP ( 1,11202
from EPA-Low-Flow(Minimal Drawdown)Groundwater Sampling Procedures,April 1996(Rev 2017)
3.Sam Bee to analyzed immediate upon cutl a n followed by the stuff me inlliala and date _...
2.Documentation errors are to be crossed out with a single line,so the original text is still legible, p �f'
p z hr— & ,�= 9, d ° �;r v I 4 r1
4.NC Field Laboratn Certflcate Number 5445 1 ;"1 s
Abbreviation 1
p5/cnw 4,,„,mr "r° t "
l i 4,5
Method 1taXaracrteo /
'C:degrees Celsius S.U.:standard units Tempereunre:SM 2530 B,.2010 M C �t `. l�.ti ,c
pmhos/cm:micromhos per centimeter ft:feet Specific conductivity:EPA Method 120.1,Rev.1902 {I
'... mg/L milligrams per liter in:inches DO:SM 4500 0 G-2011 (J'C- 1 1.k 1 I (0
mV:millivolt bgs:below ground surface pH:SM 4500-H-B-2011
NTU:nephelometric turbidity units TOC:top of casing Turbidity:SM 2130 B-2011
` (\e“tt/`r `''(-
t 7 f hik d 4,. r�i1 t /r� ,„ �r °
r
P <j• I �;,, , " 1w' /'h d ' , ,,,,,;(4,,, &..i i it) 1'w ,&.�. ���q& ,
11A i5 ,
In� „�, 4 ,Q ��y ",��... � Page 1 of 1

k ANCHOR Anchor QEA of North Carolina,PLLC
QE A ,.u. 231 Haywood Street
a.u✓
Asheville,North Carolina 28801
Surface Water Sampling Log �l!ot,cati n ID: )-"
w
Project Name: 1. u630ed p.,t ,,,t.y Date: 10f?-7/l- Z C, (,
Project Number: G((i-(a -n.01 Weather:
Project Location: 4t./,,ct„is OiNv (tt, /VC Facility ID or Permit#(if applicable): IW '7 4 !"
Sample Collectors) r c Sample ID(on COC): (��(
1 Comments: a ""dtet 4 I-'`D'"'N-
1 Sample Method(circle
ra Syringe Pump Bailer-Disp. Other:
one):
Specific Oxidation
Temperature Dissolved Conductivity pH(S.U.) Reduction Turbidity
Time ('C) Oxygen(mg/L) (pmhos/cm) report to DJ S.U. Potential(mV) (NTU) Comments
y1 yj`{y 1 }fly
Sampling Container Number of Containers Requested Analysis
500 mL Plastic c '
250 mL Plastic , a 1e�.)�: f
1 ( q �� li„G. . ..�. C f�""
4,„ �. "�
125 mL Plastic g pp r.
40 mL Glass r :L
1 L Glass
Other
Vegetation: Access: B end')
c, Sample Analyst
SampleAnalyst ' �� -
Name: " Py Sc (f.,( ate R rj 1(1 ^ L _
Notes: p
1.Documentation errors are to be crossed out with a single line,so the oriainal At is still leaible,followed by the staff members initials and date 12 7 q( .,
2.Samples are analyzed immediatelyupon collection.
P ML P `
3.NC Field Laboratory Certificate Number 5445 'r--" "
Abbreviations: Method Reference:
'C:degrees Celsius Temperature:SM 2550 B-2010
pmhos/cm:micromhos per centimeter Specific conductivity:EPA Method 120.1,Rev.1982
mg/L milligrams per liter DO:SM 4500 0 G-2011
mV:millivolt pH:SM 4500-H'B-2011
NTU:nephelometricturbidity units Turbidity:SM 2130 B-2011
S.U.:standard units
sic. ,‘-a "v - `L �- ° 0
Yµ \-c c,,t,, „ r,e 4 1 L Ty n c'\c\t,
i
p \
�� Vn< 5' G c1 ,� fct c u
jlv CA
Page 1 of 1

ANCHOR
Anchor QEA of North Carolina,PLLC
QEA(....4...4...."
4......4...4....,
231 Haywood Street
Aheville,.North Carolina 28801
e. .. 1
Surface Water Sampling Log I
Location ID: utdi)--2....
Project Name: t,et 5 so A JR_ p Date: Lo1)..7/toz/
( i
Project Number. (,,,((r-f 61_pi_0 ( Weather
Project Location: H t 06,-.50 v i re A/C Facility ID or Permit#(if applicable) 1/42C.,m kt 7.ci r
.4 „. .
Sample Collector(s): I( '' i S t Sample ID(on COQ SLid,r- i., •_
r Comments: t , 4-peo.4,„, l,K 4,.i „)) „y,ci ,,,,i/
.. .
, w4
Sample Method(circle all
one): Syringe Pump Bailer-Disp. Other
1
Specific ' Oxidation
Temperature Dissolved Conductivity pH(S.U.) Reduction Turbidity
I Time J (C) Oxygen(ing S.U. Potential CrnV) (NTU) Comments
/L) (pmirs/cm) report to 0.1 I— —
•//'•
cr14-4 1 1),-; 1 )) l 1 -1 ,
, ..,... .4
Sampling Container Number of Containers Requested Analysis
, 1
500 mL Plastic ,,,m,—b>
'a
250 mL Plastic
a.125 te if
0 Cti Ar, ',, 1(4e. I; (
40 mL Glass
1 L Glass
Other
, .
Vegetation: gc&0c•tr_s
Access: 0 [C.,
r
•!'
Sample Analyst c.. t /7 t i Sample Analyst Signature: t - 'Z._ ----- Date:
netes.1
1.Documentation errors are to be crossed out with a amble line,so the orioinal text is still leaible,followed by the staff members initials and date
2.Samples are analyzed immediately upon collection
3.NC Field Laboratory Certificate Number 5445
Abbreviations:
Method Reference: "'"iMk Vr)CAel O ),C 11 t
C.degrees Celsius
Temperature:SM 2550 B-2010 gmhos/cm:micromhos per centimeter Specific conductivity:EPA Method 120.1,Rev.1982 El b i CLAA-1:ic: e
4 4. O ' V
mg/I:milligrams per liter DO:SM 4500 0 G-2011
i
ht V i, 1 A
mV:millivolt
pH:SM 4500-H*B-2011
NTU:nephelometric turbidity units Turbidity:SM 2130 B-2011
S.U.:standard units
Page 1 of 1
1

ANCHOR Anchor QEA of North Carolina,PLLC
QEA �v 4..-9...4..i 231 Haywood Street
Asheville,North Carolina 28801
c w'(pfent Documentation and Instrument Calibration Data Sheet
Project Name; i ) w Analyst Conducting Calibration:
Pro act Number. N r Date of Calibration: ' r ,;,
J
Project Location: +" i Date of Field Measurements:
Facili4y ID or Permit I(if aai:plsrutlo):'' Q 1 F f') ,._. ... _..
SQURPMENT DOCUMENTATION
Rental sarinple analysis equipment or meters used to take measurements:
1 Equipment Type Brand Sellal Number Date of Use Rental Company '
41-1,t'i[t'lfEll lel r I1 , ` ,. z V .nn,v f t'‘,
Select Turbld1nmeter. X., 1 Hach 21000(s/n 151006045207)
HF Scientific MicroTPW(s/n 20 0 601 04 5)
Instrument Readings Instrument Readings
(Hach 2100Q) (HP Scientific MIeroTP1N)
NTU NTU 1,000 NTU 10.0 NTU 0.02 NTU
Cal Std lnfarrtatl�f1 10 NTU - 20 NTU 100 BOO
L
1 4'1
,—. .
Radon Date
I Cal(NTU[, Cal(N TAU.n Cal aft Cal(NTU): Cal(NTU): Cal(N
c''( I U l '6,00
Time: Time: . Time: Time: Time:
lr"7 1.- fit(P 4 0(.
�gbwti 'Pre-Analyse Result(NTU): Time: me:
Re U): Time:
Veeiflcsdon.Check(10 NTU): l o - I Q 1, +� Check(10 NTU,),..,
• s U)' Time: °P'ost-Arpsis Result(NTU): Time:
PChedt(10 NdTU): Res�rlq(PST 1 kl ( R"g 10 N1U)r: �..
TSSI Professfonal Plus Mu-ltiparameter Ma^t'elr Is/n 1f b109502)
Cal 5td Information
Instrument Readings Loth Date.
Exp.Date•aced
Dissolved Oxygen Inllial06) Cal( ) mmHg: Temperature C)
(%wtundo) la (Li J
DO(Site 112, Initial(%): Cal(%): mmHg: Temperature CC):
N applicable).
l QC"Ch•dc DO Dine /1LI 1 Result Ls): f k Time twio" Rawly) r•, iResult(%):
pH75.U. illy! pHmV: /J�� Cal(S.U.): pHmV: i
i re••rtto0.1ill ,1 � " la 1p V f I 1- ,.D bell
Zl1 r
PH 4 S.U. iti-• p Cal(S.U.)' i)>HrrW' I Time:
11111111. s (� n
report to O.T S. . ran,�,a1nt.:.. s of
p pH : Time: I� I
,. .r Time:_t t Resul ( 1, Time:0) ,,,/ Result l u i.): a :«I lime:
,J •
;Result(S.UJ: � III +�7
P� erI_ - IHS11 �f =I * ai13111!a
,f o 3Spec Cond. , 1.
Initial: A Cal(P tioslcm): 'Time: , '1.--ell 0l f 1 f 4j n,
• Result(pmhosdcml. Time: Result(ilmhos/cm): Time: Result(ilmhos/cm): 4
.' ra, ! ' I' Ili 51 Got? �r ct I�2 0 23I
%Recovery. --. ! L.
Initial: Cal: iem nature°C): "time:
/� e� i /-1 1 q
ORP 200 my 110D, (r � 1`1-,.� 1F (Of (....,�14
Analyst Signature: r " }} , ,*))Lifl W Anal sit Name: ) Date:
Note. 1
Revision 6,12/20/20,MAK
1 Instruments shall be calibrated In accordance with the manufacturer's operation manual.
2 Specific Conductivity should be calibrated according to values representative of historic range
3.Order of Calibration is as follows:Specific Conductivity,pH 7,pH 4,pH 10,00,ORP,oC checks.
4.`When performing DO analyses at multiple sample sites(i.e.project/facility locations),the 00 probe must be calibrated at each sample site prior to analysis.
S.QC Acceptable Ranges:pH r/-0.1 5.U.and Specific Conductivity 10%of the hue value.If QC readings are out of range,the instrument needs to be recall brrated.
6.•-OC check must be performed prior to sampling and following completion of sampling,at a minimum.QC checks must be performed with callbrarlon statcSard from a separate lots as the initial QC
7.%Recovery=(Value Obtained,pmhos/cm r True Value,pmhos/mn)a 1DO
B.NC field Laboratory Certificate Number 5445
9.Documentation errors are to be crossed out with a single line,so the original teat is still legible,fo lowed hythe staff members initials and date
10.Unless otherwise noted,all DO calibrations and measurements are performed at 0 ppt Salinity.
11.1 bmno/cm=1 p5/rrn
Abbreviations: Method Reference:
tamhos/cm:micrombos per centimeter NTU:nephelometnc turbidity units Temperature SM 2550 0-2010
':degrees Celsius ORP:oxidation reduction potential Specific conductivity EPA Method 120.1,Rev 1902
DO:dissolved oxygen sin:serial number DO:5M 4500 0 G-2011
mg/14 Milligrams per liter S.U.:standard units pH:5M 4500•H'B-2011
mV:millivolt Spec.Coed:Spedfic Conductivity Turbidity.SM 2130 B-2011
CD 1%4{ Cif E.A 14 e U 1 f ,C )II WA-CA.- Page 1 of 1

3ci- R J
5L#_ Pr f. „ 9p- f p� co-a . Q fc t ed
OD e1r p re d 3 pi- 04 cliQ . Cu 'failed •
oIa►0
1 a y -o lti Attexnptcli P t au . Cal) Kacci .
® - ► F\Wompi.ec I Pi- ectP on f i 1 . u c.0 eS S .
Ki;#-C,nii red not mi. bin pH 4. ec i to .
)161 a red pH r° to defctidt eas - iktitfr Pt-d
s p CCU . S uLctss EuQ

ANCHOR Anchor QEA of North Carolina,PLLC
Q1[ 4.'t"'.1-.." 231 Haywood Street
Project Name. e Site ( ) Ashe
ville,North Carolina 28801
Project Number. gDir01a» "" Analyst Conducting Calibration 9.1,��..
EI rat melt DocumentationratiDra Data
) °.�
a � ,. _ ,.. Date of G,.udd..:rallor � IQ 864),Al ....,..�Project Location: 0"` ° ° v
r � � zfi.of Fled Measurements: ,�uys� �),
Facility ID or Permit e.(if apialieayike) i,,j L.' i ( L i k ,., �,. uI
I EQUIPMENT DOCUMENTATION
-..
Rental sample onalyia eaqu➢pnieait or meters used to take measurements:
wEqulPneMTy e Brand Serial NumberDelta(
Ga t tt pa" 1 ammo Co r
� , ' 1a '--�� —
Select'Tueb➢dirncateer 7 Hach 21000!sin 151006045207) -..
I HF Scientific MicroTPW(s/n 20060104S)
iraatrur+wazra4 Fleaw2ifny➢e IMAM Readings
(Mach 21000,1 (HP Scientific Micro11,00
GI Sid Information NTU B00 hi T1i rm 1tl NTU 20 NTU i,000 N'rn lot)Mittp.02 HTU
""� IµM1 'r� Ia �wil.f ' ""'C E.xpimaEtaru Wag' N. 'eti I n i- ).w® I d 11,4 Jwp1' Cal(N U): Cal(NTU): Cal . .
o .---
taVl4UI y
TI cal
,�. . 9 ( � II n? ,r pT k I N R th
rune
I_.. ep N rc5 Time: T¢na Time: -....
CaiibraUon ePec Analya➢s Rnr.il'k, Tl kl Time: ... 'Pre-Analysis •11
's ^^"""�
Chedt t0 yd Reatglq t IT'ii Time:
Varifiaatlon. ( N Ttrtl): � ) ».. . Check(10 NTU)•.a�^"''�
''Ptart-aaaa(ysla ITI•sub N7i,b time ^pdkat•an B' Ra+iult(NTU): -Tirrp_
,aitaLic(10 Nan)t I
,., ,.:... TSt (Ika,s(ottn)P1ue iltn4ti aa�rdmarbW,I Helot tun(s,Ycr'10k➢M10'StI0 U}.
r LION
Instrument Readings Cal Ltd W mCnrrrtec Mrnz
Date
(%setutation) �� 1 mmHg,•'� ^ Temperature(°[}: rime: >�.....i Lot Exp.Dale'
Dissolved Oxygen initial nitial(%): Cal(Yqr)' ,.. r p. •/� 4 - 0 nad
DO(Site t2nonl
'H mytT,nliraab14) _ � „ww„I ' "5..,I r Ton riW-..;
St
,. AIM �
Trye^�,. � toll .".. .• _. PM! w
QC Chick DO It
•.�� _,.. I Q tr Resu.
pHmV Cal(S.U.) �1� r
report Ilia
pto 0.1,U, Ntifis; ITime:
pH di S.U. mmlnlilvlr� pHmV: 1Cai1(S.R:➢..... PHmV:. _... ITime: ...e ..,. I� VS' �j
six report to 0.7 S.U. ...�»..,_..,_,.r-^ EMI I n�
� .m � t �
pH 10S.U. tlntt ail: pHm,'Mr• 'C'Ftinc �,
m ,-,—„ v. Time" I (1
re ri to 0.7 S.U. 2otx. IVJ11 IO '2:1
QC""pH T S.U. Hine; Result(S.U-): 'lime Result(S U) Time: �Resul'(S U.:
dJr ra 9.I SCA, ) l�-r 09 aR'
5 ;twd t" fndfuF Cal(pm�hoslcrD}, Time: 1 Q� ��
yl (L"J�
5 N�iercaD/ r d .,, 11 O ! �'I" ✓ . .,.I J I«". ^tea • rr 1 l a. pi(cal �I i1I.
Q
Speccoed 1 Time:���y Result(pmhos/cm); Time: " Result OJmhos/cm} h::
1,OOOpmhat(cm a..,} 1 y0 lags s ( V© 10b4 �L1�p� 1 Al �1
DC"5 Dchova Time, Result Cprn ._.. at s1 i® V Ug 2
_VS__ Ilnitlah Cal Temperature1 rt.):: Time: ,,k a 1,,.
ORP _mV y t
Ana�I➢yst Signature "�" �,, ,
�S �
,� ..a �� � ) ,+� Analyst Name: ^!m. .. - S�
Notes: �i " ..... �.. uu...... . �,.".,r ,� c .' .. . � w," ^ ., Date: ^7 .rv 'I d
Revision fi 12/20/20,MAR
Y W'') 1
I kna(r'slily/ntu Insr at eat bruted In at ryrruantc,with inn wren,Ili 1:u i^r I rptla".fro,0:01 1lad, 9 1
l'S Sports totounl.iwlhny si ri lid Reim cal Uwaaa l e tredlr g ID'awl,ra tr nen ntsrr ri I I s tt reerpe..
r.Cedar'as l ollbruilii in as talluws rnr,Vlu bend Pa,lllte ay pit 1,pti d pal In,I I Ullt,QC rheas
4'Oh,pa lOr^ira n;gCIO trtrti 001 at maaatt tamp a sites trt City teritnciliCr le 1 Cant al r ll 0[(mato,Inuit N tat is t alt,11 at r torn ale v s,te prior co analysis,
CC Acceptable Asnya s pH ti.,C 15 I,A zee llappettit,Con tvt y IC`B of the'a u Ire It ct,,,7,roarlpags ore mil in1 ramp,,i on k m:unison needs to be recelibrated
e"^ITV.chess most he ow In:old ate l emxuItaing erAl Inatr.mace''5 run plea an dA ratliplin9 at a ri'lliiirrorn QC IIiL e MUM be parkson ref with calibraboe standard Prom a separate lot a as the initial QC
P N tosnoneyr..C"valuwa Obbleinrd,k11,1,lneri'r.Ink;vaw00,utrlaa2Jarn1 n KM
3 Ni:rie d Ca;nroarun Ceniih:,dme ItN r"Imrr raoa'T
7 ODIAMIErIblilE,n.'rnit sap to be rr.n,gild out with a single line,so itea q500,151 texts still legible,Viewed by The staff members initials and date
10 ll;l ss od5e"w"ita rwster„It DO:Alg ra.'tens end measurementt.,are pnrferrned MO ppt Salinity.
II,i anmllofam.a tiSk,
Abbreeletlons:
Method Reference:
,pmhos/ctl:miaom(tos per centimeter NTLe nephelometdc turbidity units Temperature:SM 2550 B-2010
`C degrees Celsius ORFt oxidation reductior,potential Specific conductivity:EPA Method 120.1,Rev.1512
00 dissolved oxygen sirs sedal number
DO:SM 45000 G•2017
mg/L•milligrams per liter S.U.:standard units SHi 5M4500-H"B-20t 1
mV:millivolt Spec Cand:Specirie Conductivity Turbidity SM 2130 B-2011
G1J
LaiAOf V' 1 ,G (Co- CoG Pagelorl

Hack) ip h rn CaS k ra10IA o(d /c ) t co s k...
?FA pyl ki °G LO f yir ..
a
ktaL40 ocias
1 aCPS%o
•.{19 re ccx-ciIpv M� -g'
twine-di ()Cif' e-u12 Seri .
bL pc.„ k,bt- X-P
Ytr "" 4,0 t o S ,9 « , 61 - - 1 )4 Q'IL 0495
pV ° —T t(‘) 1°0 t c/ A sw 0 i ( 3

CHAIN-OF-CUSTODY I Analytical Request Document
The Chain-of-Custody is a LEGAL DOCUMENT.All relevant fields must be completed accurately,
Submitting a sample via this chain of custody constitutes acknowledgment and acceptance of the Pace Terris and Conditions found at hops:/linfoparretahz mitltl6tslpas-standard- rms adf
Section A Section B Section C ---- --
Rewired Client information: Bernalred Project Information: Invoice Information: Pane: t Of i
L` ---.ANCHOR QEA OF NC,PLLC -_-. RePur-i To Sly Co€ilut un 'Oen/Ion- --_. __ -- -- -- -- - 1
p:.=se ;Haywood Str ',-‘1-: ---- - COPY To; =1 I., Canpany ffeT : i
E l ST a T v tea.-, Pur- : G A -.. --> Paco Quote.
Phone ta2S)7O7-527 1Faz Project Roams Lassonde Piss Pew Project k k A a tab ccel,
Lit teu Due Date r%l r"t v'.tl _... Pace PrortoO 1
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L _ cjJ�nkig ware SW j O i 1 t
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SAMPLE ID usam L Z 0.1 o u START END r rc :r2 a 1
One Character per box. '+5 v^' u w ---- - E `-' 0 0
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.1.,
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CHAIN-OF-CUSTODY/Analytical Request Document
-/ NceAnalytical* The Chain-of-Custody is a LEGAL DOCUMENT.All relevant fields must be Luirtpleted accurately.
vovet.saceNeszent
Section A Section B Section C Page: of
Required Client Information! Required Project Information: Invoice Intormatroe
ce,r4)8ny ., t r - ‘RePoc TV-.Crx .
2066967
A 1' = ' cut N i- , t,k(-- , - • , - ,.
Address: Cooy Tor ,.. - - -);7 ompany Name:C2, REGULATORY AGENCY
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11 tY ,----JC 2,Sgt) -:'1 021)k€t . ... , Ilrins: r NPDES 1— GROUND WATER -'-' DRINKING WATER
Purchase Order No.: Pace Quote - __
I- UST r RCRA r OTFIER
k 114 nuut,v-kw , ot:c -, Reference:
Pticz 1 , ifv-_-',., -pvt Pmject Neale. ‘,._ tx Pace Project
Manager ) ,.. Site Location ---
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Requested Due Data/TAT: Project Number. ;Pace PnDfila#- STATE-
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Requested Analysis Filtered(YIN)
Section D Matrix Codes
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COLLECTED Preservatives 5: 1 RequiredCliera Infomrabon LIMN(I Q.Q.DE
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Product P T; I START 1 FNINGRAI3 III
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SAMPLE ID
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Attachment 3
DEQ GW-59A — Compliance Report Form

GW-59A COMPLIANCE REPORT FORM Permit# WQ0004797
(Submit one each monitoring period with GIV-59forms.)
1..M Enter date monitoring results were due.(12/31/2
1/2o2i) Will this monitoring report(GW-59 and GW-59A) YES NO
be submitted after the established due date? X
2 Was any required information missing on the GW-59 report forms? YES NO
IF the answer to question 1 or 2 is"YES", list the space provided below
the well
l.iden..ti identification
�
in
beloww identification number(s)and
explain the problems encountered in obtaining the required information.
3 I Are any of the monitor wells in need of repair or maintenance(damaged casing,unlocked or missing cap,missing YES NO
identification plate,area overgrown,etc.)?If the answer is "Yes",",contact the Regional Office for guidance. X
4 Are any monitored constituents equal to or above the established standards? YES NO
If the answer to question 4 is"NO", skip to section 8.
If the answer to question 4 is"YES"list the affected wells individually with constituent(s)and concentration(s)
exceeding standards in the space provided below:
Nitrate (2L = l0mg/L): MW-7R® 26.0 mg/L
Fecal Coliform (Total Coliform 2L standard = 1.0 CFU/100mL): MW-5® 5.0 CFU/100mL
Tetrachloroethene (2L = 0.7mg/L): MW-5® 30.7mg/L; Trichloroethene 2L standard = 3.0mg/L: MW-5® 11..6mg/L
For the constituents identified inquestion 4 above,have standards been exce
eded previously for the YES NO
same constituent(s)in the same well(s)in the last two years? X
if the answer to question 5 is"NO", skip to section 8.
if the answer to question 5 is"YES",list in the space provided below,each well with constituent(s)exceeding
standards,concentration(s)reported, and sample collection date for each occurrence(for the last two years).
Nitrate Fecal Coliform Tetrachloroethene Trichloroethene
MW-7R (mg/L) MW-5 (CFU/100mL) Mw-5 (ug/L) MW-5
11/14/19: 17.1 11/14/19: 7 0 11/14/2019: 22.4 11/14/2019: 4.4 '..
05/06/20: 21.5 05/06/20: 8,0 11/6/2020: 0.80
11/06/20: 13.0 11/06/20: B.0 '.,.
5/11/21: 40.4
Are the g wells iS listet or bd in sectioneyond 5 locatede t t or beyond the review boundary? YX
6 monitoringY ry NO
MW-7If the answer is"YES",a groundwater quality problem maybe occurring. CONTACT THE REGIONAL
OFFICE IMMEDIATELY FOR GUIDANCE.If the answer is"NO",monitoring wells may be improperly
located;contact the Regional Office.
Is thepermitteem implementing previouslyinvolving
7 p g approved actions required by the Division this YES NO
groundwater quality problem? X
If the answer to question 7 is"YES", describe those actions in the space provided below.
If the answer to question 7 is"NO",contact the Reetional Office within 90 days an evaluation may be
required to determine the impact the waste disposal system is hawing at the review and compliance
boundaries surrounding(this facility„ Failure to do so may subject the permittee to a Notice of Violation,
fines,and/or penalties.
Fecal coliform, tetrachloroethene, and trichoroethene standard exceedances are in the background well, MW-5.
Elevated nitrate concentrations are likely due to root growth and decay of a dense mass of root matter found in MW-7R,
during monitoring well evaluation with down-hole camera in September 2021 The Regional Office was contacted and
recommended chlorination and removal of organic matter in MW-7R prior to next sampling event in May 2022.
8 The person completing this portion((G W-59A)of the monitoring report should sign below and
submit this
form with GW-59 forms for required wells to the address provided at the top of the current GW-59 form.
J hereby acknowledge that the above information was evaluated and the information submitted in this
report(Compliance Report GW-59A)is true and complete to the best of my knowledge.
_.
Signature of Permittee(or Authorized Agent) Date
Gil'-59A 12/8/2093

SUBMIT FORM ON YELLOW PAPER ONLY
-- - � �� a a\ O \® -;;7. \�\
Mail original � \\� � � \��� \ \ \\
GROUNDWATER QUALITY MONITORING: v -� e.and_I copyto: �� , \\_\ _,�\�_\�. -�
COMPLIANCE REPORT FORM \��, ��� ;\���
FACILITY INFORMATION Please 31 or Ty PERMIT Number: Expiration Date: /31/2026
Facility Name: Clement Pappas Non Discharge W00004797 UIC
Permit Name(if different): NPDES Other
Facility Address: 485 Brookside Camp Road TYPE OF PERMITTED OPERATION BEING MONITORED
Hendersonville 5" NC 28792 County Henderson ❑ Lagoon ❑ Remediation: Infiltration Gallery
0 Spray Field ❑ Remediation:
Contact Person: Blake Kehoe Telephone#: [phone] ❑ Rotary Distributor ❑ Land Application of Sludge
Weil Location/Site Name:Irrigation Area No. of wells to be sampled: 6 ❑ Water Source Heat Pump ❑ Other:
t� )
:SAMPUNG INFORMATION f if WELL
WELL ID NUMBER(from Permit): MW-4 Date sample collected: 10/28/2021 FIELD ANALYSES: WAS
Weil Depth: 18.17 ft. Well Diameter: 2 in. pH o0400 5.7 units Temp.noon: 16.3 °C DRY at
Depth to Water Level 82546:9.15 ft. below measuring point Screened Interval: 5 ft. to 15 ft. Spec. Cond. 000sa: 247.4 µMhos t °f
sampling,
Measuring Point is 2.43 ft.above land surface Relative M.P. Elevation: 2063.77 ft. Odor 00085: none check
8/Warne of water pumped/bailed before sampling: 0.97 gallons Appearance here: --1
Sar pl for metals were collected unfiltered: M YES 0 NO and field acidified: It YES ❑NO
RAT-OR > RMA
Date sample analyzed:1 Laboratory Name_ Pace Analytical Services Certification No. 37712
PARAMETERS NOTE:Values should reffectdissoIved and colloidal concentrations.
COD 00335 mg/L Nitrite(NO2)as N oos1s mg/L Pb-Lead o1051 ug/L
Coliform: MF Fecal 31616 <1.0 /100mL Nitrate(NO3)as N noun 0.084 mg/L Zn-Zinc o10s2 mg/L
Coliform: MF Total 31504 /100mL Phosphorus:Total as P noses <0.050 mg/L
(Note Use MPN method for highly turbid samples) Orthophosphate 70507 mg/L Other(Specify Compounds and Concentration Units)=
)ism Solids:Total 70300 161 mg/L Al-Aluminum 011os mg/L
pH(Lab)00403 units Ba-Barium o1007 ug/L
TOC oosso 3.1 mg/L Ca-Calcium noels mg/L
Chloride oosao 6.7
mg/L Cd-Cadmium 01027 ug/L
Arsenic o1002 ug/L Chromium:Total 01034 ug!L
Grease and Oils 00552 mg/L Cu-Copper o1042 mg/L ORGANICS: (by GC, GC/MS, HPLC)
Phenol 32730 ug/L Fe-Iron oloas ug/L (Specify test and method#.ATTACH LAB REPORT.)
Sulfate 00945 mg/L Hg-Mercury 71900 ug/L Lab Report Attached? a Yes(1) ❑ No(0)
pacific Conductance 00095 µMhos K Potassium 00937' _mg/L VOC 7873 method#
Total Ammonia oosso <0.10 mg/L Mg-Magnesium 00927 _ mg/L method#
(Ammonia Nitrogen,NH,as N,Ammonia Nitrogen,Total) Mn-Manganese moss ug/L , method#
TKN as N 00625 mg/L Ni-Nickel 01067 uglL , method#
_ I
For Remediation Systems Only(Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal%
I certify that,to the best of my knowledge and belief,the information submitted in this report is true accurate,and complete,and that the laboratory analytical data was produced using approved methods of analysis by a
T?'-at aet : ry _—he, l a, vus a€r at rear re-Y= rtt° ena€ries for-8U t' take �- izne7 thhe; il)ty of tines and Ore- a_fat knowing violations,- — \ — —
Blake Kehoe,Director Engineering4�/ a' .
Permittee(or Auttnoln` 3Agent)NameandTitle=Pfer=e/8mwa print or type Sty et (orA _ — Agent) (Date)
GW-59 Rev,06-07-2018

SUBMIT FORM ON YELLOW PAPER ONLY
Mail original .
GROUNDWATER QUALITY MONITORING: � °�
COMPLIANCE REPORT FORM and 1 copy to: \ ���_� .'' 'g
Please ?tom or Type FACILITY INFORMATION Please Number: Expiration Date: 7l31/2026
Facility Name: Clement Pappas Non-Discharge WQ0004797 UIC
Permit Name(if different): NPDES Other
Facility Address: 485 Brookside Camp Road TYPE OF PERMITTED OPERATION BEING MONITORED
Hendersonville NC 28792 Count
y Henderson CI Lagoon CI Remediation: Infiltration Gallery
E Spray Field ❑ Remediation:
Contact Person: Blake Kehoe Telephone#: [phone] CIRotary Distributor CILand Application of Sludge
Wall Location/Site Name:Irrigation Area No.of wells to be sampled: 6 ❑ Water Source Heat Pump ❑Other:
AMPLING INFORMATION If WELL
WELL ID NUMBER(from Permit): MW-5 Date sample collected: 10/28/2021 FIELD ANALYSES: WAS
Welt Depth: 18.58 ft. Well Diameter: 2 in. pH 00400. 5.7 units Temp. o0o10: 16.0 °C DRY at
Brits of
Depth to Water Level 82546:9.44 ft.below measuring point Screened Interval: 9 ft. to 19 ft. Spec. Cond. 00094: 81.9 µMhos saripling,
Measuring Point is 3.00 ft.above land surface Relative M.P.Elevation: 2085.60 ft. Odor moss none check
Volume of water pumped/bailed before sampling: 0.69 gallons Appearance here:0
Samples for metals were collected unfiltered: *DYES 0 NO and field acidified: it YES 0 NO
ORATORY RMATION
Date sample analyzed:10/28/2021 Laboratory Name: Pace Analytical Services Certification No. 37712
PARAMETERS NOTE:Values should reflect dissolved and colloidal concentrations.
COD 00335 mg/L Nitrite(NO2)as N 00615 mg/L Pb-Lead 01051 ug/L
Coliform: MF Fecal 31616
5.0 /100mL Nitrate(NO3)as N 00620 <0.040 mg/L Zn-Zinc elm mg/L
Coliform: MF Total 31504 /100mL Phosphorus:Total as P oosss 0.054 mg/L
(Note Use MPN method for highly turbid samples) Orthophosphate 70507 mg/L Other(Specify Compounds and Concentration Units):
Dissolved Solids:Total 70300 76.0 mg/L Al-Aluminum o11os mg/L Tetrachloroethene-30.7 pg/L
pH (Lab)00403 units Ba-Barium 01007 uglL Trichloroethene-11.6 pg/L
TOC acme 6.6 mg/L Ca-Calcium oo91s mg/L Cis-1,2-dichloroethene-12.6 pg/L
Chloride 00940 17.3 mg/L Cd-Cadmium 01027 ug/L
Arsenic olooz ug/L Chromium: Total 01034 uglL
Grease and Oils oossz mg/L Cu-Copper 01042 mg/L ORGANICS: (by GC,GC/MS, HPLC)
Phenol 32730 uglL Fe-Iron 01oas ug/L (Specify test and method#.ATTACH LAB REPORT.)
Sulfate 000ss mg/L Hg-Mercury 71900 uglL Lab Report Attached? le Yes(1) ❑ No(0)
Specific Conductance cocas µMhos K-Potassium 00937 mg/L VOC 7873 , method#
Total Ammonia 00610 <0.10 mg/L Mg-Magnesium 00927 mg/L , method#
(Ammonia Nitrogen,NH,as N,Ammonia Nitrogen,total) Mn-Manganese moss ug/L , method#
TKN as N o0szs mg/L Ni-Nickel et067 ug/L , method#
For Remediation Systems Only(Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal%
r`cert€fy that,to the pest of my knowledge and t3 Ise$ the information submitted rn this report s true,accurate and complete,and that the laborato€y analytical data was produced using approved rrtethbds of naty_€_ .}v
L3NtIR-carlfied ori- I am aware that there are significant penalties for simmittime_false mfdilnat or€_:Prt�;uding the vassiblily of fi-2es and imprisonment for knowing violations. - _
Blake Kehoe,Director Engineering � Z �
Permittee(or Authorized Agent)Name and Title-Please print or type S�ti of Perm€ltee terAut--. 4 A rrtl Male)
GW-59 Rev.06-07-2018

SUBMIT FORM ON YELLOW PAPER ONLY
Mail original ` -N- \ „..
GROUNDWATER QUALITY MONITORING: and 1 a �' \� o�\ N\\ � ��\
COMPLIANCE REPORT FORM copy \ _..~\ \\
FACILITY INFORMATION Plea. PM a y or Type PERMIT Number: Expiration Date: 7/31/2026
Facility Name: Clement Pappas Nan-Discharga WQ0004797 UIC
Permit Name(if different): NPDES Other
Facility Address: 485 Brookside Camp Road TYPE OF PERMITTED OPERATION BEING MONITORED
Hendersonville NC 28792 County Henderson ❑ Lagoon ❑ Remediation: Infiltration Gallery
a Spray Field ❑ Remediation:
Contact Person: Blake Kehoe Telephone#: [phone] D Rotary Distributor ❑ Land Application of Sludge
Well Location/Site Name:Irrigation Area No.of wells to be sampled: 6 ❑ Water Source Heat Pump ❑Other:
A
All PI NINFORMATIONIf WELL
I ID NUMBER(from Permit): MW-6 Date sample collected: 10/28/2021 FIELD ANALYSES: WAS
11.60 17.1 DRY at
Well Depth; ft. Well Diameter: 2 in. pH moo 5.4 units Temp.o0010: C
Depth to Water Level 82546:5.94 ft. below measuring point Screened Interval: 5 ft. to 10 ft. Spec.Cond.00094: 150.4 µMhos time
of
sampling,
Measuring Point is 3.00 ft.above land surface Relative M.P.Elevation: 2061.17 ft. Odor o0085; none check
Plum of water pumped/bailed before sampling: 1.70 gallons Appearance here:r-7
�tp( for metals were collected unfiltered EYES= ❑ NO and field acidified: YES El Appearance
LABORATORY RY INFORMATION
Date sample analyzed:10/28/2021 Laboratory Name: Pace Analytical Services Certification No. 37712
PARAMETERS NOTE:Values should reflect dissolved and colloidal concentrations.
COD 00335 mg/L Nitrite(NO2)as N 00615 mg/L Pb-Lead()lost ug/L
Coliform: MF Fecal 31616 <1.0 /100mL Nitrate(NO3)as N 00620<0.040 mg/L Zn-Zinc o1092 mg/L
Coliform: MF Total 31504 /100mL Phosphorus.Total as P 00665 <0.050 mg/L
(Note Use MPN method for highly turbid samples) Orthophosphate 70507 _ mg/L Other(Specify Compounds and Concentration Units):
)I salved Solids:Total 70300 85.0 mg/L Al-Aluminum o11os mg/L
pH(Lab)00403 units Ba-Barium 01007 ug/L
TOC 00680 2.3 mg/L Ca-Calcium o0916 mg/L _
Chloride 00940 8.7 mg/L Cd-Cadmium 01027 ug/L
Arsenic 010oz ug/L Chromium:Total 01034 ug/L
Grease and Oils 00552 mg/L Cu-Copper 01042 mg/L ORGANICS:(by GC, GC/MS, HPLC)
Phenol 32730_ ug/L Fe-Iron 61045 ug/L (Specify test and method#.ATTACH LAB REPORT.)
Sulfate 00945 mg/L Hg-Mercury 71900 ug/L Lab Report Attached? ❑■ Yes(1) ❑ No(0)
Spec Conductance 00095 µMhos K-Potassium 00937 mg/L VOC 7873 _, method#
Total Ammonia o0610 <0.10 mg/L Mg-Magnesium 00927 mg/L , method#
(Ammonia Nitrogen;NH3 as N,Ammonia Nitrogen,Total) Mn-Manganese 01055 Ug/L , method#
TKN as N oo625 mg/L Ni-Nickel 01067 ug/L ,method#
For Remediation Systems Only(Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal%
I certify hat_lu the beat ca ,y roivwteuy�.alit.LJ,ot,t=.0 information suv,,,rttes,in this'tepv 2 a true,accurate,an;.complete a,id that the laboratory analytical data was produced using approved methods of analysis by a
CWR cert=fi y tarn aware that there are s grtrfr nt perms[ for subm€tti g false€nfori tsor €nclr r 'the kf €af i9res a?d r '-fit=for knowing_violat ons
Blake Kehoe,Director Engineering � 20-
Permittee(or Authorized Agent)Name and Title-Please print or type _. flee(or ut) A nt) t `o
GW-59 Rev.06-07-2018

SUBMIT FORM ON YELLOW PAPER ONLY
Mail original \
GROUNDWATER QUALITY MONITORING: ��� ��� °�-� � � �
copyand 9fa •o��oo ®"��� �
COMPLIANCE REPORT FORM �,, o����,,,, �, ,��,,, �„y O
FACILITY INFORMATION Reese Pane Clearly or Ty PERMIT Number: Expiration Date: 7/31/2026
Facility Name; Clement Pappas Non-Discharge WQ0004797 UIC
Permit Name(if different)- NDES Other
Facility Address: 485 Brookside Camp Road TYPE OF PERMITTED OPERATION BEING MONITORED
Hendersonville �
NC 28792 County Henderson CI Lagoon ❑Remediation: Infiltration Gallery
❑■ Spray Field El Remediation:
Contact Person: Blake Kehoe Telephone#: [phone] ❑ Rotary Distributor CILand Application of Sludge
Well Location/Site Name:Irrigation Area No.of wells to be sampled: 6 ❑ Water Source Heat Pump ❑Other:
SAMPLINGINFORMATION mot€WELL
WELL ID NUMBER(from Permit): MW-7R _ Date sample collected: 10/27/2021 FIELD ANALYSES: WAS
Well Depth: 17.34 ft. Well Diameter: 2 in. pH oo400: 5.3 units Temp.000to: 16.0 °C DRY at
Mhos time of
Depth to Water Level 82546:11.74 ft.below measuring point Screened Interval: 5 ft. to 15 ft. Spec. Cond.moat 348.8 µ sampling,
Measuring Point is 3.00 ft.above land surface Relative M.P.Elevation: 2062.86 ft. Odor 00085: none Vic.
Volume of water pumped/bailed before sampling: 1.39 gallons Appearance here:--
Samples for metals were collected unfiltered: 11 YES ❑ NO and field acidified: A YES ❑NO
LABORATORY INFORMATION
Date sample analyzed:10/27/2021 Laboratory Name: Pace AneMi Services Certification No. 37712
PARAMETERS NOTE:Values should reflect dissolved and colloidal concentrations.
COD 00335 mg/L Nitrite(NO2)as N oos15 mg/L Pb-Lead olos1 ug/L
Coliform: MF Fecal 31616 <1.0 /100mL Nitrate(NO3)as N 00620 26.0 mg/L Zn-Zinc 01092 mg/L
Coliform: MF Total 31504 /100mL Phosphorus:Total as P oos65 <0.050 mg/L
(Note. Use MPN method for highly turbid samples) Orthophosphate 70507 mg/L Other(Specify Compounds and Concentration Units):
delved Solids:Total 70300 222 mg/L Al-Aluminum o11os mg/L
pH (Lab)00403 units Ba-Barium 01007 ug/L _
TOC 00680 1.1 mg/L Ca-Calcium owls mg/L
Chloride oosao 24.9 mg/L Cd-Cadmium 01027 ug/L
Arsenic olooz ug/L Chromium:Total 01034 ug/L
Grease and Oils o0552 mg/L Cu-Copper o1o42 mg/L ORGANICS: (by GC, GC/MS, HPLC)
Phenol 32730 ug/L Fe-Iron aims ug/L (Specify test and method#.ATTACH LAB REPORT.)
Sulfate 00945 mg/L Hg Mercury 71900 ug/L Lab Report Attached? Yes(1) ❑ No(0)
wax
Conductance mossµMhos K-Potassium 00937 mg/L VOC 7873 , method#
Total Ammonia oo610 <0.10 mg/L Mg-Magnesium 00927 mg/L _, method#
(Ammonia Nitrogen,NH3 as N,Ammonia Nitrogen,Tota€) Mn-Manganese o1o5s ug/L , method#
TKN as N o0625 mg/L Ni-Nickel 01067 ug/L method#
For Remediation Systems Only(Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs mg/L VOC Removal%
I certify that.to the best of ray knowledge arc€belief the information subrm fitted;n this repot istrue.accurate,and complete,and that the laboratory anaiycieal data was produced using approved methods of analysis by a
t2W§certified -.t -,I am aware that there are significani enalties for tes , _talse information i do the ',, of fines artsl mptisonmen,for known volations
Blake Kehoe,Director Engineering Z
Permittee(or Authorized Agent)Name and Title-Please print or type =.re arPerrnittee(or AlAftwised Agent) r<Ci
GW-59 Rev.06-07-2018

SUBMIT FORM ON YELLOW PAPER ONLY
Flail original\� - 1, ' \. ,,„ .
GROUNDWATER QUALITY MONITORING: \\ "� i-gy ��` \-
COMPLIANCE REPORT FORM an 'I copy to: \\�; 0-� �\`\aw..-.\ \�--\ \\\
FACILITY INFORMATION RMATIOiRMIT Number: Expiration Date: 7/31/2026
��Pontrrf y or Type
Facility Name: Clement Papp Non-Discharge
NDisch e WQ0004797 UIC
Pe
rmit Name(if different): _ NPDES Other
Facility Address: 485 Brookside Camp Road TYPE OF PERMITTED OPERATION BEING MONITORED
Hendersonville NC 28792 County Henderson ❑ Lagoon ❑ Remediation: Infiltration Gallery
Spray Field ❑ Remediation:
Contact Person: Blake Kehoe Telephone#: (2 ) 93-0711 ❑ Rotary Distributor ❑ Land Application of Sludge
Well Location/Site Name:Irrigation Area No.of wells to be sampled: 6 ❑ Water Source Heat Pump ❑Other:
( r
SA PUG INFORMATION If WELL
WELL.ID NUMBER(from Permit): MW-8 Date sample collected: 10/27/2021 FIELD ANALYSES: WAS
Well Depth_ 13.92 ft. Well Diameter: 2 in. pH 00400: 6.6 units Temp.Nolo: 15.3 °C DRY at
Depth to Water Level 82546:10.06 ft. below measuring point Screened Interval: 3 ft. to 13 ft. Spec.Cond.00094: 321.1 µMhos tirrie
of
Measuring Point is 3.00 ft. above land surface Relative M.P.Elevation: 2060.80 ft. Odor moss: none sr 1plingcheck
Volume of water pumped/bailed before sampling: 1.41 gallons Appearance heren
Samples for metals were collected unfiltered: lL YES ❑ NO and field acidified: U YES ❑NO ,,
OtATORY INFORMATION
Date sample anted:5/11/2021 Laboratory Name: Pace Analytical Services Certification No. 37712
PARAMETERS NOTE:Values should reflect dissolved and colloidal concentrations.
COD 00335 mg/L Nitrite(NO2)as N 00615 mg/L Pb-Lead o1os1 ug/L
Coliform: MF Fecal 31616 1.0 /100mL Nitrate(NO3)as N ooszo 0.86 mg/L Zn-Zinc 01092 mg/L
Coliform: MF Total 31504 /100mL Phosphorus:Total as P noses <0.050 mg/L
(Note Use MPN method for highly turbid samples) Orthophosphate 70507 mg/L Other(Specify Compounds and Concentration Units):
)tssolved Solids:Total 70300 189 mg/L Al-Aluminum 011n5 mg/L
pH(Lab)00403 units Ba-Barium 01007 ug/L
TOC oosso 4.7 mg/L Ca-Calcium noels mg/L
Chloride oosao 3.5 mg/L Cd-Cadmium 01027 ug/L
Arsenic 01002 ug/L Chromium: Total 01034 ug/L
Grease and Oils ooss2 mg/L Cu-Copper o1o42 mg/L ORGANICS:(by GC, GC/MS, HPLC)
Phenol 32730 ug/L Fe-Iron o10a5 ug/L (Specify test and method#.ATTACH LAB REPORT.)
Sulfate o0s45 mg/L Hg-Mercury 71900 ug/L Lab Report Attached? ❑■ Yes(1) ❑ No(0)
Specific Conductance moss µMhos K-Potassium 00937 mg/L VOC 7873 ,method#
Total Ammonia oosso <0.10 mg/L Mg-Magnesium 00927 mg/L ,method#
(Ammonia Nitrogen,NH3 as N,Ammonia Nitrogen,Total) Mn-Manganese 01055 ug/L , method#
TKN as N nos2s mg/L Ni-Nickel 01067 ug/L , method#
For Remediation Systems Only(Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs; mg/L VOC Removal%
,., m
r€try ihat,ta the best of�,y knit-Mediae and beltef the tnfo�i;5tion=ut�rr`itted in4?�i5'report is true,accurate and complete and that the daratory analytical data win produces using Approved met;€Oc9s of analysts by a
tfre 1 amakva t t' a \„ ;
L � 1 � . mPfi� et e eu5rnittneitl-T- :iiw'at�e . ,f1-1Tinest!f�"virnertttos, 'tto[ttsnc.-: - Y =, ; _ I'
Blake Kehoe,Director Engineering - ...,
Permittee(or Authorized Agent)Name and Title-Please print or type Signature dpermittee(or Authorized Ate) e)
GW-59 Rev.06-07-2018

SUBMIT FORM ON YELLOW PAPER ONLY
GROUNDWATER QUALITY MONITORING: �� O ���000�\\ ''\o�,'N���o \�\��� �\ �\
COMPLIANCE REPORT FORM �����`��`��y�---, ‘,---N-o��- -v-\vv�
FACILITY INFORMATION Reese Print Clearly or Toe PERMIT Number: Expiration Date: 7_/31/2o26
Facility Name: Clement Pappas Non-Discharge WQ0004797 UIC
Permit Name(if different): NPDES Other
Facility Address: 485 Brookside Camp Road TYPE OF PERMITTED OPERATION BEING MONITORED
Hendersonville s' NC 28792 Count
y Henderson ❑ Lagoon El Remediation: Infiltration Gallery
❑■ Spray Field ❑ Remediation:
Otaet Person: Blake Kehoe Telephone#: [phone] CI Rotary Distributor ❑ Land Application of Sludge
Well Location/Site Name:Irrigation Area No.of wells to be sampled: 6 El Water Source Heat Pump ❑Other:
SAMPLING INFORMATION If WPt
WELL ID NUMBER(from Permit): MW-9 Date sample collected: 10/27/2021 FIELD ANALYSES: WAS
Well Depth: 18.1 at
ft. Well Diameter: 2 in. pH moo. 5.4 units Temp.00o10: 17.6 °C DRY
time
Depth to Water Level 82546:5.57 ft. below measuring point Screened Interval: 3 ft. to 13 ft. Spec.Cond.00094: 71.2 µMhos of
saMplirtg,
Measuring Point is 1.44 ft. above land surface Relative M.P.Elevation: 2060.23 ft. Odor 00085: none
Volume of water pumped/bailed before sampling: 0.95 gallons Appearance hewn
Samples for metals were collected unfiltered: 'YES ❑ NO and field acidified: ❑■ YES El NO ,
LABORATORY INFORMATION
Date sample analyzed lea// 1 Laboratory Name: Pace Analytical Services Certification No. 37712
PARAMETERS NOTE:Valuesreflect le dissolved and colloidal concentrations.
COD 00335 mg/L Nitrite(NO2)as N oos15 mg/L Pb-Lead o1051 ug/L
Coliform: MF Fecal 31616 1.0 /100mL Nitrate(NO3)as N ooszo 0.35 mg/L Zn-Zinc 010s2 mg/L
Coliform:MF Total 31504 /100mL Phosphorus:Total as P 00665 <0.050 mg/L
(Note: Use MPN method for highly turbid samples) Orthophosphate 70507 mg/L Other(Specify Compounds and Concentration Units):
dissolved Solids:Total 70300 48.0 mg/L Al-Aluminum cows mg/L
pH (Lab)00403 units Ba-Barium 01007 ug/L
TOC 00680 3.8 mg/L Ca-Calcium oasis _mg/L
Chloride 00940 3.2 mg/L Cd-Cadmium 01027 ug/L
Arsenic o1002 ug/L Chromium:Total 01034 ug/L
Grease and Oils ooss2 mg/L Cu-Copper 01042 mg/L ORGANICS: (by GC,GC/MS, HPLC)
Phenol 32730 _ug/L Fe-Iron 01045 ug/L (Specify test and method#.ATTACH LAB REPORT.)
Sulfate 00945 mg/L Hg-Mercury 71900 ug/L Lab Report Attached? R Yes(1) ❑ No(0)
$pecific Conductance moss µMhos K-Potassium 0os37 mg/L VOC 7873 , method#
Total Ammonia noslo <0.10 mg/L Mg-Magnesium 00927 mg/L , method#
(Ammonia Nitrogen,NH3as N,Ammonia Nitrogen,Total) Mn-Manganese o1055 ug/L ,method#
TKN as N onus mg/L Ni-Nickel 01067 ug/L , method#
For Remediation Systems Only(Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal%
t Certify that,to the best of my knowledge and belief,the information submitted in this report is true Accurate,and complete_and that the laboratory analytical data was produced using approved methods of analysis by a
DWR-cAstifiAd taborato . t arrt:a *w that there arc nificant t
ry i ��fstr subrnt:ts�tatse tztfzarettatton i ��thi3 sslb#Ir' _ A- - �cht-krihsiiho iihi'gt h-_ _.... -
Blake Kehoe,Director Erig(eeeng
Petrottift ter Authorized Agent)Name anti Title Magee print or type - ure Pennittee(or Authdrftad Agent) (Data)
GW-59 Rev.06-07-2018